Composition containing at least one pigment and a specific organic compound

Abstract

Composition containing at least one pigment and a specific organic compound. The present invention relates to a cosmetic composition comprising, in a physiologically acceptable aqueous medium: a) at least one saturated organic compound, linear or branched, cyclic or non-cyclic, of general formula CnH2nO3, in which the subscript n is an integer such that 6 ≤ n ≤ 9, and said compound comprises at least one hydroxyl group and at least one ester or ether functional group; and b) at least one pigment colorant. Figure for the abstract: none

Description

Title of the invention: Composition containing at least one pigment and a specific organic compound

[0001] The present invention relates to a cosmetic composition comprising, in a physiologically acceptable medium:

[0002] a) at least one saturated organic compound, linear or branched, cyclic or non-cyclic, of general formula CnH2nO3 in which the index n is an integer such that 6 < n < 9 (in other words, n is an integer between 6 and 9 inclusive), and said compound comprises at least one hydroxyl group and at least one functional group selected from carboxylic ester or ether; and

[0003] b) at least one pigment colouring material.

[0004] It also relates to a method of makeup and / or skin care and / or hair care, in which the composition according to the invention is applied to the skin and / or hair.

[0005] Cosmetic compositions for makeup very often contain volatile compounds. These compounds are necessary first and foremost to provide users with textures and sensory qualities when applying cosmetic products. Furthermore, these volatile compounds contribute to the expression of the final properties of the product film applied to the skin, such as coverage and film homogeneity.

[0006] There are several chemical classes of volatile cosmetic compounds, which can be lipophilic or hydrophilic. The main lipophilic volatile cosmetic compounds are, on the one hand, hydrocarbon compounds, which can be of mineral, vegetable, or animal origin, and on the other hand, synthetic silicones. Among hydrocarbon compounds, alkanes are increasingly used to limit the use of volatile silicones in cosmetic products, particularly in products based on natural or naturally derived ingredients. However, it turns out that the alkanes used for this purpose are nonpolar molecules, which do not exhibit optimal compatibility properties with a wide variety of colorants.

[0007] The main hydrophilic compounds such as water, or hydrophilic volatile solvents such as ethanol and isopropanol, which are polar, also do not show optimal compatibility properties with a wide variety of pigments.

[0008] In anhydrous compositions, in order to increase the polarity of the medium, it is possible to mix the alkanes with absolute ethanol. However, absolute ethanol is not always compatible with coloring raw materials or other cosmetic raw materials. Furthermore, ethanol can cause discomfort, necessitating limiting its concentration in cosmetic formulations. In addition, ethanol has a very low flash point (13°C), requiring the implementation of safety measures not only when using this pure solvent, but also during the manufacturing, storage, and transport of cosmetic products containing ethanol. Finally, ethanol's very high volatility can lead to a very short playtime, potentially resulting in a depreciation of the cosmetic product.

[0009] The "playtime" of a cosmetic product refers to the time the user can work with it during application, particularly on the skin, and therefore reflects the ease of application. Playtime can play a key role in the effectiveness of a cosmetic skincare and / or makeup routine. For example, the "contouring" technique is a cosmetic technique for sculpting the face, which requires roughly applying a light shade to areas to be highlighted and a dark shade to areas to be slimmed, then blending the two shades with a finger or brush for a unified and natural finish. The playtime of the tinted compositions used must be long enough to allow for the various steps of makeup application: applying, blending different shades, smudging, etc.Thus, playtime can have a real impact on the ease of application, on the perception of a cosmetic product, and on the final result, particularly of makeup.

[0010] It is therefore necessary to find polar volatile compounds which are favorable to the good dispersion, in all types of aqueous and / or oily formulas, of coloring materials regardless of their nature or surface, in particular with or without coating, and which also allow good expression of colonic properties at the deposition, in particular in terms of homogeneity and coverage, while ensuring good sensory properties at the application and sufficient playtime.

[0011] Colonial properties at the deposit refer to both makeup performance (color, homogeneity, coverage) and photoprotection performance according to the same criteria (color, homogeneity, coverage), particularly with regard to mineral pigments for photoprotection or inorganic UV filters.

[0012] The formulator is therefore looking for raw materials and / or systems enabling the production of compositions with covering, homogeneous deposition and good playtime.

[0013] Furthermore, the formulation of environmentally friendly cosmetic products, that is to say whose design and development take into account environmental issues, is becoming a major concern to help meet global challenges.

[0014] It is therefore essential to propose more sustainable compositions and / or preparation processes and / or ingredients, thus enabling us to meet these environmental challenges.

[0015] In this context, it is important to develop new cosmetic compositions with a better carbon footprint, in particular by promoting the use of raw materials that are at least partially renewable and / or have a good naturalness index and / or are of natural origin and as much as possible of plant origin, while increasingly reducing the use of petrochemical compounds.

[0016] The present invention aims to provide cosmetic compositions, preferably coloured, with good properties, particularly in terms of homogeneity, coverage, and sufficient playtime to guarantee, in use, a quality of application and a sensory experience that meets the expectations of the user of these compositions.

[0017] The applicant unexpectedly discovered that these objectives could be achieved with a skincare and / or makeup composition of keratinous materials, comprising, in particular in a physiologically acceptable environment, the combination of a polar solvent having a specific chemical structure and physicochemical properties with at least one coloring raw material, enabling the development of fluid to viscous cosmetic products exhibiting good dispersion of coloring materials, good playtime, good homogeneity of application, and good coverage. Indeed, after application, these compositions leave a covering and homogeneous film-forming deposit. These compositions can also contain more sustainable ingredients, thus addressing environmental concerns.

[0018] The present invention therefore relates to a cosmetic composition, in particular makeup and / or skin and / or lip care, in particular skin care, comprising, in a physiologically acceptable aqueous medium: a. at least one saturated organic compound, linear or branched, cyclic or non-cyclic, of general formula CnH2nO3 in which: the index n is an integer such that 6 < n < 9 (n is an integer between 6 and 9 inclusive), and said compound comprises at least one hydroxyl group and at least one functional group selected from carboxylic ester (hereinafter "ester") or ether (hereinafter "ether"); and b. at least one pigmentary coloring matter.

[0019] By “physiologically acceptable”, we mean a medium compatible with keratinous materials.

[0020] It also relates to a method of makeup and / or skin care and / or hair care, in which the composition according to the invention is applied to the skin and / or hair.

[0021] Preferably, the composition according to the invention comprises less than 10% by weight, preferably less than 5% by weight, of silicone oil, relative to the total weight of the composition.

[0022] Preferably, the composition according to the invention is substantially free of silicone oil, or even free of silicone.

[0023] By "substantially free of silicone" is meant that the composition comprises less than 1%, preferably less than 0.5% by weight, preferably less than 0.3% by weight, preferably less than 0.1% of silicone oil, preferably silicone. Preferably, the composition is totally free of silicone. By silicone is meant any silicone compound. Compound a)

[0024] The composition of the invention comprises at least one saturated organic compound, linear or branched, cyclic (at least partially cyclic) or non-cyclic, of general formula CnH2nO3 in which the index n is an integer such that 6 < n < 9, in other words n is an integer between 6 and 9 inclusive, and said compound of formula CnH2nO3 comprises at least one hydroxyl group and at least one function selected from carboxylic ester or ether-oxide.

[0025] The flash point of said compound a) is advantageously between 20°C and 120°C, preferably between 25°C and 115°C, preferably between 30°C and 110°C, preferably between 35°C and 107°C, preferably between 40°C and 105°C, or even between 45°C and 100°C.

[0026] The flash point (FP) is the lowest temperature of a test portion of a product, reduced to a barometric pressure of 101.3 kPa, at which the introduction of an ignition source causes the vapors of that source to ignite after a short delay, with the flame propagating across the surface of the liquid, operating under the prescribed test conditions. If the heat source is removed, the ignition ceases. This testing method follows the international standard ISO 3679:2015 (Method A - flash no-flash test, at equilibrium in a closed vessel). A measuring device of the "Setaflash Series 8 Active Cool Flash Point Tester" type can be used.

[0027] The compound a) advantageously exhibits a non-zero vapor pressure at ambient temperature and atmospheric pressure, in particular a vapor pressure ranging from 2.66 Pa to 40,000 Pa, particularly from 2.66 Pa to 13,000 Pa, particularly from 3 Pa to 2,000 Pa, or even from 3 Pa to 1,000 Pa, and more particularly from 4 Pa ​​to 500 Pa, preferably from 4 to 200 Pa, or even from 5 to 100 Pa, better still from 5 to 50 Pa. The vapor pressure can be measured by the static method or by the effusion method. isothermal thermogravimetry, according to the vapor pressure of the oil (OECD standard 104).

[0028] Advantageously, said compound a) is selected from those comprising a hydroxyl group and two ether functions, preferably comprising at least one cyclic ether function, preferably comprising a cyclic ether containing two ether functions, such as a dioxane ring or a dioxolane ring; preferably said compound a) comprises a hydroxyl group and a 1,3-dioxolane ring, and mixtures thereof. Preferably in this case, the index n of compound a) is an integer such that 6 < n < 8 (n is between 6 and 8 inclusive). Preferably said compound a) is then selected from 2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane (or isopropylideneglycerol), 4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane, (4S)-(+)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane, and mixtures thereof.

[0029] According to a second embodiment, said compound a) is selected from among the hydroxycarboxylic esters in which the index n is an integer such that 7 < n < 9 (n is between 7 and 9 inclusive). Preferably, said compound a) is thus selected from Propyl Lactate, Butyl Glycolate, Butyl Lactate, Isobutyl Lactate, Methyl 3-hydroxyhexanoate, tert-Butyl 3-hydroxypropionate, Amyl Lactate, Isoamyl Lactate, Hexyl Lactate, and mixtures thereof.

[0030] Preferably, compound a) is present in a content ranging from 1% to 99% by weight, preferably from 1% to 98% by weight, preferably from 1% to 95% by weight, preferably from 2% to 90%, preferably from 2% to 80% by weight, preferably from 3% to 70%, preferably from 4% to 60% by weight, preferably from 4% to 50% by weight, preferably from 5% to 40% by weight, preferably from 6% to 30% by weight, preferably from 7% to 25% by weight, or even from 8% to 20%, by weight of compound a), on the total weight of the composition representing 100%.

[0031] Preferably, compound a) is present in a content of less than 80% by weight, preferably less than 70% by weight, preferably less than 60% by weight, preferably less than 50% by weight, or even less than 40% by weight, better less than 30%, or even less than 20%, in particular less than 15%, or even less than 10% by weight, on the total weight of the composition representing 100%.

[0032] Thus, the solvents of the invention correspond, for example, to derivatives of lactic acid or dioxolane. They may optionally contain rings.

[0033] By way of example, the following compounds a) may be cited:

[0034] INCI formula name Chemical structure Flash point (°C) (Suppliers) Mw (g / mo) c6h12o3 Isopropylideneglyce roi 91 132 c6h12o3 Propyl lactate OH 57 132 c6h12o3 Butyl glycolate 74 132 c7h14o3 4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dio xolane Z~%CH3 66-92 146 c7h14o3 (4S)-(+)-4-(2-Hydro xyethyl)-2,2-dimethy 1-1,3-dioxolane „"x .-OH HjC CHS 101 146 c7h14o3 Butyl Lactate GO CH3 GH 69-79 146 c7h14o3 Isobutyl Lactate O ÔH 67 146 c7h14o3 Methyl 3-hydroxyhe xanoate OH O À L HSC OCHa 85 146 c7h14o3 tert-Butyl 3-hydroxy propionate G . ü HO G HjG—|—0¾ CH3 84 146 c8h16o3 Amyl lactate 79 160 c8h16o3 Isoamyl Lactate 74-78 160 c9h18o3 Hexyl Lactate 100 174

[0035] Examples of preferred lactates include isopropyl lactate (C6), butyl lactate (C7) and hexyl lactate (C9).

[0036] As examples of compounds a) we can also mention Isopropylidene glycerol, also called 2,2-dimethyl-4-hydroxymethyl-l,3-dioxolane, or 1,2-isopropylidene glycerol.

[0037] Butyl lactate, and Isopropylidene glycerol, are among the preferred compounds a) of the Invention.

[0038] The compound a) advantageously forms a polar volatile hydrocarbon solvent, particularly compatible with the pigment coloring matter b) according to the invention.

[0039] Other volatile hydrocarbon solvents - possible polar solvents

[0040] Advantageously the composition according to the invention may further comprise an additional "polar volatile hydrocarbon solvent", different from compound a) according to the invention.

