Photoprotective and thermal protective agrochemical compositions

Abstract

The present invention relates to a synergistic combination of a photoprotective agent and a thermal protective agent in an agrochemical composition, to a corresponding agrochemical liquid composition, and to the use of a synergistic combination of a thermal protective agent and a photoprotective agent for stabilizing an agrochemical composition comprising at least one pesticidal agent.

Description

Technical Field

[0001] The following invention relates to a synergistic photoprotective and heat-protective agricultural chemical composition, to a corresponding agricultural chemical liquid composition, and to the use of a synergistic combination of heat protectants and photoprotectants for stabilizing an agricultural chemical composition comprising at least one pest control agent. Summary of the Invention

[0002] This invention relates to a photoprotective and heat-protective agricultural chemical composition comprising:

[0003] a) At least one biocidal agent, in an amount of 0.5% to 50% by weight based on the total composition;

[0004] b) Stabilizers, which consist of a synergistic combination of thermal and photoprotective agents.

[0005] Another aspect of the present invention relates to an agricultural chemical liquid composition comprising:

[0006] a) At least one pest control agent, selected from insecticides, fungicides, herbicides, and mixtures thereof;

[0007] b) Stabilizers, which comprise a synergistic combination of thermal protectants and photoprotectants;

[0008] c) Organic solvents;

[0009] d) Nonionic surfactants;

[0010] e) Anionic surfactants.

[0011] The present invention further relates to the use of a synergistic combination of heat protectants and photoprotectants for stabilizing agricultural chemical compositions comprising at least one insecticide, fungicide, herbicide, or mixture thereof. Background Technology

[0012] It is well known that many pesticides tend to decompose when exposed to direct sunlight or contact with leaves and other plant parts treated with pesticides. This means that the actual amount of pesticide applied will eventually decrease, resulting in lower efficacy of the pesticide and requiring repeated treatments or higher doses to achieve the desired effect.

[0013] A second factor affecting the stability of some pesticides is heat. For some pesticides, prolonged exposure to heat leads to thermal decomposition, resulting in a situation where the actual concentration of the active ingredient is not the effective concentration needed in the field or intended for application. Preventing thermal decomposition is important in two ways: First, when the material has already been applied in the field and a high level of active ingredient needs to be maintained for an extended period to achieve the desired effect. Second, it must be possible to maintain the concentration of the pesticide product during storage for future use.

[0014] Macrolides are a class of compounds characterized by large macrolide rings. They are initially produced by soil bacteria during fermentation and possess antibiotic and pest-killing abilities. Among them, emamectin and spinosad are widely used as crop protectants. However, both are susceptible to light and heat instability.

[0015] Several solutions exist in this field that attempt to overcome photodegradation of pest control agents by adding certain photoprotective molecules that can reduce potential damage caused by sunlight radiation.

[0016] WO 2010 / 106314 describes a biocidal composition comprising biocidal particles of avermectin (A) (abamectin and / or emamectin benzoate) coated with a photoprotectant having a size of 0.1 to 100 μm. Preferred photoprotectants are 2,6-di(tert-butyl)-4-methylphenol (commonly known as BHT); ethylene bis(oxyethylene)bis-(3-(5-tert-butyl-4-hydroxy-m-tolyl)-propionate (e.g., as Irganox). R 245 is available); azo dyes (e.g., available from Sigma-Aldrich as Oil Red O™); synthetic beeswax (e.g., available from Croda as Syncrowax™ BB4); and hydroxyphenylbenzotriazole UV absorbers (e.g., available from BASF as Tinuvin). R 328 is available.

[0017] In this context, applications are limited to high-melting-point biocidal microparticles coated with UV blockers. The methods described in this application are relatively complex and require specially designed machinery. Furthermore, the types of formulations are limited to solid compositions, such as water-dispersible or water-soluble granules.

[0018] WO 2010 / 126578 and WO 2010 / 126583 describe a pest-killing suspension concentrate containing ethyl spinosad and at least one metal oxide such as ZnO, Fe2O3, TiO2, and CuO. This application has demonstrated improved efficacy with formulations containing a high concentration of metal oxides, up to 52.6% by weight of the total composition. However, high concentrations of metal oxides are known to cause phytotoxicity, as mentioned in Plants 2023, 12(4), 778.

[0019] IN 202221036514 describes a synergistic pest-killing solid formulation with improved stability, comprising: spinosad, one or more other insecticides (such as emamectin benzoate, cyantraniliprole, abamectin, and oxadiazon), and a UV photodegradation inhibitor (such as ZnO, TiO2, and kojic acid). The application also describes a method for formulating the composition into granular compositions (WG) effective against a variety of pests (such as Lepidoptera, Thysanoptera, Diptera, and Hemiptera insects) and exhibiting resistance to UV degradation. However, this composition is limited to solid granular WG formulations.

[0020] However, despite previous efforts, there remains a need to develop new stable compositions for photosensitive and heat-sensitive biocides. Detailed Implementation

[0021] definition:

[0022] Before detailing the subject matter of this invention, it may be helpful to provide definitions for certain terms used herein. Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this subject matter pertains. For clarity, the following definitions are provided.

[0023] Unless otherwise specified, the term "a / an" as used herein includes both the singular and the plural. Therefore, the terms "a / an" or "at least one" are used interchangeably in this application.

[0024] As used herein, the verb “comprising” and its variations as used in this specification and claims are used in their non-limiting sense to mean including items that follow the word, but not excluding items not specifically mentioned.

[0025] As used herein, the term "about," when used in conjunction with numerical values, includes ±10% of the indicated value. Furthermore, all ranges relating to the same component or property herein include endpoints, are independently combinable, and include all intermediate points and ranges. It should be understood that, where a parameter range is provided, the invention also provides all integers within that range and their tenths digits.

[0026] As used herein, the term "stabilizer" refers to a chemical agent added to a composition to prevent undesirable changes in the state or form of the composition and / or the active biocidal agent contained therein.

[0027] As used herein, the term "effective amount" refers to the amount of an active ingredient commercially recommended for the control and / or prevention of pests. The commercially recommended amount of each active ingredient (usually specified as the application rate of the commercial formulation) can be found on the label accompanying the commercial formulation. The commercially recommended application rate of a commercial formulation can vary depending on factors such as the plant species and the pest to be controlled.

[0028] As used herein, the term “insecticide” broadly refers to compounds or combinations used as acaricides, insecticides, insecticide synergists, tickicides, nematicides, and molluscicides. For chemical categories and applications, as well as specific compounds in each category, see “The Pesticide Manual Thirteenth Edition” (British Crop Protection Council, Hampshire, UK, 2003) and “The e-Pesticide Manual, Version 3” (British Crop Protection Council, Hampshire, UK, 2003-04), the contents of which are incorporated herein by reference in their entirety.

[0029] As used herein, the terms "plant" or "crop" refer to, but are not limited to, whole plants, plant organs (e.g., leaves, stems, twigs, roots, trunks, branches, buds, fruits, etc.), plant cells, or plant seeds. This term also covers plant crops such as fruits and vegetables. In some embodiments, the term "plant" may include its propagation material, which may include all reproductive parts of the plant (e.g., seeds) and vegetative plant material (e.g., cuttings and tubers) that can be used for the propagation of the plant. This includes seeds, tubers, spores, bulbs, rhizomes, bud-based branchlets, stolons, and buds, as well as other parts of the plant (including seedlings and young plants) that will be transplanted after germination or emergence from the soil.

[0030] As used herein, the term "plant propagation material" refers to, but is not limited to, all reproductive parts of a plant (such as seeds) and vegetative plant material (such as cuttings and tubers) that can be used for plant propagation, including tubers, spores, bulbs, rhizomes, bud-based branchlets, stolons, and buds, as well as other parts of the plant (including seedlings and young plants) that will be transplanted after germination or after emergence from the soil.

[0031] As used herein, the term “site” means, but is not limited to, the place where plants grow, the place where plant propagation material is sown, or the place where plant propagation material will be sown, including cultivated areas.

[0032] As used herein, the term “treatment of a plant or site to resist pests” includes, but is not limited to, protecting the plant or site from pests and / or controlling the pests on the plant or site.

[0033] As used herein, the term “pest” means any biological agent that may pose a risk to one or more plants in the general sense and / or to crops in particular, or that may cause any minor or major damage thereto, including but not limited to insects, mites, fungi, weeds, or any combination thereof.

[0034] As used in this article, the term "ha" refers to a hectare.

[0035] As used herein, the terms “mixture” or “combination” refer to, but are not limited to, combinations in any physical form, such as blends, solutions, suspensions, etc.

[0036] As used herein, the term "synergistic combination" refers to, but is not limited to, a combination of photoprotectants and thermal protectants that has a greater impact on the stability of the composition than the effect of each component alone or the sum of the effects obtained by each component alone.

[0037] As used herein, the term "photoprotectant" refers to, but is not limited to, compounds that can reduce photodegradation of components in a composition caused by natural or artificial sunlight.

[0038] As used herein, the term "thermal protectant" refers to, but is not limited to, compounds that can reduce thermal degradation of components in a composition caused by heat.

[0039] As used herein, the term "composition" means, but is not limited to, a combination of two or more components brought together. The term "composition" also means, but is not limited to, solid compositions, liquid compositions, and formulations (including barrel mixes).

[0040] As used herein, the term "composition" refers to, but is not limited to, a combination of two or more components brought together. The term "composition" also refers to, but is not limited to, solid compositions, liquid compositions, and formulations (including barrel mixes).

[0041] Agricultural chemical compositions of the subject of this invention :

[0042] The present invention provides a photoprotective and heat-protective agricultural chemical composition comprising: a) at least one pest control agent in an amount of 0.5% to 50% by weight based on the total composition; b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0043] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 40% to 50% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0044] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 30% to 40% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0045] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 20% to 30% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0046] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 10% to 20% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0047] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 0.5% to 10% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0048] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 0.5% to 20% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0049] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 0.5% to 1% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0050] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 0.5% to 2% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0051] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 0.5% to 2.5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0052] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 1% to 3% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0053] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 1% to 2.5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0054] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 0.5% to 3% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0055] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) at least one pest control agent in an amount of 0.5% to 5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0056] In some embodiments, the light-protecting and heat-protecting agricultural chemical composition comprises at least one pest control agent a), which is selected from insecticides, fungicides, herbicides, and mixtures thereof.

[0057] In some embodiments, at least one pest control agent a) is an insecticide.

[0058] In some embodiments, at least one pest control agent a) is a fungicide.

[0059] In some embodiments, at least one of the pest-killing agents a) is a herbicide.

