Exterior member for vehicle, and exterior member for vehicle with far-infrared camera

Abstract

To provide an exterior member for a vehicle which is excellent in strength and cost and in which a visual field of definition of a thermal image obtained by a far-infrared camera is secured sufficiently.SOLUTION: An exterior member for a vehicle is mounted on a vehicle equipped with a far-infrared camera and has a light-shielding area, and further comprises, in the light-shielding area, a far-infrared transmitting area having an opening part and a far-infrared transmitting member arranged in the opening part. An average transmission of far-infrared of the far-infrared transmitting member is above 25%. A length of a longest straight line of straight lines connecting arbitrary two points in a surface outside a vehicle of the far-infrared transmitting member is below 80 mm. A diameter of a largest circle of circles formed inside a projection drawing obtained by projecting the far-infrared transmitting member in an optical axis direction of the far-infrared camera is above 12 mm. An average thickness of the far-infrared transmitting member is above 1.5 mm.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to a vehicle exterior member and a vehicle exterior member equipped with a far-infrared camera. [Background technology]

[0002] In recent years, various sensors are automatically installed in automobiles to improve safety. Examples of sensors that can be installed in automobiles include cameras, LiDAR (Light Detecting and Ranging), millimeter wave radar, and infrared sensors.

[0003] Infrared rays are classified according to their wavelength band into near-infrared (for example, wavelengths of 0.7 μm to 2 μm), mid-infrared (for example, wavelengths of 3 μm to 5 μm), and far-infrared (for example, wavelengths of 8 μm to 13 μm). Infrared sensors that detect these infrared rays include touch sensors, near-infrared cameras, and LiDAR for near-infrared rays, gas analysis and mid-infrared spectroscopy (functional group analysis) for mid-infrared rays, and night vision and thermo viewers (hereinafter, far-infrared cameras) for far-infrared rays.

[0004] Since far-infrared rays with wavelengths of 8 μm to 13 μm do not usually pass through automobile window glass, far-infrared cameras have conventionally been installed outside the vehicle cabin, on the front grille, as in Patent Document 1, for example. However, when installing a far-infrared camera outside the vehicle cabin, the structure becomes more complicated in order to ensure robustness, water resistance, dust resistance, etc., which leads to high costs. By installing a far-infrared camera inside the vehicle cabin, especially in the operating area of ​​the wipers, the far-infrared camera is protected by the window glass, which solves this problem. However, due to the problem of the far-infrared transmittance of the window glass as described above, it has conventionally been impossible to install a far-infrared camera inside the vehicle cabin.

[0005] In order to meet the above demand, Patent Document 2 discloses a window member in which a through hole is formed in part of the window glass and filled with an infrared-transmitting material. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] US Patent Application Publication No. 2003 / 0169491 [Patent Document 2] GB 2271139 Summary of the Invention [Problem to be solved by the invention]

[0007] In the window member shown in Patent Document 2, if the through-hole is too large, the strength of the window member is reduced, and the amount of infrared-transmitting material used to fill the window member is increased, resulting in increased costs. On the other hand, if the through-hole is too small, the amount of far-infrared radiation reaching the far-infrared camera is reduced, resulting in reduced brightness and blurring of the thermal image obtained. In other words, the clarity of the thermal image is reduced. However, Patent Document 2 does not fully consider the size of the through-hole, and therefore the specific configuration of a window member that has sufficient strength, cost, and field of view for practical use by the far-infrared camera has not yet been clarified.

[0008] In view of the above, an object of the present invention is to provide an exterior component for a vehicle, such as a window component, which is excellent in strength and cost and further ensures sufficient clarity of a thermal image obtained by a far-infrared camera. Another object of the present invention is to provide a vehicle exterior member equipped with a far-infrared camera, in which a far-infrared camera is attached to the vehicle exterior member. [Means for solving the problem]

