Ester, base for cosmetics, and cosmetics

Abstract

The present invention provides an ester synthesized from at least one component (A) selected from diols having 2-8 carbon atoms, at least one component (B) selected from dicarboxylic acids having 2-10 carbon atoms, and at least one component (C) selected from hydroxycarboxylic acids having 4-6 carbon atoms and two or more carboxyl groups.

Description

Technical Field

[0001] This invention relates to esters, cosmetic bases composed of the esters, and cosmetics containing the cosmetic bases. Background Technology

[0002] Maintaining moisture is essential for healthy skin, leading to the development of numerous moisturizing cosmetics. In cosmetics, hydrocarbon oils such as petrolatum and liquid paraffin, as well as ester oils such as neopentyl glycol didecanoate and glyceryl tri(2-ethylhexanoate), are used to moisturize and improve skin suppleness. However, due to the stickiness and greasiness associated with some waxes and other hydrocarbon oils, ester oils with less oiliness are preferred. Examples of ester oils with good moisturizing properties and a pleasant user experience include, for instance, an ester synthesized from glycerol, behenic acid, and eicosanoic acid (hereinafter referred to as "glyceryl behenic acid eicosanoate") disclosed in Patent Document 1, and esters composed of polyols, fatty acids with 8 to 30 carbon atoms, and dicarboxylic acids with 12 to 30 carbon atoms (dicarboxylic acids).

[0003] In recent years, there has been a growing preference for environmentally friendly products, with a preference for using natural materials in the bases of these products. In particular, there is a pursuit of superior moisturizing effects without a sticky feel through the use of bases made from natural materials. Specifically, there is a desire for a moisturizing ingredient that is soluble in both oil and water and possesses an oil-like moisturizing effect, allowing it to be incorporated into various formulations for a wide range of applications. As a moisturizing base using natural materials, malic acid, as a type of hydroxycarboxylic acid, is widely used in cosmetics due to its excellent safety and stability. As a derivative of malic acid, for example, diisostearic acid is disclosed in Patent Document 2.

[0004] However, although esters such as glyceryl behenate eicosadecanedioate and diisostearate malate have the functions of oiling agents and moisturizing properties, their application range is limited because they are insoluble in water.

[0005] Existing technical documents

[0006] Patent documents

[0007] Patent Document 1: Japanese Patent Application Publication No. 2009-19049

[0008] Patent Document 2: Japanese Patent Application Publication No. 2020-2055 Invention Summary

[0009] The problem that the invention aims to solve

[0010] The present invention is based on the above circumstances, and its purpose is to provide an ester that has good solubility in water and oil and is non-sticky.

[0011] Methods for solving problems

[0012] The present invention, which achieves the above objectives, is described below.

[0013] [1] An ester obtained by synthesizing components A, B and C.

[0014] Component A is at least one selected from diols having 2 to 8 carbon atoms.

[0015] Component B is at least one selected from dicarboxylic acids having 2 to 10 carbon atoms.

[0016] The component C is at least one selected from hydroxycarboxylic acids having 4 to 6 carbon atoms and having two or more carboxyl groups.

[0017] [2] A cosmetic base, which is composed of the ester described in [1].

[0018] [3] A cosmetic product comprising the cosmetic base described in [2].

[0019] The effects of the invention

[0020] According to the present invention, an ester with good solubility in water and oil and without stickiness can be obtained. Detailed Implementation

[0021] The preferred embodiments of the present invention will be described in detail below.

[0022] Furthermore, all descriptions in this specification may be combined with each other unless explicitly stated otherwise. The numerical ranges specified by “~” in this specification include the values ​​at both ends of the “~” (upper and lower limits). For example, “2~8” means “more than 2 and less than 8”.

[0023] <ester>

[0024] The ester of this invention is synthesized from components A, B, and C.

[0025] Component A is at least one selected from diols having 2 to 8 carbon atoms.

[0026] Component B is at least one selected from dicarboxylic acids having 2 to 10 carbon atoms.

[0027] Component C is at least one of hydroxycarboxylic acids selected from those having 4 to 6 carbon atoms and containing two or more carboxyl groups.

[0028] As component A, examples include, for instance, ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, 1,2-pentanediol, 1,5-pentanediol, 1,2-hexanediol, 1,6-hexanediol, neopentanediol, 1,2-octanediol, 1,6-octanediol, etc.

[0029] From the perspective of the water solubility and user experience of the esters of this invention

[0030] Component A is preferably selected from at least one diol having 2 to 6 carbon atoms.

[0031] More preferably, it is at least one selected from diols having 2 to 4 carbon atoms.

[0032] More preferably, it is selected from at least one type of straight-chain diol having 3 to 4 carbon atoms.

[0033] Particularly preferred are 1,3-propanediol and / or 1,4-butanediol.

[0034] The preferred option is 1,3-propanediol.

[0035] Component B includes, for example, oxalic acid, malonic acid, succinic acid, maleic acid, glutaric acid, adipic acid, sebacic acid, and azelaic acid.

[0036] From the perspective of the solubility of esters in water and oil and their user experience in this invention,

[0037] Component B is preferably selected from at least one dicarboxylic acid having 2 to 8 carbon atoms.

[0038] More preferably, it is selected from at least one dicarboxylic acid having 2 to 6 carbon atoms.

[0039] More preferably, it is selected from at least one of disaturated carboxylic acids having 4 to 6 carbon atoms.

[0040] Succinic acid and / or adipic acid are particularly preferred.

[0041] Examples of components C include malic acid, tartaric acid, and citric acid. The number of carboxyl groups in one molecule of component C is preferably 2 or 3.

[0042] From a user experience perspective

[0043] Component C is preferably selected from at least one hydroxycarboxylic acid having 4 to 6 carbon atoms and having 1 hydroxyl group and 2 or more carboxyl groups.

[0044] More preferably, it is at least one selected from hydroxycarboxylic acids having one hydroxyl group and two or three carboxyl groups, having 4 to 6 carbon atoms.

[0045] Further preferred are malic acid and / or citric acid.

[0046] Malic acid is particularly preferred.

[0047] From the perspective of inhibiting stickiness and water solubility of the ester of the present invention, the preferred proportion is that of the structural component from component A (hereinafter referred to as "A"). mol% The percentage of structural components from component B is 50–65 mol% (hereinafter referred to as "B"). mol% The percentage of structural components derived from component C is 1–25 mol% (hereinafter referred to as “C”). mol% "" is 25-34 mol%. In addition, A mol% B mol% and C mol% The benchmark is the sum of the structural components from components A to C.

[0048] From the perspective of inhibiting the stickiness and water solubility of the ester of this invention, A mol% More preferably, it is 55–65 mol%. Based on the same viewpoint, B mol% More preferably, it is 10-25 mol%, and even more preferably, it is 10-20 mol%. Based on the same viewpoint, C mol% More preferably, it is 25-32 mol%, and even more preferably, it is 25-29 mol%. Based on the same viewpoint, A is more preferably... mol% 50-65 mol%, B mol% 10–25 mol%, C mol% The concentration is 25-32 mol%, with A being the preferred option. mol% 55-65 mol%, B mol% 10–20 mol%, C mol% It is 25-29 mol%.

[0049] A mol% B mol% C mol% By analyzing the ester of the present invention 1 The value was calculated from the 1H NMR spectrum (frequency: 400MHz, solvent: deuterated methanol).

[0050] From the perspective of inhibiting stickiness and water solubility, the hydroxyl value of the ester of the present invention is preferably 100-500 mgKOH / g, more preferably 200-450 mgKOH / g, and even more preferably 300-400 mgKOH / g.

[0051] From the perspective of suppressing stickiness, the kinematic viscosity of the ester of the present invention at 40°C is preferably 100-600 mmHg. 2 / s, more preferably 150-450mm 2 / s, further preferably 150–300 mm 2 / s.

[0052] The esters of the present invention can be prepared by esterification of components A, B, and C. Esterification is well known to those skilled in the art, and they can prepare the esters of the present invention by appropriately setting the conditions for the esterification reaction.

[0053] In esterification reactions, water is typically removed from the system to promote the reaction. Esterification can be carried out under normal or reduced pressure. The temperature for esterification is, for example, 100–200°C. To obtain esters with good color, the preferred temperature for esterification is 100–160°C, more preferably 120–150°C.

[0054] Esterification can be carried out in the presence of a catalyst (e.g., Brønsted acid catalyst, Lewis acid catalyst) or in the absence of a catalyst.

[0055] The esterification reaction can be monitored by determining the acid value of the reaction mixture. The resulting ester is preferably purified using known methods. For example, residual free carboxylic acids in the reaction mixture can be removed with an alkaline aqueous solution, or the reaction mixture can be distilled, deodorized with steam, or treated with activated carbon to reduce odor and improve stability.

[0056] <Cosmetic bases and cosmetics>

[0057] This invention provides a cosmetic base composed of the esters of this invention. Here, "cosmetic base" refers to a basic ingredient constituting a cosmetic. Furthermore, this invention also provides a cosmetic containing the cosmetic base of this invention.

[0058] The content of the cosmetic base of the present invention in the cosmetic of the present invention is preferably 0.001 to 90% by mass, more preferably 0.1 to 50% by mass, further preferably 0.1 to 20% by mass, and particularly preferably 0.1 to 10% by mass, relative to the total cosmetic.

