Overall immersion / local movement integrated hydrogen permeation capacity detection device suitable for water-based and non-water-based media

Abstract

The invention discloses an integral immersion / local movement integrated hydrogen permeation capacity detection device suitable for water-based and non-water-based media, and aims to solve the problem that a hydrogen permeation capacity monitoring device suitable for alternate deposition working conditions is lacked in the prior art. The integrated hydrogen permeation capacity detection device comprises an electro-deposition module, an electric brush plating module, a hydrogen permeation detection module and a solution circulation system, a sealing cover covers an electro-deposition tank, and a first power source is electrically connected with a first auxiliary electrode, a first reference electrode and a workpiece in the electro-deposition process; the electric brush plating module comprises a second power supply, a mechanical arm, a brush plating pen and a solution bottle, the hydrogen permeation detection module comprises a third power supply, a second auxiliary electrode, a second reference electrode and a hydrogen detection pool, and the solution circulation system provides solution circulation and temperature control functions. Through the multi-module integrated design, the hydrogen permeation dynamic state in different technological processes can be comprehensively and systematically detected, and meanwhile, the interference of bubbles on the deposition and detection process can be reduced.

Description

Technical Field

[0001] The invention relates to an integrated hydrogen permeation detection device, which is particularly applicable to detecting hydrogen permeation in electrodeposition, brush plating, alternating electrodeposition and brush plating processes and hydrogen charging processes. Background Art

[0002] As one of the core mechanisms of material failure, hydrogen embrittlement poses a risk throughout the entire material life cycle, encompassing both manufacturing and service applications. Reducing the hazards of hydrogen embrittlement has always been a major concern. Electrodeposition technology plays an irreplaceable and important role in the field of surface processing because it can deposit complex samples, has significant economic benefits, and is simple and easy to mass-produce. However, since most electrodepositions rely on aqueous solutions as the deposition environment and ion source, water dissociation reactions (H2O→H + +OH - ) and hydrogen evolution reaction (H + +e - →H), some of the generated active hydrogen atoms recombine to form hydrogen molecules and escape, while others diffuse into the substrate. This hydrogen permeation behavior causes lattice distortion and stress concentration at the microscale, and at the macroscale, it leads to embrittlement and delayed fracture of the coating. To address this problem, precise monitoring of changes in hydrogen evolution during surface modification can be used to adjust process parameters in a timely manner, effectively reducing the probability of hydrogen embrittlement and improving the stability and reliability of the coating. Current research primarily uses a dual-electrolytic cell system, as described in the paper "Hydrogen Permeation Behavior and Corrosion Resistance of Zn-Ni Alloy Electrodeposition," to achieve dynamic monitoring of hydrogen permeation.

[0003] In the field of modern surface engineering, brush plating has become a key branch of electrodeposition technology due to its unique non-immersion operation mode. Conventional electrodeposition achieves global electrochemical deposition by immersing the entire workpiece in an electrolyte system; brush plating uses a plating pen to dynamically apply electrolyte to achieve localized, targeted deposition. The former exhibits excellent coating uniformity and deposition efficiency, significantly improving the material's corrosion resistance and wear resistance. The latter, by virtue of its ability to precisely control the coating composition and structure, imparts unique physical and chemical properties to the material. The combination of the two can achieve multiple performance optimization combinations on the same workpiece, meeting the stringent material performance requirements of complex working conditions. However, due to differences in process principles and equipment configurations, traditional electrodeposition and brush plating have long been used independently, making it difficult to achieve complementary process advantages. Furthermore, this composite process experiences a cumulative effect of hydrogen permeation during dynamic switching, and no detection technology has yet developed a hydrogen permeation monitoring device suitable for alternating deposition conditions. Consequently, process parameter optimization lacks a quantitative evaluation basis for hydrogen-induced damage. Summary of the Invention

[0004] The object of the present invention is to solve the problem of the lack of a hydrogen permeation amount monitoring device applicable to alternating deposition conditions in the prior art, and to provide an integrated hydrogen permeation amount detection device for overall immersion / local movement applicable to aqueous and non-aqueous media.

