Efficient glass cleaning fluid for vehicles and preparation method of efficient glass cleaning fluid
A high-efficiency automotive windshield washer fluid prepared by using a specific combination of surfactants and chelating agents solves the problems of poor cleaning performance and wiper noise in existing washer fluids, achieving both high-efficiency cleaning and reduced noise.
Patent Information
- Application Number
- CN202410747536.3
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2024-06-11
- Publication Date
- 2025-12-12
AI Technical Summary
Existing automotive windshield washer fluids are not effective at cleaning, especially for oil stains. Furthermore, windshield washer fluids containing surfactants can easily cause abnormal noise from the wipers or a blurry windshield surface.
A high-efficiency automotive windshield washer fluid was prepared by using sulfonates of fatty acid methyl ester ethoxylates, fatty acid methyl ester ethoxylates, and sodium alkyl alcohol polyether sulfate as surfactants, and in combination with sodium ethylenediaminetetraacetic acid as a chelating agent. The synergistic effect of different surfactants improves the cleaning effect and reduces wiper noise.
It achieves efficient cleaning of oil stains, reduces wiper noise, has high and low temperature stability and low residue characteristics, and provides good driving visibility.
Smart Images

Figure BDA0004886864650000041 
Figure BDA0004886864650000042 
Figure BDA0004886864650000043
Abstract
Description
TECHNICAL FIELD
[0001] The application belongs to the technical field of glass cleaning solution, and particularly relates to a high-efficiency glass cleaning solution for vehicles and a preparation method thereof. BACKGROUND
[0002] During driving, the automobile is impacted by pollution particles such as coal ash, dust and insects, and the pollution particles are adhered to the glass to form dirt which is difficult to remove. The glass cleaning solution has a high wetting, dissolving and dissociating dispersion effect, and has a very significant dirt removal effect. In particular, the glass cleaning solution is sprayed onto the automobile glass through a nozzle, and the glass is cleaned by starting the wiper, so that the glass is easily cleaned, the glass is not damaged by the irregular small sand particles carried by the wiper, and the glass is effectively protected, and the glass cleaning solution also has a certain anti-fog effect.
[0003] However, the cleaning ability of the automobile glass cleaning solution on the market is generally low, and the glass with oil stains cannot be cleaned well. Although the special oil film removing glass cleaning solution has good cleaning effect, the glass cleaning solution has the problem of excessive solid particle residue after evaporation due to excessive addition of the surfactant.
[0004] In addition, most of the glass cleaning solutions on the market are not comprehensively considered, especially when the glass cleaning solution is used with the wiper, the glass cleaning solution with the defoaming agent can cause abnormal sound of the wiper, and the glass cleaning solution with ethylene glycol can cause the surface of the windshield to be blurred after being cleaned by the wiper. SUMMARY
[0005] Therefore, the application aims to provide a high-efficiency glass cleaning solution for vehicles and a preparation method thereof, which has high cleaning effect and is suitable for use with the wiper.
[0006] The application provides a high-efficiency glass cleaning solution for vehicles, which comprises:
[0007] 0.01-0.5 parts by weight of a surfactant;
[0008] 0.01-0.5 parts by weight of a chelating agent;
[0009] water, supplemented to 100 parts by weight;
[0010] The surfactant comprises a sulfonate of fatty acid methyl ester ethoxylate, a sodium salt of fatty acid methyl ester ethoxylate and alkyl alcohol polyether sulfate.
[0011] Preferably, the mass ratio of the sulfonate of fatty acid methyl ester ethoxylate, the sodium salt of fatty acid methyl ester ethoxylate and alkyl alcohol polyether sulfate is (0.015-0.06):(0.03-0.1):(0.1-0.4).
[0012] Preferably, the structure of the alkyl alcohol polyether sulfate sodium salt is [R-O(CH2-CH2-O)2-SO3] - Na + ; wherein R is C12-C16 alkyl group;
[0013] And / or, the chelating agent is selected from the group consisting of ethylenediaminetetraacetic acid disodium salt and / or ethylenediaminetetraacetic acid tetrasodium salt.
[0014] Preferably, it also includes 10-50 parts by weight of an alcohol solvent; the alcohol solvent is a normal monohydric alcohol and / or a dihydric alcohol.
