Process for oligomerization in a reactor having zones of variable diameter, including a step of recycling pre-cooled solvent - Patent 7329963

Abstract

The present invention relates to a process for oligomerization in a reactor containing a variable diameter zone, which includes a step of recycling a pre-cooled solvent.

Description

[Technical field]

[0001] The present invention relates to a process for the oligomerization of an olefin feedstock, carried out in a reactor with zones of variable diameter, in which the solvent fraction resulting from the downstream separation step is cooled and recycled.In particular, the present invention relates to a process for the oligomerization of a gaseous olefin feedstock, preferably gaseous ethylene, to give linear α-olefins, such as but-1-ene, hex-1-ene or oct-1-ene, or a mixture of linear α-olefins. [Background technology]

[0002] The present invention relates to the field of oligomerization directed towards producing α-olefins used as comonomers in processes for producing polyethylene. The oligomerization reactions are usually carried out in homogeneous catalyzed processes in the liquid phase in two-phase gas / liquid reactors, generally with implementation in a bubble column.

[0003] The oligomerization reaction is highly exothermic; it is usual to regulate the reaction temperature by using external cooling. The reactor may be connected to one or more recirculation loops, withdrawing a liquid fraction, cooling it through one or more exchangers and reintroducing it into the reactor. Said recirculation loop makes it possible to obtain a good uniformity of concentration and to control the temperature throughout the reaction volume. In US Pat. No. 5,399,433 a process for the trimerization of ethylene to give hex-1-ene is proposed, which allows reducing the costs of the plant by limiting the energy consumption associated with the recirculation loop. For this purpose, the bottom fraction, mainly composed of solvent coming from the separation section, is used in the heat exchangers of the recirculation loop and also for reboiling the bottom of the column of the separation section.

[0004] One drawback encountered during the use of gas / liquid two-phase reactors in processes for oligomerization, such as the oligomerization of ethylene, is the management of the gas headspace, which corresponds to the upper part of the reactor, which is in a gaseous state. Said gas headspace contains gaseous compounds with low solubility in the liquid phase, compounds that are partially soluble in the liquid but inert, and also gaseous ethylene, which is not dissolved in said liquid. The passage of gaseous ethylene from the lower liquid part of the reaction chamber into the gas headspace is a phenomenon called breakthrough. In practice, the gas headspace is extracted to remove said gaseous compounds. When the amount of gaseous ethylene present in the gas headspace is high, the extraction of the gas headspace leads to a loss of a significant amount of ethylene, which is detrimental to the productivity and cost of the oligomerization process. Furthermore, a significant breakthrough phenomenon means that a large amount of gaseous ethylene is not dissolved in the liquid phase and therefore cannot react, which is detrimental to the productivity and selectivity of the oligomerization process.

[0005] In order to improve the efficiency of the oligomerization process in terms of productivity and costs, it is thus essential to limit the breakthrough of ethylene and increase its conversion in the process while at the same time maintaining good selectivity for the desired linear α-olefins.

[0006] In the field of the present invention, the skilled person is always seeking to improve the process for oligomerization, in particular by controlling the size ratios of the equipment that affect the performance and the cost of the process. The skilled person is also seeking to reduce the cost of the plants used to carry out the oligomerization.

[0007] The applicant has discovered a process for the oligomerization of an olefin feedstock carried out in a reactor with zones of variable diameter, in which the solvent fraction resulting from the downstream separation step is cooled and recycled to partially control the exothermicity caused by the oligomerization reaction in the reactor. The object of the present invention is to improve the process for the oligomerization of an olefin feedstock, in particular of ethylene, in a gas / liquid reactor. The present invention seeks, inter alia, to increase the productivity / feasibility of the process, in particular to avoid the phenomenon of breakthrough and / or to keep the investment and / or running costs of the process low. The implementation of the recycle of the cooled solvent fraction from the separation section in the process according to the invention makes it possible to limit the size of the heat exchanger or exchangers used in at least one recycle loop. The implementation of a reactor with zones of variable diameter according to the present invention makes it possible to increase the solubility of the gaseous olefin feedstock and therefore to limit the phenomenon of breakthrough. [Prior art documents] [Patent documents]

[0008] [Patent Document 1] European Patent No. 2703373 Summary of the Invention [Means for solving the problem]

[0009] BRIEF DESCRIPTION OF THE DRAWINGS The present invention relates to a process for the oligomerization of an olefin feedstock, comprising the steps of: a) a process for oligomerization of an olefin feedstock, carried out in a reaction section at a temperature between 30° C. and 200° C. and at a pressure between 0.1 and 10 MPa in the presence of a homogeneous oligomerization catalyst system and a solvent; the reaction section comprises: an oligomerization reactor having zones of variable diameter and containing a liquid phase; and The temperature T of at least a portion of the liquid fraction loop At least one recirculation loop allowing cooling to; b) separating the reaction effluent resulting from the oligomerization step a) in a separation section; obtaining a solvent fraction; c) cooling the solvent fraction resulting from step b) to a temperature T loop cooling to a temperature below d) introducing the cooled solvent fraction resulting from step c) into the reaction section of the oligomerization step a).

[0010] Preferably, the reactor with variable diameter zones comprises n consecutive zones, n being a positive integer between 2 and 10; - for each of the n zones, a diameter Dn is present, the diameter Dn decreasing in a direction from the bottom zone towards the top zone of said reactor, the ratio of the diameter of the upper zone (denoted Dn) to the diameter of the adjacent lower zone (denoted Dn-1) (Dn / Dn-1) is less than or equal to 0.9; - for a given zone, the ratio of the volume of said zone (denoted as Vn) to the total volume of the reaction chamber (denoted as Vtot) is between 0.2 and 0.8.

[0011] Preferably, n successive zones of the reactor having zones of variable diameter are arranged in series along the vertical axis of the reactor to define within the reaction enclosure zones having diameters that decrease from bottom to top.

[0012] Preferably, the solvent fraction resulting from step b) is cooled in step c) to a temperature between 0°C and 150°C.

[0013] Preferably, the solvent fraction resulting from step b) is cooled in step c) to a temperature T loop The temperature is cooled to a minimum of 40° C. relative to the

[0014] Preferably, the cooling of the solvent fraction in step c) is carried out by means of one or more heat exchangers, preferably selected from one or more heat exchangers of the process fluid / process fluid type, the air cooler type and the cooling water exchanger type.

[0015] Preferably, the separation section comprises at least two distillation columns, preferably at least three distillation columns, preferably at least four distillation columns.

[0016] Preferably, step d) of introducing the cooled solvent fraction is carried out in the reactor and / or in one or more recycle loops.

[0017] Preferably, step d) of introducing at least a portion of the cooled solvent fraction is carried out upstream or downstream of the recirculation loop of a heat exchanger of one or more recirculation loops, preferably downstream of said heat exchanger.

[0018] Preferably, the flow rate of the cooled solvent fraction, expressed as a percentage by weight relative to the flow rate of the liquid phase fraction circulating in the recirculation loop or loops, is between 0.05% and 15.0%, preferably between 0.1% and 10.0%.

[0019] Preferably, the olefin feedstock comprises olefins having from 2 to 6 carbon atoms, preferably from 2 to 4 carbon atoms.

[0020] Preferably, the oligomerization step a) comprises at least one of the following substeps: - substep a1) of introducing a catalytic system, - substep a2) of contacting with an olefin feedstock, - a substep a3) of withdrawing a liquid phase fraction from the oligomerization reactor, - at least a part of the liquid fraction withdrawn in step a3) is circulated in at least one recirculation loop at a temperature T loopa4) cooling the mixture to a temperature of 100° C.; - Substep a5) of introducing the cooled liquid fraction into a reactor.

[0021] Preferably, the cooling substep a4) is carried out by passing at least a part of the liquid fraction withdrawn in substep a3) through one or more heat exchangers located in one or more recirculation loops.

[0022] Preferably, the heat exchanger or exchangers used in sub-step a4) reduce the temperature of the liquid fraction withdrawn in sub-step a3) by 1.0°C to 30.0°C, preferably by 2.0°C to 25.0°C.

[0023] Preferably, the reaction effluent is obtained by splitting the liquid fraction withdrawn in sub-step a3) into two streams. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0024] (definition) In the context of the present invention, the term "separation section" denotes one or more devices for separation, in particular separation by distillation, located downstream of the reaction section and comprising a single device or multiple devices arranged in series and / or parallel, which devices may be identical or different in their sizing or their design / operation.

