Method for controlling harmful arthropods using heterocyclic compounds

Abstract

To provide a method for controlling harmful arthropods.SOLUTION: A compound represented by formula (I) or an N-oxide thereof, or a salt of them, can be used for controlling harmful arthropods. [In the formula: L represents a single bond or the like; R1 represents a C1-C6 linear hydrocarbon group or the like; R2 represents a 5- or 6-membered aromatic heterocyclic group or the like; X represents NR11C(Z)R12 or the like; Z represents an oxygen atom or the like; R11 represents a C1-C6 linear hydrocarbon group or the like; R12 represents a phenyl group or the like optionally substituted with one or more substituents; and Q represents, e.g., a group represented by formula A1 (where # represents the bonding site to R2, and the solid circle represents the bonding site to a carbon atom).]SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a method for controlling arthropod pests using a heterocyclic compound. [Background technology]

[0002] Various compounds have been investigated so far for the purpose of controlling harmful arthropods. For example, Patent Document 1 describes that certain compounds have a pest control effect. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] International Publication No. 2022 / 233777 Summary of the Invention [Problem to be solved by the invention]

[0004] An object of the present invention is to provide a method for controlling arthropod pests. [Means for solving the problem]

[0005] The present invention is as follows. [1] Formula (I) [ka] [During the ceremony, L is a single bond or -(CR 4a R 4b ) n - represents R 4a and R 4b are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, a halogen atom, or a hydrogen atom; n represents 1, 2, 3, 4, 5, or 6; R 1 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from the group consisting of a cyclopropyl group and a halogen atom, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a cyano group, a halogen atom, a hydroxyl group, or a hydrogen atom; Q is a group represented by formula A1, a group represented by formula A2, a group represented by formula A3, a group represented by formula A4, a group represented by formula A5, or a group represented by formula A6 (# is R 2 represents a bonding site with a carbon atom), [ka] Q 1 , Q 2 , and Q 3 The combination of Q 1 CR 3q1 And Q 2 CR 3q2 And Q 3 CR 3q3 A combination that is: Q 1 is a nitrogen atom, and Q 2 CR 3q2 And Q 3 CR 3q3 A combination that is: Q 1 CR 3q1 And Q 2 is a nitrogen atom, and Q 3 CR 3q3 or Q 1 CR 3q1 And Q 2 CR 3q2 And Q 3 represents a nitrogen atom, Q 1a and Q 2a The combination of Q 1a CR 3q4 And Q 2aCR 3q5 A combination that is: Q 1a is a nitrogen atom, and Q 2a CR 3q5 or Q 1a CR 3q4 And Q 2a represents a nitrogen atom, R 3q1 , R 3q2 , R 3q3 , R 3q4 , R 3q5 and R 4 are the same or different and each represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group B, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, NR 6 C(O)R 5 , N.R. 6 C(O)OR 5 , N.R. 6 C(O)NR 5 R 12 , C(O)NR 6 R 7 , C(=NOR 9 )R 5 , C(=NOR 9 )(NR 6 R 7 ), N=S(O) p R 28 R 15 , a cyano group, a halogen atom, or a hydrogen atom; Z 1 represents an oxygen atom or a sulfur atom, p represents 0 or 1; R 5represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group B, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R 6 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R 7 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group B, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R 9 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group B, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R 12 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R 15 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group B, or a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group B, R 2represents a phenyl group which may be substituted with one or more substituents selected from group A, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group A, C(O)NR 6 R 7 , C(=NOR 9 )R 5 , C(=NOR 9 )(NR 6 R 7 ), C(O)R 5 , N.R. 16 C(O)R 17 , N.R. 16 C(O)OR 17 , N.R. 16 C(O)NR 17 R 18 , S(O) 2 NR 16 R 17 , OR 18 , S(O) m R 15 , a mercapto group, a group represented by formula E1, a group represented by formula E2, or a group represented by formula E3 (# 2 represents a bonding site to a group represented by formula A1, a group represented by formula A2, a group represented by formula A3, a group represented by formula A4, a group represented by formula A5, or a group represented by formula A6), [ka] m represents 0, 1, or 2; R 16 , R 17 , and R 18 are the same or different and represent a phenyl group which may be substituted with one or more substituents selected from group B, a 5- or 6-membered heterocyclic group which may be substituted with one or more substituents selected from group B, a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R 2 NR 16 C(O)R 17 If R 16 and R 17 is R 16 The nitrogen atom to which R is bonded 17may form, together with the carbon atom to which it is bonded, a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {which may be substituted with one or more halogen atoms}; R 2 NR 16 C(O)OR 17 If R 16 and R 17 is R 16 The nitrogen atom to which the nitrogen atom is bonded, the carbon atom to which the nitrogen atom is bonded, and R 17 may form, together with the oxygen atom to which it is bonded, a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group (the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms); R 2 NR 16 C(O)NR 17 R 18 If R 16 and R 17 is R 16 The nitrogen atom to which the nitrogen atom is bonded, the carbon atom to which the nitrogen atom is bonded, and R 17 may form, together with the nitrogen atom to which it is bonded, a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {which may be substituted with one or more halogen atoms}; Q 5 CR E11 R 27 , N.R. E12 , an oxygen atom, or a sulfur atom; Q 4 CR E13 or a nitrogen atom, Q 6 CR E14 or a nitrogen atom, Q 7 CR E15 or a nitrogen atom, Q 8 CR E16 or a nitrogen atom, Q 9 CR E17or a nitrogen atom (provided that in the group represented by formula E2, Q 6 and Q 7 If is also a nitrogen atom, Q 6 , Q 8 , and Q 9 is simultaneously a nitrogen atom, and Q 7 , Q 8 , and Q 9 is also a nitrogen atom), Q 10 CR E18 or a nitrogen atom, R E11 and R E31 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group C, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, C(O)NR 7 R 8 , N.R. 9 C(O)R 5 a C3-C6 cycloalkyl group optionally substituted by one or more substituents selected from group E, a cyano group, a halogen atom, or a hydrogen atom; R 8 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R E12 and R E32 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group C, a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from group E, or a hydrogen atom; R 27 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, a phenyl group optionally substituted with one or more substituents selected from group B, or a hydrogen atom; R E13 , R E14 , R E15 , R E16 , R E17 , and R E18are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group C, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, C(O)NR 7 R 8 , N.R. 9 C(O)R 5 a C3-C6 cycloalkyl group optionally substituted by one or more substituents selected from group E, a cyano group, a halogen atom, or a hydrogen atom; X is NR 10 C(Z)R 11 , N.R. 10 C(O)OR 11 , N.R. 10 C(Z)NR 11 R 12 , N.R. 10 C(=NOR 9 )R 11 , N.R. 10 C(=NOR 9 )(NR 11 R 12 ), N=C(OR 9 )R 11 , N=C(SR 15 )R 11 , N=C(NR 6 R 7 )R 11 , N.R. 10 X 1 , or N=S(O) p R 11 R 28 represents Z represents an oxygen atom or a sulfur atom; X 1 represents a 9- or 10-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from group A, R 10 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group F, a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from group E, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, OR 14 , C(O)R 13 , C(O)OR 13 , C(=NR 7 )R13 , C(O)NR 6 R 7 、 or a hydrogen atom, R 11 represents a phenyl group which may be substituted with one or more substituents selected from group A, or a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group A, R 13 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group {the phenyl group may be substituted with one or more substituents selected from the group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a cyano group, and a halogen atom}, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom, R 14 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a phenylmethyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 28 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, or a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E. Group A: C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, a cyano group, and a halogen atom}, a C3-C6 cycloalkyl group {the C3-C6 cycloalkyl group may be substituted with one or more substituents selected from the group consisting of a C1-C6 alkoxy group, a cyano group, and a halogen atom}, a phenyl group which may be substituted with one or more substituents selected from Group B, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from Group B, OR3a ,SCIENCE FICTION 5 , N.R. 3d OR 3b , N.R. 3b C(O)R 3c , N.R. 3d NR 3b C(O)R 3c , N.R. 3b C(O)OR 3e , N.R. 3d NR 3b C(O)OR 3e , N.R. 3b C(O)NR 3f R 3g , N.R. 3d NR 3b C(O)NR 3f R 3g , N=S(O) p R 3h R 3i , C(O)R 3c , C(O)OR 3j , C(O)NR 3f R 3g , S(O) 2 NR 3f R 3g , N.R. 3b C(=NOR 3j )R 3d , N.R. 3b S(O) 2 R 3k , S(O) m R 3k The group consisting of a cyano group, a nitro group, and a halogen atom. R 3a represents a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group B, C(O)R 3c , C(O)OR 3j , C(O)NR 3f R 3g , S(O) 2 R 3k or a hydrogen atom, R 3brepresents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 3c represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group B, or a hydrogen atom; R 3d represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 3e represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a (C1-C3 alkyl)phenyl group {the phenyl moiety in the (C1-C3 alkyl)phenyl group may be substituted with one or more substituents selected from group B}, R 3f represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 3g represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 3h represents a C1-C6 alkyl group optionally substituted by one or more halogen atoms, a phenyl group optionally substituted by one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from group B, or a C3-C6 cycloalkyl group optionally substituted by one or more halogen atoms, R 3i represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, R3j represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group B, or a hydrogen atom; R 3k represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group B, or a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms. Group B: A group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom. Group C: a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from group E, a phenyl group optionally substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group B, OR 3a , N.R. 3d OR 3b , N.R. 3b C(O)R 3c , N.R. 3d NR 3b C(O)R 3c , N.R. 3b C(O)OR 3e , N.R. 3d NR 3b C(O)OR 3e , N.R. 3b C(O)NR 3f R 3g , N.R. 3d NR 3b C(O)NR 3f R 3g , N=S(O) p R 3h R 3i , C(O)R 3c , C(O)OR 3j , C(O)NR 3f R 3g , S(O) m R 3kThe group consisting of a cyano group, a nitro group, and a halogen atom. Group E: C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, OR 3a , S(O) m R 3k The group consisting of an oxo group, a cyano group, and a halogen atom. Group F: a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from group E, a phenyl group optionally substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group B, OR 3a , S(O) m R 3k , C(O)R 3c , C(O)OR 3j , C(O)NR 3f R 3g , N.R. 3b R 3c , N.R. 3b C(O)R 3c , N.R. 3b C(O)NR 3f R 3g , N=S(O) p R 3h R 3i , a 3- to 6-membered non-aromatic heterocyclic group, a cyano group, and a halogen atom. or an N-oxide thereof, or a salt thereof (hereinafter, the compound represented by formula (I) or an N-oxide thereof, or a salt thereof will be referred to as "the compound") to harmful arthropods, a habitat of harmful arthropods, a plant, or a cultivation carrier of a plant. [2] The method for controlling arthropod pests according to [1], wherein the cultivation carrier for plants is soil. [3] A composition comprising the compound represented by formula (I) according to [1] or an N-oxide thereof, or a salt thereof, and one or more components selected from the group consisting of group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i), and group (j): Group (a): A group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients; Group (b): Fungicidally active ingredients; Group (c): Plant growth regulating components; Group (d): phytotoxicity reducing components; Group (e): synergists; Group (f): repellent components; Group (g): molluscicidal ingredients; Group (h): insect pheromones; Group (i): herbicidal active ingredients; Group (j): Biological control materials. [4] A method for controlling harmful arthropods, comprising the step of applying an effective amount of the composition according to [3] to harmful arthropods, a habitat of harmful arthropods, a plant, or a cultivation carrier of a plant. [5] The method for controlling arthropod pests according to [4], wherein the cultivation carrier for plants is soil. [6] A seed or a vegetative reproductive organ comprising an effective amount of the compound represented by formula (I) according to [1] or an N-oxide thereof or a salt thereof, or the composition according to [3]. Effect of the Invention

[0006] According to the present invention, arthropod pests can be controlled. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0007] The substituents in the present invention will be described below. A halogen atom means a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom. When a substituent has two or more halogen atoms or substituents, those halogen atoms or substituents may be the same or different. In this specification, the notation "CX-CY" means that the number of carbon atoms is X to Y. For example, the notation "C1-C6" means that the number of carbon atoms is 1 to 6. The chain hydrocarbon group refers to an alkyl group, an alkenyl group, or an alkynyl group. Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a 1,1-dimethylpropyl group, a 1,2-dimethylpropyl group, a 1-ethylpropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group. Examples of alkenyl groups include vinyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, 3-butenyl, 4-pentenyl, and 5-hexenyl groups. Examples of the alkynyl group include an ethynyl group, a 1-propynyl group, a 2-propynyl group, a 1-methyl-2-propynyl group, a 1,1-dimethyl-2-propynyl group, a 1-ethyl-2-propynyl group, a 2-butynyl group, a 4-pentynyl group, and a 5-hexynyl group. Examples of alkoxy groups include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tert-butoxy, pentyloxy, and hexyloxy groups. Examples of the 5- or 6-membered aromatic heterocyclic group include a pyrazolyl group, an imidazolyl group, a triazolyl group, a tetrazolyl group, an oxazolyl group, an isoxazolyl group, a thiazolyl group, an isothiazolyl group, an oxadiazolyl group, a thiadiazolyl group, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, and a pyrazinyl group. The (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted by one or more halogen atoms refers to a group in which the (C3-C6 cycloalkyl) and / or (C1-C3 alkyl) may have one or more halogen atoms, and examples thereof include a cyclopropylmethyl group, a cyclopropylethyl group, a (2,2-difluorocyclopropyl)methyl group, a 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, and a 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl group. Examples of the phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from group B} include a benzyl group, a 2-fluorobenzyl group, a 4-chlorobenzyl group, a 4-(trifluoromethyl)benzyl group, and a 2-[4-(trifluoromethyl)phenyl]ethyl group. Examples of the 3- to 6-membered non-aromatic heterocyclic group include an oxetanyl group, a pyrrolidinyl group, a 2-oxopyrrolidinyl group, a 2-oxoimidazolidinyl group, a 3,4,5,6-tetrahydro-2-pyrimidinyl group, a tetrahydrofuranyl group, a piperidyl group, a tetrahydropyranyl group, an isoxazolidinyl group, and a morpholinyl group. Examples of the alkylsulfonyl group include a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, and an isopropylsulfonyl group.

[0008] Cycloalkyl groups include, for example, cyclopropyl, cyclobutyl, cyclopentyl, and cyclohexyl groups.

[0009] The present compound may exist in one or more stereoisomers. Stereoisomers include enantiomers, diastereomers, and geometric isomers. The present compound includes each stereoisomer and mixtures of stereoisomers in any ratio.

[0010] The compound represented by formula (I) or its N-oxide may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrogen chloride, phosphoric acid, and sulfuric acid, and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid. The acid addition salt can be obtained, for example, by mixing the compound represented by formula (I) or its N-oxide with an acid.

[0011] Next, the method for producing the present compound will be described.

[0012] Manufacturing method 1 The compound represented by formula (I-1) (hereinafter referred to as compound (I-1)) can be produced by reacting a compound represented by formula (I-2) (hereinafter referred to as compound (I-2)) with a compound represented by formula (I-3) (hereinafter referred to as compound (I-3)). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction is usually carried out in a solvent. Examples of the solvent include ethers (hereinafter referred to as ethers) such as tetrahydrofuran (hereinafter referred to as THF), 1,4-dioxane, 1,2-dimethoxyethane, methyl tert-butyl ether, and diethyl ether; halogenated hydrocarbons (hereinafter referred to as halogenated hydrocarbons) such as dichloromethane and chloroform; nitriles (hereinafter referred to as nitriles) such as acetonitrile; aromatic hydrocarbons (hereinafter referred to as aromatic hydrocarbons) such as toluene and xylene; aprotic polar solvents (hereinafter referred to as aprotic polar solvents) such as N-methylpyrrolidone (hereinafter referred to as NMP) and N,N-dimethylformamide (hereinafter referred to as DMF), and mixtures thereof. In the reaction, a base can be used as necessary, for example, organic bases such as triethylamine, N,N-diisopropylethylamine, pyridine, 4-(dimethylamino)pyridine (hereinafter referred to as organic bases), and alkali metal carbonates such as sodium carbonate, potassium carbonate, cesium carbonate (hereinafter referred to as alkali metal carbonates). In the reaction, compound (I-3) is usually used in an amount of 1 to 10 moles per mole of compound (I-2). The reaction temperature is usually in the range of 0° C. to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (I-1). Compound (I-3) is a commercially available compound or can be prepared using known methods.

[0013] Manufacturing method 2 The compound represented by formula (I) (i.e., compound N) can be produced by reacting a compound represented by formula (I-8) (hereinafter referred to as compound (I-8)) with a compound represented by formula (IM) (hereinafter referred to as compound (IM)). [ka] [In the formula, X a represents a chlorine atom, a bromine atom, or an iodine atom; M A represents a 9-borabicyclo[3.3.1]nonan-9-yl group, a borono group, a 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl group, or a tributylstannyl group, and the other symbols have the same meanings as above. The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures of two or more of these. Examples of the metal catalyst include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), 1,1'-bis(diphenylphosphino)ferrocenepalladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; iron catalysts such as iron(III) chloride and iron(III) acetylacetonate; copper catalysts such as copper(I) iodide and copper(I) chloride; and combinations of two or more of these. The reaction may, if necessary, use a ligand, a base, and / or an inorganic halide. Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline. The bases include alkali metal carbonates and organic bases. Examples of inorganic halides include alkali metal fluorides such as potassium fluoride and sodium fluoride; and alkali metal chlorides such as lithium chloride and sodium chloride. In the reaction, the compound (IM) is usually used in a ratio of 1 to 10 moles and the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of the compound (I-8). When a ligand is used in the reaction, the ligand is usually used in a ratio of 0.01 to 1 mole per mole of the compound (I-8). When a base is used in the reaction, the base is usually used in a ratio of 0.1 to 5 moles per mole of the compound (I-8). When an inorganic halide is used in the reaction, the inorganic halide is usually used in a ratio of 0.1 to 5 moles per mole of the compound (I-8). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is completed, the compound N can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer. Compounds (IM) are commercially available compounds or can be prepared using known methods. The reaction can also be carried out, for example, according to the method described in Example H2 of WO 2020 / 070049.

[0014] Manufacturing method 3 The compound represented by formula (I-1A) (hereinafter referred to as compound (I-1A)) can be produced by reacting a compound represented by formula (I-2A) (hereinafter referred to as compound (I-2A)) with a compound represented by formula (Mg) (hereinafter referred to as compound (Mg)) in the presence of an acid. [ka] [In the formula, X C represents a leaving group such as a chlorine atom, Boc represents a tert-butoxycarbonyl group, and the other symbols have the same meanings as above. The reaction is usually carried out in a solvent, which may include ethers, halogenated hydrocarbons, aromatic hydrocarbons, nitriles, aprotic polar solvents, water, and mixtures of two or more of these. The acid used in the reaction includes, for example, trifluoroacetic acid and hydrogen chloride. When hydrogen chloride is used, a solution of hydrogen chloride such as hydrochloric acid or a hydrogen chloride / methanol solution may be used in the reaction. The reaction can be carried out, for example, by first mixing compound (I-2A) with an acid, then distilling off the acid, and mixing compound (Mg). In the reaction, a base can be used as necessary. Examples of the base include organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 10 moles per mole of compound (I-2A). In the reaction, the compound (Mg) is usually used in a ratio of 1 to 2 moles and the acid is usually used in a ratio of 1 to 100 moles, relative to 1 mole of the compound (I-2A). The reaction temperature is usually within the range of −20 to 200° C. The reaction time is usually within the range of 0.1 to 24 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures are carried out to obtain compound (I-1A). The compound (Mg) is a commercially available compound or can be prepared using known methods.

[0015] Manufacturing method 4 Compound (I-1A) can also be produced by reacting compound (I-2A) with a compound represented by formula (Me) (hereinafter referred to as compound (Me)) in the presence of a condensing agent and an acid. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction is usually carried out in a solvent, which may include ethers, halogenated hydrocarbons, aromatic hydrocarbons, nitriles, esters such as ethyl acetate and butyl acetate (hereinafter referred to as esters), aprotic polar solvents, nitrogen-containing aromatic compounds such as pyridine, picoline, lutidine, and quinoline (hereinafter referred to as nitrogen-containing aromatic compounds), and mixtures of two or more of these. The acid used in the reaction includes, for example, trifluoroacetic acid and hydrogen chloride. When hydrogen chloride is used, a solution of hydrogen chloride such as hydrochloric acid or a hydrogen chloride / methanol solution may be subjected to the reaction. The reaction can be carried out, for example, by first mixing compound (I-2A) with an acid, then distilling off the acid, and mixing compound (Me) with a condensing agent. Condensing agents used in the reaction include, for example, carbodiimides such as 1-ethyl-3-[3-(dimethylamino)propyl]carbodiimide hydrochloride and 1,3-dicyclohexylcarbodiimide. A catalyst can be used in the reaction if necessary. An example of the catalyst is 1-hydroxybenzotriazole. When a catalyst is used in the reaction, the catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (I-2A). In the reaction, a base can be used as necessary. Examples of the base include organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 5 moles per mole of compound (I-2A). In the reaction, compound (Me) is usually used in a ratio of 1 to 2 moles, a condensing agent is usually used in a ratio of 1 to 5 moles, and an acid is usually used in a ratio of 1 to 100 moles, relative to 1 mole of compound (I-2A). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (I-1A). Compound (Me) is a commercially available compound or can be prepared using known methods.

[0016] Manufacturing method 5 Compound (I-1A) can also be produced by reacting a compound represented by formula (I-11) (hereinafter referred to as compound (I-11)) with compound (I-3). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 1, except that compound (I-11) is used in place of compound (I-2).

[0017] Manufacturing method 6 Compound (I-1A) can also be produced by reacting compound (I-11) with compound (Me) in the presence of a condensing agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include ethers, halogenated hydrocarbons, aromatic hydrocarbons, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these. Condensing agents used in the reaction include, for example, carbodiimides such as 1-ethyl-3-[3-(dimethylamino)propyl]carbodiimide hydrochloride and 1,3-dicyclohexylcarbodiimide. A catalyst can be used in the reaction if necessary. An example of the catalyst is 1-hydroxybenzotriazole. When a catalyst is used in the reaction, the catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (I-11). In the reaction, a base can be used as necessary. Examples of the base include organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 5 moles per mole of compound (I-11). In the reaction, compound (Me) is usually used in a ratio of 1 to 2 moles and a condensing agent is usually used in a ratio of 1 to 5 moles, relative to 1 mole of compound (I-11). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (I-1A).

[0018] Manufacturing method 7 The compound represented by formula (I-1B) (hereinafter referred to as compound (I-1B)) can be produced by reacting a compound represented by formula (I-2B) (hereinafter referred to as compound (I-2B)) with compound (I-3). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 1, except that compound (I-2B) is used in place of compound (I-2).

[0019] Manufacturing method 8 Compound (I-1B) can also be produced by reacting compound (I-2B) with compound (Me) in the presence of a condensing agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 6, except that compound (I-2B) is used instead of compound (I-11).

[0020] Manufacturing method 9 Compound (I-1) can also be produced by reacting a compound represented by formula (I-20) (hereinafter referred to as compound (I-20)) with compound (IM). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 2, except that compound (I-20) is used in place of compound (I-8).

[0021] Manufacturing method 10 The compound represented by formula (II-1) (hereinafter referred to as compound (II-1)) can be produced by reacting a compound represented by formula (II-2) (hereinafter referred to as compound (II-2)) with compound (I-3). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 1, except that compound (II-2) is used in place of compound (I-2).

[0022] Manufacturing method 11 Compound (II-1) can also be produced by reacting compound (II-2) with compound (Me) in the presence of a condensing agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 6, except that compound (II-2) is used instead of compound (I-11).

[0023] Manufacturing method 12 Compound (II-1) can also be produced by reacting a compound represented by formula (II-19) (hereinafter referred to as compound (II-19)) with compound (IM). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 2, except that compound (II-19) is used instead of compound (I-8).

[0024] Manufacturing method 13 The compound represented by formula (II-1A) (hereinafter referred to as compound (II-1A)) can be produced by reacting the compound represented by formula (II-3A) (hereinafter referred to as compound (II-3A)) with compound (I-3) in the presence of an acid. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 3, except that compound (II-3A) is used in place of compound (I-2A) and compound (I-3) is used in place of compound (Mg).

[0025] The production methods of the intermediates are described below.

[0026] Reference manufacturing method 1 Compound (I-2) can be produced from a compound represented by formula (I-4) (hereinafter referred to as compound (I-4)). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out, for example, according to the method described in Green's PROTECTIVE GROUPS in ORGANIC SYNTHESIS FORTH EDITION, p. 727. Compound (I-2) may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrochloric acid and sulfuric acid; and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid.

[0027] Reference manufacturing method 2 Compound (I-4) can be produced by reacting a compound represented by formula (I-5) (hereinafter referred to as compound (I-5)) with compound (IM). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 2, except that compound (I-5) is used instead of compound (I-8).

[0028] Reference manufacturing method 3 Compound (I-5) can be produced by reacting a compound represented by formula (I-6) (hereinafter referred to as compound (I-6)) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction is usually carried out in a solvent, such as alcohols (hereinafter referred to as alcohols) such as methanol and ethanol, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, water, and mixtures thereof. Examples of the halogenating agent include chlorine, bromine, iodine, N-chlorosuccinimide, N-bromosuccinimide, and N-iodosuccinimide (hereinafter referred to as NIS). In the reaction, a base can be used as necessary. Examples of the base include alkali metal carbonates. When a base is used in the reaction, the base is usually used in a ratio of 1 to 10 moles per mole of compound (I-6). In the reaction, the halogenating agent is usually used in an amount of 1 to 10 moles per mole of compound (I-6). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (I-5).

[0029] Reference manufacturing method 4 Compound (I-6) can be produced from a compound represented by formula (I-7) (hereinafter referred to as compound (I-7)). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out, for example, according to the method described in Intermediate 23 of WO 2007 / 147794 or Example 5 of WO 2003 / 037900. Compound (I-7) is either a commercially available compound or can be prepared using known methods.

[0030] Reference manufacturing method 5 Compound (I-9) can be produced from a compound represented by formula (I-7A) (hereinafter referred to as compound (I-7A)) and a compound represented by formula (IA) (hereinafter referred to as compound (IA)). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out, for example, according to the method described in International Publication No. 2007 / 147794, Intermediate 23.

[0031] Reference manufacturing method 6 Compound (I-8) can be produced by reacting compound (I-10) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 3, except that compound (I-10) is used instead of compound (I-6).

[0032] Reference manufacturing method 7 Compound (I-11) can be produced from a compound represented by formula (I-2A) (hereinafter referred to as compound (I-2A)). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out, for example, according to the method described in Green's PROTECTIVE GROUPS in ORGANIC SYNTHESIS FORTH EDITION, p. 727. Compound (I-11) may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrochloric acid and sulfuric acid; and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid.

[0033] Reference manufacturing method 8 Compound (I-2A) can be produced by reacting a compound represented by formula (I-12) (hereinafter referred to as compound (I-12)) with compound (IM). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 2, except that compound (I-12) is used in place of compound (I-8).

[0034] Reference manufacturing method 9 Compound (I-12) can be produced by reacting a compound represented by formula (I-13) (hereinafter referred to as compound (I-13)) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 3, except that compound (I-13) is used instead of compound (I-6). Compound (I-13) is a commercially available compound or can be prepared using known methods.

[0035] Reference manufacturing method 1-1 Compound (I-2) can also be produced from a compound represented by formula (I-4B) (hereinafter referred to as compound (I-4B)). [ka] (In the formula, Cbz represents a benzyloxycarbonyl group, and the other symbols have the same meanings as defined above.) The reaction can be carried out, for example, according to the method described in Green's PROTECTIVE GROUPS in ORGANIC SYNTHESIS FORTH EDITION, p. 750. Compound (I-2) may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrochloric acid and sulfuric acid; and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid.

[0036] Reference manufacturing method 2-1 Compound (I-4B) can be produced by reacting a compound represented by formula (I-5B) (hereinafter referred to as compound (I-5B)) with compound (IM). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 2, except that compound (I-5B) is used in place of compound (I-8).

[0037] Reference manufacturing method 3-1 Compound (I-5B) can be produced by reacting a compound represented by formula (I-6B) (hereinafter referred to as compound (I-6B)) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 3, except that compound (I-6B) is used instead of compound (I-6).

[0038] Reference manufacturing method 4-1 Compound (I-6B) can be produced from a compound represented by formula (I-7B) (hereinafter referred to as compound (I-7B)). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out, for example, according to the method described in WO 2007 / 147794 Intermediate 23, the method described in WO 2003 / 037900 Example 5, the method described in WO 2007 / 134362 Example 1, the method described in WO 2021 / 158634 Intermediate BMR step 1, or the method described in Huaxue Xuebao (2005), 63(9), 855-860.

[0039] Reference manufacturing method 10-1 Compound (I-7B) can be produced from a compound represented by formula (I-14B) (hereinafter referred to as compound (I-14B)). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out, for example, in accordance with the method described in WO 2016 / 148145, Example 1-1, Step 1-1-3.

[0040] Reference manufacturing method 10-2 Compound (I-14B) can be produced from a compound represented by formula (I-14A) (hereinafter referred to as compound (I-14A)). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out, for example, according to the method described in Inventive Example 25 of US Patent Application Publication No. 2002 / 6387938. Compound (I-14A) is either a commercially available compound or can be prepared using known methods.

[0041] Reference manufacturing method 11 Compound (I-2B) can be produced by reacting a compound represented by formula (I-15) (hereinafter, compound (I-15) with an amine or an ammonium salt, and a reducing agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction is usually carried out in a solvent, such as alcohols, ethers, aprotic polar solvents, and mixtures thereof. Examples of the amines include methylamine and ethylamine. The ammonium salt includes ammonium acetate and the like. In the reaction, an acid can be used as necessary. Examples of the acid include organic acids such as acetic acid. When an acid is used in the reaction, the acid is usually used in a ratio of 0.1 to 10 moles per mole of compound (I-15). In the reaction, the reducing agent is usually used in a ratio of 1 to 10 moles per mole of compound (I-15). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After completion of the reaction, compound (I-2B) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer.

[0042] Reference manufacturing method 12 Compound (I-15) can be produced by reacting a compound represented by formula (I-16) (hereinafter referred to as compound (I-16)) with a compound represented by formula (Mf) (hereinafter referred to as compound (Mf)). [ka] [In the formula, X d represents a chlorine atom, a bromine atom, or an iodine atom, and the other symbols have the same meanings as above. The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, aprotic polar solvents, and mixtures of two or more thereof. In the reaction, compound (Mf) is usually used in an amount of 1 to 10 moles per mole of compound (I-16). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (I-15). Compound (Mf) is a commercially available compound or can be prepared using known methods.

[0043] Reference manufacturing method 13 Compound (I-16) can be produced by reacting a compound represented by formula (I-17) (hereinafter referred to as compound (I-17)) with compound (IM). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 2, except that compound (I-17) is used instead of compound (I-8).

[0044] Reference manufacturing method 14 Compound (I-17) can be produced by reacting a compound represented by formula (I-18) (hereinafter referred to as compound (I-18)) with a compound represented by formula (Mg) (hereinafter referred to as compound (Mg)) in the presence of a condensing agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include ethers, halogenated hydrocarbons, aromatic hydrocarbons, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these. The condensing agent used in the reaction includes, for example, 1-[bis(dimethylamino)methylene]-1H-1,2,3-triazolo[4,5-b]pyridinium 3-oxide hexafluorophosphate. In the reaction, a base can be used as necessary. Examples of the base include organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 10 moles per mole of compound (I-18). In the reaction, the compound (Mg) is usually used in a ratio of 1 to 3 mol and the condensing agent is usually used in a ratio of 1 to 5 mol, relative to 1 mol of the compound (I-18). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After completion of the reaction, compound (I-17) can be obtained by post-treatment such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

[0045] Reference manufacturing method 15 Compound (I-18) can be produced by subjecting a compound represented by formula (I-19) (hereinafter referred to as compound (I-19)) to hydrolysis reaction in the presence of a base. [ka] [In the formula, R X represents a C1-C4 alkyl group, and the other symbols have the same meanings as above. The reaction is carried out in the presence of a base, water and an organic solvent, such as ethers, nitriles, alcohols, and mixtures thereof. The base used in the reaction includes, for example, alkali metal hydroxides such as lithium hydroxide, sodium hydroxide, potassium hydroxide, etc. The reaction time is usually within a range of 5 minutes to 72 hours, and the reaction temperature is usually within a range of 0°C to 100°C. The amount of the base used in the reaction can be any amount from 1 mole to an excess amount, and is preferably 1 mole to 5 moles, per mole of compound (I-19). After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (I-18). Compound (I-19) is a commercially available compound or can be prepared using known methods.

