Waste gas treatment equipment for sodium ion battery positive electrode material production

In the waste gas treatment equipment for the production of positive electrode materials of sodium ion battery, the motor drives the scraper to clean the impurities on the bottom of the filter plate, and soak the filter plate through the liquid storage box and the liquid conduit, the filter plate is blocked due to the adhesion of particulate matter in the waste gas. The problem has significantly improved the filtering effect.

CN222196307UActive Publication Date: 2024-12-20无锡钠科能源科技有限公司
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Patent Information

Application Number
CN202420944816.9
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-04-30
Publication Date
2024-12-20
Estimated Expiration
2034-04-30

AI Technical Summary

Technical Problem

In the existing waste gas treatment device for the production of positive electrode materials of sodium ion batteries, particulate matter in the waste gas adheres to the surface of the filter plate over time, resulting in clogging of the pores of the filter plate and affecting the filtration effect.

Method used

A device including a processing device housing, a motor, a connecting rod, a slide column, a scraper, a liquid storage box, a fluid conduit, an elastic membrane, a fixing sleeve, a slider, a slag collecting box, an elastic band and a bristle was designed, and the motor was used to Drive the connecting rod and slide column to rotate the scraper to clean the impurities on the bottom of the filter plate, use the liquid storage box and liquid conduit to soak the filter plate, improve the filtration effect, and reduce impurities falling on the motor surface through the elastic band and slag collection box.

Benefits of technology

It effectively reduces the filtering capacity of the filter plate due to impurities blockage, improves the filtration effect, makes it difficult for scraped impurities to block the filter plate again, and improves the efficiency and effect of waste gas treatment.

✦ Generated by Eureka AI based on patent content.

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Abstract

The utility model relates to waste gas treatment equipment for sodium ion battery positive electrode material production. The waste gas treatment equipment comprises a treatment device shell, an air inlet is formed in the middle of the side wall of the treatment device shell; an exhaust port is formed in the top of the treatment device shell; a filter plate is fixedly connected to the interior of the treatment device shell; the filter plate is positioned between the air inlet and the air outlet; a motor is fixedly connected to the inner bottom of the treatment device shell; the output end of the motor is fixedly connected with a connecting rod; the top end of the connecting rod is slidably connected with a sliding column. A spring is mounted in the sliding column; the other end of the spring is fixedly connected with the top end of the connecting rod; the top of the sliding column is fixedly connected with a scraping plate; by means of the structure, the situation that the filtering effect of the filtering plate is reduced due to the fact that particulate matter in waste gas blocks the surface of the filtering plate when being filtered can be reduced.
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Description

Technical Field

[0001] The utility model relates to the technical field of waste gas treatment, in particular to waste gas treatment equipment for the production of positive electrode materials for sodium ion batteries. Background Art

[0002] Sodium ion battery is a secondary battery. Its working principle is that during the charge and discharge process, sodium ions are embedded and released back and forth between the positive and negative electrodes. During charging, sodium ions are released from the positive electrode and embedded into the negative electrode through the electrolyte. The opposite is true during discharge.

[0003] The production of positive electrodes for sodium-ion batteries is a complex process, which mainly includes the steps of mixing materials and solvents, high-temperature sintering, intermediate treatment, low-temperature sintering, and demagnetization. A large amount of industrial waste gas will be generated during the treatment process. These waste gases need to be treated before they can be discharged to the outside, otherwise they will cause pollution to the environment. However, when the existing waste gas treatment device for the production of positive electrode materials for sodium-ion batteries is used for treatment, some particulate matter in the waste gas will adhere to the surface of the filter plate inside the treatment device over time, causing the pores of the filter plate to be blocked, thereby causing a certain impact on the filtering effect. Utility Model Content

[0004] To this end, the technical problem to be solved by the utility model is to overcome the problem in the prior art that some particulate matter in the exhaust gas will adhere to the surface of the filter plate inside the treatment device over time, causing blockage of the pores of the filter plate, thereby causing a certain impact on the filtering effect.