[0025] In the context of the present invention, the terms "upstream" and "downstream" are understood relative to the general direction of flow of reaction fluids within the production unit.

[0026] In the context of the present invention, the expressions heat exchanger and thermal exchanger are used equivalently.

[0027] A homogeneous catalyst or catalyst system is understood to mean the fact that this catalyst or catalyst system is in the same phase as the reactants and products of the oligomerization reaction.

[0028] Breakthrough is understood to mean the passage of a gaseous olefin feedstock, preferably gaseous ethylene, from the liquid phase to the gas phase in a gas / liquid reactor.

[0029] The solvent content is understood to mean the weight ratio of the total flow rate of the injected solvent to the sum of the total flow rate of the injected gaseous olefin feedstock, preferably gaseous ethylene, and the flow rate of the solvent introduced into the reactor.

[0030] The term "two-phase gas / liquid reactor" means a reactor comprising a liquid phase and a gas phase, the liquid phase comprising the olefin feedstock, preferably in gaseous form, in particular gaseous ethylene, the reaction products, e.g. the desired linear α-olefins (i.e. but-1-ene, hex-1-ene, oct-1-ene or a mixture of linear α-olefins), preferably in liquid form, the catalyst system, preferably in liquid form, and the solvent, and the gaseous phase is located in the section located at the top of the reactor.

[0031] In the context of the present invention, the term "reaction section" is a device that includes, and preferably consists of, an oligomerization reactor with variable diameter zones and one or more recirculation loops.

[0032] The bottom or lower part of the reaction chamber or reactor is understood to mean the lower quarter of the reaction chamber or reactor.

[0033] The top of the reaction chamber or reactor is understood to mean the upper quarter of the reaction chamber or reactor.

[0034] Bottom zone is understood to mean the first zone according to the invention which is located in the lower part of the reaction chamber or reactor, at the level of the bottom of said chamber or reactor.

[0035] Top zone is understood to mean the final zone according to the invention which is located in the upper part of the reaction chamber or reactor, at the level of the top of said chamber or reactor.

[0036] Saturation is understood to mean the percentage of the olefin feedstock, preferably ethylene, dissolved in the liquid phase relative to the maximum amount of gaseous olefin feedstock, preferably ethylene, that can be dissolved in said liquid phase, which is defined by the thermodynamic equilibrium between the partial pressure of the gaseous olefin feedstock, preferably gaseous ethylene, and said liquid phase. Saturation can be measured by gas chromatography.

[0037] The upper part of the reactor is understood to mean the upper quarter of said reactor containing the liquid phase.

[0038] Volume of reaction liquid is understood to mean the amount by volume of the liquid phase contained in the reactor and / or in the recirculation loop or loops and in which the oligomerization reaction takes place.

[0039] The volume of the recirculation loop or loops indicates the size of said loop or loops, which corresponds to the volume of reaction liquid that may be contained by said loop or loops.

[0040] (Detailed Description) For the purposes of the present invention, the various embodiments presented may be used alone or in combination with each other, without any limitations on the combinations.

[0041] For purposes of the present invention, various ranges of parameters for a given process, such as pressure ranges and temperature ranges, may be used alone or in combination, e.g., for purposes of the present invention, a preferred range of pressure values ​​may be combined with a more preferred range of temperature values.

[0042] (method) The present invention relates to a process for the oligomerization of an olefin feedstock carried out in a reactor with variable diameter zones, in which the solvent fraction resulting from a downstream separation step is cooled and recycled to the reaction section to partially control the exothermicity of the oligomerization reaction.

[0043] In particular, the present invention relates to a process for the oligomerization of an olefin feedstock, comprising the steps of: a) a process for oligomerization of an olefin feedstock, carried out at a temperature between 30° C. and 200° C. and a pressure between 0.1 and 10 MPa in the presence of a homogeneous oligomerization catalyst system and a solvent in a reaction section, the reaction section comprising: an oligomerization reactor having zones of variable diameter and containing a liquid phase; and At least a portion of the liquid fraction has a temperature T loop at least one recirculation loop to allow cooling to the b) separating the reaction effluent resulting from the oligomerization step a) in a separation section; obtaining a solvent fraction; c) cooling the solvent fraction resulting from step b) to a temperature T loop cooling to a temperature below d) introducing the cooled solvent fraction resulting from step c) into the reaction section of the oligomerization step a).

[0044] The invention makes it possible to minimize the temperature of the solvent introduced into the reactor with zones of variable diameter by means of one or more recirculation loops and to reduce the temperature difference between the liquid phase fraction withdrawn and the fluid used for heat exchange at the level of the one or more recirculation loops, while maximizing the volume of reaction liquid in the reactor, thereby making it possible to improve the saturation of said liquid with the gaseous olefin feedstock. The control of temperature by the introduction into the reaction section of the cooled solvent fraction resulting from the downstream separation makes it possible to reduce the amount of heat to be exchanged in the recirculation loops and therefore to reduce the size of the exchangers. The saving in the exchange surface area of ​​the thermal exchangers of the one or more recirculation loops may advantageously be of the order of 1% to 50%, preferably 2% to 40%, preferentially 3% to 30% over the exchange surface area.

[0045] Furthermore, the oligomerization reaction takes place in the reaction liquid contained both in the reactor and in one or more recycle loops. The reduction in the size of the heat exchanger means that the volume of at least one recycle loop is reduced. In the process according to the invention, the volume of the reaction liquid in the reactor is increased with the same volume of total reaction liquid (reactor + recycle loop) compared to a process not implementing the invention, which makes it possible to improve the saturation of the liquid reaction medium with the olefin feedstock and therefore improve the performance of the process.

[0046] In the process according to the invention, the proportion of the volume of reaction liquid in the recirculation loop relative to the total volume of reaction liquid is lower compared to a process not embodying the invention, for the same amount of reaction liquid in the reactor. This reduction, especially in combination with the use of a reactor with zones of variable diameter, makes it possible to shorten the residence time while improving the saturation of the liquid with the olefin feedstock, and therefore to improve the performance of the catalyst system in terms of activity and selectivity.

[0047] Thus, the present invention makes it possible to easily adjust the productivity and profitability of the oligomerization process depending on the performance of the catalyst system used.

[0048] (Oligomerization homogeneous catalyst system) All catalytic systems known to those skilled in the art and capable of being used in the dimerization, trimerization or tetramerization process, and more generally in the oligomerization process according to the invention, fall within the field of the present invention. Said catalytic systems, and also their implementation, are described, inter alia, in applications FR 2984311, FR 2552079, FR 3019064, FR 3023183, FR 3042989 or else in application FR 3045414.

[0049] Preferably, the catalyst system comprises, preferably consists of: - a metal precursor, preferably based on nickel, titanium or chromium, - an optional activator, - optional additives, and - Optional solvent.

[0050] (Metal Precursors) The metal precursors used in the catalyst system are selected from compounds based on nickel, titanium or chromium.

[0051] In one embodiment, the metal precursor is based on nickel and preferentially comprises nickel in the (+II) oxidation state. Preferably, the nickel precursor is a nickel(II) carboxylate, such as nickel 2-ethylhexanoate, nickel(II) phenate, nickel(II) naphthenate, nickel(II) acetate, nickel(II) trifluoroacetate, nickel(II) triflate, nickel(II) acetylacetonate, nickel(II) hexafluoroacetylacetonate, π-allylnickel(II) chloride, π-allylnickel(II) bromide, methallylnickel(II) chloride dimer, η hexafluorophosphate ... 3 -Allylnickel(II), η hexafluorophosphate3 - methallylnickel(II) and nickel(II) 1,5-cyclooctadienyl, in their hydrated or anhydrous form, used alone or as a mixture.

[0052] In a second embodiment, the metal precursor is based on titanium and preferentially comprises an aryloxy or alkoxy compound of titanium.

[0053] The titanium alkoxy compound advantageously corresponds to the general formula [Ti(OR)4], where R is a linear or branched alkyl group. Among suitable alkoxy groups, non-limiting examples that may be mentioned include tetraethoxy, tetraisopropoxy, tetra(n-butoxy) and tetra(2-ethylhexyloxy).