[0046] Reference manufacturing method 16 The compound represented by formula (I-20) (hereinafter referred to as compound (I-20)) can be produced by reacting a compound represented by formula (I-21) (hereinafter referred to as compound (I-21)) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 3, except that compound (I-21) is used instead of compound (I-6).

[0047] Reference manufacturing method 17 Compound (I-21) can be produced by reacting a compound represented by formula (I-22) (hereinafter referred to as compound (I-22)) with compound (I-3). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 1, except that compound (I-22) is used in place of compound (I-2).

[0048] Reference manufacturing method 18 Compound (I-21) can also be produced by reacting compound (I-22) with compound (Me) in the presence of a condensing agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 6, except that compound (I-22) is used instead of compound (I-11).

[0049] Reference manufacturing method 19 Compound (I-22) can be produced by reacting a compound represented by formula (I-23) (hereinafter, compound (I-23) with an amine or an ammonium salt, and a reducing agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 11, except that compound (I-23) is used instead of compound (I-15).

[0050] Reference manufacturing method 20 Compound (I-23) can be produced by reacting a compound represented by formula (I-24) (hereinafter referred to as compound (I-24)) with compound (Mf). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 12, except that compound (I-24) is used instead of compound (I-16).

[0051] Reference manufacturing method 21 Compound (I-24) can be produced by reacting a compound represented by formula (I-25) (hereinafter referred to as compound (I-25)) with compound (Mg) in the presence of a Lewis acid. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction is usually carried out in a solvent, such as ethers, halogenated hydrocarbons, aromatic hydrocarbons, aprotic polar solvents, and mixtures of two or more of these. The Lewis acid used in the reaction includes, for example, trimethylaluminum. In the reaction, the Lewis acid is usually used in a proportion of 0.1 to 5 mol per 1 mol of compound (I-25). In the reaction, the compound (Mg) is usually used in an amount of 1 to 5 moles per mole of the compound (I-25). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (I-24). Compound (I-25) is a commercially available compound or can be prepared using known methods.

[0052] Reference manufacturing method 22 Compound (II-2) can be produced from a compound represented by formula (II-3) (hereinafter referred to as compound (II-3)). [ka] (In the formula, PG represents a tert-butoxycarbonyl group or a benzyloxycarbonyl group, and the other symbols have the same meanings as above.) The reaction can be carried out, for example, according to the method described in Green's PROTECTIVE GROUPS in ORGANIC SYNTHESIS FORTH EDITION, p. 727 or p. 750. Compound (II-2) may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrochloric acid and sulfuric acid; and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid.

[0053] Reference manufacturing method 23 Compound (II-3) can be produced by reacting a compound represented by formula (II-4) (hereinafter referred to as compound (II-4)) with a compound represented by formula (Mh) (hereinafter referred to as compound (Mh)) in the presence of an acid. [ka] [In the formula, R v represents a C1-C3 alkyl group, and the other symbols have the same meanings as above. The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include ethers, halogenated hydrocarbons, aromatic hydrocarbons, esters, nitriles, aprotic polar solvents, and mixtures of two or more of these. The acid used in the reaction includes organic acids such as trifluoroacetic acid and acetic acid. In the reaction, the acid is usually used in a proportion of 0.1 to 100 moles per mole of compound (II-4). In the reaction, a base can be used as necessary. Examples of the base include organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 10 moles per mole of compound (II-4). In the reaction, compound (Mh) is usually used in an amount of 1 to 10 moles per mole of compound (II-4). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (II-3).

[0054] Reference manufacturing method 24 Compound (II-4) can be produced by reacting a compound represented by formula (II-5) (hereinafter referred to as compound (II-5)) with a hydrazine. [ka] [In the formula, X brepresents a chlorine atom or a bromine atom, and the other symbols have the same meanings as above. The reaction is usually carried out in a solvent, such as ethers, halogenated hydrocarbons, aromatic hydrocarbons, alcohols, aprotic polar solvents, water, and mixtures of two or more of these. The hydrazines used in the reaction include anhydrous hydrazine, hydrazine monohydrate, hydrazine monohydrochloride, and the like. In the reaction, the hydrazine is usually used in an amount of 1 to 10 moles per mole of compound (II-5). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (II-4).

[0055] Reference manufacturing method 25 Compound (II-5) can be produced by reacting a compound represented by formula (II-6) (hereinafter referred to as compound (II-6)) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction is usually carried out in a solvent. Examples of the solvent used in the reaction include ethers, halogenated hydrocarbons, aromatic hydrocarbons, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these. The halogenating agent used in the reaction includes phosphorus oxychloride and the like. In the reaction, the halogenating agent is usually used in an amount of 1 to 10 moles per mole of compound (II-6). In the reaction, a base can be used as necessary. Examples of the base include organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 10 moles per mole of compound (II-6). In the reaction, a quaternary ammonium salt can be used as necessary. Examples of the quaternary ammonium salt include triethylbenzylammonium chloride. When a quaternary ammonium salt is used in the reaction, the quaternary ammonium salt is usually used in a ratio of 0.1 to 5 moles per mole of compound (II-6). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (II-5).

[0056] Reference manufacturing method 26 Compound (II-6) can be produced by reacting a compound represented by formula (II-7) (hereinafter referred to as compound (II-7)) with compound (IM). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 2, except that compound (II-7) is used instead of compound (I-8).

[0057] Reference manufacturing method 27 Compound (II-7) can be produced by reacting a compound represented by formula (II-8) (hereinafter referred to as compound (II-8)) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 3, except that compound (II-8) is used instead of compound (I-6).

[0058] Reference manufacturing method 28 Compound (II-8) can be produced by reacting a compound represented by formula (II-9) (hereinafter referred to as compound (II-9)) with a compound represented by formula (Mi) (hereinafter referred to as compound (Mi)). [ka] [In the formula, R y represents a C1-C4 alkyl group, and the other symbols have the same meanings as above. The reaction is usually carried out in a solvent, such as alcohols, ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, halogenated hydrocarbons, and mixtures of two or more of these. In the reaction, compound (Mi) is usually used in an amount of 1 to 5 moles per mole of compound (II-9). In the reaction, a base can be used as necessary. Examples of the base include alkali metal alkoxides such as sodium methoxide and sodium ethoxide; alkali metal carbonates; and organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 10 moles per mole of compound (II-9). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is completed, the compound (II-8) can be obtained by carrying out post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, drying and concentrating the organic layer. Compound (Mi) is a commercially available compound or can be prepared using known methods. Compound (II-9) is publicly known, or can be produced according to a known method described in Tetrahedron (2013) 69, 11092-11108.

[0059] Reference manufacturing method 29 The compound represented by formula (II-10) (hereinafter referred to as compound (II-10)) can be produced by reacting the compound represented by formula (II-11) (hereinafter referred to as compound (II-11)) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 3, except that compound (II-11) is used instead of compound (I-6).

[0060] Reference manufacturing method 30 Compound (II-11) can be produced by reacting a compound represented by formula (II-12) (hereinafter referred to as compound (II-12)) with compound (Mh) in the presence of an acid. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 23, except that compound (II-12) is used instead of compound (II-4).

[0061] Reference manufacturing method 31 Compound (II-12) can be produced by reacting a compound represented by formula (II-13) (hereinafter referred to as compound (II-13)) with a hydrazine. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 24, using compound (II-13) instead of compound (II-5).

[0062] Reference manufacturing method 32 Compound (II-13) can be produced by reacting compound (II-8) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 25, using compound (II-8) instead of compound (II-6).

[0063] Reference manufacturing method 33 Compound (II-3A) can be produced by reacting a compound represented by formula (II-14) (hereinafter referred to as compound (II-14)) with compound (IM). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 2, except that compound (II-14) is used instead of compound (I-8).

[0064] Reference manufacturing method 34 Compound (II-14) can be produced by reacting a compound represented by formula (II-15) (hereinafter referred to as compound (II-15)) with a compound represented by formula (Mj) (hereinafter referred to as compound (Mj)). [ka] [In the formula, X c represents a chlorine atom, a bromine atom, or an iodine atom; R z represents a C1-C3 alkyl group, and the other symbols have the same meanings as above. The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, and mixtures of two or more of these. In the reaction, compound (Mj) is usually used in an amount of 1 to 5 moles per mole of compound (II-15). In the reaction, an acid can be used as necessary. Examples of the acid include organic acids such as acetic acid and p-toluenesulfonic acid. When an acid is used in the reaction, the acid is usually used in a ratio of 0.1 to 100 moles per mole of compound (II-15). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (II-14).

[0065] Reference manufacturing method 35 Compound (II-15) can be produced from a compound represented by formula (II-16) (hereinafter referred to as compound (II-16)). [ka] [In the ceremony, PG 1 represents a 2,4,6-trimethoxyphenylmethyl group, a 2,4-dimethoxyphenylmethyl group, or a 4-methoxyphenylmethyl group, and the other symbols have the same meanings as above. The reaction is usually carried out in a solvent, such as ethers, alcohols, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, water, and mixtures of two or more of these. In the reaction, an acid can be used as necessary. Examples of the acid include inorganic acids such as hydrochloric acid, and organic acids such as trifluoroacetic acid and p-toluenesulfonic acid. When an acid is used in the reaction, the acid is usually used in a ratio of 0.1 to 100 moles per mole of compound (II-16). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (II-15).

[0066] Reference manufacturing method 36 Compound (II-16) can be produced by reacting a compound represented by formula (II-17) (hereinafter referred to as compound (II-17)) with a compound represented by formula (Mk) (hereinafter referred to as compound (Mk)). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, aprotic polar solvents, nitriles, halogenated hydrocarbons, and mixtures of two or more of these. In the reaction, compound (Mk) is usually used in an amount of 1 to 5 moles per mole of compound (II-17). In the reaction, a base can be used as necessary. Examples of the base include alkali metal carbonates and organic bases. When a base is used in the reaction, the base is usually used in a ratio of 0.1 to 10 moles per mole of compound (II-17). The reaction temperature is usually in the range of −20 to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is completed, the reaction mixture is added with water, extracted with an organic solvent, and the organic layer is dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (II-16).

[0067] Reference manufacturing method 37 Compound (II-17) can be produced by reacting compound (II-7) with a halogenating agent. [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Reference Production Method 25, using compound (II-7) instead of compound (II-6).

[0068] Reference manufacturing method 38 The compound represented by formula (II-18) (hereinafter referred to as compound (II-18)) can be produced from compound (II-10). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out, for example, according to the method described in Green's PROTECTIVE GROUPS in ORGANIC SYNTHESIS FORTH EDITION, p. 727 or p. 750. Compound (II-18) may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrochloric acid and sulfuric acid; and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid.

[0069] Reference manufacturing method 39 Compound (II-19) can be produced by reacting compound (II-18) with compound (I-3). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 1, except that compound (II-18) is used in place of compound (I-2).

[0070] Reference manufacturing method 40 Compound (II-3) can be produced by reacting compound (II-10) with compound (IM). [ka] (In the formula, the symbols have the same meanings as defined above.) The reaction can be carried out according to Production Method 2, except that compound (II-10) is used instead of compound (I-8).

[0071] This compound can be mixed or used in combination with one or more components selected from the group consisting of the following groups (a), (b), (c), (d), (e), (f), (g), (h), (i), and (j) (hereinafter referred to as this component). The above-mentioned mixture or combination use means that the present compound and the present ingredient are used simultaneously, separately or with an interval in time. When the present compound and the present ingredient are used simultaneously, the present compound and the present ingredient may be contained in separate preparations or may be contained in one preparation. One aspect of the present invention is a composition (hereinafter referred to as Composition A) containing one or more components selected from the group consisting of Group (a), Group (b), Group (c), Group (d), Group (e), Group (f), Group (g), Group (h), Group (i), and Group (j) (i.e., the present components), and the present compound.

[0072] Group (a) includes acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphorus insecticides), GABAergic chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-gated chloride channel allosteric modulators (e.g., macrolide insecticides), Juvenile hormone mimics, multisite inhibitors, chordotonal organ TRPV channel modulators, acarid growth inhibitors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, mitochondrial electron transport chain complex I, II, III and IV inhibitors, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ryanodine receptor modulators (e.g., diamide insecticides), chordotonal organ modulators, and other insecticidal, acaricidal and nematicidal active ingredients. These are described in the IRAC classification based on the mechanism of action.

[0073] Group (b) is a group consisting of nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acylamino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiration inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyrimidine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., DMI fungicides such as triazoles), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-site contact active fungicides, microbial fungicides, and other fungicidal active ingredients. These are described in the classification based on the mechanism of action of FRAC.

[0074] Group (c) is a group of plant growth regulators.

[0075] Group (d) is a group of safeners.

[0076] Group (e) is a group of synergists.

[0077] Group (f) is a group of repellent components consisting of bird repellent components, insect repellent components and animal repellent components.

[0078] Group (g) is the group of molluscicidal ingredients.

[0079] Group (h) is a group of signaling substances consisting of pheromones and allelochemicals used by insects.

[0080] Group (i) is a group consisting of acetyl-CoA carboxylase (ACCase) inhibitors, acetolactate synthase (ALS) inhibitors, photosynthesis (photosystem II) inhibitors, photosystem I electron converters, protoporphyrinogen oxidase (PPO) inhibitors, phytoene desaturase system (PDS) inhibitors, 4-hydroxyphenylpyruvate dioxygenase (4-HPPD) inhibitors, carotenoid biosynthesis inhibitors, EPSP synthase inhibitors, glutamine synthase inhibitors, dihydropteroic acid (DHP) synthase inhibitors, microtubule polymerization inhibitors, mitosis / microtubule formation inhibitors, very long chain fatty acid (VLCFA) inhibitors, cellulose synthesis inhibitors, uncoupling agents, lipid synthesis inhibitors, indole acetic acid-like active agents, auxin transport inhibitors, and other herbicidal active ingredients. These are described in the classification based on the mechanism of action of HRAC.

[0081] Group (j) is a group of biological control materials consisting of bacteria, fungi, yeasts, protozoa, viruses, natural products, insects, mites, and mollusks that have a control effect against harmful organisms (e.g., insecticidal activity, acaricidal activity, nematocidal activity, fungicidal activity, etc.), herbicidal activity, or a plant growth regulating effect such as rhizobia and mycorrhizal fungi. Specifically, group (j) is divided into subgroup (j-1): bacteria, subgroup (j-2): fungi and yeasts, subgroup (j-3): protozoa, subgroup (j-4): viruses, subgroup (j-5): nematodes, subgroup (j-6): natural products, subgroup (j-7): insects, subgroup (j-8): mites, and subgroup (j-9): mollusks.

[0082] Examples of combinations of the present components and compounds are described below. For example, alanycarb + SX means a combination of alanycarb and SX. The abbreviation SX means any one of the present compounds selected from the compounds described in the compound group SX1 to SX1338 or any one of the present compounds 1 to 58. The present components described below are all known components and can be obtained from commercially available preparations or produced by known methods. When the present component is a microorganism, it can also be obtained from a bacterial depository institution. The number in parentheses indicates the CAS RN (registered trademark).

[0083] Combinations of the present components and the present compounds of group (a) above: abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetic acid + SX, acetoprole + SX, acrinathrin + SX, acinonapyr + SX, afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, aluminium phosphide + SX, Amitraz + SX, Azamethiphos + SX, Azinphos-ethyl + SX, Azinphos-methyl + SX, Azocyclotin + SX, Bendiocarb + SX, Benfluthrin + SX, Benfuracarb + SX, Bensultap + SX, Bentioflumin + SX, Benzoic acid + SX, Benzoximate + SX, Benzpyrimoxan + SX, Beta-cyfluthrin + SX, Beta-cypermethrin + SX, Bifenazate + SX, bifenthrin + SX, bilobalide + SX, bioallethrin + SX, bioresmethrin + SX,Bistrifluron + SX, bisulflufen + SX, borax + SX, boric acid + SX, broflanilide + SX, bromopropylate + SX, buprofezin + SX, butyric acid + SX, butocarboxim + SX, butoxycarboxim + SX, cadusafos + SX, calcium phosphide + SX, carbaryl + SX, carbofuran + SX, carbosulfan + SX, cartap hydrochloride + SX, Cartap + SX, chinomethionat + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chloropicrin + SX, chlorpyrifos + SX, chlorpyrifos-methyl + SX, chromafenozide + SX, citric acid + SX, clofentezine + SX, clothianidin + SX, coumaphos + SX, cryolite + SX, cyanophos + SX,Cyantraniliprole + SX, Cybenzoxasulfyl + SX, Cyclaniliprole + SX, Cyclobutrifluram + SX, Cycloprothrin + SX, Cycloxaprid + SX, Cyenopyrafen + SX, Cyetpyrafen + SX, Cyflumetofen + SX, Cyfluthrin + SX, Cyhalodiamide + SX, Cyhalothrin + SX, Cyhexatin + SX, Cypermethrin + SX, Cyphenothrin + SX, cyproflanilide + SX, cyromazine + SX, dazomet + SX, deltamethrin + SX, demeton-S-methyl + SX, diafenthiuron + SX, diatomaceous earth + SX, diazinon + SX, dichlorvos + SX, dichloromezotiaz + SX, dicofol + SX, dicrotophos + SX, diflovidazin + SX, diflubenzuron + SX, dimefluthrin + SX, Dimethoate + SX, dimethylvinphos + SX, dimpropyridaz + SX, dinotefuran + SX, disodium octaborate + SX,disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, doramectin + SX, emamectin-benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethiofencarb + SX, ethion + SX, ethiprole + SX, ethoprophos + SX, etofenprox + SX, etoxazole + SX, famphur + SX, fenamiphos + SX, fenazaquin + SX, fenbutatin oxide + SX, fenitrothion + SX, fenmezoditiaz + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin + SX, fenpyroximate + SX, fenthion + SX, fenvalerate + SX, fipronil + SX, flometoquin + SX, flonicamid + SX, fluacrypyrim + SX, fluazaindolizine + SX,fluazuron + SX, flubendiamide + SX, fluchlordiniliprole + SX, flucycloxuron + SX, flucythrinate + SX, fluensulfone + SX, flufenprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupentiofenox + SX, flupyradifurone + SX, flupyrimin + SX, flupyroxystrobin + SX, fluralaner + SX, fluvalinate + SX, fluxametamide + SX, formetanate + SX, fosthiazate + SX, fumaric acid + SX, furamethrin + SX, furathiocarb + SX, gamma-cyhalothrin + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, Potassium salt of hop beta acid + SX, hydramethylnon + SX, imicyafos + SX, imidacloprid + SX,imidaclothiz + SX, imiprothrin + SX, indazapyroxamet + SX, indoxacarb + SX, isocycloseram + SX, isofenphos + SX, isoflualanam + SX, isoprocarb + SX, isopropyl-O-(methoxyaminothiophosphoryl) salicylate + SX, isoxathion + SX, kadethrin + SX, kappa-tefluthrin + SX, kappa-bifenthrin + SX, Lactic acid +SX, lambda-cyhalothrin +SX, lavandulyl senecioate +SX, ledprona +SX, lenoremycin +SX, lepimectin +SX, lime sulfur +SX, lotilaner +SX, lufenuron +SX, machine oil +SX, malathion +SX, malic acid +SX, mecarbam +SX, meperfluthrin +SX, metaflumizone +SX, methamidophos +SX + SX, methidathion + SX, methiocarb + SX, methomyl + SX, methoxychlor + SX,Methoxyfenozide + SX, methyl bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, mevinphos + SX, milbemectin + SX, milbemycin oxime + SX, mivorilaner + SX, modoflaner + SX, momfluorothrin + SX, monocrotophos + SX, moxidectin + SX, naled + SX, nicofluprole + SX, nicotine + SX, Nicotine sulfate + SX, nitenpyram + SX, novaluron + SX, noviflumuron + SX, omethoate + SX, organic acid + SX, oxalic acid + SX, oxamyl + SX, oxazosulfyl + SX, oxydemeton-methyl + SX, Parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phenthoate + SX, phorate + SX, phosalone + SX, phosmet + SX, phosphamidon + SX, phosphine + SX, phoxim + SX, pioxaniliprole + SX, piperflanilide + SX, pirimicarb + SX, pirimiphos-methyl + SX, prallethrin + SX, profenofos + SX, profluthrin + SX, propionic acid + SX, propargite + SX, propetamphos + SX, propoxur + SX, propylene glycol alginate + SX, prothiofos + SX, pyflubumide + SX, pymetrozine + SX, pyraclofos + SX, pyrethrins + SX, pyridaben + SX, pyridalyl + SX, pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX, pyriminostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX,Resmethrin + SX, Sarolaner + SX, Selamectin + SX, Sigma-Cypermethrin + SX, Silafluofen + SX, Sodium borate + SX, Sodium metaborate + SX, Spidoxamat + SX, Spinetoram + SX, Spirobudifen + SX, Spirodiclofen + SX, Spiromesifen + SX, Spiropidione + SX, Spirotetramat + SX, Sulfiflumin + SX, sulfuramid + SX, sulfotep + SX, sulfoxaflor + SX, sulfoxamyl + SX, sulfur + SX, sulfuryl fluoride + SX, tartar emetic + SX, tartaric acid + SX, tau-fluvalinate + SX, tebufenozide + SX, tebufenpyrad + SX, tebupirimfos + SX, teflubenzuron + SX, tefluthrin + SX, temephos + SX, terbufos + SX, tetrachlorantraniliprole + SX, tetrachlorvinphos + SX, tetradifon + SX, tetramethrin + SX,tetramethylfluthrin + SX, tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX, thiometon + SX, thiosultap-disodium + SX, thiosultap-monosodium + SX, tigolaner + SX, thioantraniliprole + SX, tioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin + SX, triazamate + SX, triazophos + SX, trichlorfon + SX, trifluenfuronate + SX, triflumezopyrim + SX, triflumuron + SX, trimethacarb + SX, trioxyflanilide + SX, tyclopyrazoflor + SX, umifoxolaner + SX, vadescana + SX, vamidothion + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX, xylylcarb + SX, zeta-cypermethrin + SX,Zinc phosphide + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-N-ethyl-3-(3,3,3-trifluoropropanesulfinyl)propanamide (1477923-37-7) + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, 2-({2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}imino)-3-(2,2,2-trifluoroethyl)-1,3-thiazolidin-4-one (1445683-71-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methanesulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methanesulfonyl)propanamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7) + SX, 4-[5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, (S)-2-chloro-N-(3-ethylpentan-2-yl)furan-3-carboxamide + SX。,

[0084] Combination of this component of group (b) and this compound: acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, benthiavalicarb-isopropyl + SX, benzovindiflupyr + SX, bifemetstrobin + SX, binapacryl + SX, biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin-S + SX, Bordeaux mixture + SX, boscalid + SX, bromothalonil + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, carbendazim + SX, carboxin + SX, Carpropamid + SX, chinomethionat + SX, chloroinconazide + SX, chloroneb + ​​SX,chlorothalonil + SX, chlozolinate + SX, copper(II) acetate + SX, copper(II) hydroxide + SX, copper oxychloride + SX, copper(II) sulfate + SX, coumoxystrobin + SX, cyazofamid + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX, cyprodinil + SX, dichlobentiazox + SX, dichlofluanid + SX, Diclocymet + SX, Diclomezine + SX, Dicloran + SX, Diethofencarb + SX, Difenoconazole + SX, Diflumetorim + SX, Dimethachlone + SX, Dimethirimol + SX, Dimethomorph + SX, Dimoxystrobin + SX, Diniconazole + SX, Diniconazole-M + SX, Dinocap + SX, Dipotassium hydrogenphosphite + SX, Dipymetitrone + SX, dithianon + SX, dodecylbenzenesulphonic acid bisethylenediamine copper(II) salt + SX,dodemorph + SX, dodine + SX, edifenphos + SX, enoxastrobin + SX, epoxiconazole + SX, etaconazole + SX, ethaboxam + SX, ethirimol + SX, etridiazole + SX, famoxadone + SX, fenamidone + SX, fenaminstrobin + SX, fenarimol + SX, fenbuconazole + SX, feneptamidoquin + SX, fenfuram + SX, fenhexamid + SX, fenopyramid + SX, fenoxanil + SX, fenpiclonil + SX, fenpicoxamid + SX, fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, fentin acetate + SX, fentin chloride + SX, fentin hydroxide + SX, ferbam + SX, ferimzone + SX, florylpicoxamid + SX, fluazinam + SX, Flubeneteram + SX, Fludioxonil + SX, Flufenoxadiazam + SX, Flufenoxystrobin + SX,fluindapyr + SX, flumetylsulforim + SX, flumorph + SX, fluopicolide + SX, fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxapiprolin + SX, fluoxastrobin + SX, fluoxytioconazole + SX, fluquinconazole + SX, fluquinometoate + SX, flusilazole + SX, flusulfamide + SX, flutianil + SX, Flutolanil + SX, Flutriafol + SX, Fluxapyroxad + SX, Folpet + SX, Fosetyl + SX, Fosetyl-aluminium + SX, Fuberidazole + SX, Furalaxyl + SX, Furamethpyr + SX, Galquin + SX, Guazatine + SX, Hexaconazole + SX, Hymexazole + SX, Imazalil + SX, Imibenconazole + SX, Iminoctadine + SX, iminoctadine triacetate + SX, iminoctadine trialbesilate + SX, inpyrfluxam + SX, iodocarb + SX,Ipconazole + SX, Ipfentrifluconazole + SX, Ipflufenoquin + SX, Iprobenfos + SX, Iprodione + SX, Iprovalicarb + SX, Isofetamide + SX, Isoflutipram + SX, Isoprothiolane + SX, Isopyrazam + SX, Isotianil + SX, Kresoxim-methyl + SX, Mancozeb + SX, Mandestrobin + SX, Mandipropamid + SX, maneb + ​​SX, mefentrifluconazole + SX, mepanipyrim + SX, mepronil + SX, meptyldinocap + SX, metalaxyl + SX, metalaxyl-M + SX, metarylpicoxamid + SX, metconazole + SX, methasulfocarb + SX, metiram + SX, metominostrobin + SX, metrafenone + SX, metyltetraprole + SX, mineral oils + SX, myclobutanil + SX, naftifine + SX, nuarimol + SX, octhilinone + SX, ofurace + SX, orysastrobin + SX,oxadixyl + SX, oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, oxpoconazole + SX, oxpoconazole fumarate + SX, oxycarboxin + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen + SX, penthiopyrad + SX, phenamacril + SX, phosphorous acid + SX, phthalide + SX, picarbutrazox + SX, picoxystrobin + SX, piperalin + SX, potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX, probenazole + SX, prochloraz + SX, procymidone + SX, propamidine + SX, propamocarb + SX, propiconazole + SX, propineb + ​​SX, proquinazid + SX, prothiocarb + SX, prothioconazole + SX, pydiflumetofen + SX, Pyraclostrobin + SX,pyrametostrobin + SX, pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, pyrazophos + SX, pyribencarb + SX, pyributicarb + SX, pyridaclomethyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX, pyriophenone + SX, pyrisoxazole + SX, pyroquilon + SX, quinconazole + SX, quinofumelin + SX, quinoxyfen + SX, quintozene + SX, saccharin + SX, saccharin sodium + SX, saccharin potassium + SX, saccharin calcium + SX, saccharin ammonium + SX, saccharin salt + SX, seboctylamine + SX, sedaxane + SX, silthiofam + SX, simeconazole + SX, sodium carbonate peroxhydrate + SX, sodium hydrogencarbonate + SX, spiroxamine + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX, tecnazene + SX, terbinafine + SX, Tetraconazole + SX, Thiabendazole + SX,Thifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, tiadinil + SX, tolclofos-methyl + SX, tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triadimefon + SX, triadimenol + SX, triazoxide + SX, triclopyricarb + SX, tricyclazole + SX, tridemorph + SX, trifloxystrobin + SX, triflumizole + SX, triforine + SX, triticonazole + SX, validamycin + SX, valifenalate + SX, vinclozolin + SX, zinc thiazole + SX, zineb + ​​SX, ziram + SX, zoxamide + SX, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1R)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-48-7) + SX, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1S)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-49-8) + SX, 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide (141573-94-6) + SX, 3-(difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide (1513466-73-3) + SX, N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055589-28-9) + SX,N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylmethanimidamide (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylmethanimidamide (2101814-55-3) + SX, N'-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylmethanimidamide (1817828-69-5) + SX, [4-(difluoromethoxy)phenyl]methyl 4-[(N-ethyl-N-methylamino)methylidene]amino-2,5-dimethylbenzoate + SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, α-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229605-96-2) + SX, (αS)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-46-5) + SX, (αR)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-02-3) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S, 5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX, (1S, 2R, 5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol ( 1801930-07-3) + SX, (1R,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-53-8) + SX, (1S,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-54-9) + SX, (1R,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-55-0) + SX, (1S,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-56-1) + SX, (1R,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-57-2) + SX, (1S,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-58-3) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (1791398-02-1) + SX, methyl (1R,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-90-2) + SX, methyl (1S,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-91-3) + SX, methyl (1R,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-92-4) + SX,methyl (1S,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-93-5) + SX, methyl (1R,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-94-6) + SX, methyl (1S,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-95-7) + SX, methyl (1R,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-22-3) + SX, methyl (1S,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-23-4) + SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) + SX, (1R,2S,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S,2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, (1R,2R,3R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-08-4) + SX, (1S,2S,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-10-8) + SX, (1R,2R,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-13-1) + SX, (1S,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-16-4) + SX, (1R,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-20-0) + SX, (1S,2R,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-24-4) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX, methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-33-8) + SX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952305-97-3) + SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, 2-(difluoromethyl)-N-[(3R)-3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952306-00-1) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX, 5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-[(1S)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide + SX, N-[(1R)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide (2132414-06-1) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N'-ethyl-N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-acetyl-2-(ethanesulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9) + SX,3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromoindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX,3,3,3-trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide + SX, N-methoxy-N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-diethyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one + SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, ethyl 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylate + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine + SX, ethyl 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, ethyl 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxetan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxolan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX,5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX,3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, methyl ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl (Z)-2-(5-cyclopentyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-(5-cyclohexyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-[(3-isopropyl-1H-pyrazol-1-yl)-2-methylphenoxy]-3-methoxyprop-2-enoate + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one + SX, rel-N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[2-(pyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2S)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2R)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-(2-{6-[(1E)-(methoxyimino)ethyl]pyridin-2-yl}-2-(1-methylpyrazol-4-yl)propyl)-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(5-methylpyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-dichlorophenyl)isoxazole-3-carboxamide + SX, methyl 6-(2-{[5-(2,4-difluorophenyl)isoxazole-3-carbonyl]amino}-1-methyl-1-(1-methylpyrazol-4-yl)ethyl)pyridine-3-carboxylate + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-3-(2,4-difluorophenyl)-1,2,4-oxadiazole-5-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-Thiadiazole-2-carboxamide + SX, N-[2-(5-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,6-difluoropyridin-3-yl)-1,3,4-thiadiazole-2-carboxamide + SX.,

[0085] Combination of this component of group (c) and this compound: 1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 1,3,5-triazinane-2,4,6-trithione + SX, 2,3,5-triiodobenzoic acid + SX, IAA ((1H-indol-3-yl)acetic acid) + SX, IBA (4-(1H-indol-3-yl)butyric acid) + SX, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat-chloride + SX, chlorpropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, cyclanilide + SX, cyprosulfamide + SX, daminozide + SX, Decane-1-ol + SX,Dichlorprop + SX, Dikegulac + SX, Dimethipin + SX, Diquat + SX, Ethephon + SX, Ethychlozate + SX, Flumetralin + SX, Flurprimidol + SX, Forchlorfenuron + SX, Formononetin + SX, Gibberellin A + SX, Gibberellin A3 + SX, Inabenfide + SX, Kinetin + SX, Lipochitooligosaccharide MOR116 + SX, Lipochitooligosaccharide SP104 + SX, maleic hydrazide + SX, mefluidide + SX, mepiquat-chloride + SX, methyl-alpha-D-mannopyranoside + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione-calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, pyroglutamic acid + SX, sintophen + SX, sodium 1-naphthalene acetate 1-naphthaleneacetate + SX, sodium cyanate + SX, thidiazuron + SX, titanium apatite + SX,triapenthenol + SX, tribufos + SX, trinexapac-ethyl + SX, uniconazole-P + SX, 2-(naphthalen-1-yl)acetamide + SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid + SX, methyl 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, strigolactone + SX, (1E)-1-[[1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-5-oxo-2H-pyrrol-2-yl]oxymethylene]-3,3a,4,8b-tetrahydroindeno[2,1-b]pyrrol-2-one + SX described in WO 2018 / 145979, (2R)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one + SX described in WO 2018 / 145979, (2S)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one + SX, as described in International Publication No. 2018 / 145979.

