Uses and compositions
Nitrogen-containing compounds, derived from polycarboxylic acids and polyfunctional reactants, provide effective alternatives to silicone compounds by enhancing water repellency, reducing friction, and improving visual appearance while being more environmentally friendly.
Patent Information
- Authority / Receiving Office
- GB · GB
- Patent Type
- Applications
- Current Assignee / Owner
- INNOSPEC LTD
- Filing Date
- 2025-11-14
- Publication Date
- 2026-06-17
AI Technical Summary
Silicone compounds used for imparting water repellency, low-friction, and shine properties to surfaces have low biodegradability, leading to environmental concerns, and there is a need for alternatives that provide similar properties while being more biodegradable.
Using nitrogen-containing compounds, specifically the reaction product of polycarboxylic acids or their reactive equivalents and polyfunctional reactants with reactive amino groups, to treat surfaces, providing increased water repellency, reduced friction, and improved visual appearance.
The nitrogen-containing compounds offer comparable or improved water repellency, low-friction, and shine properties while being more biodegradable, addressing the environmental concerns associated with silicone compounds.
Abstract
Description
Various compounds and compositions are known to impart various properties to substrates, especially the surfaces of substrates, with which they are contacted. Some materials have surfaces (such as rough and / or water absorbent surfaces) that readily accumulate dust and / or dirt and are difficult to clean. This can cause problems such as reducing the cleanliness, robustness, and / or longevity of the material, as well as making the material aesthetically unappealing. It can be desirable to apply suitable compounds and compositions to such materials to provide benefits such as increased water repellency, reduced friction, and improved visual appearance (such as improved visual appearance). Silicone compounds, such as polydimethylsiloxane, functionalised polydimethylsiloxanes, organosilicones, and related compounds are widely used to impart water repelling, low-friction and shine properties to surfaces, including imparting lubrication and / or softening properties. However, there are a number of disadvantages associated with the use of such silicone compounds, including their low biodegradability, which has led to environmental concerns. It is thus an object of the invention to provide an alternative to silicone compounds that can be used in a wide range of applications to provide impart water repelling, low-friction and shine properties to surfaces, including imparting lubrication and / or softening properties. It is another object of the invention to provide alternatives to silicone compounds that are more biodegradable whilst having equal or improved water repelling, low-friction and shine properties to surfaces, including imparting lubrication and / or softening properties. Summary of the Invention According to aspects of the present invention, there is provided a use, method, composition and substrate as set forth in the appended claims. Other features of the invention will be apparent from the dependent claims, and from the description which follows. The inventors have identified that certain nitrogen containing compounds can provide at least one of increased water repellency, reduced friction, and improved visual appearance to surfaces, which is at least comparable to that provided by known silicone compounds, whilst also being more biodegradable. According to a first aspect of the invention, there is provided a use of a nitrogen containing compound to treat a surface, wherein the surface is not a surface of a home care substrate and wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance; and wherein the nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group. According to a second aspect of the invention, there is provided a method of treating a surface, wherein the surface is not a surface of a home care substrate and wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance, the method comprising contacting the surface with a nitrogen containing compound, wherein the nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group. According to a third aspect of the invention, there is provided a composition for treating a surface that is not a surface of a home care substrate, wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance, and wherein the composition comprises one or more nitrogen containing compounds, wherein the or each nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group. According to a fourth aspect of the invention, there is provided a substrate that is not a home care substrate, wherein a surface of the substrate is treated with a nitrogen containing compound, wherein the nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group. Other features of the invention will be apparent from the dependent claims, and from the description which follows. Features described in relation to the third and fourth aspects may have any of the suitable features and advantages described in relation to the first and second aspects. Detailed Description of the Invention Unless otherwise stated, the following terms used in the specification and claims have the meanings set out below. The terms “alkyl” and “alkylene” include both straight and branched chain alkyl and alkylene groups respectively unless otherwise stated. References to individual alkyl groups such as “propyl” are specific for the straight chain version only and references to individual branched chain alkyl groups such as “isopropyl” are specific for the branched chain version only. For example, “C3-30 alkyl” includes C6-24 alkyl, Ce-s alkyl, propyl, isopropyl and t-butyl. The term “alkenyl” includes both straight and branched chain alkenyl groups. References to individual alkenyl groups such as “propenyl” are specific for the straight chain version only and references to individual branched chain alkenyl groups such as “isopropenyl” are specific for the branched chain version only. For example, “C3-30 alkenyl” includes C6-24 alkenyl, Ce-s alkenyl, propenyl and isopropenyl. Herein C3-30 means a group having from 3 to 30 carbons atoms therein, for example having 3, 4, 5 etc up to 30 carbon atoms. The term "hydrocarbyl" is used in its ordinary sense, which is well-known to those skilled in the art. Specifically, it refers to a group having a carbon atom directly attached to the remainder of the molecule and having predominantly hydrocarbon character. As used in the specification and the appended claims, the singular forms "a", "an," and "the" include both singular and plural referents unless the context clearly dictates otherwise. Throughout this specification, the term “comprising” or “comprises” means including the component(s) specified but not to the exclusion of the presence of other components. The term “consisting essentially of’ or “consists essentially of’ means including the components specified but excluding other components except for components added for a purpose other than achieving the technical effect of the invention. The term “consisting of’ or “consists of’ means including the components specified but excluding other components. Whenever appropriate, depending upon the context, the use of the term “comprises” or “comprising” may also be taken to include the meaning “consists essentially of’ or “consisting essentially of’, and also may also be taken to include the meaning “consists of’ or “consisting of’. As used herein, unless otherwise expressly specified, all numbers such as those expressing values, ranges, amounts of percentages may be read as if prefaced by the word “about”, even if the term does not expressly appear. The recitation of numerical ranges by endpoints includes all integer numbers and, where appropriate, fractions subsumed within that range (e.g. 1 to 5 can include 1,2,3,4 when referring to, for example, a number of elements, and can also include 1.5,2,2.70 and 3.80, when referring to, for example, measurements). The recitation of end points also includes the end point values themselves (e.g. from 1.0 to 5.0 includes both 1.0 and 5.0). Any numerical range recited herein is intended to include all sub-ranges subsumed therein. The optional features set out herein may be used either individually or in combination with each other where appropriate and particularly in the combinations as set out in the accompanying claims. The optional features for each exemplary aspect of the invention, as set out herein are also applicable to any other aspects or exemplary aspects of the invention, where appropriate. In other words, the skilled person reading this specification should consider the optional features for each aspect or embodiment of the invention as interchangeable and combinable between different aspects of the invention. As used herein, the term "and / or," when used in a list of two or more items, means that any one of the listed items can be employed by itself or any combination of two or more of the listed items can be employed. For example, if a list is described as comprising group A, B, and / or C, the list can comprise A alone; B alone; C alone; A and B in combination; A and C in combination, B and C in combination; or A, B, and C in combination. The term “monomer” is used herein to refer to a compound comprising at least one polymerisable functional group. As reported herein, the number average molecular weight was determined by gel permeation chromatography using a polystyrene standard according to ASTM D6579-11 (“Standard Practice for Molecular Weight Averages and Molecular Weight Distribution of Hydrocarbon, Rosin and Terpene Resins by Size Exclusion Chromatography”. UV detector; 254 nm, solvent: unstabilised THF, retention time marker: toluene, sample concentration: 2mg / ml). According to a first aspect of the invention, there is provided a use of a nitrogen containing compound to treat a surface, wherein the surface is not a surface of a home care substrate and wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance; and wherein the nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group. According to a second aspect of the invention, there is provided a method of treating a surface, wherein the surface is not a surface of a home care substrate and wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance, the method comprising contacting the surface with a nitrogen containing compound, wherein the nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group. Suitable features of the first and second aspects will now be described. The nitrogen containing compound may be a polymer, a non-polymer, or a mixture of polymers and non-polymers. The nitrogen containing compound is preferably a polymer. The reactants are preferably monomers. The one or more first reactants are preferably one or more first monomers, the one or more second reactants are preferably one or more second monomers, and the polyfunctional reactant is preferably a polyfunctional monomer having at least one reactive amino group. According to the first aspect of the invention, there may be provided a use of a polymer to treat a surface, wherein the surface is not a surface of a home care substrate and wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance; and wherein the polymer is the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is a polycarboxylic acid or a reactive equivalent thereof and the or each second monomer is a polyfunctional monomer having at least one reactive amino group. According to the second aspect of the invention, there may be provided a method of treating a surface, wherein the surface is not a surface of a home care substrate and wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance, the method comprising contacting the surface with a polymer, wherein the polymer is the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is a polycarboxylic acid or a reactive equivalent thereof and the or each second monomer is a polyfunctional monomer having at least one reactive amino group. The embodiments described herein relating to ‘polymers’ may equally be applied to nitrogen containing compounds as defined herein, and the embodiments described herein relating to ‘monomers’ may equally be applied to reactants as defined herein. However, polymers and monomers are preferred. The polymer as preferably used herein is the reaction product of monomers comprising one or more first monomers and one or more second monomers as defined herein. In other words, the polymer may be obtainable or obtained by polymerising monomers comprising one or more first monomers and one or more second monomers as defined herein. Thus, the reaction product is a polymer comprising repeat units derived from the one or more first monomers and repeat units derived from the one or more second monomers as defined herein. The polymer as preferably used herein may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers as defined herein. In other words, the polymer may be obtainable or obtained by polymerising monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers as defined herein. Thus, the reaction product may be a polymer consisting essentially of or consisting of repeat units derived from the one or more first monomers and the one or more second monomers as defined herein. Typically, the polymer that is the reaction product of the monomers defined herein is a polyamide. The first and second monomers may be reacted in any suitable molar ratio to make the polymer, as would be appreciated by a person skilled in the art. Thus repeat units in the polymer derived from the first and second monomers may be present in the polymer in any suitable molar ratio and in any suitable arrangement. The first and second monomers may be reacted in a molar ratio of from 1:10 to 10:1, preferably from 1:6 to 6:1, for example from 1:3 to 3:1. Ratios refer to the total amounts of first monomers or second monomers if more than one first monomer or second monomer is present. The first and second monomers may be reacted in a molar ratio of from 1:1.5 to 1.5:1, suitably a molar ratio of from 1.2:1 to 1:1.2, such as a molar ratio of 1:1. The polymer may be prepared by any suitable method, as would be known to persons skilled in the art. Suitably, the polymer is not in a solid form. For example, the polymer is preferably in the form of a liquid or gel, preferably a liquid. Suitably, the polymer herein that is the reaction product of monomers comprising one or more first monomers and one or more second monomers is substantially free or free of cross-linking. References herein to a reaction product of monomers comprising the first and second monomers are intended to refer to a product of the reaction of monomers comprising the first and second monomers conducted in any suitable manner. For example, the reaction may occur between the first and second monomers in the absence of other monomer(s) or may occur in the presence of other monomer(s). The or each of the one or more first monomers used to make the polymer is a polycarboxylic acid or a reactive equivalent thereof. By the term “reactive equivalent”, we mean a compound that results in the same reaction product as the corresponding polycarboxylic acid. Suitable reactive equivalents include anhydrides (preferably cyclic anhydrides), acid chlorides and esters of polycarboxylic acids (preferably of the polycarboxylic acids described herein). Mixtures of two or more different first monomers (i.e. different polycarboxylic acids or reactive equivalents thereof, such as different polycarboxylic acids, different anhydrides, acid chlorides, or esters thereof, or for example a cyclic anhydride and a polycarboxylic acid or an acid chloride or ester thereof thereof) may be used to make the polymer. Any suitable polycarboxylic acid and / or reactive equivalent thereof may be used to make the polymer, as would be understood by the person skilled in the art. The or each of the one or more first monomers may comprise one or more cyclic anhydrides. The or each of the one or more first monomers may consist essentially of or consist of one or more cyclic anhydrides. By the term cyclic anhydride we mean a compound (or monomer) that comprises at least one anhydride group that is contained within a ring structure. For example, the ring structure that contains the anhydride group may comprise from 4 to 8 atoms, which atoms are typically carbon and oxygen. The ring structure that contains the anhydride group may be saturated or partially unsaturated. The cyclic anhydride compound may typically comprise more than 8 atoms. For example, suitable cyclic anhydrides may include one or more of an anhydride of formula (I), of formula (II) and of formula (III): wherein in formula (I) R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group, or R1 and R2 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group; in formula (II) R3 and R4 are each independently selected from hydrogen, an alkyl group and an alkenyl group, or R3 and R4 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group; and in formula (III) X is CR9R10, O, S, or NR11; R5, R6, R7, R8, R9, R10, and R11 are each independently selected from hydrogen, an alkyl group and an alkenyl group, and / or any of R5, R6, R7, R8, R9, R10, and R11 together with the atoms to which they are attached represent an optionally substituted cyclic group. X may suitably be CR9R10, O, or S. Preferably, X is CR9R10. When any of R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and R11 represents an alkyl group or an alkenyl group, the or each alkyl or alkenyl group may be branched or unbranched. The or each alkyl group may contain from 1 to 30 carbon atoms and the or each alkenyl group may contain from 2 to 30 carbon atoms. Preferably, each alkyl or alkenyl group may contain 6 or more carbon atoms. For example, the or each alkyl or alkenyl group may contain from 6 to 30, such as from 8 to 24, carbon atoms (i.e. may be a Ce-30, such as a Cs-24, alkyl or alkenyl group). When any of R1 and R2, or R3 and R4, orR5, R6, R7, R8, R9, and R10 represents an alkenyl group, the alkenyl group may be a branched alkenyl group, such as a tetrapropenyl group or a polyisobutenyl group. When any of R1 and R2, or R3 and R4, orR5, R6, R7, R8, R9, and R10 represents an alkenyl group, the alkenyl group may be a polyisobutenyl group. The polyisobutenyl group (when present) suitably has a number average molecular weight of from 100 to 2000, preferably from 100 to 1000, for example 260 or 550. The cyclic anhydride may be a polyisobutenyl succinic anhydride, for example wherein the polyisobutenyl group has a number average molecular weight of 260 or 550. When any of R1 and R2, or R3 and R4, orR5, R6, R7, R8, R9, and R10 represents an alkenyl group, the alkenyl group may be derived from a terminal olefin or an internal olefin. For example, the cyclic anhydride monomer may be an alkenyl substituted succinic anhydride prepared by the reaction of an alkene with maleic anhydride, wherein the alkene is a terminal olefin or an internal olefin. In some embodiments the alkenyl group may be derived from a terminal olefin. The term terminal olefin is used to refer to alkene compounds having a predominantly terminal double bond. Such compounds are also commonly described as terminal alkenes. Terminal double bonds terminate in a =CH2 group and may either be at the a-position or may be vinylidene groups. The terminal olefin is preferably an a-olefin. Examples of suitable terminal olefins include C15-18 terminal olefin and Cie terminal olefin. In some preferred embodiments the alkenyl group is derived from an internal olefin. The term internal olefin is used to refer to alkene compounds in which the alkene groups are predominantly not terminal. Examples of suitable internal olefins include C12 internal olefin, C15-18 internal olefin, C16 internal olefin and C18 internal olefin. The internal olefin is a p or higher olefin, such as a p-olefin. Internal olefins are sometimes known as isomerised olefins and may be prepared by isomerisation of an a-olefin. Typically, terminal olefins and internal olefins may be provided as a mixture of isomers. Suitably at least 70 mol%, such as at least 80 mol%, preferably at least 90 mol%, for example at least 95 mol% of the double bonds in terminal olefins are terminal double bonds. Suitably at least 70 mol%, such as at least 80 mol%, preferably at least 90 mol%, for example at least 95 mol% of the terminal double bonds in the terminal olefins are at the a-position (i.e. they are a-alkene groups). Suitably at least 70 mol%, such as at least 80 mol%, preferably at least 90 mol%, for example at least 95 mol% of the double bonds in internal olefins are non-terminal double bonds. Suitably, one of R1 and R2, R3 and R4, orR5, R6, R7, R8, R9, R10, and R11 may be an alkyl group or an alkenyl group (such as an alkenyl group derived from a terminal olefin or an internal olefin, preferably an internal olefin) and the other (or others) may be hydrogen. Examples of cyclic anhydride monomers of the formula (I), (II) or (III) wherein any of R1 and R2, R3 and R4, orR5, R6, R7, R8, R9, R10, and R11 represents hydrogen or a Ce-30, such as a Cs-24, branched or unbranched alkyl or alkenyl group include succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), tetrapropenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, nonenyl succinic anhydride, C20-24 alkenyl succinic anhydride, C15-18 internal olefin-derived alkenyl succinic anhydride, C16 internal olefin-derived alkenyl succinic anhydride, C16 terminal olefin-derived alkenyl succinic anhydride, maleic anhydride and glutaric anhydride. The cyclic anhydride monomers of the formula (I), (II) or (III) wherein any of R1 and R2, R3 and R4, orR5, R6, R7, R8, R9, R10, and R11 represents hydrogen or a C6-30, such as a Cs-24, branched or unbranched alkyl or alkenyl group may be selected from succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), tetrapropenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, nonenyl succinic anhydride, C20-24 alkenyl succinic anhydride, maleic anhydride and glutaric anhydride. The cyclic anhydride monomers are preferably selected from C15-18 internal olefin-derived alkenyl succinic anhydride, C16 internal olefin-derived alkenyl succinic anhydride, and C16 terminal olefin-derived alkenyl succinic anhydride. When any of R1 and R2, or R3 and R4, orR5, R6, R7, R8, R9, R10, and R11, together with the atoms to which they are attached represent an optionally substituted cyclic group, the cyclic group so formed may be mono or polycyclic (preferably mono or bicyclic) and may be aromatic or nonaromatic. Examples of aromatic groups that may be so formed include benzene and naphthalene. Examples of non-aromatic groups that may be so formed include cyclopentane, cyclohexane, and cyclooctane. Any of R5, R6, R7, R8, R9, R10, and R11 together with the atoms to which they are attached may represent an optionally substituted cyclic group. Any of R5, R6, R7, R8, R9, R10, and R11 not representing a cyclic group are independently selected from hydrogen, an alkyl group and an alkenyl group as described herein. Two, three, four, five, or six of R5, R6, R7, R8, R9, R10, and R11 together with the atoms to which they are attached may represent an optionally substituted cyclic group. Suitably at least R5 and R7, or R5 and R9, or R5 and R11, or R7 and R9, or R7 and R11, or R5, R7 and R9, or R5, R7 and R11 together with the atoms to which they are attached may represent an optionally substituted cyclic group. For the avoidance of doubt, when any of R5, R6, R7, R8, R9, and R10 together with the atoms to which they are attached represent an optionally substituted cyclic group, one or more of R5, R6, R7, R8, R9, and R10 may contribute to one or more double bonds (for example, aromaticity) in the cyclic group. For example, R8 and R10 may together form a carbon-carbon double bond, which may form part of an aromatic cyclic group. The optionally substituted cyclic group represented by R1 and R2, or R3 and R4, or any of R5, R6, R7, R8, R9, R10, and R11, together with the atoms to which they are attached (when present) may be optionally substituted with any suitable substituent(s), such as for example one or more substituents independently selected from alkyl (for example C1-30, preferably C1-24, such as C1-4 or Ca-24, alkyl), alkenyl (for example C2-30, preferably C2-24, such as C2-4 or Ca-24, alkenyl), alkoxy (for example C1-30, preferably C1-24, such as C1-4 or Ca-24, alkoxy), alkenyloxy (for example C2-30, preferably C2-24, such as C2-4 or Ca-24, alkenyloxy), carboxy, alkoxy-carbonyl (for example C1-30, preferably C1-24, such as C1-4 or Ca-24, alkoxy-carbonyl), alkenyloxy-carbonyl (for example C2-30, preferably C2-24, such as C2-4 or Ca-24, alkenyloxy-carbonyl), hydroxy, halo (for example chloro or fluoro), nitro and cyano groups. The optionally substituted cyclic group represented by R1 and R2, or R3 and R4, or any of R5, R6, R7, R8, R9, R10, and R11, together with the atoms to which they are attached (when present) may alternatively be substituted by groups which form a further cyclic anhydride group. An example of such a cyclic anhydride is pyromellitic dianhydride. However, in some embodiments the cyclic anhydride monomers of the formula (I), (II) or (III) contain a single (i.e. only one) anhydride group. In such embodiments, the optionally substituted cyclic group represented by R1 and R2, or R3 and R4, or any of R5, R6, R7, R8, R9, R10, and R11, together with the atoms to which they are attached (when present) may not be substituted by a further cyclic anhydride group. Examples of suitable cyclic anhydrides of formula (I) in which R1 and R2 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group include optionally substituted 1,2-cyclohexanedicarboxylic anhydride and 1,3-cyclopentanedicarboxylic anhydride. 