A green hydrogen production and combined heat and power supply device based on solar energy conversion

By introducing water circulation electrolysis and high-heat water insulation technology into solar energy production equipment, the problems of high-temperature water discharge and thermal energy utilization are solved, and high energy utilization and safety are achieved.

CN119913539BActive Publication Date: 2025-06-20JIANGSU CHANGHYDROGEN TECH ENG RES INST CO LTD
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Patent Information

Application Number
CN202510414252.7
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-04-03
Publication Date
2025-06-20
Estimated Expiration
2045-04-03

AI Technical Summary

Technical Problem

The existing solar energy production equipment has problems of waste of resources and degradation of equipment material performance in terms of high-temperature water discharge and thermal energy utilization.

Method used

A green hydrogen production and co-heating supply equipment based on solar energy conversion is designed. By setting up an ion resin exchanger on the electrolytic tank for water circulation electrolysis, and using high-heat chemical reaction water in the heat exchanger for insulation, improving the thermal energy utilization rate, and using leakage-proof disks and rubber blocks in the leakage prevention mechanism to prevent hydrogen leakage.

Benefits of technology

The production of green hydrogen with high energy utilization and combined heat and power supply is achieved, which prevents high-temperature water heat loss, reduces the thermal stress of equipment materials, and improves the safety and protection of equipment.

✦ Generated by Eureka AI based on patent content.

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Abstract

The present invention discloses a green hydrogen production and cogeneration equipment based on solar energy conversion, which relates to the field of energy utilization technology, including a cabinet, one side of which is provided with a solar cell panel, and the interior of the cabinet is fixedly connected with an electrolysis tank for electrolyzing circulating water, and by conveying high-calorie chemical reaction water into the interior of an ion resin exchanger, not only can the ions of the chemical reaction water be removed, so that the chemical reaction water is purified and then re-enters the interior of the electrolysis tank, thereby circulating and electrolyzing the water, but also the entire first cooling water pipe can be wrapped during the conveying process to insulate the high-temperature water that is about to enter the interior of the heat exchanger, effectively preventing the high-temperature water from losing heat when passing through the first cooling water pipe, thereby causing the subsequent heat exchange efficiency between the high-temperature water and the water extracted from the water tank to be reduced, thereby achieving a high energy utilization effect.
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Description

Technical Field

[0001] The present invention relates to the technical field of energy utilization, and particularly to a green hydrogen production and combined heat and power supply device based on solar energy conversion. Background Art

[0002] Producing green hydrogen from solar energy is a technology that uses solar energy to decompose water into hydrogen and oxygen, which has the advantages of being clean, renewable, and having zero carbon emissions, and is an important development direction in the future energy field.

[0003] The principle of producing green hydrogen from solar energy is that solar panels absorb sunlight and convert light energy into electrical energy. The electrolyzer is used to electrolyze water with the electrical energy. Water molecules are decomposed into hydrogen and oxygen in the electrolyzer. The electrolyzer usually consists of an anode, a cathode, and an electrolyte. Under the action of an electric field, water molecules lose electrons at the anode and undergo an oxidation reaction to generate oxygen, while at the cathode, they gain electrons and undergo a reduction reaction to generate hydrogen.

[0004] Hydrogen combined heat and power supply means that after the generated hydrogen and oxygen enter the fuel cell, an electrochemical reaction will occur inside the fuel cell, directly converting chemical energy into electrical energy, while generating heat energy and water, and the generated electrical energy and heat energy are utilized. The overall energy utilization rate can generally reach more than 90%.

[0005] After high-temperature water is generated by the chemical reaction of hydrogen and oxygen, the staff will store the generated high-temperature water centrally and then discharge it into the environment separately. Discharging the high-temperature water that has undergone a chemical reaction will not only affect the surrounding environment, but also reduce the utilization rate of the heat energy of the high-temperature water, resulting in waste of resources. Moreover, the discharge of high-temperature water may cause the equipment to bear greater thermal stress, leading to a decline in the performance of the equipment materials, and even problems such as cracks and deformation.

[0006] Therefore, it is necessary to design a green hydrogen production and combined heat and power supply device based on solar energy conversion with high energy utilization rate. Summary of the Invention

[0007] The purpose of the present invention is to provide a green hydrogen production and combined heat and power supply device based on solar energy conversion to solve the problems raised in the above background art.

[0008] To solve the above technical problems, the present invention provides the following technical solution: A green hydrogen production and combined heat and power supply device based on solar energy conversion, including a cabinet body. A solar panel is provided on one side of the cabinet body. An electrolysis tank for electrolyzing circulating water is fixedly connected inside the cabinet body. An electrolysis cell is provided inside the electrolysis tank. The solar panel is used to convert light energy into electrical energy to supply power to the electrolysis cell. A water tank for storing domestic hot water is provided on one side of the electrolysis tank. A heat exchanger is fixedly connected to the upper side of the water tank. A reaction mechanism for producing electrical energy and heat energy is provided on the upper side of the heat exchanger. An ion resin exchanger for removing impurities and ions from the chemical reaction water generated by the reaction mechanism is provided on one side of the reaction mechanism.

