Composition, polarized light emitting element, light emitting element and application

Abstract

The invention provides a composition. The composition contains compounds as shown in a formula (I) and a formula II as a first compound and a second compound: # imgabs0, and other detailed information is described in the specification. The composition can generate exciplex luminescence with polarization luminescence characteristics under light induction. The compounds can be used for preparing OLED devices with polarized light emission.

Description

Technical Field

[0001] The present invention belongs to the field of organic luminescence, and in particular relates to a composition having polarized luminescence, a luminescent element containing the composition, and applications thereof. Background Art

[0002] Polarized luminescence has attracted widespread attention and research, with applications in fields such as encryption, display, and medicine. In particular, organic light-emitting diodes (OLEDs) can be used to prepare a new generation of light-emitting elements with polarized luminescence. Many papers have been published on single-molecule polarized luminescence, but research on polarized luminescence from composites is relatively limited. Building on existing research, the present invention proposes a novel composition that can achieve exciplex luminescence. A compound having a para-aromatic ring structure is used as the first compound in the composition to obtain exciplex luminescence with polarized luminescence characteristics, particularly blue and green exciplex luminescence, and demonstrates their potential application in the OLED field. Summary of the Invention

[0003] In order to obtain polarized luminescence of an exciplex, the present invention provides a composition comprising at least one or more compounds represented by formula (I) and chemical formula II:

[0004] Formula (I) is shown below:

[0005] wherein L is independently selected from a combination of two or more of the following structures,

[0006] L 1 Independently selected from one of the following structures:

[0007]

[0008] L 2 Absent, or independently selected from a single bond, NR 1 , CR 1 R 2 、SiR 1 R 2 , O, S, or one of the following structures:

[0009]

[0010] Above R, R 1 、R 2independently selected from H, D, F, or substituted or unsubstituted C1-C30 alkyl, substituted or unsubstituted C1-C30 cycloalkyl, substituted or unsubstituted C1-C30 heteroalkyl, substituted or unsubstituted C6-C30 aryl, substituted or unsubstituted C1-C30 heteroaryl, substituted or unsubstituted C1-C30 silicon

[0011] One of; n is 0 or an integer from 1 to 6;

[0012] Chemical formula II is shown below:

[0013]

[0014] In Formula II, Y1 to Y6 are independently selected from N or C-L4-R 4 At least two of Y1 to Y6 are N; L4 is independently selected from a single bond, a substituted or unsubstituted C6-C20 arylene group, a substituted or unsubstituted C2-C20 heterocyclic group, or a combination thereof; R 4 independently selected from hydrogen, deuterium, CN, halogen, substituted or unsubstituted C1-C60 alkyl, substituted or unsubstituted C1-C60 cycloalkyl, substituted or unsubstituted C1-C60 heteroalkyl, substituted or unsubstituted C6-C60 aryl, substituted or unsubstituted C1-C60 heteroaryl, substituted or unsubstituted C1-C60 silicon, substituted or unsubstituted C1-C60 amino; when adjacent R 4 When there are two or more, they can form a ring with each other; in Formula I or Formula II, R 1 to R 4 Each independently may be partially or fully deuterated, each independently may be partially or fully fluorinated; R 1 to R 4 It can be unsubstituted or polysubstituted according to the principle of valence.

[0015] Preferably, L in formula (I) is independently selected from one of the following structures to form a cyclophane, but this does not mean that the present invention is limited thereto:

[0016]

[0017] Wherein R is independently selected from one of hydrogen, deuterium, F, C1-C6 alkyl, C1-C6 heteroalkyl, substituted or unsubstituted C1-C30 cycloalkyl, substituted or unsubstituted C6-C30 aryl, or substituted or unsubstituted C1-C30 heteroaryl.

[0018] Preferably, formula (I) is independently selected from one of formula 2-1 to formula 2-12, but is not limited thereto:

[0019]

[0020] X in Formula 2-1 to Formula 2-12 is independently selected from CR 1 R 2 、SiR 1 R 2 , O; Y is a single bond or independently selected from CR 1 R 2 、SiR 1 R 2 , O, R, R 1 、R 2 Independently selected from H, D, F, or one selected from substituted or unsubstituted C1-C30 alkyl, substituted or unsubstituted C1-C30 cycloalkyl, substituted or unsubstituted C1-C30 heteroalkyl, substituted or unsubstituted C6-C30 aryl, substituted or unsubstituted C1-C30 heteroaryl, substituted or unsubstituted C1-C30 silicon.

[0021] Preferably, Chemical Formula II is selected from one of the structures represented by E-1 or E-2, but is not limited thereto:

[0022]

[0023] Among them, L4, R 1 to R 4 Same as the above definition.

[0024] Preferably, the compound represented by formula (I) is selected from one of the following structures, but is not limited thereto:

[0025]

[0026] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1 H H S-30 S-1 Compound-51 H S-1 S-30 S-1 Compound-2 H H S-30 S-2 Compound-52 H S-1 S-30 S-2 Compound-3 H H S-30 S-3 Compound-53 H S-1 S-30 S-3 Compound-4 H H S-30 S-4 Compound-54 H S-1 S-30 S-4 Compound-5 H H S-30 S-5 Compound-55 H S-1 S-30 S-5 Compound-6 H H S-30 S-6 Compound-56 H S-1 S-30 S-6 Compound-7 H H S-30 S-7 Compound-57 H S-1 S-30 S-7 Compound-8 H H S-30 S-8 Compound-58 H S-1 S-30 S-8 Compound-9 H H S-30 S-9 Compound-59 H S-1 S-30 S-9 Compound-10 H H S-30 S-12 Compound-60 H S-1 S-30 S-12 Compound-11 H H S-30 S-13 Compound-61 H S-1 S-30 S-13 Compound-12 H H S-30 S-14 Compound-62 H S-1 S-30 S-14 Compound-13 H H S-30 S-15 Compound-63 H S-1 S-30 S-15 Compound-14 H H S-30 S-16 Compound-64 H S-1 S-30 S-16 Compound-15 H H S-30 S-18 Compound-65 H S-1 S-30 S-18 Compound-16 H H S-30 S-19 Compound-66 H S-1 S-30 S-19 Compound-17 H H S-30 S-20 Compound-67 H S-1 S-30 S-20 Compound-18 H H S-30 S-21 Compound-68 H S-1 S-30 S-21 Compound-19 H H S-30 S-30 Compound-69 H S-1 S-30 S-30 Compound-20 H H S-30 S-31 Compound-70 H S-1 S-30 S-31 Compound-21 H H S-30 S-32 Compound-71 H S-1 S-30 S-32 Compound-22 H H S-30 S-33 Compound-72 H S-1 S-30 S-33 Compound-23 H H S-30 S-34 Compound-73 H S-1 S-30 S-34 Compound-24 H H S-30 S-35 Compound-74 H S-1 S-30 S-35 Compound-25 H H S-30 S-36 Compound-75 H S-1 S-30 S-36 Compound-26 H H S-30 S-37 Compound-76 H S-1 S-30 S-37 Compound-27 H H S-30 S-38 Compound-77 H S-1 S-30 S-38 Compound-28 H H S-30 S-39 Compound-78 H S-1 S-30 S-39 Compound-29 H H S-30 S-40 Compound-79 H S-1 S-30 S-40 Compound-30 H H S-30 S-41 Compound-80 H S-1 S-30 S-41 Compound-31 H H S-30 S-42 Compound-81 H S-1 S-30 S-42 Compound-32 H H S-30 S-43 Compound-82 H S-1 S-30 S-43 Compound-33 H H S-30 S-44 Compound-83 H S-1 S-30 S-44 Compound-34 H H S-30 S-45 Compound-84 H S-1 S-30 S-45 Compound-35 H H S-30 S-46 Compound-85 H S-1 S-30 S-46 Compound-36 H H S-30 S-48 Compound-86 H S-1 S-30 S-48 Compound-37 H H S-30 S-49 Compound-87 H S-1 S-30 S-49 Compound-38 H H S-30 S-51 Compound-88 H S-1 S-30 S-51 Compound-39 H H S-30 S-55 Compound-89 H S-1 S-30 S-55 Compound-40 H H S-30 S-56 Compound-90 H S-1 S-30 S-56 Compound-41 H H S-30 S-57 Compound-91 H S-1 S-30 S-57 Compound-42 H H S-30 S-58 Compound-92 H S-1 S-30 S-58 Compound-43 H H S-30 S-59 Compound-93 H S-1 S-30 S-59 Compound-44 H H S-30 S-60 Compound-94 H S-1 S-30 S-60 Compound-45 H H S-30 S-61 Compound-95 H S-1 S-30 S-61 Compound-46 H H S-30 S-63 Compound-96 H S-1 S-30 S-63 Compound-47 H H S-30 S-64 Compound-97 H S-1 S-30 S-64 Compound-48 H H S-30 S-66 Compound-98 H S-1 S-30 S-66 Compound-49 H H S-30 S-67 Compound-99 H S-1 S-30 S-67 Compound-50 H H S-30 S-68 Compound-100 H S-1 S-30 S-68

[0027]

[0028] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-101 H H S-30 H Compound-151 H H S-54 H Compound-102 H S-1 S-30 H Compound-152 H S-1 S-54 H Compound-103 H S-3 S-30 H Compound-153 H S-3 S-54 H Compound-104 H S-4 S-30 H Compound-154 H S-4 S-54 H Compound-105 H S-5 S-30 H Compound-155 H S-5 S-54 H Compound-106 H S-6 S-30 H Compound-156 H S-6 S-54 H Compound-107 H S-7 S-30 H Compound-157 H S-7 S-54 H Compound-108 H S-8 S-30 H Compound-158 H S-8 S-54 H Compound-109 H S-9 S-30 H Compound-159 H S-9 S-54 H Compound-110 H S-12 S-30 H Compound-160 H S-12 S-54 H Compound-111 H S-13 S-30 H Compound-161 H S-13 S-54 H Compound-112 H S-14 S-30 H Compound-162 H S-14 S-54 H Compound-113 H S-15 S-30 H Compound-163 H S-15 S-54 H Compound-114 H S-16 S-30 H Compound-164 H S-16 S-54 H Compound-115 H S-18 S-30 H Compound-165 H S-18 S-54 H Compound-116 H S-19 S-30 H Compound-166 H S-19 S-54 H Compound-117 H S-20 S-30 H Compound-167 H S-20 S-54 H Compound-118 H S-21 S-30 H Compound-168 H S-21 S-54 H Compound-119 H S-30 S-30 H Compound-169 H S-30 S-54 H Compound-120 H S-31 S-30 H Compound-170 H S-31 S-54 H Compound-121 H S-32 S-30 H Compound-171 H S-32 S-54 H Compound-122 H S-33 S-30 H Compound-172 H S-33 S-54 H Compound-123 H S-34 S-30 H Compound-173 H S-34 S-54 H Compound-124 H S-35 S-30 H Compound-174 H S-35 S-54 H Compound-125 H S-36 S-30 H Compound-175 H S-36 S-54 H Compound-126 H S-37 S-30 H Compound-176 H S-37 S-54 H Compound-127 H S-38 S-30 H Compound-177 H S-38 S-54 H Compound-128 H S-39 S-30 H Compound-178 H S-39 S-54 H Compound-129 H S-40 S-30 H Compound-179 H S-40 S-54 H Compound-130 H S-41 S-30 H Compound-180 H S-41 S-54 H Compound-131 H S-42 S-30 H Compound-181 H S-42 S-54 H Compound-132 H S-43 S-30 H Compound-182 H S-43 S-54 H Compound-133 H S-44 S-30 H Compound-183 H S-44 S-54 H Compound-134 H S-45 S-30 H Compound-184 H S-45 S-54 H Compound-135 H S-46 S-30 H Compound-185 H S-46 S-54 H Compound-136 H S-48 S-30 H Compound-186 H S-48 S-54 H Compound-137 H S-49 S-30 H Compound-187 H S-49 S-54 H Compound-138 H S-51 S-30 H Compound-188 H S-51 S-54 H Compound-139 H S-55 S-30 H Compound-189 H S-55 S-54 H Compound-140 H S-56 S-30 H Compound-190 H S-56 S-54 H Compound-141 H S-57 S-30 H Compound-191 H S-57 S-54 H Compound-142 H S-58 S-30 H Compound-192 H S-58 S-54 H Compound-143 H S-59 S-30 H Compound-193 H S-59 S-54 H Compound-144 H S-60 S-30 H Compound-194 H S-60 S-54 H Compound-145 H S-61 S-30 H Compound-195 H S-61 S-54 H Compound-146 H S-63 S-30 H Compound-196 H S-63 S-54 H Compound-147 H S-64 S-30 H Compound-197 H S-64 S-54 H Compound-148 H S-66 S-30 H Compound-198 H S-66 S-54 H Compound-149 H S-67 S-30 H Compound-199 H S-67 S-54 H Compound-150 H S-68 S-30 H Compound-200 H S-68 S-54 H