[0086] Combinations of the present components and the present compounds of group (d) above: allidochlor + SX, benoxacor + SX, cloquintocet + SX, cloquintocet-mexyl + SX, cyometrinil + SX, cyprosulfamide + SX, dichlormid + SX, dicyclonone + SX, dimepiperate + SX, disulfoton + SX, dymron + SX, fenchlorazole + SX, fenchlorazole-ethyl + SX, fenclorim + SX, flurazole + SX, furilazole + SX, fluxofenim + SX, hexim + SX, isoxadifen + SX, isoxadifen-ethyl + SX, jiecaowan + SX, jiecaoxi + SX, mecoprop + SX, mefenpyr + SX, mefenpyr-ethyl + SX, mefenpyr-diethyl + SX, mephenate + SX, metcamifen + SX, oxabetrinil + SX, 1,8-naphthalic anhydride + SX, Octane-1,8-diamine + SX, AD-67 (4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5] decane) + SX, CL-304415 (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) + SX, CSB (1-bromo-4-[(chloromethyl)sulfonyl]benzene) + SX, DKA-24 (2,2-dichloro-N-[2-oxo-2-(2-propenylamino)ethyl]-N-(2-propenyl)acetamide) + SX, MG191 (2-(dichloromethyl)-2-methyl-1,3-dioxolane) + SX, MG-838 (2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate) + SX, PPG-1292 (2,2-dichloro-N-(1,3-dioxan-2-ylmethyl)-N-(2-propenyl)acetamide) + SX, R-28725 (3-(dichloroacetyl)-2,2-dimethyl-1,3-oxazolidine) + SX, R-29148 (3-(dichloroacetyl)-2,2,5-trimethyl-1,3-oxazolidine) + SX, TI-35 (1-(dichloroacetyl)azepane) + SX。

[0087] Combination of this component of group (e) and this compound: 1-dodecyl-1H-imidazole + SX, N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide + SX, bucarpolate + SX, N,N-dibutyl-4-chlorobenzenesulfonamide + SX, dietholate + SX, diethylmaleate + SX, Jiajizengxiaolin + SX, octachlorodipropyl ether + SX, perbutin + SX, piperonyl butoxide butoxide) + SX, piperonyl cyclonene + SX, piprotal + SX, propyl isome + SX, safroxan + SX, sesamex + SX, sesamolin + SX, sulfoxide + SX, verbutin + SX, 1,1-bis(4-chlorophenyl)ethanol (DMC) + SX, 1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethanol (FDMC) + SX, 1,2-epoxy-1,2,3,4-tetrahydronaphthalene (ETN) + SX, 1,1,1-trichloro-2,3-expoxypropane (ETP) + SX, phenylsaligenin cyclic phosphate (PSCP) + SX, TBPT (S,S,S-tributyl phosphorotrithioate) + SX, TPP (triphenyl phosphate) + SX.

[0088] Combinations of the present components and the present compounds in group (f) above: anthraquinone + SX, chloralose + SX, acrep + SX, butopyronoxyl + SX, camphor + SX, d-camphor + SX, carboxide + SX, dibutyl phthalate + SX, deet + SX, dimethyl carbate + SX, dimethyl phthalate + SX, dibutyl succinate + SX, dibutyl adipate + SX, ethohexadiol + SX, hexamide + SX, icaridin + SX, methoquin-butyl + SX, methylneodecanamide + SX, 2-(octylthio)ethanol + SX, butoxypolypropylene glycol + SX, oxamate + SX, quwenzhi + SX, quyingding + SX, zengxiaon + SX, rebemide + SX, copper naphthenate + SX, zinc naphthenate + SX.

[0089] Combinations of the present components and the present compounds in group (g) above: Bis(tributyltin) oxide + SX, allicin + SX, bromoacetamide + SX, calcium arsenate + SX, cloethocarb + SX, copper sulfate + SX, fentin + SX, ferric phosphate + SX, metaldehyde + SX, niclosamide + SX, Paris green + SX, pentachlorophenol + SX, sodium ferric EDTA + SX, sodium pentachlorophenoxide + SX, tazimcarb + SX, Tralopyril + SX, tributyltin oxide + SX, trifenmorph + SX.

[0090] Combinations of the present components and compounds of group (h) above: (4Z,7Z)-deca-4,7-dien-1-yl acetate + SX, (2E)-dec-2-en-1-ol + SX, (4Z)-dec-4-en-1-yl acetate + SX, (5Z)-dec-5-en-1-ol + SX, +-5Z a-ceta-1-dec (8Z)-dec-8-en-1-ol + SX, (7Z,13Z,16Z,19Z)-docosa-7,13,16,19-tetraen-1-ly isobutylate + SX, (7Z)-dodec-7-en-1-yl acetate + SX-,1-ol +8)-endo (8E)-dodec-8-en-1-yl acetate + SX, (8Z)-dodec-8-en-1-yl acetate + SX, (9E)-dodec-9-en-1-yl acetate + SX, (9Z)-dodec-9-en-1-yl acetate-Z3-Z-endo, (de (2E)-but-2-enoate + SX, (7E,9E)-dodeca-7,9-diene-1-yl acetate + SX, (7E,9Z)-dodeca-7,9-diene-1-yl acetate + SX, (7Z,9E)-dodeca-7,9-dien-te +1-yl (8E,10E)-dodeca-8,10-diene-1-ol + SX, (8E,10E)-dodeca-8,10-diene-1-yl acetate + SX, (6Z)-henicos-6-en-1-one + SX, (9Z)-hexadec-9-enal-9l- SX, + SX, (10Z)-hexadec-10-en-1-yl acetate + SX, (11Z)-hexadec-11-enal + SX, (11Z)-hexadec-11-en-1-ol + SX, (11Z)-hexadec-11-en-1-yl acetate (13Z)-hexadec-13-en-11-yn-1-yl acetate + SX, (7Z,11Z)-hexadeca-7,11-dienal + SX, (7E,11E)-hexadeca-7,11-diene-1-yl acetate + SX, (7E,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (7Z,11E)-hexadeca,ta-7,1-Xcel-diene (7Z,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (10E,12E)-hexadeca-10,12-dienal + SX, (11Z,13Z)-hexadeca-11,13-dienal + SX, (7Z,1caZ-17-Z + SX, (7Z,11Z,13E)-hexadeca-7,11,13-trienal + SX, (13Z)-icos-13-en-10-one + SX, (2E)-6-methylhept-2-en-4-ol + SX, (11Z)-ol-octadec,1-11 (11Z)-octadec-11-enal + SX, (13Z)-octadec-13-enal + SX, (2E,13Z)-octadeca-2,13-diene-1-ol + SX, (2E,13Z)-octadeca-2,13-dienete-1-1-yl acetate (2Z,13Z)-octadeca-2,13-diene-1-yl acetate + SX, (3E,13Z)-octadeca-3,13-diene-1-ol + SX, (3E,13Z)-octadeca-3,13-dien-1-yl acetate + SX, (3Z,13Z)-octadeca-3,13-diene-1-ol + SX, (3Z,13Z)-octadeca-3,13-diene-1-yl acetate + SX, (7Z)-tetradec-7-enal + SX, (7Z)-tetradec-1-Z-7-en-X-en-enal + SX + SX, (9Z)-tetradec-9-en-1-yl acetate + SX, (11Z)-tetradec-11-enal + SX,(11E)-tetradec-11-en-1-yl acetate + SX, (11Z)-tetradec-11-en-1-yl acetate + SX, (3E,8Z)-tetradeca-3,8-dien-1-yl acetate + SX, (4E,10Z)-tetradeca-4,10-dien-1-yl acetate + SX, (8E,10Z)-tetradeca-8,10-dienal + SX, (9E,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,12E)-tetradeca-9,12-dien-1-yl acetate + SX, (3E,8Z,11Z)-tetradeca-3,8,11-trien-1-yl acetate + SX, (9E)-tricos-9-ene + SX, (4E)-tridec-4-en-1-yl acetate + SX, (4Z)-tridec-4-en-1-yl acetate + SX, allyl isothiocyanate + SX, 4-allylanisole + SX, 3-carene + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + eugenol + 2-phenylethyl propionate + SX, (Z)-2-(3,3-dimethylcyclohexylidene)ethanol + SX, (4R,8R)-4,8-dimethyldecanal + SX, (4R,8S)-4,8-dimethyldecanal + SX, 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo[3,2,1]octane + SX, 1,7-dioxaspiro[5,5]undecane + SX, dodecan-1-ol + SX, dodecyl acetate + SX, ethyl (2E,4Z)-deca-2,4-dienoate + SX, ethyl 4-methyloctanoate + SX, (2R,5R)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (2R,5S)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (E)-β-farnesene + SX, farnesyl alcohol + SX, ferrugineol + SX, geranyl hexanoate + SX, (E)-2-hexenyl butyrate + SX, (E)-2-hexenyl butyrate + hexyl butyrate + (E)-4-oxo-2-hexenal + SX, hexyl butyrate + SX, jasmone + SX, 3-ketopetromyzonol-24-sulfate ammonium salt + SX, methyl 2,6,10-trimethyldodecanoate + SX, methyl (2E,4E)-hepta-2,4-dienoate + SX, 2-methylbut-3-en-1-ol + SX, 2-(1-methyl-2-prop-1-en-2-ylcyclobutyl)ethanol + SX, 3-methylcyclohex-2-en-1-one + SX, (-)-4-methylheptan-3-ol + SX, 4-methylnonan-5-ol + SX, 4-methylnonan-5-one + SX, 14-methyloctadec-1-ene + SX, nepetalactone + SX, ocimene + SX, 1,2-octanediol + SX, oct-1-en-3-ol + SX, (R)-oct-1-en-3-ol + SX, olean + SX, 4-(3-oxobutyl)phenyl acetate + SX, (E)-4-oxo-2-hexenal + SX, pentacosane + SX, penta-termanone + SX, phenylacetaldehyde + SX, putrescine + SX, tetradecan-1-ol + SX,tetradecyl acetate + SX, tricosane + SX, tridecan-2-one + SX, 1,2,4-trimethoxybenzene + SX, trimethylamine + SX, trimethylamine hydrochloride + SX, 2-(undecyloxy)ethanol + SX, querciverol + SX, alpha-terpinene + SX, alpha-terpineol + SX, alpha-terpinoline + SX, animal tissue hydrolysate + SX, beet molasses-urea hydrolysate + SX, camphene + SX, capilure + SX, ceralure + SX, chalcogran + SX, codlerure + SX, codlemone + SX, copaene + SX, cosmolure + SX, cucujolide VIII + SX, cuelure + SX, cyclotene + SX, disparlure + SX, dominicalure + SX, endobrevicomin + SX, eugenol + SX, exitlure + SX, exobrevicomin + SX, farnesol + SX, ferrolure + SX, frontalin + SX, german cockroach pheromone + SX, gossyplure + SX, gossyplure HF + SX,Grandlure + SX, Grandlure I + SX, Grandlure II + SX, Grandlure III + SX, Grandlure IV + SX, Hexalure + SX, Ipsdienol + SX, Ipsenol + SX, Japonilure + SX, Lavandin Oil + SX, Lineatin + SX, Litlue + SX, Looplure + SX, Medlure + SX, Megatomoic Acid + SX, Methyl Eugenol + SX, multistriatin + SX, muscalure + SX, nerolidol + SX, orfralure + SX, oryctalure + SX, ostramone + SX, peachflure + SX, prodenialure B + SX, rescalure + SX, rhyncolure + SX, siglure + SX, sordidin + SX, sulcatol + SX, trimedlure + SX, trimedlure A + SX, trimedlure B1 + SX, Trimedlure B2 + SX, trimedlure C + SX, trunc-call + SX, (E)-verbenol + SX, (Z)-verbenol + SX, trans-verbenol + SX,S-verbenone + SX.

[0091] Combinations of the present components and the present compounds of group (i) above: 2,3,6-TBA (2,3,6-trichlorobenzoic acid) + SX, 2,3,6-TBA-dimethylammonium + SX, 2,3,6-TBA-lithium + SX, 2,3,6-TBA-potassium + SX, 2,3,6-TBA-sodium + SX, 2,4-D + SX, 2,4-D choline salt + SX, 2,4-D-biproamine + SX, 2,4-D-doboxyl + SX, 2,4-D 2,4-D-2-ethylhexyl + SX, 2,4-D 3-butoxypropyl + SX, 2,4-D-ammonium + SX, 2,4-D-butotyl + SX, 2,4-D-butyl + SX, 2,4-D-diethylammonium + SX, 2,4-D-dimethylammonium + SX, 2,4-D-diolamine + SX, 2,4-D-dodecylammonium + SX, 2,4-D-ethyl + SX, 2,4-D-heptylammonium + SX, 2,4-D-isobutyl + SX, 2,4-D-isooctyl + SX, 2,4-D-isopropyl + SX, 2,4-D-isopropylammonium + SX, 2,4-D-lithium + SX, 2,4-D-mepty + SX, 2,4-D-methyl4-D-methyl + SX, 2,4-D-octyl + SX, 2,4-D-pentyl + SX, 2,4-D-propyl + SX, 2,4-D-sodium + SX, 2,4-D-tefuryl + SX, 2,4-D-tetradecylammonium + SX, 2,4-D-triethylammonium + SX, 2,4-D-tris(2-hydroxypropyl)ammonium + SX, 2,4-D-trolamine + SX, 2,4-DB + SX, 2,4-DB choline salt + SX, 2,4-DB-biproamine + SX, 2,4-DB-butyl + SX, 2,4-DB-dimethylammonium + SX, 2,4-DB-isoctyl + SX, 2,4-DB-potassium + SX, 2,4-DB-sodium + SX, acetochlor + SX, acifluorfen + SX, acifluorfen-sodium + SX, aclonifen + SX, ACN (2-amino-3-chloronaphthalene-1,4-dione) + SX, alachlor + SX, alloxydim + SX, ametryn + SX, amicarbazone + SX, amidosulfuron + SX, aminocyclopyrachlor + SX,Aminocyclopyrachlor-methyl + SX, Aminocyclopyrachlor-potassium + SX, Aminopyralid + SX, Aminopyralid choline salt + SX, Aminopyralid-potassium + SX, Aminopyralid-tripromine + SX, Amioprophos-methyl + SX, Amitorol + SX, Anilofos + SX, Asulam + SX, Atrazine + SX, Azafenidin + SX, Azimsulfuron + SX, Beflubutamid + SX, benazolin-ethyl + SX, bencarbazone + SX, benfluralin + SX, benfuresate + SX, benquitrione + SX, bensulfuron + SX, bensulfuron-methyl + SX, bensulide + SX, bentazon + SX, benthiocarb + SX, benzfendizone + SX, benzobicyclon + SX, benzofenap + SX, benzthiazuron + SX, bialaphos + SX, bicyclopyrone + SX, bifenox + SX, bipyrazone + SX, bispyribac + SX,bispyribac-sodium + SX, bixlozone + SX, bromacil + SX, bromobutide + SX, bromofenoxim + SX, bromoxynil + SX, bromoxynil-octanoate + SX, butachlor + SX, butafenacil + SX, butamifos + SX, butroxydim + SX, butyrate + SX, cafenstrole + SX, carbetamide + SX, carfentrazone + SX, carfentrazone-ethyl + SX, chlomethoxyfen + SX, chloramben + SX, chloridazon + SX, chlorimuron + SX, chlorimuron-ethyl + SX, chlorbromuron + SX, chlorotoluron + SX, chloroxuron + SX, chlorpropham + SX, chlorsulfuron + SX, chlorthal-dimethyl + SX, chlorthiamid + SX, cinflubrolin + SX, cinidon + SX, cinidon-ethyl + SX, Cinmethylin + SX, Cinosulfuron + SX, Clethodim + SX, Clodinafop + SX,clodinafop-propargyl + SX, clomazone + SX, clomeprop + SX, clopyralid + SX, clopyralid choline salt + SX, clopyralid-methyl + SX, clopyralid-olamine + SX, clopyralid-potassium + SX, clopyralid-tris(2-hydroxypropyl)ammonium + SX, cloransulam + SX, cloransulam-methyl + SX, cumyluron + SX, cyanazine + SX, cycloate + SX, cyclopyranil + SX, cyclopyrimorate + SX, cyclosulfamuron + SX, cycloxydim + SX, cyhalofop + SX, cyhalofop-butyl + SX, cypyrafluone + SX, dalapon + SX, dazomet + SX, desmedipham + SX, desmetryn + SX, di-allate + SX, dicamba + SX, dicamba choline salt + SX, dicamba-biproamine + SX, Dicamba-trolamine + SX, Dicamba-diglycolamine + SX,Dicamba-dimethylammonium + SX, Dicamba-diolamine + SX, Dicamba-isopropylammonium + SX, Dicamba-methyl + SX, Dicamba-olamine + SX, Dicamba-potassium + SX, Dicamba-sodium + SX, Dichlobenil + SX, Dichlorprop choline salt + SX, Dichlorprop-biproamine + SX, Dichlorprop-2-ethylhexyl + SX, Dichlorprop-butotyl + SX, dichlorprop-dimethylammonium + SX, dichlorprop-ethylammonium + SX, dichlorprop-isoctyl + SX, dichlorprop-methyl + SX, dichlorprop-P + SX, dichlorprop-P choline salt + SX, dichlorprop-P-biproamine + SX, dichlorprop-P-etexyl + SX, dichlorprop-P-dimethylammonium + SX, dichlorprop-potassium + SX, dichlorprop-sodium + SX, Diclofop + SX,Diclofop-methyl + SX, diclosulam + SX, difenoxuron + SX, difenzoquat + SX, difenzoquat metilsulfate + SX, diflufenican + SX, diflufenzopyr + SX, diflufenzopyr-sodium + SX, dimefuron + SX, dimepiperate + SX, dimesulfazet + SX, dimethachlor + SX, dimethametryn + SX, dimethenamid + SX, dimethenamid-P + SX, dinitramine + SX, dinoseb + SX, dinoterb + SX, dioxopyritrione + SX, diphenamid + SX, diquat-dibromide + SX, DSMA (disodium methylarsonate) + SX, dithiopyr + SX, diuron + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, epirifenacil + SX, esprocarb + SX, ethalfluralin + SX, ethametsulfuron + SX, ethametsulfuron-methyl + SX, ethidimuron + SX, ethofumesate + SX, ethoxyfen-ethyl + SX, Ethoxysulfuron + SX, etobenzanid + SX, fenoxaprop + SX, fenoxaprop-ethyl + SX, fenoxaprop-P + SX,fenoxaprop-P-ethyl + SX, fenoxasulfone + SX, fenpyrazone + SX, fenquinotrione + SX, fentrazamide + SX, fenuron + SX, feproxydim + SX, flamprop-M + SX, flazasulfuron + SX, florasulam + SX, florpyrauxifen + SX, florpyrauxifen-benzyl + SX, fluazifop + SX, fluazifop-butyl + SX, fluazifop-P + SX, fluazifop-P-butyl + SX, fluazolate + SX, flucarbazone + SX, flucarbazone-sodium + SX, flucetosulfuron + SX, fluchloraminopyr + SX, fluchloraminopyr-tefuryl + SX, flufenacet + SX, flufenoximacil + SX, flufenpyr + SX, flufenpyr-ethyl + SX, flumetsulam + SX, Flumetsulam + SX, Flumiclorac + SX, Flumiclorac-pentyl + SX, Flumioxazin + SX, Fluometuron + SX,fluoroglycofen-ethyl + SX, flupoxam + SX, flupropanate + SX, flupyrsulfuron + SX, flupyrsulfuron-methyl-sodium + SX, flurenol + SX, fluridone + SX, flurochloridone + SX, fluroxypyr + SX, fluroxypyr-butometyl + SX, fluroxypyr-meptyl + SX, flurtamone + SX, flusulfinam + SX, fluthiacet + SX, fluthiacet-methyl + SX, fomesafen + SX, fomesafen-sodium + SX, foramsulfuron + SX, fosamine + SX, glufosinate + SX, glufosinate-ammonium + SX, glufosinate-P + SX, glufosinate-P-ammonium + SX, glufosinate-P-sodium + SX, glyphosate + SX, glyphosate choline salt + SX, glyphosate-isopropylammonium + SX, glyphosate-biproamine + SX, glyphosate-ammonium + SX,glyphosate-diammonium + SX, glyphosate-potassium + SX, glyphosate-sodium + SX, glyphosate-trimesium + SX, halauxifen + SX, halauxifen-benzyl + SX, halauxifen-methyl + SX, halosaphen + SX, halosulfuron + SX, halosulfuron-methyl + SX, haloxyfop + SX, haloxyfop-ethotyl + SX, haloxyfop-methyl + SX, haloxyfop-P + SX, haloxyfop-P-etotyl + SX, haloxyfop-P-methyl + SX, hexazinone + SX, icafolin + SX, icafolin-methyl + SX, imazamethabenz + SX, imazamethabenz-methyl + SX, imazamox + SX, imazamox-ammonium + SX, imazamox-sodium + SX, imazapic + SX, imazapic-ammonium + SX, imazapyr + SX, Imazapyr-ammonium + SX, Imazapyr-isopropylammonium + SX,Imazaquin + SX, Imazaquin-ammonium + SX, Imazethapyr + SX, Imazethapyr-ammonium + SX, Imazosulfuron + SX, Indanofan + SX, Indaziflam + SX, Indolauxipyr + SX, Indolauxipyr-cyanomethyl + SX, Iodosulfuron + SX, Iodosulfuron-methyl-sodium + SX, Iofensulfuron + SX, Iofensulfuron-sodium + SX, Ioxynil + SX, ioxynil-octanoate + SX, ipfencarbazone + SX, iptriazopyrid + SX, isoproturon + SX, isouron + SX, isoxaben + SX, isoxachlortole + SX, isoxafenacil + SX, isoxaflutole + SX, lactofen + SX, lenacil + SX, linuron + SX, maleic hydrazide + SX, MCPA choline salt + SX, MCPA-biproamine + SX, MCPA-etexyl + SX, MCPA-butotyl + SX, MCPA-butyl + SX,MCPA-dimethylammonium + SX, MCPA-diolamine + SX, MCPA-ethyl + SX, MCPA-isobutyl + SX, MCPA-isoctyl + SX, MCPA-isopropyl + SX, MCPA-methyl + SX, MCPA-olamine + SX, MCPA-sodium + SX, MCPA-trolamine + SX, MCPB (4-(4-chloro-2-methylphenoxy)butanoic acid) + SX, MCPB choline salt + SX, MCPB-biproamine + SX, MCPB-ethyl + SX, MCPB-methyl + SX, MCPB-sodium + SX, mecoprop choline salt + SX, mecoprop-biproamine + SX, mecoprop-2-ethylhexyl + SX, mecoprop-dimethylammonium + SX, mecoprop-diolamine + SX, mecoprop-ethadyl + SX, mecoprop-isoctyl + SX, mecoprop-methyl + SX, mecoprop-potassium + SX, mecoprop-sodium + SX, Mecoprop-trolamine + SX, Mecoprop-P + SX,mecoprop-P choline salt + SX, mecoprop-P-2-ethylhexyl + SX, mecoprop-P-dimethylammonium + SX, mecoprop-P-isobutyl + SX, mecoprop-P-potassium + SX, mefenacet + SX, mesosulfuron + SX, mesosulfuron-methyl + SX, mesotrione + SX, metam + SX, metamifop + SX, metamitron + SX, metazachlor + SX, Metazosulfuron + SX, methabenzthiazuron + SX, methiozolin + SX, methyldymron + SX, Metobromuron + SX, metolachlor + SX, metoxuron + SX, metosulam + SX, metproxybicyclone + SX, metribuzin + SX, metsulfuron + SX, metsulfuron-methyl + SX, molinate + SX, monolinuron + SX, naproanilide + SX, naproamide + SX, naptalam + SX, neburon + SX, Nicosulfuron + SX, norflurazon + SX, oleic acid + SX, orbencarb + SX, orthosulfamuron + SX, oryzalin + SX, oxadiargyl + SX, oxadiazon + SX, oxasulfuron + SX, oxaziclomefone + SX, oxyfluorfen + SX, paraquat + SX, paraquat-dichloride + SX, pebulate + SX, pelargonic acid + SX, pendimethalin + SX, penoxsulam + SX, pentanochlor + SX, pentoxazone + SX, pethoxamid + SX, phenisopham + SX,phenmedipham + SX, picloram, picolinafen + SX, picolinafen + SX, pinoxaden + SX, piperophos + SX, pretilachlor + SX, primisulfuron + SX, primisulfuron-methyl + SX, prodiamine + SX, profluazol + SX, profoxydim + SX, prometon + SX, prometryn + SX, propachlor + SX, propanil + SX, propaquizafop + SX, propazine + SX, propham + SX, propisochlor + SX, propoxycarbazone + SX, propoxycarbazone-sodium + SX, propyrisulfuron + SX, propyzamide + SX, prosulfocarb + SX, prosulfuron + SX, pyraclonil + SX, pyraquinate + SX, pyrasulfotole + SX, pyrazolynate + SX, pyrazosulfuron + SX, pyrazosulfuron-ethyl + SX, Pyrazoxyfen + SX, Pyribenzoxim + SX, Pyributicarb + SX,pyridafol + SX, pyridate + SX, pyriflubenzoxim + SX, pyriftalid + SX, pyriminobac + SX, pyriminobac-methyl + SX, pyrimisulfan + SX, pyrithiobac + SX, pyrithiobac-sodium + SX, pyroxasulfone + SX, pyroxsulam + SX, quinclorac + SX, quinmerac + SX, quizalofop + SX, quizalofop-ethyl + SX, Quizalofop-tefuryl + SX, Quizalofop-P + SX, Quizalofop-P-ethyl + SX, Quizalofop-P-tefuryl + SX, Rimisoxafen + SX, Rimsulfuron + SX, Saflufenacil + SX, Sethoxydim + SX, EPTC (S-ethyl N,N-dipropylcarbamothioate) + SX, Siduron + SX, Simazine + SX, Simetryn + SX, S-metolachlor + SX, MSMA (sodium hydrogen methylarsonate + SX, sulcotrione + SX, sulfentrazone + SX, sulfometuron + SX, sulfometuron-methyl + SX,sulfosulfuron + SX, swep + SX, TCA (2,2,2-trichloroacetic acid) + SX, TCA-ammonium + SX, TCA-calcium + SX, TCA-ethadyl + SX, TCA-magnesium + SX, TCA-sodium + SX, tebutam + SX, tebuthiuron + SX, tefuryltrione + SX, tembotrione + SX, tepraloxydim + SX, terbacil + SX, terbumeton + SX, terbuthylazine + SX, terbutryn + SX, tetflupyrolimet + SX, thaxtomin A + SX, thenylchlor + SX, thiazopyr + SX, thidiazimin + SX, thiencarbazone + SX, thiencarbazone-methyl + SX, thifensulfuron + SX, thifensulfuron-methyl + SX, thiafenacil + SX, thiocarbazil + SX, tolpyralate + SX, topramezone + SX, tralkoxydim + SX, triafamone + SX, tri-allate + SX, triasulfuron + SX, triaziflam + SX,tribenuron + SX, tribenuron-methyl + SX, triclopyr + SX, triclopyr-butotyl + SX, triclopyr-ethyl + SX, triclopyr-triethylammonium + SX, tridiphane + SX, trietazine + SX, trifloxysulfuron + SX, trifloxysulfuron-sodium + SX, trifludimoxazin + SX, trifluralin + SX, triflusulfuron + SX, triflusulfuron-methyl + SX, tripyrasulfone + SX, tritosulfuron + SX, vernolate + SX, 4-(4-fluorophenyl)-6-[(2-hydroxy-6-oxo-1-cyclohexen-1-yl)carbonyl]-2-methyl-1,2,4-triazine-3,5(2H,4H)-dione + SX, 2-chloro-N-(1-methyl-1H-tetrazol-5-yl)-3-(methylthio)-4-(trifluoromethyl)benzamide + SX, 2-methyl-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-(methanesulfonyl)-4-(trifluoromethyl)benzamide + SX, 1-{2-chloro-6-[(5-chloropyrimidin-2-yl)oxy]phenyl}-4,4,4-trifluorobutan-1-one (2052297-97-7) + SX. ,

[0092] Combinations of the present components and the present compounds of the above group (j):