[0009] According to the above technical solution, an oxygen output end and a hydrogen output end are respectively provided on the upper side of the electrolysis tank. The oxygen output end and the hydrogen output end are respectively fixedly connected with an oxygen pipe and a hydrogen pipe. A leak prevention mechanism for preventing hydrogen leakage is provided on the outer side of the hydrogen pipe.

[0010] According to the above technical solution, the reaction mechanism includes a heat dissipation plate fixedly connected inside the cabinet body. A fuel cell is fixedly connected inside the heat dissipation plate. An oxygen input end, a hydrogen input end, a power generation end, and a water output end are respectively provided on the outer side of the fuel cell. The other end of the oxygen pipe is fixedly connected to the oxygen input end of the fuel cell. The other end of the hydrogen pipe is provided with a charging socket and is fixedly connected to the hydrogen end of the fuel cell. The water output end of the fuel cell is fixedly connected with a first water pipe. The other end of the first water pipe penetrates and is connected with a water guide pipe. The other side of the water guide pipe is fixedly connected with a second water pipe. A first water pump is provided on one side of the ion resin exchanger. The first water pump is fixedly connected with the cabinet body and the input end of the first water pump is fixedly connected to the other end of the second water pipe. The output end of the first water pump is connected to the ion resin exchanger through a pipeline. A return pipe is fixedly connected to the upper end of the ion resin exchanger and the other end of the return pipe penetrates and is connected with the electrolysis tank.

[0011] According to the above technical solution, a first liquid inlet and a first liquid outlet are respectively provided on one side of the heat exchanger. A second liquid inlet and a second liquid outlet are respectively provided on the upper side of the heat exchanger. A second water pump and a third water pump are respectively fixedly connected to the upper side of the water tank. The input end of the third water pump is connected to the output end of the water tank through a pipeline. The output end of the third water pump is connected to the first liquid inlet of the heat exchanger through a pipeline. The first liquid outlet of the heat exchanger is connected to the input end of the water tank through a pipeline.

[0012] According to the above technical solution, a waterway is provided inside the heat dissipation plate. The output end of the waterway is fixedly connected to a first cooling water pipe, and the other end of the first cooling water pipe is fixedly connected to the second liquid inlet of the heat exchanger. The water guide pipe is arranged outside the first cooling water pipe, and the upper and lower ends of the water guide pipe are both closed. Two flow guide plates are respectively fixedly connected to the outside of the first cooling water pipe, and the other sides of the two flow guide plates are fixedly connected to the inner wall of the water guide pipe. The two flow guide plates divide the inner wall of the water guide pipe into a downstream chamber and an upstream chamber, and the lower parts of the downstream chamber and the upstream chamber are interconnected.

[0013] According to the above technical solution, the input end of the second water pump is fixedly connected to a third cooling water pipe, and the other end of the third cooling water pipe is fixedly connected to the second liquid outlet of the heat exchanger. The output end of the second water pump is fixedly connected to a second cooling water pipe, and the other end of the second cooling water pipe is fixedly connected to the input end of the waterway.

[0014] According to the above technical solution, the anti-leakage mechanism includes a leak-proof disc arranged outside the hydrogen pipe. A transmission component and a crimping component are respectively arranged inside the leak-proof disc, and a plug-in ring is fixedly connected to one side of the leak-proof disc.

[0015] According to the above technical solution, the transmission component includes a guide sliding plate fixedly connected to the outside of the leak-proof disc. A first spring is fixedly connected inside the guide sliding plate, and the other end of the first spring is fixedly connected to a slider. The slider is slidably connected inside the leak-proof disc. The other side of the slider is fixedly connected to a motor, and the output end of the motor is fixedly connected to a first roller. A storage battery box is arranged on one side of the motor, and the storage battery box is fixedly connected to the leak-proof disc. Three second springs are evenly and fixedly connected inside the leak-proof disc, and the other end of each second spring is fixedly connected to a U-shaped plate. A second roller is rotatably connected inside the U-shaped plate. The first roller and the second roller are slidably connected to the hydrogen pipe.

[0016] According to the above technical solution, the crimping component includes four detection grooves arranged inside the leak-proof disc. A gas sensor is fixedly connected inside each detection groove. Slide grooves are arranged on four sides of each detection groove, and a ventilation groove is communicated with one side of the slide groove. A slide plate is slidably connected inside the ventilation groove, and a rubber block is fixedly connected to the other side of the slide plate. The other side of the rubber block is mutually attached to the outside of the hydrogen pipe.

[0017] According to the above technical solution,

[0018] Compared with the prior art, the beneficial effects achieved by the present invention are:

[0019] 1. By sending high-calorie chemical reaction water into the ion resin exchanger, not only can the ions in the chemical reaction water be removed, enabling the purified chemical reaction water to re-enter the electrolysis tank for the cyclic electrolysis of water, but also during the transportation process, the entire first cooling water pipe can be wrapped to keep the high-temperature water about to enter the heat exchanger warm. This effectively prevents the loss of heat from the high-temperature water when it passes through the first cooling water pipe, thus avoiding the phenomenon of reduced heat exchange efficiency between the subsequent high-temperature water and the water pumped from the water tank, achieving a high energy utilization rate. Moreover, after the high-calorie chemical reaction water keeps the high-temperature water warm, the heat inside the chemical reaction water will quickly dissipate, thereby reducing the temperature of the chemical reaction water and effectively preventing the subsequent ion resin exchanger from suffering from excessive thermal stress, which may lead to a decline in the material properties of the equipment.

