High-transmittance anti-erosion wear-resistant functional gradient coating and preparation process thereof

By preparing a Ti-Ta2O5 transition underlayer, a Ti-Ta2O5-N composition gradient intermediate layer, and a Ti-Ta2O5-N nanocomposite surface layer on a glass substrate, high light transmittance and erosion and wear resistance of glass-based transparent materials under erosion and friction environments were achieved. This solved the problem of easy peeling of coatings in existing technologies and achieved a balance between high light transmittance and high erosion resistance.

CN122406170APending Publication Date: 2026-07-17LUOYANG INST OF SCI & TECH
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
LUOYANG INST OF SCI & TECH
Filing Date
2026-06-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing glass-based transparent materials suffer a significant decrease in light transmittance during use due to the impact and friction of hard particles. Furthermore, traditional coatings are prone to peeling under stress concentration, making it difficult to achieve both high light transmittance and erosion and wear resistance.

Method used

Employing a functional gradient design, the coating consists of a Ti-Ta2O5 transition layer, a Ti-Ta2O5-N composition gradient intermediate layer, and a Ti-Ta2O5-N nanocomposite surface layer, arranged sequentially from the glass substrate outwards. The gradient transition of composition and performance is achieved by dynamically controlling the nitrogen flow rate, thus avoiding interfacial stress concentration.

Benefits of technology

The coating exhibits a light transmittance loss rate of less than 10% after erosion, a bonding strength of up to 30.2N, a microhardness of 17.5GPa, and excellent wear resistance. It solves the problem of traditional coatings being prone to peeling under stress concentration, achieving a balance between high light transmittance and high erosion resistance.

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Abstract

本发明公开了一种高透光抗冲蚀耐磨功能梯度涂层及其制备工艺,属于涂层制备技术领域。该涂层沉积于玻璃基底上,由内至外依次包括:不含氮的Ti‑Ta2O5过渡底层、氮含量连续增加的Ti‑Ta2O5‑N成分梯度中间层和氮含量稳定的Ti‑Ta2O5‑N纳米复合表层。本发明通过磁控溅射技术动态控制N2流量,在同一沉积过程中依次形成三层结构。该涂层利用过渡底层实现与玻璃基底的高结合力,利用梯度中间层消除界面应力并缓冲冲击能量,利用纳米复合表层提供高硬度和优异耐磨性。测试结果表明,本发明涂层的结合力达30.2N,冲蚀后透光率损失率低至6.5%,最小磨痕宽度仅78μm,综合性能显著优于现有涂层,适用于光伏玻璃盖板、汽车玻璃等透明基体的防护。
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