[0029]

[0030] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-201 S-30 S-1 S-30 H Compound-251 S-30 S-1 S-54 H Compound-202 S-30 S-2 S-30 H Compound-252 S-30 S-2 S-54 H Compound-203 S-30 S-3 S-30 H Compound-253 S-30 S-3 S-54 H Compound-204 S-30 S-4 S-30 H Compound-254 S-30 S-4 S-54 H Compound-205 S-30 S-5 S-30 H Compound-255 S-30 S-5 S-54 H Compound-206 S-30 S-6 S-30 H Compound-256 S-30 S-6 S-54 H Compound-207 S-30 S-7 S-30 H Compound-257 S-30 S-7 S-54 H Compound-208 S-30 S-8 S-30 H Compound-258 S-30 S-8 S-54 H Compound-209 S-30 S-9 S-30 H Compound-259 S-30 S-9 S-54 H Compound-210 S-30 S-12 S-30 H Compound-260 S-30 S-12 S-54 H Compound-211 S-30 S-13 S-30 H Compound-261 S-30 S-13 S-54 H Compound-212 S-30 S-14 S-30 H Compound-262 S-30 S-14 S-54 H Compound-213 S-30 S-15 S-30 H Compound-263 S-30 S-15 S-54 H Compound-214 S-30 S-16 S-30 H Compound-264 S-30 S-16 S-54 H Compound-215 S-30 S-18 S-30 H Compound-265 S-30 S-18 S-54 H Compound-216 S-30 S-19 S-30 H Compound-266 S-30 S-19 S-54 H Compound-217 S-30 S-20 S-30 H Compound-267 S-30 S-20 S-54 H Compound-218 S-30 S-21 S-30 H Compound-268 S-30 S-21 S-54 H Compound-219 S-30 S-30 S-30 H Compound-269 S-30 S-30 S-54 H Compound-220 S-30 S-31 S-30 H Compound-270 S-30 S-31 S-54 H Compound-221 S-30 S-32 S-30 H Compound-271 S-30 S-32 S-54 H Compound-222 S-30 S-33 S-30 H Compound-272 S-30 S-33 S-54 H Compound-223 S-30 S-34 S-30 H Compound-273 S-30 S-34 S-54 H Compound-224 S-30 S-35 S-30 H Compound-274 S-30 S-35 S-54 H Compound-225 S-30 S-36 S-30 H Compound-275 S-30 S-36 S-54 H Compound-226 S-30 S-37 S-30 H Compound-276 S-30 S-37 S-54 H Compound-227 S-30 S-38 S-30 H Compound-277 S-30 S-38 S-54 H Compound-228 S-30 S-39 S-30 H Compound-278 S-30 S-39 S-54 H Compound-229 S-30 S-40 S-30 H Compound-279 S-30 S-40 S-54 H Compound-230 S-30 S-41 S-30 H Compound-280 S-30 S-41 S-54 H Compound-231 S-30 S-42 S-30 H Compound-281 S-30 S-42 S-54 H Compound-232 S-30 S-43 S-30 H Compound-282 S-30 S-43 S-54 H Compound-233 S-30 S-44 S-30 H Compound-283 S-30 S-44 S-54 H Compound-234 S-30 S-45 S-30 H Compound-284 S-30 S-45 S-54 H Compound-235 S-30 S-46 S-30 H Compound-285 S-30 S-46 S-54 H Compound-236 S-30 S-48 S-30 H Compound-286 S-30 S-48 S-54 H Compound-237 S-30 S-49 S-30 H Compound-287 S-30 S-49 S-54 H Compound-238 S-30 S-51 S-30 H Compound-288 S-30 S-51 S-54 H Compound-239 S-30 S-55 S-30 H Compound-289 S-30 S-55 S-54 H Compound-240 S-30 S-56 S-30 H Compound-290 S-30 S-56 S-54 H Compound-241 S-30 S-57 S-30 H Compound-291 S-30 S-57 S-54 H Compound-242 S-30 S-58 S-30 H Compound-292 S-30 S-58 S-54 H Compound-243 S-30 S-59 S-30 H Compound-293 S-30 S-59 S-54 H Compound-244 S-30 S-60 S-30 H Compound-294 S-30 S-60 S-54 H Compound-245 S-30 S-61 S-30 H Compound-295 S-30 S-61 S-54 H Compound-246 S-30 S-63 S-30 H Compound-296 S-30 S-63 S-54 H Compound-247 S-30 S-64 S-30 H Compound-297 S-30 S-64 S-54 H Compound-248 S-30 S-66 S-30 H Compound-298 S-30 S-66 S-54 H Compound-249 S-30 S-67 S-30 H Compound-299 S-30 S-67 S-54 H Compound-250 S-30 S-68 S-30 H Compound-300 S-30 S-68 S-54 H

[0031]

[0032] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-301 H S-59 S-30 S-1 Compound-351 H S-41 S-30 S-1 Compound-302 H S-59 S-30 S-2 Compound-352 H S-41 S-30 S-2 Compound-303 H S-59 S-30 S-3 Compound-353 H S-41 S-30 S-3 Compound-304 H S-59 S-30 S-4 Compound-354 H S-41 S-30 S-4 Compound-305 H S-59 S-30 S-5 Compound-355 H S-41 S-30 S-5 Compound-306 H S-59 S-30 S-6 Compound-356 H S-41 S-30 S-6 Compound-307 H S-59 S-30 S-7 Compound-357 H S-41 S-30 S-7 Compound-308 H S-59 S-30 S-8 Compound-358 H S-41 S-30 S-8 Compound-309 H S-59 S-30 S-9 Compound-359 H S-41 S-30 S-9 Compound-310 H S-59 S-30 S-12 Compound-360 H S-41 S-30 S-12 Compound-311 H S-59 S-30 S-13 Compound-361 H S-41 S-30 S-13 Compound-312 H S-59 S-30 S-14 Compound-362 H S-41 S-30 S-14 Compound-313 H S-59 S-30 S-15 Compound-363 H S-41 S-30 S-15 Compound-314 H S-59 S-30 S-16 Compound-364 H S-41 S-30 S-16 Compound-315 H S-59 S-30 S-18 Compound-365 H S-41 S-30 S-18 Compound-316 H S-59 S-30 S-19 Compound-366 H S-41 S-30 S-19 Compound-317 H S-59 S-30 S-20 Compound-367 H S-41 S-30 S-20 Compound-318 H S-59 S-30 S-21 Compound-368 H S-41 S-30 S-21 Compound-319 H S-59 S-30 S-30 Compound-369 H S-41 S-30 S-30 Compound-320 H S-59 S-30 S-31 Compound-370 H S-41 S-30 S-31 Compound-321 H S-59 S-30 S-32 Compound-371 H S-41 S-30 S-32 Compound-322 H S-59 S-30 S-33 Compound-372 H S-41 S-30 S-33 Compound-323 H S-59 S-30 S-34 Compound-373 H S-41 S-30 S-34 Compound-324 H S-59 S-30 S-35 Compound-374 H S-41 S-30 S-35 Compound-325 H S-59 S-30 S-36 Compound-375 H S-41 S-30 S-36 Compound-326 H S-59 S-30 S-37 Compound-376 H S-41 S-30 S-37 Compound-327 H S-59 S-30 S-38 Compound-377 H S-41 S-30 S-38 Compound-328 H S-59 S-30 S-39 Compound-378 H S-41 S-30 S-39 Compound-329 H S-59 S-30 S-40 Compound-379 H S-41 S-30 S-40 Compound-330 H S-59 S-30 S-41 Compound-380 H S-41 S-30 S-41 Compound-331 H S-59 S-30 S-42 Compound-381 H S-41 S-30 S-42 Compound-332 H S-59 S-30 S-43 Compound-382 H S-41 S-30 S-43 Compound-333 H S-59 S-30 S-44 Compound-383 H S-41 S-30 S-44 Compound-334 H S-59 S-30 S-45 Compound-384 H S-41 S-30 S-45 Compound-335 H S-59 S-30 S-46 Compound-385 H S-41 S-30 S-46 Compound-336 H S-59 S-30 S-48 Compound-386 H S-41 S-30 S-48 Compound-337 H S-59 S-30 S-49 Compound-387 H S-41 S-30 S-49 Compound-338 H S-59 S-30 S-51 Compound-388 H S-41 S-30 S-51 Compound-339 H S-59 S-30 S-55 Compound-389 H S-41 S-30 S-55 Compound-340 H S-59 S-30 S-56 Compound-390 H S-41 S-30 S-56 Compound-341 H S-59 S-30 S-57 Compound-391 H S-41 S-30 S-57 Compound-342 H S-59 S-30 S-58 Compound-392 H S-41 S-30 S-58 Compound-343 H S-59 S-30 S-59 Compound-393 H S-41 S-30 S-59 Compound-344 H S-59 S-30 S-60 Compound-394 H S-41 S-30 S-60 Compound-345 H S-59 S-30 S-61 Compound-395 H S-41 S-30 S-61 Compound-346 H S-59 S-30 S-63 Compound-396 H S-41 S-30 S-63 Compound-347 H S-59 S-30 S-64 Compound-397 H S-41 S-30 S-64 Compound-348 H S-59 S-30 S-66 Compound-398 H S-41 S-30 S-66 Compound-349 H S-59 S-30 S-67 Compound-399 H S-41 S-30 S-67 Compound-350 H S-59 S-30 S-68 Compound-400 H S-41 S-30 S-68

[0033]

[0034] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-401 H H S-30 S-1 Compound-451 H S-30 S-30 S-1 Compound-402 H H S-30 S-2 Compound-452 H S-30 S-30 S-2 Compound-403 H H S-30 S-3 Compound-453 H S-30 S-30 S-3 Compound-404 H H S-30 S-4 Compound-454 H S-30 S-30 S-4 Compound-405 H H S-30 S-5 Compound-455 H S-30 S-30 S-5 Compound-406 H H S-30 S-6 Compound-456 H S-30 S-30 S-6 Compound-407 H H S-30 S-7 Compound-457 H S-30 S-30 S-7 Compound-408 H H S-30 S-8 Compound-458 H S-30 S-30 S-8 Compound-409 H H S-30 S-9 Compound-459 H S-30 S-30 S-9 Compound-410 H H S-30 S-12 Compound-460 H S-30 S-30 S-12 Compound-411 H H S-30 S-13 Compound-461 H S-30 S-30 S-13 Compound-412 H H S-30 S-14 Compound-462 H S-30 S-30 S-14 Compound-413 H H S-30 S-15 Compound-463 H S-30 S-30 S-15 Compound-414 H H S-30 S-16 Compound-464 H S-30 S-30 S-16 Compound-415 H H S-30 S-18 Compound-465 H S-30 S-30 S-18 Compound-416 H H S-30 S-19 Compound-466 H S-30 S-30 S-19 Compound-417 H H S-30 S-20 Compound-467 H S-30 S-30 S-20 Compound-418 H H S-30 S-21 Compound-468 H S-30 S-30 S-21 Compound-419 H H S-30 S-30 Compound-469 H S-30 S-30 S-30 Compound-420 H H S-30 S-31 Compound-470 H S-30 S-30 S-31 Compound-421 H H S-30 S-32 Compound-471 H S-30 S-30 S-32 Compound-422 H H S-30 S-33 Compound-472 H S-30 S-30 S-33 Compound-423 H H S-30 S-34 Compound-473 H S-30 S-30 S-34 Compound-424 H H S-30 S-35 Compound-474 H S-30 S-30 S-35 Compound-425 H H S-30 S-36 Compound-475 H S-30 S-30 S-36 Compound-426 H H S-30 S-37 Compound-476 H S-30 S-30 S-37 Compound-427 H H S-30 S-38 Compound-477 H S-30 S-30 S-38 Compound-428 H H S-30 S-39 Compound-478 H S-30 S-30 S-39 Compound-429 H H S-30 S-40 Compound-479 H S-30 S-30 S-40 Compound-430 H H S-30 S-41 Compound-480 H S-30 S-30 S-41 Compound-431 H H S-30 S-42 Compound-481 H S-30 S-30 S-42 Compound-432 H H S-30 S-43 Compound-482 H S-30 S-30 S-43 Compound-433 H H S-30 S-44 Compound-483 H S-30 S-30 S-44 Compound-434 H H S-30 S-45 Compound-484 H S-30 S-30 S-45 Compound-435 H H S-30 S-46 Compound-485 H S-30 S-30 S-46 Compound-436 H H S-30 S-48 Compound-486 H S-30 S-30 S-48 Compound-437 H H S-30 S-49 Compound-487 H S-30 S-30 S-49 Compound-438 H H S-30 S-51 Compound-488 H S-30 S-30 S-51 Compound-439 H H S-30 S-55 Compound-489 H S-30 S-30 S-55 Compound-440 H H S-30 S-56 Compound-490 H S-30 S-30 S-56 Compound-441 H H S-30 S-57 Compound-491 H S-30 S-30 S-57 Compound-442 H H S-30 S-58 Compound-492 H S-30 S-30 S-58 Compound-443 H H S-30 S-59 Compound-493 H S-30 S-30 S-59 Compound-444 H H S-30 S-60 Compound-494 H S-30 S-30 S-60 Compound-445 H H S-30 S-61 Compound-495 H S-30 S-30 S-61 Compound-446 H H S-30 S-63 Compound-496 H S-30 S-30 S-63 Compound-447 H H S-30 S-64 Compound-497 H S-30 S-30 S-64 Compound-448 H H S-30 S-66 Compound-498 H S-30 S-30 S-66 Compound-449 H H S-30 S-67 Compound-499 H S-30 S-30 S-67 Compound-450 H H S-30 S-68 Compound-500 H S-30 S-30 S-68