[0020] 2. By controlling the rotation of the first roller and the second roller with a motor, the anti-leakage plate is indirectly driven to slide on the uneven surface of the hydrogen pipe. During the sliding process, the rubber block always adheres to the surface of the hydrogen pipe, and the gas sensor continuously detects the surface of the hydrogen pipe. When leakage occurs, the motor controls the anti-leakage plate to stop moving, and the rubber block covers the leakage area. The solar panel is controlled to stop power supply, and the remaining hydrogen inside the hydrogen pipe is collected. Moreover, when the air pressure inside the rubber block and the ventilation groove gradually increases, the hydrogen generates a large thrust on the slide plate, driving the slide plate to slide along the chute and exerting an extrusion force on the rubber block. At this time, the pressing force of the rubber block on the surface of the hydrogen pipe increases, effectively preventing the rubber block from turning out due to excessive internal pressure, which may cause the hydrogen to leak again, achieving a high level of protection. BRIEF DESCRIPTION OF THE DRAWINGS

[0021] The drawings are used to provide a further understanding of the present invention and constitute a part of the specification. They are used together with the embodiments of the present invention to explain the present invention, but do not constitute a limitation to the present invention. In the drawings:

[0022] Figure 1 is a schematic diagram of the overall structure of a green hydrogen production and combined heat and power supply device based on solar energy conversion according to the present invention;

[0023] Figure 2 is a schematic diagram of the internal structure of the cabinet in the present invention;

[0024] Figure 3 is a schematic diagram of the overall structure of the combined heat and power supply device in the present invention;

[0025] Figure 4 is in the present invention Figure 3 is an enlarged schematic diagram of area A;

[0026] Figure 5 is a schematic diagram of the structure of the combined heat and power supply device from another perspective in the present invention;

[0027] Figure 6 It is a schematic structural diagram of the inside of the heat dissipation plate in the present invention;

[0028] Figure 7 In the present invention Figure 6 An enlarged schematic diagram of area B;

[0029] Figure 8 It is a schematic structural diagram of the anti-leakage mechanism in the present invention;

[0030] Figure 9 It is a schematic structural diagram of the transmission component in the present invention;

[0031] Figure 10 It is a schematic structural diagram of the inside of the anti-leakage tray in the present invention;

[0032] Figure 11 It is a schematic structural diagram of the edge pressing component in the present invention;

[0033] Figure 12 It is an assembly schematic diagram of the sliding plate and the sliding groove in the present invention.

[0034] In the figure: 1. Solar panel; 2. Cabinet; 3. Ion resin exchanger;

[0035] 4. Electrolysis tank; 41. Oxygen pipe; 42. Hydrogen pipe; 43. Charging socket; 44. Return pipe;

[0036] 5. Reaction mechanism; 51. First water delivery pipe; 52. Heat dissipation plate; 521. Water path; 53. Water guide pipe; 54. Second water delivery pipe; 55. First water pump; 56. Fuel cell; 57. Deflector; 58. First cooling water pipe;

[0037] 6. Water tank;

[0038] 7. Heat exchanger; 71. Second cooling water pipe; 72. Second water pump; 73. Third cooling water pipe; 74. Third water pump;

[0039] 8. Anti-leakage mechanism; 81. Anti-leakage tray; 82. Transmission component; 821. First roller; 822. Slide block; 823. Guide slide plate; 824. First spring; 825. Motor; 826. Battery storage box; 827. U-shaped plate; 828. Second spring; 829. Second roller; 83. Edge pressing component; 831. Detection groove; 832. Slide groove; 833. Ventilation groove; 834. Rubber block; 835. Slide plate; 836. Gas sensor; 84. Plug-in ring. Detailed implementation manners

[0040] The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. All other embodiments obtained by those of ordinary skill in the art based on the embodiments of the present invention without creative efforts shall fall within the protection scope of the present invention.

[0041] Please refer to Figures 1-12 , the present invention provides a technical solution: a green hydrogen production and combined heat and power supply device based on solar energy conversion, including a cabinet body 2. A solar panel 1 is provided on one side of the cabinet body 2. An electrolysis tank 4 for electrolyzing circulating water is fixedly connected inside the cabinet body 2. An electrolysis cell is provided inside the electrolysis tank 4. The solar panel 1 is used to convert light energy into electrical energy to supply power to the electrolysis cell. A water tank 6 for storing domestic hot water is provided on one side of the electrolysis tank 4. A heat exchanger 7 is fixedly connected to the upper side of the water tank 6. A reaction mechanism 5 for producing electrical energy and heat energy is provided on the upper side of the heat exchanger 7. An ion resin exchanger 3 for removing impurities and ions from the chemical reaction water generated by the reaction mechanism 5 is provided on one side of the reaction mechanism 5.