[0005] The integrated hydrogen permeation amount detection device for overall immersion / local movement applicable to aqueous and non-aqueous media of the present invention comprises an electroplating module, an electro-brush plating module, a hydrogen permeation detection module and a solution circulation system; the electroplating module comprises a first power supply, an electroplating cell, a first auxiliary electrode, a first reference electrode, a workpiece, a fixture and a sealing cover, the sealing cover is arranged on the electroplating cell, in the electroplating process, the first power supply is electrically connected to the first auxiliary electrode, the first reference electrode and the workpiece respectively, the workpiece serves as a working electrode, the fixture is arranged at the bottom of the electroplating cell, and the workpiece is clamped in the fixture;

[0006] The electro-brush plating module comprises a second power supply, a robotic arm, an electro-brush plating pen and a (piston type) solution bottle, the electro-brush plating pen is installed on the robotic arm, the solution bottle is installed on the sealing cover, in the electro-brush plating process, the second power supply is electrically connected to the electro-brush plating pen and the workpiece, the robotic arm passes through the sealing cover to make the electro-brush plating pen contact with the workpiece, and the solution bottle is filled with electro-brush plating solution;

[0007] The hydrogen permeation detection module comprises a third power supply, a second auxiliary electrode, a second reference electrode and a hydrogen detection cell, the third power supply is electrically connected to the second auxiliary electrode, the second reference electrode and the workpiece respectively, the second auxiliary electrode and the second reference electrode are located in the hydrogen detection cell, the upper surface of the workpiece communicates with the electroplating cell, and the lower surface of the workpiece communicates with the hydrogen detection cell;

[0008] The solution circulation system comprises a circulation tank, a first water inlet pipe, a first water outlet pipe and a first circulation pump, the water outlet of the circulation tank is connected to the water inlet of the electroplating cell through the first water inlet pipe, the first circulation pump is arranged on the first water inlet pipe, and the water outlet of the electroplating cell is connected to the water inlet of the circulation tank through the first water outlet pipe.

[0009] The integrated hydrogen permeation amount detection device of the present invention can satisfy the electroplating process, the electro-brush plating process or the alternating process of electroplating and electro-brush plating of the substrate in aqueous and non-aqueous media, detect the hydrogen permeation amount in this process, and can reduce the interference of bubbles on the deposition and detection processes.

[0010] It is difficult for the prior art to flexibly carry out various surface treatment processes under closed conditions. The present invention enables the substrate to perform electroplating, brush plating, and their alternating operations under closed conditions, and to detect the hydrogen permeation amount. Electroplating under a closed environment can avoid impurity interference, make the coating more uniform and dense, and improve the corrosion resistance and wear resistance of the substrate; brush plating can precisely control the volatilization and pollution of the plating solution and achieve precise repair of the substrate surface; the alternation of electroplating and brush plating can give play to the advantages of both and realize the optimal combination of the substrate performance to meet the requirements of complex working conditions. At the same time, the present invention can detect the hydrogen permeation amount in real time and accurately during the above process. By detecting the hydrogen permeation amount, potential problems can be discovered in time and adjusted and controlled to ensure the substrate performance and coating quality. Description of the Drawings

[0011] Figure 1 It is a schematic structural diagram of an integrated hydrogen permeation amount detection device for overall immersion / local movement applicable to aqueous and non-aqueous media according to the present invention;

[0012] Figure 2 It is a schematic structural diagram of a movable sealing slider;

[0013] Figure 3 It is a partial schematic structural diagram of a fixture. Detailed Embodiments

[0014] Detailed Embodiment 1: The integrated hydrogen permeation amount detection device for overall immersion / local movement applicable to aqueous and non-aqueous media in this embodiment includes an electroplating module, a brush plating module, a hydrogen permeation detection module, and a solution circulation system; the electroplating module includes a first power supply 1, an electroplating cell 2, a first auxiliary electrode 3, a first reference electrode 4, a workpiece 5, a fixture 6, and a sealing cover 26. The sealing cover 26 is covered on the electroplating cell 2. In the electroplating process, the first power supply 1 is electrically connected to the first auxiliary electrode 3, the first reference electrode 4, and the workpiece 5 respectively. The workpiece 5 serves as a working electrode. The fixture 6 is arranged at the bottom of the electroplating cell 2 (outside), and the workpiece 5 is clamped in the fixture 6;

[0015] The brush plating module includes a second power supply 7, a robotic arm 8, a brush plating pen 9, and a (piston-type) solution bottle 10. The brush plating pen 9 is installed on the robotic arm 8, and the solution bottle 10 is installed on the sealing cover 26. In the brush plating process, the second power supply 7 is electrically connected to the brush plating pen 9 and the workpiece 5. The robotic arm 8 passes through the sealing cover 26 to make the brush plating pen 9 contact the workpiece 5, and the solution bottle 10 contains a brush plating solution;