[0060] Suitable insecticides are selected from allosamidin, thuringiensin, spinosad, spintoram, spinosads (including spinosad A, spinosad D, 21-butenyl spinosad and their derivatives), abamectin, doramectin, emamectin, emamectin benzoate, eprinomectin, ivermectin, selamectin, lepimectin, and milbemectin. oxime), moxidectin, calcium arsenate, copper arsenite, copper arsenate, lead arsenate, potassium arsenite, sodium arsenite, anabasine, azadirachtin, d-limonene, nicotine, pyrethrins, cinerins, cinerins I, cinerins II, jasmine I, jasmine II, pyrethrin I, pyrethrin II, quassia, rotenone, ryania, sabadilla, bendiocarb, carbaryl, benfiiracarb, carbofuran, carbosulfan, decarbofuran, furathiocarb, dimitan, difenocarb Metilan, Hyquincarb, Pirimicarb, Alanycarb, Aldicarb, Aldoxycarb, Butocarboxim, Butoxycarboxim, Methomyl, Nitrilacarb, Oxamyl, Tazimcarb, Thiocarboxime, Thiodicarb, Thiofanox, Allyxycarb, Aminocarb, Bufencarb, Butacarb, Carbanolate, Cloethocarb, Dioxacarb, EMPC,Ethiofencarb, fenethacarb, fenobucarb, isoprocarb, methiocarb, metolcarb, mexacarbate, promacyl, promecarb, propoxur, trimethacarb, XMC, xylylcarb, dinex, dinoprop, dinosam, DNOC, barium hexafluorosilicate, cryolite Sodium fluoride, sodium hexafluorosilicate, fipronil; chlordimeform, formetanate, formparanate, acrylonitrile, carbon disulfide, carbon tetrachloride, chloroform, chloropicrin, p-dichlorobenzene, 1,2-dichloropropane, ethyl formate, ethylene dibromide, ethylene dichloride, ethylene oxide, hydrogen cyanide, iodomethane, bromomethane, methyl chloroform, dichloromethane, naphthalene, phosphine, sulfonyl fluoride, tetrachloroethane, borax, calcium polysulfide, copper oleate, mercurous chloride, potassium thiocyanate, sodium thiocyanate, bistrifiuron, buprofezin ), chlorfluazuron, cyromazine, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron, triflumuron, epofenonane, fenoxycarb, tebufenozide ( Hydroprene, Kinoprene, Methoprene, Pyriproxyfen, Triprene, Juvenile Hormone I, Juvenile Hormone II, Juvenile Hormone HI, Chlorfenozide, Halofenozide, Methoxyfenozide, Tebufenozide, Alpha-ecdysone, Ecdysterone, Diofenolan, Precocious Pulsatilla I, Precocious Pulsatilla II, Precocious Pulsatilla HI,Dicyclanil, Bensultap, Cartap, Thiocyclam, Thiosultap, Flunicamid, Clothianidin, Dinotefuran, Imidacloprid, Thiamethoxam, Nitenpyram, Nithiaazine, Acetamiprid, Imidacloprid, Nitenpyram, Thiacloprid (The following are listed as examples of chemical compounds and their properties: oprid, bromo-DDT, camphechlor, DDT, pp'-DDT, ethyl-DDD, HCH, γ-HCH, lindane, methoxychlor, pentachlorophenol and TDE, aldrin, bromocyclen, chlorbicyclen, chlordane, chlordecone, dieldrin, dilor, endosulfan, endrin, HEOD, heptachlor) HHDN, isobenzan, isodrin, kelevan, mirex, bromfenvinfos, chlorfenvinphos, crotoxyphos, dichlorvos, didicrotophos, dimethylvinphos, fospirate, heptenophos, methocrotophos, mevinphos, monophos Crotophos, dibromophos, naftalofos, phosphamidon, propaphos, TEPP, tetrachlorvinphos, dioxabenzofos, fosmethilan, phenthoate, acethion, amiton, cadusafos, chlorethoxyfos, chlormephos, demephion, demephion-O,Demeton-S, Demeton-O, Demeton-S, Methyl Demeton, Demeton-O-methyl, Demeton-S-methyl, Demeton-S-methylsulphon, Disulfoton, Ethion, Ethoprophos, IPSP, Isothioate, Malathion, Methacrifos, Oxydemeton-methyl, Oxydeprofos, Oxydisulfoton, Phosphate Phosphorate), sulfotep, terbufos, thiometon, aliphatic amides, amidithion, cyanthoate, dimethoate, ethoate-methyl, formothion, mecarbam, omethoate, prothoate, sophamide, vamidothion, oxime, chlorphoxim, phoxim Methyl phorate, azamethiphos, coumaphos, coumithoate, dioxathion, endothion, menazon, morphothion, phosalone, pyraclofos, pyridaphenthion, quinothion, dithicrofos, thicrofos, phosalone, dialifos and dimethophoxim, dialifos, phosalone Phosmet), isoxathion, zolaprofos, chlorprazophos, pyrazophos, chlorpyrifos, methyl chlorpyrifos, butathiofos, diazinon, etrimfos, lirimfos, pirimiphos-ethyl, methyl pyrimiphos, primidophos, pyrimitate, tebupirimfos.Quinalphos, methyl quinalphos, atnidathion, lythidathion, methidathion, prothidathion, isazofos, triazophos, azothoate, bromophos, ethyl bromophos, carbophenothion, chlorthiophos, cyanophos, cythioate, dicapthon Dichlofenthion, Etaphos, Famphur, Fenchlorphos, Finitrothion, Fensulfothion, Fenthion, Methyl Fensulfothion, Heterophos, Jcκifenphos, Mesulfenfos, Parathion, Methyl Parathion, Phenkapton, Phosnichlor, Profenofos, Profenofos Phosphorus (prothiofos), sulprofos, temephos, trichlormetaphos-3, trifenofos, butonate, trichlorfon, mecarphon, fonofos, trichloronat, cyanofenphos, EPN, leptophos, crufomate, fenamiphos, fosthietan, imidazole Imicyafos, mephosfolan, phosfolan, pirimetaphos, acephate, isocarbophos, isofenphos, methamidophos, propetamphos, dimefox, mazidox, mipafox, schradan, indoxacarb, dialifos, phosmetTetramethrin, acetoprole, ethiprole, fipronil, pyrafluprole, pyriprole, tebufenpyrad, tolfenpyrad, vaniliprole, acridine lactate, allethrin, bioallethrin, barthrin, bifenthrin, and cypermethrin. bioethanomethrin, cyclethrin, cycloprothrin, cyfluthrin, β-cyhalothrin, cyhalothrin, γ-cyhalothrin, λ-cyhalothrin, cypermethrin, α-cypermethrin, alpha-methrin, β-cypermethrin, θ-cypermethrin, ζ-cypermethrin, β-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin n), dimethrin, empenthrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, τ-flucythrinate, furthrin, imiprothrin, metofluthrin, permethrin Biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, pyresmethrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, terallethrin, tetramethrin, and tralomethrin are all examples of permethrin-related compounds.Transfluthrin, etofenprox, fenpropathrin, flufenprox, halfenprox, protrifenbute, silafluofen, flufenerim, pyrimidifen, chlorfenapyr, spirodiclofen, spiromesifen, spirotetramat, diafenthiuron, flucofiiron, sulcofuron, AKD-3088, chlorantraniliprole, closantel, crotamiton, cyflumetofen E2Y45, EXD, fenazaflor, fenazaquin, fenoxacrim, fenpyroximate, FKI-1033, flubendiamide, HGW86, hydramethylnon, IKI-2002, isoprothiolane, malonoben, metaflumizone, metoxadiazone, nifluridide, NNI-9850, NNI-0101, pymetrozine, pyridaben, pyridalyl, pyrifluquinazon, Qcide, rafoxanide, rynaxypyr™, SYJ-159, triarathene.

[0061] In the embodiments, the insecticide a) is selected from the group comprising: abamectin, ivermectin, selamectin, epramectin, doramectin, emamectin, emamectin benzoate, deltamethrin, tetrabromocyanide, cypermethrin, α-methinin, ζ-cypermethrin, fenvalerate, cypermethrin, flufenacetate, allethrin, bifenthrin, bioallethrin, biobenzaloflavone, cypermethrin, β-cypermethrin, trifluralin, β-cypermethrin, fenfluroxyfen, fenfluroxyfen, fenfluroxyfen, fenfluroxyfen, cypermethrin, t-cypermethrin, fenfluroxyfen, fenfluroxyfen, benzalkonium chloride, heptafluthrin, fenfluroxyfen, λ-cypermethrin, spinosad, ethyl spinosad, spinosad A, spinosad D.

[0062] In another embodiment, the pest control agent a) is an insecticide selected from the following: emamectin, emamectin benzoate, abamectin, spinosad, ethyl spinosad, spinosad A, and spinosad D.

[0063] In another embodiment, the biocidal agent a) is emamectin.

[0064] In some embodiments, insecticide a) is emamectin benzoate.

[0065] In another embodiment, the pest control agent a) is an insecticide selected from the following: spinosad, ethyl spinosad, spinosad A, spinosad D.

[0066] In another embodiment, the pest control agent a) is ethyl spinosad, spinosad A, spinosad D, or a combination thereof.

[0067] In another embodiment, the pest-killing agent a) is spinosad.

[0068] In another embodiment, the biocidal agent a) is spinosad A.

[0069] In another embodiment, the pest-killing agent a) is spinosad D.

[0070] In another embodiment, the pest control agent a) is spinosad A, spinosad D, or a combination thereof.

[0071] In some embodiments, the insecticide a) is abameadine.

[0072] Suitable herbicides include allidochlor, beflubutamid, benzadox, benzzipram, bromobutide, cafenstrole, CDEA, chlorthiamid, cyprazole, dimethenamid, diphenamid, epronaz, etnipromid, fentrazamide, and flumetsulam. Flupoxam, flumethrin, halosafen, isocarbamid, isoxaben, napropamide, naptalam, pethoxamid, propyzamide, quinonamid, tebutam, chloranocryl, cisanilide, clonprop, cypromid, diflubenzuron ufenican, ethoxybenzanid, fenasulam, flufenacet, flufenican, mefenacet, mefluidide, metamifop, monalide, naproanilide, pentanochlor, picolinafen, propanil, benzoylprop, flamprop, wheat Grass-M, acetochlor, alachlor, butachlor, butenachlor, delachlor, diethatyl, dimethachlor, metazachlor, metolachlor, S-metolachlor, pretilachlor, propachlor, propisochlor, prynachlorTerbuchlor, thenylchlor, xylachlor, benzofluor, perfluidone, pyrimisulfan, profluazol, asulam, carbasulam, fenasulam, oryzalin, bilanafos, chloramben, dicamba, 2,3>6-TBA, trichlorfon MBA), bispyribac, pyriminobac, pyrithiobac, chloithal, aminopyralid, clopyralid, picloram, quinclorac, quinmerac, cacodylicacid, CMA, DSMA, hexaflurate, MAA, MAMA, MSMA, potassium arsenite, sodium arsenite, mesotrione, sulfadiazine lcotrione, tefuryltrione, tembotrione, benfuresate, ethofumesate, carboxazole, chlorprocarb, dichlormate, sulfadiazine, karbutilate, terbucarb, barban, BCPC, chlorfluazuron, carbetamide, CEPC, chlorbufam, chlorfenapyr. opropham, CPPC, desmedipham, phenisopham, phenmedipham, ethyl betaine, propham, swep, alloxydim, butroxydim, clethodim, cloproxydim, cycloxydim, profoxydim, sethoxydim, tepraloxydim, tralkoxydimIsoxachlortole, isoxaflutole, benzfendizone, cinidon-ethyl, flumezin, flumiclorac, flumioxazin, flumipropyn, benfluralin, butralin, dinitramine, ethalfluralin, fluchloralin, isopro palin, methalpropalin, nitralin, oryzalin, pendimethalin, prodiamine, profluralin and trifluralin, dinofenate, dinoprop, dinitropentanol, dinoseb, dinoterb, DNOC, etinofen, medinoterb, ethoxyfen, and acetylcholine. ifluorfen, aclonifen, bifenox, chlomethoxyfen, chlornitrofen, etnipromid, fluorodifen, fluoroglycofen, fluoronitrofen, fomesafen, furyloxyfen, halosafen, lactoferrin, nitrofen, tflumethrin (n) Itrofluorfen, oxyfluorfen, dazomet, fenprox, alarac, chloropon, dalapon, flupropanate, hexachloroacetone, iodomethane, methyl bromide, monochloroacetic acid, SMA, TCA, imidacloprid, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, ammonium aminosulfonate, borax, calcium chlorateCopper sulfate, ferrous sulfate, potassium azide, potassium cyanate, sodium azide, sodium chlorate, sulfuric acid, bromobonil, bromoxynil, chloroxynil, dichlobenil, iodobonil, ioxynil, pyraclonil, amiprofos-methyl, anilofos, bensulide, bilanafos, butamifos, 2,4-DEP, DMPA, EBEP, and other herbicides. Fosamine, glufosinate, glyphosate, piperophos, bromofenoxim, clonprop, 2,4-DEB, 2,4-DEP, difenopenten, disul, erbon, etnipromid, fenteracol, trifopsime, 4-CPA, 2,4-D, 3,4-DA, MCPA, MCPA-thioe thyl), 2,4,5-T, 4-CPB, 2,4-DB, 3,4-DB, MCPB and 2,4,5-TB, cloprop, 4-CPP, dichlorprop, dichlorprop-P, 3,4-DP, fenoprop, mecoprop and mecoprop-P, chlorazifop, clodinafop, clofop, cyhalofop, diclofop, oxazolidinone The following herbicides are listed: fenoxaprop, fenoxaprop-P, fenthiaprop, fluazifop, fluazifop-P, haloxyfop, haloxyfop-P, isoxapyrifop, metamifop, propaquizafop, quizalofop, quizalofop-P, trifop, and dinitramine.Prodiamine, benzofenap, pyrazolynate, pyrasulfotole, pyrazoxyfen, pyroxasulfone, toramezone, fluazolate, pyraflufen, credazine, pyridafol, pyridate, brompyrazon, chloridazon, and dimida zon, flufenpyr, metflurazon, norflurazon, oxapyrazon, pydanon, aminopyralid, cliodinate, clopyralid, dithiopyr, fluroxypyr, haloxydine, picloram, picolinafen, pyriclor, thiazopyr ), Trilopyr, Iprymidam, Tioclorim, Cyperquat, Diethamquat, Difenzoquat, Diquat, Morfamquat, Paraquat, Butylate, Cycloate, Di-allate, EPTC, Esprocarb, Ethiolate, Isopolinate, Methiobenca rb), molinate, orbencarb, pebulate, prosulfocarb, pyributicarb, sulfallate, thiobencarb, tiocarbazil, triallate, vernolate, dimexano, EXD, proxan, metiuron, dipropetryn, triaziflam, trihydroxytriazine,Atrazine, chlorazine, cyanazine, cyprazine, eglinazine, ipazine, mesoprazine, procyazine, proglinazine, propazine, sebuthylazine, simazine, terbuthylazine, trietazine, atraton, and methoxyfenozide. meton, prometon, secbumeton, simeton, terbumeton, ametryn, aziprotryne, cyanatryn, desmetryn, dimethametryn, methoprotryne, prometryn, simetryn, terbutryn, ametridone, amibuzin, cycloazinone hexazinone, isomethiozin, metamitron, metribuzin, amitrole, cafenstrole, epronaz, flupoxam, amicarabazone, bencarbazone, carfentrazone, flucarbazone, propoxycarbazone, sulfentxazone, thiamethoxam Thiencarbazone-methyl, cloransulam, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam, pyroxsulam, butafenacil, bromacil, flupropacil, isocillin, lenacil, terbacil, 3-phenyluracilBenzthiazuron, cumyluron, cycluron, dichloralurea, diflufenzopyr, isoruron, isouron, methabenzthiazuron, monisouron, noruron, anisuron, buturon, chlorbromuron, chloreturon, chlorotol (The following are listed as examples of herbicides): uron, chloroxuron, daimuron, difenoxuron, dimefuron, diuron, fenuron, fluometuron, fluothiuron, isoproturon, linuron, metribuzin, methyldymron, metobenzuron, metobromuron, metoxuron, monolinuron. Metfluron, neburon, parafluron, phenobenzuron, siduron, tetrafluron, thidiazuron, amidosulfuron, azimsulfuron, bensulfuron, chlorimuron, cyclosulfamuron, ethoxysulfuron, and flazasulfuron are all mentioned. Flucetosulfuron, flupyrsulfuron, foramsulfiiron, halosulfuron, imazosulfuron, mesosulfuron, nicosulfuron, orthosulfamuron, oxasulfiiron, primisulfuron, pyrazosulfuron, and rimsulfuron are all types of sulfuric acid.Sulfurylamide, sulfosulfuron, trifloxysulfuron, chlorsulfuron, cinosulfuron, ethametsulfuron, iodosulfuron, metsulfuron, prosulfuron, thifensylsulfuron, triasulfuron, tribensulfuron, triflusulfuron n), tritosulfuron, buthiuron, ethidimuron, tebuthiuron, thiazafluron, thidiazuron, acrolein, allyl alcohol, azafenidin, benzolin, bentazone, benzobicyclon, buthidazole, calcium cyanamide, cambendichlor, chlorf enac), chlorfenprop, chlorflurazole, chlorflurenol, cinmethylin, clonazepam, CPMF, cresol, o-dichlorobenzene, dimepiperate, endothal, fluoromidine, fluridone, flurochloridone, flurtamone, fluthiacet, indanofan, metribuzin ( methazole), methyl isothiocyanate, nipyraclofen, OCH, oxadiargyl, oxadiazon, oxaziclomefone, pentachlorophenol, pentoxazone, phenylmercuric acetate, pinoxaden, prosulfalin, pyribenzoxim, pyriftalid, quinoclamine, rhodethanil, sulglycapin.Thiadiazimin, tridiphane, trimeturon, tripropindan, and tritac.

