A pressure bonding, reaction bonding adhesive and pressure bonding and paving anti-sticking waterproof board

Abstract

This invention relates to a pressure-bonded, reactive adhesive, and a pressure-bonded, reverse-adhesive waterproof membrane. The pressure-bonded membrane comprises: a first strip (1), which is composed of a first base plate (11) and a plurality of hooks (12) disposed on one side surface of the first base plate (11); and a second strip (2), which is composed of a second base plate (21) and a plurality of lifting holes (22) disposed on one side surface of the second base plate (21); wherein the hooks (12) and the lifting holes (22) are interlocking and separable. The pressure-bonded, reverse-adhesive waterproof membrane of this application comprises a pressure-bonded, composite waterproof membrane and a reactive adhesive for connecting the pressure-bonded membrane and the waterproof membrane together. The waterproof membrane of this invention has superior waterproof performance and significantly enhanced tensile and compressive strength.

Description

Technical Field

[0001] This invention relates to the field of building materials technology, and in particular to a waterproof membrane system for tunnels and underground engineering projects. Specifically, it relates to a pressure-bonded, reactive adhesive, and pressure-bonded reverse-adhesive waterproof membrane. Background Technology

[0002] During the construction of underground projects such as railway and highway tunnels, groundwater often seeps out. The hazards caused by tunnel water leakage include:

[0003] (1) Deterioration of the tunnel environment and impact on train safety. Long-term water leakage in tunnels, or even water inrush, can lead to lining cracks, tunnel floor collapse, paving or invert breakage, and mud pumping in the track bed, directly deteriorating the train operating environment. On electrified railways, water leakage in the tunnel arch can cause short circuits, tripping and discharge of power supply lines, affecting the normal operation of trains and endangering the safety of maintenance personnel.

[0004] (2) Reduce the service life of equipment in the tunnel and increase maintenance costs. Water leakage in the tunnel keeps the tunnel in a high humidity environment for a long time, which can accelerate the corrosion of rails, fasteners and other equipment, and greatly reduce their service life.

[0005] (3) It causes ground subsidence and affects the surrounding environment. For example, karst subsidence in Sichuan is mainly distributed in the karst mountains around the basin. In Chongqing, the completion of railway tunnels has caused regional groundwater depletion, which has induced a lot of karst subsidence in Gele Mountain and Zhongliang Mountain.

[0006] Therefore, waterproof membranes, as a widely used waterproof material, can effectively block groundwater infiltration and prevent concrete structures such as linings from being eroded by groundwater, causing disasters such as leaching corrosion, corrosive media corrosion, freeze-thaw damage, and steel reinforcement corrosion.

[0007] Waterproof membranes are typically composed of a waterproof substrate layer, an adhesive layer, and a release layer, laminated sequentially. Common types include high-density polyethylene (HDPE) waterproof membranes, low-density polyethylene (LDPE) waterproof membranes, polyvinyl chloride (PVC) waterproof membranes, and thermoplastic polyolefin (TPO) waterproof membranes. There are two common installation methods: one is through hot-melt welding, where thermoplastic round gaskets are welded to the surface of the waterproof membrane and then anchored to the initial support surface with nails; the other is using nails to nail the waterproof membrane to the initial support surface.

[0008] Chinese patent CN106700216B proposes a reverse-adhesive waterproof membrane and its preparation method. Through innovative formula adjustment, the isolation membrane layer does not need to be removed and directly reacts with the poured concrete and disappears, which greatly improves the waterproof membrane's impermeability and solves the leakage problem caused by local damage to the waterproof membrane. However, it is still lacking in terms of ease of installation and still adopts the traditional installation method.

[0009] Chinese patent CN120607762B proposes a waterproof membrane and its preparation method. By optimizing the raw material formula of the waterproof membrane, it solves the problem of low tensile strength at break and expands the application scenarios of the waterproof membrane. However, it still does not solve the problem of water leakage caused by local damage to the waterproof membrane.

[0010] However, the aforementioned prior art has the following drawbacks:

[0011] (1) The waterproof membrane itself has good impermeability, but if there is local damage to the surface, water will quickly fill the gap between the waterproof membrane and the secondary lining, and the waterproof system formed by the waterproof membrane will be destroyed.

[0012] (2) As a waterproofing material between the secondary lining and the initial support, there are two common ways to lay the waterproofing membrane: one is to heat-melt weld the thermoplastic round gasket to the surface of the waterproofing membrane and then anchor it to the surface of the initial support with nails; during the joint welding and spot welding installation process, the phenomenon of weak welding and weld penetration often occurs; the other is to use nails to nail the waterproofing membrane to the surface of the initial support. This method will directly puncture the waterproofing membrane. Even if it is "patched" by welding, there will still be gaps. The damage to the waterproofing membrane cannot be repaired. The tunnel waterproofing is actually entirely borne by the secondary lining.

[0013] (3) Regardless of the laying method, multiple operators are required to perform tedious operations, which greatly reduces construction efficiency and increases labor and material costs.

[0014] Therefore, the market urgently needs a new type of waterproof board that can adhere more tightly to the concrete surface, has high tensile strength, compressive strength and water resistance, and is easy to install without damaging the surface integrity. Summary of the Invention

[0015] In view of the above-mentioned deficiencies of the prior art, this application provides a pressure-bonded, reactive adhesive and a pressure-bonded and laid reverse-adhesive waterproof membrane. The pressure-bonded and laid reverse-adhesive waterproof membrane of this application is composed of a pressure-bonded, composite waterproof membrane and a reactive adhesive for connecting the pressure-bonded and waterproof membrane together.

[0016] The present invention has the following three advantages: (1) The waterproof membrane of the present invention has excellent waterproof performance and significantly enhanced tensile and compressive strength. The main layer of the waterproof membrane is bonded together with the anti-adhesive coating layer through reactive adhesive. When the waterproof layer is subjected to external force, the main layer of the waterproof membrane can undergo relative displacement deformation within the reactive adhesive layer, thereby giving full play to the high strength, puncture resistance, tear resistance and other properties of the main membrane. When cracks (temperature cracks, stress cracks, structural deformation cracks) occur in the concrete structure, the reactive adhesive layer can effectively eliminate the reflective damage of the structural cracks. When the main layer of the waterproof membrane peels off from the concrete structure, it ensures that the peeling failure surface occurs within the reactive adhesive layer, and that the reactive adhesive layer of a certain thickness is still attached to the surface of the concrete structure, ensuring that the concrete surface has sufficient impermeability.

[0017] (2) The waterproof membrane structure is intact and not damaged. When the composite waterproof membrane is laid, it is installed and fixed by injection molding and pressing, avoiding the occurrence of water seepage due to incomplete welding, missing welding or weak welding caused by hot melt welding, and avoiding damage to the surface of the waterproof membrane caused by nails.

[0018] (3) Convenient operation, saving manpower and installation costs. According to on-site tests, it only takes 2 people and 4 hours to install a 12-meter longitudinal section of composite waterproof membrane. In contrast, it takes 4 people and 12 hours to install a 12-meter longitudinal section of ordinary waterproof membrane.

[0019] On the one hand, the present invention provides a pressure-adhesive method, such as... Figure 1 As shown, the pressing and pasting includes:

[0020] The first belt body (1) is composed of a first base plate (11) and a plurality of hook teeth (12) disposed on one side surface of the first base plate (11);

[0021] The second belt (2) is composed of a second base plate (21) and a plurality of lifting holes (22) provided on one side surface of the second base plate (21);

[0022] The hook teeth (12) and the lifting holes (22) can be engaged and disengaged.

[0023] Preferably, the hook teeth (12) are curved or mushroom-shaped.

[0024] Preferably, the lifting hole (22) is inverted U-shaped.

[0025] Preferably, the hook tooth (12) is double hook type and the lifting hole (22) is double inverted U-shaped.

