Method for improving corrosion resistance of high-nitrogen and low-nickel austenitic stainless steel

Abstract

The present application relates to a kind of methods for improving the corrosion resistance of high N low Ni austenitic stainless steel, belong to stainless steel hot working technology.The present application includes: (1) preparation of austenitic stainless steel raw material, smelting high N low Ni austenitic stainless steel, obtain cast blank;(2) the cast blank is pre-forging treatment, initial forging temperature is 1100-1150 ℃, final forging temperature is greater than or equal to 960 ℃, water cooling obtains pre-forging plate;(3) the forged plate is solid solution heat treatment, solid solution temperature is 1050 ℃, solid solution time is 40 min, then water cooling;(4) the sample after solid solution treatment is hot compression processing, water quenching after hot working obtains finished product;At 1050~1150 ℃ deformation temperature, 0.1~1s ‑1 Strain rate range hot working performance is best, can obtain uniform fine recrystallized grain and good corrosion resistance;At 1050 ℃ deformation temperature, 0.1s ‑1 Strain rate under hot compression obtains optimal pitting resistance performance, E b =1.08V;The present application replaces Ni by adding more N in austenitic stainless steel and improves corrosion resistance, improves the hot workability of austenitic stainless steel and the corrosion resistance of finished product by optimizing hot working parameters.

Description

Technical Field

[0001] This invention belongs to the field of stainless steel hot working technology, and relates to a method for improving the corrosion resistance of high-N, low-Ni austenitic stainless steel. Background Technology

[0002] High Ni content is a typical characteristic of austenitic stainless steel, usually ranging from 8-10%. It mainly acts as an austenite stabilizing element, giving stainless steel a stable austenitic structure. It can also improve the composition and structure of the passivation film on the metal surface, further enhancing the corrosion resistance of austenitic stainless steel.

[0003] Currently, adding inexpensive nitrogen (N) or manganese (Mn) to austenitic stainless steel is an effective way to replace nitrogen (Ni). At present, most low-Ni austenitic stainless steels contain more than 10% Mn. While increasing Mn content can effectively reduce Ni usage, higher Mn content increases the tendency for σ-phase precipitation and creates Cr-depleted zones, thus reducing the material's mechanical properties and pitting corrosion resistance. Furthermore, the addition of higher Mn leads to the formation of porous MnO in the stainless steel passivation film, further weakening the stainless steel's pitting corrosion resistance. High N addition also deteriorates the hot workability of austenitic stainless steel. The strengthening effect of N increases its resistance to high-temperature deformation, making hot deformation more difficult; high N addition intensifies the work hardening process, easily causing stress concentration and cracking during hot deformation; in addition, N also exacerbates the precipitation tendency of hard Cr₂N, further increasing the tendency for deformation cracking.

[0004] Application number CN201880066674.8 discloses a low-Ni austenitic stainless steel with excellent hot workability and resistance to hydrogen embrittlement, containing 0.15-0.30% Ni, but its pitting corrosion resistance equivalent value is only 18-22. Application number CN201710143972.X discloses a method for improving the hot plasticity of super austenitic stainless steel by adding boron and rare earth elements. This method requires precise control of the amount, method, and timing of boron and rare earth element addition to achieve the desired effect, and the addition of rare earth elements increases production costs. Therefore, it is essential to find a method that can reduce the use of Ni in austenitic stainless steel while ensuring its pitting corrosion resistance. Summary of the Invention

[0005] To address the problems in the background art, this invention provides a method for improving the corrosion resistance of high-N, low-Ni austenitic stainless steel. By controlling the strain rate and deformation temperature, the influence of hot deformation parameters on the hot working properties and pitting corrosion resistance of high-N, low-Ni austenitic stainless steel is optimized, thereby reducing the high production cost of austenitic stainless steel and providing better pitting corrosion resistance.

[0006] The technical solution adopted in this invention is as follows:

[0007] By adjusting the composition and combining the process, and by controlling the strain rate and deformation temperature, the corrosion resistance of high-N, low-Ni austenitic stainless steel can be improved.

