Photovoltaic hydrogen production modular system

By using LLC isolation resonant converters and multiple sets of alkaline electrolytic hydrogen production equipment in the photovoltaic hydrogen production system, the problem of limited application and limited equipment space in the photovoltaic hydrogen production system is solved, and high-efficiency energy transmission and low-cost hydrogen production are achieved.

CN120389437APending Publication Date: 2025-07-29XIAN PINGGAO SMART ENERGY CO LTD +3
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Patent Information

Application Number
CN202410129287.1
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-01-30
Publication Date
2025-07-29

AI Technical Summary

Technical Problem

The existing photovoltaic hydrogen production system is limited in remote areas, and traditional DC/DC converters have problems such as high switching losses, narrow input voltage range, low efficiency and limited equipment space.

Method used

The LLC isolation resonant converter is adopted, combined with multiple sets of alkaline electrolytic water hydrogen production equipment in parallel operation schemes, and its soft switching characteristics are used to realize ZVS and ZCS, optimize the converter parameters to work near the resonant point, and integrate the electrolytic cell through the "2-to-1" and "4-to-1" schemes to increase the input voltage range and energy utilization rate.

Benefits of technology

It improves the energy transmission efficiency and stability of the photovoltaic hydrogen production system, solves the problems of equipment space limitations and high costs, and achieves efficient energy utilization.

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Abstract

The invention relates to a photovoltaic hydrogen production modularization system which comprises a photovoltaic array subsystem used for providing electric energy; the hydrogen production subsystem is used for preparing hydrogen; the hydrogen production subsystem comprises a first hydrogen production module and a second hydrogen production module; the first hydrogen production module is used for preparing hydrogen through the provided electric energy; the second hydrogen production module is used for automatically starting and stopping to prepare hydrogen according to the input power; wherein the first hydrogen production module and the second hydrogen production module are connected in parallel, and the photovoltaic array subsystem is connected with the hydrogen production subsystem. According to the invention, the LLC isolated resonant converter is applied to the photovoltaic hydrogen production system, and the soft switching characteristic of the LLC isolated resonant converter is utilized, so that the switching tube realizes ZVS and ZCS, and the loss of the switching tube is reduced; when the design index range is met, converter parameters are optimized, so that the converter works near a resonance point, and the energy transmission efficiency is improved; the input voltage range is enlarged, when the voltage range changes greatly, efficient operation can still be achieved, and the system stability is facilitated.
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Description

Technical Field

[0001] The present invention relates to the technical field of photovoltaic hydrogen production, and in particular to a modular photovoltaic hydrogen production system. Background Art

[0002] Photovoltaic hydrogen production systems mainly include devices such as photovoltaic arrays and electrolyzers. On this basis, devices such as supercapacitors, storage batteries, and fuel cells can be added to form a hybrid system with higher flexibility. According to the relationship with the power grid, the structure of photovoltaic hydrogen production systems is mainly divided into grid-connected structures and off-grid structures.

[0003] Grid-connected hydrogen production systems can be applied to areas where the power grid has been laid. By combining the photovoltaic array with the power grid, uninterrupted operation of the electrolyzer can be achieved. However, this structure relies on the power grid and is difficult to apply in remote areas without a laid power grid. In addition to the DC / DC converter, the grid-connected structure also requires a rectifier or an inverter, which is likely to generate harmonic pollution to the power grid, and the control of multi-stage converters is more complex and the efficiency is lower. Off-grid hydrogen production systems are completely independent of the power grid, and the photovoltaic array supplies power to the electrolyzer. This method does not require power grid support and can be applied to remote areas with sufficient sunlight. The generated hydrogen can be transported out through pipelines. Research shows that in some cases, transporting hydrogen through pipelines may be more economical than transporting electricity over long distances. At the same time, the off-grid hydrogen production method also avoids the pollution of the power grid by converter harmonics. Off-grid hydrogen production systems are divided into direct coupling methods and indirect coupling methods. Direct coupling is to directly connect the photovoltaic array and the electrolyzer, and the I-V curves of the two are matched by configuring the respective combination methods and quantities of the photovoltaic array and the electrolyzer. However, due to the uncertainty of sunlight, the efficiency of the direct coupling method is low. The indirect coupling method is that the photovoltaic array is indirectly connected to the electrolyzer through a DC / DC converter, and the DC / DC converter can flexibly match the I-V curves of the photovoltaic array and the electrolyzer, and the system efficiency is high.