[0026] Preferably, the hook teeth (12) and the lifting hole (22) are made of the following materials by weight percentage:

[0027] Polypropylene 60%-90%;

[0028] 10%-15% EPDM rubber;

[0029] 3%-5% chopped glass fiber

[0030] First antioxidant: 0.3%-0.8%;

[0031] First light stabilizer: 0.3%-1.2%.

[0032] Preferably, the hook teeth (12) and the lifting hole (22) are made of the following materials by weight percentage:

[0033] Polypropylene 75%-90%;

[0034] 12%-15% EPDM rubber;

[0035] 3%-4% chopped glass fiber

[0036] First antioxidant: 0.5%-0.7%;

[0037] First light stabilizer 0.5%-1%.

[0038] Preferably, the polypropylene is a random copolymer polypropylene, such as random copolymer polypropylene M800E selected from Sinopec Shanghai Petrochemical Co., Ltd., Saudi PP QR6701K low-solution random copolymer polypropylene, and Korean SK PPR361Y random copolymer polypropylene, and more preferably random copolymer polypropylene M800E selected from Sinopec Shanghai Petrochemical Co., Ltd.

[0039] Preferably, the EPDM rubber is selected from, for example, Dow 6565XFC (USA) or SK S501A (Korea), with Dow 6565XFC being the most preferred.

[0040] Preferably, the chopped glass fibers are selected from brands such as Jiashuo alkali-free glass fiber with a diameter of 10-13μm, Anhui Weijia Composite Materials Co., Ltd.'s WJ1001-106 alkali-free glass fiber, and Songze alkali-free glass fiber with a diameter of 13μm, with Jiashuo's products being the preferred choice.

[0041] Preferably, the first antioxidant is selected from BASF 1010.

[0042] Preferably, the first light stabilizer is selected from BASF Tinuvin NOR® 600 and Matsubara SABO® STABUV 9, with BASF Tinuvin NOR® 600 being the most preferred.

[0043] Preferably, the first base plate (11) and the second base plate (21) are made of the following materials by weight percentage:

[0044] Linear low-density polyethylene 30%-60%;

[0045] First, 20%-25% ethylene-vinyl acetate copolymer;

[0046] Maleic anhydride-grafted polyolefin elastomer 10%-25%;

[0047] First silane coupling agent: 1.5%-3%;

[0048] Special compatibilizer 2%-6%;

[0049] Second antioxidant 0.3%-0.5%;

[0050] Second light stabilizer: 0.3%-0.5%;

[0051] Preferably, the first base plate (11) and the second base plate (21) are made of the following materials by weight percentage:

[0052] Linear low-density polyethylene 45%-60%;

[0053] First, ethylene-vinyl acetate copolymer 22%-25%;

[0054] Maleic anhydride-grafted polyolefin elastomer 18%-25%;

[0055] First silane coupling agent 2%-3%;

[0056] Special compatibilizer 4%-6%;

[0057] The second antioxidant is 0.4%-0.5%;

[0058] Second light stabilizer: 0.4%-0.5%;

[0059] Preferably, the linear low-density polyethylene is selected from Hanwha 7635 (Korea), Daqing Petrochemical 8320, and Shanghai SECCO 0209AA, with Hanwha 7635 (Korea) being the most preferred.

[0060] Preferably, the first ethylene-vinyl acetate copolymer is selected from Hanwha 1828 (Korea), DuPont 3101 (USA), and Weifang Yuexu OK112, with Hanwha 1828 (Korea) being the most preferred.

[0061] Preferably, the maleic anhydride-grafted polyolefin elastomer is selected from SABIC C1070D, Shenghao Plastics, and Mitsui SE810, with SABIC C1070D being the most preferred.

[0062] Preferably, the first silane coupling agent is selected from Guangzhou Goode GD-570, GD-151, and GD-172, with GD-151 being the most preferred;

[0063] Preferably, the special compatibilizer is selected from maleic anhydride-grafted polypropylene B1A and B1 of Coase, with B1A being more preferred.

[0064] Preferably, the second antioxidant is selected from BASF 1010;

[0065] Preferably, the second light stabilizer is selected from BASF Tinuvin NOR® 600 and Matsubara SABO® STABUV 9, with BASF Tinuvin NOR® 600 being the most preferred.

[0066] On the other hand, the present invention provides a composite waterproof board, such as Figure 2 As shown ( Figure 3 The diagram shows the structure of the reverse-adhesive waterproof membrane before (A) and after (B) pressing and laying, which includes the sequentially stacked composite structure:

[0067] Waterproof membrane main layer (3);

[0068] A reactive adhesive layer (4), at least one of its main surfaces being bonded to the waterproof membrane body layer (3); and

[0069] An anti-stick coating layer (5) is disposed on the surface of the reactive adhesive layer (4) away from the waterproof membrane body layer (3).

[0070] The waterproof membrane main layer (3) is used to undertake waterproof, tensile and compressive functions, and its outer surface is in direct contact with the initial support; the reactive adhesive layer (4) is used to bond the waterproof membrane main layer (3) and the anti-stick coating layer (5), and the anti-stick coating layer (5) is used to protect the reactive adhesive layer (4). When the reaction between the anti-stick coating layer (5) and the poured concrete disappears, the reactive adhesive layer (4) comes into contact with the moisture in the concrete environment. The moisture-curing polyurethane prepolymer undergoes a moisture-curing reaction and simultaneously forms a chemical bond with the active groups on the concrete surface, accompanied by physical penetration and anchoring, thereby forming a complete, dense, and high-strength permanent bond. It provides a plastic deformation buffer against external force damage between the adhesive layer (4) and the concrete structure. The reactive adhesive layer (4) is used to isolate dust and contaminants in the air. Its core component, the moisture-curing polyurethane prepolymer, can directly react with the active hydroxyl groups on the surface of the secondary lining concrete after it is poured. After the silane coupling agent in the formula is hydrolyzed, its silanol groups condense with the silanol groups on the concrete surface, and the organic ends are embedded in the adhesive layer network, thereby constructing a stable 'molecular bridge' at the interface. This achieves chemical bonding and physical anchoring between the film layer and the cement concrete, improving the density of the concrete surface.

[0071] Preferably, the thickness of the main layer (3) of the waterproof membrane is 0.4-0.7mm or 0.5-0.8mm, preferably 0.4-0.7mm.

[0072] Preferably, when the thickness of the waterproof membrane main layer (3) is 0.4-0.7 mm, the waterproof membrane main layer (3) is made of the following materials by weight percentage:

[0073] Second ethylene-vinyl acetate copolymer 25%-70%;

[0074] Metallocene polyethylene 15%-40%;

[0075] Modified high-density polyethylene 5%-30%;

[0076] Methyl vinyl silicone rubber 0.5%-8%;

[0077] Special compatibilizer 3%-8%;

[0078] Stabilizer 0.05%-3%;

[0079] The third antioxidant is 0.5%-1.5%.

[0080] Preferably, when the thickness of the waterproof membrane main layer (3) is 0.4-0.7 mm, the waterproof membrane main layer (3) is made of the following materials by weight percentage:

[0081] Second ethylene-vinyl acetate copolymer 35%-70%;

[0082] Metallocene polyethylene 20%-35%;

[0083] Modified high-density polyethylene 5%-25%;

[0084] Methyl vinyl silicone rubber 2%-6%;

[0085] Special compatibilizer 4%-7%;

[0086] Stabilizer 1%-3%;

[0087] The third antioxidant is 0.5%-1.2%.

[0088] Preferably, when the thickness of the waterproof membrane main layer (3) is 0.5-0.8 mm, the waterproof membrane main layer (3) is made of the following materials by weight percentage:

[0089] 45%-70% of the second ethylene-vinyl acetate copolymer;

[0090] Metallocene polyethylene 20%-40%;

[0091] Modified high-density polyethylene 5%-40%;

[0092] Methyl vinyl silicone rubber 4%-7%;

[0093] Special compatibilizer 4%-8%;

[0094] Stabilizer 0.1%-3%;

[0095] The third antioxidant is 0.8%-1.2%.

