A bi-directional conversion method based on biogas

By employing a two-way biogas-based method of biogas conversion, and utilizing the combination of metal-supported nanocatalysts and regenerated gas, the problems of catalyst deactivation and low CNT purity were solved. This enabled in-situ catalyst regeneration and the preparation of high-purity CNTs, reducing process time and costs.

CN122403430APending Publication Date: 2026-07-17HUBEI TIANJI BIOENERGY CO LTD
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Patent Information

Application Number
CN202610721241.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing methane catalytic cracking processes, the catalyst deactivates rapidly and the CNT purity is low. The catalyst regeneration and CNT purification processes are separated, resulting in extended process time and increased costs.

Method used

A two-way conversion method based on biogas is adopted, which combines metal-supported nanocatalysts with periodically introduced regeneration gas to achieve in-situ regeneration of catalysts and purification of CNTs. The process includes steps such as impurity removal, concentration, cracking, regeneration and activation. The regeneration gas is used to selectively gasify amorphous carbon, release catalytic active sites and retain highly crystalline CNTs.

Benefits of technology

This approach enables efficient catalyst regeneration and high-purity CNT preparation, significantly improving product purity and reducing process time and costs.

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Abstract

本申请提供了一种基于沼气的双向转化方法,包括:得到浓缩沼气;之后将反应气体通入流化床反应器内,在金属负载纳米催化剂的作用下,进行裂解反应和原位碳纳米管生成反应,其中,反应气体中含有浓缩沼气;然后停止反应气体的通入,将再生气体通入流化床反应器内,对金属负载纳米催化剂进行再生处理;之后停止再生气体通入,将活化气体通入流化床反应器内,对金属负载纳米催化剂进行活化处理;停止活化气体通入,重复循环上述过程;将重复循环后得到的催化剂进行碳纳米管分离处理,得到碳纳米管产物;循环上述过程中,将产生的尾气从流化床反应器顶部排出,对尾气进行纯化处理,得到纯化H2产品,该方法兼顾催化剂再生以及获得高纯度CNT。
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