[0009] The vehicle exterior member of the present invention that solves the above-mentioned problems is a vehicle exterior member having a light-shielding region that is attached to a vehicle equipped with a far-infrared camera, and further comprises a far-infrared transparent region having an opening and a far-infrared transparent member disposed within the opening within the light-shielding region, the far-infrared transparent member having an average transmittance of far-infrared rays having a wavelength of 8 to 13 μm of 25% or more, a length of the longest straight line among straight lines connecting any two points within the surface of the far-infrared transparent member on the vehicle exterior side being 80 mm or less, a diameter of the largest circle among circles formed inside a projection obtained by projecting the far-infrared transparent member in the optical axis direction of the far-infrared camera being 12 mm or more, and an average thickness of the far-infrared transparent member being 1.5 mm or more. In one aspect of the present invention, the vehicle exterior member may be a vehicle window member. In one aspect of the present invention, the vehicle exterior member may be an exterior member for a pillar of a vehicle. In one embodiment of the vehicle exterior member of the present invention, the far-infrared transmitting member may be made of at least one material selected from the group consisting of ZnS, Ge, Si, and chalcogenide glass. In one embodiment of the vehicle exterior member of the present invention, the surface of the far-infrared transmitting member facing the vehicle exterior has 3 to 12 layers of antireflection film, and the outermost layer of the antireflection film may be a diamond-like carbon film. In one embodiment of the vehicle exterior member of the present invention, the surface of the far-infrared transmitting member facing the vehicle exterior may be formed flush with the surface of the light-shielding region facing the vehicle exterior. In one embodiment of the vehicle exterior member of the present invention, the far-infrared transparent member may be attached with a urethane-based adhesive and / or an acrylic-based adhesive. In one embodiment of the vehicle exterior member of the present invention, the area of ​​the opening on the vehicle inner surface may be smaller than the area of ​​the opening on the vehicle outer surface. In one embodiment of the vehicle exterior member of the present invention, the light-shielding region may further include a visible light transmitting region having a visible light transmittance of 70% or more. In addition, the vehicle exterior member with a far-infrared camera of the present invention comprises the vehicle exterior member of the present invention and a far-infrared camera, and the far-infrared camera is attached to the vehicle exterior member so as to capture a thermal image of the outside through the far-infrared transparent area. One aspect of the vehicle exterior member with a far-infrared camera of the present invention comprises the vehicle exterior member of the present invention, a far-infrared camera, and a visible light camera, and the far-infrared camera is attached to the vehicle exterior member so as to be able to capture thermal images of the outside through the far-infrared transparent member, and the visible light camera may be attached to the vehicle exterior member so as to be able to capture images of the outside through the visible light transparent region. In one embodiment of the exterior member for a vehicle equipped with a far-infrared camera of the present invention, the optical axis of the far-infrared camera and the optical axis of the visible light camera may be approximately parallel, and the distance between these optical axes may be 20 cm or less. In one embodiment of the far-infrared camera-equipped vehicle exterior member of the present invention, the visible light camera may be a stereo camera equipped with a first camera and a second camera, and the far-infrared camera may be located between the first camera and the second camera. In one embodiment of the vehicle exterior member with a far-infrared camera of the present invention, the far-infrared camera is attached to the vehicle exterior member via a bracket, and the inside of the bracket may be kept at a vacuum or may be filled with a thermal insulating material. In one embodiment of the vehicle exterior member with a far-infrared camera of the present invention, the far-infrared camera is attached to the vehicle exterior member via a bracket, and may further include a temperature regulator for regulating the temperature inside the bracket. Effect of the Invention

[0010] According to the present invention, there is provided a vehicle exterior member such as a window member that is excellent in strength and cost and further ensures sufficient clarity of a thermal image obtained by a far-infrared camera. Also, there is provided a vehicle exterior member with a far-infrared camera in which a far-infrared camera is attached to the vehicle exterior member. [Brief description of the drawings]

[0011] [Figure 1] FIG. 1 is a schematic plan view of one embodiment of a vehicle exterior member of the present invention. [Diagram 2] FIG. 2 is a cross-sectional view taken along line AA in FIG. [Diagram 3]FIG. 3 is a schematic cross-sectional view of one embodiment of the vehicle exterior member of the present invention. [Figure 4] FIG. 4 is a schematic cross-sectional view of one embodiment of the vehicle exterior member of the present invention. [Diagram 5] FIG. 5 is a schematic cross-sectional view illustrating the positional relationship between a vehicle exterior member and a far-infrared camera according to one embodiment of the present invention. [Figure 6] FIG. 6 is a schematic diagram illustrating the projection view in FIG. [Figure 7] FIG. 7 is a schematic cross-sectional view illustrating the positional relationship between a vehicle exterior member and a far-infrared camera according to one embodiment of the present invention. [Figure 8] FIG. 8 is a schematic cross-sectional view illustrating the positional relationship between a vehicle exterior member and a far-infrared camera according to one embodiment of the present invention. [Figure 9] FIG. 9 is a schematic cross-sectional view of one embodiment of an exterior member for a vehicle equipped with a far-infrared camera according to the present invention. [Figure 10] FIG. 10 shows infrared transmission spectra of far-infrared transmitting members B, D, F, H, I, and J in the examples. [Figure 11] FIG. 11 is a thermal image showing the positional relationship with a pedestrian in a test (thermal image visual evaluation) carried out in the example. [Figure 12] FIG. 12 shows thermal images of pedestrians extracted from Example 1 (α=30° and 60°), Example 5 (α=30°), Example 10 (α=30° and 45°), Example 12 (α=30°), Example 13 (α=30°), and Example 15 (α=30°) in the tests (thermal image visual evaluation) conducted in the examples. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0012] Hereinafter, an embodiment of the present invention will be described. Note that the present invention is not limited to the embodiment described below. Also, the embodiment shown in the drawings is schematic in order to clearly explain the present invention, and does not necessarily accurately represent the actual size or scale.

[0013] Fig. 1 shows a schematic plan view of one embodiment of a vehicle exterior member of the present invention, and Fig. 2 shows a cross-sectional view taken along line AA in Fig. 1. The vehicle exterior member according to this embodiment is a window member that is applied to a vehicle windshield, and in particular, is a window member that is attached to a vehicle equipped with a far-infrared camera. The embodiment of the vehicle exterior member of the present invention is not limited to a window member applied to a windshield of a vehicle. For example, it may be a window member applied to a rear window or a side window, or it may be other than a window member, for example, an exterior member for a pillar.