[0005] In order to solve the above technical problems, the utility model provides a waste gas treatment equipment for the production of positive electrode materials for sodium ion batteries, comprising a treatment device shell; an air inlet is opened in the middle of the side wall of the treatment device shell; an exhaust port is opened at the top of the treatment device shell; a filter plate is fixedly connected to the inside of the treatment device shell; the filter plate is located between the air inlet and the exhaust port; a motor is fixedly connected to the bottom of the inner part of the treatment device shell; a connecting rod is fixedly connected to the output end of the motor; a sliding column is slidably connected to the top of the connecting rod; a spring is installed inside the sliding column; the other end of the spring is fixedly connected to the top of the connecting rod; a scraper is fixedly connected to the top of the sliding column; through the above structure, the particulate matter in the exhaust gas can be reduced from blocking the surface of the filter plate when being filtered, thereby reducing the filtering effect of the filter plate.

[0006] In one embodiment of the utility model, a liquid storage box is fixedly connected to the side wall of the treatment device shell; a liquid guide tube is fixedly connected to the bottom end of the liquid storage box; the liquid guide tube penetrates the side wall of the treatment device shell and enters the interior of the treatment device shell, and the end of the liquid guide tube is located between the exhaust port and the filter plate; a hollow bolt is threadedly connected to the top of the liquid storage box; a first elastic membrane is fixedly connected to the top of the interior of the liquid storage box; a small hole is opened in the middle of the first elastic membrane, and the small hole is located below the central hole of the hollow bolt; through the above structure, the filtering effect of the filter plate can be improved, and impurities cleaned and dropped by the scraper are difficult to flow with the exhaust gas again and block the filter plate, thereby improving the filtering effect.

[0007] In one embodiment of the utility model, a fixing sleeve is fixedly connected to the middle of the filter plate; a sliding block is slidably connected to the middle of the fixing sleeve; an inclined surface is provided at the bottom of the sliding block; through the above structure, the cleaning effect of impurities attached to the bottom of the filter plate can be further improved, thereby reducing the influence of the accumulation of impurities on the filtering capacity of the filter plate.

[0008] In one embodiment of the utility model, two groups of track plates are fixedly connected to the inner side of the outer shell of the processing device; a pair of slag collecting boxes are slidably installed on the top of the two groups of track plates; adjacent surfaces of the pair of slag collecting boxes are provided with grooves; the connecting rod is located between the pair of grooves; through the above structure, the occurrence of impurities falling on the surface of the motor and affecting the operation of the motor can be reduced.

[0009] In one embodiment of the utility model, a plurality of elastic bands are fixedly connected to the inner middle portion of the housing of the processing device; a second elastic membrane is fixedly connected to the ends of the plurality of elastic bands; the second elastic membrane is located directly below the end of the liquid guiding tube; through the above structure, the wetting of the filter plate is made more uniform, thereby further improving the filtering effect of the filter plate.

[0010] In one embodiment of the utility model, a fixed shaft is fixedly connected to the side wall of the processing device housing; the fixed shaft is located above the slag collecting box; a clamping plate is rotatably connected to the middle part of the fixed shaft; through the above structure, the occurrence of impurities falling on the surface of the motor is reduced.

[0011] In one embodiment of the utility model, a plurality of bristles are fixedly connected to the top of the scraper; the plurality of bristles are densely arranged on the top of the scraper; through the above structure, the occurrence of a decrease in filtering capacity caused by clogging of the filter plate by impurities can be further reduced.

[0012] In one embodiment of the utility model, the fixing sleeve and the sliding block are both plastic products; a counterweight block is fixedly connected to the interior of the sliding block; through the above structure, the vibration intensity of the filter plate is increased, so that more impurities can be shaken off.

[0013] The above technical solution of the utility model has the following advantages compared with the prior art:

[0014] The utility model discloses an exhaust gas treatment device for producing positive electrode materials for sodium ion batteries. The starting motor drives the connecting rod and the sliding column to rotate. Then the scraper located on the top of the sliding column will scrape and brush the bottom of the filter plate to brush off the impurities attached to the bottom of the filter plate. Through the above structure, the particulate matter in the exhaust gas can be reduced from blocking the surface of the filter plate when being filtered, thereby reducing the filtering effect of the filter plate.

