Detergent composition

Abstract

To provide a detergent composition with superior foam quality.SOLUTION: A detergent composition comprises (A) hydrophobically modified polyether urethane, (B) an anionic surfactant, and (C) an amphoteric surfactant.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a cleansing composition having excellent foam quality, such as foaming, foam persistence, foam elasticity, and foam smoothness. [Background technology]

[0002] Cleansing agents such as skin or hair cleansers usually contain various thickening components and surfactants in order to improve the viscosity, foaming properties, etc., during use. However, it is known that some combinations of thickening components and surfactants can cause problems such as inhibition of the effect of improving viscosity or foaming properties, or reduced stability.

[0003] To solve such problems, Patent Document 1 discloses a cleanser composition containing a specific hydrophobically modified polyether urethane and an anionic surfactant and / or an amphoteric surfactant. Patent Document 2 discloses a cleanser composition containing a specific aqueous gelling agent and an anionic surfactant, and Patent Document 3 discloses an aqueous cosmetic preparation characterized by containing specific amounts of anionic surfactant, amphoteric surfactant, and water-soluble polymer. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2002-105493 A [Patent Document 2] International Publication No. 2019 / 049723 [Patent Document 3] JP 2018-070490 A Summary of the Invention [Problem to be solved by the invention]

[0005] However, even with these techniques, it is still sometimes difficult to simultaneously improve various properties, and there has been a particular demand for the development of a detergent composition that is excellent in foam quality, such as foaming and foam persistence, etc. Therefore, an object of the present invention is to provide a detergent composition that is excellent in foam quality. [Means for solving the problem]

[0006] The present inventors conducted extensive research and found that a cleaning composition containing specific components can solve the above problems. That is, the present invention is a cleaning composition containing (A) a hydrophobically modified polyether urethane, (B) an anionic surfactant, and (C) an amphoteric surfactant. Effect of the Invention

[0007] The present invention can provide a detergent composition that is excellent in foam quality, such as foaming, foam durability, foam elasticity, and foam smoothness. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0008] The hydrophobically modified polyether urethane (A) used in the present invention is a thickening agent such as a urethane copolymer having a hydrophilic group as a skeleton and a hydrophobic portion at the end. It is believed that such hydrophobically modified polyether urethane exhibits a thickening effect by the hydrophobic portions of the copolymer associating with each other in an aqueous medium and the hydrophilic portions forming a loop-like or bridge-like structure. The hydrophobically modified polyether urethane used in the present invention is not limited to any known hydrophobically modified polyether urethane, and can be, for example, a hydrophobically modified polyether urethane obtained by reacting a polyoxyalkylene having 2 to 4 carbon atoms with a polyisocyanate having two or more isocyanate groups in the molecule, and, if necessary, a polyoxyalkylene alkyl ether, an alkyl glyceryl ether, or the like. In the present invention, commercially available hydrophobically modified polyether urethane can also be used, and for example, Adekanol GT-700, Adekanol GT-730, Adekanol GT-930 (all manufactured by ADEKA Corporation), etc. can also be used.

[0009] In the present invention, from the viewpoint of obtaining a cleaning composition having better foam quality, it is preferable that (A) hydrophobically modified polyether urethane contains a hydrophobically modified polyether urethane represented by the following general formula (I).

[0010] [ka]

[0011] (In the formula, R 1 , R 2 , R 8 and R 9 each independently represents a hydrocarbon group having 1 to 20 carbon atoms; R 3 , R 5 and R 7 each independently represents a divalent hydrocarbon group having 2 to 4 carbon atoms; R 4 and R 6 each independently represents a divalent hydrocarbon group having 3 to 16 carbon atoms, a and c each independently represent a number from 10 to 100, b represents a number from 100 to 500, and d represents a number from 0 to 10.

[0012] In the general formula (I), R 1 , R 2 , R 8 and R 9each independently represents a hydrocarbon group having 1 to 20 carbon atoms. Examples of the hydrocarbon group having 1 to 20 carbon atoms include a methyl group, an ethyl group, a linear propyl group, a secondary propyl group, a linear butyl group, a branched butyl group, a secondary butyl group, a tertiary butyl group, a linear pentyl group, a branched pentyl group, a secondary pentyl group, a tertiary pentyl group, a linear hexyl group, a branched hexyl group, a secondary hexyl group, a tertiary hexyl group, a linear heptyl group, a branched heptyl group, and a secondary heptyl group. , tertiary heptyl, linear octyl, 2-ethylhexyl, branched octyl, secondary octyl, tertiary octyl, linear nonyl, branched nonyl, secondary nonyl, tertiary nonyl, linear decyl, branched decyl, secondary decyl, tertiary decyl, linear undecyl, branched undecyl, secondary undecyl, tertiary undecyl, linear dodecyl, branched dodecyl, secondary dodecyl decyl, tertiary dodecyl, linear tridecyl, branched tridecyl, secondary tridecyl, tertiary tridecyl, linear tetradecyl, branched tetradecyl, secondary tetradecyl, tertiary tetradecyl, linear pentadecyl, branched pentadecyl, secondary pentadecyl, tertiary pentadecyl, linear hexadecyl, branched hexadecyl, secondary hexadecyl, tertiary hexadecyl saturated aliphatic hydrocarbon groups such as decyl group, linear heptadecyl group, branched heptadecyl group, secondary heptadecyl group, tertiary heptadecyl group, linear octadecyl group, branched octadecyl group, secondary octadecyl group, tertiary octadecyl group, linear nonadecyl group, branched nonadecyl group, secondary nonadecyl group, tertiary nonadecyl group, linear icosyl group, branched icosyl group, secondary icosyl group, and tertiary icosyl group;1-butenyl group, 2-butenyl group, 3-butenyl group, 1-methyl-2-propenyl group, 2-methyl-2-propenyl group, 1-pentenyl group, 2-pentenyl group, 3-pentenyl group, 4-pentenyl group, 1-methyl-2-butenyl group, 2-methyl-2-butenyl group, 1-hexenyl group, 2-hexenyl group, 3-hexenyl group, 4-hexenyl group, 5-hexenyl group, 1-heptenyl group, 6-heptenyl group, 1-octenyl group, 7-octenyl group, 8-nonenyl group, 1-decenyl group, 9-decenyl group, 10-undecenyl group unsaturated aliphatic hydrocarbon groups such as 1-dodecenyl, 4-dodecenyl, 11-dodecenyl, 12-tridecenyl, 13-tetradecenyl, 14-pentadecenyl, 15-hexadecenyl, 16-heptadecenyl, 1-octadecenyl, 17-octadecenyl, 1-nonadecenyl, and 1-icosenyl groups; phenyl, toluyl, xylyl, cumenyl, mesityl, benzyl, phenethyl, styryl, cinnamyl, benzhydryl, trityl, ethylphenyl, propylphenyl, butyl ... aromatic hydrocarbon groups such as a cyclopropylphenyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, a methylcyclopentyl group, a methylcyclohex ... alicyclic hydrocarbon groups such as ethylcycloheptyl group, methylcyclooctyl group, 4,4,6,6-tetramethylcyclohexyl group, 1,3-dibutylcyclohexyl group, norbornyl group, bicyclo[2.2.2]octyl group, adamantyl group, 1-cyclobutenyl group, 1-cyclopentenyl group, 3-cyclopentenyl group, 1-cyclohexenyl group, 3-cyclohexenyl group, 3-cycloheptenyl group, 4-cyclooctenyl group, 2-methyl-3-cyclohexenyl group, and 3,4-dimethyl-3-cyclohexenyl group;

[0013] Among these, R is the preferred embodiment because it can produce hydrophobically modified polyether urethane that is likely to achieve the effects of the present invention, and the raw materials can be easily procured and produced. 1 , R 2 , R 8 and R 9 are each independently preferably a saturated aliphatic hydrocarbon group having 1 to 20 carbon atoms or an unsaturated aliphatic hydrocarbon group having 1 to 20 carbon atoms, more preferably a saturated aliphatic hydrocarbon group having 5 to 18 carbon atoms, and even more preferably a saturated aliphatic hydrocarbon group having 10 to 12 carbon atoms. 1 and R 8 is a linear decyl group, and R 2 and R 9 It is particularly preferred that is a linear dodecyl group.