[0073] Suitable fungicides are selected from 2-(thiocyanomethylthio)-benzothiazole, 2-phenylphenol, 8-hydroxyquinoline sulfate, Ampelomyces (quisqualis), azaconazole, azoxystrobin, Bacillus subtilis, benalaxyl, benomyl, benthiavalicarb-isopropyl, benzylaminobenzene sulfonic acid (BABS), bicarbonate, biphenyl, bismeithiazol, bitertanol, blasticidin-S, borax, and Bordeaux mixture. mixture), boscalid, bromuconazole, bupirimate, calcium polysulfide, captafol, captan, carbendazim, carboxin, carpropamid, carvone, chloroneb, chlorothalonil, chlozolinate, Coniothyrium Minitans), copper hydroxide, copper octanoate, copper oxychloride, copper sulfate, (basic) copper sulfate, cuprous oxide, cyazofamid, cyflufenamid, cymoxanil, cyproconazole, cyprodinil, dazomet, debacarb, ethyl di-(dithiocarbamate), dichlofluanid, dichlorophen, diclomezine, dichloran, diethofencarb, difenoconazole, difenzoquation), diflumetorim, dimethomorph, dimoxystrobin, diniconazole, diniconazole-M, dinobuton, dinocap, diphenylamine, dithianon, dodemorph, dodemorph acetate, dodine, dodine free alkali, edifenphos, epoxiconazole, etha Boxam, ethoxyquin, etridiazole, famoxadone, fenamidone, fenarimol, fenbuconazole, fenfuram, fenhexamid, fenoxanil, fenpiclonil, fenpropidin, fenpropimorph, fentin, fentin acetate, fentin hydroxide Ferbam, ferimzone, fluazinam, fludioxonil, flumorph, fluopicolide, fluoroimide, fluoxastrobin, fluquinconazole, flusilazole, flusulfamide, flutolanil, flutriafol, folpet, formaldehyde, forsythiamethoxam ( Fosetyl, Fosetyl-aluminium, Fuberidazole, Furalaxyl, Furametpyr, Guazatine, Guazatine acetate, GY-81, Hexaconazole, Hymexazol, Imazalil, Imazalil sulfate, Imibenconazole, Iminoctadine, Iminoctadine triacetate, Iminoctadine trioctylbenzene sulfonateTris (albesilate), ipconazole, iprobenfos, iprodione, iprovalicarb, isoprothiolane, kasugamycin, kasugamycin hydrochloride hydrate, kresoxim-methyl, mancopper, mancozeb, maneb, mepanipyrim, mepronil, mercuric chloride, mercuric oxide, mercurous chloride, metalaxyl, mefenoxam, metalaxyl-M, metam, metam ammonium, and more. Potassium permethrin, sodium thiosulfate, metconazole, methasulfocarb, iodomethyl, methyl isothiocyanate, metiram, metominostrobin, metrafenone, mildiomycin, myclobutanil, sodium mancozeb, nitrothal-isopropyl, nuarimol, octhilinone, ofuronamide, oleic acid (fatty acid), orysastrobin, oxadixyl, oxine-copper, oxpoconazoleFumarate, oxycarboxin, pefiirazoate, penconazole, pencycuron, pentachlorophenol, pentachlorophenyl laurate, penthiophanate-methyl, phenylmercuric acetate, phosphonic acid, phthalide, picoxystrobin, polyoxin B, polyoxins, polyoxorim, potassium bicarbonate, potassium hydroxyquinoline sulfate, probenazole, prochloraz, procymidone, cymoxanil opamocarb, propiconazole, propineb, proquinazid, prothioconazole, pyraclostrobin, pyrazophos, pyributicarb, pyrifenox, pyrimethanil, pyroquilon, quinoclamine, quinoxyfen, quintozene, Reynoutria sachalinensis extractextract), silthiofam, simeconazole, sodium 2-phenylphenol, sodium bicarbonate, sodium pentachlorophenate, spiroxamine, sulfur, SYP-Z071, tar, tebuconazole, tecnazene, tetraconazole, thiabendazole, thifluzamide, thiophanate-methyl, thiram, tiadinil, tolclofos-methyl Tolylfluanid, triadimefon, triadimenol, triazoxide, tricyclazole, triridemorph, trifloxystrobin, triflumizole, triforine, triticonazole, validamycin, vinclozolin, zineb, ziram, zoxamide, Candida oleophila, Fusarium oxysporum, Gliocladium spp., Phlebiopsis gigantean, Streptomyces griseoviridis, Trichoderma spp.), (RS)-N-(3,5-dichlorophenyl)-2-(methoxymethyl)-succinimide, 1,2-dichloropropane, 1,3-dichloro-1,1,3,3-tetrafluoroacetone hydrate, 1-chloro-2,4-dinitronaphthalene, 1-chloro-2-nitropropane, 2-(2-heptadecyl-2-imidazoline-1-yl)ethanol, 2,3-dihydro-5-phenyl-1,4-dithiane 1,1,4,4-tetraoxide, 2-methoxyethylmercuric acetate, 2-methoxyethylmercuric chloride, 2-methoxyethylmercuric silicate, 3-(4-chlorophenyl)-5-methylrhodanine, 4-(2-nitroprop-1-enyl)phenyl thiocyanate (4-(2-nitroprop-l-enyl)phenyl thiocyanateme, ampropylfos, anilazine, azithiram, barium polysulfide, Bayer32394, benodanil, benquinox, bentaluron, benzamacril, benzamacril-isobutyl, benzamorf, binapacryl, bis(methylmercury)sulfate, bis(tributyltin)oxide, buthiobate, cadmium calcium copper zinc chromate sulfate, carbamorph, CECA, chlobenthiazone, chloraniformethan, chlorfenazole, chlorquinox, climbazole, copper bis(3-phenylsalicylic acid), copper zinc chromate, cufraneb, cuprichydrazinium sulfate, copper chlorpyrifos, cyclafuramid, cypendazole, cyprofiiram, decafentin, dichlone, dichlozoline, diclobutrazol, dimethirimol, diocton, dinosulfon, dinoterbon, dipyrithione, ditalimfos, dodicin, dr... azoxolon), EBP, ESBP, etaconazole, etem, ethirim, fenaminosulf, fenapanil, finitropan, fluotrimazole, furcarbanil, furconazole, cis-furazolidone, furmecyclox, fiirophanate, glyodine, griseofulvin, halacrinate, Hercules3944, Hexylthiofos, ICIA0858, Isopamphos, Isovaledione, Mebenil, Mecarbinzid, Metazoxolon, Methuroxam, Methylmercurydicyandiamide, Metsulfovax, Miln eb), chloric acid anhydride, myclozolin, N-3,5-dichlorophenyl-succinimide, N-3-nitrophenyl itaconimidide, natamycin, N-ethylmercuric-4-toluenesulfonylaniline, nickel bis(dimethyldithiocarbamate), OCH, phenylmercuric dimethyldithiocarbamate, phenylmercuric nitrate, phosdiphen, prothiocarb, prothiocarb hydrochloride, pyracarbolid, pyridin itril, pyroxychlor, pyroxyfur, quinacetol, quinacetolsulfate, quinazamid, quinconazole, rabenzazole, salicylaniline, SSF-109, sultropen, tecoram, thiadifluor, thicyofen, thiochlorfenphim, thiophanate, thioquinox, tioxymid, triamiphos, triarimol, triazbutil, trihlamide, urbacid, XRD-563, zarilamid.

[0074] The present invention provides a photoprotective and heat-protective agricultural chemical composition comprising: a) emamectin benzoate in an amount of 0.5% to 50% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0075] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 40% to 50% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0076] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 30% to 40% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0077] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 20% to 30% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0078] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 10% to 20% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0079] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 0.5% to 10% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0080] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 0.5% to 20% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0081] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 0.5% to 1% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0082] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 0.5% to 2% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0083] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 0.5% to 2.5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0084] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 1% to 3% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0085] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 1% to 2.5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0086] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 0.5% to 3% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0087] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) emamectin benzoate in an amount of 0.5% to 5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0088] The present invention provides a photoprotective and heat-protective agricultural chemical composition comprising: a) spinosad in an amount of 0.5% to 50% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0089] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 40% to 50% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0090] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 30% to 40% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0091] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 20% to 30% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0092] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 10% to 20% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0093] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 0.5% to 10% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0094] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 0.5% to 20% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0095] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 0.5% to 1% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0096] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 0.5% to 2% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0097] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 0.5% to 2.5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0098] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 1% to 3% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0099] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 1% to 2.5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0100] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 0.5% to 3% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0101] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) spinosad in an amount of 0.5% to 5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0102] The present invention provides a photoprotective and heat-protective agricultural chemical composition comprising: a) abameadine in an amount of 0.5% to 50% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0103] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 40% to 50% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0104] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 30% to 40% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0105] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 20% to 30% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0106] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 10% to 20% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0107] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 0.5% to 10% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0108] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 0.5% to 20% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0109] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 0.5% to 1% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0110] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 0.5% to 2% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0111] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 0.5% to 2.5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0112] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 1% to 3% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0113] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 1% to 2.5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0114] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 0.5% to 3% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0115] In some embodiments, the photoprotective and heat-protective agrochemical composition comprises: a) abameadine in an amount of 0.5% to 5% by weight based on the total composition; and b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

[0116] In some embodiments, the amount of photoprotectant in stabilizer b) is 0.1% to 10% by weight based on the total composition.

[0117] In some embodiments, the amount of photoprotectant in stabilizer b) is 9% to 10% by weight based on the total composition.

[0118] In some embodiments, the amount of photoprotectant in stabilizer b) is 8% to 9% by weight based on the total composition.

[0119] In some embodiments, the amount of photoprotectant in stabilizer b) is 7% to 8% by weight based on the total composition.

[0120] In some embodiments, the amount of photoprotectant in stabilizer b) is 6% to 7% by weight based on the total composition.

