A daily-use ceramic formula and its preparation method

Abstract

This invention relates to the field of ceramic technology, specifically to a daily-use ceramic formula and its preparation method, comprising the following raw materials in parts by weight: 30-35 parts quartz, 15-20 parts cerium-modified Bianstone powder, 10-14 parts modified titanium dioxide, 6-9 parts albite, 4-7 parts zinc oxide, 4-6 parts calcined talc, 2-5 parts sodium carboxymethyl cellulose, and 25-30 parts deionized water. The glaze of this invention uses quartz in combination with albite, zinc oxide, calcined talc, and sodium carboxymethyl cellulose, while adding cerium-modified Bianstone powder and modified titanium dioxide as harmonizing agents to optimize the product's gloss, far-infrared emissivity, and heating properties, thus improving product performance. Simultaneously, it significantly enhances the product's stability under humidity and hot / cold cycling conditions.

Description

Technical Field

[0001] This invention relates to the field of ceramic technology, and specifically to a daily-use ceramic formula and its preparation method. Background Art

[0002] Far-infrared emitting ceramics not only activate food, beverages, and water, but also offer health benefits to the human body. Far-infrared rays are invisible electromagnetic waves with wavelengths between microwaves and visible light. Infrared rays can be divided into near-infrared (wavelength 1-3μm), mid-infrared (wavelength 3-5μm), and far-infrared (wavelength 8-14μm). Far-infrared rays themselves possess disinfection, sterilization, and activation functions, and are mainly used in far-infrared health products.

[0003] Existing daily-use ceramic products have poor far-infrared emissivity and heating performance. At the same time, it is difficult to coordinate and improve the product's gloss with far-infrared emissivity and heating performance, which limits the product's efficiency. Furthermore, the product's poor stability under humidity and hot-cold cycle conditions further restricts its use. Summary of the Invention

[0004] In view of the deficiencies of the prior art, the purpose of this invention is to provide a daily-use ceramic formula and its preparation method to solve the problems mentioned in the background art.

[0005] The present invention solves the technical problem by adopting the following technical solution:

[0006] This invention provides a method for preparing a daily-use ceramic formula, comprising the following steps:

[0007] Step 1: Weigh the glaze raw materials according to the specified weight proportions:

[0008] 30-35 parts quartz, 15-20 parts cerium-modified Bianstone powder, 10-14 parts modified titanium dioxide, 6-9 parts albite, 4-7 parts zinc oxide, 4-6 parts calcined talc, 2-5 parts sodium carboxymethyl cellulose, and 25-30 parts deionized water

[0009] Step 2: Ball mill the glaze raw material thoroughly at a speed of 1500 r / min for 1 hour. After ball milling, the glaze is obtained.

[0010] Step 3: Mix 10-15 parts by weight of potassium feldspar, 4-7 parts by weight of kaolin, 4-7 parts by weight of clay, 3-5 parts by weight of wollastonite and 7-10 parts by weight of water and ball mill them. The ball milling speed is 1500 r / min and the ball milling time is 1 hour. After the ball milling is completed, the ball milling material is obtained.

[0011] Step 4: Place the abrasive ball into a mold and press it into shape at a pressure of 15 MPa for 30 minutes to obtain a ceramic body. Then, apply glaze to the ceramic body at a rate of 500 g / m². 2Finally, the glazed ceramic body is sintered, and after sintering, daily-use ceramics are obtained.

[0012] Preferably, the method for preparing the cerium-added modified Bianstone powder is as follows:

[0013] S01: Preparation of ball milling slurry:

[0014] S01a: Add 2-4 parts by weight of fly ash and 1-3 parts by weight of silane coupling agent KH550 to 5-8 parts by weight of sodium lignosulfonate solution, stir evenly, and obtain the first ball milling agent;

[0015] S01b: Mix 3-5 parts by weight of lignocellulose, 2-4 parts by weight of stearic acid and 5-8 parts by weight of dopamine hydrochloride solution to obtain the second ball milling agent;

[0016] S01c: Continue to mix the first ball milling agent and the second ball milling agent at a weight ratio of 3:2 until they are thoroughly mixed to obtain the ball milling liquid;

[0017] S02: Add 30-35% of the total weight of Bianstone powder to the ball milling liquid for primary ball milling improvement treatment. After ball milling, Bianstone ball milling liquid is obtained.

[0018] S03: The Bianstone ball milling liquid and cerium additive are subjected to a two-stage ball milling improvement at a weight ratio of 5:(2~3). After the ball milling is completed, the mixture is filtered and dried to obtain modified Bianstone powder with cerium additive.

[0019] Preferably, the ball milling speed of the first-stage ball milling improvement is 750-850 r / min, and the ball milling time is 1 hour; the ball milling speed of the second-stage ball milling improvement is 450-550 r / min, and the ball milling time is 2 hours.

