Secondary battery and method for manufacturing the same
The secondary battery design with a square case and sequential joining of members allows for easy electrode body insertion, ensuring reliable assembly and reduced damage, enhancing manufacturing stability.
Patent Information
- Application Number
- JP2023094760
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2023-06-08
- Publication Date
- 2024-12-19
- Estimated Expiration
- 2043-06-08
AI Technical Summary
The difficulty in inserting an electrode body into a case due to it being surrounded by the case around the axis in the insertion direction, making it hard to assemble the secondary battery reliably.
A secondary battery design with a square case comprising a first member, a second member, a third member, and a fourth member, where the electrode body is inserted between side parts of the first member, and the second member is joined to close the top opening, with the third and fourth members being temporarily joined to the first and second members before fully closing the side openings, allowing for stable assembly.
The design facilitates easy insertion of the electrode body into the case, reducing the risk of deformation or damage, enabling a highly reliable and stable manufacturing process for the secondary battery.
Smart Images

Figure 2024176305000001_ABST
Abstract
Description
[Technical field]
[0001] The present technology relates to a secondary battery and a manufacturing method thereof. [Background technology]
[0002] Japanese Patent No. 4537353 (Patent Document 1) is a prior art document that discloses the configuration of a secondary battery. The secondary battery described in Patent Document 1 includes an electrode group and a case. The electrode group is built into the case. The case has openings at both ends for inserting the electrode group. The electrode group is inserted into the case through the openings. [Prior art documents] [Patent documents]
[0003] [Patent Document 1] Patent No. 4537353 Summary of the Invention [Problem to be solved by the invention]
[0004] In the secondary battery described in Patent Document 1, when the electrode body is inserted through the opening of the case, it is difficult to insert the electrode body into the case because the electrode body is surrounded by the case around the axis in the insertion direction of the electrode body.
[0005] An object of the present technology is to provide a highly reliable secondary battery that can be stably manufactured, and a method for manufacturing the same. [Means for solving the problem]
[0006] The present technology provides the following secondary battery. [1] An electrode body; a rectangular case that includes a bottom surface portion, a top surface portion that faces the bottom surface portion, a pair of first side surface portions that face each other in a first direction, and a pair of second side surface portions that face each other in a second direction perpendicular to the first direction, and that houses the electrode body; a first electrode terminal and a second electrode terminal electrically connected to the electrode body; The case is A first member constituting the bottom surface portion and the pair of first side surface portions; a second member that configures the upper surface portion and is joined to an end portion of the first side surface portion of the first member; a third member that constitutes one of the pair of second side surface portions and is joined to each end of the first member and the second member at an end of a first side in the second direction; a fourth member that configures the other of the pair of second side portions and is joined to the ends of the first member and the second member at ends of a second side opposite to the first side in the second direction, The electrode body is a main body having a first electrode and a second electrode having a polarity different from that of the first electrode; a first electrode tab group electrically connected to the first electrodes and located at an end of the first side relative to the main body; a second electrode tab group electrically connected to the second electrodes and located at an end of the second side relative to the body portion, the first electrode terminal is provided on the third member, the second electrode terminal is provided on the fourth member, the first electrode tab group is electrically connected to the first electrode terminals; The second electrode tab group is electrically connected to the second electrode terminals. [2] the first electrode terminal is attached to the third member in a state of being electrically insulated from the third member; The secondary battery according to [1], wherein the second electrode terminal is attached to the fourth member in a state of being electrically insulated from the fourth member. [3] a first spacer between the electrode body and the third member; The secondary battery according to [1] or [2], further comprising a second spacer between the electrode body and the fourth member. [4] The third member is a first portion that is inserted into the case further than the first side ends of the first member and the second member and faces the first member and the second member from the inside of the case; The secondary battery described in any one of [1] to [3] has a second portion abutting the first side end of the first member and the second member from the second direction.
[0007] The present technology provides the following method for producing a secondary battery. [5] preparing an electrode assembly including a first electrode and a second electrode having a polarity different from that of the first electrode; preparing a first member having a bottom surface portion, a pair of first side surfaces rising from the bottom surface portion and facing each other in a first direction, a top surface opening facing the bottom surface portion, and a pair of side surface openings between both ends of each of the pair of first side surfaces in a second direction perpendicular to the first direction; Providing a second member; attaching a first electrode terminal to a third member; attaching a second electrode terminal to the fourth member; a step of electrically connecting a first electrode tab group electrically connected to the first electrodes of the electrode body to the first electrode terminals; a step of electrically connecting a second electrode tab group electrically connected to the second electrodes of the electrode body to the second electrode terminals; inserting the electrode body between the pair of first side surface portions of the first member; a step of inserting the electrode body between the pair of first side surface portions, and then joining the second member to each end of the pair of first side surface portions and closing the upper surface opening; after the step of closing the top opening, a step of joining the third member to the first member and the second member to close one of the pair of side openings, and joining the fourth member to the first member and the second member to close the other of the pair of side openings, thereby closing the pair of side openings. [6] The method for manufacturing a secondary battery described in [5], wherein at least a part of the step of closing the pair of side openings includes rotating the first member and the second member while holding the first member and the second member rotatably around an axis in the second direction. [7] The method for manufacturing a secondary battery described in [6], wherein at least a part of the step of closing the pair of side openings includes pressing the first member along the first direction to deform the first member and sandwiching the electrode body between the first member. [8] The method for manufacturing a secondary battery described in [6] or [7], wherein the step of closing the pair of side openings includes temporarily joining the third member and the fourth member to the first member and the second member. [9] The method for manufacturing a secondary battery described in any one of [5] to [8], wherein in the step of closing the pair of side openings, at least a portion of the joining of the third member and the joining of the fourth member are performed simultaneously.
[10] The method for manufacturing a secondary battery according to any one of [5] to [9], wherein the step of inserting the electrode body includes inserting the electrode body toward the bottom portion. Effect of the Invention
[0008] According to the present technology, it is possible to provide a highly reliable secondary battery that can be stably manufactured, and a method for manufacturing the same. [Brief description of the drawings]
[0009] [Figure 1] 1 is a front view showing a configuration of a secondary battery according to an embodiment of the present technology; [Diagram 2] 2 is a diagram showing the secondary battery shown in FIG. 1 as viewed from the direction of arrow II. [Diagram 3] 3 is a diagram showing the secondary battery shown in FIG. 1 as viewed from the direction of arrow III. [Figure 4] 4 is a diagram showing the secondary battery shown in FIG. 1 as viewed from the direction of arrow IV. [Diagram 5]2 is a front cross-sectional view of the secondary battery shown in FIG. [Figure 6] FIG. 2 is a front view showing a negative electrode original plate before the negative electrode plate is formed. [Figure 7] 7 is a cross-sectional view taken along the line VII-VII of the negative electrode original plate shown in FIG. 6. [Figure 8] FIG. 2 is a front view showing a negative electrode plate formed from the negative electrode original plate. [Figure 9] FIG. 2 is a front view showing a positive electrode original plate before the positive electrode plate is formed. [Figure 10] 10 is a cross-sectional view taken along the line XX in FIG. 9 . [Figure 11] FIG. 2 is a front view showing a positive electrode plate formed from a positive electrode original plate. [Figure 12] FIG. 2 is a diagram showing an electrode assembly and a current collector taken out from a secondary battery. [Figure 13] FIG. 4 is a front view of a connection structure between a negative electrode tab group and a negative electrode current collector. [Figure 14] FIG. 4 is a cross-sectional view of a connection structure between a negative electrode tab group and a negative electrode current collector. [Figure 15] 13A and 13B are diagrams showing a step of arranging a spacer between a third member and an electrode body. [Figure 16] 1 is a perspective view showing a member configuration of a case of a secondary battery according to an embodiment; [Figure 17] FIG. 2 is a perspective view showing a state in which the members of the case are joined together. [Figure 18] 4 is a cross-sectional view showing a state in which a first member and a second member are fitted together in a case. FIG. [Figure 19] 10 is a cross-sectional view showing a state in which a third member and a fourth member are joined to a first member and a second member of a case. FIG. [Figure 20] 4 is a flowchart showing a method for manufacturing a secondary battery according to an embodiment. [Figure 21] 11 is a perspective view showing a state in which an electrode body is being inserted into a first member of the case. FIG. [Figure 22] 1 is a perspective view showing a method of joining a first member, a second member and a third member of a case included in a secondary battery according to one embodiment. FIG. [Diagram 23]11 is a side view showing a state immediately after starting to join the first and second members and the third member of the case. FIG. [Figure 24] 13 is a side view showing a state in which the short side portions of the first member, the second member, and the third member of the case are joined while being rotated. FIG. [Diagram 25] 13 is a side view showing a state in which the long side portions of the first member, the second member, and the third member of the case are joined while being rotated. FIG. [Figure 26] 11 is a cross-sectional view showing a fitted state between a first member and a second member in a case according to a first modified example of one embodiment. FIG. [Figure 27] 13 is a cross-sectional view showing a fitted state between a first member and a second member in a case according to a second modified example of the embodiment. FIG. [Figure 28] FIG. 11 is a perspective view showing a joined state between a first member and a third member of a case included in a secondary battery according to a third modified example of the embodiment. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0010] Hereinafter, embodiments of the present technology will be described. Note that the same or corresponding parts are denoted by the same reference characters, and description thereof will not be repeated.