[0014] The glass base 2 constituting the window member 1 of the present embodiment may be a single sheet of glass or a laminated glass. Furthermore, the glass base 2 may be subjected to a strengthening treatment such as physical strengthening or chemical strengthening.

[0015] The window member 1 of this embodiment includes a light-shielding region 3. Usually, the window member 1 includes a light-transmitting region 4 in the center to ensure the driver's field of vision, and a light-shielding region 3 surrounding the light-transmitting region 4. Furthermore, a far-infrared camera and other sensors are usually attached to the upper part of the window member 1, and as shown in FIG. 1, a light-shielding region 3 is also provided around the parts where these are attached. Providing the light-shielding region 3 in this manner is preferable because it protects the various sensors from sunlight. Also, it is preferable from the viewpoint of design because the wiring of the various sensors is not visible from outside the vehicle.

[0016] The light-shielding region 3 is formed by providing a light-shielding layer 5 on a glass base 2 that constitutes the window member 1. That is, the light-shielding region 3 is a region where the glass base 2 is provided with the light-shielding layer 5 in a plan view of the window member 1. As the light-shielding layer 5, for example, a ceramic light-shielding layer or a light-shielding film can be used. As the ceramic light-shielding layer, for example, a ceramic layer made of a conventionally known material such as a black ceramic layer can be used. As the light-shielding film, for example, a light-shielding polyethylene terephthalate (PET) film, a light-shielding polyethylene naphthalate (PEN) film, a light-shielding polymethyl methacrylate (PMMA) film, etc. can be used. The light-shielding layer 5 is usually formed on the surface of the glass substrate 2 facing the inside of the vehicle, but may also be formed on the surface facing the outside of the vehicle. Furthermore, when the glass substrate 2 is a laminated glass, the light-shielding layer 5 may be formed between the two pieces of glass that form the laminated glass.

[0017] Moreover, the window member 1 of this embodiment includes a far-infrared ray transmitting region 6 within the light blocking region 3 . The far-infrared ray transmitting region 6 is a region having an opening 7 formed in the light-shielding region 3 and a far-infrared ray transmitting member 8 disposed in the opening 7.

[0018] If the average transmittance of far-infrared rays having a wavelength of 8 to 13 μm through the far-infrared transmitting member 8 is less than 15%, the far-infrared transmittance of the far-infrared transmitting region 6 will be insufficient, and the performance of the far-infrared camera will not be fully demonstrated. Therefore, the average transmittance of far-infrared rays having a wavelength of 8 to 13 μm through the far-infrared transmitting member 8 in this embodiment is set to 25% or more, preferably 40% or more, more preferably 50% or more, even more preferably 70% or more, and particularly preferably 85% or more. Note that an anti-reflection film is essential to improve the average transmittance of far-infrared rays to 85% or more.

[0019] The material of the far-infrared transmitting member is not particularly limited as long as it satisfies the above-mentioned transmittance, and examples thereof include ZnS, Ge, Si, chalcogenide glass, and the like. The preferred composition of the chalcogenide glass is In atomic percent, Ge+Ga; 7%~25%, Sb: 0%~35%, Bi; 0%~20%, Zn: 0%~20%, Sn: 0%~20%, Si: 0% to 20%, La: 0% to 20%, S+Se+Te; 55%~80%, Ti: 0.005%~0.3%, Li+Na+K+Cs; 0%~20%, The composition contains 0% to 20% of F+Cl+Br+I. This glass preferably has a glass transition point (Tg) of 140°C to 550°C.

[0020] The method for attaching the far-infrared transmitting member 8 to the opening 7 is not particularly limited, but it can be attached, for example, with an adhesive such as a urethane adhesive and / or an acrylic adhesive. Since there is generally a large difference in thermal expansion between the window glass of an automobile and the far-infrared transmitting member, it is preferable to select an adhesive that can alleviate this difference and also has excellent adhesive strength, impact resistance, and environmental resistance. In order to improve the environmental resistance, the adhesive surface on the outside of the vehicle may be protected with a resin or the like.

[0021] Between the far-infrared transmitting member 8 and the opening 7, there is preferably a gap of 0.2 to 1.5 mm. If the gap is less than 0.2 mm, the difference in thermal expansion between the automobile window glass and the far-infrared transmitting member may cause optical distortion of the window glass or damage to the window glass and / or the far-infrared transmitting member. The gap is more preferably 0.3 mm or more, and even more preferably 0.5 mm or more. On the other hand, if the gap exceeds 1.5 mm, there is a risk of loss of adhesive strength and impact resistance. The gap is more preferably 1.2 mm or less, and even more preferably 1.0 mm or less.