1,2-Cyclohexanedicarboxylic anhydride is preferred. Examples of suitable anhydrides of formula (II) in which R3 and R4 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group include optionally substituted phthalic anhydride, pyromellitic dianhydride, 1,2-naphthalic anhydride and 2,3-naphthalic anhydride. Examples of a substituted phthalic anhydride may include 1,2,4-benzenetricarboxylic anhydride, and 6-((octadec-9-en-1-yloxy)carbonyl)-1,3-dioxo-1,3-dihydroisobenzofuran-5-carboxylic acid. Examples of suitable anhydrides of formula (III) in which any of R5, R6, R7, R8, R9, R10, and R11 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group include optionally substituted 1,8-naphthalic anhydride and homophthalic anhydride. Preferred cyclic anhydrides include one or more cyclic anhydrides of formula (I) wherein R1 and R2 are each independently selected from hydrogen and a Cs-3o, such as a Cs-24, alkyl or alkenyl group, or wherein R1 and R2 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group; or of formula (II) wherein R3 and R4 are each independently selected from hydrogen and a Cs-3o, such as a Cs-24, alkyl or alkenyl group, or wherein R3 and R4 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group; or of formula (III) wherein X is CR9R10, O, or S and R5, R6, R7, R8, R9, and R10 are each independently selected from hydrogen and a Cs-3o, such as a Cs-24, an alkyl group or alkenyl group, and / or wherein any of R5, R6, R7, R8, R9, and R10 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group. More preferred cyclic anhydrides include one or more cyclic anhydrides of formula (I) wherein R1 and R2 are each independently selected from hydrogen and a Cs-3o, such as a Cs-24, alkenyl group, or wherein R1 and R2 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group; or of formula (II) wherein R3 and R4 are both hydrogen, or wherein R3 and R4 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group; or of formula (III) wherein X is CR9R10, O, or S and R5, R6, R7, R8, R9, and R10 are each hydrogen, and / or wherein any of R5, R6, R7, R8, R9, and R10 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group. Preferably, at least one of the first monomers is a cyclic anhydride of formula (I), (II) or (III) wherein at least one of R1 and R2, or at least one of R3 and R4, or at least one of R5, R6, R7, R8, R9, R10, and R11, is a Cs-3o, such as a Cs-24, alkyl or alkenyl (more preferably alkenyl) group (such as an alkenyl group derived from a terminal olefin or an internal olefin, preferably an internal olefin). Preferably, at least one of the first monomers is a cyclic anhydride of formula (I), (II) or (III) wherein at least one of R1 and R2, or at least one of R3 and R4, or at least one of R5, R6, R7, R8, R9, R10, and R11, is a Ce-30, such as a Cs-24, alkyl or alkenyl (more preferably alkenyl) group (such as an alkenyl group derived from a terminal olefin or an internal olefin, preferably an internal olefin) and the other (or others) is (or are) hydrogen. For example, the cyclic anhydride may be an anhydride of formula (I) wherein R1 and R2 are both hydrogen (i.e. the cyclic anhydride may be succinic anhydride). For example, the cyclic anhydride may be an anhydride of formula (II) wherein R3 and R4 are both hydrogen (i.e. the cyclic anhydride may be maleic anhydride). For example, the cyclic anhydride may be an anhydride of formula (III) in which X is CR9R10 and R5, R6, R7, R8, R9, and R10 each represent hydrogen (i.e. the cyclic anhydride may be glutaric anhydride). For example, the cyclic anhydride may be an anhydride of formula (III) in which X is O and R5, R6, R7, and R8 each represent hydrogen (i.e. the cyclic anhydride may be diglycolic anhydride). For example, the cyclic anhydride may be an anhydride of formula (III) in which X is S and R5, R6, R7, and R8 each represent hydrogen (i.e. the cyclic anhydride may be thiodiglycolic anhydride). For example, the or each cyclic anhydride may be an anhydride of formula (I) wherein R1 and R2 are both hydrogen or wherein one of R1 and R2 is an alkyl or alkenyl group (such as an alkenyl group derived from a terminal olefin or an internal olefin, preferably an internal olefin) and the other of R1 and R2 is hydrogen. For example, the or each cyclic anhydride may be an anhydride of formula (I) wherein R1 and R2 are both hydrogen or wherein one of R1 and R2 is a Ce-3o, such as a Cs-24, alkyl or alkenyl (more preferably alkenyl) group (such as an alkenyl group derived from a terminal olefin or an internal olefin, preferably an internal olefin) and the other of R1 and R2 is hydrogen. Examples of such cyclic anhydride compounds include succinic anhydride, C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, C15-18 internal olefin-derived alkenyl succinic anhydride, C16 internal olefin-derived alkenyl succinic anhydride, and C16 terminal olefin-derived alkenyl succinic anhydride. The cyclic anhydride compound may be selected from succinic anhydride, C2o-24alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride and octenyl succinic anhydride. The cyclic anhydride compound is preferably selected from C15-18 internal olefin-derived alkenyl succinic anhydride, C16 internal olefin-derived alkenyl succinic anhydride, and C16 terminal olefin-derived alkenyl succinic anhydride. Preferably, the or each cyclic anhydride may be an anhydride of formula (I) wherein one of R1 and R2 is an alkenyl group, such as a Ce-30 (preferably Cs-24) alkenyl group (such as a Ce-30 (preferably Cs-24) alkenyl group derived from a terminal olefin or an internal olefin, preferably an internal olefin), and the other of R1 and R2 is hydrogen. Examples of such cyclic anhydride compounds include C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, C15-18 internal olefin-derived alkenyl succinic anhydride, C16 internal olefin-derived alkenyl succinic anhydride, and C16 terminal olefin-derived alkenyl succinic anhydride. The cyclic anhydride compound may be selected from C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride and octenyl succinic anhydride. The cyclic anhydride compound is preferably selected from C15-18 internal olefin-derived alkenyl succinic anhydride, C16 internal olefin-derived alkenyl succinic anhydride, and C16 terminal olefin-derived alkenyl succinic anhydride. Preferably, the or each cyclic anhydride may be dodecenyl succinic anhydride, such as (2-dodecen-1-yl)succinic anhydride. The or each cyclic anhydride may be an anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other of R1 and R2 is a polyisobutenyl group, for example wherein the polyisobutenyl group suitably has a number average molecular weight of from 100 to 2000, preferably from 100 to 1000, for example 260 or 550. Preferably, the or each cyclic anhydride may be a cyclic anhydride of formula (I) or (II) wherein R1 and R2, or R3 and R4, together with the carbon atoms to which they are attached represent an optionally substituted cyclic group, wherein the cyclic group is an aromatic or a non-aromatic group and is mono or polycyclic. Preferably, the or each cyclic anhydride may be an anhydride of formula (I) wherein R1 and R2 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group, wherein the cyclic group is a non-aromatic (for example saturated) mono or bicyclic group. More preferably, the or each cyclic anhydride may be a cyclic anhydride of formula (I) wherein R1 and R2 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group, wherein the cyclic group is a non-aromatic (for example saturated) monocyclic group, such as a cyclohexane group. Preferably, the or each cyclic anhydride may be an anhydride of formula (II) wherein R3 and R4 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group, wherein the cyclic group is an aromatic mono or bicyclic group, such as a benzene or naphthalene group. More preferably, the or each cyclic anhydride may be a cyclic anhydride of formula (II) wherein R3 and R4 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group, wherein the cyclic group is an aromatic monocyclic group, such as a benzene group. Preferably, the or each cyclic anhydride may be an anhydride of formula (III) wherein X is CR9R10 and R5, R6, R7, R8, R9, and R10 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group, wherein the cyclic group is an aromatic bicyclic group, such as a naphthalene group; or R7 and R8 are hydrogen and R5, R6, R9 and R10 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group, wherein the cyclic group is an aromatic monocyclic group, such as a benzene group. More preferably, the or each cyclic anhydride may be an anhydride of formula (III) wherein X is CR9R10 and R5, R6, R7, R8, R9, and R10 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group, wherein the cyclic group is an aromatic bicyclic group, such as a naphthalene group. When the cyclic anhydride is an anhydride of formula (I) wherein R1 and R2 together with the carbon atoms to which they are attached represent an optionally substituted cyclohexane group, the cyclic anhydride may be of the formula (IA): wherein n1 is an integer from 0 to 4 and each R12 (when present) is independently selected from alkyl (for example C1-30, preferably C1-24, such as C1-4, alkyl), alkenyl (for example C2-30, preferably C2-24, such as C2-4, alkenyl), alkoxy (for example C1-30, preferably C1-24, such as C1-4, alkoxy), alkenyloxy (for example C2-30, preferably C2-24, such as C2-4, alkenyloxy), carboxy, alkoxy-carbonyl (for example C1-30, preferably C1-24, such as C1-4, alkoxy-carbonyl), alkenyloxycarbonyl (for example C2-30, preferably C2-24, such as C2-4, alkenyloxy-carbonyl), hydroxy, halo (for example chloro or fluoro), nitro and cyano groups, or when n1 is 2 the two R12 groups may represent a further cyclic anhydride group (such as a further succinic anhydride group). Examples of suitable succinic anhydrides of formula (IA) include 1,2-cyclohexanedicarboxylic anhydride. When the cyclic anhydride is an anhydride of formula (II) wherein R3 and R4 together with the carbon atoms to which they are attached represent an optionally substituted benzene group, the cyclic anhydride may be of the formula (HA): wherein n2 is an integer from 0 to 4 and each R13 (when present) is independently selected from alkyl (for example C1-30, preferably C1-24, such as C1-4, alkyl), alkenyl (for example C2-30, preferably C2-24, such as C2-4, alkenyl), alkoxy (for example C1-30, preferably C1-24, such as C1-4, alkoxy), alkenyloxy (for example C2-30, preferably C2-24, such as C2-4, alkenyloxy), carboxy, alkoxy-carbonyl (for example C1-30, preferably C1-24, such as C1-4, alkoxy-carbonyl), alkenyloxycarbonyl (for example C2-30, preferably C2-24, such as C2-4, alkenyloxy-carbonyl), hydroxy, halo (for example chloro or fluoro), nitro and cyano groups, or when n2 is 2 the two R13 groups may represent a further cyclic anhydride group (such as a further succinic anhydride group). In some embodiments, the cyclic anhydride of formula (HA) contains a single (i.e. only one) anhydride group. In such embodiments, two R13 groups may not represent a further cyclic anhydride group. When R13 represents a alkoxy-carbonyl (for example C1-30, preferably Ca-24, alkoxy-carbonyl) or alkenyloxy-carbonyl (for example C2-30, preferably Ca-24, alkenyloxy-carbonyl), substituent, the alkoxy-carbonyl or alkenyloxy-carbonyl group may be of the formula -C(O)OR13 wherein R13 is a C1-30, preferably Ca-24, alkyl group or a C2-30, preferably Ca-24, alkenyl group. Suitably R13 may represent an oleyl group. Examples of suitable succinic anhydrides of formula (IIA) include phthalic anhydride, pyromellitic dianhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-naphthalic anhydride and 2,3-naphthalic anhydride, and 6-((octadec-9-en-1-yloxy)carbonyl)-1,3-dioxo-1,3-dihydroisobenzofuran-5-carboxylic acid. When the cyclic anhydride is an anhydride of formula (III) wherein X is CR9R10 and R5, R6, R7, R8, R9, and R10 together with the carbon atoms to which they are attached represent an optionally substituted naphthalene group, the cyclic anhydride may be of the formula (IIIA): wherein each of n3 and n4 is independently an integer from 0 to 3 and each of R14 and R15 (when present) is independently selected from alkyl (for example C1-30, preferably C1-24, such as C1-4, alkyl), alkenyl (for example C2-30, preferably C2-24, such as C2-4, alkenyl), alkoxy (for example Ci-30, preferably C1-24, such as C1-4, alkoxy), alkenyloxy (for example C2-30, preferably C2-24, such as C2-4, alkenyloxy), carboxy, alkoxy-carbonyl (for example C1-30, preferably C1-24, such as C1-4, alkoxy-carbonyl), alkenyloxy-carbonyl (for example C2-30, preferably C2-24, such as C2-4, alkenyloxy-carbonyl), hydroxy, halo (for example chloro or fluoro), nitro and cyano groups. Examples of suitable succinic anhydrides of formula (IHA) include 1,8-naphthalic anhydride. When the cyclic anhydride is an anhydride of formula (III) wherein X is CR9R10, R7 and R8 are hydrogen and R5, R6, R9 and R10 together with the carbon atoms to which they are attached represent an optionally substituted benzene group, the cyclic anhydride may be of the formula (IIIB): wherein n5 is an integer from 0 to 4 and each R16 (when present) is independently selected from alkyl (for example C1-30, preferably C1-24, such as C1-4, alkyl), alkenyl (for example C2-30, preferably C2-24, such as C2-4, alkenyl), alkoxy (for example C1-30, preferably C1-24, such as C1-4, alkoxy), alkenyloxy (for example C2-30, preferably C2-24, such as C2-4, alkenyloxy), carboxy, alkoxy-carbonyl (for example C1-30, preferably C1-24, such as C1-4, alkoxy-carbonyl), alkenyloxycarbonyl (for example C2-30, preferably C2-24, such as C2-4, alkenyloxy-carbonyl), hydroxy, halo (for example chloro or fluoro), nitro and cyano groups. Examples of suitable succinic anhydrides of formula (IIIB) include homophthalic anhydride. Suitably, the or each cyclic anhydride may be selected from one or more of succinic anhydride, maleic anhydride, glutaric anhydride, a Ce-30 alkenyl succinic anhydride such as C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, octadecyl succinic anhydride, octyl succinic anhydride, C15-18 internal olefin-derived alkenyl succinic anhydride, C16 internal olefin-derived alkenyl succinic anhydride, or C16 terminal olefinderived alkenyl succinic anhydride a branched alkenyl succinic anhydride such as tetrapropenyl succinic anhydride or polyisobutenyl succinic anhydride, phthalic anhydride, pyromellitic dianhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride, 1,2-naphthalic anhydride, 2,3-naphthalic anhydride, 1,8-naphthalic anhydride and homophthalic anhydride. Suitably, the or each cyclic anhydride may be selected from one or more of succinic anhydride, maleic anhydride, glutaric anhydride, a C6-30 alkenyl succinic anhydride such as C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, octadecyl succinic anhydride, or octyl succinic anhydride, a branched alkenyl succinic anhydride such as tetrapropenyl succinic anhydride or polyisobutenyl succinic anhydride, phthalic anhydride, pyromellitic dianhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride, 1,2-naphthalic anhydride, 2,3-naphthalic anhydride, 1,8-naphthalic anhydride and homophthalic anhydride. Suitably, the or each cyclic anhydride may be selected from one or more of succinic anhydride, maleic anhydride, glutaric anhydride, a C6-30 alkenyl succinic anhydride such as C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, octadecyl succinic anhydride, or octyl succinic anhydride, and a branched alkenyl succinic anhydride such as tetrapropenyl succinic anhydride or polyisobutenyl succinic anhydride. Suitably, the or each cyclic anhydride may be selected from one or more of succinic anhydride, maleic anhydride, glutaric anhydride, and a C6-30 alkenyl succinic anhydride such as C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, octadecyl succinic anhydride, or octyl succinic anhydride. Suitably, the or each cyclic anhydride may be selected from one or more of phthalic anhydride, pyromellitic dianhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride, 1,2-naphthalic anhydride, 2,3-naphthalic anhydride, 1,8-naphthalic anhydride and homophthalic anhydride. Suitably, the or each cyclic anhydride may be selected from one or more of phthalic anhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride, 1,2-naphthalic anhydride, 2,3-naphthalic anhydride, 1,8-naphthalic anhydride and homophthalic anhydride. More suitably, the or each cyclic anhydride may be selected from one or more of succinic anhydride, maleic anhydride, C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, phthalic anhydride, pyromellitic dianhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride, 1,2-naphthalic anhydride, 2,3-naphthalic anhydride, 1,8-naphthalic anhydride, homophthalic anhydride and glutaric anhydride. More suitably, the or each cyclic anhydride may be selected from one or more of succinic anhydride, maleic anhydride, C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, and glutaric anhydride. Preferably, the or each cyclic anhydride may be selected from one or more of succinic anhydride, maleic anhydride, C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, phthalic anhydride, pyromellitic dianhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride and 1,8-naphthalic anhydride. Preferably, the or each cyclic anhydride may be selected from one or more of succinic anhydride, maleic anhydride, C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, and octenyl succinic anhydride. Preferably, the or each cyclic anhydride may be selected from one or more of phthalic anhydride, pyromellitic dianhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride and 1,8-naphthalic anhydride. Preferably, the or each cyclic anhydride may be selected from one or more of C15-18 internal olefin-derived alkenyl succinic anhydride, C16 internal olefin-derived alkenyl succinic anhydride, and C16 terminal olefin-derived alkenyl succinic anhydride. The cyclic anhydride compounds discussed herein may be commercially available or may be prepared using procedures well known in the art. For example, alkenyl substituted succinic anhydrides are typically prepared by the reaction of an alkene with maleic anhydride. Preferably, the or each cyclic anhydride may be independently selected from a Ce-30 alkyl or alkenyl substituted succinic anhydride, phthalic anhydride and pyromellitic dianhydride. Preferably, the or each cyclic anhydride may be independently selected from a Ce-30 alkyl or alkenyl substituted succinic anhydride. Preferably, the or each cyclic anhydride may be independently selected from a Ce-30 alkenyl substituted succinic anhydride wherein the alkenyl group is derived from a terminal olefin or an internal olefin, preferably an internal olefin. Preferably, the or each cyclic anhydride may be independently selected from (2-dodecen-1-yl)succinic anhydride, nonenyl succinic anhydride, octadecenyl succinic anhydride, C15-18 internal olefin-derived alkenyl succinic anhydride, C16 internal olefin-derived alkenyl succinic anhydride, C16 terminal olefin-derived alkenyl succinic anhydride, tetrapropenyl succinic anhydride, phthalic anhydride and pyromellitic dianhydride. Preferably, the or each cyclic anhydride may be independently selected from (2-dodecen-1-yl)succinic anhydride, nonenyl succinic anhydride, octadecenyl succinic