Sensor element and method for producing a sensor element
Patent Information
- Application Number
- EP2023787105
- Authority / Receiving Office
- EP · EP
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2022-10-12
- Filing Date
- 2023-10-10
- Publication Date
- 2025-08-20
AI Technical Summary
Existing temperature sensor technologies, such as thin-film NTC thermistors, face challenges in achieving tight resistance tolerances necessary for accurate temperature measurement due to manufacturing limitations, especially at the micrometer and nanometer scales, where structural miniaturization increases the influence of manufacturing tolerances, leading to excessive resistance spreads.
A sensor element with a thin-film NTC temperature sensor design featuring a carrier with an insulating layer and a functional layer made of NTC ceramic, where the resistance is adjusted by structuring the functional layer and electrodes to achieve precise resistance values, allowing for narrow resistance tolerances comparable to classic designs, using techniques like laser trimming to fine-tune the resistance.
The solution enables high accuracy in temperature measurement by achieving resistance tolerances comparable to classic designs, with a compact and flexible sensor element suitable for integration into MEMS or SESUB structures, ensuring precise resistance settings through adjustable electrode and functional layer configurations.
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Figure 1.1
Abstract
Description
[0001] Description
[0002] SENSOR ELEMENT AND METHOD FOR PRODUCING A SENSOR ELEMENT
[0003] The present invention relates to a sensor element, in particular a temperature sensor. The present invention further relates to a method for producing at least one sensor element, preferably a temperature sensor.
[0004] To integrate passive components such as sensors, capacitors, protective devices, or heaters into electrical systems, the dimensions must be adapted to modern packaging designs, which are in the micrometer and even nanometer scale range. To achieve this level of miniaturization, the components are deposited as thin films on carrier structures with electrical connections and described as discrete components. These innovative components can be integrated into MEMS (Micro Electro Mechanical System) or SESUB (Semiconductor Embedded in Substrate) structures, among others.
[0005] The increasing demands on temperature measurement accuracy require tight tolerances in the resistance variation of such sensor elements. However, with ever smaller structures, manufacturing tolerances have an ever-increasing influence, causing the resulting resistance variation to exceed the required tolerances. The resistance variation can only be reduced to a limited extent through process control.
[0006] According to the state of the art, temperatures for monitoring and control in a wide variety of applications are mainly measured using ceramic thermistor elements
[0007] (NTC), silicon temperature sensors (KTY), platinum temperature sensors (PRTD), or thermocouples (TC). NTC thermistors are the most widely used due to their low manufacturing costs. A further advantage over thermocouples and metallic resistance elements, such as Pt elements, is their pronounced negative resistance-temperature characteristic.
[0008] For use in power modules, SMD (surface mounted device) NTC temperature sensors are predominantly used, which are soldered on. Alternatively, for control modules for low power, NTC chips are used, which are mounted on the underside using Ag sinter paste, soldering or gluing, and the top side is contacted via a bonding wire.
[0009] Metallic electrodes must be applied to electrically connect the NTC chips. Current technology involves applying thick-film electrodes, primarily made of silver or gold pastes, using a screen-printing process followed by firing.
[0010] The integration of electronic components into structures such as MEMS or SESUB requires very small elements, which must also be integrated using suitable contacting techniques. Conventional assembly technologies for SMD designs or NTC chips cannot be used for this purpose.
[0011] The German patent application DE 10 2020 122 923 A1, the content of which is incorporated into this application by reference, describes a sensor element for temperature measurement with a thin-film NTC thermistor.
[0012] Until now, thin-film NTC temperature sensors could not be manufactured with tolerances as tight as classic designs (SMD NTC and NTC chips).
[0013] The object of the present invention is to describe a sensor element and a method for producing a sensor element which solve the above problems.
[0014] This object is achieved by a sensor element and a method for producing a sensor element according to the independent claims.
[0015] According to one aspect, a sensor element is described. The sensor element 1 is suitable for measuring a temperature.
[0016] The sensor element is a temperature sensor. Preferably, the sensor element is a thin-film NTC temperature sensor. The operating temperature of the sensor element is between -40 °C and 125 °C, including the limits.
[0017] The sensor element has at least one carrier. Preferably, the sensor element has exactly one carrier. The carrier has a carrier material, preferably silicon, silicon carbide, GaN, or glass (silica or borosilicate glass). Alternatively, the carrier material can also be SiSn, AlN, or Al2O3.
[0018] The carrier has a top side and a bottom side. The top side is electrically insulating. Preferably, an insulating layer, for example Al2O3, AlN, SiO2 or SiSn4 or combinations of layers of these materials, is formed on the top side of the carrier. The insulating layer is formed directly on the top side of the carrier and can be constructed from one or more layers.
[0019] The sensor element further comprises at least one functional layer. The functional layer is arranged on the carrier. In particular, the functional layer is arranged on the electrically insulating upper side of the carrier.
[0020] The carrier mechanically stabilizes the functional layer. The functional layer can be formed directly on the carrier. Alternatively, additional components of the sensor element, such as electrodes, can be formed between the carrier and the functional layer.
[0021] The resistance of the sensor element is influenced by a structure, for example, by a dimension or width and / or a specific shape of the functional layer. The width of the functional layer can vary.
[0022] The thickness of the functional layer is between 50 nm and 1 pm, preferably between 100 nm and 500 nm, particularly preferably between 250 nm and 400 nm. The functional layer comprises a material (functional material) that has specific electrical characteristics. The functional layer comprises a material with a temperature-dependent electrical resistance. For example, the specific resistance of the functional layer at an operating temperature of 25 °C is p = 3 Ωm.
[0023] The functional layer preferably comprises an NTC ceramic.
[0024] The functional layer is preferably a thin film with NTC characteristics. The NTC ceramic is preferably based on an oxide material with a perovskite or spinel structure. Alternatively, the functional layer can be based on a carbide or nitride material. Thin films of vanadium oxide or SiC represent another alternative.
[0025] The sensor element further comprises at least two electrodes. The electrodes are preferably designed as thin-film electrodes. The electrodes are formed on the carrier at a distance from one another. The electrodes preferably do not extend to an edge region of the carrier. In particular, the electrodes are preferably formed in a central or inner region on the carrier. The respective electrode has a plurality of electrode fingers. The electrode fingers of the two electrodes are arranged alternately with one another. The electrodes consequently form an interdigital structure.