[0015] The utility model discloses an exhaust gas treatment device for producing positive electrode materials for sodium ion batteries. By rotating a hollow bolt, a small hole in the middle of a first elastic membrane is opened, so that water drips from the end of a liquid guide tube onto the top of a filter plate at a suitable speed, thereby wetting the filter plate and improving the filtering capacity of the filter plate. At the same time, particles filtered by the filter plate are adsorbed on each other due to being wetted with water, so that they can fall in a cluster after being scraped by a scraper and are difficult to rise with the exhaust gas. BRIEF DESCRIPTION OF THE DRAWINGS

[0016] In order to make the content of the utility model more clearly understood, the utility model is further described in detail below based on specific embodiments of the utility model in combination with the accompanying drawings.

[0017] Figure 1 It is a three-dimensional diagram of the utility model;

[0018] Figure 2 It is a structural schematic diagram of the casing of the processing device in the utility model;

[0019] Figure 3 It is a structural schematic diagram of the elastic band in the utility model;

[0020] Figure 4 It is a structural schematic diagram of the scraper in the utility model;

[0021] Figure 5 It is a structural schematic diagram of the liquid storage box in the utility model;

[0022] Figure 6 It is a structural schematic diagram of the counterweight block in the utility model;

[0023] Explanation of the reference numerals in the drawings in the specification: 1. treatment device housing; 12. air inlet; 13. exhaust port; 14. filter plate; 15. motor; 16. connecting rod; 17. sliding column; 18. spring; 19. scraper; 2. liquid storage box; 21. liquid guide tube; 22. hollow bolt; 23. first elastic membrane; 3. fixing sleeve; 31. slider; 4. track plate; 41. slag collecting box; 42. groove; 5. elastic band; 51. second elastic membrane; 6. fixed shaft; 61. clamping plate; 7. bristles; 8. counterweight. DETAILED DESCRIPTION

[0024] The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments so that those skilled in the art can better understand the present invention and implement it, but the embodiments are not intended to limit the present invention.

[0025] Reference Figures 1 to 4 As shown, a waste gas treatment device for the production of positive electrode materials for sodium ion batteries described in an embodiment of the utility model comprises a treatment device housing 1; an air inlet 12 is provided in the middle of the side wall of the treatment device housing 1; an exhaust port 13 is provided at the top of the treatment device housing 1; a filter plate 14 is fixedly connected to the inside of the treatment device housing 1; the filter plate 14 is located between the air inlet 12 and the exhaust port 13; a motor 15 is fixedly connected to the bottom of the inside of the treatment device housing 1; a connecting rod 16 is fixedly connected to the output end of the motor 15; a sliding column 17 is slidably connected to the top of the connecting rod 16; a spring 18 is installed inside the sliding column 17; the other end of the spring 18 is fixedly connected to the top of the connecting rod 16; a scraper 19 is fixedly connected to the top of the sliding column 17 During operation, the production waste gas is injected into the interior of the treatment device housing 1 from the air inlet 12. As the waste gas content inside the treatment device housing 1 increases, the waste gas will rise and be discharged from the interior of the treatment device housing 1 through the exhaust port 13. In this process, some particulate matter in the waste gas will be filtered by the filter plate 14. As time goes by, a large amount of particulate matter will accumulate at the bottom of the filter plate 14. At this time, the starting motor 15 drives the connecting rod 16 and the sliding column 17 to rotate, and then the scraper 19 located on the top of the sliding column 17 will scrape the bottom of the filter plate 14 to brush off the impurities attached to the bottom of the filter plate 14. Through the above structure, the particulate matter in the waste gas can be reduced from blocking the surface of the filter plate 14 when being filtered, thereby reducing the filtering effect of the filter plate 14.