[0008] The chemical composition of the high-N, low-Ni austenitic stainless steel formulation, by mass percentage, is as follows: C: 0.004–0.010%, Si: 0.10–0.12%, Mn: 2.10–2.20%, Cr: 22.00–23.00%, Ni: 1.20–1.30%, Mo: 2.60–2.70%, Cu: 0.10–0.15%, N: 0.65%–0.70%, P: ≤0.01%, S: ≤0.01%, with the balance being Fe and unavoidable impurities;

[0009] Specifically, the following steps are included:

[0010] (1) Prepare high-N low-Ni austenitic stainless steel raw materials according to the formula, and refine high-N low-Ni austenitic stainless steel in a vacuum melting furnace to obtain high-N low-Ni austenitic stainless steel billet.

[0011] (2) The high-N low-Ni austenitic stainless steel billet obtained in step (1) is pre-forged and then water-cooled to obtain pre-forged plate.

[0012] (3) The hot-rolled plate obtained in step (2) is subjected to solution heat treatment using a box-type resistance furnace, and then water-cooled to obtain a solution-treated plate.

[0013] (4) The solution heat-treated plate obtained in step (3) is processed to obtain a preheated and compressed sample.

[0014] (5) The preheated and compressed sample in step (4) is subjected to a homogenization treatment to obtain a sample at the corresponding deformation temperature. Then, hot compression processing is performed immediately. After the hot processing is completed, water cooling is performed immediately to obtain a hot-processed high-N low-Ni austenitic stainless steel finished product.

[0015] Preferably, in step (2) of the present invention, the initial forging temperature of the pre-forging treatment is controlled at 1100-1150℃, the final forging temperature is ≥960℃, and the forging ratio is 2-4.

[0016] Preferably, in step (3) of the present invention, the solution temperature is 1040-1060℃ and the solution time is 40min.

[0017] Preferably, in step (5) of the present invention, the conditions for tissue homogenization treatment are as follows: the hot-compressed sample is heated to 1200°C at a heating rate of 5°C / s, held for 300s, and then cooled to the deformation temperature at a cooling rate of 10°C / s, wherein the deformation temperature is 1050~1150°C, and held for 60s.

[0018] Preferably, in step (5) of the present invention, the deformation temperature is 1050-1150℃ and the time is 0.1-10s. -1 Hot compression processing is performed using strain rates ranging from 0.1 to 1 s. -1 The optimal strain rate corresponds to the optimal hot working range, resulting in good dynamic recrystallization softening behavior and good corrosion resistance; at a deformation temperature of 1050℃, a strain rate of 0.1s⁻¹ is achieved. -1 The best pitting resistance can be obtained by hot compression processing at a strain rate of [specific value], corresponding to a pitting potential E [specific value]. b =1.08V.

[0019] The beneficial effects of this invention are:

[0020] (1) By adjusting the elements and combining the processing technology, the present invention enables the high nitrogen and low nickel austenitic stainless steel to have better corrosion resistance. Under the processing technology conditions, nitrogen improves the corrosion resistance of the steel through solid solution strengthening, passivation effect, inhibition of precipitate formation and stabilization of austenitic structure. Compared with traditional high nickel stainless steel, the high nitrogen and low nickel austenitic stainless steel prepared by the present invention performs better in terms of corrosion resistance.

[0021] (2) In this invention, N is used to replace Ni, which is inexpensive and can save costs and is easy to operate. In this invention, by controlling the strain rate and deformation temperature, good recrystallization softening behavior in the hot deformation process can be obtained, and large-scale production can be easily achieved in industry.

[0022] (3) At 1050~1150℃ / 0.1~10s -1 Hot working was performed under the conditions of 1050℃ / 0.1s. -1 Under these conditions, the sample exhibits excellent resistance to pitting corrosion, with a pitting potential of Eb = 1.08V. The sample subjected to hot compression under these conditions shows great promise for development in structural materials for petroleum, chemical, shipbuilding, and new energy industries. Attached Figure Description

[0023] Figure 1 The rheological curves of Examples 1, 2, 3, and 4 after hot compression correction at different strain rates and deformation temperatures are shown in (a) 0.01 s. -1 / 850~1150℃; (b)0.1s -1 / 850~1150℃;(c)1s-1 / 850~1150℃;(d)10s -1 / 850~1150℃.

[0024] Figure 2 Example 1 at 0.01s -1 Microstructure of specimens after hot compression at different deformation temperatures at different strain rates: (a) 850℃; (b) 950℃; (c) 1050℃; (d) 1150℃.

