A kind of all-solid waste imitation asphalt material and its preparation method and application

By using all-solid waste imitation asphalt materials made from waste as raw materials and combining them with specific preparation methods, the problems of high cost and poor performance of imitation asphalt materials are solved, low-cost and high-performance road materials are achieved, and the stability and durability of the road surface are improved.

CN120157965BActive Publication Date: 2025-09-23HEBEI TRANSPORTATION INVESTMENT GRP CO LTD +1
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Patent Information

Application Number
CN202510637702.9
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-05-19
Publication Date
2025-09-23
Estimated Expiration
2045-05-19

AI Technical Summary

Technical Problem

The preparation cost of existing imitation asphalt materials is high, and their performance cannot reach the level of traditional technology, resulting in poor mechanical properties of the prepared imitation asphalt mixture.

Method used

Using waste rubber powder, waste plastic, waste cooking oil, waste petroleum resin and waste fillers as raw materials, a specific preparation method is used to prepare all-solid waste asphalt imitation materials. The interaction of the various raw material components is utilized to improve the material's high-temperature deformation resistance, low-temperature flexibility, bonding strength and pavement stability.

Benefits of technology

It has achieved low-cost preparation of asphalt-like materials with excellent road performance, dynamic stability of up to 3876 times/mm, and Marshall stability of up to 11.3KN, effectively alleviating the pressure of solid waste disposal and improving road quality and durability.

✦ Generated by Eureka AI based on patent content.

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Abstract

The present invention relates to the technical field of pavement materials, and in particular to an all-solid waste imitation asphalt material, a preparation method thereof, and an application thereof. The all-solid waste imitation asphalt material comprises the following raw material components: waste rubber powder, waste plastic, waste kitchen grease, waste petroleum resin, and waste filler; wherein, the waste filler comprises the following raw material components in percentage by mass: 20%-30% of waste glass fiber, 15%-20% of straw residue, 15%-20% of waste white clay, and the remainder of coal gangue powder. The all-solid waste imitation asphalt material provided by the present invention has excellent road performance, and since the raw material components are all waste, the preparation cost is low and easy to obtain, which can effectively alleviate the pressure of waste treatment. The technical solution of the present invention effectively solves the problem that the preparation cost of the imitation asphalt material in the prior art is high, and the material performance cannot reach the level of traditional asphalt, thereby resulting in poor mechanical properties of the imitation asphalt mixture prepared using the imitation asphalt material.
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Description

Technical Field

[0001] The present invention relates to the technical field of pavement materials, and in particular to an all-solid waste imitation asphalt material and a preparation method and application thereof. Background Art

[0002] Asphalt, with its excellent adhesion and waterproof properties, is widely used in road construction and construction. In road construction, asphalt is one of the primary materials for paving roads, providing a smooth and comfortable driving surface for vehicles. In construction, it is primarily used to manufacture oil paper, felt, waterproof coatings, and asphalt caulking pastes for roofing and underground waterproofing. However, asphalt is highly thermally sensitive. While solid or semisolid at room temperature, it readily melts with increasing temperatures, rendering it less effective at high and low temperatures. Furthermore, asphalt is susceptible to environmental influences and aging. Under the long-term effects of heat, sunlight, oxygen, and moisture, low-molecular-weight components in petroleum asphalt transform into high-molecular-weight components, reducing its plasticity and increasing its viscosity. Asphalt gradually becomes brittle and hard, eventually cracking and losing its usability. Furthermore, during production and use, asphalt can release hazardous substances, posing a threat to the environment and human health. Therefore, the development of alternative materials with similar or superior properties has become a hot research topic.

[0003] In the prior art, the use of polymers to prepare asphalt-like materials is a common method. These materials, using synthetic rubber, synthetic resin, or a blend of both as a base material, are then added with appropriate chemical additives and fillers, and processed through a series of steps to create a rollable sheet-like material with asphalt-like properties. Other methods combine inorganic and polymer materials, leveraging the rigidity of the inorganic material and the flexibility of the polymer to produce high-performance asphalt-like materials. However, the high production costs of existing asphalt-like materials make them difficult to replace asphalt in large-scale road construction applications. Furthermore, the properties of existing asphalt-like materials, such as penetration, softening point, and ductility, do not yet match those of conventional asphalt, resulting in inferior mechanical properties of asphalt-like mixtures prepared using these materials.

