Skin cleansing composition

Abstract

To provide a skin cleansing composition which is obtainable from surfactants of natural origin and exhibits excellent cleansing ability.SOLUTION: The present invention provides a skin cleansing composition, comprising the following components (A) to (C), with the mass ratio of components (A1) and (A2) ranging from 95:5 to 5:95. The inventive skin cleansing composition exhibits excellent cleansing ability through combinational use of components (A1) and (A2). (A) A lipid composition consisting of the following components (A1) and (A2): (A1) Mannosyl erythritol lipid, (A2) Phospholipid. (B) Polyhydric alcohol. (C) Water.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a skin cleansing composition containing mannosylerythritol lipid, a phospholipid, a polyhydric alcohol and water. [Background technology]

[0002] Skin cleansing compositions such as face washes, cleansing agents, body cleansers, scalp cleansers, etc. are routinely used for the purpose of removing excess sebum, makeup stains, etc., and keeping the skin clean. Such skin cleansing compositions generally contain a surfactant to improve the cleansing power, but in recent years, from the viewpoint of sustainability, it has been desired to use naturally derived surfactants in skin cleansing compositions as well.

[0003] Mannosylerythritol lipid (MEL) is a naturally derived glycolipid surfactant produced by plant-derived yeast, and is not only highly biodegradable, low-toxicity, and environmentally friendly, but also has physiologically active effects such as improving rough skin, anti-inflammation, anti-allergy, and hair growth, making it useful as an active ingredient in cosmetics and skin care products. Lecithin is a generic name for naturally derived phospholipids obtained from animals or plants, and is very safe for humans, does not irritate the skin, and has a moisturizing effect and a unique, excellent feel when used, so it is widely used as a surfactant in cosmetics and skin care products.

[0004] Patent Document 1 describes an invention relating to an oil-in-water emulsion cosmetic composition characterized by containing MEL, phospholipid, polyhydric alcohol and water, but does not specifically disclose a skin cleansing composition containing MEL, phospholipid, polyhydric alcohol and water. In addition, Patent Document 1 provides an oil-in-water emulsion cosmetic composition having excellent skin moisture barrier ability, but does not describe its effect as a skin cleansing composition. Patent Document 2 describes an invention relating to MEL-containing vesicles obtained by dispersing a composition consisting of MEL, phospholipid and polyhydric alcohol in water, but does not specifically disclose a skin cleansing composition containing MEL, phospholipid, polyhydric alcohol and water. In addition, Patent Document 2 provides a cosmetic composition that forms MEL-containing vesicles with a particle size of 100 nm or less by a simple operation of dispersing in water with low stirring force, but does not describe its effect as a skin cleansing composition. [Prior art documents] [Patent documents]

[0005] [Patent Document 1] JP 2009-275017 A [Patent Document 2] JP 2018-024639 A Summary of the Invention [Problem to be solved by the invention]

[0006] An object of the present invention is to provide a skin cleansing composition which can be obtained from a naturally derived surfactant and has excellent detergency. [Means for solving the problem]

[0007] As a result of intensive investigations aimed at solving the above-mentioned problems, the present inventors have found that the above-mentioned problems can be solved by a skin cleansing composition containing the following components (A) to (C), in which the mass ratio of components (A1) to (A2) is 95:5 to 5:95, and have completed the present invention. (A) A lipid composition comprising the following components (A1) and (A2): (A1) Mannosylerythritol lipid represented by the following general formula (1): [ka] (In the formula, R1 and R2 represent hydrogen or an aliphatic acyl group having 2 to 24 carbon atoms (however, hydrogen is not removed at the same time). R3 and R4 represent hydrogen or an acetyl group, and R5 represents hydrogen or an aliphatic acyl group having 2 to 24 carbon atoms.) (A2) Phospholipids (B) Polyhydric alcohol (C)Water Effect of the Invention

[0008] The skin cleansing composition of the present invention can be obtained from naturally occurring surfactants, and exhibits excellent cleansing power by using the components (A1) and (A2) in combination. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0009] The skin cleansing composition of the present invention is characterized by containing the following components (A) to (C). (A) A lipid composition comprising the following components (A1) and (A2): (A1) Mannosylerythritol lipid represented by the following general formula (1): [ka] (In the formula, R1 and R2 represent hydrogen or an aliphatic acyl group having 2 to 24 carbon atoms (however, hydrogen is not removed at the same time). R3 and R4 represent hydrogen or an acetyl group, and R5 represents hydrogen or an aliphatic acyl group having 2 to 24 carbon atoms.) (A2) Phospholipids (B) Polyhydric alcohol (C)Water

[0010] The mannosylerythritol lipid of component (A1) used in the present invention is a compound represented by the above general formula (1), and the mannosylerythritol lipid of general formula (1) includes various compounds depending on the bonding position of the acyl group or acetyl group, and generally, four types, MEL-A, MEL-B, MEL-C and MEL-D, are widely known. MEL-A is a compound in which R1 and R2 in general formula (1) are acyl groups, R3 and R4 are acetyl groups, and R5 is hydrogen. MEL-B is a compound in general formula (1) in which R1 and R2 are acyl groups, R3 is hydrogen, R4 is an acetyl group, and R5 is hydrogen. MEL-C is a compound in general formula (1) in which R1 and R2 are acyl groups, R3 is an acetyl group, R4 is hydrogen, and R5 is hydrogen. MEL-D is a compound in which R1 and R2 in general formula (1) are acyl groups, R3 and R4 are hydrogen, and R5 is hydrogen. Any of these can be used in the present invention, but MEL-B or MEL-C is preferred in terms of availability and the effects of the invention, and MEL-B is the most preferred. R1, R2, and R5 in general formula (1) are preferably saturated or unsaturated acyl groups having 6 to 20 carbon atoms. There is no particular limit to the method for producing mannosylerythritol lipid, and it can be produced by a known method. For example, it may be produced by the method described in JP-A-2009-275017.

[0011] Examples of the phospholipids of component (A2) used in the present invention include diacylglycerophospholipids having polar groups such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, phosphatidylserine, and phosphatidic acid; lecithin obtained from plants such as soybean, rapeseed, sunflower, safflower, peanut, cottonseed, corn, rice, and barley, and egg yolk, and hydrogenated products thereof. These phospholipids may be used alone or in combination of two or more. Among these, lecithin and hydrogenated products thereof are preferred from the viewpoint of availability and further exerting the effects of the present invention. Lecithin with different phosphatidylcholine (hereinafter, PC) contents depending on the degree of purification is commercially available, and any PC content can be used in the present invention. From the viewpoint of further exerting the effects of the present invention, it is preferable to use lecithin with a PC content of preferably 40% by mass or more, more preferably 50% by mass or more.

[0012] Examples of the polyhydric alcohols used in the present invention as component (B) include dihydric alcohols such as ethylene glycol, propylene glycol, 1,3-propanediol, 1,2-butylene glycol, 1,3-butylene glycol, 2,3-butylene glycol, tetramethylene glycol, hexylene glycol, octylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-heptanediol, 1,2-octanediol, and 1,2-decanediol; glycerin, trimethylolpropane, and 1,2,6-hexanetriol. trihydric alcohols such as glycerol; sugar alcohols such as sorbitol, xylitol, erythritol, maltitol, mannitol; glyceryl ethers such as ethylglycerin, butylglycerin, hexylglycerin, ethylhexylglycerin; polyhydric alcohol polymers such as diethylene glycol, triethylene glycol, tetraethylene glycol, polyethylene glycol, dipropylene glycol, tripropylene glycol, polypropylene glycol, diglycerin, triglycerin, tetraglycerin, polyglycerin, etc. These may be used alone or in combination of two or more. Among these, glycerin, propylene glycol, 1,3-propanediol, dipropylene glycol, 1,3-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-heptanediol, and 1,2-octanediol are preferred, and 1,3-butylene glycol, glycerin, 1,2-pentanediol, and 1,2-hexanediol are most preferred.

[0013] The water of component (C) used in the present invention is not particularly limited, and can be purified water, ion-exchanged water, distilled water, natural water, deep sea water, hydrogen water, etc. In addition, the pH of the water may be adjusted with an acid, an alkali, a buffering agent, a chelating agent, etc., or a water-soluble component such as a preservative may be added.

[0014] In the present invention, the mass ratio of components (A1) and (A2) is 95:5 to 5:95. If the mass ratio of components (A1) and (A2) is outside this range, excellent detergency is not exhibited. From the viewpoint of further exerting the effects of the present invention, the mass ratio of components (A1) and (A2) is preferably 90:10 to 10:90, more preferably 80:20 to 10:90.

[0015] The content of component (A) in the skin cleansing composition of the present invention is not particularly limited as long as it is contained to an extent that the skin cleansing composition can exhibit cleaning power according to the purpose, but the lower limit of the content is 0.1 mass% or more, preferably 0.5 mass% or more. The upper limit of the content is 25 mass% or less, preferably 20 mass% or less, from the viewpoint of the stability over time of the skin cleansing composition.

[0016] The skin cleansing composition of the present invention is characterized in that the lipid composition consisting of component (A), i.e., components (A1) and (A2), is dispersed in water. Component (A) being dispersed in water means that components (A1) and (A2) are dispersed in water by being added to water simultaneously in a fully mixed state. When components (A1) and (A2) are dispersed in water separately, the effect of the present invention cannot be fully achieved.

[0017] As described above, in order to disperse component (A) in water, it is necessary to previously mix components (A1) and (A2) and add the mixture to water to disperse it. However, since components (A1) and (A2) are each solid or powder, it is difficult to previously mix components (A1) and (A2) in scaled-up industrial production. From this viewpoint, a polyhydric alcohol of component (B) can be used to prepare the skin cleansing composition of the present invention. Specifically, components (A1), (A2) and (B) are stirred and mixed to prepare a polyhydric alcohol solution, and water is added to the obtained polyhydric alcohol solution while stirring, or the polyhydric alcohol solution is added to water while stirring, so that components (A1) and (A2) are dispersed in water simultaneously as component (A) in a fully mixed state, which makes it easy to prepare the skin cleansing composition of the present invention. In this case, the amount of component (B) used is not particularly limited as long as component (A) is sufficiently dispersed in component (B), but it is usually at least 2 times by mass, preferably at least 2.5 times by mass, of component (A).

[0018] The skin cleansing composition of the present invention obtained as described above can exhibit excellent detergency by using the components (A1) and (A2) in combination. When the components (A1) or (A2) are used alone, the excellent detergency is not exhibited.

[0019] The reason why the skin cleansing composition of the present invention exhibits excellent cleaning power is believed to be that in the skin cleansing composition of the present invention, component (A) forms fine lipid membrane structures and disperses in water. The lipid membrane structures refer to vesicles, bicelles, etc. It is presumed that the skin cleansing composition of the present invention exhibits excellent cleaning power because the fine lipid membrane structures made of component (A) adhere to the surface of oily stains while maintaining the shape of the structures, and float and emulsify the oily stains.

[0020] Component (A) of the present invention may further contain, as component (A3), an oily component that can be encapsulated in the membrane of the lipid membrane structure formed by component (A). Specific examples of component (A3) used in the present invention include one or more selected from ceramides, sterols, carotenoids, tocopherols, lipoic acid, and coenzyme Q10. More specific examples of ceramides include ceramide 1, ceramide 2, ceramide 3, ceramide 4, ceramide 5, ceramide 6, ceramide 7, sphingosine, and phytosphingosine. Examples of sterols include cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, desmosterol, stigmasterol, sitosterol, campesterol, brassicasterol, phytosterol, ergosterol, and oryzanol. Examples of carotenoids include carotene, lycopene, cryptoxanthin, lutein, zeaxanthin, astaxanthin, crocetin, fucoxanthin, etc. Examples of tocopherols include α-tocopherol, β-tocopherol, γ-tocopherol, δ-tocopherol, α-tocotrienol, β-tocotrienol, γ-tocotrienol, δ-tocotrienol, tocopherol acetate, tocopherol nicotinate, etc.