[0059] The cosmetics of the present invention may contain other ingredients different from the cosmetic base of the present invention described above. These other ingredients include, for example, powder components, liquid oils, solid oils, waxes, hydrocarbons, higher fatty acids, higher alcohols, esters different from the esters in the cosmetic base of the present invention, silicones, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, water-soluble polymers, thickeners, film-forming agents, ultraviolet absorbers, metal ion chelating agents, lower alcohols, polyols, sugars, amino acids, organic amines, polymeric emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant auxiliaries, fragrances, water, etc., but are not limited thereto. Only one of these other ingredients may be used, or two or more may be used in combination.

[0060] The cosmetic product of the present invention is not particularly limited in shape, and may be any shape such as solution, lotion, powder, water-oil bilayer, water-oil-powder trilayer, gel, cream, mist, aerosol, mousse, rollerball, or stick. The cosmetic product of the present invention can be used in the form of impregnation or coating on sheets such as non-woven fabrics.

[0061] Furthermore, the product form of the cosmetics of the present invention is not particularly limited. For example, examples include facial cosmetics such as toners, lotions, creams, gels, masks, and water balms; makeup cosmetics such as makeup primers, foundations, lipsticks, and eyeshadows; sunscreen cosmetics (sunscreen agents); body cosmetics such as deodorants, deodorizing sprays, and deodorizing wipes; fragrance cosmetics; skin cleansing products or facial cleansing products such as makeup removers, shower gels, and facial cleansers; hair cosmetics such as hair liquids, hair tonics, hair waxes, hair conditioners, hair treatments, shampoos, rinses, and hair growth products; or ointments, etc.

[0062]

Example

[0063] The present invention will be described in more detail below through embodiments, but the present invention is not limited thereto.

[0064] <Ester Synthesis>

[0065] (Example 1)

[0066] 200 g (2.63 mol) of 1,3-propanediol, 34.9 g (0.24 mol) of adipic acid, and 134.1 g (0.56 mol) of malic acid were added to a four-necked flask. Under a nitrogen atmosphere, the generated water was removed by distillation at 130 °C and atmospheric pressure, while the acid value was measured every hour. The reaction was continued until the acid value decreased by less than 0.5 every hour. Subsequently, under the same temperature and reduced pressure of 1–5 kPa, the acid value was measured every hour, and the reaction was continued until the acid value decreased by less than 0.5 every hour, yielding crude ester. Then, 350 g of ethyl acetate was added, and excess 1,3-propanediol was removed by washing with water. Then, acidic clay and silica-alumina adsorbents were added at 1.0% by mass of the ester for adsorption treatment. The adsorption treatment temperature, pressure, and time were 100 °C, 1–5 kPa, and 2 hours. Finally, the mixture was filtered using a 1-micron filter to obtain ester 1.

[0067] (Example 2)

[0068] 230 g (3.02 mol) of 1,3-propanediol, 59.5 g (0.50 mol) of succinic acid and 64.5 g (0.34 mol) of citric acid were added to a four-necked flask, and the subsequent steps were performed in the same manner as in Example 1 to obtain ester 2.

[0069] (Comparative Example 1)

[0070] 220 g (2.89 mol) of 1,3-propanediol and 129.2 g (0.96 mol) of malic acid were added to a four-necked flask, and the subsequent steps were performed in the same manner as in Example 1 to obtain ester 3.

[0071] (Comparative Example 2)

[0072] 200 g (2.63 mol) of 1,3-propanediol and 129.1 g (0.88 mol) of adipic acid were placed in a four-necked flask, and the subsequent steps were performed in the same manner as in Example 1 to obtain ester 4.

[0073] <Ester Analysis>

[0074] The obtained esters were analyzed using the following methods. The results are shown in Table 1.

[0075] (composition)

[0076] The obtained ester was subjected to 1 H NMR measurements were performed, and A was calculated. mol% B mol% and C mol% .

[0077] (Hydroxy value)

[0078] The hydroxyl value of the obtained ester was determined according to JIS K0070 standard.

[0079] (Kinematic viscosity)

[0080] The kinematic viscosity of the obtained ester was determined according to JIS K2283 standard.

[0081] (Solubility in water)

[0082] Prepare a 50% (w / w) aqueous solution of the ester and visually inspect its appearance. A grade of ○ is given if the appearance is uniform, and a grade of × is given if the appearance is not uniform.

[0083] (Solubility in olive oil)

[0084] A 1% (w / w) solution of the prepared ester in olive oil was prepared, and its appearance was visually assessed. A grade of ○ was given if the appearance was uniform, and a grade of × was given if the appearance was not uniform.

[0085] (Sticky feeling)

[0086] Twenty women (aged 22-40) served as reviewers. After applying approximately 1g of the obtained ester to the skin, the stickiness was evaluated according to the following rating and criteria. Esters rated "○" or "◎" were determined to be non-sticky cosmetic bases.

[0087] (score)

[0088] 2 points: No stickiness after application to the skin

[0089] 1 point: Slightly sticky after application to the skin.

[0090] 0 points: Feels sticky after application to the skin.

[0091] (Benchmark)

[0092] ◎: The total score is 30 points or more.

[0093] ○: The total score is between 20 and 29 points.

[0094] ×: The total score is below 19 points.

[0095] Table 1

[0096]

[0097] As shown in Table 1, the ester of the present invention has good solubility in water and oil, and is non-sticky, resulting in an excellent user experience.

[0098] <Examples of Cosmetic Formulations>

[0099] The following describes formulation examples of cosmetics using the esters (i.e., ester 1 or ester 2) of the present invention as cosmetic bases. Furthermore, the numerical values ​​of the following components (e.g., "10" in "glycerin: 10") indicate the amount (mass %) of that component.

[0100] [Formulation Example 1] Oil-in-water emulsion

[0101] Water: Balance

[0102] Glycerin: 10

[0103] BG: 5

[0104] DPG: 5

[0105] Polydimethylsiloxane: 3

[0106] Diglycerides: 1

[0107] PEG-240 / HDI copolymer bis-decyltetradecyl alcohol polyether-20 ether: 1

[0108] Sodium chloride: 0.5

[0109] Gellan gum: 0.2

[0110] Polyquaternium-51: 0.01

[0111] Aspartic acid: 0.1

[0112] Tea extract: 0.01

[0113] Ester 1 or 2: 0.5

[0114] Acetylated sodium hyaluronate: 0.01

[0115] Trimethylsilyloxysilicate: 0.1

[0116] Water-soluble collagen: 0.01

[0117] Sodium citrate: 0.1

[0118] Sodium metaphosphate: 0.1

[0119] (Acrylic (ester) / alkyl (C10-30) ester) crosspolymer: 0.05

[0120] Ethanol: 0.5

[0121] Potassium hydroxide: 0.03

[0122] Citric acid: 0.1

[0123] Sodium metabisulfite: 0.1

[0124] BHT: 0.01

[0125] Phenoxyethanol: 0.6

[0126] Chlorphenesin: 0.2

[0127] Spices: 0.05

[0128] [Formula Example 2] Oil-in-water cream

[0129] Water: Balance

[0130] Glycerin: 10

[0131] BG: 6

[0132] Retinol: 1

[0133] Isododecane: 5

[0134] Isohexadecane: 5

[0135] Polydimethylsiloxane: 5

[0136] Cetyl ethylhexanoate: 5

[0137] Hydrogenated polydecene: 4

[0138] Distearate dimethylammonium lithium montmorillonite: 2

[0139] PEG-9 Polydimethylsiloxane (PEG-9) 1.5

[0140] PEG-150: 0.5

[0141] Ester 1 or Ester 2: 0.5

[0142] Phytosterol macadamia oleate: 1

[0143] Stearyl glycyrrhetinic acid ester: 0.1

[0144] Tocopherol acetate: 0.1

[0145] Hydroxyproline: 0.05

[0146] Acetylated sodium hyaluronate: 0.01

[0147] Yeast lysate extract: 0.1

[0148] Raspberry extract: 0.01

[0149] PEG-8 diisostearate: 0.5

[0150] Sodium citrate: 0.1

[0151] EDTA-3Na: 0.1

[0152] Citric acid: 0.05

[0153] Sodium metaphosphate: 0.02

[0154] Syzygium leaf extract: 0.01

[0155] Tocopherol: 0.01

[0156] Phenoxyethanol: 0.6

[0157] Methylparaben: 0.15

[0158] Ethylparaben: 0.15

[0159] Spices: 0.15

[0160] Iron oxide: 0.001

[0161] [Formulation Example 3] Water-in-oil cream

[0162] Water: Balance

[0163] Glycerin: 10

[0164] BG: 6

[0165] Isododecane: 5

[0166] Isohexadecane: 5

[0167] Polydimethylsiloxane: 5

[0168] Cetyl ethylhexanoate: 5

[0169] Hydrogenated polydecene: 4

[0170] Distearate dimethylammonium lithium montmorillonite: 0.5

[0171] PEG-9 Polydimethylsiloxane (PEG-9): 0.5

[0172] PEG-150: 0.5

[0173] Ester 1 or Ester 2: 0.5

[0174] Phytosterol macadamia oleate: 1

[0175] Stearyl glycyrrhetinic acid ester: 0.1

[0176] Tocopherol acetate: 0.1

[0177] Hydroxyproline: 0.05

[0178] Acetylated sodium hyaluronate: 0.01

[0179] Yeast lysate extract: 0.1

[0180] Raspberry extract: 0.01

[0181] PEG-8 diisostearate: 0.2

[0182] Sodium citrate: 0.1

[0183] EDTA-3Na: 0.1

[0184] Citric acid: 0.05

[0185] Sodium metaphosphate: 0.02

[0186] Syzygium leaf extract: 0.01

[0187] Tocopherol: 0.01

[0188] Phenoxyethanol: 0.6

[0189] Methylparaben: 0.15

[0190] Ethylparaben: 0.15

[0191] Spices: 0.15

[0192] Iron oxide: 0.001

[0193] [Formulation Example 4] Oil-in-water gel containing oil-containing microcapsules