[0121] In some embodiments, the amount of photoprotectant in stabilizer b) is 5% to 6% by weight based on the total composition.

[0122] In some embodiments, the amount of photoprotectant in stabilizer b) is 4% to 5% by weight based on the total composition.

[0123] In some embodiments, the amount of photoprotectant in stabilizer b) is 3% to 4% by weight based on the total composition.

[0124] In some embodiments, the amount of photoprotectant in stabilizer b) is 2% to 3% by weight based on the total composition.

[0125] In some embodiments, the amount of photoprotectant in stabilizer b) is 1% to 2% by weight based on the total composition.

[0126] In some embodiments, the amount of photoprotectant in stabilizer b) is 0.1% to 1% by weight based on the total composition.

[0127] In some embodiments, the amount of photoprotectant in stabilizer b) is 0.1% to 1.5% by weight based on the total composition.

[0128] In some embodiments, the amount of photoprotectant in stabilizer b) is 0.1% to 2% by weight based on the total composition.

[0129] In some embodiments, the amount of photoprotectant in stabilizer b) is 0.1% to 2.5% by weight based on the total composition.

[0130] In some embodiments, the amount of photoprotectant in stabilizer b) is 0.1% to 5% by weight based on the total composition.

[0131] In some embodiments, stabilizer b) comprises a photoprotectant selected from the group consisting of 2-(2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylpropyl)phenol (Tinuvin). ® 328), bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-sebacate (Tinuvin) ® 292), α-[3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]-ω-hydroxypoly(oxy-1,2-ethylenediyl) (Tinuvin) ® 1130), 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-[2-hydroxy-3-(dodecyloxy- and tridecyloxy)propoxy]phenol (Tinuvin) ® 400), 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-[3-[(2-ethylhexyl)oxy]-2-hydroxypropoxy]phenol (Tinuvin) ®405), 2,4,6-tris[4-(1-octyloxycarbonyl)ethoxy-2-hydroxyphenyl]-1,3,5-triazine (Tinuvin) ® 477), 2-[4-[4,6-bis([1,1'-biphenyl]-4-yl)-1,3,5-triazine-2-yl]-3-hydroxyphenoxy]-isooctyl propionate (Tinuvin) ® 479), Light stabilizer 5050 (Tinuvin) ® A mixture of 1,10-bis[2,2,6,6-tetramethyl-1-(octyloxy)-4-piperidinyl] ester of sebacic acid and octyl 3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenylpropionate (Tinuvin) ® 5060), 2,2'-[6-(2,4-dibutoxyphenyl)-1,3,5-triazine-2,4-diyl]bis[5-butoxyphenol] (Tinuvin) ® 460), UV absorber - tinuvin 5151 (Tinuvin) ® 5151), triazine-based UV absorbers (Tinuvin) ® 5248), 2-ethylhexyl 3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenylpropionic acid (Tinuvin) ® 384-2), UV absorbers based on C7-9 branched and straight-chain alkyl esters of 3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenylpropionic acid (Tinuvin) ® 99-2), 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol (Tinuvin) ® 900), UV absorber based on 2,4,6-tris([1,1'-biphenyl]-4-yl)1,3,5-triazine (Tinosorb) ® A2B), a UV absorber based on 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol (Tinosorb) ® M), a UV absorber based on 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol (Tinosorb) ® M-WG), a UV absorber based on 2,2'-[6-(4-methoxyphenyl)-1,3,5-triazine-2,4-diyl]bis[5-[(2-ethylhexyl)oxy]phenol (Tinosorb) ®S), 2-[4-(diethylamino)-2-hydroxybenzoyl]hexyl benzoate (Uvinul) ® Aplus), 2-ethylhexyl 3-(4-methoxyphenyl)-2-acrylate (Uvinul) ® MC 80), 4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tri-benzoic acid 1,1',1''-tris(2-ethylhexyl) ester (Uvinul) ® T 150), zinc oxide (Z-COTE) ® ), zinc oxide and triethoxyoctylsilane (Z-COTE) ® HP1), kojic acid and mixtures thereof.

[0132] In some embodiments, stabilizer b) comprises a photoprotectant, which is 2-(2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylpropyl)phenol (Tinuvin). ® 328).

[0133] In some embodiments, stabilizer b) comprises the photoprotective agent bis-ethylhexyloxyphenol methoxyphenyl triazine (Tinosorb ® S).

[0134] In some embodiments, the amount of heat protectant in stabilizer b) is 0.1% to 10% by weight based on the total composition.

[0135] In some embodiments, the amount of heat protectant in stabilizer b) is 9% to 10% by weight based on the total composition.

[0136] In some embodiments, the amount of heat protectant in stabilizer b) is 8% to 9% by weight based on the total composition.

[0137] In some embodiments, the amount of heat protectant in stabilizer b) is 7% to 8% by weight based on the total composition.

[0138] In some embodiments, the amount of heat protectant in stabilizer b) is 6% to 7% by weight based on the total composition.

[0139] In some embodiments, the amount of heat protectant in stabilizer b) is 5% to 6% by weight based on the total composition.

[0140] In some embodiments, the amount of heat protectant in stabilizer b) is 4% to 5% by weight based on the total composition.

[0141] In some embodiments, the amount of heat protectant in stabilizer b) is 3% to 4% by weight based on the total composition.

[0142] In some embodiments, the amount of heat protectant in stabilizer b) is 2% to 3% by weight based on the total composition.

[0143] In some embodiments, the amount of heat protectant in stabilizer b) is 1% to 2% by weight based on the total composition.

[0144] In some embodiments, the amount of heat protectant in stabilizer b) is 0.1% to 1% by weight based on the total composition.

[0145] In some embodiments, the amount of heat protectant in stabilizer b) is 0.1% to 1.5% by weight based on the total composition.

[0146] In some embodiments, the amount of heat protectant in stabilizer b) is 0.1% to 2% by weight based on the total composition.

[0147] In some embodiments, the amount of heat protectant in stabilizer b) is 0.1% to 2.5% by weight based on the total composition.

[0148] In some embodiments, the amount of heat protectant in stabilizer b) is 0.1% to 5% by weight based on the total composition.

[0149] In some embodiments, stabilizer b) comprises a heat protectant selected from: a blend of 50% tris(2,4-di-tert-butylphenyl) phosphite and 50% pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] (Irganox) ® B225), 1,1'-[2,2-bis[[3-[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenylpropionic acid]-1,3-propanediyl] ester of 3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropoxy]methyl]-1,3-propanediyl] ester (Irganox) ® 1010), di-dodecyl 3,3'-thiodipropionate (Irganox) ® 800FL), 1,1'-[1,2-ethylenedimethylbis(oxy-2,1-ethylenedimethyl)] ester of 3-(1,1-dimethylethyl)-4-hydroxy-5-methylphenylpropionic acid (Irganox) ® 245), octadecyl 3,5-bis(1,1-dimethylethyl)-4-hydroxyphenylpropionate (Irganox) ®1076), Butylated hydroxytoluene (BHT), Butylated hydroxyanisole (BHA), Epoxidized alcohol (epoxidized soybean oil) 3,3'-di-dodecyl thiodipropionate (Irganox) ® PS 800 FL), 2,4-bis(1,1-dimethylethyl)phenol phosphite (Irgafos) ® 168), ascorbic acid, α-tocopherol (vitamin E) and mixtures thereof.

[0150] In some embodiments, stabilizer b) comprises a heat protectant, which is 2,4-bis(1,1-dimethylethyl)phenol phosphite (Irgafos). ® 168).

[0151] In some embodiments, the weight ratio of photoprotectant to heat protectant is 1:5 to 5:1.

[0152] In some embodiments, the weight ratio of photoprotectant to heat protectant is 1:4 to 4:1.

[0153] In some embodiments, the weight ratio of photoprotectant to heat protectant is 1:3 to 3:1.

[0154] In some embodiments, the weight ratio of photoprotectant to heat protectant is 1:2 to 2:1.

[0155] In some embodiments, the weight ratio of photoprotectant to heat protectant is 1:2 to 1:1.

[0156] In some embodiments, the weight ratio of photoprotectant to heat protectant is 1:1 to 1:1.

[0157] In some embodiments, the weight ratio of photoprotectant to heat protectant is 1:1 to 2:1.

[0158] In some embodiments, the weight ratio of photoprotectant to heat protectant is 1:2.

[0159] In some embodiments, the weight ratio of photoprotectant to heat protectant is 2:1.

[0160] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 5:1 to 1:20.

[0161] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 4:1 to 1:20.

[0162] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 3:1 to 1:20.

[0163] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 2:1 to 1:20.

[0164] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 1:1 to 1:20.

[0165] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 5:1 to 1:10.

[0166] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 4:1 to 1:10.

[0167] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 3:1 to 1:10.

[0168] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 2:1 to 1:10.

[0169] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 1:1 to 1:10.

[0170] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 5:1 to 1:4.

[0171] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 4:1 to 1:4.

[0172] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 3:1 to 1:4.

[0173] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 2:1 to 1:4.

[0174] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 1:1 to 1:4.

[0175] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 5:1 to 1:2.

[0176] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 4:1 to 1:2.

[0177] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 3:1 to 1:2.

[0178] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 2:1 to 1:2.

[0179] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 1:1 to 1:2.

[0180] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 5:1 to 3:4.

[0181] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 4:1 to 3:4.

[0182] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 3:1 to 3:4.

[0183] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 2:1 to 3:4.

[0184] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 1:1 to 3:4.

[0185] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 5:1 to 1:1.

[0186] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 4:1 to 1:1.

[0187] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 3:1 to 1:1.

[0188] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 2:1 to 1:1.

[0189] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and pest control agent a) is 1:1 to 1:1.

[0190] In some embodiments, the ratio between stabilizer b) comprising a synergistic combination of photoprotectant and heat protectant and biocide a) is 4:1 to 5:1.

[0191] In some embodiments, the ratio between the photoprotectant and the biocide is 1:500 to 20:1.

[0192] In some embodiments, the ratio between the photoprotectant and the biocide is from 1:500 to 10:1.

[0193] In some embodiments, the ratio between the photoprotectant and the biocide is 1:500 to 5:1.

[0194] In some embodiments, the ratio between the photoprotectant and the biocide is from 1:500 to 4:1.

[0195] In some embodiments, the ratio between the photoprotectant and the biocide is 1:500 to 3:1.

[0196] In some embodiments, the ratio between the photoprotectant and the biocide is 1:500 to 2:1.

[0197] In some embodiments, the ratio between the photoprotectant and the biocide is 1:500 to 1:1.

[0198] In some embodiments, the ratio between the photoprotectant and the biocide is 1:4 to 3:1.

[0199] In some embodiments, the ratio between the photoprotectant and the biocide is 1:2 to 2:1.

[0200] In some embodiments, the ratio between the photoprotectant and the biocide is 1:2 to 3:1.

[0201] In some embodiments, the ratio between the heat protectant and the pest control agent is from 1:500 to 20:1.

[0202] In some embodiments, the ratio between the heat protectant and the pest control agent is 1:500 to 10:1.

[0203] In some embodiments, the ratio between the heat protectant and the pest control agent is 1:500 to 5:1.

[0204] In some embodiments, the ratio between the heat protectant and the pest control agent is from 1:500 to 4:1.

[0205] In some embodiments, the ratio between the heat protectant and the pest control agent is from 1:500 to 3:1.

[0206] In some embodiments, the ratio between the heat protectant and the pest control agent is 1:500 to 2:1.

[0207] In some embodiments, the ratio between the heat protectant and the pest control agent is 1:500 to 1:1.

[0208] In some embodiments, the ratio between the heat protectant and the pest control agent is 1:4 to 3:1.

[0209] In some embodiments, the ratio between the heat protectant and the pest control agent is 1:2 to 2:1.

[0210] In some embodiments, the ratio between the heat protectant and the pest control agent is 1:2 to 3:1.

[0211] In an embodiment, the present invention provides an agricultural chemical liquid composition comprising: a) at least one pest control agent selected from insecticides, fungicides, herbicides, and mixtures thereof; b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant; c) an organic solvent; d) a nonionic surfactant; and e) an anionic surfactant.

[0212] In some embodiments, at least one of the pest control agents (a) in the agricultural chemical liquid composition is an insecticide.

[0213] In some embodiments, at least one of the pest-killing agents (a) in the agricultural chemical liquid composition is a fungicide.

[0214] In some embodiments, at least one of the pest-killing agents in the agricultural chemical liquid composition is a herbicide.