[0035]

[0036] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-501 H H S-30 S-1 Compound-551 H S-30 S-30 S-1 Compound-502 H H S-30 S-2 Compound-552 H S-30 S-30 S-2 Compound-503 H H S-30 S-3 Compound-553 H S-30 S-30 S-3 Compound-504 H H S-30 S-4 Compound-554 H S-30 S-30 S-4 Compound-505 H H S-30 S-5 Compound-555 H S-30 S-30 S-5 Compound-506 H H S-30 S-6 Compound-556 H S-30 S-30 S-6 Compound-507 H H S-30 S-7 Compound-557 H S-30 S-30 S-7 Compound-508 H H S-30 S-8 Compound-558 H S-30 S-30 S-8 Compound-509 H H S-30 S-9 Compound-559 H S-30 S-30 S-9 Compound-510 H H S-30 S-12 Compound-560 H S-30 S-30 S-12 Compound-511 H H S-30 S-13 Compound-561 H S-30 S-30 S-13 Compound-512 H H S-30 S-14 Compound-562 H S-30 S-30 S-14 Compound-513 H H S-30 S-15 Compound-563 H S-30 S-30 S-15 Compound-514 H H S-30 S-16 Compound-564 H S-30 S-30 S-16 Compound-515 H H S-30 S-18 Compound-565 H S-30 S-30 S-18 Compound-516 H H S-30 S-19 Compound-566 H S-30 S-30 S-19 Compound-517 H H S-30 S-20 Compound-567 H S-30 S-30 S-20 Compound-518 H H S-30 S-21 Compound-568 H S-30 S-30 S-21 Compound-519 H H S-30 S-30 Compound-569 H S-30 S-30 S-30 Compound-520 H H S-30 S-31 Compound-570 H S-30 S-30 S-31 Compound-521 H H S-30 S-32 Compound-571 H S-30 S-30 S-32 Compound-522 H H S-30 S-33 Compound-572 H S-30 S-30 S-33 Compound-523 H H S-30 S-34 Compound-573 H S-30 S-30 S-34 Compound-524 H H S-30 S-35 Compound-574 H S-30 S-30 S-35 Compound-525 H H S-30 S-36 Compound-575 H S-30 S-30 S-36 Compound-526 H H S-30 S-37 Compound-576 H S-30 S-30 S-37 Compound-527 H H S-30 S-38 Compound-577 H S-30 S-30 S-38 Compound-528 H H S-30 S-39 Compound-578 H S-30 S-30 S-39 Compound-529 H H S-30 S-40 Compound-579 H S-30 S-30 S-40 Compound-530 H H S-30 S-41 Compound-580 H S-30 S-30 S-41 Compound-531 H H S-30 S-42 Compound-581 H S-30 S-30 S-42 Compound-532 H H S-30 S-43 Compound-582 H S-30 S-30 S-43 Compound-533 H H S-30 S-44 Compound-583 H S-30 S-30 S-44 Compound-534 H H S-30 S-45 Compound-584 H S-30 S-30 S-45 Compound-535 H H S-30 S-46 Compound-585 H S-30 S-30 S-46 Compound-536 H H S-30 S-48 Compound-586 H S-30 S-30 S-48 Compound-537 H H S-30 S-49 Compound-587 H S-30 S-30 S-49 Compound-538 H H S-30 S-51 Compound-588 H S-30 S-30 S-51 Compound-539 H H S-30 S-55 Compound-589 H S-30 S-30 S-55 Compound-540 H H S-30 S-56 Compound-590 H S-30 S-30 S-56 Compound-541 H H S-30 S-57 Compound-591 H S-30 S-30 S-57 Compound-542 H H S-30 S-58 Compound-592 H S-30 S-30 S-58 Compound-543 H H S-30 S-59 Compound-593 H S-30 S-30 S-59 Compound-544 H H S-30 S-60 Compound-594 H S-30 S-30 S-60 Compound-545 H H S-30 S-61 Compound-595 H S-30 S-30 S-61 Compound-546 H H S-30 S-63 Compound-596 H S-30 S-30 S-63 Compound-547 H H S-30 S-64 Compound-597 H S-30 S-30 S-64 Compound-548 H H S-30 S-66 Compound-598 H S-30 S-30 S-66 Compound-549 H H S-30 S-67 Compound-599 H S-30 S-30 S-67 Compound-550 H H S-30 S-68 Compound-600 H S-30 S-30 S-68

[0037]

[0038] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-601 H S-66 S-30 H Compound-651 H S-67 S-30 H Compound-602 H S-66 S-30 S-1 Compound-652 H S-67 S-30 S-1 Compound-603 H S-66 S-30 S-3 Compound-653 H S-67 S-30 S-3 Compound-604 H S-66 S-30 S-4 Compound-654 H S-67 S-30 S-4 Compound-605 H S-66 S-30 S-5 Compound-655 H S-67 S-30 S-5 Compound-606 H S-66 S-30 S-6 Compound-656 H S-67 S-30 S-6 Compound-607 H S-66 S-30 S-7 Compound-657 H S-67 S-30 S-7 Compound-608 H S-66 S-30 S-8 Compound-658 H S-67 S-30 S-8 Compound-609 H S-66 S-30 S-9 Compound-659 H S-67 S-30 S-9 Compound-610 H S-66 S-30 S-12 Compound-660 H S-67 S-30 S-12 Compound-611 H S-66 S-30 S-13 Compound-661 H S-67 S-30 S-13 Compound-612 H S-66 S-30 S-14 Compound-662 H S-67 S-30 S-14 Compound-613 H S-66 S-30 S-15 Compound-663 H S-67 S-30 S-15 Compound-614 H S-66 S-30 S-16 Compound-664 H S-67 S-30 S-16 Compound-615 H S-66 S-30 S-18 Compound-665 H S-67 S-30 S-18 Compound-616 H S-66 S-30 S-19 Compound-666 H S-67 S-30 S-19 Compound-617 H S-66 S-30 S-20 Compound-667 H S-67 S-30 S-20 Compound-618 H S-66 S-30 S-21 Compound-668 H S-67 S-30 S-21 Compound-619 H S-66 S-30 S-30 Compound-669 H S-67 S-30 S-30 Compound-620 H S-66 S-30 S-31 Compound-670 H S-67 S-30 S-31 Compound-621 H S-66 S-30 S-32 Compound-671 H S-67 S-30 S-32 Compound-622 H S-66 S-30 S-33 Compound-672 H S-67 S-30 S-33 Compound-623 H S-66 S-30 S-34 Compound-673 H S-67 S-30 S-34 Compound-624 H S-66 S-30 S-35 Compound-674 H S-67 S-30 S-35 Compound-625 H S-66 S-30 S-36 Compound-675 H S-67 S-30 S-36 Compound-626 H S-66 S-30 S-37 Compound-676 H S-67 S-30 S-37 Compound-627 H S-66 S-30 S-38 Compound-677 H S-67 S-30 S-38 Compound-628 H S-66 S-30 S-39 Compound-678 H S-67 S-30 S-39 Compound-629 H S-66 S-30 S-40 Compound-679 H S-67 S-30 S-40 Compound-630 H S-66 S-30 S-41 Compound-680 H S-67 S-30 S-41 Compound-631 H S-66 S-30 S-42 Compound-681 H S-67 S-30 S-42 Compound-632 H S-66 S-30 S-43 Compound-682 H S-67 S-30 S-43 Compound-633 H S-66 S-30 S-44 Compound-683 H S-67 S-30 S-44 Compound-634 H S-66 S-30 S-45 Compound-684 H S-67 S-30 S-45 Compound-635 H S-66 S-30 S-46 Compound-685 H S-67 S-30 S-46 Compound-636 H S-66 S-30 S-48 Compound-686 H S-67 S-30 S-48 Compound-637 H S-66 S-30 S-49 Compound-687 H S-67 S-30 S-49 Compound-638 H S-66 S-30 S-51 Compound-688 H S-67 S-30 S-51 Compound-639 H S-66 S-30 S-55 Compound-689 H S-67 S-30 S-55 Compound-640 H S-66 S-30 S-56 Compound-690 H S-67 S-30 S-56 Compound-641 H S-66 S-30 S-57 Compound-691 H S-67 S-30 S-57 Compound-642 H S-66 S-30 S-58 Compound-692 H S-67 S-30 S-58 Compound-643 H S-66 S-30 S-59 Compound-693 H S-67 S-30 S-59 Compound-644 H S-66 S-30 S-60 Compound-694 H S-67 S-30 S-60 Compound-645 H S-66 S-30 S-61 Compound-695 H S-67 S-30 S-61 Compound-646 H S-66 S-30 S-63 Compound-696 H S-67 S-30 S-63 Compound-647 H S-66 S-30 S-64 Compound-697 H S-67 S-30 S-64 Compound-648 H S-66 S-30 S-66 Compound-698 H S-67 S-30 S-66 Compound-649 H S-66 S-30 S-67 Compound-699 H S-67 S-30 S-67 Compound-650 H S-66 S-30 S-68 Compound-700 H S-67 S-30 S-68

[0039]

[0040] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-701 H S-66 H H Compound-751 H S-68 H H Compound-702 H S-66 S-1 S-1 Compound-752 H S-67 S-1 S-1 Compound-703 H S-66 S-3 S-3 Compound-753 H S-67 S-3 S-3 Compound-704 H S-66 S-4 S-4 Compound-754 H S-67 S-4 S-4 Compound-705 H S-66 S-5 S-5 Compound-755 H S-67 S-5 S-5 Compound-706 H S-66 S-6 S-6 Compound-756 H S-67 S-6 S-6 Compound-707 H S-66 S-7 S-7 Compound-757 H S-67 S-7 S-7 Compound-708 H S-66 S-8 S-8 Compound-758 H S-67 S-8 S-8 Compound-709 H S-66 S-9 S-9 Compound-759 H S-67 S-9 S-9 Compound-710 H S-66 S-12 S-12 Compound-760 H S-67 S-12 S-12 Compound-711 H S-66 S-13 S-13 Compound-761 H S-67 S-13 S-13 Compound-712 H S-66 S-14 S-14 Compound-762 H S-67 S-14 S-14 Compound-713 H S-66 S-15 S-15 Compound-763 H S-67 S-15 S-15 Compound-714 H S-66 S-16 S-16 Compound-764 H S-67 S-16 S-16 Compound-715 H S-66 S-18 S-18 Compound-765 H S-67 S-18 S-18 Compound-716 H S-66 S-19 S-19 Compound-766 H S-67 S-19 S-19 Compound-717 H S-66 S-20 S-20 Compound-767 H S-67 S-20 S-20 Compound-718 H S-66 S-21 S-21 Compound-768 H S-67 S-21 S-21 Compound-719 H S-66 S-30 S-30 Compound-769 H S-67 S-30 S-30 Compound-720 H S-66 S-31 S-31 Compound-770 H S-67 S-31 S-31 Compound-721 H S-66 S-32 S-32 Compound-771 H S-67 S-32 S-32 Compound-722 H S-66 S-33 S-33 Compound-772 H S-67 S-33 S-33 Compound-723 H S-66 S-34 S-34 Compound-773 H S-67 S-34 S-34 Compound-724 H S-66 S-35 S-35 Compound-774 H S-67 S-35 S-35 Compound-725 H S-66 S-36 S-36 Compound-775 H S-67 S-36 S-36 Compound-726 H S-66 S-37 S-37 Compound-776 H S-67 S-37 S-37 Compound-727 H S-66 S-38 S-38 Compound-777 H S-67 S-38 S-38 Compound-728 H S-66 S-39 S-39 Compound-778 H S-67 S-39 S-39 Compound-729 H S-66 S-40 S-40 Compound-779 H S-67 S-40 S-40 Compound-730 H S-66 S-41 S-41 Compound-780 H S-67 S-41 S-41 Compound-731 H S-66 S-42 S-42 Compound-781 H S-67 S-42 S-42 Compound-732 H S-66 S-43 S-43 Compound-782 H S-67 S-43 S-43 Compound-733 H S-66 S-44 S-44 Compound-783 H S-67 S-44 S-44 Compound-734 H S-66 S-45 S-45 Compound-784 H S-67 S-45 S-45 Compound-735 H S-66 S-46 S-46 Compound-785 H S-67 S-46 S-46 Compound-736 H S-66 S-48 S-48 Compound-786 H S-67 S-48 S-48 Compound-737 H S-66 S-49 S-49 Compound-787 H S-67 S-49 S-49 Compound-738 H S-66 S-51 S-51 Compound-788 H S-67 S-51 S-51 Compound-739 H S-66 S-55 S-55 Compound-789 H S-67 S-55 S-55 Compound-740 H S-66 S-56 S-56 Compound-790 H S-67 S-56 S-56 Compound-741 H S-66 S-57 S-57 Compound-791 H S-67 S-57 S-57 Compound-742 H S-66 S-58 S-58 Compound-792 H S-67 S-58 S-58 Compound-743 H S-66 S-59 S-59 Compound-793 H S-67 S-59 S-59 Compound-744 H S-66 S-60 S-60 Compound-794 H S-67 S-60 S-60 Compound-745 H S-66 S-61 S-61 Compound-795 H S-67 S-61 S-61 Compound-746 H S-66 S-63 S-63 Compound-796 H S-67 S-63 S-63 Compound-747 H S-66 S-64 S-64 Compound-797 H S-67 S-64 S-64 Compound-748 H S-66 S-66 S-66 Compound-798 H S-67 S-66 S-66 Compound-749 H S-66 S-67 S-67 Compound-799 H S-67 S-67 S-67 Compound-750 H S-66 S-68 S-68 Compound-800 H S-67 S-68 S-68