[0042] Specifically, the solar panel 1 absorbs solar energy and converts it into electrical energy. The solar panel 1 is usually composed of multiple solar cells. When these cells are irradiated by sunlight, an electric current will be generated due to the photovoltaic effect. The electrical energy generated by the solar panel 1 will directly provide the required energy for the electrolysis tank 4 to drive the electrolysis reaction. Usually, an anode and a cathode are provided inside the electrolysis tank 4, and the anode and the cathode are separated by an electrolyte such as a proton exchange membrane. When the current generated by the solar panel 1 connects the anode and the cathode of the electrolysis tank 4, the circulating water undergoes an electrolysis reaction in the electrolysis tank 4. At the anode, water molecules undergo an oxidation reaction to generate oxygen, hydrogen ions, and electrons. At the cathode, hydrogen ions gain electrons and undergo a reduction reaction to generate hydrogen.

[0043] Please refer to Figure 3 , an oxygen output end and a hydrogen output end are respectively provided on the upper side of the electrolysis tank 4. The oxygen output end and the hydrogen output end are respectively fixedly connected with an oxygen pipe 41 and a hydrogen pipe 42. An anti-leakage mechanism 8 for preventing hydrogen leakage is provided on the outer side of the hydrogen pipe 42.

[0044] Specifically, the hydrogen and oxygen generated by the electrolysis of the electrolysis tank 4 are respectively discharged from the electrolysis tank through the hydrogen pipe 42 and the oxygen pipe 41. The anti-leakage mechanism 8 is used to slide on the surface of the pipeline, monitor in real time whether the pipeline is leaking, and stop moving when the pipeline leaks, and use the leaked hydrogen flow to block the leakage point.

[0045] Please refer to Figures 3-7, the reaction mechanism 5 includes a heat dissipation plate 52 fixedly connected to the inside of the cabinet body 2. Inside the heat dissipation plate 52, a fuel cell 56 is fixedly connected. An oxygen input end, a hydrogen input end, a power generation end, and a water output end are respectively arranged outside the fuel cell 56. The other end of the oxygen pipe 41 is fixedly connected to the oxygen input end of the fuel cell 56. The other end of the hydrogen pipe 42 is provided with a charging socket 43 and is fixedly connected to the hydrogen end of the fuel cell 56. The water output end of the fuel cell 56 is fixedly connected to a first water pipe 51. The other end of the first water pipe 51 is connected through a water guide pipe 53. The other side of the water guide pipe 53 is fixedly connected to a second water pipe 54. A first water pump 55 is arranged on one side of the ion exchange resin device 3. The first water pump 55 is fixedly connected to the cabinet body 2, and the input end of the first water pump 55 is fixedly connected to the other end of the second water pipe 54. The output end of the first water pump 55 is connected to the ion exchange resin device 3 through a pipeline. The upper end of the ion exchange resin device 3 is fixedly connected to a return pipe 44, and the other end of the return pipe 44 penetrates and is connected to the electrolysis tank 4.

[0046] Specifically, the charging socket 43 is used to charge the leakage prevention mechanism 8. After hydrogen and oxygen enter the fuel cell 56, hydrogen undergoes an oxidation reaction under the action of an anode catalyst, decomposing into hydrogen ions and electrons. The electrons generated by the decomposition of hydrogen flow through an external circuit to the cathode, forming an electric current, thereby generating electrical energy. This electrical energy can be output through the power generation end. The power generation end of the fuel cell 56 is used to provide power for the first water pump 55, the second water pump 72, the third water pump 74, and the charging socket 43. At the cathode, oxygen undergoes a reduction reaction under the action of a cathode catalyst. Oxygen combines with hydrogen ions and electrons to generate chemical reaction water. The first water pump 55 starts to pump it. The chemical reaction water is discharged from the water output end and sequentially enters the ion exchange resin device 3 through the first water pipe 51, the water guide pipe 53, and the second water pipe 54. The chemical reaction water is transmitted from bottom to top. When the water containing cations passes through the cation exchange resin, the cations in the water will be adsorbed by the resin. When the water containing anions passes through the anion exchange resin, the anions in the water will be adsorbed by the resin, thereby effectively removing the ions in the water. After the water quality is further purified, it returns to the inside of the electrolysis tank 4 through the return pipe 44, and then electrolysis is carried out again, thus completing the cyclic electrolysis of water without manual water addition by personnel.

[0047] A first liquid inlet and a first liquid outlet are respectively arranged on one side of the heat exchanger 7. A second liquid inlet and a second liquid outlet are respectively arranged on the upper side of the heat exchanger 7. A second water pump 72 and a third water pump 74 are respectively fixedly connected to the upper side of the water tank 6. The input end of the third water pump 74 is connected to the output end of the water tank 6 through a pipeline. The output end of the third water pump 74 is connected to the first liquid inlet of the heat exchanger 7 through a pipeline. The first liquid outlet of the heat exchanger 7 is connected to the input end of the water tank 6 through a pipeline.

