Copper-based catalysts suitable for use in acidic media, processes for their preparation and use

CN122406302APending Publication Date: 2026-07-17CHONGQING UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHONGQING UNIV
Filing Date
2026-05-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing copper-based catalysts exhibit a dominant hydrogen evolution reaction in acidic media, resulting in decreased selectivity for multi-carbon products and poor catalytic stability, making it difficult to maintain high selectivity and stability at industrial-grade current densities.

Method used

A copper-based catalyst with a core-shell structure is used, in which a copper oxide core is coated with a polymer layer and formed through in-situ polymerization. This process regulates the electronic structure and interfacial microenvironment, thereby suppressing hydrogen evolution side reactions.

Benefits of technology

It achieves high stability and high selectivity in acidic media, with a multi-carbon product selectivity of 77.8%, and is suitable for industrial-grade current densities.

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Abstract

本发明公开了一种适用于酸性介质的铜基催化剂,其为具有核壳结构的复合颗粒,包括氧化铜内核,包覆于核外的高分子聚合物层,其中高分子聚合物能够有效保护酸性介质中铜的活性位点的稳定性,同时还能够调控反应界面的氢键强度。本发明所提供的适用于酸性介质的铜基催化剂在电催化二氧化碳还原制备多碳产物中的应用,外层包覆有聚吡咯且富含有氧化空位的铜纳米片在反应体系中调控催化剂的电子结构与界面微环境,具体为聚吡咯层改变了表面浸润性降低了表面质子可及性,且重构了界面水分子氢键网络,在抑制析氢副反应。本发明催化剂在强酸电解质中具备高稳定性,可实现77.8%的多碳产物选择性。
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