[0014] In the general formula (I), R 3 , R 5 and R 7 each independently represents a divalent hydrocarbon group having 2 to 4 carbon atoms. Examples of the divalent hydrocarbon group having 2 to 4 carbon atoms include an ethylene group, a linear propylene group, a branched propylene group, a linear butylene group, and a branched butylene group. Among these, R 3 , R 5 and R 7 are each independently preferably a divalent linear hydrocarbon group having 2 to 4 carbon atoms, more preferably an ethylene group or a linear propylene group, and even more preferably an ethylene group.

[0015] In the general formula (I), R 4 and R 6each independently represents a divalent hydrocarbon group having 3 to 16 carbon atoms. Examples of the divalent hydrocarbon group having 3 to 16 carbon atoms include a divalent aliphatic hydrocarbon group having 3 to 16 carbon atoms, a divalent aromatic hydrocarbon group having 6 to 16 carbon atoms, and a divalent alicyclic hydrocarbon group having 3 to 16 carbon atoms. Among these, a group in which two isocyanate groups have been removed from a diisocyanate compound is preferred, since it provides a hydrophobically modified polyether urethane that is likely to achieve the effects of the present invention, and is easy to procure and produce from raw materials. Examples of the diisocyanate compound in this case include trimethylene diisocyanate, tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, 2,2-dimethylpentane diisocyanate, octamethylene diisocyanate, 2,2,4-trimethylpentane diisocyanate, nonamethylene diisocyanate, decamethylene diisocyanate, dodecamethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane diisocyanate, hydrogenated xylylene diisocyanate, 2,4,4-trimethylhexamethylene diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, tolylene diisocyanate, diphenylmethane diisocyanate, toluidine diisocyanate, xylylene diisocyanate, and naphthalene diisocyanate. Among these, R 4 and R 6 is particularly preferably a group obtained by removing two isocyanate groups from hexamethylene diisocyanate, that is, a hexylene group.

[0016] In general formula (I), a and c each independently represent a number from 10 to 100. Since a hydrophobically modified polyether urethane that easily achieves the effects of the present invention can be obtained, a and c each are preferably 12 to 50, more preferably 15 to 30, and even more preferably 20. Furthermore, the values ​​of a and c may each be an average value.

[0017] In general formula (I), b represents a number from 100 to 500. Since a hydrophobically modified polyether urethane that easily achieves the effects of the present invention can be obtained, b is preferably from 120 to 450, more preferably from 150 to 400, even more preferably from 200 to 300, and particularly preferably 240. The value of b may be an average value.

[0018] In general formula (I), d represents a number from 0 to 10. Since a hydrophobically modified polyether urethane that can easily achieve the effects of the present invention can be obtained, d is preferably from 0 to 8, and more preferably from 0 to 6. The value of d may be an average value.

[0019] In the present invention, from the viewpoint of easily obtaining a cleaning composition having excellent foam quality, it is particularly preferable to use a hydrophobically modified polyether urethane containing at least a (PEG-240 / decyltetradeceth-20 / HDI) copolymer or polyurethane-59 as the hydrophobically modified polyether urethane (A).

[0020] The content of (A) hydrophobically modified polyether urethane in the cleaning composition of the present invention is not particularly limited, but from the viewpoint of obtaining a cleaning composition having better foam quality, the content of (A) hydrophobically modified polyether urethane is preferably 0.001 to 20 mass%, more preferably 0.01 to 10 mass%, even more preferably 0.05 to 5 mass%, and particularly preferably 0.1 to 3 mass%, relative to the total amount of the cleaning composition.

[0021] The anionic surfactant (B) used in the present invention is not particularly limited as long as it is a known anionic surfactant, and examples thereof include soap, metal soap, higher fatty acid salt, higher alcohol sulfate ester salt, sulfurized olefin salt, higher alkyl sulfonate salt, α-olefin sulfonate salt, sulfated fatty acid salt, sulfonated fatty acid salt, phosphate ester salt, sulfate ester salt of fatty acid ester, glyceride sulfate ester salt, sulfonate salt of fatty acid ester, α-sulfofatty acid methyl ester salt, polyoxyalkylene alkyl ether sulfate ester salt, polyoxyalkylene alkyl phenyl ether sulfate ester salt, poly Examples of the anionic surfactant include oxyalkylene alkyl ether carboxylate, acylated peptide, sulfate ester salt of fatty acid alkanolamide or its alkylene oxide adduct, sulfosuccinate, alkylbenzene sulfonate, alkylnaphthalene sulfonate, alkylbenzimidazole sulfonate, polyoxyalkylene sulfosuccinate, acyloxyethanesulfonate, alkoxyethanesulfonate, acyl lactate, N-acyl sarcosine salt, alkyl or alkenyl amino carboxymethyl sulfate, amino acid-based anionic surfactant, etc., and one or more of these can be used. Among these, in the present invention, from the viewpoint of obtaining a detergent composition with better foam quality, it is preferable to use one or more anionic surfactants selected from the group consisting of sulfonic acid surfactants, sulfate ester surfactants, and amino acid-based anionic surfactants as the anionic surfactant (B).

[0022] The sulfonic acid surfactant can be any known sulfonic acid surfactant without any particular limitation. Examples of the sulfonic acid surfactant include higher alkyl sulfonates, α-olefin sulfonates, sulfonates of fatty acid esters, alkylbenzene sulfonates, alkylnaphthalene sulfonates, alkylbenzimidazole sulfonates, acyloxyethane sulfonates, and alkoxyethane sulfonates. More specific examples of the sulfonic acid surfactant include sodium dodecylbenzene sulfonate, sodium tridecylbenzene sulfonate, sodium tetradecylbenzene sulfonate, triethanolamine dodecylbenzene sulfonate, triethanolamine tridecylbenzene sulfonate, triethanolamine tetradecylbenzene sulfonate, and sodium olefin (C14-16) sulfonate. One or more of these can be used.

[0023] The sulfate surfactant may be any known sulfate surfactant without any particular limitation. Examples of the sulfate surfactant include higher alcohol sulfate salts, sulfate salts of fatty acids, alkyl ether sulfate salts, alkyl phenyl ether sulfate salts, glyceride sulfate salts, polyoxyalkylene alkyl ether sulfate salts, polyoxyalkylene alkyl phenyl ether sulfate salts, and sulfate salts of fatty acid alkanolamides or alkylene oxide adducts thereof. More specific examples include sodium lauryl sulfate, potassium lauryl sulfate, ammonium lauryl sulfate, triethylamine lauryl sulfate, monoethanolamine lauryl sulfate, diethanolamine lauryl sulfate, triethanolamine lauryl sulfate, sodium laureth sulfate, potassium laureth sulfate, ammonium laureth sulfate, triethylamine laureth sulfate, monoethanolamine laureth sulfate, diethanolamine laureth sulfate, and triethanolamine laureth sulfate. One or more of these may be used.

[0024] The amino acid anionic surfactant can be any known amino acid anionic surfactant without any particular limitation, and examples thereof include triethanolamine cocoyl glutamate, ammonium palm kernel oil fatty acid glutamate, sodium cocoyl glutamate, sodium lauroyl glutamate, triethanolamine lauroyl glutamate, triethanolamine cocoyl aspartate, sodium cocoyl aspartate, ammonium palm kernel oil fatty acid aspartate, sodium lauroyl aspartate, triethanolamine lauroyl aspartate, potassium cocoyl threonine, sodium cocoyl threonine, triethanolamine cocoyl threonine, ammonium palm kernel oil fatty acid threonine, and lauroyl threonine. Examples of the fatty acid ammonium sarcosine include sodium lauroyl threonine triethanolamine, potassium cocoyl sarcosine, sodium cocoyl sarcosine, triethanolamine cocoyl sarcosine, palm kernel oil fatty acid ammonium sarcosine, sodium lauroyl sarcosine, triethanolamine lauroyl sarcosine, potassium cocoyl methyl alanine, sodium cocoyl methyl alanine, potassium cocoyl methyl taurate, sodium cocoyl methyl taurate, triethanolamine cocoyl methyl alanine, palm kernel oil fatty acid ammonium methyl alanine, sodium lauroyl methyl alanine, sodium lauroyl hydroxyethyl-β-alanine, triethanolamine lauroyl methyl alanine, and the like. One or more of these may be used.