[0093] Subgroup (j-1): Combination of bacterial components and compounds: Acidovorax wautersii + SX, Agrobacterium radiobacter strain K1026 + SX, Agrobacterium radiobacter strain K84 + SX, Agrobacterium vitis strain VAR03-1 + SX, Arthrobacter globiformis + SX, Arthrobacter globiformis + Erwinia gerundensis + SX, Azorhizobium spp. + SX, Azorhizobium caulinodans strain ZB-SK-5 + SX, Azospirillum amazonense + SX, Azospirillum brasilense + SX, Azospirillum brasilense strain XOH + SX, Azospirillum brasilense strain Ab-V5 + SX, Azospirillum brasilense strain Ab-V6 + SX, Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Azotobacter + SX,Azotobacter chroococcum + SX, Azotobacter chroococcum strain H23 + SX, Azotobacter salinestris strain CECT9690 + SX, Azotobacter vinelandii strain ATCC12837 + SX, Bacillus acidocaldarius + SX, Bacillus acidoterrestris + SX, Bacillus agri + SX, Bacillus albolactis + SX, Bacillus alcalophilus + SX, Bacillus alvei + SX, Bacillus aminoglucosidicus + SX, Bacillus aminovorans + SX, Bacillus amyloliquefaciens strain PTA-4838 (Aveo (Trademark) EZ Nematicide)) + SX, Bacillus amyloliquefaciens strain AH2 + SX, Bacillus amyloliquefaciens strain AT79 + SX, Bacillus amyloliquefaciens strain AT332 + SX, Bacillus amyloliquefaciens strain B3 + SX,Bacillus amyloliquefaciens strain BV03 + SX, Bacillus amyloliquefaciens strain CECT7657 + SX, Bacillus amyloliquefaciens strain D203 + SX, Bacillus amyloliquefaciens strain D747 + SX, Bacillus amyloliquefaciens strain DB101 + SX, Bacillus amyloliquefaciens strain DB102 + SX, Bacillus amyloliquefaciens strain ENV503 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain GB03 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain IT-45 + SX, Bacillus amyloliquefaciens strain MBI600 + SX,Bacillus amyloliquefaciens strain R6-CDX + SX, Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens subsp. Plantarum strain D747 +SX, Bacillus amylolyticus + SX, Bacillus aneurinolyticus + SX, Bacillus atrophaeus + SX, Bacillus atrophaeus strain Abi05 + SX, Bacillus azotoformans + SX, Bacillus badius + SX, Bacillus cereus strain Ar56 + SX, Bacillus cereus strain B4 + SX, Bacillus cereus strain BP01 + SX, Bacillus cereus strain bromelia + SX, Bacillus cereus strain CIL + SX, Bacillus cereus CNCM strain I-1562 + SX, Bacillus cereus strain DGA34 + SX, Bacillus cereus strain N6 + SX, Bacillus cereus strain N7 + SX,Bacillus cereus strain peumo + SX, Bacillus cereus strain UW85 + SX, Bacillus chitinosporus strain AQ746 + SX, Bacillus chitinosporus strain CM-1 + SX, Bacillus circulans + SX, Bacillus coagulans strain TQ33 + SX, Bacillus fastidiosus + SX, Bacillus firmus strain GB-126 + SX, Bacillus firmus strain I-1582 + SX, Bacillus firmus strain NCIM2637 + SX, Bacillus lacticola + SX, Bacillus lactimorbus + SX, Bacillus lactis + SX, Bacillus lautus + SX, Bacillus lentimorbus + SX, Bacillus lentus + SX, Bacillus licheniformis strain copihue + SX, Bacillus licheniformis B000106 + SX licheniformis strain B000106) + SX, Bacillus licheniformis strain DSM17236 + SX,Bacillus licheniformis strain FMCH001 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus maroccanus + SX, Bacillus medusa + SX, Bacillus megaterium strain ATCC10778 + SX, Bacillus megaterium strain NCIM2087 + SX, Bacillus megaterium strain YFM3.25 + SX megaterium strain YFM3.25 + SX, Bacillus methylotrophicus strain BAC-9912 + SX, Bacillus methylotrophicus strain C1 + SX, Bacillus methylotrophicus isolate UFPEDA20 + SX, Bacillus metiens + SX, Bacillus mojavensis strain R3 + SX, Bacillus mojavensis strain SR11 + SX, Bacillus mycoides strain AQ726 + SX, Bacillus mycoides isolate J + SX, Bacillus nematocida + SX, Bacillus nigrificans + SX,Bacillus nigrum + SX, Bacillus popilliae + SX, Bacillus psychrosaccharolyticus + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain CCTB05 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus safensis strain HCX-01 + SX, Bacillus siamensis strain KCTC 13613 + SX, Bacillus simplex strain CGF2856 + SX, Bacillus smithii + SX, Bacillus sp. strain AQ175 + SX, Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b ... 2362 serotype H5a5b) + SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus subtilis strain AFS032321 + SX, Bacillus subtilis strain antumavida + SX, Bacillus subtilis strain AP-01 + SX, Bacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain B246 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain BV02 + SX, Bacillus subtilis strain BV09 + SX, Bacillus subtilis strain C-3102 + SX, Bacillus subtilis strain CCTB04 + SX, Bacillus subtilis strain CX-9060 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain DB102 + SX, Bacillus subtilis strain FMCH002 + SX,Bacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX, Bacillus subtilis strain IAB / BS03 + SX, Bacillus subtilis strain MBI600 + SX, Bacillus subtilis strain DSM17231 + SX, Bacillus subtilis strain N5 + SX, Bacillus subtilis strain NCIM2063 + SX, Bacillus subtilis strain NCIM8872 + SX, Bacillus subtilis strain NSRS89-24 + SX, Bacillus subtilis strain PAH17 + SX, Bacillus subtilis strain QST30002 / AQ30002 + SX, Bacillus subtilis strain QST30004 / AQ30004 + SX, Bacillus subtilis strain QST713 + SX, Bacillus subtilis strain QST714 + SX, Bacillus subtilis strain RTI477 + SX,Bacillus subtilis strain S1 + SX, Bacillus subtilis strain S2 + SX, Bacillus subtilis strain SEIBS23 + SX, Bacillus subtilis strain UFPEDA764 + SX, Bacillus subtilis strain Y1336 + SX, Bacillus subtilis strain YL13 + SX, Bacillus subtillis subsp. natto + SX, Bacillus subtilis var. Amyloliquefaciens strain FZB24 + SX, Bacillus tequilensis strain 10b + SX, Bacillus tequilensis strain NII-0943 + SX, Bacillus thuringiensis strain 4042 + SX, Bacillus thuringiensis strain anemophila + SX, Bacillus thuringiensis strain AQ52 + SX, Bacillus thuringiensis strain BD#32 + SX thuringiensis strain BD#32 + SX, Bacillus thuringiensis strain CR-371 + SX, Bacillus thuringiensis strain EX297512 + SX,Bacillus thuringiensis subsp. aizawai strain ABTS-1857 + SX, Bacillus thuringiensis subsp. aizawai strain GC-91 + SX, Bacillus thuringiensis subsp. aizawai strain NB200 + SX, Bacillus thuringiensis subsp. aizawai serotype H-7 + SX, Bacillus thuringiensis subsp. galleriae strain SDS-502 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 serotype H-14 + SX, Bacillus thuringiensis subsp. israelensis strain BMP144 + SX, Bacillus thuringiensis subsp. israelensis strain D142 + SX, Bacillus thuringiensis subsp. israelensis strain EG2215 + SX,Bacillus thuringiensis subsp. israelensis strain SA3A + SX, Bacillus thuringiensis subsp. israelensis strain SUM-6218 + SX, Bacillus thuringiensis subsp. israelensis strain VCRC B17 serotype 11-14 + SX, Bacillus thuringiensis subsp. japonensis + SX, CrylA delta endotoxins (Bacillus thuringiensis subsp. Kurstaki CrylA delta endotoxins + SX, Bacillus thuringiensis subsp. Kurstaki CrylC delta endotoxins + SX, Bacillus thuringiensis subsp. Kurstaki strain 3A3B + SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351 + SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306) + SX,Bacillus thuringiensis subsp. Kurstaki strain EG2348 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2371 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2424 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7673 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7826 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki strain F810 + SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1 + SX, Bacillus thuringiensis subsp. Kurstaki strain M-200 + SX, Bacillus thuringiensis subsp. Kurstaki strain NCIM2514 + SX, Bacillus thuringiensis subsp. Kurstaki strain PB54 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12 + SX, Bacillus thuringiensis subsp. Kurstaki strain VBTS-2546 + SX, Bacillus thuringiensis subsp. Kurstaki strain Z-52, serotype H-3a, 3b + SX, Bacillus thuringiensis subsp. morrisoni + SX, Bacillus thuringiensis subsp. tenebriosis strain NB 176 + SX, Bacillus thuringiensis subsp. tenebriosis strain SA-10 + SX, Bacillus thuringiensis subsp. thuringiensis strain MPPL002 + SX MPPL002) + SX, Bacillus thuringiensis subsp. var. colmeri + SX,Bacillus thuringiensis subsp. var. darmstadiensis strain 24-91 + SX, Bacillus thuringiensis subsp. var. dendrolimus + SX, Bacillus thuringiensis subsp. var. galleriae + SX, Bacillus thuringiensis subsp. var. japonensis strain buibui + SX, Bacillus thuringiensis subsp. var. aegypti + SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. sandiego strain M-7 + SX, Bacillus thuringiensis var. T36 + SX, Bacillus velezensis + SX, Bacillus velezensis isolate CNPSo3602 + SX, Bacillus velezensis strain ABi19 + SX, Bacillus velezensis strain FZB42 + SX, Bacillus velezensis strain FZB45 + SX, Bacillus velezensis strain NRRL B-41580 + SX,Bacillus velezensis strain RTI301 + SX, Bradyrhizobium spp. + SX, Bradyrhizobium elkanii + SX, Bradyrhizobium elkanii strain SEMIA 587 + SX, Bradyrhizobium elkanii strain SEMIA 5019 + SX, Bradyrhizobium japonicum + SX, Bradyrhizobium japonicum strain TA-11 + SX, Bradyrhizobium japonicum strain USDA 110 + SX, Bradyrhizobium japonicum strain WB74 + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Bradyrhizobium lupini strain LL13 + SX, Bradyrhizobium spp. (Arachis) + SX, Bradyrhizobium spp. (Vigna) + SX, Brevibacillus brevis strain maguellines I + SX, Brevibacillus brevis strain 2904 + SX, Brevibacillus brevis strain SS86-3 + SX,Brevibacillus brevis strain SS86-4 + SX, Brevibacillus brevis strain SS86-5 + SX, Brevibacillus laterosporus strain ATCC64 + SX, Brevibacillus laterosporus strain BPM3 + SX, Brevibacillus laterosporus strain G4 + SX, Brevibacillus laterosporus strain NCIMB 41419 + SX, Brevibacillus laterosporus strain NRS1111 + SX, Brevibacillus laterosporus strain NRS1645 + SX, Brevibacillus laterosporus strain NRS1647 + SX, Burkholderia ambifaria strain AMMD + SX, Burkholderia cenocepacia strain A396 + SX, Burkholderia cenocepacia strain Ral-3 + SX, Burkholderia cepacia type Wisconsin strain J82 + SX, Burkholderia cepacia type Wisconsin strain M54 + SX,Burkholderia cepacia + SX, Burkholderia gladii strain BA-7 + SX, Burkholderia rinojensis strain A396 + SX, Chromobacterium subtsugae strain PRAA4-1T + SX, Corynebacterium flavescens strain B2575 + SX, Corynebacterium glutamicum + SX, Delftia acidovorans + SX, Delftia acidovorans strain RAY209 + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Erwinia gerundensis + SX, Gluconacetobacter diazotrophicus strain IMI504853 + SX, Klebsiella variicola 137 + SX, Kosakonia cowanii strain SYM00028 + SX, Lactobacillus acidophilus + SX, Lactobacillus brevis + SX, Lactobacillus casei strain LPT-111 + SX, Lactobacillus plantarum + SX,Lactobacillus spp. + SX, Lysobacter antibioticus strain 13-1 + SX, Lysobacter enzymogenes strain B25 + SX, Lysobacter enzymogenes strain C3 + SX, Metylobacterium spp. + SX, Methylobacterium isolate ISO01 + SX, Methylobacterium isolate ISO02 + SX, Methylobacterium isolate ISO03 + SX, Methylobacterium isolate ISO04 + SX, Methylobacterium isolate ISO07 + SX, Methylobacterium isolate ISO09 + SX, Methylobacterium isolate ISO10 + SX, Methylobacterium isolate ISO11 + SX, Methylobacterium symbioticum + SX, Mesorhizobium spp. + SX, Mesorhizobium ciceri + SX, Mesorhizobium huakii + SX, Mesorhizobium loti + SX, Paenibacillus alvei strain 2771 + SX,Paenibacillus alvei strain 46C3 + SX, Paenibacillus alvei strain III2E + SX, Paenibacillus alvei strain III3DT-1A + SX, Paenibacillus alvei strain T36 + SX, Paenibacillus macerans + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Paenibacillus polymyxa strain H-5 + SX, Paenibacillus popilliae + SX, Pantoea agglomerans strain E325 + SX, Pantoea vagans strain C9-1 + SX, Pasteuria nishizawae strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria ramose + SX, Pasteuria usgae + SX, Pectobacterium carotovorum + SX, Pasteuria thornei + SX, Pseudomonas aeruginosa strain PN1 + SX, Pseudomonas aeruginosa strain WS-1 + SX, Pseudomonas aureofaciens strain TX-1 + SX TX-1) + SX, Pseudomonas alcaligenes + SX, Pseudomonas cepacia type Wisconsin strain J82 + SX,Pseudomonas cepacia type Wisconsin strain M54 + SX, Pseudomonas chlororaphis strain 63-28 + SX, Pseudomonas chlororaphis strain AFS009 + SX, Pseudomonas chlororaphis strain MA342 + SX, Pseudomonas entomophilla strain 1257 + SX, Pseudomonas fluorescens isolate Pf-5 + SX, Pseudomonas fluorescens strain 1629RS + SX, Pseudomonas fluorescens strain A506 + SX, Pseudomonas fluorescens strain ACK55 + SX, Pseudomonas fluorescens strain CL145A + SX, Pseudomonas fluorescens strain D7 + SX, Pseudomonas fluorescens strain G7090 + SX, Pseudomonas fluorescens biover B XJ3 + SX Pseudomonas fluorescens biover B strain XS18 + SX,Pseudomonas fluorescens biover A strain LRS12 + SX, Pseudomonas proradix + SX, Pseudomonas putida strain CECT8538 + SX, Pseudomonas reactans + SX, Pseudomonas resinovorans + SX, Pseudomonas rhodesiae strain HAI-0804 + SX, Pseudomonas sp. strain CAB-02 + SX, Pseudomonas sp. DSMZ13134 + SX sp. strain DSMZ13134 + SX, Pseudomonas syringae strain 742RS + SX, Pseudomonas syringae strain ESC-10 + SX, Pseudomonas syringae strain ESC-11 + SX, Pseudomonas syringae strain MA-4 + SX, Pseudomonas trivialis + SX, Rhizobium etli + SX, Rhizobium galegae + SX, Rhizobium leguminosarum bv. Phaseoli (Rhizobium leguminosarum bv. Phaseoli) + SX, Rhizobium leguminosarum bv. Trifolii + SX,Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Rhodococcus globerulus strain AQ719 + SX, Saccharopolyspora spinosa + SX, Serratia entomophila strain 626 + SX, Serratia marcescens strain 35 + SX, Serratia marcescens strain SRM + SX, Serratia nematodiphila strain S-CSR-0024 + SX, Sphingobacterium nematocida strain ZY-71-1 + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX, Streptomyces acidiscabies strain RL-110T + SX, Streptomyces candidus strain Y21007-2 + SX, Streptomyces colombiensis + SX, Streptomyces galbus strain QST6047 + SX, Streptomyces globosus strain LZH-48 + SX,Streptomyces goshikiensis + SX, Streptomyces griseofuscus strain 200101 + SX, Streptomyces griseoviridis strain K61 + SX, Streptomyces jalisciencis isolate CM-CNRG0001 + SX, Streptomyces jofer isolate CM-CNRG0002 + SX, Streptomyces lavendulae + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Streptomyces microflavus strain AQ6121 + SX, Streptomyces prasinus + SX, Streptomyces rimosus + SX, Streptomyces saraceticus + SX, Streptomyces sp. strain NRRL No.B-30145 + SX, Streptomyces sp. strain WYE20 + SX, Streptomyces sp. strain WYE 324 + SX, Streptomyces venezuelae + SX,Thiobacillus spp. + SX, Variovorax paradoxus strain GF4526 + SX, Virgibacillus pantothenticus strain ATCC14576 + SX, Virgibacillus pantothenticus strain DSM491 + SX, Wolbachia pipientis + SX, Xanthomonas campestris pv poae + SX, Xanthomonas campestris + SX, Xenorhabdus luminescens + SX, Xenorhabdus nematophila + SX.,

[0094] Subgroup (j-2): Combination of this compound with the main component of fungi and yeast Acaulospora spp. + SX, Acaulospora longula + SX, Alternaria destruens + SX, Alternaria destruens strain 59 + SX, Ambispora spp. + SX, Ambispora leptoticha + SX, Ampelomyces quisqualis strain AQ10 + SX, Ampelomyces quisqualis strain RSAQ7690 + SX, Ampelomyces quisqualis strain M-10 + SX SX, Archaeospora spp. + SX, Arkansas Fungus 18 + SX, Arthrobotrys dactyloides + SX, Arthrobotrys superba + SX, Aschersonia aleyrodis + SX, Aspergillus flavus strain AF36 + SX, Aspergillus flavus strain MUCL54911 + SX, Aspergillus flavus strain NRRL21882 + SX, Aureobasidium pullulans strain DSM14940 + SX, Aureobasidium pullulans strain DSM14941 + SX,Aureobasidium pullulans strain YBCA5 + SX, Beauveria bassiana isolate B21 + SX, Beauveria bassiana isolate B33 + SX, Beauveria bassiana isolate CBMAI1306 + SX, Beauveria bassiana strain 147 + SX, Beauveria bassiana strain 203 + SX, Beauveria bassiana strain 447 + SX, Beauveria bassiana strain ANT-03 + SX ANT-03 + SX, Beauveria bassiana strain ATCC74040 + SX, Beauveria bassiana strain ATP02 + SX, Beauveria bassiana strain CFL-A + SX, Beauveria bassiana strain CG716 + SX, Beauveria bassiana strain ESALQ PL63 + SX, Beauveria bassiana strain GHA + SX, Beauveria bassiana strain HF23 + SX, Beauveria bassiana strain IBCB66 + SX, Beauveria bassiana strain IMI389521 + SX,Beauveria bassiana strain J25 + SX, Beauveria bassiana strain NCIM1216 ATCC26851 + SX, Beauveria bassiana strain NPP111B005 + SX, Beauveria bassiana strain PL63 + SX, Beauveria bassiana strain PPRI 5339 + SX, Beauveria bassiana strain R444 + SX, Beauveria bassiana strain ZJU435 + SX ZJU435 + SX, Beauveria brongniartii + SX, Beauveria brongniartii isolate IMBST95.031 + SX, Beauveria brongniartii isolate IMBST95.041 + SX, Candida oleophila strain O + SX, Candida oleophila isolate I-182 + SX, Candida saitoana + SX, Candida spp. + SX, Cell walls of Saccharomyces cerevisiae strain LAS117 + SX, Chaetomium cupreum + SX, Chlorella + SX, Chondrostereum purpureum + SX,Cladosporium cladosporioides strain H39 + SX, Claroideoglomus spp. (formerly Glomus spp.) + SX, Claroideoglomus claroideum (formerly Glomus claroideum) + SX, Claroideoglomus etunicatum (formerly Glomus etunicatum) + SX, Claroideoglomus luteum + SX, Clonostachys rosea strain ACM941 + SX, Clonostachys rosea strain CR-7 CR-7) + SX, Clonostachys rosea strain IDAC 040913-01 + SX, Clonostachys rosea strain J1446 + SX, Colletotrichum gloeosporioides + SX, Conidiobolus obscurus + SX, Conidiobolus thromboide + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-08 CON / M / 91-08) + SX, Cryphonectria parasitica + SX, Cryptococcus albidus + SX,Cryptococcus flavescens + SX, Cylindrobasidium laeve + SX, Dactyllela ellipsospora + SX, Decylaria thaumasia + SX, Dilophosphora alopecuri + SX, Diversispora spp. + SX, Enterococcus faecium + SX, Entomophthora virulenta + SX, Entrophospora spp. + SX, Entyloma ageratinae + SX, ageratinae + SX, Epicoccum nigrum + SX, Funneliformis spp. (formerly Glomus spp.) + SX, Funneliformis mosseae (formerly Glomus mosseae) + SX, Fusarium oxysporum strain Fo47 + SX, Fusarium oxysporum strain RS-21 + SX, Fusarium oxysporum strain RS-25 + SX, Fusarium proliferatum strain NCIM1101 + SX, Geosiphon spp. + SX, Gigaspora spp. + SX, Gigaspora margarita + SX, Gigaspora rosea + SX,Gliocladium catenulatum strain J1446 + SX, Gliocladium roseum + SX, Gliocladium virens strain GL-21 + SX, Glomus spp. + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus etunicatum + SX, Glomus iranicum + SX, Glomus monosporum + SX, Hirsutella minnesotensis + SX, Glomus spp. + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus etunicatum + SX, Glomus iranicum + SX, Glomus monosporum + SX, Hirsutella minnesotensis + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Isaria fumosorosea isolate B3 + SX, Isaria fumosorosea strain Isfm-CPF + SX, Isaria tenuipes + SX, Laccaria bicolor + SX, Laccaria laccata + SX, Lagenidium giganteum + SX, Lecanicillium lecanii KV01 + SX, Lecanicillium lecanii conidia of strain DAOM198499 + SX, Lecanicillium lecanii conidia of strain DAOM216596 + SX,Lecanicillium muscarium (formerly Verticillium lecanii) strain 1 / 1 + SX, Lecanicillium muscarium (formerly Verticillium lecanii) strain Ve6 + SX, Metarhizium anisopliae isolate D1 + SX, Metarhizium anisopliae isolate IBCB425 + SX, Metarhizium anisopliae strain CQMa421 + SX, Metarhizium anisopliae strain ESALQ E9 + SX, Metarhizium anisopliae strain ESF1 + SX, Metarhizium anisopliae strain F52 + SX, Metarhizium anisopliae strain FI-985 + SX anisopliae strain FI-985 + SX, Metarhizium anisopliae strain FI-1045 + SX, Metarhizium anisopliae strain ICIPE30 + SX, Metarhizium anisopliae strain ICIPE62 + SX, Metarhizium anisopliae strain ICIPE69 + SX, Metarhizium anisopliae strain ICIPE78 + SX, Metarhizium anisopliae strain NCIM1311 + SX NCIM1311) + SX, Metarhizium anisopliae var. acridum strain EVCH077) + SX,Metarhizium anisopliae var. acridum isolate IMI 330189 + SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Metarhizium brunneum strain Cb15-III + SX, Metarhizium flavoviride strain F001 + SX, Metarhizium rileyi strain PHP1705 + SX, Metschnikowia fructicola strain NRRLY-27328 + SX, Metschnikowia fructicola strain NRRLY-30752 + SX, Microdochium dimerum strain L13 + SX, Microsphaeropsis ochracea + SX, Monacrosporium phymatopagum + SX, Mucor hiemalis + SX, Muscodor albus strain 620 + SX, Muscodor albus QST Muscodor albus strain QST 20799 + SX, Muscodor albus strain SA13 + SX, Muscodor roseus strain A3-5 + SX,Myrothecium verrucaria strain AARC-0255 + SX, Nomuraea rileyi strain CG128 + SX, Nomuraea rileyi strain GU87401 + SX, Nomuraea rileyi strain SA86101 + SX, Nomuraea rileyi strain SR86151 + SX, Nomuraea rileyi strain VA9101 + SX, Ophiostoma piliferum strain D97 + SX, Pacispora spp. + SX, Paecilomyces fumosoroseus Apopka strain 97 (Now, Isaria fumosorosea Apopka strain 97) + SX, Paecilomyces fumosoroseus strain FE9901 (Now, Isaria fumosorosea strain FE9901) + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 T1) + SX, Paecilomyces variotii strain Q-09 + SX, Pandora delphacis + SX, Paraglomus spp. + SX,Paraglomus brasilianum (formerly Glomus brasilianum) + SX, Penicillium bilaiae strain ATCC22348 + SX, Penicillium citrinum strain VFI-51 + SX, Penicillium vermiculatum + SX, Phlebiopsis gigantea strain FOC PG410.3 + SX, Phlebiopsis gigantea strain VRA1835 + SX, Phlebiopsis gigantea strain VRA1984 + SX, Phlebiopsis gigantea strain VRA1985 + SX, Phlebiopsis gigantea strain VRA1986 + SX, Phlebiopsis gigantea strain VRA1992 + SX, Phlebiopsis spp. + SX, Phoma macrostroma strain 94-44B + SX, Phytophthora palmivora + SX, Pichia anomala strain WRL-076 + SX, Pichia guilliermondii strain Z1 + SX, Pichia guilliermondii strain Z8 + SX, Pisolithus tinctorius + SX,Pochonia chlamydosporia isolate strain PC10 + SX, Pochonia chlamydosporia + SX, Pseudozyma flocculosa strain ATTC64874 + SX, Pseudozyma flocculosa strain PF-A22UL + SX, Puccinia thlaspeos strain woad + SX, Purpureocillium lilacinum strain 251 + SX, Purpureocillium lilacinum strain PL11 + SX PL11) + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Racocetra spp. + SX, Rhizophagus spp. (formerly Glomus spp.) + SX, Rhizophagus clarus (formerly Glomus clarum) + SX, Rhizophagus intraradices (formerly Glomus intraradices) + SX, Rhizophagus intraradices strain RTI-801 + SX, Rhizophagus irregularis (formerly Glomus clarum) + SX, Rhizophagus clarus ... Rhizophagus irregularis strain DAOM 197198 + SX,Scutellospora spp. + SX, Rhizopogon amylopogon + SX, Rhizopogon fulvigleba + SX, Rhizopogon luteolus + SX, Rhizopogon villosullus + SX, Saccharomyces cerevisiae strain LAS02 + SX, Saccharomyces cerevisiae strain DDSF623 + SX, Saccharomyces cerevisiae strain SP.1026 + SX, Scleroderma cepa + SX, Scleroderma citrinum + SX, Sclerotinia minor strain IMI34414 + SX, Sporothrix insectorum + SX, Suillus granulatus + SX, Suillus punctatapies + SX, Talaromyces flavus strain SAY-Y-94-01 + SX, Talaromyces flavus strain V117b + SX, Trichoderma afroharzianum + SX, afroharzianum + SX, Trichoderma album + SX, Trichoderma asperelloides strain JM41R + SX,Trichoderma asperellum strain CBMAI840 + SX, Trichoderma asperellum strain CBMAI1622 + SX, Trichoderma asperellum strain BV09 + SX, Trichoderma asperellum strain BV10 + SX, Trichoderma asperellum strain ICC012 + SX, Trichoderma asperellum strain kd + SX, Trichoderma asperellum strain M103 + SX, Trichoderma asperellum strain RNCIM F-1323 + SX, Trichoderma asperellum T11 + SX, Trichoderma asperellum T25 + SX, Trichoderma asperellum strain T34 + SX, Trichoderma asperellum strain SKT-1 + SX, Trichoderma asperellum strain TV1 + SX, Trichoderma atroviride strain 77B + SX, Trichoderma atroviride strain CNCM 1-1237 + SX, Trichoderma atroviride strain I-1237 + SX, Trichoderma atroviride strain IMI 206040 + SX, Trichoderma atroviride strain K4 + SX, Trichoderma atroviride strain LC52 + SX, Trichoderma atroviride Trichoderma atroviride strain LU132 + SX, Trichoderma atroviride strain SC1 + SX, Trichoderma atroviride strain SKT-1 + SX, Trichoderma atroviride strain T11 + SX, Trichoderma atroviride strain TV1 + SX, Trichoderma atroviride strain WW10TC4 + SX, Trichoderma gamsii strain ICC080 + SX, Trichoderma harmatum strain 382 + SX, Trichoderma harmatum strain TH382 + SX, Trichoderma harzianum strain 21 + SX,Trichoderma harzianum strain AP-001 + SX, Trichoderma harzianum strain BK-Th001 + SX, Trichoderma harzianum strain CBS101525 + SX, Trichoderma harzianum strain DB 104 + SX, Trichoderma harzianum strain DSM 14944 + SX, Trichoderma harzianum strain ESALQ-1303 + SX, Trichoderma harzianum strain ESALQ-1306 + SX, Trichoderma harzianum strain F11Bab + SX, Trichoderma harzianum strain Gomorteka + SX, Trichoderma harzianum strain IB19 / 17 + SX, Trichoderma harzianum strain IBLF006 + SX, Trichoderma harzianum strain IIHR-Th-2 + SX, Trichoderma harzianum strain ITEM908 + SX, Trichoderma harzianum strain K2 + SX, Trichoderma harzianum strain kd + SX,Trichoderma harzianum strain KRL-AG2 + SX, Trichoderma harzianum strain MO1 + SX, Trichoderma harzianum strain queule + SX, Trichoderma harzianum strain RR17Bc + SX, Trichoderma harzianum strain SF + SX, Trichoderma harzianum strain T5 + SX, Trichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T24 + SX harzianum strain T24 + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma harzianum strain TH315 + SX, Trichoderma harzianum rifai + SX, Trichoderma koningii + SX, Trichoderma lignorum strain TL-0601 + SX SX, Trichoderma lignorum + SX, Trichoderma longibrachiatum strain T-397 + SX,Trichoderma polysporum strain IMI206039 + SX, Trichoderma parceramosum + SX, Trichoderma reesei + SX, Trichoderma strain SKT-1 + SX, Trichoderma spp. + SX, Trichoderma saturnisporium strain PBP-TH-001 + SX, Trichoderma stromaticum + SX, Trichoderma virens strain chagual + SX, Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 (formy Gliocladium virens GL-21) + SX, Trichoderma virens strain nire + SX, Trichoderma virens strain sherwood + SX, Trichoderma viride strain (NRRL B-50520) + SX, Trichoderma viride strain K5 + SX, Trichoderma viride strain T111 + SX, Tsukamurella paurometabola strain C-924 + SX, Tsukamurella paurometabola + SX,Typhula phacorrhiza strain 94671 + SX, Ulocladium oudemansii strain HRU3 + SX, Ulocladium oudemansii strain U3 + SX, Verticillium alboatrum strain WCS850 + SX, Verticillium chlamydosporium + SX, Verticillium dahliae + SX, Verticillium lecanii strain ID05-F0117 + SX, Verticillium lecanii strain NCIM1312 + SX, Verticillium lecanii strain SZWL7 + SX, Zoophtora radicans + SX.

[0095] Subgroup (j-3): Combination of the protozoan component with the compound: Nosema locustae + SX, Thelohania solenopsis + SX, Vairimorpha spp. strain Q-09 + SX.

[0096] Subgroup (j-4): Combination of this component of the virus with this compound: Adoxophyes orana GV(granulovirus) strain BV-0001 + SX, Agrotis segetum NPV(nucleopolyhedrovirus) + SX, Anagraoha falcifera NPV + SX, Anticarsia gemmatalis MNPV(multiple nucleocapsid nucleopolyhedrovirus) + SX, Autographa californica MNPV strain FV11 + SX, Autographa californica MNPV strain R3 + SX, Bacteriophage of Clavibacter michiganesis + SX, Bacteriophage active against Clavibacter michiganensis subsp. michiganensis + SX, Bacteriophage active against Erwinia amylovora + SX, Bacteriophage active against Pseudomonas syringae pv. tomato + SX, Bacteriophage active against Xanthomonas campestris pv. vesicatoria + SX, Bacteriophage active against Xanthomonas citri subsp. citri + SX, Bacteriophage against Xylella fastidiosa + SX, Biston suppressaria NPV + SX, Bombyx mori NPV + SX,Chrysodeixis includens NPV isolate 460 + SX, Cryptophlebia leucotreta GV + SX, Cydia pomonella GV + SX, Cydia pomonella GV M + SX, Cydia pomonella GV strain CP4 + SX, Cydia pomonella GV strain R5 + SX, Cydia pomonella GV strain V15 + SX, Cydia pomonella GV strain V22 + SX, Douglas fir tussock moth NPV + SX, Dendrolimus punctatus cypovirus + SX, Ectropis obliqua picorna-like virus + SX, Helicoverpa armigera NPV + SX, Helicoverpa armigera NPV strain BV-0003 + SX, Helicoverpa zea NPV + SX, Indian meal moth granulosis virus GV) + SX, Leucoma salicis NPV + SX, Lymantria dispar MNPV + SX, Mamestra brassicae NPV + SX,Mamestra configurata NPV + SX, Neodiprion abietis NPV + SX, Neodiprion lecontei NPV + SX, Neodiprion sertifer NPV + SX, Orgyia pseudotsugata NPV + SX, pepino mosaic virus strain CH2 isolate 1906 + SX, pepino mosaic virus strain CH2 isolate Abp1 + SX, pepino mosaic virus strain CH2 isolate Abp2 + SX, pepino mosaic virus isolate VC1 + SX, pepino mosaic virus isolate VX1 + SX, Phthorimaea operculella GV isolate DSMZ GV-0019 + SX, Pieris rapae GV + SX, Plodia interpunctella GV + SX, Plutella xylostella GV + SX, Spodoptera albula MNPV + SX, Spodoptera exempta MNPV + SX,Spodoptera exigua MNPV strain BV-0004 + SX, Spodoptera frugiperda MNPV + SX, Spodoptera littoralis MNPV isolate DSMZ BV-0005 + SX, Spodoptera litura NPV + SX, Tobacco mild tobamovirus strain U2 + SX, Zucchini Yellow Mosaik Virus weak strain + SX.

[0097] Subgroup (j-5): Combination of the present component of nematodes and the present compound: Abreviata caucasica + SX, Acuaria spp. + SX, Agamermis decaudata + SX, Allantonema spp. + SX, Amphimermis spp. + SX, Deladenus siricidicola + SX, Bovienema spp. + SX, Cameronia spp. + SX, Chitwoodiella ovofilamenta + SX, Contortylenchus spp. + SX, Culicimermis spp. + SX, Diplotriaena spp. + SX, Empidomermis spp. + SX, Filipjevimermis leipsandra + SX, Gastromermis spp. + SX, Gongylonema spp.) + SX, Gynopoecilia pseudovipara + SX, Heterorhabditis bacteriophora + SX, Heterorhabditis baujardi + SX, Heterorhabditis downesi + SX, Heterorhabditis heliothidis + SX, Heterorhabditis indica + SX, Heterorhabditis marelatus + SX, Heterorhabditis megidis + SX, Heterorhabditis zealandica + SX, Hexamermis spp. + SX, Hydromermis spp. + SX, Isomermis spp. + SX, Limnomermis spp. + SX, Maupasina weissi + SX, Mermis nigrescens + SX, Mesomermis spp. + SX, Neomesomermis spp. + SX, Neoparasitylenchus rugulosi + SX, Octomyomermis spp. spp.) + SX, Parasitaphelenchus spp.) + SX, Parasitorhabditis spp.) + SX, Parasitylenchus spp.) + SX, Perutilimermis culicis + SX, Phasmarhabditis hermaphrodita isolate DDT M1 + SX, Physaloptera spp. + SX, Protrellatus spp. + SX, Pterygodermatites spp. + SX, Romanomermis spp. + SX, Seuratum cadarachense + SX, Sphaerulariopsis spp. + SX, Spirura guianensis + SX, Steinernema bibionis + SX, Steinernema carpocapsae + SX, Steinernema feltiae isolate DDT D2 + SX, Steinernema glaseri + SX, Steinernema indica + SX, Steinernema kraussei + SX, Steinernema riobrave + SX, Steinernema scapterisci + SX, Steinernema scarabaei + SX, Steinernema siamkayai + SX, Steinernema thailandse + SX, Steinernema spp.) + SX, Strelkovimermis peterseni + SX, Subulura spp. + SX, Sulphuretylenchus elongatus + SX, Tetrameres spp. + SX.