[0015] Preferably, the normal monohydric alcohol is selected from the group consisting of methanol and / or ethanol; the dihydric alcohol is selected from the group consisting of ethylene glycol.
[0016] Preferably, it also includes 5-20 parts by weight of isopropanol.
[0017] Preferably, it also includes 0.001-0.01 parts by weight of a preservative;
[0018] And / or, it also includes 0.001-0.01 parts by weight of a pigment.
[0019] Preferably, the preservative is selected from the group consisting of carzone preservative and / or BIT-10 preservative;
[0020] The pigment is selected from the group consisting of indigo pigment and / or lemon yellow.
[0021] Preferably, the pH value of the high-efficiency glass cleaning solution for vehicles is 8-9.
[0022] The application also provides a preparation method of the above-mentioned high-efficiency glass cleaning solution for vehicles, comprising the following steps:
[0023] Mixing water, a surfactant and a chelating agent to obtain a high-efficiency glass cleaning solution for vehicles.
[0024] This invention provides a high-efficiency automotive glass cleaner, comprising: 0.01 to 0.5 parts by weight of surfactant; 0.01 to 0.5 parts by weight of chelating agent; and water to a total of 100 parts by weight; wherein the surfactant comprises sulfonate of fatty acid methyl ester ethoxylate, fatty acid methyl ester ethoxylate, and sodium sulfate of alkyl alcohol polyether. Compared with existing technologies, this invention uses three surfactants—FMES, FMEE, and sodium alkyl alcohol polyether sulfate—as active, cleaning, degreasing, and lubricating components. FMEE and FMES both have excellent degreasing and dewaxing capabilities and are easily soluble in water, while also possessing low pollution and high stability. The sodium alkyl alcohol polyether sulfate surfactant has highly efficient foaming properties, which can effectively lubricate the windshield wipers during operation, reducing abnormal noise during wiper operation, and further enhancing the foaming and degreasing film removal effects of the windshield washer fluid. Through the synergistic use of different surfactants, the high-efficiency automotive windshield washer fluid not only has a strong degreasing film and windshield lubrication effect to prevent windshield wiper noise, but also has advantages such as good high and low temperature stability and low residue after being sprayed on the windshield and dried. Attached Figure Description
[0025] Figure 1 Charts showing the grading of wiper cleaning performance and the classification of wiper wiping defects;
[0026] Figure 2 This is a chart for classifying the wiper cleaning performance and categorizing wiper defects. Detailed Implementation
[0027] The technical solutions of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. Obviously, the described embodiments are only some embodiments of the present invention, and not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative effort are within the scope of protection of the present invention.
[0028] This invention provides a high-efficiency automotive windshield washer fluid, comprising:
[0029] Surfactant: 0.01–0.5 parts by weight;
[0030] Chelating agent 0.01-0.5 parts by weight;
[0031] Add water to bring the total to 100 parts by weight;
[0032] The surfactants include sulfonates of fatty acid methyl ester ethoxylates, fatty acid methyl ester ethoxylates, and sodium sulfate of alkyl alcohol polyethers.
[0033] The high-efficiency glass cleaning solution for vehicles provided by the present application adds non-ionic and anionic surfactants as active, cleaning, oil-removing and lubricating components, further strengthens the foaming and oil-removing film effect of the glass water, and makes the cleaning solution not only have strong oil-removing film and lubricating windshield glass to avoid the abnormal sound of the windscreen wiper, but also have good high and low temperature stability, low residue after spraying and drying on the windshield glass, and other advantages.
[0034] According to the present application, the content of the surfactant in the high-efficiency glass cleaning solution for vehicles is preferably 0.05-0.5 parts by weight, more preferably 0.1-0.5 parts by weight, and more preferably 0.2-0.5 parts by weight; in some embodiments provided by the present application, the content of the surfactant in the high-efficiency glass cleaning solution for vehicles is specifically 0.23 parts by weight, 0.31 parts by weight, 0.2 parts by weight, 0.295 parts by weight or 0.5 parts by weight.
