Electrolytic bath for producing electrodeposited zinc

By designing the inlet fabric, spinning cylinder, and mixer in the electrolytic groove, the problem of local acid and zinc ratio of zinc ratio is solved during zinc electroculation, and the uniformity and electrolyte efficiency of the electrolyte are achieved.

CN222411900UActive Publication Date: 2025-01-28NANHUA MAOSEN REGENERATION TECH CO LTD
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Patent Information

Application Number
CN202420802815.0
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-04-17
Publication Date
2025-01-28
Estimated Expiration
2034-04-17

AI Technical Summary

Technical Problem

The existing electrolytic cells are prone to local acid and zinc ratio loss during the zinc electrostatic accumulation process, resulting in a decrease in electrolytic efficiency.

Method used

Design an electrolytic groove for electricity -stitched zinc production, including the inlet cloth water room, electrolytic chamber and outlet water collection room of the inlet, electrolytic chamber, and the water collection room of the water. Eliminate the polarization of stirring and rotation by stirring and rotation, making the electrolyte more uniform.

Benefits of technology

Through this design, the uniformity of the solution is improved, and the zinc sulfate solution in the middle and upper part is fully electrolytic, which improves the electrolytic efficiency, simple structure, and convenient implementation.

✦ Generated by Eureka AI based on patent content.

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Abstract

The utility model discloses an electrolytic bath for producing electrodeposited zinc, and relates to the technical field of metallurgical refining equipment. Comprising a tank body, a liquid inlet and water distribution chamber, an electrolysis chamber and a liquid outlet and water collection chamber are sequentially arranged in the tank body from left to right, a liquid inlet pipe is arranged on the lower portion of the liquid inlet and water distribution chamber, a rotational flow cylinder is installed in the liquid inlet and water distribution chamber, spiral blades are arranged on the outer wall of the rotational flow cylinder, a stirrer is installed on the top of the liquid inlet and water distribution chamber, and the stirring section of the stirrer is located in the rotational flow cylinder. According to the electrolytic bath for zinc electrodeposition production, a solution enters the bath body from the bottom, is stirred by the stirrer, enters in a tangent mode and flows near the inner wall and the outer wall of the rotational flow cylinder, adverse factors such as concentration polarization on electrolysis are eliminated, the electrolyte components are more uniform, and then the electrolyte flows into the electrolysis chamber through the flow guide holes to be subjected to electrolysis operation; the zinc sulfate solution at the middle upper part can be fully electrolyzed through the arrangement of the previous procedure, the electrolysis efficiency is improved, the structure is simple, and the implementation is convenient.
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Description

Technical Field

[0001] The utility model relates to the technical field of metallurgical refining equipment, in particular to an electrolytic cell for electrolytic zinc production. Background Art

[0002] Zinc electrowinning refers to the metallurgical process of electrolytically extracting zinc using zinc sulfate aqueous solution as the electrolyte, also known as zinc electrolysis. The zinc electrolytic cell is one of the core equipment used for zinc electrolysis. The electrodes in the zinc electrolytic cell are usually arranged in an alternating pattern, that is, a row of anodes and a row of cathodes are arranged alternately. When the electrolytic cell is working, the current transmitted through the electrodes will dissolve the zinc metal on the anode into zinc ions, which are deposited on the cathode to form a zinc plate.

[0003] The existing liquid inlet and outlet methods of the electrolytic cell are top-in-top-out or bottom-in-top-out. In order to suppress the generation of sulfuric acid mist and volatile gases during the electrolysis process, additives must be added during the electrolysis process to cover the liquid surface with foam generated by the additives. However, the top-in-bottom-out liquid inlet method can easily cause the local acid-zinc ratio to be out of control, thereby reducing the electrolysis efficiency. Utility Model Content

[0004] The utility model provides an electrolytic cell for electrolytic zinc production to solve the problems in the background technology.

[0005] To achieve the above-mentioned purpose, the utility model provides the following technical solutions: an electrolytic cell for electrolytic zinc production, comprising a cell body, wherein a liquid inlet and water distribution chamber, an electrolytic chamber and a liquid outlet water collection chamber are sequentially arranged in the cell body from left to right, a liquid inlet pipe is arranged at the lower part of the liquid inlet and water distribution chamber, a cyclone cylinder is installed in the liquid inlet and water distribution chamber, and spiral blades are arranged on the outer wall of the cyclone cylinder, an agitator is installed at the top of the liquid inlet and water distribution chamber, and the stirring section of the agitator is located in the cyclone cylinder, a guide hole is arranged on the wall between the liquid inlet and water distribution chamber and the electrolytic chamber, an anode mud cleaning pipe is arranged at the bottom of the electrolytic chamber, a through opening is arranged on the wall between the electrolytic chamber and the liquid outlet water collection chamber, a liquid discharge pipe is arranged at the bottom of the liquid outlet water collection chamber, and a liquid outlet pipe is arranged at the upper part of the liquid outlet water collection chamber.