[0020] Preferably, the sodium lignosulfonate solution has a mass fraction of 2-5%; and the dopamine hydrochloride solution has a mass fraction of 3-6%.

[0021] Preferably, the preparation method of the cerium additive is as follows:

[0022] Zirconia, sodium silicate solution and magnesium oxide are mixed thoroughly in a weight ratio of (2-4):(3-5):2 to obtain a zirconia agent;

[0023] Cerium oxide is added to a lanthanum chloride solution at a weight ratio of 1:3. Then, 8-12% of the total weight of the lanthanum chloride solution is added to the lanthanum chloride solution and stirred thoroughly. The mixture is then filtered, dried, and heat-treated at 170-180°C for 20 minutes. Finally, it is air-cooled to room temperature to obtain the cerium additive.

[0024] Preferably, the sodium silicate solution has a mass fraction of 3-5%; and the lanthanum chloride solution has a mass fraction of 2-4%.

[0025] Preferably, the modified titanium dioxide agent is prepared by:

[0026] S11: First, place titanium dioxide in a sufficient amount of sodium alginate solution with a mass fraction of 5% and disperse it evenly to obtain titanium dioxide solution;

[0027] S12: Mix 1-2 parts by weight of sodium dodecylbenzenesulfonate, 2-4 parts by weight of silicon carbide, 1-3 parts by weight of boron oxide and 5-8 parts by weight of chitosan solution with a mass fraction of 5% to obtain a modifier.

[0028] S13: Add 5-8% of the total weight of the titanium dioxide liquid modifier to the titanium dioxide liquid and stir. The stirring temperature is 55℃, the stirring time is 1-2 hours, the stirring speed is 550 r / min, and then the mixture is filtered and dried to obtain the modified titanium dioxide agent.

[0029] Preferably, the sintering temperature in step four is 1250℃, and the sintering time is 2 hours.

[0030] A method for preparing a daily-use ceramic formula.

[0031] Compared with the prior art, the present invention has the following beneficial effects:

[0032] The glaze for daily-use ceramics prepared in this invention uses quartz combined with albite, zinc oxide, calcined talc, and sodium carboxymethyl cellulose as raw materials. Cerium-modified Bianstone powder and modified titanium dioxide are added as harmonizing agents to optimize the product's gloss, far-infrared emissivity, and heating properties, thus improving overall product performance. The product also exhibits significant stability under humidity and hot / cold cycling conditions. The cerium-modified Bianstone powder is formulated using fly ash, silane coupling agent KH550, and sodium lignosulfonate solution to form a first grinding agent. A second grinding agent is prepared using lignocellulose, stearic acid, and dopamine hydrochloride solution. The grinding fluid is obtained by combining the first and second grinding agents. The fly ash in the grinding fluid, combined with lignocellulose and other raw materials such as the silane coupling agent, optimizes and improves the Bianstone powder, allowing for better coordination between the Bianstone grinding fluid and the cerium additive. The cerium additive is formulated using zirconium oxide, sodium silicate solution, and magnesium oxide. As a matrix agent, cerium oxide and lanthanum chloride solutions are blended and then cerium additives are formulated. The resulting cerium additives enhance the synergistic effect between Bianstone powder and the matrix in the Bianstone ball milling slurry system, thereby further enhancing the system's gloss, far-infrared emissivity, and heat generation, as well as optimizing the product's stability under humidity and thermal cycling conditions. The modified titanium dioxide agent is prepared by using titanium dioxide with sodium alginate solution to optimize the dispersion of nano-titanium dioxide. Simultaneously, sodium dodecylbenzenesulfonate, silicon carbide, boron oxide, and a 5% (w / w) chitosan solution are thoroughly mixed to obtain a modifier. The modifier is used to improve the nano-titanium dioxide slurry. Through the blending and formulation of raw materials, silicon carbide and boron oxide are used to improve the nano-titanium dioxide. The resulting modified titanium dioxide agent has an enhanced synergistic effect with the cerium-added modified Bianstone powder, thereby further improving the product's performance and significantly enhancing its stability under humidity and thermal cycling conditions. Detailed Implementation

[0033] The technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to specific examples. Obviously, the described embodiments are only some embodiments of the present invention, and not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative effort are within the scope of protection of the present invention.

[0034] A glaze according to this embodiment comprises the following raw materials in parts by weight:

[0035] The ingredients are: 30-35 parts quartz, 15-20 parts cerium-modified Bianstone powder, 10-14 parts modified titanium dioxide, 6-9 parts sodium feldspar, 4-7 parts zinc oxide, 4-6 parts calcined talc, 2-5 parts sodium carboxymethyl cellulose, and 25-30 parts deionized water.

