固化速率可调节的超分子主客体光引发剂和环氧胶粘剂

By using supramolecular host-guest photoinitiators to create a delayed curing window in UV epoxy adhesives, the problem of curing UV epoxy adhesives on low UV transmittance substrates is solved, enabling flexible control of the curing rate and improvement of bond strength.

CN121005912BActive Publication Date: 2026-07-17STEADYCHEM (SHANGHAI) CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
STEADYCHEM (SHANGHAI) CO LTD
Filing Date
2025-08-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing UV epoxy adhesives cannot be effectively cured on substrates that cannot be penetrated by ultraviolet light, and existing delayed curing solutions lack universality, making it difficult to meet the delay effects and process requirements of various formulations.

Method used

A supramolecular host-guest photoinitiator is used, in which the guest photoinitiator is encapsulated by the supramolecular host compound to form a delayed curing window. An adjustable delayed window is provided by adjusting the macrocyclic size of the host compound and the type of initiator. Reactive functional groups are combined to enhance adhesion and moisture barrier properties.

Benefits of technology

It enables delayed curing on low UV transmission components, provides flexible curing rate control, solves the curing problem of low UV transmission components, and improves construction convenience and bonding strength.

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Abstract

本发明公开了一种固化速率可调节的超分子主客体光引发剂和环氧胶粘剂,所述超分子主客体光引发剂包括超分子主体化合物和包结其中的客体光引发剂,超分子主体化合物具有重复单元数在2‑30的大环结构,客体光引发剂包括阳离子光引发剂;超分子主客体光引发剂中,超分子主体化合物和客体光引发剂的摩尔比例为(0.8‑1.5):1,碳元素和氢元素的质量百分比为(40‑75):(3‑8)。UV环氧胶粘剂包括所述固化速率可调节的超分子主客体光引发剂,在UV光照射引发后形成延迟固化的窗口期,胶粘剂流动和涂覆性能优异,窗口期之后胶粘剂可不依赖光照继续引发聚合固化,也可控制热量输入,调节固化速率。
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