Highly flame retardant wood frame, shaped composite phase change material and preparation method thereof

By synergistically treating wood with P-DES impregnation and thermal modification, covalent bonds and a dense carbon layer are formed, which are then loaded with phase change materials. This solves the problems of single flame retardant mechanism, destruction of pore structure and insufficient durability in existing technologies, and achieves synergy between high-efficiency flame retardancy and energy storage, making it suitable for building materials.

CN122401583APending Publication Date: 2026-07-17KUNMING UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
KUNMING UNIV OF SCI & TECH
Filing Date
2026-04-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing DES-modified wood technology suffers from problems such as a single flame retardant mechanism, damage to pore structure, insufficient durability, and limited functionality, making it difficult to achieve synergy between efficient flame retardancy and energy storage. Furthermore, traditional flame retardants present environmental issues.

Method used

Wood was impregnated and thermally modified using phosphorylcholine chloride eutectic solvent (P-DES). Covalent bonds were formed by the reaction of phosphoric acid with cellulose hydroxyl groups, which promoted lignin rearrangement and the formation of a dense carbon layer, achieving dual flame retardancy in both the condensed phase and gas phase. Shaped composite phase change materials were prepared by loading polyethylene glycol and graphene oxide.

Benefits of technology

It achieves a synergistic effect of high flame retardancy and high energy storage performance, improves the flame retardancy efficiency of the material, retains porosity, and the modification process is green and pollution-free, making it suitable for the field of building materials.

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Abstract

本发明公开一种高阻燃木材框架、定型复合相变材料及其制备方法。将磷酸和氯化胆碱按照配比制备氯化磷酰胆碱浸渍液,将清洗后的木材置于其中浸泡,通过高温热改性,洗涤、干燥,制得高阻燃木材框架,将该高阻燃木材框架真空浸渍于聚乙二醇和氧化石墨烯配制的复合相变材料中,制得定型复合相变材料。本发明有益效果如下:所用的设备简单、工艺简单、试剂绿色无毒害,所制备的改性高阻燃木材框架拓宽了孔隙结构,提高了阻燃性能,所制备的复合相变材料提高了光热转化性能以及阻燃性能,扩大了木材在建筑领域的应用范围,具有规模化生产前景。
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