[0041]

[0042] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-801 S-1 S-66 H H Compound-851 S-1 S-67 H H Compound-802 S-1 S-66 S-1 S-1 Compound-852 S-1 S-67 S-1 S-1 Compound-803 S-1 S-66 S-3 S-3 Compound-853 S-1 S-67 S-3 S-3 Compound-804 S-1 S-66 S-4 S-4 Compound-854 S-1 S-67 S-4 S-4 Compound-805 S-1 S-66 S-5 S-5 Compound-855 S-1 S-67 S-5 S-5 Compound-806 S-1 S-66 S-6 S-6 Compound-856 S-1 S-67 S-6 S-6 Compound-807 S-1 S-66 S-7 S-7 Compound-857 S-1 S-67 S-7 S-7 Compound-808 S-1 S-66 S-8 S-8 Compound-858 S-1 S-67 S-8 S-8 Compound-809 S-1 S-66 S-9 S-9 Compound-859 S-1 S-67 S-9 S-9 Compound-810 S-1 S-66 S-12 S-12 Compound-860 S-1 S-67 S-12 S-12 Compound-811 S-1 S-66 S-13 S-13 Compound-861 S-1 S-67 S-13 S-13 Compound-812 S-1 S-66 S-14 S-14 Compound-862 S-1 S-67 S-14 S-14 Compound-813 S-1 S-66 S-15 S-15 Compound-863 S-1 S-67 S-15 S-15 Compound-814 S-1 S-66 S-16 S-16 Compound-864 S-1 S-67 S-16 S-16 Compound-815 S-1 S-66 S-18 S-18 Compound-865 S-1 S-67 S-18 S-18 Compound-816 S-1 S-66 S-19 S-19 Compound-866 S-1 S-67 S-19 S-19 Compound-817 S-1 S-66 S-20 S-20 Compound-867 S-1 S-67 S-20 S-20 Compound-818 S-1 S-66 S-21 S-21 Compound-868 S-1 S-67 S-21 S-21 Compound-819 S-1 S-66 S-30 S-30 Compound-869 S-1 S-67 S-30 S-30 Compound-820 S-1 S-66 S-31 S-31 Compound-870 S-1 S-67 S-31 S-31 Compound-821 S-1 S-66 S-32 S-32 Compound-871 S-1 S-67 S-32 S-32 Compound-822 S-1 S-66 S-33 S-33 Compound-872 S-1 S-67 S-33 S-33 Compound-823 S-1 S-66 S-34 S-34 Compound-873 S-1 S-67 S-34 S-34 Compound-824 S-1 S-66 S-35 S-35 Compound-874 S-1 S-67 S-35 S-35 Compound-825 S-1 S-66 S-36 S-36 Compound-875 S-1 S-67 S-36 S-36 Compound-826 S-1 S-66 S-37 S-37 Compound-876 S-1 S-67 S-37 S-37 Compound-827 S-1 S-66 S-38 S-38 Compound-877 S-1 S-67 S-38 S-38 Compound-828 S-1 S-66 S-39 S-39 Compound-878 S-1 S-67 S-39 S-39 Compound-829 S-1 S-66 S-40 S-40 Compound-879 S-1 S-67 S-40 S-40 Compound-830 S-1 S-66 S-41 S-41 Compound-880 S-1 S-67 S-41 S-41 Compound-831 S-1 S-66 S-42 S-42 Compound-881 S-1 S-67 S-42 S-42 Compound-832 S-1 S-66 S-43 S-43 Compound-882 S-1 S-67 S-43 S-43 Compound-833 S-1 S-66 S-44 S-44 Compound-883 S-1 S-67 S-44 S-44 Compound-834 S-1 S-66 S-45 S-45 Compound-884 S-1 S-67 S-45 S-45 Compound-835 S-1 S-66 S-46 S-46 Compound-885 S-1 S-67 S-46 S-46 Compound-836 S-1 S-66 S-48 S-48 Compound-886 S-1 S-67 S-48 S-48 Compound-837 S-1 S-66 S-49 S-49 Compound-887 S-1 S-67 S-49 S-49 Compound-838 S-1 S-66 S-51 S-51 Compound-888 S-1 S-67 S-51 S-51 Compound-839 S-1 S-66 S-55 S-55 Compound-889 S-1 S-67 S-55 S-55 Compound-840 S-1 S-66 S-56 S-56 Compound-890 S-1 S-67 S-56 S-56 Compound-841 S-1 S-66 S-57 S-57 Compound-891 S-1 S-67 S-57 S-57 Compound-842 S-1 S-66 S-58 S-58 Compound-892 S-1 S-67 S-58 S-58 Compound-843 S-1 S-66 S-59 S-59 Compound-893 S-1 S-67 S-59 S-59 Compound-844 S-1 S-66 S-60 S-60 Compound-894 S-1 S-67 S-60 S-60 Compound-845 S-1 S-66 S-61 S-61 Compound-895 S-1 S-67 S-61 S-61 Compound-846 S-1 S-66 S-63 S-63 Compound-896 S-1 S-67 S-63 S-63 Compound-847 S-1 S-66 S-64 S-64 Compound-897 S-1 S-67 S-64 S-64 Compound-848 S-1 S-66 S-66 S-66 Compound-898 S-1 S-67 S-66 S-66 Compound-849 S-1 S-66 S-67 S-67 Compound-899 S-1 S-67 S-67 S-67 Compound-850 S-1 S-66 S-68 S-68 Compound-900 S-1 S-67 S-68 S-68

[0043]

[0044] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-901 H S-1 S-30 H Compound-951 S-1 S-1 S-30 H Compound-902 H S-1 S-30 S-1 Compound-952 S-1 S-1 S-30 S-1 Compound-903 H S-1 S-30 S-3 Compound-953 S-1 S-1 S-30 S-3 Compound-904 H S-1 S-30 S-4 Compound-954 S-1 S-1 S-30 S-4 Compound-905 H S-1 S-30 S-5 Compound-955 S-1 S-1 S-30 S-5 Compound-906 H S-1 S-30 S-6 Compound-956 S-1 S-1 S-30 S-6 Compound-907 H S-1 S-30 S-7 Compound-957 S-1 S-1 S-30 S-7 Compound-908 H S-1 S-30 S-8 Compound-958 S-1 S-1 S-30 S-8 Compound-909 H S-1 S-30 S-9 Compound-959 S-1 S-1 S-30 S-9 Compound-910 H S-1 S-30 S-12 Compound-960 S-1 S-1 S-30 S-12 Compound-911 H S-1 S-30 S-13 Compound-961 S-1 S-1 S-30 S-13 Compound-912 H S-1 S-30 S-14 Compound-962 S-1 S-1 S-30 S-14 Compound-913 H S-1 S-30 S-15 Compound-963 S-1 S-1 S-30 S-15 Compound-914 H S-1 S-30 S-16 Compound-964 S-1 S-1 S-30 S-16 Compound-915 H S-1 S-30 S-18 Compound-965 S-1 S-1 S-30 S-18 Compound-916 H S-1 S-30 S-19 Compound-966 S-1 S-1 S-30 S-19 Compound-917 H S-1 S-30 S-20 Compound-967 S-1 S-1 S-30 S-20 Compound-918 H S-1 S-30 S-21 Compound-968 S-1 S-1 S-30 S-21 Compound-919 H S-1 S-30 S-30 Compound-969 S-1 S-1 S-30 S-30 Compound-920 H S-1 S-30 S-31 Compound-970 S-1 S-1 S-30 S-31 Compound-921 H S-1 S-30 S-32 Compound-971 S-1 S-1 S-30 S-32 Compound-922 H S-1 S-30 S-33 Compound-972 S-1 S-1 S-30 S-33 Compound-923 H S-1 S-30 S-34 Compound-973 S-1 S-1 S-30 S-34 Compound-924 H S-1 S-30 S-35 Compound-974 S-1 S-1 S-30 S-35 Compound-925 H S-1 S-30 S-36 Compound-975 S-1 S-1 S-30 S-36 Compound-926 H S-1 S-30 S-37 Compound-976 S-1 S-1 S-30 S-37 Compound-927 H S-1 S-30 S-38 Compound-977 S-1 S-1 S-30 S-38 Compound-928 H S-1 S-30 S-39 Compound-978 S-1 S-1 S-30 S-39 Compound-929 H S-1 S-30 S-40 Compound-979 S-1 S-1 S-30 S-40 Compound-930 H S-1 S-30 S-41 Compound-980 S-1 S-1 S-30 S-41 Compound-931 H S-1 S-30 S-42 Compound-981 S-1 S-1 S-30 S-42 Compound-932 H S-1 S-30 S-43 Compound-982 S-1 S-1 S-30 S-43 Compound-933 H S-1 S-30 S-44 Compound-983 S-1 S-1 S-30 S-44 Compound-934 H S-1 S-30 S-45 Compound-984 S-1 S-1 S-30 S-45 Compound-935 H S-1 S-30 S-46 Compound-985 S-1 S-1 S-30 S-46 Compound-936 H S-1 S-30 S-48 Compound-986 S-1 S-1 S-30 S-48 Compound-937 H S-1 S-30 S-49 Compound-987 S-1 S-1 S-30 S-49 Compound-938 H S-1 S-30 S-51 Compound-988 S-1 S-1 S-30 S-51 Compound-939 H S-1 S-30 S-55 Compound-989 S-1 S-1 S-30 S-55 Compound-940 H S-1 S-30 S-56 Compound-990 S-1 S-1 S-30 S-56 Compound-941 H S-1 S-30 S-57 Compound-991 S-1 S-1 S-30 S-57 Compound-942 H S-1 S-30 S-58 Compound-992 S-1 S-1 S-30 S-58 Compound-943 H S-1 S-30 S-59 Compound-993 S-1 S-1 S-30 S-59 Compound-944 H S-1 S-30 S-60 Compound-994 S-1 S-1 S-30 S-60 Compound-945 H S-1 S-30 S-61 Compound-995 S-1 S-1 S-30 S-61 Compound-946 H S-1 S-30 S-63 Compound-996 S-1 S-1 S-30 S-63 Compound-947 H S-1 S-30 S-64 Compound-997 S-1 S-1 S-30 S-64 Compound-948 H S-1 S-30 S-66 Compound-998 S-1 S-1 S-30 S-66 Compound-949 H S-1 S-30 S-67 Compound-999 S-1 S-1 S-30 S-67 Compound-950 H S-1 S-30 S-68 Compound-1000 S-1 S-1 S-30 S-68

[0045]