[0041] By "volatile solvent", for the purposes of the invention, means any solvent of the pigment colouring material(s) b) according to the invention, capable of evaporating on contact with the skin in less than one hour, preferably in less than 30 minutes, when applied as a thin film of 10 pm wet thickness, at room temperature and atmospheric pressure. The volatile solvent is a volatile cosmetic compound, liquid at room temperature (20°C), having a non-zero vapor pressure at room temperature and atmospheric pressure, specifically a vapor pressure ranging from 2.66 Pa to 40,000 Pa, particularly from 2.66 Pa to 13,000 Pa, and more specifically from 2.66 Pa to 1300 Pa. The vapor pressure can be measured using the static method or the isothermal thermogravimetric effusion method, according to the vapor pressure of the oil (OECD 104 standard).

[0042] The term "polar hydrocarbon solvent" means a solvent of the pigment colouring material(s) b) according to the invention containing mainly hydrogen and carbon atoms and one or more functions selected from among the hydroxyl, ester, ether and ketone functions.

[0043] According to a preferred form, the polar volatile hydrocarbon solvent(s) is / are chosen from among the C2-C4 monoalcohols.

[0044] The composition according to the invention may optionally include at least one linear or C2-C4 branched monoalcohol, such as, for example, ethanol, propanol, isopropanol, tert-butanol, n-butanol, and mixtures thereof, and more particularly ethanol.

[0045] An advantage of the composition of the invention is the ability to limit the volatile alcohol(s) level, which often causes discomfort (dryness, tingling) without losing solubilizing power.

[0046] If the composition includes them, the content of linear or branched C2-C4 monoalcohol(s) may advantageously be less than or equal to 50% by weight, preferably less than 40% by weight, more particularly less than or equal to 30% by weight, advantageously less than or equal to 20% by weight relative to the total weight of the composition.

[0047] Preferably, the content of linear or branched C2-C4 monoalcohol(s) is less than or equal to 15% by weight, preferably less than or equal to 12%, preferably less than or equal to 10%, preferably less than or equal to 8%, preferably less than or equal to 5%, preferably less than or equal to 4%, preferably less than or equal to 3%, preferably less than or equal to 2%, preferably less than or equal to 1%, by weight relative to the total weight of the composition.

[0048] Furthermore, if the composition includes, the content of linear or branched C2-C4 monoalcohol(s) is such that the weight ratio of the total amount of compound(s) a) to the total amount of volatile polar hydrocarbon solvent(s) other than compound(s) a) is greater than 1, it being understood that the linear or branched C2-C4 monoalcohol(s) are considered with the volatile polar hydrocarbon solvents other than compound a). Pigment coloring substances b)

[0049] The composition according to the invention further comprises at least one pigmentary coloring material. For the purposes of the present invention, the pigmentary coloring material is selected from powdered coloring materials such as mineral pigments, mother-of-pearl, organic pigments, and also includes inorganic UV filters, as defined below.

[0050] “Pigments” means white or colored particles, mineral or organic, insoluble in an aqueous medium, intended to color the composition and / or the resulting deposit.

[0051] Colouring materials may be present in the composition in a content ranging from 0.5% to 70% by weight relative to the total weight of the composition, preferably from 1% to 60% by weight, preferably from 2% to 50% by weight, preferably from 3% to 45% by weight, relative to the weight of the composition, preferably from 4% to 30% by weight, preferably from 5% to 20% by weight, preferably from 6% to 15% by weight, relative to the total weight of the composition representing 100%. Mineral pigments

[0052] According to a particular embodiment, the pigments used according to the invention are chosen from mineral pigments.

[0053] By "mineral pigment" is meant any pigment that meets the definition in the Ullmann encyclopedia in the chapter on inorganic pigment. Examples of mineral pigments useful in the present invention include zirconium or cerium oxides, as well as zinc oxides, iron oxides (black, yellow or red) or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue, titanium dioxide, metallic powders such as aluminum powder and copper powder, mother-of-pearl, monochromatic pigments; and mixtures thereof.

[0054] The following mineral pigments can also be used: Ta2O5, Ti3O5, Ti2O3, TiO, ZrO2 in mixture with TiO2, ZrO2, Nb2O5, CeO2, ZnS.

[0055] The size of the pigment used in the present invention is generally greater than 100 nm and can be up to 10 µm, preferably from 200 nm to 5 µm, and more preferably from 300 nm to 1 µm. According to a particular embodiment of the invention, the pigments have a size characterized by a D

[50] greater than 100 nm and can be up to 10 µm, preferably from 200 nm to 5 µm, and more preferably from 300 nm to 1 µm. The sizes are measured by static light scattering using a commercial particle size analyzer such as the Malvern MasterSizer 3000®, which allows for the determination of the particle size distribution of all the particles over a wide range from 0.01 µm to 1000 µm. The data are processed based on the classical Mie scattering theory. This theory is best suited for size distributions ranging from submicron to multi-micron, it allows us to determine an "effective" particle diameter.This theory is notably described in the work of Van de Hulst, HC, "Light Scattering by Small Particles", Chapters 9 and 10, Wiley, New York, 1957. D

[50] represents the maximum size that 50% of the particles have by volume.

[0056] In the context of the present invention, the mineral pigments are more particularly iron oxide and / or titanium dioxide.

[0057] The pigment(s) usable in a composition according to the invention can be chosen respectively from coated pigment(s), uncoated pigment(s), and their mixtures.

[0058] According to a particular embodiment of the invention, the composition according to the invention comprises at least one uncoated pigment.

[0059] According to an alternative embodiment of the invention, or according to a complementary embodiment of the invention, the composition according to the invention comprises at least one coated pigment.

[0060] According to an advantageous embodiment of the invention, the mineral pigment comprises a lipophilic or hydrophobic coating. The latter is preferably present in the oily phase of the composition according to the invention.

[0061] According to a particular embodiment of the invention, the pigments can be coated with at least one compound selected from: metallic soaps; N-acylated amino acids or their salts; lecithin and its derivatives; isopropyl trisostearyl titanate; isostearyl sebacate; waxes; fatty esters; phospholipids; and mixtures thereof.

[0062] According to a preferred embodiment, the pigments can be coated according to the invention with an N-acylated amino acid or one of its salts, which may comprise a acyl group having from 8 to 22 carbon atoms, such as for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl, cocoyl group.

[0063] The amino acid may be, for example, lysine, glutamic acid, or alanine. The salts of these compounds may be aluminum, magnesium, calcium, zirconium, zinc, sodium, or potassium salts. Thus, according to a particularly preferred embodiment, the pigments may be coated with an N-acylated amino acid derivative, which may be, in particular, a glutamic acid derivative and / or one of its salts, and more specifically a stearoyl glutamate, such as aluminum stearoyl glutamate. Examples of pigments treated with aluminum stearoyl glutamate include titanium dioxide pigments and the iron oxide pigments black CI77499, red CI77491, and yellow CI77492, sold under the trade name NAI® by MIYOSHI KASEI.

[0064] According to a particular embodiment, the pigments can be coated according to the invention with isopropyl titanium triisostearyl titanate. Examples of pigments treated with isopropyl titanium triisostearate (ITT) include titanium dioxide pigments and black, red, and yellow iron oxide pigments sold under the trade names BWB0-I2® (Iron Oxide CI77499 and Isopropyl Titanium Triisostearate), BWY0-I2® (Iron Oxide CI77492 and Isopropyl Titanium Triisostearate), and BWR0-I2® (Iron Oxide CI77491 and Isopropyl Titanium Triisostearate) by KOBO.

[0065] As mineral pigments that can be used in the invention, nacres can also be mentioned.

[0066] By “mother-of-pearl”, one must understand colored particles of any shape, iridescent or not, in particular, produced by certain molluscs in their shell or synthesized and which exhibit a color effect by optical interference.

[0067] The pearlescent pigments can be selected from pearlescent pigments, such as titanium mica coated with iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with an organic dye, as well as pearlescent pigments based on bismuth oxychloride. They can also consist of mica particles on the surface of which at least two successive layers of metal oxides and / or organic coloring materials are superimposed. Natural mica coated with titanium oxide, iron oxide, natural pigment, or bismuth oxychloride can also be cited as examples of pearlescent pigments. More specifically, the pearlescent pigments can have a yellow, pink, red, bronze, orange, brown, gold, and / or copper color or sheen.

[0068] Among the pigments that can be used according to the invention, we can also mention those with an optical effect different from a simple conventional hue effect, that is to say, unified and stabilized as produced by conventional coloring materials, such as monochromatic pigments. For the purposes of this invention, "stabilized" means free from any color variation with the viewing angle or in response to temperature changes. For example, this material can be selected from metallic-reflecting particles, goniochromatic coloring agents, diffracting pigments, thermochromic agents, optical brighteners, and, in particular, interference fibers. Naturally, these different materials can be combined to produce two effects simultaneously, or even a new effect according to the invention. Organic pigments

[0069] According to another embodiment of the invention, the pigment colouring material is an organic, synthetic, natural or naturally derived pigment.

[0070] By "organic pigment" is meant any pigment that meets the definition in the Ullmann encyclopedia in the chapter on organic pigment. The organic pigment may in particular be chosen from the compounds nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, of the metal complex type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, quinophthalone; and mixtures thereof.

[0071] The organic pigment(s) may be chosen, for example, from carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, phthalocyanine blue, sorghum red, the blue pigments coded in the Color Index under references CI 42090, 69800, 69825, 73000, 74100, 74160, the yellow pigments coded in the Color Index under references CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000, 47005, the green pigments coded in the Color Index under references CI 61565, 61570, 74260, the orange pigments coded in the Color Index under the references CI 11725, 15510, 45370, 71105, red pigments coded in the Color Index under the references CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915, 75470, and pigments obtained by oxidative polymerization of indole derivatives,phenolic compounds as described in French patent FR 2 679 771.

[0072] The pigments can also be in the form of composite pigments as described in patent EP 1 184 426. These composite pigments can be composed in particular of particles comprising an inorganic core covered at least partially with an organic pigment and at least one binder ensuring the fixation of the organic pigments on the core.

[0073] The pigment can also be a lacquer.

[0074] By "lacquer", we mean insolubilized dyes adsorbed onto insoluble particles, the whole thus obtained remaining insoluble during use.

[0075] The inorganic substrates on which the dyes are adsorbed are, for example, alumina, silica, calcium sodium borosilicate or calcium aluminium borosilicate, and aluminium.

[0076] Among the organic dyes, we can mention cochineal carmine. We can also mention the products known under the following names: D&C Red 21 (CI 45 380), D&C Orange 5 (CI 45 370), D&C Red 27 (CI 45 410), D&C Orange 10 (CI 45 425), D&C Red 3 (CI 45 430), D&C Red 4 (CI 15 510), D&C Red 33 (CI 17 200), D&C Yellow 5 (CI 19 140), D&C Yellow 6 (CI 15 985), D&C Green (CI 61 570), D&C Yellow 1 O (CI 77 002), D&C Green 3 (CI 42 053), D&C Blue 1 (CI 42 090).

[0077] As examples of lacquers, we can cite the product known under the name D&C Red 7 (CI 15 850 :1).

[0078] Photoprotection pigments or inorganic UV filters

[0079] The pigments used according to the present invention can also be photoprotection pigments. These are metal oxide pigments that form inorganic UV filters.

[0080] More preferably, the inorganic UV filters of the invention are metal oxide particles having an average particle size less than or equal to 0.5 pm, more preferably between 0.005 and 0.5 pm, and even more preferably between 0.01 and 0.2 pm, even better between 0.01 and 0.1 pm, and more particularly between 0.015 and 0.05 pm. They are described in particular in Annex VI, updated on 22 / 09 / 2021, of European Cosmetics Regulation No. 1223 / 2009, but are not limited to this list.

[0081] They can in particular be chosen from titanium, zinc, iron, zirconium, cerium oxides or mixtures thereof.

[0082] Such metallic oxide pigments, coated or uncoated, are described in particular in patent application EP-A-0 518 773. As commercial pigments, mention may be made of the products sold by the companies CRODA, TAYCA, and MERCK.

