Negative active material, method for preparing the same, and lithium ion battery

By introducing crosslinking agents and catalysts into silicon-based anode materials to form a three-dimensional crosslinked network, the problems of insufficient cohesion and decreased cycle performance caused by volume changes during charging and discharging of silicon-based anode materials are solved, thereby improving cohesion and reducing expansion rate, and improving the cycle life of lithium-ion batteries.

CN122417899APending Publication Date: 2026-07-17JIANGSU RELIANCE ENERGY TECHNOLOGY CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JIANGSU RELIANCE ENERGY TECHNOLOGY CO LTD
Filing Date
2026-05-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, silicon-based anode materials exhibit significant volume changes during charging and discharging, leading to insufficient cohesion of the anode coating, deformation of the cell casing, and decreased cycle performance. Simply increasing the amount of binder or using a high-viscosity binder cannot effectively solve these problems.

Method used

By introducing a crosslinking agent and catalyst containing at least two epoxy ring functional groups into the negative electrode active material, low-temperature rapid crosslinking is carried out to form a three-dimensional crosslinking network, which enhances cohesion and restricts the volume expansion of silicon particles, thereby improving cycle life.

Benefits of technology

Without increasing the amount of binder, it significantly improves the cohesiveness of the negative electrode active material coating, reduces the fully charged expansion rate, improves cycle life, and maintains the stability of electron and ion transport channels.

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Abstract

本发明涉及锂离子电池技术领域,公开了一种负极活性材料及其制备方法和锂离子电池。该负极活性材料包括以下原料:主材,包括硅基活性物质,硅基活性物质选自硅氧化物、硅碳复合材料或纳米硅中至少一种;粘结剂;交联剂;催化剂,用于催化所述交联剂与所述粘结剂进行缩合反应;导电剂。本发明通过引入含有至少两个环氧环官能团的交联剂和催化剂,在涂布干燥过程中实现低温快速交联,在粘结剂用量不增加的前提下显著提升负极活性材料涂层的内聚力,降低满电态膨胀率,并改善循环寿命。
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