Fragrance mixture (VI)

Abstract

The invention relates to a perfume mixture comprising or consisting of (a) at least one main perfume having fruity and floral notes, and (b) 1-(3, 3-dimethylcyclohexyl) ethanone.

Description

Field of the Invention

[0001] The present invention relates to the field of perfumes and to perfume mixtures containing 1-(3,3-dimethylcyclohexyl)ethanone having improved odor notes. Background of the Invention

[0002] As far as the perfume industry is concerned, there is a great demand for fragrances, especially notes, which allow the fragrance palette to expand. There is a particularly high demand for fragrances that, in small doses, can have a big impact on other fragrances and make them better. Prior art

[0003] US2013336911 AA (GIVAUDAN) describes a deodorant composition comprising a mixture of at least three fragrances, one of which has, for example, an ethyl ketone structure.

[0004] EP 1395542 B1 (FIRMENICH) relates to a process for preparing enones in one step by aldol condensation of ketones, for example gem-dimethylcyclohexyl ethyl ketone or gem-dimethylcyclohexenyl ethyl ketone derivatives, in the presence of a novel catalyst system and auxiliary components such as carboxylic anhydrides or anhydrous salts, without prior formation of the enolate. Purpose of the Invention

[0005] The object of the present invention was therefore to provide novel fragrance mixtures based on fragrances with original fruity and floral notes which show an improvement especially with regard to stronger odor notes, while for example technical notes are reduced. Summary of the invention

[0006] The first object of the present invention relates to a flavor mixture, which comprises or consists of the following ingredients: (a) at least one primary fragrance having fruity and floral notes, and (b) 1-(3,3-Dimethylcyclohexyl)ethanone.

[0007] Surprisingly, it has been observed that 1-(3,3-dimethylcyclohexyl)ethanone is able to increase, improve and / or adjust the original notes of a main fragrance with fruity and floral notes, even in very small doses. In particular, the fruity and floral notes are enhanced, becoming more intense, while other desired odor notes, such as intense, are emphasized, and less desirable odor notes, such as technical notes, are weakened. In this way, the perfumer's fragrance palette can be significantly expanded by adding very small amounts of several ingredients. 1-(3,3-Dimethylcyclohexyl)ethanone

[0008] 1-(3,3-Dimethylcyclohexyl)ethanone(Cas No:25304-14-7) It is known in the perfumery industry. There is applicability of perfume ingredients and precise odor descriptions. According to perfumers, the compound of formula (I) smells woody, camphorous, earthy, eucalyptus-like and minty. Main spices

[0009] The main fragrance group is characterized by dominant fruity and floral notes. Typical examples include allyl cyclohexylpropionate, dimethylbenzyl butyrate, ethyl 2-methylbutyrate, ethyl 2,4-dimethyl-1,3-dioxane-2-acetate, 1,3-dimethylbutyl 2-butenoate, 1,1'-bis(cyclopentyl)-2-(2E)-but-2-enoate, tetradecane, phenylethyl alcohol, β-methylphenylpentyl alcohol, benzyl acetate, methyl dihydrojasmonate, hydroxycitronellal, citronellol, linalool, benzyl salicylate, tetrahydro-2-isobutyl-4-methylpyran-4-ol and mixtures thereof.

[0010] The mixture according to the present invention may contain the main fragrance and the 1-(3,3-dimethylcyclohexyl)ethanone in an amount ranging from about 98 to 2 to about 99.9 to 0.5 wt %, preferably in a range of about 0.6 to 1.0 wt %, based on the mixture. Solvents

[0011] In a preferred embodiment, the mixture according to the present invention may contain at least one solvent. Suitable solvents are selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol and triethyl citrate. Typically, the at least one solvent is present in the mixture in an amount of about 10% by weight to about 90% by weight, preferably about 25% by weight to about 50% by weight. Aromatherapy composition

[0012] Another object of the present invention relates to a fragrance composition comprising a mixture as defined above and at least one secondary fragrance different from the main fragrance and 1-(3,3-dimethylcyclohexyl)ethanone. The secondary fragrance can be selected from the following group: ·[(3,7-Dimethyl-6-octenyl)-oxy]-acetaldehyde, ·1-(p-menthen-6(2)-yl)-1-propanone, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, ·10-Undecene-1-aldehyde, ·10-Undecen-1-ol, 1-Decanal, 1-Dodecanal, ·1-Methyl-3-(4-methylpentyl)-3-cyclohexene-carboxaldehyde, ·1-Methyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carbaldehyde, 1-Nonanal, 1-Octanal, 1-Octene-3-ol, ·1-p-menthene-q-carboxaldehyde, 1-Undecanal, ·2-(2-(4-methyl-3-cyclohexen-1-yl)propyl)-cyclopentanone, ·2,4,4,7-Tetramethyl-oct-6-en-3-one, 2,4,6-Trimethyl-3-cyclohexene-l-carbaldehyde, ·2,4-Dimethyl-3-cyclohexene-1-carboxaldehyde 4-methoxybenzaldehyde, 2,4-Dimethyl-3-cyclohexene-1-carbaldehyde, 2,6,10-Trimethyl-5,9-undecadienal, ·2,6,10-Trimethyl-9-undecenal,3-dodecen-1-al, 2,6-Dimethyl-5-heptenal; ·2,6-Dimethylhept-5-en-1-al, 2,6-Dimethylheptan-2-ol, 2,6-nonadienal, ·2-Acetyl-3,3-dimethyl-norbornane, 2-Methyldecanal, 2-Methyloctanal, 2-Methylundecanal, ·2-Methyl-3-(4-tert-butyl)propanal, ·2-Methyl-3-(isopropyl-phenyl)propanal, ·2-Methyl-3-(p-methoxy-phenylpropanal), ·2-Methyl-3-phenyl-2-propene-1-aldehyde, ·2-Methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal, 2-Methylbutanol, 2-Methylpentanol, 2-Phenoxyethanol, 2-Phenylpropan-1-aldehyde, 2-Phenylpropanol, 2-tert-Butylcyclohexanol, ·3-(3,4-Methylenedioxy-phenyl)-2-methylpropan-1-aldehyde, ·3-(3-Isopropylphenyl)-butan-1-aldehyde, ·3-(4-ethylphenyl)-2,2-dimethylpropan-1-aldehyde, ·3-(4-ethylphenyl)-2,2-dimethylpropanal, ·3-(4-isopropylphenyl)-2-methylpropan-1-al, ·3-(4-methoxyphenyl)-2-methylpropanal, ·3-(4-tert-Butylphenyl)-2-methyl-propanal, ·3-(4-tert-Butylphenyl)-propanal, ·3,4-Dimethoxybenzaldehyde, ·3,4-Methylenedioxybenzaldehyde, 3,5,5-Trimethylcyclohexanol, ·3,5,5-Trimethylhexanal, ·3,5,6-Trimethyl-3-cyclohexenecarboxaldehyde, ·3,7-Dimethyl-2-methylene-6-octenal, ·3,7-Dimethyl-6-octen-1-al, ·3,7-Dimethyloctan-1-aldehyde, ·3-Ethoxy-4-hydroxybenzaldehyde, 3-Hexanol, ·3-Methoxy-4-hydroxy-benzaldehyde, ·3-Methyl-5-phenyl-1-pentanal, 3-Methyl-5-phenylpentanol, 3-Octanol, ·3-phenyl-2-hexylprop-2-enal, ·3-phenyl-2-pentylprop-2-en-1-al, ·3-phenyl-2-propenal, ·3-phenylprop-2-en-1-al, 3-Phenylpropanol, ·3-propyl-bicyclo[2.2.1]-hept-5-ene-2-carbaldehyde, ·4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanone, ·4-(3)(4-methyl-3-pentenyl)-3-cyclohexene-carboxaldehyde, ·4-(4-Hydroxy-3-methoxyphenyl)-2-butanone, 4-(4-Hydroxy-4-methylpentyl)-3-cyclohexene-l-carbaldehyde, 4-(Tricyclo[5.2.1.0(2,6)]-decanedyl-8)-butyraldehyde; 4-Dihydrodamascol, 4-Heptenol, 4-Hydroxy-3-methoxybenzaldehyde, 4-Isopropylbenzaldehyde, 4-Isopropylcyclohexanol, 4-Methoxybenzaldehyde, 4-Methylphenylacetaldehyde, 4-tert-Butylcyclohexanol, 5,9-Dimethyl-4,8-decadienal, ·5-Methoxyhexahydro-4,7-methyleneindene-1-carbaldehyde, ·5-Methoxyhexahydro-4,7-methyleneindene-2-carbaldehyde, ·6,10-Dimethyl-3-oxa-5,9-undecadien-1-al, ·6,6-Dimethylbicyclo[3.3.1]hept-2-ene-2-propanal, ·6,7-Dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, ·6,8-Dimethyl-2-nonanol,6-nonen-1-ol, ·6-Isopropyl-decahydro-2-naphthone (naphtone), ·6-Methoxyhexahydro-4,7-methyleneindane-1-carbaldehyde, ·6-Methoxyhexahydro-4,7-methyleneindane-2-carbaldehyde, 7-Hydroxy-3,7-dimethyloctanal, 7-Methoxy-3,7-dimethyloctan-1-aldehyde, 9-Decen-1-ol, 9-Decenal, ·Acetophenone, Adoxaldehyde, ·Allyl cyclohexyl propionate, · alpha-ionone (alphalonen), ·Ambroxan, ·Amyl salicylate, Anethole, ·Anisaldehyde, Benzaldehyde, ·Benzophenone, Benzyl acetate, Benzyl acetone, Benzyl alcohol, Benzyl salicylate, Benzyl ethyl ether, ·Polychlorinated red aldehyde, ·Buccoxime, ·Butyl salicylate, Camphor, ·Consinaldehyde, ·Carvone, · Piperonyl acetone (cassione), Celery cetone ·Chlorhydral, · Cinnamyl alcohol, ·cis- / trans-3,7-dimethyl-2,6-octadiene-1-aldehyde, ·cis-Jasmone, Citral or its mixtures, Citronellal, Citronellol, Citronellyl acetaldehyde, ·Cumaldehyde, Cyclamen aldehyde, Cyclohexyl salicylate, Cymal, ·Damarose, ·Damascenone, ·Decanol, ·Decanal, ·2-pentylcyclopentanone (delphone), ·Dihydrojasmone, ·Dihydromyrcenol, ·Dihydrocinnamaldehyde, ·Dihydro-β-ionone, ·Dimethylbenzyl alcohol, ·Dimethylbenzyl acetate, ·Dimethylheptanol, ·Dimethyloctanol, ·Dimethyl octenone, ·Dulcinyl ·Ethyl salicylate, ·Ethyl vanillin, ·Methylphenylglycine ethyl ester, Eugenol, ·Fenchnone, 2-Heptylcyclopentanone (fleuramone), ·Floralozon, ·2-tert-Butylcyclohexylethyl carbonate (floramat), · Florhydral, ·2-Acetyloctanoate (gelsone), ·Geraniol, · Methyl dihydrojasmonate (hedione), · Neohexymol, ·Piperonal, Heptanol, ·Hexahydro-4,7-methyleneindan-1-carbaldehyde, ·Hexahydro-8,8-dimethyl-2-naphthaldehyde, · Hexalone, ·Hexyl salicylate, ·Hydroxycitronellal, ·Isoborneol, ·Isodacamone, ·Isoeugenol, ·Isojasmone, ·Isopulegol, · Methylcyclohexyl carbonate (jasmacyclatat), ·koavon, ·Lauryl aldehyde, · Ligustrum aldehyde, Citral, ·Lilial, · Limonene, Linalool, Linalyl acetate, ·livescon, Lyral, · Cymene-7-carboxaldehyde, Melonaldehyde, ·3,5,5-Trimethylhexanoic acid ethyl ester (melusat), ·Menthol, Menthone, Methylacetophenone, ·Methyl cedryl ketone, Methyl cedryl ketone, Methyl cedryl ketone, Methylcyclocitron, ·Methyl dihydrojasmonate, ·Methyl heptenone, Methyl lavandinone, ·Methyl dihydrojasmonate, ·Methylnonyl acetaldehyde, ·Methyl-β-naphthone, Musk indanone, Musk ketone, ·Myrtenol, n-Dodecanal, Neobutenone, ·Nerolidol, · n-Hexanol, Nonanol, n-Undecanal, Octahydro-4,7-methylene-1H-indenecarboxaldehyde; ·Octylaldehyde, Octanol, o-Methoxycinnamaldehyde, ·4-(2-methylbutyl-2-yl)cyclohexane-1-one (orivone), · p-Ethyl-α,α-dimethylhydrocinnamaldehyde, ·phenol, Phenoxyacetaldehyde; ·Phenoxy isobutyrate, · Phenyl acetaldehyde, · Phenyl salicylate, · Phenylethyl acetate, · Phenylethyl alcohol, · 4-Hydroxyphenylbutanone, ·Pinene ·Plictone, · p-Menth-7-ol, · p-Methoxyacetophenone, · p-Methylphenoxyacetaldehyde, ·P-tert.-bucinal, · 4-tert-Butylcyclohexanone, · 4-tert-Butyl Cyclohexylacetate, p-Tolyl acetaldehyde; ·Styryl propionate, ·Tetrahydrogeraniol, ·Tetrahydrolinalool, ·tetrameran, · Thymol, ·tonalid / musk plus, · trans-2-cis-6-nonadienol, · trans-2-nonen-1-ol, · trans-2-octenol, · trans-4-decenal, · Ligustrum aldehyde, Undecanal, ·Undecanol, ·Undecenal, · Vanillin, ·Valone, ·2-tert-Butylhexaphenol ester (verdone), ·α.-Methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde, α-Damascenone, ·α-Methylbenzyl alcohol, ·α-Methyl-4-(l-methylethyl)phenylacetaldehyde, ·α-Methylphenylacetaldehyde, ·α-Amylcinnamaldehyde, ·α-n-Hexylcinnamaldehyde, α-Terpineol, β-Damascenone, β-ionone, β-Terpineol, γ-Methylionone, ·δ-Damascenone, The fragrance composition may contain the 1-(3,3-dimethylcyclohexyl)ethanone alone, or a mixture of 1-(3,3-dimethylcyclohexyl)ethanone and the main fragrance, in an amount ranging from about 0.01 to about 2% by weight, preferably from about 0.1 to 1% by weight, based on the composition. Cosmetic and personal care compositions

[0013] Another object of the present invention relates to a cosmetic or personal care preparation, which comprises the fragrance mixture or the fragrance composition as described above. The preparation may contain about 0.01 to about 2% by weight, preferably about 0.1 to 1% by weight of the fragrance mixture or fragrance composition - based on the preparation. The composition may represent, for example, a cosmetic cream, a lotion, a spray, an emulsion, an ointment, a gel, a mousse, and the like.

[0014] The preparations according to the present invention may include anti-dandruff agents, anti-irritants, anti-irritants, antioxidants, astringents, antiperspirants, bactericides, antistatic agents, adhesives, buffers, carriers, chelating agents, cell stimulants, cleaning agents, care agents, deodorants, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibers, film formers, color fixatives, foam formers, foam stabilizers, defoamers, foam boosters, gelling agents, gel formers, hair care agents, hair fixatives, hair straighteners, moisturizers, wetting agents, moisturizers, bleaching agents, strengthening agents, stain repellents, optical brighteners, impregnants, stain repellents, friction reducers, lubricants, moisturizing creams, ointments, sunscreens, plasticizers, covering agents, polishes, glosses, polymers, powders, proteins, re-oiling agents, As additional auxiliaries and additives, there are used agents, abrasives, silicones, hair growth agents, coolants, skin coolants, warming agents, skin warming agents, stabilizers, UV absorbers, UV filters, detergents, thickeners, vitamins, oils, waxes, fats, phospholipids, saturated fatty acids, mono- or polyunsaturated fatty acids, alpha-hydroxy acids, polyhydroxy fatty acids, liquidifiers, dyes, color protection agents, pigments, fragrance substances, polyols, surfactants, electrolytes, organic solvents or silicone derivatives. Surfactants

[0015] Preferred auxiliaries and additives are anionic and / or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants may also be present in the composition. Suitable examples are mentioned in the paragraph relating to emulsifiers.