[0026] The resistance of the sensor element is influenced by a structure of the electrodes, for example a length and / or number of electrode fingers and / or by a distance between the electrode fingers (gap width).
[0027] The sensor element further has at least two contact pads for electrically contacting the sensor element. The sensor element preferably has exactly two contact pads. The contact pads are directly electrically and mechanically connected to the electrodes. One contact pad is arranged directly on a partial area of each of the electrodes. The sensor element can also be mounted using thin wire bonding via the contact pads. The sensor element is very compact. In particular, the sensor element is designed to be embedded as a discrete component directly into an electrical or electronic system. For example, the sensor element has a maximum edge length of 1000 pm, preferably <800 pm, particularly preferably <500 pm. A thickness of the sensor element is <100 pm, preferably <80 pm, particularly preferably <50 pm. The dimensions of the sensor element are particularly preferably 300 pm x 500 pm x 50 pm.Preferably, the component is designed for direct integration into a MEMS structure and / or into a SESUB structure.
[0028] The sensor element also has a narrow resistance tolerance. This means that the sensor element has a very small deviation range from a target resistance (nominal value of the resistance).
[0029] The at least one functional layer and / or at least one of the at least two electrodes are structured to adjust the resistance value. The at least one functional layer and / or at least one of the at least two electrodes are trimmable to adjust the resistance value. In particular, at least a partial region of the at least one functional layer and / or at least a partial region of at least one of the two electrodes is severed to adjust the resistance.
[0030] If the resistance of the component to be trimmed already corresponds to the target value, the structured / trimmable areas are not severed.
[0031] By achieving a tight resistance tolerance, the
[0032] The sensor element offers very high temperature measurement accuracy. The sensor element preferably has a resistance tolerance comparable to the narrow resistance tolerance of conventional designs such as SMD NTCs or NTC chips.
[0033] An electrical characterization of the sensor element is similar to that of a standard NTC chip:
[0034] - R(25°C) = 10 kQ to 100 kQ;
[0035] - B(25 / 100) = 2000 K to 4000 K, including the limits. With a nominal resistance value of R(25°C) < 100 kΩ, the thickness of the functional layer in the optimized sensor element is 300 nm and the specific resistance of the functional layer is p = 3 Ωm.
[0036] According to one embodiment, the functional layer only partially covers the carrier or the insulating layer on top of the carrier. Furthermore, the functional layer only partially covers the electrode fingers of the two electrodes.
[0037] A geometry / arrangement of the functional layer is initially selected such that the functional layer covers the carrier / insulating layer only in the region of the finger structure of the electrodes. Alternatively, the functional layer can also protrude beyond the finger structure of the electrodes. Preferably, the functional layer is only formed in a central region of the carrier. In particular, the functional layer does not protrude to an edge region of the carrier. Furthermore, the structure of the functional layer, for example a width of the functional layer, is selected such that a specific resistance (setpoint) of the sensor element can be set. This makes the sensor element particularly flexible to use and particularly precise. According to one embodiment, the functional layer has a plurality of strips. In other words, the functional layer consists of discrete individual elements. The strips are arranged at a distance from one another.The stripes are arranged parallel to each other.
[0038] The sensor element's design is based on the principle of a parallel connection of individual resistors. The strips are perpendicular to the electrode fingers and are contacted via them. This results in several individual resistors connected in parallel between the electrode fingers.
[0039] The width of the strips can be the same for all strips of the functional layer. Alternatively, the width of the strips can also vary. For example, very narrow, medium, and wide strips can be combined. This results in greater variance in the resistance setting. In a parallel circuit, where the individual resistors are added as reciprocals, this means that trimming larger resistors causes a small change in resistance across the entire sensor element. This makes fine adjustment of the resistance setpoint easy.
[0040] Trimming can be carried out in two ways. Either the functional layer or the electrode fingers can be severed. In particular, to adjust the resistance value of the sensor element, at least one strip of the functional layer and / or at least one electrode finger is severed, preferably by means of a laser (laser trimming). According to one exemplary embodiment, the functional layer or at least a partial region of the functional layer is stepped, trapezoidal or triangular. The functional layer therefore does not have any discrete individual elements, but is formed in one piece. The functional layer covers the electrodes, in particular the electrode fingers, but only partially.
[0041] The specific structure of the functional layer and the only partial coverage of the electrode fingers result in different individual resistances that are connected in parallel between the electrode fingers. This makes trimming to a desired target resistance (nominal resistance) possible in a simple manner. To set the resistance value, at least one electrode finger is severed, in particular using a laser (laser trimming). Another possible variant for setting the resistance value is to cut the functional layer along an electrode finger (i.e., between the electrode fingers) using a laser.
[0042] According to one embodiment, at least one electrode finger is structured. In particular, at least one of the electrode fingers has a different shape than the other electrode fingers. Preferably, at least one of the electrode fingers is trapezoidal or triangular. In comparison, the other electrode fingers have a square shape. This results in an even finer adjustment option for the resistance due to a wider spread of the trimmable individual resistors between two adjacent electrode fingers. According to one embodiment, the electrode fingers of at least one of the at least two electrodes are of different lengths. In other words, at least one, preferably exactly one, of the two electrodes has electrode fingers of different lengths.
[0043] This results in different individual resistances of the electrode fingers, which are connected in parallel between the electrode fingers, thus enabling trimming to the desired target resistance. To adjust the resistance value, at least one of the electrode fingers of different lengths is severed, particularly with the aid of a laser.
[0044] According to one embodiment, the distance between adjacent electrode fingers varies. This provides additional areas with varying distances for trimming, resulting in even finer gradations in the resistance setting. To adjust the resistance value, at least one of the electrode fingers is severed, in particular with the aid of a laser.
[0045] According to one embodiment, at least one of the electrode fingers has a comb-shaped region. The comb-shaped region has a plurality of teeth. The teeth point in the direction of the subsequent electrode finger. The comb-shaped region is preferably formed on one of the outer electrode fingers.