[0025] The content of the anionic surfactant (B) in the cleaning composition of the present invention is not particularly limited. From the viewpoint of obtaining a cleaning composition having more excellent foam quality, the content of the anionic surfactant (B) is preferably from 0.001 to 70 mass%, more preferably from 0.1 to 60 mass%, further more preferably from 1 to 50 mass%, and particularly preferably from 2 to 40 mass%, based on the total amount of the cleaning composition.

[0026] The amphoteric surfactant (C) used in the present invention is not particularly limited as long as it is a known amphoteric surfactant, and for example, a betaine surfactant, a sulfobetaine surfactant, a hydroxysultaine surfactant, an imidazoline surfactant, and the like can be used. More specifically, lauryl betaine, lauric acid amidopropyl betaine, lauryl dimethylaminoacetate betaine, myristyl dimethylaminoacetate betaine, cocoyl dimethylaminoacetate betaine, cocamidopropyl betaine, palm kernel oil fatty acid amidopropyl betaine, lauramidopropyl betaine, sodium cocoamphoacetate, 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, and the like can be used alone or in combination.

[0027] The content of the amphoteric surfactant (C) in the cleaning composition of the present invention is not particularly limited. From the viewpoint of obtaining a cleaning composition having better foam quality, the content of the amphoteric surfactant (C) is preferably from 0.001 to 30 mass%, more preferably from 0.01 to 20 mass%, even more preferably from 0.1 to 15 mass%, and particularly preferably from 1 to 10 mass%, relative to the total amount of the cleaning composition.

[0028] The ratio of the contents of the hydrophobically modified polyether urethane (A) and the anionic surfactant (B) in the cleaning composition of the present invention is not particularly limited. From the viewpoint of obtaining a cleaning composition having better foam quality, the content of the anionic surfactant (B) is preferably 0.1 to 1,500, more preferably 0.5 to 750, and even more preferably 1 to 400, relative to the content of the hydrophobically modified polyether urethane (A) in the cleaning composition.

[0029] The content ratio of the (A) hydrophobically modified polyether urethane to the (C) amphoteric surfactant in the cleaning composition of the present invention is not particularly limited. From the viewpoint of obtaining a cleaning composition having better foam quality, the content of the (C) amphoteric surfactant is preferably 0.1 to 500, more preferably 0.5 to 200, and even more preferably 1 to 100, relative to the content of the (A) hydrophobically modified polyether urethane in the cleaning composition.

[0030] The content ratio of the anionic surfactant (B) to the amphoteric surfactant (C) in the cleaning composition of the present invention is not particularly limited. From the viewpoint of obtaining a cleaning composition having better foam quality, the content of the amphoteric surfactant (C) in the cleaning composition is preferably 0.001 to 20, more preferably 0.025 to 10, and even more preferably 0.05 to 5, relative to the content of the anionic surfactant (B) in the cleaning composition.

[0031] The cleaning composition of the present invention may further contain (D) a nonionic surfactant. The nonionic surfactant that can be used in the present invention is not particularly limited as long as it is a known nonionic surfactant, and examples thereof include fatty acid alkanolamides, sorbitan fatty acid esters, sucrose fatty acid esters, alkyl glucosides, alkyl maltosides, glycerin fatty acid / polyglycerin fatty acid, propylene glycol fatty acid esters, hydrogenated castor oil derivatives, POE-sorbitan fatty acid esters, POP-sorbitan fatty acid esters, POE sorbitol fatty acid esters, POP sorbitol fatty acid esters, POE-glycerin fatty acid esters, POP-glycerin fatty acid es, and the like. Examples of suitable surfactants include POE-alkyl ethers, POE-fatty acid esters, POP-fatty acid esters, POE-alkyl ethers, POE·POP-alkyl ethers, tetraPOE·tetraPOP-ethylenediamine condensates, POE-hydrogenated castor oil derivatives, POE-beeswax·lanolin derivatives, POE-propylene glycol fatty acid esters, POP-propylene glycol fatty acid esters, POE-alkylamines, POP-alkylamines, POE-fatty acid alkanolamides, POP-fatty acid alkanolamides, and alkylethoxydimethylamine oxides, and one or more of these can be used. Among these, in the present invention, from the viewpoint of obtaining a cleaning composition having better foam quality, it is preferable that the nonionic surfactant (D) contains one or more nonionic surfactants selected from the group consisting of fatty acid alkanolamides, POE-fatty acid amides, and POP-fatty acid alkanolamides.

[0032] The fatty acid alkanolamide can be any known fatty acid alkanolamide without any particular limitation. For example, lauric acid monoethanolamide, lauric acid diethanolamide, lauric acid monoisopropanolamide, oleic acid monoethanolamide, oleic acid diethanolamide, oleic acid monoisopropanolamide, stearic acid monoethanolamide, stearic acid diethanolamide, stearic acid monoisopropanolamide, lauric acid myristic acid diethanolamide, cocamide methyl monoethanolamide (cocamide methyl MEA), cocamide diethanolamide (cocamide DEA), palm kernel oil fatty acid monoethanolamide, palm kernel oil fatty acid diethanolamide, etc. can be mentioned, and one or more of these can be used.

[0033] Furthermore, the POE-fatty acid alkanolamides and POP-fatty acid alkanolamides that can be used are not particularly limited as long as they are known POE-fatty acid amides and POP-fatty acid alkanolamides, respectively. Examples of such POE-fatty acid amides and POP-fatty acid alkanolamides include the POE adducts and POP adducts of the above-mentioned fatty acid alkanolamides, and one or more of these can be used.

[0034] When the cleaning composition of the present invention contains a nonionic surfactant (D), the content of the nonionic surfactant (D) is not particularly limited. From the viewpoint of obtaining a cleaning composition having more excellent foam quality, the content of the nonionic surfactant (D) is preferably from 0.001 to 30 mass%, more preferably from 0.01 to 20 mass%, even more preferably from 0.1 to 15 mass%, and particularly preferably from 1 to 10 mass%, relative to the total amount of the cleaning composition.

[0035] When the cleaning composition of the present invention contains a nonionic surfactant (D), the content ratio of the hydrophobically modified polyether urethane (A) to the nonionic surfactant (D) in the cleaning composition of the present invention is not particularly limited. From the viewpoint of obtaining a cleaning composition having better foam quality, the content of the nonionic surfactant (D) in the cleaning composition is preferably 0.1 to 500, more preferably 0.5 to 300, and even more preferably 1 to 100, relative to the content of the hydrophobically modified polyether urethane (A) in the cleaning composition.

[0036] When the cleaning composition of the present invention contains a nonionic surfactant (D), the content ratio of the anionic surfactant (B) to the nonionic surfactant (D) in the cleaning composition of the present invention is not particularly limited. From the viewpoint of obtaining a cleaning composition having better foam quality, the content of the nonionic surfactant (D) in the cleaning composition is preferably 0.001 to 20, more preferably 0.025 to 10, and even more preferably 0.05 to 5, relative to the content of the anionic surfactant (B) taken as 1.

[0037] When the cleaning composition of the present invention contains a nonionic surfactant (D), the content ratio of the amphoteric surfactant (C) to the nonionic surfactant (D) in the cleaning composition of the present invention is not particularly limited. From the viewpoint of obtaining a cleaning composition having better foam quality, the content of the nonionic surfactant (D) in the cleaning composition is preferably 0.01 to 20, more preferably 0.05 to 15, and even more preferably 0.1 to 10, relative to the content of the amphoteric surfactant (C) taken as 1.