[0011] In the embodiments described below, when referring to the number, amount, etc., the scope of the present technology is not necessarily limited to the number, amount, etc., unless otherwise specified. In addition, in the following embodiments, each component is not necessarily essential to the present technology, unless otherwise specified. In addition, the present technology is not necessarily limited to those that achieve all of the effects and advantages mentioned in the present embodiment.
[0012] In this specification, the words "comprise", "include" and "have" are open-ended, i.e., when a certain configuration is included, other configurations may or may not be included.
[0013] Furthermore, when geometric terms and terms expressing positional and directional relationships, such as "parallel," "orthogonal," "45° diagonal," "coaxial," and "along" are used in this specification, these terms allow for manufacturing errors and slight variations. When terms expressing relative positional relationships, such as "upper side" and "lower side," are used in this specification, these terms are used to indicate relative positional relationships in one state, and the relative positional relationships can be inverted or rotated to any angle depending on the installation direction of each mechanism (for example, by turning the entire mechanism upside down).
[0014] In this specification, the term "secondary battery" is not limited to lithium ion batteries, but may include other secondary batteries such as nickel-metal hydride batteries and sodium ion batteries. In this specification, the term "electrode" may collectively refer to a positive electrode and a negative electrode.
[0015] In the drawings, the direction along the winding axis of the electrode body of the secondary battery is the X direction as the second direction, the short side direction of the electrode body that is perpendicular to the second direction and seen from the second direction is the Y direction as the first direction, and the long side direction of the electrode body that is perpendicular to the second direction and seen from the second direction is the Z direction as the third direction. In addition, in order to make the invention easier to understand, the dimensions of each component in the drawings are sometimes shown differently from the actual dimensions.
[0016] In this specification, the first direction (Y direction) may be referred to as the "thickness direction" of the secondary battery or the case body, the second direction (X direction) may be referred to as the "width direction" of the secondary battery or the case body, and the third direction (Z direction) may be referred to as the "height direction" of the secondary battery or the case body.
[0017] (Overall battery configuration) Fig. 1 is a front view of a secondary battery 1 according to the present embodiment. Figs. 2 to 4 are views of the secondary battery 1 shown in Fig. 1 as viewed from the directions of arrows II, III, and IV, respectively. Fig. 5 is a front cross-sectional view of the secondary battery 1 shown in Fig. 1.
[0018] The secondary battery 1 can be mounted in an electric vehicle (BEV: Battery Electric Vehicle), a plug-in hybrid electric vehicle (PHEV: Plug-in Hybrid Electric Vehicle), a hybrid electric vehicle (HEV: Hybrid Electric Vehicle), etc. However, the use of the secondary battery 1 is not limited to being mounted on a vehicle.
[0019] 1 to 5, the secondary battery 1 includes a case 100, an electrode body 200, an electrode terminal 300, and a current collector 400. The case 100 includes a case body 110 configured of a first member 120 and a second member 130, which will be described later, a third member 150, and a fourth member 160.
[0020] When configuring an assembled battery including the secondary batteries 1, multiple secondary batteries 1 are stacked in their thickness direction. The stacked secondary batteries 1 may be constrained in the stacking direction (Y direction) by a restraining member to form a battery module, or the assembled battery may be directly supported on the side surface of a battery pack case without using a restraining member.
[0021] The case body 110 is made of a cylindrical, preferably rectangular, member. This results in a rectangular secondary battery 1. The case body 110 is made of metal. Specifically, the case body 110 is made of aluminum, an aluminum alloy, iron, an iron alloy, or the like.
[0022] 1 and 2, a third member 150 and a fourth member 160 are provided at both ends of the case body 110. The third member 150 and the fourth member 160 function as sealing plates that seal the opening of the case body 110.
[0023] In this embodiment, the case body 110 is formed to be longer in the width direction (X direction) of the secondary battery 1 than in the thickness direction (Y direction) and height direction (Z direction) of the secondary battery 1. The dimension (width) of the case body 110 in the X direction is preferably about 30 cm or more. This allows a relatively large (high capacity) secondary battery 1 to be configured. The dimension (height) of the case body 110 in the Z direction is preferably about 20 cm or less, more preferably about 15 cm or less, and even more preferably about 10 cm or less. This allows a relatively low height (low height) secondary battery 1 to be configured, improving the mountability in a vehicle, for example.
[0024] 3, a first opening 113 is provided at an end of the case body 110 on the first side in the second direction (X direction). The first opening 113 is sealed by a third member 150. The first opening 113 and the third member 150 have a substantially rectangular shape with the Y direction as the short side direction and the Z direction as the long side direction.
[0025] The third member 150 is provided with a negative electrode terminal 301 (first electrode terminal), a liquid inlet 154, and a gas exhaust valve 155. The positions of the negative electrode terminal 301, the liquid inlet 154, and the gas exhaust valve 155 can be changed as appropriate.
[0026] 4, a second opening 114 is provided at an end of a second side opposite to the first side in the second direction (X direction) of the case body 110. The second opening 114 is sealed by a fourth member 160. The second opening 114 and the fourth member 160 have a substantially rectangular shape with the Y direction as the short side direction and the Z direction as the long side direction.
[0027] The fourth member 160 is provided with a positive electrode terminal 302 (second electrode terminal), a liquid inlet 164, and a gas exhaust valve 165. The positions of the positive electrode terminal 302, the liquid inlet 164, and the gas exhaust valve 165 can be changed as appropriate.
[0028] The third member 150 and the fourth member 160 are made of metal. Specifically, the third member 150 and the fourth member 160 are made of aluminum, an aluminum alloy, iron, an iron alloy, or the like.
[0029] In this embodiment, the thickness of each of the third member 150 and the fourth member 160 is greater than the thickness (plate thickness) of the case body 110. This makes it possible to mitigate the thermal influence when forming the bonding portions 170a, 170b, 171a, and 171b described below in the third member 150 and the fourth member 160, which have a smaller occupied volume than the case body 110, and to suppress the formation of holes during bonding.
[0030] The negative electrode terminal 301 is electrically connected to the negative electrode of the electrode body 200. The negative electrode terminal 301 is provided on the outer surface of the third member 150, that is, on the outer surface of the case 100.
[0031] The positive electrode terminal 302 is electrically connected to the positive electrode of the electrode body 200. The positive electrode terminal 302 is provided on the outer surface of the fourth member 160, that is, on the outer surface of the case 100.
[0032] The negative terminal 301 is made of a conductive material (more specifically, a metal), and may be made of, for example, copper or a copper alloy. The outer surface of the negative terminal 301 may be provided with a portion or layer made of aluminum or an aluminum alloy.