[0194] Water: Balance

[0195] Glycerin: 10

[0196] DPG: 10

[0197] Ethanol: 3

[0198] Diglycerides: 1

[0199] PEG-20: 1.5

[0200] Pentaerythritol tetra(ethylhexanoate): 2

[0201] Polydimethylsiloxane: 2

[0202] (Sodium acrylate / sodium acryloyldimethyl taurate) copolymer: 1

[0203] Ester 1 or Ester 2: 1

[0204] Candelilla wax: 0.6

[0205] Yeast lysate extract: 0.01

[0206] Aspartic acid: 0.01

[0207] Squalane: 0.5

[0208] Lysine in HCl: 0.01

[0209] Phytosterol macadamia oleate: 0.1

[0210] Sesame oil: 0.1

[0211] Jojoba seed oil: 0.1

[0212] Acetylated sodium hyaluronate: 0.01

[0213] Betaine: 0.01

[0214] Wild soybean seed extract: 0.01

[0215] Water-soluble collagen: 0.01

[0216] Isohexadecane: 1

[0217] PEG-400: 0.5

[0218] Polysorbate 80: 0.2

[0219] Sorbitan oleate: 0.05

[0220] Talc: 0.5

[0221] EDTA-2Na: 0.1

[0222] (Acrylic (ester) / alkyl (C10-30) alcohol acrylate) crosspolymer: 0.01

[0223] Dextrin palmitate: 0.002

[0224] Calcium stearate: 0.01

[0225] Potassium hydroxide: 0.001

[0226] PEG-9 Polydimethylsiloxane (PEG-9) 0.01

[0227] Tetrahydrotetramethylcyclotetrasiloxane: 0.01

[0228] Citric acid: 0.001

[0229] Sodium phosphate: 0.001

[0230] Tetradecene: 0.001

[0231] BG: 1

[0232] Tocopherol: 0.01

[0233] Phenoxyethanol: 0.35

[0234] Spices: 0.05

[0235] Iron oxide: 0.01

[0236] [Formula Example 5] Toner

[0237] Water: Balance

[0238] Ethanol: 5

[0239] Glycerin: 5

[0240] DPG: 5

[0241] Ester 1 or Ester 2: 5

[0242] Diglycerides: 1

[0243] PEG / PPG-17 / 4 dimethyl ether: 2

[0244] Crystalline cellulose (*1): 2

[0245] Betaine: 4

[0246] Aspartic acid: 0.1

[0247] Lysine in HCl: 0.01

[0248] Acetylated sodium hyaluronate: 0.1

[0249] Wild soybean seed extract: 0.01

[0250] Water-soluble collagen: 0.1

[0251] PPG-13 Decyltetradecyl alcohol polyether-24:1

[0252] Carbomer: 0.05

[0253] Potassium hydroxide: 0.05

[0254] EDTA-2Na: 0.02

[0255] BG: 1

[0256] Tocopherol: 0.01

[0257] Phenoxyethanol: 0.6

[0258] (*1 rheocrysta C-2SP (manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd.))

[0259] [Formula Example 6] Liposome-containing toner

[0260] Water: Balance

[0261] DPG: 5

[0262] Glycerin: 5

[0263] Diglycerides: 3

[0264] Propylene glycol: 4

[0265] Ester 1 or Ester 2: 2

[0266] BG: 2

[0267] Diphenylsiloxyphenyl polytrimethylsiloxane: 1

[0268] PEG-60 hydrogenated castor oil: 1

[0269] PCA-Na: 0.5

[0270] Erythritol: 0.5

[0271] Dipotassium glycyrrhizate: 0.1

[0272] Sodium polyacrylate: 0.02

[0273] Hydrogenated lecithin: 0.01

[0274] Magnesium chloride: 0.01

[0275] Angelica sinensis root extract: 0.01

[0276] Olive leaf extract: 0.01

[0277] Calcium chloride: 0.01

[0278] Serine: 0.01

[0279] Acetylated sodium hyaluronate: 0.01

[0280] Oryzanol: 0.001

[0281] North American witch hazel leaf extract: 0.01

[0282] Papaya extract: 0.01

[0283] Ginger extract: 0.01

[0284] Prickly pear fruit extract: 0.01

[0285] Polyquaternium-51: 0.01

[0286] Altai Bupleurum root extract: 0.01

[0287] Isostearyl alcohol: 1

[0288] Polyglycerol distearate-2: 0.5

[0289] PEG-20: 1

[0290] Sodium citrate: 0.1

[0291] Ethanol: 1

[0292] EDTA-2Na: 0.05

[0293] Citric acid: 0.05

[0294] Phenoxyethanol: 0.3

[0295] Spices: 0.1

[0296] [Formula Example 7] Oil-in-water cream

[0297] Water: Balance

[0298] Ethanol: 3

[0299] Glycerin: 3

[0300] DPG: 5

[0301] Cyclohexylsiloxane: 5

[0302] Cetyl ethylhexanoate: 5

[0303] Hydrogenated polydecene: 2

[0304] Phytosterols / Ocyldodecyl lauroyl glutamate: 2

[0305] Polydimethylsiloxane: 2

[0306] PPG-3 neopentanoate: 2

[0307] Myristyl myristate: 1

[0308] Methyl methacrylate crosspolymer: 1

[0309] Polydimethylsiloxane / vinyl polydimethylsiloxane crosslinked polymer: 0.6

[0310] Erythritol: 0.5

[0311] Ester 1 or Ester 2: 0.5

[0312] PEG / PPG-17 / 4 dimethyl ether: 0.5

[0313] Tocopherol acetate: 0.2

[0314] Caffeine: 0.1

[0315] Sapindus mukorossi fruit peel extract: 0.01

[0316] Sea angelica leaf / stem extract: 0.01

[0317] Tea extract: 0.01

[0318] Orange seed extract: 0.01

[0319] Jujube fruit extract: 0.01

[0320] Extracts of *Euphorbia dentata*, *Euphorbia sparsera*, kelp, *Ulva tubiflora*, and *Wakame*: 0.01

[0321] Turmeric rhizome extract: 0.01

[0322] Kelp / Wakame extract: 0.01

[0323] Chlorella extract: 0.01

[0324] Hydrogenated palm oil: 1

[0325] Betaine alcohol: 0.5

[0326] Polysorbate 60: 0.5

[0327] PEG-30 phytosterols: 0.5

[0328] Acryloyldimethyl taurate ammonium / VP copolymer: 0.6

[0329] Squalene: 0.3

[0330] BG: 1

[0331] Carbomer: 0.04

[0332] Acrylic (ester) crosspolymer / C10-30 alkyl acrylate crosspolymer: 0.05

[0333] Potassium hydroxide: 0.03

[0334] EDTA-2Na: 0.01

[0335] Sodium metaphosphate: 0.02

[0336] Tocopherol: 0.01

[0337] Sodium metabisulfite: 0.1

[0338] HDI / Trimethylolhexyl lactone crosspolymer: 0.01

[0339] Silicon dioxide: 0.1

[0340] Phenoxyethanol: 0.3

[0341] Spices: 0.05

[0342] Iron oxide: 0.01

[0343] [Formulation Example 8] Oil-in-water emulsion

[0344] Water: Balance

[0345] Dipotassium glycyrrhizate: 0.1

[0346] DL-α-Tocopherol Acetate: 0.1

[0347] Seaweed extract: 0.01

[0348] Magnesium chloride: 0.01

[0349] Calcium chloride: 0.01

[0350] Lemon extract: 0.05

[0351] Glycerin: 5

[0352] Dipropylene glycol: 5

[0353] Ethanol: 4

[0354] 1,3-Butanediol: 3

[0355] Methyl polysiloxane: 3

[0356] Betaine alcohol: 1.5

[0357] α-Olefin oligomers: 1

[0358] Diisostearyl malate: 2

[0359] Pentaerythritol tetra(2-ethylhexanoic acid) ester: 1

[0360] Ester 1 or Ester 2: 1

[0361] Stearyl alcohol: 0.5

[0362] Sodium N-stearoyl-N-methyltaurate: 0.3

[0363] Disodium ethylenediaminetetraacetate: 0.02

[0364] Xanthan gum: 0.1

[0365] Sodium citrate: 0.1

[0366] Distearate dimethyl ammonium chloride: 0.05

[0367] Citric acid: 0.02

[0368] L-Arginine Hydrochloride: 0.01

[0369] Isopropanol: 0.01

[0370] Angelica sinensis extract: 0.01

[0371] dl-α-tocopherol 2-L-ascorbic acid phosphate diester potassium salt: 0.01

[0372] Acetylated sodium hyaluronate: 0.01

[0373] Hairy-leaved tea extract: 0.01

[0374] Perilla extract: 0.01

[0375] Job's tears extract: 0.01

[0376] Phenoxyethanol: 0.5

[0377] [Formula Example 9] Water-in-oil cream

[0378] Water: Balance

[0379] Cetyl ethylhexanoate: 7

[0380] Glycerin: 5

[0381] Ethanol: 1

[0382] Nylon-12:5

[0383] Cetearyl alcohol: 5

[0384] DPG: 5

[0385] Triglycerides (caprylic / capric acid): 5

[0386] Phytosterol macadamia oleate: 3

[0387] Glyceryl stearate: 1.5

[0388] Polydimethylsiloxane: 1

[0389] Diisostearyl malate: 1

[0390] Erythritol: 1

[0391] Ester 1 or Ester 2: 1

[0392] PEG / PPG-17 / 4 dimethyl ether: 1

[0393] Tocopherol acetate: 0.2

[0394] Caffeine: 0.1

[0395] Xanthan gum: 0.02

[0396] Sapindus mukorossi fruit peel extract: 0.01

[0397] Sea angelica leaf / stem extract: 0.01

[0398] Tea extract: 0.01

[0399] Orange seed extract: 0.01

[0400] Jujube fruit extract: 0.01

[0401] Extracts of *Euphorbia dentata*, *Euphorbia sparsera*, kelp, *Ulva tubiflora*, and *Wakame*: 0.01