[0035] According to the present application, the surfactant includes sulfonate of fatty acid methyl ester ethoxylate (FMEE), fatty acid methyl ester ethoxylate (FMEE) and sodium salt of alkyl alcohol polyether sulfate; the structure of the sodium salt of alkyl alcohol polyether sulfate is preferably [R-O(CH2-CH2-O)2-SO3] - Na + ; wherein R is preferably C12-C16 alkyl, and more preferably C12-C14 alkyl; in embodiments provided by the present application, Genapol LRO liquid surfactant is specifically taken as an example for illustration; the mass ratio of the sulfonate of fatty acid methyl ester ethoxylate, the fatty acid methyl ester ethoxylate and the sodium salt of alkyl alcohol polyether sulfate is preferably (0.015-0.06):(0.03-0.1):(0.1-0.4); in some embodiments provided by the present application, the mass ratio of the sulfonate of fatty acid methyl ester ethoxylate, the fatty acid methyl ester ethoxylate and the sodium salt of alkyl alcohol polyether sulfate is specifically 0.05:0.08:0.1, 0.06:0.1:0.15, 0.02:0.03:0.15, 0.015:0.03:0.25 or 0.04:0.06:0.4.
[0036] According to the present application, the content of the chelating agent in the high-efficiency glass cleaning solution for vehicles is preferably 0.01-0.3 parts by weight, more preferably 0.01-0.2 parts by weight, more preferably 0.01-0.1 parts by weight, more preferably 0.01-0.05 parts by weight, and most preferably 0.01-0.02 parts by weight; the chelating agent can be any chelating agent known to those skilled in the art without special limitation, and in the present application, sodium ethylenediaminetetraacetate is preferred, and disodium ethylenediaminetetraacetate (EDTA-2Na) and / or tetrasodium ethylenediaminetetraacetate are more preferred.
[0037] According to the present application, the high-efficiency glass cleaning solution for vehicles preferably further comprises 10-50 parts by weight of an alcohol solvent, more preferably 15-45 parts by weight of the alcohol solvent, even more preferably 20-40 parts by weight of the alcohol solvent, and most preferably 20-35 parts by weight of the alcohol solvent; the alcohol solvent is a normal monohydric alcohol and / or a dihydric alcohol; in one specific embodiment provided by the present application, the normal monohydric alcohol is preferably methanol and / or ethanol; in another specific embodiment provided by the present application, the dihydric alcohol is preferably ethylene glycol.
[0038] According to the present application, the high-efficiency glass cleaning solution for vehicles preferably further comprises 5-20 parts by weight of isopropyl alcohol, more preferably 5-15 parts by weight of isopropyl alcohol, even more preferably 8-12 parts by weight of isopropyl alcohol, and most preferably 10 parts by weight of isopropyl alcohol.
[0039] In one specific embodiment provided by the present application, the high-efficiency glass cleaning solution for vehicles preferably further comprises 10-50 parts by weight of an alcohol solvent and 5-20 parts by weight of isopropyl alcohol. Through the action of the alcohol solvent and isopropyl alcohol, the freezing point of the liquid is reduced, the automobile glass water has good antifreeze effect, the ice frost is quickly dissolved, and the oil removal capacity is increased.
[0040] According to the present application, the high-efficiency glass cleaning solution for vehicles preferably further comprises 0.001-0.01 parts by weight of a preservative, more preferably 0.005-0.01 parts by weight of the preservative, and even more preferably 0.008-0.01 parts by weight of the preservative; the preservative is any preservative known to those skilled in the art without special limitation, and in the present application, a Kathon preservative and / or a BIT-10 preservative are preferred.
[0041] According to the present application, the high-efficiency glass cleaning solution for vehicles preferably further comprises 0.001-0.01 parts by weight of a pigment, more preferably 0.005-0.01 parts by weight of the pigment, and even more preferably 0.008-0.01 parts by weight of the pigment; the pigment is any pigment known to those skilled in the art without special limitation, and in the present application, an indigo pigment and / or a lemon yellow pigment are preferred.