[0046] The teeth of the comb-shaped section can be of different lengths and / or widths. This allows for greater variance in resistance adjustment. In particular, different individual resistances are obtained, which allows trimming to the desired target resistance. To adjust the resistance value of the sensor element, at least one of the teeth is cut.
[0047] According to one embodiment, the electrodes are formed directly on a top side of the functional layer. In other words, the functional layer is formed between the electrodes and the carrier. This design allows trimming of the electrode after application and testing of the sensor element. Furthermore, in this design, the electrode does not have to withstand the conditions of the sintering process of the functional layer. Alternatively, the electrodes can also be arranged directly on a bottom side of the functional layer.
[0048] According to one embodiment, the sensor element has a protective layer. The protective layer can be made of oxides, nitrides, ceramics, glasses, or plastic. The protective layer completely covers an upper side of the sensor element with the exception of the contact pads. For this purpose, the protective layer has recesses at the location of the contact pads. The protective layer has a thickness of < 10 pm, preferably < 5 pm, ideally < 1 pm. The protective layer improves the long-term stability of the sensor element.
[0049] According to a further aspect, a method for producing at least one sensor element, in particular a plurality of sensor elements, is described. It should be noted that the method preferably produces many sensor elements in parallel and subsequently separates them from one another. For the sake of simplicity, reference is made below essentially to one sensor element. Preferably, the method produces the sensor element described above. All properties disclosed with respect to the sensor element or the method are also correspondingly disclosed with respect to the respective other aspect and vice versa, even if the respective property is not explicitly mentioned in the context of the respective aspect. The method comprises the following steps:
[0050] A) Providing a carrier material for forming a carrier. The carrier material preferably comprises Si, SiC, GaN, or glass. Alternatively, the carrier material may comprise SiSn, AlN, or Al2O3. The carrier has a top side and a bottom side. An electrically insulating layer, preferably SiO2, may also be formed on the top side of the carrier material.
[0051] B) Forming or depositing at least two electrodes on the substrate. The deposition is carried out using a PVD ("physical vapor deposition") process, a CVD ("chemical vapor deposition") process, or electroplating. Alternatively, the deposition can also be carried out using an ALD (atomic layer deposition) process.
[0052] The electrodes are formed spaced apart from one another. In particular, the electrodes are spatially and electrically insulated from one another. The electrodes have electrode fingers. The electrodes interlock in the form of interdigital structures. The electrodes are preferably formed directly on the upper side of the carrier or on the insulating layer. Alternatively, the electrodes can also be formed on the upper side of the functional layer. The electrodes are formed such that they are spaced apart from an edge region of the carrier. The electrodes can be structured to adjust the resistance of the sensor element (see step E).
[0053] C) Applying, preferably sputtering, a functional material to a portion of the electrodes to form a functional layer. The functional material preferably comprises an NTC ceramic based on an oxide material in the perovskite or spinel structure type. Alternatively, the functional material can also be based on a carbide or nitride material. Alternatively, the functional material can comprise or represent a thin layer of vanadium oxide or SiC.
[0054] The functional layer is formed as a thin film. The functional layer only partially covers the carrier or the electrodes. In particular, the functional layer is formed so that it is spaced from the edge region of the carrier and is formed in the region of the finger structures (interdigital structures) of the electrode. The functional layer can also protrude beyond the interdigital structure of the electrodes. The functional layer is deposited as a full-surface thin film and only structured in a further process step, e.g. by means of wet-chemical etching or dry etching. After deposition, the NTC layer has not yet crystallized.
[0055] The functional layer can be structured to adjust the resistance of the sensor element (see step E). D) Temperature treatment of the functional layer. This serves to develop the NTC properties of the functional material and is carried out at temperatures up to 1000 °C.
[0056] The functional layer is then measured. This determines the initial tolerance range of the resistance value. At this stage of the process, this tolerance range is, for example, the nominal resistance value ± 5%.
[0057] E) Adjusting the resistance value of the sensor element. This is done by trimming at least one of the electrodes and / or the functional layer using a laser. The resistance value is set to a predetermined nominal value (setpoint value). By precisely adjusting the resistance value, the finished sensor element has a very narrow resistance tolerance. The resistance tolerance of the nominal value of the finished sensor element is a maximum of ± 5%, preferably a maximum of ± 1%, particularly preferably a maximum of ± 0.5%.
[0058] The functional layer and / or at least one of the electrodes, for example at least one electrode finger, are structured for resistance adjustment. In other words, the functional layer and / or at least a portion of the electrodes have a structured region. An initial resistance of the functional layer is selected such that it lies within a tolerance window at low resistance values.
[0059] The final resistance value is adjusted by trimming the structured region. In particular, at least one of the electrode fingers and / or at least a portion of the functional layer is severed using the laser. In other words, material is removed from at least one electrode finger and / or from at least a portion of the functional layer, changing the resistance of the relevant component and thus the overall resistance of the sensor element. The resistance of the sensor element is increased to the target value by trimming the structured regions.
[0060] However, if the resistance of the sensor element already corresponds to the target value, no additional adjustment of the resistance value is required.
[0061] According to one embodiment, the method comprises the following further steps:
[0062] F) Applying a protective layer to the top side of the sensor element. The protective layer covers the top side completely except for two partial areas. The partial areas are arranged over a flat end area of the electrodes, onto which the contact pads can be applied in the subsequent process step. The protective layer is structured either
[0063] ( a ) applied over the entire surface and the free partial areas are created by a subsequent process such as wet chemical etching or dry etching or laser structuring or
[0064] (b) directly applied in a structured manner by using a mask during the deposition process.
[0065] G) Forming contact pads in the partial areas free of the protective layer for electrically contacting the sensor element. One contact pad is formed directly on a flat end area of each of the electrodes. The contact pads can protrude beyond the structured protective layer. The contact pads can comprise Cu, Au, Ni, Cr, Ag, Ti, Ta, W, Pd or Pt. If the sensor element is integrated into a SESUB structure, the contact pads preferably comprise Cu. The contact pads then preferably have a thickness of > 5 pm. The contact pads are designed such that they protrude beyond a surface of the finished sensor element.