[0016] The hydrogen permeation detection module includes a third power supply 11, a second auxiliary electrode 13, a second reference electrode 14, and a hydrogen detection cell 15. The third power supply 11 is electrically connected to the second auxiliary electrode 13, the second reference electrode 14, and the workpiece 5 respectively. The second auxiliary electrode 13 and the second reference electrode 14 are located inside the hydrogen detection cell 15. The upper surface of the workpiece 5 communicates with the electrodeposition cell 2, and the lower surface of the workpiece 5 communicates with the hydrogen detection cell 15.

[0017] The solution circulation system includes a circulation tank 25, a first water inlet pipe 17-1, a first water outlet pipe 20-1, and a first circulation pump 24-1. The water outlet of the circulation tank 25 is connected to the water inlet of the electrodeposition cell 2 through the first water inlet pipe 17-1. A first circulation pump 24-1 is provided on the first water inlet pipe 17-1. The water outlet of the electrodeposition cell 2 is connected to the water inlet of the circulation tank 25 through the first water outlet pipe 20-1.

[0018] This embodiment is applicable to aqueous and non-aqueous media. The aqueous medium is an electrodeposition solution prepared with water as the solvent, and the non-aqueous solution is a solution prepared with an ionic solution (such as a eutectic solution) as the medium.

[0019] This embodiment includes an electrodeposition module, a brush plating module, a hydrogen permeation detection module, and a solution circulation system. The electrodeposition module and the brush plating module provide a working environment for electrodeposition and brush plating. The hydrogen permeation detection module detects the amount of hydrogen atoms permeating through the specimen. The solution circulation system provides the functions of solution circulation and temperature control. The electrodeposition module and the hydrogen permeation detection module are in an up-and-down structure, which can reduce the interference caused by bubbles during the processing and detection processes.

[0020] By using an integral immersion / local movement integrated hydrogen permeation amount detection device applicable to aqueous and non-aqueous media, this embodiment enables the substrate to perform alternating operations of electrodeposition and brush plating under closed conditions, and detects the hydrogen permeation amount during this processing. Electrodeposition in a closed environment can avoid impurity interference, make the coating more uniform and dense, and improve the corrosion resistance and wear resistance of the substrate. Brush plating can precisely control the volatilization and pollution of the plating solution and achieve precise plating on the surface of the substrate. The alternation of electrodeposition and brush plating can give full play to the advantages of both and achieve an optimized combination of the substrate properties to meet the requirements of complex working conditions. At the same time, the present invention can detect the hydrogen permeation amount in real time and accurately during the above process. By detecting the hydrogen permeation amount, potential problems can be discovered in time and adjusted and controlled to ensure the substrate properties and coating quality.

[0021] Specific Embodiment 2: The difference between this embodiment and Specific Embodiment 1 is that a sealing device is provided on the sealing cover 26. The sealing device includes a guiding slider 27-3, a spring 27-4, and two fixed end members 27-5. A rectangular hole is formed on the sealing cover 26. The two fixed end members 27-5 are oppositely arranged at both ends of the rectangular hole. Oppositely arranged grooves are formed on the two fixed end members 27-5. Both ends of the guiding slider 27-3 are respectively inserted into the grooves of the two fixed end members 27-5. A spring 27-4 is arranged between the end of the guiding slider 27-3 and the fixed end member 27-5. A through hole 27-1 is formed on the guiding slider 27-3, and the robotic arm 8 passes through the through hole 27-1.

[0022] Specific Embodiment 3: The difference between this embodiment and Specific Embodiment 2 is that a second sealing rubber ring 27-2 is arranged between the robotic arm 8 and the through hole 27-1.

[0023] Specific Embodiment 4: The difference between this embodiment and any one of Specific Embodiments 1 to 3 is that an electroplating solution is contained in the electro-deposition cell 2 during the electro-deposition process.

[0024] Specific Embodiment 5: The difference between this embodiment and any one of Specific Embodiments 1 to 4 is that an electrolyte solution is contained in the hydrogen detection cell 15.

[0025] Specific Embodiment 6: The difference between this embodiment and any one of Specific Embodiments 1 to 5 is that a porous ceramic membrane 12 is arranged in the hydrogen detection cell 15.