[0036] The preparation method of the cerium-added modified Bianstone powder in this embodiment is as follows:

[0037] S01: Preparation of ball milling slurry:

[0038] S01a: Add 2-4 parts by weight of fly ash and 1-3 parts by weight of silane coupling agent KH550 to 5-8 parts by weight of sodium lignosulfonate solution, stir evenly, and obtain the first ball milling agent;

[0039] S01b: Mix 3-5 parts by weight of lignocellulose, 2-4 parts by weight of stearic acid and 5-8 parts by weight of dopamine hydrochloride solution to obtain the second ball milling agent;

[0040] S01c: Continue to mix the first ball milling agent and the second ball milling agent at a weight ratio of 3:2 until they are thoroughly mixed to obtain the ball milling liquid;

[0041] S02: Add 30-35% of the total weight of Bianstone powder to the ball milling liquid for primary ball milling improvement treatment. After ball milling, Bianstone ball milling liquid is obtained.

[0042] S03: The Bianstone ball milling liquid and cerium additive are subjected to a two-stage ball milling improvement at a weight ratio of 5:(2~3). After the ball milling is completed, the mixture is filtered and dried to obtain modified Bianstone powder with cerium additive.

[0043] In this embodiment, the first-stage ball milling improvement has a ball milling speed of 750-850 r / min and a ball milling time of 1 hour; the second-stage ball milling improvement has a ball milling speed of 450-550 r / min and a ball milling time of 2 hours.

[0044] In this embodiment, the sodium lignosulfonate solution has a mass fraction of 2-5%; the dopamine hydrochloride solution has a mass fraction of 3-6%.

[0045] The preparation method of the cerium additive in this embodiment is as follows:

[0046] Zirconia, sodium silicate solution and magnesium oxide are mixed thoroughly in a weight ratio of (2-4):(3-5):2 to obtain a zirconia agent;

[0047] Cerium oxide is added to a lanthanum chloride solution at a weight ratio of 1:3. Then, 8-12% of the total weight of the lanthanum chloride solution is added to the lanthanum chloride solution and stirred thoroughly. The mixture is then filtered, dried, and heat-treated at 170-180°C for 20 minutes. Finally, it is air-cooled to room temperature to obtain the cerium additive.

[0048] In this embodiment, the sodium silicate solution has a mass fraction of 3-5%; the lanthanum chloride solution has a mass fraction of 2-4%.

[0049] The preparation method of the modified titanium dioxide agent in this embodiment is as follows:

[0050] S11: First, place titanium dioxide in a sufficient amount of sodium alginate solution with a mass fraction of 5% and disperse it evenly to obtain titanium dioxide solution;

[0051] S12: Mix 1-2 parts by weight of sodium dodecylbenzenesulfonate, 2-4 parts by weight of silicon carbide, 1-3 parts by weight of boron oxide and 5-8 parts by weight of chitosan solution with a mass fraction of 5% to obtain a modifier.

[0052] S13: Add 5-8% of the total weight of the titanium dioxide liquid modifier to the titanium dioxide liquid and stir. The stirring temperature is 55℃, the stirring time is 1-2 hours, the stirring speed is 550 r / min, and then the mixture is filtered and dried to obtain the modified titanium dioxide agent.

[0053] This embodiment describes a method for preparing a daily-use ceramic formula, using the aforementioned glaze, and includes the following steps:

[0054] Weigh the glaze raw materials according to the weight proportions, then ball mill the glaze raw materials thoroughly at a speed of 1500 r / min for 1 hour. After ball milling, the glaze is obtained.

[0055] 10-15 parts by weight of potassium feldspar, 4-7 parts by weight of kaolin, 4-7 parts by weight of clay, 3-5 parts by weight of wollastonite and 7-10 parts by weight of water are mixed and ball-milled at a speed of 1500 r / min for 1 hour. The ball milling is then completed to obtain the ball milled material.

[0056] The abrasive particles are placed in a mold and molded at a pressure of 15 MPa for 30 minutes to obtain a ceramic body. Then, glaze is applied to the ceramic body at a rate of 500 g / m². 2 Finally, the glazed ceramic body is sintered at 1250℃ for 2 hours. After sintering, daily-use ceramics are obtained.

[0057] This embodiment of a daily-use ceramic formula is prepared by the method described above.

[0058] Example 1: A glaze comprising the following raw materials in parts by weight:

[0059] 30 parts quartz, 15 parts cerium-modified Bianstone powder, 10 parts modified titanium dioxide, 6 parts sodium feldspar, 4 parts zinc oxide, 4 parts calcined talc, 2 parts sodium carboxymethyl cellulose, and 25 parts deionized water.

[0060] The preparation method of the cerium-added modified Bianstone powder in this embodiment is as follows:

[0061] S01: Preparation of ball milling slurry:

[0062] S01a: Add 2 parts fly ash and 1 part silane coupling agent KH550 to 5 parts sodium lignosulfonate solution by weight, stir evenly, and obtain the first ball milling agent.