[0054] The titanium aryloxy compounds advantageously correspond to the general formula [Ti(OR')4], where R' is an aryl group that is unsubstituted or substituted with an alkyl or aryl group. The group R' may contain heteroatom-based substituents. Preferred aryloxy groups are selected from phenoxy, 2-methylphenoxy, 2,6-dimethylphenoxy, 2,4,6-trimethylphenoxy, 4-methylphenoxy, 2-phenylphenoxy, 2,6-diphenylphenoxy, 2,4,6-triphenylphenoxy, 4-phenylphenoxy, 2-(tert-butyl)-6-phenylphenoxy, 2,4-di(tert-butyl)-6-phenylphenoxy, 2,6-diisopropylphenoxy, 2,6-di(tert-butyl)phenoxy, 4-methyl-2,6-di(tert-butyl)phenoxy, 2,6-dichloro-4-(tert-butyl)phenoxy and 2,6-dibromo-4-(tert-butyl)phenoxy, biphenoxy groups, binaphthoxy and 1,8-naphthalenedioxy.

[0055] According to a third embodiment, the metal precursor is based on chromium and preferentially comprises chromium(II) salts, chromium(III) salts or salts of different oxidation states which may contain one or more identical or different anions, such as halides, carboxylates, acetylacetonates or alkoxy or aryloxy anions. Preferably, the chromium-based precursor is chosen from CrCl3, CrCl3(tetrahydrofuran)3, Cr(acetylacetonate)3, Cr(naphthenate)3, Cr(2-ethylhexanoate)3 and Cr(acetate)3.

[0056] The concentration of nickel, titanium or chromium is between 0.001 and 300.0 ppm by weight of atomic metal relative to the reaction weight, preferably between 0.002 and 100.0 ppm by weight, preferentially between 0.003 and 50.0 ppm by weight, more preferentially between 0.05 and 20.0 ppm by weight, even more preferentially between 0.1 and 10.0 ppm by weight, by weight of atomic metal relative to the liquid reaction weight, i.e. the weight of the liquid phase contained in the reactor and / or in the recirculation loop(s).

[0057] (Activator) In some cases, regardless of the metal precursor, the catalyst system includes one or more activators selected from aluminum-based compounds, such as methylaluminum dichloride (MeAlCl2), dichloroethylaluminum (EtAlCl2), ethylaluminum sesquichloride (Et3Al2Cl3), chlorodiethylaluminum (Et2AlCl), chlorodiisobutylaluminum (i-Bu2AlCl), triethylaluminum (AlEt3), tripropylaluminum (Al(n-Pr)3), triisobutylaluminum (Al(i-Bu)3), diethylethoxyaluminum (Et2AlOEt), methylaluminoxane (MAO), ethylaluminoxane, and modified methylaluminoxane (MMAO).

[0058] (Additives) Optionally, the catalyst system includes one or more additives.

[0059] The additives are selected from monodentate phosphorus-based compounds, bidentate phosphorus-based compounds, tridentate phosphorus-based compounds, olefinic compounds, aromatic compounds, nitrogen compounds, bipyridines, diimines, monodentate ethers, bidentate ethers, monodentate thioethers, bidentate thioethers, monodentate or bidentate carbenes, mixed ligands, such as phosphinopyridines, iminopyridines, bis(imino)pyridines.

[0060] When the metal precursor of the catalytic system is based on nickel, the additive is chosen from: - nitrogen-based compounds, such as trimethylamine, triethylamine, pyrrole, 2,5-dimethylpyrrole, pyridine, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, 2-methoxypyridine, 3-methoxypyridine, 4-methoxypyridine, 2-fluoropyridine, 3-fluoropyridine, 3-trifluoromethylpyridine, 2-phenylpyridine, 3-phenylpyridine, 2-benzylpyridine, 3,5-dimethylpyridine, 2,6-di(tert-butyl)pyridine and 2,6-diphenylpyridine, quinoline, 1,10-phenanthroline, N-methylpyrrole, N-butylpyrrole, N-methylimidazole, N-butylimidazole, 2,2'-bipyridine, N,N'-dimethylethane-1,2-diimine, N,N'-di(t-butyl)ethane-1,2-diimine, N,N'-di(t-butyl)butane-2,3-diimine, N,N'-diphenylethane-1,2-diimine, N,N'-bis(2,6-dimethylphenyl)ethane-1,2-diimine, N,N'-bis(2,6-diisopropylphenyl)ethane-1,2-diimine, N,N'-diphenylbutane-2,3-diimine, N,N'-bis(2,6-dimethylphenyl)butane-2,3-diimine or N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine, or - phosphine type compounds, independently selected from tributylphosphine, triisopropylphosphine, tricyclopentylphosphine, tricyclohexylphosphine, triphenylphosphine, tris(o-tolyl)phosphine, bis(diphenylphosphino)ethane, trioctylphosphine oxide, triphenylphosphine oxide or triphenylphosphite, or a compound corresponding to general formula (I) or one of the tautomers of said compound

[0061] [ka]

[0062] During the ceremony: - A and A', which may be the same or different, are independently a single bond between an oxygen or phosphorus atom and a carbon atom; - R 1a and R 1b are independently selected from the groups methyl, trifluoromethyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, pentyl, cyclohexyl and adamantyl, which may be substituted or unsubstituted and may or may not contain heteroatoms; selected from the groups phenyl, o-tolyl, m-tolyl, p-tolyl, mesityl, 3,5-dimethylphenyl, 4-(n-butyl)phenyl, 2-methylphenyl, 4-methoxyphenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-isopropoxyphenyl, 4-methoxy-3,5-dimethylphenyl, 3,5-bis(tert-butyl)-4-methoxyphenyl, 4-chlorophenyl, 3,5-bis(trifluoromethyl)phenyl, benzyl, naphthyl, bisnaphthyl, pyridyl, bisphenyl, furyl or thiophenyl, - R 2are independently selected from methyl, trifluoromethyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, pentyl, cyclohexyl and adamantyl groups; which may be substituted or unsubstituted and may or may not contain heteroelements; phenyl, o-tolyl, m-tolyl, p-tolyl, mesityl, 3,5-dimethylphenyl, 4-(n-butyl)phenyl, 4-methoxyphenyl, 2-methoxyphenyl, 3-methoxyphenyl, 4-methoxyphenyl, 2-isopropoxyphenyl, 4-methoxy-3,5-dimethylphenyl, 3,5-di(tert-butyl)-4-methoxyphenyl, 4-chlorophenyl, 3,5-bis(trifluoromethyl)phenyl, benzyl, naphthyl, bisnaphthyl, pyridyl, bisphenyl, furyl and thiophenyl groups.

[0063] When the metal precursor of the catalytic system is based on titanium, the additives are selected from diethyl ether, diisopropyl ether, dibutyl ether, diphenyl ether, 2-methoxy-2-methylpropane, 2-methoxy-2-methylbutane, 2,2-dimethoxypropane, 2,2-bis(2-ethylhexyloxy)propane, 2,5-dihydrofuran, tetrahydrofuran, 2-methoxytetrahydrofuran, 2-methyltetrahydrofuran, 3-methyltetrahydrofuran, 2,3-dihydropyran, tetrahydropyran, 1,3-dioxolane, 1,3-dioxane, 1,4-dioxane, dimethoxyethane, bis(2-methoxyethyl)ether, benzofuran, glyme and diglyme, employed alone or in mixtures.

[0064] When the metal precursor of the catalytic system is based on chromium, the additive is chosen from: - nitrogen type compounds, e.g. trimethylamine, triethylamine, pyrrole, 2,5-dimethylpyrrole, pyridine, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, 2-methoxypyridine, 3-methoxypyridine, 4-methoxypyridine, 2-fluoropyridine, 3-fluoropyridine, 3-trifluoromethylpyridine, 2-phenylpyridine, 3-phenylpyridine, 2-benzylpyridine, 3,5-dimethylpyridine, 2,6-di(tert-butyl)pyridine and 2,6-diphenylpyridine, quinoline, 1,10-phenanthroline, N-methylpyrrole, N-butylpyrrole, N-methylimidazole, N -butylimidazole, 2,2'-bipyridine, N,N'-dimethylethane-1,2-diimine, N,N'-di(t-butyl)ethane-1,2-diimine, N,N'-di(t-butyl)butane-2,3-diimine, N,N'-diphenylethane-1,2-diimine, N,N'-bis(2,6-dimethylphenyl)ethane-1,2-diimine, N,N'-bis(2,6-diisopropylphenyl)ethane-1,2-diimine, N,N'-diphenylbutane-2,3-diimine, N,N'-bis(2,6-dimethylphenyl)butane-2,3-diimine or N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine, or - General formula [M(R 3 O) 2-n X n ] y Aryloxy compounds of During the ceremony: * M is selected from magnesium, calcium, strontium and barium, preferably magnesium; * R 3 is an aryl group containing 6 to 30 carbon atoms, and X is a halogen or an alkyl group containing 1 to 20 carbon atoms; * n is an integer that can take the value 0 or 1, and *y is an integer from 1 to 10; preferably, y is equal to 1, 2, 3 or 4.