[0066] As an alternative to contact pads, bumps or thin electrodes can also be provided. All of these possible contact elements contain at least one metal, such as Cu, Au, or a solderable alloy.
[0067] H) Separating or isolating the sensor elements.
[0068] The separation takes place in two steps:
[0069] (1) Slicing in the x / y direction (length & width). This can be done, for example, by plasma etching or sawing. The substrate is not sawn through, but only cut to a defined thickness.
[0070] (2) Singling in the z-direction (height). Grinding takes place from the back side. Material is removed from the underside of the carrier through a grinding process until a defined final component thickness is reached.
[0071] I) If a thicker sensor element design is desired, grinding the substrate is not necessary. In this case, separation is achieved solely by sawing or plasma etching.
[0072] J) Optional plasma etching of the ground underside of the carrier to reduce, for example, microcracks.
[0073] According to one embodiment, the functional material is applied in a structured manner. In other words, the functional layer is structured to adjust the resistance value. The functional layer can have a plurality of strips. Alternatively, a portion of the functional layer can be stepped, trapezoidal, or triangular. This results in different individual resistances that are connected in parallel between the electrode fingers, thus enabling trimming to the desired target resistance.
[0074] According to one exemplary embodiment, the electrodes are structured for adjusting the resistance value. The electrode fingers of at least one of the two electrodes can have different lengths. Alternatively or additionally, adjacent electrode fingers can have different spacings from one another. Alternatively or additionally, the electrode fingers can have different shapes. For example, at least one of the electrode fingers is trapezoidal or at least one of the electrode fingers can have a comb-shaped region. The comb-shaped region can have a plurality of teeth, which preferably point in the direction of the subsequent electrode finger.
[0075] The structured design of the electrodes and / or the functional layer creates individual laser-trimmable areas, which make it possible to adjust the resistance. The corresponding trimming increases the resistance to the target value. The individual trimmable / structured areas have a greater resistance than the non-structured areas. In a parallel circuit, in which the individual resistors are added as reciprocal values, this means that trimming larger resistors causes a small change in resistance across the entire sensor element. This makes it possible to provide a sensor element with a particularly narrow resistance tolerance.
[0076] The drawings described below are not to be considered to scale. Rather, individual dimensions may be enlarged, reduced, or distorted for clarity.
[0077] Elements that are identical or that perform the same function are designated by the same reference symbols.
[0078] It shows :
[0079] Figure 1 is an exploded view of a sensor element according to the prior art,
[0080] Figure 2 is a sectional view of the sensor element according to Figure 1 (state of the art),
[0081] Figure 3a is a plan view of a partial area of a sensor element according to a first embodiment,
[0082] Figure 3b is a plan view of a portion of a sensor element according to a further embodiment,
[0083] Figure 4 is a plan view of a partial area of a sensor element according to a further embodiment, Figure 5 is a plan view of a partial area of a sensor element according to a further embodiment,
[0084] Figure 6 is a plan view of a portion of a sensor element according to a further embodiment,
[0085] Figure 7 is a plan view of a portion of a sensor element according to a further embodiment.
[0086] Figures 1 and 2 show a representation of a sensor element 1 according to the prior art. The sensor element 1 serves to illustrate a basic structure of the sensor element 100 described below. Regarding the essential features of the sensor element 1 according to Figures 1 and 2, reference is made to German patent application DE 10 2020 122 923 A1.
[0087] The sensor element 1 is an NTC thin-film temperature sensor and has a carrier 2 with a top side 11 and a bottom side 12. The top side 11 of the carrier 2 has an insulating layer 3, for example, comprising SiO2. The sensor element 1 further has at least two electrodes 4a, 4b. The two electrodes 4a, 4b are formed spaced apart from one another on the insulating layer 3 of the carrier 2 and have thin metal films.
[0088] The electrodes 4a, 4b are designed as interdigital thin-film electrodes. In particular, the electrodes 4a, 4b each have a flat end region 6 and a region with electrode fingers 5. The region with the electrode fingers 5 is formed in a central region of the carrier 2. The flat end region 6 and the region with the electrode fingers 5 merge into one another. The two electrodes 4a, 4b each engage with one another in the region of the electrode fingers 5 in the central region of the carrier 2 and form an interdigital structure there. The electrode fingers 5 of the electrodes 4a, 4b are arranged alternately.
[0089] The sensor element 1 further has a functional layer 7 with a top side 14 and a bottom side 15. The functional layer 7 is an NTC thin film. The functional layer 7 only partially covers the insulating layer 3 on the top side 11 of the carrier 2. The functional layer 7 is preferably applied at least partially to the electrodes 4a, 4b. As can be seen from Figures 1 and 2, the electrodes 4a, 4b are formed between the carrier 2 and the functional layer 7, in particular on a bottom side 15 of the functional layer 7. The functional layer 7 lies directly on the area with the electrode fingers 5.
[0090] The sensor element 1 further comprises at least two contact pads 10a, 10b for electrically contacting the sensor element 1.
[0091] The sensor element 1 can further comprise a protective layer 8. The protective layer 8 completely covers a top side of the sensor element 1, with the exception of the contact pads 10a, 10b. The protective layer 8 has recesses 9 from which the contact pads 10a, 10b protrude for electrically contacting the sensor element 1. Due to the compact design of the individual components of the sensor element 1, the sensor element 1 is ideally suited for integration into MEMS or SESUB structures.
[0092] The basic design shown in Figures 1 and 2 is based on the principle of a parallel connection of individual resistors. However, in the design of sensor element 1 shown in Figures 1 and 2, the resistance cannot be adjusted to specific components. Therefore, the resistance variation cannot be adjusted within the required tolerances.
[0093] Figures 3a, 3b, and 4 to 7 each show a partial region of a sensor element 100. The sensor element 100 has essentially the same components as the sensor element 1 according to Figures 1 and 2. The basic structure of the sensor element 100 corresponds to the structure of the sensor element 1 of Figures 1 and 2, as already mentioned above. For details of the components and the functioning of the sensor element 100, reference is therefore made to the above description or to the document DE 10 2020 122 923 A1.