[0048] Specifically, the third water pump 74 is used to pump the water inside the water tank 6 into the heat exchanger 7. The heat exchanger 7 is used to perform heat exchange on the normal-temperature water inside the water tank 6, so as to convert the water entering the heat exchanger 7 into hot water and then return it to the inside of the water tank 6, thereby circularly heating the water inside the water tank 6.

[0049] A water path 521 is provided inside the heat dissipation plate 52. The output end of the water path 521 is fixedly connected to a first cooling water pipe 58. The other end of the first cooling water pipe 58 is fixedly connected to the second liquid inlet of the heat exchanger 7. A guide water pipe 53 is arranged outside the first cooling water pipe 58. The upper and lower ends of the guide water pipe 53 are both closed. Two flow guide plates 57 are fixedly connected to the outside of the first cooling water pipe 58, and the other sides of the two flow guide plates 57 are fixedly connected to the inner wall of the guide water pipe 53. The two flow guide plates 57 divide the inner wall of the guide water pipe 53 into a downstream chamber and an upstream chamber, and the lower parts of the downstream chamber and the upstream chamber are communicated with each other.

[0050] Specifically, since the fuel cell 56 generates high temperature during the reaction, the cooling water circulating inside the water path 521 cools down the fuel cell 56. The cooling water exchanges heat with the heat generated by the fuel cell 56, thereby taking away the heat generated by the fuel cell 56. At this time, the fuel cell 56 is cooled down, and the cooling water is heated up to become high-temperature water. The high-temperature water reaches the inside of the heat exchanger 7 through the first cooling water pipe 58 and performs heat exchange on the water pumped from the inside of the water tank 6 again. At this time, the heat inside the high-temperature water is taken away by the water pumped from the inside of the water tank 6 and becomes low temperature again, and then returns to the inside of the water path 521. The water pumped from the inside of the water tank 6 obtains heat and becomes high-temperature water and then returns to the inside of the water tank 6, thereby indirectly using the heat generated by the chemical reaction of the fuel cell 56 to heat the water source inside the water tank 6, and thus facilitating the provision of domestic hot water.

[0051] The input end of the second water pump 72 is fixedly connected to a third cooling water pipe 73. The other end of the third cooling water pipe 73 is fixedly connected to the second liquid outlet of the heat exchanger 7. The output end of the second water pump 72 is fixedly connected to a second cooling water pipe 71, and the other end of the second cooling water pipe 71 is fixedly connected to the input end of the water path 521.

[0052] Specifically, the cooling water circulating inside the water channel 521 cools down the fuel cell 56 and then heats up to high-temperature water after obtaining heat. Since it needs to enter the heat exchanger 7 through the first cooling water pipe 58, when passing through the first cooling water pipe 58, heat loss of the high-temperature water will occur, gradually reducing the temperature of the high-temperature water, which in turn leads to a decrease in the heat exchange efficiency between the subsequent high-temperature water and the water extracted from the water tank 6, and further causes the water extracted from the water tank 6 to fail to reach the required temperature. Therefore, when the first cooling water pipe 58 transports the high-temperature water, the high-calorie chemical reaction water reaches the upper flow chamber through the first water delivery pipe 51. The upper flow chamber transports the high-calorie chemical reaction water from top to bottom, enabling the high-calorie chemical reaction water to fully contact the semi-circle on one side of the first cooling water pipe 58, insulating the high-temperature water inside the semi-circle on one side of the first cooling water pipe 58 to prevent heat loss. When the high-calorie chemical reaction water reaches the bottom inside the water guide pipe 53, the high-calorie chemical reaction water enters the upper flow chamber and is driven to be transported from bottom to top, enabling the high-calorie chemical reaction water to fully contact the semi-circle on the other side of the first cooling water pipe 58, insulating the high-temperature water inside the semi-circle on the other side of the first cooling water pipe 58 to prevent heat loss. Until the high-calorie chemical reaction water reaches the top inside the water guide pipe 53, the chemical reaction water with reduced heat enters the second water delivery pipe 54.

[0053] By transporting the high-calorie chemical reaction water into the ion resin exchanger 3, not only can the ions of the chemical reaction water be removed, enabling the chemical reaction water to be purified and then enter the electrolysis tank 4 again for cyclic electrolysis of water, but also during the transportation process, the entire first cooling water pipe 58 can be wrapped to insulate the high-temperature water about to enter the heat exchanger 7, effectively preventing heat loss of the high-temperature water when passing through the first cooling water pipe 58, which would otherwise lead to a decrease in the heat exchange efficiency between the subsequent high-temperature water and the water extracted from the water tank 6, achieving the effect of high energy utilization rate. Moreover, after the high-calorie chemical reaction water insulates the high-temperature water, the heat inside the chemical reaction water will quickly dissipate, thereby reducing the temperature of the chemical reaction water, effectively preventing the subsequent ion resin exchanger 3 from suffering from excessive thermal stress, which would cause a decline in the material properties of the equipment.