[0046] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1001 H H S-30 S-1 Compound-1051 H H S-54 S-1 Compound-1002 H H S-30 S-2 Compound-1052 H H S-54 S-2 Compound-1003 H H S-30 S-3 Compound-1053 H H S-54 S-3 Compound-1004 H H S-30 S-4 Compound-1054 H H S-54 S-4 Compound-1005 H H S-30 S-5 Compound-1055 H H S-54 S-5 Compound-1006 H H S-30 S-6 Compound-1056 H H S-54 S-6 Compound-1007 H H S-30 S-7 Compound-1057 H H S-54 S-7 Compound-1008 H H S-30 S-8 Compound-1058 H H S-54 S-8 Compound-1009 H H S-30 S-9 Compound-1059 H H S-54 S-9 Compound-1010 H H S-30 S-12 Compound-1060 H H S-54 S-12 Compound-1011 H H S-30 S-13 Compound-1061 H H S-54 S-13 Compound-1012 H H S-30 S-14 Compound-1062 H H S-54 S-14 Compound-1013 H H S-30 S-15 Compound-1063 H H S-54 S-15 Compound-1014 H H S-30 S-16 Compound-1064 H H S-54 S-16 Compound-1015 H H S-30 S-18 Compound-1065 H H S-54 S-18 Compound-1016 H H S-30 S-19 Compound-1066 H H S-54 S-19 Compound-1017 H H S-30 S-20 Compound-1067 H H S-54 S-20 Compound-1018 H H S-30 S-21 Compound-1068 H H S-54 S-21 Compound-1019 H H S-30 S-30 Compound-1069 H H S-54 S-30 Compound-1020 H H S-30 S-31 Compound-1070 H H S-54 S-31 Compound-1021 H H S-30 S-32 Compound-1071 H H S-54 S-32 Compound-1022 H H S-30 S-33 Compound-1072 H H S-54 S-33 Compound-1023 H H S-30 S-34 Compound-1073 H H S-54 S-34 Compound-1024 H H S-30 S-35 Compound-1074 H H S-54 S-35 Compound-1025 H H S-30 S-36 Compound-1075 H H S-54 S-36 Compound-1026 H H S-30 S-37 Compound-1076 H H S-54 S-37 Compound-1027 H H S-30 S-38 Compound-1077 H H S-54 S-38 Compound-1028 H H S-30 S-39 Compound-1078 H H S-54 S-39 Compound-1029 H H S-30 S-40 Compound-1079 H H S-54 S-40 Compound-1030 H H S-30 S-41 Compound-1080 H H S-54 S-41 Compound-1031 H H S-30 S-42 Compound-1081 H H S-54 S-42 Compound-1032 H H S-30 S-43 Compound-1082 H H S-54 S-43 Compound-1033 H H S-30 S-44 Compound-1083 H H S-54 S-44 Compound-1034 H H S-30 S-45 Compound-1084 H H S-54 S-45 Compound-1035 H H S-30 S-46 Compound-1085 H H S-54 S-46 Compound-1036 H H S-30 S-48 Compound-1086 H H S-54 S-48 Compound-1037 H H S-30 S-49 Compound-1087 H H S-54 S-49 Compound-1038 H H S-30 S-51 Compound-1088 H H S-54 S-51 Compound-1039 H H S-30 S-55 Compound-1089 H H S-54 S-55 Compound-1040 H H S-30 S-56 Compound-1090 H H S-54 S-56 Compound-1041 H H S-30 S-57 Compound-1091 H H S-54 S-57 Compound-1042 H H S-30 S-58 Compound-1092 H H S-54 S-58 Compound-1043 H H S-30 S-59 Compound-1093 H H S-54 S-59 Compound-1044 H H S-30 S-60 Compound-1094 H H S-54 S-60 Compound-1045 H H S-30 S-61 Compound-1095 H H S-54 S-61 Compound-1046 H H S-30 S-63 Compound-1096 H H S-54 S-63 Compound-1047 H H S-30 S-64 Compound-1097 H H S-54 S-64 Compound-1048 H H S-30 S-66 Compound-1098 H H S-54 S-66 Compound-1049 H H S-30 S-67 Compound-1099 H H S-54 S-67 Compound-1050 H H S-30 S-68 Compound-1100 H H S-54 S-68

[0047]

[0048] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1101 H H S-30 S-1 Compound-1151 H H S-54 S-1 Compound-1102 H H S-30 S-2 Compound-1152 H H S-54 S-2 Compound-1103 H H S-30 S-3 Compound-1153 H H S-54 S-3 Compound-1104 H H S-30 S-4 Compound-1154 H H S-54 S-4 Compound-1105 H H S-30 S-5 Compound-1155 H H S-54 S-5 Compound-1106 H H S-30 S-6 Compound-1156 H H S-54 S-6 Compound-1107 H H S-30 S-7 Compound-1157 H H S-54 S-7 Compound-1108 H H S-30 S-8 Compound-1158 H H S-54 S-8 Compound-1109 H H S-30 S-9 Compound-1159 H H S-54 S-9 Compound-1110 H H S-30 S-12 Compound-1160 H H S-54 S-12 Compound-1111 H H S-30 S-13 Compound-1161 H H S-54 S-13 Compound-1112 H H S-30 S-14 Compound-1162 H H S-54 S-14 Compound-1113 H H S-30 S-15 Compound-1163 H H S-54 S-15 Compound-1114 H H S-30 S-16 Compound-1164 H H S-54 S-16 Compound-1115 H H S-30 S-18 Compound-1165 H H S-54 S-18 Compound-1116 H H S-30 S-19 Compound-1166 H H S-54 S-19 Compound-1117 H H S-30 S-20 Compound-1167 H H S-54 S-20 Compound-1118 H H S-30 S-21 Compound-1168 H H S-54 S-21 Compound-1119 H H S-30 S-30 Compound-1169 H H S-54 S-30 Compound-1120 H H S-30 S-31 Compound-1170 H H S-54 S-31 Compound-1121 H H S-30 S-32 Compound-1171 H H S-54 S-32 Compound-1122 H H S-30 S-33 Compound-1172 H H S-54 S-33 Compound-1123 H H S-30 S-34 Compound-1173 H H S-54 S-34 Compound-1124 H H S-30 S-35 Compound-1174 H H S-54 S-35 Compound-1125 H H S-30 S-36 Compound-1175 H H S-54 S-36 Compound-1126 H H S-30 S-37 Compound-1176 H H S-54 S-37 Compound-1127 H H S-30 S-38 Compound-1177 H H S-54 S-38 Compound-1128 H H S-30 S-39 Compound-1178 H H S-54 S-39 Compound-1129 H H S-30 S-40 Compound-1179 H H S-54 S-40 Compound-1130 H H S-30 S-41 Compound-1180 H H S-54 S-41 Compound-1131 H H S-30 S-42 Compound-1181 H H S-54 S-42 Compound-1132 H H S-30 S-43 Compound-1182 H H S-54 S-43 Compound-1133 H H S-30 S-44 Compound-1183 H H S-54 S-44 Compound-1134 H H S-30 S-45 Compound-1184 H H S-54 S-45 Compound-1135 H H S-30 S-46 Compound-1185 H H S-54 S-46 Compound-1136 H H S-30 S-48 Compound-1186 H H S-54 S-48 Compound-1137 H H S-30 S-49 Compound-1187 H H S-54 S-49 Compound-1138 H H S-30 S-51 Compound-1188 H H S-54 S-51 Compound-1139 H H S-30 S-55 Compound-1189 H H S-54 S-55 Compound-1140 H H S-30 S-56 Compound-1190 H H S-54 S-56 Compound-1141 H H S-30 S-57 Compound-1191 H H S-54 S-57 Compound-1142 H H S-30 S-58 Compound-1192 H H S-54 S-58 Compound-1143 H H S-30 S-59 Compound-1193 H H S-54 S-59 Compound-1144 H H S-30 S-60 Compound-1194 H H S-54 S-60 Compound-1145 H H S-30 S-61 Compound-1195 H H S-54 S-61 Compound-1146 H H S-30 S-63 Compound-1196 H H S-54 S-63 Compound-1147 H H S-30 S-64 Compound-1197 H H S-54 S-64 Compound-1148 H H S-30 S-66 Compound-1198 H H S-54 S-66 Compound-1149 H H S-30 S-67 Compound-1199 H H S-54 S-67 Compound-1150 H H S-30 S-68 Compound-1200 H H S-54 S-68

[0049]

[0050] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1201 H H H H Compound-1251 S-1 H H H Compound-1202 H H S-1 S-1 Compound-1252 S-1 H S-1 S-1 Compound-1203 H H S-3 S-3 Compound-1253 S-1 H S-3 S-3 Compound-1204 H H S-4 S-4 Compound-1254 S-1 H S-4 S-4 Compound-1205 H H S-5 S-5 Compound-1255 S-1 H S-5 S-5 Compound-1206 H H S-6 S-6 Compound-1256 S-1 H S-6 S-6 Compound-1207 H H S-7 S-7 Compound-1257 S-1 H S-7 S-7 Compound-1208 H H S-8 S-8 Compound-1258 S-1 H S-8 S-8 Compound-1209 H H S-9 S-9 Compound-1259 S-1 H S-9 S-9 Compound-1210 H H S-12 S-12 Compound-1260 S-1 H S-12 S-12 Compound-1211 H H S-13 S-13 Compound-1261 S-1 H S-13 S-13 Compound-1212 H H S-14 S-14 Compound-1262 S-1 H S-14 S-14 Compound-1213 H H S-15 S-15 Compound-1263 S-1 H S-15 S-15 Compound-1214 H H S-16 S-16 Compound-1264 S-1 H S-16 S-16 Compound-1215 H H S-18 S-18 Compound-1265 S-1 H S-18 S-18 Compound-1216 H H S-19 S-19 Compound-1266 S-1 H S-19 S-19 Compound-1217 H H S-20 S-20 Compound-1267 S-1 H S-20 S-20 Compound-1218 H H S-21 S-21 Compound-1268 S-1 H S-21 S-21 Compound-1219 H H S-30 S-30 Compound-1269 S-1 H S-30 S-30 Compound-1220 H H S-31 S-31 Compound-1270 S-1 H S-31 S-31 Compound-1221 H H S-32 S-32 Compound-1271 S-1 H S-32 S-32 Compound-1222 H H S-33 S-33 Compound-1272 S-1 H S-33 S-33 Compound-1223 H H S-34 S-34 Compound-1273 S-1 H S-34 S-34 Compound-1224 H H S-35 S-35 Compound-1274 S-1 H S-35 S-35 Compound-1225 H H S-36 S-36 Compound-1275 S-1 H S-36 S-36 Compound-1226 H H S-37 S-37 Compound-1276 S-1 H S-37 S-37 Compound-1227 H H S-38 S-38 Compound-1277 S-1 H S-38 S-38 Compound-1228 H H S-39 S-39 Compound-1278 S-1 H S-39 S-39 Compound-1229 H H S-40 S-40 Compound-1279 S-1 H S-40 S-40 Compound-1230 H H S-41 S-41 Compound-1280 S-1 H S-41 S-41 Compound-1231 H H S-42 S-42 Compound-1281 S-1 H S-42 S-42 Compound-1232 H H S-43 S-43 Compound-1282 S-1 H S-43 S-43 Compound-1233 H H S-44 S-44 Compound-1283 S-1 H S-44 S-44 Compound-1234 H H S-45 S-45 Compound-1284 S-1 H S-45 S-45 Compound-1235 H H S-46 S-46 Compound-1285 S-1 H S-46 S-46 Compound-1236 H H S-48 S-48 Compound-1286 S-1 H S-48 S-48 Compound-1237 H H S-49 S-49 Compound-1287 S-1 H S-49 S-49 Compound-1238 H H S-51 S-51 Compound-1288 S-1 H S-51 S-51 Compound-1239 H H S-55 S-55 Compound-1289 S-1 H S-55 S-55 Compound-1240 H H S-56 S-56 Compound-1290 S-1 H S-56 S-56 Compound-1241 H H S-57 S-57 Compound-1291 S-1 H S-57 S-57 Compound-1242 H H S-58 S-58 Compound-1292 S-1 H S-58 S-58 Compound-1243 H H S-59 S-59 Compound-1293 S-1 H S-59 S-59 Compound-1244 H H S-60 S-60 Compound-1294 S-1 H S-60 S-60 Compound-1245 H H S-61 S-61 Compound-1295 S-1 H S-61 S-61 Compound-1246 H H S-63 S-63 Compound-1296 S-1 H S-63 S-63 Compound-1247 H H S-64 S-64 Compound-1297 S-1 H S-64 S-64 Compound-1248 H H S-66 S-66 Compound-1298 S-1 H S-66 S-66 Compound-1249 H H S-67 S-67 Compound-1299 S-1 H S-67 S-67 Compound-1250 H H S-68 S-68 Compound-1300 S-1 H S-68 S-68

[0051]