[0025] Figure 3 Example 1 at 0.1s -1 Microstructure of specimens after hot compression at different deformation temperatures at different strain rates: (a) 850℃; (b) 950℃; (c) 1050℃; (d) 1150℃.

[0026] Figure 4 Example 1 at 1s- 1 Microstructure of specimens after hot compression at different deformation temperatures at different strain rates: (a) 850℃; (b) 950℃; (c) 1050℃; (d) 1150℃.

[0027] Figure 5 Example 1 at 10s -1 Microstructure of specimens after hot compression at different deformation temperatures at different strain rates: (a) 850℃; (b) 950℃; (c) 1050℃; (d) 1150℃.

[0028] Figure 6 The diagram shows the hot working of the experimental steel at 50% deformation (true strain = 0.67).

[0029] Figure 7 The cyclic voltammetric polarization test curves are for Example 1 after thermal compression.

[0030] Figure 8 The cyclic voltammetric polarization test curves after thermal compression in Example 2 are shown.

[0031] Figure 9 The cyclic voltammetric polarization test curves are for Example 3 after thermal compression.

[0032] Figure 10 The cyclic voltammetric polarization test curves after thermal compression in Example 4 are shown. Detailed Implementation

[0033] The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments, but the scope of protection of the present invention is not limited to the content described.

[0034] This invention obtains experimental steel and true stress-strain curves through hot compression deformation; draws hot working diagrams based on true stress-strain data to predict the material's hot deformation behavior; tests the material's pitting corrosion resistance under different deformation conditions through electrochemical analysis; and analyzes the influence of strain rate and deformation temperature on the material's hot deformation behavior and pitting corrosion resistance.

[0035] Example 1

[0036] The chemical composition (wt%) of the high-N, low-Ni austenitic stainless steel described in this embodiment is as follows: C: 0.005%, Si: 0.10%, Mn: 2.20%, Cr: 22.12%, Ni: 1.25%, Mo: 2.6%, Cu: 0.10%, N: 0.67%, P: ≤0.01%, S: ≤0.01%, with the balance being Fe and unavoidable impurities.

[0037] (1) A 50kg vacuum melting furnace was used to melt high-N low-Ni austenitic stainless steel to obtain a billet.

[0038] (2) The billet is pre-forged. The initial forging temperature of the steel ingot is 1100~1150℃, the final forging temperature is ≥960℃, the forging ratio is 2~4, and the forging is fast cooled.

[0039] (3) The rolled and water-cooled plate was solution-treated in a box-type resistance furnace at a temperature of 1050℃ for 40 minutes. After solution treatment, it was water-cooled. Then it was processed into a thermal simulation sample with a diameter × height of 8mm × 12mm.

[0040] (4) The thermal simulation specimen was subjected to metallographic homogenization treatment in a Gleeble-3800 thermal simulation tester. The homogenization treatment process was as follows: the pre-pressed specimen was heated to 1200℃ at a heating rate of 5℃ / s, held for 300s, and then cooled to the deformation temperature of 850~1150℃ at a cooling rate of 10℃ / s (as shown in Table 1), and held for 60s.

[0041] (5) Hot compression thermal simulation experiments were conducted using a Gleeble-3800 thermal simulation testing machine, with deformation temperatures of 850, 950, 1050, and 1150℃, and a duration of 0.01s. -1 The strain rate was subjected to single-pass hot compression with a deformation of 50%. After deformation, the material was immediately water-cooled to maximize the preservation of the high-temperature deformed microstructure.

[0042] (6) The obtained hot-compressed sample was electrochemically etched with 10% acetic acid at a DC voltage of 5V for 100s.

[0043] (7) The hot-compressed sample obtained in step 5 was subjected to potentiodynamic design test using a three-electrode system to obtain the polarization curve and pitting resistance of the austenitic stainless steel under the deformation condition.