[0083] Metal oxide pigments may be coated or uncoated. Coated pigments are pigments that have undergone one or more surface treatments of a chemical, electronic, mechanochemical, and / or mechanical nature with compounds such as amino acids, wax, fatty acids, fatty alcohols, anionic surfactants, lecithins, sodium, potassium, zinc, iron, or aluminum salts, fatty acids, metal alkoxides (titanium or aluminum), polyethylene, silicones, proteins (collagen, elastin), alkanolamines, silicon oxides, metal oxides or sodium hexametaphosphate. The coated pigments are more specifically titanium oxides coated with: hydrated silica such as TAYCA's "MT-100WP", silica and iron oxide such as IKEDA's "SUNVEIL F®", silica and alumina such as TAYCA's "MT-500SA®" and "MT-100SA®", CRODA's "TIOVEIL™ AQ-N", alumina such as ISHIHARA's "TTO-55 (A)®", alumina and aluminum stearate such as TAYCA's "MT-100TV®, MT100Z®, MT-01®", CRODA's "Solaveil™ CT100", and Eusolex T-AVO®. MERCK, silica, alumina and alginic acid such as the product "MT-100AQ®" from the company TAYCA, alumina and aluminum laurate, iron oxide and iron stearate, zinc oxide and zinc stearate,of silica and alumina and treated with silicone such as the products "MTY500SAS®" or "MICROTITANIUM DIOXIDE MT-100SAS®" from the company TAYCA, of silica, alumina, aluminum stearate and treated with silicone,

[0084] - of silica and treated with a silicone, of alumina and treated with a silicone such that the "TTO-55(S)®" products from ISHIHARA, triethanolamine, stearic acid such as the "TTO-55(C)®" product from ISHIHARA, sodium hexametaphosphate, TiO2 treated with octyl trimethylsiloxane, TiO2 treated with polydimethylsiloxane, TiO2 anatase / rutile treated with polydimethylhydrogensiloxane, TiO2 coated with triethylhexanoin, aluminum stearate, alumina sold under the trade name "Solaveil™ CT-200" from CRODA, TiO2 coated with aluminum stearate, alumina and silicone sold under the trade name "Solaveil™ CT-12W" from CRODA, TiO2 coated with lauroyl lysine, TiO2 coated with C9-C15 fluoroalcohol phosphate and aluminium hydroxide.

[0085] We can also mention TiO2 pigments doped with at least one transition metal such as iron, zinc, manganese, and more particularly manganese.

[0086] Preferably, said doped pigments are in the form of an oily dispersion. The oil present in the oily dispersion is preferably selected from triglycerides, including those of capric / caprylic acids. The oily dispersion of titanium dioxide particles may further comprise one or more dispersing agents, such as, for example, a sorbitan ester like sorbitan isostearate, a polyoxyalkylated fatty acid and glycerol ester like TRLPPG3 MYRISTYLETHER CITRATE and POLYGLYCERYL-3 POLYRICINOLEATE. Preferably, the oily dispersion of titanium dioxide particles comprises at least one dispersing agent selected from polyoxyalkylated fatty acid and glycerol esters. A particular example is the oily dispersion of TiO2 particles doped with manganese in capric / caprylic acid triglyceride in the presence of TRLPPG-3 MYRISTYLETHER CITRATE and POLYGLYCERYL-3-POLYRICINOLEATE and SORBITAN ISOSTEARATE of INCI name: TITANIUM DIOXIDE (and) TRI-PPG-3 MYRISTYLETHER CITRATE (and) POLYGLYCERYL-3 RICINOLEATE (and) SORBITAN ISOSTEARATE as the product sold under the trade name "OPTISOL™ OTP-1" by the company CRODA.

[0087] Uncoated titanium oxide pigments are for example sold by the company TAYCA under the trade names "MT-500B" or "MT-600B®", by the company Evonik under the name "DEGUSSA P 25".

[0088] Uncoated zinc oxide pigments include, for example: those marketed under the name "Z-COTE®" by BASF; those marketed under the name "NanoArc® Zinc Oxide" by Nanophase Technologies. Coated zinc oxide pigments include, for example: ZnO coated with polymethylhydrogenesiloxane; "Solaveil™ CZ-100" from CRODA dispersed in Cl2-15 alkyl benzoate (INCI: Zinc Oxide (and) Cl2-15 Alkyl Benzoate (and) Polyhydroxystearic Acid (and) Isostearic Acid); Those marketed under the name "DAITOPERSION Zn-60VA®" by Daito Kasei (dispersions in C9-12 alkane with a dispersing agent), and those marketed under the name "SPD-Z5®" by Shin-Etsu (ZnO coated with silicone-grafted acrylic polymer, dispersed in cyclodimethylsiloxane). Uncoated cerium oxide pigments may include, for example, those sold under the name RHODIGARD® W185 by Solvay.

[0089] We can also mention mixtures of metal oxides, in particular titanium dioxide and cerium dioxide, including the equal weight mixture of titanium dioxide and cerium dioxide coated with silica, as well as the mixture of titanium dioxide and zinc dioxide coated with alumina, silica and silicone or coated with alumina, silica and glycerin.

[0090] According to the invention, titanium oxide pigments, coated or uncoated, are particularly preferred.

[0091] Inorganic UV filters can be present in the composition according to the invention in a content ranging from 0.1% to 60% by weight, preferably from 1% to 40% by weight, and even more preferably from 5% to 30% by weight, and better from 10% to 25% by weight relative to the total weight of the composition.

[0092] The composition according to the invention preferably comprises at least one pigment colouring material chosen from mineral pigments, preferably from titanium dioxide, iron oxides, zirconium or cerium oxides, zinc or chromium oxides and mixtures thereof, preferably the pigment is chosen from titanium dioxide, iron oxides and mixtures thereof. Charges

[0093] The composition according to the invention may also include at least one filler.

[0094] The term "fillers" means particles of any shape, colorless or white, mineral or synthetic, insoluble and dispersed in the medium of the composition regardless of the temperature at which the composition is manufactured. Generally, the fillers included in the compositions according to the invention are not pigmentary coloring agents.

[0095] Preferably, the filler is chosen from cellulose particles, silicas, starch, kaolin, clays, nylon or polymethyl methacrylate (PMMA) particles and mixtures thereof.

[0096] The cellulose particles usable according to the invention are preferably spherical (cellulose beads).

[0097] For the purposes of this invention, spherical particles are defined as solid or porous particles having a circularity parameter of at least 0.95. The circularity parameter is defined as the ratio of the circumference of a disk having the same area as the particle to the perimeter of the particle. A value of 1 characterizes perfectly spherical particles.

[0098] They preferably have an average size of less than 40 pm, preferably ranging from 1 to 20 pm, more preferably from 2 to 10 pm.

[0099] Among the cellulose particles that can be used according to the invention, particular mention can be made of those sold by the company Daito under the brand CELLULOBEADS® such as CELLULOBEADS USF® (D

[50] = 4 pm), CELLULOBEADS D-5® (D

[50] < 10 pm), CELLULOBEADS D-10® (D

[50] < 15 pm), CELLULOBEADS D-30® (D

[50] < 30 pm).

[0100] Preferably, the possible fillers are present in a content ranging from 0.1% to 25% by weight relative to the total weight of the composition, preferably from 0.2% to 20% by weight relative to the weight of the composition, preferably from 0.3% to 15% by weight, preferably from 0.4% to 10% by weight, preferably from 0.5% to 5% by weight relative to the weight of the composition representing 100%. Oils

[0101] Advantageously, the composition of the invention comprises an oily phase comprising at least one volatile oil selected from volatile hydrocarbon oils, volatile silicone oils and mixtures thereof.

[0102] Advantageously, the oily phase is dispersed in an aqueous phase, and forms with it a direct emulsion (O / W).

[0103] Alternatively, the oil phase may be the continuous phase of a reverse (W / O) emulsion. Preferably, the oil phase is a continuous oil phase.

[0104] Said oily phase is liquid (in the absence of structuring agent) at ambient temperature (20°C) and atmospheric pressure 1.013.105 Pa). It is organic, namely comprising at least carbon and hydrogen atoms and is immiscible in water.

[0105] The oily phase comprises at least one volatile oil and optionally ingredients soluble or miscible in said phase.

[0106] The total concentration in the oil phase of the composition of the invention is advantageously within the range of 5 to 100%, preferably 10 to 98% by weight, preferably 15 to 90% by weight, preferably 20 to 80% by weight, preferably 25 to 70% by weight, preferably 30 to 60% by weight, relative to the total weight of the composition.

[0107] By "oil" is meant a liquid compound at 20°C and atmospheric pressure (1.013105 Pa), immiscible with water.

[0108] By "immiscible" is meant that the mixture of the same quantity of water and oil, after stirring, does not lead to a stable solution comprising only one phase, under the aforementioned temperature and pressure conditions. The observation is made visually or, if necessary, using a phase-contrast microscope, on 100 g of the mixture obtained after sufficient Rayneri shaking to create a vortex within the mixture (for example, 200 to 1000 rpm); the resulting mixture being left to stand in a closed bottle for 24 hours at room temperature before observation. Volatile oils

[0109] By "volatile oil" is meant an oil having a vapor pressure greater than or equal to 1.3 Pa, preferably greater than or equal to 2.66 Pa, at ambient temperature (20°C) and atmospheric pressure, preferably within the range of 2.66 Pa to 40,000 Pa, preferably from 2.66 Pa to 13,000 Pa, and preferably from 2.66 Pa to 1300 Pa.

[0110] Conversely, "non-volatile oil" means an oil whose vapor pressure at 20°C and atmospheric pressure is non-zero and less than 2.66 Pa, more particularly less than 0.13 Pa.

[0111] By way of example, vapor pressure can be measured according to the static method or by the isothermal thermogravimetric effusion method, according to the vapor pressure of the oil (OECD standard 104).

[0112] The volatile oil or oils are preferably present in a content ranging from 1 to 90% by weight, preferably from 2 to 70%, preferably from 3 to 50%, preferably from 5 to 45% by weight, preferably from 8 to 40% by weight, and even more preferentially from 10 to 35%, by weight relative to the total weight of the composition.

[0113] The volatile oil or oils are advantageously chosen from volatile hydrocarbon oils, volatile silicone oils, and mixtures thereof; preferably chosen from volatile hydrocarbon oils. volatile hydrocarbon oil

[0114] The term "hydrocarbon oil" means an oil containing primarily hydrogen and carbon atoms and optionally one or more functional groups selected from among the hydroxyl, ester, ether, and carboxylic groups. A hydrocarbon oil therefore does not contain silicon or fluorine atoms.

[0115] By "nonpolar hydrocarbon oil" is meant a hydrocarbon oil comprising only carbon and hydrogen atoms, preferably non-aromatic (also called hydrocarbon).

[0116] By "polar hydrocarbon oil" is meant hydrocarbon oils comprising mainly hydrogen and carbon atoms and one or more functions chosen from among the hydroxyl, ester, ether, carboxylic functions, therefore oils with only C, H and O.

[0117] By way of example of a volatile hydrocarbon oil usable in the invention, one may cite:

[0118] - hydrocarbon oils having 8 to 16 carbon atoms, and in particular C8-C16 isoalkanes (also called isoparaffins) such as isododecane (also called 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane, and for example the oils sold under the trade names Isopars® or Permethyls®,

[0119] - linear alkanes, in the C6-C16 range, for example in Cl1-C15, alone or in mixtures, for example such as hexane, decane, undecane, tridecane, isoparaffins such as, or n-dodecane (C12) and n-tetradecane (C14) sold by Sasol respectively under the references PARAFOL 12-97 and PARAFOL 14-97, the undecane-tridecane mixture, the mixtures of n-undecane (C11) and n-tridecane (C13) obtained in examples 1 and 2 of application WO 2008 / 155059 of the Cognis Company, and their mixtures as well as the mixtures of n-undecane (C1) and n-tridecane (C13), such as Cetiol Ultimate®, or Cetiol UT® of the BASF company; or plant-based alkanes, particularly from coconut, such as those marketed under the name VEGELIGHT SILK by BIOSYNTHIS, or the mixture of C13-15 alkanes marketed under the name NEOSSANCE HEMISQUALANE CN by AMYRIS;

[0120] - volatile non-aromatic cyclic C5-C12 alkanes;

[0121] - C8-C16 branched esters, iso-hexyl neopentanoate;

[0122] - short-chain esters (having from 3 to 8 carbon atoms in total) such as Methyl acetate, ethyl acetate, methyl acetate, propyl acetate, n-butyl acetate or isobutyl acetate for example sold by SOLVAY, DOW or OXEA;

[0123] - volatile carbonate hydrocarbon oils of structure R' lO-CO-O-R'2 in in which R'1 and R'2 independently designate a linear, branched, or cyclic C4-C8 alkyl group, preferably a C4-C8 alkyl group. It may be preferable for R1 and R2 to be identical. Preferably, R'1 and R'2 designate a linear butyl alkyl radical or a pentyl group. Advantageously, the ether oil is chosen from dibutyl carbonate or dipentyl carbonate;

[0124] - volatile ether oils of formula R1OR2 in which RI and R2 denote independently a linear, branched or cyclic C4-C8 alkyl group, preferably a C4-C8 alkyl group. It may be preferable for RI and R2 to be identical.