[0004] Traditional Buck converters have advantages such as simple structure, simple control, and low cost, and are widely used in hydrogen production systems. There are also technical solutions that apply isolated topologies to hydrogen production systems, such as half-bridge and full-bridge DC / DC converters, specifically LC resonant converters and LCL resonant converters. However, generally there are switching losses, resulting in low efficiency.

[0005] At present, most alkaline electrolyzers operate individually. Each alkaline electrolyzer requires one gas-liquid separation device and one purification device, which will cause limited project space and high hydrogen production costs. Summary of the Invention

[0006] The object of the present invention is to provide a photovoltaic hydrogen production modular system to solve the problems existing in the above-mentioned prior art. By applying an LLC isolated resonant converter to the photovoltaic hydrogen production system and utilizing its soft-switching characteristics, the switching tubes achieve ZVS and ZCS, reducing the switching tube losses. Within the range of meeting the design specifications, the converter parameters are optimized to make it operate near the resonant point, improving the energy transfer efficiency. The input voltage range is increased, and it can still operate efficiently when the voltage range changes greatly, which is beneficial to the system stability. In addition, an operation scheme of paralleling multiple sets of alkaline electrolytic water hydrogen production equipment is adopted, combining the "2-to-1 scheme" and the "4-to-1 scheme", integrating the electrolytic cells, and solving the problem that it is difficult to integrate equipment with limited space; solving the problem of broadband tuning of hydrogen production equipment; solving the problem of high hydrogen production cost. This system can cut in or out of the "2-to-1" according to needs, making full use of the power generated by the photovoltaic array and maximizing the energy utilization rate.

[0007] To achieve the above object, the present invention provides the following solutions:

[0008] A photovoltaic hydrogen production modular system, comprising:

[0009] A photovoltaic array subsystem for providing electrical energy;

[0010] A hydrogen production subsystem for producing hydrogen; the hydrogen production subsystem includes: a first hydrogen production module and a second hydrogen production module;

[0011] The first hydrogen production module is used to produce hydrogen by the provided electrical energy; the second hydrogen production module is used to automatically start and stop according to the input power and produce hydrogen;

[0012] Wherein, the first hydrogen production module and the second hydrogen production module are connected in parallel, and the photovoltaic array subsystem and the hydrogen production subsystem are connected.

[0013] Optionally, automatically starting and stopping according to the input power includes: cutting in a plurality of LLC converters and alkaline electrolytic cells according to the input power; wherein, the LLC converters and the alkaline electrolytic cells are connected in parallel.

[0014] Optionally, the second hydrogen production module includes:

[0015] The hydrogen production sub-module is used to set the cut-in target thresholds, which include the first cut-in threshold, the second cut-in threshold, and the third cut-in threshold. Combining the input power, it determines whether to cut in a number of LLC converters and alkaline electrolyzers. When the input power is greater than the first cut-in threshold and less than or equal to the second cut-in threshold, a number of LLC converters and alkaline electrolyzers are not cut in. When the input power is greater than the second cut-in threshold and less than or equal to the third cut-in threshold, a number of LLC converters and alkaline electrolyzers are cut in to produce hydrogen.

[0016] Optionally, the hydrogen production sub-module includes:

[0017] A control unit, which is used to obtain the terminal voltage and terminal current of the alkaline electrolyzer when a number of LLC converters and alkaline electrolyzers are cut in, obtain the actual power according to the terminal voltage and the terminal current, set the power set value of the alkaline electrolyzer, subtract the actual power from the power set value, pass through a first PI controller to obtain a current reference value, subtract the current reference value from the terminal current value, pass through a second PI controller to obtain the trigger signal of the LLC converter, and based on the trigger signal, control a number of the LLC converters and the alkaline electrolyzer to produce hydrogen.

[0018] Optionally, the hydrogen production sub-module further includes:

[0019] A device optimization unit, which is used to collect the operating frequency of the LLC converter, obtain the operating state of the LLC converter through the operating frequency, select the parameter range of the LLC converter based on the operating state, and improve the operating efficiency of the LLC converter.

[0020] Optionally, the operating states include: under-resonant operating state, quasi-resonant operating state, and over-resonant operating state.

[0021] Optionally, the method for automatic start and stop according to the input power is:

[0022]

[0023] where signal is the switch signal and P is the input power.