[0065] Preferably, the aryloxy group R 3O is selected from 4-phenylphenoxy, 2-phenylphenoxy, 2,6-diphenylphenoxy, 2,4,6-triphenylphenoxy, 2,3,5,6-tetraphenylphenoxy, 2-(tert-butyl)-6-phenylphenoxy, 2,4-di(tert-butyl)-6-phenylphenoxy, 2,6-diisopropylphenoxy, 2,6-dimethylphenoxy, 2,6-di(tert-butyl)phenoxy, 4-methyl-2,6-di(tert-butyl)phenoxy, 2,6-dichloro-4-(tert-butyl)phenoxy and 2,6-dibromo-4-(tert-butyl)phenoxy. Two aryloxy groups may be carried by one and the same molecule, for example biphenoxy group, binaphthoxy or 1,8-naphthalenedioxy. Preferably, the aryloxy group R 3 O is 2,6-diphenylphenoxy, 2-(tert-butyl)-6-phenylphenoxy or 2,4-di(tert-butyl)-6-phenylphenoxy.

[0066] (Oligomerization step a) The process according to the invention therefore comprises a step a) of oligomerization of an olefinic feedstock, which step a) is carried out in the presence of an oligomerization homogeneous catalyst system and a solvent at a temperature between 30° C. and 200° C. and at a pressure between 0.1 and 10 MPa. Said oligomerization step a) is carried out in a reaction section comprising an oligomerization reactor with zones of variable diameter and at least one recirculation loop allowing the control of the temperature in said reactor via the cooling of the liquid phase fraction. The cooling of the liquid fraction consists in cooling said fraction to a temperature below the oligomerization temperature (i.e. the temperature of the liquid phase in the reactor), thus controlling the exothermicity of the reaction.

[0067] Preferably, the reactor with variable diameter zones used in the process according to the invention comprises n successive zones, n being a positive integer between 2 and 10, where: * for each of the n zones, the diameter Dn decreases in a direction from the bottom zone to the top zone of the reactor, the ratio (Dn / Dn-1) of the diameter of the upper zone (denoted as Dn) to the diameter of the adjacent lower zone (denoted as Dn-1) is less than or equal to 0.9; * For a given zone, the ratio of the volume of said zone (denoted as Vn) to the total volume of the reaction chamber (denoted as Vtot) is between 0.2 and 0.8.

[0068] The use of a reactor with variable diameter zones according to the invention makes it possible to increase the overall height of the reactor and therefore the height of the liquid phase without modifying the reactor or the volume of the liquid phase used in the oligomerization reaction, which has the effect of improving the solubility of the gaseous olefin feedstock, in particular gaseous ethylene, and therefore limiting the phenomenon of breakthrough for a given volume of liquid phase and therefore improving the productivity of the process. Thus, a reactor with variable diameter zones makes it possible to increase the height of the liquid phase for a given volume of liquid phase compared to a constant diameter reactor.

[0069] Advantageously, the use of a reactor with variable diameter zones according to the invention in an oligomerization process allows a degree of saturation of the olefin feedstock, in particular ethylene, dissolved in the liquid phase, preferably using a homogeneous catalyst, of 70.0% or more, preferably between 70.0% and 100%, preferably between 80.0% and 100%, preferably between 80.0% and 99.0%, preferably between 85.0% and 99.0%, even more preferably between 90.0% and 98.0%.

[0070] The saturation of the dissolved olefin feedstock, particularly the dissolved ethylene, may be measured by any method known to those skilled in the art, for example, by gas chromatography (commonly referred to as GC) analysis of the liquid phase fraction withdrawn from the reactor.

[0071] The process using a reactor with variable diameter zones according to the invention makes it possible to obtain linear olefins, in particular linear α-olefins, by contacting one or more olefins with a catalyst system, optionally in the presence of additives and / or solvents, and by using said gas / liquid reactor with variable diameter zones.

[0072] The n successive zones of the reactor used in the process according to the invention are arranged in series along the vertical axis of the reactor to define reaction zones having a diameter that decreases from the bottom to the top of the reactor, thus increasing the height of the liquid phase that may be contained in the reactor according to the invention compared to the height of a reactor having a constant diameter, thus increasing the time that the olefin feedstock is present in the liquid phase and facilitating its dissolution.

[0073] Advantageously, for a given reactor volume and therefore a given liquid volume, n successive zones have decreasing diameters in the reactor, making it possible to increase the height of liquid that may be contained in the reactor and therefore the residence time of the gaseous olefin feedstock introduced into the liquid phase, thus making it possible, by the invention, to increase the amount of olefin feedstock, preferably ethylene, dissolved in the liquid phase and therefore limiting the breakthrough phenomenon.

[0074] Preferably, the number n of reactor zones is between 2 and 10, preferably between 2 and 8, preferably between 2 and 6, preferably between 2 and 5, and highly preferably n is preferably equal to 2, 3, 4 or 5.

[0075] The ratio (Dn / Dn-1) of the diameter of the upper zone n (denoted Dn) to the diameter of the adjacent lower zone n-1 (denoted Dn-1) is less than or equal to 0.9. Preferably, the ratio Dn / Dn-1 is between 0.1 and 0.9, preferably between 0.15 and 0.85, preferably between 0.2 and 0.8, preferably between 0.25 and 0.75, highly preferably between 0.3 and 0.7.

[0076] The total height of the n zones making up the reactor is denoted Htot and their sum is equal to the total height of the reactor.

[0077] Advantageously, the ratio (Hn / Hn-1) of the height of an upper zone n (denoted Hn) to the height of the adjacent lower zone n-1 (denoted Hn-1) is between 0.2 and 3.0, preferably between 0.3 and 2.5, preferably between 0.4 and 2.0, preferably between 0.5 and 1.5, preferably between 0.6 and 1.0.

[0078] Preferably, for a given zone, the ratio of the volume (denoted Vn) to the total volume of the reactor corresponding to the sum of n zones (denoted Vtot), said ratio being denoted Vn / Vtot, is between 0.2 and 0.8. Preferably, said ratio (Vn / Vtot) is between 0.25 and 0.75, preferably between 0.3 and 0.7, preferably between 0.35 and 0.65.

[0079] Preferably, the reactor is of cylindrical shape and the ratio of the total height of the reactor to the diameter of the bottom zone of said reactor (denoted Htot / D1) is between 1 and 17, preferably between 1 and 8, preferably between 2 and 7.

[0080] In a first particular embodiment represented in Figure 2 or 3, the n zones making up the reactor according to the invention are formed by cylinders of decreasing diameter, said cylinders being connected to one another by walls either perpendicular to the vertical axis or making an angle α (between 90 and 160°) with the vertical axis, as represented in Figure 2, in order to promote and in particular not hinder the rise of the gaseous ethylene bubbles in the liquid phase. Preferably, said angle is between 95 and 145°, preferably between 100 and 130°.

[0081] In a second particular embodiment, represented in Figure 4, the n zones making up the reactor according to the invention are formed by internal structures located within the reactor, reducing its diameter over a given zone, said internal structures may for example be solid metal walls.

[0082] Advantageously, regardless of the embodiment, the fixing of the elements constituting the reactor is carried out by attaching the cylinder and / or the internal structure, for example by welding, adhesive bonding, screwing or bolting, alone or in combination, or by any other similar means. Preferably, the attachment is carried out by welding.

[0083] Preferably, the oligomerization reactor is selected from two-phase gas / liquid reactors, preferably from bubble column type reactors.

[0084] The olefin feedstock preferably contains olefins having from 2 to 6 carbon atoms, preferably from 2 to 4 carbon atoms. Preferably, the olefin feedstock is selected from butenes, more particularly isobutene or but-1-ene, propylene and ethylene, either alone or in mixtures.

[0085] Hereinafter, unless otherwise specified, when ethylene is specifically mentioned, this also denotes olefins having 2 to 6 carbon atoms, such as isobutene or but-1-ene, propylene, as well as ethylene, etc.