[0042] In order to make the high-efficiency glass cleaning solution for vehicles have a stable pH value and reduce corrosion to metal, the high-efficiency glass cleaning solution for vehicles preferably further comprises a pH value adjusting agent; the pH value adjusting agent is any alkaline compound known to those skilled in the art without special limitation, and in the present application, an alkali metal hydroxide is preferred, and more preferably sodium hydroxide; the amount of the pH value adjusting agent preferably makes the pH value of the high-efficiency glass cleaning solution for vehicles be 8-9.
[0043] In addition to the above components, the high-efficiency glass cleaning solution for vehicles is supplemented with water to make the whole cleaning solution be 100 parts by weight; the water is preferably deionized water.
[0044] In a specific embodiment provided by the present application, the high-efficiency glass cleaning solution for vehicles comprises:
[0045]
[0046] or comprises:
[0047]
[0048] or comprises:
[0049]
[0050] or comprises:
[0051]
[0052] or comprises:
[0053]
[0054] The present application uses three surfactants, FMES, FMEE and alkyl alcohol polyether sulfate sodium salt, as active, cleaning, oil removal and lubricating components. FMEE and FMES have excellent oil and wax removal ability, are easily soluble in water, and have the characteristics of low pollution and high stability. The alkyl alcohol polyether sulfate sodium salt surfactant has high foaming performance and can well lubricate the operation of the rain screen, reduce the occurrence of abnormal sound during the operation of the rain screen, further strengthen the foaming and dirt / oil removal effect of the glass cleaner, and through the mutual cooperation of different surfactants, the high-efficiency glass cleaning solution for vehicles not only has the effect of strong oil film removal and lubrication of the windshield to avoid abnormal sound of the rain screen, but also has the advantages of good high and low temperature stability, low residue after spraying and drying on the windshield, etc.
[0055] The present application also provides a preparation method of the high-efficiency glass cleaning solution for vehicles, comprising the following steps: mixing water, a surfactant and a chelating agent to obtain the high-efficiency glass cleaning solution for vehicles.
[0056] In the present application, all raw materials are commercially available without special restrictions; the surfactant and the chelating agent are the same as described above and will not be repeated here.
[0057] According to the present application, the water is preferably mixed with the surfactant uniformly first, then the chelating agent is added, preferably the preservative and / or pigment are further added, and then the alcohol solvent and / or isopropyl alcohol are further added, and the high-efficiency glass cleaning solution for vehicles is obtained after mixing uniformly; the preservative, pigment, alcohol solvent and isopropyl alcohol are the same as described above and will not be repeated here.
[0058] In a specific embodiment provided by the application, the preparation method of the high-efficiency glass cleaning solution for vehicles specifically comprises the following steps: Step 1, taking deionized water for standby, and adding FMES, FMEE and alkyl alcohol polyether sodium sulfate surfactant into the deionized water while stirring to mix uniformly; Step 2, then adding Kathon preservative, EDTA-2Na (chelating agent) and industrial indigo pigment into the solution obtained in Step 1 in sequence and stirring to mix uniformly; and Step 3, adding mono-alcohol and / or di-alcohol and isopropyl alcohol into the solution obtained in Step 2, and stirring gently until the solution is completely mixed to obtain the high-efficiency glass cleaning solution for vehicles.
[0059] In order to make the high-efficiency glass cleaning solution for vehicles have a stable pH value and reduce corrosion to metal, the obtained high-efficiency glass cleaning solution for vehicles needs to be finally adjusted in pH value to meet the national standard.
[0060] The high-efficiency glass cleaning solution for vehicles prepared by the application has good cleaning effect, can greatly reduce the abnormal sound problem of wiper caused by oil film on the windshield, and can clean the windshield well to provide a good driving view for customers.
[0061] In order to further illustrate the application, the high-efficiency glass cleaning solution for vehicles and the preparation method thereof provided by the application are described in detail below in combination with examples.
[0062] The reagents used in the following examples are all commercially available. The selection of raw materials used in each example is as follows:
[0063] Deionized water, purity 99.9%;
[0064] FMES surfactant, purity 70%;
[0065] FMEE surfactant, purity 70%;
[0066] Alkyl alcohol polyether sodium sulfate, Genapol LRO liquid surfactant is selected, purity 28%;
[0067] Kathon preservative, purity 99%;
[0068] Isopropyl alcohol, purity 98%;
[0069] Mono-alcohol and di-alcohol, purity 99.9%.