[0033] The positive terminal 302 is made of a conductive material (more specifically, a metal), and may be made of, for example, aluminum or an aluminum alloy.
[0034] The liquid inlet holes 154, 164 are sealed with a sealing member (not shown) which may be, for example, a blind rivet or other metal member.
[0035] The gas exhaust valves 155, 165 break when the pressure inside the case 100 reaches or exceeds a predetermined value, and exhaust the gas inside the case 100 to the outside.
[0036] The electrode body 200 is a flat-shaped electrode body having a positive electrode plate and a negative electrode plate, which will be described later. Specifically, the electrode body 200 is a wound-type electrode body in which a band-shaped positive electrode plate and a band-shaped negative electrode plate are both wound via a band-shaped separator (not shown). However, in this specification, the "electrode body" is not limited to a wound-type electrode body, and may be a laminated electrode body in which a plurality of positive electrode plates and a plurality of negative electrode plates are alternately laminated. The band-shaped separator may be composed of, for example, a polyolefin microporous film. The electrode body may include a plurality of positive electrode plates and a plurality of negative electrode plates, and the positive electrode tabs provided on each positive electrode plate may be laminated to form a positive electrode tab group, or the negative electrode tabs provided on each negative electrode plate may be laminated to form a negative electrode tab group.
[0037] 5, case 100 houses electrode assembly 200. Electrode assembly 200 is housed in case 100 so that its winding axis is parallel to the X direction.
[0038] Specifically, one or more wound electrode bodies are housed together with an electrolytic solution (electrolyte) (not shown) inside an insulating sheet (described later) arranged in the case 100. As the electrolytic solution (non-aqueous electrolytic solution), for example, LiPF6 dissolved at a concentration of 1.2 mol / L in a non-aqueous solvent in which ethylene carbonate (EC), ethyl methyl carbonate (EMC), and diethyl carbonate (DEC) are mixed in a volume ratio (25°C) of 30:30:40 can be used. Note that a solid electrolyte may be used instead of the electrolytic solution.
[0039] The electrode body 200 includes a main body portion, a negative electrode tab group 220 (first electrode tab group), and a positive electrode tab group 250 (second electrode tab group).
[0040] The main body includes a negative electrode plate 210 (first electrode) and a positive electrode plate 240 (second electrode) which will be described later. The negative electrode tab group 220 is located at the end of a first side of the electrode body 200 in the second direction (X direction) with respect to the main body. The first side in this embodiment is the third member 150 side. The positive electrode tab group 250 is located at the end of a second side in the second direction (X direction) with respect to the main body. The second side in this embodiment is the fourth member 160 side.
[0041] The negative electrode tab group 220 and the positive electrode tab group 250 are formed so as to protrude from the central portion of the electrode body 200 toward the third member 150 or the fourth member 160, respectively.
[0042] The current collector 400 includes a negative electrode current collector 410 (first current collector) and a positive electrode current collector 420 (second current collector). The negative electrode current collector 410 and the positive electrode current collector 420 are each made of a plate-shaped member. The electrode body 200 is electrically connected to the negative electrode terminal 301 and the positive electrode terminal 302 via the current collector 400.
[0043] The negative electrode current collector 410 is disposed on the third member 150 via a resin insulating member. The negative electrode current collector 410 is electrically connected to the negative electrode tab group 220 and the negative electrode terminal 301. As a result, the negative electrode tab group 220 is electrically connected to the negative electrode terminal 301. The negative electrode current collector 410 is made of a conductive material (more specifically, a metal) and may be made of, for example, copper or a copper alloy.
[0044] The positive electrode current collector 420 is disposed on the fourth member 160 via a resin insulating member. The positive electrode current collector 420 is electrically connected to the positive electrode tab group 250 and the positive electrode terminal 302. As a result, the positive electrode tab group 250 is electrically connected to the positive electrode terminal 302. The positive electrode current collector 420 is made of a conductive material (more specifically, a metal), and may be made of, for example, aluminum or an aluminum alloy.
[0045] (Configuration of electrode body 200) FIG. 6 is a front view showing the negative electrode original plate 210S before the negative electrode plate 210 (first electrode) is formed, FIG. 7 is a cross-sectional view taken along line VII-VII of the negative electrode original plate 210S shown in FIG. 6, and FIG. 8 is a front view showing the negative electrode plate 210 formed from the negative electrode original plate 210S.
[0046] The negative electrode plate 210 is manufactured by processing a negative electrode original plate 210S. As shown in Figures 6 and 7, the negative electrode original plate 210S includes a negative electrode core 211 and a negative electrode active material layer 212. The negative electrode core 211 is a copper foil or a copper alloy foil.
[0047] A negative electrode active material layer 212 is formed on both sides of the negative electrode core 211 except for one end portion. The negative electrode active material layer 212 is formed by applying a negative electrode active material layer slurry with a die coater.
[0048] The negative electrode active material layer slurry is prepared by kneading graphite as the negative electrode active material, styrene butadiene rubber (SBR) and carboxymethyl cellulose (CMC) as binders, and water as a dispersion medium so that the mass ratio of graphite:SBR:CMC is approximately 98:1:1.
[0049] The negative electrode core 211 coated with the negative electrode active material layer slurry is dried to remove water contained in the negative electrode active material layer slurry, thereby forming the negative electrode active material layer 212. Furthermore, the negative electrode active material layer 212 is compressed to form a negative electrode original plate 210S including the negative electrode core 211 and the negative electrode active material layer 212. The negative electrode original plate 210S is cut into a predetermined shape to form the negative electrode plate 210. The negative electrode original plate 210S can be cut by laser processing using energy beam irradiation, die processing, cutter processing, or the like.
[0050] As shown in FIG. 8, a plurality of negative electrode tabs 230 made of a negative electrode core 211 are provided at one end in the width direction of a negative electrode plate 210 formed from a negative electrode original plate 210S. When the negative electrode plate 210 is wound, the plurality of negative electrode tabs 230 are stacked to form a negative electrode tab group 220. As a result, the negative electrode tab group 220 is connected to the negative electrode plate 210 (first electrode). The position and length in the protruding direction of each of the plurality of negative electrode tabs 230 are appropriately adjusted in consideration of the state in which the negative electrode tab group 220 is connected to the negative electrode current collector 410. The shape of the negative electrode tab 230 is not limited to the one exemplified in FIG. 8.
[0051] FIG. 9 is a front view showing the positive electrode original plate 240S before the positive electrode plate 240 (second electrode) is formed, FIG. 10 is a cross-sectional view taken along line XX of the positive electrode original plate 240S shown in FIG. 9, and FIG. 11 is a front view showing the positive electrode plate 240 formed from the positive electrode original plate 240S.
[0052] The positive electrode plate 240, which is the second electrode, has a polarity different from that of the negative electrode plate 210, which is the first electrode. The positive electrode plate 240 is manufactured by processing a positive electrode original plate 240S. As shown in Fig. 9 and Fig. 10, the positive electrode original plate 240S includes a positive electrode core body 241, a positive electrode active material layer 242, and a positive electrode protective layer 243. The positive electrode core body 241 is an aluminum foil or an aluminum alloy foil.
[0053] A positive electrode active material layer 242 is formed on both sides of the positive electrode core 241 except for one end portion. The positive electrode active material layer 242 is formed on the positive electrode core 241 by applying a positive electrode active material layer slurry with a die coater.
[0054] The positive electrode active material layer slurry is prepared by kneading lithium nickel cobalt manganese composite oxide as the positive electrode active material, polyvinylidene fluoride (PVdF) as a binder, a carbon material as a conductive material, and N-methyl-2-pyrrolidone (NMP) as a dispersion medium, so that the mass ratio of lithium nickel cobalt manganese composite oxide:PVdF:carbon material is approximately 97.5:1:1.5.
