Sheet-like cosmetic

Abstract

To provide a sheet-like cosmetic that is impregnated with a cosmetic and is applied to a user's face, giving a favorable skin touch, and achieves, in a balanced manner, the permeation of the cosmetic through the skin, the retention of moisture, no spillage, the adhesion of the sheet, and no stickiness.SOLUTION: This sheet-like cosmetic is obtained by impregnating a sheet base material with a composition containing: an oily component having a melting point of 50-150°C as component (A); an ionic surfactant as component (B); 0.05-1 mass% of a water-soluble polymer as component (C); and water as component (D).SELECTED DRAWING: None

Description

Technical field

[0001] TECHNICAL FIELD The present invention relates to sheet-shaped cosmetics. [Background technology]

[0002] Patent Documents 1 to 4 describe techniques related to sheet-like cosmetics. Patent Document 1 (Japanese Patent Application Laid-Open No. 2011-207817) describes a higher alcohol having 14 to 22 carbon atoms, a hydrophilic polyoxyethylene alkyl ether having a specific structure, and a glycerin monoalkyl ether having a specific structure. It describes a sheet-like cosmetic in which the sheet is impregnated with an oil-in-water emulsified cosmetic that further includes an alkyl acrylate / methacrylate copolymer and has a viscosity within a specific range (claim 1 , 2). In addition, the same document describes that the oil-in-water emulsified cosmetic is not sticky, has a fresh touch, has excellent penetration, and has excellent adhesion to the skin when used by being impregnated in a sheet or the like. (Paragraph 0011).

[0003] Patent Document 2 (Japanese Patent Application Laid-Open No. 2003-335627) discloses that a sheet material such as a non-woven fabric is impregnated with an o / w emulsion cosmetic, and a uniform, non-sticky feel is obtained from the beginning to the end of wiping. To provide a cosmetic-impregnated sheet capable of sustaining , emulsifying, impregnating, etc. without using a special device, having excellent productivity, excellent stability over time, storage stability, etc., and convenient to carry. (Paragraph 0006), a sheet material is impregnated with a two-phase cosmetic having an aqueous phase as a continuous phase, and the two-phase cosmetic has a static viscosity and a stirring viscosity within a specific range. (Claim 1).

[0004] Patent Document 3 (JP-A-2011-126846) discloses a sheet-like cosmetic in which a plurality of sheet-like base materials are packaged in a bag, wherein the cosmetic having a specific viscosity is a plurality of sheet-like base materials. A sheet-like cosmetic impregnated in a material is described (claim 1). In the same document, the sheet-like cosmetic can be easily impregnated with the cosmetic even when a plurality of sheet-like base materials are packed in a bag, and furthermore, the sheet-like cosmetic can be easily impregnated with the cosmetic material. It is described that it is possible to provide a sheet-shaped cosmetic using a cosmetic that does not drip and has a high moisturizing effect (paragraph 0009).

[0005] In addition, Patent Document 4 (Japanese Patent Application Laid-Open No. 2000-63230) describes a technique for providing a wrinkle-improving means that is extremely effective in improving wrinkles beyond what has been conventionally provided (paragraph 0005). , a wrinkle-improving agent and a hydrophilic gel-forming agent in its liquid component (claim 1). [Prior art documents] [Patent document]

[0006] [Patent document 1] JP 2011-207817 A [Patent document 2] JP-A-2003-335627 [Patent Document 3] JP 2011-126846 A [Patent Document 4] JP-A-2000-63230 [Outline of the Invention] [Problems to be solved by the invention]

[0007] The present inventors have conducted studies to further improve the feeling of use of sheet-like cosmetics. As a result, in the above-mentioned technology, there is room for improvement in terms of the texture of the sheet when the cosmetic sheet impregnated with the cosmetic is applied to the face. Also, it was found that when the face is moved while the sheet is applied, the user tends to feel friction with the skin. In addition, it was found that there is room for improvement in terms of the feeling of penetration of the cosmetic into the skin, the durability of moisturizing, the lack of dripping, the feeling of adhesion of the sheet, and the lack of stickiness. Therefore, in the present invention, when a sheet-shaped cosmetic impregnated with a cosmetic is applied to the face, the texture of the sheet, the feeling of penetration of the cosmetic into the skin, the persistence of moisturizing, the absence of dripping, and the adhesion of the sheet To provide a sheet-like cosmetic excellent in balance between feeling and non-stickiness. [Means for solving the problem]

[0008] According to the invention, A sheet-shaped cosmetic is provided by impregnating a sheet substrate with a composition containing the following components (A), (B), (C) and (D). (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) water

[0009] According to the invention, Provided is a sheet-like cosmetic containing a composition containing the following components (A), (B), (C) and (D) in a sheet base material. (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) water According to the invention, A sheet-shaped cosmetic is provided by impregnating a sheet substrate with a composition containing the following components (A), (B), (C) and (D). (A) 0.7% by mass or more and 5% by mass or less of an oily component having a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) water According to the invention, A sheet-shaped cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D), wherein the component (C) is an alkyl-modified carboxyl A sheet-shaped cosmetic containing a vinyl polymer is provided. (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) water According to the invention, A sheet-shaped cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D), wherein the component (C) is alkyl-modified. A sheet-like cosmetic containing a good carboxyvinyl polymer and hydroxyalkyl cellulose is provided. (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) water According to the invention, A sheet-shaped cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D), wherein the component (C) is alkyl-modified. A sheet-like cosmetic containing a good carboxyvinyl polymer and hydroxyalkyl cellulose is provided. (A) 0.7% by mass or more and 5% by mass or less of an oily component having a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) water

[0010] Further, according to the present invention, there is provided a packaging body in which the sheet-like cosmetic of the present invention is accommodated in a packaging material.

Effect of the invention

[0011] According to the present invention, when a sheet-shaped cosmetic impregnated with a cosmetic is applied to the face, the feel of the sheet, the feeling of penetration of the cosmetic into the skin, the persistence of moisturizing, the absence of dripping, and the close contact of the sheet. It is possible to provide a sheet-like cosmetic having an excellent balance of non-stickiness and non-stickiness. [Mode for carrying out the invention]

[0012] Embodiments of the present invention will be described below. Each component contained in the composition can be contained alone or in combination of two or more. In addition, in this specification, unless otherwise specified, "~" representing a numerical range represents from the above to the following, including both the upper limit and the lower limit.

[0013] (Sheet cosmetics) In the present embodiment, the sheet-like cosmetic is obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D). That is, the sheet-like cosmetic more specifically contains a composition containing the following components (A), (B), (C) and (D) in the sheet base material. (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) water

[0014] The present inventors obtained a sheet-shaped cosmetic by impregnating a woven or non-woven fabric with a liquid cosmetic containing components (A) to (D) and having an adjusted amount of the component (C) to obtain a sheet-shaped cosmetic. The present inventors have newly found that the feeling of use of cosmetics can be improved. More specifically, by applying the sheet-shaped cosmetic of the present embodiment to the skin, it is possible to improve the texture of the sheet when the sheet-shaped cosmetic is applied to the face. It is also possible to suppress unevenness and roughness of the surface of the sheet and the feeling of friction with the skin when the face is moved while the sheet is attached. In addition, according to the present embodiment, it is possible to provide an excellent balance among the texture of the sheet, the feeling of penetration of cosmetics into the skin, the durability of moisturizing, the absence of dripping, the feeling of adhesion of the sheet, and the absence of stickiness. can. Each configuration will be described in more detail below.