[0070] Example 1
[0071] A formula of high-efficiency glass cleaning solution, according to mass percentage, comprises deionized water, 0.5‰ FMES surfactant, 0.8‰ FMEE surfactant, 1‰ alkyl alcohol polyether sodium sulfate, 0.1‰ Kathon preservative, 0.1‰ EDTA-2Na chelating agent and 0.1‰ industrial indigo pigment.
[0072] The preparation method of the windscreen washer fluid of the embodiment specifically comprises the following steps:
[0073] Step one, take deionized water for standby, and add 0.5‰ of FMES surfactant, 0.8‰ of FMEE surfactant and 1‰ of alkyl alcohol polyether sulfate sodium salt surfactant into the deionized water while stirring, and stir uniformly;
[0074] Step two, then add 0.1‰ of Kathon preservative, 0.1‰ of EDTA-2Na chelating agent and 0.1‰ of industrial indigo pigment into the liquid obtained in step one in sequence and stir fully.
[0075] Step three, test the pH value of the above-mentioned stock solution, and use pH regulator NaOH to adjust the pH value so that the pH value of the windscreen washer fluid is between 8 and 9.
[0076] Embodiment 2
[0077] A high-efficiency cleaning windscreen washer fluid formula comprises, in terms of mass percentage, deionized water, 0.6‰ of FMES surfactant, 1‰ of FMEE surfactant, 1.5‰ of alkyl alcohol polyether sulfate sodium salt, 0.1‰ of Kathon preservative, 0.1‰ of EDTA-2Na chelating agent and 0.1‰ of industrial indigo pigment.
[0078] The high-efficiency cleaning windscreen washer fluid formula of the embodiment specifically comprises the following steps:
[0079] Step one, take deionized water for standby, 0.2‰ of FMES surfactant, 0.3‰ of FMEE surfactant and 1.5‰ of alkyl alcohol polyether sulfate sodium salt surfactant, and stir uniformly;
[0080] Step two, then add 0.1‰ of Kathon preservative, 0.1‰ of EDTA-2Na chelating agent and 0.1‰ of industrial indigo pigment into the liquid obtained in step one in sequence and stir fully.
[0081] Step three, test the pH value of the above-mentioned stock solution, and use pH regulator NaOH to adjust the pH value so that the pH value of the windscreen washer fluid is between 8 and 9.
[0082] Embodiment 3
[0083] A high-efficiency cleaning windscreen washer fluid formula comprises, in terms of mass percentage, deionized water, 0.2‰ of FMES surfactant, 0.3‰ of FMEE surfactant, 1.5‰ of alkyl alcohol polyether sulfate sodium salt surfactant, 0.1‰ of Kathon preservative, 0.1‰ of EDTA-2Na chelating agent, 0.1‰ of industrial indigo pigment, 20% of ethanol and 10% of isopropyl alcohol.
[0084] The preparation method of the high-efficiency cleaning glass water of the embodiment specifically comprises the following steps:
[0085] Step one, take deionized water for standby, and add 0.2‰ FMES surfactant, 0.3‰ FMEE surfactant and 1.5‰ alkyl alcohol polyether sulfate sodium salt surfactant into the deionized water while stirring, and stir uniformly;
[0086] Step two, then add 0.1‰ Kason preservative, 0.1‰ EDTA-2Na chelating agent and 0.1‰ industrial indigo pigment into the liquid obtained in step one in sequence and stir uniformly.
[0087] Step three, add 20% ethanol and 10% isopropyl alcohol into the solution obtained in step two, and gently stir until the solution is completely mixed to prepare the automobile glass water.
[0088] Embodiment 4
[0089] The formula of the high-efficiency cleaning glass water comprises deionized water, 0.15‰ FMES surfactant, 0.3‰ FMEE surfactant, 2.5‰ alkyl alcohol polyether sulfate sodium salt surfactant, 0.1‰ Kason preservative, 0.1‰ EDTA-2Na chelating agent, 0.1‰ industrial indigo pigment and 35% methanol according to the mass percentage.