[0063] S01b: Mix 3 parts by weight of lignocellulose, 2 parts by weight of stearic acid and 5 parts by weight of dopamine hydrochloride solution to obtain the second ball milling agent;

[0064] S01c: Continue to mix the first ball milling agent and the second ball milling agent at a weight ratio of 3:2 until they are thoroughly mixed to obtain the ball milling liquid;

[0065] S02: Add 30% of the total weight of Bianstone powder to the ball milling liquid for primary ball milling improvement treatment. After ball milling, Bianstone ball milling liquid is obtained.

[0066] S03: The Bianstone ball milling liquid and cerium additive are subjected to a two-stage ball milling improvement at a weight ratio of 5:2. After the ball milling is completed, the mixture is filtered and dried to obtain modified Bianstone powder with added cerium.

[0067] In this embodiment, the first-stage ball milling improvement has a ball milling speed of 750 r / min and a ball milling time of 1 hour; the second-stage ball milling improvement has a ball milling speed of 450 r / min and a ball milling time of 2 hours.

[0068] In this embodiment, the sodium lignosulfonate solution has a mass fraction of 2%; the dopamine hydrochloride solution has a mass fraction of 3%.

[0069] The preparation method of the cerium additive in this embodiment is as follows:

[0070] Zirconia, sodium silicate solution and magnesium oxide are mixed thoroughly in a weight ratio of 2:3:2 to obtain a zirconium oxide agent.

[0071] Cerium oxide was added to a lanthanum chloride solution at a weight ratio of 1:3. Then, zirconium oxide (8% of the total weight of the lanthanum chloride solution) was added to the lanthanum chloride solution and stirred thoroughly. The mixture was then filtered, dried, and heat-treated at 170°C for 20 minutes. Finally, it was air-cooled to room temperature to obtain the cerium additive.

[0072] In this embodiment, the sodium silicate solution has a mass fraction of 3%; the lanthanum chloride solution has a mass fraction of 2%.

[0073] The preparation method of the modified titanium dioxide agent in this embodiment is as follows:

[0074] S11: First, place titanium dioxide in a sufficient amount of sodium alginate solution with a mass fraction of 5% and disperse it evenly to obtain titanium dioxide solution;

[0075] S12: Mix 1 part sodium dodecylbenzenesulfonate, 2 parts silicon carbide, 1 part boron oxide and 5 parts chitosan solution (5% by mass) thoroughly to obtain the modifier;

[0076] S13: Add 5% of the total weight of the titanium dioxide liquid modifier to the titanium dioxide liquid and stir. Stir at 55℃ for 1 hour at a stirring speed of 550 r / min. Then filter and dry to obtain the modified titanium dioxide agent.

[0077] This embodiment describes a method for preparing daily-use ceramics, using glaze, and includes the following steps:

[0078] Weigh the glaze raw materials according to the weight proportions, then ball mill the glaze raw materials thoroughly at a speed of 1500 r / min for 1 hour. After ball milling, the glaze is obtained.

[0079] 10 parts by weight of potassium feldspar, 4 parts by weight of kaolin, 4 parts by weight of clay, 3 parts by weight of wollastonite and 7 parts by weight of water were mixed and ball-milled at a speed of 1500 r / min for 1 hour. The ball milling was then completed to obtain the ball milled material.

[0080] The abrasive particles are placed in a mold and molded at a pressure of 15 MPa for 30 minutes to obtain a ceramic body. Then, glaze is applied to the ceramic body at a rate of 500 g / m². 2 Finally, the glazed ceramic body is sintered at 1250℃ for 2 hours. After sintering, daily-use ceramics are obtained.

[0081] This embodiment of a daily-use ceramic is prepared by the method described above.

[0082] Example 2: A glaze comprising the following raw materials in parts by weight:

[0083] The ingredients are: 35 parts quartz, 20 parts cerium-modified Bianstone powder, 14 parts modified titanium dioxide, 9 parts sodium feldspar, 7 parts zinc oxide, 6 parts calcined talc, 5 parts sodium carboxymethyl cellulose, and 30 parts deionized water.

[0084] The preparation method of the cerium-added modified Bianstone powder in this embodiment is as follows:

[0085] S01: Preparation of ball milling slurry:

[0086] S01a: Add 4 parts by weight of fly ash and 3 parts by weight of silane coupling agent KH550 to 8 parts by weight of sodium lignosulfonate solution, stir evenly, and obtain the first ball milling agent;

[0087] S01b: Mix 5 parts by weight of lignocellulose, 4 parts by weight of stearic acid and 8 parts by weight of dopamine hydrochloride solution to obtain the second ball milling agent;

[0088] S01c: Continue to mix the first ball milling agent and the second ball milling agent at a weight ratio of 3:2 until they are thoroughly mixed to obtain the ball milling liquid;

[0089] S02: Add 35% of the total weight of Bianstone powder to the ball milling liquid for primary ball milling improvement treatment. After ball milling, Bianstone ball milling liquid is obtained.