[0015] (Composition) The composition with which the sheet substrate is impregnated may specifically be a cosmetic composition.

[0016] (Component (A)) Component (A) is an oily component with a melting point of 50 to 150°C. An oily component having a melting point of 50 to 150°C is a solid oily component at room temperature (5 to 35°C).

[0017] Component (A), for example, sphingolipids such as ceramides and sphingosines (including natural products and synthetic products); sterols such as cholesterol, dehydrocholesterol, β-sitosterol, stearoyl cholesteryl ester, isostearoyl cholesteryl ester, vegetable oil fatty acid cholesteryl ester; Fatty acids with 16 to 22 carbon atoms such as stearic acid and behenic acid; Alcohols with 16 to 22 carbon atoms such as cetyl alcohol, stearyl alcohol, behenyl alcohol, batyl alcohol and chimyl alcohol; monoalkyl glyceryl ethers having 14 to 22 carbon atoms such as monomyristyl glyceryl ether, monocetyl glyceryl ether, monostearyl glyceryl ether, monobehenyl glyceryl ether, isostearyl glyceryl ether; Waxes such as beeswax, candelilla wax, carnauba wax, bayberry wax, jojoba wax, lanolin, shellac wax, whale wax, and Japanese wax; C14-22 mono fatty acid glycerol (e.g., glycerin monomyristate, glycerin monopalmitate, glycerin monostearate, glycerin monobehenate, glycerin monooleate, glycerin monoisostearate) , C14-22 mono fatty acid sorbitan esters (e.g., sorbitan monomyristate, sorbitan monopalmitate, sorbitan monostearate, sorbitan monobehenate), myristyl myristate, cholesteryl isostearate, behenyl behenylate, trimyristate Ester oils such as glycerin, dextrin fatty acid esters (e.g., dextrin palmitate, dextrin stearate, dextrin behenate); and Hydrocarbon oils such as petrolatum, ceresin, ozokerite, microcrystalline wax and candelilla wax are included.

[0018] Among them, ceramides include natural ceramides (for example, ceramide 2), sphingosine derivatives, Japanese Patent Laid-Open Nos. 228048 / 1987, 216812 / 1988, 227513 / 1988, and the like. Examples include ceramide-like structural substances described in JP-A-64-29347, JP-A-64-31752 and JP-A-8-319263. Ceramides are preferable because they have excellent moisturizing effect and skin barrier function, and have high moisturizing persistence and skin improving effect. Ceramides are preferably natural ceramides, compounds represented by the following general formula (1) or (2), from the viewpoint of having excellent moisturizing effect and skin barrier function, and high moisturizing retention and skin improving effect. and more preferably a compound represented by the following general formula (1).

[0019] [formation]

[0020] (In the above general formula (1), R 11 is a hydrocarbon group with 10 to 26 carbon atoms, and R 12 is a hydrocarbon group with 9 to 25 carbon atoms, and X is -(CH 2 ) n - (n is an integer from 2 to 6). ) Examples of compounds represented by general formula (1) include N-(hexadecyloxyhydroxypropyl)-N-hydroxyethylhexadecanamide. The compound represented by the general formula (1) is a pseudo-ceramide, a ceramide functional component, and can supplement the action of ceramide and improve skin conditions (moisture content, etc.).

[0021] [formation]

[0022] (In the above general formula (2), R 1 and R 2 are the same or different and are optionally hydroxylated hydrocarbon groups having 1 to 40 carbon atoms, and R 3 is an alkylene group having 1 to 6 carbon atoms or a single bond, and R 4 is a hydrogen atom, an alkoxy group having 1 to 12 carbon atoms, or a 2,3-dihydroxypropyloxy group. However, R 3 is a single bond, R 4 is a hydrogen atom. ) Further, examples of compounds represented by general formula (2) include long-chain dibasic acid bis-3-methoxypropylamide.

[0023] In general formulas (1) and (2) above, the hydrocarbon group is preferably an alkyl group or an alkenyl group.

[0024] Component (A) is preferably ceramides, sphingolipids other than ceramides, sterols, fatty acids having 16 to 22 carbon atoms, and 16 to 22 carbon atoms, from the viewpoint of improving moisturizing persistence and skin improvement effect. Contains one or more selected from the group consisting of the following alcohols, more preferably one selected from the group consisting of ceramides, fatty acids having 16 to 22 carbon atoms and alcohols having 16 to 22 carbon atoms Alternatively, it contains two or more kinds, more preferably contains at least one selected from the group consisting of ceramides and alcohols having 16 to 22 carbon atoms, and still more preferably contains ceramides.

[0025] The content of component (A) in the composition is preferably 0.1 based on the entire composition from the viewpoints of improving the texture of the sheet, improving the sense of penetration, improving the moisturizing durability and preventing dripping. % by mass or more, more preferably 0.3% by mass or more, still more preferably 0.7% by mass or more, and even more preferably 1.5% by mass or more. In addition, from the viewpoint of suppressing stickiness and improving penetration, the content of component (A) in the composition is preferably 5% by mass or less, more preferably 4% by mass or less, relative to the entire composition. , more preferably 3% by mass or less, and even more preferably 2.5% by mass or less.

[0026] When component (A) contains ceramides and mono-fatty acid glycerol ester, the content of ceramides is 20% by mass based on the entire component (A) from the viewpoint of improving moisturizing persistence and skin improvement effect. 50 mass % or more is more preferable, 80 mass % or more is still more preferable, 99 mass % or more is even more preferable, and it may be less than 100 mass %, for example. From the same point of view, it is preferable that component (A) does not contain mono-fatty acid glycerol esters but contains ceramides, and component (A) does not contain mono-fatty acid glycerol esters and the content of ceramides is less than that of component (A). It is more preferably 100% by mass with respect to the whole.

[0027] (Component (B)) Component (B) is an ionic surfactant. Component (B) is specifically one or more selected from the group consisting of anionic surfactants, cationic surfactants and amphoteric surfactants. In the present embodiment, since the composition contains the components (A) and (B), aggregation and coalescence of the components in the composition can be suppressed, and the storage stability of the composition can be improved.

[0028] anionic surfactants such as sodium laurate, potassium palmitate, arginine stearate and other fatty acids having 12 to 22 carbon atoms or salts thereof; C12-22 alkyl sulfates such as sodium lauryl sulfate, potassium lauryl sulfate, sodium cetyl sulfate, or salts thereof; C12-22 alkyl ether sulfate such as polyoxyethylene lauryl sulfate triethanolamine or a salt thereof; C12-22 alkyl phosphates such as sodium monostearyl phosphate or salts thereof; Polyoxyethylene C12-22 alkyl ether phosphates such as sodium polyoxyethylene oleyl ether phosphate and sodium polyoxyethylene stearyl ether phosphate, or salts thereof; dialkylsulfosuccinic acid having 12 to 24 carbon atoms such as sodium di-2-ethylhexylsulfosuccinate or a salt thereof; N-alkyloylmethyltaurine having 12 to 22 carbon atoms such as sodium N-stearoyl-N-methyltaurate or a salt thereof; Acylsarcosine having 12 to 22 N-carbon atoms such as sodium lauroyl sarcosinate or a salt thereof; sodium dilauroyl glutamate, monosodium N-lauroyl glutamate, sodium N-stearoyl-L-glutamate, arginine N-stearoyl-L-glutamate, Acylglutamic acid having 12 to 22 N-carbon atoms such as sodium N-stearoyl glutamate, sodium N-myristoyl-L-glutamate, or a salt thereof; acylglycine).