[0026] The ceramic membrane in this embodiment can prevent the gas generated during the hydrogen detection process from floating to the surface of the specimen and interfering with the detection process.

[0027] Specific Embodiment 7: The difference between this embodiment and any one of Specific Embodiments 1 to 6 is that a heater 22-1 is arranged in the electro-deposition cell 2 or the circulation cell 25.

[0028] Specific Embodiment 8: The difference between this embodiment and any one of Specific Embodiments 1 to 7 is that a first water inlet valve 18-1 is arranged on the first water inlet pipe 17-1, and a first water outlet valve 21-1 is arranged on the first water outlet pipe 20-1.

[0029] Specific Embodiment 9: The difference between this embodiment and any one of Specific Embodiments 1 to 8 is that the fixture 6 includes a plurality of bolts 6-2, an upper clamping plate 6-6, a lower clamping plate 6-3, and a sealing ring 6-4. A workpiece 5 is clamped between the upper clamping plate 6-6 and the lower clamping plate 6-3. The upper clamping plate 6-6 and the lower clamping plate 6-3 are connected by a plurality of bolts 6-2. An upper short pipe 6-1 is arranged on the upper surface of the upper clamping plate 6-6. The upper short pipe 6-1 is connected to the electro-deposition cell 2 by a thread. A lower short pipe 6-5 is arranged on the lower surface of the lower clamping plate 6-3. The lower short pipe 6-5 is inserted into the hydrogen detection cell 15.

[0030] In this embodiment, a sealing ring 6-4 is provided between the workpiece 5 and the upper clamping plate 6-6 and the lower clamping plate 6-3. A sealing ring 6-4 is also provided between the lower short pipe 6-5 and the hydrogen detection cell 15. The upper short pipe 6-1 communicates with the electroplating cell 2, and the lower short pipe 6-5 communicates with the hydrogen detection cell 15.

[0031] Specific Embodiment Ten: The difference between this embodiment and one of Embodiments One to Nine is that the solution circulation system further includes a second water inlet pipe 17-2, a second water outlet pipe 20-2, and a second circulation pump 24-2. The water outlet of the circulation tank 25 is connected to the water inlet of the electroplating cell 2 through the second water inlet pipe 17-2. A second circulation pump 24-2 is provided on the second water inlet pipe 17-2. The water outlet of the electroplating cell 2 is connected to the water inlet of the circulation tank 25 through the second water outlet pipe 20-2.

[0032] In this embodiment, a second water inlet valve 18-2 is provided on the second water inlet pipe 17-2, and a second water outlet valve 21-2 is provided on the second water outlet pipe 20-2.

[0033] In this embodiment, since the electroplating cell needs to be compatible with both the electroplating and electro-brush plating systems, which are relatively large, an additional set of solution circulation is added to ensure the smooth discharge of the solution.

[0034] Embodiment 1: The integrated hydrogen permeation amount detection device for overall immersion / local movement applicable to aqueous and non-aqueous media includes an electroplating module, an electro-brush plating module, a hydrogen permeation detection module, and a solution circulation system; the electroplating module includes a first power supply 1, an electroplating cell 2, a first auxiliary electrode 3, a first reference electrode 4, a workpiece 5, a fixture 6, and a sealing cover 26. The sealing cover 26 is provided on the electroplating cell 2. In the electroplating process, the first power supply 1 is electrically connected to the first auxiliary electrode 3, the first reference electrode 4, and the workpiece 5 respectively. The workpiece 5 serves as the working electrode, and the working electrode is connected to the "WE" port on the electrochemical workstation (first power supply). The first reference electrode 4 is connected to the "RE" port on the electrochemical workstation, and the first auxiliary electrode 3 is connected to the "CE" port on the electrochemical workstation. The fixture 6 is provided at the bottom of the electroplating cell 2, and the workpiece 5 is clamped in the fixture 6; the electro-brush plating module includes a second power supply 7, a robotic arm 8, an electro-brush plating pen 9, and a (piston-type) solution bottle 10. The electro-brush plating pen 9 is installed on the robotic arm 8. In the electro-brush plating process, the positive pole of the second power supply 7 is connected to the electro-brush plating pen 9, and the negative pole of the second power supply 7 is connected to the workpiece 5. A sealing device is provided on the sealing cover 26. The sealing device includes a sealing ring 27-2, a guiding slider 27-3, a spring 27-4, and two fixed end members 27-5. A rectangular hole is opened on the sealing cover 26. The two fixed end members 27-5 are oppositely arranged at both ends of the rectangular hole. Oppositely arranged grooves are opened on the two fixed end members 27-5. Both ends of the guiding slider 27-3 are respectively inserted into the grooves of the two fixed end members 27-5. A spring 27-4 is provided between the end of the guiding slider 27-3 and the fixed end member 27-5. A through hole 27-1 is opened on the guiding slider 27-3, and the robotic arm 8 passes through the through hole 27-1. The solution bottle 10 contains electro-brush plating solution, and the electro-brush plating solution dropped from the solution bottle 10 falls on the workpiece 5;