[0022] As shown in FIG. 2, the surface of the far-infrared transmitting member 8 on the vehicle exterior side is preferably formed flush with the surface of the light-shielding region 3 on the vehicle exterior side. If the surface is not formed flush with the surface on the vehicle exterior side, for example, when the far-infrared transmitting member is applied to the windshield of a vehicle, the wiping effect of the wiper may be impaired. Even when the far-infrared transmitting member is applied to a place other than the windshield, the design of the vehicle may be impaired due to the step, and sand and dust may accumulate on the step. Furthermore, the far-infrared transmitting member is preferably molded to fit the curved shape of the vehicle exterior member to which it is applied. There is no particular limitation on the method of molding the far-infrared transmitting member, but polishing or molding is selected depending on the curved shape and the member.

[0023] The far-infrared transmitting member 8 may be coated on the surface on the vehicle exterior side or the surface on the vehicle interior side. For example, an anti-reflection film may be provided on the vehicle exterior side or the vehicle interior side, or on both surfaces, i.e., on at least one of the vehicle exterior side and the vehicle interior side. The anti-reflection film is preferably an anti-reflection film having 1 to 12 layers, and the material is not particularly limited, but is preferably Ge, Si, ZnS, ZnSe, As2S3, As2Se3, metal oxides (Al2O3, Bi2O3, CeO2, CuO, HfO2, MgO, SiO, SiO2, TiO, TiO2, Ti2O3, Y2O3, ZrO2), hydrogenated carbon, diamond-like carbon (DLC), and metal fluorides (MgF2, CaF2, SrF2, BaF2, PbF2, LaF3, YF3). From the viewpoint of scratch resistance, the layer on the outermost side of the vehicle is preferably a film having a Mohs hardness of 7 or more and a high transmittance of far-infrared rays. It is particularly preferable that the layer on the outermost side of the vehicle is a diamond-like carbon film.

[0024] The shape of the far-infrared ray transmitting member 8 is not particularly limited, but it is preferably a plate shape that matches the shape of the opening 7. That is, for example, when the opening 7 is circular, the far-infrared ray transmitting member 8 is preferably a disk shape (cylindrical shape). As shown in Fig. 3, in the window member 1 of this embodiment, the area of ​​the opening 7 on the surface facing the vehicle interior side is preferably smaller than the area of ​​the opening 7 on the surface facing the vehicle exterior side, and the shape of the far-infrared transmitting member 8 is also preferably such that the area of ​​the surface facing the vehicle interior side is smaller than the area of ​​the surface facing the vehicle exterior side accordingly. By adopting such a configuration, the strength against impact from the outside of the vehicle is improved. As shown in Fig. 4, when the glass substrate of the window member of this embodiment is a laminated glass including a first glass 2a (on the vehicle exterior side) and a second glass 2b (on the vehicle interior side), the area of ​​the opening 7a of the first glass 2a is made larger than the area of ​​the opening 7b of the second glass 2b, and the far-infrared transmitting member 8 that matches the size of the opening 7a of the first glass 2a is disposed within the opening 7a of the first glass 2a. From the viewpoint of strength, the thickness of the far-infrared transmitting member 8 is 1.5 mm or more, preferably 2.0 mm or more, and more preferably 3.0 mm or more. As long as the average transmittance of far-infrared rays having a wavelength of 8 to 13 μm is ensured, the upper limit of the thickness of the far-infrared transmitting member 8 is not particularly limited, but is usually 5.0 mm or less. In addition, the far-infrared transmitting member may be shaped like a lens in order to achieve both a wider viewing angle of the far-infrared camera and improved mechanical properties. This configuration is preferable because far-infrared light can be efficiently collected even if the area of ​​the far-infrared transmitting member is small. In this case, the number of lens-shaped far-infrared transmitting members is preferably 1 to 3, and typically 2. Furthermore, it is particularly preferable that the lens-shaped far-infrared transmitting member is pre-aligned and modularized, and is integrated with a housing or bracket that bonds the far-infrared camera to an exterior member for a vehicle.

[0025] If the surface of the far-infrared transmitting member 8 facing the vehicle exterior is too large, the strength of the window member is insufficient. Therefore, the length of the longest straight line among the straight lines connecting any two points on the surface of the far-infrared transmitting member 8 facing the vehicle exterior in this embodiment is set to 80 mm or less, preferably 70 mm or less, and more preferably 65 mm or less. Note that this length is the length equivalent to the diameter when the shape of the surface of the far-infrared transmitting member 8 facing the vehicle exterior is circular.