[0029] As the cationic surfactant, quaternary ammonium salts are preferred, and examples thereof include alkyltrimethylammonium chlorides such as stearyltrimethylammonium chloride and behenyltrimethylammonium chloride, dialkyldimethylammonium chlorides, trialkylmethylammonium chlorides, and alkylamine salts. be done.

[0030] Amphoteric surfactants include alkyldimethylamine oxides, alkylcarboxybetaines, alkylsulfobetaines, amide amino acid salts, alkylamidopropylbetaines.

[0031] Component (B) preferably contains an anionic surfactant, and more preferably has 12 or more and 22 or less carbon atoms, from the viewpoints of improving the texture of the sheet, suppressing dripping, improving adhesion, and suppressing stickiness. At least one selected from the group consisting of N-alkyloylmethyltaurine or a salt thereof and an acylamino acid surfactant, more preferably N-stearoyl-N-methyltaurine or a salt thereof and an acylamino acid surfactant It is at least one selected from the group consisting of From the same point of view, component (B) is preferably N-alkyloylmethyltaurine having 12 to 22 carbon atoms or a salt thereof, more preferably N-stearoyl-N-methyltaurine or a salt thereof.

[0032] The content of component (B) in the composition is preferably 0.01% by mass or more relative to the entire composition, from the viewpoints of improving the texture of the sheet, improving the moisturizing durability, and suppressing dripping. It is more preferably 0.05% by mass or more, still more preferably 0.15% by mass or more, and even more preferably 0.3% by mass or more. In addition, from the viewpoint of improving penetration feeling and suppressing stickiness, the content of component (B) in the composition is preferably 1% by mass or less, more preferably 0.8% by mass or less, and more preferably 0.8% by mass or less, relative to the entire composition. It is preferably 0.6% by mass or less.

[0033] (Component (C)) Component (C) is a water-soluble polymer. Specific examples of component (C) include proteins or polypeptides such as gelatin and collagen; polysaccharides such as hyaluronic acid and its salts, xanthan gum, chondroitin sulfate and its salts, dextrin, pectin, gellan gum, carrageenan, pullulan; Carboxyvinyl polymer which may be alkyl-modified, polyacrylamide, copolymer of acrylamide and acrylic acid, copolymer obtained by copolymerizing at least acrylate or hydroxyalkyl acrylate with acryloyldimethyltaurate, etc. acrylic polymers and polyvinyl alcohol; Cellulosic polymers such as methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose; alginic acid-based polymers such as alginic acid and salts thereof; and Carboxymethyl chitin, chitosan.

[0034] Among acrylic acid-based polymers, carboxyvinyl polymers include polymers containing acrylic acid or methacrylic acid as constituent monomers. made). In addition, the alkyl-modified carboxyvinyl polymer is a polymer containing acrylic acid or methacrylic acid ester-bonded (alkyl-modified) with a fatty acid having 1 to 35 carbon atoms as a constituent monomer. is mentioned. Among them, those known as alkyl acrylate / methacrylate copolymers (acrylic acid / alkyl acrylate (C10-30)) copolymers in which the alkyl group has 10 to 30 carbon atoms are preferable from the viewpoint of suppressing stickiness. Specific examples of such polymers include Carbopol ETD2020, Carbopol 1382, Pemulen TR-1 and Pemulen TR-2 (manufactured by Lubrizol).

[0035] Specific examples of polyacrylamide include SEPIGEL 305 (manufactured by SEPPIC). Copolymers of acrylamide and acrylic acid include acrylamide / ammonium acrylate) copolymers, specifically SEPIPLUS 265 (manufactured by SEPPIC) and the like.

[0036] Examples of copolymers obtained by copolymerizing at least acrylate or hydroxyalkyl acrylate with acryloyldimethyltaurate include copolymers of acrylate and acryloyldimethyltaurate, hydroxyalkyl acrylate and acryloyl Examples thereof include copolymers with dimethyltaurate, copolymers of acrylic acid, acrylic acid amide, acrylate and acryloyldimethyltaurate. Among them, copolymers of acrylates and acryloyldimethyltaurate salts include, for example, (Na acrylate / Na acryloyldimethyltaurate) copolymers, more specifically SIMULGEL EG (manufactured by SEPPIC) and the like. mentioned. Copolymers of hydroxyalkyl acrylates and acryloyldimethyltaurate salts include, for example, (hydroxyethyl acrylate / Na acryloyldimethyltaurate) copolymers, more specifically SIMULGEL FL, SIMULGEL NS, SEPIPLUS S, SEPINOV. EMT 10 (manufactured by SEPPIC) and the like. Copolymers of acrylic acid, acrylic acid amide, acrylate and acryloyldimethyltaurate include, for example, polyacrylate-13, more specifically SEPIPLUS 400 (manufactured by SEPPIC) and the like.

[0037] Component (C) is preferably selected from the group consisting of acrylic acid-based polymers and cellulose-based polymers from the viewpoints of improving the texture of the sheet, suppressing dripping, improving adhesion, and suppressing stickiness. at least one, more preferably acrylic acid-based polymer and cellulose-based polymer, more preferably alkyl-modified carboxyvinyl polymer and hydroxyalkyl cellulose, still more preferably alkyl-modified carboxyvinyl It includes polymer and hydroxyalkyl cellulose, and more preferably includes alkyl acrylate-methacrylate copolymer and hydroxypropylmethyl cellulose (HPMC) in which the alkyl group has 10 to 30 carbon atoms.

[0038] The content of component (C) in the composition is determined from the viewpoints of improving the texture of the sheet, improving the sense of penetration, improving the moisturizing durability, suppressing dripping, improving adhesion, and suppressing stickiness. Therefore, it is 0.05% by mass or more, preferably 0.06% by mass or more, more preferably 0.07% by mass or more, and still more preferably 0.08% by mass or more, relative to the entire composition. In addition, from the viewpoint of improving penetration feeling and suppressing stickiness, the content of component (C) in the composition is 1% by mass or less, preferably 0.8% by mass or less, more preferably 0.8% by mass or less, relative to the entire composition. It is 0.6% by mass or less, more preferably 0.5% by mass or less, and even more preferably 0.2% by mass or less.

[0039] Further, when the component (C) contains an acrylic acid-based polymer and a cellulose-based polymer, the mass ratio of the content of the acrylic acid-based polymer to the content of the cellulose-based polymer in the composition (acrylic acid-based polymer / Cellulose-based polymer) is preferably 1 or more, more preferably 2 or more, and still more preferably 5 or more, from the viewpoints of improving the texture of the sheet, improving the sense of penetration, and suppressing stickiness. In addition, from the viewpoint of improving the texture of the sheet, improving the penetration feeling, and suppressing stickiness, the mass ratio (acrylic acid-based polymer / cellulose-based polymer) is preferably 60 or less, more preferably 40. 20 or less, more preferably 20 or less.