[0055] The positive electrode protective layer 243 is in contact with the positive electrode core 241 and is formed at one end in the width direction of the positive electrode active material layer 242. The positive electrode protective layer 243 is formed on the positive electrode core 241 by applying a positive electrode protective layer slurry with a die coater. The positive electrode protective layer 243 has a larger electric resistance than the positive electrode active material layer 242.
[0056] The positive electrode protective layer slurry is prepared by kneading alumina powder, a carbon material as a conductive material, PVdF as a binder, and NMP as a dispersion medium so that the mass ratio of alumina powder:carbon material:PVdF is approximately 83:3:14.
[0057] The positive electrode core 241 coated with the positive electrode active material layer slurry and the positive electrode protective layer slurry is dried, and the NMP contained in the positive electrode active material layer slurry and the positive electrode protective layer slurry is removed to form the positive electrode active material layer 242 and the positive electrode protective layer 243. Furthermore, the positive electrode active material layer 242 is compressed to form a positive electrode original plate 240S including the positive electrode core 241, the positive electrode active material layer 242, and the positive electrode protective layer 243. The positive electrode original plate 240S is cut into a predetermined shape to form the positive electrode plate 240. The positive electrode original plate 240S can be cut by laser processing using energy beam irradiation, die processing, cutter processing, or the like.
[0058] As shown in FIG. 11, a plurality of positive electrode tabs 260 made of a positive electrode core 241 are provided at one end in the width direction of the positive electrode plate 240 formed from the positive electrode original plate 240S. When the positive electrode plate 240 is wound, the plurality of positive electrode tabs 260 are stacked to form a positive electrode tab group 250. As a result, the positive electrode tab group 250 is connected to the positive electrode plate 240 (second electrode). The position and length in the protruding direction of each of the plurality of positive electrode tabs 260 are appropriately adjusted in consideration of the state in which the positive electrode tab group 250 is connected to the positive electrode current collector 420. The shape of the positive electrode tab 260 is not limited to the one exemplified in FIG. 11.
[0059] A positive electrode protection layer 243 is provided at the base of each of the positive electrode tabs 260. The positive electrode protection layer 243 does not necessarily have to be provided at the base of the positive electrode tab 260.
[0060] In a typical example, the thickness of the negative electrode tab 230 (one piece) is smaller than the thickness of the positive electrode tab 260 (one piece). In this case, the thickness of the negative electrode tab group 220 is smaller than the thickness of the positive electrode tab group 250.
[0061] (Connection structure between electrode body 200 and current collector 400) Fig. 12 is a diagram showing the electrode body 200 and the current collector 400 taken out from the secondary battery 1. As shown in Fig. 12, the electrode body 200 is formed by stacking two electrode bodies 201, 202, each of which is a wound type electrode body. In the example shown in Fig. 12, a structure in which two wound type electrode bodies are stacked is shown, but the electrode body 200 may be composed of one wound type electrode body, may be composed of three or more wound type electrode bodies, or may be composed of a laminated type electrode body.
[0062] The negative electrode tab group 220 is joined to the negative electrode current collector 410 at joint points 434 , and the positive electrode tab group 250 is joined to the positive electrode current collector 420 at joint points 454 .
[0063] (Insulation sheet composition) Between the electrode body 200 and the case body 110, an insulating sheet (electrode body holder) made of resin (not shown) is disposed.
[0064] The insulating sheet may be made of, for example, resin. More specifically, the material of the insulating sheet may be, for example, polypropylene (PP), polyethylene terephthalate (PET), polyphenylene sulfide (PPS), polyimide (PI), or polyolefin (PO).
[0065] The insulating sheet does not necessarily have to cover the entire surface of the electrode body 200. The insulating sheet preferably covers about 50% or more, and more preferably about 70% or more, of the area of the outer surface of the electrode body. Of the six faces of the substantially rectangular parallelepiped (flat) electrode body 200, the insulating sheet preferably covers the entire four faces other than at least the two faces on which the negative electrode tab group 220 and the positive electrode tab group 250 are formed, respectively.
[0066] Fig. 13 is a front view of the connection structure between the negative electrode tab group and the negative electrode current collector, and Fig. 14 is a cross-sectional view of the connection structure between the negative electrode tab group and the negative electrode current collector.
[0067] 13 and 14, the negative electrode current collector 410 electrically connects the negative electrode terminal 301 and the negative electrode tab group 220. The negative electrode current collector 410 in this embodiment is connected to the negative electrode terminal 301 between the electrode body 200 and the third member 150.
[0068] The negative electrode current collector 410 includes a first conductive member 430 and a second conductive member 440. The first conductive member 430 and the second conductive member 440 are joined at a joint portion 433. The first conductive member 430 and the second conductive member 440 are joined by, for example, laser welding.
[0069] The first conductive member 430 is joined to the negative electrode tab group 220 at a joint 434. The joint 434 can be formed by, for example, ultrasonic welding, resistance welding, laser welding, crimping, etc. In the present embodiment, the first conductive member 430 and the negative electrode tab group 220 are joined by, for example, ultrasonic bonding.
[0070] Second conductive member 440 is connected to negative terminal 301 at joint 441. Joint 441 may be formed by, for example, ultrasonic welding, resistance welding, laser welding, crimping, or the like. In this embodiment, negative terminal 301 and second conductive member 440 are joined by, for example, providing a through hole in second conductive member 440, inserting negative terminal 301 into the through hole, crimping negative terminal 301 onto second conductive member 440, and then welding the crimped portion to second conductive member 440.
[0071] The first conductive member 430 has a first planar portion 431 and a second planar portion 432. The first planar portion 431 is connected to the second conductive member 440. The second planar portion 432 is connected to the negative electrode tab group 220. The second planar portion 432 is disposed so as to extend along the third member 150.
[0072] A step portion 435 is provided between the first flat portion 431 and the second flat portion 432. The step portion 435 makes the positions of the first flat portion 431 and the second flat portion 432 in the second direction (X direction) different after the secondary battery 1 is assembled. This allows the first flat portion 431 and the second flat portion 432 to be arranged side by side in one direction. The step portion 435 extends along the third direction (Z direction).
[0073] A first insulating member 510 (resin member) is disposed between the negative electrode terminal 301 and the third member 150. A second insulating member 520 (resin member) is disposed between the third member 150 and the first conductive member 430 and the second conductive member 440. The first insulating member 510 and the second insulating member 520 may be an integrated part.
[0074] The negative electrode terminal 301 is attached to the third member 150 via the first insulating member 510. Thus, the negative electrode terminal 301 is attached to the third member 150 (third member) in a state of being electrically insulated from the third member 150 (third member). The negative electrode terminal 301 is provided so as to be exposed to the outside of the third member 150 and to reach the second conductive member 440 of the negative electrode current collector 410 provided on the inner surface side of the third member 150.
[0075] The procedure for assembling each part is as follows: first, the negative electrode terminal 301 and the second conductive member 440 are attached to the third member 150 together with the first insulating member 510 and the second insulating member 520. Next, the first conductive member 430 electrically connected to the electrode body 200 is attached to the second conductive member 440. At this time, the first conductive member 430 is placed on the first insulating member 510 so that a portion of the first conductive member 430 overlaps with the second conductive member 440. Next, the first conductive member 430 and the second conductive member 440 are connected by welding at a joint 434.
[0076] However, the negative electrode terminal 301 may be electrically connected to the third member 150. In addition, the third member 150 may serve as the negative electrode terminal 301.
[0077] 13 and 14, the negative electrode current collector 410 is illustrated as being made up of two components (the first conductive member 430 and the second conductive member 440), but the negative electrode current collector 410 may be made up of a single component.
[0078] 13 and 14 show the connection structure on the negative electrode side, but the basic connection structure on the positive electrode side is similar to that on the negative electrode side. Specifically, an insulating member (not shown) is disposed between the positive electrode terminal 302 and the fourth member 160. The positive electrode current collector 420 is attached to the inner surface side of the fourth member 160 via a resin insulating member. The insulating member is provided so as to reach the inner surface side of the fourth member 160 from the outer surface side through a through hole provided in the fourth member 160.