[0038] The cleaning composition of the present invention may further contain water. When the cleaning composition of the present invention contains water, the content of water in the cleaning composition of the present invention is not particularly limited and can be appropriately adjusted depending on the purpose, but from the viewpoint of obtaining a cleaning composition with better foam quality, the content of water is preferably 1 to 99 mass%, more preferably 5 to 98 mass%, even more preferably 10 to 95 mass%, and particularly preferably 20 to 90 mass% based on the total amount of the cleaning composition.

[0039] The cleansing composition of the present invention may contain other components, such as cationic surfactants, chelating agents, low molecular weight polyols, oily components, zinc compounds, thickeners other than hydrophobically modified polyether urethanes, powders, antibacterial preservatives, moisturizing agents, antioxidants, ultraviolet absorbers, sequestering agents, monosaccharides, oligosaccharides, polysaccharides, amino acids and derivatives thereof, organic amines, vitamins, cosmetic components, fragrances, pH adjusters, and other possible components, in order to improve or modify various properties (solubility, dispersibility, stability, usability, application, penetration, moisturizing properties, safety, design properties, optical properties, fragrance, whitening properties, etc.) during storage, during use, and after use depending on the purpose of use, within a range that does not impair the object of the present invention.

[0040] As the cationic surfactant, a known cationic surfactant generally used in a cleaning agent can be used, for example, alkyl(alkenyl)trimethylammonium salt, dialkyl(alkenyl)dimethylammonium salt, alkyl(alkenyl)quaternary ammonium salt, mono- or dialkyl(alkenyl)quaternary ammonium salt containing an ether group, an ester group, or an amide group, alkyl(alkenyl)pyridinium salt, alkyl(alkenyl)dimethylbenzylammonium salt, alkyl(alkenyl)isoquinolinium salt, dialkyl(alkenyl)morphonium salt, polyoxyethylene alkyl(alkenyl)amine, alkyl(alkenyl)amine salt, polyamine fatty acid derivative, amyl alcohol fatty acid derivative, benzalkonium chloride, benzethonium chloride, etc., and one or more of these can be used. When the cleaning agent composition of the present invention contains a cationic surfactant, the content of the cationic surfactant in the cleaning agent composition of the present invention is not particularly limited and can be adjusted according to the purpose, but for example, the cationic surfactant can be contained in an amount of 0.01% by mass to 20% by mass based on the total amount of the cleaning agent composition.

[0041] The chelating agent may be a known chelating agent generally used in cleaning agents, such as aminopolycarboxylic acid chelating agents, aromatic or aliphatic carboxylic acid chelating agents, amino acid chelating agents, etherpolycarboxylic acid chelating agents, phosphonic acid chelating agents, phosphoric acid chelating agents, hydroxycarboxylic acid chelating agents, polymer electrolyte (including oligomeric electrolyte) chelating agents, dimethylglyoxime, ascorbic acid, thioglycolic acid, phytic acid, glyoxylic acid, glyoxalic acid, etc., and one or more of these may be used. In addition, these chelating agents may be in the form of a free acid or a salt such as a sodium salt, potassium salt, or ammonium salt. Furthermore, they may be in the form of a hydrolyzable ester derivative thereof. When the cleaning agent composition of the present invention contains a chelating agent, the content of the chelating agent in the cleaning agent composition of the present invention is not particularly limited and can be adjusted according to the purpose, but for example, the chelating agent may be contained in an amount of 0.01% by mass to 10% by mass based on the total amount of the cleaning agent composition.

[0042] The low molecular weight polyol may be a known low molecular weight polyol generally used in cleaning agents, such as saturated diols or condensates thereof, unsaturated diols, alicyclic diols, trihydric alcohols, tetrahydric alcohols, pentahydric alcohols, hexahydric alcohols, glycerin monoethers, N-substituted diethanolamines, N-substituted diisopropanolamines, N-disubstituted-3-amino-1,2-propanediols, etc., and one or more of these may be used. When the cleaning agent composition of the present invention contains a low molecular weight polyol, the content of the low molecular weight polyol in the cleaning agent composition of the present invention is not particularly limited and can be adjusted according to the purpose, but for example, the low molecular weight polyol may be contained in an amount of 0.01% by mass to 20% by mass based on the total amount of the cleaning agent composition.

[0043] As the oily component, known oily components generally used in cleaning agents can be used, for example, fats and oils, wax, hydrocarbon oils, ester oils, silicone oils, fluorine-based oils, higher fatty acids, higher alcohols, etc. can be mentioned, and one or more of these can be used. As the fats and oils, for example, avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, perilla oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, Chinese ginger oil, Japanese tung oil, jojoba oil, germ oil, triglycerin, cacao butter, coconut oil, hardened coconut oil, palm oil, palm kernel oil, Japanese laurel kernel oil, hardened oil, Japanese laurel ... Examples of effective active ingredients include wax, hydrogenated castor oil, rosemary oil, chamomile oil, eucalyptus oil, rice germ oil, wheat germ oil, γ-oryzanol, plant ceramide (glycosylceramide), carrot oil, coix seed extract, horsetail extract, arnica extract, chamomilla extract, lithospermum root extract, linden extract, yarrow extract, sedge extract, angelica extract, horse chestnut extract, peach leaf extract, rosemary extract, pearl barley extract, loquat extract, borage oil, and evening primrose oil.

[0044] Examples of waxes include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ivory wax, whale wax, montan wax, bran wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugarcane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, lanolin fatty acid polyethylene glycol, and POE hydrogenated lanolin alcohol ether.

[0045] Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, and microcrystalline wax.

[0046] Examples of ester oils include synthetic esters and esters of higher alcohols and higher fatty acids. More specific examples include diisobutyl adipate, isostearyl isostearate, cetyl 2-ethylhexanoate, isopropyl myristate, glyceryl trioctanoate, distearyl triisostearate, and glyceryl caprate.

[0047] As the silicone oil, any of liquid, gel, and swellable silicone compounds can be used. Examples of the silicone oil include linear polysiloxane, cyclic polysiloxane, amino-modified polysiloxane, alkyl-modified polysiloxane, polyether-modified silicone, dimethicone crosspolymer, and the like. More specific examples of the silicone oil include dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane, methylhydrogenpolysiloxane, cyclopentasiloxane, hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetramethyltetrahydrogencyclotetrasiloxane, phenyltrimethicone, diphenyldimethicone, phenyldimethicone, caprylyl methicone, lauryldimethicone / vinyldimethicone crosspolymer, dimethicone / vinyldimethicone crosspolymer, dimethicone / phenylvinyldimethicone crosspolymer, and the like.

[0048] Examples of fluorine-based oils include perfluorodecane, perfluorooctane, and perfluoropolyether.

[0049] Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, tall oil fatty acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), and docosahexaenoic acid (DHA).

[0050] Examples of higher alcohols include monohydric alcohols having a hydrocarbon group (straight-chain or branched, saturated or unsaturated) with 8 to 30 carbon atoms. More specific examples include caprylyl alcohol, capryl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, hexyldecanol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, octyldodecanol, chimyl alcohol, decyltetradecanol, hexyldecanol, arachyl alcohol, behenyl alcohol, carnaubyl alcohol, and ceryl alcohol.

[0051] When the detergent composition of the present invention contains an oily component, the content of the oily component in the detergent composition of the present invention is not particularly limited and can be adjusted depending on the purpose. For example, the detergent composition may contain 0.01% by mass to 50% by mass of the oily component relative to the total amount of the detergent composition.