[0040] The mass ratio of the content of component (B) to the content of component (C) in the composition ((B) / (C)) is determined from the viewpoint of improving the texture of the sheet, improving the moisturizing durability, and suppressing stickiness. from the viewpoint of, it is preferably 0.1 or more, more preferably 0.5 or more, still more preferably 1.0 or more, even more preferably 2.0 or more, and even more preferably 4.2 or more. In addition, from the viewpoint of improving the texture of the sheet, improving the penetration feeling, and suppressing stickiness, the mass ratio ((B) / (C)) is preferably 30 or less, more preferably 20 or less, and further. It is preferably 10 or less, and even more preferably 6.7 or less.

[0041] (Component (D)) Component (D) is water. The content of component (D) in the composition can be, for example, the remainder after excluding components other than component (D) in the composition.

[0042] In addition, the content of component (D) in the composition is preferably 50% by mass or more, more preferably 50% by mass or more, based on the entire composition, from the viewpoint of improving the texture of the sheet and improving the storage stability of the composition. It is 60% by mass or more, more preferably 65% ​​by mass or more, and even more preferably 70% by mass or more. In addition, from the viewpoint of improving the texture of the sheet and improving the storage stability of the composition, the content of component (D) in the composition is less than 99.95% by mass, preferably 98% by mass, based on the total composition. Below, it is more preferably 95% by mass or less, still more preferably 90% by mass or less, even more preferably 85% by mass or less, and even more preferably 80% by mass or less.

[0043] The composition may also contain components other than components (A) to (D). For example, the composition further comprises component (E) below.

[0044] (Component (E)) Component (E) is a polyhydric alcohol. However, the aforementioned component (C) is excluded from component (E). The number of carbon atoms in component (E) is preferably 2 or more, more preferably 3 or more, and more preferably 8 or less, from the viewpoint of excellent liquid retention and transferability of the composition to the skin. is less than or equal to 6.

[0045] Examples of component (E) include polyhydric alcohols having 2 to 8 carbon atoms and polymers thereof. Specific examples of polyhydric alcohols having 2 to 8 carbon atoms include ethylene glycol, diethylene glycol, glycerin, 1,3-propanediol, 1,2-propanediol, sorbitol, propylene glycol, dipropylene glycol, 1,3 - One or more selected from the group consisting of butylene glycol, isoprene glycol and polymers thereof. The molecular weight of component (E) is, for example, 200 or less, preferably 150 or less, still more preferably 100 or less, or, for example, 50 or more.

[0046] From the viewpoint of improving the liquid retention of the sheet-like cosmetic, component (E) preferably contains one or more compounds selected from the group consisting of glycerin, 1,3-butylene glycol and dipropylene glycol. It preferably contains two or more compounds selected from the group consisting of glycerin, 1,3-butylene glycol and dipropylene glycol.

[0047] The content of component (E) in the composition is preferably 5% by mass or more, more preferably 10% by mass or more, and still more preferably 15% by mass, relative to the entire composition, from the viewpoint of improving moisturizing durability. That's it. In addition, from the viewpoint of suppressing stickiness and improving the storage stability of the composition, the content of component (E) in the composition is preferably 40% by mass or less, more preferably 30% by mass, based on the total composition. % by mass or less, more preferably 25% by mass or less.

[0048] The composition may also contain ingredients other than those mentioned above. For example, the composition may contain one or more selected from the group consisting of pH adjusters, preservatives, moisturizers, extracts, and other active ingredients and additives used in cosmetics. Among them, pH adjusters include organic acids such as succinic acid, citric acid and tartaric acid and salts thereof; inorganic acids such as phosphoric acid and salts thereof; amino acids such as L-arginine and salts thereof; Bases such as potassium and ammonium chloride are included. Examples of preservatives include phenoxyethanol and methylparaben. Humectants include, for example, trimethylglycine and methylgluceth-20. Extracts or extracts such as eucalyptus extract, asunaro extract, ginger extract, Phellodendron bark extract, licorice extract, aloe extract, horsetail extract, tea extract, cucumber extract, clove extract, carrot extract, hamamelis extract, placenta extract, seaweed extract, horse chestnut extract, rosemary extract, yuzu extract, asunaro extract, royal jelly extract, asunaro extract, and other animal and plant extracts. Other active ingredients and additives used in cosmetics include, for example, anti-inflammatory agents such as allantoin and dipotassium glycyrrhizinate; chelating agents such as disodium edetate; L-ascorbic acid 2-glucoside, niacinamide, and N-amidino. -L-proline.

[0049] When the composition contains an oil agent that is liquid at 25°C, the content thereof is preferably 5% by mass or less relative to the entire composition, from the viewpoint of suppressing an increase in the viscosity of the composition and the accompanying decrease in the sense of penetration and stickiness. , 3% by mass or less is more preferable, 1% by mass or less is even more preferable, and 0.8% by mass or less is even more preferable. From the same point of view, it is also preferable that the content of the oil that is liquid at 25°C in the composition is 0% by mass. Examples of oils that are liquid at 25°C include silicone oils such as methylpolysiloxane, ester oils such as neopentyl glycol dicaprate, hydrocarbon oils such as squalane, and vegetable oils such as jojoba oil. Here, specifically, an oil that is liquid at 25°C is an oil having a melting point of 25°C or lower.

[0050] In this embodiment, the composition is preferably liquid at 25°C. The viscosity of the composition at 25°C is preferably 50 mPa s or more, more preferably 130 mPa s or more, and even more preferably 130 mPa s or more, from the viewpoints of improving the texture of the sheet, improving the durability of moisturizing, and suppressing dripping. is 170 mPa·s or more, more preferably 280 mPa·s or more, and most preferably 400 mPa·s or more. In addition, from the viewpoint of improving the feeling of penetration of the cosmetic into the skin and from the viewpoint of suppressing stickiness, it is preferably 5,000 mPa s or less, more preferably 3,000 mPa s or less, still more preferably 2,500 mPa s or less. Even more preferably, it is 2,000 mPa·s or less. Here, the viscosity of the composition is measured using a Brookfield viscometer at a rotation speed of 12 rpm, a measurement time of 60 seconds, and a measurement temperature of 25° C. The viscosity of the composition is measured using the following rotor. Viscosity less than 250mPa s: Rotor No.1, Viscosity 250 mPa s or more and less than 2,500 mPa s: Rotor No.2, Viscosity 2,500mPa s or more and less than 10,000mPa s: Rotor No.3, Viscosity 10,000mPa s or more: Rotor No.4

[0051] The composition is also preferably a dispersion of vesicle particles. The particle size of the vesicle particles measured by a dynamic light scattering method (for example, ZETASIZER nano-ZS, manufactured by Malvern Panalytical) is preferably 100 nm or more from the viewpoint of improving the texture of the sheet and suppressing stickiness, More preferably, it is 200 nm or more. In addition, from the viewpoint of improving the texture of the sheet, suppressing stickiness, and improving the storage stability of the composition, the particle diameter is preferably 1,000 nm or less, more preferably 800 nm or less.