[0021] When component (A) contains component (A3), the content of component (A3) in component (A) is 36% by mass or less, preferably 34% by mass or less, and more preferably 32% by mass or less. If the content of component (A3) is higher than this range, component (A3) may not be encapsulated in the membrane of the lipid membrane structure.

[0022] The skin cleansing composition in which component (A) contains component (A3) can be prepared in the same manner as in the case in which component (A) consists of components (A1) and (A2).

[0023] The skin cleansing composition of the present invention may contain oily components other than component (A3) within a range that does not impair the effects of the present invention. However, if the amount of the oily component is large relative to the contents of components (A1) and (A2), the lipid membrane structure formed by components (A1) and (A2) cannot be maintained. From this viewpoint, the amount of the oily component contained in the skin cleansing composition of the present invention is preferably 50 parts by mass or less, and preferably 40% by mass or less, relative to 100 parts by mass of the total of components (A1) and (A2).

[0024] The oily component other than component (A3) that can be blended in the skin cleansing composition of the present invention is not particularly limited, and one or more of the oily components generally used in cosmetics can be used. Specific examples of the oily component used in the skin cleansing composition of the present invention include hydrocarbons such as dodecane, isododecane, hexadecane, isohexadecane, (C13-15) alkanes, liquid paraffin, heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, and petrolatum; coconut oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, vegetable oils and fats such as avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, Argania spinosa kernel oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, camellia oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cacao butter, jojoba oil, cocoa butter, shea butter, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, and hydrogenated jojoba oil;Methylheptyl laurate, isopropyl myristate, methylheptyl myristate, hexyldecyl myristate, octyldodecyl myristate, isopropyl palmitate, methylheptyl palmitate, ethylhexyl palmitate, cetyl palmitate, octyldodecyl palmitate, cetyl ethylhexanoate, hexyldecyl ethylhexanoate, isotridecyl isononanoate, isononyl isononanoate, ethylhexyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldodecyl neodecanoate, ethyl oleate, oleyl oleate, octyldodecyl oleate, isopropyl isostearate Monoalcohol carboxylates such as methylheptyl isostearate, octyldodecyl isostearate, octyldodecyl ricinoleate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isopropyl lanolate, octyldodecyl lanolate, diethylhexyl succinate, diisopropyl adipate, diisobutyl adipate, diethylhexyl adipate, diethyl sebacate, diisopropyl sebacate, diethylhexyl sebacate, dibutyloctyl sebacate, and dicaprylyl carbonate; oxyacid esters such as cetyl lactate, hydrogenated castor oil monoisostearate, γ-erucalactone, diisostearyl malate, and triethyl citrate;Glyceryl triethylhexanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, caprylic / capric triglyceride, caprylic / capric / myristic / stearic triglyceride, glyceryl behenate eicosandioate, trimethylolpropane triethylhexanoate, trimethylolpropane triisostearate, neopentyl glycol diethylhexanoate, neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol diethylhexanoate, propylene glycol dioleate, pentaerythrityl tetraethylhexanoate, ditrimethylolpropane triethylhexanoate, pentaerythrityl triethylhexanoate, hydroxystearic acid / stearic acid / rosin polyhydric alcohol fatty acid esters such as dipentaerythrityl diisostearate, diglyceryl tetraisostearate, 3-methyl-1,5-pentanediol dineopentanoate, and 2,4-diethyl-1,5-pentanediol dineopentanoate; alkyl ethers such as dicaprylyl ether; acyl amino acid esters such as dioctyldodecyl N-lauroyl-L-glutamate, di(phytosteryl / octyldodecyl) N-lauroyl-L-glutamate, di(cholesteryl / octyldodecyl) N-lauroyl-L-glutamate, di(cholesteryl / behenyl / octyldodecyl) N-lauroyl-L-glutamate, di(phytosteryl / behenyl / octyldodecyl) N-lauroyl-L-glutamate, and isopropyl N-lauroyl sarcosine;Phytosteryl oleate, phytosteryl hydroxystearate, phytosteryl isostearate, phytosteryl lanolate, phytosteryl macadamiate, phytosteryl sunflower seed oil, phytosteryl rice bran oil, cholesteryl acetate, cholesteryl nonanoate, cholesteryl oleate, cholesteryl 12-hydroxystearate, cholesteryl isostearate, cholesteryl lanolate, cholesteryl macadamiate, Sterol esters such as cholesteryl sunflower seed oil fatty acid, cholesteryl rice bran oil fatty acid, cholesteryl soft lanolin fatty acid, cholesteryl hard lanolin fatty acid, cholesteryl long-chain branched fatty acid, cholesteryl long-chain α-hydroxy fatty acid; diisopropyl dimer dilinoleate, diisostearyl dimer dilinoleate, di(isostearyl / phytosteryl) dimer dilinoleate, phytosteryl / behenyl dimer dilinoleate, phytosteryl dimer dilinoleate / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleyl dimer dilinoleate, dimer dilinoleyl diisostearate, dimer dilinoleyl hydrogenated rosin condensate, dimer dilinoleic acid hydrogenated castor oil, hydroxyalkyl dimer dilinoleyl ether and other dimer acid or dimer diol derivatives; lanolin, liquid lanolin, hard lanolin, reduced lanolin, adsorption refined lanolin, lanolin alcohol and other lanolins; dimethicone, highly polymerized dimethicone, cyclopentadiene, etc. silicones such as dimethicone, phenyl trimethicone, diphenyl dimethicone, phenyl dimethicone, and dimethiconol; higher alcohols such as cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, arachyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, selachyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, and 2-octyldodecanol;Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long-chain branched fatty acids, long-chain α-hydroxy fatty acids, lanolin fatty acids, dimer acids, and hydrogenated dimer acids.

[0025] The skin cleanser composition of the present invention may contain, as necessary, additives that are usually blended into cosmetics, such as oily bases, moisturizers, texture improvers, surfactants, polymers, thickeners, gelling agents, antioxidants, reducing agents, oxidizing agents, antioxidants, whitening agents, vitamins and derivatives thereof, plant, animal or microbial extracts, UV absorbers, antibacterial agents, preservatives, chelating agents, pH adjusters, acids or alkalis, solvents or propellants, antipruritics, keratin exfoliants and dissolving agents, antiperspirants, cooling agents, astringents, enzymes, nucleic acids, anti-inflammatory agents and anti-inflammatory agents, hair growth agents, blood circulation promoters and stimulants, hormones, anti-wrinkle and anti-aging agents, irritation mitigators, cooling agents, warming agents, powders, dyes, colorants, dyes, pigments, fragrances and the like, to an extent that does not impair the effects of the present invention.

[0026] Examples of oily bases include higher alcohols such as cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, arachyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, selachyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, 2-octyldodecanol, and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, Higher fatty acids such as undecylenic acid, 12-hydroxystearic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexadecanoic acid, anteisohenicosanoic acid, long-chain branched fatty acids, long-chain α-hydroxy fatty acids, dimer acids, hydrogenated dimer acids, and their aluminum salts, calcium salts, magnesium salts, zinc salts, potassium salts, sodium salts, and other metal soaps, as well as nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin , α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, solid paraffin, and other hydrocarbons; candelilla wax, carnauba wax, rice wax, Japan wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, Fischer-Tropsch wax, polyethylene wax, ethylene-propylene copolymer, and other waxes; coconut oil, palm oil, palm kernel oil, safflower oil, olive oil , castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut oil, hazelnut oil, kukui nut oil, rosehip oil, meadowfoam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran oil, cocoa butter, shea butter, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil, and other vegetable oils and fats; beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle oil, and other animal waxes; whale wax, lanolin, orange raffy oil, and other animal waxes;Lanolin derivatives such as liquid lanolin, reduced lanolin, adsorbed purified lanolin, acetated lanolin, acetated liquid lanolin, hydroxylanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, acetated lanolin alcohol, acetate (cetyl lanoyl) ester; lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin, etc. Phospholipids such as lysophospholipids, phosphatidic acid, cyclic lysophosphatidic acid or its salt, and lysolecithin; phospholipid derivatives such as hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, and partially hydrogenated egg yolk phospholipid; sterols such as cholesterol, dihydrocholesterol, lanosterol, dihydrolanosterol, phytosterol, and cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonanoate, cholesteryl stearate, Acyl sarcosine alkyl esters such as cholesteryl isostearate, cholesteryl oleate, N-lauroyl-L-glutamic acid di(cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamic acid di(cholesteryl / octyldodecyl), N-lauroyl-L-glutamic acid di(phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamic acid di(phytosteryl / octyldodecyl), and N-lauroyl sarcosine isopropyl. Sterol esters such as sterol esters of 12-hydroxystearate, cholesteryl macadamiate, phytosteryl macadamiate, phytosteryl sunflower seed oil, phytosteryl isostearate, cholesteryl soft lanolinate, cholesteryl hard lanolinate, cholesteryl long-chain branched fatty acid, and cholesteryl long-chain α-hydroxy fatty acid; lipid complexes such as phospholipid-cholesterol complex and phospholipid-phytosterol complex;Octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl palmitate, octyldodecyl palmitate, cetyl octanoate, hexyldecyl octanoate, isotridecyl isononanoate, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, octyldodecyl lanolinate, dicaprylyl carbonate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, hydrogenated castor oil isostearate, Monoalcohol carboxylates such as ethyl oleate, avocado oil fatty acid ethyl, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, isopropyl lanolin fatty acid, methylheptyl laurate, methylheptyl myristate, methylheptyl palmitate, methylheptyl isostearate, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, diisopropyl adipate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate, and triethyl citrate; oxyacid esters such as cetyl lactate, hydrogenated castor oil monoisostearate, γ-erucalactone, and diisostearyl malate;Glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, caprylic / capric triglyceride, caprylic / capric / myristic / stearic triglyceride, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl behenate eicosandioate, trimethylolpropane trioctanoate, trimethylolpropane triisostearate, neopentyl glycol dioctanoate, dicaprylate Neopentyl glycol dioctanoate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin pentaerythrityl, ditrimethylolpropane triethylhexanoate, ditrimethylolpropane isostearate / sebacic acid, pentaerythrityl triethylhexanoate, dipentaerythrityl hydroxystearic acid / stearic acid / rosin acid, diglyceryl diisostearate, polyglyceryl tetraisostearate Polyhydric alcohol fatty acid esters such as polyglyceryl-10 nonaisostearate, polyglyceryl-8 deca(erucic acid / isostearate / ricinoleic acid), diglyceryl oligoester (hexyldecanoic acid / sebacic acid), glycol distearate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentanediol dineopentanoate; alkyl ethers such as dicaprylyl ether; diisopropyl dimer dilinoleate, ... -Diisostearyl dimer dilinoleate, di(isostearyl / phytosteryl) dimer dilinoleate, phytosteryl / behenyl dimer dilinoleate, phytosteryl / isostearyl / cetyl / stearyl / behenyl dimer dilinoleate, dimer dilinoleyl diisostearate, dimer dilinoleyl hydrogenated rosin condensate, dimer dilinoleic acid hydrogenated castor oil, hydroxyalkyl dimer dilinoleyl ether and other dimer acid or dimer diol derivatives;Fatty acid alkanolamides such as coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (palmitamide MEA), palmitic acid diethanolamide (palmitamide DEA), coconut oil fatty acid methylethanolamide (cocamide methyl MEA); dimethicone (dimethylpolysiloxane), highly polymerized dimethicone (highly polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyl trimethicone, diphenyl dimethicone, phenyl dimethicone, (aminoethyl aminopropyl methicone / dimethicone) copolymer, dimethiconol, dimethiconol crosspolymer, silicone resin, silicone Preferred examples of the silicones include corn gum, amino-modified silicones such as aminopropyl dimethicone and amodimethicone, cationic modified silicones, polyether-modified silicones such as dimethicone copolyol, polyglycerin-modified silicones, sugar-modified silicones, carboxylic acid-modified silicones, phosphoric acid-modified silicones, sulfate-modified silicones, alkyl-modified silicones, fatty acid-modified silicones, alkyl ether-modified silicones, amino acid-modified silicones, peptide-modified silicones, fluorine-modified silicones, cationic and polyether-modified silicones, amino and polyether-modified silicones, alkyl and polyether-modified silicones, amidoalkyl-modified silicones, aminoglycol-modified silicones, aminophenyl-modified silicones, and polysiloxane-oxyalkylene copolymers; and fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether.