[0052] The zinc compound may be any known zinc compound generally used in detergents, and examples of such zinc compounds include organic acid zinc salts such as zinc acetate, zinc laurate, zinc myristate, zinc palmitate, zinc ricinoleate, zinc undecylenate, zinc aspartate, zinc acetylmethionine, zinc gluconate, zinc citrate, zinc polypyrrolidonecarboxylate, and zinc picolinate; zinc sulfonates such as zinc p-phenolsulfonate; zinc phosphates such as zinc ascorbyl phosphate, zinc sodium cetyl phosphate, and zinc DNA; and zinc complexes such as zinc pyrithione. Examples of zinc-supported zeolites include (silver / zinc / ammonium) zeolite and silicic acid (ammonium / silver / zinc / aluminum), aluminum hydroxides such as aluminum oxide / zinc, aluminum oxide / zinc / cerium, and aluminum oxide / zinc / iron, inorganic zinc salts such as zinc sulfate, zinc sulfide, zinc chloride, zinc bromide, zinc nitrate, zinc ammonium chloride, zinc aluminum sulfate, zinc potassium sulfate, zinc iodide, and basic zinc carbonate, (hydroxide / carbonate) (Mg / Al / zinc), and zinc oxide, and one or more of these can be used. Among these, compounds that are easily dissolved in water to become zinc ions are preferred, and the solubility in 100 g of water at 20° C. is preferably 5 g or more, and more preferably 10 g or more. Examples of such zinc compounds include zinc sulfate, zinc chloride, zinc gluconate, zinc bromide, zinc nitrate, zinc ammonium chloride, zinc aluminum sulfate, zinc potassium sulfate, and zinc iodide, and one or more of these can be used. When the cleaning composition of the present invention contains a zinc compound, the content of the zinc compound in the cleaning composition of the present invention is not particularly limited and can be adjusted depending on the purpose. For example, the cleaning composition can contain the zinc compound in an amount of 0.01 mass % to 10 mass % based on the total amount of the cleaning composition.

[0053] As the thickener other than hydrophobically modified polyether urethane, any known thickener generally used in cleaning agents other than hydrophobically modified polyether urethane can be used, and examples thereof include diallyl quaternary ammonium salt / acrylamide copolymers such as dimethyldiallylammonium chloride-acrylamide copolymer, diallyl quaternary ammonium salt / acrylamide / acrylic acid copolymers such as dimethyldiallylammonium chloride-acrylic acid-acrylamide copolymer, quaternary ammonium salt polymers such as polydimethylmethylene piperidinium chloride, quaternized polyvinylpyrrolidone derivatives such as vinylpyrrolidone-N,N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, cationic polymers such as polyquaternium-10, cationic starch, polyglycol polyamine condensates, and adipic acid-dimethylaminohydroxypropylethylenetriamine copolymer. Examples of the quaternary nitrogen-containing cellulose ether derivatives include quaternary nitrogen-containing cellulose ether derivatives such as O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethyl cellulose chloride, quaternary nitrogen-containing guar gum derivatives such as guar hydroxypropyltrimonium chloride, cationized dextran, cellulose or a derivative thereof, keratin and collagen or a derivative thereof, calcium alginate, pullulan, agar, gelatin, tamarind seed polysaccharides, xanthan gum, carrageenan, high methoxyl pectin, low methoxyl pectin, guar gum, gum arabic, crystalline cellulose, arabinogalactan, karaya gum, tragacanth gum, alginic acid, albumin, casein, curdlan, β-glucan, gellan gum, dextran, acrylate crosspolymer, hydrophobically modified alkyl cellulose, and the like. One or more of these may be used. When the cleaning composition of the present invention contains a thickener other than hydrophobically modified polyether urethane, the content of the thickener other than hydrophobically modified polyether urethane in the cleaning composition of the present invention is not particularly limited and can be adjusted according to the purpose, but can be contained in an amount of, for example, 0.01 mass % to 20 mass % relative to the total amount of the cleaning composition.

[0054] As the powder, known powders generally used in cleaning agents can be used, for example, inorganic powders (e.g., talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, red mica, black mica, vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, tungstate metal salts, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (calcined gypsum), calcium phosphate, fluorapatite, hydroxyapatite, ceramics, etc.) powder, metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc.), organic powder (e.g. polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene-acrylic acid copolymer resin powder, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, etc.), inorganic white pigment (e.g. titanium dioxide, zinc oxide, etc.), inorganic red pigment (e.g. iron oxide (red oxide), iron titanate, etc.), inorganic brown pigment (e.g. gamma-iron oxide, etc.), inorganic yellow pigment Color pigments (e.g., yellow iron oxide, ocher, etc.), inorganic black pigments (e.g., black iron oxide, low-order titanium oxide, etc.), inorganic purple pigments (e.g., manganese violet, cobalt violet, etc.), inorganic green pigments (e.g., chromium oxide, chromium hydroxide, cobalt titanate, etc.), inorganic blue pigments (e.g., ultramarine, Prussian blue, etc.), pearl pigments (e.g., titanium dioxide coated mica, titanium dioxide coated bismuth oxychloride, titanium dioxide coated talc, colored titanium dioxide coated mica, bismuth oxychloride, fish scale foil, etc.), metal powder pigments (e.g., aluminum powder, copper powder, etc.), organic pigments such as zirconium, barium or aluminum lakes (e.g., organic pigments such as Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, and Blue 404, Red 3, Red 104, Red 106, Red 227, Red 230, Red 401, Red 505, Orange 205, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Green 3, and Blue 1, etc.), natural pigments (e.g., chlorophyll,β-carotene, etc.), and one or more of these can be used. These powders may also be surface-treated by a conventionally known surface treatment, such as a fluorine compound treatment, a silicone treatment, a silicone resin treatment, a pendant treatment, a silane coupling agent treatment, a titanium coupling agent treatment, an oil treatment, an N-acylated lysine treatment, a polyacrylic acid treatment, a metal soap treatment, an amino acid treatment, an inorganic compound treatment, a plasma treatment, a mechanochemical treatment, etc. When the detergent composition of the present invention contains a powder, the content of the powder in the detergent composition of the present invention is not particularly limited and can be adjusted depending on the purpose, but for example, the powder can be contained in an amount of 0.01% by mass to 40% by mass based on the total amount of the detergent composition.

[0055] The antibacterial preservative may be a known antibacterial preservative generally used in cleaning agents, and examples thereof include parabens such as methylparaben, ethylparaben, propylparaben, and butylparaben; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, and 1,2-octanediol; alkyl glyceryl ethers such as 2-ethylhexylglyceryl ether; imidazole antibacterial agents such as thiabendazole and 2-benzimidazolylcarbamate methyl preventol; thiazole antibacterial agents; triazine antibacterial agents; isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; lanolin fatty acids and salts thereof; sodium benzoate; quaternary ammonium salts; phenoxyethanol; phenylethyl alcohol; and photosensitizers. One or more of these may be used. When the cleaning composition of the present invention contains an antibacterial preservative, the content of the antibacterial preservative in the cleaning composition of the present invention is not particularly limited and can be adjusted depending on the purpose. For example, the cleaning composition may contain 0.01% by mass to 10% by mass of the antibacterial preservative relative to the total amount of the cleaning composition.

[0056] The moisturizing agent may be a known moisturizing agent generally used in a detergent, and examples thereof include diethylene glycol monoethyl ether, sorbitol, deoxyribonucleic acid, mucopolysaccharides, sodium hyaluronate, sodium chondroitin sulfate, collagen, elastin, chitin, chitosan, biopolymers such as hydrolyzed eggshell membrane, amino acids, sodium lactate, urea, sodium pyrrolidone carboxylate, whey, etc., and one or more of these may be used. When the detergent composition of the present invention contains a moisturizing agent, the content of the moisturizing agent in the detergent composition of the present invention is not particularly limited and can be adjusted depending on the purpose, but for example, the moisturizing agent may be contained in an amount of 0.01% by mass to 40% by mass relative to the total amount of the detergent composition.

[0057] The antioxidant may be any known antioxidant generally used in detergents, such as dibutylhydroxytoluene, butylhydroxyanisole, sorbic acid, sodium sulfite, sodium hydrogensulfite, sodium thiosulfate, metabisulfite, thiotaurine, hypotaurine, thioglycerol, thiourea, thioglycolic acid, cysteine ​​hydrochloride, propyl gallate, gallic acid derivatives, ascorbic acid, ascorbic acid derivatives (ascorbic acid phosphate, etc.), tocopherol, tocopherol derivatives, erythorbic acid, pt-butylphenol, phytic acid, L-cysteine ​​hydrochloride, etc., and one or more of these may be used. When the detergent composition of the present invention contains an antioxidant, the content of the antioxidant in the detergent composition of the present invention is not particularly limited and may be adjusted according to the purpose, but may be, for example, 0.01% by mass to 10% by mass of the antioxidant relative to the total amount of the detergent composition.