[0052] (sheet base material) In the present embodiment, the sheet base material constituting the sheet-like cosmetic is not limited, and is a sheet-like support that can be impregnated with the composition. A woven fabric or a non-woven fabric is preferable as the sheet base material. The sheet base material may be a laminate (that is, a laminate sheet), and may be, for example, a laminate of woven fabrics, a laminate of nonwoven fabrics, a laminate of woven fabrics and nonwoven fabrics, and the like. The sheet base material is preferably a sheet base material containing a non-woven fabric, more preferably a non-woven fabric, from the viewpoints of improved usability, ease of processing, and the like. Examples of the nonwoven fabrics include spunbond nonwoven fabrics, spunlace nonwoven fabrics, thermal bonded nonwoven fabrics, needle punch nonwoven fabrics, stitchbond nonwoven fabrics, and the like.

[0053] Fibers constituting woven fabrics and non-woven fabrics are not limited, and include, for example, natural fibers, synthetic fibers, and semi-natural fibers. Among these, natural fibers include cotton, pulp, silk, cellulose, hemp, linter, and kabok. Examples of the synthetic fibers include nylon fibers, polyester fibers (eg, polyethylene terephthalate fibers, polybutylene terephthalate fibers, etc.), acrylic fibers, polyolefin fibers (eg, polypropylene fibers, polyethylene fibers, etc.). Semi-natural fibers include rayon and acetate. Only one kind of fibers constituting the woven fabric or nonwoven fabric may be used, or two or more kinds thereof may be used. A blended fiber composed of two or more of the above fibers may also be used. From the viewpoint of improving skin feel and moisture retention, the fibers constituting the sheet base material are particularly preferably natural fibers or semi-natural fibers, and more preferably rayon and pulp. When the material of the sheet base material is rayon and pulp, the (rayon / pulp) ratio is, for example, 5 / 95 to 95 / 5, preferably 50 / 50 to 95 / 5, more preferably 70 / 30. ~90 / 10.

[0054] Further, the sheet base material may be embossed. The embossing process is not limited, and includes, for example, a method in which the back surface is pushed up to float (therefore, the back surface is dented), and a method in which a special ink is applied to the surface to form convex portions (the back surface is not dented). mentioned.

[0055] The sheet base material can be manufactured by a known manufacturing method depending on the type of woven fabric, non-woven fabric, or the like. A commercially available product can also be used as the sheet base material. Specific examples of commercially available sheet base materials include Daiwabo Polytech Co., Ltd., trade name "RH"; Daiwabo Polytech Co., Ltd., trade name "AS-40"; Futamura Chemical Co., Ltd., trade name "TCF404WJ"; Product name: "Cotto Ace A060S / A18"; manufactured by Unitika, product name: "Cotto Ace C030S / A18"; manufactured by Kuraray, product name: "Kuraflex JP2445B019"; manufactured by Kuraray, product name: "Kuraflex JP0509B056"; Asahi Kasei Co., Ltd., trade name "Bemliese SE803"; Asahi Kasei Co., Ltd., trade name "Bemliese JP254"; Asahi Kasei Co., Ltd., trade name "Bemliese RE75K"; Trade name "Sunmore SP8740"; trade name "NR91060" manufactured by Sanwa Paper Co., Ltd.; trade name "M1-30-2PE" manufactured by Inogami Co., Ltd.;

[0056] Although the basis weight (basis weight) of the sheet base material is not limited, it is preferably 20 g / m2 from the viewpoint of improving the feeling of use of the sheet-like cosmetic material. 2 and more preferably 45g / m 2 above, more preferably 50g / m 2 and preferably 150 g / m 2 or less, more preferably 125g / m 2 below, more preferably 100g / m 2 It is below. In addition, the basis weight of the sheet base material is based on JIS L 1913, the nonwoven fabric is cut into a certain area size, the mass (g) is measured, and this is 1 m 2 It can be obtained by converting to the mass of

[0057] The thickness of the sheet base material is preferably 0.1 mm or more, more preferably 0.3 mm or more, from the viewpoints of improving the texture of the sheet and suppressing dripping. The thickness of the sheet base material is preferably 1.5 mm or less, more preferably 0.7 mm or less, from the viewpoints of improving the texture of the sheet and suppressing dripping. Here, the thickness of the sheet base material is 20 gf / cm 2 Obtained by measuring the load with a dial gauge.

[0058] Next, a method for producing a sheet-like cosmetic will be described. A method for producing a sheet-shaped cosmetic includes, for example, a step of preparing a composition, a step of preparing a sheet substrate, and a step of impregnating the sheet substrate with the composition.

[0059] In the step of preparing the composition, for example, the composition can be prepared according to the following procedure. That is, the component (A), the component (B) and other components are heated and mixed while stirring, a part of the heated component (D) is added, mixed uniformly, cooled to about 25 ° C. get the phase On the other hand, component (C) is added to oily components other than component (A) and stirred and mixed to obtain a mixture, which is then added to the heated mixture of the remainder of component (D) and the aqueous component and mixed, Cool to about 25°C to obtain Phase II. Phase II is then added to phase I at 25° C. with stirring and mixed until uniform to obtain a composition.

[0060] In the step of impregnating the composition, for example, the sheet substrate can be immersed in the composition in a container such as an aluminum pouch.

[0061] The impregnation rate of the composition is preferably 300% by mass or more, more preferably 500% by mass, based on the mass of the sheet base material, from the viewpoints of improving the texture of the sheet, improving the feeling of penetration, and improving the feeling of adhesion. % or more, more preferably 700 mass % or more. In addition, from the viewpoint of suppressing dripping, the impregnation rate of the composition is preferably 2000% by mass or less, more preferably 1800% by mass or less, and still more preferably 1500% by mass or less with respect to the mass of the sheet base material. .

[0062] (package) In the present embodiment, the package is, for example, a sheet-like cosmetic according to the present embodiment contained in a packaging material, preferably a hermetically sealed package. There are no restrictions on the material of the package, and the front and back sides are made of polyethylene, polyethylene terephthalate, polypropylene, polyester, polyamide, polyvinyl chloride, etc., with a barrier layer such as an aluminum sheet (aluminum foil) or silica-deposited film sandwiched between them. It can be a laminated film or the like covered with a synthetic resin film layer. Moreover, the shape of the package is not limited, and may be, for example, a pillow bag, a gusset bag, a pouch, a box, a bottle, a jar, or the like. One packaging material may contain one sheet-like cosmetic material, or may contain two or more sheet-like cosmetic materials. In addition, two or more sheet-like cosmetics may be accommodated in one packaging material in a connected state. At this time, for example, perforations may be provided in the nonwoven fabric, and the sheet-like cosmetic material to be used can be cut along the perforations and used. A sheet-shaped cosmetic is stored, for example, in a folded or rolled state.