[0016] Typical examples of anionic and zwitterionic surfactants include: almond amidopropylamine oxide, almond amidopropyl betaine, aminopropyl lauryl glutamine, ammonium C12-15 alkyl sulfate, ammonium C12-16 alkyl sulfate, ammonium capryl sulfate, ammonium monococoglyceryl sulfate, ammonium coconut sulfate, ammonium cocoyl isethionate, ammonium cocoyl sarcosinate, ammonium C12-15 alkylene sulfate, ammonium C9-10 perfluoroalkyl sulfonate, ammonium dinonyl sulfosuccinate, ammonium dodecylbenzene sulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 sulfate, ammonium octanol ... Ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myristyl sulfate, ammonium myristyl sulfate, ammonium nonylphenol polyether-4 sulfate, ammonium nonylphenol polyether-30 sulfate, ammonium oleate, ammonium palm kernel alcohol sulfate, ammonium stearate, ammonium tall oil acid, isostearyl hydrolyzed collagen AMPD salt, rosin (acyl) hydrolyzed collagen AMPD salt, isostearyl hydrolyzed collagen AMP salt, isostearyl hydrolyzed keratin AMP salt, isostearyl hydrolyzed soy protein AMP salt, isostearyl hydrolyzed wheat protein AMP salt, wild apricot oleamidopropyl betaine, arachidic acid, hexyldecyl phosphate arginine salt, avocado oleamidopropyl betaine, avocado oil glyceryl polyether-8 esters, babassu Seed oil acid, babassu amidopropylamine oxide, babassu amidopropyl betaine, beeswax acid, behenamidopropyl betaine, behenamine oxide, beheneth-25, beheneth-30, behenic acid, behenyl betaine, bis-butyl dimethicone polyglyceryl-3, butylphenol polyether-5 carboxylic acid, butylphenol polyether-19 carboxylic acid, butyldimethyl (hydroxypropyl butyl glucoside) ammonium chloride, butyldimethyl (hydroxypropyl lauryl glucoside) ammonium chloride, butyl glucoside, butyl glucoside decanoate, butyl glucoside hydroxypropyltrimonium chloride, butyl caprylate, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C 9-16 Alkane / Cycloalkane, C10-14 Alkylbenzenesulfonic Acid, C12-14 Alkyl Di(Aminoethyl)Glycine HCl, C9-15 Alkyl Phosphate, Candida / Glucose / Rapeseed Methyl Ester Ferment, Canola Amidopropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glucoside, Caprylyl / Caprylamidopropyl Betaine, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Caprylic Acid, Capryloyl Collagen Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids, Capryl / Decyl Glucoside, Capryl / Decyl Wheat Bran / Straw Glycosides, Capryl Glucoside, Caprylyl Glyceryl Ether, Capryl Pyrrolidone, Carnitine, Ceteareth-20,Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Ceteareth-4 Phosphate Acid, Ceteareth-5 Phosphate, Ceteareth-10 Phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Ceteth-22, Ceteth-24, Ceteth-25, Ceteth-30, Cetyl Betaine, Chrysanthemum Sinense flower extract, C12-14 hydroxyalkyl hydroxyethyl beta-alanine, C12-14 hydroxyalkyl hydroxyethyl sarcosine, cocamidoethyl betaine, cocamidopropylamine oxide, cocamidopropyl betainamide MEA chloride, cocamidopropyl betaine, cocamidopropyl hydroxysultaine, cocamine oxide, cocoaminobutyric acid, cocoaminopropionic acid, coceth-7 carboxylic acid, coceth-4 glucoside, cocoamphopropionic acid, cocobeth-4 glucoside, cocoamphopropionic acid, cocobeth-betaine amidoamphopropionate, cocobetaine, cocodimonium hydroxypropyl hydrolyzed rice protein, cocodimonium hydroxypropyl hydrolyzed soy protein, cocodimonium hydroxypropyl hydrolyzed wheat protein, coco-glucoside, coco-glucoside hydroxypropyltrimonium chloride, coco-hydroxysultaine, cocomorpholine oxide, cocoic acid, cocoglyceryl polyether-8 Esters, cocoyl / oleamidopropyl betaine, cocoyl-sulfobetaine, (coconut oil / sunflower seed oil) amidopropyl betaine, cocoyl choline methyl sulfate, cocoyl glutamic acid, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn oil acid, cotton Seed oil acid, cottonseed oil glyceryl polyether-8 esters, C10-16 parathion-1, C10-16 parathion-2, C11-13 parathion-6, C11-13 parathion-9, C11-13 parathion-10, C11-15 parathion-30, C11-15 parathion-40, C12-13 parathion-1, C12-13 parathion-23,C12-14 Pareth-5, C12-14 Pareth-9, C13-15 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 Carboxylic Acid, C9-11 Pareth-8 Carboxylic Acid, C11-15 Pareth-7 carboxylic acid, C12-13 pareth-5 carboxylic acid, C12-13 pareth-7 carboxylic acid, C12-13 pareth-8 carboxylic acid, C12-13 pareth-12 carboxylic acid, C12-15 pareth-7 carboxylic acid, C12-15 pareth-8 carboxylic acid, C12-15 pareth-12 carboxylic acid, C14-15 pareth-8 carboxylic acid, C6-10 pareth-4 phosphate, C12-13 pareth-2 phosphate, C12-13 C12-15 Pareth-6 Phosphate, C12-15 Pareth-8 Phosphate, C12-15 Pareth-10 Phosphate, C12-16 Pareth-6 Phosphate, C4-18 Perfluoroalkyl Ethyl Mercaptopropyl Trimethylammonium Chloride, Cocoamidopropyl Betaine, C12-13 Alcohol Sulfate DEA, C12-15 Alcohol Sulfate DEA, Ceteareth-2 Phosphate DEA, Cetyl Sulfate DEA, Cocoyl DEA amphoteric dipropionate, DEA C12-13 alkane polyether-3 sulfate, DEA cyclopentyl oleate, DEA dodecylbenzene sulfonate, DEA isostearate, DEA laureth sulfate, DEA lauryl sulfate, DEA linoleate, DEA myristyl methyl sulfonate, DEA myristyl ether sulfate, DEA myristate, DEA myristyl sulfate, DEA oleth-5 phosphate, DEA oleth-20 phosphate, DEA PG-oleate, Deceth-7 carboxylic acid, Deceth-7 glucoside, Deceth-9 phosphate, Decylamine oxide, Decyl betaine, Decyl glucoside, Decyltetradeceth-30, Decyltetradeceth-2 oxide, Lauramide-MEA diammonium sulfosuccinate, Laureth-2 diammonium sulfosuccinate, Oleamido PEG-2 diammonium sulfosuccinate, Dibutoxymethane, Di-C12-15 Pareth-2 phosphate, Di C12-15 pareth-4 phosphate, di-C12-15 pareth-6 phosphate, di-C12-15 pareth-8 phosphate, di-C12-15 pareth-10 phosphate, didoyl butane tetracarboxylate, laureth sulfate diethylamine salt, sodium diethylhexyl sulfosuccinate, di(hydroxyethyl) C8-10 alkoxypropylamine oxide, di(hydroxyethyl) C9-11 alkoxypropylamine oxide,Di(hydroxyethyl) C12-15 alkoxypropylamine oxide, di(hydroxyethyl) cocamine oxide, di(hydroxyethyl) laurylamine oxide, di(hydroxyethyl) stearamine oxide, di(hydroxyethyl) tallowamine oxide, dimethicone PEG-7 phosphate, dimethicone PEG-10 phosphate, dimethicone PEG / PPG-7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone / polyglyceryl-3 crosspolymer, dimethicone propyl PG-betaine, dimyristyl phosphate, dioleamide ethyl hydroxyethyl Methylammonium methylsulfate, hydrogenated coconut oil DIPA salt, lanolin acid DIPA salt, myristic acid DIPA salt, dipotassium capryloyl glutamate, dipotassium lauryl sulfosuccinate, dipotassium undecylenyl glutamate, disodium babassu oleamido MEA-sulfosuccinate, disodium capryloylamphodiacetate, disodium capryloylamphodipropionate, disodium capryloylamphodiacetate, disodium capryloylamphodipropionate, disodium capryloyl glutamate, disodium cetearyl sulfosuccinate, disodium cetyl phenyl ether disulfonate, disodium cetyl alcohol sulfosuccinate, disodium cocamido MEA-sulfosuccinate, cocamido MIPA Disodium PEG-4 Sulfosuccinate, Disodium Cocoamido MIPA-Sulfosuccinate, Disodium Cocoamido PEG-3 Sulfosuccinate, Disodium Cocoeth-3 Sulfosuccinate, Disodium Cocoamphocarboxyethyl Hydroxypropyl Sulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Coco-Glucoside Sulfosuccinate, Disodium Coco-Sulfosuccinate, Cocoyl Butyl Glucose Disodium Cocoyl Glutamate, Disodium C12-14 Pareth-1 Sulfosuccinate, Disodium C12-14 Pareth-2 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium C12-14 Sec-Pareth-3 Sulfosuccinate, Disodium C12-14 Sec-Pareth-5 Sulfosuccinate, Disodium C12-14 Sec-Pareth -7 sulfosuccinate disodium, C12-14 sec-alkanol pareth-9 sulfosuccinate disodium, C12-14 sec-alkanol pareth-12 sulfosuccinate disodium, deceth-5 sulfosuccinate disodium, deceth-6 sulfosuccinate disodium, decyl phenyl ether disulfonate disodium, dihydroxyethyl sulfosuccinyl undecylenate disodium, dicocoyl ethylenediamine PEG-15 disulfate disodium, hydrogenated cottonseed oil glycerides sulfosuccinate Disodium amber ester, disodium hydrogenated tallow glutamate, disodium hydroxydecyl sorbitan citrate, disodium isodecyl sulfosuccinate, disodium isostearamide MEA-sulfosuccinate, disodium isostearamide MIPA-sulfosuccinate, disodium isostearylamphodiacetate, disodium isostearylamphodipropionate, disodium isostearyl sulfosuccinate, disodium lanolin alcohol ether-5 sulfosuccinate, disodium lauryl amide MEA-sulfosuccinate,Disodium lauroyl MIPA glycol sulfosuccinate, disodium lauroyl PEG-2 sulfosuccinate, disodium lauroyl PEG-5 sulfosuccinate, disodium laureth-5 carboxyamphodiacetate, disodium laureth-7 citrate, disodium laureth sulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium laurimidobishydroxypropyl sulfonate, disodium laurimidodiacetate, disodium laurimidodipropionate, disodium laurimidodipropionate tocopheryl phosphate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium N-lauroyl aspartate, lauroyl glutamate Disodium lauryl phenyl ether disulfonate, diammonium lauryl sulfosuccinate, disodium myristamide MEA-sulfosuccinate, disodium nonylphenol polyether-10 sulfosuccinate, disodium oleamide MEA sulfosuccinate, disodium oleamide MIPA sulfosuccinate, disodium oleamide PEG-2 sulfosuccinate, disodium oleoamphodipropionate, disodium oleeth-3 sulfosuccinate, disodium oleyl phosphate, disodium oleyl sulfosuccinate, disodium palmitamide PEG-2 sulfosuccinate, disodium palmitamide PEG-2 sulfosuccinate, disodium palmitamide PEG-4 sulfosuccinate, disodium PEG-12 polydimethylsiloxane sulfosuccinate, PEG-8 palmitic acid Glycerides Disodium sulfosuccinate, PPG-2-isodecyl polyether-7 sodium carboxyamphodiacetate, disodium ricinoleamide MEA sulfosuccinate, disodium sitosterol polyether-14 sulfosuccinate, disodium soybean oleylamphodiacetate, disodium stearamide MEA-sulfosuccinate, disodium stearimidodipropionate, disodium stearamidodiacetate, disodium stearoyl glutamate, disodium sulfosuccinic acid monoacyl stearylamine, disodium stearyl alcohol sulfosuccinate, disodium 2-sulfolaurate, disodium 2-sulfopalmitate, disodium tallowamide MEA sulfosuccinate, disodium tallowamide MEA sulfosuccinate, disodium tallowamidodiacetate, disodium tallowimidodipropionate, disodium sulfosuccinic acid monoacyl tallowamine, tridecyl alcohol Disodium sulfosuccinate, disodium undecylenamide MEA sulfosuccinate, disodium undecylenamide PEG-2 sulfosuccinate, disodium undecylenyl glutamate, disodium monowheat germ oleoyl MEA sulfosuccinate, disodium monowheat germ oleoyl PEG-2 sulfosuccinate, disodium wheat germ oleoyl amphoteric acid, cocamide diacetate di-TEA salt, oleamide PEG-2 sulfosuccinate di-TEA salt, palmitoyl aspartate di-TEA salt, sodium tridecyl sulfosuccinate, dodecylbenzenesulfonic acid, erucamidopropyl hydroxysulfobetaine, ethylhexyl alcohol polyether-3 carboxylic acid, ethyl PEG-15 cocamide sulfate, caprylyl glyceryl ether, hexyl capric acid, hydrogenated coconut acid, hydrogenated lanolin alcohol polyether-25,Hydrogenated menhaden oil fatty acid, hydrogenated palmitoleic acid, hydrogenated palm kernel oil amine oxide, hydrogenated tallow acid, hydrogenated tallow amine oxide, hydrogenated tallow betaine, hydrogenated tallow alcohol polyether-25, hydrogenated tallow acyl glutamate, hydrogenated candida extract, hydroxycetyl alcohol polyether-60, hydroxyethyl acetoxymethyl ammonium PG-polydimethylsiloxane, laureth sulfate hydroxyethyl butylamine salt, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylauryl / hydroxymyristyl betaine, hydroxystearic acid, hydroxysuccinimide C10-40 isoalkanoate, hydroxysuccinimide C21-22 isoalkanoate, hydroxysultaine, IPDI / PEG-15 soybean oil amine oxide copolymer, IPDI / PEG-15 soybean oil amine ethanol methyl sulfate copolymer, IPDI / PEG-15 soybean oil glycine ester copolymer, lsoceteth-30, isolaureth-4 phosphate, isopolyglyceryl-3 polydimethylsiloxane, isopolyglyceryl-3 polydimethylsiloxane, isopropylamine lanolin acid ester, isopropylamine dodecylbenzenesulfonate, isostearamidopropylamine oxide, isostearamidopropyl betaine, isostearamidopropyl morpholine oxide, isosteareth-8, isosteareth-16, isosteareth-22, isosteareth-25, isosteareth-50, isostearic acid, isostearyl hydrolyzed collagen, jojoba oil PEG-150 esters, jojoba wax PEG-80 esters, jojoba oil PEG-120 esters of joba wax, lanolin alcohol polyether-20, lanolin alcohol polyether-25, lanolin alcohol polyether-40, lanolin alcohol polyether-50, lanolin alcohol polyether-60, lanolin alcohol polyether-75, lanolin acid, lauramide propylamine oxide, lauramide propyl betaine, lauramide propyl hydroxysulfobetaine, lauramine oxide, lauryl aminopropionic acid, lauryl dimethyl hydroxypropyl decyl glucoside ammonium chloride, lauryl dimethyl lauryl glucoside hydroxypropyl ammonium chloride, laureth-16, laureth-20, laureth-21, laureth-23, laureth-25, laureth-30, laureth-38, laureth-40, laureth-3 carboxylic acid, lauryl Alcohol polyether-4 carboxylic acid, laureth-5 carboxylic acid, laureth-6 carboxylic acid, laureth-8 carboxylic acid, laureth-10 carboxylic acid, laureth-11 carboxylic acid, laureth-12 carboxylic acid, laureth-13 carboxylic acid, laureth-14 carboxylic acid, laureth-17 carboxylic acid, laureth-6 citrate, laureth-7 citrate, laureth-1 phosphate, laureth-2 phosphate, laureth-3 phosphate, laureth-4 phosphate, laureth-7 phosphate, laureth-8 phosphate, laureth-7 tartrate, lauric acid, lauriminodipropylene glycol, lauriminodipropionic acid, lauroylamphodipropionic acid, lauroyl β-aminopropionic acid,Lauroyl collagen amino acid, lauroyl ethyltrimonium methosulfate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methyl glucamide, lauroyl sarcosine, lauroyl silk amino acid, lauryl betaine, lauryl dimethicone / polyglyceryl-3 crosspolymer, lauryl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, lauryl glucoside, lauryl glucoside hydroxypropyltrimonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysulfobetaine, lauryl malic acid amide, lauryl methyl glucosamine, (laury / myristic) glycol hydroxypropyl ether, (laury / myristic) wheat bran / straw glycosides, lauryl polyglyceryl-3 polydimethylsiloxyethyl polydimethicone, lauryl pyrrolidone, lauryl dimethyl Sultaine, Linoleic Acid, Linolenic Acid, Linolenic Acid, Lysine Cocoate, Macadamia Seed Oil Glyceryl Ether-8 Esters, Magnesium Cocoyl Sulfate, Magnesium Cocoyl Sulfate, Magnesium Isododecylphenyl Sulfonate, Magnesium Laureth-11 Carboxylate, Magnesium Laureth Sulfate, Magnesium Laureth-5 Sulfate, Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfonate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myristyl Sulfate, Magnesium Oleth Sulfate, Magnesium Cocoyl Sulfate / TEA, Manigold Root Glacial Mud, Coconut Oil MEA Salt, Laureth-6 Carboxylate MEA Salt, Laureth Sulfate MEA Salt, Moon Lauryl sulfate MEA salt, PPG-6-laureth-7 carboxylic acid MEA salt, PPG-8-stearyl alcohol polyether-7 carboxylic acid MEA salt, undecylenic acid MEA salt, meroxapol 108, meroxapol 174, meroxapol 178, meroxapol 254, meroxapol 255, meroxapol 258, meroxapol 314, methoxy PEG-450 amidoglutaryl succinamide, methoxy PEG-450 amidohydroxysuccinimide succinate, methoxy PEG-450 maleimide, methylmorpholine oxide, milk amide propylamine oxide, milk amide propyl betaine, mink oil amide propylamine oxide, mink oil amide propyl betaine, C12-15 alkyl alcohol polyether sulfate MIPA salt, dodeca MIPA salt of alkylbenzene sulfonate, MIPA salt of lauryl alcohol polyether sulfate, MIPA salt of lauryl alcohol sulfate, mixed isopropanolamine lanolin acid salt, mixed isopropanolamine lauryl sulfate, mixed isopropanolamine myristate, morpholine oleate, morpholine stearate, myristeth-3 carboxylic acid, myristeth-5 carboxylic acid, myristyl benzyl dimethyl ammonium chloride, myristamidopropylamine oxide, myristamidopropyl betaine, myristamidopropyl dimethylamine phosphate, myristamidopropyl hydroxysulfobetaine, myristamidopropyl PG-dimethyl ammonium chloride phosphate, myristamine oxide, myristyl aminopropionic acid, myristic acid, myristoyl ethyltrimethyl ammonium methyl sulfate, myristoyl glutamic acid, myristoyl hydrolyzed collagen,Myristoyl Sarcosine, Myristyl Betaine, Myristyl / Cetylamine Oxide, Myristyl Dimethyl Hydroxypropyl Cocoyl Glucoside Ammonium Chloride, Myristyl Glucoside, Myristyl Alcohol Phosphate, Nonylphenol Eth-20, Nonylphenol Eth-23, Nonylphenol Eth-25, Nonylphenol Eth-30, Nonylphenol Eth-35, Nonylphenol Eth-40, Nonylphenol Eth-44, Nonylphenol Eth-50, Nonylphenol Eth-100, Nonylphenol Eth-120, Nonylphenol Eth-5 Carboxylic Acid, Nonylphenol Eth-8 Carboxylic Acid, Nonylphenol Eth-10 Carboxylic Acid, Nonylphenol Eth-3 Phosphate, Nonylphenol Eth-4 Phosphate, Nonylphenol Eth-6 Phosphate, Nonylphenol Eth-9 Phosphate, Nonylphenol Eth-10 Phosphate, Dinonylphenol Polyether-30, dinonylphenol polyether-49, dinonylphenol polyether-100, dinonylphenol polyether-150, dinonylphenol polyether-7 phosphate, dinonylphenol polyether-8 phosphate, dinonylphenol polyether-9 phosphate, dinonylphenol polyether-10 phosphate, dinonylphenol polyether-11 phosphate, dinonylphenol polyether-15 phosphate, dinonylphenol polyether-24 phosphate, oat oil amidopropyl betaine, octylphenol polyether-16, octylphenol polyether-25, octylphenol polyether-30, octylphenol polyether-33, octylphenol polyether-40, octylphenol polyether-70, octylphenol polyether-20 carboxylic acid, octyldodecyl polyether-20, octyldodecyl polyether-25, octyldodecyl polyether-30, oleamidopropylamine oxide, oleamide Propyl Betaine, Oleamidopropyl (Hydroxysulfonyl)propyl Dimethyl Ammonium, Oleamine Oxide, Oleic Acid, Oleyl Hydrolyzed Collagen, Oleyl Sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleth-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Oleamidopropyl Betaine, Oleic Acid, Oleoyl Hydrolyzed Wheat Protein, Ophiopogon Japonicus Extract Stearate, Ozonoxigenated Oleth-10, Ozonoxigenated PEG-10 Oleate, Ozonoxigenated PEG-14 Oleate, Ozonoxigenated Polysorbate 8 0, Palmitoleic acid, palmitamidopropyl betaine, palmitoleyl alcohol polyether-2 phosphate, palmitamidopropylamine oxide, palmitamidopropyl betaine, palmitamine oxide, palmitic acid, palmitoyl collagen amino acids, palmitoyl glycine, palmitoyl hydrolyzed collagen, palmitoyl hydrolyzed milk protein, palmitoyl hydrolyzed wheat protein, palmitoyl keratin amino acids, palmitoyl oligopeptide, palmitoyl silk amino acids, palm kernel oleic acid, palm kernel oleamidopropyl betaine, peach kernel oil glyceryl polyether-8 esters, arachidic acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-50 castor oil, PEG-54 castor oil, PEG-55 castor oil, PEG-60 castor oil, PEG-80 castor oil,PEG-100 castor oil, PEG-200 castor oil, PEG-11 cocamide, PEG-6 cocamide phosphate, PEG-4 cocamide, PEG-8 cocamide, PEG-12 cocamide, PEG-150 dibehenate, PEG-90 diisostearate, PEG-75 dilaurate, PEG-150 dilaurate, PEG-75 dioleate, PEG-150 dioleate, PEG-75 distearate, PEG-120 distearate, PEG-150 distearate, PEG-175 distearate, PEG-190 distearate, PEG-250 distearate, PEG-30 glyceryl cocoate, PEG-40 glyceryl coconut oil Acid PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soybean Oleate, PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tallowate, PEG- PEG-80 glyceryl tallow ester, PEG-82 glyceryl tallow ester, PEG-130 glyceryl tallow ester, PEG-200 glyceryl tallow ester, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-30 hydrogenated lanolin, PEG-70 hydrogenated lanolin, PEG-50 hydrogenated palmitamide, PEG-2 isostearate, PEG-3 isostearate, PEG-4 isostearate, PEG-6 isostearate, PEG-8 isostearate, PEG -10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide,PEG-20 laurate, PEG-32 laurate, PEG-75 laurate, PEG-150 laurate, PEG-70 mango seed oil glycerides, PEG-20 mannide laurate, PEG-8 methyl ether polydimethylsiloxane, PEG-120 methyl glucose dioleate, PEG-80 methyl glucose laurate, PEG-120 methyl glucose trioleate, PEG-4 montanate, PEG-30 oleamine, PEG-20 oleate, PEG-23 oleate, PEG-32 oleate, PEG-36 oleate, PEG-75 oleate, PEG-150 oleate, PEG-20 palmitate, PEG-150 polyglyceryl-2 tristearate, PE PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG-10 / 30 Copolymer, PEG / PPG-10 / 65 Copolymer, PEG / PPG-12 / 35 Copolymer, PEG / PPG-16 / 17 Copolymer, PEG / PPG-20 / 9 Copolymer, PEG / PPG-20 / 20 Copolymer, PEG / PPG-20 / 60 Copolymer, PEG / PPG-20 / 65 Copolymer, PEG / PPG-22 / 25 Copolymer, PEG / PPG-28 / 30 copolymer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer, PEG / PPG-300 / 55 copolymer, PEG / PPG-20 / 22 methyl ether polydimethylsiloxane, PEG-26-PPG-30 phosphate, PEG / PPG-4 / 2 propyl heptyl ether, PEG / PPG-6 / 2 propyl heptyl ether, PEG-7 / PPG-2 Propyl Heptyl Ether, PEG / PPG-8 / 2 Propyl Heptyl Ether, PEG / PPG-10 / 2 Propyl Heptyl Ether, PEG / PPG-14 / 2 Propyl Heptyl Ether, PEG / PPG-40 / 2 Propyl Heptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glycerides, PEG-75 Sorbitan Cocoate,PEG-20 sorbitan isostearate, PEG-40 sorbitan lanolinate, PEG-75 sorbitan lanolinate, PEG-10 sorbitan laurate, PEG-40 sorbitan laurate, PEG-44 sorbitan laurate, PEG-75 sorbitan laurate, PEG-80 sorbitan laurate, PEG-20 sorbitan oleate, PEG-80 sorbitan palmitate, PEG-40 sorbitan stearate, PEG-60 sorbitan stearate, PEG-160 sorbitan triisostearate, PEG-40 soybean sterol, PEG-2 stearamide carboxylic acid, PEG-9 stearamide carboxylic acid, PE G-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG-120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallate, PEG-50 Tallowamide, PEG-2 Tallowamide DEA, PEG-20 Tallowamide, PEG-66 Trihydroxystearate Lipoic acid, PEG-200 trihydroxystearin, PEG-60 camellia oleate glyceride, nonanoic acid, pentadecylphenol polyether-200, phenol polyether-6 phosphate, poloxamer 105, poloxamer 108, poloxamer 182, poloxamer 183, poloxamer 184, poloxamer 188, poloxamer 217, poloxamer 234, poloxamer 235, poloxamer 237, poloxamer 238, poloxamer 288, poloxamer 334, poloxamer 335, poloxamer 338, poloxamer 908, poloxamer 1508, polydimethylsiloxy PEG / PPG-24 / 19 butyl ether silsesquioxane, polydimethylsiloxy PPG-13 butyl ether silsesquioxane, polyglyceryl Oil-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Laureth, Polyglyceryl-10 Laureth, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomaderris Kumerahou Flower / Leaf Extract, Poria Cocos Extract,Potassium abietic acid hydrolyzed collagen, potassium babassu oleate, potassium behenate, potassium C9-15 alcohol phosphate, potassium C11-15 alcohol phosphate, potassium C12-13 alcohol phosphate, potassium C12-14 alcohol phosphate, potassium caprate, potassium capryloyl glutamate, potassium capryloyl hydrolyzed rice protein, potassium ricinoleate, potassium cocoate, potassium cocoyl glutamate, potassium cocoyl glycinate, potassium cocoyl hydrolyzed casein, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin, potassium cocoyl hydrolyzed oat protein, potassium cocoyl hydrolyzed potato protein, potassium cocoyl hydrolyzed rice bran protein, potassium cocoyl hydrolyzed rice protein, potassium cocoyl hydrolyzed silk, potassium cocoyl hydrolyzed soy protein, potassium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed yeast protein, cocoyl PCA Potassium, Potassium Cocoyl Sarcosine, Potassium Cocoyl Taurine, Potassium Corn Oleate, Potassium Cyclopropyl Oleate, Potassium Dihydroxyethyl Cocoamine Oxide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecylbenzenesulfonate, Potassium Hemp Seed Oil, Potassium Hydrogenated Coconut Oil, Potassium Hydrogenated Palm Oleate, Potassium Hydrogenated Tallow, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolin Oleate, Potassium Laurate, Potassium Laureth-3 Carboxylate, Potassium Laureth-4 Carboxylate, Potassium Laureth-5 Carboxylate, Potassium Laureth-6 Carboxylate, Potassium Laureth-10 Carboxylate, Potassium Laureth Phosphate, Potassium Lauroyl Collagen Amino Acids, Potassium Lauroyl Glutamate, Potassium Lauroyl Hydrolyzed Collagen, Potassium Lauroyl Hydrolyzed Pea Protein, Potassium Lauroyl Hydrolyzed Soy Protein, Potassium Lauroyl PCA, Laury Potassium acyl pea amino acids, potassium lauroyl sarcosine, potassium lauroyl silk amino acids, potassium lauroyl wheat amino acids, potassium lauryl phosphate, potassium lauryl sulfate, potassium linoleate, potassium metaphosphate, potassium methyl cocoyl taurate, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octylphenol polyether-12 phosphate, potassium oleate, potassium oleoyl hydrolyzed collagen, potassium olivetate, potassium olivetate hydrolyzed oat protein, potassium olivetate hydrolyzed wheat protein, potassium olivetate / lauroyl wheat amino acids, potassium olivetate PCA, potassium palmitoleate, potassium palmitate, potassium palmitoyl hydrolyzed corn protein, potassium palmitoyl hydrolyzed oat protein, potassium palmitoyl hydrolyzed rice protein, potassium palmitoyl hydrolyzed sweet almond protein, potassium palmitoyl hydrolyzed wheat protein, palm kernel oleic acid Potassium, Potassium arachidate, Potassium rapeseed oleate, Potassium ricinoleate, Potassium safflower oleate, Potassium soybean oleate, Potassium stearate, Potassium stearoyl hydrolyzed collagen, Potassium tallowate, Potassium taurine, Potassium taurine laurate, Potassium trideceth-3 carboxylate, Potassium trideceth-4 carboxylate, Potassium trideceth-7 carboxylate, Potassium trideceth-15 carboxylate, Potassium trideceth-19 carboxylate, Potassium trideceth-6 phosphate, Potassium trideceth-7 phosphate, Potassium camellia oleate, Potassium undecylenate, Potassium undecylenyl hydrolyzed collagen, Potassium undecylenyl hydrolyzed rice protein, PPG-30-buteth-30, PPG-36-buteth-36, PPG-38-buteth-37, PPG-30-octanol polyether-4 phosphate,PPG-10 cetyl ether phosphate, PPG-2C9-11 alcohol polyether-8, PPG-1-decyl polyether-5, PPG-3-decyl polyether-2 carboxylic acid, PPG-30-ethylhexyl alcohol polyether-4 phosphate, PPG-20-glyceryl polyether-30, PPG-2 hydroxyethyl coconut oil / isostearamide, PPG-2-isodecyl alcohol polyether-8, PPG-2-isodecyl alcohol polyether-10, PPG-2-isodecyl alcohol polyether-18, PPG-2-isodecyl alcohol polyether-25, PPG-4-isodecyl alcohol polyether-10, propyltrimonium hydrolyzed collagen, quaternium-24, quaternium-52, quaternium-87, rapeseed oleic acid, rice bran acid, rice oil glyceryl polyether-8 esters, ricinoleic acid amidopropyl betaine, ricinoleic acid, ricinoleic acid polyether-40, safflower oleic acid, Sapindus Oahuensis fruit extract, Saponaria officinalis fruit extract Officinalis) root powder, saponins, potassium soap, sodium / potassium soap, soap base, potassium soap base, sesame oil glyceryl polyether-8 esters, sesame oil amidopropylamine oxide, sesame amidopropyl betaine, shea butter amidopropyl betaine, shea butter glyceryl polyether-8 esters, sodium arachidate, sodium arganoate, sodium arganoamphoacetate, sodium mururu palm oleate, sodium avocado oleate, sodium babassu oleoylamphoacetate, sodium babassu oleate, sodium babassu sulfate, sodium behenate, Sodium diethylene glycol ricinoleyl sulfosuccinate, sodium bis(hydroxyethyl)glycinate cocoyl glucoside cross-polymer, sodium bis(hydroxyethyl)glycinate lauryl glucoside cross-polymer, sodium borage oleamidopropyl PG-dimonium chloride phosphate, sodium butylphenol polyether-12 sulfate, sodium butyl glucoside hydroxypropyl phosphate, sodium C13-17 alkane sulfonate, sodium C14-18 alkane sulfonate, sodium C12-15 alkoxypropyl iminodipropionate, sodium C10-16 alcohol sulfate, sodium C11-15 alkyl sulfate, sodium C12 Sodium C-13 alkyl sulfate, sodium C12-15 alkyl sulfate, sodium C12-18 alkyl sulfate, sodium C16-20 alkyl sulfate, sodium C9-22 secondary alkyl sulfonate, sodium C14-17 secondary alkyl sulfonate, sodium caprate, sodium caprylate, sodium capryloylamphoacetate, sodium capryloylamphohydroxypropyl sulfonate, sodium capryloylamphopropionate, sodium capryloylmethyl taurate, sodium caprylate, sodium capryleth-2 carboxylate, sodium capryleth-9 carboxylate, sodium capryloylamphoacetate, sodium capryloylamphohydroxypropyl sulfonate, sodium capryloylamphopropionate, capryloylglutamate Disodium iodide, Sodium capryloyl hydrolyzed wheat protein, Sodium capryl PG-sulfonate, Sodium capryl sulfonate, Sodium ricinoleate, Sodium ceteareth-13 carboxylate, Sodium cetearyl sulfate, Sodium ceteth-13 carboxylate, Sodium cetyl sulfate, Sodium cocamidopropyl PG-dimonium chloride phosphate, Sodium cocoyl aminopropionate, Sodium cocoether sulfate, Sodium cocoether-30 sulfate, Sodium cocoamphoacetate, Sodium cocoa butter esters, Sodium cocoamphoacetate, Sodium cocoamphohydroxypropyl sulfonate,Sodium Cocoamphopropionate, Sodium Coconut Oil Acid, Sodium Cocoyl / Babassu / Andyraba Sulfate, Sodium Cocoyl / Babassu Sulfate, Sodium Cocoyl Glucoside Hydroxypropyl Phosphate, Sodium Cocoyl Glucoside Hydroxypropyl Sulfonate, Sodium Coco-Glucoside Tartrate, Sodium Cocoyl Glyceryl Ether Sulfonate, Sodium Cocoyl / Hydrogenated Tallow Alcohol Sulfate, Sodium Cocoiminodiacetate, Sodium Coco Monoglyceride Sulfate, Sodium Cocoyl Monoglyceride Sulfonate, Sodium Cocoyl PG-Dimethylammonium Chloride Phosphate, Sodium Cocoyl Sulfate, Sodium Cocoyl Sulfoacetate, Sodium Cocoyl Aminopropionate, Sodium Cocoyl Amino Acids, Sodium Cocoyl Collagen Amino Acids, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutamate, Sodium Cocoyl Glycinate, Sodium Cocoyl / Hydrogenated Tallow Glutamate , Sodium Cocoyl Hydrolyzed Collagen, Sodium Cocoyl Hydrolyzed Keratin, Sodium Cocoyl Hydrolyzed Rice Protein, Sodium Cocoyl Hydrolyzed Silk, Sodium Cocoyl Hydrolyzed Soy Protein, Sodium Cocoyl Hydrolyzed Sweet Almond Protein, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Isethionate, Sodium Cocoyl Methylaminopropionate, Sodium Cocoyl Oat Amino Acids, Sodium Cocoyl / Palmitoyl / Sunfloweroyl Glutamate, Sodium Cocoyl Proline, Sodium Cocoyl Sarcosinate, Sodium Cocoyl Taurine, Sodium Cocoyl Threonine, Sodium Cocoyl Wheat Amino Acids, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium Corn Amphoteric Propionate , Sodium cottonseed oil acyl amphoacetate, Sodium C13-15 pareth-8 butanol phosphate, Sodium C9-11 pareth-6 carboxylate, Sodium C11-15 pareth-7 carboxylate, Sodium C12-13 pareth-5 carboxylate, Sodium C12-13 pareth-8 carboxylate, Sodium C12-13 pareth-12 carboxylate, Sodium C12-15 pareth-6 carboxylate, Sodium C12-15 pareth-7 carboxylate, Sodium C12-15 pareth-8 carboxylate, Sodium C14-15 pareth-8 carboxylate, Sodium C12-14 secondary pareth-8 carboxylate, Sodium C14-15 pareth-PG sulfonate, Sodium C12-13 pareth-2 phosphate, Sodium C13-15 pareth-8 phosphate, C9-15 Sodium C10-15 polyether sulfate, sodium C10-16 polyether-2 sulfate, sodium C12-13 polyether sulfate, sodium C12-15 polyether sulfate, sodium C12-15 polyether sulfate, sodium C12-15 polyether-3 sulfate, sodium C13-15 polyether-3 sulfate, sodium C12-14 secondary polyether-3 sulfate, sodium C12-15 polyether-3 sulfonate, sodium C12-15 polyether-7 sulfonate, sodium C12-15 polyether-15 sulfonate, sodium deceth-2 carboxylate, sodium deceth sulfate, sodium decylbenzene sulfonate, sodium decyl glucoside hydroxypropyl phosphate, sodium decyl glucoside hydroxypropyl sulfonate, sodium di(laureth-7) citrate, sodium di(laureth-10) phosphate,Sodium dilinoleamidopropyl PG-dimonium chloride phosphate, sodium dimer dimer linoleate, sodium dioleth-8 phosphate, sodium dodecylbenzene sulfonate, sodium 2-ethyl sulfolaurate, sodium glyceryl oleate phosphate, sodium grapeseed oleamidopropyl PG-dimonium chloride phosphate, sodium grapeseed oleoylamphoacetate, sodium grapeseed oleoyl acid, sodium hexyl alcohol polyether-4 carboxylate, sodium hydrogenated coconut oil, sodium hydrogenated coconut oil methyl isethionate, sodium hydrogenated palm oleate, sodium hydrogenated tallow acid, sodium hydrogenated tallow glutamate, sodium hydroxylauryldimonium ethyl phosphate, sodium palm kernel hydroxypropyl sulfonate, sodium hydroxypropyl decyl glucoside crosspolymer, sodium hydroxypropyl lauryl glucoside crosspolymer, sulfonic acid Sodium Hydroxypropyl Cocoyl Glucoside Crosspolymer, Sodium Hydroxypropyl Decyl Glucoside Sulfonate Crosspolymer, Sodium Hydroxypropyl Lauryl Glucoside Sulfonate Crosspolymer, Sodium Hydroxystearate, Sodium Isostearate, Sodium Isosteareth-6 Carboxylate, Sodium Isosteareth-11 Carboxylate, Sodium Isostearylamphoacetate, Sodium Isostearylamphopropionate, Sodium N-Isostearyl Methyl Taurate, Sodium Lanolin Sulfate, Sodium Lanolin Acid, Sodium Lardate, Sodium Lauramidodiacetate, Sodium Lauryl Aminopropionate, Sodium Laurate, Sodium Laureth-3 Carboxylate, Sodium Laureth-4 Carboxylate, Sodium Laureth-5 Carboxylate, Sodium Laureth-6 Carboxylate, Sodium Laureth-8 Carboxylate, Sodium Laureth-11 Carboxylate, Sodium Laureth-12 Carboxylate , Sodium Laureth-13 Carboxylate, Sodium Laureth-14 Carboxylate, Sodium Laureth-16 Carboxylate, Sodium Laureth-17 Carboxylate, Sodium Laureth Sulfate, Sodium Laureth-5 Sulfate, Sodium Laureth-7 Sulfate, Sodium Laureth-8 Sulfate, Sodium Laureth-12 Sulfate, Sodium Laureth-40 Sulfate, Sodium Laureth-7 Tartrate, Disodium Lauriminodipropionate, Sodium Lauroamphoacetate, Sodium Lauroamphohydroxypropylsulfonate, Sodium Lauroampho PG-acetate Phosphate, Sodium Lauroamphopropionate, Sodium Lauroyl Aspartate, Sodium Lauroyl Collagen Amino Acids, Sodium Lauroyl Glycine Propionate, Sodium Lauroyl Hydrolyzed Collagen, Sodium Lauroyl Hydrolyzed Silk, Lauroyl Hydroxypropyl Sodium Lauroyl Isethionate, Sodium Lauroyl Methylaminopropionate, Sodium Lauroyl Methyl Isethionate, Sodium Lauroyl Millet Amino Acids, Sodium Lauroyl / Myristoyl Aspartate, Sodium Lauroyl Oat Amino Acids, Sodium Lauroyl Sarcosinate, Sodium Lauroyl Silk Amino Acids, Sodium Lauroyl Taurate, Sodium Lauroyl Wheat Amino Acids, Sodium Lauryl Di (Ethylenediamino) Glycine, Sodium Lauryl Glucose Carboxylate, Sodium Lauryl Glucoside Hydroxypropyl Phosphate, Sodium Lauryl Glucoside Hydroxypropyl Sulfonate, Sodium Lauryl Glycol Carboxylate, Sodium Lauryl Glycol Sulfate, Disodium Lauryl Phosphate, Sodium Lauryl Sulfate, Sodium Lauryl Sulfoacetate, Sodium Linoleate, Sodium Macadamia Seed Oil Acid, Sodium Mango Amphoacetate, Sodium Mango Seed Oil Esters,Sodium Laureth-2 Sulfosuccinate / MEA, Sodium Methoxy PPG-2 Acetate, Sodium Methyl Cocoyl Taurate, Sodium Methyl Lauroyl Taurate, Sodium Methyl Myristoyl Taurate, Sodium Methyl Oleoyl Taurate, Sodium Methyl Palmitoyl Taurate, Sodium Methyl Stearoyl Taurate, Sodium Methyl 2-Sulfolaurate, Sodium Methyl 2-Sulfopalmitate, Sodium Isopalmitoyl Methyl Taurate, Sodium Methyl Cocoyl Methyl Taurate, Sodium Myristeth Sulfate, Sodium Myristate, Sodium Myristoyl Amphoacetate, Sodium Myristoyl Glutamate, Myristoyl Water Sodium decollagen, Sodium myristoyl isethionate, Sodium myristoyl sarcosinate, Sodium myristyl sulfate, Sodium nonoxynol 6 phosphate, Sodium nonoxynol 9 phosphate, Sodium nonoxynol 1 sulfate, Sodium nonoxynol 3 sulfate, Sodium nonoxynol 4 sulfate, Sodium nonoxynol 6 sulfate, Sodium nonoxynol 8 sulfate, Sodium nonoxynol 10 sulfate, Sodium nonoxynol 25 sulfate, Sodium octylphenol 2 ethanesulfonate, Sodium octylphenol 2 sulfate, Sodium octylphenol 6 sulfate, Sodium octylphenol 9 sulfate Sodium ester, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropyl sulfonate, sodium oleoamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl isethionate, sodium oleyl polyether sulfate, sodium oleoyl methyl isethionate, sodium oleyl sulfate, sodium oliveoamphoacetate, sodium olive oil, sodium oliveoyl glutamate, sodium palmitoleoamphoacetate, sodium palmitoleate, sodium palmitoleyl glyceride sulfonate, sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat protein, sodium palmitoyl sarcosine, sodium palm kerneloleate, sodium palmitoleoyl isethionate, palm Sodium Oleoyl Glutamate, Sodium Passionflower Seed Oil, Sodium Peanut Amphoacetate, Sodium Peanut Acid, Sodium PEG-6 Cocoamide Carboxylate, Sodium PEG-8 Cocoamide Carboxylate, Sodium PEG-4 Cocoamide Sulfate, Sodium PEG-3 Lauramide Carboxylate, Sodium PEG-4 Lauramide Carboxylate, Sodium PEG-8 Palm Glycerides Carboxylate, Sodium Pentaerythrityl Hydroxypropyliminodiacetate Dendrimer, Sodium Propoxy PPG-2 Acetate, Sodium Rapeseed Oil, Sodium Rice Bran Amphoacetate, Sodium Ricinoleate, Sodium Ricinole Amphoacetate, Sodium Rose Hipsamphoacetate, Sodium Rosinate, Sodium Safflower Oleate, Sodium Saffloweroyl Hydrolyzed Soy Protein, Sodium Sesame Seed Oleate, Sodium Sesame Amphoacetate, Sodium Shea Butter Amphoacetate, Sodium Soy Oleate, Sodium Soy Hydrolyzed Collagen, Sodium Stearate, Sodium Stearoyl Amphoacetate, Sodium Stearoyl Amphopropyl Sulfonate, Sodium Stearoyl Amphopropionate, Sodium Stearoyl Casein, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl Hydrolyzed Silk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Whey Protein, Sodium Stearoyl Methyl Isethionate, Sodium Stearoyl Oat Protein,Sodium stearoyl pea protein, sodium stearoyl soy protein, sodium stearyl dimethyl glycinate, sodium stearyl sulfate, sodium sunflower seed oil acyl amphoacetate, sodium subtilisin, sodium sweet almond oil acyl amphoacetate, sodium sweet almond oil acid, sodium tallow acyl propionate, sodium tallow acid, sodium tallow acyl acetate, sodium tallow acid, sodium tallow alcohol sulfate, sodium callophyllum (CALLOPHYLLUMINOPHYLLUM) seed oil acid, sodium taurine, sodium cocoyl methyl taurate taurate, laurel Sodium taurate, sodium lauroyl collagen amino acid / TEA salt, sodium lauroyl hydrolyzed collagen / TEA salt, sodium lauroyl hydrolyzed keratin / TEA salt, sodium lauroyl keratin amino acid / TEA salt, sodium undecylenyl collagen amino acid / TEA salt, sodium undecylenyl hydrolyzed collagen / TEA salt, sodium undecylenyl hydrolyzed corn protein / TEA salt, sodium undecylenyl hydrolyzed soy protein / TEA salt, sodium undecylenyl hydrolyzed wheat protein / TEA salt, Theobroma grandiflora Grandiflorum) seed oil sodium, sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium trideceth sulfate, sodium tridecylbenzene sulfonate, sodium tridecyl sulfate, sodium trimethylolpropane hydroxypropyl iminodiacetic acid dendrimer Compounds, sodium undecylene-5 carboxylate, sodium undecylenate, sodium undecylenylamphoacetate, sodium undecylenylamphopropionate, disodium undecylenyl glutamate, sodium wheat germ oleylamphoacetate, sorbitan polyether-160 tristearate, soybean oleic acid, soybean amidopropylamine oxide, soybean amidopropyl betaine, soybean glyceryl polyether-8 esters, stearamidopropylamine oxide, stearamidopropyl betaine, stearamine oxide, steareth-15, stearyl alcohol polyether Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyltrimonium Chloride, Stearoyl Glutamic Acid, Stearoyl Sarcosine, Stearyl Betaine, Stearyl Dimethyl Butyl Glucoside Hydroxypropyl Ammonium Chloride, Stearic Acid, Lipoic acid dimethyl decyl glucoside hydroxypropyl ammonium chloride, stearyl dimethyl lauryl glucoside hydroxypropyl ammonium chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower oleamide MEA, sunflower oil acid, sunflower oil amidopropyl hydroxyethyl dimonium chloride, sunflower oil glyceryl polyether-8 esters, tallow acid, tallow acid, tallow amidopropylamine oxide, tallow amidopropyl betaine, tallow amidopropyl hydroxysulfonate,Tallowamine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallow ethyl glucoside, abietic hydrolyzed collagen TEA salt, C12-14 alcohol phosphate TEA salt, C10-15 alkyl sulfate TEA salt, C11-15 alcohol sulfate TEA salt, C12-13 alkyl sulfate TEA salt, TEA-C12-14 alkyl sulfate TEA salt, TEA-C12-15 alkyl sulfate TEA salt, TEA C14-17 secondary alkyl sulfonate TEA salt, canola oil TEA salt, cocamide diacetate TEA salt, coconut oil acid TEA salt, coconut oil alcohol sulfate TEA salt, cocoyl alanine TEA salt, cocoyl glutamate TEA salt, cocoyl glutamine TEA salt, cocoyl glycine TEA salt, cocoyl hydrolyzed collagen TEA salt, cocoyl hydrolyzed soy protein TEA salt, cocoyl sarcosine TEA salt, polydimethylsiloxane PEG-7 phosphate TEA salt, dodecylbenzene sulfonate TEA salt, hydrogenated coconut acid TEA salt, hydrogenated tallow glutamate TEA salt, isostearic acid TEA salt, TEA-Isostearyl Hydrolyzed Collagen TEA Salt, Lauryl Amine Propionic Acid TEA Salt, Lauric Acid TEA Salt, Lauric Acid / Myristic Acid TEA Salt, Laureth Sulfate TEA Salt, Lauroyl Collagen Amino Acid TEA Salt, Lauroyl Glutamate TEA Salt, Lauroyl Hydrolyzed Collagen TEA Salt, Lauroyl Keratin Amino Acid TEA Salt, Lauroyl Methylaminopropionic Acid TEA Salt, Lauroyl / Myristoyl Aspartic Acid TEA Salt, Lauroyl Sarcosine TEA Salt, Lauryl Phosphate TEA Salt, Lauryl Sulfate TEA Salt, Myristyl Amine Propionic Acid TEA Salt, Myristyl Acid TEA Salt, Myristoyl Hydrolyzed Collagen TEA salt, TEA oleate, TEA oleoyl hydrolyzed collagen, TEA oleoyl sarcosine, TEA oleyl sulfate, TEA palmitate, TEA palm kernel sarcosine, TEA PEG-3 cocamide sulfate, TEA rosinate, TEA stearate, TEA tallate, TEA tridecylbenzenesulfonate, TEA undecylenate, TEA undecylenate hydrolyzed collagen, tetramethyldecynediol, tetrasodium dicarboxyethyl stearyl sulfosuccinamate, TIPA laureth sulfate, TIPA lauryl sulfate, TIPA myristic acid, TIPA stearate, Tocopheryl phosphate, trehalose undecylenate, TM-C12-15 pareth-2 phosphate, TM-C12-15 pareth-6 phosphate, TM-C12-15 pareth-8 phosphate, TM-C12-15 pareth-10 phosphate, trideceth-20, trideceth-50, trideceth-3 carboxylic acid, trideceth-4 carboxylic acid, trideceth-7 carboxylic acid, trideceth-8 carboxylic acid, trideceth-15 carboxylic acid, trideceth-19 carboxylic acid, trideceth-10 phosphate, tridecylbenzenesulfonic acid, trilaureth-9 citrate,Trimethylolpropane Hydroxypropyl Bis(hydroxyethyl)amine Dendrimer, Sodium Tri(lauroampho PG-acetate chloride) Phosphate, Undecanoic Acid, Undeceth-5 Carboxylic Acid, Undecylenamidopropylamine Oxide, Undecylenamidopropyl Betaine, Undecylenic Acid, Undecylenyl Collagen Amino Acids, Undecylenyl Glycine, Undecylenyl Hydrolyzed Collagen, Undecylenyl Wheat Amino Acids, Undecyl Glucoside, Wheat Germ Oleic Acid, Wheat Germ Oleic Acid, Wheat Germ Oleic Acid, Wheat Germ Oleic Acid, Wheat Germ Oleic Acid, Yucca Schidigera Leaf / Root / Stem Extract, Yucca Schidigera Stem Extract, Zinc Cocoeth Sulfate and Zinc Cocoyl Sulfate.