[0004] Based on this, developing an asphalt-like material with good adhesion and low cost has important practical significance for road construction. Summary of the Invention

[0005] To address the high production costs of existing asphalt-like materials and the fact that their performance cannot reach the level of traditional asphalt, resulting in poor mechanical properties of asphalt-like mixtures prepared using these materials, the present invention provides an all-solid waste asphalt-like material, its preparation method, and its application. The raw materials for this all-solid waste asphalt-like material include waste rubber powder, waste plastics, waste cooking oil, waste petroleum resin, and waste fillers. By utilizing the interactions of these raw material components and combining them with a specific preparation method, the all-solid waste asphalt-like material exhibits excellent road performance. Furthermore, since all the raw material components are waste, the preparation cost is low and readily available, effectively alleviating the burden of solid waste disposal.

[0006] In order to achieve the above-mentioned object of the invention, the present invention provides the following technical solutions:

[0007] The first aspect of the present invention provides an all-solid waste asphalt-imitation material, comprising the following raw material components in parts by weight: 60-80 parts of waste rubber powder, 20-50 parts of waste plastics, 5-15 parts of waste kitchen grease, 5-15 parts of waste petroleum resin, and 20-30 parts of waste fillers;

[0008] The waste filler includes the following raw material components in percentage by mass: 20%-30% of waste glass fiber, 15%-20% of straw residue, 15%-20% of waste clay and the remainder of coal gangue powder.

[0009] Compared to the existing technology, the present invention utilizes waste rubber powder, waste plastic, waste cooking oil, waste petroleum resin, and waste fillers as the main raw materials to prepare an all-solid waste asphalt-like material. The waste rubber powder and waste plastic possess a certain degree of elasticity and toughness, which can impart the asphalt-like material with excellent high-temperature deformation resistance and low-temperature flexibility, thereby helping to improve the durability of the asphalt-like material. Furthermore, some components in the waste rubber powder and waste plastic can resist the aging effects of ultraviolet rays, slowing the aging rate of the asphalt-like material. The fatty acids contained in the waste cooking oil can, to a certain extent, increase the fluidity and needle penetration of the asphalt-like material, enabling it to better adapt to road deformation under different temperature environments. Furthermore, the waste cooking oil can enhance the adhesion between the asphalt-like material and aggregate, thereby improving the mechanical strength and stability of the road surface, helping to resist the effects of vehicle loads, improving the quality and durability of the road surface, and reducing the occurrence of road surface diseases.

[0010] The addition of waste petroleum resin forms strong intermolecular forces with other components of the asphalt-like material, effectively enhancing its internal cohesion and increasing its overall bond strength and softening point. Furthermore, waste petroleum resin improves the bond between the asphalt-like material and the base layer, increasing adhesion and friction between the two, making it less likely to separate from the base layer and improving the overall stability of the pavement. More importantly, waste petroleum resin exhibits both heat and cold resistance, reducing the temperature sensitivity of the asphalt-like material. In high-temperature environments, it reduces its fluidity, maintaining good pavement smoothness and rutting resistance. In low-temperature environments, it increases the material's flexibility, preventing cracks caused by thermal contraction.

[0011] The waste filler materials used in the present invention include waste glass fiber, straw residue, waste clay, and coal gangue powder. Waste glass fiber has high strength and modulus, effectively bearing and transmitting stress, reducing stress concentration. Furthermore, waste glass fiber acts as a skeletal support, limiting deformation of the asphalt-like material and preventing the expansion of microcracks, thereby enhancing the asphalt-like material's compressive strength and improving its road performance. Straw residue has a certain fiber structure and strength, which can share some of the stress under vehicle loads, reducing deformation and damage to the asphalt-like material and extending the service life of the pavement material. Furthermore, the unique fiber structure of straw residue has a certain degree of flexibility and elasticity, which can absorb and buffer stress caused by low-temperature shrinkage, reducing the probability of cracks in the pavement material under low-temperature conditions. Waste clay has certain high-temperature resistance properties, which can improve the thermal stability of the asphalt-like material and reduce its thermal expansion coefficient. The waste clay particles also act as a dispersion medium, ensuring a more uniform distribution of the various components in the asphalt-like material, helping to improve the overall stability of the material. The addition of coal gangue powder can give the imitation asphalt material higher hardness and rigidity, improve the compressive strength and fatigue resistance of the pavement material, and extend the service life of the pavement material under alternating loads.