[0054] In Embodiment 2, hydrogen molecules are extremely small and easily penetrate into the metal lattice, reacting with the carbon element in the metal to form methane, resulting in the generation of microcracks inside the metal, ultimately causing the pipeline strength to decline and rupture, thereby allowing hydrogen to leak into the air. Personnel cannot promptly detect the hydrogen leakage and close the gas source. When the volume concentration of hydrogen in the air reaches 4% - 75%, it can explode when encountering an open flame, high temperature, or static electric spark, causing serious safety accidents. Therefore, the following structure is designed to solve the above technical problems.

[0055] Please refer to Figures 8-12, the anti-leakage mechanism 8 includes a leak-proof plate 81 provided outside the hydrogen pipe 42. Inside the leak-proof plate 81, there are respectively a transmission component 82 for driving the anti-leakage mechanism 8 to slide adaptively on the surface of the convex hydrogen pipe 42 for monitoring, and a pressing component 83 for using the leaked hydrogen pressure to seal the periphery of the leakage area. One side of the leak-proof plate 81 is fixedly connected with a plug-in ring 84.

[0056] Specifically, the plug-in ring 84 is used to insert into the charging socket 43 to charge the electricity storage box 826. The electricity storage box 826 is used to provide power for the motor 825. The transmission component 82 is used to drive the leak-proof plate 81 to slide on the uneven surface of the hydrogen pipe 42, and the pressing component 83 is used to block the leaked area on the surface of the hydrogen pipe 42.

[0057] The transmission component 82 includes a guide slide plate 823 fixedly connected to the outside of the leak-proof plate 81. Inside the guide slide plate 823, there is a first spring 824 fixedly connected. The other end of the first spring 824 is fixedly connected with a slider 822. The slider 822 is slidably connected inside the leak-proof plate 81. On the other side of the slider 822, there is a motor 825 fixedly connected. The output end of the motor 825 is fixedly connected with a first roller 821. There is an electricity storage box 826 on one side of the motor 825. The electricity storage box 826 is fixedly connected with the leak-proof plate 81. Three second springs 828 are evenly and fixedly connected inside the leak-proof plate 81. The other end of each second spring 828 is fixedly connected with a U-shaped plate 827. Inside the U-shaped plate 827, there is a second roller 829 connected by a bearing. The first roller 821 and the second roller 829 are slidably connected with the hydrogen pipe 42.

[0058] Specifically, when hydrogen is transported in the pipeline, hydrogen molecules will dissociate on the inner wall of the pipeline to form hydrogen atoms and adsorb on the pipe wall surface. These hydrogen atoms will diffuse into the interior of the pipeline material and accumulate at positions such as material defects, grain boundaries, and dislocations. When the hydrogen atoms accumulate to a certain extent in a local area, hydrogen molecules will be formed, generating local internal pressure, causing local expansion of the material to form bulges, making some areas on the pipeline surface bulge. The bulging areas will jam the wheels and prevent the leak-proof plate 81 from sliding on the surface of the hydrogen pipe 42.

[0059] The rotation of the output end of the motor 825 is used to control the rotation of the first roller 821, so that the first roller 821 rubs against the surface of the hydrogen pipe 42, and then the leak-proof plate 81 slides on the surface of the hydrogen pipe 42 and indirectly drives the three second rollers 829 to roll for auxiliary sliding. When the first roller 821 or the second roller 829 presses on the bulging area of the hydrogen pipe 42, the corresponding first spring 824 or second spring 828 is compressed, so that the first roller 821 and the second roller 829 can roll to adapt to the bulging area of the hydrogen pipe 42, effectively preventing the phenomenon that the first roller 821 and the second roller 829 are jammed and the leak-proof plate 81 cannot move.

[0060] The edge pressing assembly 83 includes four detection grooves 831 arranged inside the leak-proof disk 81, and a gas sensor 836 is fixedly connected inside each detection groove 831. Each detection groove 831 is provided with a slide groove 832 on four sides, and one side of the slide groove 832 is connected to a ventilation groove 833. A slide plate 835 is slidably connected inside the ventilation groove 833, and a rubber block 834 is fixedly connected to the other side of the slide plate 835. The other side of the rubber block 834 is in contact with the outer side of the hydrogen pipe 42, and one side of the rubber block 834 is pressed against the inner wall of the leak-proof disk 81.

[0061] Specifically, the four gas sensors 836 are used to detect hydrogen in four different directions respectively. The gas sensor 836 can be an infrared gas sensor. The infrared gas sensor is a sensor that uses infrared absorption spectroscopy technology to detect gas concentration. It measures the gas concentration based on the principle that different gas molecules have different absorption characteristics for infrared light of a specific wavelength. When the infrared gas sensor detects a hydrogen leak, the infrared gas sensor transmits a signal to the solar panel 1 to stop powering it, thereby stopping the electrolysis of water.

[0062] However, when the electrolysis of water stops, there is still some untransmitted hydrogen inside the hydrogen pipe 42, and the leak is still leaking the remaining hydrogen. Therefore, the infrared gas sensor transmits a signal to the output end of the motor 825 while transmitting a signal to the solar panel 1, and the output end of the motor 825 stops rotating, and the first roller 821 and the second roller 829 stop moving, so that the anti-leakage plate 81 stops sliding.