[0058] As the ultraviolet absorber, a known ultraviolet absorber generally used in a cleaning agent can be used, for example, benzoic acid ultraviolet absorbers, anthranilic acid ultraviolet absorbers, salicylic acid ultraviolet absorbers, cinnamic acid ultraviolet absorbers, benzophenone ultraviolet absorbers, benzotriazole ultraviolet absorbers, triazine ultraviolet absorbers, benzoate ultraviolet absorbers, cyanoacrylate ultraviolet absorbers, oxanilide ultraviolet absorbers, formamidine ultraviolet absorbers, etc. can be mentioned, and one or more of these can be used. When the cleaning composition of the present invention contains an ultraviolet absorber, the content of the ultraviolet absorber in the cleaning composition of the present invention is not particularly limited and can be adjusted according to the purpose, but for example, the ultraviolet absorber can be contained in an amount of 0.01% by mass to 20% by mass based on the total amount of the cleaning composition.

[0059] As the sequestering agent, a known sequestering agent generally used in detergents can be used, and examples thereof include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, tetrasodium edetate, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, trisodium ethylenediaminehydroxyethyltriacetate, etc., and one or more of these can be used. When the detergent composition of the present invention contains a sequestering agent, the content of the sequestering agent in the detergent composition of the present invention is not particularly limited and can be adjusted depending on the purpose, but for example, the sequestering agent can be contained in an amount of 0.01% by mass to 10% by mass based on the total amount of the detergent composition.

[0060] The monosaccharide may be a known monosaccharide that is generally used in a detergent, and examples of such monosaccharides include trioses (e.g., D-glyceryl aldehyde, dihydroxyacetone, etc.), tetraoses (e.g., D-erythrose, D-erythrulose, D-threose, erythritol, etc.), pentoses (e.g., L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc.), hexoses (e.g., D-glucose, D-talose, D-psicose, D-galactose, D-fructose, L-galactose, etc.), and the like. , L-mannose, D-tagatose, etc.), heptose (e.g., aldoheptose, heptose, etc.), octose (e.g., octose, etc.), deoxy sugar (e.g., 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc.), amino sugar (e.g., D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.), uronic acid (e.g., D-glucuronic acid, D-mannuronic acid, L-guluronic acid, D-galacturonic acid, L-iduronic acid, etc.), etc., and one or more of these can be used. When the detergent composition of the present invention contains a monosaccharide, the content of the monosaccharide in the detergent composition of the present invention is not particularly limited and can be adjusted depending on the purpose, but for example, the content of the monosaccharide can be 0.01% by mass to 20% by mass based on the total amount of the detergent composition.

[0061] As the oligosaccharide, known oligosaccharides generally used in detergents can be used, such as sucrose, umbelliferose, lactose, planteose, isolichnoses, α,α-trehalose, raffinose, lychnoses, umbilicin, stachyose, verbascoses, etc., and one or more of these can be used. When the detergent composition of the present invention contains an oligosaccharide, the content of the oligosaccharide in the detergent composition of the present invention is not particularly limited and can be adjusted depending on the purpose, but for example, the oligosaccharide can be contained in an amount of 0.01% by mass to 20% by mass based on the total amount of the detergent composition.

[0062] The polysaccharide may be any known polysaccharide generally used in detergents, such as cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran, keratosulfate, locust bean gum, succinoglucan, caronic acid, etc., and one or more of these may be used. When the detergent composition of the present invention contains a polysaccharide, the content of the polysaccharide in the detergent composition of the present invention is not particularly limited and can be adjusted according to the purpose, but for example, the polysaccharide may be contained in an amount of 0.01% by mass to 20% by mass based on the total amount of the detergent composition.

[0063] As the organic amine, known organic amines generally used in detergents can be used, such as monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1-propanol, etc., and one or more of these can be used. When the detergent composition of the present invention contains an organic amine, the content of the organic amine in the detergent composition of the present invention is not particularly limited and can be adjusted depending on the purpose, but for example, the organic amine can be contained in an amount of 0.01% by mass to 20% by mass based on the total amount of the detergent composition.

[0064] The vitamins may be any known vitamin that is generally used in cleaning agents, such as, but not limited to, vitamin E and its derivatives, vitamin C and its derivatives, vitamin D and its derivatives, vitamin F and its derivatives, vitamin K and its derivatives, vitamin A and its derivatives, and vitamin B derivatives. Specific examples include γ-tocopherol, stearyl ascorbate, ascorbyl dipalmitate, tocopherol nicotinate, menadione, dehydrocholesterol, ergocalciferol, pyridoxine dicaprylate, ascorbyl tetra-hexyldecanoate (VCIP), retinol, retinol palmitate, retinol acetate and other retinol derivatives, docosahexaenoic acid, linoleic acid, panthenol, tocopherol linoleate, isopropyl linoleate, linolenic acid, pyridoxine palmitate, vitamin A, β-carotene, pyridoxine dipalmitate, phylloquinone, pantothenic acid and its derivatives, biotin, and the like, and one or more of these can be used. When the cleaning composition of the present invention contains vitamins, the content of the vitamins in the cleaning composition of the present invention is not particularly limited and can be adjusted depending on the purpose. For example, the cleaning composition may contain 0.01% by mass to 20% by mass of vitamins relative to the total amount of the cleaning composition.

[0065] The beauty ingredient may be a known beauty ingredient generally used in cleansers, such as placenta extract, mulberry extract, saxifrage extract, perilla extract, white mustard extract or hydrolysate thereof, fermented white mustard, damask rose extract, peony extract or hydrolysate thereof, lactic acid bacteria fermented rice, lotus seed extract or hydrolysate thereof, fermented lotus seed product, party ginseng extract, Job's tears hydrolysate, Job's tears seed fermented product, royal jelly fermented product, fermented sake lees product, Pandanus amaryllis extract, Arcangelisia flava extract, kiwi extract, chamomile extract, coral grass extract, rice leaf extract or hydrolysate thereof, eggplant (water eggplant, long eggplant, Kamo eggplant, rice eggplant), etc.) extract or hydrolysate thereof, extract of seaweed such as Eucalyptus tschonoskii, extract of marine flowering plants such as Zostera marina, fermented soy milk, jellyfish water, fermented rice extract, linoleic acid and its derivatives or processed products, collagen and its derivatives derived from animals or fish, elastin and its derivatives, glycyrrhizic acid and its derivatives, t-cycloamino acid derivatives, allantoin, arbutin, diisopropylamine dichloroacetate, γ-amino-β-hydroxybutyric acid, gentian extract, licorice extract, carrot extract, aloe extract, Laminaria oleracea extract, Ulva pertusa extract, Laminaria oleracea extract, immature peach extract, etc., and one or more of these may be used. When the cleaning composition of the present invention contains a cosmetic ingredient, the content of the cosmetic ingredient in the cleaning composition of the present invention is not particularly limited and can be adjusted according to the purpose, but for example, the cosmetic ingredient can be contained in an amount of 0.001% by mass to 20% by mass based on the total amount of the cleaning composition.