[0086] Preferably, the oligomerization process is a process for the dimerization, trimerization or tetramerization of an olefin feedstock, preferably ethylene.

[0087] Advantageously, the oligomerization process is carried out at a pressure between 0.1 and 10.0 MPa, preferably between 0.2 and 9.0 MPa and preferentially between 0.3 and 8.0 MPa, and at a temperature between 30°C and 200°C, preferably between 35°C and 180°C, preferably between 45°C and 170°C, preferentially between 60°C and 160°C, preferably between 70°C and 150°C, preferably between 80°C and 145°C and preferably between 100°C and 140°C.

[0088] The reaction effluent resulting from step a) is sent to a separation section downstream of the reaction section, which is obtained by withdrawing a liquid fraction from the reactor. In particular, the reaction effluent resulting from step a) sent to the separation section downstream of the reaction section corresponds to at least a part of the liquid phase fraction withdrawn from the oligomerization reactor with variable diameter zones. Advantageously, the flow rate of the reaction effluent is regulated to maintain a constant liquid level in the reactor.

[0089] Since the oligomerization reaction occurs in both the reactor and the recycle loop(s), the residence time in the reaction section is therefore understood to span the entire volume of the reactor and the volume of the recycle loop(s) that form the reaction section.

[0090] Advantageously, the oligomerization process is carried out with a solvent content of 0-90% by weight, preferably 10-85% by weight, preferably 20-80% by weight, preferably 30-75% by weight. According to one preferred embodiment of the invention, the oligomerization process is carried out with a gaseous olefin feedstock, for example a gaseous ethylene feedstock, in a two-phase gas / liquid reactor of the bubble column type. The dissolution of the olefin feedstock, in particular ethylene bubbles, in the reaction medium takes place in the bubble column. The higher the height of liquid available in this column, the closer the solubility of ethylene approaches complete saturation. Since the selectivity of the reaction towards the main reaction product is inversely proportional to the conversion of the olefin feedstock, preferably ethylene, in the liquid, maximizing the amount of dissolved olefin feedstock makes it possible, at a constant olefin feedstock flow rate at the reactor inlet, to decrease the conversion and therefore increase the selectivity.

[0091] Since the recirculation loop occupies a significant proportion of the reaction liquid volume of the reaction section, reducing this volume as much as possible is advantageous in order to either: - Synergistically increasing the volume of reaction liquid in the reactor (e.g. in a bubble column) by means of a reactor with zones of variable diameter, thereby increasing the height of the liquid phase in the reactor and maximizing the saturation of ethylene in the liquid; or It makes it possible to reduce the volume of one or more recirculation loops while keeping the reactor volume constant, and therefore the residence time, thereby improving the performance of the catalyst system in terms of activity and selectivity.

[0092] The solvent or solvents are advantageously chosen from ethers, alcohols, halogenated solvents and hydrocarbons, which may be saturated or unsaturated, cyclic or acyclic, aromatic or non-aromatic and contain between 1 and 20 carbon atoms, preferably between 4 and 15 carbon atoms, preferentially between 4 and 12 carbon atoms and even more preferentially between 4 and 8 carbon atoms.

[0093] Preferably, the solvent is selected from pentane, hexane, cyclohexane, methylcyclohexane, heptane, butane or isobutane, cycloocta-1,5-diene, benzene, toluene, ortho-xylene, mesitylene, ethylbenzene, diethyl ether, tetrahydrofuran, 1,4-dioxane, dichloromethane, dichloroethane, tetrachloroethane, hexachloroethane, chlorobenzene, dichlorobenzene, butene, hexene and octene, alone or in mixtures.

[0094] Preferably, the solvent may be advantageously selected from the products of the oligomerization reaction. Preferably, the solvent used is cyclohexane.

[0095] To release the energy of the reaction, one or more recycle loops are used, which make it possible to pass from the bottom of the reactor the liquid phase fraction containing the products of the reaction, the solvent and the catalytic system through an exchanger and then to the top of the reactor.

[0096] Preferably, the resulting linear α-olefin contains from 4 to 20 carbon atoms, preferably from 4 to 18 carbon atoms, preferably from 4 to 10 carbon atoms, preferably from 4 to 8 carbon atoms. Preferably, the olefin is a linear α-olefin selected from but-1-ene, hex-1-ene and oct-1-ene.

[0097] Advantageously, the reaction section comprises one or more reactors of gas / liquid or all-liquid type, at least one of which has a zone of variable diameter, arranged in series and / or in parallel, and also their associated equipment, such as, for example: - one or more recirculation loops; including one or more heat exchangers, associated with the (respective) reactor(s), to control the exothermicity of the reaction; - means for introducing an oligomerization catalyst system into one or more reaction sections; - Means for isolating / neutralizing the catalyst system, external to the reaction section.

[0098] Advantageously, the oligomerization step a) comprises at least one of the following substeps: - a step a1) of introducing a catalytic system, - a step a2) of contacting with an olefin feedstock, - a step a3) of withdrawing the liquid fraction, - a step a4) of cooling at least a portion of the liquid fraction, - a step a5) of introducing the cooled liquid fraction into the reactor.

[0099] Preferably, the oligomerization step a) comprises the substeps a1), a2), a3), a4) and a5).

[0100] In one particular embodiment, the reaction effluent resulting from step a) and advantageously sent to a separation section downstream of the reaction section is obtained by splitting the liquid fraction withdrawn at step a3) into two streams. The first stream is sent to the cooling step d) and the second stream corresponds to the reaction effluent and is sent to the downstream separation section. Advantageously, the flow rate of the reaction effluent is regulated to keep the liquid level in the reactor constant. Preferably, said flow rate of the reaction effluent is 5 to 200 times less than the liquid flow rate sent to the cooling step a4) (i.e. the flow rate of the part of the liquid phase fraction sent to step a4)). Preferably, said flow rate of the reaction effluent is 5 to 150 times less, preferably 10 to 120 times less, more preferably 20 to 100 times less than the liquid flow rate sent to the cooling step a4).

[0101] (Step a1) of introducing the catalytic system) Advantageously, the oligomerization step a) comprises a substep a1) of introducing a catalytic system comprising a metal precursor, advantageously an activator, optionally an additive and optionally a solvent or a mixture of solvents.

[0102] Preferably, the catalyst system is introduced as a mixture with the cooled liquid fraction introduced into the reactor in step a5).

[0103] Preferably, the pressure for introduction into the reactor is between 0.1 and 10.0 MPa, preferably between 0.2 and 9.0 MPa, preferentially between 0.3 and 8.0 MPa.

[0104] (Step a2) of contacting with olefin feedstock) Advantageously, the oligomerization step a) comprises a substep a2) of introducing a gaseous olefin feedstock, preferably gaseous ethylene. Preferably, said olefin feedstock is introduced in the liquid phase in the lower part of the reactor. The olefin feedstock may comprise fresh feedstock, preferably in a mixture with olefin feedstock recycled to the oligomerization step a) from a downstream separation step.

[0105] Preferably, when the olefin feedstock introduced is gaseous, said feedstock is distributed by dispersion during its introduction into the liquid phase below the reactor, this being carried out by means capable of carrying out said dispersion uniformly throughout the reactor section, preferably the dispersion means being chosen from a distribution system which distributes the injection points of the olefin feedstock uniformly throughout the reactor section.

[0106] Preferably, the flow rate at which the olefin feedstock is introduced is from 1 to 250 t / h, preferably from 2 to 200 t / h, preferably from 5 to 100 t / h.

[0107] Preferably, the flow rate of the olefin feedstock introduced in step a2) is controlled by the pressure in the reactor.

[0108] According to a particular implementation of the invention, a gaseous hydrogen stream may also be introduced into the reactor, the flow rate representing 0.01% to 1.0% by weight of the flow rate of the incoming olefin feedstock. Preferably, the gaseous hydrogen stream is introduced by the pipe used for the introduction of the olefin feedstock.

[0109] (Step a3) of extracting the liquid phase fraction) Advantageously, the oligomerization step a) comprises a substep a3) of withdrawing a liquid phase fraction from the oligomerization reactor, preferably in the lower part of said reactor.

[0110] The withdrawal carried out in step a3) is preferably carried out below the level of injection of the olefin feedstock, preferably at the bottom of the chamber, by any means capable of carrying out the withdrawal, preferably by a pipe associated with a pump.