[0125] Examples of linear alkyl groups include a butyl group and a pentyl group. Examples of branched alkyl groups include a 1-methylpropyl group, a 2-methylpropyl group, a β-butyl group, and a 1,1-dimethylpropyl group. Advantageously, the ether oil is selected from dicaprylyl ether, particularly dicaprylyl ether.

[0126] Other volatile hydrocarbon oils such as petroleum distillates, in particular those sold under the name Shell Sol T by the company SHELL, may also be used; or even volatile linear alkanes such as those described in the patent application of the company Cognis DE102008012457.

[0127] Volatile hydrocarbon oils are preferably chosen from hydrocarbon-type hydrocarbon oils (i.e., non-polar hydrocarbon oils, consisting solely of carbon and hydrogen) having 8 to 16 carbon atoms and mixtures thereof, and in particular:

[0128] - C8-C16 branched alkanes such as isoalkanes (also called isoparaffins), isododecane, isodecane, isohexadecane, and for example oils sold under the trade names Isopars or Permetyls, alone or in mixtures,

[0129] -linear alkanes, for example in Cl 1-C15, alone or in mixtures, and

[0130] -their mixtures.

[0131] The volatile hydrocarbon oil(s) are in particular chosen from among the alkanes and in C6-C16 and in particular alkanes such as dodecane, tetradecane, isohexadecane, mixtures of undecane and tridecane, and isoparaffins such as Cl3-16 Isoparaffin.

[0132] According to a preferred embodiment of the invention, the volatile oil(s) are hydrocarbon oils, linear or branched, which are volatile, in particular selected from undecane, decane, dodecane, isododecane, isohexadecane, tridecane, tetradecane and mixtures thereof, preferably comprising isododecane and / or a mixture of undecane and tridecane.

[0133] According to a particular embodiment of the invention, the volatile oil(s) of the invention are a mixture of C9-C12 alkanes, preferably of natural origin, whose chains comprise 9 to 12 carbon atoms, preferably linear or branched C9-C12 alkanes. This mixture is notably known under the INCI name C9-C12 ALCANE, CAS 68608-12-8, VEGELIGHT SILK® marketed by BioSynthls.

[0134] According to a preferred embodiment, the volatile oil or oils are at least partially of vegetable origin.

[0135] According to a preferred embodiment of the invention, the composition according to the invention contains less than 70% by weight, preferably less than 60% by weight, preferably less than 50% by weight, preferably less than 40% by weight, preferably less than 30%, preferably less than 20%, or even less than 15% by weight, or even less than 10% by weight of volatile hydrocarbon oil relative to the total weight of the composition.

[0136] According to another preferred embodiment, the composition of the invention contains between 1% and 50% by weight, preferably between 2% and 40% by weight, preferably between 3% and 30% by weight, preferably between 4% and 25% by weight, or even between 5% and 20% by weight of volatile hydrocarbon oil relative to the total weight of the composition.

[0137] According to another particular embodiment, the composition of the invention comprises a volatile hydrocarbon oil in a particular weight ratio [volatile hydrocarbon oil] / [compound a)] of between 99 / 1 and 1 / 99, preferably between 95 / 5 and 5 / 95, preferably between 90 / 10 and 10 / 90, preferably between 85 / 15 and 20 / 80, preferably between 80 / 20 and 30 / 70, preferably between 75 / 25 and 40 / 60, preferably between 70 / 30 and 50 / 50. volatile silicone oil

[0138] By "siliconized oil" is meant an oil comprising at least one silicon atom, and in particular at least one Si-O group, and more particularly an organopolysiloxane.

[0139] Volatile silicone oils can be selected from linear, branched or cyclic silicone oils such as polydimethylsiloxanes (PDMS) having 3 to 7 silicon atoms.

[0140] Examples of such oils include octyltrimethicone, hexyltrimethicone, methyl trimethicone, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, decamethyltetrasiloxane, polydimethysiloxanes such as those marketed under the reference DC 200 (1.5 cSt), DC 200 (3 cSt) by Dow Corning, or KF 96 A from Shin Etsu; alone or in mixtures.

[0141] According to a particular embodiment of the invention, a mixture of at least one volatile hydrocarbon oil and at least one volatile silicone oil will be used, and more particularly a mixture of isododecane and dodecamethylpentasiloxane.

[0142] Advantageously, the composition according to the invention contains less than 30%, preferably less than 20%, preferably less than 10%, preferably less than 1%, preferably less than 0.5%, preferably less than 0.2%, preferably less than 0.1%, by weight of silicone oil on the total weight of the composition, and ideally the composition of the invention is free of any silicone oil.

[0143] Preferably, in the composition according to the invention, the volatile oil or oils are selected from volatile hydrocarbon oils, in particular different from compound a), preferably selected from volatile nonpolar hydrocarbon oils having 8 to 16 carbon atoms, preferably selected from: C8-C16 isoalkanes such as isododecane, isodecane, or isohexadecane; C6-C16 linear alkanes, in particular C11-C15, alone or in mixtures, such as hexane, decane, undecane, tridecane, n-dodecane (C12), n-tetradecane (C14), in particular the undecane-tridecane mixture, mixtures of n-undecane (C11) and n-tridecane (C14); plant-derived alkanes, particularly from coconut, or mixtures of C13-C15 alkanes; and mixtures thereof.

[0144] Preferably, in the composition according to the invention, the volatile oil or oils are chosen from volatile hydrocarbon oils.

[0145] The composition of the present invention preferably comprises isododecane, linear or branched C9-C12 alkanes, and / or mixtures of n-undecane (C11) and n-tridecane (C13); preferably it comprises isododecane

[0146] According to one embodiment of the invention, the composition may further comprise one or more non-volatile oils. Non-volatile oils

[0147] By "non-volatile oil" is meant an oil whose vapor pressure at 20°C and atmospheric pressure is non-zero and less than 2.66 Pa, more particularly less than 0.13 Pa. By way of example, the vapor pressure can be measured according to the static method or by the isothermal thermogravimetric effusion method, according to the vapor pressure of the oil (OECD standard 104).

[0148] The non-volatile oil(s) of the invention are of natural or synthetic origin, preferably natural.

[0149] According to a particular embodiment of the invention, composition Cl or C' 1 comprises one or more non-volatile oils.

[0150] Among the non-volatile oils, we can mention: Non-volatile silicone oils

[0151] The non-volatile silicone oil may in particular be chosen from the following non-volatile silicones with INCI names: dimethicone, dimethiconol, trimethyl pentaphenyl trisiloxane, tetramethyl tetraphenyl trisiloxane, diphenyl dimethicone, trimethylsiloxyphenyl dimethicone, phenyltrimethicone, diphenylsiloxy phenyl trimethicone; as well as mixtures thereof.

[0152] These products are marketed in particular under the names PH-1555 HRI Cosmetic Fluid (Trimethyl Pentaphenyl Trisiloxane), Dow Corning 556 Cosmetic Grade Fluid (Phenyltrimethicone) by Dow Corning; Diphenyl Dimethicone such as the products KF-54, KF54HV, KF-50-300CS, KF-53 d, KF-50-100CS or Diphenylsiloxy Phenyl Trimethicone KF56 A marketed by Shin Etsu; the products Belsil PDM 1000, Belsil PDM 20 marketed by Wacker Chemie (Trimethylsiloxy Phenyl Dimethicone), alone or in mixtures. Non-volatile fluorinated oils

[0153] By "fluoridated oil" is meant an oil comprising at least one fluorine atom.

[0154] The fluorinated oil may in particular be selected from fluorinated polyethers, as well as from fluorosilicone oils, fluorinated silicones as described in document EP-A-847752. Non-volatile, non-polar hydrocarbon oils

[0155] Non-volatile, non-polar hydrocarbon oils may be selected from linear or branched compounds of mineral or synthetic origin, such as, for example:

[0156] - paraffin oil,

[0157] - squalane, such as the NEOSSANCE SQUALANE reference marketed by AMYRIS,

[0158] - isoeicosan,

[0159] - linear, saturated hydrocarbons, and their mixtures, more particularly in C15-C28, such as mixtures whose INCI names are for example the following: C15-19 Alkane, C18-C21 Alkane, C21-C28 Alkane, such as for example the products Gemseal 40, Gemseal 60, Gemseal 120 marketed by Total, Emogreen L19, Emogreen L15 marketed by SEPPIC,

[0160] - polybutenes, hydrogenated or not, such as, for example, products from the range Indopol products marketed by INEOS Oligomers, with the INCI name HYDROGENATED POLYISOBUTENE

[0161] - polyisobutenes, hydrogenated or not, such as for example non- volatile oils from the Parléam® range marketed by the company NIPPON OIL FATS,

[0162] - polydecenes, hydrogenated or not, such as for example non- volatiles of the PURESYN® range marketed by ExxonMobil),

[0163] - decene / butene copolymers, butene / isobutene copolymers

[0164] - and their mixtures. Polar non-volatile hydrocarbon oils

[0165] They can be chosen from:

[0166] - fatty alcohols, saturated, unsaturated, linear or branched, in the C10-C26 range, preferably Monoalcohols. Advantageously, C10-C26 alcohols are fatty alcohols, preferably branched when they comprise at least 16 carbon atoms. Preferably, the fatty alcohol comprises from 10 to 24 carbon atoms, and more preferably from 12 to 22 carbon atoms, such as in particular lauric, isostearyl, oleic alcohol, 2-butyloctanol, 2-undecyl pentadecanol, 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol and mixtures thereof;

[0167] - triglycerides consisting of fatty acid esters and glycerol, in particular whose fatty acids can have chain lengths ranging from C4 to C36, and in particular from C8 to C36, preferably from C18 to C36, these oils being linear or branched, saturated or unsaturated. Examples include heptanoic or octanoic triglycerides, caprylic / capric acid triglycerides; vegetable oils such as wheat germ, sunflower, grapeseed, sesame, corn, apricot, castor, shea, avocado, olive, soybean, sweet almond, palm, rapeseed, cottonseed, hazelnut, macadamia, jojoba, alfalfa, poppy, pumpkin, squash, blackcurrant, evening primrose, millet, barley, quinoa, rye, safflower, candlenut, passionflower, and rosehip oils; the liquid fraction of shea butter and the liquid fraction of cocoa butter; as well as mixtures thereof;

[0168] - linear aliphatic hydrocarbon esters of formula RCOOR' in whichRCOO represents a carboxylic acid remnant comprising from 2 to 40 carbon atoms, and R' represents a hydrocarbon chain containing from 1 to 40 carbon atoms, the aliphatic hydrocarbon esters of alkylene glycol, in particular ethylene glycol or propylene glycol; the total number of carbon atoms advantageously being at least 10.Examples of such esters include isoamyl laurate, cetostearyl octanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate or isostearate, ethyl palmitate, 2-ethylhexyl palmitate, isostearyl isostearate, octyl stearate, isostearyl heptanoate, coco caprylate / caprate, and octanoates, decanoates, or ricinoleates of alcohols or polyalcohols such as propylene glycol dioctanoate, cetyl octanoate, tridecyl octanoate, ethyl 2-hexyl palmitate, alkyl benzoate, polyethylene glycol diheptanoate, and diethyl 2-Propylene glycol hexanoate. and their mixtures, hexyl laurate, neopentanoic acid esters such as isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyl-2-docecyl neopentanoate, isononanoic acid esters such as isononyl isononanoate, isotridecyl isononanoate, octyl isononanoate, oleyl erucate; lauroyl isopropyl sarcosinate, diisopropyl sebacate, isocetyl stearate, isodecyl neopentanoate, isostearyl behenate, myristyl myristate;

[0169] - hydroxylated esters such as polyglycerol-2 triisostearate;

[0170] - aromatic esters such as tridecyl trimellitate, benzoate of Cl2- alcohols C15, 2-phenyl ethyl ester of benzoic acid, butyl octyl salicylate;

[0171] - linear fatty acid esters having a total carbon number from 35 to 70 such as pentaerythrityl tetrapelargonate;

[0172] - fatty alcohol esters or C24-C28 branched fatty acids such as citrate triisoarachidyl, pentaerythrityl tetraisononanoate, glyceryl triisostearate, glyceryl tridecyl-2 tetradecanoate, pentaerythrityl tetraisostearate, polyglyceryl-2 tetraisostearate or pentaerythrityl tetradecanoate;

[0173] - polyesters obtained by condensation of fatty acid dimers and / or trimers unsaturated and diol such as those with INCI name dilinoleic acid / butanediol copolymer, dilinoleic acid / propanediol copolymer; polyesters obtained by condensation of fatty acid dimer and diol dimer such as dilinoleyl dimer dilinoleate;

[0174] - synthetic ethers having 10 to 40 carbon atoms such as dicaprylyl ether;

[0175] - di-alkyl carbonates, the two alkyl chains being able to be identical or different ones, such as dicaprylyl carbonate;

[0176] - vinylpyrrolidone copolymers such as vinylpyrrolidone / 1- copolymer hexadecene (INCI name);

[0177] - their mixtures.