[0066] The fragrance may be a known fragrance generally used in cleaning agents, for example, a blended fragrance containing a natural fragrance and / or a synthetic fragrance.Specifically, natural fragrances include amyris oil, ambrette seed oil, ylang-ylang oil, ylang-ylang absolute, iris resinoid, iris absolute, iris oil, wintergreen oil, estragon oil, elemi oleoresin, elemi resinoid absolute, elemi tincture, oakmoss concrete, oakmoss absolute, oakmoss resin, oakmoss resinoid, osmanthus absolute, osmanthus concrete, opopanax resinoid, opopanax oleoresin, ... Nax Absolute, Opopanax Oil, Olibanum Resinoid, Olibanum Absolute, Olibanum Oil, Allspice Oil, Origanum Oil, Oregano Oil, Oregano Oleoresin, Orange Flower Absolute, Orange Flower Concrete, Cananga Oil, Garjun Balsam, Garjun Balsam Oil, Cassi Absolute, Cassi Flower Oil, Cassia Oil, Gardenia Absolute, Carnation Absolute, Cabreuva Oil, Chamomile Oil Ile, Cardamom Oil, Galbanum Oil, Galbanum Resin, Galbanum Resinoids, Caraway Seed Oil, Carrot Seed Oil, Cubeba Oil, Guaiac Wood Oil, Guaiac Resin, Guaiac Concrete, Camphor Oil, Cumin Oil, Cumin Absolute, Cumin Oleoresin, Clary Sage Oil, Grapefruit Oil, Clove Oil, Costus Oil, Copaiba Balsam, Copaiba Balsam Oil, Copaiba Balsam Resin, Coriander Oil, Sandalwood Oil, Perilla Oil, Cedarwood Oil, Citronella Oil, Jasmine Oil, Jasmine Absolute, Jasmine Concrete, Juniper Berry Oil, Junee Absolute, Jonquil Absolute, Ginger Oil, Cinnamon Oil, Cinnamon Bark Oil, Cinnamon Leaf Oil, Cedar Oil, Star Anise Oil, Styrax Oil, Styrax Resinoid, Spike Lavender Oil, Spearmint Oil, Savory Oil, Sage Oil, Cedar Oil, Cedar Leaf Oil,Geranium Oil, Celery Seed Oil, Thyme Oil, Taghetto Oil, Tangerine Oil, Tuberose Absolute, Tea Tree Oil, Tree Moss Absolute, Tonka Bean Oil, Tolu Balsam, Nutmeg Oil, Narcissus Absolute, Neroli Oil, Violet Leaf Absolute, Pine Oil, Pine Needle Oil, Basil Oil, Parsley Leaf Oil, Parsley Seed Oil, Parsley Herb Oil, Patchouli Oil, Peppermint Oil, Vanilla Absolute, Honeysuckle Absolute, Palmarosa Oil, Valerian Oil, Bitter Orange Oil, Hyssop Oil, Hiba Oil, Cypress Oil, Hyacinth Absolute, Fennel Oil, Fig Absolute, Petitgrain Oil, Butt Oil, Bay Oil, Vetiver oil, pepper oil, peppermint absolute, peppermint oil, bergamot oil, Peru balsam, benzoin tincture, benzoin resinoid, hosho oil, marjoram oil, mandarin oil, tangerine oil, mimosa concrete, mimosa absolute, mimosa oil, myrrh resinoid, myrrh absolute, myrrh oil, musk absolute, musk tincture, eucalyptus oil, yuzu oil, lime oil, labdanum oil, labdanum resinoid, lavender oil, lavender absolute, lavandin oil, lavandin absolute, lemon oil, lemongrass oil, rose oil, rose absolute, rose concrete, rosemary oil, laurel oil, laurel leaf oil, etc.

[0067] Synthetic fragrances include: Ambredride, Aldehydes C6-C12, Anisaldehyde, Acetal R, Acetophenone, Acetyl Cedrene, Adoxal, Allyl Amyl Glycolate, Allyl Cyclohexane Propionate, Ambroxan, Amyl Cinnamic Aldehyde, Amyl Cinnamic Aldehyde Dimethyl Acetal, Amyl Valerianate, Amyl Salicylate, Acetyl Eugenol, Isoamyl Acetate, Isoamyl Salicylate, Indole, Ionone, Isobornyl Acetate, Isocyclocitral, Iso E Super, Iso Eugenol, isononyl acetate, isobutylquinoline, gamma-undecalactone, ethylene brassylate, ethylene dodecanedioate, ethyl vanillin, 2-ethylhexanol, aurantiol, 10-oxahexadecanolide, 11-oxahexadecanolide, 12-oxahexadecanolide, oxahexadecen-2-one, eugenol, oribone, oxyphenylone, galaxolide, caryophyllene, cashmeran, carvone, beta-caryophyllene, carone, coumarin, p-cresyl methyl ether, geraniol, geranyl Acetate, Geranyl Formate, Geranyl Nitrile, Coabon, Sandalore, Sandela, Santarex, Cinnamic Alcohol, Cinnamic Aldehyde, Cis-Jasmone, Citral, Citral Dimethyl Acetal, Citrasal, Citronellal, Citronellol, Citronellyl Acetate, Citronellyl Formate, Citronellyl Nitrile, Cyclacet, Cyclamen Aldehyde, Cyclaprop, Dimethylbenzyl Carbinol, Dihydrojasmone, Dihydrolinalool, Dihydromyrcenol, Dimetol, Dimyrcetol , diphenyl oxide, jasmal, jasmolactone, jasmophillan, cinnamyl acetate, cyclopentadecanone, cyclohexadecenone, cyclopentadecanolide, cyclohexadecanolide, dimethylbenzylcarbinyl acetate, jasmacyclene, styralyl acetate, styralyl propionate, cedroamber, cedryl acetate, cedrol, celestride, α-damascone, β-damascone, δ-damascone, damascenone, terpineol, terpinyl acetate, thymol, tetrahydrolinalool,Tetrahydrolinalyl acetate, tetrahydrogeraniol, tetrahydrogeranyl acetate, tonalid, traseolide, triplal, neryl acetate, nerol, neobergamate, gamma-nonalactone, nopyr alcohol, nopyr acetate, bacdanol, hydrotropic alcohol, alpha-pinene, beta-pinene, hydroxycitronellal, hyacinth dimethyl acetal, butyl butyrate, pt-butyl cyclohexanol, pt-butyl cyclohexyl acetate , ot-butylcyclohexanol, ot-butylcyclohexyl acetate, fruitate, fenchyl alcohol, phenylethyl phenyl acetate, phenylethyl acetate, pentalid, verdox, benzyl acetate, benzyl alcohol, benzyl salicylate, bergamyl acetate, benzaldehyde, benzyl formate, hedione, helional, heliotropin, cis-3-hexenol, cis-3-hexenyl acetate, cis-3-hexenyl Neil Salicylate, Hexyl Cinnamic Aldehyde, Hexyl Salicylate, Bornyl Acetate, Borneol, Manzanate, Mayol, Myrcene, Mirac Aldehyde, Muguet Aldehyde, Mugol, Musk TM-11, Musk 781, Musk C14, Muscone, Musk Ketone, Musk Tibetin, Menthanyl Acetate, Menthonate, Methyl Anthranilate, Methyl Eugenol, Menthol, Alpha Methyl Ionone, Beta Methyl Ionone, Gamma Methyl Ionone, Methyl Ionone Examples of such amines include sougenol, methyl lavender ketone, methyl salicylate, 14-methyl-hexadecenolide, 14-methyl-hexadecanolide, methyl naphthyl ketone, methyl phenyl acetate, yara-yara, δ-C6 to C13 lactone, lime oxide, γ-C6 to C13 lactone, raspberry ketone, limonene, ligustral, lilial, linalool, linalool oxide, linalyl acetate, lyral, rhubarb, rosephenone, rose oxide, and vanillin.

[0068] Examples of pH adjusters include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate, and one or more of these can be used.

[0069] Other possible ingredients include blood circulation promoters (e.g., nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantharides tincture, ichthammol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, γ-oryzanol, etc.), anti-inflammatory agents (e.g., glycyrrhizinic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.), activators, Examples of such agents include agents (e.g., royal jelly, photosensitizers, cholesterol derivatives, etc.), antiseborrheic agents (e.g., sulfur, thianthol, etc.), anti-inflammatory agents (e.g., tranexamic acid, thiotaurine, hypotaurine, etc.), and various extracts (e.g., extracts of Phellodendron Bark, Coptis Rhizome, Lithospermum Root, Peony Root, Swertia japonica, Birch, sage, Loquat, Carrot, Aloe, Mallow, Iris, Grape, Coix Seed, Luffa, Lily, Saffron, Cnidium Rhizome, Angelica Root, Hypericum Perforatum, Ononis, Garlic, Capsicum Annuum, Tangerine Pepper, Angelica Root, Seaweed, etc.), and one or more of these may be used.

