SKIN CARE AND / OR MAKE-UP PROCESS

A skin care and makeup composition with C14-C30 fatty alcohol, anionic surfactant, and acrylic polymer addresses the issues of greasiness and stickiness, ensuring easy application and stability.

FR3155135B3Active Publication Date: 2025-12-12LOREAL SA
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Patent Information

Application Number
FR2023014374
Authority / Receiving Office
FR · FR
Patent Type
Utility models
Current Assignee / Owner
Priority Date
2023-11-15
Filing Date
2023-12-18
Publication Date
2025-12-12
Estimated Expiration
2033-12-18

AI Technical Summary

Technical Problem

Existing skin care and makeup compositions provide an unpleasant greasy and sticky sensation, are difficult to apply evenly, and lack stability during storage.

Method used

A composition comprising C14-C30 fatty alcohol, at least 0.3% anionic surfactant, and an acrylic polymer, preferably in an oil-in-water emulsion, ensuring easy application and a non-greasy, non-sticky feel while maintaining stability.

Benefits of technology

The composition provides a stable, easy-to-apply solution with a non-greasy and non-sticky sensation, maintaining uniform application and preventing phase separation during storage.

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Abstract

SKIN CARE AND / OR MAKE-UP METHOD The present invention relates to a skin care and makeup method comprising the application to the skin of a composition comprising: (i) at least one C14-C30 fatty alcohol; (ii) more than 0.3% by weight of at least one anionic surfactant selected from C14-C22 alkyl sulfate, relative to the total weight of the composition; and (iii) at least one acrylic polymer. Figure for the abstract: none
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Description

Title of the invention: SKIN CARE AND / OR MAKE-UP METHOD technical field

[0001] The present invention relates to a method for the care and / or makeup of keratinous materials. In particular, the present invention relates to a skin care method. STATE OF THE ART

[0002] The development of formulas dedicated to skin and / or lip care and / or makeup is ongoing. These formulas must have satisfactory properties in terms of application, such as ease of use, and also in terms of sensory properties, such as a non-greasy and non-sticky feeling after application.

[0003] A wide variety of cosmetic compositions are used to care for the skin, particularly to provide hydration. These compositions typically contain lipophilic moisturizing agents that inhibit water loss by occlusion. For example, efforts have been made to formulate compositions in the form of creams or emulsions. Thanks to the thick texture of these compositions, it is possible to provide the skin with a moisturizing sensation through occlusion.

[0004] However, these types of products are still not satisfactory.

[0005] Consumers experience an unpleasant greasy feeling after applying the product. In addition, due to the thick texture of the products, it is not easy to apply them evenly to the skin and the change in texture is not very good.

[0006] It is therefore always necessary to implement a skin care process which can provide a non-greasy and non-sticky sensation.

[0007] It is also desired that the composition used in the process be stable and that it can be applied easily. Summary of the invention

[0008] An objective of the present invention is to propose a method for skin care and / or makeup, the composition used in the method is stable and can be easily applied to the skin and can provide a non-greasy and non-sticky sensation.

[0009] Therefore, the present invention relates to a method for skin care and / or makeup, comprising the application to the skin of a composition comprising:

[0010] (i) at least one C14-C30 fatty alcohol;

[0011] (ii) more than 0.3% by weight of at least one anionic surfactant selected from sulfate of C14-C22 alkyl, relative to the total weight of the composition; and

[0012] (iii) at least one acrylic polymer.

[0013] Preferably, the composition used in the process of the present invention is in the form of an oil-in-water emulsion.

[0014] The composition used in the process of the present invention is easily applied evenly to the skin, without long massage with the fingers.

[0015] The composition used in the process of the present invention may have a non-greasy and non-sticky feel.

[0016] The composition used in the process of the present invention is stable, that is to say, it does not exhibit phase separation after storage for 1 month at 55 °C.

[0017] Other features and advantages of the invention will become clearer upon reading the description and examples that follow. DETAILED DESCRIPTION OF THE INVENTION

[0018] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as that commonly understood by a person skilled in the art in the field covered by the present invention. Where the definition of a term in this description conflicts with the meaning commonly understood by a person skilled in the art in the field covered by the present invention, the definition described herein shall apply.