[0017] Preferred are one or more compounds selected from the group consisting of sodium laureth sulfate, cocamidopropyl betaine, sodium cocoamphoacetate, coco-glucoside and ammonium lauryl sulfosuccinate.

[0018] The percentage content of the surfactant in the preparation may be 0.1 to 10% by weight, and preferably 0.5 to 5% by weight, based on the preparation. Oil body

[0019] Suitable oil bodies, which are a component of O / W emulsions, are based, for example, on Guerbet alcohols containing 6 to 18, preferably 8 to 10, carbon atoms, linear C6-C 22 -Fatty acids with straight or branched C6-C 22 -Ester of aliphatic alcohol or branched C6-C 13 -Carboxylic acid with straight or branched C6-C 22- esters of fatty alcohols, such as, for example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, stearyl Isostearyl, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate. Also suitable are straight-chain C6-C 22 - Esters of fatty acids with branched alcohols, especially 2-ethylhexanol, C 18 -C 38 -alkyl hydroxycarboxylic acid with a straight or branched C6-C 22 - esters of fatty alcohols, in particular dioctyl malate, esters of linear and / or branched fatty acids with polyols (such as, for example, propylene glycol, dimerdiol or trimertriol) and / or Guerbet alcohols, 10 -Triglycerides of fatty acids, based on C6-C 18 -Liquid mono- / di- / triglyceride mixture of fatty acids, C6-C 22 - esters of aliphatic alcohols and / or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, C2-C 12 - esters of dicarboxylic acids with straight-chain or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, straight-chain and branched C6-C 22 - Carbonates of fatty alcohols, such as, for example, dicaprylyl carbonate ( C-C), Guerbet carbonates based on aliphatic alcohols having 6 to 18, preferably 8 to 10, carbon atoms, benzoic acid and linear and / or branched C6-C 22 -Ester of alcohol (e.g. TN), linear or branched, symmetrical or asymmetrical dialkyl ethers in which each alkyl radical has 6 to 22 carbon atoms, such as, for example, dicaprylyl ether ( OE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclopolydimethylsiloxane, silicone methicone grades, etc.) and / or aliphatic or cycloalkanes, such as, for example, squalane, squalene or dialkylcyclohexanes. Emulsifier

[0020] Other nonionic or cationic surfactants may also be added to the formulation as emulsifiers, including for example: · 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear C 8-22 Aliphatic alcohols, and C 12-22 Addition products of fatty acids and alkylphenols having 8 to 15 carbon atoms in the alkyl group; · C of addition products of 1 to 30 mol of ethylene oxide onto glycerol 12 / 18 Fatty acid monoesters and diesters; glycerol monoesters and diesters and sorbitan monoesters and diesters of saturated and unsaturated fatty acids containing 6 to 22 carbon atoms and their ethylene oxide addition products; Addition products of 15 to 60 mol of ethylene oxide onto castor oil and / or hydrogenated castor oil; Polyol esters, in particular polyglycerol esters such as polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimer oil isostearate. Also suitable are mixtures of a plurality of such compounds; Addition products of 2 to 15 mol of ethylene oxide onto castor oil and / or hydrogenated castor oil; Based on straight chain, branched, unsaturated or saturated C 6 / 22 Partial esters of fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (such as sorbitol), alkyl glucosides (such as methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (such as cellulose); Mono-, di- and tri-alkyl phosphates and mono-, di- and / or tri-PEG alkyl phosphates and their salts; Wool wax alcohols; Polysiloxane / polyalkyl polyether copolymers and corresponding derivatives; Pentaerythritol, fatty acids, citric acid and aliphatic alcohols and / or C 6-22 A mixed fat of fatty acids, methyl glucose and a polyol, preferably glycerol or polyglycerol; Polyglycols and Glyceryl carbonate.

[0021] The addition products of ethylene oxide and / or propylene oxide with aliphatic alcohols, fatty acids and alkylphenols, mono- and diesters of glycerol and sorbitan mono- and diesters of fatty acids or castor oil are commercially available products. They are homologous mixtures whose average degree of alkoxylation corresponds to the ratio of the amount of ethylene oxide and / or propylene oxide and substrate used for the addition reaction. 12 / 18 Fatty acid monoesters and diesters are known for use as superfatting agents for cosmetic preparations. Preferred emulsifiers are listed in detail below:

[0022] Partial glycerides. Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid monoglyceride, malic acid diglyceride and technical mixtures thereof which still contain small amounts of triglycerides originating from the production process. Addition products of 1 to 30 and preferably 5 to 10 mol of ethylene oxide to the abovementioned partial glycerides are also suitable.

[0023] Sorbitan esters. Suitable sorbitan esters are sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diricinoleate, sorbitan triricinoleate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diricinoleate, sorbitan triricinoleate, sorbitan monooleate, sorbitan sesquioleate, sorbitan di ...oleate, sorbitan monooleate, sorbitan Suitable esters include sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimalate and technical mixtures thereof. Also suitable are the addition products of 1 to 30 and preferably 5 to 10 mol of ethylene oxide to the abovementioned sorbitan esters.

[0024] Polyglycerol esters. A typical example of a suitable polyglycerol ester is polyglyceryl-2 dipolyhydroxystearate ( PGPH), polyglyceryl-3-diisostearate ( TGI), polyglyceryl-4 isostearate ( GI 34), Polyglyceryl-3 Oleate, Diisostearyl Polyglyceryl-3 Diisostearate ( PDI), Polyglyceryl-3 Methyl Glucose Distearate (Tego 450), Polyglyceryl-3 Beeswax (Cera )、Polyglyceryl-4 Caprate (Polyglyceryl Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether ( NL), Polyglyceryl-3 Distearate ( GS32) and polyglycerol polyricinoleate ( WOL 1403), polyglyceryl dimerateisostearate and mixtures thereof. Other examples of suitable polyol esters are the monoesters, diesters and triesters of lauric acid, coconut acid, tallow acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like, optionally reacted with 1 to 30 mol of ethylene oxide, and trimethylolpropane or pentaerythritol.

[0025] Tetraalkyl quaternary ammonium salts. Cationic surfactants in aqueous solution contain hydrophobic polymer groups required for surface activity in dissociated cations. An important representative of cationic surfactants is the general formula (R 1 R 2 R 3 R 4 N + )X - A tetraalkyl quaternary ammonium salt. 1 represents C1-C8 alkane (alkenyl), R 2 , R 3 and R 4 , independently represent an alkane (enyl) group containing 1 to 22 carbon atoms. X is a counter ion, preferably selected from halogen, alkyl sulfate and alkyl carbonate. Particularly preferred are cationic surfactants, wherein the nitrogen atom is substituted by two long acyl groups and two short alkane (enyl) groups.

[0026] Esterquats. A group of cationic surfactants which are particularly useful as cosurfactants according to the invention are the so-called esterquats. Esterquats are generally understood to mean quaternized fatty acid triethanolamine ester salts. They are known compounds which can be obtained by relevant processes of preparative organic chemistry. Reference is made in this regard to the international patent application WO 91 / 01295 A1, in which triethanolamine is partially esterified with fatty acids in the presence of hypophosphorous acid, air is passed through the reaction mixture and the whole is subsequently quaternized with dimethyl sulfate or ethylene oxide. In addition, German patent DE 4308794 C1 describes a process for preparing solid esterquats, in which the quaternization of the triethanolamine ester is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0027] A typical example of an esterquat suitable for use according to the invention is a product whose acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, wherein RCO is an acyl group containing 6 to 10 carbon atoms, and the amino component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof, such as, for example, so-called head fractionated fatty acids. Preferably used esterquats whose acyl component is derived from a monocarboxylic acid containing 8 to 10 carbon atoms. Other esterquats are those whose acyl component is derived from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. In general, it is preferred to use esterquats whose acyl component is derived from a mixture of monocarboxylic acids containing 6 to 22 carbon atoms and adipic acid. The molar ratio of monocarboxylic acid to dicarboxylic acid in the final esterquat is 1:99 to 99:1, and preferably 50:50 to 90:10 and more particularly 70:30 to 80:20. In addition to quaternized fatty acid triethanolamine ester salts, other suitable esterquats are quaternized ester salts of mono / dicarboxylic acid mixtures with diethanolalkylamine or 1,2-dihydroxypropyldialkylamine. Esterquats can be obtained from fatty acids and from the corresponding triglycerides mixed with the corresponding dicarboxylic acids. One such process, which is representative of the relevant prior art, is proposed by European patent EP 0750606B1. For the preparation of quaternized esters, mixtures of mono- and dicarboxylic acids with triethanolamine in a molar ratio of 1.1:1 to 3:1 can be used - based on the available carboxyl functions. Considering the properties of the esterquats, ratios of 1.2:1 to 2.2:1 and in particular 1.5:1 to 1.9:1 have proven to be particularly advantageous. Preferred esterquats are technical mixtures of mono-, di- and triesters having an average degree of esterification of 1.5 to 1.9. Superfatting agents and consistency factors

[0028] Superfatting agents may be selected from substances such as, for example, lanolin and lecithin and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, the latter also serving as foam stabilizers.

[0029] The main consistency factors used are fatty alcohols or hydroxyaliphatic alcohols and partial glycerides, fatty acids or hydroxyfatty acids having 12 to 22 and preferably 16 to 18 carbon atoms. Preference is given to using combinations of these substances with alkyl oligoglucosides and / or fatty acid N-methylglucamides of the same chain length and / or polyglycerol poly-12-hydroxystearate. Thickeners and rheology additives

[0030] Suitable thickeners are polymeric thickeners, such as polysaccharides, more particularly xanthan gum, guar gum, agar, alginates and tyloses, carboxymethylcellulose and hydroxyethylcellulose, and relatively high molecular weight polyethylene glycol monoesters and diesters of fatty acids, polyacrylates (e.g. [Goodrich] or [Sigma]), polyacrylamide, polyvinyl alcohol and polyvinyl pyrrolidone, surfactants such as, for example, ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, narrow homolog distribution fatty alcohol ethoxylates and electrolytes such as sodium chloride and ammonium chloride. polymer

[0031] Suitable cationic polymers are, for example, cationic cellulose derivatives, such as are available from Amerchol as Polymer JR Quaternized hydroxyethylcellulose obtained under the name of quaternized hydroxyethylcellulose, cationic starch, copolymers of diallyl ammonium salt and acrylamide, quaternized vinyl pyrrolidone / vinylimidazole polymers, for example (BASF), condensates of polyethylene glycol and amines, quaternized collagen peptides, such as lauryl diammonium hydroxypropyl hydrolyzed collagen ( L, Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers such as aminodimethicone, copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetriamine ( Sandoz), copolymer of acrylic acid and dimethyldiallylammonium chloride ( 550, Chemviron), polyaminopolyamides and crosslinked water-soluble polymers thereof, cationic chitin derivatives, such as quaternized chitosan, optionally in microcrystalline distribution, condensation products of dihaloalkanes, such as dibromobutane, and bisdialkylamines, such as bisdimethylamino-1,3-propane, cationic guar gums, such as Celanese CBS, C-17, C-16, quaternary ammonium polymers, such as Miranol A-15, AD-1, AZ-1, and can be marketed under the trade name CC or Various polyquaternium types found in 300 (e.g. 6, 7, 32 or 37).

[0032] Suitable anionic, zwitterionic, amphoteric and nonionic polymers are, for example, vinyl acetate / crotonic acid copolymers, vinyl pyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and their esters, uncrosslinked and polyol-crosslinked polyacrylic acids, acrylamidopropyltrimethylammonium chloride / acrylate copolymers, octylacrylamide / methyl methacrylate / tert-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / dimethylaminoethyl methacrylate / vinylcaprolactam terpolymers and optionally derivatized cellulose ethers and silicones. Pearlescent wax

[0033] Suitable pearlescent waxes are, for example, alkanediol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially coconut fatty acid diethanolamide; partial glycerides, especially stearic acid monoglyceride; esters of polybasic, optionally hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; fatty substances having a total of at least 24 carbon atoms, such as, for example, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, especially laurone and distearyl ether; fatty acids such as stearic acid, hydroxystearic acid or behenic acid, ring-opening products of epoxides having 12 to 22 carbon atoms with fatty alcohols having 12 to 22 carbon atoms and / or polyols having 2 to 15 carbon atoms and 2 to 10 hydroxyl groups, and mixtures thereof. Silicone

[0034] Suitable silicones are selected from the group consisting of: theophylline methylsilanol mannuronate, acetylmethionylmethylsilanol elastin esters, acrylates / behenyl acrylate, acrylates / dimethicone methacrylate copolymer, acrylates / behenyl methacrylate / dimethicone methacrylate copolymer, acrylates / bishydroxypropyl dimethicone crosspolymer, acrylates / dimethicone copolymer, acrylates / dimethicone methacrylate / ethylhexyl acrylate copolymer, acrylates / dimethicone alcohol acrylate copolymer, acrylates / ethylhexyl acrylate / dimethicone methacrylate Acid copolymer, acrylates / octylacrylamide / diphenyl amino-terminated polydimethylsiloxane copolymer, acrylates / polytrimethylsiloxane methacrylate copolymer, acrylates / propyl polytrimethylsiloxane methacrylate copolymer, acrylates / stearyl alcohol acrylate / polydimethylsiloxane methacrylate copolymer, acrylates / tridecyl acrylate / triethoxysilylpropanol methacrylate / polydimethylsiloxane methacrylate copolymer, acrylates / trifluoropropyl methacrylate / polytrimethylsiloxane methacrylate copolymer, aminobispropyl polydimethylsiloxane, aminoethylaminopropyl polydimethylsiloxane, aminopropyl polydimethylsiloxane, amino Propyl phenyl trimethicone, aminopropyl triethoxysilane, dimethicone PEG-7 ammonium sulfate, amodimethicone, amodimethicone hydroxystearate, amodimethicone / silsesquioxane copolymer, ascorbyl carboxydecyl trisiloxane, ascorbyl methylsilanol pectate, behenoxy dimethicone, behentrimonium dimethicone PEG-8 phthalate, behenyl dimethicone, bisamino PEG / PPG-41 / 3 aminoethyl PG-propyl dimethicone, bis-aminopropyl / ethoxyaminopropyl dimethicone, bis(butyl benzoate) diaminotriazine aminopropyl trisiloxane, bis-butyl dimethicone polyglyceryl- 3. Bis-butoxy amino dimethicone / PEG-60 copolymer, bis (C13-15 alkoxy) hydroxybutyramide amino dimethicone, bis (C13-15 alkoxy) PG-amino dimethicone, bis (C1-8 alkyl lauroyl lysine decyl carboxamide) dimethicone, bis-cetyl cetyl dimethicone, bis-cetyl / PEG-8 cetyl PEG-8 dimethicone, bis-diphenylethyl dimethicone, bis-ethylethyl dimethicone, bis-glucamideethyl-aminopropyl dimethicone, bis-hydrogen dimethicone, bis-hydroxyethoxypropyl dimethicone bis-hydroxylauryl, dimethicone / IPDI copolymer,Bis-Hydroxy / Methoxy Amodimethicone, Bis-Hydroxypropyl Dimethicone Behenate, Bis-Hydroxypropyl Dimethicone / SMDI Copolymer, Bis-Isobutyl PEG-14 / Amodimethicone Copolymer, Bis-Isobutyl PEG-15 / Amodimethicone Copolymer, Bis-Isobutyl PEG / PPG-20 / 35 / Amodimethicone Copolymer, Bis-Isobutyl PEG / PPG-10 / 7 / Dimethicone Copolymer, Bis-Isobutyl PEG-24 / PPG-7 / Dimethicone Copolymer, Bis-PEG-1 Dimethicone, Bis-PEG-4 Dimethicone, Bis-PEG-8 Dimethicone, Bis-PEG -12 Polydimethylsiloxane, Bis-PEG-20 Polydimethylsiloxane, Bis-PEG-12 Polydimethylsiloxane Beeswax Acid, Bis-PEG-12 Polydimethylsiloxane Candelilla Cetearate, Bis-PEG-15 Polydimethylsiloxane / IPDI Copolymer, Bis-PEG-15 Methyl Ether Polydimethylsiloxane, Bis-PEG-18 Methyl Ether Dimethyl Silane, Bis-PEG / PPG-14 / 14 Polydimethylsiloxane, Bis-PEG / PPG-15 / 5 Polydimethylsiloxane, Bis-PEG / PPG-18 / 6 Polydimethylsiloxane, Bis-PEG / PPG-20 / 20 Polydimethylsiloxane, Bis-PEG / PPG-16 / 16 PEG / PPG-16 / 16 Polydimethylsiloxane Dimethicone, Bis-PEG / PPG-20 / 5PEG / PPG-20 / 5 Dimethicone, Bis-phenylhexamethicone, Bis-phenylpropyl dimethicone, Bis-polyethylene dimethicone, Bis-(polyglyceryl-3 oxyphenylpropyl) dimethicone, Bis-(polyglyceryl-7 oxyphenylpropyl) dimethicone, Bis-PPG-15 dimethicone / IPDI copolymer, Bis-(PPG-7 undecenyl alcohol polyether-21) dimethicone, Bis-stearyl dimethicone, Bis-trimethoxysilylethyl tetramethyl disiloxyethyl dimethicone, Bis-vinyl dimethicone, Bis-vinyl dimethicone / dimethicone copolymer, Borago seed oil PEG -7 polydimethylsiloxane esters, butyl acrylate / C6-14 perfluoroalkyl alcohol acrylate / mercaptopropyl polydimethylsiloxane copolymer, butyl acrylate / hydroxypropyl polydimethylsiloxane acrylate copolymer, butyl polydimethylsiloxane acrylate / cyclohexyl methacrylate / ethylhexyl acrylate copolymer, butyl polydimethylsiloxane methacrylate / methyl methacrylate crosspolymer, tert-butyldimethylsilane grape seed extract, butyl polydimethylsiloxane ethylene / propylene / ethylene norbornene copolymer, C6-8 alkyl C3-6 alkyl glucoside polydimethylsiloxane, C20-24 alkyl polydimethylsiloxane, C24-28 alkyl polydimethylsiloxane, C26-28 alkyl polydimethylsiloxane,C30-45 Alkyl Dimethicone, C30-60 Alkyl Dimethicone, C32 Alkyl Dimethicone, C30-45 Alkyl Dimethicone / Polycyclohexene Oxide Crosspolymer, C26-28 Alkyl Dimethyl Silane Polypropyl Silsesquioxane, C30-45 Alkyl Dimethyl Silane Polypropyl Silsesquioxane, C20-24 Alkyl Methicone, C24-28 Alkyl Methicone, C26-28 Alkyl Methicone, C30-45 Alkyl Methicone, C20-28 Alkyl Fluordecyl Ethoxy Dimethicone, C26-54 Alkyl Tetradecyl Dimethicone, Caprylyl Dimethicone, Caprylyl Dimethicone Ethoxy Glucoside, Caprylyl Methicone, Caprylyl Trimethicone, Carboxydecyl Trisiloxane, Castor Oil Bis-Hydroxypropyl Dimethicone Esters, Wax Dimethicone, Cetearyl Dimethicone Crosspolymer, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer, Cetearyl Methicone, Cetrimonium Carboxydecyl PEG-8 Polydimethylsiloxane Dimethicone, Cetyl Dimethicone, Cetyl Dimethicone, Cetyl Dimethicone / Bis-vinyl Dimethicone Crosspolymer, Cetyl Dimethicone, Cetyl Dimethicone, Cetyl PEG-8 Dimethicone, Cetyl PEG / PPG-15 / 15 Butyl Ether Dimethicone, Cetyl PEG / PPG-7 / 3 Dimethicone, Cetyl PEG / PPG-10 / 1 Dimethicone Methylsiloxane, cetyl triethylammonium dimethicone PEG-8 phthalate, cetyl triethylammonium dimethicone PEG-8 succinate, acetyl tyrosine copper methylsilanol, PCA copper methylsilanol, C4-14 perfluoroalkyl ethoxy polydimethylsiloxane, cycloethoxy polymethicone, cycloheptylsiloxane, cyclohexasiloxane, cyclomethicone, cyclopentasiloxane, cyclophenyl polymethicone, cyclotetramethicone, cyclovinyl polymethoxysilane, cystine bis-PG-propyl silanetriol, DEA PG-propyl PEG / PPG-18 / 21 dimethicone, diisostearyl trimethylolpropane siloxysilicate, dilauroyl trimethylolpropane siloxysilicate, dilinoleamidopropyl dimethylamine dimethicone PEG-7 phosphate, dimethicone, dimethicone crosspolymer, dimethicone crosspolymer-3, dimethicone / divinyl dimethicone / silsesquioxane crosspolymer, dimethicone ethoxylated glucoside, dimethicone hydroxypropyltrimonium chloride, dimethicone / mercaptopropyl methicone copolymer, dimethicone PEG-15 acetate,Dimethicone PEG-8 Adipate, Dimethicone PEG-7 Avocado Oleate, Dimethicone PEG-8 Avocado Oleate, Dimethicone PEG-8 Beeswax Oleate, Dimethicone PEG-8 Benzoate, Dimethicone PEG-8 Borage Oleate, Dimethicone PEG-7 Cocoate, Dimethicone / PEG-10 Crosspolymer, Dimethicone PEG-10 / 15 Crosspolymer, Dimethicone / PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG-8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG -8 Lanolin Acid, Dimethicone PEG-8 Laurate, Dimethicone PEG-8 Limnanthes Alba Seed Oil Acid, Dimethicone PEG-7 Octyldodecyl Citrate, Dimethicone PEG-7 Olivate, Dimethicone PEG-8 Olivate, Dimethicone PEG-7 Phosphate, Dimethicone PEG-8 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG-7 Phthalate, Dimethicone PEG-8 Phthalate, Dimethicone PEG-8 Polyacrylate, Dimethicone PEG / PPG-20 / 23 Benzoate, Dimethicone PEG / PPG- 7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone PEG-7 succinate, dimethicone PEG-8 succinate, dimethicone PEG-7 sulfate, dimethicone PEG-7 undecanoate, dimethicone PG-diethylmethylammonium chloride, dimethicone / phenyl vinyl dimethicone crosspolymer, dimethicone / polyglyceryl-3 crosspolymer, dimethicone / PPG-20 crosspolymer, dimethicone propyl ethylenediamine behenate, dimethicone propyl PG-betaine, dimethicone / silsesquioxane copolymer, dimethicone silylate, dimethicone Siloxane / vinyl dimethicone crosspolymer, dimethicone / vinyl trimethylsiloxysilicate crosspolymer, dimethiconol, dimethicone arginine, dimethicone beeswax acid ester, dimethicone behenate, dimethicone boragonate, dimethicone candelilla wax acid ester, dimethicone carnaubamate, dimethicone cysteine, dimethicone drupaate, dimethicone fluoroalcohol dimer linoleic acid polyester, dimethicone hydroxystearate, dimethicone indica hematite resinate, dimethicone / IPDI copolymer, dimethicone isostearate,Dimethicone Candle Butter, Dimethicone Lactate, Dimethicone White Limnanthes Alba Seed Oil, Dimethicone Methionine, Dimethicone / Methylsilanol / Silicate Crosspolymer, Dimethicone Chenopodium Alpinum Lactate, Dimethicone Panthenol, Dimethicone Salicylate, Dimethicone / Silica Crosspolymer, Dimethicone / Silsesquioxane Copolymer, Dimethicone Stearate, Dimethicone / Stearyl Methicone / Phenyl Trimethicone Copolymer, Dimethoxysilyl Ethylene Diaminopropyl Dimethicone, Dimethylaminopropionamide PCA Polydimethylsiloxysilane Methicone, dimethyloxybenzodioxane, dimethylsilanol hyaluronate, dioleyl tocopheryl methylsilanol, diphenyl amodimethicone, diphenyl dimethicone, diphenyl dimethicone crosspolymer, diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane crosspolymer, diphenylethyl benzyloxydimethyldisiloxane, diphenyl isopropyl dimethicone, diphenylsiloxyphenyl / propyl trimethicone, diphenylsiloxyphenyl trimethicone, dimethicone, disodium amodimethicone disuccinimide, disodium PEG-12 polydimethicone sulfosuccinate, PEG -8 lauryl dimethicone sulfosuccinate disodium, divinyl dimethicone / dimethicone copolymer, divinyl dimethicone / dimethicone crosspolymer, drometrizole trisiloxane, ethylhexyl acrylate / VP / dimethicone methacrylate copolymer, ethyl polymethicone, ethyl trisiloxane, fluorinated C2-8 alkyl polydimethicone, glucamidopropyl aminopropyl polydimethicone, 4-(2-β-pyranosyl methylsiloxy) propoxy-2-hydroxybenzophenone, glyceryl undecyl polydimethicone, glycidoxy polydimethicone, polyhexadecyl methicone, hexyl polydimethicone, hexyl polydimethicone Methylsiloxane, Hexyl Trimethoxysilane, Hydrogen Dimethicone, Hydrogen Dimethicone / Capryl Silsesquioxane Copolymer, Hydrolyzed Collagen PG-Propyl Dimethicone, Hydrolyzed Collagen PG-Propyl Methylsilanediol, Hydrolyzed Collagen PG-Propyl Silanetriol, Hydrolyzed Keratin PG-Propyl Methylsilanediol, Hydrolyzed Sesame Protein PG-Propyl Methylsilanediol, Hydrolyzed Silk PG-Propyl Methylsilanediol, Hydrolyzed Silk PG-Propyl Methylsilanediol Crosspolymer, Hydrolyzed Soy Protein / Dimethicone PEG-7 Acetate, Hydrolyzed Soy Protein PG-Propyl Methylsilanediol, Hydrolyzed Vegetable Protein PG-Propyl Silanetriol, Hydrolyzed Wheat (TRITICUM VULGARE) Protein / Cysteine ​​Bis-PG-Propyl Silanetriol Copolymer, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Acetate,Hydrolyzed wheat protein / dimethicone PEG-7 phosphate copolymer, hydrolyzed wheat protein PG-propyl methylsilanediol, hydrolyzed wheat protein PG-propyl silanetriol, hydroxyethyl acetoxymethyl ammonium PG-dimethicone, hydroxypropyl dimethicone, hydroxypropyl dimethicone behenate, hydroxypropyl dimethicone isostearate, hydroxypropyl dimethicone stearate, isobutyl methacrylate / bis-hydroxypropyl dimethicone acrylate copolymer, isobutyl methacrylate / trifluoroethyl methacrylate / bis-hydroxypropyl dimethicone acrylate copolymer, isopentanol trimethoxycinnamate trisiloxane, isopolyglyceryl-3 dimethicone, isopolyglyceryl-3 dimethiconol 、Isopropyl Titanium Triisostearate / Triethoxysilylethyl, Polydimethylsiloxyethyl Dimethicone Crosspolymer, Isostearyl Carboxydecyl PEG-8 Dimethicone, Lactyl Methylsilanol Elastin Esters, Lauryl Dimethicone, Lauryl Dimethicone PEG-15 Crosspolymer, Lauryl Dimethicone PEG-10 Phosphate, Lauryl Dimethicone / Polyglyceryl-3 Crosspolymer, Lauryl Methicone, Lauryl PEG-8 Dimethicone, Lauryl PEG-10 Methyl Ether Dimethicone, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Lauryl PEG / PPG-18 / 18 Methicone, Lauryl Benzene Isopropyl Alcohol, Propyl Methicone, Lauryl Phenyl Propyl Methicone, Lauryl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Lauryl Polyglyceryl-3 Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Lauryl Trimethicone, Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone, Methacryloylpropyl Trimethoxysilane, Methicone, Methoxyamodimethicone / Silsesquioxane Copolymer, Methoxycinnamamidopropyl Polysilsesquioxane, Methoxycinnamylpropyl Silsesquioxane Silicate, Methoxy PEG-13 Ethyl Polysilsesquioxane, Methoxy PEG / PPG-7 / 3 Aminopropyl Dimethicone, Methoxy PEG / PPG-2 5 / 4 Dimethicone, Methoxy PEG-10 Propyl Trimethoxy Silane, Methyl Eugenol PEG-8 Dimethicone, Methyl Polysiloxane Emulsion, Methylsilanol Acetyl Methionine Ester, Methylsilanol Acetyl Tyrosine Ester, Methylsilanol Ascorbate, Methylsilanol Carboxymethyl Theophylline, Methylsilanol Carboxymethyl Theophylline Alginate, Methylsilanol Elastin Ester, Methylsilanol Glycyrrhizate, Methylsilanol Hydroxyproline Ester, Methylsilanol Hydroxyproline Ester Aspartate, Methylsilanol Mannosuronate, Methylsilanol PCA Ester, Methylsilanol PEG-7 Glyceryl Cocoate, Methylsilanol / Silicate Crosspolymer, Methylsilanol Spirulina Protein Ester, Methylsilanol Tri-PEG-8 Glyceryl Cocoate,Methyl trimethicone, methyl trimethoxysilane, myristamidopropyl dimethylamine dimethicone PEG-7 phosphate, myristyl polymethicone, myristyl trisiloxane, nylon-611 / dimethicone copolymer, PCA dimethicone, PEG-7 amodimethicone, PEG-8 amodimethicone, PEG-8 cetyl dimethicone, PEG-3 dimethicone, PEG-6 dimethicone, PEG-7 dimethicone, PEG-8 dimethicone, PEG-9 dimethicone, PEG-10 dimethicone, PEG-12 dimethicone, PEG-14 dimethicone, PE G-17 Dimethicone, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoleate, PEG-8 Dimethicone / Dimer Dilinoleic Acid Copolymer, PEG-10 Dimethicone / Vinyl Dimethicone Crosspolymer, PEG-8 Distearyl Methylmonium Chloride PG-Dimethicone, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-8 Methicone, PEG-6 Methicone Acetate, PEG-6 Methyl Ether Dimethicone, PEG-7 Methyl Ether Dimethicone, PEG-8 Methyl Ether Dimethicone, PEG-9 Methyl Ether Dimethicone, PEG-10 Methyl Ether Dimethicone, PEG-11 Methyl Ether Dimethicone, PEG-32 Methyl Ether Dimethicone, PEG-8 Methyl Ether Triethoxysilane, PEG-10 Nonafluorohexyl Dimethicone Copolymer, PEG-4 PEG-12 Dimethicone, PEG-8 PG Cocoyl Glucoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG / PPG-20 / 22 Butyl Ether Dimethicone, PEG / PPG-22 / 22 Butyl Ether Dimethicone PEG / PPG-23 / 23 butyl ether polydimethylsiloxane, PEG / PPG-24 / 18 butyl ether polydimethylsiloxane, PEG / PPG-27 / 9 butyl ether polydimethylsiloxane, PEG / PPG-3 / 10 polydimethylsiloxane, PEG / PPG-4 / 12 polydimethylsiloxane, PEG / PPG-6 / 4 polydimethylsiloxane, PEG / PPG-6 / 11 polydimethylsiloxane, PEG / PPG-8 / 14 polydimethylsiloxane, PEG / PPG-8 / 26 polydimethylsiloxane, PEG / PPG-10 / 2 polydimethylsiloxane, PEG / PPG-12 / 16 polydimethylsiloxane, PEG / PPG-12 / 18 polydimethylsiloxane,PEG / PPG-14 / 4 Dimethicone, PEG / PPG-15 / 5 Dimethicone, PEG / PPG-15 / 15 Dimethicone, PEG / PPG-16 / 2 Dimethicone, PEG / PPG-16 / 8 Dimethicone, PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 6 Dimethicone, PEG / PPG-18 / 12 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG / PPG-20 / 6 Dimethicone, PEG / PPG-20 / 15 Dimethicone, PEG / PPG-20 / 20 polydimethylsiloxane, PEG / PPG-20 / 23 polydimethylsiloxane, PEG / PPG-20 / 29 polydimethylsiloxane, PEG / PPG-22 / 23 polydimethylsiloxane, PEG / PPG-22 / 24 polydimethylsiloxane, PEG / PPG-23 / 6 polydimethylsiloxane, PEG / PPG-25 / 25 polydimethylsiloxane, PEG / PPG-27 / 27 polydimethylsiloxane, PEG / PPG-30 / 10 polydimethylsiloxane, PEG / PPG-25 / 25 polydimethylsiloxane / acrylic acid (ester) copolymer, PEG / PPG-20 / 22 methyl ether polydimethylsiloxane, PEG / PPG-24 / 24 Methyl Ether Glycidoxy Dimethicone, PEG / PPG-10 / 3 Oleyl Ether Dimethicone, PEG / PPG-5 / 3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorooctyl Triethoxysilylethyl Methicone, Perfluorononyl Dimethicone, Perfluorononyl Dimethicone / Methicone / Amodimethicone Crosspolymer, Perfluorononyl Ethyl Carboxydecyl Behenyl Dimethicone, Perfluorononyl Ethyl Carboxydecyl Behenyl Dimethicone, Perfluorononyl Ethyl Carboxydecyl Behenyl Dimethicone, Perfluorononyl Ethyl Carboxydecyl Behenyl Dimethicone, Perfluorononyl Ethyl Carboxydecyl Behenyl Dimethicone Lauryl / Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl Dimethicone, Perfluorononylethyl Carboxydecyl PEG-8 Dimethicone, Perfluorononylethyl Carboxydecyl PEG-10 Dimethicone, Perfluorononylethyl Dimethicone / Methicone Copolymer, Perfluorononylethyl PEG-8 Dimethicone, Perfluorononylethyl Stearyl Dimethicone, Perfluorooctylethyl / Diphenyl Dimethicone Copolymer, Perfluorooctylethyl Triethoxysilane, Perfluorooctylethanol Trimethoxysilane, Perfluorooctylethyl Trisiloxane, Perfluorooctyl Triethoxysilane, PG-Amodimethicone, Phenyl Dimethicone, Phenyl Disiloxane, Phenyl Dimethicone,Phenyl isopropyl dimethicone, phenyl methicone, phenyl methicone alcohol, phenylpropyl dimethylsiloxysilicate, phenylpropylethyl methicone, phenylpropyl trimethicone, phenylpropyl trimethicone / diphenyl methicone, phenyl trimethicone, divinyl disiloxane platinum, polyacrylate-6, polydiethylsiloxane, polydimethylsiloxyethyl dimethicone / bisvinyl dimethicone crosspolymer, polydimethylsiloxyethyl dimethicone / methicone copolymer, polydimethylsiloxy PEG / PPG-24 / 19 butyl ether silsesquioxane, polydimethylsiloxy PPG-13 butyl ether silsesquioxane, polyglyceryl-3 disiloxane polydimethylsiloxy Oxane, Polyglyceryl-3 / Lauryl Dimethicone Crosspolymer, Polyglyceryl-3 Dimethicone Crosspolymer, Poly(ethylene glycol adipate) / Bis-hydroxyethoxypropyl Dimethicone Copolymer, Polymethyl Silsesquioxane, Polymethyl Silsesquioxane / Trimethylsiloxysilicate, Polyphenyl Silsesquioxane, Polypropyl Silsesquioxane, Polysilicone-1, Polysilicone-2, Polysilicone-3, Polysilicone-4, Polysilicone-5, Polysilicone-6, Polysilicone-7, Polysilicone-8, Polysilicone-9, Polysilicone-10, Polysilicone-11, Polysilicone-12, Polysilicone-13, Polysilicone-14, Polysilicone-15, Polysilicone-16, Polysilicone Oxalate-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysilicone-21, Polysilicone-18 Cetyl Phosphate, Polysilicone-1 Crosspolymer, Polysilicone-18 Stearate, Polyurethane-10, Methylsilicone PEG-7 Panthenol Phosphate Potassium, Polydimethylsiloxane PEG-7 Phosphate Potassium, PPG-12 Butyl Ether Polydimethylsiloxane, PPG-2 Polydimethylsiloxane, PPG-12 Polydimethylsiloxane, PPG-27 Polydimethylsiloxane, PPG-4 Oleth-10 Polydimethylsiloxane, Propoxytetramethylpiperidinyl Polydimethylsiloxane, Propyl Trimethicone, Quaternium-80, Retinyl Trimethyl Silane, Silanediol Salicylate, Silane Trimethicone Alcohol, Silanetriol Arginine Ester, Silanetriol Glutamate, Silanetriol Lysine Ester, Silanetriol Melanin Ester, Silanetriol Trehalose Ether, Silica, Silica Dimethicone Silylate, Silica Dimethyl Silylate, Silica Silylate, Silicon Carbide, Polysilicone Quaternary Ammonium Salt-1, Polysilicone Quaternary Ammonium Salt-2, Polysilicone Quaternary Ammonium Salt-2 Panthenol Succinate, Polysilicone Quaternary Ammonium Salt-3, Polysilicone Quaternary Ammonium Salt-4, Polysilicone Quaternary Ammonium Salt-5, Polysilicone Quaternary Ammonium Salt-6, Polysilicone Quaternary Ammonium Salt-7, Polysilicone Quaternary Ammonium Salt-8, Polysilicone Quaternary Ammonium Salt-9, Polysilicone Quaternary Ammonium Salt-10, Polysilicone Quaternary Ammonium Salt-11, Polysilicone Quaternary Ammonium Salt-12, Polysilicone Quaternary Ammonium Salt-15, Polysilicone Quaternary Ammonium Salt-16,Polysilicone Quaternium-16 / Glycidoxy Dimethicone Crosspolymer, Polysilicone Quaternium-17, Polysilicone Quaternium-18, Polysilicone Quaternium-19, Polysilicone Quaternium-20, Polysilicone Quaternium-21, Polysilicone Quaternium-22, Polysilicone Quaternium-24, Polysilicone Quaternium-25, Siloxanetriol Alginate, Siloxanetriol Phytate, Silicone Resin, Sodium Carboxydecyl PEG-8 Dimethicone, Sodium Dimethicone PEG-7 Acetylmethyl Taurate, Sodium Dimethicone Hyaluronate, Sodium Lactate Methylsilanol, Sodium Mannoureate Methylsilanol, Sodium PCA Methylsilanol, Sodium PG-Propyl Dimethicone Thiosulfate Copolymer, PG-Propyl Sodium Thiosulfate Dimethicone, Sodium Propoxy Hydroxypropyl Thiosulfate Silica, Sorbitol Silanediol, Soybean Triethoxysilylpropyl Dimonium Chloride, Stearalkonium Dimethicone PEG-8 Phthalate, Stearamidopropyl Dimethicone, Stearyldimonium Hydroxypropyl Panthenol PEG-7 Dimethicone Phosphate Chloride, Stearyldimonium Hydroxypropyl PEG-7 Dimethicone Phosphate Chloride, Stearyldimonium Hydroxypropyl PEG-7 Dimethicone Phosphate Chloride, Stearyl Dimethicone, Stearyloxymethicone / Dimethicone Copolymer, Stearyl Trimethylsilane, Stearylaminopropyl Methicone, Stearyl Dimethicone, Stearyl / Lauryl Methacrylate Crosspolymer, Stearyl Methicone, Stearyl Trimethicone Ethoxysilane, stearyl trimethicone, styrene / acrylates / dimethicone acrylate crosspolymer, styrene / acrylates / dimethicone copolymer, dimethicone PEG-7 phosphate TEA, (tetrabutoxy)propyl trisiloxane, tetramethyl hexaphenyltetrasiloxane, tetramethyl tetraphenyl tripolysiloxane, tocopheryloxypropyl trisiloxane, trideceth-9PG-amodimethicone, triethoxycaprylylsilane, triethoxysilylethyl dimethicone / methicone copolymer, triethoxysilylethyl dimethicone, triethoxysilylethyl dimethicone ethylhexyl dimethicone, triethoxysilylethyl Oxysilylpropylcarbamoylethoxypropylbutyldimethicone, trifluoromethyl C1-4 alkyl dimethicone, trifluoropropyl cyclopentasiloxane, trifluoropropyl cyclotetrasiloxane, trifluoropropyl dimethicone, trifluoropropyl dimethicone / PEG-10 crosspolymer, trifluoropropyl dimethicone / trifluoropropyl divinyl dimethicone crosspolymer, trifluoropropyl dimethicone / vinyl trifluoropropyl dimethicone / silsesquioxane crosspolymer, trifluoropropyl dimethiconol, trifluoropropyl dimethyl / trimethylsiloxysilicate, trifluoropropyl methicone, trimethoxycaprylylsilane, trimethoxysilyl dimethicone, trimethylpentaphenyl trisiloxane,Trimethylsiloxyamodimethicone, trimethylsiloxyphenyl dimethicone, trimethylsiloxysilicate, trimethylsiloxysilicate / dimethicone crosspolymer, trimethylsiloxysilicate / dimethiconol crosspolymer, trimethylsiloxysilylcarbamoyl pullulan, trimethylsilyl hydrolyzed conchiolin protein PG-propyl methylsilanediol crosspolymer, trimethylsilyl hydrolyzed silk PG-propyl methylsilanediol crosspolymer, trimethylsilyl hydrolyzed wheat protein PG-propyl methylsilanediol crosspolymer, trimethylsilyl pullulan, trimethylsilanol trisiloxyglycolate, trimethylsilanol Silane trisiloxyl lactate, trimethylsilane trisiloxysalicylate, triphenyl trimethicone, trisiloxane, tris(tributoxysiloxy)methyl silane, undecene dimethicone, vinyl dimethicone, vinyl dimethicone / lauryl dimethicone crosspolymer, vinyl dimethicone / methicone silsesquioxane crosspolymer, vinyl dimethicone / trimethylsiloxysilicate / stearyl dimethicone crosspolymer, VP / dimethylaminoethyl methacrylate / polyethylene glycol polyurethane, zinc carboxydecyl trisiloxane and dimethicone PEG-8 zinc succinate and mixtures thereof.