[0035] A third power supply 11 is electrically connected to a second auxiliary electrode 13, a second reference electrode 14, and the workpiece 5 respectively. The working electrode is connected to the "WE" port on the third power supply 11, the reference electrode is connected to the "RE" port on the third power supply 11, the second auxiliary electrode 13 is connected to the "CE" port on the electrochemical workstation, a data analyzer 16 detects electrical signals. The second auxiliary electrode 13 and the second reference electrode 14 are located in a hydrogen detection cell 15. The upper surface of the workpiece 5 communicates with the electroplating cell 2, and the lower surface of the workpiece 5 communicates with the hydrogen detection cell 15. The electrolyte contained in the hydrogen detection cell 15 is 0.2 mol / L NaOH solution;

[0036] The solution circulation system includes a circulation pool 25, an inlet pipe 17-1, an outlet pipe 20-1, and a circulation pump 24-1. The outlet of the circulation pool 25 is connected to the inlet of the electroplating cell 2 through the inlet pipe 17-1. A circulation pump 24-1 is provided on the inlet pipe 17-1. A first sealing rubber ring 19-1 is provided between the inlet pipe 17-1 and the electroplating cell 2. The outlet of the electroplating cell 2 is connected to the inlet of the circulation pool 25 through the outlet pipe 20-1.

[0037] In this embodiment, through modular design and function decoupling, the electro-brush plating module independently performs the electro-brush plating process and combines with the hydrogen permeation detection module to detect the hydrogen permeation amount. This embodiment is equipped with an independent DC adjustable power supply (the second power supply). During electro-brush plating, the electrode circuit can be automatically switched. Local potential control is achieved through the reference electrode built into the brush plating pen 9. The robotic arm 8 supports multiple motion paths, and the piston-type solution bottle 10 can also support various types of electro-brush plating solutions.

[0038] In this embodiment, through modular design and function decoupling, the electroplating module only performs the electroplating process and combines with the hydrogen permeation detection module to detect the hydrogen permeation amount. At this time, the brush plating pen 9 is in a non-working state. The robotic arm 8 controls the brush plating pen 9 to fold above the electroplating solution surface, ensuring a safe distance between the brush head and the liquid surface to avoid cross-contamination of the plating solutions.

[0039] In this embodiment, the electroplating module does not work, and the electroplating cell 2 acts as a hydrogen charging cell, cooperating with the hydrogen detection system to complete the hydrogen charging test.

[0040] Taking the example of first depositing nickel by the electro-brush plating method and then preparing a zinc-nickel coating by the electroplating method, this embodiment illustrates the hydrogen permeation amount detection process during the electro-brush plating - electroplating process:

[0041] 1.1 Material substrate

[0042] The substrate is a 35CrMnSiA high-strength steel sheet with a length of 15 mm, a width of 10 mm, and a thickness of 1 mm. First, it is polished and cleaned.

[0043] 1.2 Hydrogen detection process for electro-brush plating

[0044] ① Brush plating preparation: The workpiece 5 is fixed with a fixture 6. The workpiece 5 is connected to the negative pole of the second power supply 7 and serves as the anode. The brush plating pen 9 is made of nickel wire with a diameter of 0.3 mm wrapped with absorbent cotton. The brush plating pen 9 is connected to the positive pole of the second power supply 7 and serves as the cathode.

[0045] ② Activation: The piston-type solution bottle is filled with an activation solution composed of 10 mL / L of concentrated hydrochloric acid and 80 g / L of NaCl. At room temperature, with a voltage of 6 V and a plating pen moving rate of 3 - 5 m / min, activation treatment is carried out.