[0178] According to one embodiment, the non-volatile oil(s) are chosen from non-volatile silicone oils, non-volatile hydrocarbon oils, polar hydrocarbon oils as defined above, and mixtures thereof, preferably chosen from non-volatile hydrocarbon oils, polar hydrocarbon oils as defined above and mixtures thereof.

[0179] According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil selected from linear aliphatic hydrocarbon esters of formula RCOOR' in which RCOO represents a carboxylic acid residue comprising from 2 to 40 carbon atoms, and R' represents a hydrocarbon chain containing from 1 to 40 carbon atoms, the aliphatic hydrocarbon esters of alkylene glycol, in particular ethylene glycol or propylene glycol as defined above, more preferably chosen from isoamyl laurate, isopropyl myristate, isodecyl neopentanoate, isostearyl neopentanoate, isononyl isononanoate, coco caprylate caprate and mixtures thereof, and even better designate isononyl isononanoate.;

[0180] According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil selected from fatty alcohols, saturated, unsaturated, linear or branched, in C10-C26, preferably monoalcohols, preferably branched when they comprise at least 16 carbon atoms as described above, in particular selected from oleic alcohol, 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol such as reference EUTANOL G marketed by BASF and their mixtures.

[0181] According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil selected from triglycerides consisting of esters of fatty acids and glycerol, in particular whose fatty acids may have chain lengths ranging from C4 to C36, and in particular from C18 to C36, these oils being linear or branched, saturated or unsaturated as described above, preferably selected from heptanoic or octanoic triglycerides, caprylic / capric acid triglycerides and mixtures thereof, and more preferably caprylic / capric acid triglycerides such as reference PALMESTER 3585 marketed by KLK OLEO.

[0182] According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil selected from non-polar hydrocarbon non-volatile oils as described above, preferably selected from mixtures of linear, saturated hydrocarbons, more particularly C15-C28, polybutenes, hydrogenated or not, and mixtures thereof.

[0183] According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil selected from the non-polar hydrocarbon non-volatile oils selected from mixtures whose INCI names are for example the following: C15-19 Alkane, C18-C21 Alkane, C21-C28 Alkane, such as for example the products Gemseal 40, Gemseal 60, Gemseal 120 marketed by Total, Emogreen L19 marketed by SEPPIC, Emogreen L15 marketed by SEPPIC, the products with the INCI name HYDROGENATED POLYISOBUTENE, and their mixtures.

[0184] According to a particular embodiment of the invention, the non-volatile hydrocarbon oil(s) c) comprise or consist of at least one non-volatile oil selected from isoamyl laurate, isopropyl myristate, isodecyl neopentanoate, isostearyl neopentanoate, isononyl isononanoate, alcohol oleic, 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol, caprylic / capric acid triglycerides, mixtures whose INCI names are for example the following: C15-19 Alkane, C18-C21 Alkane, C21-C28 Alkane, such as for example the products Gemseal 40, Gemseal, the products with INCI name HYDROGENATED POLYISOBUTENE, and their mixtures, more particularly chosen from products with INCI name HYDROGENATED POLYISOBUTENE, the mixtures with INCI name C15-19 Alkane such as Emogreen L15 marketed by SEPPIC, isononyl isononanoate.

[0185] According to one embodiment, the non-volatile hydrocarbon oil(s) consist of one or more polar or non-polar non-volatile hydrocarbon oils as defined above.

[0186] According to one embodiment, the non-volatile oil(s) comprise at least one silicone oil as defined above, preferably chosen from among the dimethicones, such as the grade BELSIL DM 5 PLUS DIMETHICONE marketed by Wacker, the reference DOWSIL SH 200 C FLUID 10 CST marketed by DOW CHEMICAL or the reference XIAMETER PMX-200 SILICONE FLUID 1000 CST marketed by DOW CHEMICAL, or the PHENYL TRIMETHICONE such as the reference DOWSIL SH 556 FLUID marketed by DOW CHEMICAL.

[0187] Preferably when the non-volatile oil(s) is a mixture of at least one non-volatile hydrocarbon oil, preferably chosen from non-polar non-volatile hydrocarbon oils and polar non-volatile hydrocarbon oils with at least one volatile silicone oil, the amount of silicone oil is less than 30%, preferably less than 20%, preferably less than 10% by weight, relative to the total weight of the composition.

[0188] Advantageously, the possible non-volatile oil(s) are present in the composition at a rate of 0.1% to 50%, preferably 0.2% to 40%, preferably 0.5% to 35%, preferably 1% to 30%, more preferably between 1% and 20%, preferably between 1% and 10%, by weight, relative to the total weight of the composition.

[0189] Preferably, the composition according to the invention comprises at least one non-volatile oil, preferably in a weight content of less than or equal to 50%, preferably less than or equal to 40%, preferably less than or equal to 30%, and preferably less than or equal to 20%, preferably less than or equal to 15%, and preferably less than or equal to 10%, and preferably less than or equal to 8%, relative to the total weight of the composition.

[0190] By weight ratio denoted R, we mean the ratio of the sum of the masses of volatile oil(s) (VO) to the sum of the masses of non-volatile oil(s) (NVO), defined by:

[0191] R = [Sum of HV masses] / [Sum of HNV masses].

[0192] Preferably, R is such 0 < R < 10,000, more particularly 0.01 < R < 1,000; more particularly 0.05 < R < 500; preferably 0.1 < R < 100, preferably 0.2 < R < 50, or even 0.5 < R < 10. Possible silicone(s)

[0193] Preferably, the composition according to the invention comprises, in relation to the total weight of the composition, 10% by weight or less, preferably 5% by weight or less, preferably from 0.1 to 10% by weight, of silicone.

[0194] By silicone, we mean any silicone compound.

[0195] Preferably, the composition according to the invention is substantially free of silicone, different from a film-forming or tackant silicone polymer, preferably different from a silicone resin or a silicone acrylate copolymer, preferably different from an MQ resin or an acrylates / polytrimethylsiloxy-methacrylate copolymer.

[0196] By "substantially free of silicone other than a film-forming or tack-forming silicone polymer, preferably a silicone resin or a silicone acrylate copolymer, preferably other than an MQ resin or an acrylates / polytrimethylsiloxy-methacrylate copolymer", it is understood that the composition comprises less than 1% by weight relative to the total weight of the composition, preferably less than 0.5% by weight, preferably less than 0.3% by weight, preferably less than 0.1% by weight of silicone other than a film-forming or tack-forming silicone polymer, preferably a silicone resin or a silicone acrylate copolymer, preferably other than an MQ resin or an acrylates / polytrimethylsiloxy-methacrylate copolymer.Preferably, the composition is totally free of silicone other than a film-forming or tackifying silicone polymer, preferably a silicone resin or a silicone acrylate copolymer, preferably other than an MQ resin or an acrylates / polytrimethylsiloxy-methacrylate copolymer. By silicone other than a film-forming or tackifying silicone polymer, preferably other than a silicone resin or a silicone acrylate copolymer, preferably other than an MQ resin or an acrylates / polytrimethylsiloxy-methacrylate copolymer, is meant any silicone compound that is not a film-forming or tackifying silicone polymer, preferably not a silicone resin or a silicone acrylate copolymer, preferably not an MQ resin or an acrylates / polytrimethylsiloxy-methacrylate copolymer.

[0197] The term "resin" refers to a compound with a three-dimensional structure. Thus, for the purposes of the present invention, a polydimethylsiloxane is not a silicone resin.

[0198] The nomenclature of silicone resins is known as "MDTQ", the resin being described according to the different siloxane monomeric units it comprises, each of the letters "MDTQ" characterizing a type of unit.

[0199] The letter “M” represents the Monofunctional unit of formula RlR2R3SiOi / 2, the silicon atom being bonded to a single oxygen atom in the polymer comprising this unit.

[0200] The letter “D” signifies a Difunctional unit R1 R2SiO2 / 2 in which the silicon atom is bonded to two oxygen atoms.

[0201] The letter “T” represents a Trifunctional unit of formula RlSiO3 / 2.

[0202] In the motifs M, D, T defined above, Ri, namely RI, R2 and R3, identical or different, represent a hydrocarbon radical (in particular alkyl) having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or even a hydroxyl group.

[0203] Finally, the letter “Q” signifies a Tetrafunctional SiO4 / 2 unit in which the silicon atom is bonded to four oxygen atoms which are themselves bonded to the rest of the polymer.

[0204] Such resins are described for example in "Encyclopedia of Polymer Science and Engineering, vol. 15, John and Wiley and Sons, New York, (1989), p. 265-270, and US 2,676,182, US 3,627,851, US 3,772,247, US 5,248,739 or US 5,082,706, US 5,319,040, US 5,302,685 and US 4,935,484.

[0205] MQ-type silicone resins are, for example, alkylsiloxysilicates of the formula [(Rl)3SiO1 / 2]x(SiO4 / 2)y (MQ units), where x and y are integers from 50 to 80, and such that the RI group represents a radical as defined above, and preferably is an alkyl group having from 1 to 8 carbon atoms, or a hydroxyl group, preferably a methyl group. In particular, trimethylsiloxysilicate or phenylalkylsiloxysilicate resins, such as phenylpropyldimethylsiloxysilicate, are distinguished.

[0206] Silicone polymers include siloxanes having an organo group, such as polyalkylsiloxanes, where at least one alkyl group is other than methyl, for example organopolysiloxanes with the INCI name Stearyl Dimethicone, Cetyl Dimethicone or C26-28 Alkyl Dimethicone, or, for example, polyarylsiloxanes and polyarylalkylsiloxanes, for example organopolysiloxanes with the INCI name Phenyl Trimethicone, Trimethylsiloxyphenyl Dimethicone or Dimethylphenyl Dimethicone, or, for example, organopolysiloxanes having an organo group such as an aminopropyl, aminopropyl-aminoethyl, aminopropyl-aminoisobutyl group, for example organopolysiloxanes with the INCI name Amodimethicone, or, for example, the organopolysiloxanes having a polyethylene glycol or polyalkylene glycol radical, for example organopolysiloxanes having the INCI name PEG-12 Dimethicone, PEG / PPG-25,25-Dimethicone or Cetyl PEG / PPG-15 / 15 Butyl ether Dimethicone.

[0207] Silicone acrylate copolymers are polymers comprising a siloxane group and a hydrocarbon group. For example, suitable polymers include polymers comprising a hydrocarbon backbone such as, for example, a backbone selected from vinyl polymers, methacrylic polymers and / or acrylic polymers and at least one chain selected from pendant siloxane groups and polymers comprising a backbone of siloxane groups and at least one pendant hydrocarbon chain such as, for example, a pendant vinyl, methacrylic and / or acrylic group.

[0208] The silicone acrylate copolymer can be selected from polymers derived from non-polar silicone copolymers comprising repeating units of at least one polar (meth)acrylate unit and vinyl copolymers grafted with at least one non-polar silicone chain. Non-limiting examples of such copolymers include acrylate / dimethicone copolymers such as those commercially available from Shin-Etsu, for example, products sold under the brand names KP-545 (cyclopentasiloxane (and) acrylates / dimethicone copolymer), KP-543 (butyl acetate (and) acrylates / dimethicone copolymer), KP-549 (methyl trimethicone (and) acrylates / dimethicone copolymer), KP-550 (INCI name: isododecane (and) acrylate / dimethicone copolymer), KP-561 (acrylates / stearyl acrylate / dimethicone acrylates copolymer), KP-562 (acrylates / behenyl acrylate / dimethicone acrylates copolymer), and mixtures thereof.Additional examples include acrylate / dimethicone copolymers sold by Dow Corning under the brand names FA 4001 CM SILICONE ACRYLATE (cyclopentasiloxane (and) acrylates / polytrimethylsiloxymethacrylate copolymer), FA 4002 ID SILICONE ACRYLATE (isododecane (and) acrylates / polytrimethylsiloxymethacrylate Copolymer), and FA 4004 ID SILICONE ACRYLATE (isododecane (and) acrylates / polytrimethylsiloxymethacrylate Copolymer), and mixtures thereof.