[0035] The silicones contained in the mixture according to the invention are more preferably dimethicone, cyclomethicone, phenyl trimethicone, cyclohexasiloxane and cyclopentasiloxane. A detailed description of suitable volatile silicone compounds is given by Todd et al. in Cosm. Toil. 91, 27 (1976). Waxes and stabilizers

[0036] In addition to the natural oils used, the preparations may also contain waxes, in particular natural waxes such as, for example, candelilla wax, carnauba wax, Japan wax, espartograss wax, cork wax, guaruma wax, rice oil wax, sugar cane wax, ouricury wax, montan wax, beeswax, shellac wax, spermaceti, wool wax, uropygial fat, ozokerite, ceresin (paraffin), vaseline, petroleum waxes and microwaxes; chemically modified waxes (hard waxes) such as, for example, montan ester waxes, sasol waxes, hydrogenated jojoba waxes and synthetic waxes such as, for example, polyalkylene waxes and polyethylene glycol waxes.

[0037] Metal salts of fatty acids, such as, for example, magnesium, aluminum and / or zinc stearate or ricinoleate, may be used as stabilizers. Main sunscreen agents

[0038] Essential sunscreens in the context of the present invention are, for example, organic substances which are liquid or crystalline at room temperature (light filters), which are able to absorb UV radiation and release the absorbed energy again in the form of long-wave radiation, for example heat.

[0039] The preparations according to the invention advantageously contain at least one UV-A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic dye. The preparations according to the invention preferably contain at least one UV-B filter or a broadband filter, more particularly at least one UV-A filter and at least one UV-B filter.

[0040] The UV filter substances cited below that can be used in the present invention are preferred, but are not limited to these substances. The UV filter agents preferably used are selected from one, two, three, four, five or more of the following categories:

[0041] In a preferred embodiment, the sunscreen filters forming component (ii) represent a blend of UV-A and UV-B filters selected from the group consisting of homosalate, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, butyl methoxydibenzoylmethane, ethylhexyl salicylate and mixtures thereof. Particularly preferred are mixtures of all these filters, which are available on the market under the trademark Flat (SYMRISE), which is also the subject of WO 2020 088778 A1.

[0042] Suitable pigments include titanium oxide (TiO2), zinc oxide (ZnO), iron oxide (Fe2O3), zirconium oxide (ZrO2), silicon oxide (SiO2), manganese oxide (e.g., MnO), aluminum oxide (Al2O3), cerium oxide (e.g., Ce2O3) and / or mixtures thereof.

[0043] In a further preferred embodiment, the preparations according to the invention comprise a total amount of sunscreens, ie in particular UV filters and / or inorganic pigments (UV filter pigments), such that the preparations according to the invention have a photoprotection factor of greater than or equal to 5 and at most 50. Such preparations according to the invention are particularly suitable for protecting the skin and hair. Secondary sunscreen

[0044] In addition to the above-mentioned primary sunscreen groups, secondary sunscreens of the antioxidant type may also be used. Secondary sunscreens of the antioxidant type block the photochemical reaction chain initiated when UV rays penetrate into the skin. Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and its derivatives (e.g. anserine), carotenoids, carotenes (e.g. α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and its glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, α-linoleoyl, cholesteryl and their glycerides) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and very low tolerance doses of sulfoximine compounds (e.g. buthionine sulfoximine, homocysteine ​​sulfoximine, buthionine sulfone, penta-, hexa- and heptathionine sulfoximine), and (metal) chelators (e.g. α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids , citric acid, lactic acid, malic acid), humic acid, bile acid, bile extract, bilirubin, biliverdin, EDTA, EGTA and its derivatives, unsaturated fatty acids and their derivatives (such as linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (such as ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate), tocopherol and its derivatives (such as vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate), as well as benzoyl benzoate of benzoin resin, rutin and its derivatives, glycosyl rutin, ferulic acid, fusin The invention also includes the following: sorbitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiaretic acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (for example, dispersion in ethanol), zinc and its derivatives (for example, ZnO, ZnSO4), selenium and its derivatives (for example, methionine selenium), stilbenes and their derivatives (for example, stilbene oxide, trans-stilbene oxide) and derivatives of these active compounds suitable for the purposes of the invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids).

[0045] Advantageous inorganic secondary light protection pigments are finely dispersed metal oxides and metal salts, which are also mentioned in WO 2005123101 A1. The total amount of inorganic pigments, in particular hydrophobic inorganic micropigments, in the finished cosmetic preparations according to the invention is advantageously 0.1 to 30% by weight, preferably 0.5 to 10.0% by weight, in each case based on the total weight of the preparation.

[0046] Also preferred are particulate UV filters or inorganic pigments, which may optionally be hydrophobized, for example titanium oxide (TiO2), zinc oxide (ZnO), iron oxide (Fe2O3), zirconium oxide (ZrO2), silicon oxide (SiO2), manganese oxide (e.g. MnO), aluminum oxide (Al2O3), cerium oxide (e.g. Ce2O3) and / or mixtures thereof. Biologics and Antioxidants

[0047] Biologically active substances include, for example, tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy)ribonucleic acid and its fragmentation products, β-glucan, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acid, amino acids, ceramides, pseudoceramides, essential oils, plant extracts, such as plum extract, bambaranus extract and vitamin complexes.

[0048] Antioxidants interrupt the photochemical reaction chain initiated when UV rays penetrate into the skin. Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, pentyl , butyl and lauryl, palmitoyl, oleyl, α-linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and very low tolerable doses (pmol to mol / k) of sulfoximine compounds (e.g. buthionine sulfoximine, homocysteine ​​sulfoximine, buthionine sulfone, penta-, hexa- and heptathionine sulfoximine), and (metal) chelators (e.g. hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin) , hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g. linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (e.g. ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate), tocopherol and its derivatives (e.g. vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate), as well as benzoyl benzoate of benzoin resin, rutin and its derivatives , glycosyl rutin, ferulic acid, furfurylidene sorbitol, carnosine, butylated hydroxytoluene, butylated hydroxyanisole, nordihydroguaiaretic acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (e.g. ZnO, ZnSO4), selenium and its derivatives (e.g. methionine selenium), stilbenes and their derivatives (e.g. stilbene oxide, trans-stilbene oxide) and derivatives of these active compounds suitable for the purposes of the present invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids). Active substances that regulate hair pigmentation

[0049] Preferred active ingredients for hair lightening are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyrone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinol and 4-(1-phenylethyl)1,3-resorcinol (phenethylresorcinol), cyclohexylcarbamates (preferably WO 2010 / 122178 and WO2010 / 097480), sulfur-containing molecules, preferably glutathione or cysteine, α-hydroxy acids (preferably citric acid, lactic acid, malic acid), their salts and esters, N-acetyl tyrosine and derivatives, undecylenoyl phenylalanine, gluconic acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, niacinamide, zinc salts, preferably zinc chloride or zinc gluconate, thujacin and derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably ligustolide, vinyl guaiacol, ethyl guaiacol, dionic acids (dionic acids), preferably octadecene dioic acid and / or azelaic acid, inhibitors of nitrogen oxide synthesis, preferably L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiocitrulline, metal chelators (preferably α-hydroxy fatty acids, phytic acid, humic acid, bile acid, bile extracts, EDTA, EGTA and their derivatives), retinoids, soy milk and extracts, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for skin and hair lightening, the latter preferably in the form of extracts from plants, preferably bearberry extract, rice extract, papaya extract, turmeric extract, mulberry extract, jasmine extract, cyperus extract, liquorice root extract or components concentrated or isolated therefrom, preferably glabridin or licoricechalcone A, jackfruit extract, Rumex and Uncaria rhynchophylla extracts, extracts of Pinus (pine), extracts of Vitis or stilbene derivatives isolated or concentrated therefrom, Saxifraga extract, Scutellaria baicalensis extract (scutelleria extract), grape extract and / or microalgae extract, in particular Tetrascelis quadriscapularis extract.

[0050] Skin and hair tanning active ingredients which are advantageous in this context are substrates or substrate analogs for tyrosinase, such as L-tyrosine, N-acetyltyrosine, L-DOPA or L-dihydroxyphenylalanine, xanthine alkaloids, such as caffeine, theobromine and theophylline and their derivatives, proopiomelanocortin peptides, such as ACTH, α-MSH, their peptide analogs, and other substances which bind to melanocortin receptors, peptides such as Val-Gly-Val-Ala-Pro-Gly, Lys-lle-Gly-Arg-Lys or Leu-Ile-Gly ly-Lys, purines, pyrimidine compounds, folic acid, copper salts such as copper gluconate, copper chloride or copper pyrrolidinoate, 1,3,4-oxadiazole-2-thiol such as 5-pyrazin-2-yl-1,3,4-oxadiazole-2-thiol, curcumin, zinc diglycinate (Zn(GIy)2)), manganese(II) dicarbonate complexes ("pseudocat-alases"), as described, for example, in EP0584178, tetrasubstituted cyclohexene derivatives, as described, for example, in WO2005 / 032501, isoprene terpenes, as described, for example, in WO 2005 / 102252 and WO2006 / 010661, melanin derivatives such as Melasyn-100 and MelanZe, diacylglycerols, aliphatic or cyclic diols, psoralens, prostaglandins and their analogs, activators of adenylate cyclase and compounds that activate the conversion of hair melanosomes into keratinocytes, such as serine proteases or PAR-2 ​​receptor agonists, extracts of plants and plant parts of the genus Chrysanthemum, extracts of plants and plant parts of the genus Sanguisorba, walnut extracts, urucum extracts, rhubarb extracts, microalgae extracts, especially Isochrysis galbana, trehalose, erythrulose and dihydroxyacetone. Flavonoids that cause skin and hair staining or browning (e.g., quercetin, rhamnosine, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosgenin and geranyl, morin, quercetin, naringenin, hesperidin, phloridzin, phloretin) may also be used.

[0051] The amount of the aforementioned examples of further active ingredients (one or more compounds) for regulating skin and hair pigmentation in the products according to the invention is preferably from 0.00001 to 30% by weight, preferably from 0.0001 to 20% by weight, particularly preferably from 0.001 to 5% by weight, based on the total preparation. Hair growth activators or inhibitors

[0052] Preparations and products according to the invention may also contain one or more hair growth activators, ie preparations which stimulate hair growth. The hair growth activator is preferably selected from the group consisting of pyrimidine derivatives, such as 2,4-diaminopyrimidine-3-oxide (Aminexil), 2,4-diamino-6-piperidopyrimidine-3-oxide (Minoxidil) and its derivatives, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidopyrimidine and its derivatives, xanthine alkaloids, such as caffeine, theobromine and theophylline and their derivatives, quercetin and derivatives, dihydroquercetin (taxifolin) and derivatives, potassium channel openers, antiandrogens, synthetic or natural 5-reductase inhibitors, nicotinates, such as tocopheryl nicotinate, benzyl nicotinate and C1-C6 alkyl nicotinates, proteins such as the tripeptide Lys-Pro-Val, diphencypren, hormones, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, cyproterone acetate ketones, spironolactone and other diuretics, calcineurin inhibitors such as FK506 (Tacrolimus, Fujimycin) and their derivatives, cyclosporin A and its derivatives, zinc and zinc salts, polyphenols, proanthocyanidins, proanthocyanidins, phytosterols such as β-sitosterol, biotin, eugenol, (±)-β-citronellol, panthenol, glycogen, for example from mussels, from microorganisms, from seaweed, Extracts of plants and plant parts, for example plants of the genera: dandelion (genus Leontopodium or Taraxacum), Codonopsis pilosula, Vitex, coffee, Paulownia oleracea, cocoa, Asarum gracile, Cucurbita spp. or Sophora japonica, Serenoa repens (Saw Palmetto), Sophora flavescens, Pygeum africanum, Panicum foetida, Cimicifuga foetida, Soybean, Clove, Cotinus coggygria, Hibiscus rosa-sinensis, Camellia sinensis, Yerba mate, Isochrysis galbana, Licorice, grape, apple, barley or hops, or / and rice or wheat hydrolysates.

[0053] Optionally, the preparations and products according to the invention may also contain one or more hair growth inhibitors (as described above), i.e. preparations that slow down or prevent hair growth. The hair growth inhibitors are preferably selected from the group consisting of activin, activin derivatives or activin agonists, ornithine decarboxylase inhibitors, such as α-difluoromethylornithine or pentacyclic triterpenoids such as ursolic acid, betulin, betulinic acid, oleanolic acid and its derivatives, 5α-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, γ-glutamyl transpeptidase inhibitors, transglutaminase inhibitors, serine protease inhibitors of soybean origin, extracts from microorganisms, seaweed, different microalgae or plants and plant parts, such as Leguminosae, Solanaceae, Gramineae, Asclepiadaceae or Cucurbitaceae, Chondrus, Hemerocallis, Ceropegia, Dulvilla, Glycine max, Sanguisorba officinalis, Calendula, Hamamelis, Arnica montana, Salix alba, Hypericum perforatum or Gymnema sylvestre. Physiological cooling and warming agents

[0054] Physiological cooling agents are preferably selected from the classes described in the following table (including their optical isomers and racemates):

[0055] The physiological warming agent may be selected from the group consisting of capsaicin, dihydrocapsaicin, nordihydrocapsaicin, homocapsaicin, homodihydrocapsaicin, N-vanillyl nonivamide and chili pepper extract. Anti-inflammatory agents

[0056] Suitable anti-inflammatory agents are selected from the group consisting of: (i) steroidal anti-inflammatory substances of the corticosteroid class, in particular hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone, (ii) nonsteroidal anti-inflammatory substances, in particular oxoxicam such as piroxicam or tenoxicam, salicylates such as aspirin, salsalate, solprin or fendosal, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or clindanac, fenamic acid esters such as mefenamic acid, meclofenamic acid, flufenamic acid or niflumic acid, propionic acid derivatives such as ibuprofen, naproxen or benoxaprofen, pyrazoles such as phenylbutazone, oxyphenbutazone, febrazone or azapropazone, (iii) natural or naturally occurring anti-inflammatory substances or substances which relieve redness and / or itching, in particular extracts or fractions of camomile, aloe, myrrh, madder, willow, willowherb, oats, calendula, arnica, St John's wort, honeysuckle, rosemary, passion flower (Passiflora incarnata), witch hazel, ginger or echinacea, or the single active compounds thereof, (iv) histamine receptor antagonists, serine protease inhibitors (e.g. soybean extract), TRPV1 antagonists (e.g. 4-tert-butylcyclohexanol), NK1 antagonists (e.g. aprepitant, hydroxyphenylpropionamide benzoic acid), cannabinoid receptor agonists (e.g. palmitoylethanolamine) and TRPV3 antagonists. Antimicrobial Agents

[0057] Suitable antimicrobial agents are in principle all substances which are active against Gram-positive bacteria, such as, for example, 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether (triclosan), 4-chloro-3,5-dimethyl-phenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chloro-phenol, 3-(4 -chlorophenoxy)-1,2-propanediol, 3-iodo-2-propynylcarbamic acid butyl ester, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial fragrance, thymol, thyme oil, eugenol, clove oil, menthol, peppermint oil, farnesol, phenoxyethanol, glyceryl monocaprate, glyceryl monocaprylate, glyceryl monolaurate (GML), diglyceryl monocaprate (DMC), salicylic acid N-alkyl amides, for example, n-octyl salicylic acid amide or n-decyl salicylic acid amide. Enzyme inhibitors

[0058] Suitable enzyme inhibitors are, for example, esterase inhibitors. These enzyme inhibitors are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and, in particular, triethyl citrate (HydagenCAT). These substances can inhibit the activity of the enzyme, thereby reducing the formation of odors. Other substances suitable as esterase inhibitors are sterol sulfates or phosphates, for example, lanosterol sulfate or phosphate, cholesterol sulfate or phosphate, campesterol sulfate or phosphate, stigmasterol sulfate or phosphate and sitosterol sulfate or phosphate; dicarboxylic acids and esters thereof, for example glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid and diethyl malonate, hydroxycarboxylic acids and esters thereof, for example citric acid, malic acid, tartaric acid or diethyl tartrate, and zinc glycinate. Odor absorbers and antiperspirant actives

[0059] Suitable odor absorbers are substances that can absorb and retain the compounds that form the taste to a great extent. They reduce the partial pressure of each component, thereby also reducing its diffusion rate. It is important that the fragrance must remain intact during this process. Odor absorbers have no effect on bacteria. They contain, for example, a composite zinc salt of ricinoleic acid as a main component, or a specific main fragrance known to those skilled in the art as a "fixing agent", for example, an extract of rock rose or styrax or some rosin acid derivatives. Odor masking agents are fragrances or fragrance oils, which, in addition to their function as odor masking agents, also provide their respective fragrances to the deodorant. Fragrance oils that can be mentioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers, stems and leaves, fruits, peels, roots, wood, herbs and grasses, pine needles and branches, as well as resins and balsams. Also suitable are animal products, such as civet and castoreum. Typical synthetic aromatic compounds are esters, ethers, aldehydes, ketones, alcohols and hydrocarbon products. Ester fragrance compounds are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styroyl propionate and benzyl salicylate. Ethers include, for example, benzyl ethyl ether; aldehydes include, for example, linear alkanals containing 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lily aldehyde and bourgeonal; ketones include, for example, ionone and methyl cedryl ketone; alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol; hydrocarbons mainly include terpenes and balsams. However, it is preferred to use a mixture of different fragrances, which together produce a pleasant fragrance. Less volatile essential oils commonly used as fragrance ingredients are also suitable as fragrance oils, such as sage oil, chamomile oil, clove oil, melissa oil, peppermint oil, cinnamon leaf oil, linden flower oil, juniper berry oil, vetiver oil, frankincense oil, galbanum oil, labdanum oil, and lavender oil.Preference is given to using bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, α-hexylcinnamaldehyde, geraniol, benzylacetone, cyclamen aldehyde, linalool, boisambrene forte, ambroxan, indole, methyl dihydrojasmonate, sandelice, lemon oil, mandarin oil, orange oil, allyl isopentoxyacetate, cyclovertal, lavender oil, clary sage oil, β-damascenone, bourbon geranium oil, cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, 2-ethyl-hexanoic acid ethyl ester (irotyl) and 2-tert-butylcyclohexylethyl carbonate (floramat), alone or in a mixture.

[0060] Suitable astringent antiperspirant active ingredients are primarily salts of aluminum, zirconium or zinc. Suitable antihydrotic active ingredients of this type are, for example, aluminum chloride, aluminum hydrochlorate, aluminum dihydrochlorate, aluminum sesquichlorate and their complexes, for example with 1,2-propylene glycol, aluminum hydroxyallantoinate, aluminum chlorotartrate, aluminum zirconium trihydrochloride, aluminum zirconium tetrahydrochloride, aluminum zirconium pentahydrochloride and their complexes, for example with amino acids such as glycine. Film formers and anti-dandruff agents

[0061] Standard film formers are, for example, chitosan, microcrystalline chitosan, quaternary chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, acrylic polymers, quaternary cellulose derivatives, collagen, hyaluronic acid and its salts and similar compounds.

[0062] Suitable antidandruff agents are Pirocton Olamin (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), (Climbazole), (4-acetyl-1-{4-[2-(2,4-dichlorophenyl) r-2-(1H-imidazol-1-ylmethyl)-1,3-dioxolane (dioxylan)-c-4-ylmethoxyphenyl}-piperazine, ketoconazole, neoconazole, selenium disulfide, colloidal sulfur, sulfur polyethylene glycol dehydrated sorbitan monooleate, sulfur ricinoleyl alcohol polyethoxylate, sulfur tar fraction, salicylic acid (or combined with hexachlorophene), undecylenic acid, monoethanolamide sulfosuccinic acid sodium salt, UD (protein / undecylenic acid concentrate), zinc pyrithione, aluminum pyrithione, and magnesium pyrithione / dipyrithione magnesium sulfate. Carriers and hydrotropes

[0063] Preferred cosmetic carrier materials are solid or liquid (including high viscosity substances) at 25° C. and 1013 mbar, such as glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water and mixtures of two or more of the liquid carrier substances and water. Optionally, these preparations of the present invention can be prepared using preservatives or cosolvents. Other preferred liquid carrier substances that can be used as ingredients of the preparations of the present invention are selected from the group consisting of oils, such as vegetable oils, neutral oils and mineral oils.

[0064] Preferred solid carrier substances which can be used as components of the preparations according to the invention are hydrocolloids, for example starch, degraded starch, chemically or physically modified starch, dextrin, (powdered) maltodextrin (preferably with a dextrose value of 5 to 25, preferably 10-20), lactose, silicon dioxide, glucose, modified cellulose, gum arabic, gum ghatti, gum traganth, gum karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar gum, carob powder, alginates, agar, pectin and inulin and mixtures of two or more of these solid substances, in particular maltodextrin (preferably with a dextrose value of 15 to 20), lactose, silicon dioxide and / or glucose.

[0065] In addition, hydrotropes, such as ethanol, isopropanol or polyols, can be used to improve fluidity. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. Such polyols may contain other functional groups, more specifically amino groups, or may be nitrogen-modified. Typical examples are: ·glycerin; Alkanediols, for example ethylene glycol, diethylene glycol, propylene glycol, butanediol, hexanediol and polyethylene glycols having an average molecular weight of 100 to 1000 daltons; Technical oligoglycerol mixtures having a degree of self-condensation of 1.5 to 10, such as technical diglycerol mixtures having a diglycerol content of 40 to 50% by weight; methylol compounds, in particular, for example trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol; lower alkyl glycosides, especially those containing 1 to 8 carbon atoms in the alkyl group, for example methyl glycoside and butyl glycoside; Sugar alcohols containing 5 to 12 carbon atoms, such as sorbitol or mannitol; Sugars containing 5 to 12 carbon atoms, such as glucose or sucrose; Amino sugars, such as glucosamine; - Diolamines, for example diethanolamine or 2-aminopropane-1,3-diol. Preservatives and / or product protectants

[0066] Suitable preservatives are listed in Annex 6 Parts A and B of the Kosmetikverordnung ("Cosmetics Directive").