[0019] In what follows and unless otherwise indicated, the limits of a range of values ​​are included in that range, in particular in the expressions "between...and..." and "from...to...".

[0020] Furthermore, the expression "at least one" used in this description is equivalent to the expression "one or more".

[0021] Throughout this application, the term "including" shall be interpreted as encompassing all the specifically mentioned features as well as optional, additional, unspecified features. As used herein, the use of the term "including" also discloses the embodiment in which no features other than the specifically mentioned features are present (i.e., "consisting of").

[0022] In the present invention, all percentages refer, unless otherwise specified, to a percentage by weight.

[0023] The composition used in the process according to the present invention comprises:

[0024] (i) at least one C14-C30 fatty alcohol;

[0025] (ii) more than 0.3% by weight of at least one anionic surfactant selected from C14-C22 alkyl sulfate, relative to the total weight of the composition; and

[0026] (iii) at least one acrylic polymer. C14-C30 Fatty Alcohols

[0027] The composition used in the process of the present invention comprises at least one C14-C30 fatty alcohol.

[0028] The expression "fatty alcohol" refers to any alcohol having the structure R—OH, in which R designates a linear hydrocarbon chain, saturated or unsaturated.

[0029] The expression "hydrocarbon chain" refers to an organic group consisting mainly of hydrogen atoms and carbon atoms.

[0030] The alcohol or fatty alcohols present in the composition according to the invention comprise a hydrocarbon chain comprising 14 to 30 carbon atoms.

[0031] Preferably, the C14-C30 fatty alcohol comprises a hydrocarbon chain that is a linear alkyl or alkenyl comprising 14 to 30 carbon atoms, more preferably, the C14-C30 fatty alcohol comprises a hydrocarbon chain that is a linear alkyl or alkenyl comprising 14 to 22 carbon atoms.

[0032] The C14-C30 fatty alcohol or alcohols suitable for the composition of the present invention, for example, are myristyl alcohol (1-tetradecanol), cetyl alcohol (1-hexadecanol), palmitoleyl alcohol (cis-9-hexadecen-l-ol), cetearyl alcohol, stearyl alcohol (1-octadecanol), arachidyl alcohol (1-eicosanol), behenyl alcohol (1-docosanol), erucyl alcohol (cis-13-docosen-l-ol), lignoceryl alcohol (1-tetracosanol), ceryl alcohol (1-hexacosanol), myricyl alcohol and melissyl alcohol (1-triacontanol).

[0033] Preferably, the C14-C30 fatty alcohol is selected from cetyl alcohol (1-hexadecanol), stearyl alcohol (1-octadecanol), cetearyl alcohol, arachidyl alcohol (1-eicosanol), behenyl alcohol (1-docosanol) and mixtures thereof.

[0034] More preferably, the C14-C30 fatty alcohol is chosen from cetyl alcohol (1-hexadecanol), stearyl alcohol (1-octadecanol), cetearyl alcohol, behenyl alcohol (1-docosanol) and mixtures thereof.

[0035] In some embodiments, the composition of the present invention comprises cetearyl alcohol.

[0036] Advantageously, the C14-C30 fatty alcohol is present in the composition according to the present invention in an amount ranging from 2% by weight to 20% by weight, preferably from 3% by weight to 15% by weight, more preferably from 3% by weight to 8% by weight, relative to the total weight of the composition. Anionic surfactants

[0037] The composition used in the process of the present invention comprises more than 0.3% by weight of at least one anionic surfactant selected from C14-C22 alkyl sulfate, relative to the total weight of the composition.

[0038] Preferably, the anionic surfactant is chosen from tetradecyl sulfate ammonium, sodium tetradecyl sulfate, potassium tetradecyl sulfate, ammonium hexadecyl sulfate, sodium hexadecyl sulfate, potassium hexadecyl sulfate, ammonium octadecyl sulfate, sodium octadecyl sulfate, potassium octadecyl sulfate, ammonium cetearyl sulfate, sodium cetearyl sulfate, potassium cetearyl sulfate, and their combinations.