[0063] The contact area between hydrogen and the skateboard 835 is larger than that between hydrogen and the rubber block 834. In the state of hydrogen leakage, the rubber block 834 fits against the surface of the hydrogen pipe 42, and hydrogen continuously leaks into the internal of the loop-shaped rubber block 834. As hydrogen continuously enters, the internal air pressure of the loop-shaped rubber block 834 becomes higher. Under the push of high-pressure hydrogen, the loop-shaped rubber block 834 may turn outwards, causing hydrogen to leak again. Therefore, during the process of the internal air pressure of the loop-shaped rubber block 834 becoming higher, the air flow thrust generated at the leakage port continuously pushes the leaked hydrogen to the periphery of the ventilation groove 833. The air pressure inside the rubber block 834 and the ventilation groove 833 becomes higher, and hydrogen gas generates a direct thrust on the skateboard 835 through the ventilation groove 833. The skateboard 835 slides along the chute 832, generating an extrusion force on the rubber block 834, increasing the pressing force of the rubber block 834 against the surface of the hydrogen pipe 42, preventing the rubber block 834 from turning outwards due to excessive internal pressure. Since the friction between the skateboard 835 and the chute 832 is small, the rubber block 834 needs to overcome the friction between the rubber block 834 and the outer wall of the pipe and the elastic resistance of the rubber block 834 itself when turning outwards. These resistances are large, resulting in a larger air pressure difference required for the rubber block 834 to turn outwards. Therefore, the rubber block 834 will not turn outwards in advance before the skateboard 835 slides.

[0064] The motor 825 is used to control the rotation of the first roller 821 and the second roller 829, indirectly driving the leakage prevention plate 81 to slide on the uneven surface of the hydrogen pipe 42. During the sliding process, the rubber block 834 always fits against the surface of the hydrogen pipe 42. The gas sensor 836 continuously detects the surface of the hydrogen pipe 42. When air leakage occurs, the motor 825 controls the leakage prevention plate 81 to stop moving, and the rubber block 834 covers the air leakage area, controls the solar panel 1 to stop power supply, and starts to collect the remaining hydrogen inside the hydrogen pipe 42. And when the air pressure inside the rubber block 834 and the ventilation groove 833 gradually increases, hydrogen generates a large thrust on the skateboard 835, driving the skateboard 835 to slide along the chute 832, generating an extrusion force on the rubber block 834. At this time, the pressing force of the rubber block 834 against the surface of the hydrogen pipe 42 increases, effectively preventing the rubber block 834 from turning outwards due to excessive internal pressure, thus preventing the phenomenon of hydrogen leaking again, achieving a high protection effect.

[0065] It should be noted that, in this document, relational terms such as first and second are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply any actual relationship or order between these entities or operations. Moreover, the terms "comprising", "including" or any other variant thereof are intended to cover non-exclusive inclusion, so that a process, method, article or device comprising a series of elements not only includes those elements, but also includes other elements not expressly listed, or further includes elements inherent to such process, method, article or device.

[0066] Finally, it should be noted that the above are only preferred embodiments of the present invention and are not used to limit the present invention. Although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art can still modify the technical solutions described in the foregoing embodiments, or perform equivalent replacements for some of the technical features. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.

Claims

1. A green hydrogen production and heat and power cogeneration device based on solar energy conversion, comprising a cabinet (2), characterized in that: A solar panel (1) is provided on one side of the cabinet (2); an electrolytic tank (4) for electrolyzing circulating water is fixedly connected to the interior of the cabinet (2); an electrolytic cell is provided inside the electrolytic tank (4); the solar panel (1) is used to convert light energy into electrical energy to supply power to the electrolytic cell; a water tank (6) for storing domestic hot water is provided on one side of the electrolytic tank (4); a heat exchanger (7) is fixedly connected to the upper side of the water tank (6); a reaction mechanism (5) for producing electrical energy and thermal energy is provided on the upper side of the heat exchanger (7); an ion resin exchanger (3) for removing impurities and ions from chemical reaction water produced by the reaction mechanism (5) is provided on one side of the reaction mechanism (5); An oxygen output end and a hydrogen output end are respectively provided on the upper side of the electrolytic tank (4), and the oxygen output end and the hydrogen output end are respectively fixedly connected to an oxygen pipe (41) and a hydrogen pipe (42). An anti-leakage mechanism (8) for preventing hydrogen leakage is provided on the outer side of the hydrogen pipe (42), and the anti-leakage mechanism (8) comprises an anti-leakage disk (81) provided on the outer side of the hydrogen pipe (42). A transmission component (82) for driving the anti-leakage mechanism (8) to perform adaptive sliding monitoring on the raised surface of the hydrogen pipe (42) and an edge pressing component (83) for sealing the periphery of the leakage area using the pressure of the leaked hydrogen are respectively provided inside the anti-leakage disk (81); The reaction mechanism (5) comprises a heat sink (52) fixedly connected to the interior of the cabinet (2); a fuel cell (56) is fixedly connected to the interior of the heat sink (52); and an oxygen input end, a hydrogen input end, a power generation end and a water output end are respectively provided on the exterior of the fuel cell (56); The water outlet end of the fuel cell (56) is fixedly connected to a first water pipe (51); the other end of the first water pipe (51) is penetrated by a water pipe (53); the other side of the water pipe (53) is fixedly connected to a second water pipe (54); and a first water pump (55) is provided on one side of the ion resin exchanger (3); The first water pump (55) is fixedly connected to the cabinet (2), and the input end of the first water pump (55) is fixedly connected to the other end of the second water pipe (54), and the output end of the first water pump (55) is connected to the ion resin exchanger (3) pipeline; A water channel (521) is provided inside the heat sink (52), the output end of the water channel (521) is fixedly connected to a first cooling water pipe (58), the other end of the first cooling water pipe (58) is fixedly connected to a second liquid inlet of the heat exchanger (7), the water guide pipe (53) is provided on the outside of the first cooling water pipe (58), the upper end and the lower end of the water guide pipe (53) are both closed, the outside of the first cooling water pipe (58) is respectively fixedly connected to two guide plates (57), and the other sides of the two guide plates (57) are fixedly connected to the inner wall of the water guide pipe (53), the two guide plates (57) divide the inner wall of the water guide pipe (53) into a downstream chamber and an upstream chamber, and the lower parts of the downstream chamber and the upstream chamber are connected to each other.