[0052] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1301 H S-1 S-30 H Compound-1351 H S-1 S-54 H Compound-1302 H S-2 S-30 H Compound-1352 H S-2 S-54 H Compound-1303 H S-3 S-30 H Compound-1353 H S-3 S-54 H Compound-1304 H S-4 S-30 H Compound-1354 H S-4 S-54 H Compound-1305 H S-5 S-30 H Compound-1355 H S-5 S-54 H Compound-1306 H S-6 S-30 H Compound-1356 H S-6 S-54 H Compound-1307 H S-7 S-30 H Compound-1357 H S-7 S-54 H Compound-1308 H S-8 S-30 H Compound-1358 H S-8 S-54 H Compound-1309 H S-9 S-30 H Compound-1359 H S-9 S-54 H Compound-1310 H S-12 S-30 H Compound-1360 H S-12 S-54 H Compound-1311 H S-13 S-30 H Compound-1361 H S-13 S-54 H Compound-1312 H S-14 S-30 H Compound-1362 H S-14 S-54 H Compound-1313 H S-15 S-30 H Compound-1363 H S-15 S-54 H Compound-1314 H S-16 S-30 H Compound-1364 H S-16 S-54 H Compound-1315 H S-18 S-30 H Compound-1365 H S-18 S-54 H Compound-1316 H S-19 S-30 H Compound-1366 H S-19 S-54 H Compound-1317 H S-20 S-30 H Compound-1367 H S-20 S-54 H Compound-1318 H S-21 S-30 H Compound-1368 H S-21 S-54 H Compound-1319 H S-30 S-30 H Compound-1369 H S-30 S-54 H Compound-1320 H S-31 S-30 H Compound-1370 H S-31 S-54 H Compound-1321 H S-32 S-30 H Compound-1371 H S-32 S-54 H Compound-1322 H S-33 S-30 H Compound-1372 H S-33 S-54 H Compound-1323 H S-34 S-30 H Compound-1373 H S-34 S-54 H Compound-1324 H S-35 S-30 H Compound-1374 H S-35 S-54 H Compound-1325 H S-36 S-30 H Compound-1375 H S-36 S-54 H Compound-1326 H S-37 S-30 H Compound-1376 H S-37 S-54 H Compound-1327 H S-38 S-30 H Compound-1377 H S-38 S-54 H Compound-1328 H S-39 S-30 H Compound-1378 H S-39 S-54 H Compound-1329 H S-40 S-30 H Compound-1379 H S-40 S-54 H Compound-1330 H S-41 S-30 H Compound-1380 H S-41 S-54 H Compound-1331 H S-42 S-30 H Compound-1381 H S-42 S-54 H Compound-1332 H S-43 S-30 H Compound-1382 H S-43 S-54 H Compound-1333 H S-44 S-30 H Compound-1383 H S-44 S-54 H Compound-1334 H S-45 S-30 H Compound-1384 H S-45 S-54 H Compound-1335 H S-46 S-30 H Compound-1385 H S-46 S-54 H Compound-1336 H S-48 S-30 H Compound-1386 H S-48 S-54 H Compound-1337 H S-49 S-30 H Compound-1387 H S-49 S-54 H Compound-1338 H S-51 S-30 H Compound-1388 H S-51 S-54 H Compound-1339 H S-55 S-30 H Compound-1389 H S-55 S-54 H Compound-1340 H S-56 S-30 H Compound-1390 H S-56 S-54 H Compound-1341 H S-57 S-30 H Compound-1391 H S-57 S-54 H Compound-1342 H S-58 S-30 H Compound-1392 H S-58 S-54 H Compound-1343 H S-59 S-30 H Compound-1393 H S-59 S-54 H Compound-1344 H S-60 S-30 H Compound-1394 H S-60 S-54 H Compound-1345 H S-61 S-30 H Compound-1395 H S-61 S-54 H Compound-1346 H S-63 S-30 H Compound-1396 H S-63 S-54 H Compound-1347 H S-64 S-30 H Compound-1397 H S-64 S-54 H Compound-1348 H S-66 S-30 H Compound-1398 H S-66 S-54 H Compound-1349 H S-67 S-30 H Compound-1399 H S-67 S-54 H Compound-1350 H S-68 S-30 H Compound-1400 H S-68 S-54 H

[0053]

[0054] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1401 H S-1 S-30 H Compound-1451 H S-1 S-54 H Compound-1402 H S-2 S-30 H Compound-1452 H S-2 S-54 H Compound-1403 H S-3 S-30 H Compound-1453 H S-3 S-54 H Compound-1404 H S-4 S-30 H Compound-1454 H S-4 S-54 H Compound-1405 H S-5 S-30 H Compound-1455 H S-5 S-54 H Compound-1406 H S-6 S-30 H Compound-1456 H S-6 S-54 H Compound-1407 H S-7 S-30 H Compound-1457 H S-7 S-54 H Compound-1408 H S-8 S-30 H Compound-1458 H S-8 S-54 H Compound-1409 H S-9 S-30 H Compound-1459 H S-9 S-54 H Compound-1410 H S-12 S-30 H Compound-1460 H S-12 S-54 H Compound-1411 H S-13 S-30 H Compound-1461 H S-13 S-54 H Compound-1412 H S-14 S-30 H Compound-1462 H S-14 S-54 H Compound-1413 H S-15 S-30 H Compound-1463 H S-15 S-54 H Compound-1414 H S-16 S-30 H Compound-1464 H S-16 S-54 H Compound-1415 H S-18 S-30 H Compound-1465 H S-18 S-54 H Compound-1416 H S-19 S-30 H Compound-1466 H S-19 S-54 H Compound-1417 H S-20 S-30 H Compound-1467 H S-20 S-54 H Compound-1418 H S-21 S-30 H Compound-1468 H S-21 S-54 H Compound-1419 H S-30 S-30 H Compound-1469 H S-30 S-54 H Compound-1420 H S-31 S-30 H Compound-1470 H S-31 S-54 H Compound-1421 H S-32 S-30 H Compound-1471 H S-32 S-54 H Compound-1422 H S-33 S-30 H Compound-1472 H S-33 S-54 H Compound-1423 H S-34 S-30 H Compound-1473 H S-34 S-54 H Compound-1424 H S-35 S-30 H Compound-1474 H S-35 S-54 H Compound-1425 H S-36 S-30 H Compound-1475 H S-36 S-54 H Compound-1426 H S-37 S-30 H Compound-1476 H S-37 S-54 H Compound-1427 H S-38 S-30 H Compound-1477 H S-38 S-54 H Compound-1428 H S-39 S-30 H Compound-1478 H S-39 S-54 H Compound-1429 H S-40 S-30 H Compound-1479 H S-40 S-54 H Compound-1430 H S-41 S-30 H Compound-1480 H S-41 S-54 H Compound-1431 H S-42 S-30 H Compound-1481 H S-42 S-54 H Compound-1432 H S-43 S-30 H Compound-1482 H S-43 S-54 H Compound-1433 H S-44 S-30 H Compound-1483 H S-44 S-54 H Compound-1434 H S-45 S-30 H Compound-1484 H S-45 S-54 H Compound-1435 H S-46 S-30 H Compound-1485 H S-46 S-54 H Compound-1436 H S-48 S-30 H Compound-1486 H S-48 S-54 H Compound-1437 H S-49 S-30 H Compound-1487 H S-49 S-54 H Compound-1438 H S-51 S-30 H Compound-1488 H S-51 S-54 H Compound-1439 H S-55 S-30 H Compound-1489 H S-55 S-54 H Compound-1440 H S-56 S-30 H Compound-1490 H S-56 S-54 H Compound-1441 H S-57 S-30 H Compound-1491 H S-57 S-54 H Compound-1442 H S-58 S-30 H Compound-1492 H S-58 S-54 H Compound-1443 H S-59 S-30 H Compound-1493 H S-59 S-54 H Compound-1444 H S-60 S-30 H Compound-1494 H S-60 S-54 H Compound-1445 H S-61 S-30 H Compound-1495 H S-61 S-54 H Compound-1446 H S-63 S-30 H Compound-1496 H S-63 S-54 H Compound-1447 H S-64 S-30 H Compound-1497 H S-64 S-54 H Compound-1448 H S-66 S-30 H Compound-1498 H S-66 S-54 H Compound-1449 H S-67 S-30 H Compound-1499 H S-67 S-54 H Compound-1450 H S-68 S-30 H Compound-1500 H S-68 S-54 H

[0055]

[0056] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1601 H S-66 S-30 H Compound-1651 H S-67 S-30 H Compound-1602 H S-66 S-30 S-1 Compound-1652 H S-67 S-30 S-1 Compound-1603 H S-66 S-30 S-3 Compound-1653 H S-67 S-30 S-3 Compound-1604 H S-66 S-30 S-4 Compound-1654 H S-67 S-30 S-4 Compound-1605 H S-66 S-30 S-5 Compound-1655 H S-67 S-30 S-5 Compound-1606 H S-66 S-30 S-6 Compound-1656 H S-67 S-30 S-6 Compound-1607 H S-66 S-30 S-7 Compound-1657 H S-67 S-30 S-7 Compound-1608 H S-66 S-30 S-8 Compound-1658 H S-67 S-30 S-8 Compound-1609 H S-66 S-30 S-9 Compound-1659 H S-67 S-30 S-9 Compound-1610 H S-66 S-30 S-12 Compound-1660 H S-67 S-30 S-12 Compound-1611 H S-66 S-30 S-13 Compound-1661 H S-67 S-30 S-13 Compound-1612 H S-66 S-30 S-14 Compound-1662 H S-67 S-30 S-14 Compound-1613 H S-66 S-30 S-15 Compound-1663 H S-67 S-30 S-15 Compound-1614 H S-66 S-30 S-16 Compound-1664 H S-67 S-30 S-16 Compound-1615 H S-66 S-30 S-18 Compound-1665 H S-67 S-30 S-18 Compound-1616 H S-66 S-30 S-19 Compound-1666 H S-67 S-30 S-19 Compound-1617 H S-66 S-30 S-20 Compound-1667 H S-67 S-30 S-20 Compound-1618 H S-66 S-30 S-21 Compound-1668 H S-67 S-30 S-21 Compound-1619 H S-66 S-30 S-30 Compound-1669 H S-67 S-30 S-30 Compound-1620 H S-66 S-30 S-31 Compound-1670 H S-67 S-30 S-31 Compound-1621 H S-66 S-30 S-32 Compound-1671 H S-67 S-30 S-32 Compound-1622 H S-66 S-30 S-33 Compound-1672 H S-67 S-30 S-33 Compound-1623 H S-66 S-30 S-34 Compound-1673 H S-67 S-30 S-34 Compound-1624 H S-66 S-30 S-35 Compound-1674 H S-67 S-30 S-35 Compound-1625 H S-66 S-30 S-36 Compound-1675 H S-67 S-30 S-36 Compound-1626 H S-66 S-30 S-37 Compound-1676 H S-67 S-30 S-37 Compound-1627 H S-66 S-30 S-38 Compound-1677 H S-67 S-30 S-38 Compound-1628 H S-66 S-30 S-39 Compound-1678 H S-67 S-30 S-39 Compound-1629 H S-66 S-30 S-40 Compound-1679 H S-67 S-30 S-40 Compound-1630 H S-66 S-30 S-41 Compound-1680 H S-67 S-30 S-41 Compound-1631 H S-66 S-30 S-42 Compound-1681 H S-67 S-30 S-42 Compound-1632 H S-66 S-30 S-43 Compound-1682 H S-67 S-30 S-43 Compound-1633 H S-66 S-30 S-44 Compound-1683 H S-67 S-30 S-44 Compound-1634 H S-66 S-30 S-45 Compound-1684 H S-67 S-30 S-45 Compound-1635 H S-66 S-30 S-46 Compound-1685 H S-67 S-30 S-46 Compound-1636 H S-66 S-30 S-48 Compound-1686 H S-67 S-30 S-48 Compound-1637 H S-66 S-30 S-49 Compound-1687 H S-67 S-30 S-49 Compound-1638 H S-66 S-30 S-51 Compound-1688 H S-67 S-30 S-51 Compound-1639 H S-66 S-30 S-55 Compound-1689 H S-67 S-30 S-55 Compound-1640 H S-66 S-30 S-56 Compound-1690 H S-67 S-30 S-56 Compound-1641 H S-66 S-30 S-57 Compound-1691 H S-67 S-30 S-57 Compound-1642 H S-66 S-30 S-58 Compound-1692 H S-67 S-30 S-58 Compound-1643 H S-66 S-30 S-59 Compound-1693 H S-67 S-30 S-59 Compound-1644 H S-66 S-30 S-60 Compound-1694 H S-67 S-30 S-60 Compound-1645 H S-66 S-30 S-61 Compound-1695 H S-67 S-30 S-61 Compound-1646 H S-66 S-30 S-63 Compound-1696 H S-67 S-30 S-63 Compound-1647 H S-66 S-30 S-64 Compound-1697 H S-67 S-30 S-64 Compound-1648 H S-66 S-30 S-66 Compound-1698 H S-67 S-30 S-66 Compound-1649 H S-66 S-30 S-67 Compound-1699 H S-67 S-30 S-67 Compound-1650 H S-66 S-30 S-68 Compound-1700 H S-67 S-30 S-68

[0057]