anhydride, phthalic anhydride and pyromellitic dianhydride. Preferably, the or each cyclic anhydride may be independently selected from (2-dodecen-1-yl)succinic anhydride, nonenyl succinic anhydride, and octadecenyl succinic anhydride. Preferably, the or each cyclic anhydride may be independently selected from phthalic anhydride and pyromellitic dianhydride. The or each of the one or more first monomers may comprise one or more polycarboxylic acids or acid chloride or esters thereof. The or each of the one or more first monomers may consist essentially of or consist of one or more polycarboxylic acids or acid chloride or esters thereof. The polycarboxylic acid may comprise two or more carboxylic acid groups, such as two or three carboxylic acid groups. Preferred polycarboxylic acids are dicarboxylic acids. The polycarboxylic acid may be aliphatic or aromatic. The aliphatic polycarboxylic acid may be cycloaliphatic. The aliphatic polycarboxylic acid may be saturated or unsaturated. By the term “unsaturated” we mean that the polycarboxylic acid comprises one or more carbon-carbon double bonds. The polycarboxylic acid may comprise one or more heteroatoms other than the oxygen atoms in the carboxylic acid groups. By the term “heteroatoms” we mean atoms other than carbon or hydrogen, such as oxygen, nitrogen and sulfur atoms. For example, the polycarboxylic acid may comprise one or more moieties selected from hydroxy groups, amino groups, ether groups, and / or thioether groups. The polycarboxylic acid may be of the formula HOOC(CR2)nCOOH, wherein n is from 0 to 30; and each R is independently hydrogen or a substituent; and / or two R groups on the same carbon atom may be taken together to form a methylene (=CH2) group; and / or when n is two or more, two R groups on adjacent carbon atoms may be taken together to form a double bond. n is suitably from 1 to 20, preferably from 2 to 16, more preferably from 2 to 12, for example from 2 to 10. Each (CR2) group can be the same or different. Unless otherwise specified, the terms “each R”, “R groups” and the like are intended to refer to all instances of the “R” group in the formula HOOC(CR2)nCOOH, Each R may be hydrogen. Alternatively, one or two R groups may be a substituent and the remaining R groups may be hydrogen. Any suitable substituent may be used as R. The substituent may be a hydrocarbyl group or a heteroatom-containing group. Examples of suitable substituents include hydroxy groups, amino groups, carboxyl groups, alkyl groups, alkenyl groups, aryl groups, aralkyl groups, and alkaryl groups, wherein the alkyl groups, alkenyl groups, aryl groups, aralkyl groups, and alkaryl groups are optionally substituted with one or more of a hydroxy group, an amino group, and / or a carboxyl group. One or two of the R groups may be a hydroxy group. Another of the R groups may optionally be a carboxyl group or a carboxyl-substituted methyl group, and the remaining R groups are suitably hydrogen. Suitably, one or two of the R groups may be a hydroxy group, another of the R groups may be a carboxyl group or a carboxyl-substituted methyl group, and the remaining R groups may be hydrogen; or one or two of the R groups may be a hydroxy group and the remaining R groups may be hydrogen. The polycarboxylic acid may be malic acid, tartaric acid, or citric acid. One or two R groups may be an alkyl or alkenyl group. Preferably, one R group is an alkyl or alkenyl group. The remaining R groups are suitably hydrogen. Each alkyl or alkenyl group may contain from 6 to 30, such as from 8 to 24, carbon atoms. The polycarboxylic acid may be an alkyl or alkenyl substituted succinic acid, preferably an alkenyl substituted succinic acid. Examples of such polycarboxylic acids include C20-24 alkenyl succinic acid, dodecenyl succinic acid (such as (2-dodecen-1-yl)succinic acid), nonenyl succinic acid, octadecenyl succinic acid and octenyl succinic acid. One R group may be a polyisobutenyl group and the remaining R groups may be hydrogen. The polyisobutenyl group suitably has a number average molecular weight of from 100 to 2000, preferably from 100 to 1000, for example 260 or 550. The polycarboxylic acid may be a polyisobutenyl succinic acid, for example wherein the polyisobutenyl group has a number average molecular weight of 260 or 550. Two R groups on the same carbon atom may be taken together to form a methylene (=CH2) group. The polycarboxylic acid may comprise one or more such methylene groups. Two R groups on the same carbon atom may be taken together to form a methylene (=CH2) group and the remaining R groups may be hydrogen. The polycarboxylic acid may be itaconic acid. When n is 2 or more, two R groups on adjacent carbon atoms may be taken together to form a double bond. The polycarboxylic acid may comprise one or more such double bonds. The double bond may be in a cis or trans configuration. Two R groups on adjacent carbon atoms may be taken together to form a double bond and the remaining R groups may be hydrogen. The polycarboxylic acid may be maleic acid or fumaric acid. The polycarboxylic acid may be of the formula HOOC(CH2)nCOOH, wherein n is from 0 to 30. n is suitably from 1 to 20, preferably from 2 to 16, more preferably from 4 to 12, for example from 5 to 10. The polycarboxylic acid may be selected from oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, or dodecanedioic acid. Preferably, the polycarboxylic acid may be selected from pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, or dodecanedioic acid. The polycarboxylic acid may be of the formula HOOC(CH2)mX1(CH2)m2COOH, wherein m+m2 is from 0 to 30 and X1 is O, S, or NR17 wherein R17 is hydrogen or a hydrocarbyl group. m+m2 is suitably from 1 to 20, preferably from 2 to 16, more preferably from 2 to 12, for example from 2 to 6. m and m2 may each independently be from 0 to 30, suitably from 1 to 19, preferably from 1 to 15, more preferably from 1 to 11, for example from 1 to 5. R17 may be a hydrocarbyl group, such as an alkyl or alkenyl group. The hydrocarbyl group may contain from 1 to 12 carbon atoms, preferably from 1 to 6 carbon atoms. Preferably, R17 is hydrogen. X1 is preferably O or S. The polycarboxylic acid may be selected from diglycolic acid, thiodiglycolic acid, 3,3’-thiodipropanoic acid, or iminodiacetic acid, preferably from diglycolic acid or thiodiglycolic acid. The polycarboxylic acid may be of the formula HOOCCH2(OCH2CHR18)XOCH2COOH, wherein x is from 1 to 30 and each R18 is independently hydrogen or a hydrocarbyl group. x is suitably from 1 to 20, preferably from 2 to 16, more preferably from 4 to 14, for example from 6 to 12, such as 10. Each R18 may independently be a hydrocarbyl group, such as an alkyl group. The alkyl group may contain from 1 to 6 carbon atoms, preferably from 1 to 4 carbon atoms. The alkyl group is preferably methyl. In some embodiments, a portion of R18 groups are hydrocarbyl groups (such as methyl groups) and the remaining R18 groups are hydrogen. Preferably, each R18 is hydrogen. The polycarboxylic acid may be a poly(ethylene glycol)bis(carboxymethyl) ether. The poly(ethylene glycol)bis(carboxymethyl) ether may contain from 1 to 20 ethylene oxide units (i.e. -CH2CH2O-), preferably from 2 to 16 ethylene oxide units, more preferably from 4 to 14 ethylene oxide units, for example from 6 to 12 ethylene oxide units, such as 10 ethylene oxide units. The polycarboxylic acid may be a poly(ethylene glycol)bis(carboxymethyl) ether containing 10 ethylene oxide units. The polycarboxylic acid may comprise a cyclic group. The cyclic group may be substituted, for example with alkyl or alkenyl groups. The carboxyl groups of the polycarboxylic acid may be attached directly to the cyclic group, or via an alkyl or alkenyl group. The cyclic group may be a cycloaliphatic group. Examples of cycloaliphatic groups include cyclohexane and cyclohexene. The polycarboxylic acid may be 1,2-cyclohexanedicarboxylic acid or 1,4-cyclohexanedicarboxylic acid. The cyclic group may be an aromatic group. Examples of aromatic groups include benzene and naphthalene. The polycarboxylic acid may be selected from phthalic acid, isophthalic acid, terephthalic acid, homophthalic acid, 1,2,4-benzenetricarboxylic acid, pyromellitic acid, 1,2-naphthalenedicarboxylic acid, 2,3-naphthalenedicarboxylic acid. 1,8-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, or 2,7-naphthalenedicarboxylic acid. The polycarboxylic acid may be a dimer acid. Such compounds are formed from the dimerisation of unsaturated acids, for example unsaturated fatty acids having from 6 to 50, suitably from 8 to 40, preferably from 10 to 36, for example from 10 to 20 carbon atoms, or from 16 to 20 carbon atoms. The dimer acid may be hydrogenated or unhydrogenated. Preferably, the dimer acid is hydrogenated. The dimer acid may have from 12 to 100 carbon atoms, preferably from 16 to 72 carbon atoms such as from 20 to 40 carbon atoms, for example from 32 to 40 carbon atoms. Preferred dimer acids comprise C36 dimer acids such as those prepared by dimerising oleic acid, linoleic acid and mixtures comprising oleic and linoleic acid, for example, tall oil fatty acids. Preferably, the dimer acid comprises a dimer acid prepared by dimerising oleic acid. The dimer acid may be a hydrogenated C36 dimer acid. A reactive equivalent of the polycarboxylic acid may be used. The reactive equivalent may be an acid chloride of the polycarboxylic acid. The acid chloride of the polycarboxylic acid suitably does not comprise any free carboxylic acid groups. The reactive equivalent may be an ester of the polycarboxylic acid. The ester of the polycarboxylic acid suitably does not comprise any free carboxylic acid groups. The ester of the polycarboxylic acid is suitably a hydrocarbyl ester, such as an alkyl ester, an alkenyl ester, an aryl ester, an aralkyl ester, or an alkaryl ester. Preferably the ester is an alkyl ester. The alkyl ester is suitably formed by reacting the polycarboxylic acid with an alkanol. The alkanol suitably contains from 1 to 10 carbon atoms, such as from 1 to 6 carbon atoms, preferably from 1 to 4 carbon atoms. The alkanol is preferably methanol. The alkyl ester is preferably a methyl ester. Suitably, the or each polycarboxylic acid or the acid chloride or ester thereof may be selected from oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, maleic acid, fumaric acid, malic acid, tartaric acid, citric acid, C20-24 alkenyl succinic acid, dodecenyl succinic acid (such as (2-dodecen-1-yl)succinic acid), nonenyl succinic acid, octadecenyl succinic acid, octenyl succinic acid, polyisobutenylsuccinic acid, itaconic acid, 1,2-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, phthalic acid, isophthalic acid, terephthalic acid, homophthalic acid, 1,2,4-benzenetricarboxylic acid, pyromellitic acid, 1,2-naphthalenedicarboxylic acid, 2,3-naphthalenedicarboxylic acid, 1,8-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, 2,7-naphthalenedicarboxylic acid, diglycolic acid, thiodiglycolic acid, 3,3’-thiodipropanoic acid, iminodiacetic acid, poly(ethylene glycol)bis(carboxymethyl) ether, a dimer acid, or an acid chloride or ester thereof. Suitably, the or each polycarboxylic acid or the acid chloride or ester thereof may be selected from oxalic acid, succinic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, maleic acid, malic acid, tartaric acid, citric acid, 1,4-cyclohexanedicarboxylic acid, isophthalic acid, terephthalic acid, diglycolic acid, thiodiglycolic acid, poly(ethylene glycol)bis(carboxymethyl) ether, a hydrogenated dimer acid or an acid chloride or ester thereof. Suitably, the or each polycarboxylic acid or the acid chloride or ester thereof may be selected from oxalic acid, succinic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, maleic acid, malic acid, tartaric acid, citric acid, 1,4-cyclohexanedicarboxylic acid, isophthalic acid, diglycolic acid, thiodiglycolic acid, poly(ethylene glycol)bis(carboxymethyl) ether, a hydrogenated dimer acid, or an acid chloride or ester thereof. Preferably, the or each polycarboxylic acid or the acid chloride thereof may be selected from succinic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, maleic acid, malic acid, tartaric acid, citric acid, 1,4-cyclohexanedicarboxylic acid, terephthalic acid, diglycolic acid, thiodiglycolic acid, poly(ethylene glycol)bis(carboxymethyl) ether, a hydrogenated dimer acid, oxalyl chloride, isophthaloyl chloride, or terephthaloyl chloride. In some embodiments, mixtures of two or more different polycarboxylic acids may be used to make the polymer. For example, a mixture of dodecanedioic acid and tartaric acid may be used. Preferably, the or each first monomer may be a cyclic anhydride selected from one or more of formula (I), of formula (II) and of formula (III): wherein in formula (I) R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group, or R1 and R2 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group; in formula (II) R3 and R4 are each independently selected from hydrogen, an alkyl group and an alkenyl group, or R3 and R4 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group; and in formula (III) X is CR9R10, O, S, or NR11; R5, R6, R7, R8, R9, R10, and R11 are each independently selected from hydrogen, an alkyl group and an alkenyl group, and / or any of R5, R6, R7, R8, R9, R10, and R11 together with the atoms to which they are attached represent an optionally substituted cyclic group; or a polycarboxylic acid or an acid chloride or ester thereof, wherein the polycarboxylic acid is selected from: a polycarboxylic acid of the formula HOOC(CR2)nCOOH, wherein n is from 0 to 30; and each R is independently hydrogen or a substituent; and / or two R groups on the same carbon atom are taken together to form a methylene (=CH2) group; and / or when n is two or more, two R groups on adjacent carbon atoms are taken together to form a double bond; and n is suitably from 1 to 20, preferably from 2 to 16, more preferably from 2 to 12, for example from 2 to 10; a polycarboxylic acid of the formula HOOC(CH2)mX1(CH2)m2COOH, wherein m+m2 is from 0 to 30 and X1 is O, S, or NR17 wherein R17 is hydrogen or a hydrocarbyl group; a polycarboxylic acid of the formula HOOCCH2(OCH2CHR18)XOCH2COOH, wherein x is from 1 to 30 and each R18 is independently hydrogen or a hydrocarbyl group; a polycarboxylic acid comprising a cyclic group; or a dimer acid. Preferably, the or each first monomer may be a cyclic anhydride selected from one or more of succinic anhydride, maleic anhydride, glutaric anhydride, a C6-30 alkenyl succinic anhydride such as C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, octadecyl succinic anhydride, or octyl succinic anhydride, a branched alkenyl succinic anhydride such as tetrapropenyl succinic anhydride or polyisobutenyl succinic anhydride, phthalic anhydride, pyromellitic dianhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride, 1,2-naphthalic anhydride, 2,3-naphthalic anhydride, 1,8-naphthalic anhydride and homophthalic anhydride; or a polycarboxylic acid or an acid chloride or ester thereof selected from oxalic acid, succinic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, maleic acid, malic acid, tartaric acid, citric acid, 1,4-cyclohexanedicarboxylic acid, isophthalic acid, terephthalic acid, diglycolic acid, thiodiglycolic acid, poly(ethylene glycol)bis(carboxymethyl) ether, a hydrogenated dimer acid or an acid chloride or ester thereof. Preferably, the or each first monomer may be a cyclic anhydride selected from one or more of succinic anhydride, maleic anhydride, glutaric anhydride, a Ce-30 alkenyl succinic anhydride such as C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, octadecyl succinic anhydride, or octyl succinic anhydride, phthalic anhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride, 1,2-naphthalic anhydride, 2,3-naphthalic anhydride, 1,8-naphthalic anhydride and homophthalic anhydride; or a polycarboxylic acid or an acid chloride or ester thereof selected from oxalic acid, succinic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, maleic acid, malic acid, tartaric acid, citric acid, 1,4-cyclohexanedicarboxylic acid, isophthalic acid, terephthalic acid, diglycolic acid, thiodiglycolic acid, poly(ethylene glycol)bis(carboxymethyl) ether, a hydrogenated dimer acid or an acid chloride or ester thereof. Preferably, the or each first monomer may be selected from one or more of sebacic acid, dodecanedioic acid, pimelic acid, hydrogenated dimer acid, nonenyl succinic anhydride, (2-dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride. The polycarboxylic acid compounds or reactive equivalents thereof discussed herein may be commercially available or may be prepared using procedures well known in the art. The or each of the one or more second monomers used to make the polymer is a polyfunctional monomer having at least one reactive amino group. Mixtures of two or more different second monomers (i.e. different polyfunctional monomers having at least one reactive amino group) may be used to make the polymer. Any suitable polyfunctional monomer having at least one reactive amino group may be used to make the polymer, as would be understood by the person skilled in the art. By the term “polyfunctional monomer” we mean a monomer with at least two reactive groups. By the term “reactive group” we mean a group that reacts or may react with the first monomer. At least one of the reactive groups is a reactive amino group. The other reactive groups in the polyfunctional monomer may be reactive amino groups, or may be reactive groups other than amino groups, such as hydroxyl groups. Reactive amino groups are suitably primary amino groups or secondary amino groups. The polyfunctional monomer may comprise at least one reactive amino group and at least one hydroxyl group. The polyfunctional monomer may be an alkanolamine or an alkoxylated alkanolamine. Examples of suitable alkanolamines and alkoxylated alkanolamines include ethanolamine, isopropanolamine, mixed isopropanolamines, aminomethyl propanol, 2-aminobutanol, tromethamine, N-methylmethanolamine, N-methylethanolamine, diethanolamine, N-methylpropanolamine, dipropanolamine, diisopropylamine, N-methylbutanolamine, dibutanolamine, N-ethylmethanolamine, N-ethylethanolamine, N-ethylpropanolamine, N-ethylbutanolamine, N-propylmethanolamine, N-propylethanolamine, N-propylpropanolamine, N-propylbutanolamine, N-butylmethanolamine, N-butylethanolamine, N-butylpropanolamine, N-butylbutanolamine, 2-(2-aminoethoxy)ethanol, aminoethyl propanol, aminomethyl propanediol, and hydroxyethylbenzylamine. The polyfunctional monomer may be a monoalkanolamine or a dialkanolamine. The polyfunctional monomer is preferably a monoalkanolamine, such as ethanolamine. In some embodiments, the polyfunctional monomer does not comprise hydroxyl groups. The polyfunctional monomer may comprise at least two reactive amino groups. The polyfunctional monomer may be a polyamine. By “polyamine” we mean a compound having two or more amino groups. The polyamine may comprise further functional groups, such as ether groups and / or hydroxyl groups. The polyamine may be a diamine. The diamine may be an aliphatic diamine or an aromatic diamine. The aliphatic diamine may be a cycloaliphatic diamine such as isophorone diamine. The diamine may be alkylene diamine, an N-hydrocarbyl alkylene diamine, or an N,N’-dihydrocarbyl alkylene diamine. Examples of suitable diamines include ethylene diamine, trimethyl-1,6-hexanediamine and coco propylene diamine (commercially available as Duomeen CD). The polyamine may be a polyalkylene polyamine, such as a polyethylene polyamine. Suitable polyethylene polyamines include diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA) and mixtures and isomers thereof. The polyamine may comprise one or more hydroxyl groups and / or one or more ether groups. The polyamine may comprise one or more hydroxyalkyl groups, or one or more alkoxylated hydroxyalkyl groups. The polyamine may be a hydroxyalkylaminoalkylamine, an alkoxylated hydroxyalkylaminoalkylamine, a di(hydroxyalkyl)aminoalkylamine, or an alkoxylated di(hydroxyalkyl)amino alkylamine. Suitable polyamines of this type include (2-aminoethyl)aminoethanol, ethoxylated (2-aminoethyl)aminoethanol, di(hydroxyethyl)aminopropylamine, and ethoxylated di(hydroxyethyl)aminopropylamine. The polyamine may comprise one or more ether groups. The polyamine may be a polyether diamine. The polyether diamine suitably has a molecular weight of from 150 to 6000, preferably from 200 to 4000 or from 400 to 3000, for example from 600 to 2000. The polyether diamine may have a molecular weight of 600, 900, or 2000. The polyether diamine may have a weight average molecular weight of from 150 to 6000, preferably from 400 to 3000, for example from 600 to 2000. The polyether diamine may have a weight average molecular weight of from 150 to 1800, such as from 400 to 1500, for example from 600 to 1000. The polyether diamine may have a weight average molecular weight of from 1000 to 6000, such as from 1500 to 3000, for example from 1800 to 2000. The polyether diamine may have a weight average molecular weight of 600, 900, or 2000. In some embodiments, the polyether diamine has a molecular weight of from 150 to 1500, such as from 400 to 1200, for example from 600 to 900. The polyether diamine comprises a polyether backbone. The polyether backbone may be selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG). The copolymer of PEG and PPG may be a block copolymer or a random copolymer. Polyamines of this type are commercially available as Jeffamine D and Jeffamine ED compounds. Examples of suitable polyether diamines include poly(propylene glycol) bis(aminopropyl)ether (preferably having a molecular weight of around 230), Jeffamine ED-600, Jeffamine ED-900, and Jeffamine ED-2003. In some embodiments, the polyether diamine is selected from poly(propylene glycol) bis(aminopropyl)ether (preferably having a molecular weight of around 230), Jeffamine ED-600, and Jeffamine ED-900. In some embodiments, the polyether diamine is selected from poly(propylene glycol) bis(aminopropyl)ether (preferably having a molecular weight of around 230), Jeffamine ED-600, and Jeffamine ED-2003. In some embodiments, the polyether diamine is selected from poly(propylene glycol) bis(aminopropyl)ether (preferably having a molecular weight of around 230), Jeffamine ED-900, and Jeffamine ED-2003. The polyfunctional monomer may be a monomer of formula (IV): R19—N-(-R20--X2-VH ' 'n6 (|V) wherein R19 is H or an optionally substituted hydrocarbyl group; each R20 is independently a hydrocarbylene group; each X2 is independently NR21 or O; each R21 is