[0090] The preparation method of the high-efficiency cleaning glass water of the embodiment specifically comprises the following steps:
[0091] Step one, take deionized water for standby, and add 0.15‰ FMES surfactant, 0.3‰ FMEE surfactant and 2.5‰ alkyl alcohol polyether sulfate sodium salt surfactant into the deionized water while stirring, and stir uniformly;
[0092] Step two, then add 0.1‰ Kason preservative, 0.1‰ EDTA-2Na chelating agent and 0.1‰ industrial indigo pigment into the liquid obtained in step one in sequence and stir uniformly.
[0093] Step three, add 35% methanol into the solution obtained in step two, and gently stir until the solution is completely mixed to prepare the automobile glass water.
[0094] Embodiment 5
[0095] The formula of the high-efficiency cleaning glass water comprises deionized water, 0.4‰ FMES surfactant, 0.6‰ FMEE surfactant, 4‰ alkyl alcohol polyether sulfate sodium salt surfactant, 0.1‰ Kason preservative, 0.1‰ EDTA-2Na chelating agent, 0.1‰ industrial indigo pigment and 20% ethanol according to the mass percentage.
[0096] The preparation method of the high-efficiency cleaning glass water of the embodiment specifically comprises the following steps:
[0097] Step one, take deionized water for standby, and add 0.4 ‰ FMES surfactant, 0.6 ‰ FMEE surfactant and 4 ‰ alkyl alcohol polyether sulfate sodium salt surfactant into the deionized water while stirring, and stir uniformly;
[0098] Step two, then add 0.1 ‰ Kason preservative, 0.1 ‰ EDTA-2Na chelating agent and 0.1 ‰ industrial indigo pigment into the liquid obtained in step one in sequence, and stir uniformly.
[0099] Step three, add 20% ethanol into the solution obtained in step two, and gently stir until the solution is completely mixed, to prepare the automobile glass water.
[0100] Comparative example 1
[0101] In the embodiment 5, the alkyl alcohol polyether sulfate sodium salt is replaced by AEO-9 as the surfactant: including deionized water, 0.4 ‰ FMES surfactant, 0.6 ‰ FMEE surfactant, 4 ‰ AEO-9 surfactant, 0.1 ‰ Kason preservative, 0.1 ‰ EDTA-2Na chelating agent, 0.1 ‰ industrial indigo pigment and 20% ethanol.
[0102] Comparative example 2
[0103] In the embodiment 5, the FMES is replaced by Genapol LRO liquid surfactant as the surfactant: including deionized water, 0.4 ‰ Genapol LRO liquid surfactant, 0.6 ‰ FMEE surfactant, 4 ‰ alkyl alcohol polyether sulfate sodium salt surfactant, 0.1 ‰ Kason preservative, 0.1 ‰ EDTA-2Na chelating agent, 0.1 ‰ industrial indigo pigment and 20% ethanol.
[0104] The glass water prepared by the embodiment of the application and the glass water obtained by the comparative examples are compared in performance, and the results are shown in Table 1. The windshield glass (length 1400 mm, width 1000 mm) is uniformly coated with 20 g of edible blend oil on the surface of the windshield glass, which pollutes the glass and makes it hydrophobic. The wiper is brushed on the windshield glass, the abnormal sound of the wiper under the glass water is checked, the wiper cleaning degree after 30 times of brushing is checked, and the width of the residue after the glass water completely volatilizes is checked, and the results are shown in Table 1. Among them, the detection method of the wiper cleaning degree after 30 times of brushing is specifically as follows: take a new rubber strip, check the brushing level of the new state as 10, then uniformly spray the glass with the glass water, the flow rate is 15-20 mL / s, and continuously brush for 30 cycles, and the wiper cleaning degree checking classification and the wiper defect classification table are as follows: Figure 1 and Figure 2The width of the residue after the glass water is completely volatilized is detected. The detection method is as follows: the test environment is as follows: the air humidity is 60% to 70%, the ambient temperature is 25±2 degrees Celsius, the environment is windless, the pressure is 100±10 Kpa, 3 mL of the test liquid is measured by a dropper, and is dropped on a clean transparent windshield glass with an inclination of 60°±5°, the liquid is allowed to flow on the glass by gravity until the width of the residue of the non-volatile substance is observed after the glass is dried.