[0058] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1701 H S-66 H H Compound-1751 H S-68 H H Compound-1702 H S-66 S-1 S-1 Compound-1752 H S-67 S-1 S-1 Compound-1703 H S-66 S-3 S-3 Compound-1753 H S-67 S-3 S-3 Compound-1704 H S-66 S-4 S-4 Compound-1754 H S-67 S-4 S-4 Compound-1705 H S-66 S-5 S-5 Compound-1755 H S-67 S-5 S-5 Compound-1706 H S-66 S-6 S-6 Compound-1756 H S-67 S-6 S-6 Compound-1707 H S-66 S-7 S-7 Compound-1757 H S-67 S-7 S-7 Compound-1708 H S-66 S-8 S-8 Compound-1758 H S-67 S-8 S-8 Compound-1709 H S-66 S-9 S-9 Compound-1759 H S-67 S-9 S-9 Compound-1710 H S-66 S-12 S-12 Compound-1760 H S-67 S-12 S-12 Compound-1711 H S-66 S-13 S-13 Compound-1761 H S-67 S-13 S-13 Compound-1712 H S-66 S-14 S-14 Compound-1762 H S-67 S-14 S-14 Compound-1713 H S-66 S-15 S-15 Compound-1763 H S-67 S-15 S-15 Compound-1714 H S-66 S-16 S-16 Compound-1764 H S-67 S-16 S-16 Compound-1715 H S-66 S-18 S-18 Compound-1765 H S-67 S-18 S-18 Compound-1716 H S-66 S-19 S-19 Compound-1766 H S-67 S-19 S-19 Compound-1717 H S-66 S-20 S-20 Compound-1767 H S-67 S-20 S-20 Compound-1718 H S-66 S-21 S-21 Compound-1768 H S-67 S-21 S-21 Compound-1719 H S-66 S-30 S-30 Compound-1769 H S-67 S-30 S-30 Compound-1720 H S-66 S-31 S-31 Compound-1770 H S-67 S-31 S-31 Compound-1721 H S-66 S-32 S-32 Compound-1771 H S-67 S-32 S-32 Compound-1722 H S-66 S-33 S-33 Compound-1772 H S-67 S-33 S-33 Compound-1723 H S-66 S-34 S-34 Compound-1773 H S-67 S-34 S-34 Compound-1724 H S-66 S-35 S-35 Compound-1774 H S-67 S-35 S-35 Compound-1725 H S-66 S-36 S-36 Compound-1775 H S-67 S-36 S-36 Compound-1726 H S-66 S-37 S-37 Compound-1776 H S-67 S-37 S-37 Compound-1727 H S-66 S-38 S-38 Compound-1777 H S-67 S-38 S-38 Compound-1728 H S-66 S-39 S-39 Compound-1778 H S-67 S-39 S-39 Compound-1729 H S-66 S-40 S-40 Compound-1779 H S-67 S-40 S-40 Compound-1730 H S-66 S-41 S-41 Compound-1780 H S-67 S-41 S-41 Compound-1731 H S-66 S-42 S-42 Compound-1781 H S-67 S-42 S-42 Compound-1732 H S-66 S-43 S-43 Compound-1782 H S-67 S-43 S-43 Compound-1733 H S-66 S-44 S-44 Compound-1783 H S-67 S-44 S-44 Compound-1734 H S-66 S-45 S-45 Compound-1784 H S-67 S-45 S-45 Compound-1735 H S-66 S-46 S-46 Compound-1785 H S-67 S-46 S-46 Compound-1736 H S-66 S-48 S-48 Compound-1786 H S-67 S-48 S-48 Compound-1737 H S-66 S-49 S-49 Compound-1787 H S-67 S-49 S-49 Compound-1738 H S-66 S-51 S-51 Compound-1788 H S-67 S-51 S-51 Compound-1739 H S-66 S-55 S-55 Compound-1789 H S-67 S-55 S-55 Compound-1740 H S-66 S-56 S-56 Compound-1790 H S-67 S-56 S-56 Compound-1741 H S-66 S-57 S-57 Compound-1791 H S-67 S-57 S-57 Compound-1742 H S-66 S-58 S-58 Compound-1792 H S-67 S-58 S-58 Compound-1743 H S-66 S-59 S-59 Compound-1793 H S-67 S-59 S-59 Compound-1744 H S-66 S-60 S-60 Compound-1794 H S-67 S-60 S-60 Compound-1745 H S-66 S-61 S-61 Compound-1795 H S-67 S-61 S-61 Compound-1746 H S-66 S-63 S-63 Compound-1796 H S-67 S-63 S-63 Compound-1747 H S-66 S-64 S-64 Compound-1797 H S-67 S-64 S-64 Compound-1748 H S-66 S-66 S-66 Compound-1798 H S-67 S-66 S-66 Compound-1749 H S-66 S-67 S-67 Compound-1799 H S-67 S-67 S-67 Compound-1750 H S-66 S-68 S-68 Compound-1800 H S-67 S-68 S-68

[0059]

[0060]

[0061] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1899 H H S-30 H Compound-1949 H H S-54 H Compound-1900 H S-1 S-30 H Compound-1950 H S-1 S-54 H Compound-1901 H S-3 S-30 H Compound-1951 H S-3 S-54 H Compound-1902 H S-4 S-30 H Compound-1952 H S-4 S-54 H Compound-1903 H S-5 S-30 H Compound-1953 H S-5 S-54 H Compound-1904 H S-6 S-30 H Compound-1954 H S-6 S-54 H Compound-1905 H S-7 S-30 H Compound-1955 H S-7 S-54 H Compound-1906 H S-8 S-30 H Compound-1956 H S-8 S-54 H Compound-1907 H S-9 S-30 H Compound-1957 H S-9 S-54 H Compound-1908 H S-12 S-30 H Compound-1958 H S-12 S-54 H Compound-1909 H S-13 S-30 H Compound-1959 H S-13 S-54 H Compound-1910 H S-14 S-30 H Compound-1960 H S-14 S-54 H Compound-1911 H S-15 S-30 H Compound-1961 H S-15 S-54 H Compound-1912 H S-16 S-30 H Compound-1962 H S-16 S-54 H Compound-1913 H S-18 S-30 H Compound-1963 H S-18 S-54 H Compound-1914 H S-19 S-30 H Compound-1964 H S-19 S-54 H Compound-1915 H S-20 S-30 H Compound-1965 H S-20 S-54 H Compound-1916 H S-21 S-30 H Compound-1966 H S-21 S-54 H Compound-1917 H S-30 S-30 H Compound-1967 H S-30 S-54 H Compound-1918 H S-31 S-30 H Compound-1968 H S-31 S-54 H Compound-1919 H S-32 S-30 H Compound-1969 H S-32 S-54 H Compound-1920 H S-33 S-30 H Compound-1970 H S-33 S-54 H Compound-1921 H S-34 S-30 H Compound-1971 H S-34 S-54 H Compound-1922 H S-35 S-30 H Compound-1972 H S-35 S-54 H Compound-1923 H S-36 S-30 H Compound-1973 H S-36 S-54 H Compound-1924 H S-37 S-30 H Compound-1974 H S-37 S-54 H Compound-1925 H S-38 S-30 H Compound-1975 H S-38 S-54 H Compound-1926 H S-39 S-30 H Compound-1976 H S-39 S-54 H Compound-1927 H S-40 S-30 H Compound-1977 H S-40 S-54 H Compound-1928 H S-41 S-30 H Compound-1978 H S-41 S-54 H Compound-1929 H S-42 S-30 H Compound-1979 H S-42 S-54 H Compound-1930 H S-43 S-30 H Compound-1980 H S-43 S-54 H Compound-1931 H S-44 S-30 H Compound-1981 H S-44 S-54 H Compound-1932 H S-45 S-30 H Compound-1982 H S-45 S-54 H Compound-1933 H S-46 S-30 H Compound-1983 H S-46 S-54 H Compound-1934 H S-48 S-30 H Compound-1984 H S-48 S-54 H Compound-1935 H S-49 S-30 H Compound-1985 H S-49 S-54 H Compound-1936 H S-51 S-30 H Compound-1986 H S-51 S-54 H Compound-1937 H S-55 S-30 H Compound-1987 H S-55 S-54 H Compound-1938 H S-56 S-30 H Compound-1988 H S-56 S-54 H Compound-1939 H S-57 S-30 H Compound-1989 H S-57 S-54 H Compound-1940 H S-58 S-30 H Compound-1990 H S-58 S-54 H Compound-1941 H S-59 S-30 H Compound-1991 H S-59 S-54 H Compound-1942 H S-60 S-30 H Compound-1992 H S-60 S-54 H Compound-1943 H S-61 S-30 H Compound-1993 H S-61 S-54 H Compound-1944 H S-63 S-30 H Compound-1994 H S-63 S-54 H Compound-1945 H S-64 S-30 H Compound-1995 H S-64 S-54 H Compound-1946 H S-66 S-30 H Compound-1996 H S-66 S-54 H Compound-1947 H S-67 S-30 H Compound-1997 H S-67 S-54 H Compound-1948 H S-68 S-30 H Compound-1998 H S-68 S-54 H

[0062]

[0063] Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Structural formula <![CDATA[R 1 ]]> <![CDATA[R 2 ]]> <![CDATA[R 3 ]]> <![CDATA[R 4 ]]> Compound-1999 H H H H Compound-2049 H H S-30 S-30 Compound-2000 H S-1 H H Compound-2050 H S-1 S-30 S-30 Compound-2001 H S-3 H H Compound-2051 H S-3 S-30 S-30 Compound-2002 H S-4 H H Compound-2052 H S-4 S-30 S-30 Compound-2003 H S-5 H H Compound-2053 H S-5 S-30 S-30 Compound-2004 H S-6 H H Compound-2054 H S-6 S-30 S-30 Compound-2005 H S-7 H H Compound-2055 H S-7 S-30 S-30 Compound-2006 H S-8 H H Compound-2056 H S-8 S-30 S-30 Compound-2007 H S-9 H H Compound-2057 H S-9 S-30 S-30 Compound-2008 H S-12 H H Compound-2058 H S-12 S-30 S-30 Compound-2009 H S-13 H H Compound-2059 H S-13 S-30 S-30 Compound-2010 H S-14 H H Compound-2060 H S-14 S-30 S-30 Compound-2011 H S-15 H H Compound-2061 H S-15 S-30 S-30 Compound-2012 H S-16 H H Compound-2062 H S-16 S-30 S-30 Compound-2013 H S-18 H H Compound-2063 H S-18 S-30 S-30 Compound-2014 H S-19 H H Compound-2064 H S-19 S-30 S-30 Compound-2015 H S-20 H H Compound-2065 H S-20 S-30 S-30 Compound-2016 H S-21 H H Compound-2066 H S-21 S-30 S-30 Compound-2017 H S-30 H H Compound-2067 H S-30 S-30 S-30 Compound-2018 H S-31 H H Compound-2068 H S-31 S-30 S-30 Compound-2019 H S-32 H H Compound-2069 H S-32 S-30 S-30 Compound-2020 H S-33 H H Compound-2070 H S-33 S-30 S-30 Compound-2021 H S-34 H H Compound-2071 H S-34 S-30 S-30 Compound-2022 H S-35 H H Compound-2072 H S-35 S-30 S-30 Compound-2023 H S-36 H H Compound-2073 H S-36 S-30 S-30 Compound-2024 H S-37 H H Compound-2074 H S-37 S-30 S-30 Compound-2025 H S-38 H H Compound-2075 H S-38 S-30 S-30 Compound-2026 H S-39 H H Compound-2076 H S-39 S-30 S-30 Compound-2027 H S-40 H H Compound-2077 H S-40 S-30 S-30 Compound-2028 H S-41 H H Compound-2078 H S-41 S-30 S-30 Compound-2029 H S-42 H H Compound-2079 H S-42 S-30 S-30 Compound-2030 H S-43 H H Compound-2080 H S-43 S-30 S-30 Compound-2031 H S-44 H H Compound-2081 H S-44 S-30 S-30 Compound-2032 H S-45 H H Compound-2082 H S-45 S-30 S-30 Compound-2033 H S-46 H H Compound-2083 H S-46 S-30 S-30 Compound-2034 H S-48 H H Compound-2084 H S-48 S-30 S-30 Compound-2035 H S-49 H H Compound-2085 H S-49 S-30 S-30 Compound-2036 H S-51 H H Compound-2086 H S-51 S-30 S-30 Compound-2037 H S-55 H H Compound-2087 H S-55 S-30 S-30 Compound-2038 H S-56 H H Compound-2088 H S-56 S-30 S-30 Compound-2039 H S-57 H H Compound-2089 H S-57 S-30 S-30 Compound-2040 H S-58 H H Compound-2090 H S-58 S-30 S-30 Compound-2041 H S-59 H H Compound-2091 H S-59 S-30 S-30 Compound-2042 H S-60 H H Compound-2092 H S-60 S-30 S-30 Compound-2043 H S-61 H H Compound-2093 H S-61 S-30 S-30 Compound-2044 H S-63 H H Compound-2094 H S-63 S-30 S-30 Compound-2045 H S-64 H H Compound-2095 H S-64 S-30 S-30 Compound-2046 H S-66 H H Compound-2096 H S-66 S-30 S-30 Compound-2047 H S-67 H H Compound-2097 H S-67 S-30 S-30 Compound-2048 H S-68 H H Compound-2098 H S-68 S-30 S-30 ,

[0064] Among the above compounds, S-1 to S-68 are as follows

[0065]

[0066] Preferably, chemical formula II is selected from When one of the 1 to R 3 Independently selected from the group consisting of one or more of S-30 to S-113:

[0067]

[0068] The present invention claims protection for a preparation comprising a composition of the organic compound and at least one solvent. The solvent is not limited in any way and can include unsaturated hydrocarbon solvents such as toluene, xylene, mesitylene, tetralin, decalin, bicyclohexane, n-butylbenzene, sec-butylbenzene, tert-butylbenzene, carbon tetrachloride, chloroform, dichloromethane, dichloroethane, chlorobutane, bromobutane, chloropentane, bromopentane, hexyl chloride, bromohexane, chlorocyclohexane, bromocyclohexane, halogenated unsaturated hydrocarbon solvents such as chlorobenzene, dichlorobenzene, trichlorobenzene, ether solvents such as tetrahydrofuran and tetrahydropyran, and ester solvents such as alkyl benzoate.