[0027] Moisturizing agents and texture improvers include polyols and their polymers such as glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, and ethylene glycol-propylene glycol copolymers; glycol alkyl ethers such as diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, and diethylene glycol dibutyl ether; water-soluble esters such as polyglyceryl-10 (eicosane diacid / tetradecanedioic acid), polyglyceryl-10 tetradecanedioic acid, and bisethoxydiglycol cyclohexanedicarboxylate; and sugar alkanes such as sorbitol, xylitol, erythritol, mannitol, and maltitol. Alcohols; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, and modified cyclodextrins such as maltosylated and hydroxyalkylated), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabinogalactan, dextrin, dextran, glycine Sugars and their derivatives, such as cogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate, caronin sulfate, keratosulfate, dermatan sulfate; Tremella fuciformis extract, Tremella fuciformis polysaccharide; fructans, such as inulin and levan; fucoidan; tuberose polysaccharide, naturally occurring polysaccharides; organic acids, such as citric acid, tartaric acid, lactic acid, and their salts; urea; 2-pyrrolidone-5-carboxylic acid and its sodium salts, etc.;Amino acids and their salts, such as betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine, γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid, carnitine, carnosine, and creatine; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen hydrolysis peptides, hydrolyzed collagen, hydroxypropylammonium chloride hydrolysis collagen, elastin hydrolysis peptides, keratin hydrolysis peptides, hydrolyzed keratin, conchiolin hydrolysis peptides, hydrolyzed conchiolin, silk protein hydrolysis peptides, hydrolyzed silk, sodium lauroyl hydrolyzed silk, soy protein hydrolysis peptides, small Protein peptides and their derivatives such as wheat proteolysis peptides, hydrolyzed wheat protein, casein hydrolysis peptides, and acylated peptides; acylated peptides such as palmitoyl oligopeptide, palmitoyl pentapeptide, and palmitoyl tetrapeptide; silylated peptides; lactic acid bacteria culture liquid, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesame lignan glycoside, glutathione, albumin, whey; choline chloride, phosphorylcholine; placenta extract, air Preferred examples of the active ingredient include animal and plant extracts such as lastin, collagen, aloe extract, witch hazel water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, rose roe extract, yarrow extract, eucalyptus extract, and melilot extract, and ceramides such as natural ceramides (types 1, 2, 3, 4, 5, and 6), hydroxyceramides, pseudoceramides, sphingoglycolipids, ceramides, and glycoceramide-containing extracts.

[0028] Preferred examples of surfactants include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, and polymer surfactants. There is no particular limitation on the HLB of the surfactant, and surfactants with a low HLB of about 1 to a high HLB of about 20 can be used, and it is also preferable to combine surfactants with low and high HLB. Preferred examples of surfactants include anionic surfactants such as fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfate ester salts such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; polyoxyethylene alkyl sulfate salts such as sodium laureth sulfate and triethanolamine laureth sulfate; acyl N-methyl amino acid salts such as sodium cocoyl methyl taurate, potassium cocoyl methyl taurate, sodium lauroyl methyl taurate, sodium myristoyl methyl taurate, sodium lauroyl methyl alanine, sodium lauroyl sarcosine, triethanolamine lauroyl sarcosine, and sodium lauroyl glutamate methyl alanine; sodium cocoyl glutamate, triethanolamine cocoyl glutamate, and sodium lauroyl glutamate. Acyl amino acid salts such as sodium myristoyl glutamate, sodium stearoyl glutamate, palmitoyl aspartic acid ditriethanolamine, cocoyl alanine triethanolamine, and sodium dilauroyl glutamate lysine; polyoxyethylene alkyl ether acetates such as sodium laureth acetate; succinic acid ester salts such as sodium lauroyl monoethanolamide succinate; fatty acid alkanolamide ether carboxylates; acyl lactates; polyoxyethylene fatty amine sulfates; fatty acid alkanolamide sulfates; fatty acid glyceride sulfates such as sodium hydrogenated coconut oil fatty acid glycerin sulfate; alkyl benzene polyoxyethylene sulfates; olefin sulfonates such as sodium α-olefin sulfonate; alkyl sulfosuccinates such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate;alkyl ether sulfosuccinates such as disodium laureth sulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate; alkyl benzene sulfonates such as sodium tetradecylbenzene sulfonate, triethanolamine tetradecylbenzene sulfonate; alkyl naphthalene sulfonates; alkane sulfonates; α-sulfofatty acid methyl ester salts; acyl isethionates; alkyl glycidyl ether sulfonates; alkyl sulfoacetates; alkyl ether phosphate salts such as sodium laureth phosphate, sodium dilaureth phosphate, sodium trilaureth phosphate, sodium monoolethate; alkyl phosphate salts such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphate salts; fatty acid amide ether phosphate salts; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof; silicones such as carboxylic acid modified silicones, phosphate modified silicones, and sulfate modified silicones. ricone-based anionic surfactants, etc.; nonionic surfactants include polyoxyethylene alkyl ethers with various polyoxyethylene addition numbers, such as laureths (polyoxyethylene lauryl ethers), ceteths (polyoxyethylene cetyl ethers), steareths (polyoxyethylene stearyl ethers), beheneths (polyoxyethylene behenyl ethers), isosteareths (polyoxyethylene isostearyl ethers), and octyldodeceths (polyoxyethylene octyldodecyl ethers); polyoxyethylene alkyl phenyl ethers. esters; castor oil and hydrogenated castor oil derivatives such as polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearate diester, and polyoxyethylene hydrogenated castor oil maleic acid; polyoxyethylene phytosterols; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin;Polyoxyethylene-polyoxypropylene cetyl ether, polyoxyethylene-polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene-polyoxypropylene monobutyl ether, polyoxyethylene-polyoxypropylene hydrogenated lanolin, polyoxyethylene-polyoxypropylene glycerin ether, etc. Polyoxyethylene-polyoxypropylene alkyl ethers; polyoxyethylene-polyoxypropylene glycol; PPG-9 diglyceryl, etc. ) Glycerin polyoxypropylene glycol; glyceryl stearate, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, glyceryl coconut oil fatty acid, glyceryl monocottonseed oil fatty acid, glyceryl monoerucate, glyceryl sesquioleate, glyceryl α,α'-oleate pyroglutamate, glyceryl monostearate malate, and other glycerin fatty acid partial esters; polyglyceryl-2, 3, 4, 5, 6, and 8 stearate , 10, polyglyceryl-6 distearate, 10, polyglyceryl-2 tristearate, polyglyceryl-10 deca stearate, polyglyceryl-2 isostearate, 3, 4, 5, 6, 8, 10, polyglyceryl-2 diisostearate (diglyceryl diisostearate), 3, 10, polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate, 3, No. 4, No. 5, No. 6, No. 8, No. 10, polyglycerin fatty acid esters such as polyglyceryl-6 dioleate, polyglyceryl-2 trioleate, and polyglyceryl-10 decaoleate; ethylene glycol mono fatty acid esters such as ethylene glycol monostearate; propylene glycol mono fatty acid esters such as propylene glycol monostearate; pentaerythritol partial fatty acid esters; sorbitol partial fatty acid esters; maltitol partial fatty acid esters; maltitol ethers;Sorbitan fatty acid esters such as sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, and diglycerol sorbitan tetra-2-ethylhexylate; sucrose fatty acid esters such as sucrose laurate, sucrose myristate, sucrose palmitate, sucrose dilaurate, sucrose dimyristate, and sucrose dipalmitate. Partial esters of sugar derivatives such as glyceryl, methyl glucoside fatty acid esters, and trehalose undecylenate; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides; glycolipids such as mannosyl erythritol lipid; lanolin alcohol; reduced lanolin; polyoxyethylene distearate, polyethylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene dioleate, and other polyoxyethylene fatty acid mono- and diesters; polyoxyethylene propylene glycol fatty acid esters; polyoxyethylene glycol Polyoxyethylene glycerin fatty acid esters such as polyoxyethylene monooleates such as serine monostearate, polyoxyethylene glycerin monoisostearate, and polyoxyethylene glycerin triisostearate; polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, and polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol fatty acid esters such as polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene sorbitol pentaoleate, and polyoxyethylene sorbitol monostearate; polyoxyethylene methyl glucoside fatty acid esters; polyoxyethylene alkyl ether fatty acid esters; polyoxyethylene sorbitol beeswax and other polyoxyethylene animal and vegetable oils and fats; isostearyl glyceryl ether, alkyl glyceryl ethers such as chimyl alcohol, selachyl alcohol, and batyl alcohol; polyhydric alcohol alkyl ethers;Polyoxyethylene alkylamines; tetrapolyoxyethylene-tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponin, surfactin, rhamnolipid, sophorolipid, etc.; polyoxyethylene fatty acid amides; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid Fatty acid alkanolamides such as palmitic acid monoethanolamide (paltamide MEA), palmitic acid diethanolamide (paltamide DEA), coconut oil fatty acid methylethanolamide (cocamide methyl MEA); alkyl dimethylamine oxides such as lauramine oxide, cocamine oxide, stearamine oxide, behenamine oxide; alkyl ethoxydimethylamine oxide; polyoxyethylene alkyl mercaptan; polyether modified silicones such as dimethicone copolyol, polysiloxane-oxyalkylene copolymers, polyglycerin modified Silicone-based nonionic surfactants such as silicone and sugar-modified silicone; cationic surfactants include alkyltrimethylammonium chlorides such as behentrimonium chloride, steartrimonium chloride, cetrimonium chloride, and lauryltrimonium chloride; alkyltrimethylammonium bromides such as stearyltrimonium bromide; dialkyldimethylammonium chlorides such as distearyldimonium chloride and dicocodimonium chloride; fatty acid amidoamines and their salts such as stearamidopropyl dimethylamine and stearamidoethyl diethylamine; alkyl ether amines and their salts or quaternary salts such as stearoxypropyl dimethylamine; fatty acid amide-type quaternary ammonium salts such as ethyl sulfate long-chain branched fatty acid (12-31) aminopropyl ethyl dimethyl ammonium and ethyl sulfate lanolin fatty acid aminopropyl ethyl dimethyl ammonium; polyoxyethylene alkylamines and their salts or quaternary salts; alkylamine salts; fatty acid amide guanidinium salts; alkyl ether amine monium salts; alkyl trialkylene glycol ammonium salts; benzalkonium salts;benzethonium salts; pyridinium salts such as cetylpyridinium chloride; imidazolinium salts; alkylisoquinolinium salts; dialkylmorphonium salts; polyamine fatty acid derivatives; silicone-based cationic surfactants such as amino-modified silicones such as aminopropyl dimethicone and amodimethicone, cation-modified silicones, cation-modified and polyether-modified silicones, and amino-modified and polyether-modified silicones; amphoteric surfactants include N-alkyl-N,N-dimethyl amino acid betaines such as lauryl betaine (lauryl dimethyl amino acetate betaine); fatty acid amidoalkyl-N,N-dimethyl amino acid betaines such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline-type betaines such as sodium cocoamphoacetate and sodium lauroamphoacetate; betaines such as alkyldimethyltaurine; sulfate type betaines such as alkyldimethylaminoethanol sulfate ester; phosphate type betaines such as alkyldimethylaminoethanol phosphate ester; sphingophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, and sphingomyelin, phospholipids such as lysolecithin, hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid, and hydroxide lecithin; silicone-based amphoteric surfactants, etc.; and among the polymer surfactants, preferred examples include polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, and acrylic acid / alkyl methacrylate copolymers; and various silicone-based surfactants.