independently H or an optionally substituted hydrocarbyl group; and n6 is 1 or more. R19 is H or an optionally substituted hydrocarbyl group. R19 may be H, an unsubstituted hydrocarbyl group, or a substituted hydrocarbyl group of formula (A): —r-R20a—X2a4-H ' (A) wherein each R20a is independently a hydrocarbylene group; each X2a is independently NR21a or O; each R21a is independently H or an optionally substituted hydrocarbyl group; and n7 is 1 or more. Each R20a is suitably an alkylene group. The alkylene group suitably contains from 1 to 6 carbon atoms. The alkylene group may independently be selected from ethylene (such as 1,2-ethylene), propylene (such as 1,2-propylene or 1,3-propylene) or butylene (such as 1,2-butylene, 1,3-butylene, or 1,4-butylene). Each R20a may independently be -CH2CH2-, -CH2CH(CH3)-, or CH(CH3)CH2-. Each R20a is preferably -CH2CH2-. Suitably, each R21a is independently H or an unsubstituted hydrocarbyl group. The hydrocarbyl group is suitably an alkyl or alkenyl group. The hydrocarbyl group may be a Ci to C12 alkyl or alkenyl group, preferably a Ci to Ce alkyl or alkenyl group, for example a Ci to C4 alkyl or alkenyl group. Suitably, each R21a is independently H or a Ci to C4 alkyl group. Preferably, each R21a is H. Each X2a is preferably O. Suitably, n7 is from 1 to 30, such as from 1 to 20, for example from 1 to 10. n7 may be 1 or 2. Preferably, n7 is 1. Suitably, R19 is H or an unsubstituted hydrocarbyl group. The hydrocarbyl group is suitably an alkyl or alkenyl group. The hydrocarbyl group may be a Ci to C12 alkyl or alkenyl group, preferably a Ci to Ce alkyl or alkenyl group, for example a Ci to C4 alkyl or alkenyl group. Suitably, R19 is H or a Ci to C4 alkyl group. Preferably, R19 is H. Each R20 is suitably an alkylene group. The alkylene group suitably contains from 1 to 6 carbon atoms. The alkylene group may independently be selected from ethylene (such as 1,2-ethylene), propylene (such as 1,2-propylene or 1,3-propylene) or butylene (such as 1,2-butylene, 1,3-butylene, or 1,4-butylene). Each R20 may independently be -CH2CH2-, -CH2CH(CH3)-, or CH(CH3)CH2-. Each R20 is preferably -CH2CH2-. Each X2 is suitably independently NR20 or O wherein each R20 is independently H or an optionally substituted hydrocarbyl group. Suitably, at least one X2 is NR20. Suitably, each R20 is independently H or an unsubstituted hydrocarbyl group. The hydrocarbyl group is suitably an alkyl or alkenyl group. The hydrocarbyl group may be a Ci to C12 alkyl or alkenyl group, preferably a Ci to Ce alkyl or alkenyl group, for example a Ci to C4 alkyl or alkenyl group. Suitably, each R20 is independently H or a Ci to C4 alkyl group. Preferably, each R20 is H. Suitably, n6 is from 1 to 150, preferably from 1 to 50, for example from 1 to 10. n6 may be 1 or 2. For example, n6 may be 1. For example, the polyfunctional monomer may be a monomer of formula (IV): R19—N—r—R20—X2-4-H ' / n6 (IV) wherein R19 is H, a Ci to C4 alkyl group, or a substituted hydrocarbyl group of formula (A): (A) R20a is an alkylene group containing from 1 to 6 carbon atoms; X2a is O; n7 is 1; R20 is an alkylene group containing from 1 to 6 carbon atoms; X2 is O; and n6 is 1. For example, the polyfunctional monomer may be a monomer of formula (IV): (IV) wherein R19 is H; each R20 is -CH2CH2-; each X2 is NH; and n6 is from 1 to 10. For example, the polyfunctional monomer may be a monomer of formula (IVA): H2N—r—R20—O—j—R20—NH2 ' / n6 (IVA) wherein each R20 is independently -CH2CH2-, -CH2CH(CH3)-, or CH(CH3)CH2-; and n6 is from 1 to 150. The polyfunctional monomer may be a monomer of formula (IVB): (IVB) wherein each R20 and R21 is independently -CH2CH2-, -CH2CH(CH3)-, or CH(CH3)CH2-; and each of n8, n9 and n10 is from 1 to 150. In some preferred embodiments, R20 is -CH2CH(CH3)-, R21 is independently -CH2CH2-, the sum of n8 and n10 is from 2 to 10, preferably from 5 to 7, and n9 is from 5 to 100, preferably from 10 to 50. In some preferred embodiments, R20 is -CH2CH(CH3)-, R21 is -CH2CH2-, the sum of n8 and n10 is from 3 to 7, and n9 is from 5 to 15. Preferably in the formula (IVB), R20 is -CH2CH(CH3)-, R21 is independently -CH2CH2-, the sum of n8 and n10 is from 2 to 10, preferably from 5 to 7, and n9 is from 5 to 100, preferably from 30 to 50. In some embodiments, R20 is -CH2CH(CH3)-, R21 is -CH2CH2-, the sum of n8 and n10 is from 5 to 7, and n9 is from 10 to 15. In some embodiments, R20 is -CH2CH(CH3)-, R21 is -CH2CH2-, the sum of n8 and n10 is from 3 to 4, and n9 is from 5 to 10. Suitably, the polyfunctional monomer may be selected from ethanolamine, diethanolamine, ethylene diamine, coco propylene diamine, diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA), trimethyl-1,6-hexane diamine, isophorone diamine or a polyether diamine (preferably polypropylene glycol bis(aminopropyl) ether with MW around 230Da, Jeffamine ED-600, Jeffamine ED-900, or Jeffamine ED-2003). Suitably, the polyfunctional monomer may be selected from ethylene diamine, coco propylene diamine, diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA), trimethyl-1,6-hexane diamine, isophorone diamine or a polyether diamine (preferably polypropylene glycol bis(aminopropyl) ether with MW around 230Da, Jeffamine ED-600, Jeffamine ED-900, or Jeffamine ED-2003). Suitably, the polyfunctional monomer may be selected from ethylene diamine, coco propylene diamine, triethylenetetramine (TETA), tetraethylenepentamine (TEPA), trimethyl-1,6-hexane diamine, isophorone diamine or a polyether diamine (preferably polypropylene glycol bis(aminopropyl) ether with MW around 230Da, Jeffamine ED-600, Jeffamine ED-900, or Jeffamine ED-2003). In one embodiment, the polymer may be the reaction product of monomers comprising one (i.e. a single) polycarboxylic acid or a reactive equivalent thereof and one (i.e. a single) polyfunctional monomer having at least one reactive amino group. In other embodiments, the polymer may be the reaction product of monomers comprising two different polycarboxylic acids or reactive equivalents thereof and one (i.e. a single) polyfunctional monomer having at least one reactive amino group, or the polymer may be the reaction product of monomers comprising one (i.e. a single) polycarboxylic acid or a reactive equivalent thereof and two different polyfunctional monomers having at least one reactive amino group. The combined amount of the one or more first monomers and the one or more second monomers may be at least 50 mol%, suitably at least 75 mol%, preferably at least 90 mol%, for example at least 95 wt% of the monomers that are reacted to obtain the polymer. The combined amount of the one or more first reactants and the one or more second reactants may be at least 50 mol%, suitably at least 75 mol%, preferably at least 90 mol%, for example at least 95 wt% of the reactants that are reacted to obtain the nitrogen containing compound. In one embodiment, the polymer may be the reaction product of monomers consisting essentially of or consisting of one (i.e. a single) polycarboxylic acid or a reactive equivalent thereof and one (i.e. a single) polyfunctional monomer having at least one reactive amino group. In other embodiments, the polymer may be the reaction product of monomers consisting essentially of or consisting of two different polycarboxylic acids or reactive equivalents thereof and one (i.e. a single) polyfunctional monomer having at least one reactive amino group, or the polymer may be the reaction product of monomers consisting essentially of or consisting of one (i.e. a single) polycarboxylic acid or a reactive equivalent thereof and two different polyfunctional monomers having at least one reactive amino group. The polymer for use herein may be the reaction product of monomers comprising the one or more first monomers and one or more second monomers as disclosed herein and additionally one or more third monomers. In other words, the polymer may be the reaction product of monomers comprising one or more first monomers as disclosed herein, one or more second monomers as disclosed herein and one or more third monomers. The one or more third monomers may for example act as end capping groups and / or may introduce additional functional groups to the polymers. The one or more third monomers may be selected to impart the desired groups and / or properties to the polymer by the person skilled in the art. In embodiments relating to nitrogen containing compounds as defined herein, the third monomer may be referred to as a third reactant. The combined amount of the one or more first monomers, the one or more second monomers, and the one or more third monomers may be at least 50 mol%, suitably at least 75 mol%, preferably at least 90 mol%, for example at least 95 wt% of the monomers that are reacted to obtain the polymer. The combined amount of the one or more first reactants, the one or more second reactants, and the one or more third reactants may be at least 50 mol%, suitably at least 75 mol%, preferably at least 90 mol%, for example at least 95 wt% of the reactants that are reacted to obtain the nitrogen containing compound. The polymer for use herein may be the reaction product of monomers consisting essentially of or consisting of the one or more first monomers and one or more second monomers as disclosed herein and additionally one or more third monomers. In other words, the polymer may be the reaction product of monomers consisting essentially of or consisting one or more first monomers as disclosed herein, one or more second monomers as disclosed herein and one or more third monomers. The polymer for use herein is suitably the reaction product of no more than four different monomers. Preferably, the polymer is the reaction product of no more than three different monomers. For example, the polymer may be the reaction product of one first monomer, one second monomer, and one third monomer, orthe reaction product of two different first monomers and one second monomer as disclosed herein. In some preferred embodiments, the polymer is the reaction product of only two different monomers, i.e. one first monomer and one second monomer as disclosed herein (and no further monomers). Examples of suitable third monomers include one or more of the following: (i) monocarboxylic acids or esters thereof; (ii) hydroxycarboxylic acids or cyclic esters thereof; (iii) polyols; (iv) epoxide compounds; (v) monoalcohols; and (vi) monofunctional monomers having a reactive amino group. The third monomer may be (i) a monocarboxylic acid or an ester thereof. Suitable monocarboxylic acids may be aliphatic or aromatic. The aliphatic monocarboxylic acid may be cycloaliphatic. The aliphatic monocarboxylic acid may be saturated or unsaturated. The monocarboxylic acid may contain from 2 to 40 carbon atoms, suitably from 4 to 30 carbon atoms, preferably from 6 to 20 carbon atoms, for example from 8 to 18 carbon atoms. The monocarboxylic acid may be a fatty acid. Examples of suitable monocarboxylic acids or esters thereof include hexanoic acid, octanoic acid, decanoic acid, lauric acid, myristic acid, myristoleic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, elaidic acid, linoleic acid, linolelaidic acid, arachidic acid, arachidonic acid, behenic acid, erucic acid, and esters (preferably methyl esters) thereof. Preferably, the monocarboxylic acid is selected from propionic acid, hexanoic acid, lauric acid, stearic acid, oleic acid, or erucic acid. The third monomer may be (ii) a hydroxycarboxylic acid or a cyclic ester thereof. Suitable hydroxycarboxylic acids comprise one or more hydroxy groups and one or more carboxylic acid groups. The hydroxycarboxylic acid may be a monocarboxylic acid comprising one or more hydroxy groups. By the term “cyclic ester” of a hydroxycarboxylic acid we mean a compound comprising a cyclic group, wherein the cyclic group comprises one or more ester groups. The ester may be a cyclic monoester or a cyclic diester. The cyclic ester may correspond to a single cyclised molecule of the hydroxycarboxylic acid. This may, for example, be formed by an intramolecular reaction between the hydroxy group and the carboxylic acid group on one molecule of the hydroxycarboxylic acid. Alternatively, the cyclic ester may correspond to a cyclic dimer of a hydroxycarboxylic acid. This may, for example, be formed by an intermolecular reaction between the hydroxy groups and the carboxylic acid groups on two molecules of the hydroxycarboxylic acid. Examples of suitable hydroxycarboxylic acids or cyclic esters thereof include glycolic acid, lactic acid, hydroxybutyric acid, hydroxyvaleric acid, hydroxycaproic acid, hydroxystearic acid (preferably 12-hydroxystearic acid), dihydroxystearic acid, 2,2-bis(hydroxymethyl)propionic acid, mandelic acid, ricinoleic acid, malic acid, tartaric acid, citric acid, y-butyrolactone, 5-valerolactone, s-caprolactone, menthide, D-lactide, L-lactide, or DL-lactide. Preferably, the hydroxycarboxylic acid is selected from ricinoleic acid or citric acid. The third monomer may be (iii) a polyol. The term polyol is used to refer to any compound including two or more hydroxy (OH) functional groups. In some embodiments the or each polyol may comprise carbon, hydrogen and oxygen atoms, and optionally additionally nitrogen atoms. In other embodiments, the or each polyol may consist essentially of or consist of carbon, hydrogen and oxygen atoms. Suitable polyols for preparing the polymer may be compounds having from 2 to 10, preferably from 2 to 6, more preferably 2 or 3, hydroxy groups. Examples of suitable polyols include ethylene glycol, propylene glycol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, 1,6-hexanediol, 1,12-dodecanediol, trimethylolpropane, 2-ethyl-1,3,-hexanediol, 2,2-diethyl-1,3-propanediol, 2,2- bis(hydroxymethyl)propionic acid, penta erythritol, sorbitol, xylitol, glycerol, neopentyl glycol, diethylene glycol, triethylene glycol, di propylene glycol, tripropylene glycol, polyethylene glycol (PEG), for example having a molecular weight of from 150 to 6000, polypropylene glycol (PPG), for example having a molecular weight of from 400 to 2000, castor oil, polyoxyethylene (80) sorbitan monooleate (also known as Tween® 80), 2,4,7,9-tetramethyl-5-decyne-4,7-diol ethoxylate, N-methyl diethanolamine, N-butyl diethanolamine, triethanolamine and diethanolamine, tris(2-hydroxyethyl)methylammonium methylsulfate, and polyols formed by reaction of a hydroxy substituted cyclic ester or cyclic carbonate, such as glycerol carbonate or gluconolactone, with a suitable primary or secondary amine compound, such as ethanolamine, dipropylamine, hexylamine, dodecylamine, phenethylamine, dipropylamine, ethylenediamine, or a polyether polyamine. The third monomer may be (iv) an epoxide compound. Suitable epoxide compounds may comprise one or more than one epoxide group. For example, suitable epoxide compounds may comprise two epoxide groups. Examples of suitable epoxide compounds include 1,2-epoxydodecane, ethyl glycidyl ether, isopropyIglycidyI ether, 2-ethylhexyl glycidyl ether, octyl glycidyl ether, nonyl glycidyl ether, decyl glycidyl ether, butyl glycidyl ether (such as n-butyl glycidyl ether), 1,2-epoxyhexane, epichlorohydrin, glycidyltrimethylammonium chloride, cyclopentene oxide, cyclohexene oxide, poly(ethylene glycol) diglycidyl ether, poly(propylene glycol) diglycidyl ether and poly(butylene glycol) diglycidyl ether. The third monomer may be (v) a monoalcohol. Suitable monoalcohols may be aliphatic or aromatic. The aliphatic monoalcohol may be cycloaliphatic. The aliphatic monoalcohol may be saturated or unsaturated. The monoalcohol may contain from 2 to 40 carbon atoms, suitably from 4 to 30 carbon atoms, preferably from 6 to 20 carbon atoms, for example from 8 to 18 carbon atoms. The monoalcohol may be a fatty alcohol. Examples of suitable monoalcohols include hexanol, octanol, 2-ethylhexanol, decanol, dodecanol alcohol, myristyl alcohol, myristoleyl alcohol, palmityl alcohol, palmitoleyl alcohol, stearyl alcohol, oleyl alcohol, elaidyl alcohol, linoleyl alcohol, linolelaidyl alcohol, arachidyl alcohol, arachidonyl alcohol, behenyl alcohol, erucyl alcohol, benzyl alcohol, and choline chloride. Preferably, the monoalcohol is hexanol or oleyl alcohol. The third monomer may be (vi) a monofunctional monomer having a reactive amino group. Suitable monofunctional monomers having a reactive amino group have one reactive amino group and no other reactive groups. The monofunctional monomer may contain other functional groups that are not reactive groups, such as tertiary amino groups or ether groups. The monofunctional monomer may be an aliphatic monoamine (such as a fatty alkyl amine), an N,N-dialkylaminoalkylamine, or a polyether monoamine. The polyether monoamine suitably comprises a polyether backbone selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG). The copolymer of PEG and PPG may be a block copolymer or a random copolymer. The polyether backbone is suitably capped at one end with the reactive amino group, and capped at the other end with an alkyl group (preferably a methyl group). The polyether monoamine suitably has a molecular weight of from 150 to 6000, preferably from 400 to 3000, for example from 600 to 2000. The polyether monoamine may have a weight average molecular weight of from 150 to 6000, preferably from 400 to 3000, for example from 600 to 2000. Examples of suitable monofunctional monomers having a reactive amino group include propylamine, dipropylamine, butylamine, hexylamine, octylamine, decylamine, dodecylamine, tetradecylamine, hexadecylamine, octadecylamine, tallow alkyl amine, benzylamine, phenethylamine, 3-dimethylaminopropylamine (DMAPA), or Jeffamine M-1000 (which is commercially available). Preferably, the monofunctional monomer having a reactive amino group is selected from dodecylamine, N,N-dimethylaminopropylamine (DMAPA), or Jeffamine M-1000. The polymers may be prepared from the first, second and optionally third monomers by any suitable method, as would be known to the person skilled in the art. The polymerisation reaction will typically be conducted in the presence of a suitable polymerisation catalyst, such as tin(ll) ethylhexanoate, tin(ll) oxalate, p-toluenesulfonic acid, methanesulfonic acid, or sulfuric acid. These catalysts may also be used in reactions that form nitrogen containing compounds that are not polymers. Another suitable catalyst system comprises 1,8-diazabicyclo(5.4.0)undec-7-ene and dicyclohexylurea. The polymerisation reaction may be carried out for any suitable length of time, such as at least 1 hour, preferably at least 3 hours, for example at least 5 hours. The polymerisation reaction may be carried out at any suitable temperature, such as from 50 to 300°C, preferably from 150 to 250°C. Suitable molar ratios of the first, second and optional third monomers may be used to prepare the polymers. Thus repeat units in the polymer derived from the first, second and third monomers when present may be present in the polymer in any suitable molar ratio and in any suitable arrangement. Suitably, the polymer is not further reacted after the reaction of the monomers. For example, the polymer is suitably not quaternised, e.g. by reacting the polymer with a quaternising agent. Suitably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of: (i) a cyclic anhydride of formula (I) wherein R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group; and (ii) a dicarboxylic acid or an acid chloride or ester thereof, and wherein the or each second monomer is one or more of: (iii) a polyfunctional monomer comprising at least one reactive amino group and at least one hydroxyl group; (iv) a polyether diamine; and (v) a diamine. Suitably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of: (i) a cyclic anhydride of formula (I) wherein R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group; and (ii) a dicarboxylic acid or an acid chloride or ester thereof, and wherein the or each second monomer is one or more of: (iii) a polyfunctional monomer comprising at least one reactive amino group and at least one hydroxyl group; (iv) a polyether diamine; and (v) a diamine. Preferably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of: (i) a cyclic anhydride of formula (I) wherein R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group; and (ii) a dicarboxylic acid or an acid chloride or ester thereof, and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Suitably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of: (i) a cyclic anhydride of formula (I) wherein R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group; and (ii) a dicarboxylic acid or an acid chloride or ester thereof, and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Suitably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Suitably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group; and wherein the or each second monomer is one or more monomer of the formula (IVA) as defined herein. Suitably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group); and wherein the or each second monomer is one or more monomer of the formula (IVA) as defined herein. Suitably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Suitably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a dicarboxylic acid or an acid chloride or ester thereof; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Suitably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a dicarboxylic acid or an acid chloride or ester thereof; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Suitably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group); and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Suitably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group); and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Suitably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is a dicarboxylic acid or an acid chloride or ester thereof, and wherein the or each second monomer is one or more of a polyfunctional monomer comprising at least one reactive amino group and at least one hydroxyl group (such as an alkanol amine). Suitably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is a dicarboxylic acid or an acid chloride or ester thereof, and wherein the or each second monomer is one or more polyfunctional monomer comprising at least one reactive amino group and at least one hydroxyl group (such as an alkanol amine). Suitably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the first monomer is pimelic acid or an acid chloride or ester thereof, and wherein the or each second monomer is one or more of a polyfunctional monomer comprising at least one reactive amino group and at least one hydroxyl group (such as