[0098] Subgroup (j-6): Combination of the present component of a natural product and the present compound: (2S,3R,4R,5S)-2,5-bis(hydroxymethyl)pyrrolidine-3,4-diol + SX, 1,4-dimethylnaphthalene + SX, 2-methyl-1-butanol + SX, 2-phenylethyl propionate + SX, 9,21-didehydroryanodine + SX, alizarin 2-glucoside + SX, dihydroazadirachtin + SX, ethyl 3-[acetyl(butyl)amino]propanoate + SX, glycerol monocaprate + SX, glycerol monocaprylate + SX, glycerol monolaurate + SX, heptyl butyrate + SX, methyl anthranilate + SX, methyl nonyl ketone + SX, methyl Salicylate + SX, N-(3-methyl-2-buten-1-yl)-9H-purin-6-amine + SX, N,N'-diformylurea + SX, octanal + SX, oxypurinol + SX, p-cymene + SX, p-menthane-3,8-diol + SX, phenazine-1-carboxylic acid + SX, propylene glycol monocaprylate + SX, propylene glycol monolaurate + SX, sorbitol octanoate + SX, sucrose octanoate + SX, terpinen-4-ol + SX, balsam fir oil (Abies balsamea oil) + SX, α-ionone + SX, β-citronellol + SX, gamma-Terpinene + SX, ammonium bicarbonate + SX, anabasine + SX, anise oil + SX,Ascaridole + SX, azadirachtin + SX, bark of Celastrus angulatus + SX, mustard (Brassica juncea) + SX, brassinolide + SX, Cry1Ab protein from Bacillus thuringiensis + SX, Cry1Ac protein from Bacillus thuringiensis + SX, Cry1Fa protein from Bacillus thuringiensis + SX, Cry1A.105 protein from Bacillus thuringiensis + SX, Bacillus Cry2Ab protein from Bacillus thuringiensis + SX, Vip3A protein from Bacillus thuringiensis + SX, mCry3A protein from Bacillus thuringiensis + SX, Cry3Ab protein from Bacillus thuringiensis + SX, Cry3Bb protein from Bacillus thuringiensis + SX,Cry34Ab1 / Cry35Ab1 protein derived from Bacillus thuringiensis + SX, insecticidal protein Tma12 derived from Tactaria macrodonta + SX, insecticidal protein IPD083 derived from Adiantum spp. + SX, insecticidal protein IPD113 derived from Pteris cretica cv. albolineata or Pteris umbrosa + SX, calcium acetate + SX, calcium lactate + SX, calcium polysulfide + SX, canola oil + SX, capsaicin + SX, Capsicum oleoresin + SX, castor oil + SX, cedarwood oil + SX, cevadine + SX, chitin + SX, chitosan + SX, chlorophyllin + SX, chlortetracycline + SX, cinerin I + SX, cinerin II + SX, cinnamaldehyde + SX, cis-jasmone + SX, citral + SX, citric acid + SX,Citronella oil + SX, Citrus bergamia fruit oil + SX, clarified hydrophobic extract of neem oil + SX, Clove oil + SX, Collagen protein hydrolysate + SX, Colletochlorin B + SX, Concanamycin A + SX, Cottonseed oil + SX, Cytokinin + SX, Cow's milk + SX, Deguelin + SX, Diallyl sulfide + SX, d-limonene + SX, Dried leaves of Dryopteris filix-mas + SX, Ea peptide 91398 + SX, eucalyptol + SX, black wattle extract + SX, Achillea fragrantissima extract + SX, onion extract + SX, garlic extract + SX, dill extract + SX, Annona squamosa extract + SX, burdock extract + SX, Artemisia absinthium extract + SX, jackfruit extract + SX,extract of Azadirachta indica + SX, extract of Calendula officinalis + SX, extract of Camelia sinensis + SX, extract of Capsicum annuum + SX, extract of Cassia nigricans + SX, extract of Chenopodium ambrosioides + SX, extract of Chenopodium quinoa + SX, extract of Cinnamomum verum + SX, extract of Clitoria ternatea + SX, extract of the cotyledons of lupine plantlets ("BLAD") + SX, extract of Daphne gnidium Daphne gnidium) + SX, extract of Equisetum arvense + SX, extract of Equisetum giganteum + SX, extract of Galenia africana + SX, extract of green tea + SX, extract of Liliaceae plant Liliaceae) + SX, extract of Macleaya + SX, extract of Matricaria chamomilla + SX, extract of Melaleuca alternifolia + SX, extract of Millettia pinnata + SX,Extract of Opuntia lindheimeri + SX, Extract of Origanum vulgare + SX, Extract of Piper auritum + SX, Extract of Pyrethrum, Extract of Quercus falcata + SX, Extract of Quillaja saponaria + SX, Extract of Reynoutria sachalinensis + SX, Extract of Rhamnus utilis + SX, Extract of Rhus aromatica + SX, Extract of Rheum officinale + SX, Extract of Rhizophora mangle + SX, Extract of Rosemary Rosmarinus officinalis + SX, extract of Ruta chalepensis + SX, extract of Schoenocaulon spp. seed + SX, extract of Sweet lupin seed + SX, extract of Swinglea glutinosa + SX, extract of Symphytum officinale + SX, extract of Sweet lupinseed + SX, extract of Tagetes erecta + SX, extract of Tanacetum vulgare + SX, extract of Thymus vulgaris + SX,extract of Tropaeolum majus + SX, extract of Urtica dioica + SX, extract of Viscum album + SX, extract of Yucca schidigera + SX, fenugreek seed powder + SX, fish oil + SX, formic acid + SX, geraniol + SX, ginkgolide A + SX, ginkgolide B + SX, ginkgolide C + SX, ginkgolide J + SX, ginkgolide M + SX, gougerotin + SX, GS-omega / kappa HXTX-Hv1a peptide + SX, Harpin protein + SX, hydrogenated castor oil + SX, hydroprene + SX, Illicium verum oil + SX, ivermectin + SX, jasmolin I + SX, jasmolin II + SX, Jojoba oil + SX, Karanjin + SX, kasugamycin + SX, kinoprene + SX, Laminarine + SX, L-ascorbic acid + SX, Oak leaves and bark of Quercus + SX, Lemongrass oil + SX, L-glutamic acid + SX, Linalool + SX,Linseed oil + SX, Lobularia maritima + SX, lysophosphatidylethanolamine + SX, maltodextrin + SX, matrine + SX, matrine N-oxide + SX, menthol + SX, methoprene + SX, Milbemycin A4 + SX, Mildiomycin + SX, Natamycin + SX, Nemadectin + SX, Nepeta cataria oil + SX, Nootkatone + SX, Oil of the seeds of Chenopodium anthelminticum + SX, Orange oil + SX, Pelargonium odoratissimum oil + SX, Pellitorine + SX, Piperine + SX, Piper nigrum seed oil + SX, Polyoxin B + SX, Polyoxorim + SX, potassium phosphonate + SX, potassium silicate + SX, precocene II + SX, putrescent whole egg solids + SX, pyrethrin I + SX, pyrethrin II + SX, Quillaja extract + SX, rotenone + SX, rapeseed oil + SX, rhamnolipid + SX, ryanodine + SX, rosemary oil + SX, Sabadilla + SX, salicylic acid + SX, sanguinarine + SX, Saponins of Chenopodium quinoa + SX, Sesame oil + SX, Soy lecithin + SX,soybean oil + SX, spinosad + SX, squamocin + SX, streptomycin + SX, sunflower oil + SX, Tagetes oil + SX, terpene constituents of the extract of chenopodium ambrosioides near ambrosioides, Brand name: Terpenoid blend QRD 460 + SX, thyme oil + SX, thymol + SX, trypsin modulating oostatic factor + SX, veratrine + SX, veratridine + SX, wood extract of Quassia amara + SX, Xanthine + SX, yellow mustard powder + SX.,

[0099] Subgroup (j-7): Combination of the present compound with the present ingredient of insects: Adalia bipunctata + SX, Amitus hesperidum + SX, Amitus spiniferus + SX, Anagrus atomus + SX, Anagrus epos + SX, Anagyrus fusciventris + SX, Anagyrus fusciventris + SX, Anagyrus pseudococci + SX, Anaphes flavipes + SX, Anaphes iole + SX, Anaphes nitens + SX, Anastatus tenuipes + SX, Anthocoris nemoralis + SX, Aphelinus abdominalis + SX, Aphelinus asychis + SX, Aphelinus mali + SX, Aphelinus semiflavus + SX, Aphidius colemani + SX, Aphidius ervi + SX, Aphidius gifuensis + SX, Aphidius matricariae + SX, Aphidius smithi + SX, Aphidius aphidimyza + SX, Aphytis holoxanthus + SX, Aphytis lepidosaphes + SX, Aphytis lignanensis + SX, Aphytis melinus + SX, Aphytis mytilaspidis + SX, Apion fuscirostre + SX, Apion ulicis + SX, Aprostocetus hagenowii + SX, Avetianella longoi + SX, Bangasternus orientalis + SX, Bathyplectes anurus + SX, Bathyplectes curculionis + SX, Bracon cushmani + SX,Bracon gelechiae + SX, Bracon hebetor + SX, Cales noacki + SX, Calosoma sycophanta + SX, Carcinops pumillio + SX, Catolaccus grandis + SX, Cephalonomia tarsalis + SX, Chilocorus baileyi + SX, Chilocorus bipustulatus + SX, Chilocorus circumdatus + SX, Chilocorus kuwanae + SX, Chilocorus nigritus + SX, Chilocorus stigma + SX, Chrysoperla carnea + SX, Chrysoperla rufilabris + SX, Clitostethus arcuatus + SX, Coccidoxenoides perminutus + SX, Coccophagus cowperi + SX, Coccophagus lycimnia + SX, Coenosia attenuata + SX, Coleomegilla maculata + SX, Comperia merceti + SX, Comperiella bifascita + SX, Copidosoma floridanum + SX, Copidosoma truncatellum + SX, Cotesia flavipes + SX, Cotesia glomerata + SX, Cotesia marginiventris + SX, Cotesia medicaginis + SX, Cotesia melanoscela + SX, Cotesia plutellae + SX, Cotesia ruficrus + SX, Cryptolaemus montrouzieri + SX, Cybocephalus nipponicus + SX,Dacnusa sibirica + SX, Dalotia coriaria + SX, Delphastus catalinae + SX, Delphastus pusillus + SX, Dendrolimus punctatus + SX, Deraeocoris brevis + SX, Diaeretiella rapae + SX, Dicyphus hesperus + SX, Diglyphus isaea + SX, Encarsia aurantii + SX, Encarsia formosa + SX, Encarsia inaron + SX, Encarsia opulenta + SX, Encarsia perplexa + SX, Ephedrus cerasicola + SX, Episyrphus balteatus + SX, Eretmocerus eremicus + SX, Eretmocerus mundus + SX, Feltiella acarisuga + SX, Franklinothrips megalops + SX, Franklinothrips orizabensis + SX, Franklinothrips vespiformis + SX, Geocoris punctipes + SX, Glyptapanteles liparidis + SX, Goniozus legneri + SX, Harmonia axyridis + SX, Hippodamia convergens + SX, Hyposoter exiguae + SX, Hyposoter fugitivus + SX, Lariophagus distinguendus + SX, Leptomastidea abnormis + SX, Leptomastix algirica + SX, Leptomastix dactylopii + SX,Leptomastix epona + SX, Lydella thompsoni + SX, Lysiphlebus testaceipes + SX, Macrocentrus ancylivorus + SX, Macrocentrus iridescens + SX, Macrolophus pygmaeus + SX, Mallada signata + SX, Metaphycus bartletti + SX, Metaphycus californicus + SX, Metaphycus flavus + SX, Metaphycus funicularis + SX, Metaphycus helvolus + SX, Metaphycus luteolus + SX, Metaphycus stanleyi + SX, Meteorus autographae + SX, Meteorus laphygmae + SX, Meteorus pulchricornis + SX, Meteorus trachynotus + SX, Metoecus paradoxus + SX, Microctonus aethiopoides + SX, Red-bellied toad (Micromus angulatus) + SX, Micromus tasmaniae + SX, Micromus variegatus + SX, Microplitis brassicae + SX, Microplitis plutellae + SX, Microterys flavus + SX, Muscidifurax raptor + SX, Muscidifurax raptorellus + SX, Nabis kinbergii + SX, Necremnus artynes ​​+ SX, Neochrysocharis formosa + SX, Neodryinus typhlocybae + SX, Nesidiocoris tenuis + SX, Orius albidipennis + SX, Orius armatus + SX, Orius insidiosus + SX, Orius laevigatus + SX,Orius majusculus + SX, Orius niger + SX, Orius strigicollis + SX, Orygia pseudotsugata + SX, Pediobius foveolatus + SX, Pentalitomastix plethorica + SX, Pnigalio flavipes + SX, Podisus maculiventris + SX, Praon volucre + SX, Pseudaphycus maculipennis + SX, Psyllaephagus pilosus + SX, Rhapalosiphum padi + SX, Rhizophagus grandis + SX, Rhyzobius forestieri + SX, Rhyzobius lophantae + SX, Bedariia tentacles (Rodolia cardinalis) + SX, Scolothrips sexmaculatus + SX, Serangium parcesetosum + SX, Spalangia cameroni + SX, Spalangia endius + SX, Stethorus punctillum + SX, Sympiesis stigmata + SX, Telenomus podisi + SX, Tenodera sinensis + SX, Tetrastichus brevistigma + SX, Tetrastichus gallerucae + SX, Tetrastichus howardi + SX, Tetrastichus setifer + SX, Thripobius semiluteus + SX, Torymus sinensis + SX, Trichogramma achaeae + SX, Trichogramma brassicae + SX, Trichogramma evanescens + SX, Trichogramma minutum + SX, Trichogramma ostriniae + SX, Trichogramma platneri + SX,Trichogramma pretiosum + SX, Trichogramma semifumatum + SX, Trichogrammatoidea bactrae + SX, Trichopoda pennipes + SX, Trioxys complanatus + SX, Trioxys curvicaudus + SX, Trioxys pallidus + SX, Trioxys tenuicaudus + SX, Trissolcus bathos + SX, Vairimorpha necatrix + SX, Volucella inanis + SX, Voria ruralis + SX, Squid (Xylocoris flavipes) + SX, Zelus renardii + SX.

[0100] Material (j-8): Details and designs of the fish: Amblydromalus limonicus + SX, Amblyseius andersoni + SX, Amblyseius barkeri + SX, Amblyseius californicus + SX, Amblyseius cucumeris + SX, Amblyseius degenerans + SX, Amblyseius montdorensis + SX, Amblyseius swirskii + SX, Amblyseius womersleyi + SX, Anystis agilis + SX, Cheyletus eruditus + SX, Euseius gallicus + SX, Euseius stipulatus + SX, Euseius tularensis + SX, Gaeolaelaps gillespiei + SX, Galendromus annectens + SX, Galendromus helveolus + SX, Galendromus occidentalis + SX, Hypoaspis aculeifer + SX, Hypoaspis miles + SX, Macrocheles robustulus + SX, Mesoseiulus longipes + SX, Neoseiulus fallacis + SX, Phytoseiulus macropilis + SX, Phytoseiulus persimilis + SX, Thyreophagus entomophagus + SX, Typhlodromus pyri + SX。

[0101] Subgroup (j-9): Combination of the present component of mollusks and the present compound: Rumina decollata + SX。

[0102] The component selected from group (j) is usually prepared by a method known in the art. For example, in the case of (j-1) bacteria or (j-2) fungi / yeast, it is prepared by a medium and a fermentation method known in the art. In the case of (j-1) bacteria or (j-2) fungi / yeast, the preparation is prepared at a concentration of 1×10 per gram. 4 ~1×10 13 CFU (colony forming units), preferably 1 x 10 8 ~1×10 12 CFU of the component. If the component is a (j-4) virus, the preparation contains 1 x 10 4 ~1×10 13 Occlurion bodies (sometimes written as Obs), preferably 1×10 8 ~1×10 12 The ingredient contains occlurion bodies (sometimes written as Obs). When the ingredient is (j-5) nematodes, the preparation contains 1 × 10 4 ~1×10 13 Individual, preferably 1 x 10 8 ~1×10 12 Contains solid components.

[0103] This compound can be mixed or used in combination with chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.).

[0104] The weight ratio of the application amount of the present compound to the application amount of the present component in composition A is not particularly limited, but can be appropriately adjusted to an optimal weight ratio depending on the type of plant to be protected, the type and occurrence frequency of harmful arthropods, harmful nematodes, harmful mollusks, plant pathogenic microorganisms or weeds to be controlled, the formulation form, application time, application method, application location, weather conditions, etc. For example, in the agricultural field, when applied to plants (particularly, stems and leaves, seeds, and vegetative reproductive organs) or when applied to a cultivation carrier for cultivating plants (particularly, soil), the following weight ratios can be mentioned. The weight of the present component selected from group (j) means the weight of the preparation. For example, a weight ratio of 1:500 means that the application amount of the preparation of one or more components selected from group (j) is 500 parts by weight per 1 part by weight of the present compound.

[0105] Weight ratio [(this compound):(this component)] = 1:10^15 to 10^15:1, specifically, for example, approximately, 1:10^15, 1:10^14, 1:10^13, 1:10^12, 1:10^11, 1:10^10, 1:10^9, 1:10^8, 1:10^7, 1:10^6, 1:10^5, 1:10000, 1:9000, 1:8000, 1:7000, 1:6000, 1:5000, 1:4000, 1:3000, 1:2000, 1:1000, 1:900, 1:800, 1:700, 1:600, 1:500 ,1:400,1:350,1:300,1:250,1:200,1:150,1:100,1:90,1:80,1:70,1:60,1:50,1:40,1:30,1:20,1:19,1:18,1:17,1:16,1:15,1:14,1:13,1:12,1:11,1:10,1:9,1:8,1:7,1:6,1:5,2:9,1:4,2:7,3:10,1:3,3:8,2:5,3:7,4:9,1:2,5:9,4:7,3:5,5:8,2:3,7:10,5:7,3:4,7:9, 4:5, 5:6, 6:7, 7:8, 8:9, 9:10, 1:1, 10:9, 9:8, 8:7, 7:6, 6:5, 5:4, 9:7, 4:3, 7:5, 10:7, 3:2, 8:5, 5:3, 7:4, 9:5, 2:1, 9:4, 7:3, 5:2, 8:3, 3:1, 10:3, 7:2, 4:1, 9:2, 5:1, 6:1, 7:1, 8:1, 9:1, 10:1, 11:1, 12:1, 13:1, 14:1, 15:1, 16:1, 17:1, 18:1, 19:1, 20:1, 30:1, 40:1, 50:1, 60:1, 70:1 , 80:1, 90:1, 100:1, 150:1, 200:1, 250:1, 300:1, 400:1, 500:1, 600:1, 700:1, 800:1, 900:1, 1000:1, 2000:1, 3000:1, 4000:1, 5000:1, 6000:1, 7000:1, 8000:1, 9000:1, 10000:1, 10^5:1, 10^6:1, 10^7:1, 10^8:1, 10^9:1, 10^10:1, 10^11:1, 10^12:1, 10^13:1, 10^14:1, 10^15:1. Here, the caret symbol "^" is an operator that indicates exponentiation. For example, "10^5" means "10 5" (i.e., 10 to the power of 5). In the preceding paragraph, "approximately" includes a range of ratios that are 10% higher or lower by weight from the specified ratio. For example, "approximately 1:2" includes a range of 1:1.8 to 1:2.2.

[0106] The present compound or composition A is usually used as a composition further containing an inert carrier (hereinafter referred to as composition B). Composition B is usually prepared by mixing the present compound or composition A with a solid carrier, a liquid carrier, a surfactant, etc., and adding formulation auxiliary agents such as binders, dispersants, stabilizers, and gases as necessary to prepare aqueous suspension preparations, oil suspension preparations, emulsifiable concentrates, emulsion preparations, microemulsion preparations, microcapsule preparations, wettable powders, wettable granules, dusts, granules, tablets, aerosols, resin preparations, etc. ... B can be used by formulating the present compound or composition B into the dosage form described in the Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271 to 276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2016, ISSN:0259-2517, without being limited to these formulations. Composition B may also be processed into, for example, sprays (aerosols, pump sprays, ultrasonic vibration preparations, electrostatic spray preparations, etc.), poison baits, combustion agents (incense sticks, etc.), heat-transmitting agents (electric mosquito mats, liquid mosquito preparations, etc.), air-blowing transmitting agents (fan-type mosquito preparations, etc.), fumigants (self-burning fumigants, chemical reaction fumigants, porous ceramic plate fumigants, etc.), fumigants, aerosols, ULV agents, mist agents, foam agents, paste-like preparations, paints, wood protection paints, sealants, carbon dioxide preparations, sheet preparations, tape preparations, paper preparations, nonwoven fabric preparations, animal collars, animal ear tags, shampoos, spot-on preparations, pour-on preparations, suppositories, injections, oral treatments (capsules, tablets, chewable preparations, feed, etc.), sublimation tablets, mosquito nets, attractant strings, gardening posts, and screen doors for use. These preparations contain the present compound in an amount of usually 0.0001 to 99%, preferably 0.1 to 99%, and more preferably 0.2 to 90% by weight.

[0107] When the present compound or composition A is formulated into an aqueous suspension preparation, an oil suspension preparation, a wettable powder, or a wettable powder, the particle size of the present compound or composition A is usually in the range of 0.1 to 20 μm, preferably 0.2 μm to 15 μm. When the present compound or composition A is formulated into a granule, the particle size of the present compound or composition A is usually in the range of 0.1 to 200 μm, preferably 0.5 μm to 100 μm. The particle size of the present compound or composition A means a particle size (volume median size) that is 50% cumulative in a volume-based frequency distribution, and can be determined by wet measurement using a laser diffraction particle size distribution measuring device. An example of a laser diffraction particle size measuring device is the Mastersizer 3000 manufactured by Malvern Instruments. The cumulative frequency in the volume-based frequency distribution can be expressed based on any percentage other than the median (50%), and a preferred range can be expressed as "volume 40% diameter 2.5 μm to volume 60% diameter 2.5 μm", etc. Also, it can be expressed by weight median diameter other than volume median diameter, and further it can be expressed by any percentage.

[0108] Examples of solid supports include the following: Inorganic substances: minerals (natural silicates, marble, pumice, limestone, rare earth minerals, cryolite, activated clay, lime, activated carbon, talc, attapulgite, sodium montmorillonite, calcium montmorillonite, kaolinite, calcite, dolomite, diatomite, bentonite, zeolite, sepiolite, pyrophyllite, vermiculite, crystalline silica, amorphous silica, etc.), silicon dioxide, calcium sulfate, magnesium sulfate, barium sulfate, magnesium oxide, aluminum oxide, ammonium sulfate, ammonium phosphate, ammonium nitrate, calcium phosphate, sulfur, calcium carbonate, sodium bicarbonate, sodium carbonate, synthetic silicates, and their crushed products; Organic matter: Grain powders (rice bran, rice flour, corn flour, wheat flour, etc.), sugars (cellulose, starch, lactose, glucose, fructose, sucrose, etc.), plant-derived powders (ground nut shells (ground nut shells of coconut, walnut, peanut, etc.), tree-derived powders (bark powder and sawdust, etc.), other plant powders (tobacco stems, soybeans, cottonseed husks, etc.)), lignin, wax, shells, urea, polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenolic resin, melamine resin, epoxy resin. The above solid carriers can also be used as adsorption carriers.

[0109] Examples of liquid carriers include water, aliphatic hydrocarbons (hexane, 1-hexene, cyclohexane, octane, isooctane, 1-heptene, d-limonene, pinene, hexadecane, etc.), Aromatic hydrocarbons (alkylbenzenes (toluene, xylene, isopropylbenzene, p-diethylbenzene, etc.), alkylbenzene derivatives, alkylnaphthalenes, alkylnaphthalene derivatives, tetrahydronaphthalene, etc.), chlorinated hydrocarbons (monochloroethylene, dichloroethylene, trichloroethylene, tetrachloroethylene, dichloromethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane, 1,2-dichloropropane, etc.), ketones (cyclohexanone, acetone, 2-heptanone, isophorone, mesityl oxide, methyl isoamyl ketone, methyl ethyl ketone, methyl isobutyl ketone, acetophenone, diacetone alcohol, methylcyclohexanone, etc.), esters (fatty acid esters (ethyl acetate, butyl acetate, amyl acetate, isoamyl acetate, isobornyl acetate, hexyl acetate, heptyl acetate, octyl acetate, isopropyl myristate, methyl octanoate, methyl oleate, methyl laurate, dibutyl adipate, tributyl citrate, dibutyl phthalate, etc.), lactate esters (ethyl lactate, propyl lactate, etc.), carbonate esters (ethylene carbonate, propylene carbonate, butylene carbonate, diethyl carbonate, dibutyl carbonate, etc.), esterified polyols (glycerol acetate, glycol acetate, glycerin monoacetate, glycerin diacetate, glycerin triacetate, diethylene glycol abietate, dipropylene glycol dibenzoate, dipropylene glycol monomethyl ester, etc.), lactones (γ-butyl lactone, etc.), ethers (1,4-dioxane, tetrahydrofuran, dipropylene glycol methyl ether, ethylene glycol methyl ether, propylene glycol methyl ether, etc.), amides (N-octyl-caprolactam, N-dodecyl-caprolactam, N,N-dimethylformamide, fatty acid dimethylamides (N,N-dimethylacetamide, N,N-dimethyldecanamide, N,N-dimethyloctaneamide, etc.), alkylpyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone, N-dodecylpyrrolidone, etc.), lactams (α-lactam, β-lactam, γ-lactam, δ-lactam, etc.), amines (octylamine, octylamine acetate, oleylamine, diethanolamine, laurylamine, etc.), alcohols (methanol, ethanol, butanol, propanol, isopropanol, butanol, amyl alcohol, hexanol, heptanol, octanol, 2-ethylhexanol, etc.), hexylene glycol, cyclohexanol, phenol, benzyl alcohol, methoxypropanol (1-methoxy-2-propanol), tetrahydrofurfuryl alcohol, furfuryl alcohol, polyethylene glycol, ethylene glycol, diethylene glycol, hexylene glycol, ethylene glycol methyl ether, diethylene glycol Lithium methyl ether, diethylene glycol butyl ether, triethylene glycol, propylene glycol methyl ether, dipropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol ether, dipropylene glycol monomethyl ether, glycerin, etc.), mineral oils (naphtha, petroleum ether, kerosene, diesel oil, paraffin, olefin, etc.), oils derived from animals and plants, oils derived from plants (palm oil, rapeseed oil, castor oil, coconut oil, soybean oil and derivatives thereof, etc.), oils derived from animals (sardine oil, saury oil, whale oil and derivatives thereof, etc.), dimethyl sulfoxide, silicone oil, acetonitrile, propanenitrile, acid anhydrides (such as acetic anhydride), triethyl phosphate, oleic acid, propionic acid, lactic acid, xylene sulfonic acid.

[0110] Examples of gaseous carriers include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide gas.

[0111] Examples of the anionic surfactant include carboxylic acids, sulfonic acids, sulfates, and phosphates. Specific examples include the following: Carboxylic acids: fatty acid salts (octanoates, decanoates, laurates, myristates, palmitates, stearates, behenates, oleates, polyoxyethylene alkyl ether carboxylates (laureth-3-carboxylate, α-(carboxymethyl)-ω-(dodecyloxy)poly(oxyethylene) salts, etc.), N-acyl sarcosine salts (N-lauroyl sarcosine salts, etc.), N-acyl glutamates (N-lauroyl glutamates, etc.), polycarboxylates (polyacrylates, polyvinyl acetates, comb-type polymers of polyacid salts, and their derivatives, etc.), sulfonic acids: alkyl sulfonic acids and their salts (dodecyl sulfonates, etc.), alpha olefins, etc. sulfonates (alkene (C14-18) hydroxysulfonates, alkapolyene (C12-20) hydroxysulfonates, alkenes (C14-18) hydroxysulfonates, alkenes (C12-20) hydroxysulfonates, tetradecene-1-sulfonates, α-olefins (C14-16) sulfonates, etc.), alkylbenzenesulfonates (decylbenzenesulfonates, dodecylbenzenesulfonates, tridecylbenzenesulfonates, diphenylsulfonates, etc.), alkylnaphthalenesulfonates (naphthalenesulfonates, 6-methyl-2-naphthalenesulfonates, dibutylnaphthalenesulfonates, 2,2'-dinaphthylmethane-6,6'-disulfonates, diisopropyl naphthalene sulfonates, triisopropyl naphthalene sulfonates, 1-isopropyl 2-naphthalene sulfonates, etc.), sulfosuccinic acid, monoalkyl sulfosuccinates, dialkyl sulfosuccinates, (di(2-ethylhexyl) sulfosuccinate, etc.), N-methyl-N-acyltaurates (oleoyl methyl taurate, etc.), lignin sulfonates, alkylphenol sulfonates, naphthalene sulfonate-formaldehyde condensates, benzimidazole sulfonates and their derivatives, sulfates, alkyl sulfates (hexyl sulfate, heptyl sulfate, octyl sulfate, lauryl sulfate, diethanolamine sulfate, etc.), salts, hexadecyl sulfate, octadecyl sulfate, etc.), polyoxyethylene alkyl ether sulfate and its salts (laureth-3 sulfate, polyoxyethylene monotridecyl ether sulfate, α-sulfo-ω-hydroxyalkyl (C6-10) ether poly(oxyethylene) salts, etc.), polyoxyethylene alkyl phenyl ether sulfates (poly(oxyethylene) 2-decyl phenyl ether sulfate, poly(oxyethylene) 3-decyl phenyl ether sulfate, α-sulfo-ω-[2,4-bis(1,1,3,3-tetramethylbutyl)phenoxy]poly(oxyethylene) salts, etc.), polyoxypropylene alkyl ether sulfates, lignosulfite waste liquor, and derivatives thereof; Phosphate esters: alkyl phosphates (propyl phosphate, hexadecyl phosphate, lauryl phosphate, dioctyl phosphate, etc.), polyoxyethylene alkyl ether phosphates (polyoxyethylene decyl phosphate, α-phosphono-ω-butoxypoly(oxyethylene), etc.), polyoxyethylene alkyl phenyl ether phosphates (α-(dinonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(dodecylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(nonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, etc.), polyoxypropylene alkyl ether phosphates, and derivatives thereof.

[0112] Examples of cationic surfactants include amine salts and quaternary ammonium salts, and specific examples thereof include the following: Amine salts: alkylamine salts (monomethylamine salts, dimethylamine salts, trimethylamine salts, etc.), fatty acid amidoamine salts (stearamidopropyldimethylamine, behenamidopropyldimethylamine, etc.), polyamine salts (polyvinylamine, polyethyleneimine, etc.), and derivatives thereof; Quaternary ammonium salts: lauryltrimethylammonium salt, cetyltrimethylammonium salt, dodecyltrimethylammonium salt, stearyltrimethylammonium salt, benzalkonium chloride, benzethonium chloride, benzylbis(2-chloroethyl)ethylammonium bromide salt.

[0113] Examples of amphoteric surfactants include betaine, alkyl betaine, alkyl dimethyl betaine, imidazoline, taurine, alkyl taurine, dodecyl dimethyl ammonio acetate, 4-carboxy-N,N,N-trimethyl-1-butanaminium, 1-carboxy-N,N,N-2-tetramethyl-1-propanaminium, N-alkyl (or alkenyl) (C12-18) glycine and its salt, N-dodecyl glycine and its salt, and derivatives thereof.