[0094] The sensor element 100 according to the invention has an operating temperature between -40 ° C and 125 ° C, including the limits. The dimensions of the sensor element 100 are preferably 300 pm x 500 pm x 50 pm. The sensor element 100 has a resistance value R for which the following applies: 10 kΩ < R (25 ° C) < 100 kΩ.
[0095] In contrast to sensor element 1, the resistance of sensor element 100 according to Figures 3 to 7 can be adjusted component-specifically. This can be achieved through various variants of the layer structure of sensor element 100, which are described in detail below. In particular, the structure of functional layer 7 and / or electrodes 4a, 4b is adapted / modified compared to sensor element 1.
[0096] A width and / or shape of the functional layer 7 and / or a length of the electrode fingers 5 and / or a distance (gap width) between the electrode fingers 5 and / or a number of the electrode fingers 5 or the distances (gaps) between the electrode fingers 5 influences the resistance value of the sensor element 100.
[0097] The relationship between the resistance and the interdigital structure of the electrodes 4a, 4b is shown in particular in the following Table 1:
[0098] Table 1 : Relationship between the structure of the electrodes and the resistance value .
[0099] The table shows that the resistance of the sensor element 100 at an operating temperature of 25 ° C decreases with an increasing number of electrode fingers 5 / number of gaps between the electrode fingers 5 as well as an increasing length of the electrode fingers 5 and a decreasing distance (gap width) between the electrode fingers 5. Thus, in variant B with a greater length and number of electrode fingers 5 and a smaller distance between the electrode fingers 5, a resistance of R (25 ° C) = 12 kQ is to be expected. In variant A with a shorter length, number and larger distance, a resistance of R (25 ° C) = 50 kQ is present.
[0100] Thus, the resistance value can be specifically influenced by targeted structuring of the interdigital structure of the electrodes 4a, 4b or the functional layer 7. This will be described in more detail in connection with Figures 3A to 7.
[0101] The structured design of the electrodes 4a, 4b and / or the functional layer 7 creates individual laser-trimmable regions, which allows for resistance adjustment. The initial resistance of the functional layer 7 is selected such that it lies within the tolerance window for low resistance values. Appropriate trimming increases the resistance to the target value.
[0102] The individual trimmable / structured regions have a greater resistance than the non-structured regions of the base structure (sensor element 1). In a parallel circuit, where the individual resistors are added as reciprocals, this means that trimming larger resistors results in a small change in resistance across the entire sensor element 100. Trimming is performed using a suitable laser.
[0103] In the embodiment according to Figure 3a, the functional layer 7 is structured. In particular, in contrast to the basic structure, the functional layer 7 is structured in such a way that individual strips 7a are formed, which are perpendicular to the electrode fingers 5 and are contacted via them. This results in several individual resistors that are connected in parallel between the electrode fingers 5.
[0104] A width b of the strips 7a can be the same for all strips 7a or it can vary, so that, for example, (very) narrow, medium, and wide strips 7a are combined, thus providing greater variance in the resistance setting. The strips 7a can only partially cover the electrode fingers 5, as shown in Figure 3a. Alternatively, the strips 7a can also be formed in at least part of the flat end region 6 of the electrodes 4a, 4b (not explicitly shown).
[0105] Trimming is performed with the aid of a laser. It can be performed in two ways. Depending on the type of laser used, either the functional layer 7 (in particular individual strips 7a of the functional layer 7) or one or more electrode fingers 5 can be severed.
[0106] In this embodiment, the electrode fingers 5 can be severed both in the transition region of the electrode fingers 5 to the flat end regions 6 of the electrode 4a, 4b and in a region between the individual strips 7a of the functional layer 7.
[0107] In the embodiment according to Figure 3b, an electrode finger 5 of one of the electrodes 4a, 4b is additionally structured. In particular, in this embodiment, an outer electrode finger 5 of the electrode 4a is trapezoidal. Furthermore, several electrode fingers 5 can also be structured, or alternatively or additionally, one of the inner electrode fingers 5 can be structured (not explicitly shown).
[0108] The specific design of at least one electrode finger 5 results in an even finer adjustment of the resistance through a wider spread of the trimmable individual resistors between adjacent electrode fingers 5.
[0109] Here, too, trimming (depending on the laser used) can be performed by severing individual strips 7a of the functional layer 7 or the electrode fingers 5. The electrode fingers 5 can be severed both in the transition region of the electrode fingers 5 to the flat end regions 6 of the electrode 4a, 4b and in a region between the individual strips 7a of the functional layer 7.
[0110] In the exemplary embodiment according to Figure 4, the functional layer 7 is structured. In particular, the functional layer 7 has a stepped structure. Alternatively, the functional layer can also be trapezoidal or triangular (not explicitly shown). Unlike in the exemplary embodiments shown in Figures 3a and 3b, the functional layer here does not have a plurality of discrete individual elements, but is formed in one piece.
[0111] Despite the planar design, the functional layer 7 covers only a partial area, in particular partial areas of different sizes, of the individual electrode fingers 5. The functional layer 7 can also extend into the planar end area 6 of the electrodes 4a, 4b (not explicitly shown), i.e., the overall width of the functional layer 7 can vary.
[0112] This results in different individual resistances that are connected in parallel between the electrode fingers 5, thus enabling trimming to the desired target resistance. Trimming is performed by separating at least one electrode finger 5 using a laser.
[0113] In the exemplary embodiment according to Figure 5, one of the electrodes 4a, 4b is structured. In particular, the electrode 4a has electrode fingers 5 of different lengths, whereby the structuring can alternatively or additionally also be formed on the electrode 4b.
[0114] The electrode finger shown at the very bottom in Figure 5 (lower outer electrode finger 5) is the shortest electrode finger 5. The electrode finger shown at the very top in Figure 5 (upper outer electrode finger 5) is the longest electrode finger 5. Of course, another electrode finger 5, for example a middle electrode finger 5, can be shorter or longer than the other electrode fingers 5. In other words, the length of the electrode fingers 5 and the arrangement of the electrode fingers 5 of different lengths can be freely selected depending on the desired resistance value.