[0039] More preferably, the anionic surfactant is chosen from ammonium cetearyl sulfate, sodium cetearyl sulfate, potassium cetearyl sulfate and their combinations.

[0040] According to some preferred embodiments of the present invention, the anionic surfactant is sodium cetearyl sulfate.

[0041] Advantageously, the anionic surfactant is present in the composition according to the present invention in an amount ranging from 0.35% by weight to 6% by weight, preferably from 0.4% by weight to 5% by weight, more preferably from 0.4% by weight to 4% by weight, even more preferably from 0.5% by weight to 3% by weight, relative to the total weight of the composition. Acrylic polymers

[0042] The composition used in the process of the present invention comprises at least one acrylic polymer.

[0043] Preferably, the acrylic polymer is chosen from acrylic copolymers having a hydrophobic fatty chain having 8 to 40 carbon atoms.

[0044] Preferably, the acrylic polymer is chosen from copolymers derived from 2-acrylamido-2-methylpropanesulfonic acid (AMPS) and polyoxyalkylated C8-C40 alkyl (meth)acrylates, the number of moles of oxyalkylene motifs ranges from 1 to 30 mol, preferably from 3 to 25 mol and more preferably from 5 to 25 mol, which are also called AMPS copolymers.

[0045] The AMPS^ copolymers according to the invention can be crosslinked or non-crosslinked, neutralized or non-neutralized.

[0046] Among the crosslinking agents that may be suitable for use, the following may be mentioned without limitation: methylene bisacrylamide, allyl methacrylate and trimethylolpropane triacrylate (TMPTA).

[0047] The degree of crosslinking generally ranges from 0.01% in moles to 10% in moles and more particularly from 0.2% in moles to 2% in moles relative to the copolymer.

[0048] A polyoxyalkylene chain can be formed from ethylene oxide motifs and / or propylene oxide motifs and, more particularly, can be formed solely from ethylene oxide motifs.

[0049] The acrylic polymer that can be used in the process according to the invention can be partially or totally neutralized with a mineral base (sodium hydroxide, potassium hydroxide or ammonia) or an organic base such as mono- ethanolamine, diethanolamine, triethanolamine, an aminomethylpropanediol, N-methylglucamine, basic amino acids, for example arginine and lysine, and mixtures of these compounds.

[0050] Examples include amphiphilic copolymers, cross-linked or non-cross-linked, comprising, or even formed from:

[0051] 2-acrylamido-2-methylpropanesulfonic acid (AMPS^) motifs of formula (A) below: ......- (HAS)

[0052] in which X may be a proton, an alkali metal cation, an alkaline earth metal cation or an ammonium ion;

[0053] and formula motifs (B) below: ^7 <B) --CHj--,,---

[0054] in which:

[0055] n and p, independently of each other, denote a number of moles and range from 0 to 30, in particular from 1 to 25 and more particularly from 3 to 25, provided that n + p is less than or equal to 30;

[0056] R27 designates a hydrogen atom or a linear or branched Ci-C6 alkyl radical, And

[0057] R29 designates a linear or branched alkyl radical comprising 8 to 40 atoms of carbon.

[0058] In formula (A), the cation X may more particularly designate sodium or ammonium.

[0059] Examples include, in particular:

[0060] non-crosslinked copolymers for which p = 0, n = 7 or 25, R27 denotes methyl and R29 represents a C18 alkyl or a mixture of C16 and C18 alkyl, and

[0061] crosslinked copolymers for which p = 0, n = 8 or 25, R27 designates methyl and R29 represents a Cl8 alkyl or a mixture of C16 alkyl and Cl8 alkyl.

[0062] These copolymers are described and synthesized in document EP 1 069 142.

[0063] The molar percentage concentration of the formula motifs (A) and the formula motifs (B) in an acrylic polymer according to the invention can vary depending on the desired cosmetic application, the nature and rheological properties of the composition used in the process of the present invention.