[0111] The withdrawal flow rate is preferably 10 to 10,000 t / h, more preferably 100 to 7,000 t / h.

[0112] (Step a4) of cooling the liquid fraction) Advantageously, the oligomerization step a) comprises a substep a4) of cooling at least a part of the liquid phase fraction withdrawn in step a3) to a temperature T(loop). Preferably, the cooling step is carried out by making at least a part of the liquid phase fraction withdrawn in step a3) flow through one or more heat exchangers located in a recirculation loop.

[0113] Advantageously, the heat exchanger or exchangers used in substep a4) make it possible to reduce the temperature of the liquid fraction by between 1.0° C. and 30.0° C., preferably between 2.0° C. and 25° C., preferably between 3.0° C. and 20.0° C., preferably between 5.0° C. and 15.0° C. Advantageously, the cooling of the liquid fraction makes it possible to maintain the temperature of the reaction medium within the desired temperature range for carrying out the oligomerization reaction in the reactor.

[0114] Advantageously, the implementation of a step of cooling the liquid through a recirculation loop also makes it possible to provide stirring of the reaction medium and therefore to homogenize the concentration of the reactants throughout the liquid volume of the reactor.

[0115] (Step a5) of introducing the cooled liquid fraction) Advantageously, the oligomerization step a) comprises a substep a5) of introducing the cooled liquid fraction resulting from step a4).

[0116] The introduction of the cooled liquid fraction resulting from step a4) is preferably carried out in the liquid phase of the reactor, preferably in the upper part of said reactor, by any means known to the skilled person, for example by a pipe.

[0117] Preferably, the flow rate for the introduction of the cooled liquid fraction is between 10 and 10,000 t / h, preferably between 100 and 7,000 t / h.

[0118] Substeps a3) to a5) constitute a recirculation loop which advantageously makes it possible, in addition to controlling the temperature in the reactor, to ensure stirring of the reaction medium and therefore a homogenization of the concentration of the reactants throughout the liquid volume of the reactor.

[0119] (Downstream separation process b)) The process according to the invention therefore comprises a step b) of separation of the effluent resulting from the oligomerization step a) in a separation section to obtain, inter alia, a solvent fraction.

[0120] Said solvent fraction consists mainly of solvent. Advantageously, the solvent content of said solvent fraction is greater than or equal to 95% by weight, preferably greater than or equal to 98% by weight, preferably greater than or equal to 99% by weight.

[0121] Typically, the separation step located downstream of the reaction section may employ separation means, e.g., distillation columns, operating in series and based on the difference in boiling points of the compounds to be separated, including one or more products of the oligomerization reaction, e.g., the resulting linear α-olefins, optionally unreacted olefin feedstock, and one or more solvents.

[0122] Preferably, the separation step also comprises a preliminary step of neutralizing the catalyst. For this reason, separation step c) can be carried out in a catalyst neutralization section located upstream of the separation section, said neutralization section being advantageously downstream of the reaction section. The catalyst may then be removed from the product of the reaction in a dedicated manner or in a mixture with the heaviest compounds.

[0123] Preferably, the separation section comprises at least two distillation columns, preferably at least three distillation columns, preferably at least four distillation columns. Said columns are positioned in parallel and / or in series, preferably in series. According to a preferred variant, the distillation section comprises three distillation columns. Separation of the solvent fraction can be carried out in any one of the distillation columns of the downstream separation section, as long as said solvent fraction consists mainly of solvent, said solvent fraction can be recycled to the oligomerization reactor.

[0124] Advantageously, the separation step b) uses a first distillation column, the pressure of which is between 0.1 and 3.0 MPa, preferably between 0.5 and 1 MPa, the temperature at the top of the column being between 0° C. and 100° C., preferably between 40° C. and 80° C., and the temperature at the bottom of the column being between 100° C. and 300° C., preferably between 140° C. and 220° C. Said first distillation column makes it possible to separate the unconverted olefin feedstock in the top fraction, in particular the unconverted ethylene, from the remaining compounds in the bottom fraction.

[0125] Advantageously, the separation step b) uses a second distillation column, the pressure of which is between 0 and 2.0 MPa, preferably between 0.01 and 1.0 MPa, the temperature at the top of the column is between 20° C. and 150° C., preferably between 40° C. and 130° C., and the temperature at the bottom of the column is between 50° C. and 300° C., preferably between 80° C. and 250° C. Preferably, said second distillation column makes it possible to separate the bottom fraction resulting from the first distillation column into a top fraction containing the linear α-olefins obtained, in particular hex-1-ene, and a bottom fraction containing the solvent and the heaviest compounds.

[0126] Advantageously, the separation step b) uses a third distillation column, in which the pressure is 0 to 1.0 MPa, preferably 0.01 to 0.5 MPa, the column top temperature is 30° C. to 130° C., preferably 50° C. to 90° C., and the column bottom temperature is 50° C. to 200° C., preferably 90° C. to 180° C. Preferably, the third distillation column makes it possible to separate hex-1-ene at the top from the solvent at the bottom.

[0127] As a non-limiting example, in the case of the trimerization of ethylene to hex-1-ene, the reaction effluent resulting from the ethylene trimerization step a) comprising ethylene, the solvent, the catalytic system for the trimerization of ethylene and the formed product comprising hex-1-ene may be separated in a separation step b) comprising at least the following substeps: b1) a first step, in which in a first distillation column the effluent from the ethylene trimerization reaction is separated into a top fraction containing unconverted ethylene and a bottom fraction, - b2) a second step, in which at least a portion of the bottom fraction resulting from step b1) is separated in at least one other distillation column into an overhead fraction comprising hex-1-ene and a bottom fraction comprising solvent and C8+ hydrocarbons, - b3) a third step, in which in a final distillation column at least part of the fraction comprising hex-1-ene and the solvent resulting from step b2) are separated into a top fraction comprising mainly hex-1-ene and a bottom fraction comprising mainly solvent and advantageously at least partly constituting the solvent fraction.

[0128] According to the invention, at least one solvent fraction originating from the bottom fraction resulting from step b3) is cooled in step c) and then sent back to the reaction section in step d).

[0129] (Cooling process c)) The process according to the invention comprises cooling the solvent fraction resulting from the downstream separation step b) to a temperature T loop and c) cooling the mixture to a temperature below

[0130] Temperature T of the solvent fraction recirculation loop loopCooling to a temperature below 0.1 V, preferably from the temperature of the cooled liquid fraction obtained at the end of step a4), makes it possible to reduce the heat exchange, i.e. the amount of heat exchanged, required in the recirculation loop or loops to reach the temperature of the cooled liquid fraction emerging from said loops and introduced into the reactor, and therefore reduce the size of the exchanger or exchangers.

[0131] The cooling of the solvent fraction in step c) may be carried out by exchange in one or more heat exchangers, either with a process fluid, with air, with cooling water or with any other type of cryogenic fluid making it possible to reach the desired temperature, or by using a combination of these exchangers. Advantageously, the exchangers are chosen from one or more heat exchangers of the process fluid / process fluid type (TEMA type or other types known to the skilled person), of the air cooler type, of the cooling water exchanger type or with any other type of cryogenic fluid making it possible to reach the desired temperature.

[0132] Advantageously, the solvent fraction resulting from step b) is cooled in step c) to a temperature between 0°C and 150°C, preferably between 5°C and 100°C, preferably between 10°C and 90°C, preferably between 20°C and 80°C, preferably between 25°C and 70°C, preferably between 30°C and 60°C.

[0133] Advantageously, the solvent fraction resulting from step b) is cooled in step c) to a temperature T loop C., preferably at least 50.degree. C., preferably at least 60.degree. C., preferably at least 70.degree. C. lower than that.

[0134] Step d) of introducing the fraction resulting from (c) The process according to the invention therefore comprises a step d) of introducing into the reaction section of the oligomerization step a) a solvent fraction cooled in step c) to a temperature below the temperature T(loop) of the recycle loop.

[0135] The introduction of the cooled solvent fraction according to the invention makes it possible to partially control the exothermicity of the oligomerization reaction and therefore to limit the size of the heat exchanger or exchangers used in at least one recycle loop.

[0136] Advantageously, the introduction of the cooled solvent fraction takes place in the reaction section, preferably in one or more of the reactors and / or recycle loops. Preferably, the introduction takes place in a recycle loop, advantageously upstream or downstream of the heat exchanger of said recycle loop, i.e. upstream or downstream of step a4). Preferably, the introduction of the cooled solvent fraction takes place in the recycle loop of the reaction section, downstream of the heat exchanger of said recycle loop.