[0012] Preferably, the waste rubber powder is any one or more of waste styrene-butadiene rubber powder, waste ethylene-propylene rubber powder or waste nitrile-butadiene rubber powder.

[0013] Preferably, the waste plastic is waste PP plastic or waste PE plastic.

[0014] Preferably, the waste petroleum resin is waste C5 / C9 copolymerized petroleum resin.

[0015] Preferably, the length of the waste glass fiber is 0.3 mm to 0.6 mm.

[0016] Preferably, the specific surface area of ​​the straw residue is 80m 2 / g-120m 2 / g.

[0017] Preferably, the particle size of the waste clay is 0.1 mm to 0.5 mm.

[0018] Preferably, the particle size of the coal gangue powder is 100 μm-200 μm.

[0019] A second aspect of the present invention provides a method for preparing the all-solid waste asphalt-imitation material, comprising the following steps:

[0020] Step 1: Weigh the raw materials of each component according to the designed ratio, mix the waste rubber powder and waste plastic evenly, disperse them in an organic solvent, add a degradation agent, and carry out a hydrothermal reaction at 160°C-185°C under an inert atmosphere to obtain an organic degradation liquid;

[0021] Step 2: crushing the waste filler, calcining at 520°C-600°C, and grinding to obtain filler powder;

[0022] Step 3: Add waste cooking oil and waste petroleum resin to the organic degradation liquid, mix well, heat once at 120°C-140°C, add the filler powder, heat to 150°C-200°C for a second heating, and cool to obtain a full solid waste imitation asphalt material.

[0023] Preferably, in step 1, the organic solvent is dimethyl sulfide, 1,4-dioxane and toluene in a volume ratio of 1:2:10-3:5:10.

[0024] Preferably, in step 1, the mass-to-volume ratio of the total mass of the waste rubber powder and waste plastic to the organic solvent is 1 g:3 mL to 1 g:5 mL.

[0025] Preferably, in step 1, the degradation agent is a mixed solution of sodium hydroxide solution and tetrahydrofuran; wherein the concentration of the sodium hydroxide solution is 0.5 mol / L-1.0 mol / L; and the volume ratio of the sodium hydroxide solution to tetrahydrofuran is 1:1-1:2.

[0026] Preferably, in step 1, the amount of the degradation agent added is 70%-80% of the total mass of the waste rubber powder and waste plastic.

[0027] Preferably, in step 1, the hydrothermal reaction time is 8h-10h.

[0028] Preferably, in step 2, the calcination time is 3h-4h.

[0029] Preferably, in step 2, the temperature is raised to 520°C-600°C by programmed temperature increase at a heating rate of 8°C / min-10°C / min.

[0030] Preferably, in step 2, the grinding speed is 500 rpm-1000 rpm, and the grinding time is 20 min-40 min.

[0031] Preferably, in step three, the insulation time of the primary heating is 2h-3h.

[0032] Preferably, in step three, the holding time of the secondary heating is 3h-4h.

[0033] A third aspect of the present invention provides a use of the all-solid waste asphalt-imitation material or the all-solid waste asphalt-imitation material prepared by the method for preparing the all-solid waste asphalt-imitation material in preparing pavement materials.

[0034] In summary, the all-solid waste imitation asphalt material provided by the present invention has good road performance and low preparation cost, which can effectively alleviate the pressure of solid waste treatment. The imitation asphalt mixture prepared using the all-solid waste imitation asphalt material has excellent mechanical properties, with a dynamic stability of up to 3876 times / mm and a Marshall stability of up to 11.3KN, providing new ideas for the development of pavement materials. DETAILED DESCRIPTION

[0035] The following is a clear and complete description of the technical solutions in the embodiments of the present invention. Obviously, the embodiments described are only some embodiments of the present invention, not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making any creative efforts are within the scope of protection of the present invention.

[0036] Example 1

[0037] This embodiment provides a full-solid waste asphalt-like material and a preparation method thereof, which specifically includes the following contents:

[0038] The all-solid waste asphalt-like material includes the following raw material components in proportion by mass: 70g of waste styrene-butadiene rubber powder, 40g of waste PP plastic, 10g of waste cooking oil, 10g of waste C5 / C9 copolymer petroleum resin and 25g of waste filler; the waste filler includes the following raw material components in proportion by mass: 25% of waste glass fiber, 20% of straw residue, 18% of waste white clay and the remainder of coal gangue powder.