[0024] Optionally, the hydrogen production subsystem further includes:

[0025] A gas-liquid separation module, which is used to separate the gas and KOH solution in the hydrogen-containing mixed liquid or oxygen-containing mixed liquid, and reduce the moisture content in the gas;

[0026] A purification module, which is used to remove impurities;

[0027] A gas collection and storage module is used to collect the prepared hydrogen and store the collected hydrogen.

[0028] Among them, the gas-liquid separation module, the purification module, and the gas collection and storage module are connected in sequence.

[0029] The beneficial effects of the present invention are as follows:

[0030] The photovoltaic hydrogen production system based on the LLC resonant converter of the present invention helps to improve the accommodation capacity of photovoltaic power generation and alleviate the problem of photovoltaic power abandonment. It utilizes the soft-switching characteristics of the LLC resonant converter to achieve zero-voltage turn-on (ZVS) and zero-current turn-off (ZCS) of the switching tube, reducing the switching loss of the converter. In addition, the input and output voltage ranges are increased, and it can still operate efficiently when the voltage range changes greatly, which is beneficial to improving the system stability. And through parameter design, the converter works near the resonance point, improving the energy transfer efficiency and thus the efficiency of the photovoltaic hydrogen production system.

[0031] The present invention adopts an operation scheme of parallel connection of multiple sets of alkaline electrolytic water hydrogen production equipment, combines the "2-to-1 scheme" and the "4-to-1 scheme", integrates the electrolytic cells, solves the problem of difficult integration of space-limited equipment; solves the problem of broadband tuning of hydrogen production equipment; solves the problem of high hydrogen production cost. This system can cut in or cut out the "2-to-1" according to needs, make full use of the power generated by the photovoltaic array, and maximize the energy utilization rate. BRIEF DESCRIPTION OF THE DRAWINGS

[0032] In order to more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the following will briefly introduce the drawings required to be used in the embodiments. Obviously, the drawings in the following description are only some embodiments of the present invention. For those of ordinary skill in the art, other drawings can be obtained based on these drawings without creative efforts.

[0033] Figure 1 It is a topological structure diagram of a modular photovoltaic hydrogen production system according to an embodiment of the present invention;

[0034] Figure 2 It is a topological diagram of the LLC resonant converter according to an embodiment of the present invention;

[0035] Figure 3 It is a topological diagram of the 2-to-1 scheme according to an embodiment of the present invention;

[0036] Figure 4 It is a topological diagram of the modular electrolytic cell according to an embodiment of the present invention;

[0037] Figure 5 It is a schematic diagram of a modular photovoltaic hydrogen production system according to an embodiment of the present invention;

[0038] Figure 6 It is the working waveform diagram of the LLC converter according to the embodiment of the present invention;

[0039] Figure 7 It is the schematic diagram of working mode 1 (t0~t1) according to the embodiment of the present invention;

[0040] Figure 8 It is the schematic diagram of working mode 2 (t1~t2) according to the embodiment of the present invention;

[0041] Figure 9 It is the schematic diagram of working mode 3 (t2~t3) according to the embodiment of the present invention;

[0042] Figure 10 It is the schematic diagram of working mode 4 (t3~t4) according to the embodiment of the present invention;

[0043] Figure 11 It is the signal schematic diagram of switch tubes S1 and S4 when only "4 pairs to 1" operation occurs in the system according to the embodiment of the present invention;

[0044] Figure 12 It is the signal schematic diagram of switch tubes S2 and S3 when only "4 pairs to 1" operation occurs in the system according to the embodiment of the present invention;

[0045] Figure 13 It is the signal schematic diagram of switch tubes S1 and S4 when the system according to the embodiment of the present invention accesses "2 pairs to 1" and then operates in "4 pairs to 1";

[0046] Figure 14 It is the signal schematic diagram of switch tubes S2 and S3 when the system according to the embodiment of the present invention accesses "2 pairs to 1" and operates in "4 pairs to 1" after that;

[0047] Figure 15 It is the signal schematic diagram of switch tubes S1 and S4 when the system according to the embodiment of the present invention accesses "2 pairs to 1" and then operates in "2 pairs to 1";

[0048] Figure 16 It is the signal schematic diagram of switch tubes S2 and S3 when the system according to the embodiment of the present invention accesses "2 pairs to 1" and operates in "2 pairs to 1" after that;

[0049] Figure 17 It is the floor plan of the modular alkaline electrolyzer system according to the embodiment of the present invention;

[0050] Figure 18 It is the power control block diagram according to the embodiment of the present invention;

[0051] Figure 19 It is the working flow chart of the photovoltaic hydrogen production modular system according to the embodiment of the present invention. Detailed implementation manners

[0052] Next, the technical solutions in the embodiments of the present invention will be clearly and completely described in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

[0053] To make the above objects, features, and advantages of the present invention more obvious and understandable, the present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.