[0064] It can be between 0.1 and 99.9% by moles.

[0065] The molar proportion of the formula (A) motifs in an acrylic polymer according to the invention can preferably range from 0.1% to 50%, more particularly from 1% to 25% and even more particularly from 3% to 10%.

[0066] The molar proportion of the formula (B) motifs in an acrylic polymer according to the invention can preferably range from 50.1% to 99.9%, more particularly from 60% to 95% and even more particularly from 65% to 90%.

[0067] The distribution of monomers in the polymers of the invention can be, for example, alternating, block (including multiblock) or random.

[0068] By way of example, and without limitation, the following commercial references may be cited: Aristoflex^ HMS and Aristoflex^ HMB sold by Clariant, these two references being relating to crosslinked polymers.

[0069] Aristoflex^ HMS is the name of the AMPS❖ / ethoxylated cetearyl methacrylate (25 EO) 80 / 20 copolymer, crosslinked with trimethylolpropane triacrylate (TMPTA) or ammonium acryloyldimethyltaurate / stearate-25 methacrylate crosspolymer as INCI name.

[0070] As an INCI name, Aristoflex^ HMB is an ammonium acryloyldimethyltaurate / Beheneth-25 methacrylate crosspolymer.

[0071] More preferably, the acrylic polymer is chosen from copolymers optionally derived from a crosslinked and / or neutralized copolymer of AMPS and polyoxyethylenated alkyl methacrylate, the alkyl containing from 7 to 30 carbon atoms, in particular from 8 to 22 carbon atoms, the number of moles of oxyethylene motifs ranges from 1 to 30 mol, preferably from 3 to 25 mol and more preferably from 5 to 25 mol.

[0072] More preferably, the acrylic polymer is chosen from ammonium acryloyldimethyltaurate / beheneth-25 methacrylate crosslinked polymer, ammonium acryloyldimethyltaurate / stearate-25 methacrylate crosslinked polymer, and their combinations.

[0073] According to a more preferred embodiment, the composition used in the process of the present invention comprises a crosslinked polymer of ammonium acryloyldimethyltaurate / steareth-25 methacrylate.

[0074] Advantageously, the acrylic polymer is present in the composition used in the process according to the present invention in an amount ranging from 0.01% by weight to 9% by weight, preferably from 0.1% by weight to 4% by weight, and more preferably tiellement from 0.1% by weight to 2% by weight, relative to the total weight of the composition. Humectants

[0075] Preferably, the composition used in the process of the present invention comprises one or more humectants.

[0076] Preferably, the humectant is chosen from polyhydric alcohols.

[0077] As used here, the expression "polyhydric alcohol" refers to an alcohol comprising more than one hydroxyl.

[0078] More preferably, the humectant is chosen from glycerin, butylene glycol, panthenol, hexylene glycol, polyethylene glycol, polypropylene glycol, propylene glycol, sorbitol, and their combinations.

[0079] Most preferably, the humectant is glycerin.

[0080] Advantageously, the humectant is present in the composition used in the process of the present invention in an amount ranging from 0.1% by weight to 30% by weight, preferably from 1% by weight to 25% by weight, and more preferably from 3% by weight to 20% by weight, relative to the total weight of the composition.

[0081] In certain embodiments, the composition used in the present invention is in the form of an oil-in-water emulsion. Thus, said composition comprises a continuous aqueous phase and a dispersed oily phase. Aqueous phase

[0082] Preferably, the composition of the present invention comprises an aqueous phase.

[0083] Said aqueous phase is preferably present in an amount ranging from 10% by weight to 90% by weight, more preferably from 20% by weight to 85% by weight, relative to the total weight of the composition.

[0084] The continuous aqueous phase may include water.

[0085] Water is preferably present in the composition of the present invention in an amount ranging from 10% by weight to 85% by weight, preferably from 20% by weight to 80% by weight, relative to the total weight of the composition. Oily phase

[0086] Preferably, the composition of the present invention comprises an oily phase.

[0087] The oily phase contains at least one oil, in particular a cosmetic oil. It may also contain other fatty substances.