[0029] Polymers, thickeners, and gelling agents include guar gum, locust bean gum, queen seed, carrageenan, galactan, gum arabic, tara gum, tamarind, furcellan, karaya gum, aoi, caragam, tragacanth gum, pectin, pectinic acid and its salts, alginic acid and its salts, mannan; starches such as rice, corn, potato, and wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salts, xanthan gum, pullulan, gellan gum, chitin, chitosan, etc. cellulose, agar, cassou extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose and its sodium salts, methylhydroxypropylcellulose, carboxylated cellulose nanofiber, carboxymethylcellulose nanofiber, phosphated cellulose nanofiber, sulfonated cellulose nanofiber, sodium cellulose sulfate, dialkyldimethylammonium sulfate cellulose and its derivatives such as cellulose acetate, crystalline cellulose, cellulose powder; starch-based polymers such as soluble starch, carboxymethyl starch, methyl hydroxypropyl starch, methyl starch, starch derivatives such as hydroxypropyltrimonium starch chloride, corn starch aluminum octenyl succinate; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyrrolidone (PVP), polyvinyl alcohol (PVA), vinylpyrrolidone-vinyl alcohol copolymer, polyvinyl methyl ether; polyethylene glycol, polypropylene glycol, polyoxyethylene-polyoxypropylene copolymer; amphoteric methacrylate copolymers such as (methacryloyloxyethyl carboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine oxide methacrylate) copolymer; (dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP;Partially saponified polyvinyl acetate, maleic acid copolymer; vinylpyrrolidone-dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; polyacrylamide; polyacrylic acid ester copolymers such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid-methacrylic acid ester copolymer; acrylic acid-alkyl methacrylate copolymer; cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride-acrylamide copolymer such as polyquaternium-7, acrylic acid-diallyldimethylammonium chloride copolymer such as polyquaternium-22, acrylic acid-diallyldimethylammonium chloride-acrylamide copolymer such as polyquaternium-39, acrylic acid-cationized methacrylic acid ester copolymer, acrylic acid-cationized methacrylic acid amide copolymer, acrylic acid-cationized methacrylic acid amide copolymer, acrylic acid-47 ... copolymer of methacrylic acid, methyl acrylate, methacrylamidopropyltrimethylammonium chloride, polymer of choline ester of methacrylic acid chloride; cationic oligosaccharides, cationic dextran, cationic polysaccharides such as guar hydroxypropyltrimonium chloride; polyethyleneimine; cationic polymers; polymers of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymers with butyl methacrylate copolymers; acrylic resin emulsions, polyethyl acrylate emulsions, polyacrylic alkyl ester emulsions, polyvinyl acetate resin emulsions, natural rubber latex, synthetic latex and other polymer emulsions; nitrocellulose; polyurethanes and various copolymers; various silicones; various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluorine-based polymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate;Preferred examples include anhydrous silicic acid, fumed silica (ultrafine particle anhydrous silicic acid), aluminum magnesium silicate, sodium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay minerals, sucrose fatty acid esters, and fructooligosaccharide fatty acid esters.

[0030] The antioxidants preferably include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or its derivatives; erythorbic acid and its derivatives; sulfites such as sodium sulfite; hydrogen sulfites such as sodium hydrogen sulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, and cysteine ​​hydrochloride. The reducing agents preferably include thioglycolic acid, cysteine, and cysteamine. The oxidizing agents preferably include hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate. Examples of antioxidants include ascorbic acid, ascorbic acid phosphate salts such as sodium ascorbic acid phosphate and magnesium ascorbic acid phosphate; ascorbic acid fatty acid esters such as monostearate ascorbic acid, monopalmitate ascorbic acid, dipalmitate ascorbic acid, and tetraisopalmitate ascorbic acid; ascorbic acid ethers such as 3-O-ethyl ascorbic acid, 2-O-ethyl ascorbic acid, cetyl ascorbic acid, glyceryl ascorbic acid, and hexylglyceryl ascorbic acid; ascorbic acid glucoside and its fatty acid esters such as ascorbic acid-2-glucoside; Preferred examples of the vitamin A derivatives include ascorbic acid derivatives such as tocopheryl ascorbyl phosphate and tocopheryl ascorbyl phosphate; vitamin A derivatives such as retinol, retinol acetate, retinol palmitate, and hydrogenated retinol; vitamin E derivatives such as tocopherol, tocopherol acetate, and tocotrienol; carotenoids such as carotene, lycopene, astaxanthin, and lutein; polyphenols such as phlorotannin, curcumin, anthocyanin, proanthocyanin, catechin, ellagic acid, quercetin, and apple polyphenol; coenzyme Q10, lipoic acid, lactoferrin, sesamin, hesperidin, protoanthocyanidin, lignan, chlorogenic acid, rutin, fullerene, and platinum nanocolloid.

[0031] Examples of the whitening agent include hydroquinone glycosides and esters thereof, such as arbutin and α-arbutin; ascorbic acid, ascorbic acid phosphate salts, such as sodium ascorbic acid phosphate and magnesium ascorbic acid phosphate; ascorbic acid fatty acid esters, such as ascorbic acid monostearate, ascorbic acid monopalmitate, ascorbic acid dipalmitate, and ascorbic acid tetraisopalmitate; ascorbic acid esters, such as 3-O-ethyl ascorbic acid, 2-O-ethyl ascorbic acid, cetyl ascorbic acid, glyceryl ascorbic acid, and hexylglyceryl ascorbic acid; ascorbic acid glucoside and its fatty acid esters, such as ascorbic acid sulfate and tocopheryl ascorbyl phosphate; tranexamic acid derivatives, such as tranexamic acid, cetyl tranexamate, and tranexamic acid amide; licorice extract-related substances, such as glabridin, glabrene, liquiritin, and isoliquiritin; and plant extracts, such as kojic acid, ellagic acid, ferulic acid and their derivatives, placenta extract, glutathione, oryzanol, butylresorcinol, oil-soluble chamomilla extract, oil-soluble licorice extract, Nishikawa willow extract, and saxifrage extract, are preferred.

[0032] Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, and retinol palmitate; vitamin B such as thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, flavin adenine dinucleotide, cyanocobalamin, folic acids, nicotinic acids such as nicotinamide and benzyl nicotinate, and choline; vitamin C such as ascorbic acid and its sodium salts; vitamin D; vitamin E such as α-, β-, γ-, and δ-tocopherol; other vitamins such as pantothenic acid and biotin; and vitamin B such as sodium ascorbic acid phosphate and magnesium ascorbic acid phosphate. Preferred examples of the compound include ascorbic acid phosphate salts, ascorbic acid fatty acid esters such as ascorbic acid tetraisopalmitate, ascorbyl stearate, ascorbyl palmitate, ascorbyl dipalmitate, etc., ascorbic acid alkyl ethers such as ascorbic acid ethyl ether, ascorbic acid glucoside and its fatty acid esters such as ascorbic acid-2-glucoside, and ascorbic acid derivatives such as tocopheryl ascorbyl phosphate; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol linoleate, tocopherol ferulate, tocopherol phosphate, etc., tocotrienol, and various other vitamin derivatives.

[0033] Plant, animal and microbial extracts include iris extract, angelica extract, asparagus extract, avocado extract, amacha extract, almond extract, althea extract, arnica extract, aloe extract, apricot extract, apricot kernel extract, ginkgo extract, inchiko extract, fennel extract, turmeric extract, oolong tea extract, uva-ursi extract, angelica extract, echinacea leaf extract, enmeiso extract, scutellaria extract, phellodendron bark extract, coptis extract, barley extract, ginseng extract, hypericum extract, and nettle extract. Sow extract, Ononis extract, Dutch mustard extract, Orange extract, Seawater dried product, Seaweed extract, Oyster leaf extract, Kakyoku extract, Hydrolyzed elastin, Hydrolyzed wheat powder, Hydrolyzed silk, Pueraria root extract, Chamomilla extract, Oil-soluble Chamomilla extract, Carrot extract, Artemisia capillaris extract, Oat extract, Karkade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Jew's ear extract, Cinchona extract, Cucumber extract, Paulownia leaf extract, Guanosine, Guava extract, Sophora root extract, Gardenia extract, Sasa veitchii extract, Sophora flavonoides extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar extract, chlorella extract, mulberry extract, gentiana extract, geranium extract, black tea extract, yeast extract, magnolia bark extract, coffee extract, burdock extract, rice extract, fermented rice extract, fermented rice bran extract, rice germ oil, comfrey extract, collagen, cowberry extract, Chinese laurel extract, bupleurum extract, umbilical cord extract, umbilical cord extract, saffron extract, salvia extract, soapwort extract, bamboo grass extract, hawthorn extract, sanschae Japanese flounder, Japanese pepper extract, shiitake mushroom extract, rehmannia extract, lithospermum extract, perilla extract, linden extract, meadowsweet extract, jatoba extract, peony extract, angelica extract, calamus root extract, white birch extract, white wood ear extract, horsetail extract, stevia extract, stevia fermentation product, Nishikawa willow extract, ivy extract, hawthorn extract, elderberry extract, yarrow extract, peppermint extract, sage extract, mallow extract, cnidium rhizome extract, swertia britannica extract, sophora japonica extract, rhubarb extract,Soybean extract, Chinese laurel extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, Imperata cylindrica extract, tangerine extract, tea tree oil, sweet tea extract, chili pepper extract, angelica extract, calendula extract, toad extract, spruce extract, dokudami extract, tomato extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, burdock extract, lotus extract, parsley extract, birch extract, honey, witch hazel extract, parietaria extract, yarrow extract, bisabolol, cypress extract, bifidobacteria extract, loquat extract, coltsfoot extract, butterbur bud extract, bupleurum extract, butcher's broom extract, grape extract, grape seed extract Preferred examples of the extract include whiting, propolis, loofah extract, safflower extract, peppermint extract, linden extract, peony extract, hop extract, squid extract, pine extract, horse chestnut extract, skunk cabbage extract, soapberry extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, saxifrage extract, yuzu extract, lily extract, coix seed extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, lychee extract, lettuce extract, lemon extract, forsythia extract, astragalus extract, rose extract, rosemary extract, Roman chamomile extract, royal jelly extract, and burnet extract.