[0044] In this embodiment, at 0.01s -1 The rheological curves obtained by strain rate and hot compression at temperatures of 850–1150 °C are shown below. Figure 1 As shown in (a), at lower deformation temperatures, the rheological curve exhibits dynamic recovery characteristics, and the rheological stress increases rapidly with the increase of strain. Figure 2 For 0.01s -1 Microstructure after deformation at strain rates and temperatures of 850–1150 °C. No dynamic recrystallized grains appeared after deformation at 850 °C, while fine recrystallized grains formed at 950 °C. As the deformation temperature increased to 1050–1150 °C, the austenite underwent good dynamic recrystallization softening, resulting in a reduction of the deformed microstructure and the formation of uniform recrystallized grains. Table 1 shows the electrochemical parameters fitted by the polarization curves. Lower strain rates are detrimental to the pitting corrosion resistance of high-N austenitic stainless steel, and the electrochemical parameters under the four deformation temperature conditions differ significantly from those in the solid solution state.

[0045] Table 1

[0046]

[0047] Example 2

[0048] The chemical composition (wt%) of the high-N, low-Ni austenitic stainless steel described in this embodiment is as follows: C: 0.005%, Si: 0.10%, Mn: 2.20%, Cr: 22.12%, Ni: 1.25%, Mo: 2.6%, Cu: 0.10%, N: 0.67%, P: ≤0.01%, S: ≤0.01%, with the balance being Fe and unavoidable impurities.

[0049] (1) High-N low-Ni austenitic stainless steel was melted in a 50kg vacuum melting furnace to obtain a billet;

[0050] (2) The billet is pre-forged. The initial forging temperature of the steel ingot is 1100~1150℃, the final forging temperature is ≥960℃, the forging ratio is 2~4, and it is rapidly cooled after forging.

[0051] (3) The rolled and water-cooled plate was solution-treated in a box-type resistance furnace at a temperature of 1050℃ for 40 minutes. After solution treatment, it was water-cooled. Then it was processed into a thermal simulation sample with a diameter × height of 8mm × 12mm.

[0052] (4) The thermal simulation specimen was subjected to metallographic homogenization treatment in the Gleeble-3800 thermal simulation tester. The homogenization treatment process was as follows: the pre-pressed specimen was heated to 1200℃ at a heating rate of 5℃ / s, held for 300s, and then cooled to the deformation temperature of 850~1150℃ at a cooling rate of 10℃ / s, and held for 60s.

[0053] (5) Hot compression thermal simulation experiments were conducted using a Gleeble-3800 thermal simulation testing machine, with deformation temperatures of 850, 950, 1050, and 1150℃, and a duration of 0.1s. -1 The strain rate was subjected to single-pass hot compression with a deformation of 50%. After deformation, the material was immediately water-cooled to maximize the preservation of the high-temperature deformed microstructure.

[0054] (6) The obtained hot-compressed sample was electrochemically etched with 10% acetic acid at a DC voltage of 5V for 100s.

[0055] (7) The hot-compressed sample obtained in step 5 was subjected to potentiodynamic design test using a three-electrode system to obtain the polarization curve and pitting resistance of the austenitic stainless steel under the deformation condition.

[0056] In this embodiment, at 0.1s -1 The rheological curves obtained by strain rate and hot compression at temperatures of 850–1150 °C are shown below. Figure 1 As shown in (b), when the deformation temperature is 1050℃, the rheological curve exhibits obvious dynamic recrystallization characteristics. The softening effect of dynamic recrystallization offsets the hardening effect caused by hot working. Figure 8 The strain rate is 0.1 s. -1 The cyclic voltammetric polarization test curves show no obvious passivation region at 850℃. Figure 3 The microstructure revealed no obvious recrystallized grains in the austenite, and the structure consisted of non-uniform compressed grains. The Eb and Eb-Ecoor values ​​of the sample at 1050℃ were 1.08 and 1.28V, respectively, which are close to the pitting corrosion resistance of the sample in the solution state.

[0057] Table 2

[0058]

[0059] Example 3

[0060] The chemical composition (wt%) of the high-N, low-Ni austenitic stainless steel described in this embodiment is as follows: C: 0.005%, Si: 0.10%, Mn: 2.20%, Cr: 22.12%, Ni: 1.25%, Mo: 2.6%, Cu: 0.10%, N: 0.67%, P: ≤0.01%, S: ≤0.01%, with the balance being Fe and unavoidable impurities.

[0061] (1) A 50kg vacuum melting furnace was used to melt high-N low-Ni austenitic stainless steel to obtain a billet.

[0062] (2) The billet is pre-forged. The initial forging temperature of the steel ingot is 1100~1150℃, the final forging temperature is ≥960℃, the forging ratio is 2~4, and the forging is fast cooled.