[0115] In this exemplary embodiment, the functional layer 7 is flat or rectangular in shape, analogous to the basic structure described in connection with Figures 1 and 2. However, the functional layer 7 can also extend into the flat end region 6 of the electrodes 4a, 4b (not explicitly shown). In other words, the width of the functional layer 7 or a width of the region of the electrodes 4a, 4b covered by the functional layer 7 can vary. By varying the width, the resistance value can be influenced, as already mentioned above.
[0116] The different lengths of the electrode fingers 5 result in different individual resistances which are connected in parallel between the electrode fingers 5 and thus enable trimming to the desired target resistance.
[0117] Here, too, trimming is performed by cutting at least one electrode finger 5 using a laser. Unlike the embodiments with a structured functional layer 7, cutting the electrode fingers 5 is only possible in the transition region of the electrode fingers 5 to the flat end regions 6 of the electrode 4a, 4b (the region of the electrode fingers 5 not covered by the functional layer 7).
[0118] In the exemplary embodiment according to Figure 6, the electrode fingers 5 are spaced at different distances from one another. In particular, the specific design of the electrodes 4a, 4b allows a distance A between adjacent electrode fingers 5 to be varied. As described above, the resistance value of the sensor element 100 is influenced by changing the distance A between the electrode fingers 5 (see Table 1).
[0119] Thus, the electrode fingers 5, which are shown at the bottom of Figure 6, have a greater distance A from one another than the other electrode fingers 5. This configuration is not limited to this specific embodiment; rather, the distance A between adjacent electrode fingers 5 can be increased or decreased as desired, depending on the desired resistance values. The distance A can be varied between only one adjacent pair of electrode fingers or between several pairs of electrode fingers.
[0120] This special design allows for additional trimming areas with varying distances. This provides the option of even finer gradation of the resistance setting.
[0121] In the exemplary embodiment according to Figure 7, at least one electrode finger 5 is structured. In particular, one electrode finger 5 (in this exemplary embodiment, an outer electrode finger 5 of the electrode 4b) has a comb-shaped region. However, a corresponding comb-shaped region can also be provided on further or other outer electrode fingers 5 (not explicitly shown).
[0122] The comb-shaped region has a plurality of teeth 20. These point in the direction of the following electrode finger 5. The teeth 20 are configured with different lengths. Alternatively or additionally, the teeth 20 can also be configured with different widths.
[0123] The functional layer 7 does not extend completely over the structured electrode finger 5, as can be seen from Figure 7. Rather, the functional layer 7 only partially covers the structured electrode finger 5. In this exemplary embodiment, the functional layer can also be made even wider and extend in particular up to the flat end regions 6 and even partially over the flat end regions 6 of the electrodes 4a, 4b (see functional layer 22 indicated by dashed lines). As already mentioned above, the resistance value is influenced by varying the width of the functional layer 7.
[0124] The comb-shaped structured area of the electrode finger 5 allows for greater variance in the resistance setting. This results in different individual resistances, which enable trimming to the desired target resistance. Trimming is performed by separating the structured electrode finger 5 with the aid of a laser (see exemplary separation area 21).
[0125] A method for manufacturing the sensor element 100 is described below. Preferably, the method produces a plurality of sensor elements 100 according to one of the exemplary embodiments described above (see Figures 3a, 3b and 4 to 7). All features described in connection with the sensor element 100 therefore also apply to the method, and vice versa.
[0126] In a first step A), a carrier material is provided for forming the carrier 2 described above. The carrier material preferably comprises Si, SiC, GaN, or glass. Alternatively, the carrier material may comprise SiβN, AlN, or Al2O3. The carrier 2 has a top side 11 and a bottom side 12. The carrier 2 preferably has a maximum edge length L of less than 500 pm.
[0127] Subsequently, an electrically insulating layer 3 is formed on the upper side 11 of the carrier 2. For example, the insulating layer 3 comprises SiO2. Ideally, an insulating layer 3 with a thickness of up to 1.5 pm is produced on the upper side 11 of the carrier 2. In a further step B), at least two electrodes 4a, 4b are formed / deposited on the carrier 2. The deposition takes place using a PVD or CVD process or galvanically.
[0128] The electrodes 4a, 4b can be single-layer or multi-layer and comprise, for example, Cu, Au, Ni, Cr, Ag, Ti, Ta, W, Pd, or Pt. The electrodes 4a, 4b are designed as thin-film electrodes. The electrodes 4a, 4b each have a flat end region 6 and a plurality of electrode fingers 5.
[0129] The structuring of the electrodes 4a, 4b takes place in a subsequent process, this can be, for example, wet-chemical etching or dry etching or laser structuring. The electrode fingers 5 of at least one of the two electrodes 4a, 4b can have a different length (Figure 5). Alternatively or additionally, adjacent electrode fingers 5 can have a different distance A from one another (Figure 6). Alternatively or additionally, the electrode fingers 5 can have a different shape (Figures 3b, 7). For example, at least one of the electrode fingers 5 is trapezoidal or step-shaped or at least one of the electrode fingers 5 can have a comb-shaped region with teeth 20. The resistance value of the sensor element 100 is influenced by the structuring. The structuring creates a laser-trimmable region for adjusting the resistance value of the sensor element 100.Additionally or alternatively, the functional layer 7 can also have a structure (Figures 3a, 3b, 4). The resistance of the sensor element 100 is also influenced by the structure of the functional layer 7. In a further step C), a functional material is applied to form a functional layer 7. This is done, for example, by sputtering or a spin-coating process. The functional material is first applied over the entire area and then structured in a further process (for example, by wet-chemical etching, dry etching, or laser structuring). The functional layer 7 preferably has a thickness of between 250 nm and 400 nm.
[0130] Alternatively, step C) can also be carried out before step B), so that the functional material 7 is sputtered directly onto the insulating layer 3 of the carrier 2 and then the electrodes 4a, 4b are applied to the functional layer 7.
[0131] The functional material comprises an NTC ceramic based on an oxide material with a perovskite or spinel structure. Alternatively, the functional material can also be based on a carbide or nitride material. In another alternative, the functional material comprises or consists of thin films of vanadium oxide or SiC.