[0137] Advantageously, the introduction of the cooled solvent fraction downstream of the thermal exchanger of the recirculation loop makes it possible to minimize the temperature difference between the cooled solvent fraction and the liquid fraction of the recirculation loop, which also makes it possible to maximize the use of the exchanger(s) of the recirculation loop and therefore to minimize their size.

[0138] Advantageously, the mixture of the cooled solvent fraction in step c) with the circulating liquid fraction makes it possible, preferably downstream of the heat exchanger, in the recirculation loop of the reaction section to reduce the temperature of the liquid fraction in the recirculation loop by between 0.1° C. and 20.0° C., preferably between 0.2° C. and 15.0° C., preferably between 0.5° C. and 10.0° C.

[0139] Advantageously, the flow rate of the cooled solvent fraction, as a percentage by weight relative to the flow rate of the liquid circulating in the recirculation loop, is between 0.05% and 15.0%, preferably between 0.1% and 10.0%, preferably between 0.5% and 8.0%, preferably between 0.8% and 6.0%, preferably between 1.0% and 5.0%.

[0140] Thus, the implementation of steps c) and d) according to the invention makes it possible to lower the energy exchanged in the recycle loop by the cooled solvent fraction and therefore to reduce the size of the exchangers. The expected savings may advantageously be of the order of magnitude of 1% to 50%, preferably 2% to 30%, preferentially 3% to 20% over the entire exchange surface area.

[0141] (Figure description) FIG. 1 shows a schematic diagram of a plant for carrying out an embodiment of the oligomerization process according to the invention. The plant comprises a two-phase gas / liquid oligomerization reactor (A), a variable diameter zone (not shown), a recirculation loop including an exchanger (B) and a pump (C), a separation section (D), a pump (E) for distributing the solvent fraction, and an exchanger (F) for cooling the solvent fraction. In this plant, stream (2) is a mixture of fresh ethylene stream (1) and ethylene originating from the separation section. Stream (2) is introduced into the reactor (A). Stream (3) is the liquid phase fraction withdrawn from the reactor and is sent to a recirculation loop including an exchanger (B) and a pump (C) to obtain a cooled liquid fraction (4). Stream (6) is the solvent fraction separated in the separation section (D), which passes through a pump (E) and is cooled in an exchanger (F) to give a cooled solvent fraction (7). Fractions (7) and (4) are mixed and then introduced into the reactor (A) to give stream (8). Stream (5), which represents a portion of the effluent withdrawn from the reactor (A), is sent to a separation section (D), which makes it possible to obtain stream (6), stream (9) which represents light reaction products, stream (10) which represents heavy reaction products and stream (11) which represents a heavy fraction comprising the spent catalyst.

[0142] FIG. 2 shows a gas / liquid reactor (A) according to the invention with successive zones of decreasing diameter. The gas / liquid reactor (A) comprises a lower part containing a liquid phase, an upper part containing a gas phase and means for introducing a gaseous olefin feedstock (12) into the liquid phase by a gas distributor (13). The upper part comprises a withdrawal means (15). The fractions divided into two streams are withdrawn from the bottom of the reactor (A), the first main stream (3) being sent to a heat exchanger (B) and a pump (C) to obtain a cooled fraction (4). The second stream (5) corresponds to the effluent sent to the separation section. The fractions (7) and (4) are mixed in stream (8) before being introduced into the reactor (A). The catalyst system (14) is introduced into the bottom of the reactor. The zone (1) located at the bottom of the reactor has a larger diameter than the zone located at the top of the reactor. The first, bottom zone is characterized by its diameter, denoted D1, and its height H1, these two parameters defining the volume of said zone, denoted V1. Similarly, the second zone, located at the top, is characterized by its height, denoted H2, and its diameter, denoted D2 (D2 being less than D1), which define the volume of the second zone (V2). In this embodiment, the two zones making up the reactor (A) are formed by cylinders with decreasing diameters.

[0143] FIG. 3 shows another embodiment, which differs from that of FIG. 2 in that the second zone, located at the top of the reactor (A), is delimited by an internal structure (11) located inside the reactor (A).

[0144] FIG. 4 shows another embodiment, which differs from that of FIG. 2 in that reactor A contains three successive zones of decreasing diameter.

[0145] 1, 2, 3 and 4 provide schematic illustrations of certain embodiments of the present subject matter, but are not intended to limit the scope of said invention.

[0146] (Example) The following examples are illustrative of the present invention and are not intended to limit the scope of the invention.

[0147] The following example describes a process for the oligomerization of ethylene. The process is carried out continuously in a two-phase gas / liquid reactor of the bubble column type at a pressure of 6.1 MPa and a temperature of 135° C. The catalytic system is introduced into the reactor at a concentration of 1 ppm by weight of chromium. The catalytic system comprises 11 molar equivalents of triethylaluminum and 8 molar equivalents of diethylaluminum chloride relative to chromium in the presence of the chromium precursor Cr(2-ethylhexanoate)3, 2,5-dimethylpyrrole in a molar ratio of 3 relative to chromium, o-xylene as additive in a molar ratio of 500 relative to chromium, and cyclohexane as solvent.

[0148] The amount of cyclohexane used as solvent (6) and introduced into reactor (A) depends on the amount of ethylene (stream (2)) entering the same reactor (A); the amount of solvent is adjusted so that the solvent content in the reactor is 58%.

[0149] (Example 1 (Comparative Example)) Example 1 illustrates an oligomerization process according to the prior art, in which the solvent fraction (7) is separated in a downstream separation section and recycled to the reaction section without cooling by a heat exchanger (F), in which a gas-liquid reactor of the bubble column type is used.

[0150] The catalyst system is contacted with gaseous ethylene by introducing said gaseous ethylene into the lower part of the reactor, and the reaction effluent is subsequently collected at the bottom of the reactor.

[0151] The conversion of ethylene required for the production of hex-1-ene is 14,000 kg / h. The solvent flow rate under the operating conditions adopted is 19,500 kg / h. The temperature of the recycled solvent fraction is 101° C.

[0152] The residence time in the reaction section (reactor + recirculation loop(s)) is 40 minutes.

[0153] The oligomerization reaction is exothermic, so the heat generated by the reaction is dissipated by a 1,650m2 sieve. 2 This is removed by a heat exchanger placed on the recirculation loop outside the reactor. 3 The total reaction liquid volume is distributed between the volumes occupied by the heat exchangers and their recycle loops and the reactor. The total reaction liquid volume is distributed in the following manner: 30.4 m 3 is the heat exchange loop, and 11.0m 3 is the reactor. The height of the liquid in the reactor is then 4.8 meters (expressed as m) for a diameter of 1.7 m. The temperature of the mixture (8) of the solvent fraction (7) and the recycle fluid (4) is then 120° C. at the reactor inlet. The temperature of the stream (4), which corresponds to the stream at the outlet of the exchanger (B) of the recycle loop of the reaction section, is then 120.4° C.

[0154] The production amount of hex-1-ene was 9.32 tons / hour, and the selectivity for hex-1-ene was 93.2% by weight.

[0155] Example 2 (in accordance with the present invention) An oligomerization process according to the invention is shown in Figure 1. The process is carried out under the same conditions as in Example 1. Example 2 includes the step of cooling the solvent fraction coming from the separation section before its introduction into the reaction section using an exchanger (F) and a reactor (A) with a variable diameter zone as shown in Figure 1. The solvent fraction is cooled to a temperature of 40°C.

[0156] The total surface area of ​​the recirculation loop exchangers is 1,440 m 2 Therefore, the method according to the invention makes it possible to reduce the exchange surface area of ​​the heat exchanger by about 13% (=100×(1,650−1,440) / 1,650) compared to the exchange surface area of ​​Example 1. This represents a saving in the operating costs of the unit.

[0157] In this example, the residence time is kept the same as in Example 1, namely 40 minutes (min). The total reaction liquid volume is the same as in Example 1. The step of cooling the solvent fraction therefore makes it possible to reduce the exchange requirements in the recirculation loop, which leads to a reduction in the surface area of ​​the exchangers.

[0158] The volume of the recirculation loop was reduced by 3% (volume 29.5 m) due to the reduction in the surface area required for the exchanger. 3 ) at the same time, the liquid volume of the reactor is reduced by 8% (working volume 11.9 m 3 ) which results in an 8% increase in the liquid height.