[0063] Regarding the above-described embodiments, the present invention further discloses the following sheet-shaped cosmetics and packaging materials. <1> A sheet-like cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D). (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) water

[0064] <2> Component (A) is preferably one selected from the group consisting of ceramides, sphingolipids other than ceramides, sterols, fatty acids having 16 to 22 carbon atoms, and alcohols having 16 to 22 carbon atoms. or contain two or more, more preferably ceramides, one or more selected from the group consisting of fatty acids having 16 to 22 carbon atoms and alcohols having 16 to 22 carbon atoms, more preferably contains at least one selected from the group consisting of ceramides and alcohols having 16 to 22 carbon atoms, more preferably ceramides. <3> The content of component (A) in the composition is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, still more preferably 0.7% by mass or more, and even more preferably, based on the total composition. is 1.5% by mass or more, preferably 5% by mass or less, more preferably 4% by mass or less, even more preferably 3% by mass or less, and even more preferably 2.5% by mass or less, <1> or The sheet-like cosmetic according to <2>. <4> Component (A) contains ceramides and a mono-fatty acid glycerol ester, and the content of ceramides is preferably 20% by mass or more, more preferably 50% by mass, based on the total amount of component (A). % or more, more preferably 80% by mass or more, still more preferably 99% by mass or more, and for example less than 100% by mass, the sheet-like cosmetic according to any one of <1> to <3> . <5> The component (B) preferably contains an anionic surfactant; More preferably, it is at least one selected from the group consisting of N-alkyloylmethyl taurine having 12 to 22 carbon atoms or a salt thereof and an acylamino acid-based surfactant, and more preferably N-stearoyl-N-methyltaurine or its At least one selected from the group consisting of salts and acyl amino acid surfactants; or Any one of <1> to <4>, more preferably N-alkyloylmethyltaurine having 12 to 22 carbon atoms or a salt thereof, more preferably N-stearoyl-N-methyltaurine or a salt thereof The sheet-shaped cosmetic described in . <6> The content of component (B) in the composition is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.15% by mass or more, and even more preferably, relative to the entire composition. is 0.3% by mass or more, preferably 1% by mass or less, more preferably 0.8% by mass or less, and further preferably 0.6% by mass or less, according to any one of <1> to <5> sheet cosmetic. <7> The component (C) is preferably at least one selected from the group consisting of acrylic acid-based polymers and cellulose-based polymers, more preferably acrylic acid-based polymers and cellulose-based polymers, and further Preferably, it contains a carboxyvinyl polymer that may be alkyl-modified and a hydroxyalkyl cellulose, and more preferably contains an alkyl acrylate-methacrylate copolymer having an alkyl group having 10 to 30 carbon atoms and HPMC, <1> The sheet-like cosmetic according to any one of <6>. <8> The content of component (C) in the composition is 0.05% by mass or more, preferably 0.06% by mass or more, more preferably 0.07% by mass or more, and still more preferably 0.08% by mass relative to the entire composition. % by mass or more, and 1% by mass or less, preferably 0.8% by mass or less, more preferably 0.6% by mass or less, even more preferably 0.5% by mass or less, and even more preferably 0.2% by mass or less, < The sheet-like cosmetic according to any one of 1> to <7>. <9> Component (C) contains an acrylic acid-based polymer and a cellulose-based polymer, and the mass ratio of the content of the acrylic acid-based polymer to the content of the cellulose-based polymer in the composition (acrylic acid-based polymer / cellulose polymer) is preferably 1 or more, more preferably 2 or more, still more preferably 5 or more, and preferably 60 or less, more preferably 40 or less, further preferably 20 or less. The sheet-like cosmetic according to any one of <1> to <8>. <10> The mass ratio of the content of component (B) to the content of component (C) in the composition ((B) / (C)) is preferably 0.1 or more, more preferably 0.5 or more, and further Preferably 1.0 or more, still more preferably 2.0 or more, still more preferably 4.2 or more, preferably 30 or less, more preferably 20 or less, still more preferably 10 or less, still more preferably The cosmetic sheet according to any one of <1> to <9>, which is 6.7 or less. <11> The content of component (D) in the composition is preferably 50% by mass or more, more preferably 60% by mass or more, still more preferably 65% ​​by mass or more, and even more preferably, relative to the entire composition. is 70% by mass or more and less than 99.95% by mass, preferably 98% by mass or less, more preferably 95% by mass or less, even more preferably 90% by mass or less, still more preferably 85% by mass or less, and especially The sheet-like cosmetic according to any one of <1> to <10>, preferably 80% by mass or less. <12> The composition preferably further contains component (E): a polyhydric alcohol, more preferably a polyhydric alcohol having 2 to 8 carbon atoms and a polymer thereof, more preferably glycerin, 1,3 - one or more compounds selected from the group consisting of butylene glycol and dipropylene glycol, more preferably two or more compounds selected from the group consisting of glycerin, 1,3-butylene glycol and dipropylene glycol; The sheet-like cosmetic according to any one of <1> to <11>. <13> The content of component (E) in the composition is preferably 5% by mass or more, more preferably 10% by mass or more, still more preferably 15% by mass or more, relative to the entire composition, and , preferably 40% by mass or less, more preferably 30% by mass or less, and even more preferably 25% by mass or less, the sheet-like cosmetic according to <12>. <14> The content of the oil that is liquid at 25°C in the composition is preferably 5% by mass or less, more preferably 3% by mass or less, still more preferably 1% by mass or less, and further preferably The sheet-like cosmetic according to any one of <1> to <13>, which is more preferably 0.8% by mass or less, and particularly preferably 0% by mass. <15> The viscosity of the composition at 25°C is preferably 50 mPa s or more, more preferably 130 mPa s or more, still more preferably 170 mPa s or more, still more preferably 280 mPa s or more, and more preferably 280 mPa s or more. It is preferably 400 Pa s or more, preferably 5,000 mPa s or less, more preferably 3,000 mPa s or less, still more preferably 2,500 mPa s or less, and even more preferably 2,000 mPa s or less. , The cosmetic sheet according to any one of <1> to <14>. <16> The sheet-like cosmetic according to any one of <1> to <15>, wherein the fibers constituting the sheet base material are preferably natural fibers or semi-natural fibers, more preferably rayon and pulp. . <17> The impregnation rate of the composition is preferably 300% by mass or more, more preferably 500% by mass or more, still more preferably 700% by mass or more, and preferably 2000% by mass, relative to the mass of the sheet base material. The sheet-like cosmetic according to any one of <1> to <16>, which is 1800% by mass or less, more preferably 1500% by mass or less. <18> A package in which the sheet-shaped cosmetic according to any one of <1> to <17> is accommodated in a packaging material. <19> A sheet-shaped cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D). (A) 0.1% by mass or more and 5% by mass or less of an oily component having a melting point of 50 to 150°C (B) Ionic surfactant 0.01% by mass or more and 1% by mass or less (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water <20> A sheet-like cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C), (D) and (E). (A) 0.1% by mass or more and 5% by mass or less of an oily component having a melting point of 50 to 150°C (B) Ionic surfactant 0.01% by mass or more and 1% by mass or less (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water (E) Polyhydric alcohol 5% by mass or more and 40% by mass or less <21> A sheet-like cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D). (A) 0.3% by mass or more and 4% by mass or less of an oily component containing at least one selected from the group consisting of ceramides and alcohols having 16 to 22 carbon atoms (B) at least one ionic surfactant selected from the group consisting of N-stearoyl-N-methyltaurine or a salt thereof and an acylamino acid-based surfactant 0.05% by mass or more and 0.8% by mass or less (C) 0.08% by mass or more and 0.5% by mass or less of a water-soluble polymer containing a carboxyvinyl polymer that may be alkyl-modified and a hydroxyalkyl cellulose (D) Water <22> A sheet-like cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C), (D) and (E). (A) 0.3% by mass or more and 4% by mass or less of an oily component containing at least one selected from the group consisting of ceramides and alcohols having 16 to 22 carbon atoms (B) at least one ionic surfactant selected from the group consisting of N-stearoyl-N-methyltaurine or a salt thereof and an acylamino acid-based surfactant 0.05% by mass or more and 0.8% by mass or less (C) 0.08% by mass or more and 0.5% by mass or less of a water-soluble polymer containing a carboxyvinyl polymer that may be alkyl-modified and a hydroxyalkyl cellulose (D) Water (E) Polyhydric alcohol 15% by mass or more and 25% by mass or less <23> A sheet-like cosmetic containing a composition containing the following components (A), (B), (C) and (D) in a sheet base material. (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water <24> A sheet-like cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D). (A) 0.7% by mass or more and 5% by mass or less of an oily component having a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water <25> A sheet-shaped cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D), wherein the component (C) is alkyl-modified A sheet-like cosmetic containing a carboxyvinyl polymer. (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water <26> A sheet-like cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D), wherein the component (C) is alkyl-modified A sheet-like cosmetic containing a carboxyvinyl polymer and a hydroxyalkyl cellulose that may be used. (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water <27> A sheet-shaped cosmetic obtained by impregnating a sheet base material with a composition containing the following components (A), (B), (C) and (D), wherein the component (C) is alkyl-modified A sheet-like cosmetic containing a carboxyvinyl polymer and a hydroxyalkyl cellulose that may be used. (A) 0.7% by mass or more and 5% by mass or less of an oily component having a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water <28> A sheet-like cosmetic containing a composition containing the following components (A), (B), (C) and (D) in a sheet base material. (A) 0.7% by mass or more and 5% by mass or less of an oily component having a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water <29> A sheet-like cosmetic containing a composition containing the following components (A), (B), (C) and (D) in a sheet base material, wherein the component (C) is alkyl-modified A sheet-like cosmetic containing a carboxyvinyl polymer. (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water <30> A sheet-like cosmetic containing a composition containing the following components (A), (B), (C) and (D) in a sheet base material, wherein the component (C) is alkyl-modified A sheet-like cosmetic containing a carboxyvinyl polymer and a hydroxyalkyl cellulose. (A) an oily component with a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water <31> A sheet-like cosmetic containing a composition containing the following components (A), (B), (C) and (D) in a sheet base material, wherein the component (C) is alkyl-modified A sheet-like cosmetic containing a carboxyvinyl polymer and a hydroxyalkyl cellulose. (A) 0.7% by mass or more and 5% by mass or less of an oily component having a melting point of 50 to 150°C (B) an ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less <32> A package in which the sheet-like cosmetic according to any one of <19> to <31> is accommodated in a packaging material.