[0090] S03: The Bianstone ball milling liquid and cerium additive are subjected to a two-stage ball milling improvement at a weight ratio of 5:3. After the ball milling is completed, the mixture is filtered and dried to obtain modified Bianstone powder with cerium additive.

[0091] In this embodiment, the first-stage ball milling improvement has a ball milling speed of 850 r / min and a ball milling time of 1 hour; the second-stage ball milling improvement has a ball milling speed of 550 r / min and a ball milling time of 2 hours.

[0092] In this embodiment, the sodium lignosulfonate solution has a mass fraction of 5%; the dopamine hydrochloride solution has a mass fraction of 6%.

[0093] The preparation method of the cerium additive in this embodiment is as follows:

[0094] Zirconia, sodium silicate solution and magnesium oxide are mixed thoroughly in a weight ratio of 4:5:2 to obtain a zirconium oxide agent.

[0095] Cerium oxide was added to a lanthanum chloride solution at a weight ratio of 1:3. Then, zirconium oxide (12% of the total weight of the lanthanum chloride solution) was added to the lanthanum chloride solution and stirred thoroughly. The mixture was then filtered, dried, and heat-treated at 180°C for 20 minutes. Finally, it was air-cooled to room temperature to obtain the cerium additive.

[0096] In this embodiment, the sodium silicate solution has a mass fraction of 5%; the lanthanum chloride solution has a mass fraction of 4%.

[0097] The preparation method of the modified titanium dioxide agent in this embodiment is as follows:

[0098] S11: First, place titanium dioxide in a sufficient amount of sodium alginate solution with a mass fraction of 5% and disperse it evenly to obtain titanium dioxide solution;

[0099] S12: Mix 2 parts by weight of sodium dodecylbenzenesulfonate, 4 parts by weight of silicon carbide, 3 parts by weight of boron oxide and 8 parts by weight of chitosan solution with a mass fraction of 5% to obtain a modifier.

[0100] S13: Add 8% of the total weight of the titanium dioxide liquid modifier to the titanium dioxide liquid and stir. Stir at 55℃ for 2 hours at a stirring speed of 550 r / min. Then filter and dry to obtain the modified titanium dioxide agent.

[0101] This embodiment describes a method for preparing daily-use ceramics, using glaze, and includes the following steps:

[0102] Weigh the glaze raw materials according to the weight proportions, then ball mill the glaze raw materials thoroughly at a speed of 1500 r / min for 1 hour. After ball milling, the glaze is obtained.

[0103] 15 parts by weight of potassium feldspar, 7 parts by weight of kaolin, 7 parts by weight of clay, 5 parts by weight of wollastonite and 10 parts by weight of water were mixed and ball-milled at a speed of 1500 r / min for 1 hour. The ball milling was then completed to obtain the ball milled material.

[0104] The abrasive particles are placed in a mold and molded at a pressure of 15 MPa for 30 minutes to obtain a ceramic body. Then, glaze is applied to the ceramic body at a rate of 500 g / m². 2 Finally, the glazed ceramic body is sintered at 1250℃ for 2 hours. After sintering, daily-use ceramics are obtained.

[0105] This embodiment of a daily-use ceramic is prepared by the method described above.

[0106] Example 3: A glaze comprising the following raw materials in parts by weight:

[0107] The composition includes 32.5 parts quartz, 17.5 parts cerium-modified Bianstone powder, 12.5 parts modified titanium dioxide, 7.5 parts sodium feldspar, 5.5 parts zinc oxide, 5 parts calcined talc, 3.5 parts sodium carboxymethyl cellulose, and 27.5 parts deionized water.

[0108] The preparation method of the cerium-added modified Bianstone powder in this embodiment is as follows:

[0109] S01: Preparation of ball milling slurry:

[0110] S01a: Add 3 parts fly ash and 2 parts silane coupling agent KH550 to 6.5 parts sodium lignosulfonate solution by weight, stir evenly, and obtain the first ball milling agent;

[0111] S01b: Mix 4 parts by weight of lignocellulose, 3 parts by weight of stearic acid and 6.5 parts by weight of dopamine hydrochloride solution thoroughly to obtain the second ball milling agent;

[0112] S01c: Continue to mix the first ball milling agent and the second ball milling agent at a weight ratio of 3:2 until they are thoroughly mixed to obtain the ball milling liquid;

[0113] S02: Add 32.5% of the total weight of Bianstone powder to the ball milling liquid for primary ball milling improvement treatment. After ball milling, Bianstone ball milling liquid is obtained.

[0114] S03: The Bianstone ball milling liquid and cerium additive are subjected to a two-stage ball milling improvement at a weight ratio of 2:1. After the ball milling is completed, the mixture is filtered and dried to obtain modified Bianstone powder with added cerium.