[0402] Turmeric rhizome extract: 0.01

[0403] Kelp / Wakame extract: 0.01

[0404] Chlorella extract: 0.01

[0405] Behenyl alcohol polyether-20: 0.5

[0406] HDI / trimethylolhexyl lactone crosspolymer: 0.1

[0407] Carbomer: 0.07

[0408] BG: 1

[0409] Sodium citrate: 0.07

[0410] EDTA-3Na: 0.05

[0411] Potassium hydroxide: 0.06

[0412] Citric acid: 0.05

[0413] Sodium metabisulfite: 0.01

[0414] Sodium metaphosphate: 0.02

[0415] PPG-3 neopentanoate: 0.1

[0416] Tocopherol: 0.1

[0417] Silicon dioxide: 0.1

[0418] Phenoxyethanol: 0.7

[0419] Spices: 0.1

[0420] Iron oxide: 0.01

[0421] [Formulation Example 10] Oil-in-water emulsion

[0422] Water: Balance

[0423] Dipotassium glycyrrhizate: 0.1

[0424] Glucosyl hesperidin: 0.01

[0425] Hawthorn extract: 0.01

[0426] Turmeric extract: 0.01

[0427] Soapberry pericarp extract: 0.001

[0428] Inositol: 0.01

[0429] Iris root extract: 0.01

[0430] Ginkgo extract: 0.01

[0431] Watercress extract: 0.01

[0432] Water-soluble collagen (F): 0.01

[0433] Glycerin: 6

[0434] 1,3-Butanediol: 6

[0435] α-Olefin oligomers: 4

[0436] Ethanol: 3

[0437] 2-Cetyl ethylhexanoate: 3

[0438] Methyl polysiloxane: 3

[0439] Dipropylene glycol: 2

[0440] Polyoxyethylene glycerol isostearate: 1.5

[0441] Polyethylene glycol 1000:1

[0442] Polyoxyethylene glycerol monostearate: 1

[0443] Betaine alcohol: 0.5

[0444] Vaseline: 0.5

[0445] Polyethylene glycol 20000: 0.5

[0446] Stearic acid: 0.4

[0447] Isostearic acid: 0.3

[0448] Behenic acid: 0.3

[0449] Squalene: 0.2

[0450] Carboxyethylene polymer: 0.2

[0451] Potassium hydroxide: 0.2

[0452] Ester 1 or Ester 2: 0.5

[0453] Succinyl polysaccharide: 0.04

[0454] Disodium ethylenediaminetetraacetate: 0.03

[0455] Phytosterols / Ocyldodecyl lauroyl glutamate: 0.1

[0456] Sodium metabisulfite: 0.01

[0457] Phenoxyethanol: 0.6

[0458] Spices: 0.05

[0459] [Formulation Example 11] Water-in-oil type toner

[0460] Water: Balance

[0461] Ethanol: 4

[0462] DPG: 4

[0463] BG: 3.5

[0464] Glycerin: 3

[0465] Diglycerides: 1.5

[0466] Ester 1 or Ester 2: 1

[0467] Lactobacillus / rice ferment: 1

[0468] PEG-60 hydrogenated castor oil: 0.3

[0469] Diphenylsiloxyphenyl polytrimethylsiloxane: 0.3

[0470] Erythritol: 0.1

[0471] Dipotassium glycyrrhizate: 0.1

[0472] Xanthan gum: 0.05

[0473] Sodium polyacrylate: 0.005

[0474] Orange fruit extract: 0.01

[0475] Acetylated sodium hyaluronate: 0.01

[0476] North American witch hazel leaf extract: 0.01

[0477] Carbomer: 0.15

[0478] Polyglycerol-2 diisostearate: 0.12

[0479] Potassium hydroxide: 0.12

[0480] EDTA-2Na: 0.12

[0481] Isostearyl alcohol: 0.1

[0482] Isostearic acid: 0.1

[0483] Sodium citrate: 0.1

[0484] Citric acid: 0.02

[0485] Sodium metabisulfite: 0.01

[0486] Phenoxyethanol: 0.6

[0487] Spices: 0.01

[0488] [Formula Example 12] Toner

[0489] Water: Balance

[0490] Watercress extract: 0.01

[0491] Inositol: 0.01

[0492] Water-soluble collagen (F): 0.01

[0493] Lysine hydrochloride: 0.01

[0494] Dipropylene glycol: 5

[0495] Glycerin: 5

[0496] Ethanol: 3

[0497] Maltitol: 1.5

[0498] 1,3-Butanediol: 1

[0499] Ester 1 or Ester 2: 3

[0500] Polyoxyethylene polyoxypropylene decyl tetradecyl ether: 0.2

[0501] Carboxylated ethylene polymer: 0.1

[0502] Erythritol: 1

[0503] Disodium ethylenediaminetetraacetate: 0.02

[0504] L-Ascorbic acid phosphate magnesium: 0.1

[0505] Sodium polyacrylate: 0.01

[0506] Sodium metabisulfite: 0.01

[0507] Rosemary leaf oil: 0.01

[0508] Yeast extract (3): 0.01

[0509] L-Arginine Hydrochloride: 0.01

[0510] Phenoxyethanol: 0.5

[0511] Spices: 0.02

[0512] [Formulation Example 13] Water-in-oil cream

[0513] Water: Balance

[0514] Hydrogenated polydecene: 12

[0515] Glycerin: 6

[0516] Mineral oil: 7

[0517] Vaseline: 6

[0518] BG: 5

[0519] Paraffin: 4

[0520] Polyglycerol-2 diisostearate: 2

[0521] Squalane: 3

[0522] Glyceryl oleate: 2

[0523] PCA-Na: 1.5

[0524] DPG: 1

[0525] Beeswax: 2

[0526] Carnosine: 1.2

[0527] Polyethylene: 0.5

[0528] Tocopherol acetate: 0.2

[0529] Phytosterols / Ocyldodecyl lauroyl glutamate: 0.1

[0530] Caffeine: 0.1

[0531] Ester 1 or Ester 2: 0.5

[0532] Sapindus mukorossi fruit peel extract: 0.1

[0533] Catechu and Uncaria extract: 0.1

[0534] Sea angelica leaf / stem extract: 0.1

[0535] Sanguisorba officinalis root extract: 0.1

[0536] Hawthorn flower extract (with sharp spines): 0.1

[0537] Tea extract: 0.1

[0538] Acetylated sodium hyaluronate: 0.01

[0539] Hydroxyproline: 0.1

[0540] Orange seed extract: 0.1

[0541] Jujube fruit extract: 0.1

[0542] Chlorella extract: 0.1

[0543] Extracts of *Euphorbia dentata*, *Sparse Centipedea*, kelp, *Ulva tubiflora*, and *Wakame*: 0.1