[0067] Suitable species may be selected from preservatives selected from the group consisting of benzoic acid and p-hydroxybenzoic acid, their esters and salts, benzyl benzoate, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienoic acid (sorbic acid) and its salts, levulinic acid and its salts, anisic acid and its salts, perillic acid and its salts, cinnamic acid and its salts, formaldehyde and paraformaldehyde, 4-hydroxybenzaldehyde, o-, m- and p-anisaldehyde, cinnamaldehyde, cinnamyl alcohol, 2-hydroxydiphenyl ether and its salts, 2-zinc-thiopyridine N-oxide, inorganic sulfites and bisulfites, sodium iodate, chlorobutanol, 4-ethylmercury-(II) 5-amino-1,3-bis(2 -hydroxybenzoic acid), its salts and esters, dehydrated acetic acid, formic acid, 1,6-bis(4-amidino-2-bromophenoxy)-n-hexane and its salts, sodium salt of ethylmercury(II)-thiosalicylic acid, phenylmercury and its salts, 10-undecenoic acid and its salts, 5-amino-1,3-bis(2-ethylhexyl)-5-methyl-hexahydropyrimidine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3-propanediol, 2,4-dichlorobenzyl alcohol, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 4-chloro-m-cresol, 2,4,4'-trichloro-2'-hydroxy-di Phenyl ether, 4-chloro-3,5-dimethylphenol, 1,1'-methylene-bis(3-(1-hydroxymethyl-2,4-dioxoimidazolidin-5-yl)urea), poly-(hexamethylene biguanide) hydrochloride, (benzyloxymethoxy)-methanol, hexamethylenetetramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azoniaadamantane chloride, 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethyl-2-butanone, 1,3-bis(hydroxymethyl)-5,5-dimethyl-2,4-imidazolidinedione, 1, 2-Dibromo-2,4-dicyanobutane, 2,2'-methylene-bis(6-bromo-4-chloro-phenol), bromochlorobenzene, 5-chloro-2-methyl-3(2H)-isothiazolinone and 2-methyl-3(2H)-isothiazolinone mixed with magnesium chloride and magnesium nitrate, 2-octyl-2H-isothiazol-3-one, 1,2-benzisothiazol-3(2H)-one, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy)-1,2-propanediol (Chlorphenesin), 2-chloroacetamide, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, N-alkyl(C 12 -C 22 )trimethylammonium bromide and N-alkyl (C 12 -C22 )trimethyl-ammonium chloride, 4,4-dimethyl-1,3-oxazolidine, N-hydroxymethyl-N-(1,3-bis(hydroxymethyl)-2,5-dioxoimidazoline-4-yl)-N'-hydroxymethylurea, 1,6-bis(4-carbamimidoyl-phenoxy)-n-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, 3-(4-chlorophenoxy)-1,2-propanediol, hyamines, alkyl-(C8-C 18 )-dimethyl-benzylammonium chloride, alkyl-(C8-C 18 )-dimethyl-benzylammonium bromide, alkyl-(C8-C 18)-dimethyl-benzylammonium saccharide, benzyl hemiformal, 3-iodo-2-propynyl butylcarbamate, sodium hydroxymethyl-aminoacetate or sodium hydroxymethyl-aminoacetate, imidazolidinyl urea, diazolidinyl urea, sodium hydroxymethylglycinate, DMDM ​​hydantoin, tropolone, (ethylenedioxy)dimethanol, 2-bromo-2-(bromomethyl)valeronitrile, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, α,α',α"-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol, pyridine-2-thiol-1-oxide, sodium salt, tetrahydro-1,3,4,6-tetra(hydroxymethyl)imidazo[4,5-d]imidazole-2,5(1H,3H)-dione, 1,3-bis(hydroxymethyl)-1-(1,3,4-tri(hydroxy-methyl)-2,5-dioxoimidazolidin-4-yl)urea (bis-imidazolidinyl urea), 1,3-bis(hydroxy-methyl)-5,5-dimethylimidazolidine-2,4-dione, 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, hexadecylpyridinium chloride, octanoylhydroxamic acid, sorbitol hydroxamic acid (sorbohydroxamic acid acid) and mixtures thereof, 1,3-propylene glycol, methylpropylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, 1,5-pentanediol, 1,6-hexanediol, 1,8-octanediol, 1,2-decanediol, ethylhexylglycerol, hexyloxy-propane-1,2-diol, heptyloxy-propane-1,2-diol, octyloxy-propane-1,2-diol, 3-phenoxy-propane-1,2-diol, 3-benzyloxy-propane-1,2-diol, 3-phenylethoxy-propane-1,2-diol, 3-phenylpropoxy-propane-1,2-diol, 3-methylbenzyloxy-propane-1,2-diol, sorbitan octanoate, triclosan, clofenazole, Octopirox (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)-pyridinone, 2-aminoethanol), chitosan, farnesol, 2-butyloctanoic acid, 2-benzylheptan-1-ol, glycerol monolaurate, bis(2-pyridylthio)zinc 1,1'-dioxide, N,N'-(decylidene 1,10-diylpyridin-1-yl-4-ylidene)-dioctane-1-amine dihydrochloride (octenidine dihydrochloride), thymol, eugenol, benzyl alcohol, 2-phenylethanol, 3-phenylpropanol, 2-phenoxyethanol, 1-phenoxy-propan-2-ol, 3-phenoxypropanol, benzyloxymethanol, 4-hydroxyacetophenone and mixtures thereof. Fragrance Oil

[0068] Suitable fragrance oils are mixtures of natural and synthetic fragrances. Natural fragrances include extracts of flowers (lily, lavender, rose, jasmine, orange blossom, ylang-ylang), stems and leaves (geranium, patchouli, bitter orange), fruits (fennel, coriander, caraway, juniper), peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calamus), wood (pine, sandalwood, guaiac, cedar, mahogany), herbs and grasses (tarragon, lemongrass, sage, thyme), needles and branches (spruce, fir, pine, dwarf pine), resins and balsams (galbanum, elemi, benzoin, myrrh, frankincense, opoponax). Animal raw materials, such as civet and castoreum, can also be used. Woody spices

[0069] Suitable woody fragrances are selected from the group consisting of: Amber scented fragrance

[0070] Suitable fragrances having an amber smell are selected from the group consisting of: Fruity aroma spices

[0071] Suitable fragrances having a fruity aroma are selected from the group consisting of: Musky scent

[0072] Suitable perfumes having a musky odor are selected from the group consisting of:

[0073] The fragrances compiled above also represent preferred embodiments of said secondary fragrances forming the major component of the claimed fragrance composition. dye

[0074] Suitable dyes are, for example, the publication "Kosmetische ”, Verlag Chemie, Weinheim, 1984, pages 81 to 106, any of the substances suitable and approved for use in cosmetics. Examples include carmine A (CI16255), patent blue V (CI42051), indigo (CI73015), chlorophyllin (CI75810), quinoline yellow (CI47005), titanium dioxide (CI77891), indanthrene blue RS (CI69800) and madder red (CI58000). Luminol can also be used as a fluorescent dye. Advantageous coloring pigments are, for example, titanium dioxide, mica, iron oxides (e.g., Fe2O3, Fe3O4, FeO(OH)) and / or tin oxide. Advantageous dyes are, for example, carmine, Berlin blue, chromium oxide green, ultramarine and / or manganese violet. preparation

[0075] Preferred compositions according to the invention are chosen from products for treating, protecting, caring for and cleansing the skin and / or hair or as make-up products, preferably as leave-on products (meaning that the compound or compounds remain on the skin and / or hair for a longer time compared to rinse-off products).

[0076] The preparations according to the invention are preferably in the form of emulsions, for example W / O (water-in-oil), O / W (oil-in-water), W / O / W (water-in-oil-in-water), O / W / O (oil-in-water-in-oil) emulsions, PIT emulsions, Picking emulsions, emulsions with a low oil content, microemulsions or nanoemulsions, solutions, for example in oils (fatty oils or fatty acid esters, in particular C6-C32 fatty acid C2-C30 esters) or silicone oils, dispersions, suspensions, creams, emulsions or milks, depending on the preparation method and the ingredients, gels (including hydrogels, hydrodispersible gels, oleogels), sprays (for example pump sprays or sprays containing propellants) or foams or impregnating solutions for wipe-off cosmetics, detergents, for example soaps, synthetic detergents, washing liquids, shower and bath preparations, bath products (capsules, oils, tablets, salts, bath salts, soaps, etc.); effervescent preparations, skin care products such as emulsions (as described above), ointments , pastes, gels (as above), oils, balms, serums, powders (e.g. face powders, body powders), perfumes, eau de toilette, aftershaves, facial masks, eyebrow pencils, lipsticks, roll-ons, pumps, aerosols (foaming, non-foaming or post-foaming), deodorants and / or antiperspirants, mouthwashes and mouth rinses, foot care products (including exfoliants, deodorants), insect repellents, sunscreens, after-sun products, shaving products, aftershave balms, pre-shave and after-shave washes, depilatories, hair care Products such as shampoos (including 2-in-1 shampoos, anti-dandruff shampoos, baby shampoos, shampoos for dry hair, concentrated shampoos), conditioners, hair tonics, hair tonics, hair dyes, styling creams, pomades, perms and curling lotions, hair sprays, styling aids (such as gels or waxes), hair smoothing agents (conditioners, relaxers), hair dyes such as short-term direct hair dyes, semi-permanent hair dyes, permanent hair dyes, conditioners, hair mousses, eye care products, make-up, make-up removers or baby products.

[0077] The content of auxiliary substances and additives is 5 to 99% by weight, preferably 10 to 80% by weight, based on the total amount of the preparation. The amount of cosmetic or skin care product auxiliary agents and additives and fragrances used in each case can be easily determined by a simple trial and error method according to the properties of the specific product by a skilled person in the art.

[0078] The formulation may also contain up to 99% by weight, preferably about 5 to about 80% by weight and more preferably about 10 to about 50 or about 60 to about 80% by weight water, based on the total weight of the formulation. Detergent preparations

[0079] Another object of the present invention relates to a detergent formulation comprising a perfume mixture or the aromatic composition as described above. The formulation may contain from about 0.01 to about 2% by weight, preferably from about 0.1 to 1% by weight of the perfume mixture or the aromatic composition, calculated on the formulation. Suitable examples for detergents include heavy duty powder detergents, heavy duty liquid detergents, light duty powder detergents, light duty liquid detergents, detergent tablets, fabric softeners, manual dishwashing detergents, multi-purpose detergents, and the like.

[0080] The detergent compositions according to the present invention may contain any ingredients commonly used in such compositions, for example anionic, nonionic, cationic, amphoteric or zwitterionic (co) surfactants, organic solvents, builders, enzymes and additional auxiliaries such as stain repellents, thickeners, colorants and fragrances and the like. Anionic and zwitterionic surfactants

[0081] Typical examples of anionic and zwitterionic surfactants include: almond amidopropylamine oxide, almond amidopropyl betaine, aminopropyl lauryl glutamine, ammonium C12-15 alkyl sulfate, ammonium C12-16 alkyl sulfate, ammonium capryl sulfate, ammonium monococoglyceryl sulfate, ammonium coconut sulfate, ammonium cocoyl isethionate, ammonium cocoyl sarcosinate, ammonium C12-15 alkylene sulfate, ammonium C9-10 perfluoroalkyl sulfonate, ammonium dinonyl sulfosuccinate, ammonium dodecylbenzene sulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 sulfate, ammonium octanol ... Ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myristyl sulfate, ammonium myristyl sulfate, ammonium nonylphenol polyether-4 sulfate, ammonium nonylphenol polyether-30 sulfate, ammonium oleate, ammonium palm kernel alcohol sulfate, ammonium stearate, ammonium tall oil acid, isostearyl hydrolyzed collagen AMPD salt, rosin (acyl) hydrolyzed collagen AMPD salt, isostearyl hydrolyzed collagen AMP salt, isostearyl hydrolyzed keratin AMP salt, isostearyl hydrolyzed soy protein AMP salt, isostearyl hydrolyzed wheat protein AMP salt, wild apricot oleamidopropyl betaine, arachidic acid, hexyldecyl phosphate arginine salt, avocado oleamidopropyl betaine, avocado oil glyceryl polyether-8 esters, babassu Seed oil acid, babassu amidopropylamine oxide, babassu amidopropyl betaine, beeswax acid, behenamidopropyl betaine, behenamine oxide, beheneth-25, beheneth-30, behenic acid, behenyl betaine, bis-butyl dimethicone polyglyceryl-3, butylphenol polyether-5 carboxylic acid, butylphenol polyether-19 carboxylic acid, butyldimethyl (hydroxypropyl butyl glucoside) ammonium chloride, butyldimethyl (hydroxypropyl lauryl glucoside) ammonium chloride, butyl glucoside, butyl glucoside decanoate, butyl glucoside hydroxypropyltrimonium chloride, butyl caprylate, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C 9-16 Alkane / Cycloalkane, C10-14 Alkylbenzenesulfonic Acid, C12-14 Alkyl Di(Aminoethyl)Glycine HCl, C9-15 Alkyl Phosphate, Candida / Glucose / Rapeseed Methyl Ester Ferment, Canola Amidopropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glucoside, Caprylyl / Caprylamidopropyl Betaine, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Caprylic Acid, Capryloyl Collagen Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids, Capryl / Decyl Glucoside, Capryl / Decyl Wheat Bran / Straw Glycosides, Capryl Glucoside, Caprylyl Glyceryl Ether, Capryl Pyrrolidone, Carnitine, Ceteareth-20,Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Ceteareth-4 Phosphate Acid, Ceteareth-5 Phosphate, Ceteareth-10 Phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Ceteth-22, Ceteth-24, Ceteth-25, Ceteth-30, Cetyl Betaine, Chrysanthemum Sinense flower extract, C12-14 hydroxyalkyl hydroxyethyl beta-alanine, C12-14 hydroxyalkyl hydroxyethyl sarcosine, cocamidoethyl betaine, cocamidopropylamine oxide, cocamidopropyl betainamide MEA chloride, cocamidopropyl betaine, cocamidopropyl hydroxysultaine, cocamine oxide, cocoaminobutyric acid, cocoaminopropionic acid, coceth-7 carboxylic acid, coceth-4 glucoside, cocoamphopropionic acid, cocobeth-4 glucoside, cocoamphopropionic acid, cocobeth-betaine amidoamphopropionate, cocobetaine, cocodimonium hydroxypropyl hydrolyzed rice protein, cocodimonium hydroxypropyl hydrolyzed soy protein, cocodimonium hydroxypropyl hydrolyzed wheat protein, coco-glucoside, coco-glucoside hydroxypropyltrimonium chloride, coco-hydroxysultaine, cocomorpholine oxide, cocoic acid, cocoglyceryl polyether-8 Esters, cocoyl / oleamidopropyl betaine, cocoyl-sulfobetaine, (coconut oil / sunflower seed oil) amidopropyl betaine, cocoyl choline methyl sulfate, cocoyl glutamic acid, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn oil acid, cotton Seed oil acid, cottonseed oil glyceryl polyether-8 esters, C10-16 parathion-1, C10-16 parathion-2, C11-13 parathion-6, C11-13 parathion-9, C11-13 parathion-10, C11-15 parathion-30, C11-15 parathion-40, C12-13 parathion-1, C12-13 parathion-23,C12-14 Pareth-5, C12-14 Pareth-9, C13-15 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 Carboxylic Acid, C9-11 Pareth-8 Carboxylic Acid, C11-15 Pareth-7 carboxylic acid, C12-13 pareth-5 carboxylic acid, C12-13 pareth-7 carboxylic acid, C12-13 pareth-8 carboxylic acid, C12-13 pareth-12 carboxylic acid, C12-15 pareth-7 carboxylic acid, C12-15 pareth-8 carboxylic acid, C12-15 pareth-12 carboxylic acid, C14-15 pareth-8 carboxylic acid, C6-10 pareth-4 phosphate, C12-13 pareth-2 phosphate, C12-13 C12-15 Pareth-6 Phosphate, C12-15 Pareth-8 Phosphate, C12-15 Pareth-10 Phosphate, C12-16 Pareth-6 Phosphate, C4-18 Perfluoroalkyl Ethyl Mercaptopropyl Trimethylammonium Chloride, Cocoamidopropyl Betaine, C12-13 Alcohol Sulfate DEA, C12-15 Alcohol Sulfate DEA, Ceteareth-2 Phosphate DEA, Cetyl Sulfate DEA, Cocoyl DEA amphoteric dipropionate, DEA C12-13 alkane polyether-3 sulfate, DEA cyclopentyl oleate, DEA dodecylbenzene sulfonate, DEA isostearate, DEA laureth sulfate, DEA lauryl sulfate, DEA linoleate, DEA myristyl methyl sulfonate, DEA myristyl ether sulfate, DEA myristate, DEA myristyl sulfate, DEA oleth-5 phosphate, DEA oleth-20 phosphate, DEA PG-oleate, Deceth-7 carboxylic acid, Deceth-7 glucoside, Deceth-9 phosphate, Decylamine oxide, Decyl betaine, Decyl glucoside, Decyltetradeceth-30, Decyltetradeceth-2 oxide, Lauramide-MEA diammonium sulfosuccinate, Laureth-2 diammonium sulfosuccinate, Oleamido PEG-2 diammonium sulfosuccinate, Dibutoxymethane, Di-C12-15 Pareth-2 phosphate, Di C12-15 pareth-4 phosphate, di-C12-15 pareth-6 phosphate, di-C12-15 pareth-8 phosphate, di-C12-15 pareth-10 phosphate, didoyl butane tetracarboxylate, laureth sulfate diethylamine salt, sodium diethylhexyl sulfosuccinate, di(hydroxyethyl) C8-10 alkoxypropylamine oxide, di(hydroxyethyl) C9-11 alkoxypropylamine oxide,Di(hydroxyethyl) C12-15 alkoxypropylamine oxide, di(hydroxyethyl) cocamine oxide, di(hydroxyethyl) laurylamine oxide, di(hydroxyethyl) stearamine oxide, di(hydroxyethyl) tallowamine oxide, dimethicone PEG-7 phosphate, dimethicone PEG-10 phosphate, dimethicone PEG / PPG-7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone / polyglyceryl-3 crosspolymer, dimethicone propyl PG-betaine, dimyristyl phosphate, dioleamide ethyl hydroxyethyl Methylammonium methylsulfate, hydrogenated coconut oil DIPA salt, lanolin acid DIPA salt, myristic acid DIPA salt, dipotassium capryloyl glutamate, dipotassium lauryl sulfosuccinate, dipotassium undecylenyl glutamate, disodium babassu oleamido MEA-sulfosuccinate, disodium capryloylamphodiacetate, disodium capryloylamphodipropionate, disodium capryloylamphodiacetate, disodium capryloylamphodipropionate, disodium capryloyl glutamate, disodium cetearyl sulfosuccinate, disodium cetyl phenyl ether disulfonate, disodium cetyl alcohol sulfosuccinate, disodium cocamido MEA-sulfosuccinate, cocamido MIPA Disodium PEG-4 Sulfosuccinate, Disodium Cocoamido MIPA-Sulfosuccinate, Disodium Cocoamido PEG-3 Sulfosuccinate, Disodium Cocoeth-3 Sulfosuccinate, Disodium Cocoamphocarboxyethyl Hydroxypropyl Sulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Coco-Glucoside Sulfosuccinate, Disodium Coco-Sulfosuccinate, Cocoyl Butyl Glucose Disodium Cocoyl Glutamate, Disodium C12-14 Pareth-1 Sulfosuccinate, Disodium C12-14 Pareth-2 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium C12-14 Sec-Pareth-3 Sulfosuccinate, Disodium C12-14 Sec-Pareth-5 Sulfosuccinate, Disodium C12-14 Sec-Pareth -7 sulfosuccinate disodium, C12-14 sec-alkanol pareth-9 sulfosuccinate disodium, C12-14 sec-alkanol pareth-12 sulfosuccinate disodium, deceth-5 sulfosuccinate disodium, deceth-6 sulfosuccinate disodium, decyl phenyl ether disulfonate disodium, dihydroxyethyl sulfosuccinyl undecylenate disodium, dicocoyl ethylenediamine PEG-15 disulfate disodium, hydrogenated cottonseed oil glycerides sulfosuccinate Disodium amber ester, disodium hydrogenated tallow glutamate, disodium hydroxydecyl sorbitan citrate, disodium isodecyl sulfosuccinate, disodium isostearamide MEA-sulfosuccinate, disodium isostearamide MIPA-sulfosuccinate, disodium isostearylamphodiacetate, disodium isostearylamphodipropionate, disodium isostearyl sulfosuccinate, disodium lanolin alcohol ether-5 sulfosuccinate, disodium lauryl amide MEA-sulfosuccinate,Disodium lauroyl MIPA glycol sulfosuccinate, disodium lauroyl PEG-2 sulfosuccinate, disodium lauroyl PEG-5 sulfosuccinate, disodium laureth-5 carboxyamphodiacetate, disodium laureth-7 citrate, disodium laureth sulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium laurimidobishydroxypropyl sulfonate, disodium laurimidodiacetate, disodium laurimidodipropionate, disodium laurimidodipropionate tocopheryl phosphate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium N-lauroyl aspartate, lauroyl glutamate Disodium lauryl phenyl ether disulfonate, diammonium lauryl sulfosuccinate, disodium myristamide MEA-sulfosuccinate, disodium nonylphenol polyether-10 sulfosuccinate, disodium oleamide MEA sulfosuccinate, disodium oleamide MIPA sulfosuccinate, disodium oleamide PEG-2 sulfosuccinate, disodium oleoamphodipropionate, disodium oleeth-3 sulfosuccinate, disodium oleyl phosphate, disodium oleyl sulfosuccinate, disodium palmitamide PEG-2 sulfosuccinate, disodium palmitamide PEG-2 sulfosuccinate, disodium palmitamide PEG-4 sulfosuccinate, disodium PEG-12 polydimethylsiloxane sulfosuccinate, PEG-8 palmitic acid Glycerides Disodium sulfosuccinate, PPG-2-isodecyl polyether-7 sodium carboxyamphodiacetate, disodium ricinoleamide MEA sulfosuccinate, disodium sitosterol polyether-14 sulfosuccinate, disodium soybean oleylamphodiacetate, disodium stearamide MEA-sulfosuccinate, disodium stearimidodipropionate, disodium stearamidodiacetate, disodium stearoyl glutamate, disodium sulfosuccinic acid monoacyl stearylamine, disodium stearyl alcohol sulfosuccinate, disodium 2-sulfolaurate, disodium 2-sulfopalmitate, disodium tallowamide MEA sulfosuccinate, disodium tallowamide MEA sulfosuccinate, disodium tallowamidodiacetate, disodium tallowimidodipropionate, disodium sulfosuccinic acid monoacyl tallowamine, tridecyl alcohol Disodium sulfosuccinate, disodium undecylenamide MEA sulfosuccinate, disodium undecylenamide PEG-2 sulfosuccinate, disodium undecylenyl glutamate, disodium monowheat germ oleoyl MEA sulfosuccinate, disodium monowheat germ oleoyl PEG-2 sulfosuccinate, disodium wheat germ oleoyl amphoteric acid, cocamide diacetate di-TEA salt, oleamide PEG-2 sulfosuccinate di-TEA salt, palmitoyl aspartate di-TEA salt, sodium tridecyl sulfosuccinate, dodecylbenzenesulfonic acid, erucamidopropyl hydroxysulfobetaine, ethylhexyl alcohol polyether-3 carboxylic acid, ethyl PEG-15 cocamide sulfate, caprylyl glyceryl ether, hexyl capric acid, hydrogenated coconut acid, hydrogenated lanolin alcohol polyether-25,Hydrogenated menhaden oil fatty acid, hydrogenated palmitoleic acid, hydrogenated palm kernel oil amine oxide, hydrogenated tallow acid, hydrogenated tallow amine oxide, hydrogenated tallow betaine, hydrogenated tallow alcohol polyether-25, hydrogenated tallow acyl glutamate, hydrogenated candida extract, hydroxycetyl alcohol polyether-60, hydroxyethyl acetoxymethyl ammonium PG-polydimethylsiloxane, laureth sulfate hydroxyethyl butylamine salt, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylauryl / hydroxymyristyl betaine, hydroxystearic acid, hydroxysuccinimide C10-40 isoalkanoate, hydroxysuccinimide C21-22 isoalkanoate, hydroxysultaine, IPDI / PEG-15 soybean oil amine oxide copolymer, IPDI / PEG-15 soybean oil amine ethanol methyl sulfate copolymer, IPDI / PEG-15 soybean oil glycine ester copolymer, lsoceteth-30, isolaureth-4 phosphate, isopolyglyceryl-3 polydimethylsiloxane, isopolyglyceryl-3 polydimethylsiloxane, isopropylamine lanolin acid ester, isopropylamine dodecylbenzenesulfonate, isostearamidopropylamine oxide, isostearamidopropyl betaine, isostearamidopropyl morpholine oxide, isosteareth-8, isosteareth-16, isosteareth-22, isosteareth-25, isosteareth-50, isostearic acid, isostearyl hydrolyzed collagen, jojoba oil PEG-150 esters, jojoba wax PEG-80 esters, jojoba oil PEG-120 esters of joba wax, lanolin alcohol polyether-20, lanolin alcohol polyether-25, lanolin alcohol polyether-40, lanolin alcohol polyether-50, lanolin alcohol polyether-60, lanolin alcohol polyether-75, lanolin acid, lauramide propylamine oxide, lauramide propyl betaine, lauramide propyl hydroxysulfobetaine, lauramine oxide, lauryl aminopropionic acid, lauryl dimethyl hydroxypropyl decyl glucoside ammonium chloride, lauryl dimethyl lauryl glucoside hydroxypropyl ammonium chloride, laureth-16, laureth-20, laureth-21, laureth-23, laureth-25, laureth-30, laureth-38, laureth-40, laureth-3 carboxylic acid, lauryl Alcohol polyether-4 carboxylic acid, laureth-5 carboxylic acid, laureth-6 carboxylic acid, laureth-8 carboxylic acid, laureth-10 carboxylic acid, laureth-11 carboxylic acid, laureth-12 carboxylic acid, laureth-13 carboxylic acid, laureth-14 carboxylic acid, laureth-17 carboxylic acid, laureth-6 citrate, laureth-7 citrate, laureth-1 phosphate, laureth-2 phosphate, laureth-3 phosphate, laureth-4 phosphate, laureth-7 phosphate, laureth-8 phosphate, laureth-7 tartrate, lauric acid, lauriminodipropylene glycol, lauriminodipropionic acid, lauroylamphodipropionic acid, lauroyl β-aminopropionic acid,Lauroyl collagen amino acid, lauroyl ethyltrimonium methosulfate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methyl glucamide, lauroyl sarcosine, lauroyl silk amino acid, lauryl betaine, lauryl dimethicone / polyglyceryl-3 crosspolymer, lauryl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, lauryl glucoside, lauryl glucoside hydroxypropyltrimonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysulfobetaine, lauryl malic acid amide, lauryl methyl glucosamine, (laury / myristic) glycol hydroxypropyl ether, (laury / myristic) wheat bran / straw glycosides, lauryl polyglyceryl-3 polydimethylsiloxyethyl polydimethicone, lauryl pyrrolidone, lauryl dimethyl Sultaine, Linoleic Acid, Linolenic Acid, Linolenic Acid, Lysine Cocoate, Macadamia Seed Oil Glyceryl Ether-8 Esters, Magnesium Cocoyl Sulfate, Magnesium Cocoyl Sulfate, Magnesium Isododecylphenyl Sulfonate, Magnesium Laureth-11 Carboxylate, Magnesium Laureth Sulfate, Magnesium Laureth-5 Sulfate, Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfonate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myristyl Sulfate, Magnesium Oleth Sulfate, Magnesium Cocoyl Sulfate / TEA, Manigold Root Glacial Mud, Coconut Oil MEA Salt, Laureth-6 Carboxylate MEA Salt, Laureth Sulfate MEA Salt, Moon Lauryl sulfate MEA salt, PPG-6-laureth-7 carboxylic acid MEA salt, PPG-8-stearyl alcohol polyether-7 carboxylic acid MEA salt, undecylenic acid MEA salt, meroxapol 108, meroxapol 174, meroxapol 178, meroxapol 254, meroxapol 255, meroxapol 258, meroxapol 314, methoxy PEG-450 amidoglutaryl succinamide, methoxy PEG-450 amidohydroxysuccinimide succinate, methoxy PEG-450 maleimide, methylmorpholine oxide, milk amide propylamine oxide, milk amide propyl betaine, mink oil amide propylamine oxide, mink oil amide propyl betaine, C12-15 alkyl alcohol polyether sulfate MIPA salt, dodeca MIPA salt of alkylbenzene sulfonate, MIPA salt of lauryl alcohol polyether sulfate, MIPA salt of lauryl alcohol sulfate, mixed isopropanolamine lanolin acid salt, mixed isopropanolamine lauryl sulfate, mixed isopropanolamine myristate, morpholine oleate, morpholine stearate, myristeth-3 carboxylic acid, myristeth-5 carboxylic acid, myristyl benzyl dimethyl ammonium chloride, myristamidopropylamine oxide, myristamidopropyl betaine, myristamidopropyl dimethylamine phosphate, myristamidopropyl hydroxysulfobetaine, myristamidopropyl PG-dimethyl ammonium chloride phosphate, myristamine oxide, myristyl aminopropionic acid, myristic acid, myristoyl ethyltrimethyl ammonium methyl sulfate, myristoyl glutamic acid, myristoyl hydrolyzed collagen,Myristoyl Sarcosine, Myristyl Betaine, Myristyl / Cetylamine Oxide, Myristyl Dimethyl Hydroxypropyl Cocoyl Glucoside Ammonium Chloride, Myristyl Glucoside, Myristyl Alcohol Phosphate, Nonylphenol Eth-20, Nonylphenol Eth-23, Nonylphenol Eth-25, Nonylphenol Eth-30, Nonylphenol Eth-35, Nonylphenol Eth-40, Nonylphenol Eth-44, Nonylphenol Eth-50, Nonylphenol Eth-100, Nonylphenol Eth-120, Nonylphenol Eth-5 Carboxylic Acid, Nonylphenol Eth-8 Carboxylic Acid, Nonylphenol Eth-10 Carboxylic Acid, Nonylphenol Eth-3 Phosphate, Nonylphenol Eth-4 Phosphate, Nonylphenol Eth-6 Phosphate, Nonylphenol Eth-9 Phosphate, Nonylphenol Eth-10 Phosphate, Dinonylphenol Polyether-30, dinonylphenol polyether-49, dinonylphenol polyether-100, dinonylphenol polyether-150, dinonylphenol polyether-7 phosphate, dinonylphenol polyether-8 phosphate, dinonylphenol polyether-9 phosphate, dinonylphenol polyether-10 phosphate, dinonylphenol polyether-11 phosphate, dinonylphenol polyether-15 phosphate, dinonylphenol polyether-24 phosphate, oat oil amidopropyl betaine, octylphenol polyether-16, octylphenol polyether-25, octylphenol polyether-30, octylphenol polyether-33, octylphenol polyether-40, octylphenol polyether-70, octylphenol polyether-20 carboxylic acid, octyldodecyl polyether-20, octyldodecyl polyether-25, octyldodecyl polyether-30, oleamidopropylamine oxide, oleamide Propyl Betaine, Oleamidopropyl (Hydroxysulfonyl)propyl Dimethyl Ammonium, Oleamine Oxide, Oleic Acid, Oleyl Hydrolyzed Collagen, Oleyl Sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleth-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Oleamidopropyl Betaine, Oleic Acid, Oleoyl Hydrolyzed Wheat Protein, Ophiopogon Japonicus Extract Stearate, Ozonoxigenated Oleth-10, Ozonoxigenated PEG-10 Oleate, Ozonoxigenated PEG-14 Oleate, Ozonoxigenated Polysorbate 8 0, Palmitoleic acid, palmitamidopropyl betaine, palmitoleyl alcohol polyether-2 phosphate, palmitamidopropylamine oxide, palmitamidopropyl betaine, palmitamine oxide, palmitic acid, palmitoyl collagen amino acids, palmitoyl glycine, palmitoyl hydrolyzed collagen, palmitoyl hydrolyzed milk protein, palmitoyl hydrolyzed wheat protein, palmitoyl keratin amino acids, palmitoyl oligopeptide, palmitoyl silk amino acids, palm kernel oleic acid, palm kernel oleamidopropyl betaine, peach kernel oil glyceryl polyether-8 esters, arachidic acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-50 castor oil, PEG-54 castor oil, PEG-55 castor oil, PEG-60 castor oil, PEG-80 castor oil,PEG-100 castor oil, PEG-200 castor oil, PEG-11 cocamide, PEG-6 cocamide phosphate, PEG-4 cocamide, PEG-8 cocamide, PEG-12 cocamide, PEG-150 dibehenate, PEG-90 diisostearate, PEG-75 dilaurate, PEG-150 dilaurate, PEG-75 dioleate, PEG-150 dioleate, PEG-75 distearate, PEG-120 distearate, PEG-150 distearate, PEG-175 distearate, PEG-190 distearate, PEG-250 distearate, PEG-30 glyceryl cocoate, PEG-40 glyceryl coconut oil Acid PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soybean Oleate, PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tallowate, PEG- PEG-80 glyceryl tallow ester, PEG-82 glyceryl tallow ester, PEG-130 glyceryl tallow ester, PEG-200 glyceryl tallow ester, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-30 hydrogenated lanolin, PEG-70 hydrogenated lanolin, PEG-50 hydrogenated palmitamide, PEG-2 isostearate, PEG-3 isostearate, PEG-4 isostearate, PEG-6 isostearate, PEG-8 isostearate, PEG -10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide,PEG-20 laurate, PEG-32 laurate, PEG-75 laurate, PEG-150 laurate, PEG-70 mango seed oil glycerides, PEG-20 mannide laurate, PEG-8 methyl ether polydimethylsiloxane, PEG-120 methyl glucose dioleate, PEG-80 methyl glucose laurate, PEG-120 methyl glucose trioleate, PEG-4 montanate, PEG-30 oleamine, PEG-20 oleate, PEG-23 oleate, PEG-32 oleate, PEG-36 oleate, PEG-75 oleate, PEG-150 oleate, PEG-20 palmitate, PEG-150 polyglyceryl-2 tristearate, PE PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG-10 / 30 Copolymer, PEG / PPG-10 / 65 Copolymer, PEG / PPG-12 / 35 Copolymer, PEG / PPG-16 / 17 Copolymer, PEG / PPG-20 / 9 Copolymer, PEG / PPG-20 / 20 Copolymer, PEG / PPG-20 / 60 Copolymer, PEG / PPG-20 / 65 Copolymer, PEG / PPG-22 / 25 Copolymer, PEG / PPG-28 / 30 copolymer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer, PEG / PPG-300 / 55 copolymer, PEG / PPG-20 / 22 methyl ether polydimethylsiloxane, PEG-26-PPG-30 phosphate, PEG / PPG-4 / 2 propyl heptyl ether, PEG / PPG-6 / 2 propyl heptyl ether, PEG-7 / PPG-2 Propyl Heptyl Ether, PEG / PPG-8 / 2 Propyl Heptyl Ether, PEG / PPG-10 / 2 Propyl Heptyl Ether, PEG / PPG-14 / 2 Propyl Heptyl Ether, PEG / PPG-40 / 2 Propyl Heptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glycerides, PEG-75 Sorbitan Cocoate,PEG-20 sorbitan isostearate, PEG-40 sorbitan lanolinate, PEG-75 sorbitan lanolinate, PEG-10 sorbitan laurate, PEG-40 sorbitan laurate, PEG-44 sorbitan laurate, PEG-75 sorbitan laurate, PEG-80 sorbitan laurate, PEG-20 sorbitan oleate, PEG-80 sorbitan palmitate, PEG-40 sorbitan stearate, PEG-60 sorbitan stearate, PEG-160 sorbitan triisostearate, PEG-40 soybean sterol, PEG-2 stearamide carboxylic acid, PEG-9 stearamide carboxylic acid, PE G-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG-120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallate, PEG-50 Tallowamide, PEG-2 Tallowamide DEA, PEG-20 Tallowamide, PEG-66 Trihydroxystearate Lipoic acid, PEG-200 trihydroxystearin, PEG-60 camellia oleate glyceride, nonanoic acid, pentadecylphenol polyether-200, phenol polyether-6 phosphate, poloxamer 105, poloxamer 108, poloxamer 182, poloxamer 183, poloxamer 184, poloxamer 188, poloxamer 217, poloxamer 234, poloxamer 235, poloxamer 237, poloxamer 238, poloxamer 288, poloxamer 334, poloxamer 335, poloxamer 338, poloxamer 908, poloxamer 1508, polydimethylsiloxy PEG / PPG-24 / 19 butyl ether silsesquioxane, polydimethylsiloxy PPG-13 butyl ether silsesquioxane, polyglyceryl Oil-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Laureth, Polyglyceryl-10 Laureth, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomaderris Kumerahou Flower / Leaf Extract, Poria Cocos Extract,Potassium abietic acid hydrolyzed collagen, potassium babassu oleate, potassium behenate, potassium C9-15 alcohol phosphate, potassium C11-15 alcohol phosphate, potassium C12-13 alcohol phosphate, potassium C12-14 alcohol phosphate, potassium caprate, potassium capryloyl glutamate, potassium capryloyl hydrolyzed rice protein, potassium ricinoleate, potassium cocoate, potassium cocoyl glutamate, potassium cocoyl glycinate, potassium cocoyl hydrolyzed casein, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin, potassium cocoyl hydrolyzed oat protein, potassium cocoyl hydrolyzed potato protein, potassium cocoyl hydrolyzed rice bran protein, potassium cocoyl hydrolyzed rice protein, potassium cocoyl hydrolyzed silk, potassium cocoyl hydrolyzed soy protein, potassium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed yeast protein, cocoyl PCA Potassium, Potassium Cocoyl Sarcosine, Potassium Cocoyl Taurine, Potassium Corn Oleate, Potassium Cyclopropyl Oleate, Potassium Dihydroxyethyl Cocoamine Oxide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecylbenzenesulfonate, Potassium Hemp Seed Oil, Potassium Hydrogenated Coconut Oil, Potassium Hydrogenated Palm Oleate, Potassium Hydrogenated Tallow, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolin Oleate, Potassium Laurate, Potassium Laureth-3 Carboxylate, Potassium Laureth-4 Carboxylate, Potassium Laureth-5 Carboxylate, Potassium Laureth-6 Carboxylate, Potassium Laureth-10 Carboxylate, Potassium Laureth Phosphate, Potassium Lauroyl Collagen Amino Acids, Potassium Lauroyl Glutamate, Potassium Lauroyl Hydrolyzed Collagen, Potassium Lauroyl Hydrolyzed Pea Protein, Potassium Lauroyl Hydrolyzed Soy Protein, Potassium Lauroyl PCA, Laury Potassium acyl pea amino acids, potassium lauroyl sarcosine, potassium lauroyl silk amino acids, potassium lauroyl wheat amino acids, potassium lauryl phosphate, potassium lauryl sulfate, potassium linoleate, potassium metaphosphate, potassium methyl cocoyl taurate, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octylphenol polyether-12 phosphate, potassium oleate, potassium oleoyl hydrolyzed collagen, potassium olivetate, potassium olivetate hydrolyzed oat protein, potassium olivetate hydrolyzed wheat protein, potassium olivetate / lauroyl wheat amino acids, potassium olivetate PCA, potassium palmitoleate, potassium palmitate, potassium palmitoyl hydrolyzed corn protein, potassium palmitoyl hydrolyzed oat protein, potassium palmitoyl hydrolyzed rice protein, potassium palmitoyl hydrolyzed sweet almond protein, potassium palmitoyl hydrolyzed wheat protein, palm kernel oleic acid Potassium, Potassium arachidate, Potassium rapeseed oleate, Potassium ricinoleate, Potassium safflower oleate, Potassium soybean oleate, Potassium stearate, Potassium stearoyl hydrolyzed collagen, Potassium tallowate, Potassium taurine, Potassium taurine laurate, Potassium trideceth-3 carboxylate, Potassium trideceth-4 carboxylate, Potassium trideceth-7 carboxylate, Potassium trideceth-15 carboxylate, Potassium trideceth-19 carboxylate, Potassium trideceth-6 phosphate, Potassium trideceth-7 phosphate, Potassium camellia oleate, Potassium undecylenate, Potassium undecylenyl hydrolyzed collagen, Potassium undecylenyl hydrolyzed rice protein, PPG-30-buteth-30, PPG-36-buteth-36, PPG-38-buteth-37, PPG-30-octanol polyether-4 phosphate,PPG-10 cetyl ether phosphate, PPG-2C9-11 alcohol polyether-8, PPG-1-decyl polyether-5, PPG-3-decyl polyether-2 carboxylic acid, PPG-30-ethylhexyl alcohol polyether-4 phosphate, PPG-20-glyceryl polyether-30, PPG-2 hydroxyethyl coconut oil / isostearamide, PPG-2-isodecyl alcohol polyether-8, PPG-2-isodecyl alcohol polyether-10, PPG-2-isodecyl alcohol polyether-18, PPG-2-isodecyl alcohol polyether-25, PPG-4-isodecyl alcohol polyether-10, propyltrimonium hydrolyzed collagen, quaternium-24, quaternium-52, quaternium-87, rapeseed oleic acid, rice bran acid, rice oil glyceryl polyether-8 esters, ricinoleic acid amidopropyl betaine, ricinoleic acid, ricinoleic acid polyether-40, safflower oleic acid, Sapindus Oahuensis fruit extract, Saponaria officinalis fruit extract Officinalis) root powder, saponins, potassium soap, sodium / potassium soap, soap base, potassium soap base, sesame oil glyceryl polyether-8 esters, sesame oil amidopropylamine oxide, sesame amidopropyl betaine, shea butter amidopropyl betaine, shea butter glyceryl polyether-8 esters, sodium arachidate, sodium arganoate, sodium arganoamphoacetate, sodium mururu palm oleate, sodium avocado oleate, sodium babassu oleoylamphoacetate, sodium babassu oleate, sodium babassu sulfate, sodium behenate, Sodium diethylene glycol ricinoleyl sulfosuccinate, sodium bis(hydroxyethyl)glycinate cocoyl glucoside cross-polymer, sodium bis(hydroxyethyl)glycinate lauryl glucoside cross-polymer, sodium borage oleamidopropyl PG-dimonium chloride phosphate, sodium butylphenol polyether-12 sulfate, sodium butyl glucoside hydroxypropyl phosphate, sodium C13-17 alkane sulfonate, sodium C14-18 alkane sulfonate, sodium C12-15 alkoxypropyl iminodipropionate, sodium C10-16 alcohol sulfate, sodium C11-15 alkyl sulfate, sodium C12 Sodium C-13 alkyl sulfate, sodium C12-15 alkyl sulfate, sodium C12-18 alkyl sulfate, sodium C16-20 alkyl sulfate, sodium C9-22 secondary alkyl sulfonate, sodium C14-17 secondary alkyl sulfonate, sodium caprate, sodium caprylate, sodium capryloylamphoacetate, sodium capryloylamphohydroxypropyl sulfonate, sodium capryloylamphopropionate, sodium capryloylmethyl taurate, sodium caprylate, sodium capryleth-2 carboxylate, sodium capryleth-9 carboxylate, sodium capryloylamphoacetate, sodium capryloylamphohydroxypropyl sulfonate, sodium capryloylamphopropionate, capryloylglutamate Disodium iodide, Sodium capryloyl hydrolyzed wheat protein, Sodium capryl PG-sulfonate, Sodium capryl sulfonate, Sodium ricinoleate, Sodium ceteareth-13 carboxylate, Sodium cetearyl sulfate, Sodium ceteth-13 carboxylate, Sodium cetyl sulfate, Sodium cocamidopropyl PG-dimonium chloride phosphate, Sodium cocoyl aminopropionate, Sodium cocoether sulfate, Sodium cocoether-30 sulfate, Sodium cocoamphoacetate, Sodium cocoa butter esters, Sodium cocoamphoacetate, Sodium cocoamphohydroxypropyl sulfonate,Sodium Cocoamphopropionate, Sodium Coconut Oil Acid, Sodium Cocoyl / Babassu / Andyraba Sulfate, Sodium Cocoyl / Babassu Sulfate, Sodium Cocoyl Glucoside Hydroxypropyl Phosphate, Sodium Cocoyl Glucoside Hydroxypropyl Sulfonate, Sodium Coco-Glucoside Tartrate, Sodium Cocoyl Glyceryl Ether Sulfonate, Sodium Cocoyl / Hydrogenated Tallow Alcohol Sulfate, Sodium Cocoiminodiacetate, Sodium Coco Monoglyceride Sulfate, Sodium Cocoyl Monoglyceride Sulfonate, Sodium Cocoyl PG-Dimethylammonium Chloride Phosphate, Sodium Cocoyl Sulfate, Sodium Cocoyl Sulfoacetate, Sodium Cocoyl Aminopropionate, Sodium Cocoyl Amino Acids, Sodium Cocoyl Collagen Amino Acids, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutamate, Sodium Cocoyl Glycinate, Sodium Cocoyl / Hydrogenated Tallow Glutamate , Sodium Cocoyl Hydrolyzed Collagen, Sodium Cocoyl Hydrolyzed Keratin, Sodium Cocoyl Hydrolyzed Rice Protein, Sodium Cocoyl Hydrolyzed Silk, Sodium Cocoyl Hydrolyzed Soy Protein, Sodium Cocoyl Hydrolyzed Sweet Almond Protein, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Isethionate, Sodium Cocoyl Methylaminopropionate, Sodium Cocoyl Oat Amino Acids, Sodium Cocoyl / Palmitoyl / Sunfloweroyl Glutamate, Sodium Cocoyl Proline, Sodium Cocoyl Sarcosinate, Sodium Cocoyl Taurine, Sodium Cocoyl Threonine, Sodium Cocoyl Wheat Amino Acids, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium Corn Amphoteric Propionate , Sodium cottonseed oil acyl amphoacetate, Sodium C13-15 pareth-8 butanol phosphate, Sodium C9-11 pareth-6 carboxylate, Sodium C11-15 pareth-7 carboxylate, Sodium C12-13 pareth-5 carboxylate, Sodium C12-13 pareth-8 carboxylate, Sodium C12-13 pareth-12 carboxylate, Sodium C12-15 pareth-6 carboxylate, Sodium C12-15 pareth-7 carboxylate, Sodium C12-15 pareth-8 carboxylate, Sodium C14-15 pareth-8 carboxylate, Sodium C12-14 secondary pareth-8 carboxylate, Sodium C14-15 pareth-PG sulfonate, Sodium C12-13 pareth-2 phosphate, Sodium C13-15 pareth-8 phosphate, C9-15 Sodium C10-15 polyether sulfate, sodium C10-16 polyether-2 sulfate, sodium C12-13 polyether sulfate, sodium C12-15 polyether sulfate, sodium C12-15 polyether sulfate, sodium C12-15 polyether-3 sulfate, sodium C13-15 polyether-3 sulfate, sodium C12-14 secondary polyether-3 sulfate, sodium C12-15 polyether-3 sulfonate, sodium C12-15 polyether-7 sulfonate, sodium C12-15 polyether-15 sulfonate, sodium deceth-2 carboxylate, sodium deceth sulfate, sodium decylbenzene sulfonate, sodium decyl glucoside hydroxypropyl phosphate, sodium decyl glucoside hydroxypropyl sulfonate, sodium di(laureth-7) citrate, sodium di(laureth-10) phosphate,Sodium dilinoleamidopropyl PG-dimonium chloride phosphate, sodium dimer dimer linoleate, sodium dioleth-8 phosphate, sodium dodecylbenzene sulfonate, sodium 2-ethyl sulfolaurate, sodium glyceryl oleate phosphate, sodium grapeseed oleamidopropyl PG-dimonium chloride phosphate, sodium grapeseed oleoylamphoacetate, sodium grapeseed oleoyl acid, sodium hexyl alcohol polyether-4 carboxylate, sodium hydrogenated coconut oil, sodium hydrogenated coconut oil methyl isethionate, sodium hydrogenated palm oleate, sodium hydrogenated tallow acid, sodium hydrogenated tallow glutamate, sodium hydroxylauryldimonium ethyl phosphate, sodium palm kernel hydroxypropyl sulfonate, sodium hydroxypropyl decyl glucoside crosspolymer, sodium hydroxypropyl lauryl glucoside crosspolymer, sulfonic acid Sodium Hydroxypropyl Cocoyl Glucoside Crosspolymer, Sodium Hydroxypropyl Decyl Glucoside Sulfonate Crosspolymer, Sodium Hydroxypropyl Lauryl Glucoside Sulfonate Crosspolymer, Sodium Hydroxystearate, Sodium Isostearate, Sodium Isosteareth-6 Carboxylate, Sodium Isosteareth-11 Carboxylate, Sodium Isostearylamphoacetate, Sodium Isostearylamphopropionate, Sodium N-Isostearyl Methyl Taurate, Sodium Lanolin Sulfate, Sodium Lanolin Acid, Sodium Lardate, Sodium Lauramidodiacetate, Sodium Lauryl Aminopropionate, Sodium Laurate, Sodium Laureth-3 Carboxylate, Sodium Laureth-4 Carboxylate, Sodium Laureth-5 Carboxylate, Sodium Laureth-6 Carboxylate, Sodium Laureth-8 Carboxylate, Sodium Laureth-11 Carboxylate, Sodium Laureth-12 Carboxylate , Sodium Laureth-13 Carboxylate, Sodium Laureth-14 Carboxylate, Sodium Laureth-16 Carboxylate, Sodium Laureth-17 Carboxylate, Sodium Laureth Sulfate, Sodium Laureth-5 Sulfate, Sodium Laureth-7 Sulfate, Sodium Laureth-8 Sulfate, Sodium Laureth-12 Sulfate, Sodium Laureth-40 Sulfate, Sodium Laureth-7 Tartrate, Disodium Lauriminodipropionate, Sodium Lauroamphoacetate, Sodium Lauroamphohydroxypropylsulfonate, Sodium Lauroampho PG-acetate Phosphate, Sodium Lauroamphopropionate, Sodium Lauroyl Aspartate, Sodium Lauroyl Collagen Amino Acids, Sodium Lauroyl Glycine Propionate, Sodium Lauroyl Hydrolyzed Collagen, Sodium Lauroyl Hydrolyzed Silk, Lauroyl Hydroxypropyl Sodium Lauroyl Isethionate, Sodium Lauroyl Methylaminopropionate, Sodium Lauroyl Methyl Isethionate, Sodium Lauroyl Millet Amino Acids, Sodium Lauroyl / Myristoyl Aspartate, Sodium Lauroyl Oat Amino Acids, Sodium Lauroyl Sarcosinate, Sodium Lauroyl Silk Amino Acids, Sodium Lauroyl Taurate, Sodium Lauroyl Wheat Amino Acids, Sodium Lauryl Di (Ethylenediamino) Glycine, Sodium Lauryl Glucose Carboxylate, Sodium Lauryl Glucoside Hydroxypropyl Phosphate, Sodium Lauryl Glucoside Hydroxypropyl Sulfonate, Sodium Lauryl Glycol Carboxylate, Sodium Lauryl Glycol Sulfate, Disodium Lauryl Phosphate, Sodium Lauryl Sulfate, Sodium Lauryl Sulfoacetate, Sodium Linoleate, Sodium Macadamia Seed Oil Acid, Sodium Mango Amphoacetate, Sodium Mango Seed Oil Esters,Sodium Laureth-2 Sulfosuccinate / MEA, Sodium Methoxy PPG-2 Acetate, Sodium Methyl Cocoyl Taurate, Sodium Methyl Lauroyl Taurate, Sodium Methyl Myristoyl Taurate, Sodium Methyl Oleoyl Taurate, Sodium Methyl Palmitoyl Taurate, Sodium Methyl Stearoyl Taurate, Sodium Methyl 2-Sulfolaurate, Sodium Methyl 2-Sulfopalmitate, Sodium Isopalmitoyl Methyl Taurate, Sodium Methyl Cocoyl Methyl Taurate, Sodium Myristeth Sulfate, Sodium Myristate, Sodium Myristoyl Amphoacetate, Sodium Myristoyl Glutamate, Myristoyl Water Sodium decollagen, Sodium myristoyl isethionate, Sodium myristoyl sarcosinate, Sodium myristyl sulfate, Sodium nonoxynol 6 phosphate, Sodium nonoxynol 9 phosphate, Sodium nonoxynol 1 sulfate, Sodium nonoxynol 3 sulfate, Sodium nonoxynol 4 sulfate, Sodium nonoxynol 6 sulfate, Sodium nonoxynol 8 sulfate, Sodium nonoxynol 10 sulfate, Sodium nonoxynol 25 sulfate, Sodium octylphenol 2 ethanesulfonate, Sodium octylphenol 2 sulfate, Sodium octylphenol 6 sulfate, Sodium octylphenol 9 sulfate Sodium ester, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropyl sulfonate, sodium oleoamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl isethionate, sodium oleyl polyether sulfate, sodium oleoyl methyl isethionate, sodium oleyl sulfate, sodium oliveoamphoacetate, sodium olive oil, sodium oliveoyl glutamate, sodium palmitoleoamphoacetate, sodium palmitoleate, sodium palmitoleyl glyceride sulfonate, sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat protein, sodium palmitoyl sarcosine, sodium palm kerneloleate, sodium palmitoleoyl isethionate, palm Sodium Oleoyl Glutamate, Sodium Passionflower Seed Oil, Sodium Peanut Amphoacetate, Sodium Peanut Acid, Sodium PEG-6 Cocoamide Carboxylate, Sodium PEG-8 Cocoamide Carboxylate, Sodium PEG-4 Cocoamide Sulfate, Sodium PEG-3 Lauramide Carboxylate, Sodium PEG-4 Lauramide Carboxylate, Sodium PEG-8 Palm Glycerides Carboxylate, Sodium Pentaerythrityl Hydroxypropyliminodiacetate Dendrimer, Sodium Propoxy PPG-2 Acetate, Sodium Rapeseed Oil, Sodium Rice Bran Amphoacetate, Sodium Ricinoleate, Sodium Ricinole Amphoacetate, Sodium Rose Hipsamphoacetate, Sodium Rosinate, Sodium Safflower Oleate, Sodium Saffloweroyl Hydrolyzed Soy Protein, Sodium Sesame Seed Oleate, Sodium Sesame Amphoacetate, Sodium Shea Butter Amphoacetate, Sodium Soy Oleate, Sodium Soy Hydrolyzed Collagen, Sodium Stearate, Sodium Stearoyl Amphoacetate, Sodium Stearoyl Amphopropyl Sulfonate, Sodium Stearoyl Amphopropionate, Sodium Stearoyl Casein, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl Hydrolyzed Silk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Whey Protein, Sodium Stearoyl Methyl Isethionate, Sodium Stearoyl Oat Protein,Sodium stearoyl pea protein, sodium stearoyl soy protein, sodium stearyl dimethyl glycinate, sodium stearyl sulfate, sodium sunflower seed oil acyl amphoacetate, sodium subtilisin, sodium sweet almond oil acyl amphoacetate, sodium sweet almond oil acid, sodium tallow acyl propionate, sodium tallow acid, sodium tallow acyl acetate, sodium tallow acid, sodium tallow alcohol sulfate, sodium callophyllum (CALLOPHYLLUMINOPHYLLUM) seed oil acid, sodium taurine, sodium cocoyl methyl taurate taurate, laurel Sodium taurate, sodium lauroyl collagen amino acid / TEA salt, sodium lauroyl hydrolyzed collagen / TEA salt, sodium lauroyl hydrolyzed keratin / TEA salt, sodium lauroyl keratin amino acid / TEA salt, sodium undecylenyl collagen amino acid / TEA salt, sodium undecylenyl hydrolyzed collagen / TEA salt, sodium undecylenyl hydrolyzed corn protein / TEA salt, sodium undecylenyl hydrolyzed soy protein / TEA salt, sodium undecylenyl hydrolyzed wheat protein / TEA salt, Theobroma grandiflora Grandiflorum) seed oil sodium, sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium trideceth sulfate, sodium tridecylbenzene sulfonate, sodium tridecyl sulfate, sodium trimethylolpropane hydroxypropyl iminodiacetic acid dendrimer Compounds, sodium undecylene-5 carboxylate, sodium undecylenate, sodium undecylenylamphoacetate, sodium undecylenylamphopropionate, disodium undecylenyl glutamate, sodium wheat germ oleylamphoacetate, sorbitan polyether-160 tristearate, soybean oleic acid, soybean amidopropylamine oxide, soybean amidopropyl betaine, soybean glyceryl polyether-8 esters, stearamidopropylamine oxide, stearamidopropyl betaine, stearamine oxide, steareth-15, stearyl alcohol polyether Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyltrimonium Chloride, Stearoyl Glutamic Acid, Stearoyl Sarcosine, Stearyl Betaine, Stearyl Dimethyl Butyl Glucoside Hydroxypropyl Ammonium Chloride, Stearic Acid, Lipoic acid dimethyl decyl glucoside hydroxypropyl ammonium chloride, stearyl dimethyl lauryl glucoside hydroxypropyl ammonium chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower oleamide MEA, sunflower oil acid, sunflower oil amidopropyl hydroxyethyl dimonium chloride, sunflower oil glyceryl polyether-8 esters, tallow acid, tallow acid, tallow amidopropylamine oxide, tallow amidopropyl betaine, tallow amidopropyl hydroxysulfonate,Tallowamine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallow ethyl glucoside, abietic hydrolyzed collagen TEA salt, C12-14 alcohol phosphate TEA salt, C10-15 alkyl sulfate TEA salt, C11-15 alcohol sulfate TEA salt, C12-13 alkyl sulfate TEA salt, TEA-C12-14 alkyl sulfate TEA salt, TEA-C12-15 alkyl sulfate TEA salt, TEA C14-17 secondary alkyl sulfonate TEA salt, canola oil TEA salt, cocamide diacetate TEA salt, coconut oil acid TEA salt, coconut oil alcohol sulfate TEA salt, cocoyl alanine TEA salt, cocoyl glutamate TEA salt, cocoyl glutamine TEA salt, cocoyl glycine TEA salt, cocoyl hydrolyzed collagen TEA salt, cocoyl hydrolyzed soy protein TEA salt, cocoyl sarcosine TEA salt, polydimethylsiloxane PEG-7 phosphate TEA salt, dodecylbenzene sulfonate TEA salt, hydrogenated coconut acid TEA salt, hydrogenated tallow glutamate TEA salt, isostearic acid TEA salt, TEA-Isostearyl Hydrolyzed Collagen TEA Salt, Lauryl Amine Propionic Acid TEA Salt, Lauric Acid TEA Salt, Lauric Acid / Myristic Acid TEA Salt, Laureth Sulfate TEA Salt, Lauroyl Collagen Amino Acid TEA Salt, Lauroyl Glutamate TEA Salt, Lauroyl Hydrolyzed Collagen TEA Salt, Lauroyl Keratin Amino Acid TEA Salt, Lauroyl Methylaminopropionic Acid TEA Salt, Lauroyl / Myristoyl Aspartic Acid TEA Salt, Lauroyl Sarcosine TEA Salt, Lauryl Phosphate TEA Salt, Lauryl Sulfate TEA Salt, Myristyl Amine Propionic Acid TEA Salt, Myristyl Acid TEA Salt, Myristoyl Hydrolyzed Collagen TEA salt, TEA oleate, TEA oleoyl hydrolyzed collagen, TEA oleoyl sarcosine, TEA oleyl sulfate, TEA palmitate, TEA palm kernel sarcosine, TEA PEG-3 cocamide sulfate, TEA rosinate, TEA stearate, TEA tallate, TEA tridecylbenzenesulfonate, TEA undecylenate, TEA undecylenate hydrolyzed collagen, tetramethyldecynediol, tetrasodium dicarboxyethyl stearyl sulfosuccinamate, TIPA laureth sulfate, TIPA lauryl sulfate, TIPA myristic acid, TIPA stearate, Tocopheryl phosphate, trehalose undecylenate, TM-C12-15 pareth-2 phosphate, TM-C12-15 pareth-6 phosphate, TM-C12-15 pareth-8 phosphate, TM-C12-15 pareth-10 phosphate, trideceth-20, trideceth-50, trideceth-3 carboxylic acid, trideceth-4 carboxylic acid, trideceth-7 carboxylic acid, trideceth-8 carboxylic acid, trideceth-15 carboxylic acid, trideceth-19 carboxylic acid, trideceth-10 phosphate, tridecylbenzenesulfonic acid, trilaureth-9 citrate,Trimethylolpropane Hydroxypropyl Bis(hydroxyethyl)amine Dendrimer, Sodium Tri(lauroampho PG-acetate chloride) Phosphate, Undecanoic Acid, Undeceth-5 Carboxylic Acid, Undecylenamidopropylamine Oxide, Undecylenamidopropyl Betaine, Undecylenic Acid, Undecylenyl Collagen Amino Acids, Undecylenyl Glycine, Undecylenyl Hydrolyzed Collagen, Undecylenyl Wheat Amino Acids, Undecyl Glucoside, Wheat Germ Oleic Acid, Wheat Germ Oleic Acid, Wheat Germ Oleic Acid, Wheat Germ Oleic Acid, Wheat Germ Oleic Acid, Yucca Schidigera Leaf / Root / Stem Extract, Yucca Schidigera Stem Extract, Zinc Cocoeth Sulfate and Zinc Cocoyl Sulfate. Nonionic surfactants