[0115] In this embodiment, the first-stage ball milling improvement has a ball milling speed of 800 r / min and a ball milling time of 1 hour; the second-stage ball milling improvement has a ball milling speed of 500 r / min and a ball milling time of 2 hours.

[0116] In this embodiment, the sodium lignosulfonate solution has a mass fraction of 3.5%; the dopamine hydrochloride solution has a mass fraction of 4.5%.

[0117] The preparation method of the cerium additive in this embodiment is as follows:

[0118] Zirconia, sodium silicate solution and magnesium oxide are mixed thoroughly in a weight ratio of 3:4:2 to obtain zirconium oxide agent;

[0119] Cerium oxide was added to a lanthanum chloride solution at a weight ratio of 1:3. Then, zirconium oxide (10% of the total weight of the lanthanum chloride solution) was added to the lanthanum chloride solution and stirred thoroughly. The mixture was then filtered, dried, and heat-treated at 175°C for 20 minutes. Finally, it was air-cooled to room temperature to obtain the cerium additive.

[0120] In this embodiment, the sodium silicate solution has a mass fraction of 4%; the lanthanum chloride solution has a mass fraction of 3%.

[0121] The preparation method of the modified titanium dioxide agent in this embodiment is as follows:

[0122] S11: First, place titanium dioxide in a sufficient amount of sodium alginate solution with a mass fraction of 5% and disperse it evenly to obtain titanium dioxide solution;

[0123] S12: Mix 1.5 parts by weight of sodium dodecylbenzenesulfonate, 3 parts of silicon carbide, 2 parts of boron oxide and 6.5 parts by weight of 5% chitosan solution thoroughly to obtain the modifier;

[0124] S13: Add 6.5% of the total weight of the titanium dioxide liquid modifier to the titanium dioxide liquid and stir. The stirring temperature is 55℃, the stirring time is 1.5h, the stirring speed is 550r / min, and then the mixture is filtered and dried to obtain the modified titanium dioxide agent.

[0125] This embodiment describes a method for preparing daily-use ceramics, using glaze, and includes the following steps:

[0126] Weigh the glaze raw materials according to the weight proportions, then ball mill the glaze raw materials thoroughly at a speed of 1500 r / min for 1 hour. After ball milling, the glaze is obtained.

[0127] 12.5 parts by weight of potassium feldspar, 5.5 parts of kaolin, 5.5 parts of clay, 4 parts of wollastonite, and 8.5 parts of water were mixed and ball-milled at a speed of 1500 r / min for 1 hour. The ball milling was then completed to obtain the ball milled material.

[0128] The abrasive particles are placed in a mold and molded at a pressure of 15 MPa for 30 minutes to obtain a ceramic body. Then, glaze is applied to the ceramic body at a rate of 500 g / m². 2 Finally, the glazed ceramic body is sintered at 1250℃ for 2 hours. After sintering, daily-use ceramics are obtained.

[0129] This embodiment of a daily-use ceramic is prepared by the method described above.

[0130] Comparative Example 1:

[0131] Unlike Example 3, this is modified Bianstone powder without the addition of cerium.

[0132] Comparative Example 2:

[0133] Unlike Example 3, the modified Bianstone powder with added cerium was not ball-milled using Bianstone ball milling slurry.

[0134] Comparative Example 3:

[0135] Unlike Example 3, no Bianstone powder was added to the Bianstone ball milling fluid.

[0136] Comparative Example 4:

[0137] Unlike Example 3, the Bianstone powder was not subjected to primary ball milling treatment with ball milling fluid in the preparation of Bianstone ball milling fluid.

[0138] Comparative Example 5:

[0139] Unlike Example 3, no first milling agent was added to the milling fluid.

[0140] Comparative Example 6:

[0141] Unlike Example 3, the first ball milling agent did not contain fly ash or silane coupling agent KH550.

[0142] Comparative Example 7:

[0143] Unlike Example 3, no second ball milling agent was added to the ball milling fluid.

[0144] Comparative Example 8:

[0145] Unlike Example 3, the second ball milling agent did not contain lignocellulose or stearic acid.

[0146] Comparative Example 9:

[0147] Unlike Example 3, no cerium additive was added during the preparation of the modified Bianstone powder without cerium addition.

[0148] Comparative Example 10:

[0149] Unlike Example 3, no modified titanium dioxide agent was added.

[0150] Comparative Example 11:

[0151] Unlike Example 3, no modifier was added in step S13 of the preparation of the modified titanium dioxide agent.

[0152] Comparative Example 12:

[0153] Unlike Example 3, silicon carbide and boron oxide were not added to the modifier.

[0154] The ceramic products of Examples 1-3 and Comparative Examples 1-12 were tested for gloss, far-infrared emissivity, and heating properties. The products were placed under 50% humidity and 2°C for 12 hours, then heated to 75°C at a rate of 2°C / min and held for 12 hours. This was one cycle, and the cycle was repeated 5 times to test the stability of each property of the products under humidity and thermal cycling conditions. The test results are shown in Table 1.