[0065] Although the embodiments of the present invention have been described above, these are examples of the present invention, and various configurations other than those described above can also be adopted.

Example

[0066] (Examples 1-11, Comparative Examples 1-6) A composition of each example was prepared according to the formulation shown in Tables 1 and 2, and a sheet base material was impregnated with the composition to obtain a sheet-like cosmetic of each example. In Tables 1 and 2 and Tables 3 and 6 below, the amount of each component is the active amount (unit: % by mass).

[0067] (Method for preparing composition) While stirring with a propeller stirrer, components (A), (B) and (E) are heated and mixed at 80 to 95°C, and a part of component (D) heated to 80 to 95°C is added and mixed uniformly. After that, it was cooled to 25°C to obtain phase I. On the other hand, while stirring with a propeller stirrer, the component (C) was added to the oily component excluding the component (A) and mixed to obtain a mixture. Thereafter, the above mixture was added to the remaining component (D) and the aqueous component which had been heated and mixed at 80°C, and after mixing, the mixture was cooled to 25°C to obtain phase II. Phase II was then added to Phase I at 25° C. while stirring with a propeller stirrer and mixed until uniform to obtain a composition.

[0068] (Measurement of composition viscosity) The viscosity was measured using a Brookfield viscometer (Model TVB-10 manufactured by Toki Sangyo Co., Ltd.) at a rotation speed of 12 rpm, a measurement time of 60 seconds, and a temperature of 25°C. The following rotors were used depending on the viscosity of the composition. Viscosity less than 250mPa s: Rotor No.1, Viscosity 250 mPa s or more and less than 2,500 mPa s: Rotor No.2, Viscosity 2,500mPa s or more and less than 10,000mPa s: Rotor No.3, Viscosity 10,000mPa s or more: Rotor No.4

[0069] (Method for producing sheet-shaped cosmetic) In the aluminum pouch, the non-woven fabric (rayon 85%, pulp 15%; basis weight 60g / m 2 average thickness of 0.4 mm) was immersed in the composition obtained in each example to obtain a face mask. The impregnation rate of the composition was 1200% by mass.

[0070] (Evaluation method) The sheet-shaped cosmetics obtained in each example were evaluated for sheet texture, permeation, moisturizing durability, dripping, adhesion and stickiness by the following methods. Evaluation results are shown in Tables 1 and 2.

[0071] (Seat texture) (Evaluation method) (1) Sheet texture A professional evaluator evaluated the smoothness of the surface of the sheet when it was touched with a finger, and how difficult it was to feel unevenness and roughness of the sheet itself when it was applied to the face and when the face was moved after application5. It was evaluated according to a graded scale. 5: No obvious feeling 4: I don't feel it 3: hardly felt 2: Slightly feel 1: I feel it clearly

[0072] (2) Penetration and adhesion One professional evaluator applied the sheet to the face, and after 10 minutes evaluated the feeling of penetration and adhesion of the composition to the skin according to the following 5-grade criteria. 5: Clearly feels strong 4: I feel it clearly 3: feel 2: I don't feel much 1: do not feel

[0073] (3) Sustained moisturizing feeling (moisturizing persistence) One professional evaluator applied the sheet to the face, peeled it off after 10 minutes, and evaluated the duration of the moisturizing feeling after 30 minutes according to the following 5-grade criteria. 5: Clearly feels strong 4: I feel it clearly 3: feel 2: I don't feel much 1: do not feel

[0074] (4) Dripping One professional evaluator applied the sheet to the face, and evaluated dripping of the composition from the sheet 10 minutes later according to the following 5-grade criteria. 5: No dripping 4: No dripping 3: Almost no dripping 2: There is some dripping 1: Obvious dripping

[0075] (5) Stickiness One professional evaluator applied the sheet to the face, peeled off the sheet after 10 minutes, and evaluated the non-stickiness according to the following 5-grade criteria. 5: No obvious feeling 4: I don't feel it 3: hardly felt 2: Slightly feel 1: I feel it clearly

[0076]

table 1

[0077] [Table 2]

