Cathode electrode for purifying nitrate wastewater to produce ammonia and electrochemical device

By using a proton exchange membrane electrolysis device and a Cu-WO3 electrode, the problem of directly converting natural nitrate waste liquid into ammonia has been solved, achieving high-efficiency ammonia production and high energy conversion efficiency, thus avoiding the shortcomings of traditional methods.

CN122403585APending Publication Date: 2026-07-17CHANGSHU INSTITUTE OF TECHNOLOGY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHANGSHU INSTITUTE OF TECHNOLOGY
Filing Date
2026-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to efficiently convert nitrate wastewater with natural neutral pH and low ionic strength into ammonia. Furthermore, traditional methods require additional dealkalization treatment, resulting in high processing costs and the potential for OH- alkalization.

Method used

A proton exchange membrane electrolysis device is used, which provides H+ through a dilute acid anode and carries out the nitrate reduction to ammonia reaction in the Cu-WO3 cathode electrode layer. The Cu-WO3 electrode is formed by combining the acidic oxide WO3 support and highly catalytically active Cu atoms, which avoids excessive local acidity at the cathode and realizes the direct conversion of nitrate waste liquid into ammonia.

Benefits of technology

It achieves efficient ammonia production without changing the pH and ionic strength of the waste liquid. The hydrogen evolution reaction is inert, which improves energy conversion efficiency, avoids additional acid and alkali treatment steps, and does not produce hydrogen as a byproduct.

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Abstract

本发明涉及污水处理技术领域,特别涉及一种净化硝酸盐污水制氨的阴极电极,由如下方法制得:采用水热法在钛毡上原位生长WO3·xH2O前驱体,再将该电极置于铜离子溶液中吸附Cu2+,烘干后置于马弗炉中煅烧成CuOx / Cu‑WO3电极,最后将该电极置于稀硝酸中浸泡,形成Cu‑WO3电极;电化学装置包括前述阴极电极、阳极电极、导电双极板和护板,阳极电极中阳极催化剂采用质子交换膜上喷涂商业IrO2、阳极气体扩散层电极采用钛毡;阴阳极之间采用质子交换膜间隔,阳极循环通入稀酸,阴极循环通入硝酸盐污水。本装置能够实现硝酸盐的净化,并具有较高的制氨性能和惰性的氢气析出副反应性能,因此能量转换效率高。
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