[0096] Preferably, when the thickness of the waterproof membrane main layer (3) is 0.5-0.8 mm, the waterproof membrane main layer (3) is made of the following materials by weight percentage:

[0097] 50%-70% of the second ethylene-vinyl acetate copolymer;

[0098] Metallocene polyethylene 25%-38%;

[0099] Modified high-density polyethylene 10%-35%;

[0100] Methyl vinyl silicone rubber 3%-7%;

[0101] Special compatibilizer 4%-7%;

[0102] Stabilizer 1%-3%;

[0103] The third antioxidant is 0.9%-1.2%.

[0104] Preferably, the second ethylene-vinyl acetate copolymer is selected from Hanwha 1828 (Korea), DuPont 3101 (USA), and Weifang Yuexu OK112, with Hanwha 1828 (Korea) being the most preferred.

[0105] Preferably, the metallocene polyethylene is selected from the ExxonMobil Exceed™ Flow m 0523 series;

[0106] Preferably, the modified high-density polyethylene is selected from Yangzi Petrochemical 5000s, Dow CONTINUUM™ DMDA-1260 NT 7, and ExxonMobil™ HD 5403.AS, with Yangzi Petrochemical 5000s being the most preferred.

[0107] Preferably, the methyl vinyl silicone rubber is selected from the Dongjue Organosilicon 110 series.

[0108] Preferably, the special compatibilizer is selected from Hubei Co-Formula CFS-S070 and CFS-A01, with CFS-S070 being the most preferred.

[0109] Preferably, the stabilizer is selected from XY-602 and XY-803 of Xin Yaqiang Silicon Chemical Co., Ltd., with XY-803 being more preferred.

[0110] Preferably, the third antioxidant is selected from BASF compound antioxidant B900 and Yixing Angel antioxidant 1010, with BASF compound antioxidant B900 being the most preferred.

[0111] Preferably, the thickness of the reactive adhesive layer (4) is 0.2-0.4 mm or 0.2-0.3 mm, more preferably 0.2-0.3 mm.

[0112] Preferably, when the thickness of the reactive adhesive layer (4) is 0.2-0.4 mm, the reactive adhesive layer (4) is made of the following materials by mass percentage:

[0113] Brominated butyl rubber (BIIR) 20%-40%;

[0114] Moisture-curing polyurethane prepolymer 30%-45%;

[0115] Polybutene (PB) 10%-20%;

[0116] Polyolefin elastomer (POE) 15%-28%;

[0117] Second silane coupling agent 2%-6%;

[0118] Thixotropic agent 6%-10%;

[0119] The fourth antioxidant is 1%-2.5%.

[0120] Preferably, when the thickness of the reactive adhesive layer (4) is 0.2-0.4 mm, the reactive adhesive layer (4) is made of the following materials by mass percentage:

[0121] Brominated butyl rubber (BIIR) 20%-30%;

[0122] Moisture-curing polyurethane prepolymer 30%-40%;

[0123] Polybutene (PB) 10%-15%;

[0124] Polyolefin elastomer (POE) 18%-25%;

[0125] Second silane coupling agent 4%-6%;

[0126] Thixotropic agent 8%-9%;

[0127] The fourth antioxidant is 1%-2%.

[0128] Preferably, when the thickness of the reactive adhesive layer (4) is 0.2-0.3 mm, the reactive adhesive layer (4) is made of the following materials by mass percentage:

[0129] Brominated butyl rubber (BIIR) 15%-25%;

[0130] Moisture-curing polyurethane prepolymer 30%-40%;

[0131] Polybutene (PB) 10%-15%;

[0132] Polyolefin elastomer (POE) 15%-25%;

[0133] Second silane coupling agent 2%-5%;

[0134] Thixotropic agent 5%-8%;

[0135] The fourth antioxidant is 1%-2%.

[0136] Preferably, when the thickness of the reactive adhesive layer (4) is 0.2-0.3 mm, the reactive adhesive layer (4) is made of the following materials by mass percentage:

[0137] Brominated butyl rubber (BIIR) 15%-22%;

[0138] Moisture-curing polyurethane prepolymer 30%-38%;

[0139] Polybutene (PB) 12%-15%;

[0140] Polyolefin elastomer (POE) 18%-25%;

[0141] Second silane coupling agent 3%-5%;

[0142] Thixotropic agent 6%-8%;

[0143] The fourth antioxidant is 1%-1.5%.

[0144] Preferably, the brominated butyl rubber (BIIR) is selected from Exxon 2255 and Arlanxnetech BIIR2030, with Exxon 2255 being the most preferred.

[0145] Preferably, the moisture-curing polyurethane prepolymer is selected from Covestro Desmodur® Z4470 MPA / X and Wanhua Chemical Wanhua 8223, with Covestro Desmodur® Z4470 MPA / X being the most preferred.

[0146] Preferably, the polybutene (PB) is selected from HB150, PB2400 and PB1300 of Shanghai Daopu Chemical Co., Ltd. with a viscosity-average molecular weight of 1,720,000 Mv, with HB150 being the most preferred.

[0147] Preferably, the polyolefin elastomer (POE) is selected from ENGAGE (Dow Chemical) 7447, 7467, 8003, and 8180, and more preferably 8003 with a hardness of 80 or higher and a melt index of 1.0.

[0148] Preferably, the second silane coupling agent is selected from Guangzhou Zhongjie KH-602 and Nanjing Liangui Chemical Si-172, with Guangzhou Zhongjie KH-602 being the most preferred.

[0149] Preferably, the thixotropic agent is selected from polyamide wax powder D680 from Shanghai / Guangzhou Core New Materials Technology Co., Ltd. and BYK's CLAYTONE-40 (TIXOGEL® VP), with polyamide wax powder D680 from Shanghai / Guangzhou Core New Materials Technology Co., Ltd. being the most preferred.

[0150] Preferably, the fourth antioxidant is selected from BASF's compound antioxidant B900.

[0151] Preferably, the thickness of the anti-stick coating layer (5) is 0.05-0.15 mm or 0.05-0.1 mm, preferably 0.05-0.1 mm.

[0152] Preferably, when the thickness of the anti-stick coating layer (5) is 0.05-0.15 mm, the anti-stick coating layer (5) is made of the following materials by weight percentage:

[0153] PVA (polyvinyl alcohol) 5%-20%;

[0154] Metakaolinite 10%-20%;

[0155] Bentonite 0.2%-2%;

[0156] UV shielding agent 0.5%-1.5%;

[0157] Crosslinking agent 0.6%-1.2%;

[0158] Remaining water.

[0159] Preferably, when the thickness of the anti-stick coating layer (5) is 0.05-0.15 mm, the anti-stick coating layer (5) is made of the following materials by weight percentage:

[0160] PVA (polyvinyl alcohol) 10%-18%;

[0161] Metakaolinite 15%-20%;

[0162] Bentonite 0.2%-1.5%;

[0163] UV shielding agent 0.5%-1.2%;

[0164] Crosslinking agent 0.6%-1%;

[0165] Remaining water.

[0166] Preferably, when the thickness of the anti-stick coating layer (5) is 0.05-0.1 mm, the anti-stick coating layer (5) is made of the following materials by weight percentage:

[0167] PVA (polyvinyl alcohol) 5%-15%;

[0168] Metakaolinite 8%-15%;

[0169] Bentonite 0.1%-1%;

[0170] UV shielding agent 0.5%-2%;

[0171] Crosslinking agent 0.2%-0.8%;

[0172] Remaining water.