[0159] Moreover, the use of a reactor with variable diameter zones makes it possible to obtain a further increase of 35% in the liquid height (total liquid height of 7.1 m). The liquid height in the lower zone of the reactor is 2.1 m for a diameter of 1.7 m. The height of the upper part of the liquid reactor is then 4.9 m for a diameter of 1.35 m.

[0160] The target temperature of the mixture (8) of solvent fraction (7) and liquid fraction (4) circulating in the recirculation loop was kept the same as in Example 1, namely 120° C. The temperature of the cooled liquid fraction (4), corresponding to the outlet of exchanger (B), is then 121.9° C.

[0161] In addition, the 3% reduction in the volume of the recirculation loop and the use of a gas / liquid reactor with variable diameter zones also make it possible to increase the volume of liquid in the reactor by 9% and the liquid height by 47%, which makes it possible to maximize the saturation of ethylene in the liquid contained in the reactor.

[0162] The production of hex-1-ene is 9.32 tonnes / hour and the selectivity for hex-1-ene is 93.2% by weight.

[0163] Example 3 (in accordance with the present invention) The oligomerization process according to the invention is carried out under the same conditions as in Example 2.

[0164] The step of cooling the solvent fraction makes it possible to reduce the exchange requirements in the recirculation loop, which leads to a reduction in the surface area of ​​the exchangers. The solvent fraction is cooled to a temperature of 40° C. The total surface area of ​​the exchangers in the exchange loop is reduced to 1,440 m 2 The method according to the invention therefore makes it possible to reduce the exchange surface area of ​​the heat exchanger by approximately 13% (=100×(1,650−1,440) / 1,650) compared to the exchange surface area of ​​example 1, which represents a saving in the operating costs of the unit.

[0165] The liquid height in the reactor is kept the same as in Example 1. The reactor now contains two zones, the lower one 1.6 m high for a diameter of 1.7 m and the upper one 3.1 m high for a diameter of 1.35 m. Due to the reduction in the surface area required for the exchanger, the volume of the recirculation loop is reduced by 3% (volume 29.5 m). 3 The liquid volume of the reactor with variable diameter zones is reduced by 8.4 m 3 The total reaction liquid volume in the reaction section is therefore 37.8 m 3 , ie a saving of 8% compared to Example 1.

[0166] The temperature target of the mixture (8) of solvent (7) and recycle fluid (4) was kept the same as in Example 1, namely 120° C. The temperature of stream (4), which corresponds to the outlet of exchanger (B), is now 121.9° C.

[0167] In this example, the residence time is 36.6 minutes. The process according to the invention allows a reduction in the residence time, which leads to an increase in selectivity of 0.1%. This increase allows a reduction in ethylene consumption of 0.1% for a given amount of hex-1-ene produced, thus saving on the operating costs of the unit. The reduction in residence time also allows a saving of 8% (corresponding to 4 ppm chromium) in the chromium concentration required to achieve this performance, i.e. a saving in catalyst consumption and therefore a saving in the operating costs of the unit.

[0168] The production of hex-1-ene is 9.32 tonnes / hour and the selectivity for hex-1-ene is 93.3% by weight.

[0169] The following table summarizes the results obtained in Examples 1-3.

[0170] [Table 1]

[0171] [Brief description of the drawings]

[0172] [Figure 1] 1 depicts a schematic diagram of a plant for carrying out an embodiment of the oligomerization process according to the invention. [Diagram 2] FIG. 1 shows a gas / liquid reactor (A) according to the present invention having successive zones of decreasing diameter. [Diagram 3] Another embodiment is shown, which differs from that of FIG. 2 in that the second zone, located at the top of the reactor (A), is delimited by an internal structure (11) located inside the reactor (A). [Figure 4] An alternative embodiment is shown, which differs from that of FIG. 2 in that reactor A contains three successive zones of decreasing diameter.

Claims

1. A method for the oligomerization of an olefin feedstock, the method comprising the following steps: a) a step of oligomerizing the olefin feedstock; carried out in a reaction section at a temperature of 30°C to 200°C, a pressure of 0.1 to 10 MPa, in the presence of an oligomerization homogeneous contact system and a solvent; the reaction section includes the following: an oligomerization reactor having a variable diameter zone and containing a liquid phase, and The temperature T of at least a part of the liquid fraction ｌｏｏｐ At least one recirculation loop enabling cooling to b) a step of separating the reaction effluent resulting from the oligomerization step a) in a separation section; obtaining a solvent fraction, c) cooling the solvent fraction resulting from step b) to a temperature T which is lower than the temperature at which the liquid phase fraction is cooled in one or more recirculation loops ｌｏｏｐ wherein the cooling is carried out d) a step of introducing the cooled solvent fraction resulting from step c) into the reaction section of the oligomerization step a).

2. The reactor having a variable diameter zone includes n consecutive zones, where n is a positive integer from 2 to 10, - for each of the n zones, having a diameter Dn, and the diameter Dn decreases in the direction from the bottom zone to the top zone of the reactor, - the ratio (Dn / Dn - 1) of the diameter (denoted as Dn) of the adjacent lower zone to the diameter (denoted as Dn - 1) of the upper zone is 0.9 or less, - for a given zone, the ratio of the volume (denoted as Vn) of the reaction chamber of the zone to the total volume (denoted as Vtot) of the reaction chamber is 0.2 to 0.8 The method according to claim 1.

3. The method according to claim 2, wherein the n consecutive zones of the reactor having a variable diameter zone are arranged in series along the vertical axis of the reactor, defining a zone having a diameter that decreases from the bottom to the top within the reaction enclosure.

4. The method according to any one of claims 1 to 3, wherein the solvent fraction resulting from step b) is cooled to a temperature of 0°C to 150°C in step c).

5. The solvent fraction resulting from step b) is cooled in step c) to a temperature lower than at least 40 °C relative to the temperature T of the liquid phase fraction cooled in one or more recirculation loops. ｌｏｏｐ The method according to claim 1, wherein the cooling is to a temperature lower than at least 40 °C relative to the temperature T of the liquid phase fraction cooled in one or more recirculation loops.

6. The cooling of the solvent fraction in step c) is carried out by one or more heat exchangers, preferably selecting the heat exchanger from one or more heat exchangers of the process fluid / process fluid type, air cooler type, or cooling water exchanger type. The method according to claim 1.

7. The separation section includes at least two distillation columns, preferably at least three distillation columns, preferably at least four distillation columns. The method according to claim 1.

8. The method according to claim 1, wherein step d) of introducing the cooled solvent fraction is carried out in the reactor and / or one or more recirculation loops.

9. The method according to claim 5, wherein step d) of introducing at least a part of the cooled solvent fraction is carried out in a recirculation loop, upstream or downstream of the heat exchanger of one or more recirculation loops, preferably downstream of the heat exchanger.

10. The method according to claim 1, wherein the flow rate of the cooled solvent fraction is 0.05% to 15.0%, preferably 0.1% to 10.0%, as a weight percentage relative to the flow rate of the liquid phase fraction flowing in one or more recirculation loops.

11. The method according to claim 1, wherein the olefin feedstock comprises olefins having 2 to 6 carbon atoms, preferably 2 to 4 carbon atoms.

12. The method according to claim 1, wherein the oligomerization step a) comprises at least one of the following sub-steps: - Sub-step a1) of introducing a catalyst system, - Sub-step a2) of contacting with an olefin feedstock, - Sub-step a3) of withdrawing a liquid phase fraction from the oligomerization reactor, - Sub-step a4) of cooling at least a part of the liquid fraction withdrawn in sub-step a3) to a temperature T ｌｏｏｐ in at least one recirculation loop. - Sub-step a5) of introducing the cooled liquid fraction into the reactor.

13. The method according to claim 12, wherein cooling sub-step a4) is carried out by passing at least a part of the liquid phase fraction withdrawn in sub-step a3) through one or more heat exchangers located in one or more recirculation loops.

14. The method according to claim 13, wherein the one or more heat exchangers used in sub-step a4) reduce the temperature of the liquid phase fraction withdrawn in sub-step a3) by 1.0 to 30.0 °C, preferably 2.0 to 25.0 °C.

15. The method according to claim 12, wherein the reaction effluent is obtained by dividing the liquid fraction withdrawn in sub-step a3) into two streams.

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