[0026] In addition, the amount of far-infrared radiation reaching the far-infrared camera attached to the window member 1 of this embodiment depends on the size of the largest circle formed inside the projection obtained by projecting the far-infrared transparent member 8 in the optical axis direction of the far-infrared camera. Hereinafter, a detailed description will be given with reference to the drawings. FIG. 5 is an enlarged cross-sectional view of the periphery of the far-infrared transmitting region 6 in the window member 1. The window member 1 is usually attached to the vehicle in a state inclined at a predetermined angle α with respect to the horizontal direction H. On the other hand, the far-infrared camera 9 is usually attached so that the optical axis X is almost horizontal. Therefore, the amount of far-infrared radiation reaching the far-infrared camera 9 depends not only on the size of the far-infrared transmitting member 8 but also on the inclination angle α. In consideration of this, when considering the amount of far-infrared radiation reaching the far-infrared camera 9, it is appropriate to consider the size of the projection 11 obtained by projecting the far-infrared transmitting member 8 in the optical axis X direction of the far-infrared camera 9 onto a projection plane 10 perpendicular to the optical axis X. In addition, since the field of view of the far-infrared camera 9 is usually circular, it is appropriate to consider the size of the largest circle 12 among the circles formed inside the projection 11. FIG. 6 shows a schematic diagram explaining the projection 11 projected onto the projection plane 10 in FIG. 5 and the largest circle 12 among the circles formed inside the projection 11. The inventors conducted repeated experiments and found that if the diameter of the largest circle 12 formed inside the projection 11 is less than 12 mm, the amount of far-infrared radiation reaching the far-infrared camera 9 decreases, causing the obtained thermal image to have reduced brightness and become blurred, making it difficult to ensure sufficient clarity of the thermal image. Therefore, in the window member 1 of this embodiment, the diameter of the largest circle 12 among the circles formed inside the projection 11 obtained by projecting the far-infrared transmitting member 8 in the optical axis X direction of the far-infrared camera 9 is set to 12 mm or more, preferably 20 mm or more, and more preferably 30 mm or more. The projection diagram 11 obtained by projecting the far-infrared transparent member 8 in the optical axis X direction of the far-infrared camera 9 refers to a figure obtained by projecting the shape of the surface of the far-infrared transparent member 8 on the vehicle exterior side in the optical axis X direction onto a plane perpendicular to the optical axis X.

[0027] Although it depends on the size of the far-infrared transmitting member 8 and the thickness of the glass base 2, if the angle α of the inclination with respect to the horizontal direction when the window member 1 of this embodiment is attached to a vehicle is too small, the following inconvenience occurs. That is, if the angle α is too small, when the window member 1 is observed in a direction parallel to the optical axis X, the region including only the far-infrared transmitting member 8, i.e., the region including no glass base or light-shielding layer (region Y in FIG. 7), becomes small. If this region Y is too small, there is a risk that the clarity of the thermal image obtained by the far-infrared camera cannot be sufficiently ensured. Therefore, the angle α is appropriately selected so that this region Y is not too small. Furthermore, when the glass substrate is a laminated glass having a first glass 2a (vehicle exterior side) and a second glass 2b (vehicle interior side), the center of the opening 7a of the first glass 2a and the center of the opening 7b of the second glass 2b may be appropriately offset from each other as shown in Fig. 8. With this configuration, it is not necessary to make the openings 7a and 7b excessively large in order to ensure the size of the region Y, particularly even when the angle α is small, so that both particularly high strength and high clarity can be achieved.

[0028] Moreover, the window member 1 of the present embodiment preferably further comprises a visible light transmitting region 13 having a visible light transmittance of 70% or more within the light blocking region 3. By providing the visible light transmitting region 13, a visible light camera can be attached so as to capture an image of the outside from that region. By installing a visible light camera in addition to the far-infrared camera, it becomes possible to recognize information outside the vehicle by combining the information obtained by these two cameras, which contributes to improving the accuracy of object recognition. Also, by providing the far-infrared transparent area 6 and the visible light transparent area 13 within the light-shielding area 3, the far-infrared camera and the visible light camera can be installed in close proximity to each other, which reduces the load when processing the data obtained from each camera and also makes it easier to route the power supply and signal cables. The visible light transmitting region 13 is a region within the light shielding region 3 where the light shielding layer 5 is not provided. Furthermore, the window member 1 of the present embodiment may further include, in addition to the visible light camera, a LiDAR or a millimeter wave radar, for example.

[0029] <Exterior parts for vehicles equipped with far-infrared cameras> Next, the exterior member for a vehicle equipped with a far-infrared camera of the present invention will be described. A schematic cross-sectional view of one embodiment of the exterior member for a vehicle with a far-infrared camera of the present invention is shown in Fig. 9. The exterior member for a vehicle with a far-infrared camera 100 according to this embodiment is a window member with a far-infrared camera, in which a far-infrared camera 9 is attached to a window member 1 applied to the windshield of a vehicle. It should be noted that the vehicle exterior member in this embodiment is not limited to a window member applied to a vehicle windshield, as described above.

[0030] The window member 100 with a far-infrared camera of this embodiment includes the window member 1 and the far-infrared camera 9. The window member 1 is as described above. The far-infrared camera 9 is attached to the window member 1 so as to be able to capture a thermal image of the outside through the far-infrared transmitting region of the window member 1. There is no particular limitation on the type of far-infrared camera 9, and any known far-infrared camera can be used. The far-infrared camera 9 is attached to the window member 1 by, for example, a bracket 14. The far-infrared camera 9 is usually attached so that the optical axis X is approximately horizontal.