[0173] Preferably, when the thickness of the anti-stick coating layer (5) is 0.05-0.1 mm, the anti-stick coating layer (5) is made of the following materials by weight percentage:

[0174] PVA (polyvinyl alcohol) 8%-12%;

[0175] Metakaolinite 10%-15%;

[0176] Bentonite 0.2%-0.8%;

[0177] UV shielding agent 0.5%-1.5%;

[0178] Crosslinking agent 0.2%-0.6%;

[0179] Remaining water.

[0180] Preferably, the PVA (polyvinyl alcohol) is selected from Shandong Guohua 1788 2488 and Jinan Shengfeng PVA17-88, and more preferably Jinan Shengfeng PVA17-88 with a degree of alcoholysis of 88%.

[0181] Preferably, the metakaolin is selected from activated calcined kaolin with a mesh size of 1250 mesh or higher.

[0182] Preferably, the bentonite is selected from 325 mesh sodium-based bentonite from Wuhan Shizishan Chemical Coating Factory, Fenghong BS-1A and Huatai 186C from Zhejiang Huatai New Materials Co., Ltd., with 325 mesh sodium-based bentonite being the most preferred.

[0183] Preferably, the ultraviolet shielding agent is selected from ultraviolet absorbers such as UV-326, UV-328, UV-9, BP-3, and UV-531 produced by Yixing Angel Synthetic Chemical Co., Ltd., with BP-3 being the most preferred.

[0184] Preferably, the crosslinking agent is selected from industrial-grade borax.

[0185] In another aspect, the present invention provides a reactive adhesive, which, by weight percentage, comprises the following components:

[0186] Brominated butyl rubber (BIIR) 20%-40%;

[0187] Moisture-curing polyurethane prepolymer 30%-45%;

[0188] Polybutene (PB) 10%-20%;

[0189] Polyolefin elastomer (POE) 15%-28%;

[0190] Second silane coupling agent 2%-6%;

[0191] Thixotropic agent 8%-10%;

[0192] The fourth antioxidant is 1%-2.5%.

[0193] Preferably, the reactive adhesive comprises the following components by weight percentage:

[0194] Brominated butyl rubber (BIIR) 20%-30%;

[0195] Moisture-curing polyurethane prepolymer 30%-40%;

[0196] Polybutene (PB) 10%-15%;

[0197] Polyolefin elastomer (POE) 18%-25%;

[0198] Second silane coupling agent 4%-6%;

[0199] Thixotropic agent 8%-9%;

[0200] The fourth antioxidant is 1%-2%.

[0201] Preferably, the brominated butyl rubber (BIIR) is selected from Exxon 2255 and Arlanxnetech BIIR2030, with Exxon 2255 being the most preferred.

[0202] Preferably, the moisture-curing polyurethane prepolymer is selected from Covestro Desmodur® Z4470 MPA / X and Wanhua Chemical Wanhua 8223, with Covestro Desmodur® Z4470 MPA / X being the most preferred.

[0203] Preferably, the polybutene (PB) is selected from HB150, PB2400, and PB1300 of Shanghai Daopu Chemical Co., Ltd., with a viscosity-average molecular weight of 1,720,000 Mv, and HB150 is preferred.

[0204] Preferably, the polyolefin elastomer (POE) is selected from ENGAGE (Dow Chemical) 7447, 7467, 8003, and 8180, and more preferably 8003 with a hardness of 80 or higher and a melt index of 1.0.

[0205] Preferably, the second silane coupling agent is selected from Guangzhou Zhongjie KH-602 and Nanjing Liangui Chemical Si-172, with Guangzhou Zhongjie KH-602 being the most preferred.

[0206] Preferably, the thixotropic agent is selected from polyamide wax powder D680 from Shanghai / Guangzhou Core New Materials Technology Co., Ltd. and BYK's CLAYTONE-40 (TIXOGEL® VP), with polyamide wax powder D680 from Shanghai / Guangzhou Core New Materials Technology Co., Ltd. being the most preferred.

[0207] Preferably, the fourth antioxidant is selected from BASF's compound antioxidant B900.

[0208] The reactive adhesive of the present invention can bond the above-mentioned pressure bonding and the above-mentioned composite waterproof membrane together, and can also bond the waterproof membrane main layer (3) and the anti-stick coating layer (5) of the above-mentioned composite waterproof membrane together.

[0209] In another aspect, the present invention provides a pressure-adhesive reverse-adhesive waterproof membrane, which comprises the above-mentioned pressure adhesive, the above-mentioned composite waterproof membrane, and a reactive adhesive for bonding the pressure adhesive and the composite waterproof membrane.

[0210] The preparation method of the pressure-adhesive and reverse-adhesive waterproof membrane of the present invention is as follows:

[0211] 1. Preparation of pressure bonding

[0212] (1) Preparation of the pressed and pasted hook teeth and lifting holes

[0213] Polypropylene, EPDM rubber, chopped glass fiber, first antioxidant, and first light stabilizer are precisely measured according to the formula, mixed evenly, and then fed into an injection molding machine. Under the set temperature and pressure, the mixture is injected into a mold with a hook-tooth structure. After cooling and solidification, it is demolded to obtain a hook-tooth strip semi-finished product.

[0214] (2) Preparation of the pressed and bonded base plate

[0215] The first linear low-density polyethylene, ethylene-vinyl acetate copolymer, maleic anhydride-grafted polyolefin elastomer, first silane coupling agent, special compatibilizer, second antioxidant, and second light stabilizer are measured and blended according to the specified ratio. This mixture is then fed into another injection molding machine and injected into a flat base mold. After molding, it is demolded.

[0216] (3) Composite and finished product processing

[0217] The injection-molded hook teeth are firmly bonded to the lifting holes and base plate using hot pressing or high-frequency welding to form a complete press-fit. Finally, the press-fit is cut to the specified width and length according to construction requirements and packaged for later use.

[0218] 2. Preparation of composite waterproof membrane

[0219] (1) Preparation of the main layer (3) of the waterproof membrane

[0220] According to the weight proportions, the methyl vinyl silicone rubber, special compatibilizer, and 20% of the total mass of the second ethylene-vinyl acetate copolymer used in the main layer (3) of the waterproof membrane are pre-mixed and granulated to produce a uniform silicone rubber masterbatch. Then, the remaining second ethylene-vinyl acetate copolymer, metallocene polyethylene, modified high-density polyethylene, stabilizer, and third antioxidant are accurately weighed and fed together with the silicone rubber masterbatch into a co-rotating parallel twin-screw extruder through the main feed port. Dynamic vulcanization is completed under the high shear of the screw and precise temperature control (150℃~170℃). After complete plasticization and uniform mixing, the melt is extruded through a T-die and finally calendered by a three-roll calender to obtain the main layer (3) of the waterproof membrane.

[0221] (2) Preparation of reactive adhesive layer (4)

[0222] According to the weight proportions, brominated butyl rubber, polybutene, polyolefin elastomer, thixotropic agent, and fourth antioxidant for the reactive adhesive layer (4) are added to a planetary mixing vessel that can be heated and vacuumed. The mixture is melt-blended and dehydrated under continuous stirring at 110-130°C. The above adhesive is cooled to 40-50°C, and under continuous stirring and moisture-free conditions, a moisture-curing polyurethane prepolymer and a second silane coupling agent are added. After hot-melt mixing and degassing, a hot-melt adhesive liquid is obtained. On the production line adjacent to the waterproof membrane main layer (3), the lower adhesive layer of the waterproof membrane main layer (3) is first corona-treated to enhance its surface energy and reactivity, facilitating bonding with the anti-adhesive coating layer (5). After the mixed hot-melt adhesive is transported to the hot-melt adhesive coating head through an insulated pipe, the adhesive is directly applied to the surface of the waterproof membrane main layer (3) before it has completely cooled, forming the upper adhesive layer. The thickness of the adhesive layer is precisely controlled by adjusting the gap of the coating die or the roller speed.