[0034] Examples of ultraviolet absorbents include benzoic acid-based ultraviolet absorbents such as para-aminobenzoic acid, para-aminobenzoic acid monoglycerin ester, N,N-dipropoxy para-aminobenzoic acid ethyl ester, N,N-diethoxy para-aminobenzoic acid ethyl ester, N,N-dimethyl para-aminobenzoic acid ethyl ester, N,N-dimethyl para-aminobenzoic acid butyl ester, and N,N-dimethyl para-aminobenzoic acid ethyl ester; anthranilic acid-based ultraviolet absorbents such as homomenthyl-N-acetylanthranilate; salicylic acid-based ultraviolet absorbents such as salicylic acid and its sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, and p-isopropanol phenyl salicylate; octyl cinnamate, Cinnamic acid-based ultraviolet absorbers such as ethyl-4-isopropylcinnamate, methyl-2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2-ethylhexyl-p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (cinoxate), cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate (octocurin), glyceryl mono-2-ethylhexanoyl-di-paramethoxycinnamate, ferulic acid and its derivatives;Benzophenone UV absorbers such as 2,4-dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2',4,4'-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, and 4-hydroxy-3-carboxybenzophenone; 3-(4'-methylbenzylidene)-d,l-camphor, 3-benzylidene-d,l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole; 2-(2'-hydro 2-(2'-hydroxy-5'-methylphenylbenzotriazole;Dibenzalazine;Dianisoylmethane;5-(3,3-dimethyl-2-norbornylidene)-3-pentan-2-one;Dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane;Octyltriazone;Urocanic acid and ethyl urocanate derivatives; ... Preferred examples thereof include hydantoin derivatives such as 1-(3,4-dimethoxyphenyl)-4,4-dimethyl-1,3-pentanedione, dimethoxybenzylidene dioxoimidazolidinepropionate 2-ethylhexyl, phenylbenzimidazolazole sulfonic acid, terephthalidenedicamphor sulfonic acid, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, and oryzanol and its derivatives.

[0035] Antibacterial and preservative agents include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben, and butylparaben; phenoxyethanol; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, and 1,2-octanediol; alkyl glyceryl ethers such as 2-ethylhexylglyceryl ether (ethylhexylglycerin); salicylic acid; lanolin fatty acids and their salts; sodium benzoate; isothiazolinone derivatives such as methylchloroisothiazolinone and methylisothiazolinone; imidazolinium urea; dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, and quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, and benzalkonium chloride. Preferred examples of the antibacterial agent include phenyl ether, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, and hinokitiol; other phenols such as phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, and sodium phenylphenol; phenylethyl alcohol, photosensitizers, antibacterial zeolites, and silver ions. However, when used as an antibacterial agent or preservative for the purpose of preservation, it is more preferable to use phenoxyethanol; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, and 1,2-octanediol; and alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether, from the viewpoint of safety of the cosmetic or topical skin preparation.

[0036] Preferred examples of the chelating agent include edetates (ethylenediaminetetraacetates) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetates such as HEDTA3Na; pentetates (diethylenetriaminepentaacetate); phytic acid; phosphonic acids such as etidronic acid and salts thereof such as their sodium salts; sodium oxalate; polyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine, gluconic acid, ascorbic acid, succinic acid, and tartaric acid.

[0037] Preferred examples of the pH adjuster, acid, or alkali include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, sodium hydroxide, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate.

[0038] Solvents and propellants include lower alcohols such as ethanol, 2-propanol (isopropyl alcohol), butanol, and isobutyl alcohol; glycols such as propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, and isopentyl diol; diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, and diethylene glycol diethyl ether. Preferred examples of the propellant include glycol ethers such as propylene glycol monoethyl ether; glycol ether esters such as ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate, and propylene glycol monoethyl ether acetate; glycol esters such as diethoxyethyl succinate and ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate, acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbons, next-generation fluorocarbons; LPG, dimethyl ether, and carbon dioxide gas.

[0039] Examples of antipruritic agents include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, and substance-P inhibitors. Examples of keratin peeling and dissolving agents include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine, and glycolic acid. Examples of antiperspirants include aluminum chlorohydrate, aluminum chloride, zinc oxide, and zinc paraphenolsulfonate. Examples of cooling agents include menthol and methyl salicylate. Examples of astringents include citric acid, tartaric acid, lactic acid, aluminum potassium sulfate, tannic acid, and caffeine. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, and protease. Examples of nucleic acids include ribonucleic acid and its salts, deoxyribonucleic acid and its salts, and disodium adenosine triphosphate.

[0040] Preferred examples of the anti-inflammatory agent include glycyrrhizinic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid and its derivatives, azelaic acid and its derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; and plant extracts such as peach leaf extract and mugwort leaf extract. Preferred examples of hair growth agents, blood circulation promoters, and stimulants include plant extracts and tinctures such as Swertia japonica extract, Capsicum tincture, Ginger tincture, Ginger extract, and Cantharis tincture; capsaicin, nonylic acid valenylamide, zingerone, ichthammol, tannic acid, borneol, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, γ-oryzanol, cepharanthine, vitamin E, and derivatives such as tocopherol nicotinate and tocopherol acetate, γ-oryzanol, nicotinic acid, and derivatives such as nicotinamide, nicotinic acid benzyl ester, inositol hexanicotinate, and nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, flavanonol derivatives, stigmasterol or stigmastanol and its glycosides, and minoxidil. Preferred examples of hormones include estradiol, estrone, ethinylestradiol, cortisone, hydrocortisone, prednisone, and the like.

[0041] Anti-wrinkle and anti-aging agents include ascorbic acid, ascorbic acid phosphate salts such as sodium ascorbic acid phosphate and magnesium ascorbic acid phosphate; ascorbic acid fatty acid esters such as ascorbic acid monostearate, ascorbic acid monopalmitate, ascorbic acid dipalmitate, and ascorbic acid tetraisopalmitate; ascorbic acid ethers such as 3-O-ethyl ascorbic acid, 2-O-ethyl ascorbic acid, cetyl ascorbic acid, glyceryl ascorbic acid, and hexylglyceryl ascorbic acid; ascorbic acid glucoside and its fatty acid esters such as ascorbic acid 2-glucoside; and ascorbic acid derivatives such as ascorbic acid sulfate and tocopheryl ascorbyl phosphate. Preferred examples of the vitamin A derivatives include retinol, retinol acetate, retinol palmitate, and hydrogenated retinol; nicotinamide, glutathione, cysteine, crocetin, sericin, geraniol, glycerin glucoside, lactoferrin, proanthocyanin, pantothenic acid, panthenol, soybean saponin, revelastrol, isoflavone, coenzyme Q10, chondroitin sulfate, acetylglucosamine, glycerophosphatidylcholine, hydrolyzed hyaluronic acid, collagen peptide, conchiolin hydrolyzate, adenosine 5'-monophosphate, phosphatidylinositol, trifluoroisopropyloxopropylaminocarbonylpyrrolidinecarbonylmethylpropylaminocarbonylbenzoylaminoacetic acid Na, and tranexamic acid and derivatives thereof.

[0042] Preferred examples of the irritation alleviating agent include mannosylerythritol lipid, dimer dilinoleic acid diethylene glycol oligomer ester, diisostearyl malate, N-acyl-L-glutamic acid, trehalose mono fatty acid ester, fatty acid amidoamine oxide, alkyldimethylamine oxide, phenylethyl glucoside, lauryl glucoside, ferulic acid glucoside, salicin, cedrol, polyethylene glycol, polypropylene glycol, etc. Preferred examples of the cooling agent include menthol, camphor, menthyl lactate, monomenthyl succinate, menthyl acetate, borneol, cineol, thymol, peppermint oil, peppermint oil, and derivatives thereof. Preferred examples of the warming agent include vanillin and its derivatives, nonanoic acid vanillylamide, shogaol, gingerol, capsicum tincture, capsicum extract, nicotinic acid derivatives such as benzyl nicotinate, methyl nicotinate, phenyl nicotinate, and tocopherol nicotinate, capsaicin, watercress extract, Japanese pepper extract, ginger extract, and canthari extract.

[0043] Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, tungstate metal salts, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorapatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, Prussian blue, carbon black, titanium oxide, fine and ultrafine titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silicic anhydride), titanium mica. Preferred examples of the inorganic powders include inorganic powders of various sizes and shapes, such as fish scale foil, boron nitride, photochromic pigments, synthetic fluorine-containing mica, fine particle composite powders, gold, and aluminum, and inorganic powders which have been treated with silicones such as hydrogen silicone and cyclic hydrogen silicone, or other silanes, or various surface treatment agents such as titanium coupling agents to make them hydrophobic or hydrophilic; organic powders of various sizes and shapes, such as starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene-acrylic acid copolymer resin powder, polyester powder, benzoguanamine resin powder, polyethylene terephthalate-polymethyl methacrylate laminate powder, polyethylene terephthalate-aluminum-epoxy laminate powder, urethane powder, silicone powder, Teflon (registered trademark) powder, and surface-treated powders; and organic-inorganic composite powders.Preferred examples of the inorganic salts include sodium chloride-containing salts such as table salt, ordinary salt, rock salt, sea salt, and natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, aluminum / potassium sulfate (alum), aluminum / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, ferrous sulfate, and copper sulfate; and sodium phosphates such as 1Na / 2Na / 3Na phosphate, potassium phosphates, calcium phosphates, and magnesium phosphates.

[0044] Dyes, colorants, dyes and pigments include Brown No. 201, Black No. 401, Purple No. 201, Purple No. 401, Blue No. 1, Blue No. 2, Blue No. 201, Blue No. 202, Blue No. 203, Blue No. 204, Blue No. 205, Blue No. 403, Blue No. 404, Green No. 3, Green No. 201, Green No. 202, Green No. 204, Green No. 205, Green No. 3, Green No. 401, Green No. 402 No., Red No. 102, Red No. 104-1, Red No. 105-1, Red No. 106, Red No. 2, Red No. 3, Red No. 201, Red No. 202, Red No. 203, Red No. 204, Red No. 205, Red No. 206, Red No. 207, Red No. 208, Red No. 213, Red No. 214, Red No. 215, Red No. 218, Red No. 219, Red No. 220, Red No. 221, Red No. 223 , Red No. 225, Red No. 226, Red No. 227, Red No. 228, Red No. 230-1, Red No. 230-2, Red No. 231, Red No. 232, Red No. 3, Red No. 401, Red No. 40 No. 4, Red No. 405, Red No. 501, Red No. 502, Red No. 503, Red No. 504, Red No. 505, Red No. 506, Orange No. 201, Orange No. 203, Orange No. 204, Orange 20 Legal dyes such as No. 5, Orange 206, Orange 207, Orange 401, Orange 402, Orange 403, Yellow 201, Yellow 202-1, Yellow 202-2, Yellow 203, Yellow 204, Yellow 205, Yellow 4, Yellow 401, Yellow 402, Yellow 403-1, Yellow 404, Yellow 405, Yellow 406, Yellow 407, Yellow 5, etc.; Acid Other acid dyes such as Red 14; basic dyes such as Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow; nitro dyes such as HC Yellow 2, HC Yellow 5, HC Red 3, 4-hydroxypropylamino-3-nitrophenol, N,N'-bis(2-hydroxyethyl)-2-nitro-p-phenylenediamine, HC Blue 2, Basic Blue 26; disperse dyes; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (red iron oxide) and iron titanate; inorganic brown pigments such as gamma-iron oxide; inorganic yellow pigments such as yellow iron oxide and ochre; inorganic black pigments such as black iron oxide and low-order titanium oxide;Inorganic purple pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide, and cobalt titanate; inorganic blue pigments such as ultramarine and Prussian blue; pearl pigments such as titanium dioxide coated mica, titanium dioxide coated bismuth oxychloride, titanium dioxide coated talc, colored titanium dioxide coated mica, bismuth oxychloride, and fish scale foil; metal powder pigments such as aluminum powder, copper powder, and gold; anthraquinones such as astaxanthin and alizarin, anthocyanidins, β-carotene, catenal, capsanthin, chalcone, carthamine, and quercetin. Preferred examples of such dyes include naphthoquinones such as tin, crocin, chlorophyll, curcumin, cochineal, and shikonin, bixin, flavones, betacyanidin, henna, hemoglobin, lycopene, riboflavin, and rutin; oxidation dye intermediates and couplers such as p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylenediamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine, and salts thereof; autoxidation dyes such as indoline; and dihydroxyacetone.