[0155] Table 1. Product performance test results of Examples 1-3 and Comparative Examples 1-12:

[0156]

[0157]

[0158] As can be seen from Comparative Examples 1-12 and Examples 1-3, the product of Example 3 has excellent far-infrared emissivity, temperature rise and gloss, and the product has excellent stability in humidity and hot and cold cycle treatment.

[0159] As can be seen from Comparative Example 1, Comparative Example 10 and Example 3, the performance of the product is significantly reduced when neither cerium-modified Bianstone powder nor modified titanium dioxide agent is added.

[0160] As can be seen from Comparative Examples 2-4, Comparative Example 9, and Example 3, the performance of the modified Bianstone powder with cerium addition tends to deteriorate when Bianstone ball milling fluid is not added during ball milling, when Bianstone powder is not added to the ball milling fluid, when Bianstone powder is not subjected to primary ball milling treatment with ball milling fluid during the preparation of Bianstone ball milling fluid, and when cerium additive is not added during the preparation of modified Bianstone powder with cerium addition. The performance of the product is most significantly improved when a specific Bianstone ball milling fluid is used in combination with cerium additive, and the performance of the product deteriorates significantly when cerium additive is not added during the preparation of modified Bianstone powder with cerium addition.

[0161] As can be seen from Comparative Examples 5-8 and Example 3, the performance of the products deteriorated to varying degrees when the first grinding agent was not added to the ball milling fluid, when fly ash and silane coupling agent KH550 were not added to the first grinding agent, when the second grinding agent was not added to the ball milling fluid, and when lignocellulose and stearic acid were not added to the second grinding agent. The ball milling fluid prepared using the first grinding agent and the second grinding agent obtained by the specific method of this invention showed the most significant performance improvement.

[0162] As can be seen from Comparative Examples 11-12 and Example 3, in the preparation of modified titanium dioxide, if no modifier is added in step S13, or if silicon carbide and boron oxide are not added to the modifier, the performance of the product will deteriorate. The modified titanium dioxide modified by the modifier obtained by the specific method of this invention has a significant effect on product performance.

[0163] Based on the above performance tests, this invention further explores the product performance using cerium additives.

[0164] Experimental Example 1:

[0165] Same as Example 3, except that zirconium oxide was not added to the cerium additive.

[0166] Experimental Example 2:

[0167] Same as Example 3, except that zirconium oxide was not added to the zirconium oxide agent.

[0168] Experimental Example 3:

[0169] Same as Example 3, except that magnesium oxide was not added to the zirconium oxide agent.

[0170] Experiment Example 4:

[0171] Same as Example 3, except that sodium silicate solution was not added to the zirconium oxide agent.

[0172] Experimental Example 5:

[0173] Same as Example 3, except that cerium oxide was not added during the preparation of the cerium additive.

[0174] Experimental Example 6:

[0175] Same as Example 3, except that water was used instead of lanthanum chloride solution.

[0176] The ceramic products in routine tests 1-6 were tested for gloss, far-infrared emissivity, and heating properties. The products were placed in a 50% humidity environment and kept at 2°C for 12 hours. Then, the temperature was increased to 75°C at a rate of 2°C / min and held for 12 hours. This was one cycle, and the cycle was repeated 5 times to test the stability of each property of the products under humidity and thermal cycling conditions. The test results are shown in Table 2.

[0177] Table 2 shows the product performance test results for Experiment Examples 1-6:

[0178]

[0179]

[0180] As can be seen from Experiments 1-6, the absence of zirconium oxide in the cerium additive resulted in the most significant deterioration in product performance among the factors affecting the preparation of the cerium additive. The absence of zirconium oxide, magnesium oxide, or sodium silicate solution in the zirconium oxide additive all led to varying degrees of performance degradation. The use of the specific zirconium oxide agent of this invention resulted in the best product performance. Furthermore, the absence of cerium oxide and the substitution of water for lanthanum chloride solution in the preparation of the cerium additive also resulted in performance degradation. In the preparation of the cerium additive, all raw materials are indispensable, and the effects of other raw material ratios are not as significant as those of this invention.

[0181] It will be apparent to those skilled in the art that the present invention is not limited to the details of the exemplary embodiments described above, and that the invention can be implemented in other specific forms without departing from the spirit or essential characteristics of the invention. Therefore, the embodiments should be considered in all respects as exemplary and non-limiting, and the scope of the invention is defined by the appended claims rather than the foregoing description. Thus, it is intended that all variations falling within the meaning and scope of equivalents of the claims be included within the present invention.

[0182] In addition, it should be understood that although this specification is described in terms of implementation methods, not every implementation method contains only one independent technical solution. This narrative method of the specification is only for the sake of clarity. Those skilled in the art should regard the specification as a whole. The technical solutions in each embodiment can also be appropriately combined to form other implementation methods that can be understood by those skilled in the art.