[0223] (3) Preparation of the anti-stick coating layer (5)

[0224] Prepare the raw materials for the anti-stick coating layer (5) according to the weight proportions. In a mixing tank, heat deionized water to 80-90°C and slowly add polyvinyl alcohol while stirring until it is completely dissolved to form a transparent adhesive. After the polyvinyl alcohol solution cools to below 50°C, add metakaolin, bentonite, ultraviolet shielding agent and crosslinking agent in sequence. Use a high-speed disperser to stir until all powders are evenly dispersed to form a stable slurry, and then perform vacuum degassing. Apply the prepared polyvinyl alcohol slurry evenly to the lower adhesive layer of the anti-stick coating layer (5). Then, the sheet enters a multi-segment tunnel drying oven and slowly and thoroughly dries the moisture at a gradient temperature of 60°C to 110°C to form a continuous solid anti-stick coating layer (5).

[0225] (4) Post-processing

[0226] The three-layer composite sheet is cooled and shaped by a set of cooling rollers; the thickness of the product is continuously monitored by an online thickness gauge, and the edges on both sides are trimmed by an automatic edge trimming machine to ensure consistent width.

[0227] 3. Preparation of Press-Adhesive Reverse-Adhesive Waterproof Board

[0228] The composite waterproof membrane is bonded to the second tape body by reactive adhesive, and the finished product is rolled up under constant tension.

[0229] Alternatively, the composite waterproof membrane and the second tape can also be bonded together by heat pressing.

[0230] The above-mentioned method for laying the reverse-adhesive waterproof membrane is as follows:

[0231] (1) During the tunnel construction process, when the initial support is laid, nails are used to nail the first strip body to the surface of the initial support, and one first strip body is nailed at each of the four corners of each square meter.

[0232] (2) With the main layer of the composite waterproof membrane facing the initial support surface, find the four corners of the second tape and align it with the first tape on the initial support surface.

[0233] (3) Press the first and second strips to complete the laying of one square meter of composite waterproof board.

[0234] (4) Repeat (1) to (3) above to complete the waterproofing work on the tunnel arch and sides.

[0235] Compared with the prior art, this application has the following beneficial technical effects:

[0236] (1) In the waterproof membrane main layer system, the addition of metallocene polyethylene and modified high-density polyethylene improves the toughness and tensile and compressive properties of the waterproof membrane; in the reactive adhesive layer system, the use of polyolefin elastomer and moisture-curing polyurethane prepolymer effectively enhances the adhesion between the reactive adhesive and the waterproof membrane main body, while promoting the bonding between the reactive adhesive and concrete, and consuming external impact loads through plastic deformation; in the anti-adhesive coating layer system, polyvinyl alcohol is selected as the film-forming and bonding main body, with higher alcoholysis degree, and kaolinite can provide solid content to improve brushability; by adding short glass fiber, the rigidity, strength and creep resistance of injection molding press-bonded hooks and lifting holes are improved; in the injection molding press-bonded base plate system, the molecular structure of maleic anhydride grafted polyolefin elastomer has "amphiphilicity", which can act as a "molecular bridge" between the originally incompatible polypropylene and linear low-density polyethylene, ethylene-vinyl acetate copolymer, and significantly improve the interfacial bonding through physical entanglement and chemical bonding.

[0237] (2) Complete waterproof membrane system: Excellent waterproof performance and significantly enhanced tensile and compressive strength. The main layer of the waterproof membrane is bonded together with the anti-adhesive coating layer through the reactive adhesive layer. When the waterproof layer is subjected to external forces, the main layer of the waterproof membrane can undergo relative displacement deformation within the reactive adhesive layer, thereby giving full play to the high strength, puncture resistance, tear resistance and other properties of the main membrane. When cracks occur in the concrete structure (temperature cracks, stress cracks, structural deformation cracks), the reactive adhesive layer can effectively eliminate the reflective damage of the structural cracks. When the main layer of the waterproof membrane peels off from the concrete structure, it ensures that the peeling failure surface occurs within the reactive adhesive layer, and that the reactive adhesive layer of a certain thickness is still attached to the surface of the concrete structure, ensuring that the concrete surface has sufficient impermeability. When the composite waterproof membrane is laid, it is installed and fixed by injection molding and pressing, avoiding the occurrence of water seepage due to incomplete welding, missing welding or weak welding caused by hot melt welding, and avoiding damage to the surface of the waterproof membrane caused by nails.

[0238] (3) The installation and use process is convenient and saves manpower and installation costs. According to the field test, it only takes 2 people and 4 hours to install a 12-meter longitudinal section of composite waterproof membrane. In contrast, it takes 4 people and 12 hours to install a 12-meter longitudinal section of ordinary waterproof membrane. Attached Figure Description

[0239] Figure 1 For pressing and pasting structure diagram;

[0240] Figure 2 This is a structural diagram of a composite waterproof membrane.

[0241] Figure 3 The structural diagrams show the state before (A) and after (B) the pressing and bonding of the reverse-adhesive waterproof membrane. Detailed Implementation

[0242] The present invention will be further described in detail below through examples.

[0243] First example: Pressing and pasting

[0244] Examples 1-4: Pressing and pasting

[0245] Table 1. Formula and composition of the adhesive (by weight percentage)

[0246]

[0247]

[0248] Experimental Example 1

[0249] Referring to section 5.1 "Internal Quality" of GB / T 23315-2009 Hook and Loop Tape, Table 1 "Internal Quality Requirements" specifies the requirements for shear strength, peel strength, fatigue resistance (after 1000 clutch cycles), and fatigue resistance (after 3000 clutch cycles) of reinforced hook and loop tape. The test results of the press-fit tapes prepared in Examples 1-4 are shown in Table 2 below.

[0250] Table 2. Measurement results of pressure bonding

[0251]

[0252] Comparative Examples 1-5

[0253] Table 3. Formulas and composition of the pressing and bonding comparison ratio (in mass percentage).

[0254]

[0255] Comparative Example 6:

[0256] Compared with Example 1, HG type whisker silicon, CAS20071002, distributed by Shanghai Huijing Asia Nano New Materials Co., Ltd., was used to replace the short-cut glass fibers.

[0257] Comparative Example 7:

[0258] Compared with Example 1, maleic anhydride-grafted elastomer 800E (based on polyethylene copolymer elastomer with a grafting rate of 1.0-1.3%) from Nanjing Feiteng New Material Technology Co., Ltd. was used instead of maleic anhydride-grafted polyolefin elastomer.

[0259] Comparative Example 8:

[0260] Compared with Example 1, the titanate coupling agent of model 105 produced by Guangzhou Zhongjie New Materials Co., Ltd. was used instead of the silane coupling agent.

[0261] Comparative Example 9:

[0262] Compared to Example 1, nitrile rubber of grade N220S manufactured by JSR of Japan was used instead of ethylene propylene diene monomer (EPDM) rubber.

[0263] Comparative Example 10:

[0264] For products containing other compatibilizers, Mitsui Chemicals ADMER QF541E adhesive polyolefin material should be used instead of Coes maleic anhydride-grafted polypropylene B1A.

[0265] Experimental Example 2

[0266] Referring to section 5.1, "Internal Quality Requirements," of GB / T 23315-2009 Hook & Loop Tape, the requirements for shear strength, peel strength, fatigue resistance (after 1000 cycles of engagement and disengagement), and fatigue resistance (after 3000 cycles of engagement and disengagement) of reinforced hook and loop tapes were tested on samples 1-10. The test results are shown in Table 4 below.