[0105] Table 1: performance comparison results
[0106]
[0107]
[0108] The glass water obtained in Examples 3 to 5 is subjected to the inspection according to GB / T 23436-2009 "Automobile windshield glass cleaning liquid", and the detection results are shown in Table 2.
[0109] Table 2: detection results of the glass water according to the national standard
[0110]
[0111] The above only describes the preferred embodiments of the present application, and it should be noted that those skilled in the art can make several improvements and refinements without departing from the principles of the present application, and these improvements and refinements should also be considered as the protection scope of the present application.
Claims
1. A high-efficiency automotive windshield washer fluid, characterized in that, include: Surfactant: 0.01–0.5 parts by weight; Chelating agent 0.01-0.5 parts by weight; Add water to bring the total to 100 parts by weight; The surfactants include sulfonates of fatty acid methyl ester ethoxylates, fatty acid methyl ester ethoxylates, and sodium sulfate of alkyl alcohol polyethers.
2. The high-efficiency automotive windshield washer fluid according to claim 1, characterized in that, The mass ratio of the sulfonate of the fatty acid methyl ester ethoxylate, the fatty acid methyl ester ethoxylate, and the sodium sulfate of the alkyl alcohol polyether is (0.015-0.06):(0.03-0.1):(0.1-0.4).
3. The high-efficiency automotive windshield washer fluid according to claim 1, characterized in that, The structure of the alkyl alcohol polyether sodium sulfate is [RO(CH2-CH2-O)2-SO3]. - Na + Where R is a C12 to C16 alkyl group; And / or, the chelating agent is selected from disodium ethylenediaminetetraacetate and / or tetrasodium ethylenediaminetetraacetate.
4. The high-efficiency automotive windshield washer fluid according to claim 1, characterized in that, It also includes 10 to 50 parts by weight of alcohol solvent; the alcohol solvent is a monohydric alcohol and / or a dihydric alcohol.
5. The high-efficiency automotive windshield washer fluid according to claim 4, characterized in that, The monohydric alcohol is selected from methanol and / or ethanol; the dihydric alcohol is selected from ethylene glycol.
6. The high-efficiency automotive windshield washer fluid according to claim 1, characterized in that, It also includes 5 to 20 parts by weight of isopropanol.
7. The high-efficiency automotive windshield washer fluid according to claim 1, characterized in that, It also includes 0.001 to 0.01 parts by weight of preservative; And / or, also includes 0.001 to 0.01 parts by weight of pigment.
8. The high-efficiency automotive windshield washer fluid according to claim 7, characterized in that, The preservative is selected from Kathon preservative and / or BIT-10 preservative; The pigment is selected from indigo pigment and / or lemon yellow.
9. The high-efficiency automotive windshield washer fluid according to claim 1, characterized in that, The pH value of the high-efficiency automotive glass cleaner is 8-9.
10. A method for preparing a high-efficiency automotive windshield washer fluid, characterized in that, Includes the following steps: Add 0.01 to 0.5 parts by weight of surfactant to water under stirring, then add 0.001 to 0.01 parts by weight of preservative and 0.001 to 0.01 parts by weight of pigment in sequence, and adjust the pH value to 8 to 9 to obtain a high-efficiency automotive glass cleaner. Alternatively, 0.01 to 0.5 parts by weight of surfactant are added to water under stirring, followed by 0.001 to 0.01 parts by weight of preservative and 0.001 to 0.01 parts by weight of pigment, and then 10 to 50 parts by weight of alcohol solvent to obtain a high-efficiency automotive glass cleaner; wherein the alcohol solvent is a monohydric alcohol and / or a dihydric alcohol. Alternatively, 0.01–0.5 parts by weight of surfactant are added to water under stirring, followed by 0.001–0.01 parts by weight of preservative and 0.001–0.01 parts by weight of pigment, and then 10–50 parts by weight of alcohol solvent and 5–20 parts by weight of isopropanol to obtain a high-efficiency automotive glass cleaner; wherein the alcohol solvent is a monohydric alcohol and / or a dihydric alcohol. The amount of water used makes the total amount of the high-efficiency automotive windshield washer fluid 100 parts by weight.