an alkanol amine). Suitably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the first monomer is pimelic acid or an acid chloride or ester thereof, and wherein the or each second monomer is one or more polyfunctional monomer comprising at least one reactive amino group and at least one hydroxyl group (such as an alkanol amine). Preferably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the one or more first monomers are selected from one or more of pimelic acid or an acid chloride or ester thereof, hydrogenated dimer acid or an acid chloride or ester thereof, nonenyl succinic anhydride, (2-dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride, and wherein the or each second monomer is one or more monomer of the formula (IVA) as defined herein. Preferably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the one or more first monomers are selected from one or more of pimelic acid or an acid chloride or ester thereof, hydrogenated dimer acid or an acid chloride or ester thereof, nonenyl succinic anhydride, (2-dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride, and wherein the or each second monomer is one or more monomer of the formula (IVA) as defined herein. Preferably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the one or more first monomers are selected from one or more of pimelic acid or an acid chloride or ester thereof, sebacic acid or an acid chloride or ester thereof, dodecanedioic acid or an acid chloride or ester thereof, hydrogenated dimer acid or an acid chloride or ester thereof, nonenyl succinic anhydride, (2- dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride, and wherein the one or more second monomers are selected from one or more of diethanolamine, trimethyl-1,6-hexanediamine, isophorone diamine, poly(propylene glycol) bis(aminopropyl ether) (preferably having a molecular weight of around 230 Da), Jeffamine ED-600, Jeffamine ED-900, and Jeffamine ED-2003. Preferably the one or more first monomers is one (i.e. a single) first monomer and the one or more second monomers is one (i.e. a single) second monomer. Preferably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the one or more first monomers are selected from one or more of pimelic acid or an acid chloride or ester thereof, sebacic acid or an acid chloride or ester thereof, dodecanedioic acid or an acid chloride or ester thereof, hydrogenated dimer acid or an acid chloride or ester thereof, nonenyl succinic anhydride, (2-dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride, and wherein the one or more second monomers are selected from one or more of diethanolamine, trimethyl-1,6-hexanediamine, isophorone diamine, poly(propylene glycol) bis(aminopropyl ether) (preferably having a molecular weight of around 230 Da), Jeffamine ED-600, Jeffamine ED-900, and Jeffamine ED-2003. Preferably the one or more first monomers is one (i.e. a single) first monomer and the one or more second monomers is one (i.e. a single) second monomer. Preferably, the polymer may be the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the one or more first monomers are selected from one or more of pimelic acid or an acid chloride or ester thereof, hydrogenated dimer acid or an acid chloride or ester thereof, nonenyl succinic anhydride, (2-dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride, and wherein the one or more second monomers are selected from one or more of diethanolamine, poly (propylene glycol) bis(aminopropyl ether), Jeffamine ED-600 and Jeffamine ED-2003. Preferably, the polymer may be the reaction product of monomers consisting essentially of or consisting of one or more first monomers and one or more second monomers, wherein the one or more first monomers are selected from one or more of pimelic acid or an acid chloride or ester thereof, hydrogenated dimer acid or an acid chloride or ester thereof, nonenyl succinic anhydride, (2-dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride, and wherein the one or more second monomers are selected from one or more of diethanolamine, poly(propylene glycol) bis(aminopropyl ether), Jeffamine ED-600 and Jeffamine ED-2003. Preferably, the polymer may be the reaction product of monomers comprising a single (i.e. one) first monomer and a single (i.e. one) second monomer, wherein the first monomer is selected from pimelic acid or an acid chloride or ester thereof, hydrogenated dimer acid or an acid chloride or ester thereof, nonenyl succinic anhydride, (2-dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride, and wherein the second monomer is selected from diethanolamine, poly(propylene glycol) bis(aminopropyl ether), Jeffamine ED-600 and Jeffamine ED-2003. Preferably, the polymer may be the reaction product of monomers consisting essentially of or consisting of a single (i.e. one) first monomer and a single (i.e. one) second monomer, wherein the first monomer is selected from pimelic acid or an acid chloride or ester thereof, hydrogenated dimer acid or an acid chloride or ester thereof, nonenyl succinic anhydride, (2-dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride, and wherein the second monomer is selected from diethanolamine, poly(propylene glycol) bis(aminopropyl ether), Jeffamine ED-600 and Jeffamine ED-2003. Preferably, the polymer is the reaction product of monomers comprising: (i) Pimelic acid or an acid chloride or ester thereof and diethanolamine, preferably in a molar ratio of 1:1; (ii) Cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1; (iii) Hydrogenated dimer acid or an acid chloride or ester thereof and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1; or (iv) Cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a diamine selected from isophorone diamine and trimethyl-1,6-hexanediamine, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of: (i) Pimelic acid or an acid chloride or ester thereof and diethanolamine, preferably in a molar ratio of 1:1; (ii) Cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1; (iii) Hydrogenated dimer acid or an acid chloride or ester thereof and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1; or (iv) Cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a diamine selected from isophorone diamine and trimethyl-1,6-hexanediamine, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising: (i) pimelic acid or an acid chloride or ester thereof and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and a polyether diamine, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and a polyether diamine, preferably in a molar ratio of 1:1; or (iv) C20-C24 alkenyl succinic anhydride and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of: (i) pimelic acid or an acid chloride or ester thereof and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and a polyether diamine, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and a polyether diamine, preferably in a molar ratio of 1:1; or (iv) C20-C24 alkenyl succinic anhydride and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising: (i) pimelic acid or an acid chloride or ester thereof and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iv) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (v) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of (i) pimelic acid or an acid chloride or ester thereof and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iv) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (v) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising: (i) pimelic acid or an acid chloride or ester thereof and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (iv) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of (i) pimelic acid or an acid chloride or ester thereof and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (iv) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising: (i) Pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) Cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1; (iii) Hydrogenated dimer acid and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1; or (iv) Cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a diamine selected from isophorone diamine and trimethyl-1,6-hexanediamine, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of: (i) Pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) Cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1; (iii) Hydrogenated dimer acid and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1; or (iv) Cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a diamine selected from isophorone diamine and trimethyl-1,6-hexanediamine, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising: (i) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and a polyether diamine, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and a polyether diamine, preferably in a molar ratio of 1:1; or (iv) C20-C24 alkenyl succinic anhydride and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of: (i) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and a polyether diamine, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and a polyether diamine, preferably in a molar ratio of 1:1; or (iv) C20-C24 alkenyl succinic anhydride and a monomer of the formula (IVA) as defined herein, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising: (i) sebacic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and diethanolamine, preferably in a molar ratio of 1:1; (iv) dodecanedioic acid and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (v) nonenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (vi) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2300, preferably in a molar ratio of 1:1; (vii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (viii) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (ix) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1; (x) (2-dodecen-1-yl)succinic anhydride and trimethyl-1,6-hexanediamine, preferably in a molar ratio of 1:1; (xi) hydrogenated dimer acid and Jeffamine ED-600, preferably in a molar ratio of 1:1; (xii) nonenyl succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (xiii) (2-dodecen-1-yl)succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (xiv) octadecenyl succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (xv) hydrogenated dimer acid and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (xvi) octadecenyl succinic anhydride and isophorone diamine, preferably in a molar ratio of 1:1; (xvii) nonenyl succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1; (xviii) hydrogenated dimer acid and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (xix) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-900, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of: (i) sebacic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and diethanolamine, preferably in a molar ratio of 1:1; (iv) dodecanedioic acid and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (v) nonenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (vi) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2300, preferably in a molar ratio of 1:1; (vii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (viii) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (ix) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1; (x) (2-dodecen-1-yl)succinic anhydride and trimethyl-1,6-hexanediamine, preferably in a molar ratio of 1:1; (xi) hydrogenated dimer acid and Jeffamine ED-600, preferably in a molar ratio of 1:1; (xii) nonenyl succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (xiii) (2-dodecen-1-yl)succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (xiv) octadecenyl succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (xv) hydrogenated dimer acid and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (xvi) octadecenyl succinic anhydride and isophorone diamine, preferably in a molar ratio of 1:1; (xvii) nonenyl succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1; (xviii) hydrogenated dimer acid and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (xix) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-900, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising: (i) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iv) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (v) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of (i) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iv) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (v) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising: (i) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (iv) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of (i) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) octadecenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (iv) C20-C24 alkenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising: (i) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) dodecanedioic acid and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) nonenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iv) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (v) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1; (vi) nonenyl succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (vii) octadecenyl succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (viii) hydrogenated dimer acid and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (ix) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-900, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of: (i) pimelic acid and diethanolamine, preferably in a molar ratio of 1:1; (ii) dodecanedioic acid and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iii) nonenyl succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (iv) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-2003, preferably in a molar ratio of 1:1; (v) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1; (vi) nonenyl succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (vii) octadecenyl succinic anhydride and poly(propylene glycol) bis(aminopropyl ether) having a molecular weight of around 230 Da, preferably in a molar ratio of 1:1; (viii) hydrogenated dimer acid and Jeffamine ED-2003, preferably in a molar ratio of 1:1; or (ix) (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-900, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers comprising (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1. Preferably, the polymer is the reaction product of monomers consisting essentially of or consisting of (2-dodecen-1-yl)succinic anhydride and Jeffamine ED-600, preferably in a molar ratio of 1:1. Jeffamine ED-2003 is commercially available from Huntsman and is a polyetheramine that is derived from propylene oxide capped polyethylene glycol and that is of formula (V): (V) wherein y = 39 and (x + z = 6). Jeffamine ED-900 is also commercially available from Huntsman and is of formula (V) except thaty = 12.5 and (x + z) = 6. Jeffamine ED-600 is also commercially available from Huntsman and is of formula (V) except that y = 9 and (x + z) = 3.6. The polymer formed from the first, second and optional third monomers may comprise a suitable number of total monomer units (i.e. repeat units). For example, the polymer may comprise at least 4 monomer units. In other words, the polymer may comprise a total of at least 4 monomer units including the first, second and optional third monomers. Suitably, the polymer may comprise from 4 to 50 monomer units, preferably from 4 to 30 monomer units. Suitably, the polymer has a number average molecular weight of from 1,000 to 50,000 Daltons, preferably from 1,000 to 15,000 Daltons (for example from 2,000 to 7,000 Daltons). Suitably, the polymer has a polydispersity index of from 1 to 4, such as from 1.1 to 2, preferably from 1.5 to 1.6. The polydispersity index of a polymer is given by the ratio of Mw to Mn (Mw / Mn), wherein Mw is the weight-average molecular weight and Mn is the number average molecular weight. In some embodiments, the nitrogen containing compound is not a polymer. For example, the nitrogen containing compound may comprise a single residue of the first reactant and a single residue of the second reactant, or two residues of the first reactant and a single residue of the second reactant, or a single residue of the first reactant and two residues of the second reactant. The nitrogen containing compound may comprise a single residue of a cyclic anhydride of formula (I) and a single residue of a monomer of formula (IVA), and have the structure: wherein R1 and R2 are as defined in relation to formula (I) herein and R20 and n6 are as defined in relation to formula (IVA) herein. The nitrogen containing compound may comprise two residues of a cyclic anhydride of formula (I) and a single residue of a monomer of formula (IVA), and have the structure: wherein R1 and R2 are as defined in relation to formula (I) herein and R20 and n6 are as defined in relation to formula (IVA) herein. Preferably, the polymer is substantially free of silicon atoms. By substantially free of silicon atoms we mean that the polymer contains less than 1 wt% of silicon in the polymer, preferably less than 0.5 wt% of silicon in the polymer. More preferably, the polymer is free of silicon atoms, by which we mean that it is not possible to detect silicon in the polymer. Suitable methods of measuring the amount of silicon in a polymer are well known to those skilled in art and include elemental analysis and inductively coupled plasma (ICP) spectroscopy. Preferably, the polymer is substantially free of fluorine atoms. The polymer may be substantially free of halogen atoms. By substantially free of fluorine or halogen atoms we mean that the polymer contains less than 1 wt% of fluorine or halogen in the polymer, preferably less than 0.5 wt% of fluorine or halogen in the polymer. More preferably, the polymer is free of fluorine atoms. The polymer may be free of halogen atoms. By free of fluorine or halogen atoms we mean that it is not possible to detect fluorine or halogen in the polymer. Suitable methods of measuring the amount of fluorine or halogen in a polymer are well known to those skilled in art and include elemental analysis and inductively coupled plasma (ICP) spectroscopy. Preferably, the polymer is substantially free of quaternary ammonium moieties. By substantially free of quaternary ammonium moieties we mean that the polymer contains less than 1 wt% of quaternary nitrogen atoms in the polymer, preferably less than 0.5 wt% of quaternary nitrogen atoms in the polymer. More preferably, the polymer is free of quaternary ammonium moieties, by which we mean that it is not possible to detect quaternary ammonium moieties in the polymer. The use of the nitrogen containing compound (preferably the polymer) according to the first aspect is to treat a surface to provide at least one effect (i.e. to the substrate) selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance. The method according to the second aspect treats a surface to provide at least one effect (i.e. to the substrate) selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance. The use of the first aspect and method of the second aspect is to treat a surface. The surface is any surface that is not a surface of a home care substrate. The surface may be a surface of any suitable substrate, provided that it is not a home care substrate. References herein to treating and contacting a surface are intended to refer to treating or contacting the entire surface or a portion thereof. References to herein to (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance of a surface are intended to mean as compared to an otherwise identical surface that has not been treated with the nitrogen containing compound (preferably the polymer) or composition as disclosed herein. The use of the first aspect and the method of the second aspect treat a surface, wherein treating the surface provides at least one effect selected from: (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance. Treating the surface may provide at least one effect selected from: (a) increased water repellency, and (b) reduced friction. Treating the surface may provide: (a) increased water repellency, and (b) reduced friction. Treating the surface may provide at least two effects selected from: (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance. Treating the surface may provide: (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance. Treating the surface may provide (a) increased water repellency, i.e. to the surface. A surface with increased water repellency may have decreased water wettability. Wettability can be determined by measuring the contact angle between a liquid droplet and a solid surface, and a decrease in wettability may be demonstrated by measuring a greater contact angle following treatment of the surface with the polymer defined herein. Methods and equipment for the measurement of contact angle are well known to the skilled person. An example is ISO / TS 14778:2021 which is concerned with the measurement of contact angle on paper and board substrates. Water is less likely to adhere to water repellent surfaces, and water droplets may simply roll off the surface. In doing so, water droplets may carry undesirable particles, such as foulants, pollution, food waste, oils, dust or dirt away from the surface. Treating the surface may therefore provide an enhanced cleaning effect or self-cleaning effect, and / or increased resistance to undesirable particles such as foulants, pollution, food waste, oils, dust or dirt. Treating the surface may repel undesirable particles, such as foulants, pollution, food waste, oils, dust or dirt, and / or may prevent deep soiling. By repel undesirable particles we mean that treating the surface may reduce or prevent deposition of the undesirable particles on the surface. A surface with increased water repellency may dry more quickly. A surface with increased water repellency may substantially or completely prevent water from penetrating the surface, providing long-lasting protection against moisture, stains, and potential water damage. Methods and equipment for the measurement of water repellency are well known to the skilled person. An example is the test procedure TM22-2017e which may be used to measure the water repellency of a fabric. The water repellency of the surface of a substrate may be measured by weighing the substrate, immersing the substrate in water (for example, for 5 minutes), removing the substrate from the water and allowing excess water to drain off (for example, for 1 minute), then weighing the substrate again. The weight of the water in the substrate compared to the weight of the dry substrate (i.e. before immersion in water) corresponds to the water uptake of the substrate. A lower water uptake (i.e. relative