[0209] According to one embodiment, the composition according to the invention is substantially silicone-free. By "substantially silicone-free," it is understood that the composition comprises less than 1% by weight relative to the total weight of the composition, preferably less than 0.5% by weight, preferably less than 0.3% by weight, and preferably less than 0.1% by weight of silicone. Preferably, the composition is completely silicone-free. In this embodiment, silicone means any silicone compound, including film-forming or tackifying silicone polymers.

[0210] According to a particular embodiment of the invention, the composition according to the invention comprises one or more volatile oils, one or more oils non-volatile, possibly water and possibly one or more organic solvents other than oils a) and alcohols b) defined according to the invention.

[0211] According to one embodiment of the invention, the composition comprises at least one continuous oily phase of composition defined above.

[0212] According to a first embodiment, the composition of the invention is in the form of an oily composition, in particular anhydrous, such as an oily dispersion or an oily solution.

[0213] According to a second embodiment of the invention, the composition further presents an aqueous phase.

[0214] Advantageously, the total oil phase content is in the range of 5 to 100%, preferably 10 to 98% by weight, preferably 20 to 90% by weight, preferably 30 to 80% by weight, relative to the total weight of the composition. Aqueous phase

[0215] The aqueous phase comprises water and optionally ingredients soluble or miscible in water such as water-soluble solvents.

[0216] A suitable water for the invention may be a floral water such as cornflower water and / or a mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or a thermal water.

[0217] In the present invention, a water-soluble solvent is defined as a compound that is liquid at room temperature and miscible with water (miscibility in water greater than 50% by weight at 20°C and atmospheric pressure).

[0218] The water-soluble solvents usable in the composition of the invention may also be volatile.

[0219] Among the water-soluble solvents that can be used in the composition according to the invention, we can mention in particular lower monoalcohols having 1 to 5 carbon atoms such as ethanol and isopropanol, glycols having 2 to 8 carbon atoms such as ethylene glycol, propylene glycol, 1,3-butylene glycol, propanediol, pentylene glycol, glycerin and dipropylene glycol, C3-C4 ketones and C2-C4 aldehydes.

[0220] Advantageously, the aqueous phase is preferably present with a total weight content in the range of 2 to 95% by weight, preferably 5 to 90% by weight, preferably 10 to 80% by weight, more particularly 15 to 70% by weight, preferably 20 to 60% by weight, preferably 20 to 50% by weight relative to the total weight of said composition.

[0221] The composition according to the invention may further comprise at least one additive selected from those commonly used in the cosmetic field: active ingredients such as vitamins, anti-aging active ingredients; UV filters different from compound b); fillers; lipophilic thickeners; surfactants; perfumes; preservatives; and mixtures thereof. Possible surfactants

[0222] According to a particular embodiment of the invention, the composition further comprises one or more surfactant(s), preferably non-ionic, ionic or mixtures thereof.

[0223] According to another particular embodiment of the invention, the composition does not include a surfactant.

[0224] The term "surfactant" refers to a compound that modifies the surface tension between two surfaces. Surfactants are amphiphilic molecules, which have two parts of different polarities: one lipophilic (attracting fats), which is nonpolar, and the other hydrophilic (miscible or soluble in water), which is polar. The lipophilic part is generally a fat chain, and the other part, miscible with water, is polar and / or protic.

[0225] By "ionic" we mean anionic, cationic, amphoteric, or zwitterionic.

[0226] By "fatty chain" is meant a hydrocarbon chain comprising more than 6 atoms, preferably between 6 and 30 carbon atoms, preferably from 8 to 24 carbon atoms, linear or branched, saturated or not.

[0227] Emulsifying surfactants are characterized by their HLB (Hydrophilic Lipophilic Balance), the HLB being the ratio between the hydrophilic and lipophilic parts in the molecule. The term HLB is well known to those skilled in the art and is described, for example, in *The HLB System: A Time-Saving Guide to Emulsifier Selection* (published by ICI Americas Inc., 1984). For emulsifying surfactants, the HLB generally ranges from 3 to 8 for the preparation of water-in-oil emulsions. The HLB of the surfactant(s) used according to the invention can be determined by the Griffin method or the Da Vies method.

[0228] When present, the surfactant(s) shall represent in total particularly from 0.01% to 30% by weight relative to the total weight of the composition, preferably from 0.5% to 15% by weight, and even more preferably from 1% to 10% by weight, better between 1% and 7% by weight of the composition. Possible lipophilic thickeners

[0229] The composition according to the invention may optionally comprise at least one lipophilic thickener, chosen more particularly from silicas, hydrophobic or not; lipophilic clays; alone or in mixture. Silicas

[0230] The composition according to the invention may thus comprise, as a mineral thickener, a fumed silica, preferably hydrophobic, or silica aerogel particles, preferably hydrophobic. Pyrogenated silica

[0231] Suitable for the invention is hydrophobically treated fumed silica. It is indeed possible to chemically modify the surface of silica by a chemical reaction that reduces the number of silanol groups present on the silica surface. In particular, silanol groups can be replaced by hydrophobic groups, resulting in hydrophobic silica.

[0232] Hydrophobic groups can be: - Trimethylsiloxyl groups, which are obtained in particular by treating fumed silica in the presence of hexamethyldisilazane. Silicas treated in this way are called "Silica Silylate" according to the CTFA (8th edition, 2000). They are marketed, for example, under the references Aerosil R812® by the company Degussa, and CAB-O-SIL TS-530® by the company Cabot. - dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained in particular by treating fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas treated in this way are called "Silica Dimethyl Silylate" according to the CTFA (8th edition, 2000). They are marketed, for example, under the references Aerosil R972® and Aerosil R974® by the company Degussa, and CAB-O-SIL TS-610® and CAB-O-SIL TS-720® by the company Cabot. Silica aerogels

[0233] Silica aerogels are porous materials obtained by replacing (by drying) the liquid component of a silica gel with air.

[0234] They are generally synthesized by the sol-gel process in a liquid medium and then dried, usually by extraction from a supercritical fluid, most commonly supercritical CO2. This type of drying prevents pore and material contraction. The sol-gel process and the various drying methods are described in detail in Brinker CL, and Scherer GW, Sol-Gel Science: New York: Academie Press, 1990.

[0235] Hydrophobic silica aerogel particles usually have a specific surface area per unit mass (SM) of 500 to 1500 m2 / g, preferably 600 to 1200 m2 / g and better 600 to 800 m2 / g, and a size expressed as volume mean diameter (D[0,5]) of 1 to 1500 pm, better 1 to 1000 pm, preferably 1 to 1000 pm, in particular 1 to 30 pm, preferably still 5 to 25 pm, better 5 to 20 pm and better still 5 to 15 pm.

[0236] According to one embodiment, the hydrophobic silica aerogel particles used in the present invention have a size expressed in average diameter in volume (D[0,5]) ranging from 1 to 30 pm, preferably from 5 to 25 pm, better from 5 to 20 pm and even better from 5 to 15 pm.

[0237] The specific surface area per unit mass can be determined by the nitrogen absorption method known as the BET (BRUNAUER-EMMET-TELLER) method, described in "The Journal of the American Chemical Society", Vol. 60, Page 309, February 1938, and corresponding to the international standard ISO 5794 / 1 (Annex D). The BET specific surface area corresponds to the total specific surface area of ​​the particles considered.

[0238] The particle sizes of silica aerogel can be measured by static light scattering using a commercial particle size analyzer such as the Malvern MasterSizer 2000. The data are processed based on Mie scattering theory. This theory, accurate for isotropic particles, allows for the determination of an "effective" particle diameter in the case of non-spherical particles. This theory is described in particular in Van de Hulst, H.C., "Light Scattering by Small Particles," Chapters 9 and 10, Wiley, New York, 1957.

[0239] According to an advantageous embodiment, the hydrophobic silica aerogel particles used in the present invention have a specific surface area per unit mass (SM) ranging from 600 to 800 m2 / g and a size expressed in volume mean diameter (D[0.5]) ranging from 5 to 20 pm and even better from 5 to 15 pm.

[0240] Aerogels are hydrophobic silica aerogels, preferably silylated silica (INCI name Silica Silylate).

[0241] By "hydrophobic silica" is meant any silica whose surface is treated with silylation agents, for example with halogenated silanes such as alkylchlorosilanes, siloxanes, in particular dimethylsiloxanes such as hexamethyldisiloxane, or silazanes, so as to functionalize the OH groups with silyl Si-Rn groups, for example trimethylsilyl groups.

[0242] Regarding the preparation of surface-modified hydrophobic silica aerogel particles by silylation, reference can be made to US document 7,470,725.

[0243] Preferably, hydrophobic silica aerogel particles modified on the surface by trimethylsilyl groups will be used.

[0244] As examples of hydrophobic silica aerogels that can be used in the invention, we can cite, for example, the aerogel marketed under the name VM-2260 (INCI name Silica Silylate), by the company Dow Corning, whose particles have an average size of about 1000 microns and a specific surface area per unit mass ranging from 600 to 800 m2 / g.

[0245] We can also mention the aerogels marketed by the Cabot company under the references AEROGEL TLD 201®, AEROGEL OGD 201®, AEROGEL TLD 203®, ENOVA AEROGEL MT 1100®, ENOVA AEROGEL MT 120.

[0246] We can also mention the aerogel marketed under the name VM-2270 (name INCI Silica Silylate), by the company Dow Corning, whose particles have an average size ranging from 5-15 microns and a specific surface area per unit mass ranging from 600 to 800 m2 / g. Lipophilic clays

[0247] The term “lipophilic clay” means any clay that is liposoluble or lipodispersible in the oily phase of the composition.

[0248] Clay refers to a material based on hydrated silicates and / or aluminosilicates with a lamellar structure.

[0249] Clays can be natural or synthetic and are made lipophilic by treatment with an alkyl ammonium salt such as a C22 C1O ammonium chloride, in particular steralkonium chloride or di-stearyl di-methyl ammonium chloride.

[0250] They can be chosen from among bentonites, in particular bentonites, hectorites and montmorillonites, beidellites, saponites, nontronites, sepiolites, biotites, attapulgites, vermiculites and zeolites.

[0251] Preferably, they are chosen from among the hectorites and the bentonites.

[0252] For example, a lipophilic clay selected from hydrophobic modified bentonites and hydrophobic modified hectorites, in particular by a quaternary ammonium chloride in C22CIO, can be used, such as: - a bentonite modified by stearalkonium chloride such as the commercial products sold under the name CLAYTONE AF®, GARAMITE VT®, TIXOGEL® LG-M, TIXOGEL® MP 250 TIXOGEL® VZ, TIXOGEL® VZ-V XR, by the company BYK Additives Inc; the commercial products sold under the name VISCOGEL® B3, VISCOGEL® B4, VISCOGEL® B7, VISCOGEL® B8, VISCOGEL® ED, VISCOGEL® GM, VISCOGEL® S4, VISCOGEL® SD by the company Bentec SPA; - a bentonite modified by stearalkonium chloride in the presence of at least propylene carbonate and at least one oil such as the commercial products DUB VELVET GUM® from STEARINERIE DUBOIS FILS, MYGLYOL GEL T® from Cremer Oleo, TIXOGEL® CGT 6030, TIXOGEL® DBA 6060, TIXOGEL® FTN, TIXOGEL® FTN 1564, TIXOGEL® IPM, TIXOGEL® LAN, TIXOGEL® LAN 1563 by BYK Additives Inc; - a hectorite modified with distearyl dimethyl ammonium chloride (INCI name: DISTEARDIMONIUM HECTORITE) such as, for example, the commercially available one under the name BENTONE® 38VCG RHEOLOGICAL ADDITIVE by the company Elementis Specialities; - a hectorite modified by distearyl dimethyl ammonium chloride in the presence of at least propylene carbonate or triethyl citrate and at least one oil such as the commercial products sold under the name BENTONE® GEL DOA V, BENTONE® GEL EUG V, BENTONE® GEL IHD V, BENTONE® GEL ISD V, BENTONE® GEL MIO V® BENTONE® GEL PTM V® BENTONE® SS-71 V, BENTONE® VS-5 PC V, BENTONE® VS-5 by the company Elementis Specialities; the commercial products sold under the name CREAGEL BENTONE CPS / HECTONE CPS®, CREAGEL BENTONE ID / HECTONE ID® by the company Créations Couleurs; the commercial products sold under the name NS GEL DM1®, NS GEL PTIS®, NS MGEL 1152® by the company Next Step Laboratories Stop.