[0078] Details of the components used in Tables 1 and 2 are shown below. N-(Hexadecyloxyhydroxypropyl)-N-hydroxyethylhexadecanamide: Sphingolipid E, manufactured by Kao Corporation Ceramide 2: Ceramide TIC-001, manufactured by Takasago International Corporation Sodium N-stearoyl-N-methyltaurate: Nikkor SMT, manufactured by Nikko Chemicals Co., Ltd. Sodium N-stearoyl-L-glutamate: Amisoft HS-11P, manufactured by Ajinomoto Co., Inc. Alkyl acrylate / methacrylate copolymer: PEMULEN TR-1 POLYMER, manufactured by Lubrizol Carboxyvinyl polymer: Carbopol 980, manufactured by Lubrizol Hydroxypropyl methylcellulose: Metolose 60SH-4000, manufactured by Shin-Etsu Chemical Co., Ltd. Hydroxyethyl cellulose: HEC850K, manufactured by Daicel Chemical Industries, Ltd. Glycerin: Concentrated glycerin for cosmetics, manufactured by Kao Corporation 1,3-butylene glycol: 1,3-butylene glycol-P, manufactured by KH Neochem Dipropylene glycol: DPG-RF, manufactured by ADEKA Phenoxyethanol: Hi-Solv EPH, manufactured by Toho Chemical Industry Co., Ltd. Methylpolysiloxane: Silicone KF-96A-10CS(-G), manufactured by Shin-Etsu Chemical Co., Ltd. Neopentyl glycol dicaprate: Estemol N-01, Nisshin OilliO Group Co., Ltd. L-arginine: L-arginine C grade, manufactured by Ajinomoto Co., Inc.

[0079] From Tables 1 and 2, it can be seen that the sheet-like cosmetics obtained in each example had a good balance among the effects of sheet texture, permeation, moisturizing retention, non-dripping, adhesion and non-stickiness. was excellent.

[0080] (Prescription examples 1-4) Table 3 shows formulation examples of compositions in sheet-like cosmetics.

[0081] [Table 3]

[0082] (Examples 1 to 11, Comparative Examples 1 to 6: Detailed evaluation of sheet texture) The sheet-shaped cosmetics having the configurations of the respective examples shown in Tables 1 and 2 were further evaluated for the texture of the sheet by the following method. Tables 4 and 5 show the evaluation results. (Seat texture) (Evaluation method) (6) Sheet texture (smoothness when touched with a finger) Three professional evaluators evaluated the smoothness of the sheet surface when they touched it with their fingers, according to the following five-grade criteria. Tables 4 and 5 show the total scores of the three participants. 5: Feels visibly smoother 4: Feel smooth 3: Feels a little smooth 2: Not very smooth 1: Does not feel visibly smooth (7) Texture of the sheet (when applied to the face) Three professional evaluators applied the sheet to the face and evaluated the difficulty of feeling unevenness and roughness of the sheet itself when the face was moved according to the following five-level criteria. Tables 4 and 5 show the total scores of the three participants. 5: No obvious feeling 4: I don't feel it 3: hardly felt 2: Slightly feel 1: I feel it clearly

[0083] [Table 4]

[0084] [Table 5]

[0085] (Examples 12 and 13) A composition of each example was prepared in the same manner as described above in Example 1, except for the formulation shown in Table 6, and the viscosity was measured. A sheet base material was impregnated with the obtained composition in the same manner as in Example 1 to obtain a sheet-shaped cosmetic of each example. (Evaluation method) The texture of the sheet was evaluated by the methods (6) and (7) in Example 1 above. Permeability and adhesion, persistence of moisturizing sensation (moisturizing persistence), dripping, and stickiness were evaluated by the methods (2) to (5) above in Example 1, respectively, except that they were evaluated by three professional evaluators. evaluated. Table 6 also shows the evaluation results.

[0086] [Table 6]

Claims

1. A sheet-type cosmetic preparation comprising a sheet substrate impregnated with a composition comprising the following components (A), (B), (C), and (D): The sheet-form cosmetic preparation, wherein component (B) is at least one member selected from the group consisting of N-stearoyl-N-methyltaurine or a salt thereof, and an acylamino acid-based surfactant. (A) An oil component having a melting point of 50 to 150°C (B) Ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water

2. 2. The sheet-form cosmetic preparation according to claim 1, wherein the component (A) contains one or more selected from the group consisting of ceramides, sphingolipids other than the ceramides, sterols, fatty acids having from 16 to 22 carbon atoms, and alcohols having from 16 to 22 carbon atoms.

3. 3. The sheet-form cosmetic preparation according to claim 1, wherein the component (C) is at least one selected from the group consisting of acrylic acid-based polymers and cellulose-based polymers.

4. 3. The sheet-form cosmetic preparation according to claim 1, wherein the component (C) comprises an acrylic acid-based polymer and a cellulose-based polymer.

5. 3. The sheet-form cosmetic preparation according to claim 1, wherein the component (C) comprises an optionally alkyl-modified carboxyvinyl polymer and a hydroxyalkyl cellulose.

6. 3. The sheet-type cosmetic preparation according to claim 1, wherein a mass ratio ((B) / (C)) of the content of said component (B) to the content of said component (C) in the composition is 0.1 or more and 30 or less.

7. 3. The sheet-form cosmetic preparation according to claim 1, wherein the viscosity of the composition at 25°C is 50 mPa·s or more and 5,000 mPa·s or less.

8. 3. The sheet-form cosmetic preparation according to claim 1, wherein the component (A) contains one or more members selected from the group consisting of ceramides and alcohols having from 16 to 22 carbon atoms.

9. 3. The sheet-type cosmetic preparation according to claim 1, wherein an impregnation rate of the composition is from 300% by mass to 2,000% by mass.

10. A sheet-type cosmetic comprising a composition containing the following components (A), (B), (C) and (D) in a sheet substrate. (A) An oil component having a melting point of 50 to 150°C (B) Ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water

11. A sheet-like cosmetic preparation comprising a sheet substrate impregnated with a composition comprising the following components (A), (B), (C) and (D): (A) An oil component having a melting point of 50 to 150°C: 0.7% by mass or more and 5% by mass or less (B) Ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water

12. A sheet-type cosmetic preparation comprising a sheet substrate impregnated with a composition comprising the following components (A), (B), (C) and (D), wherein the component (C) comprises an alkyl-modified carboxyvinyl polymer. (A) An oil component having a melting point of 50 to 150°C (B) Ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water

13. A sheet-type cosmetic preparation comprising a sheet substrate impregnated with a composition comprising the following components (A), (B), (C) and (D), wherein the component (C) comprises an optionally alkyl-modified carboxyvinyl polymer and a hydroxyalkyl cellulose. (A) An oil component having a melting point of 50 to 150°C (B) Ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water

14. A sheet-type cosmetic preparation comprising a sheet substrate impregnated with a composition comprising the following components (A), (B), (C) and (D), wherein the component (C) comprises an optionally alkyl-modified carboxyvinyl polymer and a hydroxyalkyl cellulose. (A) An oil component having a melting point of 50 to 150°C: 0.7% by mass or more and 5% by mass or less (B) Ionic surfactant (C) Water-soluble polymer 0.05% by mass or more and 1% by mass or less (D) Water

15. A package comprising the sheet-form cosmetic material according to claim 1 or 2 contained within a packaging material.