to a control experiment in which the nitrogen containing compound is absent) corresponds to increased water repellency. A surface with increased water repellency may be especially useful for applications where surfaces require cleaning. For example, it is advantageous to provide a surface with increased water repellency, such that the surface may be readily and / or more effectively cleaned. Treating the surface may provide (b) reduced friction, i.e. to the surface. By providing reduced friction we mean that the surface has an increased smoothness and / or a reduced resistive force or coefficient of friction when an object is slid over the surface. A surface with reduced friction may be useful for applications where surfaces move against one another. Thus, when the effect is to provide reduced friction, this may advantageously provide improved lubrication. Thus, the use of the first aspect and the method of the second aspect may provide improved lubrication of a surface thereof. The use of the first aspect may therefore provide the use of a polymer as defined herein as a lubricant for a surface. The method of the second aspect may provide a method of lubricating a surface, the method comprising contacting the surface with a polymer as defined herein. The use of the first aspect may be the use of the polymer as defined herein as a lubricating agent. Friction between two surfaces may be determined by sliding the surfaces against one another and measuring the resistive force or coefficient of friction. The coefficient of friction of plastic films may be measured by the test procedure ASTM D1894. A surface with reduced friction may reduce the build up of static on the surface. Thus, treating the surface may provide (b) reduced friction and thereby provide an antistatic effect. A surface with an antistatic effect may advantageously reduce the buildup of dust and reduce electric discharges when the surface contacts another surface. Treating the surface may provide (c) improved visual appearance, i.e. to the surface. For example, improved visual appearance may provide increased shine. By “shine” we mean the perceived reflectiveness of a surface. As used herein, shine, gloss and reflectiveness are considered interchangeable. A surface with increased shine may be desirable from an aesthetic standpoint. Increased shine can also be a visual indicator of the surface having other properties provided by treatment with the polymer as defined herein, such as increased water repellency and / or reduced friction. When the shine of the surface decreases, this can be used to prompt a user to retreat the surface with the polymer. The gloss or shine of surfaces can be measured by reflectance methods, for example DIN 67530. A surface with improved visual appearance (such as increased shine) may be useful for applications where surfaces are required to look appealing visually. The use of the first aspect and the method of the second aspect suitably involve coating at least a portion of the surface with the polymer as defined herein. The polymer may be coated onto the surface by spreading, such as by a blade, brush, cloth or sponge. The polymer may be applied onto the surface by spraying, for example from a pressurised can. The polymer may be applied to the surface as a foam, for example by spraying the polymer through a foam-forming nozzle. The use of the first aspect and the method of the second aspect may involve distributing the polymer as defined herein in the substrate. When the substrate is a solid substrate, the solid substrate may be formed from a liquid precursor (such as a melt) into which the polymer is admixed. Typically, the polymer will migrate to the surface of the liquid precursor and thereby the surface of the solid substrate. For example, the polymer may be admixed into an extruded product prior to extrusion. The use and method according to the first and second aspects may treat any suitable surface that is not a surface of a home care substrate and that would benefit from one or more of (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance (especially (a) increased water repellency and (b) reduced friction). The surface is not a surface of a home care substrate. In other words, the surfaces that are referred to in this specification are non-home care surfaces. By a home care substrate we mean any substrate of the home or household contents. Home care substrate preferably includes a fabric or a hard surface. “Fabric” includes clothing, linens and other household textiles, such as upholstery, curtains, blinds etc. In the context of fabrics, the term “linen” is used to describe certain types of laundry items including bed sheets and bed covers, pillow cases, towels, tablecloths, table napkins, uniforms and the like, but also washable household items such as curtains and blinds, washable upholstery items such as cushion covers and the like. The term “ household textiles” can include woven fabrics, non-woven fabrics, and knitted fabrics and fabrics can include natural or synthetic fibres such as silk fibres, linen fibres, cotton fibres, polyester fibres, polyamide fibres such as nylon, rayon, acrylic fibres, acetate fibres, and blends thereof including cotton and polyester blends, fabrics which are elastic and / or contain elastane, and also viscose, modal and lyocell. “Hard surface” includes surfaces of dishes and other household surfaces. “Dishes” is meant generically and encompasses essentially any items which may be found in a dishwashing (manual or automatic machine) load, including crockery, chinaware, glassware, plasticware, siliconeware, silverware, hollowware and cutlery and any of these may comprise a hard surface; and “household surface” means any surface found in and around houses as in kitchens, bathrooms, e.g., floors, walls, tiles, windows, cupboards, sinks, showers, shower plastified curtains, wash basins, WCs, fixtures and fittings, and furniture. Hard surfaces may be made of different materials like ceramic, vinyl, no-wax vinyl, linoleum, melamine, glass, Inox®, Formica®, vitroceramic, any plastics, plastified wood, metal or any painted or varnished or sealed surface and the like; as well as household appliances including, but not limited to refrigerators, freezers, washing machines, automatic dryers, ovens, microwave ovens, dishwashers and so on. The surface is suitably an industrial surface. By industrial surface we mean any surface in an industrial setting and scale. The industrial surface may undergo a treatment as defined herein during an industrial process, such as an industrial process of the manufacturing industry, the packaging industry, construction industry, the automotive industry, the aviation industry, the agricultural industry, or the mining industry. An industrial process does not, for example, include a consumer-related activity. Thus, the industrial surface is found in an industrial setting not, for example, the home. The industrial surface may be a surface of an industrial product. By an industrial product we mean a product in an industrial setting and scale, which may undergo a treatment as defined herein during an industrial process. The industrial surface may be a surface of industrial equipment. By industrial equipment we mean equipment that is used in an industrial setting and scale, for example that is used in large scale manufacturing, storage, extraction, processing, treatment and / or transportation. Examples of industrial equipment will be well known to persons skilled in the art and include machinery and engines (including components thereof). The industrial surface may treated by an industrial process in the manufacturing industry. For example, the industrial surface may be the surface of a product of the manufacturing industry or the surface of equipment used in the manufacturing industry. The industrial surface may be treated by an industrial process in the packaging industry. For example, the industrial surface may be the surface of a product of the packaging industry or the surface of equipment used in the packaging industry. The industrial surface may be treated by an industrial process in the construction industry. For example, the industrial surface may be the surface of a product of the construction industry or the surface of equipment used in the construction industry. The industrial surface may be treated by an industrial process in the automotive industry. For example, the industrial surface may be the surface of a product of the automotive industry or the surface of equipment used in the automotive industry. The industrial surface may be treated by an industrial process in the aviation industry. For example, the industrial surface may be the surface of a product of the aviation industry or the surface of equipment used in the aviation industry. The industrial surface may be treated by an industrial process in the agricultural industry. For example, the industrial surface may be the surface of a product of the agricultural industry or the surface of equipment used in the agricultural industry. The industrial surface may be treated by an industrial process in the mining industry. For example, the industrial surface may be the surface of a product of the mining industry or the surface of equipment used in the mining industry. The surface is suitably a solid surface. The solid surface may be a hard surface or a soft surface. The surface may be formed from any suitable material such as one or more materials selected from metal, glass, ceramic, glass-ceramic, stone, concrete, gypsum, stucco, plastic, rubber, wood, paper-based materials (such as paper or cardboard) and leather (including combinations thereof, such as a laminate for example). Examples of suitable surfaces include the surfaces of extruded products (such as pellets, granules, or films), moulds, non-household buildings (such as walls, windows, floors, or ceilings), paper-based packaging, construction materials (such as plasterboard, gypsum, stucco, or concrete), vehicles (such as windows, tyres, vehicle bodies, or vehicle interiors), plants (such as seeds), solid agrochemical compositions, and non-household fibrous substrates. The surface may be selected from the surface of an extruded product (such as a pellet, granule, or film), a mould, paper packaging, a construction material (such as plasterboard, gypsum, stucco, or concrete), a vehicle (such as a window, tyre, vehicle body, or vehicle interior), a plant (such as a seed), a solid agrochemical composition, or a non-household fibrous substrate. The surface may be selected from the surface of an extruded product (such as a pellet, granule, or film), a mould, paper packaging, a construction material (such as plasterboard, gypsum, stucco, or concrete), a plant (such as a seed), or a solid agrochemical composition. The use of the first aspect and the method of the second aspect may provide a surface of an extruded product or a precursor thereof with reduced friction. The extruded product or the precursor thereof may be treated with the polymer defined herein during manufacture of the extruded product. By “precursor” of the extruded product, we mean the extruded product prior to extrusion. Suitably, the precursor of the extruded product is treated with the polymer defined herein prior to extrusion of the precursor. The reduced friction of the surface of the precursor may facilitate the extrusion process, for example by providing better handling and better cleaning due to reduced residue on the extrusion equipment. The extruded product may be a pellet, a granule, or a film. The extruded product may be a plastic film. The plastic film may form part of, or be suitable for manufacturing, plastic bags or packaging. The surface of the plastic film may be treated with the polymer defined herein during manufacture of the plastic film, and / or manufacture of plastic bags or packaging from the plastic film. By “manufacture of packaging” we mean to refer to the formation of the components of the packaging or the assembly of the packaging. The reduced friction of the surface of the plastic film reduces friction between the surface of the plastic film and other surfaces of the plastic film, between the surface of the plastic film and surfaces of other plastic films, and / or between the surface of the plastic film and manufacturing equipment. This may advantageously improve the movement of the plastic film through a manufacturing line (for example an extrusion line) or a packaging line, by causing the plastic film to slide more easily. The use of the first aspect may be the use of the polymer as defined herein as a slip additive. The plastic film may comprise any suitable polymeric material, such as polyethylene or polypropylene. The polyethylene may be selected from very low density polyethylene, linear low density polyethylene, low density polyethylene, medium density polyethylene, high density polyethylene, or ultra-high molecular weight polyethylene. Preferably, the polymeric material is prepared from vinyl monomers, especially alpha olefins such as ethylene or propylene. The use of the first aspect and the method of the second aspect may provide a surface of a mould with reduced friction. The mould may be for the manufacture of moulded objects. An internal surface of the mould (preferably, a surface that will be in contact with a moulded object) is treated with the polymer defined herein. The reduced friction of the surface of the mould may advantageously prevent sticking of a moulded object in the mould and facilitate removal of the moulded object from the mould. The use of the first aspect and the method of the second aspect may provide a surface of a nonhousehold building with increased water repellency, reduced friction, and / or improved visual appearance. By non-household building we mean a building that is not a home. Examples of suitable non-household buildings include commercial buildings (such as offices, shops, restaurants, and hotels), institutional buildings (such as schools and hospitals), and industrial buildings (such as factories and warehouses). The surface may be an exterior surface or an interior surface of the building. The surface of the building may be selected from a surface of a wall, a window, a floor, or a ceiling. The use of the first aspect and the method of the second aspect may provide a surface of a wall, floor, or ceiling of a non-household building with increased water repellency, reduced friction, and / or improved visual appearance. Increasing the water repellency and / or reducing the friction of the surface of the wall, floor, or ceiling may prevent dust or dirt from adhering to the surface, facilitate cleaning of the surface, and / or reduce the formation of streaks on the surface. When the wall, floor, or ceiling is painted, the colour intensity of wall, floor, or ceiling may be increased. When the wall, floor, or ceiling is treated with the polymer as disclosed herein, paint may be more easily and / or evenly applied to the treated wall, floor or ceiling. The use of the first aspect and the method of the second aspect may provide a surface of a window of a non-household building with increased water repellency and / or reduced friction. Increasing the water repellency and / or reducing the friction of the surface of the window may prevent dust or dirt from adhering to the window, facilitate cleaning of the window, shorten drying times, reduce the formation of streaks on the window, provide the window with an anti-fingerprint effect, and / or provide the window with an antifogging effect. The use of the first aspect and the method of the second aspect may provide a surface of a paper-based material with increased water repellency. Examples suitable of paper-based materials include paper and cardboard. Paper-based materials are typically vulnerable to damage from exposure to water or moisture. Therefore, increasing the water repellency of a surface of a paper-based material may advantageously increase the lifetime of the underlying paper-based material. The surface of the paper-based material may be the surface of paperbased packaging (for example packaging comprising paper or cardboard). The use of the first aspect and the method of the second aspect may provide a surface of a construction material with increased water repellency. The construction material may be plasterboard, gypsum, stucco, or concrete. The construction material is preferably plasterboard, gypsum, or stucco, further preferably plasterboard or gypsum. Plasterboard is typically a panel of gypsum between two sheets of paper, and may be prepared by feeding a foamed slurry of stucco (calcined gypsum) and water between two sheets of paper. Both paper and gypsum are typically vulnerable to damage from exposure to water (including recycled water) or moisture. Therefore, increasing the water repellency of the paper sheets and / or the gypsum in plasterboard may increase the lifespan of the plasterboard and allow the use of recycled water. The polymer as defined herein may be coated on a surface of plasterboard or gypsum. Alternatively, the polymer may be admixed into a slurry of stucco and water as an additive during the production of plasterboard or gypsum. For example, the method of the second aspect may comprise admixing the polymer into a slurry comprising water and stucco or gypsum. The method may further comprise drying the slurry to form gypsum. The polymer may be present in the bulk of the gypsum and / or at the surface of the gypsum produced in this way. The polymer is suitably present at the surface of the gypsum. The method may provide a construction material (and not just a surface thereof) with increased water repellency. The polymer preferably used to treat (for example, the surface of) the construction material (for example, by admixing into a slurry of water and stucco or gypsum) is preferably the reaction product of monomers comprising, consisting essentially of, or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a dicarboxylic acid or an acid chloride or ester thereof; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Preferably, the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group). The use of the first aspect and the method of the second aspect may provide a surface of a vehicle with increased water repellency, reduced friction, and / or improved visual appearance. The surface may be an exterior surface or an interior surface of the vehicle. The vehicle may be selected from a road vehicle, a water vehicle, or an air vehicle. Preferably the vehicle is a road vehicle, such as a car. The surface of the vehicle may be selected from a surface of a window, a tyre, a vehicle body, or a vehicle interior. The use of the first aspect and the method of the second aspect may provide a surface of a vehicle window with increased water repellency and / or reduced friction. Increasing the water repellency and / or reducing the friction of the surface of the window may prevent dust or dirt from adhering to the window, facilitate cleaning of the window, shorten drying times, reduce the formation of streaks on the window, provide the window with an anti-fingerprint effect, and / or provide the window with an antifogging effect. The use of the first aspect and the method of the second aspect may provide a surface of a tyre with increased water repellency and / or improved visual appearance. The tyre is suitably the tyre of a road vehicle such as a car. Increasing the water repellency and / or shine of the surface of the tyre may improve the appearance of the tyre, increase the durability of the tyre, reduce build up of undesirable particles (such as dirt) on the tyre, and / or reduce degradation of other components of the vehicle, such as wear brakes. The use of the first aspect and the method of the second aspect may provide a surface of a vehicle body with increased water repellency, reduced friction, and / or improved visual appearance. The surface of the vehicle body is suitably an exterior surface of the vehicle body. The vehicle body suitably comprises coated metal. The vehicle body may be a car body. Increasing the water repellency and / or reducing the friction of the surface of the vehicle body may prevent dust or dirt from adhering to the body, facilitate cleaning of the body, shorten drying times, reduce the formation of streaks on the body, facilitate water sheeting and beading, and / or provide the body with rain resistance. The use of the first aspect and the method of the second aspect may provide a surface of a vehicle interior with increased water repellency, reduced friction, improved visual appearance, and / or an antistatic effect. The vehicle interior may be interior plastic trim or leather. Increasing the water repellency and / or reducing the friction of the surface of the vehicle interior may improve the dirt resistance and facilitate cleaning of the surface. Reducing the friction of a leather surface in the vehicle interior may increase the softness thereof. The use of the first aspect and the method of the second aspect may provide leather (or a surface thereof) with increased softness and / or flexibility. This may be the result of reduced friction. The use of the first aspect and the method of the second aspect may provide a surface of a seed with increased water repellency and / or reduced friction. By “seed” we mean a plant seed. Increasing the water repellency of the surface of a seed may increase the length of time the seed may be stored before planting. Reducing the friction of the surface of a seed may improve the flow characteristics of the seed during plantation, in particular when a plurality of such seeds are being planted. The polymer used to treat the surface of the seed is preferably the reaction product of monomers comprising, consisting essentially of, or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a dicarboxylic acid or an acid chloride or ester thereof; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Preferably, the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group). The use of the first aspect and the method of the second aspect may provide a surface of a solid agrochemical composition with increased water repellency. The solid agrochemical composition may be in the form of pellets or granules. The solid agrochemical composition may be applied to the surface of a crop, such as a leaf, stem or root. The solid agrochemical composition may be a pesticide composition. Increasing the water repellency the surface of the solid agrochemical composition may advantageously slow the release of active ingredients (such as pesticides) from the solid agrochemical composition