[0215] In some embodiments, the pesticide a) in the agricultural chemical liquid composition is selected from the group consisting of: abamectin, ivermectin, selamectin, epramectin, doramectin, emamectin, emamectin benzoate, deltamethrin, tetrabromocyanide, cypermethrin, α-methinin, ζ-cypermethrin, fenvalerate, cypermethrin, flufenacetate, allethrin, bifenthrin, bio-allethrin, bio-benzaloflavone, cypermethrin, β-cypermethrin, trifluralin, β-cypermethrin, fenvalerate, fenvalerate, fenvalerate, fenvalerate, fenvalerate, cypermethrin, t-cypermethrin, fenvalerate, fenvalerate, benzalkonium chloride, heptafluthrin, fenvalerate, λ-cypermethrin, spinosad, ethyl spinosad, spinosad A, spinosad D.

[0216] In some embodiments, the pest control agent a) in the agricultural chemical liquid composition is emamectin or emamectin benzoate.

[0217] In some embodiments, the pest control agent a) in the agricultural chemical liquid composition is emamectin benzoate.

[0218] In some embodiments, the pest control agent a) in the agricultural chemical liquid composition is spinosad, ethyl spinosad, spinosad A, spinosad D, or a combination thereof.

[0219] In some embodiments, the pest control agent a) in the agricultural chemical liquid composition is spinosad.

[0220] In some embodiments, the pest control agent a) in the agricultural chemical liquid composition is ethyl spinosad.

[0221] In some embodiments, the pest control agent a) in the agricultural chemical liquid composition is spinosad A.

[0222] In some embodiments, the biocidal agent a) in the agricultural chemical liquid composition is spinosad D.

[0223] In some embodiments, the biocidal agent a) in the agricultural chemical liquid composition is selected from spinosad A, spinosad D, or a combination thereof.

[0224] In some embodiments, the biocidal agent a) in the agricultural chemical liquid composition is selected from emamectin benzoate, spinosad A, spinosad D, or combinations thereof.

[0225] In some embodiments, the agricultural chemical liquid composition of the present invention may further contain at least one additional pest control agent.

[0226] In the embodiments, at least one additional biocidal agent is selected from acrylamide, thiamethoxam, rapamycin, mibamectin, milbemex, moxifloxacin, calcium arsenate, copper acetylacetate, copper arsenate, lead arsenate, potassium arsenite, sodium arsenite, equisetin, azadirachtin, d-limonene, nicotine, pyrethroids, cucurbitacins, cucurbitacin I, cucurbitacin II, jasmine ester I, jasmine ester II, pyrethroid I, pyrethroid II, quassin, rotenone, ryanodine, veratrum saba, chlorpyrifos, carbofuran, carbofuran, carbofuran, carbofuran, carbofuran, carbofuran, carbofuran, carbofuran, carbofuran, fenvalerate, difenoconazole, fenvalerate, pirimicarb, thiamethoxam, aldicarb, aldicarb, methyl ethyl ketone, methyl ethyl ketone, methomyl, cyandiamide, fenvalerate, thiamethoxam, thiamethoxam. Carbendazim, thiocarb ... Borax, calcium polysulfide, copper oleate, mercurous chloride, potassium thiocyanate, sodium thiocyanate, bis(triflufenoxam), thiamethoxam, difenoconazole, cyromazine, diflubenzuron, flucyclovir, flufenoxam, flufenoxam, lufenuron, flufenoxam, polyfluorourea, flufenoxam, flufenoxam, chlorfenapyr, fenpropathrin, fenpropathrin, pyriproxyfen, fenpropathrin I, juvenile hormone II, juvenile hormone HI, cyclofenozide, chlorfenapyr, methoxyfenozide, tebufenozide, α-ecdysone, ecdysterone, benzyl ether, precocious hormone I, precocious hormone II, precocious hormone HI, desinil, chlorfenapyr, cypermethrin, chlorfenapyr ring, chlorfenapyr, flupyradifurone, thiamethoxam, dinotefuran, imidacloprid, thiamethoxam, nitrazepam, acetamiprid Imidacloprid, acetamiprid, thiamethoxam, brominated DDT, toxaphene, DDT, pp'-DDT, ethyl-DDD, HCH, γ-HCH, lindane, methoxydendron, pentachlorophenol and TDE, aldrin, brominated chlorpyrifos, borneol, chlordane, decachlorophen, dieldrin, thiamethoxam, endosulfan, isodrin, HEOD, heptachlor, HHDN, carbapenem, isoaldrin, clenbuterol, fenvalerate, bromophenylenephos, chlorpyrifos, phosmet, dichlorvos, chlorpyrifos, methyl chlorpyrifos, phosmet, heptamethrin, ethoxyphos, phosmet, dibromophos, naphthalenephosphide, phosmet, tebufenozide, TEPP, chlorpyrifos, phosmet, phosmet, phosmet, phosmet-OPhosphorus-S, Methionine, Methionine-O, Methionine-S, Methyl Methionine, Methionine-O-methyl, Methionine-S-methyl, Sulfonate, Ethylphosphide, Ethylphosphide, Phosphate, IPSP, Isopropafen, Malathion, Chlorpyrifos, Sulfonate, Isofenphos, Sulfonate, Phosphate, Phosphate, Terbufos, Methyl Ethylphosphide, Aliphatic Ammonium, Cypermethrin, Dimethoate, Dimethoate, Ango, Aphidicide, Omethoate, Ferox, Sugo, Aphidicide, Oxime, Chlorpyrifos, Phosphate, Methyl Phosphate, Methyl Pyridazine, Fly Phosphate, Livestock Phosphate, Dichlorvos, Indomethacin, Aphid-Song, Maoguo, Fushalphos, Pyrazophos, Pyrazophos Quinalphos, safran, safran, phosmet and phosmet, chlorpyrifos, phosmet, isoxazophos, zorafos, chlorpromazine, dimethoate, chlorpyrifos, methyl chlorpyrifos, pyrimethanil, diazinon, ethirimol, pyrimethanil, ethylpyrimidine phosphate, methylpyrimidine phosphate, pyrimidine phosphate, pyrimethanil, butylpyrimidine phosphate, quinalphos, methyl quinalphos, ethyl chlorpyrifos, chlorpyrifos, ethiazole phosphate, chlorpyrifos, triazophos, azophos, bromoxynil, ethyl bromoxynil, trithion, chloromethonium, pyridaben, cypermethrin, isochlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos, phosmet, fenitrothion, fenthion, methyl fenthion, chlorpyrifos Phosphine, phosmet sulfoxide, parathion, methyl parathion, fenthion, chlorpyrifos, profenofos, profenofos, thiopropionate, dithion, chlorpyrifos-3, trimethoate, butyl phosphate, trichlorfon, tetramethrin, terbufos, fenpyrophos, benzoylphos, EPN, parabromophos, chlorpyrifos, fenpyrophos, fosylcarb, imidacloprid, dimethoate, phosmet, methamidophos, methamidophos, pymetrozine, methamidophos, pymetrozine, azidophos, pyrimethanil, octamethrin, indoxacarb, chlorpyrifos, phosmet, pyrethroid, acetamiprid, acetamiprid, fipronil, pyridaben, pyrazopyr, pyridaben, pyridabenamide, flupyrazole, fumigant Pyrethroids, including cypermethrin, cypermethrin, γ-trifluorocypermethrin, cypermethrin, α-cypermethrin, β-cypermethrin, θ-cypermethrin, tetrafluoromethrin, benzylpyrethrin, pendimethalin, pyrethroid, cypermethrin, flumethrin, pyrethroid, propargite, methoxyfenozide, permethrin, bio-permethrin, trans-permethrin, propargite, pyrethroid, cis-benzoxyfenozide, cyclopentenylpyrethrin, tetrafluoromethrin, trifluoromethrin, benzylpyrethrin, propargite, flusilazole, pyrimethanil, pyrimethanil, chlorfenapyr, spirodiclofen, spirodiclofen, spirotetramat, fenpyroxene, fenpyroxene, pyrimethanil, chlorfenapyr, spirodiclofen, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, spirodiclofen, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, fenpyroxene, imidacloprid (AKD), ® -3088), chlorantraniliprole, chlorpyrifos, clomiphene, diflubenzuron, fenpyroxene, fenoxam, azithromycin, FKI ® -1033, flufenoxuron, cyanfenoxuron, flufenoxuron, flufenoxuron, isoprothiolane, tebufenozide, cyfluthrin, pymetrozine, NNI ® -9850, NNI® -0101, Pymetrozine, Pyridaben, Acetaminophen, Flufenoxuron, Qcide TM Iodine ethersamide, SYJ ® -159, Benzylthiazolinium.

[0227] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is from 0.5% to 50% by weight based on the total composition.

[0228] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 40% to 50% by weight based on the total composition.

[0229] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 30% to 40% by weight based on the total weight of the composition.

[0230] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 20% to 30% by weight based on the total weight of the composition.

[0231] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 10% to 20% by weight based on the total weight of the composition.

[0232] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 0.5% to 10% by weight based on the total weight of the composition.

[0233] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is from 0.5% to 20% by weight based on the total weight of the composition.

[0234] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 0.5% to 1% by weight based on the total weight of the composition.

[0235] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 0.5% to 2% by weight based on the total weight of the composition.

[0236] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 0.5% to 2.5% by weight based on the total weight of the composition.

[0237] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 1% to 3% by weight based on the total weight of the composition.

[0238] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 2% to 4% by weight based on the total weight of the composition.

[0239] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 2% to 3% by weight based on the total weight of the composition.

[0240] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 5% to 10% by weight based on the total weight of the composition.

[0241] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 1% to 2.5% by weight based on the total weight of the composition.

[0242] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 0.5% to 3% by weight based on the total weight of the composition.

[0243] In some embodiments, the amount of at least one pest control agent a) in the agricultural chemical liquid composition is 0.5% to 5% by weight based on the total weight of the composition.

[0244] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 0.1% to 10% by weight based on the total composition weight.

[0245] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 9% to 10% by weight based on the total composition weight.

[0246] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 8% to 9% by weight based on the total weight of the composition.

[0247] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 7% to 8% by weight based on the total composition weight.

[0248] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 6% to 7% by weight based on the total composition weight.

[0249] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 5% to 6% by weight based on the total weight of the composition.

[0250] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 4% to 5% by weight based on the total weight of the composition.

[0251] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 3% to 4% by weight based on the total weight of the composition.

[0252] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 2% to 3% by weight based on the total weight of the composition.

[0253] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 1% to 2% by weight based on the total weight of the composition.

[0254] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 0.1% to 1% by weight based on the total weight of the composition.

[0255] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 0.1% to 1.5% by weight based on the total weight of the composition.

[0256] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 0.1% to 2% by weight based on the total weight of the composition.

[0257] In the embodiments, the amount of photoprotectant in stabilizer b) of the agricultural chemical liquid composition is 0.1% to 2.5% by weight based on the total weight of the composition.

[0258] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 0.1% to 10% by weight based on the total composition weight.

[0259] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 9% to 10% by weight based on the total composition weight.

[0260] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 8% to 9% by weight based on the total composition weight.

[0261] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 7% to 8% by weight based on the total composition.

[0262] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 6% to 7% by weight based on the total weight of the composition.

[0263] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 5% to 6% by weight based on the total composition weight.

[0264] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 4% to 5% by weight based on the total weight of the composition.

[0265] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 3% to 4% by weight based on the total weight of the composition.

[0266] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 2% to 3% by weight based on the total weight of the composition.

[0267] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 1% to 2% by weight based on the total weight of the composition.

[0268] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 0.1% to 1% by weight based on the total weight of the composition.

[0269] In the embodiments, the amount of heat protectant in stabilizer b) of the agricultural chemical liquid composition is 0.1% to 1.5% by weight based on the total weight of the composition.

[0270] In the embodiments, the organic solvent c) in the agricultural chemical liquid composition is selected from the group consisting of: aromatic hydrocarbons, aliphatic hydrocarbons, alicyclic hydrocarbons, dimethyl sulfoxide (DMSO), N-methylvalerolamide, γ-butyrolactone, benzyl acetate, benzyl benzoate, butyl benzoate, 2-ethoxypropyl acetate, methyl proxitol acetate; tributyl phosphate, N,N-dimethyloctamide, N,N-dimethyldecylamide; 2-heptanone, cyclohexanone, acetophenone, 4-methoxyacetophenone; cyclohexanol, 4-hydroxy-4-methyl-2-pentanone, n-octanol, 2-ethylhexanol, dimethyl glutarate, dimethyl succinate, dimethyl adipate, polyethylene glycol, glycerol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether, diethylene glycol monomethyl ether Diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monophenyl ether; propylene carbonate, butenyl carbonate, N-methylpyrrolidone, N-butylpyrrolidone, N-octylpyrrolidone, N-ethylpyrrolidone, N-dodecylpyrrolidone, n-propyl lactate, methyl lactate, ethyl lactate, isopropyl lactate, butyl lactate, methyl 5-(dimethylamino)-2-methyl-5-oxovalerate, N,N-dimethyllactic acid, Altasolv TMM (Ingevity), Altasolv TM H (Ingenviz), Altasolv TM L (Ingeniev Corporation), and its mixtures.