[0031] In order to obtain a clear image (thermal image) by the far-infrared camera 9, it is preferable that the temperature of the far-infrared camera 9 be kept constant. One way to keep the temperature of the far-infrared camera 9 constant is to increase the thermal insulation inside the bracket 14. To increase the thermal insulation inside the bracket 14, the inside of the bracket 14 may be kept in a vacuum or filled with a thermal insulation material. That is, in the window member 100 with a far-infrared camera of this embodiment, the far-infrared camera 9 is attached to the window member 1 via the bracket 14, and it is preferable that the inside of the bracket 14 is kept in a vacuum or filled with a thermal insulation material. Also, as a means for keeping the temperature of the far-infrared camera 9 constant, the temperature inside the bracket 14 may be adjusted by a temperature regulator. That is, in the window member 100 with a far-infrared camera of this embodiment, the far-infrared camera 9 is attached to the window member via the bracket 14, and it is preferable that the window member 100 further includes a temperature regulator for adjusting the temperature inside the bracket 14.

[0032] Furthermore, when the window member 1 has a visible light transmitting region 13, it is preferable that the window member 100 with a far-infrared camera of this embodiment further includes a visible light camera attached to the window member 1 so as to be able to capture an image of the outside through the visible light transmitting region 13. By equipping the vehicle with a visible light camera in addition to the far-infrared camera, it becomes possible to recognize information outside the vehicle by combining the information obtained by these two cameras, as mentioned above. In this case, it is preferable that the optical axis of the far-infrared camera and the optical axis of the visible light camera are approximately parallel, and that the distance between these optical axes is 20 cm or less. Note that the concept of approximately parallel includes not only the case where these optical axes are completely parallel, but also the case where they are slightly deviated from parallel due to an error level. In this way, the optical axis of the far-infrared camera and the center of the field of view of the visible light camera are approximately aligned, which is preferable when combining images obtained from these cameras for information processing.

[0033] The visible light camera may be a stereo camera having a first camera and a second camera. In this case, it is preferable that the far-infrared camera is disposed between the first camera and the second camera. In this case, it is preferable that the optical axes of the far-infrared camera, the first camera, and the second camera are all approximately parallel, and the distance between the optical axes of all the cameras is 20 cm or less. Furthermore, in addition to the visible light camera, for example, LiDAR and millimeter wave radar may also be provided. In this case, it is preferable to arrange each sensor close to each other while suppressing signal interference. EXAMPLES

[0034] The present invention will be specifically described below with reference to examples, but the present invention is not limited thereto.

[0035] <Preparation of far-infrared transmitting material> Cylindrical far-infrared transmitting members (far-infrared transmitting members A to Q) of different sizes made of Si, Ge, ZnS, or chalcogenide glass were prepared. The material, diameter L, and thickness t of each far-infrared transmitting member are shown in Tables 1 to 3. The far-infrared transmitting member J was produced as follows. First, glass raw materials were mixed so that the atomic percentages were Ga 6.0%, Sb 24.0%, Sn 4.0%, S 62.0%, Cs 2.0%, and Cl 2.0%, and the mixture was sealed in a quartz glass tube with an inner diameter of 25 mm and heated to 750°C and melted for 4 hours. The melted glass was then quenched and slowly cooled to obtain an ingot, which was cut together with the quartz glass tube and polished to obtain the far-infrared transmitting member J. Furthermore, the far-infrared transmitting member O has a five-layer anti-reflection film made of Ge, Si, and YF3 on the exterior surface of the vehicle, the far-infrared transmitting member P has an anti-reflection film made of two layers of DLC and Si on the exterior surface of the vehicle and five layers of ZnS and Ge on the interior surface of the vehicle, and the far-infrared transmitting member Q has an anti-reflection film made of one layer of DLC on the exterior surface of the vehicle and two layers of ZnS and Ge on the interior surface of the vehicle, all of which are provided by a vapor deposition method.

[0036] <Measurement of average transmittance of far infrared rays with wavelengths of 8 to 13 μm> The infrared transmission spectrum of each far-infrared transmitting member was measured using a Fourier transform infrared spectrometer (manufactured by ThermoScientific, product name: Nicolet iS10), and the average transmittance at wavelengths of 8 to 13 μm was calculated from the obtained infrared transmission spectrum. The results are shown in Tables 1 and 2. In addition, FIG. 10 shows the infrared transmission spectra of far-infrared transmitting members B, D, F, H, I, and J.

[0037] <Manufacturing of window components> (Example 1) First, a laminated glass was prepared by disposing a PVB having a thickness of 0.76 mm between soda lime glass pieces having a size of 300 mm x 300 mm and a thickness of 2.0 mm. Next, a through hole having a diameter of 14 mm was formed at a point 100 mm away from the center of the laminated glass in the direction of one side. Next, using a urethane-based adhesive, the far-infrared transmitting member A was attached to the through hole so as to be flush with the outer surface, thereby obtaining a window member of Example 1. The urethane-based adhesive was cured by drying at room temperature for 5 days.

[0038] (Examples 2 and 3) Window members of Examples 2 and 3 were obtained in the same manner as in Example 1, except that the diameter of the through hole was 26.5 mm and that far-infrared transmitting members B and C were attached, respectively.

[0039] (Example 4) Except for using an acrylic adhesive, a window member of Example 4 was obtained in the same manner as in Example 3. The acrylic adhesive was dried at 120° C. for 1 hour and then dried at room temperature for 5 days to be cured.

[0040] (Examples 5 to 8) Window members of Examples 5 to 8 were obtained in the same manner as in Example 2 except that far-infrared transmitting members D to G were attached, respectively.