[0267] Table 4 Results of Comparative Tests of Press-Adhesion Preferences

[0268]

[0269] The comparison between the examples and comparative examples shows that Comparative Example 1, lacking chopped glass fibers, had an initial shear strength of 11.0 N / cm², resulting in insufficient rigidity due to the absence of fiber reinforcement. After 3000 clutch cycles, its performance deteriorated drastically, with a shear strength of 5.9 N / cm², indicating severely degraded fatigue resistance. The absence of maleic anhydride-grafted polyolefin elastomer in Comparative Example 2 significantly reduced the peel strength of the compression bond. Comparative Example 3 exhibited a precipitous drop in all strengths because the dedicated compatibilizer, acting as an interface strengthener between the hook teeth, lifting holes, and the base plate, weakened the bonding between these interfaces, causing the hook teeth and lifting holes to detach directly from the base plate. Comparative Example 4 verified the plasticizing properties of EPDM rubber; its absence led to brittle hook teeth / lifting holes, reduced impact and repeated bending resistance, and more severe performance degradation after fatigue. Comparative Example 5, lacking a silane coupling agent, showed a slight decrease in peel strength. Comparative Example 6 exhibited poor whisker silica flowability, affecting injection molding filling and preventing the production of finished products. Comparative Example 7 exhibited an initial peel strength of 1.2 N / cm, far below the standard requirement, and failed the fatigue resistance test. Comparative Example 8 was incompatible with the system and could not form strong Si-O-Si covalent bonds with the silicone rubber component in the reactive adhesive. The base plate made by replacing Comparative Example 9 with nitrile rubber was incompatible with the hook teeth / lifting holes, resulting in phase separation during blending. The compatibilizer in Comparative Example 10 had poor flowability and was incompatible with the injection molding process.

[0270] Second embodiment: Composite waterproof membrane

[0271] Examples 5-8: Composite Waterproof Board

[0272] Table 5. Formulation and composition of composite waterproof membrane (by mass percentage)

[0273]

[0274] Experimental Example 3

[0275] Referring to the standard "Railway Tunnel Drainage and Waterproofing Materials Part 1: Waterproof Membrane - Q / CR 562.1-2018", section 4.5.3.2, "Overall Performance of Reverse-Adhesive Waterproof Membrane", Table 6, "Overall Performance of Reverse-Adhesive Waterproof Membrane", and the requirements of serial number 6, "Peel Strength After Bonding with Post-Pouring Concrete", and serial number 7, "Peel Strength After Surface Treatment with Post-Pouring Concrete", the peel strength after bonding with post-pouring concrete and the peel strength after surface treatment of the waterproof membranes prepared in Examples 5-8, as well as their water-resistant properties (0.6 MPa), were tested. The test results are shown in Table 6 below.

[0276] Table 6 Test Results of Composite Waterproof Membrane

[0277]

[0278] Comparative Examples 11-17

[0279] Table 7. Formulas and composition of composite waterproof boards (by mass percentage)

[0280]

[0281]

[0282] Comparative Example 17: The thickness of the composite waterproof membrane is 0.2-0.5mm.

[0283] Test Example 4

[0284] Referring to the standard "Railway Tunnel Drainage and Waterproofing Materials Part 1: Waterproof Membrane - Q / CR 562.1-2018", section 4.5.3.2, "Overall Performance of Reverse-Adhesive Waterproof Membrane", Table 6, "Peel Strength After Bonding with Post-Pouring Concrete" (item 6), "Peel Strength After Surface Treatment with Post-Pouring Concrete" (item 7), the peel strength after bonding with post-pouring concrete and the peel strength after surface treatment of the waterproof membranes made in Comparative Examples 11-17, as well as their water-resistant properties (0.6 MPa), were tested. The test results are shown in Table 8 below.

[0285] Table 8 Test Results of Composite Waterproof Membrane

[0286]

[0287] The comparison between the examples and comparative examples shows that Comparative Example 11, lacking methyl vinyl silicone rubber, significantly reduces the overall performance of the waterproof membrane, especially the peel strength under UV and heat aging conditions, demonstrating the important role of methyl vinyl silicone rubber in broadening the material's working temperature range and improving durability. Comparative Example 12, lacking a silane coupling agent, significantly reduces the viscosity of the reactive adhesive layer, which is detrimental to the bonding of the three layers of the waterproof membrane. Comparative Example 13 verifies the importance of polybutene for achieving reliable construction bonding and ensuring interface density; the lack of polybutene greatly affects the peel strength between the surface-treated membrane and the subsequently poured concrete. Comparative Example 14 shows that the UV shielding agent plays a crucial role in improving the waterproof membrane's resistance to UV radiation and heat aging. Comparative Example 15 shows a severely insufficient rigidity in the waterproof membrane layer, with the membrane itself being too soft. Comparative Example 17 is technically impossible to achieve; such a thinness is not feasible.

[0288] Examples 9-12: Formulation of the anti-stick coating layer in composite waterproof membrane

[0289] Examples 9-12 were developed by adjusting the component ratios (formulations and compositions are shown in Table 9).

[0290] Table 9 Formulation and Composition of the Anti-stick Coating

[0291]

[0292] Experimental Example 5

[0293] Referring to the methods for determining the surface drying time and actual drying time of paint film in GB / T 1728-2020, the method for determining water resistance in GB / T 1733-1993, the method for determining water resistance in paint film, and the method for determining peel strength with self-adhesive film in GB / T23457-2017, the anti-stick coating layers of Examples 9-12 were tested, and the results are shown in Table 10 below.

[0294] Table 10. Test results of the anti-stick coating layer

[0295]

[0296] Comparative Example 18: The anti-stick coating prepared in Example 4 of CN 106285727 B showed the following performance results (measured with reference to Test Example 5): surface drying time 0.5 h, complete drying time 1 h, water resistance (immersion for 24 h) with no surface cracking, peeling, or detachment, and peel strength to the self-adhesive film 2.2 N / mm. In comparison, the peel strength to the self-adhesive film of the samples prepared in Examples 9-12 was generally higher than that of the comparative example, and the surface drying time of Examples 9 and 10 was shorter than that of the comparative example.

[0297] Third Example: Reactive Adhesive

[0298] Examples 13-16, Comparative Examples 19, 20: Reactive Adhesive Formulations

[0299] Prepare reactive adhesives as shown in Table 11 below.

[0300] Table 11 Formulation and Composition of Reactive Adhesives

[0301]

[0302] Experimental Example 6

[0303] Referring to the viscosity determination method in "HG / T 3660-1999 Determination of Melt Viscosity of Hot Melt Adhesives" and the softening point determination method in "GB / T15332-1994 Determination of Softening Point of Hot Melt Adhesives - Ring and Ball Method", and also visually inspecting the appearance, the reactive adhesives of Examples 13-16 and Comparative Examples 19 and 20 were tested, and the results are shown in Table 12 below.

[0304] Table 12 Results of the determination of reactive adhesives

[0305]

Claims

1. A pressing adhesive, the pressing adhesive comprising: The first belt body (1) is composed of a first base plate (11) and a plurality of hook teeth (12) disposed on one side surface of the first base plate (11); The second belt (2) is composed of a second base plate (21) and a plurality of lifting holes (22) provided on one side surface of the second base plate (21); The hook teeth (12) and the lifting holes (22) can be engaged and disengaged.

2. The pressing and pasting method according to claim 1, wherein, The hook teeth (12) are curved or mushroom-shaped; Preferably, the lifting hole (22) is inverted U-shaped; Preferably, the hook tooth (12) is double hook type and the lifting hole (22) is double inverted U-shaped.