[0082] Alcohol alkoxylates. The added nonionic surfactants are preferably alkoxylated and / or propoxylated, particularly preferably primary alcohols containing 8 to 18 carbon atoms and an average of 1 to 12 mol of ethoxy groups (EO) and / or 1 to 10 mol of propoxy groups (PO) per mol of alcohol. Particularly preferred are C8-C9 alcohols having a degree of ethoxylation of 2 to 10, preferably 3 to 8, and / or a degree of propoxylation of 1 to 6, preferably 1.5 to 5. 16 - alcohol alkoxylates, advantageously ethoxylates and / or propoxylates C 10 -C 15 - alcohol alkoxylates, especially C 12 -C 14 Alcohol alkoxylates. The stated degrees of ethoxylation and propoxylation constitute statistical averages which may be integers or fractions for a particular product. Preferred alcohol ethoxylates and propoxylates have a narrow homolog distribution (narrow range ethoxylates / propoxylates, NRE / NRP). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples are (tallow) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO.

[0083] Alkyl glycoside In addition, as an additional nonionic surfactant, a surfactant satisfying the general formula RO(G) may be added x Alkyl glycosides, for example as compounds, in particular together with nonionic surfactants, wherein R is a linear or methyl-branched, especially 2-methyl-branched, aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms, and G represents a monosaccharide unit having 5 or 6 carbon atoms, preferably glucose. The degree of glycosylation x, which defines the distribution of mono- and oligoglycosides, is a value between 1 and 10, preferably between 1.1 and 1.4.

[0084] Fatty acid ester alkoxylates. Another preferred class of nonionic surfactants, which are used either as the sole nonionic surfactant or in combination with other nonionic surfactants, in particular with alkoxylated fatty alcohols and / or alkyl polyglycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably containing 1 to 4 carbon atoms in the alkyl chain, more particularly fatty acid methyl esters, such as described in Japanese patent application JP-A-58 / 217598 or preferably prepared by the process described in international patent application WO-A-90 / 13533. Particularly preferred are fatty acid methyl esters containing an average of 3 to 15 EOs, in particular containing about 5 to 12 EOs. 12 -C 18 Fatty acid methyl esters.

[0085] Amine oxides. Nonionic surfactants of the amine oxide type, such as N-coconut alkyl-N,N-dimethylamine oxide and N-tallow alkyl-N,N-dihydroxyethylamine oxide, and fatty acid alkanolamide type are also suitable. The amount of these nonionic surfactants is preferably not more than the amount of ethoxylated fatty alcohols, especially not more than half of the amount thereof.

[0086] Gemini surfactants. Other surfactants are so-called gemini surfactants. This class of compounds is generally understood to mean compounds which contain two hydrophilic groups and two hydrophobic groups per molecule. These groups are usually separated from one another by a "spacer". This spacer is usually a carbon chain, the length of which should be sufficient to allow the hydrophilic groups to have sufficient distance to act independently of one another. This class of surfactants is generally characterized by a very small critical concentration and a great reduction in the surface tension of water. In special cases, however, gemini surfactants refer not only to dimerization but also to trimerization surfactants. Suitable gemini surfactants are, for example, the sulfated hydroxy mixed ethers of German patent application DE 4321022 A1, or dimer alcohol-di- and trimer alcohol-tri-sulfates and -ether sulfates according to international patent application 96 / 23768 A1. According to German patent application DE 19513391 A1, the end-capped dimer and trimer mixed ethers are characterized by their difunctionality and polyfunctionality. It is also possible to use gemini polyhydroxy fatty acid amides or polyhydroxy fatty acid amides such as those described in International Patent Applications WO 95 / 19953 A1, WO 95 / 19954 A1 and WO 95 / 19955 A1. Cationic surfactants

[0087] Tetraalkyl quaternary ammonium salts. Cationic surfactants in aqueous solution contain hydrophobic polymer groups required for surface activity in dissociated cations. An important representative of cationic surfactants is the general formula (R 1 R 2 R 3 R 4 N+ )X - A tetraalkyl quaternary ammonium salt. 1 represents C1-C8 alkane (alkenyl), R 2 , R 3 and R 4 Independently represent an alkane (enyl) group containing 1 to 22 carbon atoms. X is a counter ion, preferably selected from halogen, alkyl sulfate and alkyl carbonate. Particularly preferred are cationic surfactants, wherein the nitrogen atom is substituted by two long acyl groups and two short alkane (enyl) groups.

[0088] Esterquats. Cationic surfactants used in particular as auxiliary surfactants according to the invention are represented by the esterquats. Esterquats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of preparative organic chemistry. Reference can be made to the international patent application WO 91 / 01295 A1, in which triethanolamine is partially esterified with fatty acids in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate or ethylene oxide. In addition, German patent DE 4308794 C1 describes a method for preparing solid esterquats, in which the quaternization of the triethanolamine ester is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0089] A typical example of an esterquat suitable for use according to the invention is a product whose acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, wherein RCO is an acyl group containing 6 to 10 carbon atoms, and the amino component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof, such as, for example, so-called head fractionated fatty acids. Preferably used are esterquats whose acyl component is derived from monocarboxylic acids containing 8 to 10 carbon atoms. Other esterquats are those products whose acyl component is derived from dibasic carbonic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. Overall, esterquats whose acyl group is derived from a mixture of monocarboxylic acids containing 6 to 22 carbon atoms and adipic acid are preferred. The molar ratio of monocarboxylic acid to dicarboxylic acid in the finished esterquat is from 1:99 to 99:1 and preferably from 50:50 to 90:10 and in particular from 70:30 to 80:20. In addition to quaternized fatty acid triethanolamine ester salts, other suitable esterquats are mono / dicarboxylic acid mixtures with diethanolalkylamine or 1,2-dihydroxypropyldialkylamine. Esterquats can be obtained by mixing fatty acids and the corresponding triglycerides with the corresponding dicarboxylic acids. A process of this type, which can be regarded as representative of the relevant prior art, is described in European patent EP 0750606 B1. To produce the quaternized esters, the mixture of mono- and dicarboxylic acids and triethanolamine can be in a molar ratio of 1.1:1 to 3:1, based on the available carboxyl functions. In view of the properties of the esterquats, a ratio of 1.2:1 to 2.2:1 and preferably 1.5:1 to 1.9:1 has proven to be particularly advantageous. Preferred esterquats are technical mixtures of mono-, di- and triesters having an average degree of esterification of 1.5 to 1.9. Amphoteric surfactant

[0090] Betaines. Amphoteric or zwitterionic surfactants have various functional groups which can be ionized in aqueous solution and thus - depending on the medium conditions - give the compound anionic or cationic properties (see DIN 53900, July 1972). Close to the isoelectric point (approximately pH 4), amphoteric surfactants form inner salts and thus become poorly soluble or insoluble in water. Amphoteric surfactants are subdivided into amphoterics and betaines, the latter behaving as zwitterions in solution. Amphoterics are amphoteric electrolytes, i.e. compounds which have both acidic and basic hydrophilic groups and therefore behave as acids or bases depending on the conditions. In particular, betaines are known surfactants which are mainly produced by carboxylalkylation, preferably carboxymethylation, of amine compounds. The starting materials are preferably condensed with halogenated carboxylic acids or salts thereof, in particular sodium chloroacetate, forming one mole of salt per mole of betaine. The addition of unsaturated carboxylic acids, such as acrylic acid, is also possible. Examples of suitable betaines are carboxylalkylation products of secondary amines, in particular tertiary amines, which correspond to the general formula R 1 R2 R 3 N-(CH2) q COOX, where R 1 is an alkyl group having 6 to 22 carbon atoms, R 2 is hydrogen or an alkyl group containing 1 to 4 carbon atoms, R 3 is an alkyl group containing 1 to 4 carbon atoms, q is a number from 1 to 6, and X is an alkali and / or alkaline earth metal or ammonium. Typical examples are hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, C 12 / 14 - Coconut alkyl dimethylamine, myristyl dimethylamine, cetyl dimethylamine, stearyl dimethylamine, stearyl ethyl methylamine, oleyl dimethylamine, C 16 / 18 - tallow alkyldimethylamines and technical mixtures thereof and, in particular, the carboxymethylation products of dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine and technical mixtures thereof.