into soil, allowing the agrochemical composition to be effective for a longer period of time. The polymer used to treat the surface of a solid agrochemical composition is preferably the reaction product of monomers comprising, consisting essentially of, or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a dicarboxylic acid or an acid chloride or ester thereof; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Preferably, the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group). The use of the first aspect and the method of the second aspect may provide a surface of a nonhousehold fibrous substrate with reduced friction. By non-household fibrous substrate we mean a fibrous substrate that is not in the home. In other words, the fibrous substrate is treated with a polymer as defined herein outside of a household setting. The fibrous substrate is preferably treated with the polymer in an industrial setting. Suitably, the fibrous substrate is a thread. The thread may be formed from a natural fibre, such as cotton, or a synthetic fibre, such as polyester. The thread may be a cotton, denim or polyester thread (preferably a cotton or denim thread). The use of the first aspect and the method of the second aspect may provide improved lubrication of the thread outside of a household setting, for example in textile manufacturing. The use of the first aspect may therefore provide the use of a polymer as defined herein as a lubricant for a thread in textile manufacturing. Lubrication of threads in textile manufacturing may advantageously reduce damage to the threads and reduce wear and tear to industrial textile manufacturing equipment in contact with the threads. Suitably, the polymer defined herein may be coated on a surface of the thread and / or on a surface of industrial textile manufacturing equipment in contact with the thread. The polymer used to treat the surface of the non-household fibrous substrate (for example, the surface of the thread) is preferably the reaction product of monomers comprising, consisting essentially of, or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a dicarboxylic acid or an acid chloride or ester thereof; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). The polymer as preferably used herein may be formulated as a component of a composition. In other words, the polymer may be comprised in a composition. Thus, in the use or method of the first or second aspect, the polymer may be comprised in a composition. Suitably, the polymer may be comprised in a composition, wherein the composition additionally comprises at least one solvent and optionally one or more surfactants. In the use or method of the first or second aspect, the polymer may be comprised in a composition, wherein the composition additionally comprises at least one solvent and one or more surfactants. The one or more surfactants may be selected from anionic surfactants, cationic surfactants, non-ionic surfactants, and amphoteric or zwitterionic surfactants. Preferably, the one or more surfactants may be independently selected from one or more of a fatty alkyl amphoacetate, an alkyl (poly)glycoside, an acyl glycinate, a sulfosuccinate, an amphodiacetate and a fatty alcohol ether carboxylate. The composition may comprise at least 0.1 wt%, at least 0.5 wt%, at least 1 wt%, at least 2 wt%, at least 5 wt%, or at least 10 wt% of the polymer. The composition may comprise 80 wt% or less, such as 20 wt% or less, for example 10 wt% or less of the polymer. The composition may comprise from 0.1 to 20 wt%, preferably from 0.1 to 10 wt%, for example from 0.5 to 5 wt% of the polymer. The composition may comprise at least 20 wt%, such as at least 30 wt%, at least 40 wt%, at least 50 wt%, at least 60 wt%, at least 70 wt%, or at least 80 wt% of the polymer. The composition may comprise 100 wt% or less, 99 wt% or less, such as 95 wt% or less, for example 90 wt% or less of the polymer. The composition may comprise from 10 to 100 wt%, such as from 10 to 99 wt%, preferably from 20 to 95 wt%, for example from 50 to 90 wt% of the polymer. References herein to the amount of polymer in the composition are intended to refer to the total of the or each polymer as defined herein that is included in the composition. According to a third aspect of the invention, there is provided a composition for treating a surface that is not a surface of a home care substrate, wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance, and wherein the composition comprises one or more nitrogen containing compounds, wherein the or each nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group. According to the third aspect of the invention, there may be provided a composition for treating a surface that is not a surface of a home care substrate, wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance, and wherein the composition comprises one or more polymers, wherein the or each polymer is the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is a polycarboxylic acid or a reactive equivalent thereof and the or each second monomer is a polyfunctional monomer having at least one reactive amino group. The composition is suitable for treating a surface that is not a surface of a home care substrate to provide at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance of the surface. The nitrogen containing compound (preferably the polymer) referred to in relation to the third aspect may comprise the reaction product of reactants (preferably monomers) comprising one or more first reactants (preferably first monomers), one or more second reactants (preferably second monomers) and optionally one or more third reactants (preferably third monomers) as defined herein. The nitrogen containing compound (preferably the polymer) referred to in relation to the third aspect may be the reaction product of reactants (preferably monomers) consisting of one or more first reactants (preferably first monomers), one or more second reactants (preferably second monomers) and optionally one or more third reactants (preferably third monomers) as defined herein. Features of the nitrogen containing compound (preferably the polymer), and of the first and second reactants (and the third reactants when present) (preferably the first, second, and third monomers, respectively), in relation to the third aspect of the invention are as set out herein in relation to the first and second aspects of the invention. In particular, the nitrogen containing compound is preferably a polymer. The reactants are preferably monomers. The one or more first reactants are preferably one or more first monomers, the one or more second reactants are preferably one or more second monomers, and the polyfunctional reactant is preferably a polyfunctional monomer having at least one reactive amino group. The composition of the third aspect may comprise at least 0.1 wt%, at least 0.5 wt%, at least 1 wt%, at least 2 wt%, or at least 5 wt% of the one or more polymers. The composition may comprise 80 wt% or less, such as 20 wt% or less, for example 10 wt% or less of the one or more polymers. The composition may comprise from 0.1 to 20 wt%, preferably from 0.1 to 10 wt%, for example from 0.5 to 5 wt% of the one or more polymers. The composition of the third aspect may comprise at least 20 wt%, such as at least 30 wt%, at least 40 wt%, at least 50 wt%, at least 60 wt%, at least 70 wt%, or at least 80 wt% of one or more polymers. The composition of the third aspect may comprise 100 wt% or less, such as 99 wt% or less, such as 95 wt% or less, for example 90 wt% or less of the one or more polymers. The composition of the third aspect may comprise from 10 to 100 wt%, such as from 10 to 99 wt%, preferably from 20 to 95 wt%, for example from 50 to 90 wt% of the one or more polymers. The composition of the third aspect may comprise any suitable solvent, such as for example a polar solvent, such as a polar protic solvent. The solvent may be an aqueous solvent. Thus, the composition may be an aqueous composition. The term “aqueous solvent” herein is considered to mean water or mixtures of water and at least one water miscible solvent. Water miscible solvents may include alcohols and substantially water-miscible organic solvents. The solvent may be a non-aqueous solvent. The non-aqueous solvent suitably comprises an organic solvent, such as an alcohol. The non-aqueous solvent preferably does not comprise any surfactant. Suitable such alcohols for use in the solvent include monohydric alcohols, polyhydric alcohols, alkoxy alcohols and aryloxy alcohol. Suitable alcohols are monohydric alcohols, polyhydric alcohols and alkoxy alcohols. Preferred alcohols are miscible with water. Suitable simple monohydric alcohols include methanol, ethanol, isopropanol and butanol. The solvent may comprise a polyhydric alcohol or an alkoxyalcohol. Suitable alkoxy alcohols include diethylene glycol monobutyl ether, 3-methoxy-3-methyl-1-butanol and 2-butoxyethanol. Suitable aryloxy alcohols include 2-phenoxyethanol. Suitable polyhydric alcohols include glycerol, ethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol and 2-methylpentanediol. Suitable polyhydric alcohols include glycerol, ethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol and polypropylene glycol. Preferably, the non-aqueous solvent comprises a monohydric alcohol such as isopropanol. The composition of the third aspect may additionally comprise one or more surfactants (in particular when the solvent is an aqueous solvent). Any suitable surfactant(s) may be included, such as for example one or more surfactants selected from anionic surfactants, cationic surfactants, non-ionic surfactants, and amphoteric or zwitterionic surfactants. The composition may comprise an anionic surfactant. Suitable anionic surfactants may include sulfate surfactants (such as mono- or di-alkyl sulfates or alkyl ether sulfates), sulfonate surfactants, alkyl ether carboxylate surfactants, sarcosinate surfactants, phosphate surfactants, succinate surfactants, sulfosuccinate surfactants, sulfoacetate surfactants, isethionate surfactants, taurate surfactants, amino acid surfactants such as glutamates and glycinates, lactylate surfactants, and fatty acid salts. Particularly exemplary salts of the above, where applicable, are the sodium, potassium, ammonium, magnesium and triethanolamine salts. The composition may comprise a cationic surfactant. The cationic surfactant may be an ammonium salt such as an alkyl trimethyl ammonium salt, a dialkyl dimethyl ammonium salt, an alkyl-(N-hydroxyethyl)-dimethyl ammonium salt, or an alkyldimethylbenzylammonium salt (i.e. a benzalkonium salt). The salt may be a halide, hydroxide, sulfate, hydrogensulfate, phosphate, or carboxylate salt. The salt is suitably a halide salt, such as a fluoride, chloride, or bromide salt. The salt may be a carboxylate salt, such as formate or acetate salt. Preferably, the salt is chloride. The composition may comprise a non-ionic surfactant. Suitable non-ionic surfactants for use herein include alcohol alkoxylates (such as alcohol ethoxylates, alcohol propoxylates, and ethylene oxide / propylene oxide copolymer derived surfactants), aliphatic esters, aromatic esters, sugar esters (such as sorbitan esters), alkyl (poly)glycosides, fatty acid alkoxylates (such as fatty acid ethoxylates and fatty acid propoxylates), or polyethylene glycol esters (including partial esters), glycerol esters (including glycerol partial esters and glycerol triesters), fatty alcohols (such as cetearyl alcohol, lauryl alcohol, stearyl alcohol, behenyl alcohol), and alkanolamides. The composition may comprise an amphoteric or zwitterionic surfactant. The amphoteric or zwitterionic surfactant may be selected from betaines (such as alkyl betaines and alkylamidopropyl betaines), amphoacetates, diamphoacetates, and amine oxides (such as alkylamine oxides and alkylamidopropyl amine oxides). Suitable amphoteric or zwitterionic surfactants include lauryl betaine, cocamidopropyl betaine, sodium lauroamphoacetate, sodium cocoamphoacetate, disodium cocoamphodiacetate, lauramine oxide, C12-18 alkyldimethylamine oxide, myristamine oxide, and cocamidopropyl amine oxide. The one or more surfactants may be selected from a fatty alkyl amphoacetate (for example cocoyl amphoacetate, lauryl amphoacetate), an alkyl (poly)glycoside (for example lauryl glycoside), an acyl glycinate (for example cocoyl glycinate), a sulfosuccinate, an amphodiacetate and a fatty alcohol ether carboxylate (for example C8-12 alkyl ether (6-11 moles EO) carboxylate). The composition of the third aspect may comprise the one or more surfactants in an amount of from 1 to 100 wt%, suitably from 5 to 50 wt%, preferably from 10 to 25 wt% based on the total weight of the one or more polymers. The composition may comprise the one or more surfactants in an amount of from 0.1 to 99 wt%, suitably from 1 to 50 wt%, for example from 10 to 25 wt% or from 0.1 to 20 wt% based on the total weight of the composition. The composition referred to in relation to the first and second aspects of the invention may be a composition according to the third aspect of the invention. Suitably the composition of the third aspect is substantially free of silicon atoms. By substantially free of silicon atoms we mean that the composition contains less than 1 wt%, preferably less than 0.5 wt%, of silicon in the composition. More preferably, the composition is free of silicon atoms, by which we mean that it is not possible to detect silicon in the composition. Suitable methods of measuring the amount of silicon in a composition are well known to those skilled in art and include elemental analysis and inductively coupled plasma (ICP) spectroscopy. According to a fourth aspect of the invention, there is provided a substrate that is not a home care substrate, wherein a surface of the substrate is treated with a nitrogen containing compound, wherein the nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group. According to the fourth aspect of the invention, there may be provided a substrate that is not a home care substrate, wherein a surface of the substrate is treated with a polymer, wherein the polymer is the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is a polycarboxylic acid or a reactive equivalent thereof and the or each second monomer is a polyfunctional monomer having at least one reactive amino group. The substrate that has been treated with the nitrogen containing compound (preferably the polymer) is suitably provided with at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance of the surface, compared to a substrate that has not been treated with the nitrogen containing compound (or polymer). The nitrogen containing compound (preferably the polymer) referred to in relation to the fourth aspect may comprise the reaction product of reactants (preferably monomers) comprising one or more first reactants (preferably first monomers), one or more second reactants (preferably second monomers) and optionally one or more third reactants (preferably third monomers) as defined herein. The nitrogen containing compound (preferably the polymer) referred to in relation to the fourth aspect may be the reaction product of reactants (preferably monomers) consisting of one or more first reactants (preferably first monomers), one or more second reactants (preferably second monomers) and optionally one or more third reactants (preferably second monomers) as defined herein. Features of the substrate, the nitrogen containing compound (preferably the polymer), and of the first and second reactants (and the third reactants when present) (preferably the first, second, and third monomers, respectively), in relation to the fourth aspect of the invention are as set out herein in relation to the first and second aspects of the invention. In particular, the nitrogen containing compound is preferably a polymer. The reactants are preferably monomers. The one or more first reactants are preferably one or more first monomers, the one or more second reactants are preferably one or more second monomers, and the polyfunctional reactant is preferably a polyfunctional monomer having at least one reactive amino group. The polymer as preferably used in the fourth aspect may be formulated as a component of a composition. In other words, the substrate ofthe fourth aspect may be treated with a composition comprising the polymer. Suitably, the polymer may be comprised in a composition, wherein the composition additionally comprises at least one solvent and optionally one or more surfactants. The composition referred to in relation to the fourth aspect ofthe invention may be a composition according to the third aspect ofthe invention. The substrate may be selected from a construction material or a seed. The substrate may be a construction material. The construction material may be plasterboard, gypsum, stucco, or concrete. Preferably, the construction material is gypsum or plasterboard, further preferably plasterboard. Plasterboard typically comprises a gypsum core disposed between two sheets of paper. The polymer as defined herein may be present at a surface ofthe gypsum core and / or the sheets of paper. The polymer may further be present within the gypsum core. This may be achieved by admixing the polymer into a slurry of stucco and water as an additive during the production ofthe plasterboard. The polymer with which (for example, the surface of) the construction material is preferably treated (for example, by admixing into a slurry of water and stucco or gypsum) is preferably the reaction product of monomers comprising, consisting essentially of, or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a dicarboxylic acid or an acid chloride or ester thereof; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Preferably, the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group). The substrate may be a seed. By “seed” we mean a plant seed. A surface of the seed is suitably treated with the polymer as defined herein. The polymer with which the surface of the seed is preferably treated is preferably the reaction product of monomers comprising, consisting essentially of, or consisting of one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group) and a dicarboxylic acid or an acid chloride or ester thereof; and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)). Preferably, the or each first monomer is one or more of a cyclic anhydride of formula (I) wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group). Examples The invention will now be further described with reference to the following non-limiting examples. Example 1 - synthesis of polymers containing both ester and amide groups The polycarboxylic acid or anhydride (monomer 1) were combined with the amine-containing monomer (monomer 2). Tin(ll) ethylhexanoate (0.5 wt% relative to the total weight of monomers) was added. The reaction mass was heated at 160°C for 6 hours. The resulting polymer was decanted from the reaction flask, and no further purification was carried out. Polymers 1 to 3 were prepared according to Example 1, using the monomers and reaction stoichiometries as set out in Table 1. Example 2 - synthesis of polyamides The polycarboxylic acid or anhydride (monomer 1) were combined with the amine-containing monomer (monomer 2) and heated at 225°C for 6 hours. The resulting polyamide was decanted from the reaction flask. No further purification was carried out. 5 Polyamides 4 to 19 were prepared according to Example 2, using the monomers and reaction stoichiometries as set out in Table 1. Table 1 Polymer Monomer 1 (Polycarboxylic acid or cyclic anhydride) Monomer 2 (amine) Molar ratio of monomers 1 Sebacic acid Diethanolamine 1 : 1 2 Pimelic acid Diethanolamine 1 : 1 3 Octadecenyl succinic anhydride Diethanolamine 1 : 1 4 Dodecanedioic acid Jeffamine ED-2003 1 : 1 5 Nonenyl succinic anhydride Jeffamine ED-2003 1 : 1 6 (2-Dodecen-1 -yl)succinic anhydride Jeffamine ED-2003 1 : 1 7 Octadecenyl succinic anhydride Jeffamine ED-2003 1 : 1 8 C20-24 ASA Jeffamine ED-2003 1 : 1 9 (2-Dodecen-1 -yl)succinic anhydride Jeffamine ED-600 1 : 1 10 (2-Dodecen-1 -yl)succinic anhydride Trimethyl-1,6-hexanediamine 1 : 1 11 Hydrogenated dimer acid Jeffamine ED-600 1 : 1 12 Nonenyl succinic anhydride Poly(propylene glycol) bis(aminopropyl)ether Mw~230 Da 1 : 1 13 (2-Dodecen-1 -yl)succinic anhydride Poly(propylene glycol) bis(aminopropyl)ether Mw~230 Da 1 : 1 14 Octadecenyl succinic anhydride Poly(propylene glycol) bis(aminopropyl)ether Mw~230 Da 1 : 1 15 Hydrogenated dimer acid Poly(propylene glycol) bis(aminopropyl)ether Mw~230 Da 1 : 1 16 Octadecenyl succinic anhydride Isophorone diamine 1 : 1 17 Nonenyl succinic anhydride Jeffamine ED-600 1 : 1 18 Hydrogenated dimer acid Jeffamine ED-2003 1 : 1 19 (2-Dodecen-1 -yl)succinic anhydride Jeffamine ED-900 1 : 1 Table 2 - abbreviations and chemical names C20-24 ASA C20-C24 alkenyl succinic anhydride Jeffamine ED-2003 Polyether diamine comprising ethylene oxide and propylene oxide derived repeat units and having Mn ~ 2,000. Commercially available from Huntsman Corporation (Texas, United States) Jeffamine ED-600 Polyether diamine having Mn ~ 600 as defined herein. Commercially available from Huntsman Corporation (Texas, United States) Jeffamine ED-900 Polyether diamine having Mn ~ 900 as defined herein. Commercially available from Huntsman Corporation (Texas, United States) Example 3 - Preparation of gypsum cubes A series of gypsum slurry compositions were prepared by admixing 438.25 grams of commercial gypsum for plaster, 318.95 grams of water, and 21.91 grams of a polymer as shown in Table 3. Each slurry composition was poured into separate cube moulds, which were then left at room temperature to solidify. The gypsum cubes were demoulded on the next day and kept at 60°C overnight to dry. Each composition was sufficient to provide three moulded gypsum cubes. Table 3 Composition Polymer 1 Polymer 9 2 Polymer 19 3 Polymer 5 4 Polymer 4 A blank composition was prepared by following the process of Example 3, but without any polymer. Example 4 - Performance test Each of the gypsum cubes prepared in Example 3 were weighed and then immersed in water for 5 minutes. The gypsum cubes were removed from the water and were suspended in air for 1 minute to let excess water drip. Each cube was then weighed, and the water uptake (%) was calculated using the following formula : (weight after immersion) — (weight before immersion) Water uptake (%) =-----------------—■— ------------------------ weight before immersion Table 4 shows the average results from three repetitions (cubes) for each composition. Table 4 Composition Water uptake (%) Difference compared to blank (%) Blank 1 37 N / A 1 20 -17 Blank 2 39 N / A 2 14.5 -24.5 3 18.5 -20.5 4 26.9 -12.1 Compositions 1 to 4 have a water uptake that is lower than that of the corresponding blanks, demonstrating the hydrophobic effect imparted to the gypsum composition when the polymer is used. Example 5 - Coefficient of friction test The dynamic coefficient of friction (COF dn) measures the resistance to movement between two surfaces. It is the force needed to maintain the movement after it has begun. Dynamic coefficient of friction (COF dn) was measured for three different substrates (cotton, denim and polyester) using a COF-21 Friction and Peel Tester (Regmed, Brazil) with the following parameters: Test Unit: N Sled mass: 200.0 g Test Speed: 150.0 Dynamic distance: 130mm Statistic: yes Chart Scale: 2.5 N The test polymers were dissolved in ethanol at a concentration of 20 wt%. 