[0079] The positive electrode terminal 302 is attached to the fourth member 160 via an insulating member. As a result, the positive electrode terminal 302 is attached to the fourth member 160 (fourth member) in a state in which it is electrically insulated from the fourth member 160 (fourth member).
[0080] However, the positive electrode terminal 302 may be electrically connected to the fourth member 160. In addition, the fourth member 160 may serve as the positive electrode terminal 302.
[0081] FIG. 15 is a diagram showing a process of placing a first spacer 600 between the third member 150 and the electrode body 200. As shown in FIG.
[0082] 15, the negative electrode tab group 220 arranged from the electrode body 200 toward the third member 150 is curved from the center in the Y direction of the third member 150 toward the end, and then bent back toward the center. A first spacer 600 is provided to accommodate the curved portion of the negative electrode tab group 220. The first spacer 600 is disposed between the electrode body 200 and the third member 150 (sealing plate).
[0083] The first spacer 600 includes a first part 610 and a second part 620. The first part 610 and the second part 620 are engaged with each other by engagement parts 630a, 630b when the first part 610 and the second part 620 are slid along the Y direction from the end side toward the center side of the third member 150. As a result, the first spacer 600 is fixed to the third member 150 via the first insulating member 510, and the positional stability of the first spacer 600 is increased.
[0084] The secondary battery 1 according to this embodiment further includes a second spacer (not shown). The second spacer is disposed between the electrode body and the fourth member 160 (sealing plate). The second spacer may have a similar structure to the first spacer 600. The first spacer 600 and the second spacer may have different shapes.
[0085] (Components of case 100) Fig. 16 is a perspective view showing a member configuration of a case included in a secondary battery according to one embodiment, and Fig. 17 is a perspective view showing a state in which members of the case are joined together.
[0086] As shown in FIGS. 16 and 17, case 100 according to the present embodiment includes a bottom surface portion 121, an upper surface portion, a pair of first side surface portions 122, and a pair of second side surface portions 140. As shown in FIG.
[0087] Case 100 in this embodiment includes a first member 120, a second member 130, a third member 150, and a fourth member 160, which correspond to the respective parts of case 100 described above. First member 120 and second member 130 configure case body 110.
[0088] The first member 120 constitutes a bottom surface portion 121 and a pair of first side surface portions 122. The first member 120 is formed by bending a single plate-shaped member.
[0089] The second member 130 constitutes an upper surface portion. The third member 150 (sealing plate) constitutes one of the pair of second side surface portions 140. The fourth member 160 (sealing plate) constitutes the other of the pair of second side surface portions 140.
[0090] The bottom surface portion 121 has a longitudinal direction in the second direction (X direction) and a lateral direction in the first direction (Y direction).
[0091] The pair of first side surface portions 122 face each other in the first direction (Y direction). The pair of first side surface portions 122 have an area larger than that of the bottom surface portion 121 and the second member 130 (upper surface portion).
[0092] The second member 130 has a longitudinal direction in the second direction (X direction) and a lateral direction in the first direction (Y direction).
[0093] The second member 130 is joined to an end of the first side surface portion 122 of the first member 120. The second member 130 is joined to one 123 of the pair of first side surface portions by a joint 115a. The second member 130 is also joined to the other 124 of the pair of first side surface portions by a joint 115b.
[0094] The pair of second side surface portions 140 face each other in the second direction (X direction). The third member 150 (one of the pair of second side surface portions 140) is joined to the ends of the first member 120 and the second member 130 at the ends on the first side in the second direction (X direction). The third member 150 is joined to the first member 120 by a joint 170a. The third member 150 is joined to the second member 130 by a joint 170b.
[0095] The fourth member 160 (the other of the pair of second side portions 140) is joined to the ends of the first member 120 and the second member 130 at the ends of the second side opposite to the first side in the second direction (X direction). The fourth member 160 is joined to the first member 120 by a joint 171a. The fourth member 160 is joined to the second member 130 by a joint 171b.
[0096] FIG. 18 is a cross-sectional view showing a state in which the first member and the second member in the case are fitted together.
[0097] 18, a pair of first side surface portions 122 of the first member 120 are partially bent at the end portions on the second member 130 side. The pair of first side surface portions 122 have inner surfaces 125 and a first abutment surface 126. The second member 130 has an outer circumferential portion 131 and a second abutment surface 132.
[0098] The inner surface 125 fits into the outer circumferential portion 131. This positions the second member 130 relative to the first member 120 in the first direction (Y direction). The first abutment surface 126 and the second abutment surface 132 abut against each other, so that the second member 130 is positioned relative to the first member 120 in the third direction (Z direction).
[0099] (Joining state between components of case 100) FIG. 19 is a cross-sectional view showing a state in which a third member and a fourth member are joined to a first member and a second member of the case.
[0100] As shown in FIG. 19, the case body 110 further has an outer circumferential surface portion 116, a first end surface 117, and a second end surface 118.
[0101] The outer peripheral surface portion 116 extends around an axis in the second direction (X direction). The outer peripheral surface portion 116 also extends along the second direction (X direction). Note that the outer peripheral surface portion 116 extends approximately parallel to the second direction (X direction), but may be inclined from the second direction (X direction) due to processing errors during the manufacture of the case body 110.
[0102] The first end surface 117 is located at an end portion on the first side in the second direction (X direction). The first end surface 117 extends in a direction intersecting the second direction (X direction). In the present embodiment, the first end surface 117 extends in a direction substantially perpendicular to the second direction (X direction). Since the first end surface 117 extends in a direction substantially perpendicular to the second direction (X direction), the third member 150 is easily brought into contact with the first end surface 117.
[0103] The second end surface 118 is located at an end on the second side in the second direction (X direction). The second end surface 118 extends in a direction intersecting the second direction (X direction). In this embodiment, the second end surface 118 extends in a direction substantially perpendicular to the second direction (X direction). Since the second end surface 118 extends in a direction substantially perpendicular to the second direction (X direction), the fourth member 160 is likely to come into contact with the second end surface 118.
[0104] The third member 150 has a first covering portion 157. The first covering portion 157 covers at least a portion of the first end face 117 from the second direction (X direction). In the present embodiment, the first covering portion 157 covers the entire surface of the first end face 117 from the second direction (X direction). This makes it easy to stably position the third member 150 with respect to the case body 110.
[0105] The fourth member 160 has a second covering portion 167. The second covering portion 167 covers at least a portion of the second end face 118 from the second direction (X direction). In the present embodiment, the second covering portion 167 covers the entire surface of the second end face 118 from the second direction (X direction). For this reason, the fourth member 160 can be easily positioned with respect to the case body 110 in a stable manner.
[0106] Bonding portions 170a, 170b are formed between the outer peripheral surface portion 116 and the first covering portion 157. Bonding portions 171a, 171b are formed between the outer peripheral surface portion 116 and the second covering portion 167. These bonding portions 170a, 170b, 171a, 171b are formed by, for example, laser welding. Note that the bonding portions 170a, 170b, 171a, 171b are not limited to being laser welded, and may be formed by other bonding methods such as ultrasonic welding or resistance welding.
[0107] The joints 170a, 170b, 171a, and 171b are located on the outer circumferential surface portion 116 of the case body 110. Therefore, the joints 170a, 170b, 171a, and 171b can be disposed at locations farther away from the insulating members provided between the electrode terminal 300 and each of the pair of second side surface portions 140 than when the entire third member and the fourth member are inserted into the inner circumferential surface of the case body and joints are formed between the outer circumferential surfaces of the third member and the fourth member and the inner circumferential surface of the case body. This makes it possible to suppress the thermal effect on the insulating members during joining.
[0108] In the present embodiment, the case 100 is configured from four members, namely, the first member 120, the second member 130, the third member 150, and the fourth member 160, but is not limited to this configuration. The case may be configured from five or six members in which the bottom surface portion 121 and the pair of first side surface portions 122 of the first member 120 are provided separately and joined together. Furthermore, the six faces that constitute the rectangular outer surface of the case may be configured from seven or more members.