[0039] The length of the waste glass fiber is 0.45 mm; the specific surface area of ​​the straw residue is 100 m 2 / g; the particle size of the waste clay is 0.36mm; the particle size of the coal gangue powder is 150μm.

[0040] The method for preparing the all-solid waste asphalt-like material comprises the following steps:

[0041] Step 1. Weigh the raw materials of each component according to the designed ratio, mix the waste styrene-butadiene rubber powder and waste PP plastic evenly, disperse them in 400 mL of a mixed solvent of dimethyl sulfide, 1,4-dioxane and toluene in a volume ratio of 1:3:10, add 80 g of a degradation agent, and carry out a hydrothermal reaction at 175°C under an inert atmosphere for 9 hours to obtain an organic degradation liquid; wherein the degradation agent is a mixed solution of sodium hydroxide solution and tetrahydrofuran in a volume ratio of 1:1.5, and the concentration of the sodium hydroxide solution is 0.8 mol / L.

[0042] Step 2: crush the waste filler, heat it to 550°C at a heating rate of 10°C / min using a programmed temperature method, and calcine it for 3.5 hours. After cooling, grind it at a speed of 800 rpm for 30 minutes to obtain filler powder.

[0043] Step 3: Add waste cooking oil and waste petroleum resin to the organic degradation liquid, mix well, heat at 130°C for 2.5 hours, add the filler powder, heat to 180°C for a second heating of 4 hours, and cool to obtain a full-solid waste asphalt-like material.

[0044] Example 2

[0045] This embodiment provides a full-solid waste asphalt-like material and a preparation method thereof, which specifically includes the following contents:

[0046] The all-solid waste asphalt-imitation material includes the following raw material components in proportion by mass: 68g of waste EPDM rubber powder, 45g of waste PE plastic, 12g of waste cooking oil, 12g of waste C5 / C9 copolymer petroleum resin and 30g of waste filler; the waste filler includes the following raw material components in proportion by mass: 22% of waste glass fiber, 20% of straw residue, 20% of waste clay and the remainder of coal gangue powder.

[0047] The length of the waste glass fiber is 0.5 mm; the specific surface area of ​​the straw residue is 120 m 2 / g; the particle size of the waste clay is 0.4mm; the particle size of the coal gangue powder is 170μm.

[0048] The method for preparing the all-solid waste asphalt-like material comprises the following steps:

[0049] Step 1. Weigh the raw materials of each component according to the designed ratio, mix the waste styrene-butadiene rubber powder and waste PP plastic evenly, disperse them in 400 mL of a mixed solvent of dimethyl sulfide, 1,4-dioxane and toluene in a volume ratio of 1:2:10, add 80 g of a degradation agent, and carry out a hydrothermal reaction at 170°C under an inert atmosphere for 9 hours to obtain an organic degradation liquid; wherein the degradation agent is a mixed solution of sodium hydroxide solution and tetrahydrofuran in a volume ratio of 1:1.5, and the concentration of the sodium hydroxide solution is 0.5 mol / L.

[0050] Step 2: crush the waste filler, heat it to 580°C at a heating rate of 10°C / min using a programmed temperature method, and calcine it for 3.5 hours. After cooling, grind it at a speed of 800 rpm for 30 minutes to obtain filler powder.

[0051] Step 3: Add waste cooking oil and waste petroleum resin to the organic degradation liquid, mix well, heat at 140°C for 2.5 hours, add the filler powder, heat to 175°C for a second heating of 4 hours, and cool to obtain a full-solid waste asphalt-like material.

[0052] Example 3

[0053] This embodiment provides a full-solid waste asphalt-like material and a preparation method thereof, which specifically includes the following contents:

[0054] The all-solid waste asphalt-imitation material includes the following raw material components in proportion by mass: 72g of waste nitrile rubber powder, 38g of waste PP plastic, 8g of waste cooking oil, 12g of waste C5 / C9 copolymer petroleum resin and 30g of waste filler; the waste filler includes the following raw material components in proportion by mass: 25% of waste glass fiber, 20% of straw residue, 18% of waste white clay and the remainder of coal gangue powder.

[0055] The length of the waste glass fiber is 0.45 mm; the specific surface area of ​​the straw residue is 100 m 2 / g; the particle size of the waste clay is 0.36mm; the particle size of the coal gangue powder is 150μm.