[0054] Currently, the DC / DC converters applied to photovoltaic hydrogen production systems have problems such as switching losses, narrow input voltage range, high electromagnetic interference, and low efficiency. By changing the converter topology and applying the LLC resonant converter to the photovoltaic hydrogen production system, its soft-switching characteristics are utilized to reduce switching losses. In addition, the input voltage range is increased, and when the voltage range changes greatly, it can still operate efficiently, which is beneficial to improving the system stability. And through parameter design, the converter operates near the resonant point, improving the energy transfer efficiency, and thus improving the efficiency of the photovoltaic hydrogen production system. The present invention adopts an operation scheme of paralleling multiple sets of alkaline electrolytic water hydrogen production equipment, combining the "2-to-1 scheme" and the "4-to-1 scheme", integrating the electrolytic cells, solving the problem that it is difficult to integrate equipment with limited space; solving the problem of wide-frequency tuning of hydrogen production equipment; solving the problem of high hydrogen production cost. This system can cut in or cut out the "2-to-1" according to needs, making full use of the electricity generated by the photovoltaic array and maximizing the energy utilization rate.

[0055] The present invention discloses a modular photovoltaic hydrogen production system, including: applying the LLC resonant converter to the photovoltaic hydrogen production system, indirectly connecting the photovoltaic array to the modular electrolytic cell through the LLC resonant converter, and the system topology is as Figure 1 shown, the LLC resonant converter topology is as Figure 2 shown, the 2-to-1 scheme topology is as Figure 3 shown, the modular electrolytic cell topology is as Figure 4 shown, and the system scheme design is as Figure 5 shown.

[0056] Among them, S1 to S8 are the switching tubes of the inverter and rectifier network, Lm is the excitation inductor, L1 and C1 are the primary resonant elements, and the turns ratio of the transformer TR is n. It is defined that the power of the converter flows from the primary side to the secondary side as the forward operation. During the forward operation, control drive signals are applied to S1 to S4, and synchronous rectification control drive signals are applied to S5 to S8.

[0057] The working process of LLC includes:

[0058] The main working waveforms of the LLC converter are as Figure 4As shown, there are 8 modes within one working cycle. For the convenience of description, only the first 4 working modes are analyzed in this embodiment, and the rectification method is diode uncontrolled rectification. The energy flow paths under each mode are as Figure 4 shown, and the operation analysis of each mode is combined with Figure 6 the waveform introduction.

[0059] Working mode 1 (t0~t1): As Figure 7 shown, initially, S1 and S4 achieve ZVS. Since the exciting inductor Lm is large enough, it has a strong hindrance to the exciting current, and the exciting current i Lm and the resonant current i Lr rise at different speeds. The difference between the exciting current and the resonant current flows to the secondary side, and at this time the secondary side switch tube conducts. At time t1, the resonant current i Lr is equal to the exciting current i Lm , and at this time mode 1 ends.

[0060] As Figure 8 shown, at time t1, the energy only flows on the primary side, the current in the secondary side diode circuit gradually becomes zero and automatically turns off, achieving ZCS, and the voltage across the load is provided by the capacitor.

[0061] Working mode 3 (t2~t3): As Figure 9 shown, starting from time t2, S1~S4 are turned off, and the resonant current starts to charge the parasitic capacitors of S1 and S4 to the input voltage V in , while the parasitic capacitors of S2 and S3 discharge to zero voltage. When the charge and discharge are completed, this mode ends. During this mode, the rectification network has no voltage output, and the output voltage is maintained by the capacitor.

[0062] Working mode 4 (t3~t4): As Figure 10 shown, at the end of the previous mode, the parasitic capacitors of S2 and S3 have been discharged, preparing for the ZVS of S2 and S3. The resonant current continues to flow through the parasitic diodes of S2 and S3, and the energy flows from the primary side to the secondary side until the switch tubes of S2 and S3 are turned on with ZVS at time t4, and the resonant current starts to flow through the switch tubes, and this mode ends.