[0041] (Example 9) A window member of Example 9 was obtained in the same manner as in Example 8, except that an acrylic adhesive was used. The acrylic adhesive was dried at 120° C. for 1 hour and then dried at room temperature for 5 days to be cured.

[0042] (Examples 10 to 13) Window members of Examples 10 to 13 were obtained in the same manner as in Example 2 except that far-infrared transmitting members H to K were attached, respectively.

[0043] (Examples 14 and 15) Window members of Examples 14 and 15 were obtained in the same manner as in Example 1, except that the diameter of the through hole was 51.5 mm and that far-infrared transmitting members L and M were attached, respectively.

[0044] (Example 16) A window member of Example 16 was obtained in the same manner as in Example 1, except that the diameter of the through hole was 91.5 mm and the far-infrared transmitting member N was attached.

[0045] (Examples 17-19) Window members of Examples 17 to 19 were obtained in the same manner as in Example 1, except that the diameter of the through hole was 51.5 mm and that far-infrared transmitting members O, P and Q were attached, respectively.

[0046] <Dropped ball strength evaluation> Using the window members of Examples 1 to 19, the following ball drop strength evaluations 1 and 2 were carried out. Those that passed both tests were evaluated as "○", and those that failed either one of the tests were evaluated as "×". The evaluation results are shown in Tables 1 and 2. (Ball Drop Strength Evaluation 1) The evaluation was conducted using a ball drop device and support frame conforming to the impact resistance test in JIS R3211, 3212-2015. First, the window component was kept in a room with a temperature of 23°C and a relative humidity of 50% for 4 hours, and then fixed in a support frame so that the outer surface was facing upwards. Next, a 226g steel ball was dropped from a height of 10m onto the center of the window component. If the steel ball did not penetrate the window component and the total mass of the pieces peeling off from the opposite side of the impact surface was 15g or less, it was considered to have passed the test. (Fall Ball Strength Evaluation 2) The test was conducted in the same manner as in Drop Ball Strength Evaluation 1, except that a 509g steel ball was used. If the far-infrared transmitting material was not damaged or detached from the window material, and the total mass of the peeled off pieces on the opposite side of the impact surface was 15g or less, the test was deemed to have passed.

[0047] <Thermal image visual evaluation> The window members of Examples 1 to 19 were used to carry out the following thermal image visual evaluation. First, the window member was set so that the angle from the horizontal plane was α. Next, a far-infrared camera (Cube417 (resolution: 400 × 300, horizontal angle of view: 20°, vertical angle of view: 15°, focal length: 19 mm) manufactured by Wuhan Guide Infrared Co., Ltd.) was placed close enough that the housing touched the window member so that the optical axis was horizontal and at the center of the far-infrared transmitting member. Next, at an outside temperature of 26°C, a pedestrian placed 100 m away from the window was photographed with a far-infrared camera, as shown in Figure 11. From the obtained thermal image, 20 x 30 pixels were cut out with the pedestrian at the center, and the thermal image contrast of each was evaluated as "maximum brightness / minimum brightness" through image analysis. The higher the thermal image contrast value, the clearer the image was. If the thermal image contrast value is 3.0 or more, it is possible to fully recognize a pedestrian 100 m away. The window member of Example 1 was tested with α=30°, 60°, and 90°. The window members of Examples 2, 5, 7, 10, 12, 13 and 19 were tested at α=30° and 45°. The window members of Examples 3, 6, 8, 11, and 14-18 were tested at α=30°. In addition, Examples 4 and 9 differ from Examples 3 and 8 only in the type of adhesive, and the results of the thermal image visual evaluation were considered to be the same as those of these examples, so no testing was performed. Tables 1 and 2 show the values ​​of α, the diameter R of the largest circle formed inside the projection obtained by projecting the far-infrared transmitting member in the optical axis direction, and the thermal image contrast value. FIG. 12 shows thermal images of pedestrians cut out in Example 1 (α = 30° and 60°), Example 5 (α = 30°), Example 10 (α = 30° and 45°), Example 12 (α = 30°), Example 13 (α = 30°), and Example 15 (α = 30°).

[0048] [Table 1]

[0049] [Table 2]

[0050] [Table 3]

[0051] The results of the ball drop strength evaluation for each example are described below. Examples 2, 7, and 14, which used far-infrared transmitting members B, F, and L having a thickness t of 1 mm, were insufficient in strength. Moreover, Example 16, which used a far-infrared transmitting member N having a thickness t of 3 mm but a diameter L of 90 mm, also had insufficient strength. On the other hand, Examples 1, 3 to 6, 8 to 13, 15 and 17 to 19 using far-infrared transmitting members A, C to E, G to K, M, O to Q having a thickness t of 1.5 mm or more and a diameter L of 80 mm or less had sufficiently high strength.