[0056] The method for preparing the all-solid waste asphalt-like material comprises the following steps:

[0057] Step 1. Weigh the raw materials of each component according to the designed ratio, mix the waste styrene-butadiene rubber powder and waste PP plastic evenly, disperse them in 400 mL of a mixed solvent of dimethyl sulfide, 1,4-dioxane and toluene in a volume ratio of 2:5:10, add 80 g of a degradation agent, and carry out a hydrothermal reaction at 175°C under an inert atmosphere for 9 hours to obtain an organic degradation liquid; wherein the degradation agent is a mixed solution of sodium hydroxide solution and tetrahydrofuran in a volume ratio of 1:1.5, and the concentration of the sodium hydroxide solution is 0.8 mol / L.

[0058] Step 2: crush the waste filler, heat it to 600°C at a heating rate of 10°C / min using a programmed temperature method, and calcine it for 3 hours. After cooling, grind it at a speed of 600 rpm for 40 minutes to obtain filler powder.

[0059] Step 3: Add waste cooking oil and waste petroleum resin to the organic degradation liquid, mix well, heat at 130°C for 2.5 hours, add the filler powder, heat to 190°C for a second heating of 4 hours, and cool to obtain a full-solid waste asphalt-like material.

[0060] Comparative Example 1

[0061] This comparative example provides a full-solid waste asphalt-imitation material and a preparation method thereof. The difference from Example 1 is that the waste petroleum resin is replaced with an equal amount of waste epoxy resin, and the other components and raw materials remain unchanged. Specifically, the following contents are included:

[0062] The all-solid waste asphalt-like material includes the following raw material components in proportion by mass: 70g of waste styrene-butadiene rubber powder, 40g of waste PP plastic, 10g of waste cooking oil, 10g of waste epoxy resin and 25g of waste filler; the waste filler includes the following raw material components in proportion by mass: 25% of waste glass fiber, 20% of straw residue, 18% of waste white clay and the remainder of coal gangue powder.

[0063] The length of the waste glass fiber is 0.45 mm; the specific surface area of ​​the straw residue is 100 m 2 / g; the particle size of the waste clay is 0.36mm; the particle size of the coal gangue powder is 150μm.

[0064] The method for preparing the all-solid waste asphalt-like material comprises the following steps:

[0065] Step 1. Weigh the raw materials of each component according to the designed ratio, mix the waste styrene-butadiene rubber powder and waste PP plastic evenly, disperse them in 400 mL of a mixed solvent of dimethyl sulfide, 1,4-dioxane and toluene in a volume ratio of 1:3:10, add 80 g of a degradation agent, and carry out a hydrothermal reaction at 175°C under an inert atmosphere for 9 hours to obtain an organic degradation liquid; wherein the degradation agent is a mixed solution of sodium hydroxide solution and tetrahydrofuran in a volume ratio of 1:1.5, and the concentration of the sodium hydroxide solution is 0.8 mol / L.

[0066] Step 2: crush the waste filler, heat it to 550°C at a heating rate of 10°C / min using a programmed temperature method, and calcine it for 3.5 hours. After cooling, grind it at a speed of 800 rpm for 30 minutes to obtain filler powder.

[0067] Step 3: Add kitchen waste grease and waste epoxy resin to the organic degradation liquid, mix well, heat at 130°C for 2.5 hours, add the filler powder, heat to 180°C for a second heating of 4 hours, and cool to obtain a full-solid waste asphalt-like material.

[0068] Comparative Example 2

[0069] This comparative example provides a full-solid waste asphalt-imitation material and a preparation method thereof. The difference from Example 1 is that the waste filler is replaced with an equal amount of coal gangue powder, and the other components and raw materials remain unchanged. Specifically, it includes the following contents:

[0070] The all-solid waste asphalt-imitation material includes the following raw material components in parts by mass: 70g of waste styrene-butadiene rubber powder, 40g of waste PP plastic, 10g of waste cooking oil, 10g of waste C5 / C9 copolymer petroleum resin and 25g of coal gangue powder.

[0071] The length of the waste glass fiber is 0.45 mm; the specific surface area of ​​the straw residue is 100 m 2 / g; the particle size of the waste clay is 0.36mm; the particle size of the coal gangue powder is 150μm.