[0271] In the embodiments, the organic solvent c) in the agricultural chemical liquid composition is selected from the group consisting of: Altasolv TM M (Ingenviz), Altasolv TM H (Ingenviz), Altasolv TM L (Ingeniev Corporation) and its mixtures.

[0272] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 5% to 95% by weight based on the total composition.

[0273] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 10% to 95% by weight based on the total composition.

[0274] In the examples, the amount of organic solvent c) in the agricultural chemical liquid composition is 15% to 95% by weight based on the total composition.

[0275] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 20% to 95% by weight based on the total composition.

[0276] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 30% to 95% by weight based on the total composition.

[0277] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 40% to 95% by weight based on the total composition.

[0278] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 50% to 95% by weight based on the total composition.

[0279] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 60% to 95% by weight based on the total composition.

[0280] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 70% to 95% by weight based on the total composition.

[0281] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 80% to 95% by weight based on the total composition.

[0282] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 85% to 95% by weight based on the total composition.

[0283] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 80% to 90% by weight based on the total composition.

[0284] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 85% to 90% by weight based on the total composition.

[0285] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 5% to 10% by weight based on the total composition.

[0286] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 10% to 20% by weight based on the total weight of the composition.

[0287] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 20% to 30% by weight based on the total composition.

[0288] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 30% to 40% by weight based on the total composition.

[0289] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 40% to 50% by weight based on the total composition.

[0290] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 50% to 60% by weight based on the total composition.

[0291] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 60% to 70% by weight based on the total composition.

[0292] In the embodiments, the amount of organic solvent c) in the agricultural chemical liquid composition is 70% to 80% by weight based on the total composition.

[0293] In the embodiments, the nonionic surfactant d) in the agricultural chemical liquid composition is selected from EO-PO-block copolymers, C4-C18 alcohol alkoxylates, fatty acid alkoxylates, vegetable oil alkoxylates, aryl alkoxylates, alkylaryl alkoxylates, and mixtures thereof.

[0294] In the embodiments, the amount of nonionic surfactant d) in the agricultural chemical liquid composition is 0.5% to 10% by weight based on the total composition.

[0295] In the embodiments, the amount of nonionic surfactant d) in the agricultural chemical liquid composition is 0.5% to 5% by weight based on the total weight of the composition.

[0296] In the embodiments, the amount of nonionic surfactant d) in the agricultural chemical liquid composition is 4% to 5% by weight based on the total weight of the composition.

[0297] In some embodiments, the amount of nonionic surfactant d) in the agricultural chemical liquid composition is 3% to 5% by weight based on the total weight of the composition.

[0298] In some embodiments, the amount of nonionic surfactant d) in the agricultural chemical liquid composition is 2% to 5% by weight based on the total weight of the composition.

[0299] In some embodiments, the amount of nonionic surfactant d) in the agricultural chemical liquid composition is 4% to 4.5% by weight based on the total weight of the composition.

[0300] In some embodiments, the amount of nonionic surfactant d) in the agricultural chemical liquid composition is 4.2% by weight based on the total weight of the composition.

[0301] In the embodiments, the anionic surfactant e) in the agricultural chemical liquid composition is selected from naphthalene sulfonate, alkyl naphthalene sulfonate, benzene sulfonate, alkyl benzene sulfonate, C4-C18 alcohol ethoxylated phosphate, C4-C16 alkyl phosphate, sodium sulfosuccinate C1-C8 alkyl ester, sodium sulfosuccinate C1-C8 dialkyl ester, and mixtures thereof.

[0302] In the embodiments, the anionic surfactant e) in the agricultural chemical liquid composition is selected from naphthalene sulfonates, alkyl naphthalene sulfonates, benzene sulfonates, alkyl benzene sulfonates, and mixtures thereof.

[0303] In the examples, the anionic surfactant e) in the agricultural chemical liquid composition is selected from C4-C18 alcohol ethoxylated phosphates, C4-C16 alkyl phosphates, and mixtures thereof.

[0304] In the examples, the anionic surfactant e) in the agricultural chemical liquid composition is selected from sodium sulfosuccinate C1-C8 alkyl ester, sodium sulfosuccinate C1-C8 dialkyl ester, and mixtures thereof.

[0305] In the embodiments, the amount of anionic surfactant e) in the agricultural chemical liquid is 0.5% to 10% by weight based on the total composition.

[0306] In the embodiments, the amount of anionic surfactant e) in the agricultural chemical liquid composition is 0.5% to 5% by weight based on the total weight of the composition.

[0307] In the embodiments, the amount of anionic surfactant e) in the agricultural chemical liquid composition is 4% to 5% by weight based on the total weight of the composition.

[0308] In some embodiments, the amount of anionic surfactant e) in the agricultural chemical liquid composition is 3% to 5% by weight based on the total composition.

[0309] In some embodiments, the amount of anionic surfactant e) in the agricultural chemical liquid composition is 2% to 5% by weight based on the total composition.

[0310] In some embodiments, the amount of anionic surfactant e) in the agricultural chemical liquid composition is 4% to 4.5% by weight based on the total weight of the composition.

[0311] In some embodiments, the amount of anionic surfactant e) in the agricultural chemical liquid composition is 4.2% by weight based on the total weight of the composition.

[0312] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is from 5:1 to 1:20.

[0313] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 4:1 to 1:20.

[0314] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is from 3:1 to 1:20.

[0315] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 2:1 to 1:20.

[0316] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is from 1:1 to 1:20.

[0317] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 5:1 to 1:10.

[0318] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is from 4:1 to 1:10.

[0319] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 3:1 to 1:10.

[0320] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 2:1 to 1:10.

[0321] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:1 to 1:10.

[0322] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is from 5:1 to 1:4.

[0323] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is from 4:1 to 1:4.

[0324] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 3:1 to 1:4.

[0325] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 2:1 to 1:4.

[0326] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:1 to 1:4.

[0327] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 5:1 to 1:2.

[0328] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 4:1 to 1:2.

[0329] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 3:1 to 1:2.

[0330] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 2:1 to 1:2.

[0331] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:1 to 1:2.

[0332] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 5:1 to 3:4.

[0333] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 4:1 to 3:4.

[0334] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 3:1 to 3:4.

[0335] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 2:1 to 3:4.

[0336] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 1:1 to 3:4.

[0337] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 5:1 to 1:1.

[0338] In the embodiments, the ratio of stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 4:1 to 1:1.

[0339] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 3:1 to 1:1.

[0340] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 2:1 to 1:1.

[0341] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 1:1 to 1:1.

[0342] In the embodiments, the ratio between stabilizer b) and pest control agent a) in the agricultural chemical liquid composition is 6:5 to 3:2.

[0343] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:500 to 500:1.

[0344] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:400 to 400:1.

[0345] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:300 to 300:1.

[0346] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:200 to 200:1.

[0347] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is from 1:100 to 100:1.

[0348] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:50 to 50:1.

[0349] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:20 to 20:1.

[0350] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:10 to 10:1.

[0351] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:5 to 5:1.

[0352] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:4 to 4:1.

[0353] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:3 to 3:1.

[0354] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:2 to 2:1.

[0355] In the embodiments, the ratio of photoprotectant in stabilizer b) to pest control agent a) in the agricultural chemical liquid composition is 1:2 to 1:1.

[0356] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest control agent a) in the agricultural chemical liquid composition is 1:500 to 500:1.

[0357] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest control agent a) in the agricultural chemical liquid composition is 1:400 to 400:1.

[0358] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest control agent a) in the agricultural chemical liquid composition is 1:300 to 300:1.

[0359] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest control agent a) in the agricultural chemical liquid composition is 1:200 to 200:1.

[0360] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest control agent a) in the agricultural chemical liquid composition is from 1:100 to 100:1.

[0361] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest control agent a) in the agricultural chemical liquid composition is 1:50 to 50:1.

[0362] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest control agent a) in the agricultural chemical liquid composition is 1:20 to 20:1.

[0363] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest control agent a) in the agricultural chemical liquid composition is 1:10 to 10:1.

[0364] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest killer a) in the agricultural chemical liquid composition is 1:5 to 5:1.

[0365] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest killer a) in the agricultural chemical liquid composition is 1:4 to 4:1.

[0366] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest killer a) in the agricultural chemical liquid composition is 1:3 to 3:1.

[0367] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest killer a) in the agricultural chemical liquid composition is 1:2 to 2:1.

[0368] In the embodiments, the ratio of the heat protectant in stabilizer b) to the pest killer a) in the agricultural chemical liquid composition is 1:2 to 1:1.

[0369] In the embodiments, the weight ratio between nonionic surfactant d) and anionic surfactant e) in the agricultural chemical liquid composition is 1:5 to 5:1.

[0370] In some embodiments, the weight ratio of nonionic surfactant d) to anionic surfactant e) in the agricultural chemical liquid composition is 1:4 to 4:1.

[0371] In the embodiments, the weight ratio between nonionic surfactant d) and anionic surfactant e) in the agricultural chemical liquid composition is 1:3 to 4:1.

[0372] In the embodiments, the weight ratio between nonionic surfactant d) and anionic surfactant e) in the agricultural chemical liquid composition is 1:2 to 2:1.

[0373] In the embodiments, the weight ratio between nonionic surfactant d) and anionic surfactant e) in the agricultural chemical liquid composition is 1:1 to 1:1.

[0374] In the embodiments, the weight ratio of nonionic surfactant d) to anionic surfactant e) in the agricultural chemical liquid composition is 1:1.

[0375] In the embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is 1:50 to 5:1.

[0376] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is from 1:50 to 4:1.

[0377] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is from 1:50 to 3:1.

[0378] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is 1:50 to 2:1.

[0379] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is 1:20 to 2:1.

[0380] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is 1:10 to 2:1.

[0381] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is 1:5 to 2:1.

[0382] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is 1:10 to 2:1.

[0383] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is 2:5 to 2:1.

[0384] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is 1:1 to 2:1.

[0385] In some embodiments, the weight ratio between the nonionic surfactant d) and the pest control agent a) in the agricultural chemical liquid composition is 2:1 to 5:2.

[0386] In some embodiments, the weight ratio of nonionic surfactant d) to pest control agent a) in the agricultural chemical liquid composition is 2:1.

[0387] In the embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 1:50 to 5:1.

[0388] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 1:50 to 4:1.

[0389] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is from 1:50 to 3:1.

[0390] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 1:50 to 2:1.

[0391] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 1:20 to 2:1.

[0392] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 1:10 to 2:1.

[0393] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 1:5 to 2:1.

[0394] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 1:10 to 2:1.

[0395] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 2:5 to 2:1.

[0396] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 1:1 to 2:1.

[0397] In some embodiments, the weight ratio between the anionic surfactant e) and the pest control agent a) in the agricultural chemical liquid composition is 2:1 to 5:2.

[0398] In some embodiments, the weight ratio of anionic surfactant e) to pest control agent a) in the agricultural chemical liquid composition is 2:1.

[0399] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:20 to 5:1.

[0400] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is from 1:20 to 4:1.

[0401] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:20 to 3:1.

[0402] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:20 to 2:1.

[0403] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:20 to 1:1.

[0404] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:10 to 5:1.

[0405] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is from 1:10 to 4:1.

[0406] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is from 1:10 to 3:1.

[0407] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:10 to 2:1.

[0408] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:10 to 1:1.

[0409] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:2 to 5:1.

[0410] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:2 to 4:1.

[0411] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:2 to 3:1.

[0412] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:2 to 2:1.

[0413] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:2 to 1:1.

[0414] In some embodiments, the weight ratio between solvent c) and pest control agent a) in the agricultural chemical liquid composition is 1:1.

[0415] In embodiments, the present invention provides the use of a synergistic combination of heat protectants and photoprotectants for stabilizing agricultural chemical compositions comprising at least one insecticide, fungicide, herbicide, or mixture thereof.

[0416] In embodiments, the present invention provides the use of a synergistic combination of thermal and photoprotective agents as disclosed herein for stabilizing agricultural chemical liquid compositions as disclosed herein.

[0417] The following examples are provided to prevent a more complete understanding of the subject matter of the invention. The examples illustrate exemplary modes of making and practicing the invention. However, the scope of the invention is not limited to the specific embodiments disclosed in these examples, which are for illustrative purposes only. Clearly, other examples will be constructed by those skilled in the art by considering the embodiments and examples in the specification. Example

[0418] Example 1: The performance of pure emulsion concentrate compositions containing 2.11% (w / w) emamectin benzoate and various light and / or heat protectants, prepared according to Table 1, was evaluated. The pure emulsion concentrate samples were not diluted in water prior to testing.

[0419] Table 1. Emulsion concentrates containing different light and / or heat protectants:

[0420]

[0421] Active ingredients It is emamectin benzoate or spinosad.

[0422] Emamectin benzoate is commercially available or can be prepared as disclosed by Trefzer A et al., Appl. Environ. Microbiol. [Applied and Environmental Microbiology] 2007;73: 4317-4325.