[0026] Reference Figures 1 to 5As shown, a liquid storage box 2 is fixedly connected to the side wall of the treatment device shell 1; a liquid guide tube 21 is fixedly connected to the bottom end of the liquid storage box 2; the liquid guide tube 21 penetrates the side wall of the treatment device shell 1 and enters the interior of the treatment device shell 1, and the end of the liquid guide tube 21 is located between the exhaust port 13 and the filter plate 14; a hollow bolt 22 is threadedly connected to the top of the liquid storage box 2; a first elastic membrane 23 is fixedly connected to the top of the interior of the liquid storage box 2; a small hole is opened in the middle of the first elastic membrane 23, and the small hole is located below the central hollow of the hollow bolt 22; when working, clean water is added to the interior of the liquid storage box 2. Under normal circumstances, the small hole in the middle of the first elastic membrane 23 is in a closed state. At this time, the existence of air pressure above the interior of the liquid storage box 2 prevents the clean water in the hollow bolt 22 from flowing out through the liquid guide tube 21. The hollow bolt 22 is rotated to move the hollow bolt 22 toward the direction of the first elastic membrane 23, thereby The first elastic membrane 23 is squeezed to open the first elastic membrane 23, and then the small hole in the middle of the first elastic membrane 23 is opened, so that external air can enter the interior of the liquid storage box 2 through the hollow hole and the small hole in the middle of the hollow bolt 22. At this time, the liquid in the liquid storage box 2 will flow out along the liquid guide tube 21. By adjusting the opening size of the small hole in the middle of the first elastic membrane 23, water is dripped from the end of the liquid guide tube 21 onto the filter plate 14 at a suitable speed, thereby soaking the filter plate 14 and improving the filtering capacity of the filter plate 14. At the same time, the particles filtered by the filter plate 14 are adsorbed to each other due to water, so that they can fall in a cluster after being scraped by the scraper 19, and it is difficult for them to rise with the exhaust gas. Through the above structure, the filtering effect of the filter plate 14 can be improved, and the impurities cleaned and dropped by the scraper 19 are difficult to flow with the exhaust gas again and block the filter plate 14, thereby improving the filtering effect.

[0027] Reference Figures 1 to 6 As shown, a fixing sleeve 3 is fixedly connected to the middle part of the filter plate 14; a slider 31 is slidably connected to the middle part of the fixing sleeve 3; an inclined surface is provided at the bottom of the slider 31; during operation, as the scraper 19 rotates, the middle part of the scraper 19 will push the slider 31 upward when passing through the slider 31, and after the scraper 19 leaves the bottom of the fixing sleeve 3, the slider 31 will fall back to its original position along the slider 31, thereby driving the filter plate 14 to vibrate due to impact and collision, and shaking off some impurities attached to the bottom of the filter plate 14. Through the above structure, the cleaning effect of the impurities attached to the bottom of the filter plate 14 can be further improved, thereby reducing the influence of the accumulation of impurities on the filtering ability of the filter plate 14.

[0028] Reference Figures 1 to 3As shown, two groups of track plates 4 are fixedly connected to the inner side of the processing device housing 1; a pair of slag collecting boxes 41 are slidably installed on the top of the two groups of track plates 4; adjacent surfaces of the pair of slag collecting boxes 41 are provided with grooves 42; the connecting rod 16 is located between the pair of grooves 42; during operation, after impurities fall, they will fall into the inside of the pair of slag collecting boxes 41, and will not fall on the surface of the motor 15 to affect the operation of the motor 15. When there are a lot of impurities accumulated inside the slag collecting box 41, the slag collecting box 41 can be taken out to clean the impurities. Through the above structure, the situation where impurities fall on the surface of the motor 15 and affect the operation of the motor 15 can be reduced.

[0029] Reference Figures 1 to 3 As shown, a plurality of elastic bands 5 are fixedly connected to the middle part of the inner part of the treatment device housing 1; a second elastic membrane 51 is fixedly connected to the ends of the plurality of elastic bands 5; the second elastic membrane 51 is located directly below the end of the liquid guiding tube 21; during operation, after water drops from the end of the liquid guiding tube 21, the water drops will fall on the second elastic membrane 51. Since the second elastic membrane 51 is a taut elastic membrane, the water drops falling on the second elastic membrane 51 will splash around, so that they can fall on the top of the filter plate 14 more evenly, making the filter plate 14 more evenly soaked, thereby further improving the filtering effect of the filter plate 14.

[0030] Reference Figures 1 to 3 As shown, a fixed shaft 6 is fixedly connected to the side wall of the processing device housing 1; the fixed shaft 6 is located above the slag collecting box 41; the middle part of the fixed shaft 6 is rotatably connected to a clamping plate 61; during operation, after a pair of slag collecting boxes 41 are installed into the interior of the processing device housing 1, the end of the clamping plate 61 will be located below the fixed shaft 6 due to its own gravity, and the side wall of the slag collecting box 41 will be blocked, so that the slag collecting box 41 is difficult to be separated from the interior of the processing device housing 1 due to the vibration of the equipment when the equipment is running, thereby reducing the occurrence of impurities falling on the surface of the motor 15.