[0045] Fragrances include acetyl cedrene, amyl cinnamaldehyde, allyl amyl glycolate, β-ionone, isoe-super, isobutylquinoline, iris oil, iron, indole, ylang-ylang oil, undecanal, undecenal, γ-undecalactone, estragole, eugenol, oakmoss, opoponax resinoid, orange oil, eugenol, aurantiol, galacsolid, carvacrol, L-carvone, camphor, canon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile, isobornyl acetate, geranyl acetate, dimethylbenzylcarbinyl acetate, styralyl acetate, cedryl acetate, terpinel acetate, pt-butylcyclohexyl acetate. , vetiveryl acetate, benzyl acetate, linalyl acetate, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamen aldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromyrcenol, jasmine absolute, jasmine lactone, cis-jasmone, citral, citronenol, citronellal, cinnamon bark oil, 1,8-cineole, cinnamaldehyde, styrax resinoids, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascone, damascenone, thymol, tuberose absolute, decanal, decalactone, terpineol, gamma-terpinene, triplal, nerol, nonanal, 2,6-Nonadienol, Nonalactone, Patchouli Alcohol, Vanilla Absolute, Vanillin, Basil Oil, Patchouli Oil, Hydroxycitronellal, Alpha-Pinene, Piperitone, Phenethyl Alcohol, Phenylacetaldehyde, Petitgrain Oil, Hexylcinnamaldehyde, cis-3-Hexenol, Balsam of Peru, Vetiver Oil, Vetiverol, Peppermint Oil, Pepper Oil, Heliotropin, Bergamot Oil, Benzyl Benzene Preferred examples of the synthetic and natural fragrances include maltitol, borneol, myrrhizinoid, musk ketone, methylnonylacetaldehyde, γ-methylionone, menthol, L-menthol, L-menthone, eucalyptus oil, β-ionone, lime oil, lavender oil, D-limonene, linalool, lyral, lilial, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, and various essential oils, as well as various blended fragrances.

[0046] Preferred examples of water include ordinary water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionized water, and cluster water.

[0047] In addition to the above, it is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc. in known combinations, ratios, and amounts, such as ingredients listed in the Cosmetic Raw Materials Standards, Cosmetic Type Ingredient Standards, Japan Cosmetic Industry Association Ingredient Labeling Name List, INCI Dictionary (The International Cosmetic Ingredient Dictionary and Handbook), Quasi-drug Raw Materials Standards, Japanese Pharmacopoeia, Pharmaceutical Additives Standards, Food Additives Official Compendium, etc., and ingredients listed in Japanese and foreign patent gazettes and patent publications (including published gazettes and republications) that belong to the International Patent Classification IPC classifications A61K7 and A61K8.

[0048] The types of the skin cleanser composition of the present invention include facial cleansers such as paste cleanser, gel cleanser, foam cleanser, mist cleanser, spray cleanser, etc., cleansing agents such as cleansing foam, cleansing cream, cleansing milk, cleansing lotion, cleansing gel, etc., body cleansers such as body shampoo, body soap, etc., scalp cleansers such as scalp cleanser, scalp shampoo, etc. The skin cleanser composition of the present invention can be produced according to a conventional method.

[0049] The skin cleansing composition of the present invention may be preferably in the form of a liquid, gel, paste, sheet, mist, spray or the like.

[0050] The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples in any way.

[0051] Skin cleansing compositions of the present invention (Examples 1 to 5) and comparative skin cleansing compositions (Comparative Examples 1 and 2) were prepared according to the compositions shown in Table 1. The cleansing power of the obtained skin cleansing compositions was evaluated by the following method. The obtained results are shown in the lower part of Table 1. <Method for preparing skin cleansing composition> A polyhydric alcohol liquid was prepared in advance by mixing components (A) and (B) with stirring at 70° C. The obtained polyhydric alcohol liquid was added to an aqueous solution of phenoxyethanol and component (C) that had been dissolved in advance while stirring, and the mixture was stirred with a homomixer (50° C., 5000 rpm, 5 minutes) and cooled. <How to evaluate cleaning power> The following lipstick formulation was applied to artificial leather (Suprare: manufactured by Idemitsu Technofine Co., Ltd.) (application area: 1 cm x 1 cm). 50 μL of the skin cleanser composition was dropped onto the application site, and the skin was rubbed with a finger 20 times at a speed of once per second. After thoroughly rinsing with water, the degree of removal of the lipstick was visually observed, and the cleaning power was evaluated according to the following evaluation criteria. Evaluation criteria ◎: Very well removed 〇: Well removed △: A little removed ×: Almost no removal Lipstick formula Component Amount (mass%) ------------------------------------- Triethylhexanoin 80.89 Polyethylene, microcrystalline wax mixture 17.00 Methylparaben 0.20 BHT 0.01 Red 202 2.00 -------------------------------------

[0052] [Table 1]

[0053] From the results in Table 1, it was confirmed that the skin cleansing composition of the comparative example containing only component (A1) or component (A2) hardly removed lipstick, whereas the skin cleansing composition of the present invention containing components (A1) and (A2) was able to remove lipstick. Therefore, it was found that the skin cleansing composition of the present invention exhibits excellent detergency by using a combination of components (A1) and (A2).

[0054] The following skin cleansing agents were prepared. The obtained skin cleansing agents have excellent cleansing power and provide a moist feeling after cleansing. In particular, the wipe-off lotion provides skin care effects such as moisturizing effect and barrier function improvement effect.

[0055] Example 6 Cleansing Lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.2 Mannosylerythritol lipid (MEL-B) 0.8 Tocopherol 0.1 Glycerin 3.0 1,3-Butylene glycol 6.0 Part B Neosolue-Aqulio (Nippon Fine Chemicals) 1.0 Inulin-SC (Nippon Fine Chemical) 1.0 Phenoxyethanol 0.4 Purified water (total amount is 100) -------------------------------------- (Preparation method) Part A and Part B were each heated to 70°C, and Part A was added to Part B while stirring with a homomixer (7000 rpm), followed by cooling to room temperature.

[0056] Example 7 Cleansing Lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 1.6 Mannosylerythritol lipid (MEL-B) 0.4 1,2-Pentanediol 2.0 Dipropylene glycol 4.0 Part B Ethanol 10.0 Phenoxyethanol 0.4 Purified water (total amount is 100) -------------------------------------- (Preparation method) Part A and Part B were each heated to 70°C, and Part A was added to Part B while stirring with a homomixer (7000 rpm), followed by cooling to room temperature.

[0057] Example 8 Cleansing Lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 2.0 Mannosylerythritol lipid (MEL-B) 8.0 Dipropylene glycol 20.0 Part B Purified water (total amount is 100) C part Propylene glycol 10.0 PEG-20 Glyceryl Triisostearate 20.0 PEG-20 Glyceryl Isostearate 8.0 Citric acid 0.2 Sodium citrate 0.1 EDTA-2Na 0.1 Methylparaben 0.1 Purified water 30.0 -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0058] Example 9 Cleansing Lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.2 Mannosylerythritol lipid (MEL-B) 0.8 Ceramide 1 0.01 Ceramide 2 0.01 Ceramide 3 0.01 Ceramide 4 0.01 Ceramide 5 0.01 Ceramide 6 0.01 BG 10.0 Part B Purified water (total amount is 100) C part (Caprylic / Capric) PEG-6 Glycerides 10.0 Inulin-SC (Nippon Fine Chemical) 2.0 Xylitol 0.2 EDTA-2Na 0.1 Methylparaben 0.1 Purified water 30.0 -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0059] Example 10 Cleansing Lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.1 Mannosylerythritol lipid (MEL-B) 0.9 1,2-Hexanediol 2.0 Part B Purified water (total amount is 100) C part Dipropylene glycol 10.0 PEG-20 Glyceryl Triisostearate 15.0 PEG-20 Glyceryl Isostearate 6.0 Coconut oil fatty acid PEG-7 glyceryl 3.0 Dipotassium glycyrrhizinate 0.1 EDTA-2Na 0.1 Purified water 30.0 -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0060] Example 11 Cleansing Lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.3 Mannosylerythritol lipid (MEL-B) 0.7 Propylene glycol 6.0 Part B Purified water (total amount is 100) C part Sodium Lauroyl Methylalanine 10.0 PEG-60 Hydrogenated Castor Oil 2.0 EDTA-2Na 0.1 Ethanol 10.0 Purified water 30.0 -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0061] Example 12 Cleansing Lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.8 Mannosylerythritol lipid (MEL-B) 0.2 Propanediol 5.0 Part B Purified water (total amount is 100) C part Glycerin 10.0 Polyglyceryl-5 Oleate 8.0 Polyglyceryl-10 Trilaurate 4.0 Methylparaben 0.1 Purified water 30.0 -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0062] Example 13 Cleansing gel Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.6 Mannosylerythritol lipid (MEL-B) 0.4 1,3-Butylene glycol 10.0 Part B Purified water (total amount is 100) C part Glycerin 10.0 Polyglyceryl-6 Caprate 8.0 Polyglyceryl-6 Dicaprate 8.0 Polyglyceryl-10 Dimyristate 1.0 (Acrylates / Alkyl acrylate (C10-30)) Crosspolymer (2% aqueous solution) 10.0 Potassium hydroxide 0.1 EDTA-2Na 0.1 Methylparaben 0.1 Purified water 30.0 -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0063] Example 14 Cleansing gel Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.4 Mannosylerythritol lipid (MEL-B) 0.4 1,2-Pentanediol 2.0 Glycerin 5.0 1,3-Butylene glycol 5.0 Part B Purified water (total amount is 100) C part Carbomer (2% aqueous solution) 10.0 Potassium hydroxide 0.1 --------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0064] Example 15 Cleansing gel Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.4 Mannosylerythritol lipid (MEL-B) 1.6 1,2-Pentanediol 1.0 1,3-Butylene glycol 15.0 Part B Phenoxyethanol 0.5 Purified water (total amount is 100) C part Neosolue-Aqulio (Nippon Fine Chemicals) 0.5 Polyglyceryl-10 Myristate 2.0 Lauramidopropyl betaine (30% aqueous solution) 6.0 Sodium Lauryl Glycol Carboxylate 2.0 (Acrylates / Alkyl acrylate (C10-30)) Crosspolymer (2% aqueous solution) 10.0 Potassium hydroxide 0.1 --------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0065] Example 16 Cleansing gel Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.3 Mannosylerythritol lipid (MEL-B) 0.8 Phytosterols 0.05 1,2-Pentanediol 5.0 Part B Purified water 5.0 C part Inulin-SC (Nippon Fine Chemical) 0.5 Glycerin - total amount is 100 Polyglyceryl-10 Isostearate 15.0 --------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part C was heated to about 70°C and mixed until uniform, then cooled. Part A was gradually added to part B while stirring, and after mixing, cooled to 40°C. Part C was added and stirred until uniform.