[0544] Sodium lactate: 0.1

[0545] Turmeric rhizome extract: 0.1

[0546] Kelp / Wakame extract: 0.1

[0547] Microcrystalline wax: 1

[0548] Sodium hydroxide: 0.5

[0549] Ethanol: 1

[0550] EDTA-3Na: 0.1

[0551] Tocopherol: 0.1

[0552] Sodium metabisulfite: 0.1

[0553] PPG-3 neopentanoate: 0.1

[0554] Cinnamon bark extract: 0.1

[0555] Carbomer: 0.01

[0556] BHT: 0.01

[0557] Polysorbate 20:0.1

[0558] Palmitoyl tripeptide-1: 0.1

[0559] Palmitoyl tetrapeptide-7: 0.1

[0560] Methylparaben: 0.01

[0561] Ethylparaben: 0.01

[0562] Spices: 0.01

[0563] Iron oxide: 0.01

[0564] [Formulation Example 14] Creamy Facial Cleanser

[0565] Ethanol: 5

[0566] Glycerin: 5

[0567] 1,3-Butanediol: 5

[0568] PEG-8:10

[0569] Stearic acid: 15

[0570] Lauric acid: 5

[0571] Myristic acid: 10

[0572] Glyceryl stearate (SE): 5

[0573] Ester 1 or Ester 2: 0.5

[0574] Sodium methylcocoyl taurate: 1

[0575] Polyquaternium-7:15

[0576] Potassium hydroxide: appropriate amount

[0577] EDTA-2Na: Appropriate amount

[0578] Spices: as needed

[0579] Water: Balance

[0580] [Formulation Example 15] Pump-type facial cleanser

[0581] Glycerin: 10

[0582] Dipropylene glycol: 10

[0583] Sorbitol: 10

[0584] Lauric acid: 5

[0585] Myristic acid: 1

[0586] Cocoate arginine salt: 2

[0587] Sodium methyl taurate: 3

[0588] Lauryl betaine: 5

[0589] Polyquaternium-7: 0.5

[0590] Ester 1 or Ester 2: 0.5

[0591] Antioxidants: appropriate amount

[0592] Chelating agent: appropriate amount

[0593] Spices: as needed

[0594] Water: Balance

[0595] [Formulation Example 16] Liquid Facial Cleanser

[0596] Glycerin: 25

[0597] Dipropylene glycol: 10

[0598] Lauric acid: 5

[0599] Myristic acid: 1

[0600] Palmitic acid: 1

[0601] Cocoate arginine salt: 10

[0602] Sodium methyl taurate: 10

[0603] Lauryl betaine: 5

[0604] Xanthan gum: 0.5

[0605] Ester 1 or Ester 2: 0.5

[0606] Antioxidants: appropriate amount

[0607] Chelating agent: appropriate amount

[0608] Spices: as needed

[0609] Water: Balance

[0610] [Formulation Example 17] Paste-based cleaning product

[0611] Glycerin: 40

[0612] PEG-400: 0.5

[0613] Ethylene glycol distearate: 1.5

[0614] Sodium lauryl glycol carboxylate: 1

[0615] Sodium cocoyl glycinate: 20

[0616] Cocoyl arginine salt: 5

[0617] Cocamidopropyl betaine: 5

[0618] Ester 1 or Ester 2: 0.5

[0619] Potassium hydroxide: appropriate amount

[0620] Polyethylene: 1

[0621] Colorant: Appropriate amount

[0622] EDTA-2Na: Appropriate amount

[0623] Water: Balance

[0624] Spices: as needed

[0625] [Formulation Example 18] Facial Cleanser

[0626] PEG-10 polydimethylsiloxane: 0.5

[0627] Glycerin: 10

[0628] PEG-8 dioleate: 5

[0629] PEG-2 laurate: 1

[0630] Sodium lauryl glycol carboxylate: 5

[0631] Sodium lauryl ether sulfate: 10

[0632] Sodium methylcocoyl taurate: 1

[0633] Cocamidopropyl betaine: 10

[0634] Ester 1 or Ester 2: 0.5

[0635] pH adjuster: appropriate amount

[0636] Stabilizer: Appropriate amount

[0637] Preservative: appropriate amount

[0638] Spices: as needed

[0639] Water: Balance

[0640] [Formulation Example 19] Pump-type skin cleansing product

[0641] Glycerin: 10

[0642] 1,3-Butanediol: 10

[0643] PPG-9 diglyceride: 5

[0644] Ester 1 or Ester 2: 0.5

[0645] Triglyceride (ethylhexanoate): 1

[0646] PEG-60 hydrogenated castor oil: 1

[0647] PEG-60 glyceryl isostearate: 1

[0648] Potassium cocoyl glutamate: 10

[0649] Sodium cocoamphoacetate: 5

[0650] pH adjuster: appropriate amount

[0651] Preservative: appropriate amount

[0652] Water: Balance

[0653] [Formulation Example 20] Makeup Remover

[0654] Ethanol: 5

[0655] Cyclopentadimethylsiloxane: 5

[0656] 1,3-Butanediol: 10

[0657] 2-Ethylhexanoic acid glyceride: 5

[0658] POE(8) Glyceryl monoisostearate: 25

[0659] POE(20) glyceryl monoisostearate: 5

[0660] Ester 1 or Ester 2: 0.5

[0661] Dipotassium glycyrrhizate: 0.05

[0662] Citric acid: appropriate amount

[0663] Sodium citrate: appropriate amount

[0664] Phenoxyethanol: Appropriate amount

[0665] Purified water: Balance

[0666] [Formulation Example 21] Makeup Remover

[0667] Purified water: 5

[0668] Glycerin: 10

[0669] Sorbitol: 10

[0670] Sucrose stearate: 2

[0671] Sodium methylcocoyl taurate: 1

[0672] PEG-60 hydrogenated castor oil: 1

[0673] PEG / PPG-35 / 40 dimethyl ether: 2

[0674] Ester 1 or Ester 2: 0.5

[0675] Mineral oil: Balance

[0676] Cetyl ethylhexanoate: 10

[0677] Polydimethylsiloxane: 5

[0678] Diphenylsiloxyphenyl polytrimethylsiloxane: 5

[0679] Sodium alginate: appropriate amount

[0680] Sodium citrate: appropriate amount

[0681] Citric acid: appropriate amount

[0682] EDTA-2Na: Appropriate amount

[0683] [Formulation Example 22] Makeup Remover

[0684] Purified water: Balance

[0685] PEG-400: 5

[0686] Butylene glycol: 10

[0687] Mineral oil: 20

[0688] Polydimethylsiloxane: 5

[0689] Triglyceride (ethylhexanoate): 5

[0690] Stearyl alcohol: 0.5

[0691] Betaine alcohol: 0.5

[0692] Ester 1 or Ester 2: 0.5

[0693] PEG-60 glyceryl isostearate: 1

[0694] Potassium hydroxide: appropriate amount

[0695] Phenoxyethanol: Appropriate amount

[0696] EDTA-2Na: Appropriate amount

[0697] Acrylic (ester) crosspolymer / C10-30 alkanol acrylate crosspolymer: 0.05

[0698] Carbomer: 0.5

[0699] Spices: as needed

[0700] [Formulation Example 23] Makeup Remover

[0701] Ethanol: 10

[0702] Glycerin: 1

[0703] Dipropylene glycol: 5

[0704] PEG-8:5

[0705] PEG / PPG-35 / 40 dimethyl ether: 1

[0706] Ester 1 or Ester 2: 0.5

[0707] PPG-13 Decyltetradecyl alcohol polyether-24:1

[0708] pH adjuster: appropriate amount

[0709] Spices: as needed

[0710] Chelating agent: appropriate amount

[0711] Water: Balance

[0712] [Formulation Example 24] Two-Layer Makeup Remover

[0713] (oil layer)

[0714] Isododecane: 10

[0715] Polydimethylsiloxane: 25

[0716] Decyltetradecylamine oxide: 1.5

[0717] Glyceryl ethylhexanoate: 1

[0718] (Water layer)

[0719] Ethanol: 10

[0720] 1,3-Butanediol: 10

[0721] Ester 1 or Ester 2: 0.5

[0722] Lauryl betaine

[0723] Sodium chloride: appropriate amount

[0724] Preservative: appropriate amount

[0725] pH adjuster: appropriate amount

[0726] Chelating agent: appropriate amount

[0727] Water: Balance

[0728] [Formulation Example 25] Deodorant

[0729] PEG-11 methyl ether polydimethylsiloxane: 0.5

[0730] Alcohol: 60

[0731] Ethylene glycol: 0.5

[0732] Ester 1 or Ester 2: 0.5

[0733] PPG-20-Decyltetradecyl alcohol polyether-10:0.5

[0734] Aluminum hydroxychloride: 10

[0735] Sodium metaphosphate: 0.01

[0736] Tocopherol: Appropriate amount

[0737] Spices: as needed

[0738] Menthol: appropriate amount

[0739] Benzalkonium chloride: 0.05

[0740] Hydroxypropyl methylcellulose: 0.1

[0741] Polyvinylpyrrolidone: 0.05

[0742] Purified water: Balance

[0743] [Formulation Example 26] Deodorizing Spray

[0744] LPG: 75

[0745] (original solution)

[0746] Ethanol: Balance

[0747] Ester 1 or Ester 2: 0.5

[0748] Zinc oxide: 0.5

[0749] PEG-10 polydimethylsiloxane: 0.05

[0750] Diphenylsiloxyphenyl polytrimethylsiloxane: 5

[0751] Ethylhexyl palmitate: 0.5

[0752] Calcium stearate: appropriate amount

[0753] Silicon dioxide: 1

[0754] Aluminum sulfate / potassium sulfate: 1

[0755] Mixture of 3Ca phosphate and silver: 0.05

[0756] Glycerin: 0.5

[0757] Menthol: appropriate amount

[0758] Menthoxypropylene glycol: appropriate amount

[0759] Cymen-5-ol: 0.01

[0760] Spices: as needed

[0761] [Formulation Example 27] Deodorizing Wipes

[0762] The following solution is used to impregnate the nonwoven fabric.