[0031] Reference Figure 4 As shown, a plurality of bristles 7 are fixedly connected to the top of the scraper 19; the plurality of bristles 7 are densely arranged on the top of the scraper 19; during operation, as the scraper 19 rotates, the plurality of bristles 7 will extend into some filter pores at the bottom of the filter plate 14 to clean some of the accumulated impurities inside the filter plate 14. Through the above structure, the decrease in the filtering capacity of the filter plate 14 caused by the clogging of impurities can be further reduced.

[0032] Reference Figure 6As shown, the fixing sleeve 3 and the slider 31 are both plastic products; a counterweight block 8 is fixedly connected to the interior of the slider 31; during operation, since the fixing sleeve 3 and the slider 31 are both plastic products, they will not rust and get stuck due to water vapor corrosion like metal products. At the same time, the setting of the counterweight block 8 can increase the impact force of the slider 31 when it moves down, thereby increasing the vibration strength of the filter plate 14, so that more impurities can be shaken off.

[0033] During operation, the production waste gas is injected into the interior of the treatment device housing 1 from the air inlet 12. As the waste gas content inside the treatment device housing 1 increases, the waste gas rises and is discharged from the interior of the treatment device housing 1 through the exhaust port 13. In this process, some particulate matter in the waste gas will be filtered by the filter plate 14. As time goes by, a large amount of particulate matter will accumulate at the bottom of the filter plate 14. At this time, the start motor 15 drives the connecting rod 16 and the sliding column 17 to rotate, and then the scraper 19 located at the top of the sliding column 17 will scrape the bottom of the filter plate 14 to brush off the impurities attached to the bottom of the filter plate 14. Clean water is added to the inside of the liquid storage box 2. Under normal circumstances, the small hole in the middle of the first elastic membrane 23 is in a closed state. At this time, the existence of the air pressure above the inside of the liquid storage box 2 makes the hollow bolt 22 The clean water will not flow out through the liquid guide tube 21, and the hollow bolt 22 is rotated to move the hollow bolt 22 toward the direction of the first elastic membrane 23, thereby squeezing the first elastic membrane 23 to open the first elastic membrane 23, and then the small hole in the middle of the first elastic membrane 23 is opened, so that the external air can enter the interior of the liquid storage box 2 through the hollow hole and the small hole in the middle of the hollow bolt 22. At this time, the liquid in the liquid storage box 2 will flow out along the liquid guide tube 21, and by adjusting the opening size of the small hole in the middle of the first elastic membrane 23, water is dripped from the end of the liquid guide tube 21 onto the top of the filter plate 14 at a suitable speed, thereby soaking the filter plate 14, improving the filtering capacity of the filter plate 14, and at the same time making the particles filtered by the filter plate 14 adsorbed to each other due to the water, so that the particles filtered by the filter plate 14 are After being scraped, the impurities 9 can fall in a mass and are difficult to rise with the exhaust gas. As the scraper 19 rotates, the middle part of the scraper 19 will push the slider 31 upward when passing through the slider 31. After the scraper 19 leaves the bottom of the fixed sleeve 3, the slider 31 will fall back to its original position along the slider 31, thereby driving the filter plate 14 to vibrate due to the impact and collision, and vibrating some impurities attached to the bottom of the filter plate 14. After the impurities fall, they will fall into the inside of a pair of slag collection boxes 41, and will not fall on the surface of the motor 15 to affect the operation of the motor 15. When there are many impurities accumulated inside the slag collection box 41, the slag collection box 41 can be taken out to clean the impurities. After the water droplets drip from the end of the liquid guide tube 21, the water droplets will fall on the top of the second elastic membrane 51. Since the second elastic membrane 51 is a stretched The water droplets falling on the second elastic membrane 51 will splash around, so that they can fall on the top of the filter plate 14 more evenly, making the filter plate 14 more evenly soaked. After the pair of slag boxes 41 are installed into the interior of the processing device housing 1, the end of the clamping plate 61 will be under the fixed shaft 6 due to its own gravity, and block the side wall of the slag box 41, so that the slag box 41 is difficult to be separated from the interior of the processing device housing 1 due to the vibration of the equipment when the equipment is running. With the rotation of the scraper 19, a plurality of bristles 7 will extend into some filtering pores at the bottom of the filter plate 14 to clean up some accumulated impurities inside the filter plate 14. Since the fixed sleeve 3 and the slider 31 are both plastic products, they will not rust and get stuck due to water vapor corrosion like metal products.At the same time, the setting of the counterweight block 8 can increase the impact force of the slider 31 when it moves down, thereby increasing the vibration strength of the filter plate 14.