5 mL of each ethanol solution was applied to the fibrous substrate using a hand roller. The substrates were allowed to dry overnight at ambient temperature before measuring COF dn. The measurements were compared to control samples where the fibrous substrate had not been treated with the polymer, and the percentage change in COF dn was calculated. The results are shown in Table 5. A negative percentage value indicates a reduction in COF dn due to the presence of the polymer on the fibrous substrate. Table 5 Polymer Change in COF dn compared to control (%) Cotton Denim Polyester 5 -30 -11 -12 18 -27 -6 -10 Example 6 - Seed flow test Seed treatment slurry A was prepared having the following composition: Seed Treatment slurry A Component Amount (wt%) Comment Pesticide 0 Pigment 12.5 Pigment was Red 48:2 (35 wt% dispersion in water) Coating 37.5 Carnauba wax-based emulsion Polymer 2.5 Water to 100 Commercial corn seeds (Viking 99-00 hybrid, 100 g) were mixed with seed treatment slurry A (1 mL) and stood at ambient temperature and relative humidity (RH) 50 % for 5 minutes. The treated seeds were transferred to a stainless steel funnel with an opening of 30 mm diameter and a stoppered outlet. The stopper was removed and the time taken for the funnel contents to empty was recorded. The control for each test was a seed treatment slurry equivalent to A but without the specified polymer. Where the time taken for the funnel to empty was lower when using the additized seed treatment slurry, compared to the control, this was considered to be a “pass”. In other words, the polymer was providing a lubricating effect to the treated seeds and enabling faster flow. The results are shown in Table 6 below. Table 6 Polymer Performance in seed flow test 5 Pass 12 Pass 14 Pass Example 7 - Leather softness test The effect of an specified polymer was assessed in the fatliquoring step of leather manufacture. The purpose of the fatliquoring step is to add oils and fats to tanned leather hides, to make the final leather soft, flexible and durable. The polymer used was polymer 5. The polymer was tested at two different concentrations, in combination with two different commercially available products which are commonly used in the leather fatliquoring process. These are summarized in Table 7. Table 7 Fatliquoring Product Name Description Manufacturer A TANSOFTY HPL Soy lecithin based formulation, also comprising anionic surfactants Innospec Brazil B TANSOFTY HSP Sulfosuccinamate based formulation, also comprising other anionic surfactants Innospec Brazil Tests were carried out on “wet-blue” (tanned) leather pieces of size 10 cm x 30 cm and thickness 10-12 mm, using a laboratory drum apparatus operating at a spin speed of 30 rpm. The leather pieces were initially neutralized using an aqueous solution of sodium formate (2 wt%) and sodium bicarbonate (1 wt%) which was spun for 60 minutes in the laboratory drum. The neutralization liquid was discharged and replaced with the fatliquoring solution which consisted of a 10 wt% aqueous solution of product A or B in water, additionally containing the specified polymer (0.5 wt% or 1 wt% relative to the total amount of diluted fatliquoring solution). The leather pieces were spun for a further 60 minutes, before adding formic acid (0.8 wt%) and spinning for a further 20 minutes. The leather pieces were removed from the laboratory drum, excess water was removed and then the leather pieces were allowed to dry at ambient temperature. The leather softness was qualitatively assessed by feel (softness and touch) and also by draping the leather pieces over the side of a table. For both fatliquoring products (A and B) and at both treat levels of the specified polymer (0.5 wt% and 1 wt%) the leather pieces were found to be softer and more flexible (malleable) relative to samples prepared identically but in the absence of the polymer. Example 8 - Preparation of substrates and compositions for use in evaluation of improvement of shine, friction reduction and water repellency (Examples 9 to 11) Prior to treatment with polymers and evaluation of the resulting properties (reduced friction, water repellency, improved visual appearance) the substrates used in the experiments were prepared as shown in Table 8. Table 8 Substrate Preparation method Exterior car panel (painted metal) UV - ozone cleaning, 10 minutes Interior car panel (plastic) Cotton calico Used as obtained Denim Velour Boiled wool Black card (smooth, 250GSM) Leather The specified polymers were deposited on the test substrates as composition types as shown in Table 9. Table 9 Composition type Description X Emulsion containing polymer (1wt%), sodium lauroamphoacetate (0.2wt%)*, ethanol (5wt%)** and water to 100wt% Y Solution of polymer (1wt%) in ethanol * of a 25 wt% aqueous solution ** ethanol was only added if the polymer was not miscible in a solution of sodium lauroamphoacetate (0.2 wt%) in water The prepared substrates and composition types were used in Examples 9 to 11. Example 9 - Shine improvement test Shine improvement was determined by spraying a 1wt% active solution of the polymer (composition type X) onto the substrate and visually observing the surface of the substrate after drying. The visual observation was compared to the untreated substrate. A “pass” result indicates that a visual improvement in shine was observed for the polymer-treated substrate. The results are shown in Table 10. Table 10 Substrate Polymer Result Leather 4 Pass Leather 18 Pass Example 10 - Friction reduction test Substrates, which were initially prepared according to Table 8 prior to treatment, were treated by applying a liquid composition containing 1wt% of the polymer. For cotton and denim substrates, these were treated by soaking for 1 hour (composition type X). Excess liquid was removed. The substrates were dried (60°C) then cooled to ambient temperature before running the friction test. For black card, this was sprayed with the polymer composition (composition type Y) and left to dry at ambient temperature before running the friction test. For leather substrates, these were treated by spraying with the polymer composition (composition type X) and allowing to dry at ambient temperature prior to running the friction test. For the friction test, a weighted block (250g) having baize fabric attached to its surface was then rubbed across the treated substrate. The results were observed relative to an untreated substrate. Each test was repeated twice, with two different (independent) operators. A “pass” result indicates that both operators recorded lower friction for the treated substrate, compared to the untreated substrate. The results are shown in Table 11. Table 11 Substrate Polymer Result Denim 6 Pass Denim 2 Pass Denim 18 Pass Cotton calico 2 Pass Cotton calico 4 Pass Cotton calico 18 Pass Black Card 2 Pass Leather 2 Pass Leather 4 Pass Example 11 - Water repellency test Substrates, which were initially prepared according to Table 8 prior to treatment, were treated by applying a liquid composition of type X or Y. For exterior car panel (painted metal) and interior car panel (plastic rim) substrates a 1wt% solution of the polymer was sprayed onto the surface (composition type X) and the surface was buffed using a Car Buffer Polisher with a microfibre cloth attachment before carrying out the droplet test. For velour substrates, these were treated by spraying with the polymer composition (composition type X) and allowing to dry at ambient temperature prior to carrying out the droplet test. For boiled wool substrates, these were treated by soaking for 1 hour (composition type X). Excess liquid was removed. The substrates were dried (60°C) then cooled to ambient temperature before carrying out the droplet test. Other substrate types were treated as already described above in examples 9 and 10. For the droplet test, after drying, the initial shape and absorption time of a de-ionized water droplet dropped on the treated surface was visually inspected. The results were observed relative to a substrate treated with an identical composition other than the polymer being absent. A “pass” result indicates that the water droplet did not absorb into the substrate or was absorbed at a much lower speed than the comparative tests. For non absorbent substrates the spreading behaviour of the water droplet was visually compared to that on an identically treated surface, other than the polymer being absent. A “pass” result indicated less droplet spreading on the polymer treated surface relative to the comparative tests. The results are shown in Table 12. Table 12 Substrate Polymer Result Exterior Car Panel (painted metal) 18 Pass Interior Car Panel (Plastic) 18 Pass Velour 18 Pass Cotton calico 18 Pass Boiled wool 18 Pass Black Card 18 Pass Leather 18 Pass Unless otherwise stated herein, the reference to “liquid”, “gel” and “solid” refer to a state at 25 °C and standard pressure (101,325 Pa). Attention is directed to all papers and documents which are filed concurrently with or previous to this specification in connection with this application and which are open to public inspection with this specification, and the contents of all such papers and documents are incorporated herein by reference. All of the features disclosed in this specification (including any accompanying claims, and drawings), and / or all of the steps of any method or process so disclosed, may be combined in any combination, except combinations where at least some of such features and / or steps are mutually exclusive. Each feature disclosed in this specification (including any accompanying claims, and drawings) may be replaced by alternative features serving the same, equivalent or similar purpose, unless expressly stated otherwise. Thus, unless expressly stated otherwise, each feature disclosed is one example only of a generic series of equivalent or similar features. The invention is not restricted to the details of the foregoing embodiment(s). The invention extends to any novel one, or any novel combination, of the features disclosed in this specification (including any accompanying claims, and drawings), or to any novel one, or any novel combination, of the steps of any method or process so disclosed.
Claims
1. A use of a nitrogen containing compound to treat a surface, wherein the surface is not a surface of a home care substrate and wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance; and wherein the nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group.
2. A method of treating a surface, wherein the surface is not a surface of a home care substrate and wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance, the method comprising contacting the surface with a nitrogen containing compound, wherein the nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group.
3. The use or method according to claim 1 or claim 2, wherein the nitrogen containing compound is a polymer, the reactants are monomers, the one or more first reactants are one or more first monomers, the one or more second reactants are one or more second monomers, and the polyfunctional reactant is a polyfunctional monomer having at least one reactive amino group.
4. The use or method according to claim 4, wherein the polymer is a polyamide.
5. The use or method according to claim 3 or claim 4, wherein the or each first monomer isa cyclic anhydride selected from one or more of formula (I), of formula (II) and of formula (III):wherein in formula (I) R1 and R2 are each independently selected from hydrogen, an alkyl group and an alkenyl group, or R1 and R2 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group;in formula (II) R3 and R4 are each independently selected from hydrogen, an alkyl group and an alkenyl group, or R3 and R4 together with the carbon atoms to which they are attached represent an optionally substituted cyclic group; andin formula (III) X is CR9R10, O, S, or NR11; R5, R6, R7, R8, R9, R10, and R11 are each independently selected from hydrogen, an alkyl group and an alkenyl group, and / or any of R5, R6, R7, R8, R9, R10, and R11 together with the atoms to which they are attached represent an optionally substituted cyclic group; or a polycarboxylic acid or an acid chloride or ester thereof, wherein the polycarboxylic acid is selected from:a polycarboxylic acid of the formula HOOC(CR2)nCOOH, wherein n is from 0 to 30; and each R is independently hydrogen or a substituent; and / or two R groups on the same carbon atom are taken together to form a methylene (=CH2) group; and / or when n is two or more, two R groups on adjacent carbon atoms are taken together to form a double bond; and n is suitably from 1 to 20, preferably from 2 to 16, more preferably from 2 to 12, for example from 2 to 10;a polycarboxylic acid of the formula HOOC(CH2)mX1(CH2)m2COOH, wherein m+m2 is from 0 to 30 and X1 is O, S, or NR17 wherein R17 is hydrogen or a hydrocarbyl group;a polycarboxylic acid of the formula HOOCCH2(OCH2CHR18)xOCH2COOH, wherein x is from 1 to 30 and each R18 is independently hydrogen or a hydrocarbyl group;a polycarboxylic acid comprising a cyclic group; or a dimer acid.
6. The use or method any of claims 3 to 5, wherein the or each first monomer is a cyclic anhydride selected from one or more of succinic anhydride, maleic anhydride, glutaric anhydride, a Ce-30 alkenyl succinic anhydride such as C20-24 alkenyl succinic anhydride, dodecenyl succinic anhydride (such as (2-dodecen-1-yl)succinic anhydride), nonenyl succinic anhydride, octadecenyl succinic anhydride, octenyl succinic anhydride, octadecyl succinic anhydride, or octyl succinic anhydride, a branched alkenyl succinic anhydride such as tetrapropenyl succinic anhydride or polyisobutenyl succinic anhydride, phthalic anhydride, pyromellitic dianhydride, 1,2,4-benzenetricarboxylic anhydride, 1,2-cyclohexanedicarboxylic anhydride, 1,2-naphthalic anhydride, 2,3-naphthalic anhydride, 1,8-naphthalic anhydride and homophthalic anhydride; or a polycarboxylic acid or an acid chloride or ester thereof selected from oxalic acid, succinic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, maleic acid, malic acid, tartaric acid, citric acid, 1,4-cyclohexanedicarboxylic acid, isophthalic acid, terephthalic acid, diglycolic acid, thiodiglycolic acid, poly(ethylene glycol)bis(carboxymethyl) ether, a hydrogenated dimer acid or an acid chloride or ester thereof.
7. The use or method according to any of claims 3 to 6, wherein the or each first monomer is selected from one or more of sebacic acid, dodecanedioic acid, pimelic acid, hydrogenated dimer acid, nonenyl succinic anhydride, (2-dodecen-1-yl)succinic anhydride, octadecenyl succinic anhydride and C20-C24 alkenyl succinic anhydride.
8. The use or method according to any of claims 3 to 7, wherein the polyfunctional monomer comprises at least two reactive groups that reacts with the first monomer, wherein at least one of the reactive groups is the reactive amino group.
9. The use or method according to any of claims 3 to 8, wherein the polyfunctional monomer comprises at least two reactive amino groups.
10. The use or method according to any of claims 3 to 9, wherein the polyfunctional monomer is selected from ethanolamine, diethanolamine, ethylene diamine, coco propylene diamine, diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA), trimethyl-1,6-hexane diamine, isophorone diamine or a polyether diamine (preferably polypropylene glycol bis(aminopropyl) ether with MW around 230Da, Jeffamine ED-600, Jeffamine ED-900, or Jeffamine ED-2003).
11. The use or method according to any of claims 3 to 10, wherein the polyfunctional monomer is selected from ethylene diamine, coco propylene diamine, diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA), trimethyl-1,6-hexane diamine, isophorone diamine or a polyether diamine (preferably polypropylene glycol bis(aminopropyl) ether with MW around 230Da, Jeffamine ED-600, Jeffamine ED-900, or Jeffamine ED-2003).
12. The use or method according to any of claims 3 to 5 or 9 to 11, wherein the polymer is the reaction product of monomers comprising one or more first monomers and one or more second monomers, wherein the or each first monomer is one or more of a cyclic anhydride of formula (I)wherein one of R1 and R2 is hydrogen and the other is an alkenyl group (such as a Ca-24 alkenyl group); and wherein the or each second monomer is one or more polyether diamine (for example wherein the polyether backbone is selected from polyethylene glycol (PEG), polypropylene glycol (PPG), or a copolymer of polyethylene glycol (PEG) and polypropylene glycol (PPG)).
13. The use or method according to any of claims 3 to 12, wherein the polymer comprises at least 4 monomer units.
14. The use or method according to any of claims 3 to 12, wherein the polymer has a number average molecular weight of from 1,000 to 50,000 Daltons, preferably from 1,000 to 15,000 Daltons (for example from 2,000 to 7,000 Daltons).
15. The use or method according to any of claims 3 to 14, wherein the polymer is substantially free of silicon atoms.
16. The use or method according to any preceding claim, wherein the surface is an industrial surface.
17. The use or method according to claim 16, wherein the industrial surface is a surface that is found in the manufacturing industry, the packaging industry, construction industry, the automotive industry, the aviation industry, the agricultural industry, or the mining industry.
18. The use or method according to claim 17, wherein the industrial surface is found in the manufacturing industry.
19. The use or method according to claim 17, wherein the industrial surface is found in the packaging industry.
20. The use or method according to claim 17, wherein the industrial surface is found in the construction industry.
21. The use or method according to claim 17, wherein the industrial surface is found in the automotive industry.
22. The use or method according to claim 17, wherein the industrial surface is found in the aviation industry.
23. The use or method according to claim 17, wherein the industrial surface is found in the agricultural industry.
24. The use or method according to claim 17, wherein the industrial surface is found in the mining industry.
25. The use or method according to any preceding claim, wherein surface is selected from the surface of an extruded product (such as a pellet, granule, or film), a mould, paper packaging, a construction material (such as plasterboard, gypsum, stucco, or concrete), a vehicle (such as a window, tyre, vehicle body, or vehicle interior), a plant (such as a seed), a solid agrochemical composition, or a non-household fibrous substrate.
26. The use or method according to any preceding claim, which provides a surface of plasterboard, gypsum or stucco with increased water repellency.
27. The use or method according to any of claims 3 to 26, wherein the polymer is comprised in a composition, wherein the composition additionally comprises at least one solvent and optionally one or more surfactants.
28. The use or method according to claim 27, wherein the composition comprises one or more surfactants selected from anionic surfactants, cationic surfactants, non-ionic surfactants, and amphoteric or zwitterionic surfactants.
29. The use or method according to claim 28, wherein the one or more surfactants are independently selected from one or more of a fatty alkyl amphoacetate, an alkyl (poly)glycoside, an acyl glycinate, a sulfosuccinate, an amphodiacetate and a fatty alcohol ether carboxylate.
30. The use or method according to any of claims 27 to 29, wherein the composition comprises from 0.1 to 20 wt%, preferably from 0.1 to 10 wt%, for example from 0.5 to 5 wt% of the polymer.
31. A composition for treating a surface that is not a surface of a home care substrate, wherein treating the surface provides at least one effect selected from (a) increased water repellency, (b) reduced friction, and (c) improved visual appearance, and wherein the composition comprises one or more nitrogen containing compounds, wherein the or each nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group.
32. The composition according to claim 31, wherein the composition comprises at least 0.1 wt%, such as from 0.1 to 20 wt%, preferably from 0.1 to 10 wt%, for example from 0.5 to 5 wt% of the one or more nitrogen containing compounds.
33. The composition according to claim 31 or 32, wherein the composition additionally comprises one or more surfactants.
34. The composition according to claim 33, wherein the one or more surfactants are independently selected from anionic surfactants, cationic surfactants, non-ionic surfactants, and amphoteric or zwitterionic surfactants.
35. The composition according to claim 34, wherein the one or more surfactants are independently selected from one or more of a fatty alkyl amphoacetate, an alkyl (poly)glycoside, an acyl glycinate, a sulfosuccinate, an amphodiacetate and a fatty alcohol ether carboxylate.
36. A substrate that is not a home care substrate, wherein a surface of the substrate is treated with a nitrogen containing compound, wherein the nitrogen containing compound is the reaction product of reactants comprising one or more first reactants and one or more second reactants, wherein the or each first reactant is a polycarboxylic acid or a reactive equivalent thereof and the or each second reactant is a polyfunctional reactant having at least one reactive amino group.
37. The composition or substrate according to any of claims 31 to 36, wherein the nitrogen containing compound is a polymer, the reactants are monomers, the one or more first reactants are one or more first monomers, the one or more second reactants are one or more second monomers, and the polyfunctional reactant is a polyfunctional monomer having at least one reactive amino group.A