[0070] The formulation of the detergent composition of the present invention is not particularly limited, and examples thereof include liquid, gel, sherbet, emulsion, cream, ointment, solid paste, paste, solid, powder, etc. Cream-type detergents include oil-free creams that do not contain oil, anhydrous creams that do not contain water, oily creams that contain a lot of oil, weak oily creams that contain less oil, and medium oily creams whose oil content is intermediate between oily creams and weak oily creams. When the detergent composition of the present invention is in a liquid form, the viscosity is not particularly limited, and can be appropriately adjusted depending on the application.

[0071] Specific cleaners to which the cleaner composition of the present invention can be applied are not particularly limited, and examples thereof include known cleaners in which an emulsion composition is used. Examples of such cleaners include skin care cleaners such as body shampoo, body soap, facial cleansing cream, facial cleansing foam, hand cream, hand soap, foaming hand soap, solid soap, cleansing foam, makeup remover, shaving agent, and massage agent.

[0072] The present disclosure includes the following aspects.

[0073] [1] A cleaning composition comprising: (A) a hydrophobically modified polyether urethane; (B) an anionic surfactant; and (C) an amphoteric surfactant.

[0074] [2] The cleaning composition according to [1], wherein the hydrophobically modified polyether urethane (A) contains a hydrophobically modified polyether urethane represented by the following general formula (I): [ka] (In the formula, R 1 , R 2 , R 8 and R 9 each independently represents a hydrocarbon group having 1 to 20 carbon atoms; R 3 , R 5 and R 7 each independently represents a divalent hydrocarbon group having 2 to 4 carbon atoms; R 4 and R 6 each independently represents a divalent hydrocarbon group having 3 to 16 carbon atoms, a and c each independently represent a number from 10 to 100, b represents a number from 100 to 500, and d represents a number from 0 to 10.

[0075] [3] The cleaning composition according to [1] or [2], wherein the content of the hydrophobically modified polyether urethane (A) is 0.001 to 20 mass % based on the total amount of the cleaning composition.

[0076] [4] The cleaning composition according to any one of [1] to [3], wherein the content of the anionic surfactant (B) is 0.001 to 70 mass % based on the total amount of the cleaning composition.

[0077] [5] The cleaning composition according to any one of [1] to [4], wherein the content of the amphoteric surfactant (C) is 0.001 to 30 mass % based on the total amount of the cleaning composition.

[0078] [6] The cleaning composition according to any one of [1] to [5], further comprising (D) a nonionic surfactant in an amount of 0.001 to 30 mass % based on the total amount of the cleaning composition.

[0079] [7] The cleaning composition according to any one of [1] to [6], further comprising 1 to 99 mass % of water based on the total amount of the cleaning composition. EXAMPLES

[0080] The present invention will be described in detail below with reference to examples, but the present invention is not limited to these examples and may be modified without departing from the scope of the present invention. In the following examples, % is based on mass unless otherwise specified.

[0081] <Examples 1 to 20 and Comparative Examples 1 to 10> Each detergent composition was produced by mixing each component under the blending conditions in Tables 1 to 3 (the numbers in the tables indicate the blending amount (mass%) of each component). Each of the resulting detergent compositions was evaluated for foaming, foam persistence, foam elasticity, and foam smoothness by the following methods.

[0082] [How to evaluate foaming] For the obtained detergent compositions of Examples 1 to 20 and Comparative Examples 1 to 10, 3 g of the detergent composition was placed on the palm of a hand wetted with water, and the palm was rubbed together until foaming was felt. The number of times the palm was rubbed together was counted, and the foaming of each detergent composition was evaluated based on the following foaming evaluation criteria. The evaluation results are shown in Tables 1 to 3.

[0083] [Foaming evaluation criteria] ◎: Palms rubbed together less than 5 times ○: The number of times the palms were rubbed together was 6 to 10 △: The number of times the palms were rubbed together was 11 to 15 times ×: The number of times the palms were rubbed together was 16 or more

[0084] [Method of evaluating foam durability] The obtained cleaning compositions of Examples 1 to 20 and Comparative Examples 1 to 10 were diluted 3 times with water, filled into a pump former (manufactured by Glacel Co., Ltd., discharge amount 0.35 cc), and discharged in foam form. The foam height immediately after discharge and the foam height 3 minutes after discharge were measured, and the foam durability was evaluated based on the following evaluation criteria for foam durability. The evaluation results are shown in Tables 1 to 3.

[0085] [Evaluation criteria for foam durability] ◎: The foam height 3 minutes after discharge is 80% or more of the foam height immediately after discharge. ○: The foam height 3 minutes after discharge is 60% to less than 80% of the foam height immediately after discharge. △: The foam height 3 minutes after discharge is between 40% and 60% of the foam height immediately after discharge. ×: The foam height 3 minutes after discharge is less than 40% of the foam height immediately after discharge.

[0086] [Method for evaluating foam elasticity] The obtained cleaning compositions of Examples 1 to 20 and Comparative Examples 1 to 10 were diluted 3 times with water, filled into a pump former (manufactured by GLASEL Co., Ltd., discharge amount 0.35 cc), discharged in foam form, and the storage modulus was measured continuously for 5 minutes immediately after discharge using a rheometer (manufactured by Anton Paar, MCR-301), and the foam elasticity was evaluated based on the evaluation criteria for foam elasticity described below. The evaluation results are shown in Tables 1 to 3.

[0087] [Evaluation criteria for foam elasticity] ◎: The storage modulus after 5 minutes is 80% or more of the storage modulus immediately after discharge ○: The storage modulus after 5 minutes is 60% or more and less than 80% of the storage modulus immediately after discharge △: The storage modulus after 5 minutes is 40% or more but less than 60% of the storage modulus immediately after discharge. ×: The storage modulus after 5 minutes is less than 40% of the storage modulus immediately after discharge

[0088] [Method of evaluating foam smoothness] For the obtained detergent compositions of Examples 1 to 20 and Comparative Examples 1 to 10, 3 g of the detergent composition was placed on the palm of a hand wetted with water, and the palm was rubbed together 30 times to generate a lather. The lather was then spread along the arm, and the smoothness of the lather was evaluated according to the following evaluation criteria for lather smoothness. The evaluation results are shown in Tables 1 to 3.

[0089] [Evaluation criteria for foam smoothness] ◎: Very smooth ○: Smooth △: Slightly difficult to slide ×: Not easy to slide

[0090] [Table 1]

[0091] [Table 2]

[0092] [Table 3]

[0093] As described above, it is understood that according to the present invention, a cleaning composition having excellent foam quality can be obtained.

Claims

1. A cleaning composition comprising (A) a hydrophobically modified polyether urethane, (B) an anionic surfactant, and (C) an amphoteric surfactant.

2. The cleaning composition according to claim 1, wherein the hydrophobically modified polyether urethane (A) comprises a hydrophobically modified polyether urethane represented by the following general formula (I): 【Chemistry 1】 (In the formula, R １ , R ２ , R ８ and R ９ each independently represents a hydrocarbon group having 1 to 20 carbon atoms; R ３ , R ５ and R ７ each independently represents a divalent hydrocarbon group having 2 to 4 carbon atoms; R ４ and R ６ each independently represents a divalent hydrocarbon group having 3 to 16 carbon atoms, a and c each independently represent a number from 10 to 100, b represents a number from 100 to 500, and d represents a number from 0 to 10.

3. The cleaning composition according to claim 1 or 2, wherein the content of the hydrophobically modified polyether urethane (A) is 0.001 to 20 mass % based on the total amount of the cleaning composition.

4. The cleaning composition according to claim 1 or 2, wherein the content of the anionic surfactant (B) is 0.001 to 70 mass % based on the total amount of the cleaning composition.

5. The cleaning composition according to claim 1 or 2, wherein the content of the amphoteric surfactant (C) is 0.001 to 30 mass % based on the total amount of the cleaning composition.

6. The cleaning composition according to claim 1 or 2, further comprising: (D) a nonionic surfactant in an amount of 0.001 to 30 mass % based on the total amount of the cleaning composition.

7. The cleaning composition according to claim 1 or 2, further comprising water in an amount of 1 to 99 mass % based on the total amount of the cleaning composition.

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