[0046] ③ Pre - nickel plating: The piston - type solution bottle is filled with pre - nickel plating solution. The pre - nickel plating solution contains nickel chloride 200 g / L and concentrated hydrochloric acid 15 ml / L. At room temperature, the voltage is 6 V, and the moving rate of the plating pen is 3 - 5 m / min for pre - nickel plating.

[0047] ④ Brush - plating nickel: The piston - type solution bottle is filled with brush - plating solution. The brush - plating solution includes nickel sulfate hydrate 200 - 300 g / L, sodium citrate 40 - 60 g / L, glacial acetic acid 20 - 30 ml / L, and ammonia water 100 - 120 ml / L. At room temperature, the voltage is 5 - 8 V and the moving rate of the plating pen is 3 - 5 m / min for brush - plating.

[0048] ⑤ Electron flow occurs on the side of the hydrogen detection cell, and the data recorder captures the hydrogen permeation current.

[0049] 1.3 Brush - plating and electro - deposition conversion process

[0050] The robotic arm controls the brush - plating pen to retract, above the electro - deposition liquid level. Power is cut off and anhydrous ethanol is put into the solution bottle to rinse the coating, and the waste liquid flows out through the circulation system.

[0051] 1.4 Hydrogen detection process of brush - plating technology

[0052] ① On the basis of the nickel coating, a zinc - nickel coating is electro - deposited using a three - electrode system. The workpiece to be plated serves as the working electrode, the silver electrode serves as the reference electrode, and the platinum electrode serves as the auxiliary electrode.

[0053] ② In the electro - deposition process, the solution uses a deep - eutectic solvent. Choline chloride (Ch Cl) and urea are mixed in a ratio of 1:2, vacuum - dried at 80 °C for 24 h, and then stirred at 500 r / min until clear and transparent to obtain the Ch C - Urea deep - eutectic solvent.

[0054] ③ 0.4 mol / L zinc chloride and 0.08 mol / L nickel chloride hexahydrate are added to this solution, and stirred at 70 °C until a clear electroplating solution is formed.

[0055] ④ The electroplating solution is placed in the electro - deposition cell, the current density is 0.2 mA / dm 2 , the deposition potential is - 0.6 V to - 1.2 V, power is turned on and electro - deposition begins.

[0056] ⑤ Electron flow occurs on the side of the hydrogen detection cell, and the data recorder captures the hydrogen permeation current.

[0057] The integrated hydrogen permeation detection device of the present invention has a high degree of flexibility and adaptability. It can not only independently conduct real-time detection of hydrogen permeation during the electroplating process or the brush plating process, but also monitor the hydrogen permeation during the alternating process of electroplating and brush plating. Through this integrated design, it is possible to comprehensively and systematically master the hydrogen permeation dynamics during different process and alternating processes, providing strong technical support for in-depth research on the hydrogen generation mechanism, optimization of process parameters, and improvement of product quality.

Claims

1. An integrated hydrogen permeation amount detection device for overall immersion / local movement applicable to aqueous and non-aqueous media, characterized in that An integrated hydrogen permeation detection device for overall immersion / local movement applicable to aqueous and non-aqueous media includes an electroplating module, an electro-brush plating module, a hydrogen permeation detection module, and a solution circulation system. The electroplating module includes a first power supply (1), an electroplating cell (2), a first auxiliary electrode (3), a first reference electrode (4), a workpiece (5), a fixture (6), and a sealing cover (26). The sealing cover (26) is placed on the electroplating cell (2). In the electroplating process, the first power supply (1) is electrically connected to the first auxiliary electrode (3), the first reference electrode (4), and the workpiece (5) respectively. The workpiece (5) serves as the working electrode. The fixture (6) is arranged at the bottom of the electroplating cell (2), and the workpiece (5) is clamped in the fixture (6). The electro-brush plating module includes a second power supply (7), a robotic arm (8), an electro-brush plating pen (9), and a solution bottle (10). The electro-brush plating pen (9) is installed on the robotic arm (8), and the solution bottle (10) is installed on the sealing cover (26). In the electro-brush plating process, the second power supply (7) is electrically connected to the electro-brush plating pen (9) and the workpiece (5). The robotic arm (8) passes through the sealing cover (26) to make the electro-brush plating pen (9) contact the workpiece (5). The solution bottle (10) contains electro-brush plating solution. The hydrogen permeation detection module includes a third power supply (11), a second auxiliary electrode (13), a second reference electrode (14), and a hydrogen detection cell (15). The third power supply (11) is electrically connected to the second auxiliary electrode (13), the second reference electrode (14), and the workpiece (5) respectively. The second auxiliary electrode (13) and the second reference electrode (14) are located in the hydrogen detection cell (15). The upper surface of the workpiece (5) communicates with the electroplating cell (2), and the lower surface of the workpiece (5) communicates with the hydrogen detection cell (15). The solution circulation system includes a circulation pool (25), a first water inlet pipe (17-1), a first water outlet pipe (20-1), and a first circulation pump (24-1). The water outlet of the circulation pool (25) is connected to the water inlet of the electroplating cell (2) through the first water inlet pipe (17-1). A first circulation pump (24-1) is arranged on the first water inlet pipe (17-1). The water outlet of the electroplating cell (2) is connected to the water inlet of the circulation pool (25) through the first water outlet pipe (20-1).