[0132] The functional layer 7 only partially covers the upper side of the carrier 2 or the electrodes 4a, 4b. The functional layer 7 can be structured to adjust the resistance value of the sensor element 100. The functional layer 7 can, for example, be strip-shaped (Figures 3a, 3b). Alternatively, the functional layer 7 can be stepped, trapezoidal or triangular (Figure 4). Alternatively or additionally, the width of the functional layer can be varied. This results in different individual resistances that are connected in parallel between the electrode fingers 5 and thus enable trimming to the desired target resistance. The initial resistance of the functional layer 7 is selected such that it is within the tolerance window for low resistance values.
[0133] In a further step D), the functional layer 7 is subjected to a heat treatment to form the structure or properties.
[0134] Subsequently, functional layer 7 is measured. The initial resistance value is determined so that the resistance can be adjusted to the desired value in the next step.
[0135] In a next step E), the resistance value is adjusted by trimming at least one of the electrodes 4a, 4b and / or the functional layer 7 using a laser. Trimming is preferably performed in situ.
[0136] The resistance value is set to a predetermined nominal value (target value). Due to the precise setting of the resistance value, the finished sensor element 100 has a very narrow resistance tolerance. To set the resistance value, at least one of the electrode fingers 5 and / or at least a partial area of the functional layer 7 is severed with the aid of the laser. In particular, the previously described structured areas are severed.
[0137] In a next step F), a protective layer 8 is formed. The protective layer 8 can comprise oxides, nitrides, ceramics, glasses, or polymers and is produced by means of a PVD or CVD process and structured by means of wet-chemical etching or dry etching. The protective layer 8 has a thickness of < 10 gm, preferably < 5 gm, particularly preferably < 1 gm. Ideally, the protective layer 8 has a thickness of < 1.5 gm and completely covers the upper side of the sensor element 100 with the exception of the contact pads 10a, 10b.
[0138] Subsequently, in step G), contact pads 10a, 10b are formed on at least a partial region of the electrodes 4a, 4b. One contact pad 10a, 10b is formed directly on the flat end region 6 of each electrode 4a, 4b. In one embodiment, the contact pads 10a, 10b comprise metals such as Cu, Al, or Au and have a thickness of > 5 μm. In particular, the contact pads 10a, 10b protrude above the surface 13 of the sensor element 100 in the finished sensor element 100. Alternatively, bumps can be formed instead of the contact pads.
[0139] In a further step H), the sensor elements 100 are separated. This can be done, for example, by plasma etching or sawing. The carrier 2 is not sawn through, but only cut to a defined thickness.
[0140] By subsequent optional grinding from the rear side (a grinding process), material is removed from the rear side of the carrier 2 down to a defined final component thickness in a final step I). This step results in the actual separation of the sensor elements 100. If a thicker design of the sensor element 100 is desired, step I) can also be omitted. In this case, the separation of the sensor elements 100 is carried out solely by sawing or plasma etching. The assembly of the separated sensor elements 100 can take place on the upper side via thin wire bonding on the contact pads. The description of the objects specified here is not limited to the individual special embodiments.
[0141] Rather, the features of the individual embodiments can be combined with one another as desired – as long as this is technically feasible.
[0142] Reference symbol list
[0143] 1 , 100 sensor element
[0144] 2 carriers
[0145] 3 I insulating layer
[0146] 4a, b Electrode
[0147] 5 electrode fingers
[0148] 6 End area
[0149] 7 Functional layer
[0150] 7a stripes
[0151] 8 protective layer
[0152] 9 Recess
[0153] 10a, b contact pad
[0154] 11 Top of the carrier
[0155] 12 Underside of the carrier
[0156] 13 Surface of the sensor element
[0157] 14 Top of the functional layer
[0158] 15 Underside of the functional layer
[0159] 20 teeth
[0160] 21 Separation area
[0161] 22 Functional layer
[0162] D Thickness of the sensor element
[0163] L edge length of the beam
[0164] A Distance between adjacent electrode fingers b Width of the strips
Claims
Patent claims 1. Sensor element (100) for measuring a temperature, comprising - at least one carrier (2) with a top side (11) and a bottom side (12), wherein an electrically insulating layer (3) is formed on the top side (11) of the carrier (12), - at least one functional layer (7) comprising a material with a temperature-dependent electrical resistance, wherein the functional layer (7) is arranged on the electrically insulating layer (3), - at least two electrodes (4a, 4b) which are formed on the carrier (2) at a distance from one another, wherein the respective electrode (4a, 4b) has a plurality of electrode fingers (5), wherein the electrode fingers (5) of the two electrodes (4a, 4b) are arranged alternately with one another, - at least two contact pads (10a, 10b) for electrically contacting the sensor element (100), wherein in each case one contact pad (10a, 10b) is arranged directly on a partial area of one of the electrodes (4a, 4b), wherein the sensor element (100) is designed to be integrated as a discrete component directly into an electrical system, wherein the sensor element (100) has a narrow resistance tolerance and wherein the at least one functional layer (7) and / or at least one of the at least two electrodes (4a, 4b) are structured for adjusting the resistance value.
2. Sensor element (100) according to claim 1, wherein the functional layer (7) only partially covers the electrode fingers (5).
3. Sensor element (100) according to claim 1 or claim 2, wherein a width of the functional layer (7) varies.
4. Sensor element (100) according to one of the preceding claims, wherein the functional layer (7) has a plurality of strips (7a) which are arranged spaced apart and parallel to one another on the upper side (11) of the carrier (2).
5. Sensor element (100) according to claim 4, wherein the strips (7a) are perpendicular to the electrode fingers (5) are trained and are contacted through them.
6. Sensor element according to one of claims 4 or 5, wherein a width (b) of the strips (7a) for all strips (7a) is the same or wherein a width (b) of the strips (7a) varies.
7. Sensor element according to one of claims 4 to 6, wherein at least a partial area of a strip (7a) and / or at least a partial area of an electrode finger (5) is severed in order to adjust the resistance value of the sensor element (100).
8. Sensor element (100) according to one of claims 1 to 3, wherein the functional layer (7) is stepped, trapezoidal or triangular.
9. Sensor element (100) according to claim 8, wherein at least one electrode finger (5) is severed to adjust the resistance value.