[0088] The term "oil" refers to a non-aqueous compound that is immiscible with water and is liquid at room temperature (20 °C) and atmospheric pressure (760 mmHg).

[0089] Oils can be volatile or non-volatile.

[0090] The term "non-volatile" refers to an oil whose vapor pressure at ambient temperature and atmospheric pressure is non-zero and is less than 103 mmHg (0.13 Pa).

[0091] The term “volatile oil” refers to any oil which has the ability to evaporate on contact with the skin in less than one hour, at room temperature and atmospheric pressure.

[0092] The oily phase may include hydrocarbon-based oils, silicone oils, or mixtures thereof.

[0093] They can be of animal, vegetable, mineral or synthetic origin.

[0094] The expression "hydrocarbon-based oil" refers to an oil containing mainly hydrogen and carbon atoms.

[0095] In the context of the present invention, it is preferable that the hydrocarbon-based oil be isopropyl lauroyl sarcosinate.

[0096] The expression "silicone oil" refers to an oil comprising at least one silicon atom and in particular, at least one Si-O group.

[0097] The oils may include atoms of oxygen, nitrogen, sulfur and / or phosphorus, for example in the form of hydroxyl or acid radicals.

[0098] Advantageously, the oily phase is present in the composition of the present invention in an amount ranging from 1% by weight to 30% by weight, preferably from 3% by weight to 20% by weight, relative to the total weight of the composition of the present invention. cosmetic active ingredients

[0099] The composition used in the process of the present invention may include a cosmetic active ingredient.

[0100] It is easy for a person skilled in the art to adjust the quantity of the cosmetic active ingredient on the basis of the end use of the composition according to the present invention. Additional adjuvants or additives

[0101] The composition used in the process of the present invention may also contain conventional cosmetic adjuvants or additives, for example, perfumes, chelating agents, preservatives and bactericides, additional surfactants, additional thickeners, fillers, pH correctors, and mixtures thereof.

[0102] A person skilled in the art can adjust the quantity of additional adjuvants or additives so as not to have a negative impact on the final use of the composition according to the present invention.

[0103] According to a particularly preferred embodiment, the process of the present invention uses a composition, preferably in the form of an oil-in-water emulsion, comprising, relative to the total weight of the composition:

[0104] (i) from 3% by weight to 8% by weight of at least one C14-C30 fatty alcohol selected including cetyl alcohol, stearyl alcohol, cetearyl alcohol, and their combinations;

[0105] (ii) from 0.5% by weight to 3% by weight of at least one anionic surfactant selected from cetearyl ammonium sulfate, cetearyl sodium sulfate, cetearyl potassium sulfate, and combinations thereof;

[0106] (iii) from 0.1% by weight to 2% by weight of at least one acrylic polymer selected from ammonium acryloyldimethyltaurate / beheneth-25 methacrylate crosslinked polymer, ammonium acryloyldimethyltaurate / stearate-25 methacrylate crosslinked polymer, and combinations thereof; and

[0107] (iv) optionally, from 3% by weight to 20% by weight of glycerin. Preparation and use

[0108] The composition used in the process according to the present invention can be prepared by mixing ingredients (i) to (iii), as essential ingredients, together with the additional ingredient or ingredients, as explained above.

[0109] Thanks to the use of said composition, the process according to the present invention can offer a non-greasy and non-sticky sensation. EXAMPLES

[0110] The following examples are given by way of non-limiting illustrations of the present invention.

[0111] The main raw materials used, their trade names and suppliers are listed in Table 1.

[0112] [Tables 1] INCI name Trade name Supplier Cetearyl alcohol DEHYDAG WAX O OR COGNIS Sodium cetearyl sulfate LANETTE E GRANULES BASF Isopropyl lauroyl sarcosinate ELDEW SL-205 AJINOMOTO Ammonium acryloyldimethyltaurate / steareth-25 methacrylate crosspolymer ARISTOFLEX HMS CLARIANT

[0113] Example of the invention 1 and comparative examples 1 and 2

[0114] Compositions of the example of the invention (El) 1 and comparative examples (EC) 1 and 2 were prepared on the basis of the quantities of components given in Table 2. The quantities are given as % by weight of each component relative to the total weight of the composition.