3. The pressing and pasting method according to claim 1 or 2, wherein, By weight percentage, the hook teeth (12) and the lifting hole (22) are made of the following materials: Polypropylene 60%-90%; 10%-15% EPDM rubber; 3%-5% chopped glass fiber First antioxidant: 0.3%-0.8%; First light stabilizer: 0.3%-1.2%; Preferably, the hook teeth (12) and the lifting hole (22) are made of the following materials by weight percentage: Polypropylene 75%-90%; 12%-15% EPDM rubber; 3%-4% chopped glass fiber First antioxidant: 0.5%-0.7%; First light stabilizer: 0.5%-1%; Preferably, the polypropylene is a random copolymer polypropylene, such as random copolymer polypropylene M800E selected from Sinopec Shanghai Petrochemical Co., Ltd., Saudi PP QR6701K low-solubility random copolymer polypropylene, and Korean SK PPR361Y random copolymer polypropylene, and more preferably random copolymer polypropylene M800E selected from Sinopec Shanghai Petrochemical Co., Ltd. Preferably, the EPDM rubber is selected from, for example, Dow 6565XFC (USA) and SK S501A (Korea), with Dow 6565XFC being the most preferred. Preferably, the chopped glass fibers are selected from brands such as Jiashuo alkali-free glass fiber with a diameter of 10-13μm, Anhui Weijia Composite Materials Co., Ltd.'s WJ1001-106 alkali-free glass fiber, and Songze alkali-free glass fiber with a diameter of 13μm, among which Jiashuo's products are preferred. Preferably, the first antioxidant is selected from BASF 1010; Preferably, the first light stabilizer is selected from BASF Tinuvin NOR® 600 and Matsubara SABO® STAB UV 9, with BASF Tinuvin NOR® 600 being more preferred; Preferably, the first base plate (11) and the second base plate (21) are made of the following materials by weight percentage: Linear low-density polyethylene 30%-60%; First, 20%-25% ethylene-vinyl acetate copolymer; Maleic anhydride-grafted polyolefin elastomer 10%-25%; First silane coupling agent: 1.5%-3%; Special compatibilizer 2%-6%; Second antioxidant 0.3%-0.5%; Second light stabilizer: 0.3%-0.5%; Preferably, the first base plate (11) and the second base plate (21) are made of the following materials by weight percentage: Linear low-density polyethylene 45%-60%; First, ethylene-vinyl acetate copolymer 22%-25%; Maleic anhydride-grafted polyolefin elastomer 18%-25%; First silane coupling agent 2%-3%; Special compatibilizer 4%-6%; The second antioxidant is 0.4%-0.5%; Second light stabilizer: 0.4%-0.5%; Preferably, the linear low-density polyethylene is selected from Hanwha 7635 (Korea), Daqing Petrochemical 8320, and Shanghai SECCO 0209AA, with Hanwha 7635 (Korea) being the most preferred. Preferably, the first ethylene-vinyl acetate copolymer is selected from Hanwha 1828 (Korea), DuPont 3101 (USA), and Weifang Yuexu OK112, with Hanwha 1828 (Korea) being the most preferred. Preferably, the maleic anhydride-grafted polyolefin elastomer is selected from SABIC C1070D, Shenghao Plastics, and Mitsui SE810, with SABIC C1070D being the most preferred. Preferably, the first silane coupling agent is selected from Guangzhou Goode GD-570, GD-151, and GD-172, with GD-151 being the most preferred; Preferably, the special compatibilizer is selected from maleic anhydride-grafted polypropylene B1A and B1 of Coase, with B1A being more preferred. Preferably, the second antioxidant is selected from BASF 1010; Preferably, the second light stabilizer is selected from BASF Tinuvin NOR® 600 and Matsubara SABO® STAB UV 9, with BASF Tinuvin NOR® 600 being the most preferred.

4. A composite waterproof membrane, comprising: sequentially layered and laminated components: Waterproof membrane main layer (3); A reactive adhesive layer (4), at least one of its main surfaces being bonded to the waterproof membrane body layer (3); and An anti-stick coating layer (5) is disposed on the surface of the reactive adhesive layer (4) away from the waterproof membrane body layer (3).

5. The composite waterproof membrane according to claim 4, wherein, The thickness of the main layer (3) of the waterproof membrane is 0.4-0.7mm or 0.5-0.8mm, preferably 0.4-0.7mm; Preferably, when the thickness of the waterproof membrane main layer (3) is 0.4-0.7 mm, the waterproof membrane main layer (3) is made of the following materials by weight percentage: Second ethylene-vinyl acetate copolymer 25%-70%; Metallocene polyethylene 15%-40%; Modified high-density polyethylene 5%-30%; Methyl vinyl silicone rubber 0.5%-8%; Special compatibilizer 3%-8%; Stabilizer 0.05%-3%; The third antioxidant is 0.5%-1.5%; Preferably, when the thickness of the waterproof membrane main layer (3) is 0.4-0.7 mm, the waterproof membrane main layer (3) is made of the following materials by weight percentage: Second ethylene-vinyl acetate copolymer 35%-70%; Metallocene polyethylene 20%-35%; Modified high-density polyethylene 5%-25%; Methyl vinyl silicone rubber 2%-6%; Special compatibilizer 4%-7%; Stabilizer 1%-3%; The third antioxidant is 0.5%-1.2%; Preferably, when the thickness of the waterproof membrane main layer (3) is 0.5-0.8 mm, the waterproof membrane main layer (3) is made of the following materials by weight percentage: 45%-70% of the second ethylene-vinyl acetate copolymer; Metallocene polyethylene 20%-40%; Modified high-density polyethylene 5%-40%; Methyl vinyl silicone rubber 4%-7%; Special compatibilizer 4%-8%; Stabilizer 0.1%-3%; The third antioxidant is 0.8%-1.2%; Preferably, when the thickness of the waterproof membrane main layer (3) is 0.5-0.8 mm, the waterproof membrane main layer (3) is made of the following materials by weight percentage: 50%-70% of the second ethylene-vinyl acetate copolymer; Metallocene polyethylene 25%-38%; Modified high-density polyethylene 10%-35%; Methyl vinyl silicone rubber 3%-7%; Special compatibilizer 4%-7%; Stabilizer 1%-3%; The third antioxidant is 0.9%-1.2%; Preferably, the second ethylene-vinyl acetate copolymer is selected from Hanwha 1828 (Korea), DuPont 3101 (USA), and Weifang Yuexu OK112, with Hanwha 1828 (Korea) being the most preferred. Preferably, the metallocene polyethylene is selected from the ExxonMobil Exceed™ Flow m 0523 series; Preferably, the modified high-density polyethylene is selected from Yangzi Petrochemical 5000s, Dow CONTINUUM™ DMDA-1260 NT 7, and ExxonMobil™ HD 5403.AS, with Yangzi Petrochemical 5000s being the most preferred. Preferably, the methyl vinyl silicone rubber is selected from the Dongjue Organosilicon 110 series; Preferably, the special compatibilizer is selected from Hubei Co-Formula CFS-S070 and CFS-A01, with CFS-S070 being the most preferred; Preferably, the stabilizer is selected from XY-602 and XY-803 of Xinyaqiang Silicon Chemical Co., Ltd., with XY-803 being preferred; Preferably, the third antioxidant is selected from BASF compound antioxidant B900 and Yixing Angel antioxidant 1010, with BASF compound antioxidant B900 being the most preferred.