[0006] Furthermore, the tank body includes an outer frame, a liner and a stainless steel liner, the stainless steel liner is located in the outer frame, and the liner is located between the stainless steel liner and the outer frame.

[0007] Furthermore, the bottom of the trough body is provided with supporting feet, and the supporting feet are located around the bottom.

[0008] Furthermore, pads are provided on the inner walls on both sides of the liquid inlet and water distribution chamber, and the cyclone cylinder is fixed on the pads.

[0009] Furthermore, a crossbeam is provided on the top of the liquid inlet and water distribution chamber, and the motor part of the agitator is fixed on the crossbeam.

[0010] Furthermore, an overflow pipe is provided on the side wall of the liquid outlet water collecting chamber, and the overflow pipe is located above the liquid outlet pipe.

[0011] Compared with the prior art, the utility model provides an electrolytic cell for electrolytic zinc production, which has the following beneficial effects:

[0012] In the electrolytic cell for electrolytic zinc production, the solution enters the cell body from the bottom, is stirred by a stirrer, enters in a tangential manner, flows near the inner and outer walls of the cyclone, eliminates adverse factors such as concentration polarization on electrolysis, makes the electrolyte composition more uniform, and then flows into the electrolytic chamber through the guide hole for electrolysis operation. The setting of the front process can make the zinc sulfate solution in the middle and upper parts fully electrolyzed, improve the electrolysis efficiency, and has a simple structure and convenient implementation. BRIEF DESCRIPTION OF THE DRAWINGS

[0013] Figure 1 It is a structural schematic diagram of the utility model;

[0014] Figure 2 It is a partial schematic diagram of the utility model;

[0015] Figure 3 This is a structural diagram of the tank body of the utility model.

[0016] In the figure: 1. tank body; 101. outer frame; 102. gasket; 103. stainless steel lining; 104. supporting foot; 2. liquid inlet water distribution chamber; 3. electrolysis chamber; 4. liquid outlet water collection chamber; 5. liquid inlet pipe; 6. cyclone cylinder; 7. spiral blades; 8. agitator; 9. guide hole; 10. anode mud cleaning pipe; 11. through-port; 12. drain pipe; 13. liquid outlet pipe; 14. pad; 15. crossbeam; 16. overflow pipe. DETAILED DESCRIPTION

[0017] The following will be combined with the drawings in the embodiments of the utility model to clearly and completely describe the technical solutions in the embodiments of the utility model. Obviously, the described embodiments are only part of the embodiments of the utility model, not all of the embodiments. Based on the embodiments in the utility model, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the utility model.

[0018] See also Figure 1-Figure 3The utility model discloses an electrolytic cell for electrolytic zinc production, comprising a cell body 1, wherein a liquid inlet water distribution chamber 2, an electrolytic chamber 3 and a liquid outlet water collection chamber 4 are arranged in sequence from left to right in the cell body 1, a liquid inlet pipe 5 is arranged at the lower part of the liquid inlet water distribution chamber 2, a swirl cylinder 6 is installed in the liquid inlet water distribution chamber 2, and a spiral blade 7 is arranged on the outer wall of the swirl cylinder 6, an agitator 8 is installed on the top of the liquid inlet water distribution chamber 2, and the agitation section of the agitator 8 is located in the swirl cylinder 6, a guide hole 9 is arranged on the wall between the liquid inlet water distribution chamber 2 and the electrolytic chamber 3, a solution enters the cell body 1 from the bottom, and the agitator 8 is used to stir the solution, and the solution is stirred. The electrolyte enters the electrolysis chamber 3 in a tangential manner and flows near the inner and outer walls of the cyclone cylinder 6, eliminating adverse factors such as concentration polarization on electrolysis, making the electrolyte composition more uniform, and then flows into the electrolysis chamber 3 through the guide hole 9 for electrolysis. The setting of the previous process can fully electrolyze the zinc sulfate solution in the middle and upper parts, improve the electrolysis efficiency, and has a simple structure and convenient implementation. An anode mud cleaning pipe 10 is provided at the bottom of the electrolysis chamber 3, a through hole 11 is provided on the wall between the electrolysis chamber 3 and the liquid outlet water collecting chamber 4, a drain pipe 12 is provided at the bottom of the liquid outlet water collecting chamber 4, and a liquid outlet pipe 13 is provided at the upper part of the liquid outlet water collecting chamber 4.

[0019] Specifically, the tank body 1 includes an outer frame 101 , a gasket 102 and a stainless steel liner 103 . The stainless steel liner 103 is located in the outer frame 101 , and the gasket 102 is located between the stainless steel liner 103 and the outer frame 101 .

[0020] In this embodiment, the tank body 1 is the main component of the zinc electrolytic cell and is also one of the important factors determining the efficiency and quality of zinc electrolysis. The lining is the liquid contact part of the tank body 1 and is usually made of stainless steel. Stainless steel is a material with excellent corrosion resistance. Since zinc liquid has little corrosion effect on it, it has good corrosion resistance and a long service life.