[0091] Alkylamidobetaines. Other suitable betaines are the carboxyalkylation products of amidoamines, which correspond to the general formula R 1 CO(R 3 )(R 4 )-NH-(CH2) p -N-(CH2) q COOX, where R 1 CO is an aliphatic acyl group having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, R 2 is hydrogen or an alkyl group having 1 to 4 carbon atoms, R 3 is an alkyl radical having 1 to 4 carbon atoms, p is a number from 1 to 6, q is a number from 1 to 3, and X is an alkali and / or alkaline earth metal or ammonium. Typical examples are fatty acids having 6 to 22 carbon atoms, such as caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, eleostearic acid, arachidonic acid, cis(9)-eicosenoic acid, behenic acid, erucic acid and technical mixtures thereof, with N,N-dimethylaminoethylamine, N,N-dimethylaminopropylamine, N,N-diethylaminoethylamine and N,N-diethylaminopropylamine, which are condensed with sodium chloroacetate. Commercially available products include K and PK (Cognis Deutschland GmbH & Co., KG) and Betaine (Goldschmidt).

[0092] Other suitable starting materials for the betaines for the purposes of the present invention are imidazolines. These substances are also known and can be prepared, for example, by 1 or 2 mol of C6-C 22 The cyclocondensation of fatty acids with polyfunctional amines such as aminoethylethanolamine (AEEA) or diethylenetriamine is obtained. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are the condensation products of the above-mentioned fatty acids with AEEA, preferably imidazolines based on lauric acid, which are subsequently betained with sodium chloroacetate. Commercially available products include G (Cognis Deutschland GmbH & Co., KG).

[0093] The (co)surfactants are preferably used in the compositions of the invention in an amount of 0.1 to 90% by weight, in particular 10 to 80% by weight and particularly preferably 20 to 70% by weight. Organic solvents

[0094] Liquid light or heavy-duty detergents may contain organic solvents, preferably those that are miscible with water. Polyglycols, ethers, alcohols, ketones, amides and / or esters are preferably used as organic solvents in an amount of 0 to 90% by weight, preferably 0.1 to 70% by weight, in particular 0.1 to 60% by weight. Low molecular weight polar substances are preferred, for example methanol, ethanol, propylene carbonate, acetone, acetonylacetone, diacetone alcohol, ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, glycerine, diethylene glycol, dipropylene glycol monomethyl ether and dimethylformamide or mixtures thereof. Enzymes

[0095] Cellulase. Optionally, cellulase is incorporated into the detergent composition, and when used, it is preferably incorporated into the composition at a level sufficient to provide up to about 5 mg, more preferably from about 0.01 mg to about 3 mg of active enzyme per gram of composition. Unless otherwise stated, the present composition preferably contains from about 0.001% to about 5% by weight, preferably 0.01%-1% by weight of a commercial enzyme preparation.

[0096] Cellulases suitable for use in the present invention include bacterial or fungal cellulases. Preferably, they have an optimal pH range of 5-9.5. Suitable cellulases are fungal cellulases produced by Humicola insolens and Humicola strain DSM1800 or cellulases 212 produced by fungi belonging to the genus Aeromonas, and cellulases extracted from the hepatopancreas of marine molluscs (DolabellaAuricula Solander), and suitable cellulases are also disclosed in GB 2,075,028A. In addition, cellulases particularly suitable for use in the present invention are disclosed in WO 1992 013057 A1. Most preferably, cellulases used in the present detergent composition are commercially available from NOVO Industries A / S under the product names CAREZYME and CELLUZYME.

[0097] Other enzymes. In order to achieve various purposes of washing fabrics, including, for example, removing protein, carbohydrate or triglyceride stains, and in order to avoid the migration of dyes that come off and for the recovery of fabrics, other enzymes may be included in the detergent composition of the present invention. Other enzymes that may be incorporated include proteases, amylases, lipases and peroxidases, and mixtures thereof. Other types of enzymes may also be included. They may be of any suitable origin, such as plant, animal, bacterial, fungal and yeast origin. However, their selection is determined by several factors, such as pH-activity and / or stability optimum, thermostability, stability against active detergents and builders, and the possibility that they produce odors in use. In this respect, bacterial or fungal enzymes are preferred, such as bacterial amylases and proteases.

[0098] Enzymes are normally incorporated at a level sufficient to provide up to about 5 mg by weight, more typically about 0.01 mg to about 3 mg, of active enzyme per gram of the composition. Unless otherwise specified, the compositions herein typically contain from about 0.001% to about 5%, preferably 0.01% to 1%, by weight of a commercial enzyme preparation. Protease enzymes are usually present in such commercial preparations at levels providing from 0.005 to 0.1 Anson units (AU) of activity per gram of the composition.

[0099] Examples of suitable proteases are subtilisin, which is obtained from special strains of Bacillus subtilis and Bacillus licheniformis. Another suitable protease is obtained from a strain of Bacillus sp., which has maximum activity in the pH range of 8-12, and is developed and sold by Novo Industries A / S under the registered trade name The preparation of this and similar enzymes is described in British Patent No. 1,243,784 to Novo. Commercially available proteolytic enzymes suitable for removing proteinaceous stains include those sold under the trade name ANTI-PROTEINASE by Novo Industries A / S. and and sold by International Bio-Synthitics, Inc. Other proteases include Protease A, Protease B and Protease produced by Genencor International, Inc. according to US Pat. No. 5,204,015 and US Pat. No. 5,244,791.

[0100] Amylases include, for example, α-amylases such as International Bio-Synthetics, Inc., and Novo Industries.

[0101] Suitable lipase enzymes for detergent use include those produced by microorganisms of the Pseudomonas group, such as Pseudomonas stutzeri ATCC 19154. Such lipases are available from Amano Pharmaceutical Co. Ltd. Nagoya, Japan, under the trade name Lipase P "Amano". Other commercially available lipases include Amano-CES, lipase ex Chromobacter viscosum, e.g., Chromobacter viscosum varlipolyticum NRRLB 3673, commercially available from Toyo Jozo Co.; and other Chromobacter viscosum lipases sold by USBiochemical Corp. and Disoynth Co., and lipase ex Pseudomonas gladioli. Obtained from Humicola lanuginosa (commercially available from Novo Industries A / S) The enzyme is preferably lipase herein.

[0102] Peroxidases are used in combination with oxygen sources, such as percarbonate, perborate, persulfate, hydrogen peroxide, etc. They are used for "solution bleaching", i.e. to prevent dyes or pigments that come off from a substrate from migrating to other substrates in the washing solution during the washing process. Peroxidases are known in the art and include, for example, horseradish peroxidase, ligninase, and haloperoxidase, such as chloro- and bromo-peroxidase. Detergent compositions containing peroxidases are disclosed in, for example, WO1989 099813 A1.

[0103] Enzyme stabilizers. The enzymes used herein may be stabilized by water-soluble calcium and / or magnesium ion sources present in the finished detergent composition (which provide these ions to the enzymes). (Calcium ions are generally more effective than magnesium ions, and calcium ions are preferably used herein if only one such cation is used). Other stability can be obtained by the presence of stabilizers disclosed in various other prior art, especially borates, see US 4,537,706, which is cited in its entirety. Typical detergents, especially liquid detergents, contain from about 1 to about 30, preferably from about 2 to about 20, more preferably from about 5 to about 15, and most preferably from about 8 to about 12 millimoles of calcium ions per liter of finished composition. In solid detergent compositions, the formulation may contain a sufficient amount of a water-soluble calcium ion source to provide the amount of material required in the laundry water solution. On the other hand, the hardness of natural water is sufficient.

[0104] It should be recognized that the content of the above calcium and / or magnesium ions is sufficient to ensure enzyme stability. More calcium and / or magnesium ions can be added to the composition to provide other means of removing grease. Therefore, the common formulation of the composition of the present invention can contain about 0.05% by weight to about 2% by weight of a water-soluble calcium or magnesium ion source, or contain both simultaneously. Of course, this amount can vary with the quantity and type of the enzyme used in the composition.

[0105] The compositions of the present invention may also optionally, but preferably, contain various other stabilizers, particularly borate-type stabilizers. Typically, such stabilizers are used in the composition in an amount of from about 0.25% to about 10% by weight, preferably from about 0.5% to about 5% by weight, more preferably from about 0.75% to about 3% by weight, based on the weight of boric acid or other borate compounds capable of forming boric acid in the composition (based on boric acid). Although other compounds, such as boric oxide, borax, and other alkali metal borates (e.g., sodium orthoborate, sodium metaborate, sodium pyroborate, and sodium pentaborate) are suitable, boric acid is preferred. Substituted boric acids (e.g., phenylboric acid, butaneboric acid, and p-bromophenylboric acid) may also be used in place of boric acid. Detergent

[0106] Zeolites. Fine-crystalline synthetic zeolites containing bound water, preferably zeolite A and / or zeolite P, can be used as detergent builders. Particularly preferred zeolite P is zeolite MAP.RTM. (a commercial product from Crosfield). However, zeolite X and mixtures of zeolites A, X, Y and / or P are also suitable. Particularly preferred is zeolite P sold under the trade name zeolite MAP.RTM. Co-crystallized sodium / potassium aluminosilicate of zeolite A and zeolite X available as zeoliteX® RX (commercial product of Condea Augusta SpA). Preferably, the zeolite can be used in the form of a spray-dried powder. In the case of the zeolite being added in the form of a suspension, a small amount of a nonionic surfactant can be added as a stabilizer, for example 1 to 3% by weight, based on the zeolite, of an ethoxylated C 60 having 2 to 5 ethoxy groups. 12 -C 18 Fatty alcohols, C 12 -C 14 Fatty alcohol or ethoxylated isotridecanol. Suitable zeolites have an average particle size of less than 10 μm (measurement method: volume distribution Coulter counter) and preferably contain 18 to 22% by weight, more preferably 20 to 22% by weight of bound water. In addition, phosphates can also be used as builders.

[0107] Layered silicates. Suitable alternatives or partial alternatives to phosphates and zeolites are crystalline, layered sodium silicates. Such crystalline layered sodium silicates are described, for example, in European patent application EP 0164514 A1. Preferred crystalline layered silicates are those obtained, for example, by the process described in international patent application WO 91 / 08171 A1.

[0108] Amorphous silicates. Preferred builders also include amorphous sodium silicates with a modulus (Na2O:SiO2 ratio) of 1:2 to 1:3.3, preferably 1:2 to 1:2.8 and more preferably 1:2 to 1:2.6, which have the characteristics of delayed dissolution and multiple cycle washing. Compared with traditional amorphous sodium silicates, this delayed dissolution characteristic can be obtained in various ways, such as by surface treatment, compounding, densification / compression or by overdrying. Within the scope of the present invention, the term "amorphous" also refers to "X-ray amorphous". In other words, in an X-ray diffraction test, the silicate does not produce any typical X-ray reflections of a crystalline substance, but at best has one or more peaks of scattered X-rays, which have a width of a diffraction angle of several degrees. However, when the silicate particles produce inconspicuous or even clear diffraction peaks in an electron diffraction test, particularly good builder properties can be achieved. This is to be understood as products having a crystallite range of 10 to several hundred nanometers, wherein preferably this value is a maximum of 50 nanometers, in particular a maximum of 20 nanometers. Such X-ray amorphous silicates which also have delayed dissolution properties compared to conventional water glass are disclosed in German patent application DE 4400024 A1. Particularly preferred are compressed / compacted amorphous silicates, complex amorphous silicates and overdried X-ray amorphous silicates.

[0109] Phosphates. Also commonly known phosphates can be used as builders, provided that such use is not restricted for ecological reasons. Particularly suitable are the sodium salts of orthophosphoric acid, pyrophosphoric acid and in particular tripolyphosphates. Their content is usually not more than 25% by weight, preferably not more than 20% by weight, based on the final composition. In some cases, especially tripolyphosphates, at low contents of up to 10% by weight, based on the final composition, in combination with other builders, have shown a synergistic improvement in the secondary washing power. The preferred amount of phosphate is less than 10% by weight, in particular 0% by weight. Auxiliary Builder

[0110] Polycarboxylic acids. Useful organic auxiliary builders are polycarboxylic acids, which can be used, for example, in the form of their sodium polycarboxylate salts, where polycarboxylic acids refer to carboxylic acids with more than one acid function. Examples include citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA) and derivatives and mixtures thereof. Preferred salts are salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.

[0111] Organic acids. It is also possible to use the acids themselves. In addition to their builder action, acids generally also have the function of acidifying components, so that relatively low and mild pH values ​​can be established in the detergent or cleaning composition. Mention may be made in particular of citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and mixtures thereof. Other suitable acidulants are the known pH regulators such as sodium bicarbonate and sodium bisulfate.

[0112] Polymers. Particularly suitable polymeric auxiliary builders are polyacrylates, preferably with a molecular weight of 2000 to 20000 g / mol. Short-chain polyacrylates with a molar weight of 2000 to 10000 g / mol, and particularly preferably 3000 to 5000 g / mol, are preferred in this group due to their excellent solubility. Suitable polymers may also include substances composed partly or completely of vinyl alcohol units or derivatives thereof.

[0113] Other suitable copolymer carboxylates are particularly copolymers of acrylic acid and methacrylic acid and acrylic acid or methacrylic acid and maleic acid. It has been shown that copolymers of acrylic acid and maleic acid, which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid, are particularly suitable. Its relative molecular weight, based on free acid, is generally 2000 to 70000 g / mol, preferably 20000 to 50000 g / mol and especially 30000 to 40000 g / mol. (To) polycarboxylates can be added in aqueous solution or preferably with powder. In order to improve water solubility, polymers can also contain allyl sulfonic acid monomers, such as the allyloxybenzenesulfonic acid and methallylsulfonic acid in EP 0727448B1.

[0114] Particularly preferred are biodegradable polymers containing more than two different monomer units, examples being those containing acrylate and maleate, and vinyl alcohol or vinyl alcohol derivatives as monomers according to DE 4300772A1, or containing acrylic acid and 2-alkylallylsulfonate, and sugar derivatives as monomers. Other preferred copolymers are those described in German patent applications DE 4303320 A1 and DE 4417734 A1 and preferably comprise acrolein and acrylic acid / acrylate or acrolein and vinyl acetate as monomers.

[0115] Likewise, other preferred builders are polymeric aminodicarboxylic acids, their salts or their precursors. Particularly preferred are polyaspartic acid or its salts and derivatives as disclosed in German patent application DE 19540086 A1, which besides their auxiliary builder properties also have a bleach-stabilizing effect.

[0116] Other suitable builders are polyacetals which are obtained by reacting dialdehydes with polyhydroxycarboxylic acids having 5 to 7 carbon atoms and at least 3 hydroxyl groups, as described in European patent application EP 0 280 223 A1. Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof with polyhydroxycarboxylic acids, such as gluconic acid and / or glucoheptonic acid.

[0117] Carbohydrate. Other suitable organic auxiliary builders are dextrins, such as oligomers or polymers of carbohydrates, which are obtained by partial hydrolysis of starch. Hydrolysis can be carried out by conventional methods, such as acid catalysis or enzyme catalysis. It is preferred that the average molar weight is a hydrolyzate of 400 to 500000 g / mol. Preferably, a polysaccharide with a dextrose equivalent (DE) of 0.5 to 40, more particularly 2 to 30, wherein DE is an acceptable measure of the reducing effect of the polysaccharide compared to a glucose with a DE of 100. It is possible to use maltodextrins with a DE of 3 to 20 and dry glucose syrups with a DE of 20 to 37, as well as so-called yellow dextrins and white dextrins with a higher molecular weight of 2000 to 30000 g / mol. Preferred dextrins are recorded in British patent application 94 19 091.

[0118] Such oxidized derivatives of dextrins refer to the reaction products of dextrins with oxidizing agents, which are capable of oxidizing at least one alcohol function of the sugar ring to a carboxylic acid function. Such oxidized dextrins and methods for their preparation are known, for example, from European patent application EP 0 232 202 A1. A product oxidized at C6 of the sugar ring is particularly preferred.

[0119] Other suitable auxiliary builders are oxydisuccinates and other derivatives of disuccinates, preferably ethyldiamine disuccinate. Preferably, ethylenediamine-N,N'-disuccinic acid (EDDS) is used in the form of the sodium or magnesium salt, the synthesis of which is described, for example, in US 3,158,615. Particularly preferred in this context are glyceryl disuccinate and glyceryl trisuccinate, as described in US 4,524,009. The addition amount is 3 to 15% by weight in zeolite- and / or silicate-containing preparations.

[0120] Lactones. Other organic co-builders which can be used are, for example, acetylated hydroxycarboxylic acids or their salts, which can optionally also be present in the form of lactones and which contain at least 4 carbon atoms, at least 1 hydroxyl group and at most 2 acid groups. Such co-builders are described, for example, in the international patent application WO 1995 020029 A1. Bleaching compounds, bleaching preparations and bleach activators

[0121] The detergent compositions herein may optionally contain a bleaching agent or a bleaching composition containing a bleaching agent and one or more bleach activators. If present, the bleaching agent is generally present at a level of at least about 1% to about 30%, more particularly about 5% to about 20%, of the detergent composition, especially for fabric washing. If a bleach activator is present, its level is generally from about 0.1% to about 60%, more particularly from about 0.5% to about 40%, of the bleaching composition comprising the bleaching agent plus the bleach activator.

[0122] The bleaching agents used herein can be any bleaching agent suitable for use in detergent compositions for cleaning fabrics, cleaning hard surfaces, or other cleaning purposes now known or to be known. These include oxygen bleaches as well as other bleaching agents. Perborate bleaches, such as sodium perborate (e.g., monohydrate or tetrahydrate), can be used herein.

[0123] Another class of bleaching agents that can be used without limitation includes percarboxylic acid bleaching agents and their salts. Suitable examples of such bleaching agents include magnesium monoperoxyphthalate hexahydrate, magnesium metachloroperbenzoate, magnesium 4-nonylamino-4-oxoperoxybutyrate and magnesium diperoxydodecanedioate.

[0124] Peroxygen bleaching agents may also be used. Suitable peroxygen bleaching compounds include sodium carbonate peroxyhydrate and its equivalent "percarbonate" bleach, sodium pyrophosphate peroxyhydrate, urea peroxyhydrate, and sodium peroxide. Persulfate bleaches (e.g., Commercially produced by DuPont).

[0125] Preferred percarbonate bleaching agents include dry particles with an average particle size of about 500 to about 1000 microns, less than about 200 microns of the particles being no more than about 10 weight percent, and greater than about 1250 microns of the particles being no more than about 10 weight percent. Optionally, percarbonate can be coated with silicate, borate or water-soluble surfactants. Percarbonate can be obtained from various suppliers.

[0126] Mixtures of bleaching agents may also be used.

[0127] Peroxygen bleaches, perborates, percarbonates, etc. are preferably used in combination with bleach activators, which result in the in situ generation of a peroxy acid corresponding to the bleach activator in aqueous solution (i.e. during the washing process). Nonanoyloxybenzene sulfonate (NOBS) and tetraacetylethylenediamine (TAED) activators are typical activators, and mixtures thereof may also be used.

[0128] Preferred amido-derived bleach activators include (6-octylamino-hexanoyl)oxybenzenesulfonate, (6-nonanoylamino-hexanoyl)oxybenzenesulfonate, (6-decanoylamino-hexanoyl)oxybenzenesulfonate and mixtures thereof.

[0129] Another class of bleach activators includes the benzoxazine-type activators disclosed in US 4,966,723, which is incorporated herein by reference.

[0130] Very preferred lactam activators include benzoyl caprolactam, octanoyl caprolactam, 3,5,5-trimethylhexanoyl caprolactam, nonanoyl caprolactam, decanoyl caprolactam, undecenoyl caprolactam, benzoyl valerolactam, octanoyl valerolactam, decanoyl valerolactam, undecenoyl valerolactam, nonanoyl valerolactam, 3,5,5-trimethylhexanoyl valerolactam and mixtures thereof, optionally adsorbed on a solid support, for example acyl caprolactams, preferably benzoyl caprolactam, which are adsorbed into sodium perborate.

[0131] Bleaching agents other than oxygen bleaching agents are also well known in the art and can be used herein. One particularly preferred class of non-oxygen bleaching agents includes photoactivated bleaching agents such as sulfonated zinc and / or aluminum phthalocyanines. If used, detergent compositions typically contain from about 0.025% to about 1.25% by weight of such bleaching agents, especially zinc sulfonate phthalocyanine.

[0132] If desired, the bleaching compounds can be catalyzed with a manganese compound. Such manganese-based catalysts are well known in the art and include Mn IV 2(uO)3(1,4,7-trimethyl-1,4,7-triazacyclononane)2(PF6)2,Mn III 2(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)2,Mn IV 4(uO)6(1,4,7-triazacyclononane))4(ClO4)4,Mn III Mn IV 4(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)3,Mn IV (1,4,7-Trimethyl-1,4,7-triazacyclononane)-(OCH3)3(PF6), and mixtures thereof.

[0133] In practical applications, without limitation, the compositions and methods of the present invention can be adjusted to provide at least about 1 part per million active bleach catalyst in the aqueous wash solution, preferably from about 0.1 ppm to about 700 ppm, more preferably from about 1 ppm to about 500 ppm of catalyst material in the wash solution. Polymeric soil release agent

[0134] Any polymeric soil release agent known to those skilled in the art may be optionally employed in the detergent compositions and methods of the present invention. Polymeric soil release agents are characterized by containing a hydrophilic portion, which is used to hydrophilize the surface of hydrophobic fabrics such as polyester and nylon, and a hydrophobic portion, which is deposited on the hydrophobic fibers and remains adhered thereto throughout the washing process, thereby serving as an anchor for the hydrophilic portion. This makes stains treated with the soil release agent easier to remove in subsequent cleaning procedures.

[0135] The polymeric soil release agents used herein specifically include those soil release agents which have (a) one or more nonionic hydrophilic components consisting essentially of: (i) polyoxyethylene segments having a degree of polymerization of at least 2, or (ii) propylene oxide or polyoxypropylene segments having a degree of polymerization of from 2 to 10, wherein said hydrophilic segments do not contain any propylene oxide units unless they are ether-linked to adjacent moieties at each end, or (iii) a mixture of ethylene oxide and 1 to about 30 propylene oxide units, wherein said mixture contains sufficient ethylene oxide units to render the hydrophilic component sufficiently hydrophilic to enhance the deposition of the soil release agent on the fabric surface as measured by the hydrophilic properties of conventional polyester synthetic fiber surfaces, said hydrophilic segment preferably comprising at least about 25% ethylene oxide units and more preferably, particularly for those components having from about 20 to 30 propylene oxide units, at least about 50% ethylene oxide units; or (b) one or more hydrophobic components comprising The hydrophobic component comprises (i) C3 oxyalkylene terephthalate segments, wherein, if said hydrophobic component also comprises oxyethylene terephthalate, the ratio of oxyethylene terephthalate to C3 oxyalkylene terephthalate units is about 2:1 or less, (ii) C4-C6 alkenyl or oxyC4-C6 alkenyl segments, or mixtures thereof, (iii) poly(vinyl ester) segments, preferably poly(vinyl acetate) having a degree of polymerization of at least 2, or (iv) C1-C4 alkyl ether or C4 hydroxyalkyl ether substituents, or mixtures thereof, wherein said substituents are in the form of C1-C4 alkyl ether or C4 hydroxyalkyl ether cellulose derivatives, or mixtures thereof, wherein said cellulose derivatives are amphoteric and therefore have sufficient C1-C4 alkyl ether and / or C4 hydroxyalkyl ether units to deposit onto the surface of conventional polyester synthetic fibers and retain sufficient hydroxyl groups - once they are bonded to the surface of conventional synthetic fibers - to increase the hydrophilicity of the fiber surface, or a combination of (a) and (b).

[0136] Typically the polyethylene oxide segments of (a)(i) have a degree of polymerization of about 200, preferably 3 to about 150, more preferably 6 to about 100, although higher degrees of polymerization may be used. Suitable oxy-C4-C6 alkenyl hydrophobe segments include, but are not limited to, end-capping polymeric soil release agents.

[0137] Polymeric soil release agents useful herein also include cellulosic derivatives such as hydroxyether cellulosic polymers, block copolymers of ethylene terephthalate or propylene terephthalate with polyethylene oxide or polypropylene oxide terephthalate, and similar materials. Such agents are commercially available and include hydroxyethers of cellulose, such as (Dow). Cellulosic soil release agents useful in the present invention also include C1-C4 alkyl and C4 hydroxyalkyl celluloses.

[0138] Soil release agents characterized by a poly(vinyl ester) hydrophobic segment include graft copolymers of poly(vinyl esters), such as C1-C6 vinyl esters, preferably poly(vinyl acetate) grafted onto a polyalkylene oxide backbone, such as a polyethylene oxide backbone, as described in EP 0,219,048, which is incorporated herein in its entirety. Commercially available soil release agents of this type include Such substances, for example those available from BASF HP-22.

[0139] One class of preferred soil release agents are copolymers having random blocks of monoethylene terephthalate and polyethylene oxide (PEO) terephthalate. The molecular weight of such polymeric soil release agents is from about 25,000 to about 55,000.

[0140] Another preferred polymeric soil release agent is a polyester with ethylene terephthalate repeating units, containing 10 wt% to 15 wt% ethylene terephthalate units and 90 wt% to 80 wt% polyoxyethylene terephthalate units, derived from polyethylene oxide glycol having an average molecular weight of 300 to 5000. Examples of such polymers include the commercially available 5126 (Dupont) and T (manufactured by ICI).

[0141] Still another preferred polymeric soil release agent is the sulfonated product of a substantially linear ester oligomer containing a terephthalate backbone of repeating units of terephthaloyl and oxyalkyleneoxy groups and terminal moieties covalently attached to the backbone. These soil release agents are fully described in U.S. Pat. No. 4,968,451. Other suitable polymeric soil release agents include the terephthalate polyesters of U.S. Pat. No. 4,711,730, the anionically terminated oligoesters of U.S. Pat. No. 4,721,580 and the segmented polyester oligomers of U.S. Pat. No. 4,702,857, and the anionically, particularly sulfoaroyl terminated terephthalate esters of U.S. Pat. No. 4,877,896, all of which are incorporated herein by reference in their entirety.

[0142] Another preferred soil release agent is an oligomer having the following repeating units: terephthaloyl units, sulfoisophthaloyl units, oxyethyleneoxy and oxy-1,2-propylene units. These repeating units form the backbone of the oligomer and are preferably end-capped with modified isethionates. A particularly preferred soil release agent of this type comprises about one sulfoisophthaloyl unit, 5 terephthaloyl units, oxyethyleneoxy and oxy-1,2-propyleneoxy units in a ratio of about 1.7 to about 1.8, and two end-capping units of sodium 2-(2-hydroxyethoxy)ethane sulfonate. The soil release agent also comprises about 0.5 wt. % to 20 wt. % of a stabilizer to reduce crystallinity, based on the weight of the oligomer, the stabilizer preferably being selected from xylene sulfonates, cumene sulfonates, toluene sulfonates, and mixtures thereof.

[0143] If utilized, soil release agents will generally be used at levels of from about 0.01% to about 10.0%, typically from about 0.1% to about 5%, preferably from about 0.2% to about 3.0%, by weight of the detergent compositions herein. Polymer Dispersants

[0144] The polymeric dispersants are advantageously used in the detergent compositions of the present invention in amounts ranging from about 0.1% to about 7% by weight, particularly in the presence of zeolite and / or layered silicate builders. Suitable polymeric dispersants include polymeric polycarboxylates and polyethylene glycols, although other dispersants well known in the art may also be used. While not wishing to be limited by theory, it is believed that polymeric dispersants, when used in conjunction with other builders (including low molecular weight polycarboxylates), enhance the performance of the overall detergent builder by crystal growth inhibition, peptization of particulate soil release, and anti-redeposition.

[0145] Polymeric polycarboxylate materials can be prepared by polymerizing or copolymerizing suitable unsaturated monomers, preferably in acid form. Unsaturated monomeric acids which can be polymerized to form suitable polymeric polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid and methylenemalonic acid. The presence in the polymeric polycarboxylates of monomeric segments containing no carboxylic acid groups, such as vinyl methyl ether, styrene, ethylene, etc., is suitable provided that such segments do not constitute more than about 40% by weight.

[0146] Particularly suitable polymeric polycarboxylates can be made from acrylic acid. The acrylic acid-based polymers used in the present invention are water-soluble salts of polymerized acrylic acid. The average molecular weight of these polymers in the acid form is preferably about 2000-10,000, more preferably about 4,000-7,000, and most preferably about 4,000-5,000. Water-soluble salts of these acrylic acid polymers may include, for example, alkali metal, ammonium and substituted ammonium salts. Such soluble polymers are known materials. For example, US 3,308,067 discloses the use of such polyacrylates in detergent compositions.

[0147] Acrylic acid / maleic acid based copolymers may also be used as preferred components of dispersing / anti-redeposition agents. These materials include water-soluble salts of copolymers of acrylic acid and maleic acid. The average molecular weight of these copolymers in the acid form is preferably about 2,000-100,000, more preferably about 5,000-75,000, and most preferably about 7,000-65,000. The ratio of acrylate to maleate segments in these copolymers is generally from about 30:1 to about 1:1, more preferably from about 10:1 to 2:1. Water-soluble salts of these acrylic acid / maleic acid copolymers may include, for example, alkali metal, ammonium and substituted ammonium salts. Such water-soluble acrylate / maleate copolymers are known materials disclosed in EP 0193360 A1, which also records that such polymers contain hydroxypropyl acrylate. Other useful dispersants include maleic acid / acrylic acid / vinyl alcohol terpolymers, such as a 45 / 45 / 10 terpolymer of maleic acid / acrylic acid / vinyl alcohol.

[0148] Another polymeric material that can be added is polyethylene glycol (PEG). PEG can exhibit dispersant properties, as well as act as a clay soil removal-anti-redeposition agent. Typical molecular weight ranges for use for these purposes are from about 500 to about 100,000, preferably from about 1,000 to about 50,000, and more preferably from about 1,500 to about 10,000.

[0149] Polyaspartic acid and polyglutamic acid dispersants may also be used, especially in combination with zeolite builders. The molecular weight (average) of the dispersant, such as polyaspartic acid, is preferably about 10,000. Foam Inhibitor

[0150] In particular, conventional suds suppressors may be advantageously incorporated into the compositions for automatic washing processes. Suitable suds suppressors include, for example, natural or synthetic soaps containing significant amounts of C 18 -C 24Fatty acids. Foam inhibitors of the non-surface-active type are, for example, organic polysiloxanes and mixtures thereof with fine, optionally silanized silicon dioxide, and paraffins, waxes, microcrystalline waxes and mixtures thereof with silanized silicon dioxide or distearyl diethylene diamine. Preference is given to using mixtures of various foam inhibitors, for example mixtures of silicones, paraffins or waxes. Preferably, the foam inhibitors, in particular those containing silicones and / or paraffins, are loaded onto a particulate, water-soluble or dispersible carrier material. In particular, mixtures of paraffins and distearyl diethylene diamine are preferred in this case.

[0151] Compounds which reduce or suppress suds formation may be incorporated into detergent compositions in accordance with the invention. Suds suppression is particularly important in so-called "high concentration wash processes" and in front-loading European washing machines.

[0152] Various materials can be used as foam inhibitors, and foam inhibitors are known to those skilled in the art. See, for example, Kirk Othmer Encyclopedia of Chemical Technology, Third Edition, Volume 7, pages 430-447 (John Wiley & Sons, Inc., 1979). A class of foam inhibitors of particular interest includes monocarboxylic fatty acids and their soluble salts. The monocarboxylic fatty acids and their salts used as foam inhibitors generally have hydrocarbon chains of 10 to about 24 carbon atoms, preferably 12 to 18 carbon atoms. Suitable salts include alkali metal salts such as sodium, potassium, and lithium salts, as well as ammonium and alkanolammonium salts.

[0153] The detergent compositions of the present invention may also contain non-surfactant foam suppressors. These materials include, for example, high molecular weight hydrocarbons such as paraffins, fatty acid esters (e.g., fatty acid triglycerides), monohydric alcohol esters of fatty acids, aliphatic C 18 -C 40Ketones (e.g., stearone), etc. Other foam suppressors include N-alkylated aminotriazines such as tri- to hexa-alkyl melamines or di- to tetra-alkyl diamine chlorotriazines formed as products of cyanuric chloride and 2 to 3 moles of primary or secondary amines containing 1 to 24 carbon atoms, propylene oxide, monooctadecyl phosphates such as monooctadecyl alcohol phosphate, monooctadecyl dialkali metal (e.g., sodium, potassium, lithium) phosphates and phosphate esters. Hydrocarbons such as paraffins and halogenated paraffins can be used in liquid form. Liquid hydrocarbons are liquid at room temperature and atmospheric pressure, have a pour point in the range of about -40°C to about 50°C, and a minimum boiling point of not less than about 110°C (at atmospheric pressure). It is also known to utilize waxy hydrocarbons, preferably with a melting point below about 100°C. Hydrocarbon foam suppressors are known in the art and include aliphatic, alicyclic, aromatic, and heterocyclic saturated or unsaturated hydrocarbons having about 12 to about 70 carbon atoms. The term "paraffin" as used in this suds suppressor discussion is intended to include mixtures of true paraffins and cyclic hydrocarbons.

[0154] Another preferred class of non-surfactant foam suppressors includes silicone foam suppressors. Included in this class are the use of polyorganosiloxane oils, such as polydimethylsiloxane, dispersions or emulsions of polyorganosiloxane oils or resins, and compositions of polyorganosiloxanes with silica gel particles wherein the polyorganosiloxane is chemically adsorbed or fused onto the silica gel. Silicone foam suppressors are well known in the art.