[0034] Obviously, the above embodiments are merely examples for the purpose of clear explanation and are not intended to limit the implementation methods. For those skilled in the art, other different forms of changes or modifications can be made based on the above description. It is not necessary and impossible to list all the implementation methods here. The obvious changes or modifications derived from these are still within the scope of protection of the invention of the utility model.

Claims

1. A waste gas treatment device for producing sodium ion battery positive electrode materials, comprising a treatment device housing (1); characterized in that: An air inlet (12) is provided in the middle of the side wall of the processing device housing (1); an exhaust port (13) is provided at the top of the processing device housing (1); a filter plate (14) is fixedly connected to the interior of the processing device housing (1); the filter plate (14) is located between the air inlet (12) and the exhaust port (13); a motor (15) is fixedly connected to the bottom of the interior of the processing device housing (1); a connecting rod (16) is fixedly connected to the output end of the motor (15); a sliding column (17) is slidably connected to the top end of the connecting rod (16); a spring (18) is installed inside the sliding column (17); the other end of the spring (18) is fixedly connected to the top end of the connecting rod (16); and a scraper (19) is fixedly connected to the top end of the sliding column (17).

2. The waste gas treatment equipment for sodium ion battery positive electrode material production according to claim 1, characterized in that: The side wall of the treatment device housing (1) is fixedly connected to a liquid storage box (2); the bottom end of the liquid storage box (2) is fixedly connected to a liquid guide tube (21); the liquid guide tube (21) penetrates the side wall of the treatment device housing (1) and enters the interior of the treatment device housing (1), and the end of the liquid guide tube (21) is located between the exhaust port (13) and the filter plate (14); the top of the liquid storage box (2) is threadedly connected to a hollow bolt (22); the top of the interior of the liquid storage box (2) is fixedly connected to a first elastic membrane (23); a small hole is opened in the middle of the first elastic membrane (23), and the small hole is located below the central cavity of the hollow bolt (22).

3. The waste gas treatment equipment for sodium ion battery positive electrode material production according to claim 2, characterized in that: A fixing sleeve (3) is fixedly connected to the middle of the filter plate (14); a slider (31) is slidably connected to the middle of the fixing sleeve (3); and an inclined surface is provided at the bottom of the slider (31).

4. The waste gas treatment equipment for sodium ion battery positive electrode material production according to claim 3, characterized in that: Two sets of track plates (4) are fixedly connected to the inner side of the processing device housing (1); a pair of slag collecting boxes (41) are slidably mounted on the top of the two sets of track plates (4); adjacent surfaces of the pair of slag collecting boxes (41) are each provided with a groove (42); and the connecting rod (16) is located between the pair of grooves (42).

5. The waste gas treatment equipment for sodium ion battery positive electrode material production according to claim 4, characterized in that: A plurality of elastic bands (5) are fixedly connected to the middle of the inner portion of the treatment device housing (1); a second elastic membrane (51) is fixedly connected to the ends of the plurality of elastic bands (5); and the second elastic membrane (51) is located directly below the end of the catheter (21).

6. The waste gas treatment equipment for sodium ion battery positive electrode material production according to claim 5, characterized in that: A fixed shaft (6) is fixedly connected to the side wall of the processing device housing (1); the fixed shaft (6) is located above the slag collecting box (41); and a clamping plate (61) is rotatably connected to the middle of the fixed shaft (6).

7. The waste gas treatment equipment for sodium ion battery positive electrode material production according to claim 6, characterized in that: A plurality of bristles (7) are fixedly connected to the top of the scraper (19); the plurality of bristles (7) are densely arranged on the top of the scraper (19).

8. The waste gas treatment equipment for sodium ion battery positive electrode material production according to claim 7, characterized in that: The fixed sleeve (3) and the sliding block (31) are both made of plastic; a counterweight block (8) is fixedly connected to the interior of the sliding block (31).