2. The integrated immersion / local movement hydrogen permeation amount detection device applicable to aqueous and non-aqueous media according to claim 1, wherein A sealing device is arranged on the sealing cover (26). The sealing device includes a guiding slider (27-3), a spring (27-4), and two fixed end members (27-5). A rectangular hole is opened on the sealing cover (26). The two fixed end members (27-5) are arranged oppositely at both ends of the rectangular hole. Oppositely arranged grooves are opened on the two fixed end members (27-5). Both ends of the guiding slider (27-3) are inserted into the grooves of the two fixed end members (27-5) respectively. A spring (27-4) is arranged between the end of the guiding slider (27-3) and the fixed end member (27-5). A through hole (27-1) is opened on the guiding slider (27-3), and the robotic arm (8) passes through the through hole (27-1).

3. The integrated immersion / local movement hydrogen permeation amount detection device applicable to aqueous and non-aqueous media according to claim 2, characterized in that A second sealing rubber ring (27-2) is arranged between the robotic arm (8) and the through hole (27-1).

4. The integrated immersion / local movement hydrogen permeation amount detection device applicable to aqueous and non-aqueous media according to claim 1, characterized in that In the electroplating process, the electroplating cell (2) contains electroplating solution.

5. The integrated immersion / local movement hydrogen permeation amount detection device applicable to aqueous and non-aqueous media according to claim 1, characterized in that The hydrogen detection cell (15) is filled with electrolyte solution.

6. The integrated immersion / local movement hydrogen permeation amount detection device applicable to aqueous and non-aqueous media according to claim 1, characterized in that The hydrogen detection cell (15) is provided with a porous ceramic membrane (12).

7. The integrated immersion / local movement hydrogen permeation amount detection device applicable to aqueous and non-aqueous media according to claim 1, characterized in that A heater (22-1) is provided in the electrodeposition cell (2) or the circulation cell (25).

8. The integrated immersion / local movement hydrogen permeation amount detection device applicable to aqueous and non-aqueous media according to claim 1, characterized in that A first water inlet valve (18-1) is provided on the first water inlet pipe (17-1), and a first water outlet valve (21-1) is provided on the first water outlet pipe (20-1).

9. The integrated immersion / local movement hydrogen permeation amount detection device applicable to aqueous and non-aqueous media according to claim 1, characterized in that The fixture (6) includes a plurality of bolts (6-2), an upper clamping plate (6-6), a lower clamping plate (6-3) and a sealing ring (6-4). A workpiece (5) is clamped between the upper clamping plate (6-6) and the lower clamping plate (6-3). The upper clamping plate (6-6) and the lower clamping plate (6-3) are connected by a plurality of bolts (6-2). An upper short pipe (6-1) is provided on the upper surface of the upper clamping plate (6-6), and the upper short pipe (6-1) is connected to the electrodeposition cell (2) by threads. A lower short pipe (6-5) is provided on the lower surface of the lower clamping plate (6-3), and the lower short pipe (6-5) is inserted into the hydrogen detection cell (15).

10. The integrated immersion / local movement hydrogen permeation amount detection device applicable to aqueous and non-aqueous media according to claim 1, characterized in that The solution circulation system further includes a second water inlet pipe (17-2), a second water outlet pipe (20-2) and a second circulation pump (24-2). The water outlet of the circulation cell (25) is connected to the water inlet of the electrodeposition cell (2) through the second water inlet pipe (17-2). A second circulation pump (24-2) is provided on the second water inlet pipe (17-2). The water outlet of the electrodeposition cell (2) is connected to the water inlet of the circulation cell (25) through the second water outlet pipe (20-2).

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