6. The composite waterproof membrane according to claim 4 or 5, wherein, The thickness of the reactive adhesive layer (4) is 0.2-0.4 mm or 0.2-0.3 mm, preferably 0.2-0.3 mm; Preferably, when the thickness of the reactive adhesive layer (4) is 0.2-0.4 mm, the reactive adhesive layer (4) is made of the following materials by mass percentage: Brominated butyl rubber (BIIR) 20%-40%; Moisture-curing polyurethane prepolymer 30%-45%; Polybutene (PB) 10%-20%; Polyolefin elastomer (POE) 15%-28%; Second silane coupling agent 2%-6%; Thixotropic agent 6%-10%; The fourth antioxidant is 1%-2.5%; Preferably, when the thickness of the reactive adhesive layer (4) is 0.2-0.4 mm, the reactive adhesive layer (4) is made of the following materials by mass percentage: Brominated butyl rubber (BIIR) 20%-30%; Moisture-curing polyurethane prepolymer 30%-40%; Polybutene (PB) 10%-15%; Polyolefin elastomer (POE) 18%-25%; Second silane coupling agent 4%-6%; Thixotropic agent 8%-9%; Fourth antioxidant 1%-2%; Preferably, when the thickness of the reactive adhesive layer (4) is 0.2-0.3 mm, the reactive adhesive layer (4) is made of the following materials by mass percentage: Brominated butyl rubber (BIIR) 15%-25%; Moisture-curing polyurethane prepolymer 30%-40%; Polybutene (PB) 10%-15%; Polyolefin elastomer (POE) 15%-25%; Second silane coupling agent 2%-5%; Thixotropic agent 5%-8%; Fourth antioxidant 1%-2%; Preferably, when the thickness of the reactive adhesive layer (4) is 0.2-0.3 mm, the reactive adhesive layer (4) is made of the following materials by mass percentage: Brominated butyl rubber (BIIR) 15%-22%; Moisture-curing polyurethane prepolymer 30%-38%; Polybutene (PB) 12%-15%; Polyolefin elastomer (POE) 18%-25%; Second silane coupling agent 3%-5%; Thixotropic agent 6%-8%; The fourth antioxidant is 1%-1.5%; Preferably, the brominated butyl rubber (BIIR) is selected from Exxon 2255 and Arlanxnetech BIIR2030, with Exxon 2255 being more preferred; Preferably, the moisture-curing polyurethane prepolymer is selected from Covestro Desmodur® Z4470 MPA / X and Wanhua Chemical Wanhua 8223, with Covestro Desmodur® Z4470 MPA / X being the most preferred. Preferably, the polybutene (PB) is selected from HB150, PB2400 and PB1300 with a viscosity-average molecular weight of 1,720,000 Mv from Shanghai Daopu Chemical Co., Ltd., with HB150 being the most preferred. Preferably, the polyolefin elastomer (POE) is selected from ENGAGE (Dow Chemical) 7447, 7467, 8003, and 8180, and more preferably 8003 with a hardness of 80 or higher and a melt index of 1.

0. Preferably, the second silane coupling agent is selected from Guangzhou Zhongjie KH-602 and Nanjing Liangui Chemical Si-172, with Guangzhou Zhongjie KH-602 being more preferred; Preferably, the thixotropic agent is selected from polyamide wax powder D680 from Shanghai / Guangzhou Core New Materials Technology Co., Ltd. and BYK's CLAYTONE-40 (TIXOGEL® VP), with polyamide wax powder D680 from Shanghai / Guangzhou Core New Materials Technology Co., Ltd. being more preferred. Preferably, the fourth antioxidant is selected from BASF's compound antioxidant B900.

7. The composite waterproof membrane according to any one of claims 4 to 6, wherein, The thickness of the anti-stick coating layer (5) is 0.05-0.15 mm or 0.05-0.1 mm, preferably 0.05-0.1 mm; Preferably, when the thickness of the anti-stick coating layer (5) is 0.05-0.15 mm, the anti-stick coating layer (5) is made of the following materials by weight percentage: PVA (polyvinyl alcohol) 5%-20%; Metakaolinite 10%-20%; Bentonite 0.2%-2%; UV shielding agent 0.5%-1.5%; Crosslinking agent 0.6%-1.2%; Remaining water; Preferably, when the thickness of the anti-stick coating layer (5) is 0.05-0.15 mm, the anti-stick coating layer (5) is made of the following materials by weight percentage: PVA (polyvinyl alcohol) 10%-18%; Metakaolinite 15%-20%; Bentonite 0.2%-1.5%; UV shielding agent 0.5%-1.2%; Crosslinking agent 0.6%-1%; Remaining water; Preferably, when the thickness of the anti-stick coating layer (5) is 0.05-0.1 mm, the anti-stick coating layer (5) is made of the following materials by weight percentage: PVA (polyvinyl alcohol) 5%-15%; Metakaolinite 8%-15%; Bentonite 0.1%-1%; UV shielding agent 0.5%-2%; Crosslinking agent 0.2%-0.8%; Remaining water; Preferably, when the thickness of the anti-stick coating layer (5) is 0.05-0.1 mm, the anti-stick coating layer (5) is made of the following materials by weight percentage: PVA (polyvinyl alcohol) 8%-12%; Metakaolinite 10%-15%; Bentonite 0.2%-0.8%; UV shielding agent 0.5%-1.5%; Crosslinking agent 0.2%-0.6%; Remaining water; Preferably, the PVA (polyvinyl alcohol) is selected from Shandong Guohua 1788 2488 and Jinan Shengfeng PVA17-88, and more preferably Jinan Shengfeng PVA17-88 with a degree of alcoholysis of 88%; Preferably, the metakaolin is selected from activated calcined kaolin with a mesh size of 1250 mesh or higher; Preferably, the bentonite is selected from 325 mesh sodium-based bentonite from Wuhan Shizishan Chemical Coating Factory, Fenghong BS-1A and Huatai 186C from Zhejiang Huatai New Materials Co., Ltd., with 325 mesh sodium-based bentonite being the most preferred. Preferably, the ultraviolet shielding agent is selected from ultraviolet absorbers such as UV-326, UV-328, UV-9, BP-3, and UV-531 produced by Yixing Angel Synthetic Chemical Co., Ltd., with BP-3 being the most preferred; Preferably, the crosslinking agent is selected from industrial-grade borax.

8. A reactive adhesive, comprising, by weight percentage, the following components: Brominated butyl rubber (BIIR) 20%-40%; Moisture-curing polyurethane prepolymer 30%-45%; Polybutene (PB) 10%-20%; Polyolefin elastomer (POE) 15%-28%; Second silane coupling agent 2%-6%; Thixotropic agent 8%-10%; The fourth antioxidant is 1%-2.5%.

9. The reactive adhesive according to claim 8, wherein, The reactive adhesive comprises the following components by weight percentage: Brominated butyl rubber (BIIR) 20%-30%; Moisture-curing polyurethane prepolymer 30%-40%; Polybutene (PB) 10%-15%; Polyolefin elastomer (POE) 18%-25%; Second silane coupling agent 4%-6%; Thixotropic agent 8%-9%; Fourth antioxidant 1%-2%; Preferably, the brominated butyl rubber (BIIR) is selected from Exxon 2255 and Arlanxnetech BIIR2030, with Exxon 2255 being more preferred; Preferably, the moisture-curing polyurethane prepolymer is selected from Covestro Desmodur® Z4470 MPA / X and Wanhua Chemical Wanhua 8223, with Covestro Desmodur® Z4470 MPA / X being the most preferred. Preferably, the polybutene (PB) is selected from HB150, PB2400 and PB1300 with a viscosity-average molecular weight of 1,720,000 Mv from Shanghai Daopu Chemical Co., Ltd., with HB150 being the most preferred. Preferably, the polyolefin elastomer (POE) is selected from ENGAGE (Dow Chemical) 7447, 7467, 8003, and 8180, and more preferably 8003 with a hardness of 80 or higher and a melt index of 1.

0. Preferably, the second silane coupling agent is selected from Guangzhou Zhongjie KH-602 and Nanjing Liangui Chemical Si-172, with Guangzhou Zhongjie KH-602 being more preferred; Preferably, the thixotropic agent is selected from polyamide wax powder D680 from Shanghai / Guangzhou Core New Materials Technology Co., Ltd. and BYK's CLAYTONE-40 (TIXOGEL® VP), with polyamide wax powder D680 from Shanghai / Guangzhou Core New Materials Technology Co., Ltd. being more preferred. Preferably, the fourth antioxidant is selected from BASF's compound antioxidant B900.

10. A pressure-adhesive, reverse-adhesive waterproof membrane, comprising a pressure-adhesive as described in any one of claims 1 to 3, a composite waterproof membrane as described in any one of claims 4 to 7, and a reactive adhesive as described in claim 8 or 9 for bonding the pressure-adhesive and the composite waterproof membrane.

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