[0423] Spinosad is commercially available or can be prepared as disclosed in US 5,362,634 and US 5,496,931.

[0424] The following compositions were prepared as representative examples from the general table 1:

[0425] Example 1A: Emamectin Benzoate 2.11% w / w emulsion concentrate

[0426]

[0427] Example 1B: Spinosad 2.11% w / w emulsion concentrate

[0428]

[0429] Photodegradation measurement:

[0430] Samples (20 g) of emamectin emulsion concentrates containing different photoprotectants or heat protectants, prepared according to Table 1, were inserted into 40 mL glass vials. The sealed vials were placed in a circular position within a UVACUBE 400 UV chamber (Hönle - UV technology) equipped with an S-lamp (daylight simulation). The samples were exposed to light for 6 h, and the concentration of emamectin benzoate after exposure was determined using HPLC. For each experiment, samples from the same batch were kept in darkness and tested for comparison.

[0431] Thermal degradation measurement:

[0432] Samples (15 g) of emamectin emulsion concentrates containing different photoprotective or heat-protective agents, prepared according to Table 1, were inserted into 20 mL sealed glass vials. The vials were kept in an oven at a constant temperature of 54°C for 14 days. The concentration of emamectin benzoate after 14 days was determined using HPLC. For each experiment, samples from the same batch were kept at room temperature and tested for comparison.

[0433] For all samples, the degradation of the sensitive active ingredient (emamectin benzoate) concentration was calculated according to the following equation:

[0434]

[0435] C0 - is the concentration of emamectin benzoate after 6 hours in the dark (for photodegradation) or the concentration of emamectin benzoate after 14 days at room temperature (for thermal degradation).

[0436] Cf - is the final concentration of emamectin benzoate after exposure to heat or light degradation.

[0437] The results are summarized in Table 2.

[0438] Table 2: Photodegradation of emamectin benzoate (2.11% w / w) emulsion concentrate prepared according to Table 1.

[0439]

[0440] The results show that, compared to degradation obtained without any photoprotective agents, for Tinuvin... ® 328. Tinuvin ® 1130, Tinuvin ® 405, Tinuvin ® 5050 and Tinuvin ®460, the photodegradation factors of emamectin benzoate decreased by 3.64, 3.64, 3.0, 3.21, and 3.94, respectively, confirming that the photodegradation of emamectin benzoate was not reduced in samples containing only heat protectants. The photodegradation reduction factors were calculated as follows:

[0441] Photodegradation reduction factor = Degradation of emamectin benzoate after 6 hours of exposure to sunlight without photoprotective agents (in percentage) / Degradation of emamectin benzoate after 6 hours of exposure to sunlight with photoprotective agents (in percentage).

[0442] Compared to degradation obtained without any heat-protecting agents, for Irganox ® B225, Irganox ® PS 800 FL and Irgafos ® The thermal degradation of 168 emamectin benzoate decreased by factors of 3.98, 2.75 and 9.32, respectively, indicating that the thermal degradation of emamectin benzoate was not reduced in samples containing only photoprotectants.

[0443] The thermal degradation factor is calculated as follows:

[0444] Thermal degradation factor = Degradation of emamectin benzoate after 14 days at 54°C without heat protectant (in %) / Degradation of emamectin benzoate after 14 days at 54°C with heat protectant (in %).

[0445] Example 2: Using Tinuvin ® 328, as a photoprotectant, is diluted in water to a 10% (w / w) concentration of 2.11% w / w benzene. Photodegradation of emamectin formate emulsion concentrate.

[0446] For emamectin benzoate emulsion concentrate diluted in water to 10% (w / w), the same procedure described above in Example 1 was used for Tinuvin. ® The performance of 328 as a photoprotectant was evaluated and summarized in Table 3. Each measurement was taken as the average of 5 replicates (1A-1E) and (2A-2E).

[0447] Table 3. Using Tinuvin ® 328, as a photoprotectant, is diluted in water to a 10% (w / w) concentration of 2.11% w / w benzene. Photodegradation of acid emamectin emulsion concentrate.

[0448]

[0449] As shown in Table 3 above, for 10% (w / w) emmamycin benzoate emulsion concentrate diluted in water, 1% Tinuvin 328 reduced the photodegradation of emmamycin benzoate by a factor of 4.38 compared to degradation obtained without any photoprotective agent.

[0450] Example 3. Contains Tinuvin ® 328 and Irgafos ® 168 of the combination of 2.11% w / w emarginine emulsion Photodegradation and thermal degradation of liquid concentrate (in sealed glass vials).

[0451] Tinuvin-containing products prepared according to Table 1 were prepared. ® 328 (photoprotectant) and Irgafos ® Various combinations of 2.11% w / w emamectin benzoate (168, heat protectant) were studied, and the effects of the presence of both photoprotectants and heat protectants on photodegradation and thermal degradation were tested and summarized in Table 4. Thermal degradation of a pure emulsion concentrate of 2.11% w / w emamectin benzoate and photodegradation of a 2.11% w / w emamectin benzoate emulsion concentrate diluted in water to 10% (w / w) were tested.

[0452] Table 4. Tinuvin ® 328 (photoprotectant) and Irgafos ® Different combinations of 168 (heat protectant) and terebenzoic acid The effects of light and heat degradation of emamectin.

[0453]

[0454] As shown above, compared to the degradation obtained without the combination of the photoprotectant and the heat protectant, Tinuvin... ® 328 and Irgafos ® The presence of both 168 and 168 resulted in an unexpectedly high reduction factor for photodegradation and thermal degradation of emamectin benzoate.

[0455] Calculate the photodegradation factor and thermal degradation factor based on Example 1.

[0456] Example 4. Tinuvin ® 328 and Irgafos ® Combination 168 (6 hours of sunlight exposure) for emamectin benzoate The synergistic effect.

[0457] Following the procedure described in Example 1, the photodegradation of 2.11% w / w emulsion concentrate of emamectin benzoate, prepared according to Table 1 and diluted in water to a 10% (w / w) emulsion, was evaluated after 6 hours of exposure to sunlight. Table 5 summarizes the results of this study. The photodegradation factor was calculated according to Example 1.

[0458] Table 5. Tinuvin ® 328 and Irgafos ® Combination 168 (6 hours of sunlight exposure) for emamectin benzoate Synergistic effect

[0459]

[0460] Example 5. Tinuvin ® 328 and Irgafos ® Combination 168 (24-hour sunlight exposure) for E. benzoic acid Synergistic effect of elements

[0461] Following the procedure described in Example 1, the photodegradation of 2.11% w / w emulsion concentrate of emamectin benzoate, prepared according to Table 1 and diluted in water to a 10% (w / w) emulsion, was evaluated after exposure to sunlight for 24 hours. Table 6 summarizes the results of this study. The photodegradation factor was calculated according to Example 1.

[0462] Table 6. Tinuvin ® 328 and Irgafos ® Synergistic effect of combination 168 on emamectin benzoate (24 hours) Sun exposure)

[0463]

[0464] Example 6. Tinuvin ® 328 and Irgafos ® Synergistic effect of combination 168 on spinosad (24-hour sunlight) (exposure)

[0465] The photodegradation of spinosad 2.11% w / w emulsion concentrate, prepared according to Table 1 and diluted in water to a 10% (w / w) emulsion, was evaluated after exposure to sunlight for 24 hours, following the procedure described in Example 1. Table 7 summarizes the results of this study. The photodegradation factor was calculated according to Example 1.

[0466] Table 7. Tinuvin ® 328 and Irgafos ® Synergistic effect of combination 168 on spinosad (24-hour sunlight exposure) dew)

[0467]

[0468] Example 7. Tinuvin in a dry sample ® 328 and Irgafos ® Combination 168 for emamectin benzoate (6 (hours of sunlight exposure)

[0469] All photodegradation experiments, denoted as Examples 1-6, were conducted using 20 g of the emulsion or pure formulation as described above in glass vials. To simulate photodegradation occurring on the leaves of treated plants, the following setup was established.

[0470] A sample of 2 g of 2.11% w / w emulsion concentrate of emamectin benzoate, prepared according to Table 1 and diluted in water to a 10% (w / w) emulsion, was placed in a 100 mL glass beaker. The beaker was placed in a circular position in a UV chamber UVACUBE 400 (Heraeste UV Technologies) equipped with an S-lamp (sunlight simulation). The emulsion sample was completely dried, resulting in a thin film at the bottom of the beaker. The sample was exposed to sunlight for 6 hours, and the emamectin benzoate content of the film at the bottom of the beaker was extracted with acetonitrile.

[0471] The amount of emamectin benzoate (m) after exposure to sunlight was determined using HPLC. f [mg]. For each experimental group, samples from the same batch kept in the dark were also tested to determine the amount of emamectin benzoate (m0) in the absence of light exposure. The photodegradation factor was calculated according to Example 1.

[0472] For all tested samples, the photodegradation % was calculated according to the following equation:

[0473]

[0474] Table 8 below summarizes the results of Example 7.

[0475] Table 8. The combination of Tinuvin 328 and Irgafos 168 in dried samples for emamectin benzoate (6 hours) Sun exposure)

[0476]

[0477] As indicated above, Tinuvin ® 328 and Irgafos ® The combination of 168 (photoprotectant and thermal protectant) showed improved photoprotection, including liquid and dry samples, where a synergistic effect was observed for a certain ratio of photoprotectant and thermal protectant.

[0478] Example 8. Tinosorb ® S and Irgafos ® Combination 168 (24-hour sunlight exposure) for emamectin benzoate Synergistic effect

[0479] The following compositions 8A-8D, summarized in Table 9, are representative examples of those in General Table 1:

[0480] Table 9: Emulsion concentrate of 2.11% w / w emulsion of emamectin benzoate with Tinosorb S as a photoprotectant

[0481]

[0482] In this experiment, Irgafos was evaluated. ® 168 and Tinosorb ® Synergistic effect of S (bis-ethylhexyloxyphenol methoxyphenyl triazine).

[0483] Following the procedure described in Example 1, the photodegradation of emamectin benzoate emulsion concentrate prepared according to Table 9 and diluted in water to a 10% (w / w) emulsion was evaluated after exposure to sunlight for 24 hours. Table 10 summarizes the results of this study. The average of four replicates was taken for each measurement. The photodegradation factor was calculated as described in Example 1.

[0484] Table 10. TINOSORB ® S and Irgafos ® Synergistic effect of combination 168 on emamectin benzoate (24 hours) Sun exposure)

[0485]

[0486] As indicated above, TINOSORB ® S and Irgafos ® The combination of 168 (photoprotectant and thermal protectant) showed improved photoprotection, and a synergistic effect was observed for a certain ratio of photoprotectant and thermal protectant, which was similar to that of Tinuvin. ® 328 and Irgafos ® The synergistic effect obtained in 168 is similar. It is noted that the described phenomena are not limited to specific blends of photoprotective and thermal protective agents.

[0487] Example 9. TINOSORB ® S and Irganox ® Combination 245 (26 hours of sunlight exposure) for emamectin benzoate Synergistic effect with spinosad

[0488] Following the procedure described in Example 1, the photodegradation of emamectin benzoate and spinosad emulsion concentrates prepared according to Table 11 and diluted in water to 5% (w / w) emulsions after 26 hours of exposure to sunlight was evaluated. Table 12 summarizes the results of this study. The average of two replicates was taken for each measurement. The photodegradation factor was calculated as described in Example 1.

[0489] Table 11: Emulsion concentrates of 2% w / w emamectin benzoate and 10% spinosad

[0490]

[0491] Table 12. TINOSORB ® S and Irganox ® Combination 245 (26 hours of sunlight exposure) for emamectin benzoate Synergistic effect with spinosad

[0492]

[0493] Example 10. TINOSORB in a dried sample ® S and Irganox ® 245 combination (24-hour direct sunlight exposure) Synergistic effect of emamectin benzoate and spinosad

[0494] A sample of 2 g of emamectin benzoate and spinosad emulsion concentrate, prepared according to Table 11 and diluted in water to a 5% (w / w) emulsion, was placed in a 100 mL glass beaker. The beaker was exposed to direct sunlight for 24 h (May, southern Israel). The emulsion sample was completely dried, resulting in a film at the bottom of the beaker. After 24 h, the emamectin benzoate and spinosad content of the film at the bottom of the beaker was extracted with acetonitrile.

[0495] All the above-described photodegradation experiments, denoted as Examples 8-10, were conducted in a UV chamber, UVACUBE400 (Herabilis UV Technologies), equipped with an S-lamp (sunlight simulation). Example 10 was conducted to simulate the actual photodegradation conditions occurring on the leaf surface as closely as possible.

[0496] Table 13 summarizes the results of Example 10. The average of seven replicates for each measurement was taken. Photodegradation % (for dry samples) was calculated as described in Example 7. The photodegradation factor was calculated as described in Example 1.