[0072] The method for preparing the all-solid waste asphalt-like material comprises the following steps:

[0073] Step 1. Weigh the raw materials of each component according to the designed ratio, mix the waste styrene-butadiene rubber powder and waste PP plastic evenly, disperse them in 400 mL of a mixed solvent of dimethyl sulfide, 1,4-dioxane and toluene in a volume ratio of 1:3:10, add 80 g of a degradation agent, and carry out a hydrothermal reaction at 175°C under an inert atmosphere for 9 hours to obtain an organic degradation liquid; wherein the degradation agent is a mixed solution of sodium hydroxide solution and tetrahydrofuran in a volume ratio of 1:1.5, and the concentration of the sodium hydroxide solution is 0.8 mol / L.

[0074] Step 2: crush the coal gangue, heat it to 550°C at a heating rate of 10°C / min using a programmed temperature method, and calcine it for 3.5 hours. After cooling, grind it at a speed of 800 rpm for 30 minutes to obtain filler powder.

[0075] Step 3: Add waste cooking oil and waste petroleum resin to the organic degradation liquid, mix well, heat at 130°C for 2.5 hours, add the filler powder, heat to 180°C for a second heating of 4 hours, and cool to obtain a full-solid waste asphalt-like material.

[0076] Comparative Example 3

[0077] This comparative example provides an all-solid waste asphalt-imitation material, which differs from Example 1 in that no kitchen waste grease is added, and the other ingredients and preparation process remain unchanged. Specifically, it includes the following contents:

[0078] The all-solid waste asphalt-imitation material includes the following raw material components in proportion by mass: 70g of waste styrene-butadiene rubber powder, 40g of waste PP plastic, 10g of waste 5 / C9 copolymer petroleum resin and 25g of waste filler; the waste filler includes the following raw material components in proportion by mass: 25% of waste glass fiber, 20% of straw residue, 18% of waste white clay and the remainder of coal gangue powder.

[0079] The length of the waste glass fiber is 0.45 mm; the specific surface area of ​​the straw residue is 100 m 2 / g; the particle size of the waste clay is 0.36mm; the particle size of the coal gangue powder is 150μm.

[0080] The method for preparing the all-solid waste asphalt-like material comprises the following steps:

[0081] Step 1. Weigh the raw materials of each component according to the designed ratio, mix the waste styrene-butadiene rubber powder and waste PP plastic evenly, disperse them in 400 mL of a mixed solvent of dimethyl sulfide, 1,4-dioxane and toluene in a volume ratio of 1:3:10, add 80 g of a degradation agent, and carry out a hydrothermal reaction at 175°C under an inert atmosphere for 9 hours to obtain an organic degradation liquid; wherein the degradation agent is a mixed solution of sodium hydroxide solution and tetrahydrofuran in a volume ratio of 1:1.5, and the concentration of the sodium hydroxide solution is 0.8 mol / L.

[0082] Step 2: crush the waste filler, heat it to 550°C at a heating rate of 10°C / min using a programmed temperature method, and calcine it for 3.5 hours. After cooling, grind it at a speed of 800 rpm for 30 minutes to obtain filler powder.

[0083] Step 3: Add waste C5 / C9 copolymer petroleum resin to the organic degradation liquid, mix well, heat at 130°C for 2.5 hours, add the filler powder, heat to 180°C for a second heating of 4 hours, and cool to obtain a full solid waste imitation asphalt material.

[0084] In order to further demonstrate the technical effects of the present invention, the present invention conducted the following performance tests on the all-solid waste asphalt-like materials obtained in Examples 1-3 and Comparative Examples 1-3:

[0085] With reference to JTT798-2011, penetration test, softening point test and ductility test were carried out on each solid waste asphalt imitation material, and the results are shown in Table 1. With reference to JTGE20-2011, asphalt mixtures were prepared for each solid waste asphalt imitation material, and Marshall stability test and dynamic stability test were carried out on the asphalt mixtures, and the results are shown in Table 2.

[0086] Table 1 Performance test results of various solid waste asphalt imitation materials

[0087]

[0088] Table 2 Performance test results of various asphalt mixtures

[0089]

[0090] The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention. Any modifications, equivalent substitutions or improvements made within the spirit and principles of the present invention should be included in the scope of protection of the present invention.

