Ternary positive electrode material with surface-coated transition layer and preparation method thereof

By coating the surface of the ternary cathode material with an O2-structured transition layer, the problems of improving cycle performance and maintaining capacity in the prior art are solved, and the stability and reversibility of the structure under high voltage are achieved.

CN122417864APending Publication Date: 2026-07-17SICHUAN ENENGI TECHNOLOGY CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SICHUAN ENENGI TECHNOLOGY CO LTD
Filing Date
2026-04-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing strategies for high-entropy doping and surface inert material coating cannot simultaneously improve the cycle performance and maintain the capacity of ternary cathode materials, and cannot suppress the irreversible phase transition of the bulk phase under high voltage.

Method used

A transition layer with an O2 structure is coated onto the surface of a ternary cathode material. The O2 structure transition layer is formed by high-temperature solid-state sintering and ion exchange, and combined with the bulk phase of the O3 structure to form a stable coating layer.

Benefits of technology

This improved the material's cycle stability and reversible capacity under high voltage, suppressed irreversible phase transitions, and maintained the material's capacity and structural stability.

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Abstract

本发明公开了一种表面包覆过渡层的三元正极材料及其制备方法,正极材料包括体相以及包覆体相的过渡层,体相为具有O3结构的锂镍钴锰氧化物,过渡层为具有O2结构的含锂过渡金属氧化物,过渡金属选自镍、钴、锰中的至少一种。本发明通过对层状正极表面进行处理,在表面原位包覆具有高电压稳定性的O2相材料,提高材料高电压下可逆容量发挥,减少高电压下材料晶体结构不可逆相变,提高材料循环性能。
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