[0114] Examples of the nonionic surfactant include alcohols, amides, amines, esters, ethers, ether esters, and carboxylic acids. Specific examples include the following: Alcohols: aromatic alcohols (alkylphenols (allylphenol, octylphenol, nonylphenol, octylcresol, etc.), acylphenols, etc.), aliphatic alcohols (isotridecyl alcohol, oleyl alcohol, cetyl alcohol, etc.), polyhydric alcohols (polysaccharides, starch, starch derivatives, sucrose, alkyl polyglucosides, sorbitan, ethoxylated sorbitan, cellulose derivatives, gum arabic, etc.), synthetic polymers (polyvinyl alcohol, polyethylene glycol, etc.); Amides: alkanolamides (fatty acid alkanolamides (lauric acid diethanolamide, etc.), fatty acid glucamides (alkoxylated propylene oxide fatty acid glucamides, etc.), alkoxylated amides (polyoxyethylene oleic acid amide, polyoxyethylene stearic acid amide, etc.), synthetic polymers (polyvinylpyrrolidone, etc.), Amines: alkoxylated amines (polyoxyethylene oleylamine, α,α'-[(9-octadecenylimino)di2,1-ethanedyl]bis(ω-hydroxy)polyoxyethylene, etc.); Esters: fatty acid esters (polyol fatty acid esters, monoglycerides, phospholipids, etc.), sugar-derived esters (sucrose fatty acid esters (sucrose stearate diester, etc.), sorbitan fatty acid esters (sorbitan oleate monoester, etc.), glucose esters, cellulose esters, etc.), synthetic polymers (vinyl acetate copolymers, polymethacrylic acid, copolymers of methacrylic acid and methacrylic acid esters, etc.); Ethers: alcohol ethoxylates (fatty alcohol ethoxylates (tridecyl alcohol ethoxylate, isooctyl alcohol ethoxylate, lauryl alcohol ethoxylate, hexadecyl alcohol ethoxylate, stearyl alcohol ethoxylate, etc.)), alkylphenol ethoxylates (nonylphenol ethoxylate, tristyrylphenol ethoxylate, tributylphenol ethoxylate, octylphenol ethoxylate, etc.), arylalkylphenol ethoxylates, arylphenol ethoxylates (monobenzylbiphenol alcohol ethoxylate, etc.), alcohol propoxylates (fatty alcohol propoxylates, alkylphenol propoxylates, arylalkylphenol propoxylates, etc.), block polymers (block polymers of polyethylene oxide and polypropylene oxide, polyethylene oxide block polymers, polypropylene oxide block polymers, block polymers of alkanol, polyethylene oxide and polypropylene oxide, etc.); Ether esters: polyoxyethylene fatty acid esters (polyoxyethylene castor oil esters, polyoxyethylene stearate esters, polyoxyethylene beef tallow fatty acid esters, etc.), polyoxyethylene sorbitan fatty acid esters (polyoxyethylene sorbitan monooleate esters, polyoxyethylene sorbitan trioleate esters, polyoxyethylene sorbitan monolaurate esters, polyoxyethylene sorbitan stearate esters, etc.), polyoxyethylene fatty acid amine esters, polyoxyethylene rosin esters, polyoxypropylene fatty acid esters (polyoxypropylene castor oil esters, etc.), polyoxypropylene fatty acid amine esters; Carboxylic acids: Undecafluorohexanoic acid.

[0115] Other formulation adjuvants include, for example, thickeners, antifreeze agents / humectants, antifoaming agents, antioxidants, pH adjusters, colorants, preservatives / bactericides, binders, adhesives / spreaders, lubricants / lubricants, anti-caking agents, light stabilizers, fragrances, propellants, fertilizers, film-forming agents, deodorants, plasticizers, desiccants / moisture-proofing agents, fumigation auxiliary materials, attractants, encapsulating agents, and efficacy enhancers. Specific examples include the following. Thickeners: polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose and its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, carrageenan, etc.), clays (organic clays, organically modified clays, inorganic clays, inorganically modified clays, etc.), minerals (bentonite, attapulgite, silica, silicates, etc.), synthetic polymers (polycarboxylates, polyacrylic acid derivatives, polyvinylpyrrolidone, polyvinyl alcohol, etc.); Antifreeze agents and moisturizers: alcohols (ethylene glycol, propylene glycol, dipropylene glycol, triethylene glycol, ethylene glycol methyl ether, propylene glycol methyl ether, dipropylene glycol methyl ether, ethylene glycol butyl ether, glycerin, polyethylene glycol, etc.), esters (dipropylene glycol dibenzoate, glycerol acetate, glycerol diacetate, glycerol triacetate, gamma-butyrolactone, etc.), ethers (1,4-dioxane, etc.), urea; Antifoaming agents: silicones (polysiloxane, diblock ethoxyl siloxane, triblock ethoxyl siloxane, etc.), alkyl sulfosuccinates, higher alcohols, higher alcohol derivatives, salts of fatty acids, fatty acid derivatives; Antioxidants: phenols (2,6-di-t-butyl-p-cresol, 2,2'-methylenebis(4-methyl-6-t-butylphenol), etc.), amines (p,p'-dioctyldiphenylamine, N,N'-diphenyl-p-phenylenediamine, etc.), dibutylhydroxytoluene, butylhydroxyanisole, sodium erythorbate, sodium sulfite, potassium sulfite, potassium pyrosulfite, catechin, propyl gallate, sulfurs (didodecyl thiodipropionate, etc.), phosphoric acids (trisnonylphenyl phosphite, etc.), vitamins (alpha tocopherol, L-ascorbic acid, sodium ascorbate, ascorbyl palmitate, etc.); pH adjusters: sulfuric acid, nitric acid, hydrochloric acid, acetic acid, carbonic acid, oxalic acid, lactic acid, succinic acid, gluconic acid, citric acid, phosphoric acid, sorbic acid and their salts, sodium bicarbonate, sodium hydroxide, potassium hydroxide, calcium hydroxide, aluminum hydroxide, copper hydroxide, magnesium hydroxide; Colorants: Monoazo (Pigment Red 48:1, Pigment Red 48:2, Pigment Red 53:1, Pigment Red 57:1, Pigment Red 112, Pigment Brown 25, Cl Solvent Red 1, Pigment Yellow 1, Pigment Orange 5, Acid Red 14, Acid Yellow 23, etc.), disazos (Pigment Yellow 13, Pigment Orange 34, etc.), phthalocyanines (Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Green 7, Pigment Green 36, etc.), anthraquinones (Pigment Red 83, etc.), dioxazines (Pigment Blue 80, etc.), xanthenes (Basic Violet 10 (Rhodamine B), Acid Red 51, Acid Red 52, etc.), triarylmethanes (Acid Blue 9, etc.), Pigment Orange 43, iron oxide, titanium, titanium oxide, zinc oxide, zinc sulfide, hexacyanoferric salt, chrome vermilion, yellow lead, calcium carbonate, baryte powder, aluminum powder; Preservatives and disinfectants: Phenols (orthophenylphenol, thymol, 3,5-dimethyl-4-chlorophenol, etc.), isothiazolinone derivatives (methylisothiazolinone (2-methyl-4-isothiazolin-3-one), chloromethylisothiazolinone (5-chloro-2-methyl-4-isothiazolin-3-one), octylisothiazolinone (2-n-octyl-4-isothiazolin-3-one), dichlorooctylisothiazolinone (4,5-dichloro-2-octyl-4-isothiazolin-3-one), benzisothiazolinone (1,2-benzisothiazolin-3-one), etc.), bronopoly alcohol derivatives (bronopol (2-bromo-2-nitropropane-1,3-diol), etc.), benzyl alcohol hemiformal, isopropyl methylphenol, parabens (methylparaben, ethylparaben, propylparaben, isopropylparaben, butylparaben, isobutylparaben, heptylparaben, benzylparaben), imidazoles (thiabendazole), benzalkonium chloride, glyceryl caprylate, glyceryl caprate, glycerin fatty acid esters, sodium dehydroacetate, hinokitiol, acids (citric acid, phosphoric acid, sorbic acid, salicylic acid, benzoic acid, and their salts, etc.); Binders: polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clays, organically modified clays, inorganic clays, inorganically modified clays), minerals (bentonite), synthetic polymers (polycarboxylic acids or their salts, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salts), waxes (vegetable fats and oils, animal fats and oils, and derivatives thereof, paraffin, olefin, etc.); Fixing agent / spreading agent: the above-mentioned surfactants and liquid carriers (esters (alkyl fatty acid esters, sorbitan fatty acid esters, ethoxylated fatty acid esters, ethoxysorbitan fatty acids, etc.), alcohols (ethoxylated fatty alcohols, ethoxylsorbitan fatty alcohols, etc.), waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefin, etc.), vegetable oils (alkylated vegetable oils, etc.), mineral oils (mineral oils, etc.), silicone emulsions, synthetic polymers (styrene-butadiene copolymers, methyl methacrylate-butadiene copolymers, polyacrylic acid or its salts, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, polypropylene glycol, etc.), natural polymers (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, etc.); Lubricants and lubricants: alcohols, fatty acid esters, sucrose fatty acid esters, glycerin fatty acid esters, hydrocarbons, paraffin, ethylene wax, aliphatic amides, erucic acid amide, stearic acid amide, oleic acid amide, methylene bisstearic acid amide, ethylene bisstearic acid amide, metal soaps, lead stearate, zinc stearate, calcium stearate, magnesium stearate, mineral oil, vegetable oil, kerosene, diesel oil; Anti-caking agents: solid and liquid carriers as mentioned above, calcium phosphate, sodium phosphate, sodium carbonate, sodium silicate, calcium silicate, magnesium silicate, potassium aluminum silicate, silicon dioxide, talc, sodium aluminosilicate, calcium aluminosilicate, bentonite, stearic acid, dimethylpolysiloxane, powdered cellulose; Light stabilizers: titanium dioxide, zinc oxide, activated carbon, carbon black, ethylhexyl methoxycinnamate, tert-butyl methoxydibenzoylmethane, hindered amines, ferulic acid, phenyl hydroxybenzoate, ethyl paraaminobenzoate, octyl salicylate, t-butylphenyl salicylate, 4-tert-octylphenyl salicylate, 2-cyano-3,3-diphenylprop-2-enoic acid-2-ethylhexyl ester (octocrylene), drometrizole trisiloxane, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine (octyl triazone, TEAT), 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol] (MBP), 2-Ethylhexyl paradimethylaminobenzoate (EDB), homomenthyl salicylate (HS), phenylbenzimidazole sulfonic acid (PBS), hydroxymethoxybenzophenone sulfonic acid (oxybenzone 4, OXB4), sodium hydroxymethoxybenzophenone sulfonate (oxybenzone 5, OXB5), sodium dihydroxydimethoxybenzophenone disulfonate (oxybenzone 9, OXB9), tetrahydroxybenzophenone, dihydroxybenzophenone, dihydroxydimethoxybenzophenone, 2-hydroxy-4-methoxybenzophenone, dimethoxybenzylidene dioxoimidazolidinepropionate-2-ethylhexyl, 2,4-dihydroxybenzophenone, bis(2-methoxy-4-hydroxy-5-benzoylphenyl)methane; Fragrance: Hydrocarbons, alpha-limonene, beta-caryophyllene, alcohols, cis-3-hexenol, linalool, farnesol, beta-phenylethyl alcohol, aldehydes, 2,6-nonadenal, citral, alpha-hexylcinnamic aldehyde, ketones, beta-ionone, L-carvone, cyclopentadecanone, esters, linalyl acetate, benzyl benzoate, lactones, gamma-undecalactone, phenols, eugenol, oxides, rose oxide, acetals, phenylacetaldehyde dimethyl acetal, alpha-pinene, beta-pinene; Propellants: liquefied petroleum gas, aliphatic hydrocarbons having 3 to 5 carbon atoms, such as propane, normal butane, isobutane, normal pentane, and isopentane, hydrofluoroolefins, such as trans-1,3,3,3-tetrafluoroprop-1-ene and trans-2,3,3,3-tetrafluoroprop-1-ene, dimethyl ether, nitrogen gas, carbon dioxide gas, nitrous oxide gas, compressed air, and mixtures thereof; Fertilizer: Nitrogenous fertilizer components (urea, ammonium nitrate, magnesium ammonium nitrate, ammonium chloride, ammonium sulfate, ammonium phosphate, sodium nitrate, calcium nitrate, potassium nitrate, lime nitrogen, formaldehyde-modified urea (UF), acetaldehyde-modified urea (CDU), isobutyraldehyde-modified urea (IBDU), guanylyl urea (GU)), phosphate fertilizer components (superphosphate, calcium superphosphate, fused phosphorus, humic acid phosphorus, calcined phosphorus, calcined phosphorus, magnesium superphosphate, ammonium polyphosphate, potassium metaphosphate, calcium metaphosphate, magnesium phosphate, sulfur Ammonium phosphate, potassium ammonium nitrate, ammonium chloride, etc.), potassium fertilizer components (potassium chloride, potassium sulfate, potassium soda sulfate, magnesium sulfate, potassium bicarbonate, potassium phosphate, etc.), silicate fertilizer components (calcium silicate, etc.), magnesium fertilizer components (magnesium sulfate, magnesium chloride, etc.), calcium fertilizer components (quicklime, slaked lime, calcium carbonate, etc.), manganese fertilizer components (manganese sulfate, manganese sulfate, manganese slag, etc.), boron fertilizer components (boric acid, borates, etc.), iron-containing fertilizer components (steel slag, etc.), other fertilizer components (copper, cobalt, zinc, etc.); Film-forming agents: natural rubber, synthetic rubber, resins (styrene butadiene copolymers, polyacrylonitrile, polyesters, polyamides, polyurethanes, polyureas, polyethers, rosin, melamine, etc.), waxes (vegetable fats and oils, animal fats and oils, and derivatives thereof, paraffin, olefins, etc.), polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, starch xanthate, carrageenan, etc.), proteins (gelatin, etc.); Deodorants: organic clays, organic modified clays, unmodified clays, zinc silicate, silica gel; Plasticizers: triethyl phosphate, citrates, phthalates, adipates, sebacates, phosphates; Desiccants and moisture-proofing agents: silica gel, calcium chloride, quicklime, aluminum oxide, zeolite, allophane; Fumigation agents: nitrocellulose, potassium chlorate, calcium oxide, melamine, potassium nitrate, azodicarbonamide; Attractants: starch, cellulose, dextrin, vinegar, alcohol, yeast extract; Inclusion agents: cyclodextrins, α-cyclodextrin, β-cyclodextrin, γ-cyclodextrin; Efficacy enhancers: Liquid carriers and surfactants as described above.

[0116] When the compound or composition A is formulated into an aqueous suspension or oil suspension, a cryoprotectant and / or a preservative is usually added.Preferably, the cryoprotectant is ethylene glycol, propylene glycol, or glycerin.Preferably, the preservative is isothiazolinone derivative (e.g., 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-n-octyl-4-isothiazolin-3-one), and Proxel (1,2-benzisothiazolin-3-one). Ethylene glycol (EG), propylene glycol (PG), glycerin (GL), 2-methyl-4-isothiazolin-3-one (MIT), 5-chloro-2-methyl-4-isothiazolin-3-one (CMIT), 2-n-octyl-4-isothiazolin-3-one (OIT), 4,5-dichloro-2-octyl-4-isothiazolin-3-one (DCOIT), 1,2-benzisothiazolin-3-one (BIT), and 2-bromo-2-nitropropane-1,3-diol (BNPD), which are used as antifreezes and preservatives, are available as commercially available products.

[0117] Examples of combinations of the present compound or composition A with the above-mentioned antifreeze agents or preservatives are given below. SX + EG, SX + PG, SX + GL, SX + MIT, SX + CMIT, SX + OIT, SX + DCOIT, SX + BIT, SX + BNPD, Composition A + EG, Composition A + PG, Composition A + GL, Composition A + MIT, Composition A + CMIT, Composition A + OIT, Composition A + DCOIT, Composition A + BIT, composition A+ BNPD.

[0118] The weight ratio of the present compound or composition A to the above-mentioned antifreeze agent or preservative is in the range of 1:0.0001 to 1:100, for example, 1:0.0001 to 1:1, 1:0.005 to 1:0.01, 1:0.15 to 1:0.35, or 1:0.125 to 1:0.25. Specific weight ratios are 1:0.0001, 1:0.0002, 1:0.0003, 1:0.0004, 1:0.0005, 1:0.0006, 1:0.0007, 1:0.0008, 1:0.0009, 1:0.001, 1:0.002, 1:0.003, 1:0.004, 1:0.005, 1:0.006, 1:0.007, 1:0.008, 1:0.009, 1:0.01, 1:0.02, 1:0.03, 1:0.04, 1:0.05, 1 1:0.06, 1:0.07, 1:0.08, 1:0.09, 1:0.1, 1:0.125, 1:0.15, 1:0.2, 1:0.25, 1:0.3, 1:0.4, 1:0.5, 1:0.6, 1:0.7, 1:0.8, 1:0.9, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:30, 1:40, 1:50, 1:60, 1:70, 1:80, 1:90, 1:100. The above weight ratios can also be expressed as approximately. Approximately means plus or minus 10%, for example, "approximately 1:2" is 1:1.8 to 1:2.2.

[0119] Examples of combinations of the present compound or composition A with the above-mentioned antifreeze agents and preservatives are given below. SX + EG + MIT, SX + EG + CMIT, SX + EG + OIT, SX + EG + DCOIT, SX + EG + BIT, SX + EG + BNPD, SX + PG + MIT, SX + PG + CMIT, SX + PG + OIT, SX + PG + DCOIT, SX + PG + BIT, SX + PG + BNPD, SX + GL + MIT, SX + GL + CMIT, SX + GL + OIT, SX + GL + DCOIT, SX + GL + BIT, SX + GL + BNPD, Composition A + EG + MIT, Composition A + EG + CMIT, Composition A + EG + OIT, Composition A + EG + DCOIT, Composition A + EG + BIT, Composition A + EG + BNPD, composition A + PG + MIT, composition A + PG + CMIT, Composition A + PG + OIT, Composition A + PG + DCOIT, Composition A + PG + BIT, Composition A + PG + BNPD, Composition A + GL + MIT, Composition A + GL + CMIT, Composition A + GL + OIT, Composition A + GL + DCOIT, Composition A + GL + BIT, Composition A + GL + BNPD. When the present compound or composition A is combined with the above-mentioned antifreeze and preservative, the mixing ratio of the present compound or composition A to the antifreeze and the present compound or composition A to the preservative can be in the same range as the ratio described above.

[0120] In the case of granules or microgranules, a coloring agent may be added to make it easier to identify the granules or microgranules during or after application. Also, when applying Composition B to the seeds or vegetative reproductive organs of plants, a coloring agent may be added to make it easier to identify that the composition has been applied.

[0121] Examples of the substrate of the resin preparation include polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenol resin, melamine resin, and epoxy resin. These substrates may contain plasticizers such as phthalates (dimethyl phthalate, dioctyl phthalate, etc.), adipic acid esters, and stearic acid, if necessary. The resin preparation can be processed into various forms by molding as necessary, such as plates, films, tapes, threads, nets, cloths, strings, blocks, and the like, and can be used in the form of animal collars, animal ear tags, clothing, protective hats, arm / leg covers, attractant strings, gardening poles, screen doors, mosquito nets, and the like. The composition B can also be post-treated after molding the resin. Examples of base materials for poison bait include grain flour, vegetable oil, sugar, crystalline cellulose, etc., and, if necessary, antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, preservatives such as dehydroacetic acid, agents to prevent children or pets from accidentally eating the poison, such as chili powder, and pest-attracting flavors such as cheese flavoring, onion flavoring, and peanut oil may be added.

[0122] The effective amount of the present compound, composition A, or composition B can be applied directly to the harmful arthropods or to the habitat of the harmful arthropods to control them. The habitat referred to here includes not only the place where the harmful arthropods live, but also the place where they are expected to live. Specifically, it includes plants, plant cultivation areas, plant cultivation carriers, indoor and outdoor buildings, building materials, food, daily necessities, wood, vehicles, animal bodies, etc.

[0123] In the present invention, plants include whole plants and specific parts of plants, such as foliage, flowers, spikes, fruits, trunks, branches, crowns, seeds, vegetative reproductive organs and seedlings.

[0124] Vegetative reproductive organs refer to the roots, stems, leaves, etc. of plants that have the ability to grow when separated from the plant body and placed in soil. Examples of vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms (or solid bulbs), tubers, rhizomes, stolons, rhizophores, cane cuttings, propagules, and vine cuttings. Stolons are sometimes called runners, and propagules are also called bulbils, which are divided into broad buds and bulbils. Vines refer to shoots (a collective term for leaves and stems) of sweet potatoes, Chinese yams, etc. Bulbs, corms, tubers, rhizomes, stem fragments, rhizophores or tuberous roots are collectively called bulbs. Cultivation of potatoes begins with planting tubers in soil, and the tubers used are generally called seed potatoes.

[0125] Seedlings include seedlings and saplings.

[0126] Examples of land where plants are cultivated include agricultural land such as fields, rice paddies, and orchards, and non-agricultural land such as lawns and forests.

[0127] A plant cultivation carrier is a support for plants and may be any material on which plants can grow, such as soil, seedling mats, and water. Specific examples of materials for soil and seedling mats include sand, pumice, vermiculite, diatomaceous earth, gel-like substances, polymeric substances, rock wool, glass wool, wood chips, and bark.

[0128] Examples of buildings include houses, commercial facilities, stations, airports, hospitals, factories, offices, schools, accommodation facilities, waste treatment facilities, livestock barns, and warehouses. Examples of interior spaces of buildings include closets, storage rooms, chests of drawers, cupboards, toilets, bathrooms, storerooms, living rooms, bedrooms, and dining rooms.

[0129] Examples of outdoors include the ground, exterior walls, fences, ditches, spaces, water jars, water tanks, wells, puddles, rainwater catch basins, gutters, septic tanks, old tires, reservoirs, rivers, waterways, forests, and lakes.

[0130] Examples of building materials include wood, concrete, bricks, plastic, glass, wallpaper, insulation materials, packing, piping, electric wires and cables, paints, and sealants.

[0131] Examples of foods include agricultural products (grains, fruits, spices, and products processed from these, etc.), livestock and marine products (meat, fish, eggs, milk, and products processed from these, etc.), and daily necessities include plant-derived products (cotton, paper, tobacco, and products processed from these), animal-derived products (leather, hair, wool, feathers, silk, and products processed from these), electrical appliances, and other products (furniture, stationery, toys, tableware).

[0132] Examples of wood include wood processed for construction (high density wood, laminated wood, plywood and fiberboard, hardboard, MDF, insulation board, particle board, insulation hardboard, OSB, LSL, laminated timber, cross laminated timber, flooring, composite flooring, etc.).

[0133] Examples of vehicles include bicycles, cars (private cars, buses, taxis, luggage carriers, etc.), trains, airplanes, and ships.

[0134] Examples of animals include livestock (such as cows, horses, pigs, sheep, goats, and chickens) and small animals (such as dogs, cats, rats, and mice).

[0135] When composition B is used to control harmful arthropods in the agricultural field, the application amount can be varied over a wide range depending on the type of plant to be applied, the type and occurrence frequency of harmful arthropods to be controlled, the formulation form, application time, application method, application location, weather conditions, etc. Usually, the application amount of the present compound or one of the present components is 1 to 10,000 g per 1 ha, preferably 5 to 5,000 g, more preferably 50 to 2,000 g (specifically, for example, 100 g, 200 g, 300 g, 500 g). When composition B is formulated as an emulsifiable concentrate, wettable powder, flowable agent, etc., it is usually applied by diluting with water so that the concentration of the present compound or one of the present components is 0.01 to 10,000 ppm, preferably 0.1 to 5,000 ppm, more preferably 1 to 1,000 ppm (specifically, for example, 10 ppm, 100 ppm, 500 ppm). When composition B is formulated as granules, dust or the like, it is usually applied as is.

[0136] These formulations or water dilutions of the formulations may be sprayed directly onto pests or onto plants to be protected from pests, or may be applied to cultivation carriers in order to control pests that occur on the cultivation carriers.

[0137] Alternatively, composition B, which is a resin preparation processed into a sheet or string shape, can be wrapped around the plant, stretched in the vicinity of the plant, or laid on a cultivation carrier.

[0138] When applying composition B to a plant or a land where the plant is grown, the composition B is applied once or a plurality of times. The plant or the land where the plant is grown may be already infested with arthropod pests or may not be infested yet.

[0139] Methods for applying Composition B include, for example, foliage treatment, soil treatment, root treatment, shower treatment, mist spray treatment, fumigation treatment, water surface treatment, hydroponic solution treatment and seed treatment.

[0140] Examples of foliage treatment include a method in which Composition B is applied to the surfaces of foliage, tree trunks, fruits, flowers, or ears. Examples of the root treatment include a method of immersing the roots in a chemical solution containing Composition B, and a method of attaching a solid preparation containing Composition B to the roots of the plant. Examples of soil treatment include soil spraying, soil mixing, and soil irrigation. Examples of the location for soil treatment include planting holes, rows, areas near planting holes, areas near rows, and cultivation areas. Examples of the treatment time include the entire surface of the plant, the plant's ground edge, between plants, under the tree trunk, the main trunk ridge, the soil, the seedling box, the seedling tray, the seedling bed, etc. Examples of the treatment time include before sowing, at the time of sowing, after sowing, the seedling period, before planting, at the time of planting, and the growth period after planting. In the above soil treatment, the composition B may be simultaneously applied to the plant, or a paste fertilizer, liquid fertilizer, solid fertilizer, etc. containing the composition B may be applied to the soil. The composition B may also be mixed into the irrigation liquid, for example, by injection into irrigation equipment (irrigation tubes, irrigation pipes, sprinklers, etc.), mixing into inter-row flooding liquid, mixing into hydroponic liquid, etc. In addition, the irrigation liquid and the active ingredient may be mixed in advance, and the treatment may be performed using the above-mentioned irrigation method or other appropriate irrigation methods such as sprinkling and flooding. An example of the shower treatment is a method in which a diluted solution of Composition B is showered onto the fruit after harvest. Examples of the mist spray treatment include a method in which a diluted solution of composition B is made into a mist and scattered into the air to adhere to the stems, leaves, and fruits of plants. Examples of the smoke treatment include a method in which a solid preparation containing composition B is heated to make smoke, which is suspended in the air and adheres to the stems, leaves, and fruits of plants. An example of a water surface treatment is a method of spraying a liquid drug containing Composition B or a solid formulation containing Composition B onto flooded rice paddies. Examples of hydroponic solution treatments include methods in which a chemical solution containing composition B or a solid preparation containing composition B is mixed or incorporated into a hydroponic solution (hydroponic solution mixing treatment, hydroponic solution mixing treatment, etc.).

[0141] Seed treatment Seed treatment means treatment of seeds or vegetative reproductive organs with composition B. Examples of seed treatment methods with composition B include spray treatment in which a suspension of composition B is misted and sprayed onto the surface of a seed or vegetative reproductive organ, smear treatment in which composition B is applied to the seed or vegetative reproductive organ, immersion treatment in which seeds are immersed in a chemical solution of composition B for a certain period of time, and methods of coating seeds or vegetative reproductive organs with a carrier containing composition B (film coating treatment, pellet coating treatment, etc.). The above-mentioned vegetative reproductive organs in particular include seed potatoes. When applying composition A to seeds or vegetative reproductive organs, composition A can be applied to the seeds or vegetative reproductive organs as one formulation, or composition A can be applied to the seeds or vegetative reproductive organs in separate batches as multiple different formulations. Examples of the method of applying composition A in separate batches as multiple different formulations include a method of applying a formulation containing only the present compound as an active ingredient, air-drying the seeds or vegetative reproductive organs, and then applying a formulation containing the present component; and a method of applying a formulation containing the present compound and the present component as active ingredients, air-drying the seeds or vegetative reproductive organs, and then applying a formulation containing the present component other than the component that has already been applied. After seed treatment, the active ingredient may completely or partially cover the seeds or vegetative reproductive organs, may be scattered on the surface thereof, and / or may be present inside thereof. In the case of treatment, it is preferable to use a composition containing the present ingredient having one or more fungicidal activities selected from group (b) and group (j) among composition B. In this case, the present compound may be applied to commercially available seeds or vegetative reproductive organs that have been treated with the present ingredient having one or more fungicidal activities selected from group (b) and group (j). When composition B is applied to seeds or vegetative reproductive organs, manganese, copper, zinc, etc. may also be applied at the same time. When Composition B is used for seed treatment, the application amount of Composition B is usually 0.001 to 100 g, and preferably 0.02 to 50 g, per 1 kg of seeds or vegetative reproductive organs, and the application amount of each active ingredient contained in Composition B is usually 0.001 to 100 g, preferably 0.01 to 50 g, and more preferably 0.1 to 10 g, per 1 kg of seeds or vegetative reproductive organs. Specifically, for example, the following treatment amounts can be mentioned. 0.05 g of active ingredient per kg of seeds or vegetative reproductive organs; 0.5 g active ingredient per kg of seeds or vegetative reproductive organs; 5 g of active ingredient per 1 kg of seeds or vegetative reproductive organs. In the present invention, the seed or vegetative reproductive organ carrying the present compound or composition A means a seed or vegetative reproductive organ having the present compound or composition A attached to its surface. The seed or vegetative reproductive organ carrying the present compound or composition A may have a material other than the present compound or composition A attached thereto before or after the present compound or composition A is attached to the seed or vegetative reproductive organ. When composition A is attached to the surface of a seed or a vegetative reproductive organ in the form of a layer, the layer may consist of one or more layers. When the composition A consists of multiple layers, each layer may contain one or more active ingredients, or each layer may consist of a layer containing one or more active ingredients and a layer containing no active ingredients. Seeds or vegetative reproductive organs carrying the present compound or composition A can be obtained, for example, by applying composition B containing the present compound or composition A to the seeds or vegetative reproductive organs by the seed treatment method described above.

[0142] As seed treatment formulations, generally, DS, ES, FS, LS, WS, CF, GF, SS, etc. are known, but CS, EG, EW, GW, ME, OD, OF, SC, SE, SG, SL, SP, ST, WG, WP, WT, ZC, ZE, ZW, etc. can also be used. These formulations contain one of the present compounds or components in a weight ratio of 0.01 to 70%, preferably 0.1 to 50%. In addition, when these formulations are applied to seeds or vegetative reproductive organs, they may be used as is or may be diluted with water. When applying a formulation diluted with water to seeds or vegetative reproductive organs, it can be diluted as desired depending on the active ingredient content in the formulation and the amount of active ingredient to be retained in the seeds or vegetative reproductive organs, but it is generally often used after diluting 2 to 1000 times. When the treatment is carried out on seeds, the treatment may be carried out on the seeds before sowing or after germination. When the present compound or composition A is used for seed treatment, adjuvants such as colorants and binders may be mixed in when the compound or composition A is formulated, or may be further mixed in when the formulated composition B is used for seed treatment. The coloring agent makes it easy to confirm whether composition B has been applied to each seed or vegetative reproductive organ. The binder can also be added to improve the adhesion of the active ingredient to the seed or vegetative reproductive organ. Specific examples of coloring agents and binders are shown below. Colorants: For example, monoazos (Pigment Red 48:1, Pigment Red 48:2, Pigment Red 53:1, Pigment Red 57:1, Pigment Red 112, Pigment Brown 25, Cl Solvent Red 1, Pigment Yellow 1, Pigment Orange 5, Acid Red 14, Acid Yellow 23, etc.), disazos (Pigment Yellow 13, Pigment Orange 34, etc.), phthalocyanines (Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Green 7, Pigment Green 36, etc.), anthraquinones (Pigment Red 83, etc.), dioxazines (Pigment Blue 80, etc.), xanthenes (Basic Violet 10 (Rhodamine B), Acid Red 51, Acid Red 52, etc.), triarylmethanes (Acid Blue 9, etc.), Pigment Orange 43, iron oxide, titanium, titanium oxide, zinc oxide, zinc sulfide, hexacyanoferric salt, chrome vermilion, yellow lead, calcium carbonate, baryte powder, aluminum powder; Binders: polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clay, organically modified clay, inorganic clay, inorganically modified clay, etc.), minerals (bentonite, etc.), synthetic polymers (polycarboxylic acid or its salt, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salt, styrene-butadiene copolymer, methyl methacrylate-butadiene copolymer, polyacrylic acid or its salt, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, polypropylene glycol, etc.), waxes (vegetable oils and fats, animal oils and fats, and derivatives thereof, paraffin, olefin, etc.). When composition B is applied to seeds or vegetative reproductive organs, composition B may be mixed with an adjuvant, if necessary. The seeds or vegetative reproductive organs treated with composition B are sown or planted in a field in the usual manner.

[0143] The present compound and the present component may be applied separately at the same time to a plant or the soil in which the plant is cultivated, or to a place where harmful arthropods occur, or the present compound and the present component may be applied separately at different times to a plant or a cultivation carrier, or to a place where harmful arthropods occur. Specifically, for example, the present compound or the present component may be applied to the cultivation carrier before or after a seed or vegetative reproductive organ treated with either one of the present compound or the present component is planted in the cultivation carrier (e.g., soil, etc.).

[0144] Composition B can be applied to plants whose seeds have been previously treated with one or more components selected from the present components and to the cultivation carriers of said plants. Application methods include, for example, foliage treatment, soil treatment, root treatment, shower treatment, mist spray treatment, smoke treatment, water surface treatment, and hydroponic solution treatment.