[0253] Lipophilic gelling agents may also be mentioned as esters of dextrin and fatty acids, in particular C12 to C24, preferably C14 to C18, or mixtures thereof. More preferably, the dextrin ester is a dextrin and fatty acid ester in the C12-C18 range, in particular C14-C18.

[0254] Preferably, the lipophilic gelling agent may be present in the composition at concentrations ranging, preferably from 0.1% to 5% by weight, and more preferably from 0.5% to 3% by weight relative to the total weight of the composition. Composition form

[0255] The composition of the invention may be in the form of an anhydrous composition, a water-in-oil emulsion or an oil-in-water emulsion, or an aqueous composition.

[0256] According to a first embodiment of the invention, the composition is monophasic oily.

[0257] According to another advantageous embodiment of the invention, the composition comprises an aqueous phase, in which case it is preferably in the form of a water-in-oil emulsion, or an oil-in-water emulsion, or possibly a composition with several separate phases (such as a bi-phase); preferably in the form of a water-in-oil emulsion.

[0258] By "water-in-oil" or W / O emulsion, we mean a composition comprising an oily phase and an aqueous phase that are not miscible; the aqueous phase being dispersed in the form of droplets in the oily (continuous) phase so as to obtain a macroscopically homogeneous composition.

[0259] Continuous oil phase galenic forms are preferred in the case of pigment dispersion according to the invention, which promotes their homogeneity and thus optimizes the coverage obtained for the film obtained after application of the composition according to the invention (as demonstrated in the examples).

[0260] The composition of the present invention is particularly suitable for the manufacture of cosmetic products with fluid textures. Advantageously, the composition according to the invention is more particularly in the form of a viscoelastic liquid ranging from fluid to viscous, whose G* modulus (viscoelastic modulus) is between 0.1 and 20,000 Pa, more particularly between 1 and 5,000 Pa, or even between 10 and 1,000 Pa. The G* modulus is measured with a stress rheometer, and the values ​​are taken on the viscoelastic plate at 25°C. Cosmetic applications

[0261] According to one embodiment, a composition of the invention may advantageously be in the form of a skin, body or face care composition, in particular a face care composition.

[0262] According to another embodiment, a composition of the invention may advantageously be in the form of a makeup composition for keratinous materials, in particular the skin of the body or face, in particular the face.

[0263] Thus, according to a sub-mode of this embodiment, a composition of the invention can advantageously take the form of a basic composition for makeup.

[0264] A composition of the invention may advantageously be in the form of a liquid product for lip makeup, in particular in the form of a liquid lipstick, or even a gloss.

[0265] According to another sub-equation of this embodiment, a composition of the invention may advantageously be in the form of a skin makeup composition, particularly for the face. It may thus be a foundation, an eyeshadow, or a blush.

[0266] It may also be a mascara, an eyeliner, a concealer or corrector, an eyebrow product, a skin care product, a sun product, or a hygiene product, or even a hair styling product, or hair coloring; or even a nail polish.

[0267] Such compositions are notably prepared according to the general knowledge of the person skilled in the art.

[0268] Throughout the application, the expression "includes a" or "comprises a" should be understood as meaning "containing at least one" or "comprising at least one", unless otherwise specified.

[0269] The following examples will help to better understand the invention, but are not intended to be limiting. Raw materials are named by their chemical or INCI name. Quantities indicated are as a percentage by weight of raw materials relative to the total weight of the composition (% w / w), unless otherwise stated. Examples

[0270] Preparation of a composition according to the invention and comparisons with comparative compositions Preparation

[0271] The compositions according to the invention (4, 5, 9, 10, 12, 13, 16 and 17), denoted "Inv" (according to the invention), and the comparative compositions (1, 2, 3, 6, 7, 8, 11, 14 and 15), denoted "HI" (not part of the invention), were prepared by mixing the ingredients of Tables 1, 2 and 3 below, respectively, as follows. A (fixed) quantity of pigment was weighed into a bottle using a precision balance (Mettler Toledo Excellence Plus model). Then, a (fixed) quantity of solvent was added to the bottle using a precision balance (Mettler Toledo Excellence Plus model). The resulting mixture was stirred using the Vortex-Genie 2™ vibrator (Scientific Industries), vibration force 8 for 1 minute. Evaluation of dispersion quality

[0272] The pigment dispersion sample described above was re-reacted using the Vortex-Génie 2™ vibratory shaker (Scientific Industries), vibration force 8 for 1 min. It was then immediately transferred to a cylindrical glass cell suitable for performing transmission (in %) measurements using Turbiscan Lab (Formulaction). The percentage of transmission corresponds to the percentage of incident light that passes through the sample.

[0273] The transmission value was taken at the midpoint of the sample height. The lower the transmission, the more "opaque" the sample, indicating good pigment dispersion throughout the sample volume. The higher the transmission, the more the pigments tend to settle to the bottom of the sample.

[0274] The measurements were carried out at room temperature (20°C) with programmed analysis at different times after sample preparation.

[0275] When Standard Deviations are indicated, they correspond to an average transmission value obtained on 2 different samples of each formulation.

[0276] Evaluation of the coverage and homogeneity of the deposits

[0277] The coverage and homogeneity of the deposits were evaluated by Contrast ratio measurements after deposition of the solutions on contrast maps.

[0278] The product is spread on a spreading table (Elcometer 4340 Applicator) which allows adjustment of both the speed and the distance over which it is spread. The table is equipped with a suction system connected to a pump to prevent the surface being spread from moving. Contrast cards with a black background and an uncoated white background are used (1 byko-chart, uncoated N2A, code 2831). The thickness The spreading depth is set at 50 µm wet, using a square spreader placed on the support to spread the film level when the platform is activated. A 960g weight is added on top of the spreader during the spreading process. The spreading speed is set to 2.54 cm / s. The films are dried for 24 hours at 34°C and ambient humidity (50% RH) on a heated plate.

[0279] The color measurement is performed using a Konica Minolta CM-700d spectrophotometer. The contact measurement ensures the absence of light pollution.

[0280] Selected settings: Aperture 8 mm; Uncertainty: 0.04; Measurement SCI / SCE; Geometry d / 8°.

[0281] Color measurements on the two backgrounds (black background FN and white background FB) allow the coverage of a deposit to be characterized by calculating the "contrast ratio" (CR%), which is higher the more covering the deposit: CR% = YFN / YFB x 100; where YFN and YFB

[0282] are respectively the luminance values ​​measured on the black background and the white background.

[0283] For each sample, 2 cards were prepared. On each card, 3 coverage measurements were taken. The coverage value shown is therefore an average of 6 measurements.

[0284] The homogeneity of the deposits is observed qualitatively and can be expressed numerically through the evolution of the variability of the coverage measurement. The more homogeneous the deposit, the lower the standard deviation of the coverage. In vitro assessment of Playtime

[0285] The Playtime of the product corresponds to the time during which the consumer can work with it during its application and therefore reflects the ease of application of the product, in particular before it becomes too dry.

[0286] This time is difficult to measure under in vivo conditions, due to very thin film thicknesses (approximately 2g / cm2), very rapid evaporation kinetics and a strong impact of spreading gestures.

[0287] One way to estimate the order of magnitude of this playtime in a measurable and repeatable manner is to return to the evaporation kinetics of the film on sufficiently thick films. By calculation, one can then return to a drying time that would correspond to the in vivo drying time (2 mg / cm²).

[0288] The evaporation rate was measured gravimetrically in a ventilated glove box at controlled temperature and humidity (30°C, 50% relative humidity). A balance, connected to a computer, measured the mass of the sample at each instant. On the computer, the BalanceLink software recorded the data generated by the balance every 30 seconds. The evaporation kinetics correspond to the slope of the curve representing the mass lost over time for initial formula deposits of approximately 58+ / -12 mg / cm2.

[0289] By calculation, using the evaporation kinetics of the compositions, the time required to reach 70% of the drying of the formulas was estimated, for wet deposits of 2 mg / cm2.

[0290] Calculated drying rate (70%, 2 mg / cm²) = 2 / (evaporation rate)*0.7

[0291] Results on the quality of pigment dispersion

[0292] The following compositions were produced and characterized in terms of dispersion quality by the transmission measurements noted in the following table.

[0293] [Tables 1] INCI Name (Trade Name and Manufacturer) 1 (HI) 2 (HI) 3 (HI) 4 (Inv) 5 (Inv) TITANIUM DIOXIDE (and) DISODIUM STEAROYL GLUTAMA TE (and) ALUMINUM HYDROXIDE (NAI-TAO-77891 by Miyoshi Kasei) 2 2 2 2 2 Ethyl Lactate (PURASOEVEE by PURAC) 98 - - - - Ethanol (CARGILL 66212) - 98 - - - Isododecane (INEOS) - - 98 - - Butyl Lactate (PURASOLV BL by PURAC) - - - 98 - Isopropylidene glycerol (AUGEO CRYSTAL by SOLVAY) - - - - 98 Transmission after 100% 5.2 24.3 52.3 0.2 0.1 Transmission after 1 p.m., % 6.1 34.3 54.2 2.6 0.5

[0294] The examples above show that the dispersion quality of the NAI (aluminum stearoyl glutamate) surface-treated pigments is better for the solvents and compositions of the invention (examples 4 and 5) than for the solvents and compositions not in accordance with the invention (comparatives 1, 2 and 3).

[0295] [Tables2] |INCI Name |ô |7 [8 [9 [10 (HI) (HI) (HI) (Inv) (Inv) TITANIUM DIOXIDE (HO MBIT AN FF PHARMA de VENATOR) 2 2 2 2 2 Ethyl Lactate 98 - - - - Ethanol - 98 - - - Isododecane - - 98 - - Butyl Lactate - - - 98 - Isopropylidene glycerol - - - - 98 Transmission after 13h, % 45.5 + 3.6 26.4 + 0.9 62.2 + 1.6 23.9 + 4.7 0.01 + 0 Transmission after 24h, % 68.6 + 1.2 44.2 + 0.2 63.1 + 2.4 50.3 + 8.6 0.04 + 0.01

[0296] The examples above show that the dispersion quality of uncoated pigments (here, untreated anatase titanium dioxide (CI: 77891)) in the solvents of the invention (compositions 9 and 10) is very good, with transmission values ​​remaining low. The dispersion quality of the pigments is excellent for isopropylindene glycerol, which is significantly better than all the other solvents tested at both 13 and 24 hours. The dispersion quality of the pigments with butyl lactate is comparable to that of ethanol, and significantly better than that obtained with ethyl lactate or isododecane.

[0297] The examples of compositions 4, 5, 9 and 10 comprising solvents as defined according to the Invention allow good quality of dispersion of pigments, whether they are surface treated or untreated. Homogeneity and coverage results

[0298] The following compositions were produced and characterized in terms of coverage and homogeneity.

[0299] [Tables3] INCI Name (Trade Name and Manufacturer) 11 (HI) 12 (Inv) 13 (Inv) TITANIUM DIOXIDE (and) DISODIUM STEAROYL GLUTAMATE (and) ALUMINUM HYDROXIDE (NAI-TAO-77891 from Miyoshi Kasei) 10 10 10 Ethyl Lactate (PURASOEVEE from PURAC) 90 - - Butyl Lactate - 90 - (PURASOEV BE from PURAC) Isopropylidene glycerol (AUGEO CRYSTAL from SOLVAY) - - 90 CR (%) 13.8 21.8 19.5 CR Standard Deviation 2.1 1.5 1.1 Homogeneity by eye Inhomogeneous Homogeneous Homogeneous

[0300] Examples 12 and 13 show that the coverage of the deposits with the solvents of the Invention is significantly better than that obtained for Ethyl Lactate.

[0301] Similarly, the homogeneity is better for the solvents of the invention. This can be seen qualitatively by sight, as well as quantitatively through the standard deviations of the CR, which are smaller for the solvents of the invention. Estimating the order of magnitude of Playtime

[0302] For each of the 90 / 10 untreated TITANIUM solvent / pigment mixtures, the result of the playtime estimation, as calculated according to the method described above, is shown in the following table.

[0303] [Tables4] INCI Name 14 (Not Inventory) 15 (Not Inventory) 16 (Inventory) 17 (Inventory) TITANIUM DIOXIDE (HO MBIT AN FF PHARMA de VENATOR) 10 10 10 10 Ethyl Lactate 90 - - - Ethanol - 90 - - Butyl Lactate - - 90 - Isopropylidene Glycerol - - - 90 Calculated Drying Time (70%, 2mg / cm²) (min) 3.6 3.2 16.6 33 Standard Deviation 0.2 0.4 1.1 4.1

[0304] Examples 16 and 17 show that the order of magnitude of the Playtime of dispersion of the pigments in the solvents of the Invention is significantly longer than that of dispersion with Ethanol or Ethyl Lactate, and is consistent with the time required for pleasant and high-quality makeup. Examples of anhydrous oily compositions

[0305] The following two compositions, 18 (outside the invention) and 19 (according to the invention), containing an oily phase, were produced.