2. A green hydrogen production and cogeneration equipment based on solar energy conversion according to claim 1, characterized in that: The other end of the oxygen pipe (41) is fixedly connected to the oxygen input end of the fuel cell (56), and the other end of the hydrogen pipe (42) is provided with a charging socket (43) and is fixedly connected to the hydrogen end of the fuel cell (56).

3. A green hydrogen production and cogeneration equipment based on solar energy conversion according to claim 2, characterized in that: The upper end of the ion resin exchanger (3) is fixedly connected to a reflux pipe (44), and the other end of the reflux pipe (44) is connected through the electrolysis tank (4).

4. A green hydrogen production and cogeneration equipment based on solar energy conversion according to claim 3, characterized in that: A first liquid inlet and a first liquid outlet are provided on one side of the heat exchanger (7), a second liquid inlet and a second liquid outlet are provided on the upper side of the heat exchanger (7), a second water pump (72) and a third water pump (74) are fixedly connected to the upper side of the water tank (6), an input end of the third water pump (74) is connected to an output end pipeline of the water tank (6), an output end of the third water pump (74) is connected to a first liquid inlet pipeline of the heat exchanger (7), and the first liquid outlet of the heat exchanger (7) is connected to an input end pipeline of the water tank (6).

5. The green hydrogen production and cogeneration equipment based on solar energy conversion according to claim 4 is characterized in that: The input end of the second water pump (72) is fixedly connected to a third cooling water pipe (73), the other end of the third cooling water pipe (73) is fixedly connected to a second liquid outlet of the heat exchanger (7), the output end of the second water pump (72) is fixedly connected to a second cooling water pipe (71), and the other end of the second cooling water pipe (71) is fixedly connected to the input end of the water circuit (521).

6. The green hydrogen production and cogeneration equipment based on solar energy conversion according to claim 1 is characterized in that: A plug-in ring (84) is fixedly connected to one side of the leak-proof disc (81).

7. A green hydrogen production and cogeneration equipment based on solar energy conversion according to claim 6, characterized in that: The transmission assembly (82) comprises a guide slide plate (823) fixedly connected to the outside of the leak-proof disk (81); a first spring (824) is fixedly connected to the inside of the guide slide plate (823); the other end of the first spring (824) is fixedly connected to a slider (822); the slider (822) is slidably connected to the inside of the leak-proof disk (81); the other side of the slider (822) is fixedly connected to a motor (825); the output end of the motor (825) is fixedly connected to a first roller (821); and a power storage box (826) is provided on one side of the motor (825).

8. The green hydrogen production and cogeneration equipment based on solar energy conversion according to claim 7 is characterized in that: The electricity storage box (826) is fixedly connected to the leak-proof disk (81); three second springs (828) are evenly and fixedly connected inside the leak-proof disk (81); the other end of each second spring (828) is fixedly connected to a U-shaped plate (827); the internal bearing of the U-shaped plate (827) is connected to a second roller (829); and the first roller (821) and the second roller (829) are slidably connected to the hydrogen pipe (42).

9. The green hydrogen production and cogeneration equipment based on solar energy conversion according to claim 8, characterized in that: The edge pressing assembly (83) comprises four detection grooves (831) arranged inside the leak-proof disk (81), each detection groove (831) is fixedly connected to a gas sensor (836), and each detection groove (831) is provided with a slide groove (832) on four sides, one side of the slide groove (832) is connected to a ventilation groove (833), the ventilation groove (833) is slidably connected to a slide plate (835), the other side of the slide plate (835) is fixedly connected to a rubber block (834), and the other side of the rubber block (834) is in contact with the outer side of the hydrogen pipe (42).

Citation Information

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