[0063] (3) The rolled and water-cooled plate was solution-treated in a box-type resistance furnace at a temperature of 1050℃ for 40 minutes. After solution treatment, it was water-cooled. Then it was processed into a thermal simulation sample with a diameter × height of 8mm × 12mm.

[0064] (4) The thermal simulation specimen was subjected to metallographic homogenization treatment in the Gleeble-3800 thermal simulation tester. The homogenization treatment process was as follows: the pre-pressed specimen was heated to 1200℃ at a heating rate of 5℃ / s, held for 300s, and then cooled to the deformation temperature of 850~1150℃ at a cooling rate of 10℃ / s, and held for 60s.

[0065] (5) Hot compression thermal simulation experiments were conducted using a Gleeble-3800 thermal simulation testing machine, with deformation temperatures of 850, 950, 1050, and 1150℃, and the tests were performed for 1 second. -1 The strain rate was subjected to single-pass hot compression with a deformation of 50%. After deformation, the material was immediately water-cooled to maximize the preservation of the high-temperature deformed microstructure.

[0066] (6) The obtained hot-compressed sample was electrochemically etched with 10% acetic acid at a DC voltage of 5V for 100s.

[0067] (7) The hot-compressed sample obtained in step 5 was subjected to potentiodynamic design test using a three-electrode system to obtain the polarization curve and pitting resistance of the austenitic stainless steel under the deformation condition.

[0068] In this embodiment, in 1s -1 The rheological curves obtained by strain rate and hot compression at temperatures of 850–1150 °C are shown below. Figure 1 As shown in (c), at 850℃, the flow stress continuously increases with the increase of strain, indicating that the increase of strain rate intensifies the work hardening process. When the temperature rises to 950-1050℃, the flow stress decreases slightly after reaching its peak, indicating that the increase of temperature weakens the work hardening effect; at 1150℃, the flow stress tends to stabilize after rising. Figure 9 The strain rate is 1s -1 The cyclic voltammetric polarization test curves show that the sample exhibits the best pitting corrosion resistance when the temperature increases to 950℃, and the pitting corrosion resistance decreases with increasing temperature.

[0069] Table 3

[0070]

[0071] Example 4

[0072] The chemical composition (wt%) of the high-N, low-Ni austenitic stainless steel described in this embodiment is as follows: C: 0.005%, Si: 0.10%, Mn: 2.20%, Cr: 22.12%, Ni: 1.25%, Mo: 2.6%, Cu: 0.10%, N: 0.67%, P: ≤0.01%, S: ≤0.01%, with the balance being Fe and unavoidable impurities.

[0073] (1) A 50kg vacuum melting furnace was used to melt high-N low-Ni austenitic stainless steel to obtain a billet.

[0074] (2) The billet is pre-forged. The initial forging temperature of the steel ingot is 1100~1150℃, the final forging temperature is ≥960℃, the forging ratio is 2~4, and the forging is fast cooled.

[0075] (3) The rolled and water-cooled plate was solution-treated in a box-type resistance furnace at a temperature of 1050℃ for 40 minutes. After solution treatment, it was water-cooled. Then it was processed into a thermal simulation sample with a diameter × height of 8mm × 12mm.

[0076] (4) The thermal simulation specimen was subjected to metallographic homogenization treatment in the Gleeble-3800 thermal simulation tester. The homogenization treatment process was as follows: the pre-pressed specimen was heated to 1200℃ at a heating rate of 5℃ / s, held for 300s, and then cooled to the deformation temperature of 850~1150℃ at a cooling rate of 10℃ / s, and held for 60s.

[0077] (5) Hot compression thermal simulation experiments were conducted using a Gleeble-3800 thermal simulation testing machine, with deformation temperatures of 850, 950, 1050, and 1150℃ being tested for 10 seconds in sequence. -1 The strain rate was subjected to single-pass hot compression with a deformation of 50%. After deformation, the material was immediately water-cooled to maximize the preservation of the high-temperature deformed microstructure.

[0078] (6) The obtained hot-compressed sample was electrochemically etched with 10% acetic acid, DC voltage 5V, time 100s.

[0079] (7) The hot-compressed sample obtained in step 5 was subjected to potentiodynamic design test using a three-electrode system to obtain the polarization curve and pitting resistance of the austenitic stainless steel under the deformation condition.

