A polyamide acid, a method for producing the same, a liquid crystal aligning agent, a liquid crystal aligning film, and a liquid crystal display element

By controlling the reaction of dianhydride monomers through a stepwise feeding method, no free anhydride residue is left in the polyamic acid, which solves the problems of storage stability and liquid crystal contamination, improves the voltage retention rate of liquid crystal display elements and reduces image residue, making it suitable for high-resolution liquid crystal display panels.

CN122404705APending Publication Date: 2026-07-17SHENZHEN CAPCHEM TECH CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHENZHEN CAPCHEM TECH CO LTD
Filing Date
2026-06-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the prior art, the residue of free anhydride leads to poor storage stability of polyamic acid, serious liquid crystal contamination, and film defects, and it is difficult to completely eliminate and precisely control the polymer structure and properties through existing methods.

Method used

A stepwise feeding method is adopted. First, the low-reactivity dianhydride monomer G1 reacts with the diamine to ensure complete consumption. Then, the high-reactivity dianhydride monomer G2 is added to control the excess of diamine and ensure that all dianhydride monomers participate in the reaction to form amino-terminated polyamic acid, thus avoiding the residue of free anhydride.

Benefits of technology

It achieves high storage stability of polyamic acid, reduces liquid crystal contamination, improves the voltage retention rate of liquid crystal display elements, and reduces image retention, making it suitable for high-resolution, high-refresh-rate liquid crystal display panels.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明涉及液晶取向剂技术领域,具体涉及一种聚酰胺酸及其制备方法、液晶取向剂、液晶取向膜、液晶显示元件。本发明的聚酰胺酸的制备方法包括:在氮气保护下,将二胺单体A、二胺单体B溶解在有机溶剂中,添加二酐单体G1并持续搅拌,再添加二酐单体G2并搅拌,即得;二胺单体A和二胺单体B的总摩尔量与二酐单体G1和二酐单体G2的总摩尔量的比值大于1;二酐单体G1的反应活性小于二酐单体G2的反应活性。本发明确保所有二酐单体被完全消耗,从根本上解决了因游离酸酐导致的取向剂储存稳定性差和液晶污染的问题;并通过调控二酐添加顺序,对取向剂聚合物链结构的精准设计,实现了兼顾液晶取向剂“力学性能”与“界面功能”的技术效果。
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