[0069] Preferably, the combination ratio of the composition of formula (I) and chemical formula II of the present invention is I:II=1:0.25-4.

[0070] The present invention further claims protection for an organic light-emitting device, comprising:

[0071] A first electrode; a second electrode facing the first electrode; and an organic functional layer sandwiched between the first electrode and the second electrode; wherein the organic functional layer comprises the above-mentioned composition.

[0072] Preferably, the functional layer in the organic light-emitting device of the present invention is a light-emitting layer, which contains the above-mentioned composition. The organic light-emitting device has polarized light emission.

[0073] The organic electroluminescent device of the present invention can be classified as top emission, low emission or dual-side emission. The composition of the organic light-emitting device according to the embodiment of the present invention can be applied to electroluminescent devices such as OLED lighting, flexible OLED, organic photoreceptor, organic thin film transistor, etc. BRIEF DESCRIPTION OF THE DRAWINGS

[0074] Figure 1 : Photoluminescence spectrum of composition-1

[0075] Figure 2 : Photoluminescence spectrum of composition-11

[0076] Figure 3 :Polarized luminescence spectrum of compound-1899 DETAILED DESCRIPTION

[0077] In order to help those skilled in the art better understand the present invention, the following will clearly and completely describe the technical solutions in the embodiments of the present invention in conjunction with the accompanying drawings. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative work are within the scope of protection of this application.

[0078] Example 1: Compound-1899

[0079] The synthesis method refers to the examples in CN2023118168788 and known literature, H NMR: 8.68-7.78 (m, 6H), 7.75-7.32 (m, 14H), 6.72-6.64 (m, 2H), 6.54 (dd, 1H), 6.39 (dd, 1H), 6.06 (d, 1H), 5.57 (dd, 1H), 4.16-4.08 (m, 1H), 2.98-2.90 (m, 3H), 2.84 (ddd, 1H), 2.74 (ddd, 1H), 2.42 (ddd, 1H), mass spectrum (ESI) m / z: [M+H] + Theoretical value ([C 40 H 30 N2]+H) + :615.28, measured value:615.3.

[0080] Example 2: Compound-1999

[0081] The synthesis method was carried out with reference to the examples in CN2023118168788 and known literature. H NMR: 8.32-7.79 (m, 5H), 7.77-7.71 (m, 1H), 7.63-7.31 (m, 10H), 6.69 (q, 2H), 6.55 (dd, 1H), 6.41 (dd, 1H), 5.99 (s, 1H), 5.53 (d, 1H), 4.14-4.06 (m, 4H), 3.27-3.00 (m, 2H), 2.95-2.49 (m, 2H). Mass spectrum (ESI) m / z: [M+H] +Theoretical value ([C 40 H 30 N2]+H) + :539.25, measured value:539.2.

[0082]

[0083] The representative compounds of formula (I) of the present invention (Compound-101 to Compound-1319) were prepared with reference to CN2023118168788 or published literature, and the representative compounds of formula II (E-1-1 to E-1-4) were prepared with reference to published materials.

[0084] Composition Example: The compound represented by formula (I) and the compound represented by chemical formula II were mixed in a molar ratio of 1:1 to obtain composition 1-24. The photoluminescence peak positions of composition 1-24 are shown in Table 1 and Figure 1 、 2 As shown:

[0085] Table 1

[0086]

[0087]

[0088] OLED device example: The compound structure used in the OLED device is as follows

[0089]

[0090] Device Example 1: On glass containing ITO, the evaporation rate of the organic material is 2000 nm by heating and evaporation under high vacuum. An OLED device was fabricated with the following structure: ITO / HT-1:P-3 (97:3 v / v%) (10 nm) / HT-1 (35 nm) / Compound-101 (20 nm) / Compound-101:E-1-1 (1:1 v / v%) (10 nm) / E-1-4 (10 nm) / E-1-4:LiQ (50:50 v / v%) (25 nm) / Yb (1 nm) / Al (40 nm). The layers are separated by " / " and the thickness of each layer is indicated in parentheses. Current density-voltage-luminance curves were measured using a Keithley 2400 ammeter and a PR670 spectrometer. The OLED was characterized using standard methods, as shown in Table 2.

[0091] Device Example 2: Compound-701 was used to replace Compound-101 in Device Example 1, while the materials and thicknesses of other layers remained unchanged.

[0092] Device Example 3: Compound-1899 was used to replace Compound-101 in Device Example 1, while the materials and thicknesses of other layers remained unchanged.

[0093] Device Example 4: Compound-1999 was used to replace Compound-101 in Device Example 1, while the materials and thicknesses of other layers remained unchanged.

[0094] Comparative device 1: prepared by replacing compound-101 in device example 1 with mCP, while the materials and thicknesses of other layers remained unchanged.

[0095] Comparative device 2: Compound-101 in device example 1 was replaced with HT-2, while the materials and thicknesses of other layers remained unchanged.

[0096] Table 2

[0097] Turn-on voltage V Luminescence peak nm EQE (%) Device 1 3.0 426 21.6 Device 2 2.6 502 25 Device 3 2.9 428 22.3 Device 4 3.0 424 22.1 Comparison device 1 3.2 428 20.1 Comparison device 2 3.1 423 19.8

[0098] The above examples illustrate that the composition of the present invention can achieve deep blue exciplex luminescence and has polarized luminescence ( Figure 3 ); After being applied to the light-emitting layer, a high-efficiency deep blue light OLED device with polarized light emission was obtained.

[0099] While the embodiments of the present invention have been described in detail above, those skilled in the art will readily appreciate other embodiments of the present invention after considering the specification and practicing the invention disclosed herein. This application is intended to cover any variations, uses, or adaptations of the present invention that adhere to the general principles of this application and include both disclosed and undisclosed common knowledge or customary techniques in the art. The description and examples are to be considered merely as exemplary, and the true scope and spirit of the present application are indicated by the claims.

[0100] It should be understood that the present application is not limited to the precise structure described above and shown in the accompanying drawings, and various modifications and changes can be made without departing from the scope of the present application. The scope of the present application is limited only by the appended claims. The above description is only a preferred embodiment of the present application and is not intended to limit the present application. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present application shall be included in the scope of protection of the present application.

Claims

1. A composition comprising a compound represented by formula (I) and formula II, wherein formula (I) is as follows: wherein L is independently selected from a combination of two or more of the following structures, L 1 Independently selected from one of the following structures: L 2 Absent, or independently selected from a single bond, NR 1 , CR 1 R 2 、SiR 1 R 2 , O, S, or one of the following structures: Above R, R 1 、R 2 independently selected from H, D, F, or one selected from substituted or unsubstituted C1-C30 alkyl, substituted or unsubstituted C1-C30 cycloalkyl, substituted or unsubstituted C1-C30 heteroalkyl, substituted or unsubstituted C6-C30 aryl, substituted or unsubstituted C1-C30 heteroaryl, or substituted or unsubstituted C1-C30 silicon; n is 0 or an integer of 1-6; The structure of Chemical Formula II is: In Formula II, Y1 to Y6 are independently selected from N or C-L4-R 4 At least two of Y1 to Y6 are N; L4 is independently selected from a single bond, a substituted or unsubstituted C6-C20 arylene group, a substituted or unsubstituted C2-C20 heterocyclic group, or a combination thereof; R 4 independently selected from hydrogen, deuterium, CN, halogen, substituted or unsubstituted C1-C60 alkyl, substituted or unsubstituted C1-C60 cycloalkyl, substituted or unsubstituted C1-C60 heteroalkyl, substituted or unsubstituted C6-C60 aryl, substituted or unsubstituted C1-C60 heteroaryl, substituted or unsubstituted C1-C60 silicon, substituted or unsubstituted C1-C60 amino; when adjacent R 4 When there are two or more, they can form a ring with each other; in Formula I or Formula II, R 1 to R 4 Each independently may be partially or fully deuterated, each independently may be partially or fully fluorinated; R 1 to R 4 It can be unsubstituted or polysubstituted according to the principle of valence.

2. The composition according to claim 1, characterized in that L in formula (I) is independently selected from one of the following structures to form a cyclophane: Wherein R is independently selected from one of hydrogen, deuterium, F, C1-C6 alkyl, C1-C6 heteroalkyl, substituted or unsubstituted C1-C30 cycloalkyl, substituted or unsubstituted C6-C30 aryl, or substituted or unsubstituted C1-C30 heteroaryl.

3. The composition according to claim 1, characterized in that Formula (I) in the composition is independently selected from one of Formula 2-1 to Formula 2-12, X in Formula 2-1 to Formula 2-12 is independently selected from CR 1 R 2 、SiR 1 R 2 , O; Y is a single bond or independently selected from CR 1 R 2 、SiR 1 R 2 , O, R, R 1 、R 2 independently selected from H, D, F, or one selected from substituted or unsubstituted C1-C30 alkyl, substituted or unsubstituted C1-C30 cycloalkyl, substituted or unsubstituted C1-C30 heteroalkyl, substituted or unsubstituted C6-C30 aryl, substituted or unsubstituted C1-C30 heteroaryl, or substituted or unsubstituted C1-C30 silicon; Chemical formula II is selected from one of the structures represented by E-1 or E-2: Wherein, L4 is independently selected from a single bond, a substituted or unsubstituted C6-C20 arylene group, a substituted or unsubstituted C2-C20 heterocyclic group, or a combination thereof; R 4 independently selected from hydrogen, deuterium, CN, halogen, substituted or unsubstituted C1-C60 alkyl, substituted or unsubstituted C1-C60 cycloalkyl, substituted or unsubstituted C1-C60 heteroalkyl, substituted or unsubstituted C6-C60 aryl, substituted or unsubstituted C1-C60 heteroaryl, substituted or unsubstituted C1-C60 silicon, substituted or unsubstituted C1-C60 amino; when adjacent R 4 When there are two or more of them, they may form a ring with each other; they may be partially or fully deuterated, and each independently may be partially or fully fluorinated.

4. The composition according to claim 1, characterized in that The compound represented by formula (I) is selected from one of the following structures: Among the above compounds, S-1 to S-68 are as follows 5. The composition according to claim 1, characterized in that Chemical formula II is selected from When one of the 1 to R 3 Independently selected from the group consisting of one or more of S-30 to S-113:

6. A preparation, characterized in that The invention comprises the cyclophane organic compound according to any one of claims 1 to 5 and at least one solvent, wherein the solvent is an unsaturated hydrocarbon solvent, a saturated hydrocarbon solvent, an ether solvent or an ester solvent.

7. The composition according to claim 1, characterized in that The molar ratio of the combination of formula (I) and chemical formula II in the composition is I:II=1:0.25-4.

8. An organic light-emitting device, characterized in that: include: a first electrode; a second electrode, facing the first electrode; an organic functional layer, sandwiched between the first electrode and the second electrode; Wherein, the organic functional layer comprises the composition according to any one of claims 1 to 7.

9. The organic light-emitting device according to claim 8, characterized in that: The functional layer of the organic light-emitting device is a light-emitting layer, and the light-emitting layer contains the composition.

10. The organic light emitting device according to claims 8 to 9, characterized in that: The light emitting device has polarized light emission.

11. A display or lighting device, characterized in that: The display or lighting device comprises the organic light-emitting device according to any one of claims 8 to 10.

Images