[0763] (original solution)

[0764] Alcohol: 40

[0765] Ester 1 or Ester 2: 0.5

[0766] PPG-20-Decyltetradecyl alcohol polyether-10:0.05

[0767] Talc: 3

[0768] Zinc phenolsulfonate: 2

[0769] Lactic acid: appropriate amount

[0770] Sodium lactate: appropriate amount

[0771] Menthol: appropriate amount

[0772] Benzalkonium chloride: 0.05

[0773] Purified water: Balance

[0774] Spices: as needed

[0775] [Formula Example 28] Hair Mask

[0776] Water: Balance

[0777] Ethanol: 15

[0778] Glycerin: 5

[0779] PG: 5

[0780] Ester 1 or Ester 2: 0.5

[0781] Polydimethylsiloxane: 12

[0782] Aminopropyl polydimethylsiloxane: 0.6

[0783] Acrylic (ester) / C10-30 alkanol acrylate crosspolymer: 0.1

[0784] PEG-10 polydimethylsiloxane: 0.1

[0785] Carbomer: 0.35

[0786] Xanthan gum: 0.1

[0787] Hydroxyethylurea: 0.2

[0788] AMP: Appropriate amount

[0789] EDTA-2Na: Appropriate amount

[0790] Spices: as needed

[0791] [Formula Example 29] Hair Wax

[0792] Water: Balance

[0793] PG: 5

[0794] Maltitol: 5

[0795] Carbomer: 0.1

[0796] PEG-240 / HDI copolymer bis-decyltetradecyl alcohol polyether-20 ether: 0.5

[0797] Cetyl alcohol polyether-25:3

[0798] Glyceryl stearate (SE): 0.5

[0799] Hydrogenated polyisobutylene: 5

[0800] Microcrystalline wax: 5

[0801] Paraffin wax: 0.5

[0802] Stearic acid: 3

[0803] Cetyl alcohol: 3

[0804] Ester 1 or Ester 2: 0.5

[0805] Candelilla wax: 10

[0806] Brazilian carnauba wax: 1

[0807] Cetyl ethylhexanoate: 3

[0808] Pentaerythritol tetra(ethylhexanoate): 0.5

[0809] Methacryloxyethyl betaine / acrylate copolymer: 2

[0810] (VP / VA) copolymer: 0.5

[0811] TEA: Appropriate amount

[0812] Phenoxyethanol: Appropriate amount

[0813] EDTA-2Na: Appropriate amount

[0814] Tocopherol: Appropriate amount

[0815] Spices: as needed

[0816] [Formulation Example 30] Water-in-oil type sunscreen cosmetic

[0817] Purified water: Balance

[0818] Glycerin: 2.5

[0819] DPG: 5

[0820] Ester 1 or Ester 2: 0.5

[0821] PEG-60 glyceryl isostearate: 0.3

[0822] PEG-10 polydimethylsiloxane: 0.3

[0823] TEA: 0.3

[0824] Betaine alcohol: 1

[0825] Squalene: 1.5

[0826] Behenic acid: 0.6

[0827] Pentaerythritol tetra(2-ethylhexanoic acid) ester: 2

[0828] Polypropylene glycol (17): 1

[0829] Cyclopentadimethylsiloxane: 4

[0830] Polydimethylsiloxane (6 cst): 1

[0831] Ethylhexyl methoxycinnamate: 7.5

[0832] Diethylhexyloxyphenol methoxyphenyl triazine: 2

[0833] Xanthan gum: 0.2

[0834] Phenoxyethanol: 0.35

[0835] Chlorphenesin: 0.2

[0836] Thiotaurine: 0.1

[0837] Aminoethane sulfinic acid: 0.1

[0838] Wild rose fruit extract: 0.1

[0839] Rosa centipede extract: 0.1

[0840] Titanium oxide: 0.05

[0841] Mica: 0.05

[0842] Chelating agent: appropriate amount

[0843] pH adjuster: appropriate amount

[0844] [Formulation Example 31] Water-in-oil type sunscreen cosmetic

[0845] Purified water: Balance

[0846] Glycerin: 4

[0847] BG (Butanediol): 7

[0848] PEG / PPG-9 / 2 dimethyl ether: 5

[0849] Compound 1 or Compound 2: 0.5

[0850] Polyethylene glycol 300:1

[0851] Succinyl polysaccharide: 0.3

[0852] (Dimethacrylamide / sodium acryloyldimethyl taurate) cross-linked polymer: 0.3

[0853] Sucrose fatty acid esters: 3

[0854] PEG-60 hydrogenated castor oil: 2

[0855] Diisopropyl sebacate: 2

[0856] Non-volatile polydimethylsiloxane: 2

[0857] Cyclic dimethylsiloxane: 12

[0858] Triglyceride (ethylhexanoate): 5

[0859] Isostearic acid: 1

[0860] Sorbitan sesquiisostearate: 0.5

[0861] Hydrophobicated micro-particle zinc oxide: 10

[0862] Ethylhexyl methoxycinnamate: 10

[0863] Diethylaminohydroxybenzoyl benzoate: 1

[0864] Diethylhexyloxyphenol methoxyphenyl triazine: 1

[0865] Spherical polyurethane resin powder: 3

[0866] Chlorphenesin: 0.2

[0867] pH adjuster: appropriate amount

[0868] Chelating agent: appropriate amount

[0869] [Formulation Example 32] Water-in-oil type sunscreen cosmetic

[0870] Distilled water: balance

[0871] Diisopropyl sebacate: 8

[0872] Diethylhexyloxyphenol methoxyphenyl triazine: 1

[0873] Isoamyl trimethoxycinnamate trisiloxane: 1

[0874] Hydrophobicated zinc oxide: 5

[0875] Succinyl polysaccharide: 1

[0876] (Dimethacrylamide / sodium acryloyldimethyl taurate) cross-linked polymer: 0.3

[0877] Hydroxypropyl methylcellulose stearyl ether: 0.2

[0878] Chlorphenesin: 0.2

[0879] BG (Butanediol): 4

[0880] Ethanol: 4

[0881] Ester 1 or Ester 2: 0.5

[0882] [Formulation Example 33] Water-in-oil type sunscreen cosmetic

[0883] Distilled water: balance

[0884] Ethanol: 3

[0885] Ester 1 or Ester 2: 0.5

[0886] Cellulose gum: 0.1

[0887] Glycerin: 2

[0888] Isododecane: 5

[0889] Isopropyl myristate: 5

[0890] Diisopropyl sebacate: 10

[0891] PBG / PPG-9 / 1 copolymer: 1

[0892] Polydimethylsiloxane (1.5cs): 10

[0893] Polydimethylsiloxane (6cs): 5

[0894] Trimethylsilyloxysilicate: 1

[0895] Dextrin palmitate: 1

[0896] Ethylhexyl methoxycinnamate: 5

[0897] Diethylaminohydroxybenzoyl benzoate: 1

[0898] Diethylhexyloxyphenol methoxyphenyl triazine: 1

[0899] Ethylhexyl salicylate: 3

[0900] Hydrophobicated microparticle titanium dioxide: 5

[0901] Hydrophobicated micro-particle zinc oxide: 10

[0902] PEG-9 polydimethylsiloxane: 1

[0903] Cetyl PEG / PPG-10 / 1 Polydimethylsiloxane: 1

[0904] Distearate dimethylammonium lithium montmorillonite: 0.2

[0905] Chlorphenesin: 0.1

[0906] Isostearic acid: 0.1

[0907] Chelating agent: appropriate amount

[0908] Thiotaurine: 0.1

[0909] Aminoethane sulfinic acid: 0.1

[0910] Wild rose fruit extract: 0.1

[0911] Rosa centipede extract: 0.1

[0912] Titanium oxide: 0.05

[0913] Mica: 0.05

[0914] [Formulation Example 34] Water-in-oil type sunscreen cosmetic

[0915] Distilled water: balance

[0916] Ethanol: 10

[0917] EDTA-2Na·H2O: Appropriate amount

[0918] Carbomer: 0.2

[0919] Acrylic (ester) / C10-30 alkanol acrylate crosspolymer: 0.1

[0920] Xanthan gum: 0.1

[0921] Agar: 0.1

[0922] Glycerin: 3

[0923] Butylene glycol: 5

[0924] Ester 1 or Ester 2: 1

[0925] Core-crown type microgel emulsifier (acrylate / methoxy PEG-9 methacrylate) crosslinking (Manufacturing Example 9 of WO2013 / 094298): 1.5

[0926] Lauryl dimethylaminoacetic acid betaine 35% (w / w) aqueous solution: 0.1

[0927] Ethylhexyl methoxycinnamate: 7

[0928] Ethylhexyltriazine: 1

[0929] Diethylaminohydroxybenzoyl benzoate: 1

[0930] Diethylhexyloxyphenol methoxyphenyl triazine: 1

[0931] Dimethyl distearate ammonium chloride treatment for silica-treated titanium dioxide: 4

[0932] Polydimethylsiloxane: 5

[0933] Octyl polymethylsiloxane: 2

[0934] Diisopropyl sebacate: 5

[0935] C12-15 Alcohol Benzoate: 3

[0936] Dextrin palmitate / ethylhexanoate: 1

[0937] Alumina treatment of titanium dioxide: 1

[0938] Spices: as needed

[0939] Potassium hydroxide: 0.15

[0940] Phenoxyethanol: 0.5

[0941] Silicon dioxide: 1

[0942] [Formulation Example 35] Water-in-oil type sunscreen cosmetic

[0943] Distilled water: balance

[0944] Ethanol: 8

[0945] EDTA-2Na: Appropriate amount

[0946] Sodium hexametaphosphate: appropriate amount

[0947] Citric acid: appropriate amount

[0948] Sodium citrate: appropriate amount

[0949] Cherry blossom leaf extract: 1

[0950] Vitamin E acetate: 1

[0951] North American witch hazel extract: 1

[0952] Green tea extract: 1

[0953] (Dimethacrylamide / sodium acryloyldimethyl taurate) copolymer: 0.3

[0954] Succinyl polysaccharide: 0.1

[0955] Stearoxyhydroxypropyl methylcellulose: 0.1

[0956] Glycerin: 3

[0957] Butylene glycol: 5

[0958] Ester 1 or Ester 2: 1

[0959] Polyoxyethylene hydrogenated castor oil (60 mol): 1.5

[0960] Ethylhexyl methoxycinnamate: 5

[0961] Ethylhexyltriazine: 2

[0962] Diethylaminohydroxybenzoyl benzoate: 2

[0963] Diethylhexyloxyphenol methoxyphenyl triazine: 1

[0964] Polydimethylsiloxane: 6

[0965] Isododecane: 3

[0966] Dextrin palmitate / ethylhexanoate: 1

[0967] Hydrophobicated silica-coated micro-zinc oxide: 15

[0968] Alumina treatment of titanium dioxide: 1

[0969] Isostearic acid: 0.3

[0970] Sorbitan sesquiisostearate: 0.3

[0971] Spices: as needed

[0972] Silicon dioxide: 1

[0973] [Formulation Example 36] Water-in-oil type sunscreen cosmetic

[0974] Purified water: Balance

[0975] Ethanol: 8

[0976] EDTA·3Na: Appropriate amount

[0977] Salt: as needed

[0978] Sodium metabisulfite: appropriate amount

[0979] Glycerin: 2

[0980] Ester 1 or Ester 2: 0.5

[0981] Isododecane: 3

[0982] Glyceryl tri(2-ethylhexanoate): 5

[0983] Isopropyl myristate: 5

[0984] Diisopropyl sebacate: 5

[0985] Polydimethylsiloxane: 6

[0986] Trisiloxane silicic acid: 1

[0987] Dextrin palmitate: 0.5

[0988] Homosalate: 5

[0989] Diethylaminohydroxybenzoyl benzoate (0.5%)