[0063] According to the magnitude of the working frequency, it can be obtained that there are three working states of the LLC converter: under-resonant working state, quasi-resonant working state, and over-resonant working state. When the switching frequency increases, the time when the exciting current is equal to the resonant circuit in the under-resonant working condition decreases, and the circulating current time decreases. Until the switching frequency is equal to the resonant frequency, the time in the under-resonant working state no longer exists. At this time, the converter works in the quasi-resonant state, without a freewheeling process, and the energy transmission efficiency is high. When designing parameters, it should be near this working point to make the working efficiency of the converter reach the highest.

[0064] When the system input power is less than or equal to 20 MW, only the "4-in-1" operation exists in the system, and the switching tube signals of its LLC are as Figure 11 shown. The switching tube signals of S1 and S4 (such as Figure 11 ), and the switching tube signals of S2 and S3 (such as Figure 12 ).

[0065] When the system power is greater than 20 MW and less than or equal to 30 MW, the "2-in-1" is connected to the system. At this time, 6 alkaline electrolyzers in the system work simultaneously to share the system power. Among the switching tube signals of the LLC of the "4-in-1", the switching tube signals of S1 and S4 (such as Figure 13 ), and the switching tube signals of S2 and S3 ( Figure 14 shown), and among the switching tube signals of the LLC of the "2-in-1", the switching tube signals of S1 and S4 (such as Figure 15 ), and the switching tube signals of S2 and S3 ( Figure 16 shown).

[0066] The modular alkaline electrolyzer system includes:

[0067] The present invention combines the "2-in-1 scheme" with the "4-in-1 scheme". Among them, "4-in-1" means that 4 electrolyzers are connected in parallel, sharing a set of gas-liquid separation device and a set of purification device. "2-in-1" means that 2 electrolyzers are connected in parallel, sharing a set of gas-liquid separation device and a set of purification device. Moreover, according to the system requirements, when the system input power is large, the "2-in-1" can be switched in to improve the hydrogen production capacity of the system and make full use of resources; when the system input power is small, the "2-in-1" can be switched out to improve the equipment utilization rate;

[0068] Among them, the function of the gas-liquid separation device: After the hydrogen-containing mixed liquid or oxygen-containing mixed liquid flowing out of the electrolyzer passes through this component on the hydrogen side and the oxygen side respectively, the gas and the KOH solution are separated, and the moisture content in the gas is reduced. The function of the purification device: Remove impurities such as oxygen, water, mechanical impurities and dust particles in the hydrogen produced from the electrolyzer. Gas collection device: Collect the gas coming out, store it or process and discharge it. Each module has its own set of devices to carry out work.

[0069] This invention adopts an operation scheme of multiple sets of alkaline electrolytic water hydrogen production equipment connected in parallel. The hydrogen production capacity of a single set of alkaline electrolytic water hydrogen production equipment is 1000 Nm 3 / h, and the rated power of a single unit is about 5 MW. The total hydrogen production capacity target of the entire project is 6000 Nm 3 / h. The specific system layout is as Figure 10 shown. 6 alkaline electrolyzers are centrally arranged in the same plant building. Among them, 4 alkaline electrolyzers share 1 set of gas-liquid separation facilities and 1 set of hydrogen purification devices. The processing capacity of a single set of purification devices is 4000 Nm 3 / h; Another 2 alkaline electrolyzers share 1 set of gas-liquid separation facilities and 1 set of hydrogen purification devices, and the processing capacity of a single purification device is 2000 Nm 3 / h; The electrolyzers share 1 set of water injection and caustic soda injection facilities to maximize the sharing of facilities, such as Figure 17 .

[0070] The system control strategy includes:

[0071] The modular alkaline electrolyzer system adopts a power control strategy, and the specific control block diagram is as Figure 11 shown. In the figure, U eldc and I eldc are the terminal voltage and terminal current of the electrolyzer respectively, P elref is the power set value of the electrolyzer. The difference between the real-time power of the electrolyzer and the power set value is passed through a PI controller to obtain the reference value I eldcref of the terminal current of the electrolyzer. Then, the difference between it and the measured value I eldc of the terminal current of the electrolyzer is passed through a PI controller to obtain the trigger signal of the switching tube of the LLC resonant converter, so that the LLC converter works, and thus the alkaline electrolyzer works, as Figure 18 .