[0109] Hereinafter, a method for manufacturing a secondary battery according to this embodiment will be described. Fig. 20 is a flowchart showing a method for manufacturing a secondary battery according to one embodiment. Fig. 21 is a perspective view showing a state in which an electrode body is inserted into a first member of a case.
[0110] 20 and 21, in the method for manufacturing the secondary battery 1 according to the present embodiment, first, the electrode body 200 is prepared (step S1). A negative electrode current collector 410 is connected to the negative electrode tab group 220, and a positive electrode current collector 420 is connected to the positive electrode tab group 250.
[0111] Next, the first member 120 is prepared (step S2). The first member 120 is formed by bending a single plate-shaped member.
[0112] First member 120 is formed by bending a single plate-like member, and has a bottom surface portion 121, a pair of first side surface portions 122, an upper surface opening 127, and a pair of side surface openings 128 formed therein.
[0113] The pair of first side surface portions 122 rise from the bottom surface portion 121. The pair of first side surface portions 122 face each other in a first direction (Y direction). The top surface opening 127 faces the bottom surface portion 121. The pair of side surface openings 128 are located between both ends of each of the pair of first side surface portions 122 in the second direction (X direction).
[0114] Next, the second member 130 is prepared (step S3). In the present embodiment, the second member 130 is subjected to a bending process (not shown) in order to fit with the first member 120. This allows the second member 130 to fit into the upper surface opening 127 and be joined.
[0115] Next, the negative electrode terminal 301 (first electrode terminal) is attached to the third member 150 (sealing plate) (step S4). Next, the positive electrode terminal 302 (second electrode terminal) is attached to the fourth member 160 (sealing plate) (step S5).
[0116] Next, the negative electrode terminal 301 (first electrode terminal) and the electrode body 200 are electrically connected (step S6). In this embodiment, the negative electrode tab group 220 connected to the negative electrode plate 210 of the electrode body 200 and the negative electrode terminal 301 are electrically connected.
[0117] Next, the positive electrode terminal 302 (second electrode terminal) is electrically connected to the electrode body 200 (step S7). In this embodiment, the positive electrode tab group 250 connected to the positive electrode plate 240 of the electrode body 200 is electrically connected to the positive electrode terminal 302.
[0118] Next, the electrode body 200 is inserted between the pair of first side surface portions 122 of the first member 120 (step S8). The electrode body 200 is preferably inserted in the third direction (Z direction) from between the pair of first side surface portions 122 toward the bottom surface portion 121 (toward the DR1 direction in FIG. 21). The electrode body 200 is not limited to being inserted from the third direction (Z direction), and may be inserted from the second direction (X direction) or obliquely on the XZ plane. In addition, it is preferable to insert the electrode body 200 between the pair of first side surface portions 122 of the first member 120 in a state in which the electrode body 200 is covered with a resin insulating sheet (electrode body holder). For example, in the electrode body 200 after being inserted into the first member 120, it is preferable to cover the surface that will face the bottom surface portion 121, the surface that will face one of the first side surface portions 122, and the surface that will face the other first side surface portion 122 with an insulating sheet. Furthermore, the surface of the electrode body 200 that faces the upper opening 127 can be covered with an insulating sheet.
[0119] Next, after inserting the electrode body 200 between the pair of first side surface portions 122, the second member 130 is joined to each end of the pair of first side surface portions 122, and the upper surface opening 127 is closed (step S9). Each of the pair of first side surface portions 122 and the second member 130 are welded by, for example, a laser. Note that the joining of each of the pair of first side surface portions 122 and the second member 130 may be performed by ultrasonic welding, resistance welding, or the like.
[0120] The first spacer 600 and the second spacer are disposed between the electrode body 200 and the third and fourth members 150 and 160 after the electrode tabs are folded at any timing in the above-mentioned process.
[0121] 22 is a perspective view showing a method of joining a first member, a second member and a third member of a case included in a secondary battery according to one embodiment, in which joining on the negative electrode side is illustrated.
[0122] Next, as shown in FIGS. 20 and 22, before the step of closing the pair of side openings 128, the third member 150 and the fourth member 160 are temporarily joined to the first member 120 and the second member 130 (step S10).
[0123] The temporary joints are formed by joining the first and second members 120 and 130 at points among the joints, and temporarily fastening the third and fourth members 150 and 160 together. The temporary joints in this embodiment are formed, for example, by joining the first and second members 120 and 130 at one point on each of the four sides at the end of each of them. The temporary joints may be, for example, relatively short (for example, less than 1 cm) linear joints. Furthermore, temporary joints are not necessarily required.
[0124] 20 to 22, after the step of closing the top opening 127, the pair of side openings 128 are closed (step S11). Specifically, a third member 150 and a fourth member 160 are joined to the ends of the first member 120 and the second member 130 at both ends in the second direction (X direction), respectively, to close the pair of side openings 128.
[0125] The third member 150 is abutted against the first end face 117 so as to cover at least a portion of the first end face 117 from the second direction (X direction), and a joining process is performed from the outer periphery side around the axis in the second direction (X direction) to join the third member 150 and the outer periphery surface portion 116 of the case body 110.
[0126] Similar to the joining of the third member 150, the fourth member 160 is abutted against the second end face 118 so as to cover at least a portion of the second end face 118 from the second direction (X direction), and a joining process is performed from the outer periphery side around the axis in the second direction (X direction) to join the fourth member 160 and the outer periphery surface portion 116 of the case body 110.
[0127] In the step of closing the pair of side openings 128, it is preferable that at least a part of the joining of the third member 150 and the fourth member 160 is performed simultaneously. In the present embodiment, the joining of the third member 150 and the joining of the fourth member 160 are performed so that the joining starts and ends at approximately the same time.
[0128] Note that the joining steps of the third member 150 and the fourth member 160 may partially overlap. Furthermore, these joining steps may start simultaneously but not necessarily end simultaneously, or may not start simultaneously but end simultaneously. When these joining steps partially overlap, it does not matter whether the joining of the third member 150 or the joining of the fourth member 160 is performed first.
[0129] Fig. 23 is a side view showing the state immediately after starting to join the first and second members of the case with the third member. Fig. 24 is a side view showing the state in which the short side portions of the first and second members of the case and the third member are joined while rotating. Fig. 25 is a side view showing the state in which the long side portions of the first and second members of the case and the third member are joined while rotating. Only the first member 120 and the second member 130 are shown in Figs. 23 to 25.
[0130] As shown in FIG. 22 to FIG. 25, in at least a part of the process of closing the pair of side openings 128, the first member 120 and the second member 130 joined to each other are rotated (in the r1 direction in FIG. 22) in a state where they are held rotatably around an axis in the second direction (X direction), and a joining process (for example, laser welding) is performed. In this embodiment, in all of the processes of closing the pair of side openings 128, the first member 120 and the second member 130 are rotated and welding is performed by the laser 3. During joining, the case body 110 is rotated continuously. The focal length of the laser 3 is adjusted according to the continuous rotation of the case body 110 by moving the joining device 2. The joining process may be performed while changing the rotation speed of the first member 120 and the second member 130. Furthermore, after the joining process, the first member 120 and the second member 130 may be rotated and then the joining process may be performed again in a state in which the first member 120 and the second member 130 are stopped.
[0131] The first member 120 is pressed by a manufacturing device (not shown) until it is deformed along the first direction (Y direction). As a result, the electrode body 200 is sandwiched by the first member 120. At this time, it is preferable to elastically deform the first member 120. An insulating sheet may be disposed between the first member 120 and the electrode body 200.
[0132] The six faces constituting the outer surface of the rectangular case 100 are closed by joining the components of the case 100 as described above. After the above steps, electrolyte is poured into the case 100 through a pouring hole, and secondary battery 1 is completed.
[0133] The order of the steps in the method for manufacturing the secondary battery 1 is not limited, except where the order of the steps is clearly indicated.
