Gallium arsenide wafer anti-permeation protection layer capable of volatilizing at 700 DEG C and preparation method thereof

The metal-organic framework derived layer or stress mismatch-bursting desorption composite capping layer formed by organic ligands solves the problems of density and removal of the anti-permeability protective layer on the surface of gallium arsenide at high temperature in the prior art. It achieves residue-free self-evaporation and surface cleanliness in the 700℃ high temperature process, reduces production costs, and is suitable for complex patterned substrates.

CN122318894APending Publication Date: 2026-06-30JIANGSU ZHONGKE JINGYUAN INFORMATION MATERIALS CO LTD
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Patent Information

Application Number
CN202610496647.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-15
Publication Date
2026-06-30

AI Technical Summary

Technical Problem

Existing technologies cannot provide a dense anti-permeation protective layer at high temperatures, cannot remain stable in high-temperature processes at 700°C, and the removal process requires wet chemical steps, which can easily damage the gallium arsenide surface and is costly.

Method used

A metal-organic framework derived layer formed by the coordination of organic ligands with gallium atoms on the surface of gallium arsenide is transformed into a dense protective layer through thermal curing and spontaneously desorbed at 700℃. Alternatively, a composite capping layer of stress mismatch-burst desorption is used, or the arsenic capping layer is desorbed at low temperature with the assistance of hydrogen radicals, thus achieving a completely dry removal process.

Benefits of technology

It achieves residue-free self-evaporation in a 700℃ high-temperature process, resulting in a clean surface, reduced production costs, and avoids surface damage and chemical residues caused by wet etching. It is suitable for complex patterned substrates and compatible with high-throughput production.

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Abstract

The invention discloses a gallium arsenide wafer anti-permeation protective layer capable of volatilizing at 700 DEG C and a preparation method thereof, the protective layer is formed by thermocuring conversion of a metal organic framework derivative layer formed by coordination of an organic ligand and gallium atoms on the surface of gallium arsenide, and the protective layer can be self-developed to generate a gas-phase product within the temperature range of 680-720 DEG C; the residue-free removal is realized; any acid, alkali and organic solvents are not involved, and the problems of surface damage, chemical residues, lateral erosion, waste liquid pollution and the like caused by wet corrosion are thoroughly eliminated.
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