[0145] Examples of seed treatment agents that are applied to soybeans in advance include the following. STANDAK-TOP 500FS (Fipronil / Pyraclostrobin / Thiophanate-m), DERMACOR 625FS (Chlorantraniliprole), CRUISER 350FS (Thiamethoxam), CROPSTAR 600FS (Imidacloprid / Thiodicarb), FORTENZA 600FS (Cyantraniliprole), S-UNSPEC-INS-WHEAT, NEMAT 300WP (Verticillium), FIPRONIL-ALTA 250FS (Fipronil), MAXIM-ADVANCED 195FS (Fludioxonil / Metalaxyl-M / Thiabendazole), SHELTER 250SC (Fipronil), MAXIM-XL 035FS (Fludioxonil / Metalaxyl-M), DEROSAL Plus(Carbendazim / Thirum), Vitavax - THIRAM (Carboxin / Thiram).

[0146] Examples of seed treatment agents that are applied to corn in advance include the following. PONCHO-VOTIVO 601EC (Bacillus-firmus / Clothianidin), ACCELERON-IC-609 600EC (Clothianidin), CRUISER 600FS (Thiamethoxam), ACCELERON-D-342 480FS (Prothioconazole), PONCHO 600FS (Clothianidin), MAXIM-QUATTRO 382.5FS (Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole), AVICTA-COMPLETE-CORN-250 280FS, Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), AVICTA-COMPLETE-CORN-500 423FS, (Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), LUMIVIA 625FS (Chlorantraniliprole), ACCELERON-D-281 480FS (Fluoxastrobin), ACCELERON-DC-309 312FS (Metalaxyl).

[0147] Examples of seed potato treatment agents that are used to treat potatoes in advance include the following: Maxim 4FS (fludioxonil), Maxim MZ (fludioxonil+Mancozeb), Cruiser MAXX Vibrance Potato (fludioxonil+difenoconazole+Sedaxane+ Thiamethoxam), Emesto Silver (penflufen + prothioconazole), MonCoatMZ (flutolanil + Mancozeb), Moncut (flutolanil), Elatus (azoxystrobin + benzovindiflupyr), Quadris (azoxystrobin), Serenade ASO (Bacillus subtillis), DoubleNickel LC (Bacillus amyloliquefaciens), Attakin (streptomycin, thiophanate M), Fronside (fluazinam), Bashidac (mepronil), Moncut (flutolanil), Lovral (iprodione), Moncut (flutolanil), Benlate (benomyl).

[0148] When applying the composition B, a spraying device can be used. Examples of the device used when applying include a hand-cranked sprayer, a power sprayer, a punkul sprayer, a manned aircraft (such as a manned helicopter), an unmanned aircraft (such as a radio-controlled helicopter or a drone), a tractor, a planter, etc. In addition, the composition B may be applied by hand without using a spraying device.

[0149] When applying Composition B using a sprayer, the spray pressure is not particularly limited, but is usually 30 to 120 PSI, preferably 40 to 80 PSI. The spray pressure here is the setting before introduction into the nozzle.

[0150] When applying composition B using a sprayer, the spray nozzle is not particularly limited, but examples thereof include a flat spray nozzle, a conical nozzle, a rotary nozzle, a hollow cone nozzle, a deflector nozzle, and a straight nozzle.

[0151] When composition B is applied in the form of a solution, the pH and hardness of the solution are not particularly limited, but the pH is usually in the range of 5 to 9, and the hardness is usually in the range of 0 to 500 on the American hardness scale. The time period during which composition B is applied is not particularly limited, but is generally in the range of 5:00 a.m. to 9:00 p.m. In addition, the photon flux at the grass canopy level in the place where composition B is applied is usually 10 to 2500 micromoles / m 2 The weather conditions when applying the composition B are not particularly limited, but the air temperature is usually 0 to 30°C, preferably 10 to 20°C, the soil temperature is usually 0 to 30°C, preferably 10 to 20°C, the relative humidity is 50 to 90%, preferably 40 to 80%, and the wind speed is 0 to 2 MPH.

[0152] Composition B is usually sprayed by mixing composition B with water to obtain a spray liquid, and the spray liquid is prepared by directly diluting the composition with water in the amount required for the spray liquid, or by mixing composition B with a small amount of water to homogenize it, and then adding water to prepare a specified amount of liquid. The amount of the spray liquid is not particularly limited, but is usually in the range of 5 to 5000 L / ha, preferably 20 to 1000 L / ha, and more preferably 140 to 300 L / ha. Specific spraying liquid volumes are 10L / ha, 30L / ha, 50L / ha, 70L / ha, 90L / ha, 100L / ha, 120L / ha, 150L / ha, 180L / ha, 20 Examples include 0L / ha, 250L / ha, 300L / ha, 400L / ha, 500L / ha, 700L / ha, 900L / ha, 2000L / ha, and 4000L / ha.

[0153] When composition B is sprayed using a manned or unmanned aerial vehicle, the spray height is not particularly limited, but is usually 0.5 to 30 m, and preferably 1 to 10 m.

[0154] When carrying out foliage treatment, soil treatment, root treatment, shower treatment, smoke treatment, water surface treatment, seed treatment and hydroponic solution treatment with composition B, composition B may be mixed with an adjuvant. They may be mixed in advance when preparing a formulation (premix) or may be mixed immediately before use (tank mix). The type of adjuvant is not particularly limited, but examples thereof include COC (Crop oil concentrate) derived from mineral oil, MSO (methylated seed oil) derived from vegetable oil, alcohol-based solvents, nonionic surfactants, anionic surfactants, cationic surfactants, silicone-based, nitrogen fertilizers, etc., and mixtures thereof. Specifically, AgriDex (registered trademark), Induce (registered trademark), Gramin S (registered trademark), Genamin T 200BM (registered trademark), Silwet L77 (registered trademark), Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol Gold (registered trademark), BreakThru (registered trademark), Sundance II (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), BANOLE (registered trademark), Ochima (registered trademark), Agris (registered trademark), AMS (Ammonium Sulfate), UAN (Urea Ammonium Sulfate), Nitrate (urea ammonium nitrate), AdGreen (registered trademark), Mees (trademark), Rumba (registered trademark), Strides (registered trademark), Partner, Orix (registered trademark), Penetrator, etc. Furthermore, a drift reducing agent such as Intact (registered trademark) may be mixed. The weight ratio of composition B to the above adjuvant or drift reducing agent is not particularly limited, but may be, for example, in the range of 1:100 to 100:1.

[0155] Composition B and a fertilizer can be mixed or used together. When mixed, they may be mixed in advance when formulated (premix) or just before application (tank mix). Examples of fertilizers include substances containing various elements such as nitrogen (N), phosphorus (P), potassium (K), silicon, magnesium, calcium, manganese, boron, iron, copper, zinc, sulfur, molybdenum, and cobalt. Examples of substances containing nitrogen, phosphorus, and potassium include urea, ammonium nitrate, ammonium chloride, ammonium sulfate, sodium nitrate, magnesium nitrate, nitric acid, anhydrous ammonia, urea ammonium nitrate, lime nitrate, lime nitrogen, phosphoric acid, superphosphate, calcium triphosphate, potassium sulfate, potassium chloride, potassium silicate, caustic potassium, potassium nitrate, potassium phosphate, MAP (ammonium phosphate), and DAP (diammonium phosphate). The form of the fertilizer may be any of granular, powdery, lump, and liquid, and various forms of fertilizers can be used. Examples of application locations include the soil surface, in the soil, and on plants. Examples of equipment used for application include hand-cranked sprayers, power sprayers, punkul sprayers, manned aircraft (e.g., manned helicopters), unmanned aircraft (e.g., radio-controlled helicopters, drones), tractors, planters, broadcasters, sowers, seeders, etc. Application may also be done by hand without using a spraying device. A specific application method includes, for example, applying composition B and a fertilizer together to the vicinity of seeds, vegetative reproductive organs, or seedlings at the time of sowing or planting of plants, or before or after sowing or planting (e.g., sowing ±0, 1, 2, 3, 4, 5 days) (sometimes called in-furrow application). The fertilizer applied at the time of sowing or planting of plants, or before or after sowing or planting of plants, may be a solid fertilizer and / or a liquid fertilizer, including, for example, a fertilizer having an N:P:K ratio (sometimes called a starter fertilizer, pop-up fertilizer, etc.). Composition B and a fertilizer may be mixed immediately before application, or may be applied separately and simultaneously. The application site is not particularly limited as long as it is near the seed, vegetative reproductive organ, or seedling, but may be in the planting furrow of the seed, vegetative reproductive organ, or seedling, or may be a few inches away from the planting furrow of the seed, vegetative reproductive organ, or seedling, for example, 2 inches to the side and 2 inches below the planting furrow of the seed, vegetative reproductive organ, or seedling (sometimes called 2-by2 band). Crops include corn, soybean, sugarcane, potato, wheat, barley, rye, oats, rice, etc. The ratio of the weight of one active ingredient contained in composition B to the total weight of NPK contained in the fertilizer is not particularly limited, but may be, for example, in the range of 1:1 to 1:10000.

[0156] Composition B can be applied by spot treatment. Spot treatment is a concept opposite to uniform application of composition B, and means selective spraying of composition B to a place where harmful arthropods occur or a place where harmful arthropods are likely to occur. "Applying to a place" means applying to a plant or soil where harmful arthropods occur or are likely to occur, and is preferably applied to a plant. When applying to a plant, it includes applying only to an individual in a plant population where harmful arthropods occur or are likely to occur, and also includes applying to a part of an individual plant where harmful arthropods occur or are likely to occur. Even when composition B is sprayed to a place where no harmful arthropods have occurred or where there is no risk of harmful arthropods occurring due to scattering, transpiration, etc., it is included in spot treatment as long as it is not a uniform surface treatment. Also, only when all the places where harmful arthropods occur or where there is a risk of harmful arthropods occurring in a continuous cultivation area are selectively treated, it is not considered to be spot treatment. In other words, even if a part of the cultivation area is treated surface, or a part of the places where harmful arthropods occur or where there is a risk of harmful arthropods occurring is not treated with composition B, it is included in spot treatment as long as there are spots in the continuous cultivation area that have been spot treated.

[0157] Specific examples of spot treatment methods are given below. In the plant cultivation area, the applicator may visually spray composition B using a handheld nozzle or a robot arm nozzle while walking or while riding on a device that travels on the ground or a flying device. Furthermore, the spot treatment may be performed by mapping the location where harmful arthropods are occurring or are likely to occur in advance and spraying composition B based on the map information. In spraying based on map information, in addition to the above method, the spot treatment may be performed by automatically or manually opening and closing the nozzle on the boom or the robot arm nozzle based on the position information of the sprayer (obtained by GPS or the like) and the map information while the sprayer is traveling or flying. The map information may be created based on image information taken by a manned or unmanned flying object, or may be created visually by an observer walking on the ground, an observer riding on a device that travels on the ground, or an observer riding on a flying device. Furthermore, a mobile or flying applicator may be equipped with a function for detecting locations where pests have occurred or are likely to occur, and spot treatment may be performed using the boom or robotic arm while performing real-time mapping.

[0158] The location where harmful arthropods are occurring can be recognized by image analysis using visible light, in addition to visual recognition by applicators or observers, but may also be recognized by image analysis using specific wavelengths using hyperspectral images. Image analysis may be in the form of visually recognizing the occurrence of harmful arthropods on a screen, but image recognition using artificial intelligence can also be used (for example, OPTiM Corporation, press release dated December 26, 2017). These images may be taken by manned or unmanned flying objects, etc., or by photographers walking on the ground, photographers riding on devices that run on the ground, or photographers riding on flying devices. The location where harmful arthropods are likely to occur may be estimated based on the fact that the harmful arthropods occurred in patches during the past cultivation season of the crop, or may be estimated from the distribution of harmful arthropods in the soil. The distribution of harmful arthropods in the soil may be investigated by soil sampling, or may be estimated by remote sensing. In addition, the fact that harmful arthropods are hiding in plants may be detected and estimated by image analysis. Such technology is known as a form of emerging agriculture, also known as precision agriculture, smart agriculture, or digital agriculture, and the uneven spraying patterns that result from spot treatment are sometimes referred to as Variable Rate Application (VRA), a term used in emerging agriculture.

[0159] Examples of the method of spot treatment with composition B include a method of spraying the composition B on the soil of a place where harmful arthropods are present or where harmful arthropods are likely to be present (soil treatment), and a method of spraying composition B on a plant where harmful arthropods are present or where harmful arthropods are likely to be present (foliage treatment). Spraying is usually carried out using a spray solution prepared by mixing composition B with water. The amount of spray solution is not particularly limited, but is usually 50 to 1000 L / ha, preferably 100 to 500 L / ha, and more preferably 140 to 300 L / ha in the area where the spot treatment is performed. The ratio of the area of ​​the plant cultivation site to be spot treated (the ratio of the area of ​​the part where composition B is sprayed to the area of ​​the entire continuous cultivation site) is usually 1 to 99%, preferably 10 to 80%. Specifically, the ratio may be 20%, 30%, 40%, 50%, 60%, or 70%. The amount of Composition B to be applied when spot treating is 5 to 2000 g per hectare, preferably 50 to 1500 g per hectare, more preferably 200 to 1000 g per hectare, and even more preferably 400 to 700 g per hectare, as the amount of active ingredient to be applied within the area to be spot treated. When carrying out the spot treatment, an adjuvant or a drift reducing agent may be mixed in. The types of the adjuvant or drift reducing agent are not particularly limited, but examples thereof include those mentioned above. The pH and hardness of the spray solution are not particularly limited, but the pH is usually in the range of 5 to 9, and the hardness is usually in the range of 0 to 500 on the American hardness scale. The time period during which spot treatment is carried out is not particularly limited, but is usually between 5:00 a.m. and 9:00 p.m., and the photon flux at the grass canopy level in the area where spot treatment is carried out is usually 10 to 2500 micromoles / m 2 / sec. Alternatively, spot treatment can be performed overnight using the map and location information. The spray pressure when carrying out spot treatment is not particularly limited, but is usually 30 to 120 PSI, preferably 40 to 80 PSI. The spray pressure here is the setting before introduction into the nozzle. The weather conditions for carrying out the spot treatment are not particularly limited, but the air temperature is usually 0 to 30°C, preferably 10 to 20°C, the soil temperature is usually 0 to 30°C, preferably 10 to 20°C, the relative humidity is 50 to 90%, preferably 40 to 80%, and the wind speed is 0 to 2 MPH.

[0160] More specifically, the application method of Composition B includes planting hole treatment (spraying in planting holes, mixing in planting hole treatment soil), plant base treatment (spraying in plant base, mixing in soil at plant base, irrigation at plant base, plant base treatment in the latter half of the seedling raising period), planting furrow treatment (spraying in planting furrow, mixing in soil at planting furrow), crop row treatment (spraying in crop row, mixing in soil at crop row, spraying in crop row during the growing season), crop row treatment at the time of sowing (spraying in crop row at the time of sowing, mixing in soil at the time of sowing), overall treatment (spraying in overall soil, mixing in soil at the overall surface), side row treatment, water surface treatment (application on the water surface, application on the water surface after flooding), other soil spray treatments (foliar spraying of granules during the growing season, spraying under the tree crown or around the main trunk, spraying on the soil surface, mixing in soil surface, spraying in seeding holes, spraying on the ground surface of the ridges, spraying between plants), and other irrigation treatments. These are sometimes called (soil irrigation, seedling irrigation, chemical injection treatment, ground level irrigation, chemical drip irrigation, chemigation), seedling box treatment (seedling box spraying, seedling box irrigation, flooding the seedling box with chemicals), seedling tray treatment (seedling tray spraying, seedling tray irrigation, flooding the seedling tray with chemicals), seedbed treatment (seedling bed spraying, seedling bed irrigation, water seedling bed spraying, seedling immersion), bed soil mixing treatment (bed soil mixing, bed soil mixing before sowing, spraying before soil cover at sowing, spraying after soil cover at sowing, soil covering mixing), and other treatments (mixing culture soil, plowing in, mixing topsoil, mixing soil that has fallen off due to rain, planting position treatment, spraying granular inflorescences, mixing paste fertilizer, mixing hydroponic solution, mixing hydroponic solution), etc.

[0161] Application of the compound or composition A may reduce the mycotoxin content in the produced and harvested material and in the food and feed prepared therefrom. The mechanism of the mycotoxin reduction effect is not limited, but may be exerted, for example, by a direct or indirect action on mycotoxin-producing bacteria. Examples of direct effects include a bactericidal effect on mycotoxin-producing bacteria and an inhibitory effect on mycotoxin biosynthesis. Examples of indirect effects include effects on the microbiome, such as the ratio of mycotoxin-producing bacteria to non-producing bacteria, and reduction of fungal infection by suppressing feeding damage by harmful arthropods. Examples of mycotoxins include, but are not limited to, the following: Deoxynivalenol (DON), nivalenol, fusarenon X, 15-Ac-DON, 3-Ac-DON, T2- and HT2-toxins, neosolaniol, fumonisins, zearalenone, moniliformin, fusarin, diacetoxyscirpenol (DAS), beauvericin, enniatins, fusaroproliferin, fusarenol, ochratoxin, patulin, sterigmatocystin, maltodine, citrinin, rugulosine, rubratoxin, citreoviridin, cyclochlorotine, luteoskairin, lolitrem B, slaframin, sporidesmin, ergot alkaloids (e.g., lysergic acid, ergotamine, ergometrine), aflatoxins, and cyclopiazonic acid. These mycotoxins may be produced, for example, by the following fungi: Fusarium species such as F. acuminatum, F. asiaticum, F. avenaceum, F. crookwellense, F. culmorum, F. graminearum (Gibberella zeae), zeae), F. equiseti, F. fujikoroi, F. moniliforme, F. musarum, F. oxysporum, F. proliferatum, F. poae, F. pseudograminearum, F. samusiforme ... mbucinum, F. scirpi, F. semitectum, F. solani, F. sporotrichoides, F. langsethiae, F. subglutinans, F. tricinctum, F. verticillioides, etc.; Aspergillus species, such as A. flavus, A. parasiticus, A. nomius, A. ochraceus, A. carbonarius, A. clavatus, A. terreus, A. versicolor; Penicillium species, such as icillium species such as P. verrucosum, P. viridicatum, P. citrinum, P. expansum, P. claviforme, P. roqueforti, Claviceps species such as C. purpurea, C. fusiformis, C.fusiformis, C. paspali, C. africana, etc.; Stachybotrys species; Slafractonia species, such as S. leguminicola, etc.; Neotyphodium species, such as N. lolii, etc.; Pithomyces species, such as P. chartarum. .

[0162] Application of the compound or composition A can improve the seedling establishment rate of plants, improve plant growth, and improve resistance to abiotic stress (e.g., improved resistance or tolerance to high or low temperatures, improved resistance to drought, excessive moisture, or salt contained in water or soil, improved resistance to osmotic stress, improved resistance to dryness stress, improved resistance to ozone exposure, improved resistance to ultraviolet stress, improved resistance to wind stress, and improved resistance to sunlight stress) depending on the plant species or plant variety, their growing location, and growing conditions (soil, climate, growing season, nutrients). In some cases, the benefits of the invention include increased plant fertility, improved flowering ability, improved ease of harvesting, accelerated maturation, increased yield, increased number, size or weight of seeds or fruits, improved green leaf color, longer life of leaves, increased number of healthy leaves, retarded senescence, reduced plant lodging, earlier flowering, increased number of flowers or fruits, increased fruit set, improved quality and / or increased nutritional value of the harvested product (e.g., increased sugar content in fruit, improved gluten strength, optimized protein content, optimized oil content, improved nutritional value), improved storage stability and / or improved processability of the harvested product. More specifically, examples of plant growth improvement include promotion of stem elongation, promotion of stem thickening, promotion of increase in the number or total area of ​​leaves, increase in healthy leaves, promotion of stem branching (e.g., promotion of increase in the number of stem branches), promotion of lateral root formation (e.g., increase in the number of lateral roots, etc.), increase in auxin-producing sites in roots (main roots or lateral roots), promotion of root elongation, improvement of root spreading, and promotion of root thickening. In some cases, it may be possible to improve resistance to nutritional stress caused by a deficiency of any of the 17 essential nutrients (essential elements) for plant growth.

[0163] When Composition B is used against harmful arthropods in non-agricultural fields, the application amount can vary over a wide range depending on the type and frequency of occurrence of the harmful arthropods to be controlled, the formulation form, application time, application method, application location, weather conditions, etc. Specific application methods include, for example, when applying to a building, treatment of the walls, floors, under the floor, ceiling, roof, attic, doors, windows, screens, etc. of the building, treatment of the indoor space of the building, and installation of poison bait or resin preparations. When applied outdoors, examples of application include application to the ground, exterior walls, fences, and ditches, injection into soil under floors or into the ground, application into air, and application of granular or resinous formulations into water. When the composition is applied to building materials, for example, the composition may be mixed into the building materials or applied thereto. When applied to food and daily necessities, examples of the application include treatment of walls, floors and ceilings of places where the food and daily necessities are stored with emulsions, hydrated agents, flowable agents, oil agents, etc., treatment of spaces with fumigants, fumigants, aerosols, etc., installation of poison baits, resin preparations, etc., kneading, painting, or treatment of powders or emulsions, etc. into the daily necessities. When applied to wood, examples of the application include painting, spraying, dipping, impregnation, injection, mixing during wood processing, and incorporation into adhesives. When applied to vehicles, examples of application include treatment of the interior space and walls of the vehicle, and placement of poison bait or resin preparations. When applied to animals, the compounds may be administered orally in the form of capsules, chewable tablets, syrups, tablets, powders, or by mixing with feed or drinking water; by suppositories or injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.); by spraying, applying or dropping liquid formulations such as spot-ons, pour-ons, shampoos, lotions or pastes; or by processing resin formulations into collars, ear tags, bracelets, clothing, etc. and attaching them to the body.

[0164] When Composition B is used for controlling harmful arthropods in non-agricultural fields, the application rate for surface treatment is 1000 mg / m2. 2 The amount of one active ingredient per square meter is usually 0.01 to 1000 mg, preferably 10 to 500 mg, and more preferably 20 to 400 mg (specifically, for example, 25 mg, 50 mg, or 400 mg). When treating in a space, the application amount is 1 m2 of the treatment space. 3The amount of one active ingredient per kg is usually 0.01 to 500 mg. When applied in water, the amount of one active ingredient per 1 L of water volume is usually 0.001 to 1000 mg, more preferably 0.01 to 100 mg. When applied to an animal body, the amount of one active ingredient per 1 kg of animal body weight is usually in the range of 0.01 to 1000 mg. When composition B is formulated as an emulsifiable concentrate, wettable powder, flowable agent, etc., it is usually applied by diluting with water so that the concentration of one active ingredient is 0.1 to 10,000 ppm. When it is formulated as an oil agent, etc., it is usually applied as it is, or diluted with kerosene, light oil, etc. so that the concentration of one active ingredient is 0.1 to 10,000 ppm. Granules, powders, aerosols, smoke agents, fumigants, poison bait, resin preparations, etc. are applied as they are. In addition, incense coils are applied by lighting them. Electric mosquito repellent mats, liquid mosquito repellent preparations, fan-type mosquito repellent preparations, ultrasonic vibration preparations, electrostatic spray preparations, etc. are usually applied using a power source or batteries.

[0165] Composition B can be used to suppress the biting and unpleasant behavior of harmful arthropods such as mosquitoes and flies by applying it to the body surface of humans or animals. It can also be used to suppress the occurrence and growth of flies and other pests that occur in excrement by adding it to animal feed and orally giving it to animals.

[0166] Composition B can also be used to prevent the spread of infectious diseases transmitted by harmful arthropods (malaria, dengue fever, West Nile fever, yellow fever, Zika fever, filariasis, onchocerciasis, leishmaniasis, Chagas disease, African sleeping sickness, etc.). Specific application methods include application of composition B to the interior walls of houses (Indoor Residual Spray; IRS), application to outdoor spaces (Space spray), use of mosquito nets treated with composition B (Long-lasting insecticidal nets), wallpaper, poison bait, egg-laying traps, luring traps, spatial repellent devices, and automatic propagation devices, application of composition B to water jars, reservoirs, mountain streams, etc. (measures against pest source outbreaks, Larvicide), etc.

[0167] Application of the compound or composition A can improve the seedling establishment rate of plants, improve plant growth, and improve resistance to abiotic stress (e.g., improved resistance or tolerance to high or low temperatures, improved resistance to drought, excessive moisture, or salt contained in water or soil, improved resistance to osmotic stress, improved resistance to dryness stress, improved resistance to ozone exposure, improved resistance to ultraviolet stress, improved resistance to wind stress, and improved resistance to sunlight stress) depending on the plant species or plant variety, their growing location, and growing conditions (soil, climate, growing season, nutrients). In some cases, the benefits of the invention include increased plant fertility, improved flowering ability, improved ease of harvesting, accelerated maturation, increased yield, increased number, size or weight of seeds or fruits, improved green leaf color, longer life of leaves, increased number of healthy leaves, retarded senescence, reduced plant lodging, earlier flowering, increased number of flowers or fruits, increased fruit set, improved quality and / or increased nutritional value of the harvested product (e.g., increased sugar content in fruit, improved gluten strength, optimized protein content, optimized oil content, improved nutritional value), improved storage stability and / or improved processability of the harvested product. More specifically, examples of plant growth improvement include promotion of stem elongation, promotion of stem thickening, promotion of increase in the number or total area of ​​leaves, increase in healthy leaves, promotion of stem branching (e.g., promotion of increase in the number of stem branches), promotion of lateral root formation (e.g., increase in the number of lateral roots, etc.), increase in auxin-producing sites in roots (main roots or lateral roots), promotion of root elongation, improvement of root spreading, and promotion of root thickening. In some cases, it may be possible to improve resistance to nutritional stress caused by a deficiency of any of the 17 essential nutrients (essential elements) for plant growth.

[0168] When Composition B is used for controlling harmful arthropods in non-agricultural fields, the application amount can vary over a wide range depending on the type and frequency of occurrence of the harmful arthropods to be controlled, the formulation form, application time, application method, application location, weather conditions, etc. Specific application methods include, for example, when applying to a building, treatment of the walls, floors, under the floor, ceiling, roof, attic, doors, windows, screens, etc. of the building, treatment of the indoor space of the building, and installation of poison bait or resin preparations. When applied outdoors, examples of application include application to the ground, exterior walls, fences, and ditches, injection into soil under floors or into the ground, application into air, and application of granular or resinous formulations into water. When the composition is applied to building materials, for example, the composition may be mixed into the building materials or applied thereto. When applied to food and daily necessities, examples of the application include treatment of walls, floors and ceilings of places where the food and daily necessities are stored with emulsions, hydrated agents, flowable agents, oil agents, etc., treatment of spaces with fumigants, fumigants, aerosols, etc., installation of poison baits, resin preparations, etc., kneading, painting, or treatment of powders or emulsions, etc. into the daily necessities. When applied to wood, examples of the application include painting, spraying, dipping, impregnation, injection, mixing during wood processing, and incorporation into adhesives. When applied to vehicles, examples of application include treatment of the interior space and walls of the vehicle, and placement of poison bait or resin preparations. When applied to animals, the compounds may be administered orally in the form of capsules, chewable tablets, syrups, tablets, powders, or by mixing with feed or drinking water; by suppositories or injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.); by spraying, applying or dropping liquid formulations such as spot-ons, pour-ons, shampoos, lotions or pastes; or by processing resin formulations into collars, ear tags, bracelets, clothing, etc. and attaching them to the body.

[0169] When Composition B is used for controlling harmful arthropods in non-agricultural fields, the application rate for surface treatment is 1000 mg / m2. 2 The amount of one active ingredient per square meter is usually 0.01 to 1000 mg, preferably 10 to 500 mg, and more preferably 20 to 400 mg (specifically, for example, 25 mg, 50 mg, or 400 mg). When treating in a space, the application amount is 1 m2 of the treatment space. 3The amount of one active ingredient per kg is usually 0.01 to 500 mg. When applied in water, the amount of one active ingredient per 1 L of water volume is usually 0.001 to 1000 mg, more preferably 0.01 to 100 mg. When applied to an animal body, the amount of one active ingredient per 1 kg of animal body weight is usually in the range of 0.01 to 1000 mg. When composition B is formulated as an emulsifiable concentrate, wettable powder, flowable agent, etc., it is usually applied by diluting with water so that the concentration of one active ingredient is 0.1 to 10,000 ppm. When it is formulated as an oil agent, etc., it is usually applied as it is, or diluted with kerosene, light oil, etc. so that the concentration of one active ingredient is 0.1 to 10,000 ppm. Granules, powders, aerosols, smoke agents, fumigants, poison bait, resin preparations, etc. are applied as they are. In addition, incense coils are applied by lighting them. Electric mosquito repellent mats, liquid mosquito repellent preparations, fan-type mosquito repellent preparations, ultrasonic vibration preparations, electrostatic spray preparations, etc. are usually applied using a power source or batteries.

[0170] Examples of plants for which composition B can be used include: Crops; Corn (horse-tooth, hard, soft, burst, glutinous, sweet, field corn), Rice (long, short, medium, japonica, tropical japonica, indica, javanica, paddy, upland, floating, direct-seeded, transplanted, glutinous), Wheat (bread wheat (hard, soft, medium, red, white), durum, spelt) , club wheat, each winter wheat type, spring wheat type), barley (two-rowed barley (= beer barley), six-rowed barley, naked barley, waxy barley, each winter barley type, spring barley type), rye (winter rye type, spring rye type), triticale (winter triticale type, spring triticale type), oats (winter oat type, spring oat type), sorghum, cotton (upland type, pima type), soybean (fully matured seed harvested variety, green soybean variety, green cut variety, each indeterminate type, determinate type, semi-determinate type), groundnut (peanut), Japanese bean (green bean), lima bean, adzuki bean, cowpea, mung bean, urad bean, scarlet runner bean, bamboo bean, moss bean, tepary bean, fava bean, einkorn Peas, chickpeas, lentils, lupins, pigeon peas, alfalfa, potatoes (tetraploid, diploid, true seed varieties), buckwheat, sugar beet (sugar, animal feed, root, leafy, fuel), rapeseed (winter rapeseed, spring rapeseed), canola (winter canola, spring canola), sunflower (oil extraction, food, ornamental), sugarcane, tobacco, tea, mulberry, etc. Vegetables: Solanaceae vegetables (eggplant, tomato, green pepper, chilli pepper, bell pepper, etc.), Cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon, squash, etc.), Cruciferae vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, mustard, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, chrysanthemum, artichoke, lettuce, etc.), Liliaceae vegetables (leeks, onions, garlic, asparagus, etc.), Apiaceae vegetables (carrots, parsley, celery, parsley, etc.), Chenopodiaceae vegetables (spinach, Swiss chard, etc.), Lamiaceae vegetables (perilla, mint, basil, lavender, etc.), strawberries, sweet potatoes, Chinese yams, taro, etc. Fruit trees; pome fruits (apples, European pears, Japanese pears, Chinese pears, quince, quince, etc.), stone fruits (peaches, plums, nectarines, plums, cherries, apricots, prunes, etc.), citrus fruits (Satsuma mandarins, oranges, lemons, limes, grapefruits, etc.), nuts (chestnuts, walnuts, hazels, almonds, pistachios, cashew nuts, macadamia nuts, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons, figs, olives, loquats, bananas, coffee, dates, coconuts, etc. Ornamental plants; flowering trees, street trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar, redbud, liquidamum, plane tree, zelkova, arborvitae, fir, hemlock, juniper, pine, spruce, yew), flowers, ornamental plants, turf grasses.

[0171] The above-mentioned plants are not limited as long as they are varieties that are commonly cultivated.