[0134] A secondary battery according to a modified example of the embodiment will be described below. The secondary battery according to this modified example has a case structure different from that of the secondary battery 1 according to the embodiment of the present technology, and therefore the description of the same configuration as that of the secondary battery 1 according to the embodiment of the present technology will not be repeated.
[0135] FIG. 26 is a cross-sectional view showing a fitted state between a first member and a second member in a case according to a first modified example of one embodiment.
[0136] As shown in Fig. 26, the case 100A included in the secondary battery according to the first modification includes a first member 120A and a second member 130A. The first member 120A has a pair of first side surface portions 122A. The pair of first side surface portions 122A has an inner side surface 125A and a first abutment surface 126A. The second member 130A is partially bent at an end portion in the first direction (Y direction). The second member 130A has a vertical wall portion 133A and a second abutment surface 132A.
[0137] The inner surface 125A fits into the vertical wall portion 133A. This positions the second member 130A relative to the first member 120A in the first direction (Y direction). The first abutment surface 126A and the second abutment surface 132A abut against each other, so that the second member 130A is positioned relative to the first member 120A in the third direction (Z direction). The first member 120A and the second member 130A are joined at joints 115c and 115d.
[0138] FIG. 27 is a cross-sectional view showing a fitted state between a first member and a second member in a case according to a second modified example of an embodiment.
[0139] 27, the case 100B included in the secondary battery according to the second modification includes a first member 120B and a second member 130B. The first member 120B has a pair of first side surface portions 122B. The pair of first side surface portions 122B have inner surfaces 125B. The second member 130B has an outer circumferential portion 131B.
[0140] The inner surface 125B fits into the outer circumferential portion 131B. This positions the second member 130B relative to the first member 120B in the first direction (Y direction). The first member 120B and the second member 130B are joined at joints 115e and 115f.
[0141] Fig. 28 is a perspective view illustrating a joined state between a first member and a third member of a case included in a secondary battery according to a third modified example of an embodiment. Fig. 28 illustrates the joining between the first member and the third member.
[0142] 28, a secondary battery 1C according to this modification includes a case 100C. The case 100C includes a first member 120C, a second member, and a third member 150C.
[0143] The first member 120C and the second member have an inner circumferential surface portion 119C. The inner circumferential surface portion 119C extends around an axis in the second direction (X direction).
[0144] The third member 150C has a first portion 151C and a second portion 152C.
[0145] The first portion 151C enters the inside of the case 100C from the first side ends of the first member 120C and the second member. The first portion 151C faces the first member 120C and the second member from the inside of the case 100C. In this embodiment, the first portion 151C faces the first member 120C and the inner circumferential surface portion 119C of the second member from the inside of the case 100C.
[0146] The second portion 152C abuts against the ends of the first member 120C and the second member on the first side from the second direction (X direction).
[0147] A joint 170C is formed between the third member 150C and the outer circumferential surface portion 116C. The joint 170C is a welded portion formed by laser welding. In the step of closing the pair of side openings, the third member 150C and the outer circumferential surface portion 116C are welded together by irradiating a laser from the outer circumferential side around the axis in the second direction (X direction) (DR2 direction in FIG. 28).
[0148] Since the first portion 151C is disposed so as to fit into the inner circumferential surface portion 119C, the position of the third member 150C is stabilized relative to the first member 120C and the second member, so that laser welding can be performed stably.
[0149] The third member 150C has a protruding portion 153C on its outer surface. The protruding portion 153C is provided adjacent to the second portion 152C. This prevents the periphery of the second portion 152C of the third member 150C from melting excessively during laser welding, thereby preventing welding sagging or the like from occurring on the outer surface side.
[0150] In FIG. 28, the configuration of the negative electrode side is shown, but the positive electrode side may have the same structure as the negative electrode side. The fourth member may also have the same configuration as the third member 150C. Specifically, the fourth member has a third portion and a fourth portion. The third portion enters the inside of the case 100C from the end of the first member 120C and the second member on the second side. The third portion faces the first member 120C and the second member from the inside of the case 100C. The fourth portion abuts against the end of the first member 120C and the second member on the second side from the second direction (X direction). A joint is formed between the fourth member and the outer peripheral surface portion 116C. The joint is a welded portion formed by laser welding. The fourth member and the outer peripheral surface portion 116C are welded.
[0151] When the joint 170C is formed by laser welding, even if the laser enters the first member 120C and the inner surface portion 119C of the second member from the outer periphery side around the axis in the second direction (X direction) (in FIG. 28, the DR2 direction), the laser can be received by the first portion 151C and the third portion, thereby preventing the laser from missing during laser welding.
[0152] In the secondary battery 1 and its manufacturing method according to an embodiment of the present technology, the case 100 is configured to include a first member 120 and a second member 130 divided around an axis in the second direction (X direction), so that when the electrode body 200 is inserted into the case 100, the electrode body 200 can be inserted into the inner region of the first member 120 from between a pair of first side portions 122 in the first member 120. As a result, compared to a case in which the electrode body is inserted from openings located at both ends of the rectangular cylindrical case and the electrode body is surrounded by the case over the entire circumference around the axis in the insertion direction of the electrode body, the area in which the electrode body 200 is surrounded by the case 100 around the axis in the insertion direction of the electrode body 200 can be reduced, so that the electrode body 200 can be easily inserted into the case 100. Therefore, a highly reliable secondary battery 1 can be stably manufactured. For example, unintended deformation or damage to the negative electrode tab group 220 or the positive electrode tab group 250 can be suppressed, or unintended deformation or damage to the electrode body 200 can be effectively suppressed.
[0153] The structure of the case 100 included in the secondary battery 1 according to this embodiment is particularly effective when the width of the electrode body 200 in the second direction (X direction) is wide (20 cm or more, more preferably 25 cm).
[0154] In a secondary battery 1 and a manufacturing method thereof according to one embodiment of the present technology, by providing a negative electrode tab group 220 (first electrode tab group) and a positive electrode tab group 250 (second electrode tab group) of the electrode body 200, the energy density of the electrode body 200 can be improved, and therefore a secondary battery 1 with excellent output characteristics can be constructed.
[0155] In a secondary battery 1 and a manufacturing method thereof according to one embodiment of the present technology, by providing a negative electrode terminal 301 (first electrode terminal) and a positive electrode terminal 302 (second electrode terminal) on the third member 150 and the fourth member 160, respectively, the secondary battery 1 can be made low-profile when the secondary battery 1 is placed on the bottom portion 121 of the case 100 as a mounting surface.
[0156] In a secondary battery 1 according to one embodiment of the present technology, the negative terminal 301 is attached to the third member 150 while being electrically insulated from the third member 150, and the positive terminal 302 is attached to the fourth member 160 while being electrically insulated from the fourth member 160, thereby reducing the number of locations in the secondary battery 1 that require insulation.
[0157] In the secondary battery 1 according to an embodiment of the present technology, the first spacer 600 and the second spacer can be used to prevent the electrode body 200 from being too close to the third member 150 and the fourth member 160. This allows the electrode body 200 to be configured not to be located directly below the joining positions of the first member 120 and the second member 130 and the third member 150 and the fourth member 160, so that even if a laser for joining enters the inside of the case 100 between these members, damage to the electrode body 200 can be suppressed.
[0158] In a modified example of the secondary battery 1 according to the embodiment of the present technology, the third member 150C is provided with a first portion 151C facing the inner circumferential surface portion 119C of the first member 120C and the second member, and the third member 150C is provided with a second portion 152C abutting the end faces of the first member 120C and the second member, so that when these are joined, the third member 150C can be stably abutted against the first member 120C and the second member. This allows the joint between the first member 120C and the second member and the third member 150C to be stably formed.
[0159] In the manufacturing method of the secondary battery 1 according to one embodiment of the present technology, the joints 170a, 170b, 171a, 171b can be formed while rotating the first member 120 and the second member 130. Therefore, the joining device 2 can be made smaller and the secondary battery 1 can be manufactured efficiently compared to a configuration in which the first member 120 and the second member 130 are kept stationary and the joining device moves around the first member 120 and the second member 130.