[0306] [Tables5] INCI Name 18 (Not Inventory) 19 (Invention) ISODODECANE 47 47 UNDECANE (and) TRIDECANE (CETIOL ULTIMATE-® BASF) 20 20 DISTEARDIMONIUM HECTORITE (BENTONE 38 VCG RHEOLOGICAL AL ​​ADDITIVE® - ELEMENTIS) 3 3 TITANIUM DIOXIDE (and) DISO DIUM STEAROYL GLUTAMATE (and) ALUMINUM HYDROXIDE 10 10 ABSOLUTE ALCOHOL 20 - BUTYL LACTATE - 20 TOTAL (% Mass) 100 100 Mass evaporated at T5min, mg / cm2 7.65 + 0.68 2.88 + 0.09 Mass evaporated at T10min, mg / cm2 11.55 + 0.77 5.94 + 0.04 Mass evaporated at T20min, mg / cm2 17.94 + 0.88 11.81 + 0.07 Mass evaporated at T30min, mg / cm2 23.08 + 0.98 17.28 + 0.19 Operating procedure

[0307] [1] In a beaker, the volatile nonpolar hydrocarbon oils were mixed (undecane / tridecane and isododecane mixture) using a stator rotor for 5 minutes at 500 rpm.

[0308] [2] The hectorite was sprinkled on while agitating the stator rotor at 1200 rpm, then Leave under agitation for 15 minutes.

[0309] [3] The pigment was sprinkled on while agitating under a rotor-stator at 2000 rpm, then the left under agitation for 15 minutes.

[0310] [4] The temperature of the bulk was checked: If the temperature had increased, the to dig in a bath of cold water.

[0311] [5] Finally, the volatile polar solvent (ethanol or butyl lactate) was added at temperature ambient temperature (below 30°C) under rotor-stator agitation at 1000 rpm. It was left under agitation for another 5 minutes, then it was packaged.

[0312] Evaluation of the evaporation rate of compositions

[0313] Protocol:

[0314] The evaporation rate was measured gravimetrically in a ventilated glove box at controlled temperature and humidity (30°C, 50% relative humidity). A balance, connected to a computer, measured the mass of the sample at each instant. On the computer, the BalanceLink software recorded the data generated by the balance every 30 seconds. The evaporation kinetics correspond to the slope of the curve representing the mass lost over time for initial formula deposits of approximately 0.51 ± 0.02 g, or approximately 59 ± 2 mg / cm².

[0315] Results:

[0316] Example 19 of a composition with Butyl lactate shows that the evaporated mass is consistently lower compared to that of Example 18 with Ethanol, thus allowing more time for pleasant and high-quality makeup application. The playtime of composition 19 according to the invention is greater than that of composition 18 outside the scope of the invention.

[0317] Examples of compositions comprising an aqueous phase and an oily phase

[0318] The following two compositions 20 (outside the invention) and 21 (according to the invention) were prepared, containing an aqueous phase and an oily phase.

[0319] [Tableauxô] INCI Name 20 (Not in Invention) 21 (Invention) ISODODECANE 50 50 ABSOLUTE ALCOHOL 20 - BUTYL LACTATE - 20 WATER 20 20 TITANIUM DIOXIDE (and) DISODIUM STEAROYL GLUTAMATE (and) ALUMINUM HYDROXIDE 10 10 TOTAL (% Mass) 100 100 Visual Homogeneity at T0 Inhomogeneous (phase separation) Homogeneous Homogeneity after shaking at T24H: Inhomogeneous (hashing degradation) Homogeneous Operating procedure:

[0320] [1] In a beaker, mix the isododecane and the volatile polar solvent (ethanol or butyl lactate) using a stator rotor for 5 minutes at 500 rpm.

[0321] [2] Slowly add the water to the oil phase while stirring (approximately 2500 rpm / min), leave under agitation for 10-15 min.

[0322] [3] Slowly introduce the pigment (for 5 min) while stirring at 1500 rpm, Leave under agitation for 15 minutes, then package.

[0323] Results of visual observation of the homogeneity of compositions 20 and 21;

[0324] According to the observations noted in the preceding table, Example 21 of the composition with Butyl lactate forms a homogeneous mixture after manufacture and becomes homogeneous again after stirring at T24H. Example 20 of the composition with Ethanol is inhomogeneous immediately after manufacture and inhomogeneous after stirring at T24H under the same conditions.

Claims

Demands

1. Cosmetic composition, in particular makeup and / or skin and / or lip care, in particular skin, comprising, in a physiologically acceptable medium: a. at least one saturated organic compound, linear or branched, cyclic or non-cyclic, of general formula CnH2nO3 in which the index n is an integer such that 6 < n < 9 and said compound comprises at least one hydroxyl group and at least one function selected from ester or ether; and b. at least one pigment colouring material.

2. Composition according to claim 1, wherein the flash point of said compound a) is between 20°C and 120°C, preferably between 25°C and 115°C, preferably between 30°C and 110°C, preferably between 35°C and 107°C, preferably between 40°C and 105°C, or even between 45°C and 100°C.

3. Composition according to claim 1 or 2, wherein the vapor pressure of said compound a), at ambient temperature and atmospheric pressure, is in the range of 2.66 Pa to 40000 Pa, in particular from 2.66 Pa to 13000 Pa, particularly from 3 Pa to 2000 Pa, or even from 3 Pa to 1000 Pa, and more particularly from 4 Pa ​​to 500 Pa, preferably from 4 to 200 Pa, or even from 5 to 100 Pa, better from 5 to 50 Pa.

4. Composition according to any one of claims 1 to 3, wherein said compound a) is selected from those including a hydroxyl group and two ether functions, preferably comprising at least one cyclic ether function, preferably comprising a cyclic ether containing two ether functions, such as a dioxane ring or a dioxolane ring; preferably said compound a) comprises a hydroxyl group and a 1,3-dioxolane ring, and mixtures thereof.

5. Composition according to claim 4, wherein the index n of compound a) is an integer such that 6 < n < 8; preferably said compound a) is selected from 2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane (or isopropylideneglycerol), 4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane, (4S)-(+)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane, and mixtures thereof.

6. Composition according to any one of claims 1 to 3, wherein said compound a) is selected from the hydroxy carboxylic esters in in which the index n is an integer such that 7 < n < 9; preferably said compound a) is selected from Propyl Lactate, Butyl Glycolate, Butyl Lactate, Isobutyl Lactate, Methyl 3-hydroxyhexanoate, tert-Butyl 3-hydroxypropionate, Amyl Lactate, Isoamyl Lactate, Hexyl Lactate, and mixtures thereof.

7. Composition according to any one of the preceding claims, wherein compound a) is present in a content of 1% to 99% by weight, preferably 1% to 98% by weight, preferably 1% to 95% by weight, preferably 2% to 90%, preferably 2% to 80% by weight, preferably 3% to 70% by weight, preferably 4% to 60% by weight, preferably 4% to 50% by weight, preferably 5% to 40% by weight, preferably 6% to 30% by weight, preferably 7% to 25% by weight, or even 8% to 20%, by weight of compound a), on the total weight of the composition representing 100%.

8. Composition according to any one of the preceding claims, wherein the pigment colouring material is a mineral pigment selected from titanium dioxide, iron oxides, zirconium or cerium oxides, zinc or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue, metallic powders such as aluminium powder and copper powder, mother-of-pearl, monochromatic pigments; and mixtures thereof.

9. Composition according to any one of the preceding claims, wherein the pigment colouring material is an organic pigment selected from the compounds nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, quinophthalone; and mixtures thereof.

10. Composition according to claim 8 or 9, wherein the pigment colouring material is selected from mineral pigments, preferably from titanium dioxide, iron oxides, zirconium or cerium oxides, zinc or chromium oxides and mixtures thereof, preferably the pigment is selected from titanium dioxide, iron oxides and mixtures thereof.

11. Composition according to any one of the preceding claims, wherein the pigment(s) are uncoated and / or coated, of preferably coated with at least one compound chosen from: metallic soaps; N-acylated amino acids or their salts; lecithin and its derivatives; isopropyl trisostearyl titanate; isostearyl sebacate; waxes; fatty esters; phospholipids; and mixtures thereof.

12. Composition according to any one of the preceding claims, wherein the pigment colouring matter is present in a content of 0.5% to 70% by weight, preferably 1% to 60% by weight, preferably 2% to 50% by weight, preferably 3% to 45% by weight, relative to the weight of the composition, preferably 4% to 30% by weight, preferably 5% to 20% by weight, preferably 6% to 15% by weight, on the total weight of the composition representing 100%.

13. Composition according to any one of the preceding claims, characterized in that it further comprises at least one linear or C2-C4 branched monoalcohol, preferably in a content of less than or equal to 50% by weight, preferably less than or equal to 40% by weight, more particularly less than or equal to 30% by weight, advantageously less than or equal to 20% by weight, relative to the total weight of the composition; preferably the content of linear or C2-C4 branched monoalcohol(s) is less than or equal to 15% by weight, preferably less than or equal to 12% by weight, more particularly less than or equal to 10% by weight, advantageously less than or equal to 8% by weight, relative to the total weight of the composition;preferably, the content of linear or branched C2-C4 monoalcohol(s) is less than or equal to 5% by weight, preferably less than or equal to 4%, preferably less than or equal to 3%, preferably less than or equal to 2%, preferably less than or equal to 1%, by weight relative to the total weight of the composition.

14. Composition according to claim 13, wherein the content of linear or branched C2-C4 monoalcohol(s) is such that the weight ratio of the total amount of compound a) to the total amount of linear or branched C2-C4 monoalcohol(s) is greater than 1.

15. Composition according to any one of the preceding claims, characterized in that it further comprises at least one volatile oil and / or at least one non-volatile oil, preferably the weight ratio denoted R, of the sum of the masses of volatile oil(s) (VO) over the sum of the masses of non-volatile oil(s) (NVO), defined by: R = [Sum of VO masses] / [Sum of NVO masses], being such that 0 < R < 10,000, more particularly 0.01 < R < 1,000, more particularly 0.05 < R < 500, preferably 0.1 < R < 100, preferably 0.2 < R < 50, or even 0.5 < R < 10.

16. Composition according to any one of the preceding claims, characterized in that it comprises at least one additional volatile hydrocarbon oil other than compound a), preferably selected from volatile nonpolar hydrocarbon oils having 8 to 16 carbon atoms, preferably selected from: C8-C16 isoalkanes such as isododecane, isodecane, or isohexadecane; C6-C16 linear alkanes, in particular C11-C15, alone or in mixtures, such as hexane, decane, undecane, tridecane, n-dodecane (C12), n-tetradecane (C14), in particular the undecane-tridecane mixture, mixtures of n-undecane (C11) and n-tridecane (C14); plant-derived alkanes, particularly from coconut, or mixtures of C13-15 alkanes; and mixtures thereof.

17. Composition according to any one of the preceding claims, characterized in that it comprises less than 10% by weight of silicone oil, relative to the total weight of the composition, preferably less than 5% by weight, preferably less than 1% by weight, preferably less than 0.5% by weight, preferably less than 0.3% by weight, preferably less than 0.1% by weight of silicone oil, preferably silicone, preferably the composition is totally free of silicone.

18. Composition according to any one of the preceding claims, characterized in that it comprises an oily phase, with a content in the range of 5 to 100%, preferably 10 to 98% by weight, preferably 20 to 90% by weight, preferably 30 to 80% by weight, relative to the total weight of the composition.

19. Composition according to any one of the preceding claims, characterized in that it comprises an aqueous phase, with a content in the range of 2 to 95% by weight, preferably 5 to 90% by weight, preferably 10 to 80% by weight, more particularly 15 to 70% by weight, preferably 20 to 60% by weight, preferably 20 to 50% by weight relative to the total weight of said composition.

20. Composition according to any one of the preceding claims, characterized in that it is in the form of an anhydrous composition, a water-in-oil emulsion or an oil-in-water emulsion, or an aqueous composition.

21. Composition according to any one of the preceding claims, further comprising at least one additive selected from: active ingredients such as vitamins, anti-aging actives; UV filters other than compound b); fillers; lipophilic thickeners; surfactants; perfumes; preservatives; and mixtures thereof.

22. A method for making up and / or caring for the skin and / or hair, characterized in that it comprises at least the application to the skin and / or hair of a composition as defined according to any one of claims 1 to 21.