Claims

1. A solid waste asphalt-like material, characterized by: The all-solid waste asphalt-imitation material is composed of the following raw material components by weight: 60-80 parts of waste rubber powder, 20-50 parts of waste plastics, 5-15 parts of waste kitchen grease, 5-15 parts of waste petroleum resin and 20-30 parts of waste fillers; The waste filler is composed of the following raw material components in percentage by mass: 20%-30% of waste glass fiber, 15%-20% of straw residue, 15%-20% of waste clay and the balance of coal gangue powder; The preparation method of the all-solid waste asphalt-like material comprises the following steps: step 1, weighing the raw materials of each component according to the designed ratio, mixing the waste rubber powder and waste plastic evenly, dispersing them in an organic solvent, adding a degradation agent, and performing a hydrothermal reaction at 160° C.-185° C. under an inert atmosphere to obtain an organic degradation liquid; Step 2: crushing the waste filler, calcining at 520°C-600°C, and grinding to obtain filler powder; Step 3: Add waste cooking oil and waste petroleum resin to the organic degradation liquid, mix well, heat once at 120°C-140°C, add the filler powder, heat to 150°C-200°C for a second heating, and cool to obtain a full solid waste imitation asphalt material.

2. The all-solid waste asphalt-imitation material according to claim 1, characterized in that: The waste rubber powder is any one or more of waste styrene-butadiene rubber powder, waste ethylene-propylene rubber powder or waste nitrile-butadiene rubber powder; and / or The waste plastic is waste PP plastic or waste PE plastic; and / or The waste petroleum resin is waste C5 / C9 copolymerized petroleum resin.

3. The all-solid waste asphalt-imitation material according to claim 1, characterized in that: The length of the waste glass fiber is 0.3mm-0.6mm; and / or The specific surface area of ​​the straw residue is 80m 2 / g-120m 2 / g; and / or The particle size of the waste clay is 0.1 mm to 0.5 mm; and / or The particle size of the coal gangue powder is 100 μm-200 μm.

4. A method for preparing the asphalt-like material from solid waste according to any one of claims 1 to 3, characterized in that: The steps include: Step 1: Weigh the raw materials of each component according to the designed ratio, mix the waste rubber powder and waste plastic evenly, disperse them in an organic solvent, add a degradation agent, and carry out a hydrothermal reaction at 160°C-185°C under an inert atmosphere to obtain an organic degradation liquid; Step 2: crushing the waste filler, calcining at 520°C-600°C, and grinding to obtain filler powder; Step 3: Add waste cooking oil and waste petroleum resin to the organic degradation liquid, mix well, heat once at 120°C-140°C, add the filler powder, heat to 150°C-200°C for a second heating, and cool to obtain a full solid waste imitation asphalt material.

5. The method for preparing the asphalt-like material from solid waste according to claim 4, characterized in that: In step 1, the organic solvent is dimethyl sulfide, 1,4-dioxane and toluene in a volume ratio of 1:2:10-3:5:10; and / or In step 1, the mass volume ratio of the total mass of the waste rubber powder and waste plastic to the organic solvent is 1g:3mL-1g:5mL.

6. The method for preparing the asphalt-like material from solid waste according to claim 4, wherein: In step 1, the degradation agent is a mixed solution of sodium hydroxide solution and tetrahydrofuran; wherein the concentration of the sodium hydroxide solution is 0.5 mol / L-1.0 mol / L; the volume ratio of the sodium hydroxide solution to the tetrahydrofuran solution is 1:1-1:2; and / or In step 1, the amount of the degradation agent added is 70%-80% of the total mass of the waste rubber powder and waste plastic.

7. The method for preparing the asphalt-like material from solid waste according to claim 4, wherein: In step 1, the hydrothermal reaction time is 8h-10h; and / or In step 2, the calcination time is 3h-4h.

8. The method for preparing the asphalt-like material from solid waste according to claim 4, wherein: In step 2, the temperature is raised to 520°C-600°C by programmed temperature increase at a rate of 8°C / min-10°C / min; and / or In step 2, the grinding speed is 500 rpm-1000 rpm, and the grinding time is 20 min-40 min.

9. The method for preparing the asphalt-like material from solid waste according to claim 4, wherein: In step 3, the holding time of the first heating is 2h-3h; and / or In step 3, the holding time of the secondary heating is 3h-4h.

10. Use of the all-solid waste asphalt-imitation material according to any one of claims 1 to 3 or the all-solid waste asphalt-imitation material prepared by the method for preparing the all-solid waste asphalt-imitation material according to any one of claims 4 to 9 in preparing pavement materials.

Citation Information

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