[0052] The results of the thermal image visual evaluation for each example are described below. In the tests of Example 1 where α=30° and 60°, where R is 6.3 mm and 10.8 mm, respectively, sufficient thermal image contrast was not obtained, and the clarity of the thermal image was low, as shown in Figure 12. On the other hand, in the test of Example 1 where α=90°, where R is 12.5 mm, sufficient thermal image contrast was obtained. In the test of Example 6 in which the far-infrared transmitting member E, which has an average transmittance of far-infrared rays having wavelengths of 8 to 13 μm of 14%, was used, sufficient thermal image contrast was not obtained. In the tests of Examples 2, 3, 5, 7, 8, and 10 to 19 in which R was 12 mm or more and the average transmittance of the far-infrared transmitting member with far-infrared rays having wavelengths of 8 to 13 μm was 25% or more, sufficient thermal image contrast was obtained in all cases.

[0053] As is clear from the above results, a far-infrared transmitting member having a thickness t of 1.5 mm or more, a diameter L of 80 mm or less, an average transmittance of far-infrared rays with wavelengths of 8 to 13 μm of 25% or more, and a diameter R of the largest circle formed inside the projection obtained by projecting the far-infrared transmitting member in the optical axis direction of 12 mm or more, had both high strength and sufficient thermal image contrast. This international application claims priority based on Japanese Patent Application No. 2019-136326, filed on July 24, 2019, the entire contents of which are incorporated herein by reference. [Explanation of symbols]

[0054] 1 Vehicle exterior member (window member); 2 Glass substrate; 2a First glass; 2b Second glass; 3 Light-shielding region; 4 Light-transmitting region; 5 Light-shielding layer; 6 Far-infrared-transmitting region; 7 Opening; 7a Opening of first glass; 7b Opening of second glass; 8 Far-infrared-transmitting member; 9 Far-infrared camera; 10 Projection surface; 11 Projection drawing; 12 Largest circle among circles formed inside the projection drawing; 13 Visible light-transmitting region; 14 Bracket; 15 Intermediate layer; 100 Window member with far-infrared camera; X Optical axis

Claims

1. An exterior member for a vehicle having a light-shielding area, which is attached to a vehicle having a far-infrared camera, The vehicle exterior member is a vehicle window member that is attached to a vehicle so that its inclination with respect to a horizontal direction is 60° or less, The light-shielding region further includes an opening and a far-infrared-transmitting region having a far-infrared-transmitting member disposed in the opening, The far-infrared transparent member has an average transmittance of far-infrared rays having a wavelength of 8 to 13 μm of 25% or more, and the longest straight line among straight lines connecting any two points on the vehicle exterior surface of the far-infrared transparent member has a length of 80 mm or less, Among circles formed inside a projection obtained by projecting the far-infrared transparent member in the optical axis direction of the far-infrared camera, the diameter of the largest circle is 12 mm or more, and the average thickness of the far-infrared transparent member is 1.5 mm or more, At least one of the vehicle exterior surface and the vehicle interior surface of the far-infrared transmitting member is provided with an anti-reflection film having 1 to 12 layers.

2. 2. The exterior member for a vehicle according to claim 1, wherein the far-infrared transmitting member is made of at least one material selected from the group consisting of ZnS, Ge, Si, and chalcogenide glass.

3. 3. The exterior member for a vehicle according to claim 1, wherein the layer of the anti-reflection film closest to the outer surface of the vehicle is a diamond-like carbon film.

4. 3. The exterior member for a vehicle according to claim 1, wherein an exterior surface of the far-infrared transmitting member is flush with an exterior surface of the light blocking region.

5. 3. The exterior member for a vehicle according to claim 1, wherein the far-infrared transmitting member is attached with a urethane adhesive and / or an acrylic adhesive.

6. The vehicle exterior member according to claim 1 or 2, further comprising a visible light transmitting region within the light blocking region, the visible light transmitting region having a visible light transmittance of 70% or more.

7. A vehicle exterior member according to claim 1 or 2, and a far-infrared camera, The far-infrared camera is attached to the exterior member for a vehicle so as to be able to capture a thermal image of the outside through the far-infrared transmitting region.

8. 7. A vehicle exterior member with a far-infrared camera, comprising: the vehicle exterior member according to claim 6; a far-infrared camera; and a visible light camera, wherein the far-infrared camera is attached to the vehicle exterior member so as to be able to capture an external thermal image through the far-infrared transparent member, and the visible light camera is attached to the vehicle exterior member so as to be able to capture an external image through the visible light transparent region.

9. 9. The exterior member for a vehicle with a far-infrared camera according to claim 8, wherein an optical axis of the far-infrared camera and an optical axis of the visible light camera are approximately parallel to each other, and a distance between these optical axes is 20 cm or less.

10. 9. The exterior member for a vehicle with a far-infrared camera according to claim 8, wherein the visible light camera is a stereo camera having a first camera and a second camera, and the far-infrared camera is positioned between the first camera and the second camera.

11. The vehicle exterior member with a far-infrared camera according to claim 7, wherein the far-infrared camera is attached to the vehicle exterior member via a bracket, and an inside of the bracket is kept in vacuum or filled with a heat insulating material.

12. The vehicle exterior member with a far-infrared camera according to claim 7, further comprising a temperature regulator for regulating a temperature inside the bracket, the far-infrared camera being attached to the vehicle exterior member via a bracket.

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