[0990] Diethylhexyloxyphenol methoxyphenyl triazine: 1

[0991] tert-Butylmethoxydibenzoylmethane: 2

[0992] Ethylhexyl salicylate: 5

[0993] Hydrophobicated microparticle titanium dioxide: 3

[0994] Hydrophobicated micro-particle zinc oxide: 7

[0995] methyl methacrylate crosspolymer: 3

[0996] Silicon dioxide: 2

[0997] Hydrophobic treatment of silica: 5

[0998] PEG-9 polydimethylsiloxane: 1

[0999] Lauryl PEG-9 polydimethylsiloxane: 2

[1000] Distearate dimethylammonium lithium montmorillonite: 0.5

[1001] Isostearic acid: 0.5

[1002] Sorbitan sesquiisostearate: 0.5

[1003] Tocopherol: Appropriate amount

[1004] Spices: as needed

[1005] [Formula Example 37] Lipstick

[1006] Polyethylene: 7

[1007] Microcrystalline wax: 1

[1008] Candelilla wax: 1

[1009] Vaseline: 5

[1010] Macadamia nut oil: 21.92

[1011] Glyceryl triisostearate: 12

[1012] Diisostearyl malate: 10

[1013] Phytosterols / Ocyldodecyl lauroyl glutamate: 10

[1014] Hydrogenated polyisobutylene: 18.5

[1015] Diphenylsiloxyphenyl polytrimethylsiloxane: 5

[1016] Avocado (Butyrospermum Parkii) fruit oil: 0.1

[1017] Ethylhexyl methoxycinnamate: 7.5

[1018] Pentaerythritol tetra(ethylhexanoate): 0.2

[1019] Ester 1 or Ester 2: 0.5

[1020] Colorant: 0.05

[1021] Dibromofluorescein (Sun Chemical): 0.1

[1022] Tetrabromofluorescein (H. Kohnstamm & Co.): 0.1

[1023] Tetrachlorotetrabromofluorescein: 0.1

[1024] Tocopherol acetate: 0.05

[1025] (Polydimethylsiloxane / vinyl polydimethylsiloxane) crosslinked polymer: 0.01

[1026] Royal jelly extract: 0.05

[1027] Mica titanium: 0.03

[1028] Anhydrous silicic acid: 0.01

[1029] Titanium oxide: 0.01

[1030] Tocopherol: 0.05

[1031] Simethicone: 0.02

[1032] [Formula Example 38] Lipstick

[1033] Polyethylene: 7

[1034] Microcrystalline wax: 1

[1035] Candelilla wax: 1

[1036] Vaseline: 5

[1037] Macadamia nut oil: 21.72

[1038] Glyceryl triisostearate: 11

[1039] Diisostearyl malate: 9

[1040] Phytosterols / Ocyldodecyl lauroyl glutamate: 9

[1041] Hydrogenated polyisobutylene: 17.3

[1042] Diphenylsiloxyphenyl polytrimethylsiloxane: 4.5

[1043] Shea butter: 0.1

[1044] Ethylhexylmethoxycinnamic acid: 7.5

[1045] Pentaerythritol tetra(ethylhexanoate): 0.2

[1046] Ester 1 or Ester 2: 0.5

[1047] Colorant: 0.05

[1048] Dibromofluorescein (Sun Chemical): 0.1

[1049] Tetrabromofluorescein (H. Kohnstamm & Co.): 0.1

[1050] Tetrachlorotetrabromofluorescein: 0.1

[1051] Tocopherol acetate: 0.05

[1052] (Polydimethylsiloxane / vinyl polydimethylsiloxane) crosslinked polymer: 0.01

[1053] Royal jelly extract: 0.05

[1054] Mica titanium: 0.03

[1055] Anhydrous silicic acid: 0.01

[1056] Titanium oxide: 0.01

[1057] Tocopherol: 0.05

[1058] Simethicone: 0.02

[1059] [Formula Example 39] Lipstick

[1060] Polyethylene: 7

[1061] Microcrystalline wax: 1

[1062] Candelilla wax: 1

[1063] Vaseline: 5

[1064] Macadamia nut oil: 17.39

[1065] Glyceryl triisostearate: 9.3

[1066] Diisostearyl malate: 7.8

[1067] Phytosterols / Ocyldodecyl lauroyl glutamate: 7.8

[1068] Hydrogenated polyisobutylene: 14.4

[1069] Diphenylsiloxyphenyl polytrimethylsiloxane: 4

[1070] Shea butter: 0.1

[1071] Ethylhexyl methoxycinnamate: 7.5

[1072] Pentaerythritol tetra(ethylhexanoate): 5

[1073] Ester 1 or Ester 2: 0.5

[1074] Colorant: 12

[1075] Dibromofluorescein (Sun Chemical): 0.1

[1076] Tetrabromofluorescein (H. Kohnstamm & Co.): 0.1

[1077] Tetrachlorotetrabromofluorescein: 0.1

[1078] Tocopherol acetate: 0.05

[1079] (Polydimethylsiloxane / vinyl polydimethylsiloxane) crosslinked polymer: 0.01

[1080] Royal jelly extract: 0.05

[1081] Mica titanium: 0.01

[1082] Anhydrous silicic acid: 0.01

[1083] Titanium oxide: 0.01

[1084] Tocopherol: 0.05

[1085] Simethicone: 0.02

[1086] [Formula Example 40] Lipstick

[1087] Polyethylene: 7

[1088] Microcrystalline wax: 1

[1089] Candelilla wax: 1

[1090] Vaseline: 5

[1091] Macadamia nut oil: 16.29

[1092] Glyceryl triisostearate: 8.5

[1093] Diisostearyl malate: 7.1

[1094] Phytosterols / Ocyldodecanol lauroyl glutamate: 7.1

[1095] Hydrogenated polyisobutylene: 13.2

[1096] Diphenylsiloxyphenyl polytrimethylsiloxane: 3.6

[1097] Shea butter: 0.1

[1098] Ethylhexyl methoxycinnamate: 7.5

[1099] Pentaerythritol tetra(ethylhexanoate): 5

[1100] Ester 1 or Ester 2: 0.5

[1101] Colorant: 12

[1102] Dibromofluorescein (Sun Chemical): 0.1

[1103] Tetrabromofluorescein (H. Kohnstamm & Co.): 0.1

[1104] Tetrachlorotetrabromofluorescein: 0.1

[1105] Tocopherol acetate: 0.05

[1106] (Polydimethylsiloxane / vinyl polydimethylsiloxane) crosslinked polymer: 0.01

[1107] Royal jelly extract: 0.05

[1108] Mica titanium: 0.01

[1109] Anhydrous silicic acid: 0.01

[1110] Titanium oxide: 0.01

[1111] Tocopherol: 0.05

[1112] Simethicone: 0.02

[1113] [Formulation Example 41] Makeup Base Product

[1114] Water: Balance

[1115] Ethanol: 5

[1116] Glycerin: 3

[1117] BG: 5

[1118] Ester 1 or Ester 2: 0.5

[1119] Succinyl polysaccharide: 0.3

[1120] Cellulose gum: 0.3

[1121] (Dimethacrylamide / sodium acryloyldimethyl taurate) cross-linked polymer: 0.3