[0155] Other silicone suds suppressors are disclosed in US Pat. No. 3,455,839, which is incorporated herein in its entirety, and which relates to compositions and methods for defoaming aqueous solutions by the addition of small amounts of polydimethylsiloxane fluids.

[0156] Mixtures of silicones with silanized silica gels are described, for example, in DE-OS 21 24 526, which is incorporated herein in its entirety. Silicone defoamers and foam control agents in granular detergent compositions are disclosed in US 4,652,392, which is incorporated herein in its entirety.

[0157] In preferred silicone suds suppressors for use herein, the solvent of the continuous phase is composed of certain polyethylene glycols or polyethylene glycol-polypropylene glycol copolymers or mixtures thereof (preferred), or polypropylene glycol. The primary silicone suds suppressors are branched / crosslinked, preferably not linear.

[0158] Silicone suds suppressors of the present invention preferably comprise polyethylene glycol and polyethylene glycol / polypropylene glycol copolymers, these polymers having an average molecular weight of less than about 1,000, preferably from about 100 to 800. The polyethylene glycol and polyethylene glycol / polypropylene glycol copolymers used herein have a solubility in water of greater than about 2 weight percent, preferably greater than about 5 weight percent, at room temperature.

[0159] Preferred solvents for use in the present invention are polyethylene glycol, having an average molecular weight of less than about 1,000, more preferably about 100-800, and most preferably about 200-400, and polyethylene glycol / polypropylene glycol copolymers, preferably PPG200 / PEG300. The weight ratio of polyethylene glycol to polyethylene glycol / polypropylene glycol copolymer is preferably about 1:1-1:10, and most preferably 1:3-1:6.

[0160] The preferred silicone suds suppressors for use herein do not contain polypropylene glycol, especially polypropylene glycol having a molecular weight of 4000. They also preferably do not contain block copolymers of ethylene oxide and propylene oxide, such as L101.

[0161] Other foam suppressors useful herein include secondary alcohols (e.g., 2-alkyl alkanols) and mixtures of these alcohols with silicone oils. Secondary alcohols include those having C1-C 16 Chain C6-C 16 The preferred alcohol is 2-butyloctanol, which is available from Condea under the trademark 12 is available commercially. Mixtures of secondary alcohols can be obtained under the trade name 123 is available from Enichem. Mixed foam suppressors generally contain a mixture of alcohol + silicone in a weight ratio of 1:5 to 5:1.

[0162] The compositions of the present invention generally contain 0% to about 5% of a foam inhibitor. When used as a foam inhibitor, monobasic fatty acids and their salts are generally used in an amount of about 5% by weight of the detergent composition. Preferably, about 0.5% to about 3% of a monobasic fatty acid foam inhibitor is used. Silicone foam inhibitors are generally used in an amount of up to about 2% by weight of the detergent composition, although larger amounts may also be used. The upper limit of the amount may be determined based on actual conditions, primarily taking into account the lowest cost and the ability of a lower amount to effectively control the foaming effect. Preferably, about 0.01% to about 1% of a silicone foam inhibitor is used, more preferably about 0.25% to about 0.5%. As used in the present invention. These weight percentage values ​​include any silica used in the polyorganosiloxane blend, as well as any additives that may be used. Monostearate phosphate foam inhibitors are generally used in an amount of about 0.1% to about 2% by weight of the composition. Hydrocarbon foam inhibitors are generally used in an amount of about 0.01% to about 5.0% by weight, although larger amounts may also be used. Alcohol foam inhibitors are generally used in an amount of 0.2% to 3% by weight of the finished composition. Sequestrants and Chelating Agents

[0163] Polyphosphates can be considered as chelating agents or stabilizers, especially for peroxy compounds and enzymes sensitive to heavy metal ions. For example, sodium salt of 1-hydroxyethane-1,1-diphosphonic acid, sodium diethylenetriamine pentamethylenephosphonate or sodium ethylenediaminetetramethylenephosphonate are used in an amount of 0.1 to 5% by weight.

[0164] The detergent compositions of the present invention may also optionally contain one or more iron and / or manganese chelating agents. These chelating agents may be selected from the group consisting of aminocarboxylates, aminophosphonates, polyfunctional substituted aromatic chelating agents and mixtures thereof, all of which are defined below. Without being limited by theory, it is believed that the benefits of these materials are partly due to the extraordinary ability to remove iron and manganese ions from the washing solution by generating soluble chelates. Some detergent builders described above can be used as chelating agents and can provide two functions if such detergent builders are present in sufficient amounts.

[0165] Aminocarboxylates useful as optional chelating agents include ethylenediaminetetraacetate, N-hydroxyethylethylenediaminetriacetate, nitrilotriacetate, ethylenediaminetetrapropionate, triethylenetetraaminehexaacetate, diethylenetriaminepentaacetate and ethanoldiglycinate, the alkali metal, ammonium and substituted ammonium salts thereof, and mixtures thereof.

[0166] Amino phosphonates are also suitable for use as chelating agents in the compositions of the invention when at least low total levels of phosphorus are permitted in detergent compositions and include ethylenediaminetetrakis(methylenephosphonates) i.e. DEQUEST. Preferably, these amino phosphonates do not contain alkyl or alkenyl groups having more than 6 carbon atoms.

[0167] Polyfunctionally substituted aromatic chelating agents are also suitable for use in the compositions of the invention. Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1,2-dihydroxy-3,5-disulfobenzene.

[0168] A preferred biodegradable chelator for use in the present invention is ethylenediamine disuccinate ("EDDS"), especially the [S,S] isomer.

[0169] If used, these chelating agents will typically comprise from about 0.1% to about 10% by weight of the detergent compositions herein. More preferably, if used, such compositions will contain from about 0.1% to about 3.0% by weight of a chelating agent. Clay Soil Remover / Anti-redeposition Agent

[0170] The detergent compositions of the present invention can also optionally contain water-soluble ethoxylated amines which have clay soil removal and anti-redeposition properties. Granular detergent compositions containing these compounds typically contain from about 0.01% to about 10.0% by weight of the water-soluble ethoxylated amines; liquid detergent compositions typically contain from about 0.01% to about 5%.

[0171] The most preferred clay soil removal and anti-redeposition agent is ethoxylated tetraethylenepentamine. Exemplary ethoxylated amines are further described in US 4,597,898. Another class of preferred clay soil removal-anti-redeposition agents are the cationic compounds disclosed in EP 0111,965 A1, the ethoxylated amine polymers disclosed in EP 0111,984 A1, the zwitterionic polymers disclosed in EP 0112,592 A1, and the amine oxides disclosed in US 4,548,744. Another class of preferred anti-redeposition agents includes carboxymethylcellulose (CMC) materials. These materials are well known in the art. Browning Inhibitors

[0172] The task of the browning inhibitor is to keep the dirt detached from the fiber suspended in the washing liquid and thus avoid the re-adsorption of the dirt. For this purpose, most organic natural water-soluble sols, such as salts of (co)polycarboxylic acids, sizing agents, gelatin, ether carboxylic acids or ether sulfonates of starch or cellulose, or salts of acidic sulfates of cellulose or starch are suitable. Also suitable for this purpose are water-soluble polyamides containing acidic groups. In addition, soluble starch preparations, such as hydrolyzed starch, aldehyde starch, etc. can be used as the above-mentioned starch products. Polyvinyl pyrrolidone can also be used. However, preferred cellulose ethers are such as carboxymethyl cellulose (sodium salt), methyl cellulose, hydroxyalkyl cellulose and mixed ethers such as methyl hydroxyethyl cellulose, methyl hydroxypropyl cellulose, methyl carboxymethyl cellulose and mixtures thereof, as well as polyvinyl pyrrolidone, in an amount of 0.1 to 5% by weight, based on the composition. Fluorescent brighteners and UV-absorbers

[0173] Any fluorescent whitening agent or other brightening or whitening agent known in the art can be added to the detergent composition of the present invention in an amount of about 0.05% to about 1.2% by weight. Commercially available fluorescent whitening agents that can be used in the present invention can be divided into subgroups, including but not limited to stilbenes, pyrazolines, coumarins, carboxylic acids, methane cyanines, dibenzothiophene-5,5-dioxide, azoles, derivatives of 5- and 6-membered heterocycles, and other various agents.

[0174] Preferred brighteners include Verona's Series of brighteners. Other disclosed brighteners include: UNPA, Tinopal CBS and Tinopal 5BM were purchased from Ciba-Geigy; Artic CC and ArticWhite CWD, available from Hilton-Davis; 2-(4-phenylvinyl-phenyl)-2H-naphtho[1,2-d]triazoles; 4,4'-di-(1,2,3-triazol-2-yl)-stilbene; 4,4'-di(phenylvinyl)biphenyl; and aminocoumarins. Specific examples of these whitening agents include 4-methyl-7-diethyl-aminocoumarin, 1,2-di(benzimidazol-2-yl)ethylene, 1,3-diphenyl-pyrazolines, 2,5-di(benzoxazol-2-yl)thiophene, 2-phenylvinyl-naphtho[1,2-d]oxazole and 2-(stilbene-4-yl)-2H-naphtho[1,2-d]triazole. Anionic whitening agents can be preferably used in the compositions of the present invention.

[0175] The composition can contain, for example, diaminostilbene disulfonic acid derivatives and alkali metal salts thereof as fluorescent whitening agents. Suitable fluorescent whitening agents are, for example, 4,4'-bis(2-anilino-4-morpholino-1,3,5-triazinyl-6-amino)stilbene-2,2'-disulfonic acid or compounds of similar structure, which carry diethanolamino, methylamino, phenylamino or 2-methoxyethylamino to replace morpholino. In addition, substituted biphenyl styrene-based whitening agents may be present, such as 4,4'-bis(2-sulfonylstyrene)-biphenyl, 4,4'-bis(4-chloro-3-sulfonylstyrene)-biphenyl or 4-(4-chlorostyrene)-4'-(2-sulfonylstyrene)-biphenyl alkali metal salts. A mixture of the above-mentioned fluorescent whitening agents can also be used.

[0176] In addition, UV absorbers can be added. UV absorbers are compounds with excellent absorption properties for ultraviolet radiation. As UV stabilizers, they can also improve the light stability of pigments and dyes used for textile fibers and protect the skin of the wearer of the fiber product by preventing UV radiation from penetrating through the fiber. Usually, highly effective radiation-free inertizing compounds are derivatives of benzophenones substituted by hydroxyl and / or alkoxy groups, especially in the 2- and / or 4-positions. Also suitable are substituted benzotriazoles, acrylates (cinnamic acid derivatives) substituted by phenyl in the 3-position and optionally cyano in the 2-position, salicylates, organic Ni complexes, and natural substances such as umbelliferone and bulk urocanic acid. In a preferred embodiment, the UV absorber absorbs UV-A and UV-B radiation and possibly UV-C radiation and re-radiates light of blue wavelengths, which additionally has an optical brightening effect. Preferred UV absorbers contain triazine derivatives, such as hydroxyaryl-1,3,5-triazines, sulfonated 1,3,5-triazines, o-hydroxyphenylbenzotriazoles and 2-aryl-2H-benzotriazoles and bis(anilinotriazinyl-amino)stilbene disulfonic acid and its derivatives. UV absorbing dyes such as titanium dioxide can also be used as UV absorbers. Dye transfer inhibitors

[0177] Detergent compositions of the present invention can also contain one or more materials that are effective for preventing dyestuff from being transferred to another fabric by a kind of fabric in the washing process.Usually this dye transfer inhibitor comprises the copolymer of polyvinyl pyrrolidone polymer, polyamine N-oxide polymer, N-vinyl pyrrolidone and N-vinyl imidazole, manganese phthalocyanine, peroxidase and their mixture.If these preparations are used, its content is generally about 0.01 weight % to about 10 weight % of composition, preferably about 0.01 weight % to about 5 weight %, and more preferably about 0.05 weight % to about 2 weight %.

[0178] More specifically, the polyamine N-oxide polymers preferred for use in the present invention are described in US 6,491,728, incorporated herein in its entirety.

[0179] Any polymer backbone can be used as long as the amine oxide polymer formed is water soluble and has dye transfer inhibiting properties. Examples of suitable polymer backbones are polyethylene, polyalkylene, polyester, polyether, polyamide, polyimide, polyacrylate and mixtures thereof. These polymers include random or block copolymers in which one monomer type is an amine N-oxide and the other monomer type is an N-oxide. Amine N-oxide polymers typically have a ratio of amine to amine N-oxide of 10:1 to 1:1,000,000. However, the number of amine oxide groups present in the polyamine oxide polymer can be varied by suitable copolymerization or a suitable degree of N-oxidation. Polyamine oxides can be obtained in almost any degree of polymerization. The average molecular weight is typically 500-1000000; more preferably 1000-500000; most preferably 5000-100000. The preferred class of materials may be referred to as "PVNO".

[0180] The most preferred polyamine N-oxide for use in the detergent compositions herein is poly (4-vinylpyridine-N-oxide) which has an average molecular weight of about 50,000 and a ratio of amine to amine N-oxide of about 1:4.

[0181] Copolymers of N-vinylpyrrolidone and N-vinylimidazole polymers (referred to as "PVPVI") are also preferably used in the present invention. The average molecular weight of PVPVI is preferably 5,000-1,000,000, more preferably 5,000-200,000, and most preferably 10,000-20,000. PVPVI copolymers typically have a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of 1:1-0.2:1, more preferably 0.8:1-0.3:1, and most preferably 0.6:1-0.4:1. These copolymers can be linear or branched.

[0182] The compositions of the present invention may also use polyvinyl pyrrolidone ("PVP") having an average molecular weight of about 5,000 to about 400,000, preferably about 5,000 to about 200,000, and more preferably about 5,000 to about 50,000. PVP is known to those skilled in the art of detergents. Compositions containing PVP may also contain polyethylene glycol ("PEG") having an average molecular weight of about 500 to about 100,000, preferably about 1,000 to about 10,000. Preferably, the ratio of PEG to PVP provided in the wash solution is from about 2:1 to about 50:1, more preferably from about 3:1 to about 10:1.

[0183] The detergent compositions of the present invention may also optionally contain from about 0.005% to 5% by weight of certain hydrophilic optical brighteners, which can provide a dye transfer inhibition benefit. If used, the compositions of the present invention preferably contain from about 0.01% to 1% by weight of such fluorescent brighteners.

[0184] A preferred brightener is 4,4'-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-s-triazin-2-yl)amino]-2,2'-stilbene disulfonic acid and disodium salt. This particular class of brighteners is marketed under the trade name Sold by Ciba-Geigy Company. Tinopal-UNPA-GX is a preferred hydrophilic optical brightener for use in the detergent compositions of the present invention.

[0185] Another preferred brightener is 4,4'-bis[(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-s-triazin-2-yl)amino]2,2'-stilbene disulfonic acid disodium salt. This particular class of brighteners is marketed under the trade name Tinopal Sold by Ciba-Geigy.

[0186] Another preferred brightener is 4,4'-bis[(4-anilino-6-morpholino-s-triazin-2-yl)amino]-2,2'-stilbene disulfonic acid, sodium salt. This particular class of brighteners is marketed under the trade name Tinopal Sold by Ciba-Geigy.

[0187] When used in combination with the above-selected polymeric dye transfer inhibitor, the specific fluorescent whitening agent selected for the present invention provides particularly effective dye transfer inhibition performance. The combination of such selected polymeric materials (e.g., PVNO and / or PVPVI) with such selected fluorescent whitening agents (e.g., Tinopal UNPA-GX, Tinopal 5BM-GX, and / or Tinopal AMS-GX) provides significantly better inhibition of dye transfer in aqueous washing solutions than any of the two detergent composition components used alone. Without being limited by theory, it is believed that the mode of action of such brighteners is that they are deposited on these fabrics relatively quickly due to their high affinity for fabrics in the washing solution. The extent to which brighteners are deposited on fabrics in the washing solution is defined by a parameter called "consumption coefficient". The consumption coefficient generally refers to the ratio of a) the brightener material deposited on the fabric to b) the initial brightener concentration in the washing aqueous solution. Brighteners with relatively high consumption coefficients are most suitable for inhibiting dye transfer in such technical contents of the present invention.

[0188] Of course, it will be appreciated that these compounds and other types of conventional optical brighteners may optionally be used in the compositions herein to provide conventional fabric "brightness" benefits but without substantially inhibiting dye transfer. Such use is conventional and well known in detergent formulation. Thickener

[0189] The composition may also contain conventional thickeners and anti-deposition compositions and viscosity modifiers, such as polyacrylates, polycarboxylic acids, polysaccharides and their derivatives, polyurethanes, polyvinylpyrrolidone, castor oil derivatives, polyamine derivatives such as quaternized and / or ethoxylated hexamethylenediamine, and mixtures thereof. Preferred compositions have a viscosity of less than 10,000 mPa*s measured with a Brookfield viscometer at a temperature of 20°C and 50 min. -1 Measured at a shear rate of . Inorganic salt

[0190] Other suitable ingredients of the composition are water-soluble inorganic salts, such as bicarbonates, carbonates, amorphous silicates or mixtures thereof; in particular, alkali metal carbonates and amorphous silicates are used, mainly sodium silicate in a Na2O:SiO2 molar ratio of 1:1 to 1:4.5, preferably 1:2 to 1:3.5. Preferred compositions contain alkaline salts, builders and / or auxiliary builders, preferably sodium carbonate, zeolites, crystalline, layered sodium silicates and / or trisodium citrate, in an amount of 0.5 to 70% by weight, preferably 0.5 to 50% by weight, in particular 0.5 to 30% by weight of anhydrous substances. Fragrances and coloring agents

[0191] The composition may also contain typical detergent and cleaning composition ingredients, such as perfumes and / or colorants, wherein such colorants are preferred, which leave no or negligible coloration on the washed fabric. The total amount of added colorants is preferably less than 1% by weight, preferably less than 0.1% by weight, based on the composition. The composition may also contain white pigments, such as TiO2. Industrial Applicability

[0192] Another object of the present invention relates to a method for increasing, improving and / or adjusting the smell of a fragrance having fruity and floral notes, which comprises or consists of the following steps: (a) providing at least one main fragrance having original fruity and floral notes; (b) providing 1-(3,3-dimethylcyclohexyl)ethanone; (c) adding a certain amount of the 1-(3,3-dimethylcyclohexyl)ethanone to the at least one main fragrance to increase, improve and / or adjust the original smell and fragrance of the main fragrance.

[0193] The present invention also claims the use of 1-(3,3-dimethylcyclohexyl)ethanone to increase, improve and / or adjust the odor of perfumes that originally have fruity and floral notes.

[0194] For the avoidance of doubt, it should be pointed out that all preferred embodiments already mentioned above, in particular mixtures, combinations, amounts used, etc., are common to the claimed methods and the claimed uses, and therefore it is not necessary to repeat them. Furthermore, the indication of an effective amount preferably refers to the addition of about 0.1% to about 2% by weight, preferably about 0.5% to about 1% by weight, of p-tolylcarbinol to the main fragrance.

[0195] A final object of the present invention relates to the use of 1-(3,3-dimethylcyclohexyl)ethanone as a fragrance enhancer. Example Examples 1 to 16 Modification of aroma by adding 1-(3,3-dimethylcyclohexyl)ethanone

[0196] Small amounts of 1-(3,3-dimethylcyclohexyl)ethanone (DMCHE) ranging from 0.1 to 1% by weight were added to various base fragrances with fruity and floral notes. The resulting aroma changes were determined by a panel of 5 experienced perfumers. The results are listed in Table 1. Table 1 Changes in aroma by adding 1-(3,3-dimethylcyclohexyl)ethanone Examples 1 to 3

[0197] Tables 2 to 4 below show typical fragrance compositions comprising 1-(3,3-dimethylcyclohexyl)ethanone. Table 2 Fragrance composition I

[0198] Evaluations were conducted in 10% ethanol. 1-(3,3-Dimethylcyclohexyl)ethanone brings more performance to the fragrance. The floral notes are stronger and the fragrance covers the body lotion base better. It provides enhancement to the jasmine and salicylic acid parts of the fragrance. Table 3 Fragrance composition II

[0199] Evaluations were performed in 10% ethanol. With 1-(3,3-dimethylcyclohexyl)ethanone, soft rose notes were reminiscent of English roses. The scent was a more natural rose note, closer to rose petals. PI reduced the fatty notes, making the notes more earthy. Table 4 Fragrance composition III

[0200] Evaluation was done in 10% ethanol. 1-(3,3-Dimethylcyclohexyl)ethanone enhances the naturalness of the plum aroma. It creates a jammy effect, less butyrate and more apricot in the direction of dried fruit.

Claims

1. A spice mixture comprising or consisting of the following ingredients: (c) at least one primary fragrance having fruity and floral notes, and (d) 1-(3,3-Dimethylcyclohexyl)ethanone.

2. The mixture according to claim 1, wherein the main fragrance is selected from the group consisting of allyl cyclohexylpropionate, dimethylbenzyl butyrate, ethyl 2-methylbutyrate, ethyl 2,4-dimethyl-1,3-dioxane-2-acetic acid, 1,3-dimethylbutyl 2-butenoate, (2E)-1,1'-bis(cyclopentyl)-2-enoate, tetradecanal, phenylethyl alcohol, β-methylphenylpentanol, benzyl acetate, methyl dihydrojasmonate, hydroxycitronellal, citronellol, linalool, benzyl salicylate, tetrahydro-2-isobutyl-4-methylpyran-4-ol and mixtures thereof.

3. The mixture according to claim 1, wherein the content of the main fragrance and the 1-(3,3-dimethylcyclohexyl)ethanone is in the range of about 98 to 2 to about 99.9 to 0.5 weight % - based on the mixture.

4. The mixture according to claim 1, further comprising at least one solvent.

5. The mixture according to claim 4, wherein the solvent is selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol and triethyl citrate.

6. The mixture of claim 4, wherein the solvent is present in the mixture at about 10 wt % to about 90 wt %.

7. A fragrance composition comprising the mixture according to claim 1 and at least one secondary fragrance different from the primary fragrance and 1-(3,3-dimethylcyclohexyl)ethanone.

8. The composition according to claim 7, wherein the secondary fragrance is selected from the group consisting of: ·[(3,7-Dimethyl-6-octenyl)-oxy]-acetaldehyde, ·1-(p-menthen-6(2)-yl)-1-propanone, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, ·10-Undecene-1-aldehyde, ·10-Undecen-1-ol, 1-Decanal, 1-Dodecanal, ·1-Methyl-3-(4-methylpentyl)-3-cyclohexene-carboxaldehyde, ·1-Methyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carbaldehyde, 1-Nonanal, 1-Octanal, 1-Octene-3-ol, ·1-p-menthene-q-carboxaldehyde, 1-Undecanal, ·2-(2-(4-methyl-3-cyclohexen-1-yl)propyl)-cyclopentanone, ·2,4,4,7-Tetramethyl-oct-6-en-3-one, 2,4,6-Trimethyl-3-cyclohexene-l-carbaldehyde, ·2,4-Dimethyl-3-cyclohexene-1-carboxaldehyde 4-methoxybenzaldehyde, 2,4-Dimethyl-3-cyclohexene-1-carbaldehyde, 2,6,10-Trimethyl-5,9-undecadienal, ·2,6,10-Trimethyl-9-undecenal,3-dodecen-1-al, 2,6-Dimethyl-5-heptenal; ·2,6-Dimethylhept-5-en-1-al, 2,6-Dimethylheptan-2-ol, 2,6-nonadienal, ·2-Acetyl-3,3-dimethyl-norbornane, 2-Methyldecanal, 2-Methyloctanal, 2-Methylundecanal, ·2-Methyl-3-(4-tert-butyl)propanal, ·2-Methyl-3-(isopropyl-phenyl)propanal, ·2-Methyl-3-(p-methoxy-phenylpropanal), ·2-Methyl-3-phenyl-2-propene-1-aldehyde, ·2-Methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal, 2-Methylbutanol, 2-Methylpentanol, 2-Phenoxyethanol, 2-Phenylpropan-1-aldehyde, 2-Phenylpropanol, 2-tert-Butylcyclohexanol, ·3-(3,4-Methylenedioxy-phenyl)-2-methylpropan-1-aldehyde, ·3-(3-Isopropylphenyl)-butan-1-aldehyde, ·3-(4-ethylphenyl)-2,2-dimethylpropan-1-aldehyde, ·3-(4-ethylphenyl)-2,2-dimethylpropanal, ·3-(4-isopropylphenyl)-2-methylpropan-1-al, ·3-(4-methoxyphenyl)-2-methylpropanal, ·3-(4-tert-Butylphenyl)-2-methyl-propanal, ·3-(4-tert-Butylphenyl)-propanal, ·3,4-Dimethoxybenzaldehyde, ·3,4-Methylenedioxybenzaldehyde, 3,5,5-Trimethylcyclohexanol, ·3,5,5-Trimethylhexanal, ·3,5,6-Trimethyl-3-cyclohexenecarboxaldehyde, ·3,7-Dimethyl-2-methylene-6-octenal, ·3,7-Dimethyl-6-octen-1-al, ·3,7-Dimethyloctan-1-aldehyde, ·3-Ethoxy-4-hydroxybenzaldehyde, 3-Hexanol, ·3-Methoxy-4-hydroxy-benzaldehyde, ·3-Methyl-5-phenyl-1-pentanal, 3-Methyl-5-phenylpentanol, 3-Octanol, ·3-phenyl-2-hexylprop-2-enal, ·3-phenyl-2-pentylprop-2-en-1-al, ·3-phenyl-2-propenal, ·3-phenylprop-2-en-1-al, 3-Phenylpropanol, ·3-propyl-bicyclo[2.2.1]-hept-5-ene-2-carbaldehyde, ·4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanone, ·4-(3)(4-methyl-3-pentenyl)-3-cyclohexene-carboxaldehyde, ·4-(4-Hydroxy-3-methoxyphenyl)-2-butanone, 4-(4-Hydroxy-4-methylpentyl)-3-cyclohexene-l-carbaldehyde, 4-(Tricyclo[5.2.1.0(2,6)]-decanedyl-8)-butyraldehyde; 4-Dihydrodamascol, 4-Heptenol, 4-Hydroxy-3-methoxybenzaldehyde, 4-Isopropylbenzaldehyde, 4-Isopropylcyclohexanol, 4-Methoxybenzaldehyde, 4-Methylphenylacetaldehyde, 4-tert-Butylcyclohexanol, 5,9-Dimethyl-4,8-decadienal, ·5-Methoxyhexahydro-4,7-methyleneindene-1-carbaldehyde, ·5-Methoxyhexahydro-4,7-methyleneindene-2-carbaldehyde, ·6,10-Dimethyl-3-oxa-5,9-undecadien-1-al, ·6,6-Dimethylbicyclo[3.3.1]hept-2-ene-2-propanal, ·6,7-Dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, ·6,8-Dimethyl-2-nonanol,6-nonen-1-ol, ·6-Isopropyl-decahydro-2-naphthone (naphtone), ·6-Methoxyhexahydro-4,7-methyleneindane-1-carbaldehyde, ·6-Methoxyhexahydro-4,7-methyleneindane-2-carbaldehyde, 7-Hydroxy-3,7-dimethyloctanal, 7-Methoxy-3,7-dimethyloctan-1-aldehyde, 9-Decen-1-ol, 9-Decenal, ·Acetophenone, Adoxaldehyde, ·Allyl cyclohexyl propionate, · alpha-ionone (alphalonen), ·Ambroxan, ·Amyl salicylate, Anethole, ·Anisaldehyde, Benzaldehyde, ·Benzophenone, Benzyl acetate, Benzyl acetone, Benzyl alcohol, Benzyl salicylate, Benzyl ethyl ether, ·Polychlorinated red aldehyde, ·Buccoxime, ·Butyl salicylate, Camphor, ·Consinaldehyde, ·Carvone, · Piperonyl acetone (cassione), Celery cetone ·Chlorhydral, · Cinnamyl alcohol, ·cis- / trans-3,7-dimethyl-2,6-octadiene-1-aldehyde, ·cis-Jasmone, Citral or its mixtures, Citronellal, Citronellol, Citronellyl acetaldehyde, ·Cumaldehyde, Cyclamen aldehyde, Cyclohexyl salicylate, Cymal, ·Damarose, ·Damascenone, ·Decanol, ·Decanal, ·2-pentylcyclopentanone (delphone), ·Dihydrojasmone, ·Dihydromyrcenol, ·Dihydrocinnamaldehyde, ·Dihydro-β-ionone, ·Dimethylbenzyl alcohol, ·Dimethylbenzyl acetate, ·Dimethylheptanol, ·Dimethyloctanol, ·Dimethyl octenone, ·Dulcinyl ·Ethyl salicylate, ·Ethyl vanillin, ·Methylphenylglycine ethyl ester, Eugenol, ·Fenchnone, 2-Heptylcyclopentanone (fleuramone), ·Floralozon, ·2-tert-Butylcyclohexylethyl carbonate (floramat), · Florhydral, ·2-Acetyloctanoate (gelsone), ·Geraniol, · Methyl dihydrojasmonate (hedione), · Neohexymol, ·Piperonal, Heptanol, ·Hexahydro-4,7-methyleneindan-1-carbaldehyde, ·Hexahydro-8,8-dimethyl-2-naphthaldehyde, · Hexalone, ·Hexyl salicylate, ·Hydroxycitronellal, ·Isoborneol, ·Isodacamone, Isoeugenol, ·Isojasmone, ·Isopulegol, · Methylcyclohexyl carbonate (jasmacyclatat), ·koavon, ·Lauryl aldehyde, · Ligustrum aldehyde, Citral, ·Lilial, · Limonene, Linalool, Linalyl acetate, ·livescon, Lyral, · Cymene-7-carboxaldehyde, Melonaldehyde, ·3,5,5-Trimethylhexanoic acid ethyl ester (melusat), ·Menthol, Menthone, Methylacetophenone, ·Methyl cedryl ketone, Methyl cedryl ketone, Methyl cedryl ketone, Methylcyclocitron, ·Methyl dihydrojasmonate, ·Methyl heptenone, Methyl lavandinone, ·Methyl dihydrojasmonate, ·Methylnonyl acetaldehyde, ·Methyl-β-naphthone, Musk indanone, Musk ketone, ·Myrtenol, n-Dodecanal, Neobutenone, ·Nerolidol, · n-Hexanol, Nonanol, n-Undecanal, Octahydro-4,7-methylene-1H-indenecarboxaldehyde; ·Octylaldehyde, Octanol, o-Methoxycinnamaldehyde, ·4-(2-methylbutyl-2-yl)cyclohexane-1-one (orivone), · p-Ethyl-α,α-dimethylhydrocinnamaldehyde, ·phenol, Phenoxyacetaldehyde; ·Phenoxy isobutyrate, · Phenyl acetaldehyde, · Phenyl salicylate, · Phenylethyl acetate, · Phenylethyl alcohol, · 4-Hydroxyphenylbutanone, ·Pinene ·Plictone, · p-Menth-7-ol, · p-Methoxyacetophenone, · p-Methylphenoxyacetaldehyde, ·P-tert.-bucinal, · 4-tert-Butylcyclohexanone, · 4-tert-Butyl Cyclohexylacetate, p-Tolyl acetaldehyde; ·Styryl propionate, ·Tetrahydrogeraniol, ·Tetrahydrolinalool, ·tetrameran, · Thymol, ·tonalid / musk plus, · trans-2-cis-6-nonadienol, · trans-2-nonen-1-ol, · trans-2-octenol, · trans-4-decenal, Ligustrum lucidum, Undecanal, ·Undecanol, ·Undecenal, · Vanillin, ·Valone, ·2-tert-Butylhexaphenol ester (verdone), ·α.-Methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde, α-Damascenone, ·α-Methylbenzyl alcohol, ·α-Methyl-4-(l-methylethyl)phenylacetaldehyde, ·α-Methylphenylacetaldehyde, ·α-Amylcinnamaldehyde, ·α-n-Hexylcinnamaldehyde, α-Terpineol, β-Damascenone, β-ionone, β-Terpineol, γ-Methylionone, · Delta-damascenone.

9. The composition of claim 7, wherein the content of 1-(3,3-dimethylcyclohexyl)ethanone or the mixture of claim 1 is from about 0.01 to about 2 wt% - based on the composition.

10. A cosmetic or personal care formulation comprising the fragrance mixture according to claim 1 or the fragrance composition according to claim 7.

11. A detergent formulation comprising the fragrance mixture according to claim 1 or the fragrance composition according to claim 7.

12. A formulation according to claim 10 or 11, containing from about 0.01 to about 2% by weight of the fragrance mixture according to claim 1 or the fragrance composition according to claim 7.

13. A method for increasing, improving and / or adjusting the smell of a fragrance having fruity and floral notes, comprising or consisting of the following steps: (a) providing at least one main fragrance having original fruity and floral notes; (b) providing 1-(3,3-dimethylcyclohexyl)ethanone; (c) adding a certain amount of the 1-(3,3-dimethylcyclohexyl)ethanone to the at least one main fragrance to increase, improve and / or adjust the original smell and fragrance of the main fragrance.

14. Use of 1-(3,3-dimethylcyclohexyl)ethanone to increase, improve and / or adjust the odor of perfumes that originally have fruity and floral notes.

15. Use of 1-(3,3-dimethylcyclohexyl)ethanone as a fragrance enhancer.

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