[0066] Example 17 Cleansing gel Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 1.0 Mannosylerythritol lipid (MEL-B) 1.0 1,2-Hexanediol 3.0 Part B Purified water 5.0 C part Glycerin - total amount is 100 Coconut oil fatty acid PEG-7 glyceryl 15.0 --------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part C was mixed. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0067] Example 18 Cleansing Cream Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.1 Mannosylerythritol lipid (MEL-B) 0.9 1,3-Butylene glycol 5.0 Part B Purified water 30.0 C part Plandool-LG1 (Nippon Fine Chemicals) 0.3 Plandool-LG2 (Nippon Fine Chemicals) 0.3 Plandool-LG3 (Nippon Fine Chemicals) 0.3 Plandool-LG4 (Nippon Fine Chemicals) 0.3 Plandool-H (Nippon Fine Chemical) 0.3 Plandool-G (Nippon Fine Chemical) 0.3 Plandool-ISS (Nippon Fine Chemical) 0.3 Plandool-SUN (Nippon Fine Chemical) 0.3 Plandool-MAS (Nippon Fine Chemicals) 0.3 Neosolue-Aqulio (Nippon Fine Chemicals) 1.0 Ceresin 6.0 PEG-12 Isostearate 3.0 Sorbitan Sesquioleate 1.5 Polyoxyethylene sorbitan oleate 0.3 Polyglyceryl-10 Laurate 0.3 Microcrystalline Wax 2.0 Tocopherol 0.05 D part Neosolue-Aqua (Nippon Fine Chemical) 0.5 Dipropylene glycol 5.0 Disodium edetate 0.02 Phenoxyethanol 0.5 Purified water (total amount is 100) --------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and cooled (part E). Part C was heated to about 80°C and dissolved. Part D was heated to about 80°C. Part D was gradually added to part C while stirring, and after mixing, cooled to 40°C, part E was added and mixed.

[0068] Example 19: Cleansing lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.05 Mannosylerythritol lipid (MEL-B) 0.05 Glucosylceramide 0.5 Glycerin 3.0 1,3-Butylene glycol 6.0 Part B Purified water (total amount is 100) C part Tremoist-SL (Nippon Fine Chemicals) 1.0 Inulin-SC (Nippon Fine Chemical) 1.0 Dipotassium glycyrrhizinate 0.01 Isopropyl methylphenol 0.1 Methylparaben 0.1 Purified water 20.0 -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and cooled (part D). Part C was heated to about 80°C and dissolved, then cooled to 40°C, and part D was added and mixed.

[0069] Example 20: Cleansing lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.02 Mannosylerythritol lipid (MEL-B) 0.08 Coenzyme Q10 0.01 Ceramide 3 0.1 Ceramide 6 0.05 1,2-Pentanediol 2.0 Part B Purified water (total amount is 100) C part PrimeLipid ALPA (Nippon Fine Chemical) 1.0 Methylgluceth-10 1.0 Trehalose 1.0 Panax ginseng root extract 0.01 Serine 0.01 Glycine 0.01 Alanine 0.01 Glutamic acid 0.01 Threonine 0.01 L-Cysteine ​​hydrochloride 0.05 Lactic acid 0.2 Purified water 20.0 -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and cooled (part D). Part C was heated to about 80°C and dissolved, then cooled to 40°C, and part D was added and mixed.

[0070] Example 21 Cleansing lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.05 Mannosylerythritol lipid (MEL-B) 0.08 Astaxanthin 0.01 Oryzanol 0.3 Propylene glycol 3.0 1,3-Butylene glycol 5.0 Part B Purified water (total amount is 100) C part Arbutin 3.0 Hydrolyzed collagen 0.01 PEG / PPG / Polybutylene Glycol-8 / 5 / 3 Glycerin 1.0 Rice bran extract 0.01 Apricot juice 0.01 Polyquaternium-51 0.1 Ethylhexylglycerin 0.3 Purified water 20.0 -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and cooled (part D). Part C was heated to about 80°C and dissolved, then cooled to 40°C, and part D was added and mixed.

[0071] Example 22 Cleansing lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.05 Mannosylerythritol lipid (MEL-B) 0.25 Xanthophyll 0.01 1,2-Pentanediol 2.0 Part B Sodium Hyaluronate 0.001 Neosolue-Aqua (Nippon Fine Chemical) 0.5 Tremoist-TP (Nippon Fine Chemical) 0.02 Neosolue-Aqulio (Nippon Fine Chemicals) 0.5 3-O-Ethyl ascorbic acid (Nippon Fine Chemicals) 1.0 Tranexamic acid (Nippon Fine Chemicals) 1.0 Nicotinamide 5.0 Xanthan gum 0.1 Purified water (total amount is 100) -------------------------------------- (Preparation method) Part A and Part B were each heated to 70°C, and Part A was added to Part B while stirring with a homomixer (7000 rpm), followed by cooling to room temperature.

[0072] Example 23: Cleansing lotion Component Amount (wt%) -------------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.05 Mannosylerythritol lipid (MEL-B) 0.25 Xanthophyll 0.01 1,2-Pentanediol 1.0 1,3-Butylene glycol 3.0 Glycerin 1.0 Part B Tranexamic acid (Nippon Fine Chemicals) 2.0 Tocopherol Nicotinate 0.5 Allantoin 1.0 Tremoist-TP (Nippon Fine Chemical) 0.01 Hydrolyzed collagen 0.01 (PEG-240 / Decyltetradeceth-20 / HDI) Copolymer 0.05 (Acrylates / Alkyl acrylate (C10-30)) Crosspolymer 0.15 Arginine 0.25 Phosphorylated Cellulose Nanofiber 5.0 (AuroVisco CS manufactured by Oji Holdings) Betaine 1.0 Pullulan 0.2 Xanthan gum 0.1 Purified water (total amount is 100) -------------------------------------- (Preparation method) Part A and Part B were each heated to 70°C, and Part A was added to Part B while stirring with a homomixer (7000 rpm), followed by cooling to room temperature.

[0073] Example 24 Facial cleansing foam Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.5 Mannosylerythritol lipid (MEL-B) 0.4 Phytosterols 0.05 Ceramide 2 0.01 Ceramide 3 0.01 Ceramide 6 0.01 Glycerin 3.0 1,3-Butylene glycol 6.0 Part B Purified water 30.0 C part (Coconut fatty acid / hydrogenated beef tallow fatty acid) Sodium glutamate 30.0 Potassium Cocoyl Glycine 5.0 Plandool-LG2 (Nippon Fine Chemicals) 0.2 Lauric acid diethanolamide 3.0 Glyceryl stearate (SE) 0.5 Tocopherol 0.1 PEG-8 5.0 PEG-32 10.0 Glycerin 14.0 D part Glyceryl Caprylate 1.0 Hexanediol 1.0 Polyquaternium-51 1.0 Tremoist-SL (Nippon Fine Chemicals) 0.5 Crystalline cellulose 0.3 Polyquaternium-7 0.8 Purified water (total amount is 100) --------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and cooled (part E). Part C was heated to about 80°C and dissolved. Part D was heated to about 80°C. Part D was gradually added to part C while stirring, and after mixing, cooled to 40°C, part E was added and mixed.

[0074] Example 25 Facial cleansing foam Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.4 Mannosylerythritol lipid (MEL-B) 0.2 Thioctic acid 0.01 Ubiquinone 0.01 1,3-Butylene glycol 10.0 Part B Purified water 30.0 C part Lauric Acid 5.0 Myristic acid 12.0 Stearic acid 14.0 Plandool-LG2 (Nippon Fine Chemicals) 0.2 PEG-400 5.0 Glyceryl stearate 1.0 Glycerin 14.0 D part Potassium hydroxide 7.0 Polyquaternium-51 1.0 Tremoist-SL (Nippon Fine Chemicals) 0.5 Polyquaternium-7 0.8 Purified water (total amount is 100) --------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and cooled (part E). Part C was heated to about 80°C and dissolved. Part D was heated to about 80°C. Part D was gradually added to part C while stirring, and after mixing, cooled to 40°C, part E was added and mixed.

[0075] Example 26 Body Shampoo Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.4 Mannosylerythritol lipid (MEL-B) 0.8 Phytosphingosine 0.01 Glycerin 10.0 1,3-Butylene glycol 5.0 Part B Purified water 40.0 C part Sodium Methyl Cocoyl Taurate 10.0 Sodium Lauroyl Hydrolyzed Silk 6.0 Sodium Lauroyl Methylalanine 10.0 Sodium cocoamphoacetate (30%) 4.0 Cocamidopropyl Betaine (30%) 10.0 Olefin (C14-16) Sodium Sulfonate 5.0 Polyquaternium-10 1.3 Guar Hydroxypropyltrimonium Chloride 0.8 Sodium acetylated hyaluronate 0.02 Cocamide DEA 3.0 Glycerin 5.0 Methylparaben 0.2 Purified water (total amount is 100) --------------------------------- (Preparation method) Part A was heated to about 70° C. and dissolved. Part B was heated to about 70° C. Part A was gradually added to part B while stirring, and cooled (part D). Part D was added to part C, and mixed.

[0076] Example 27 Body Shampoo Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.2 Mannosylerythritol lipid (MEL-B) 0.6 Glycerin 4.0 1,3-Butylene glycol 4.0 Part B Purified water 40.0 C part Lauric Acid 5.0 Myristic acid 10.0 Stearic acid 1.0 Glycol distearate 1.5 Sodium Laureth Sulfate 5.0 Cocamide DEA 3.0 Glycerin 5.0 D part Potassium hydroxide 4.0 Purified water (total amount is 100) --------------------------------- (Preparation method) Part C was dissolved by heating to about 80° C. Part D was heated to about 80° C. Part D was gradually added to part C while stirring, and after mixing, cooled to 40° C. Part E was added and mixed.

[0077] Example 28 Scalp Shampoo Component Amount (wt%) --------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.05 Mannosylerythritol lipid (MEL-B) 0.05 Propanediol 5.0 Part B Purified water 30.0 C part Plandool-LG2 (Nippon Fine Chemicals) 0.03 Neosolue-AquaS (Nippon Fine Chemical) 0.1 Tremoist-SL (Nippon Fine Chemicals) 0.5 Sodium Laureth-4 Carboxylate (28%) 10.0 Laureth-6 Carboxylic Acid 4.0 Cocamidopropyl Betaine (30%) 10.0 Lauryl Betaine 3.0 Sodium Lauroyl Methylalanine (30%) 5.0 Cocamide methyl MEA 3.0 Coconut oil fatty acid PEG-7 glyceryl 5.0 Sodium hydroxide 1% solution 0.5 Polyquaternium-10 0.8 Glycol distearate 0.5 Polyquaternium-7 0.5 EDTA-2Na 0.05 Phenoxyethanol 0.4 Sodium benzoate 0.2 Purified water (total amount is 100) --------------------------------- (Preparation method) Part A was heated to about 70° C. and dissolved. Part B was heated to about 70° C. Part A was gradually added to part B while stirring, and cooled (part D). Part D was added to part C, and mixed.

[0078] Example 29 Scalp Shampoo Component Amount (wt%) ------------------------------------ Part A Hydrogenated lecithin (PC content 50-75%) 0.03 Mannosylerythritol lipid (MEL-B) 0.09 Cholesterol 0.01 1,3-Butylene glycol 8.0 Part B Purified water 30.0 C part Sodium Lauroyl Methylalanine (30%) 13.0 Cocamidopropyl Betaine (30%) 20.0 TEA-Cocoyl Glutamate (30%) 5.0 Cocamide DEA 1.0 Glycerin 1.0 Glyceryl Caprylate 0.4 Glyceryl Undecylenate 0.1 Neosolue-AquaS (Nippon Fine Chemical) 1.0 Sorbitol 1.6 Miconazole nitrate 0.75 Glycol distearate 1.5 Ercalactone DES 0.2 Polyquaternium-7 0.3 D part NanoRepair-CMC5 (Nippon Fine Chemical) 5.0 NanoRepair-EL (Nippon Fine Chemical) 1.0 Sodium benzoate 0.4 Sodium chloride 0.2 Purified water (total amount is 100) Part E Swertia japonica extract 3.0 Polyquaternium-10 0.2 Guar Hydroxypropyltrimonium Chloride 0.1 Polyquaternium-47 0.1 Piroctone Olamine 0.1 Purified water 9.7 ------------------------------------ (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and cooled (part F). Mixed. Part D was heated to about 80°C and dissolved uniformly. Part C was placed in a separate container, heated, and dissolved. Part D was gradually added to part C, mixed uniformly, and parts E and F were added at about 40°C.