[0497] Table 13. TINOSORB in dried samples ® S and Irganox ® 245 combination (24-hour direct sunlight exposure) for Synergistic effect of emamectin benzoate and spinosad

[0498]

[0499] As indicated above, for both liquid and dry samples, and for simulated or direct sunlight exposure, TINOSORB provides photoprotection compared to that obtained through the individual components themselves. ® S and Irganox ® The combination of 245 (photoprotectant and heat protectant) showed improved photoprotection. These results also reinforce the idea that the described phenomena are not limited to specific formulation compositions.

Claims

1. An agricultural chemical composition for photoprotection and heat protection, comprising: a) at least one pest control agent in an amount of 0.5% to 50% by weight based on the total composition; b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant.

2. The photoprotective and heat-protective agricultural chemical composition according to claim 1, wherein, The at least one pest control agent is selected from insecticides, fungicides, herbicides, and mixtures thereof.

3. The agricultural chemical composition for photoprotection and heat protection according to any one of claims 1 and 2, wherein, The amount of photoprotectant in stabilizer b) is 0.1% to 10% by weight based on the total composition.

4. The agricultural chemical composition for photoprotection and heat protection according to any one of claims 1-3, wherein, The amount of heat-protecting agent in stabilizer b) is 0.1% to 10% by weight based on the total composition.

5. The agricultural chemical composition for photoprotection and heat protection according to any one of claims 1-4, wherein, The ratio between stabilizer b) and pest control agent a) is 5:1 to 1:

20.

6. The agricultural chemical composition for photoprotection and heat protection according to any one of claims 1-5, wherein, The pest control agent a) is an insecticide selected from the group consisting of: abamectin, ivermectin, selamectin, epramectin, doramectin, emamectin, emamectin benzoate, deltamethrin, tetrabromocyanide, cypermethrin, α-methrin, ζ-cypermethrin, fenvalerate, cypermethrin, flufenacetate, allethrin, bifenthrin, bio-allethrin, bio-benzalofensulfuron, cypermethrin, β-cypermethrin, trifluralin, β-cypermethrin, fenfluroxyfen, fenfluroxyfen, fenfluroxyfen, cypermethrin, cypermethrin, τ-cypermethrin, fenfluroxyfen, fenfluroxyfen, benzalkonium chloride, heptafluthrin, methamidophos, λ-cypermethrin, spinosad, ethyl spinosad, spinosad A, spinosad D.

7. The agricultural chemical composition for photoprotection and heat protection according to any one of claims 1-6, wherein, The stabilizer b) comprises a photoprotectant selected from the group consisting of 2-(2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylpropyl)phenol (Tinuvin). ® 328), bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-sebacate (Tinuvin) ® 292), α-[3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]-ω-hydroxypoly(oxy-1,2-ethylenediyl) (Tinuvin) ® 1130), 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-[2-hydroxy-3-(dodecyloxy- and tridecyloxy)propoxy]phenol (Tinuvin) ® 400), 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-[3-[(2-ethylhexyl)oxy]-2-hydroxypropoxy]phenol (Tinuvin) ® 405), 2,4,6-tris[4-(1-octyloxycarbonyl)ethoxy-2-hydroxyphenyl]-1,3,5-triazine (Tinuvin) ® 477), 2-[4-[4,6-bis([1,1'-biphenyl]-4-yl)-1,3,5-triazine-2-yl]-3-hydroxyphenoxy]-isooctyl propionate (Tinuvin) ® 479), Light stabilizer 5050 (Tinuvin) ® A mixture of 1,10-bis[2,2,6,6-tetramethyl-1-(octyloxy)-4-piperidinyl] ester of sebacic acid and octyl 3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenylpropionate (Tinuvin) ® 5060), 2,2'-[6-(2,4-dibutoxyphenyl)-1,3,5-triazine-2,4-diyl]bis[5-butoxyphenol] (Tinuvin) ® 460), UV absorber - tinuvin 5151 (Tinuvin) ® 5151), triazine-based UV absorbers (Tinuvin) ® 5248), 2-ethylhexyl 3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenylpropionic acid (Tinuvin) ® 384-2), UV absorbers based on C7-9 branched and straight-chain alkyl esters of 3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenylpropionic acid (Tinuvin) ® 99-2), 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol (Tinuvin) ® 900), UV absorber based on 2,4,6-tris([1,1'-biphenyl]-4-yl)1,3,5-triazine (Tinosorb) ® A2B), a UV absorber based on 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol (Tinosorb) ® M), a UV absorber based on 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol (Tinosorb) ® M-WG), a UV absorber based on 2,2'-[6-(4-methoxyphenyl)-1,3,5-triazine-2,4-diyl]bis[5-[(2-ethylhexyl)oxy]phenol (Tinosorb) ® S), 2-[4-(diethylamino)-2-hydroxybenzoyl]hexyl benzoate (Uvinul) ® A plus), 2-ethylhexyl 3-(4-methoxyphenyl)-2-acrylate (Uvinul) ® MC 80), 4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tri-benzoic acid 1,1',1''-tris(2-ethylhexyl) ester (Uvinul) ® T 150), zinc oxide (Z-COTE) ® ), zinc oxide and triethoxyoctylsilane (Z-COTE) ® HP1 and its mixtures.

8. The agricultural chemical composition for photoprotection and heat protection according to any one of claims 1-7, wherein, The stabilizer b) comprises a heat protectant selected from the following: a blend of 50% tris(2,4-di-tert-butylphenyl) phosphite and 50% pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] (Irganox) ® B225), 1,1'-[2,2-bis[[3-[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenylpropionic acid]-1,3-propanediyl] ester of 3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropoxy]methyl]-1,3-propanediyl] ester (Irganox) ® 1010), di-dodecyl 3,3'-thiodipropionate (Irganox) ® 800FL), 1,1'-[1,2-ethylenedimethylbis(oxy-2,1-ethylenedimethyl)] ester of 3-(1,1-dimethylethyl)-4-hydroxy-5-methylphenylpropionic acid (Irganox) ® 245), octadecyl 3,5-bis(1,1-dimethylethyl)-4-hydroxyphenylpropionate (Irganox) ® 1076), Butylated hydroxytoluene (BHT), Butylated hydroxyanisole (BHA), Epoxidized alcohol (epoxidized soybean oil) 3,3'-di-dodecyl thiodipropionate (Irganox) ® PS 800 FL), 2,4-bis(1,1-dimethylethyl)phenol phosphite (3:1) (Irgafos) ® 168) and its mixtures.

9. The agricultural chemical composition for photoprotection and heat protection according to any one of claims 1-8, wherein, The weight ratio of the photoprotectant to the heat protectant is 1:5 to 5:

1.

10. An agricultural chemical liquid composition comprising: a) at least one pest control agent selected from insecticides, fungicides, herbicides, and mixtures thereof; b) a stabilizer comprising a synergistic combination of a heat protectant and a photoprotectant; c) an organic solvent; d) a nonionic surfactant; and e) an anionic surfactant.

11. The agricultural chemical liquid composition according to claim 10, wherein, The organic solvent c) is selected from the group consisting of: aromatic hydrocarbons, aliphatic hydrocarbons, alicyclic hydrocarbons, dimethyl sulfoxide (DMSO), N-methylvaleronamide, γ-butyrolactone, benzyl acetate, benzyl benzoate, butyl benzoate, 2-ethoxypropyl acetate, propylene glycol methyl ether acetate; tributyl phosphate, N,N-dimethyloctylamide, N,N-dimethyldecylamide; 2-heptanone, cyclohexanone, acetophenone, 4-methoxyacetophenone; cyclohexanol, 4-hydroxy-4-methyl-2-pentanone, n-octanol, 2-ethylhexanol, glutaric acid. Dimethyl ester, dimethyl succinate, dimethyl adipate, polyethylene glycol, glycerin, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monophenyl ether; propylene carbonate, butylene carbonate, N-butylpyrrolidone, N-octylpyrrolidone, N-ethylpyrrolidone, N-dodecylpyrrolidone, n-propyl lactate, methyl lactate, ethyl lactate, isopropyl lactate, butyl lactate, Altasolv TM M, Altasolv TM H, Altasolv TM L and its mixtures.

12. The agricultural chemical liquid composition according to any one of claims 10 and 11, wherein, The nonionic surfactant d) is selected from EO-PO-block copolymers, C4-C18 alcohol alkoxylates, fatty acid alkoxylates, vegetable oil alkoxylates, aryl alkoxylates, alkylaryl alkoxylates, and mixtures thereof.

13. The agricultural chemical liquid composition according to any one of claims 10-12, wherein, The anionic surfactant e) is selected from naphthalene sulfonate, alkyl naphthalene sulfonate, benzene sulfonate, alkyl benzene sulfonate, C4-C18 alcohol ethoxylated phosphate, C4-C16 alkyl phosphate, sodium sulfosuccinate C1-C8 alkyl ester, sodium sulfosuccinate C1-C8 dialkyl ester, and mixtures thereof.

14. The agricultural chemical liquid composition according to any one of claims 10-13, wherein, The amount of photoprotectant in stabilizer b) is 0.1% to 10% by weight based on the total composition.

15. The agricultural chemical liquid composition according to any one of claims 10-14, wherein, The amount of heat-protecting agent in stabilizer b) is 0.1% to 10% by weight based on the total composition.

16. The agricultural chemical liquid composition according to any one of claims 10-15, wherein, The ratio between stabilizer b) and pest control agent a) is 5:1 to 1:

20.

17. The agricultural chemical liquid composition according to any one of claims 10-16, wherein, The pest control agent a) is an insecticide selected from the group consisting of: abamectin, ivermectin, selamectin, epramectin, doramectin, emamectin, emamectin benzoate, deltamethrin, tetrabromocyanide, cypermethrin, α-methrin, ζ-cypermethrin, fenvalerate, cypermethrin, flufenacetate, allethrin, bifenthrin, bio-allethrin, bio-benzalofensulfuron, cypermethrin, β-cypermethrin, trifluralin, β-cypermethrin, fenfluroxyfen, fenfluroxyfen, fenfluroxyfen, cypermethrin, cypermethrin, τ-cypermethrin, fenfluroxyfen, fenfluroxyfen, benzalkonium chloride, heptafluthrin, methamidophos, λ-cypermethrin, spinosad, ethyl spinosad, spinosad A, spinosad D.

18. The agricultural chemical liquid composition according to any one of claims 10-17, wherein, The amount of organic solvent c) is 5% to 95% by weight based on the total weight of the composition.

19. The agricultural chemical liquid composition according to any one of claims 10-18, wherein, The amount of nonionic surfactant d) is 0.5% to 10% by weight based on the total composition.

20. The agricultural chemical liquid composition according to any one of claims 10-19, wherein, The amount of anionic surfactant (e) is 0.5% to 10% by weight of the total composition.

21. The agricultural chemical liquid composition according to any one of claims 10-20, wherein, The weight ratio between the nonionic surfactant d) and the anionic surfactant e) is 1:5 to 5:

1.

22. The agricultural chemical liquid composition according to any one of claims 10-21, wherein, The weight ratio between the nonionic surfactant d) and the biocidal agent a) is 1:50 to 5:

1.

23. The agricultural chemical liquid composition according to any one of claims 10-22, wherein, The weight ratio between the anionic surfactant e) and the biocidal agent a) is 1:50 to 5:

1.

24. The agricultural chemical liquid composition according to any one of claims 10-23, wherein, The amount of the pest control agent a) is 0.5% to 50% by weight based on the total composition.

25. The agricultural chemical liquid composition according to any one of claims 10-24, wherein, The pest control agent a) is an insecticide selected from the group consisting of: abamectin, ivermectin, selamectin, epramectin, doramectin, emamectin, emamectin benzoate, deltamethrin, tetrabromocyanide, cypermethrin, α-methrin, ζ-cypermethrin, fenvalerate, cypermethrin, flufenacetate, allethrin, bifenthrin, bio-allethrin, bio-benzalofensulfuron, cypermethrin, β-cypermethrin, trifluralin, β-cypermethrin, fenfluroxyfen, fenfluroxyfen, fenfluroxyfen, cypermethrin, cypermethrin, τ-cypermethrin, fenfluroxyfen, fenfluroxyfen, benzalkonium chloride, heptafluthrin, methamidophos, λ-cypermethrin, spinosad, ethyl spinosad, spinosad A, spinosad D.

26. The use of a synergistic combination of heat protectants and photoprotectants for stabilizing agricultural chemical compositions, said agricultural chemical compositions comprising at least one insecticide, fungicide, herbicide, or mixture thereof.

27. The use according to claim 26, wherein, The agricultural chemical composition is the composition according to any one of claims 1-9.

28. The use according to claim 26, wherein, The agricultural chemical composition is an agricultural chemical liquid composition according to any one of claims 10-25.

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