[1122] Polyglycerol-10 stearate: 3

[1123] Sorbitan sesquiisostearate: 1

[1124] Polyglycerol-6 polyricinoleate: 0.5

[1125] (C9-12) Alkane / Coconut Alcohol-Octoate / Caprate: 10

[1126] Isopropyl myristate: 8

[1127] Caprylic / Capric Triglyceride: 8

[1128] Zinc oxide / dextrin palmitate: 15

[1129] Titanium oxide / aluminum hydroxide / stearic acid: 5

[1130] Silicon dioxide: 1

[1131] Phenoxyethanol: Appropriate amount

[1132] Citric acid: appropriate amount

[1133] Sodium citrate: appropriate amount

[1134] EDTA-2Na: Appropriate amount

[1135] [Formulation Example 42] Makeup Base Product

[1136] PEG-10 polydimethylsiloxane: 3.5

[1137] Lauryl PEG-9 polydimethylsiloxane: 2

[1138] PEG-10 hydrogenated castor oil: 2

[1139] Ethylhexyl salicylate: 10

[1140] Isohexadecane: 10

[1141] Hydrogenated didecene: 20

[1142] Distearate dimethylammonium lithium montmorillonite: 2

[1143] Fatty acid-treated titanium dioxide: 4.5

[1144] Silicon dioxide: 5

[1145] Silicone-treated titanium dioxide: 4.5

[1146] Silicone-treated red iron oxide: 0.35

[1147] Silicone-treated yellow iron oxide: 0.75

[1148] Silicone-treated black iron oxide: 0.015

[1149] Water: Balance

[1150] EDTA-3Na: 0.2

[1151] Glycerin: 2.5

[1152] DPG: 7

[1153] BG: 2

[1154] Ester 1 or Ester 2: 0.5

[1155] Ethanol: 1

[1156] Phenoxyethanol: Appropriate amount

[1157] [Formulation Example 43] Mask Spray

[1158] Sugarcane extract: 1

[1159] Hydroxypropyl cyclodextrin: 2

[1160] Citric acid (food): appropriate amount

[1161] Sodium citrate: appropriate amount

[1162] Salt: 0.5g

[1163] Sodium metabisulfite: appropriate amount

[1164] Ethanol: 54

[1165] 1,3-Butanediol: 3

[1166] Ester 1 or Ester 2: 0.5

[1167] Phenoxyethanol: 0.5

[1168] Glycerin: 1

[1169] Sweet orange oil: 0.2

[1170] [Formula Example 44] Foundation

[1171] Cyclopentadimethylsiloxane: 27

[1172] Pentaerythritol tetra(ethylhexanoate): 4

[1173] PEG-10 polydimethylsiloxane: 3

[1174] PEG-9 Polydimethylsiloxane (PEG-9) 1.5

[1175] Dibutylpolydimethylsiloxane polyglycerol-3:1

[1176] Distearate dimethylammonium lithium montmorillonite: 0.5

[1177] Octyl methoxycinnamate: 6.5

[1178] Hydrophobic microparticle titanium dioxide: 11

[1179] Hydrophobic titanium dioxide: 7

[1180] Hydrophobic iron oxide red: 0.4

[1181] Hydrophobic iron oxide yellow: 0.8

[1182] Hydrophobic iron oxide black: 0.01

[1183] Spherical powder: 3

[1184] Water: Balance

[1185] Glycerin: 10

[1186] Ester 1 or Ester 2: 0.5

[1187] p-hydroxybenzoate: appropriate amount

[1188] Phenoxyethanol: Appropriate amount

[1189] [Formula Example 45] Water Balm

[1190] Agar: 0.1

[1191] Tamarind (Tamarindus indica) seed gum: 1.2

[1192] Paraffin: 1

[1193] (Dimethacrylamide / sodium acryloyldimethyl taurate) cross-linked polymer: 0.4

[1194] Polyethylene glycol (40EO) monostearate: 0.5

[1195] Polysorbate 60: 0.5

[1196] Sorbitan tristearate: 0.1

[1197] Stearyl alcohol: 0.1

[1198] Betaine alcohol: 1.5

[1199] Glycerin: 15

[1200] Pearlescent agent: 10

[1201] Citric acid: appropriate amount

[1202] Sodium citrate: appropriate amount

[1203] Preservative: appropriate amount

[1204] Sodium metabisulfite: appropriate amount

[1205] Propylene glycol: 3

[1206] Butanediol: 3

[1207] Ester 1 or Ester 2: 0.5

[1208] Spherical porous silica (average particle size: approximately 5 μm): 1

[1209] Non-porous silica (average particle size: approx. 7 μm): 1.5

[1210] PEG60 hydrogenated castor oil: 0.1

[1211] Ethylhexyl methoxycinnamate: 4

[1212] Sorbitan sesquiisostearate: 1

[1213] Isostearic acid: 1

[1214] Glyceryl stearate: 1

[1215] BHT: 0.05

[1216] Isohexadecane: 2.5

[1217] Water: Balance

[1218] [Formula Example 46] Eyeshadow

[1219] Talc: Balance

[1220] Synthetic Phlogopite: 10

[1221] Zinc oxide: 1

[1222] Barium sulfate: 1

[1223] Magnesium myristate: 1

[1224] Chlorphenesin: Appropriate amount

[1225] (Vinyl polydimethylsiloxane / polymethylsiloxane silsesquioxane) crosslinked polymer: 4

[1226] Boron nitride: 8

[1227] Jojoba ester: 3

[1228] Red 226 / Mica: 1

[1229] Synthetic phlogopite / titanium oxide / tin oxide: 20

[1230] Vaseline / Tocopherol: 2

[1231] Diisostearyl malate: 6

[1232] Triglyceride (ethylhexanoate): 2

[1233] Ester 1 or Ester 2: 0.5

[1234] [Formula Example 47] Water-in-oil type foundation

[1235] Water: Balance

[1236] Ethanol: 5

[1237] Glycerin: 2.5

[1238] 1,3-Butanediol: 7

[1239] Ester 1 or Ester 2: 0.5

[1240] Hydroxypropyl methylcellulose stearyl ether: 0.05

[1241] Succinyl polysaccharide: 0.15

[1242] (Dimethacrylamide / sodium acryloyldimethyl taurate) crosspolymer: 0.25

[1243] PEG-100 hydrogenated castor oil: 0.2

[1244] PEG-60 hydrogenated castor oil: 1.5

[1245] PPG-17:1

[1246] Polydimethylsiloxane: 2

[1247] Triglyceride (ethylhexanoate): 3

[1248] Polydimethylsiloxane: 17

[1249] Isostearic acid: 0.8

[1250] Sorbitan sesquiisostearate: 0.2

[1251] Distearate dimethylammonium chloride: 0.15

[1252] Zinc oxide: 14

[1253] Ethylhexyl methoxycinnamate: 7

[1254] Ethylhexyltriazine: 0.5

[1255] Diethylaminohydroxybenzoyl benzoate (0.5%)

[1256] 2-ethylhexyloxyphenol methoxyphenyl triazine:

[1257] Titanium oxide: 0.5

[1258] Sodium metaphosphate: appropriate amount

[1259] Phenoxyethanol: Appropriate amount

[1260] [Formulation Example 48] Makeup cosmetic (solid oil-in-water emulsion)

[1261] Cyclopentadimethylsiloxane: 16

[1262] Dimethylpolysiloxane (6cps): 10

[1263] Polyoxyalkylene modified organopolysiloxanes: 5

[1264] Paraffin (165°F): 10

[1265] Bis-PEG-18 methyl ether dimethylsilane: 0.5

[1266] Silicone-treated talc: 16

[1267] Silicone-treated spherical silica powder: 5

[1268] Zinc oxide treated with calcium stearate: 3

[1269] Silicone-treated titanium dioxide: 10

[1270] Silicone-treated iron oxide (yellow): 3

[1271] Silicone-treated iron oxide (red): 1

[1272] Silicone-treated iron oxide (black): 0.1

[1273] Ion-exchanged water: Balance

[1274] Glycerin: 5

[1275] Ester 1 or Ester 2: 0.5

[1276] Preservative: appropriate amount

[1277] Spices: as needed

[1278] [Formulation Example 49] Oily Liquid Foundation

[1279] Polydimethylsiloxane: 10

[1280] Cyclopentadimethylsiloxane: Balance

[1281] Isohexadecane: 10

[1282] Polyether-modified silicone: 2

[1283] Isostearic acid: 0.5

[1284] Polyoxyethylene (10) isostearyl ether (HLB12.4): 0.5

[1285] Organically modified bentonite: 0.1

[1286] Polymethyl methacrylate spherical powder: 5

[1287] Hydrophobic treatment of yellow iron oxide: 3

[1288] Hydrophobicated red iron oxide: 1.5

[1289] Hydrophobic treatment of black iron oxide: 0.3

[1290] Hydrophobicated titanium dioxide: 12

[1291] Ester 1 or Ester 2: 0.5

[1292] [Formulation Example 50] Facial cosmetic (water-based composition)

[1293] Water: Balance

[1294] PEG-240 / HDI copolymer bis-decyltetradecyl alcohol polyether-20 ether: 0.9

[1295] (Ammonium acryloyldimethyltaurate / VP) copolymer: 0.3

[1296] Phenoxyethanol: 0.5

[1297] DPG: 8

[1298] BG: 5

[1299] Glycerin: 2

[1300] Ester 1 or Ester 2: 0.5

[1301] Synthetic phlogopite, distearate dimethylammonium chloride: 15

[1302] Iron oxide, triethoxyoctylsilane: 0.4

[1303] Iron oxide, triethoxyoctylsilane: 0.8

[1304] Iron oxide, triethoxyoctylsilane: 0.01

[1305] [Potential for Industrial Applications]

[1306] The esters of this invention have good solubility in water and oil and are non-sticky, making them useful as a base for cosmetics.

[1307] This application is based on Japanese Patent Application No. 2023-121077, the contents of which are contained in this specification.

Claims

1. An ester synthesized from components A, B, and C, Component A is at least one selected from diols having 2 to 8 carbon atoms. Component B is at least one selected from dicarboxylic acids having 2 to 10 carbon atoms. The component C is at least one selected from hydroxycarboxylic acids having 4 to 6 carbon atoms and having two or more carboxyl groups.

2. A cosmetic base, comprising the ester described in claim 1.

3. A cosmetic product comprising the cosmetic base as described in claim 2.

Images