[0079] Example 30 Hand soap Component Amount (wt%) -------------------------------- Part A Hydrogenated lecithin (PC content 50-75%) 0.1 Mannosylerythritol lipid (MEL-B) 0.2 Glycerin 2.0 1,3-Butylene glycol 3.0 Part B Purified water 20.0 C part Sodium cocoyl isethionate 1.0 Glycerin 10.0 Sodium Lauroyl Sarcosine 12.0 Sodium myristoyl methyl taurate 2.0 Polyglyceryl-6 Laurate 2.0 Coconut oil fatty acid diethanolamide 2.0 PEG-7 Cocoyl Glyceryl 2.0 Sorbitol 8.0 Hydrolyzed conchiolin protein 0.1 1,3-Butylene glycol 8.0 Phenoxyethanol 0.8 Ethanol 3.0 Purified water (total amount is 100) --------------------------------- (Preparation method) Part A was heated to about 70° C. and dissolved. Part B was heated to about 70° C. Part A was gradually added to part B while stirring, and cooled (part D). Part D was added to part C, and mixed.

[0080] Example 31 Cleansing Lotion Component Amount (wt%) -------------------------------------- Part A Phytopresome MEL (Nippon Fine Chemicals) 1.0 1,2-Pentanediol 2.0 Dipropylene glycol 10.0 Part B Ethanol 10.0 Neosolue-Aqulio (Nippon Fine Chemicals) 1.0 Methylparaben 0.1 Purified water (total amount is 100) -------------------------------------- (Preparation method) Part A and Part B were each heated to 70°C, and Part A was added to Part B while stirring with a homomixer (7000 rpm), followed by cooling to room temperature.

[0081] Example 32 Cleansing Lotion Component Amount (wt%) -------------------------------------- Part A Phytopresome MEL (Nippon Fine Chemicals) 5.0 1,2-Hexanediol 2.0 Part B Purified water (total amount is 100) C part DPG 10.0 PEG-20 Glyceryl Triisostearate 7.0 PEG-20 Glyceryl Isostearate 4.0 Coconut oil fatty acid PEG-7 glyceryl 2.0 Polyglyceryl-10 Pentaoleate 1.0 Polyglyceryl-10 Distearate 0.5 EDTA-2Na 0.1 Purified water 30.0 -------------------------------------- (Preparation method) Part A was heated to about 50°C and dissolved. Part B was heated to about 50°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0082] Example 33 Cleansing gel Component Amount (wt%) -------------------------------------- Part A Phytopresome MEL (Nippon Fine Chemicals) 5.0 Part B Purified water 20.0 C part Glycerin 10.0 Polyglyceryl-6 Caprate 8.0 Polyglyceryl-6 Dicaprate 8.0 Polyglyceryl-10 Dimyristate 1.0 Polyglyceryl-10 Stearate 1.0 (Acrylates / Alkyl acrylate (C10-30)) Crosspolymer (2% aqueous solution) 10.0 Potassium hydroxide 0.1 EDTA-2Na 0.1 Methylparaben 0.1 Purified water (total amount is 100) -------------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and after mixing, it was cooled to 40°C. Part C was added and stirred until it was uniform.

[0083] Example 34: Cleansing lotion Component Amount (wt%) -------------------------------------- Part A Phytopresome MEL (Nippon Fine Chemicals) 1.5 1,2-Pentanediol 2.0 Part B Sodium Hyaluronate 0.001 Neosolue-Aqua (Nippon Fine Chemical) 0.5 Tremoist-TP (Nippon Fine Chemical) 0.02 Neosolue-Aqulio (Nippon Fine Chemicals) 0.5 3-O-Ethyl ascorbic acid (Nippon Fine Chemicals) 2.0 Tranexamic acid (Nippon Fine Chemicals) 2.0 Nicotinamide 5.0 Xanthan gum 0.1 Purified water (total amount is 100) -------------------------------------- (Preparation method) Part A and Part B were each heated to 70°C, and Part A was added to Part B while stirring with a homomixer (7000 rpm), followed by cooling to room temperature.

[0084] Example 35 Facial cleansing foam Component Amount (wt%) --------------------------------- Part A Phytopresome MEL (Nippon Fine Chemicals) 10.0 1,3-Butylene glycol 10.0 Part B Purified water 30.0 C part Lauric Acid 3.0 Myristic Acid 7.0 Stearic acid 10.0 Plandool-LG2 (Nippon Fine Chemicals) 0.2 PEG-400 5.0 Glyceryl stearate 1.0 Neosolue-DiSM (Nippon Fine Chemicals) 0.5 Glycerin 14.0 D part Potassium hydroxide 7.0 Polyquaternium-51 1.0 Tremoist-SL (Nippon Fine Chemicals) 0.5 Polyquaternium-7 0.8 Purified water (total amount is 100) --------------------------------- (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and cooled (part E). Part C was heated to about 80°C and dissolved. Part D was heated to about 80°C. Part D was gradually added to part C while stirring, and after mixing, cooled to 40°C, part E was added and mixed.

[0085] Example 36 Body Shampoo Component Amount (wt%) --------------------------------- Part A Phytopresome MEL (Nippon Fine Chemicals) 3.5 Part B Purified water 40.0 C part Lauric Acid 5.0 Myristic acid 10.0 Stearic acid 1.0 Glycol distearate 1.5 Sodium Laureth Sulfate 5.0 Cocamide DEA 3.0 Sodium Laureth Sulfate 5.0 Glycerin 5.0 D part Potassium hydroxide 4.0 Purified water (total amount is 100) --------------------------------- (Preparation method) Part C was dissolved by heating to about 80° C. Part D was heated to about 80° C. Part D was gradually added to part C while stirring, and after mixing, cooled to 40° C. Part E was added and mixed.

[0086] Example 37 Scalp Shampoo Component Amount (wt%) ------------------------------------ Part A Phytopresome MEL (Nippon Fine Chemicals) 7.0 Part B Purified water 30.0 C part Dipotassium glycyrrhizinate 0.2 Isopropyl methylphenol 0.5 Miconazole nitrate 1.0 Sodium Lauroyl Methylalanine (30%) 13.0 Cocamidopropyl Betaine (30%) 20.0 TEA-Cocoyl Glutamate (30%) 5.0 Cocamide DEA 1.0 Glycerin 1.0 Glyceryl Caprylate 0.4 Glyceryl Undecylenate 0.1 Neosolue-AquaS (Nippon Fine Chemical) 1.0 Sorbitol 1.6 Miconazole nitrate 0.75 Glycol distearate 1.5 Ercalactone DES 0.2 Polyquaternium-7 0.3 D part Sodium benzoate 0.4 Sodium chloride 0.2 Purified water (total amount is 100) Part E Swertia japonica extract 3.0 Polyquaternium-10 0.2 Guar Hydroxypropyltrimonium Chloride 0.1 Polyquaternium-47 0.1 Piroctone Olamine 0.1 Purified water 9.7 ------------------------------------ (Preparation method) Part A was heated to about 70°C and dissolved. Part B was heated to about 70°C. Part A was gradually added to part B while stirring, and cooled (part F). Mixed. Part D was heated to about 80°C and dissolved uniformly. Part C was placed in a separate container, heated, and dissolved. Part D was gradually added to part C, mixed uniformly, and parts E and F were added at about 40°C.

[0087] Example 38 Hand soap Component Amount (wt%) -------------------------------- Part A Phytopresome MEL (Nippon Fine Chemicals) 3.0 Part B Purified water 20.0 C part Sodium cocoyl isethionate 1.0 Glycerin 10.0 Sodium Lauroyl Sarcosine 12.0 Sodium myristoyl methyl taurate 2.0 Polyglyceryl-6 Laurate 2.0 Coconut oil fatty acid diethanolamide 2.0 PEG-7 Cocoyl Glyceryl 2.0 Sorbitol 8.0 Hydrolyzed conchiolin protein 0.1 1,3-Butylene glycol 8.0 Phenoxyethanol 0.8 Ethanol 3.0 Purified water (total amount is 100) --------------------------------- (Preparation method) Part A was heated to about 70° C. and dissolved. Part B was heated to about 70° C. Part A was gradually added to part B while stirring, and cooled (part D). Part D was added to part C, and mixed.

[0088] In the above formulation, details of the ingredients listed by product name are as follows: Plandool-H: Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl) Plandool-G: Dimer dilinoleyl bis(behenyl / isostearyl / phytosteryl) dimer dilinoleate Plandool-ISS: Phytosteryl isostearate Plandool-SUN: Sunflower seed oil fatty acid phytosteryl Plandool-MAS: Phytosteryl macadamiate 〇Plandool-LG1: Lauroyl glutamate di(phytosteryl / octyldodecyl / behenyl) Plandool-LG2: Di(phytosteryl / octyldodecyl) lauroyl glutamate 〇Plandool-LG3: Lauroyl glutamate di(phytosteryl / octyldodecyl / behenyl) 〇Plandool-LG4: Lauroyl glutamate di(phytosteryl / octyldodecyl / behenyl) NanoRepair-CMC5: Water, ceramide 1, ceramide 2, ceramide 3, ceramide 5, ceramide 6, cholesterol, quaternium-33, etc. NanoRepair-EL: Water, gamma-docosalactone, soybean sterol, etc. Neosolue-Aqulio: bisethoxydiglycol cyclohexanedicarboxylate Neosolue-Aqua: Polyglyceryl-10 (eicosane diacid / tetradecanedioic acid), glycerin Neosolue-AquaS: Polyglyceryl-10 (eicosane diacid / tetradecanedioic acid), glycerin PrimeLipid ALPA: Lysophosphatidic acid, lysolecithin, glycerin, water, aluminum hydroxide Phytopresome MEL: Hydrogenated lecithin, MEL-B, BG, glycerin Tremoist-TP: Tremella fuciformis polysaccharide Tremoist-SL: Tremella fuciformis polysaccharide aqueous solution (1%) 〇Inulin-SC: Inulin Erucalactone DES: γ-docosalactone, diethyl sebacate

Claims

1. A skin cleansing composition comprising the following components (A) to (C), in which the mass ratio of components (A1) to (A2) is 95:5 to 5:95: (A) A lipid composition comprising the following components (A1) and (A2): (A1) Mannosylerythritol lipid represented by the following general formula (1): 【Chemistry 1】 (In the formula, R1 and R2 represent hydrogen or an aliphatic acyl group having 2 to 24 carbon atoms (however, hydrogen is not removed at the same time). R3 and R4 represent hydrogen or an acetyl group, and R5 represents hydrogen or an aliphatic acyl group having 2 to 24 carbon atoms.) (A2) Phospholipid (B) Polyhydric alcohol (C) Water

2. 2. The skin cleansing composition according to claim 1, wherein the component (A2) is hydrogenated lecithin.

3. The skin cleansing composition according to claim 1 or 2, characterized in that the lipid composition of component (A) further contains component (A3) one or more selected from ceramides, sterols, carotenoids, tocopherols, lipoic acid and coenzyme Q10.

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