High light transmittance breathable PSF composite film and preparation method thereof

By introducing low-refractive-index PDMS and nano-titanium dioxide into the PSF film to form a refractive index gradient, the contradiction between maintaining transparency and gas exchange capacity of the PSF film was resolved, realizing the preparation of a high-transmittance and gas-permeable PSF composite film, which improves the transparency and gas flux of the film.

CN122399601APending Publication Date: 2026-07-17TIANJIN POLYTECHNIC UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
TIANJIN POLYTECHNIC UNIV
Filing Date
2026-04-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing PSF membranes, while maintaining air permeability, suffer from opacity due to light scattering, and densification processes block gas channels, making it difficult to simultaneously achieve high transparency and gas exchange capacity.

Method used

Asymmetric polysulfone-based membranes were prepared using a solvent-free phase separation method. A modified solution was formed by mixing polydimethylsiloxane, curing agent, diluent, and nano-titanium dioxide solution and coated onto the membrane surface. The refractive index gradient was adjusted by using low-refractive-index PDMS and nano-titanium dioxide to penetrate into the membrane pores and form an interpenetrating network structure.

Benefits of technology

It significantly improves the membrane's light transmittance and gas flux, maintains the membrane's transparency, preserves its gas exchange capacity, enhances the membrane's tensile strength and flexibility, and prevents liquid water wetting and penetration.

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Abstract

本发明提供了一种高透光率透气PSF复合膜及其制备方法,包括如下步骤:采用非溶剂致相分离法制备得到具有非对称结构的聚砜基膜;将聚二甲基硅氧烷、固化剂、稀释剂与纳米二氧化钛溶液进行混合,得到具有渗透性的光学改性液;将所述的光学改性液均匀涂覆于所述的聚砜基膜的支撑层一侧,静置后进行固化处理,得到所述的高透光率透气PSF复合膜。本发明所述的高透光率透气PSF复合膜利用PDMS填充PSF膜的多孔支撑层,消除了膜内部主要的散射中心,改性后的膜在400‑700nm可见光波段透射率较原膜提高50%以上。
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