[0080] In this embodiment, 10s -1 The rheological curves obtained by strain rate and hot compression at temperatures of 850–1150 °C are shown below. Figure 1 As shown in (d), the thermal deformation time of the material is very short at this strain rate. As the strain increases, the rheological stress rapidly increases to a peak value and then tends to stabilize. Figure 6 This is a hot working diagram at a true strain of 0.67. The contour lines represent energy dissipation rates, the shaded areas are rheological instability regions, and the white areas are safe zones. Higher power dissipation efficiency values ​​indicate that more energy is consumed in microstructure evolution, generally accompanied by dynamic recrystallization, at temperatures below 1050℃ and strain rates below 0.1 s⁻¹. -1 At this time, the power dissipation efficiency values ​​are all relatively small, and the actual thermal activation energy used to trigger dynamic recrystallization is very small. Therefore, the microstructure does not exhibit dynamic recrystallization characteristics. Thus, the optimal hot working range for the experimental steel is a temperature of 1050–1150℃ and a strain rate of 0.1–10 s⁻¹. -1 The heat dissipation coefficient in this region reaches over 0.47; Table 4 shows the electrochemical parameters of the polarization curve fitting. It can be seen from the table that the increase of deformation temperature can appropriately improve the pitting corrosion resistance. At 1150℃, Eb=0.901V and Eb-Ecoor=1.127V.

[0081] Table 4

[0082]

Claims

1. A method for improving the corrosion resistance of high-N, low-Ni austenitic stainless steel, characterized in that, By adjusting the composition and combining the process, and by controlling the strain rate and deformation temperature, the corrosion resistance of high-N, low-Ni austenitic stainless steel can be improved. The chemical composition of the high-N, low-Ni austenitic stainless steel formulation, by mass percentage, is as follows: C: 0.004–0.010%, Si: 0.10–0.12%, Mn: 2.10–2.20%, Cr: 22.00–23.00%, Ni: 1.20–1.30%, Mo: 2.60–2.70%, Cu: 0.10–0.15%, N: 0.65%–0.70%, P: ≤0.01%, S: ≤0.01%, with the balance being Fe and unavoidable impurities; Specifically, the following steps are included: (1) Prepare high-N low-Ni austenitic stainless steel raw materials according to the formula, and refine high-N low-Ni austenitic stainless steel using a vacuum melting furnace to obtain high-N low-Ni austenitic stainless steel billets. (2) The high-N low-Ni austenitic stainless steel billet obtained in step (1) is pre-forged and then water-cooled to obtain pre-forged plate. (3) Use a box-type resistance furnace to perform solution heat treatment on the hot-rolled plate obtained in step (2), and then water cool it to obtain a solution heat-treated plate. (4) The solution heat-treated plate obtained in step (3) is processed to obtain a preheated and compressed sample; (5) The preheated and compressed sample in step (4) is subjected to a homogenization treatment to obtain a sample at the corresponding deformation temperature. Then, hot compression processing is performed immediately. After the hot processing is completed, water cooling is performed immediately to obtain a hot-processed high-N low-Ni austenitic stainless steel finished product.

2. The method for improving the corrosion resistance of high-N, low-Ni austenitic stainless steel according to claim 1, characterized in that: In step (2), the initial forging temperature of the pre-forging treatment is controlled at 1100-1150℃, the final forging temperature is ≥960℃, and the forging ratio is 2-4.

3. The method for improving the corrosion resistance of high-N, low-Ni austenitic stainless steel according to claim 1, characterized in that: In step (3), the solution temperature is 1040-1060℃ and the solution time is 40min.

4. The method for improving the corrosion resistance of high-N, low-Ni austenitic stainless steel according to claim 1, characterized in that: In step (5), the conditions for tissue homogenization are as follows: the hot-compressed sample is heated to 1200°C at a heating rate of 5°C / s, held for 300s, and then cooled to the deformation temperature of 1050-1150°C at a cooling rate of 10°C / s, and held for 60s.

5. The method for improving the corrosion resistance of high-N, low-Ni austenitic stainless steel according to claim 1, characterized in that: In step (5), the deformation temperature is 1050–1150℃, and the time is 0.1–1s. -1 The strain rate is used for hot compression processing.

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