[0072] The working process of the photovoltaic hydrogen production modular system includes:

[0073] The working process of the photovoltaic hydrogen production modular system is as Figure 12 shown. The output power of the photovoltaic array is used as the system input power, and its value is in the range of 10 MW - 30 MW. When the input power is in the range of 10 MW - 20 WM, the system only operates in "4 in 1", and 4 alkaline electrolyzers share the total power equally. When the input power reaches 20 MW, the 4 electrolyzers operate at full load; when the input power is in the range of 20 MW - 30 WM, the system will automatically detect the power change, making the switch signal become 1 (as shown in Equation 1), controlling the switch to close ( Figure 4 the switch in front of "2 in 1" in), connecting "2 in 1". At this time, the system operates in "4 in 1" and "2 in 1" simultaneously, that is, 6 alkaline electrolyzers in the system operate simultaneously and share the total power equally. When the input power reaches 30 MW, the 6 electrolyzers operate at full load, and the hydrogen output of the system reaches the maximum. When the power drops below 20 MW, the system will automatically detect the power change, making the switch signal become 0, controlling the switch to open, and cutting out "2 in 1", as Figure 19 .

[0074]

[0075] The embodiments described above are only descriptions of the preferred embodiments of the present invention, and do not limit the scope of the present invention. Without departing from the spirit of the present invention, various modifications and improvements made by those of ordinary skill in the art to the technical solutions of the present invention shall fall within the protection scope determined by the claims of the present invention.

Claims

1. A photovoltaic hydrogen production modular system, characterized in that, include: Photovoltaic array subsystem for providing electrical energy; A hydrogen production subsystem for producing hydrogen; The hydrogen production subsystem includes: a first hydrogen production module and a second hydrogen production module; The first hydrogen production module is used to produce hydrogen through the provided electrical energy; the second hydrogen production module is used to automatically start and stop according to the input power to produce hydrogen; The first hydrogen production module and the second hydrogen production module are connected in parallel, and the photovoltaic array subsystem is connected to the hydrogen production subsystem.

2. The photovoltaic hydrogen production modular system according to claim 1, characterized in that, Automatically starting and stopping according to the input power includes: switching on a plurality of LLC converters and alkaline electrolytic cells according to the input power; wherein the LLC converters and the alkaline electrolytic cells are connected in parallel.

3. The photovoltaic hydrogen production modular system according to claim 1, wherein The second hydrogen production module includes: The hydrogen production submodule is used to set the cut-in target threshold, which includes a first cut-in threshold, a second cut-in threshold and a third cut-in threshold. Combined with the input power, it is determined whether to cut in several LLC converters and alkaline electrolyzers. When the input power is greater than the first cut-in threshold and less than or equal to the second cut-in threshold, the several LLC converters and alkaline electrolyzers are not cut in. When the input power is greater than the second cut-in threshold and less than or equal to the third cut-in threshold, the several LLC converters and alkaline electrolyzers are cut in to prepare hydrogen.

4. The photovoltaic hydrogen production modular system according to claim 3, wherein The hydrogen production submodule includes: A control unit is used to obtain the terminal voltage and terminal current of the alkaline electrolyzer when several LLC converters and alkaline electrolyzers are switched on, obtain actual power based on the terminal voltage and the terminal current, set a power setting value of the alkaline electrolyzer, subtract the actual power from the power setting value, obtain a current reference value through a first PI controller, subtract the current reference value from the terminal current value, obtain a trigger signal of the LLC converter through a second PI controller, and control the several LLC converters and the alkaline electrolyzers based on the trigger signal to prepare hydrogen.

5. The photovoltaic hydrogen production modular system according to claim 3, characterized in that The hydrogen production submodule further includes: The device optimization unit is used to collect the operating frequency of the LLC converter, obtain the operating status of the LLC converter through the operating frequency, and select a parameter range of the LLC converter based on the operating status to improve the operating efficiency of the LLC converter.

6. The photovoltaic hydrogen production modular system according to claim 5, characterized in that, The working states include: an under-resonance working state, a quasi-resonance working state and an over-resonance working state.

7. The photovoltaic hydrogen production modular system according to claim 1, wherein According to the input power, the automatic start and stop method is: Among them, signal is the switching signal, and P is the input power.

8. The photovoltaic hydrogen production modular system according to claim 1, characterized in that, The hydrogen production subsystem further includes: Gas-liquid separation module, used to separate gas and KOH solution in hydrogen-containing mixed liquid or oxygen-containing mixed liquid to reduce the moisture content in the gas; purification module for removing impurities; A gas collection and storage module, used to collect the prepared hydrogen and store the collected hydrogen; Wherein, the gas-liquid separation module, the purification module and the gas collection and storage module are connected in sequence.