[0160] In a manufacturing method of a secondary battery 1 according to one embodiment of the present technology, the first member 120 is held by a manufacturing device to an extent that the first member 120 can clamp the electrode body 200. This makes it possible to prevent the electrode body 200 from moving inside the first member 120 and the second member 130 when the first member 120 and the second member 130 are rotated to join them, thereby suppressing damage to the electrode body 200.
[0161] In a manufacturing method of a secondary battery 1 according to one embodiment of the present technology, by temporarily joining the third member 150 and the fourth member 160 to the first member 120 and the second member 130 before the step of closing the pair of side openings 128, it is possible to suppress misalignment of the third member 150 and the fourth member 160 relative to the first member 120 and the second member 130 when the first member 120 and the second member 130 are rotated to join them.
[0162] In a manufacturing method of a secondary battery 1 according to one embodiment of the present technology, the third member 150 and the fourth member 160 are simultaneously joined to the first member 120 and the second member 130, thereby enabling the secondary battery 1 to be manufactured efficiently.
[0163] In the manufacturing method of the secondary battery 1 according to the embodiment of the present technology, the electrode body 200 is inserted from the top opening 127, so that the electrode body 200 is surrounded only by the pair of first side portions 122 of the first member 120 during insertion. Therefore, the electrode body 200 can be inserted into the internal region of the first member 120 in a state where the area surrounded by the electrode body 200 is small, compared to the case where the electrode body 200 is inserted from a pair of side openings 128 surrounded by the bottom portion 121 and the pair of first side portions 122 of the first member 120. Therefore, a highly reliable secondary battery 1 can be stably manufactured. For example, unintended deformation or damage of the negative electrode tab group 220 or the positive electrode tab group 250 can be suppressed, or unintended deformation or damage of the electrode body 200 can be effectively suppressed.
[0164] Although the embodiment of the present technology has been described above, the embodiment disclosed herein should be considered as illustrative and not restrictive in all respects. The scope of the present technology is defined by the claims, and it is intended to include all modifications within the scope and meaning equivalent to the claims. [Explanation of symbols]
[0165] 1, 1C secondary battery, 2 bonding device, 3 laser, 100, 100A, 100B, 100C case, 110 case body, 113 first opening, 114 second opening, 115a, 115b, 115c, 115d, 115e, 115f, 170C, 170a, 170b, 171a, 171b bonding portion, 116, 116C outer peripheral surface portion, 117 first end surface, 118 second end surface, 119C inner peripheral surface portion, 120, 120A, 120B, 120C first member, 121 bottom surface portion, 122, 122A, 122B first side surface portion, 123 one of a pair of first side surface portions, 124 the other of a pair of first side surface portions, 125, 125A, 125B Inner surface, 126, 126A First contact surface, 127 Top opening, 128 Pair of side openings, 130, 130A, 130B Second member (top surface), 131, 131B Outer periphery, 132, 132A Second contact surface, 133A Vertical wall portion, 140 Second side portion, 150, 150C Third member (sealing plate), 151C First portion, 152C Second portion, 153C Convex portion, 154, 164 Liquid injection hole, 155, 165 Gas exhaust valve, 157 First covering portion, 160 Fourth member (sealing plate), 167 Second covering portion, 200, 201, 202 Electrode body, 210 Negative electrode plate, 210S Negative electrode base plate, 211 Negative electrode core, 212 Negative electrode active material layer, 220 negative electrode tab group, 230 negative electrode tab, 240 positive electrode plate, 240S positive electrode original plate, 241 positive electrode core, 242 positive electrode active material layer, 243 positive electrode protective layer, 250 positive electrode tab group, 260 positive electrode tab, 300 electrode terminal, 301 negative electrode terminal, 302 positive electrode terminal, 400 current collector, 410 negative electrode current collector, 420 positive electrode current collector, 430 first conductive member, 431 first flat portion, 432 second flat portion, 433, 434, 441, 454 joint portion, 435 step portion, 440 second conductive member, 510 first insulating member, 520 second insulating member, 600 first spacer, 610 first part, 620 second part, 630a, 630b engagement portion.
Claims
1. An electrode body; a rectangular case that includes a bottom surface portion, a top surface portion that faces the bottom surface portion, a pair of first side surface portions that face each other in a first direction, and a pair of second side surface portions that face each other in a second direction perpendicular to the first direction, and that houses the electrode body; a first electrode terminal and a second electrode terminal electrically connected to the electrode body; The case is A first member constituting the bottom surface portion and the pair of first side surface portions; a second member that configures the upper surface portion and is joined to an end portion of the first side surface portion of the first member; a third member that constitutes one of the pair of second side surface portions and is joined to an end portion of each of the first member and the second member at an end portion on a first side in the second direction; a fourth member that constitutes the other of the pair of second side portions and is joined to each end of the first member and the second member at an end of a second side opposite to the first side in the second direction, The electrode body is a main body having a first electrode and a second electrode having a polarity different from that of the first electrode; a first electrode tab group electrically connected to the first electrodes and located at an end of the first side relative to the main body; a second electrode tab group electrically connected to the second electrodes and located at an end of the second side relative to the body portion, the first electrode terminal is provided on the third member, the second electrode terminal is provided on the fourth member, the first electrode tab group is electrically connected to the first electrode terminals; The second electrode tab group is electrically connected to the second electrode terminals.
2. the first electrode terminal is attached to the third member in a state of being electrically insulated from the third member; The secondary battery according to claim 1 , wherein the second electrode terminal is attached to the fourth member in a state in which the second electrode terminal is electrically insulated from the fourth member.
3. a first spacer between the electrode body and the third member; The secondary battery according to claim 1 or 2, further comprising a second spacer between the electrode body and the fourth member.
4. The third member is a first portion that is inserted into the case further than the first side ends of the first member and the second member and faces the first member and the second member from the inside of the case; 3. The secondary battery according to claim 1, further comprising a second portion abutting the first end of the first member and the second member from the second direction.
5. preparing an electrode assembly including a first electrode and a second electrode having a polarity different from that of the first electrode; preparing a first member having a bottom surface portion, a pair of first side surfaces rising from the bottom surface portion and facing each other in a first direction, a top opening facing the bottom surface portion, and a pair of side openings between both ends of each of the pair of first side surfaces in a second direction perpendicular to the first direction; Providing a second member; attaching a first electrode terminal to a third member; attaching a second electrode terminal to the fourth member; a step of electrically connecting a first electrode tab group electrically connected to the first electrodes of the electrode body to the first electrode terminals; a step of electrically connecting a second electrode tab group electrically connected to the second electrodes of the electrode body to the second electrode terminals; inserting the electrode body between the pair of first side portions of the first member; a step of inserting the electrode body between the pair of first side surface portions, and then joining the second member to each end of the pair of first side surface portions and closing the upper surface opening; after the step of closing the top opening, a step of joining the third member to the first member and the second member to close one of the pair of side openings, and joining the fourth member to the first member and the second member to close the other of the pair of side openings, thereby closing the pair of side openings.
6. 6. The method for manufacturing a secondary battery according to claim 5, wherein at least a portion of the process of closing the pair of side openings includes rotating the first member and the second member while holding the first member and the second member rotatably around an axis in the second direction.
7. 7. The method for manufacturing a secondary battery according to claim 6, wherein at least a portion of the step of closing the pair of side openings includes pressing the first member along the first direction to deform the first member and sandwiching the electrode body between the first member.
8. 8. The method for manufacturing a secondary battery according to claim 6, wherein the step of closing the pair of side openings includes temporarily joining the third member and the fourth member to the first member and the second member.
9. 7. The method for manufacturing a secondary battery according to claim 5, wherein in the step of closing the pair of side openings, at least a part of the joining of the third member and the joining of the fourth member are performed simultaneously.
10. 7. The method for manufacturing a secondary battery according to claim 5, wherein the step of inserting the electrode body includes inserting the electrode body toward the bottom surface portion.
Citation Information
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