[0115] [Tables2] Components EL 1 EC. 1 EC. 2 Cetearyl alcohol 4 4 4 Sodium cetearyl sulfate 0.6 - 0.1 Glycerin 16 16 16 Isopropyl lauroyl sarcosinate 10 10 10 Ammonium acryloyldimethyltaurate / steareth-25 methacrylate cross-linked polymer 0.5 0.5 0.5 Sodium methylstearoyltaurate - 0.6 - Water QS100 QS100 QS100

[0116] The composition of the example of invention 1 represents a composition used in the process according to the present invention.

[0117] The composition of comparative example 1 includes sodium methylstearoyltaurate instead of at least one anionic surfactant selected from C14-C22 alkyl sulfate.

[0118] The composition of comparative example 2 comprises less than 0.3% by weight of at least one anionic surfactant selected from C14-C22 alkyl sulfate, relative to the total weight of the composition.

[0119] Preparation process:

[0120] The compositions listed above were prepared in the following manner, taking as an example the composition of example 1 of the invention:

[0121] 1. Dispersion of sodium cetearyl sulfate surfactant and glycerin in 40% of boiling water under agitation to obtain a uniform aqueous phase while maintaining the temperature at least at 75 °C;

[0122] 2. mixture of cetearyl alcohol and isopropyl lauroyl sarcosinate, then heating to 75°C to obtain a uniform oily phase;

[0123] 3. Mixing the aqueous phase and the oily phase under agitation and maintaining the temperature at 75°C for a maximum of 10 minutes;

[0124] 4. Addition of the remaining water at room temperature while stirring; and

[0125] 5. Addition of a crosslinked ammonium acryloyldimethyltaurate / methacrylate polymer of steareth-25 under stirring for 10 minutes to obtain the composition. Composition evaluation

[0126] The stability of the above-prepared compositions and the sensations delivered by them have been evaluated. Stability

[0127] Each composition was stored at 55°C for 1 week, and its appearance was observed under a microscope.

[0128] In the absence of phase separation after a composition has been stored for 1 week at 55°C, then the composition is evaluated as "stable", otherwise it is evaluated as "unstable".

[0129] Ease of use and sensory properties

[0130] The ease of use and the sensations delivered by each of the compositions of the example of the invention 1 and comparative examples 1 and 2 were evaluated in terms of ease of spreading, non-greasy character, penetration and stickiness by 5 skin experts after application of 0.1 g of each composition on the forearm according to the following standard.

[0131] [Tables4] Items and Evaluation Procedure Standardized Score Application Apply in 1 to 3 circular motions, evaluate the ease of spreading 1: Difficult 2: Normal 3: Easy Penetration time: number of circular motions from the first application until the composition is absorbed 1: > 20 circular motions, long 2: 10 to 20 circular motions, medium 3: 1 to 10 circular motions, short Sensory Properties Apply in 3 to 8 circular motions to evaluate the greasyness during spreading 1: Very greasy 2: Greasy 3: Slightly greasy 4: Non-greasy Stickiness of the film: after the test composition has been completely absorbed, press the film with your fingers to feel its stickiness 1: Very sticky 2: Sticky 3: Slightly sticky 4: Non-sticky

[0132] Within the framework of the present invention, a score greater than or equal to 2 is acceptable for the application, and a score greater than or equal to 3 is acceptable for the sensory properties.

[0133] The stability of the example of the invention 1 and comparative examples 1 and 2, as well as the average scores for the sensory properties provided by them, have been summarized in Table 3.

[0134] [Tables3] Properties El. 1 EC. 1 EC. 2 Stability Stable Unstable Stable Ease of use Spreading 3 3 3 Penetration time 2.2 1.8 1.8 Sensory properties Greasy feel when spreading 3 2.4 2.4 Stickiness of the film 4 3 3.2

[0135] The composition of the example of the invention 1 is stable, can be applied easily and provides the skin with good sensations.