Claims

1. A method for preparing a daily-use ceramic formula, characterized in that, Includes the following steps: Step 1: Weigh the glaze raw materials according to the specified weight proportions: 30-35 parts quartz, 15-20 parts cerium-modified Bianstone powder, 10-14 parts modified titanium dioxide, 6-9 parts albite, 4-7 parts zinc oxide, 4-6 parts calcined talc, 2-5 parts sodium carboxymethyl cellulose, and 25-30 parts deionized water. Step 2: Ball mill the glaze raw material thoroughly at a speed of 1500 r / min for 1 hour. After ball milling, the glaze is obtained. Step 3: Mix 10-15 parts by weight of potassium feldspar, 4-7 parts by weight of kaolin, 4-7 parts by weight of clay, 3-5 parts by weight of wollastonite and 7-10 parts by weight of water and ball mill them. The ball milling speed is 1500 r / min and the ball milling time is 1 hour. After the ball milling is completed, the ball milling material is obtained. Step 4: Place the abrasive ball into a mold and press it into shape at a pressure of 15 MPa for 30 minutes to obtain a ceramic body. Then, apply glaze to the ceramic body at a rate of 500 g / m². 2 Finally, the glazed ceramic body is sintered, and after sintering, daily-use ceramics are obtained. The preparation method of the cerium-added modified Bianstone powder is as follows: S01: Preparation of ball milling slurry: S01a: Add 2-4 parts by weight of fly ash and 1-3 parts by weight of silane coupling agent KH550 to 5-8 parts by weight of sodium lignosulfonate solution, stir evenly, and obtain the first ball milling agent; S01b: Mix 3-5 parts by weight of lignocellulose, 2-4 parts by weight of stearic acid and 5-8 parts by weight of dopamine hydrochloride solution to obtain the second ball milling agent; S01c: Continue to mix the first ball milling agent and the second ball milling agent at a weight ratio of 3:2 until they are thoroughly mixed to obtain the ball milling liquid; S02: Add 30-35% of the total weight of Bianstone powder to the ball milling liquid for primary ball milling improvement treatment. After ball milling, Bianstone ball milling liquid is obtained. S03: The Bianstone ball milling liquid and cerium additive are subjected to a two-stage ball milling improvement at a weight ratio of 5:(2~3). After the ball milling is completed, the mixture is filtered and dried to obtain modified Bianstone powder with cerium additive.

2. The method for preparing a daily-use ceramic formula according to claim 1, characterized in that, The improved primary ball mill has a ball milling speed of 750–850 r / min and a ball milling time of 1 hour; the improved secondary ball mill has a ball milling speed of 450–550 r / min and a ball milling time of 2 hours.

3. The method for preparing a daily-use ceramic formula according to claim 1, characterized in that, The sodium lignosulfonate solution has a mass fraction of 2-5%; the dopamine hydrochloride solution has a mass fraction of 3-6%.

4. The method for preparing a daily-use ceramic formula according to claim 1, characterized in that, The preparation method of the cerium additive is as follows: Zirconia, sodium silicate solution and magnesium oxide are mixed thoroughly in a weight ratio of (2-4):(3-5):2 to obtain a zirconia agent; Cerium oxide is added to a lanthanum chloride solution at a weight ratio of 1:

3. Then, 8-12% of the total weight of the lanthanum chloride solution is added to the lanthanum chloride solution and stirred thoroughly. The mixture is then filtered, dried, and heat-treated at 170-180°C for 20 minutes. Finally, it is air-cooled to room temperature to obtain the cerium additive.

5. The method for preparing a daily-use ceramic formula according to claim 4, characterized in that, The sodium silicate solution has a mass fraction of 3-5%; the lanthanum chloride solution has a mass fraction of 2-4%.

6. The method for preparing a daily-use ceramic formula according to claim 1, characterized in that, The preparation method of the modified titanium dioxide agent is as follows: S11: First, place titanium dioxide in a sufficient amount of sodium alginate solution with a mass fraction of 5% and disperse it evenly to obtain titanium dioxide solution; S12: Mix 1-2 parts by weight of sodium dodecylbenzenesulfonate, 2-4 parts by weight of silicon carbide, 1-3 parts by weight of boron oxide and 5-8 parts by weight of chitosan solution with a mass fraction of 5% to obtain a modifier. S13: Add 5-8% of the total weight of the titanium dioxide liquid modifier to the titanium dioxide liquid and stir. The stirring temperature is 55℃, the stirring time is 1-2 hours, the stirring speed is 550 r / min, and then the mixture is filtered and dried to obtain the modified titanium dioxide agent.

7. The method for preparing a daily-use ceramic formula according to claim 1, characterized in that, The sintering temperature in step four is 1250℃, and the sintering time is 2 hours.

8. A daily-use ceramic formulation prepared by the method described in any one of claims 1-7.

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