10. Sensor element (100) according to one of the preceding claims, wherein at least one of the electrode fingers (5) has a different shape than the remaining electrode fingers and wherein the at least one electrode finger (5) is trapezoidal or triangular.
11. Sensor element (100) according to one of the preceding claims, wherein the electrode fingers (5) of at least one of the at least two electrodes (4a, 4b) are of different lengths.
12. Sensor element (100) according to claim 11, wherein at least one of the electrode fingers (5) of different lengths is severed in order to adjust the resistance value.
13. Sensor element (100) according to one of the preceding claims, wherein a distance (A) between adjacent electrode fingers (5) varies.
14. Sensor element (100) according to one of the preceding claims, wherein at least one of the electrode fingers (5) has a comb-shaped region, wherein the comb-shaped region has a plurality of teeth (20) pointing in the direction of the subsequent electrode finger (5).
15. Sensor element (100) according to claim 14, wherein the comb-shaped region is formed on one of the outer electrode fingers (5).
16. Sensor element (100) according to claim 14 or 15, wherein the teeth (20) are of different lengths and / or different widths.
17. Sensor element (100) according to one of claims 14 to 16, wherein for adjusting the resistance value of the sensor element (100) at least a partial region of the electrode finger (5) is severed with the comb-shaped region.
18. Sensor element (100) according to one of the preceding claims, wherein the respective electrode (4a, 4b) is designed as a thin-film electrode.
19. Sensor element (100) according to one of the preceding claims, wherein the functional layer (7) is a thin film with NTC characteristics.
20. Sensor element (100) according to one of the preceding claims, wherein the sensor element (100) is designed for direct integration into a MEMS structure and / or into a SESUB structure.
21. Sensor element (100) according to one of the preceding claims, wherein the carrier (2) comprises silicon, silicon carbide or glass or wherein the carrier (2) comprises SiβN, AlN, GaN or Al2O3 as carrier material.
22. Sensor element (100) according to one of the preceding claims, wherein the functional layer (7) comprises an NTC ceramic based on an oxidic material in the perovskite or spinel structure type or wherein the functional layer (7) comprises an NTC ceramic based on a carbide or a nitride material.
23. Sensor element (100) according to one of the preceding claims, wherein the electrodes (4a, 4b) are formed in a single layer or in multiple layers and comprise at least one material or a material combination of Cu, Au, Ni, Cr, Ag, Ti, Ta, W, Pd and / or Pt.
24. Sensor element (100) according to one of the preceding claims, wherein the contact pads (10a, 10b) are formed in a single layer or in multiple layers and comprise at least one material or a material combination of Cu, Au, Ni, Cr, Ag, Ti, Ta, W, Pd and / or Pt.
25. Sensor element (100) according to one of the preceding claims, wherein the insulating layer (3) is formed as a single layer or a multi-layer and comprises Al2O3, AlN, SiO2 or SiSn4 or combinations of layers of these materials.
26. Sensor element (100) according to one of the preceding claims, further comprising a protective layer (8), wherein the protective layer (8) completely covers an upper side of the sensor element (100) with the exception of the contact pads (10a, 10b).
27. Sensor element (100) according to claim 26, wherein the protective layer (8) is formed in a single layer or in multiple layers and comprises Al2O3, AlN, SiCb or SiSn4 or combinations of layers of these materials.
28. Sensor element (100) according to claim 26 or 27, wherein the protective layer (8) comprises oxides, nitrides, ceramics, glasses or plastic as material.
29. A method for producing a sensor element (100) comprising the following steps: A) Providing a carrier material with an insulating layer (3) for forming a carrier (2); B) forming at least two electrodes (4a, 4b) on the carrier (2), wherein the respective electrode (4a, 4b) has a plurality of electrode fingers (5), wherein the electrode fingers (5) of the two electrodes (4a, 4b) are arranged alternately to one another; C) applying a functional material to a partial area of the electrodes (4a, 4b) to form a functional layer (7); D) temperature treatment of the functional layer (7); E) Adjusting the resistance value by trimming at least a partial area of the electrodes (4a, 4b) and / or the functional layer (7) by means of a laser.
30. The method according to claim 29, wherein the functional layer (7) and / or at least one of the electrodes (4a, 4b) are structured, and wherein an initial resistance of the functional layer (7) is selected such that it lies within a tolerance window at low resistance values, wherein a resistance of the sensor element (100) is increased to a desired value by trimming the structured areas.
31. Method according to claim 29 or 30, wherein in step E) at least a partial area of the electrode fingers (5) and / or at least a partial area of the functional layer (7) is severed in order to adjust the resistance value.
32. Method according to one of claims 29 to 31, wherein a measurement of the functional layer (7) takes place before step E).
33. The method according to any one of claims 29 to 32, further comprising the following steps: F) applying a protective layer (8) to an upper side of the sensor element (100), wherein the protective layer (8) completely covers the upper side except for two partial areas; G) forming contact pads (10a, 10b) in the partial areas free from the protective layer for electrically contacting the sensor element (100); H) Separating the sensor elements (100) .
34. Method according to one of claims 29 to 33, comprising the further steps: I) optional grinding of the sensor elements (100) from a bottom side, wherein material is removed from the back of the carrier (2) by a grinding process up to a defined final component thickness, whereby the sensor elements (100) be isolated; J) optional plasma etching of the ground underside of the carrier (2) to reduce microcracks.
35. Method according to one of claims 29 to 34, wherein the functional layer (7) comprises a plurality of strips (7a) or wherein the functional layer (7) is formed in a stepped, trapezoidal or triangular manner.
36. Method according to one of claims 29 to 35, wherein a width of the functional layer (7) varies.
37. Method according to one of claims 29 to 36, wherein the electrode fingers (5) of at least one of the two electrodes (4a, 4b) have a different length and / or wherein adjacent electrode fingers (5) have a different distance (A) from one another and / or wherein the electrode fingers (5) have a different shape.
38. The method according to claim 37, wherein at least one of the electrode fingers (5) is trapezoidal or triangular or wherein at least one of the electrode fingers (5) has a comb-shaped region, wherein the comb-shaped region has a plurality of teeth (20) pointing in the direction of the subsequent electrode finger (5).