Claims

Demands

1. A method for skin care and / or makeup, comprising the application to the skin of a composition comprising: (i) at least one C14-C30 fatty alcohol; (ii) more than 0.3% by weight of at least one anionic surfactant selected from C14-C22 alkyl sulfates, relative to the total weight of the composition; and (iii) at least one acrylic polymer.

2. 2. A process according to claim 1, wherein the C14-C30 fatty alcohol has an R—OH structure with R denoting a linear alkyl or alkenyl comprising 14 to 30 carbon atoms, preferably R denoting a linear alkyl or alkenyl comprising 14 to 22 carbon atoms.

3. A method according to claim 1 or 2, wherein the C14-C30 fatty alcohol is selected from cetyl alcohol, stearyl alcohol, cetearyl alcohol, arachidyl alcohol, behenyl alcohol and mixtures thereof, preferably, the C14-C30 fatty alcohol is selected from behenyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol and mixtures thereof.

4. A process according to any one of claims 1 to 3, wherein the C14-C30 fatty alcohol is present in an amount from 2% by weight to 20% by weight, preferably from 3% by weight to 15% by weight, more preferably from 3% by weight to 8% by weight, relative to the total weight of the composition.

5. A method according to any one of claims 1 to 4, wherein the anionic surfactant is selected from ammonium tetradecyl sulfate, sodium tetradecyl sulfate, potassium tetradecyl sulfate, ammonium hexadecyl sulfate, sodium hexadecyl sulfate, potassium hexadecyl sulfate, ammonium octadecyl sulfate, sodium octadecyl sulfate, potassium octadecyl sulfate, ammonium cetearyl sulfate, sodium cetearyl sulfate, potassium cetearyl sulfate, and combinations thereof.

6. A method according to any one of claims 1 to 5, wherein the anionic surfactant is selected from ammonium cetearyl sulfate, sodium cetearyl sulfate, potassium cetearyl sulfate, and combinations thereof.

7. A method according to any one of claims 1 to 6, wherein the acrylic polymer is selected from acrylic copolymers comprising a hydrophobic fatty chain having from 8 to 40 carbon atoms; preferably, the acrylic polymer is selected from copolymers derived from 2-acrylamido-2-methylpropanesulfonic acid and polyoxyalkylated C8-C40 alkyl (meth)acrylates, the number of moles of oxyalkylene motifs being from 1 to 30 mol, preferably from 3 to 25 mol and more preferably from 5 to 25 mol; more preferably, the acrylic polymer is selected from ammonium acryloyldimethyltaurate / beheneth-25 methacrylate crosslinked polymer, ammonium acryloyldimethyltaurate / stearate-25 methacrylate crosslinked polymer, and combinations thereof.

8. A method according to any one of claims 1 to 7, wherein the composition further comprises one or more humectants, preferably selected from polyhydric alcohols; more preferably selected from glycerin, butylene glycol, panthenol, hexylene glycol, polyethylene glycol, polypropylene glycol, propylene glycol, sorbitol, and combinations thereof.

9. A process according to claim 1, wherein the composition comprises, relative to the total weight of the composition: (i) 3% by weight to 8% by weight of at least one C14-C30 fatty alcohol selected from cetyl alcohol, stearyl alcohol, cetearyl alcohol, and combinations thereof; (ii) 0.5% by weight to 3% by weight of at least one anionic surfactant selected from ammonium cetearyl sulfate, sodium cetearyl sulfate, potassium cetearyl sulfate, and combinations thereof; (iii) 0.1% by weight to 2% by weight of at least one acrylic polymer selected from ammonium acryloyldimethyltaurate / beheneth-25 methacrylate crosslinked polymer, ammonium acryloyldimethyltaurate / stearate-25 methacrylate crosslinked polymer, and combinations thereof; and (iv) optionally, 3% by weight to 20% by weight of glycerin.

10. A method according to any one of claims 1 to 9, wherein the composition is in the form of an oil-in-water emulsion.