[0021] Specifically, the bottom of the tank body 1 is provided with supporting feet 104, and the supporting feet 104 are located around the bottom thereof.

[0022] In this embodiment, the support legs 104 are used to support the tank body 1 and can also be used for horizontal and vertical adjustments during installation.

[0023] Specifically, pads 14 are provided on the inner walls of both sides of the liquid inlet and water distribution chamber 2 , and the cyclone cylinder 6 is fixed on the pads 14 .

[0024] In this embodiment, the cushion block 14 is a supporting structure used for installing and fixing the cyclone tube 6 .

[0025] Specifically, a crossbeam 15 is provided on the top of the liquid inlet and water distribution chamber 2 , and the motor part of the stirrer 8 is fixed on the crossbeam 15 .

[0026] In this embodiment, the crossbeam 15 is a supporting structure for installing and fixing the motor part of the stirrer 8 .

[0027] Specifically, an overflow pipe 16 is provided on the side wall of the liquid outlet water collecting chamber 4 , and the overflow pipe 16 is located above the liquid outlet pipe 13 .

[0028] In this embodiment, the overflow pipe 16 is a piping system, the main function of which is to protect the container or system from being overloaded, and it maintains the safety of the system by discharging or releasing excess liquid.

[0029] When in use, the solution enters the tank body 1 from the bottom, and the solution is stirred by the stirrer 8. The solution enters in a tangential manner and flows near the inner and outer walls of the cyclone tube 6 to eliminate adverse factors such as concentration polarization on electrolysis, making the electrolyte composition more uniform, and then flows into the electrolysis chamber 3 through the guide hole 9 for electrolysis. The setting of the previous process can fully electrolyze the zinc sulfate solution in the middle and upper parts, improve the electrolysis efficiency, and has a simple structure and convenient implementation.

[0030] In summary, in the electrolytic cell for electrolytic zinc production, the solution enters the cell body 1 from the bottom, and is stirred by the stirrer 8. The solution enters in a tangential manner and flows near the inner and outer walls of the cyclone 6, eliminating adverse factors such as concentration polarization on electrolysis, making the electrolyte composition more uniform, and then flows through the guide hole 9 to the electrolysis chamber 3 for electrolysis. The setting of the previous process can fully electrolyze the zinc sulfate solution in the middle and upper parts, thereby improving the electrolysis efficiency, and the structure is simple and easy to implement.

[0031] Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the present invention, and that the scope of the present invention is defined by the appended claims and their equivalents.

Claims

1. An electrolytic cell for electrolytic zinc production, comprising a cell body (1), characterized in that: The tank body (1) is provided with a liquid inlet water distribution chamber (2), an electrolysis chamber (3) and a liquid outlet water collection chamber (4) from left to right in sequence. A liquid inlet pipe (5) is provided at the lower part of the liquid inlet water distribution chamber (2). A swirl cylinder (6) is installed in the liquid inlet water distribution chamber (2), and spiral blades (7) are provided on the outer wall of the swirl cylinder (6). A stirrer (8) is installed at the top of the liquid inlet water distribution chamber (2), and the stirring section of the stirrer (8) is located at the swirl cylinder. In the cylinder (6), a flow guide hole (9) is provided on the wall between the liquid inlet water distribution chamber (2) and the electrolysis chamber (3), an anode mud cleaning pipe (10) is provided at the bottom of the electrolysis chamber (3), a through hole (11) is provided on the wall between the electrolysis chamber (3) and the liquid outlet water collection chamber (4), a liquid discharge pipe (12) is provided at the bottom of the liquid outlet water collection chamber (4), and a liquid outlet pipe (13) is provided at the top of the liquid outlet water collection chamber (4).

2. The electrolytic cell for electrolytic zinc production according to claim 1, characterized in that: The tank body (1) comprises an outer frame (101), a liner (102) and a stainless steel liner (103); the stainless steel liner (103) is located in the outer frame (101), and the liner (102) is located between the stainless steel liner (103) and the outer frame (101).

3. The electrolytic cell for electrolytic zinc production according to claim 1, characterized in that: The bottom of the tank body (1) is provided with supporting feet (104), and the supporting feet (104) are located around the bottom.

4. The electrolytic cell for electrolytic zinc production according to claim 1, characterized in that: Pads (14) are provided on the inner walls of both sides of the liquid inlet and water distribution chamber (2), and the cyclone cylinder (6) is fixed on the pads (14).

5. The electrolytic cell for electrolytic zinc production according to claim 1, characterized in that: A crossbeam (15) is provided on the top of the liquid inlet and water distribution chamber (2), and the motor part of the stirrer (8) is fixed on the crossbeam (15).

6. The electrolytic cell for electrolytic zinc production according to claim 1, characterized in that: An overflow pipe (16) is provided on the side wall of the liquid outlet water collecting chamber (4), and the overflow pipe (16) is located above the liquid outlet pipe (13).