[0172] Examples of corn varieties include: P30F53, P30F53RR, P30F53YHV, DKB390, DKB390IPRO3, DKC62-08, DKC35-88RIB RR2 BT, P7958AM RR2 LL BT, NK1120-3122 RR+GLU+ECB+CRW, P9608AM LL RR2 CRW ECB, Golden Bantam

[0173] Examples of wheat varieties include: PAKITO; KWS Zyatt; Skyfall; Crusoe; RGT Illustrious; KWS Extrase; KWS Extase; KWS Siskin; LG Detroit; KWS Lili; KWS Firefly; KWS Barrel; Elicit; KWS Basset; Zulu; Viscount; Revelation; SY Insight; KWS Kinetic; Gleam; RGT Gravity; KWS Kerrin; Shabras; Graham; KWS Crispin; Theodore; Dunston; Costello

[0174] Examples of barley varieties include the following: Electrum; Craft; SY Venture; KWS Hawking; LG Mountain; KWS Gimlet; Jordan; LG Flynn; KWS Orwell; Valerie; Surge; KWS Creswell; KWS Tower; KWS Glacier; California; KWS Cassia; Belmont; SY Kingsbarn; SY Baracooda; Bazooka; Cosmopolitan; SY Tungsten; LG Diablo; Laureate; RGT Planet; RGT Asteroid; Iconic; KWS Sassy; Sienna; Propino; Fairing; Concerto; Fairway; Prospect

[0175] Examples of soybean varieties include the following: 5G8015 RR IPRO; ANTA 82 PR; AS 3797 IPRO; BMX POTENCIA RR; BRS 8170IPRO; BRS 8280 RR; DM 6583 IPRO; M 5947 IPRO; M 6410 IPRO; M 8644 IPRO; M8372 IPRO; M9114PR; MONSOY 5947 IPRO; MONSOY 7730 IPRO; MSOY 8372 IPRO; NA 5909 RG; NS 5445 IPRO; NS 5909 PR; NS 5969 IPRO; NS 6700 IPRO; ST 797; TMG 1180 RR; TMG 1188 RR NS 4823 RR; NS 5445 IPRO; NA 5909 RR; NS 6209 RR; NS 6601 IPRO; NS 6823 RR; NS 6906 IPRO; NS 7000 IPRO; NS 7200 RR; NS 7227 RR; NS 7300 IPRO; NS 7474 IPRO; NS 7505 IPRO; NS 7709 IPRO; NS 8270 IPRO; NS 8393 IPRO RR; NS 5106 IPRO; NS 5727 IPRO; NS 5959 IPRO; NS 6390; NS 6700 IPRO; NS 6828; NS 6909 IPRO - Centro; NS 7000 IPRO -SUL; NS 7202 IPRO; NS 7237 IPRO; NA 7337 RR; NS 7490 RR; NS 7667 IPRO; NS 7901; NS 8338 IPRO; NS 8490 IPRO; NS 5160 IPRO; NA 5909- RG IPRO; NS 6006 IPRO; NS 6535 IPRO; NS 6767 RR; NS 6906 IPRO - Centro; NS 6909 IPRO - Sul; NS 7070 IPRO; NS 7209 IPRO; NS 7300 IPRO - Centro; NS 7338 IPRO; NS 7497 RR; NS 7670 RR ; NS 8094 RR; NS 8383 RR; Syn 15600 IPRO;Syn 16861 IPRO; Syn 1059 RR; Syn 1163 RR; Syn 1258 RR; Syn 1281 RR; Syn 1683 IPRO; Syn 1785 IPRO; Syn 1687 IPRO; Syn 13610 IPRO; Syn 15640 IPRO; Syn 15630 IPRO; Syn 1562 IPRO; Syn 1561 IPRO; Syn 1366 IPRO; CZ 15B64 IPRO; CZ15B70 IPRO; CZ 15B92 IPRO; CZ 26B05 IPRO; CZ 26B10 IPRO; CZ 26B77 IPRO; CZ 7022 IPRO; CZ 26B42 IPRO; CZ 26B36 IPRO; CZ 26B42 IPRO; CZ 26B77 IPRO; TEC 7022 IPRO; CZ 37B22 IPRO; CZ 37B43 IPRO; CZ 47B90 IPRO; CZ 58B28 IPRO; CZ 48B32 IPRO; CZ 58B61 IPRO; W 791 RR; W 842 RR; CZ 58B61 IPRO; BS 1511 IPRO; BS 1543 IPRO; ST 575 IPRO; BS 1580 IPRO; ST 592 IPRO; BS 2590 IPRO; BS 2606 IPRO- SUL; ST 644 IPRO; BSIRGA 1642 IPRO; TEC 6702 IPRO; BS 1691 IPRO; TEC 7849 IPRO; TECIRGA 6070 RR; BS 1519 LL; BS 2606 IPRO -CERRADO; TEC 6702 IPRO -CERRADO; TEC 7849 IPRO-CERRADO; ST 721 IPRO; TEC 7578 IPRO; ST 777 IPRO; ST 797 IPRO; ST 804 IPRO; ST 830 IPRO; ST 845 IPRO; W 787 IPRO; W 799 RR; ST 815 RR; ST 820 RR; ST 860 RR; ST 920 RR; W 870; BRASMAX COMPACTA IPRO; BRASMAX FIBRA IPRO BRASMAX ZEUS IPRO; BRASMAX DELTA IPRO; BRASMAX RAIO IPRO; BRASMAX ICONE IPRO; BRASMAX LANCA IPRO; BRASMAX GARRA IPRO; BRASMAX PONTA IPRO BRASMAX VALENTE RR; BRASMAX POTENCIA RR; BRASMAX TORNADO RR; BRASMAX ALVO RR; BRASMAX ATIVA RR; BRASMAX VELOZ RR; BRASMAX VELOZ RR; BRASMAX VORAZ IPRO; BRASMAX EXTREMA IPRO; BRASMAX UNICA IPRO; BRASMAX DOMINIO IPRO; BRASMAX FOCO IPRO; BRASMAX EXTREMA IPRO; BRASMAX EXTRA IPRO; BRASMAX CERTA IPRO; BRASMAX POWER IPRO; BRASMAX ULTRA IPRO; BRASMAX FLX IPRO; BRASMAX BONUS; BRASMAX PONTA IPRO; BRASMAX OPUS IPRO; BRASMAX DESAFIO RR; M5705IPRO; MS5838IPRO; M5892IPRO; M8644IPRO; M5917IPRO; M5947IPRO; M6210IPRO; M7739IPRO; M8349IPRO; M8372IPRO; M6410IPRO; M7110IPRO; M7198IPRO; M8210IPRO; M8808IPRO; 95R51; 95Y52; 97R22IPRO; 99R03; P98Y70; 95R90IPRO; 95Y72; 98Y21IPRO; 99R09; 95R95IPRO; 96Y90; 98Y30; P98C81; BG4290; BG4786; CD2720 IPRO; CD2728 IPRO; CD2820 IPRO; CD2851 IPRO; CD2857 RR; DS5916 IPRO; 5D6215 IPRO; 5D634 RR; 5G8015 IPRO; DS6017 IPRO; DS7417 IRPO; B5860 IPRO; BG4781 IPRO; DS6217 IPRO; TMG2375 IPRO; TMG2379 IPRO; TMG7058 IPRO; TMG2165 IPRO; TMG2165 IPRO; TMG4377 IPRO; TMG1180 RR;TMG7063IPRO; TMG7062 IPRO; TMG7067 IPRO; TMG4182; TMG4182; TMG7262 RR; TMG2185 IPRO; TMG7061 IPRO; TMG2381 IPRO; TMG2383 IPRO; TMG1288 RR; TMG2181 IPRO; TMG1188 RR; TMG2378 IPRO; TMG2173 IPRO; TMG4185; TMG 7363 RR: TMG7260 IPRO; TMG133 RR; TMG132 RR; ANTA82; TMG1182 RR; TMG2182 IPRO; TMG7161 RR; TMG2183 IPRO; TMG2286 IPRO; K8620 IPRO; RK5519 RR; M6210 IPRO; RK6719 IPRO; RK6316 IPRO; RK7518 IPRO; RK8115 IPRO; RK8317 IPRO; RK5813 RR; RK6813 RR; BRS 1001IPRO; BRS 1074IPRO; BRS 6970IPRO; BRS 7570IPRO; BRS 9383IPRO; BRS 1003IPRO; BRS 706IPRO; BRS 7170IPRO; BRS 7780IPRO; BRS 1007IPRO; BRS 713IPRO; BRS 7270IPRO; BRS 7180IPRO; BRS1010IPRO; BRS 729IPRO; BRS 7470IPRO; BRS 9180IPRO; 413RR; BRS 8890RR; BRSGO 8151RR; BRSMG 850GRR; BRS 378RR; BRSMG 760SRR; BRS 9090RR; BRS 740SRR; 750SRR; BRS Sambaiba RR; BRS 359RR; BRS 399RR; BRS 8160RR; BRS 7460RR; BRSMG 811CRR; BRS VALIOSA RR; BRS 232; BRS 283; BRS 257;BRS 284; BRSGO LUZIANIA; BRS Petala; BRSMG 790A; BRSMG 7525; MG / BR 46 (Conquista); BRS 8381; BRS 217 (Flora); BRS 252 (Serena); BRSMG 810C; BRSMG 68 (Vencedora); BRSGO Chapadoes; BRS Raimunda; BRS313 (TIETA); BRS Corisco; BRS Barreiras; BRS 314 (Gabriela); BRS Tracaja; BRS Perola

[0176] The variety of the plant is not particularly limited as long as it is a commonly cultivated variety.

[0177] The above-mentioned plants may be plants that can be produced by natural crossbreeding, plants that can be generated by mutation, F1 hybrid plants, transgenic plants (also called genetically modified plants). These plants generally have characteristics such as resistance to herbicides, accumulation of toxic substances against harmful organisms (also called pest resistance), suppression of susceptibility to diseases (also called disease resistance), increased yield potential, improved resistance to biotic and abiotic stress factors, altered product quality (e.g., increased or decreased content of specific components, changes in composition, improved storability or processability), altered harvest time (e.g., very early, early, mid-season, late, very late), etc.

[0178] An F1 hybrid plant is a first generation hybrid obtained by crossing two varieties of different lineages, and generally has hybrid vigor characteristics with superior traits to either parent. A transgenic plant is a plant that has been endowed with traits that cannot be easily obtained by cross breeding, mutagenesis, or natural recombination in a natural environment by introducing foreign genes from other organisms such as microorganisms.

[0179] The techniques for producing the above-mentioned plants include, for example, conventional breeding techniques, recombinant gene techniques, genomic breeding techniques, new breeding techniques, and genome editing techniques. Conventional breeding techniques are techniques for obtaining plants with desired properties through mutation or crossbreeding. Recombinant gene techniques are techniques for giving new properties to an organism by extracting a target gene (DNA) from a certain organism (e.g., a microorganism) and introducing it into the genome of another target organism, or antisense or RNA interference techniques for giving new or improved characteristics by silencing other genes present in the plant. Genomic breeding techniques are techniques for using genome information to make breeding more efficient, and include DNA marker (also called genome marker or gene marker) breeding techniques and genomic selection. For example, DNA marker breeding is a method of selecting progeny having a desired useful trait gene from a large number of progeny by using a DNA marker, which is a DNA sequence that marks the location of a specific useful trait gene on the genome. This method has the advantage that the time required for breeding can be effectively shortened by analyzing the progeny of the cross using DNA markers when they are still young plants. Genomic selection is a method of creating a prediction formula from phenotype and genome information obtained in advance, and predicting characteristics from the prediction formula and genome information without evaluating the phenotype, which can contribute to the efficiency of breeding. New breeding techniques are a general term for breeding techniques that combine molecular biological techniques. Examples include cisgenesis / intragenesis, oligonucleotide-directed mutagenesis, RNA-dependent DNA methylation, genome editing, grafting onto GM rootstocks or scions, reverse breeding, agroinfiltration, and seed production technology (SPT). Genome editing technology is a technology that converts genetic information in a sequence-specific manner, and allows for deletion of base sequences, replacement of amino acid sequences, introduction of foreign genes, etc. The tools include, for example, zinc finger nucleases (ZFN, ZFNs), TALEN, CRISPR / Cas9, CRISPER / Cpf1, and Meganuclease, which are capable of sequence-specific DNA cleavage. In addition, there are sequence-specific genome modification technologies such as CAS9 nickase and Target-AID, which are created by modifying the above-mentioned tools.

[0180] Examples of the above-mentioned plants include plants listed in the GM Approval Database on the electronic information site of the International Service for the Acquisition of Agri-Biotech Applications (ISAAA) (http: / / www.isaaa.org / ). More specifically, examples of the plants include herbicide-resistant plants, pest-resistant plants, disease-resistant plants, plants with modified product quality (e.g., increased or decreased content of ingredients, changes in composition, improved storability or processability), fertility-modified plants, abiotic stress-tolerant plants, and plants with modified traits related to growth or yield.

[0181] Examples of plants that have been made to tolerate herbicides include: Mechanisms of herbicide resistance include, for example, reduced affinity between the herbicide and its target; rapid metabolism (degradation, modification, etc.) of the herbicide by expression of enzymes that inactivate the herbicide; inhibition of herbicide uptake into the plant; and inhibition of herbicide translocation within the plant.

[0182] Plants that have been made resistant to herbicides by genetic engineering technology include, for example, plants that have been made resistant to protoporphyrinogen oxidase (hereinafter abbreviated as PPO) herbicides such as flumioxazin; 4-hydroxyphenylpyruvate dioxygenase (hereinafter abbreviated as HPPD) inhibitors such as isoxaflutole and mesotrione; acetolactate synthase (hereinafter abbreviated as ALS) inhibitors such as imidazolinone herbicides such as imazethapyr and sulfonylurea herbicides such as thifensulfuron methyl; 5-enolpyruvylshikimate-3-phosphate synthase (hereinafter abbreviated as EPSPS) inhibitors such as glyphosate; glutamine synthase inhibitors such as glufosinate; auxin herbicides such as 2,4-D and dicamba; and oxynil herbicides such as bromoxynil. Preferred herbicide-tolerant transgenic plants are cereals such as wheat, barley, rye, and oats, canola, sorghum, soybean, corn, cotton, rice, rapeseed, sugar beet, sugarcane, grapes, lentils, sunflower, alfalfa, pome fruits, stone fruits, coffee, tea, strawberry, turfgrass, tomato, potato, cucumber, lettuce, and other vegetables, more preferably cereals such as wheat, barley, rye, and oats, soybean, corn, rice, grapes, tomato, potato, and pome fruits. Specific herbicide-tolerant plants are shown below. Glyphosate herbicide-resistant plants: Plants that are obtained by introducing one or more of the following: a glyphosate-resistant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4; a glyphosate N-acetyltransferase gene (gat4601 or gat4621) modified from a glyphosate N-acetyltransferase gene derived from Bacillus licheniformis; a glyphosate oxidase gene (goxv247) derived from Ochrobacterum anthropi strain LBAA; or an EPSPS gene (mepsps or 2mepsps) having a glyphosate-resistant mutation derived from Zea mays. Major plants include, for example, alfalfa (Medicago sativa), Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), creeping bentgrass (Agrostis stolonifera), corn (Zea mays L.), Polish canola (Brassica rapa), potato (Solanum tuberosum L.), soybean (Glycine max L.), sugar beet (Beta vulgaris), and wheat (Triticum aestivum). Several glyphosate-tolerant plants are commercially available. For example, genetically modified plants into which CP4 epsps has been introduced are sold under trade names including "Roundup Ready (registered trademark)", genetically modified plants into which gat4601 or gat4621 has been introduced are sold under trade names such as "Optimum GAT (trademark)" and "Optimum (registered trademark) Gly canola", and genetically modified plants into which mepsps or 2mepsps has been introduced are sold under the trade name "GlyTol (trademark)".More specific glyphosate-tolerant plants include, for example, corn, "Roundup Ready™ Maize", "Roundup Ready™ 2 Maize", "Agrisure™ GT", "Agrisure™ GT / CB / LL", "Agrisure™ GT / RW", "Agrisure™ 3000GT", "YieldGard™ VT™ Rootworm™ RR2", and "YieldGard™ VT Triple"; soybean, "Roundup Ready™ Soybean" and "Optimum GAT™"; cotton, "Roundup Ready™ Cotton", "Roundup Ready™ Flex Cotton", and "GlyTol™"; canola, "Roundup Ready™ Canola" and "Optimum® Gly canola"; alfalfa, "Roundup Ready™ Alfalfa"; rice, "Roundup Ready™ VT™ Rootworm™ RR2", "YieldGard™ VT Triple ... sugarcane is sold under the trade names "Roundup Ready™ Rice"; sugarcane is sold under the trade names "Roundup Ready™ sugarbeet" and "InVigor™ sugarbeet"; wheat (Triticum aestivum) is sold under the trade names "Roundup Ready™ wheat." Glyphosinate herbicide-tolerant plants: These can be obtained by introducing one or more of the following genes: the phosphinothricin N-acetyltransferase (PAT) gene (bar) derived from Streptomyces hygroscopicus, the PAT gene (pat) derived from Streptomyces viridochromogenes, or the synthetic PAT gene (pat syn) derived from Streptomyces viridochromogenes strain Tu494. Major plants include, for example, Argentine canola (Brassica napus), chicory (Cichorium intybus), cotton (Gossypium hirsutum L.), corn (Zea mays L.), Polish canola (Brassica rapa), rice (Oryza sativa L.), soybean (Glycine max L.), and sugar beet (Beta vulgaris). Some glufosinate-tolerant plants are commercially available. For example, transgenic plants with bar or pat introduced are sold under the trade names "LibertyLink™", "InVigor™", or "WideStrike™". More specific glyphosinate tolerant plants are sold under the trade names, for example, "Roundup Ready™ 2", "Liberty Link™", "Herculex™ I", "Herculex RW", "Herculex XTRA™", "Agrisure™ GT / CB / LL", "Agrisure™ CB / LL / RW" and "Bt10" for corn; "FiberMax™ Liberty Link™" for cotton; "Liberty Link™ Rice" for rice; "inVigor™ Canola" for canola; "Liberty Link™ Soybean" for soybeans; and "Liberty Link™ sugarbeet" for sugarcane. Oxynil herbicide (e.g. bromoxynil) resistant plants: Obtained by introducing the nitrilase gene (bxn) derived from Klebsiella pneumoniae subsp. Ozaenae. Major plants include, for example, Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.) and tobacco (Nicotiana tabacum L.). Some oxynil herbicide resistant plants are commercially available. For example, they are sold under the trade names "Navigator (trademark)" or "BXN (trademark)". More specific oxynil herbicide resistant plants include, for example, cotton sold under the trade name "BXN (trademark) Cotton" and Argentine canola sold under the trade name "Navigator (trademark) Cotton". ALS herbicide-resistant plants: Carnations (Dianthus caryophyllus) into which the ALS herbicide-resistant ALS gene (surB) derived from tobacco (Nicotiana tabacum) has been introduced as a selection marker are sold under the trade names, for example, "Moondust (trademark)", "Moonshadow (trademark)", "Moonshade (trademark)", "Moonlite (trademark)", "Moonaqua (trademark)", "Moonvista (trademark)", "Moonique (trademark)", "Moonpearl (trademark)", "Moonberry (trademark)" or "Moonvelvet (trademark)". Flax (Linum usitatissumum L.) into which the ALS herbicide-resistant ALS gene (als) derived from Arabidopsis thaliana has been introduced is sold under the trade name, for example, "CDC Triffid Flax". Corn (Zea mays L.) resistant to sulfonylurea and imidazolinone herbicides, into which the corn-derived ALS herbicide-resistant ALS gene (zm-hra) has been introduced, is sold, for example, under the trade name "Optimum GAT (trademark)". Soybeans resistant to imidazolinone herbicides, into which the Arabidopsis-derived ALS herbicide-resistant ALS gene (csr1-2) has been introduced, are sold, for example, under the trade name "Cultivance". Soybeans into which the soybean (Glycine max)-derived ALS herbicide-resistant ALS gene (gm-hra) has been introduced, are sold, for example, under the trade names "Treus (trademark)", "Plenish (trademark)" and "Optimum GAT (trademark)". Cotton into which the tobacco (Nicotiana tabacum cv. Xanthi)-derived ALS herbicide-resistant ALS gene (S4-HrA) has been introduced, is also available. HPPD herbicide-resistant plants: Obtained by introducing the HPPD gene (avhppd-03) derived from Avena sativa. For example, soybeans into which the PAT gene (pat) derived from Streptomyces viridochromogenes was introduced at the same time as the above genes are sold under the trade name "Herbicide-tolerant Soybean line" as soybeans resistant to mesotrione and glufosinate. 2,4-D-resistant plants or ACCase herbicide-resistant plants: Corn resistant to 2,4-D or ACCase herbicides, which has been introduced with the aryloxyalkanoate dioxygenase gene (aad-1) derived from Sphingobium herbicidovorans, is sold under the trade name "Enlist (trademark) Maize". Soybeans and cotton resistant to 2,4-D or ACCase herbicides, which has been introduced with the aryloxyalkanoate dioxygenase gene (aad-12) derived from Delftia acidovorans, are known and are sold under the trade name "Enlist (trademark) Soybean". Dicamba herbicide-resistant plants: Obtained by introducing the dicamba monooxygenase gene (dmo) derived from Stenotrophomonas maltophilia strain DI-6. Soybeans and cotton into which the above gene has been introduced are known. Soybeans (Glycine max L.) into which the glyphosate-resistant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4 has been introduced in addition to the above gene are sold under the trade name "Genuity (registered trademark) Roundup Ready (trademark) 2 Xtend (trademark)", for example. Further plants with engineered tolerance to herbicides are widely known, for example alfalfa, apple, barley, eucalyptus, flax, grape, lentil, rapeseed, pea, potato, rice, sugar beet, sunflower, tobacco, tomato, turfgrass and wheat resistant to glyphosate (see, for example, US5188642, US4940835, US5633435, US5804425, US5627061); bean, cotton, soybean, pea, potato, sunflower, tomato resistant to dicamba. , tobacco, corn, sorghum and sugarcane (see, for example, WO2008 / 051633, US7105724 and US5670454); soybean, sugar beet, potato, tomato and tobacco resistant to glufosinate (see, for example, US6376754, US5646024, US5561236); cotton, peppers, apple, tomato, sunflower, tobacco, potato, corn, cucumber, wheat, soybean, sorghum and millet resistant to 2,4-D (see, for example, US6153401, US6100446, WO2005 / 107437, US5608147 and US5670454); canola, corn, millet, barley, cotton, mustard, lettuce, lentil, melon, foxtail millet, oat, nata, potato, rice, rye, sorghum, soybean, sugar beet, sunflower, tobacco, tomato and wheat (see, e.g., US5013659, WO2006 / 060634, US4761373, US5304732, US6211438, US6211439 and Rice plants that are resistant to herbicides, particularly imidazolinone herbicides, are known, including rice plants with specific mutations in the acetohydroxyacid synthase gene (e.g., S653N, S654K, A122T, S653(At)N, S654(At)K, A122(At)T (e.g., see US2003 / 0217381, WO2005 / 020673); HPPD inhibitor herbicides (e.g., isoxazole herbicides such as isoxaflutole;Barley, sugarcane, rice, corn, tobacco, soybean, cotton, rapeseed, sugar beet, wheat and potato resistant to triketone herbicides such as sulcotrione and mesotrione; and pyrazole herbicides such as pyrazolinates) or diketonitrile decomposition products of isoxaflutole (see, for example, WO2004 / 055191, WO1996 / 38567, WO1997 / 049816 and US6791014); and wheat, soybean, cotton, sugar beet, rapeseed, rice, corn, sorghum, sugarcane and sugar beet resistant to PPO-inhibiting herbicides (see, for example, US2002 / 0073443, US2008 / 0052798, Pest Management Science, 61, 2005, 277-285).

[0183] Examples of plants that have been given herbicide resistance by conventional breeding techniques or genome breeding techniques include "Clearfield (registered trademark) Rice", "Clearfield (registered trademark) Wheat", "Clearfield (registered trademark) Sunflower", "Clearfield (registered trademark) lentils", and "Clearfield (registered trademark) canola" (BASF products) that are resistant to imidazolinone ALS-inhibiting herbicides such as imazethapyr and imazamox; "STS soybean" that is resistant to sulfonylurea ALS-inhibiting herbicides such as thifensulfuron-methyl; and "SR corn" ("Poast Protected (registered trademark) corn); ExpressSun® sunflower tolerant to sulfonylurea herbicides such as tribenuron; Provisia® Rice tolerant to acetyl-CoA carboxylase inhibitors such as quizalofop; and Triazine Tolerant Canola tolerant to photosystem II inhibitors; and Igrowth® sorghum tolerant to imidazolinone herbicides.

[0184] An example of a plant that has been given herbicide resistance by genome editing technology is the canola "SU Canola" that has sulfonylurea herbicide resistance using the Rapid Trait Development System (RTDS). RTDS is a genome editing technology that corresponds to oligonucleotide-directed mutagenesis, and is a technology that can introduce mutations without cutting the DNA in the plant through Gene Repair Oligonucleotide (GRON), i.e., a chimeric oligonucleotide of DNA and RNA. Other examples include corn that has reduced herbicide resistance and phytic acid content by deleting the endogenous gene IPK1 using zinc finger nuclease (see, for example, Nature 459, 437-441 2009); and rice that has been given herbicide resistance using CRISPR-Cas9 (see, for example, Rice, 7, 5 2014).

[0185] An example of a plant that has been given herbicide resistance through new breeding techniques is soybean, whose scion has been given the properties of a GM rootstock through a breeding technique using grafting.Specifically, there is soybean in which glyphosate resistance has been given to a non-transgenic soybean scion using the glyphosate-resistant Roundup Ready (registered trademark) soybean as the rootstock (see Weed Technology 2013, 27, 412).

[0186] Examples of plants that have been given pest resistance include:

[0187] Examples of plants that have been made resistant to lepidopteran pests through genetic engineering include corn (Zea mays L.), soybean (Glycine max L.), cotton (Gossypium hirsutum L.), rice (Oryza sativa L.), poplar (Populus sp.), tomato (Lycopersicon esculentum), eggplant (Solanum melongena), and sugarcane (Saccharum sp.) into which a gene encoding delta-endotoxin, an insecticidal protein derived from the soil bacterium Bacillus thuringiensis (hereinafter referred to as Bt), has been introduced. Examples of delta-endotoxins that confer resistance to lepidopteran pests include Cry1A, Cry1Ab, modified Cry1Ab (Cry1Ab with a partial deletion), Cry1Ac, Cry1Ab-Ac (a hybrid protein in which Cry1Ab and Cry1Ac are fused), Cry1C, Cry1F, Cry1Fa2 (modified cry1F), moCry1F (modified Cry1F), Cry1A.105 (a hybrid protein in which Cry1Ab, Cry1Ac and Cry1F are fused), Cry2Ab2, Cry2Ae, Cry9C, Vip3A and Vip3Aa20. Examples of plants that have been given resistance to coleopteran pests by genetic engineering include corn and potato into which a gene encoding delta-endotoxin, an insecticidal protein derived from the soil bacterium Bt, has been introduced. Examples of delta-endotoxins that confer resistance to coleopteran pests include Cry3A, mCry3A (modified Cry3A), Cry3Bb1, Cry34Ab1, Cry35Ab1, Cry6A, Cry6Aa, and mCry6Aa (modified Cry6Aa). Examples of plants that have been given resistance to dipteran pests through genetic engineering include corn (Zea mays L.) into which a synthetic gene encoding the hybrid protein eCry3.1Ab, which is a fusion of Cry3A and Cry1Ab derived from the soil bacterium Bt, has been introduced, and cotton (Gossypium hirsutum L.) into which a gene encoding the trypsin inhibitor CpTI derived from cowpea (Vigna unguiculata) has been introduced.Furthermore, there are poplars into which a gene encoding API, a protease inhibitor protein A derived from water chestnut (Sagittaria sagittifolia), has been introduced, which show resistance to a wide range of pests. Insecticidal proteins that confer pest resistance to plants also include hybrid proteins, partially deleted proteins, and modified proteins of the above-mentioned insecticidal proteins. Hybrid proteins are produced by combining different domains of multiple insecticidal proteins using genetic recombination technology, and Cry1Ab-Ac and Cry1A.105 are known. As a partially deleted protein, Cry1Ab, which is missing a part of the amino acid sequence, is known. As modified proteins, proteins in which one or more amino acids of natural delta-endotoxin are replaced, such as Cry1Fa2, moCry1F, and mCry3A, are known. In addition, modified proteins also include those in which a protease recognition sequence that does not exist in nature is inserted into a toxin, such as Cry3A055 (see WO2003 / 018810), in which a cathepsin G-recognition sequence is inserted into Cry3A toxin. Monsanto has developed cotton (event MON88702) that incorporates the modified BT protein Cry51Aa2 (Cry51Aa2.834_16) using recombinant gene technology, and the cotton exhibits resistance to lygus species such as Lygus lineolaris, Hemiptera such as aphids, and Thrips such as Frankliniella species. Other insecticidal proteins that confer pest resistance to plants by recombinant gene technology include, for example, insecticidal proteins derived from Bacillus cereus or Bacillus popilliae; plant insecticidal proteins Vip1, Vip2, Vip3 (subclasses Vip3Aa to Vip3Aj, Vip3Ba, Vip3B, and Vip3Ca are known, and specific examples thereof include Vip3Aa20 and Vip3Aa61) and Vip4; insecticidal proteins derived from nematode-symbiotic bacteria (forming colonies in nematodes) such as Photorhabdus spp., such as Photorhabdus luminescens, or Xenorhabdus spp., such as Xenorhabdus nematophilus; macrodonta (insecticidal protein Tma12 derived from Tactaria macrodonata); insecticidal protein IPD083 derived from Adiantum spp. (insecticidal protein IPD083 derived from Adiantum spp.); insecticidal protein IPD113 derived from Pteris cretica cv. albolineata or Pteris umbrosa (insecticidal protein IPD113 derived from Pteris cretica cv.albolineata or Pteris umbrosa); toxins produced by animals, including insect-specific neurotoxins such as scorpion toxins, spider toxins, wasp toxins; toxins produced by filamentous fungi such as Streptomycetes venom; plant lectins such as pea lectin, barley lectin, snowdrop lectin; agglutinins; protease inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, papain inhibitors; ribosome-inactivating proteins (RIPs) such as ricin, maize-RIP, abrin, rufin, saporin, bryodin; steroid metabolic enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, cholesterol oxidase; ecdysone inhibitors; HMG-CoA-reductase; ion channel inhibitors such as sodium channel inhibitors, calcium channel inhibitors; juvenile hormone esterase; diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase; and glucanase.

[0188] Furthermore, plants to which pest resistance has been imparted by introducing one or more insecticidal protein genes are already known, and some of these plants are commercially available. Examples of cotton that has been given pest resistance include "Bollgard(TM) cotton", "BXN(TM) Plus Bollgard(TM) Cotton", "BXN(TM) Plus Bollgard(TM) Cotton", "JK 1", "Roundup Ready(TM) Bollgard(TM) Cotton" and "Ingard(TM)" that express the insecticidal protein Cry1Ac derived from Bt bacteria; "Herculex(TM) I" and "Herculex(TM) CB" that express the insecticidal protein modified Cry1F (Cry1Fa2) derived from Bt bacteria; "VIPCOT(TM) Cotton" that expresses the insecticidal protein Vip3A derived from Bt bacteria; "Bollgard II(TM) cotton", "Roundup Ready(TM) Bollgard II(TM) Cotton", "Roundup Ready(TM) Flex(TM) Bollgard II(TM)" that express the insecticidal proteins Cry1Ac and Cry2Ab derived from Bt bacteria. "Fivermax™ Liberty Link™ Bollgard II™"; "Bollgard III™" and "Bollgard™ III x Roundup Ready™ Flex™" expressing insecticidal proteins Cry1Ac, Cry2Ab and Vip3A derived from Bt bacteria; "VIPCOT™ Roundup Ready Flex™ Cotton" expressing insecticidal proteins Vip3A and...

Claims

1. Formula (I) 【Chemistry 1】 [During the ceremony, L is a single bond or -(CR 4a R 4b ) n - represents R 4a and R 4b are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, a halogen atom, or a hydrogen atom, n represents 1, 2, 3, 4, 5, or 6; R 1 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from the group consisting of a cyclopropyl group and a halogen atom, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a cyano group, a halogen atom, a hydroxy group, or a hydrogen atom; Q is a group represented by formula A1, a group represented by formula A2, a group represented by formula A3, a group represented by formula A4, a group represented by formula A5, or a group represented by formula A6 (# is R 2 represents a bonding site with a carbon atom), 【Chemistry 2】 Q 1 , Q 2 , and Q 3 The combination of Q 1 is CR 3q1 And Q 2 is CR 3q2 And Q 3 is CR 3q3 A combination in which: Q 1 is a nitrogen atom, and Q 2 is CR 3q2 And Q 3 is CR 3q3 A combination in which: Q 1 is CR 3q1 And Q 2 is a nitrogen atom, and Q 3 is CR 3q3 or Q 1 is CR 3q1 And Q 2 is CR 3q2 And Q 3 represents a nitrogen atom, Q 1a and Q. 2a The combination of Q 1a is CR 3q4 And Q 2a is CR 3q5 A combination in which: Q 1a is a nitrogen atom, and Q 2a is CR 3q5 or Q 1a is CR 3q4 And Q 2a represents a nitrogen atom, R 3q1 , R 3q2 , R 3q3 , R 3q4 , R 3q5 and R 4 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group C, a phenyl group optionally substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group B, a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from group E, NR 6 C(O)R 5 , N.R. 6 C(O)OR 5 , N.R. 6 C(O)NR 5 R 12 , C(O)NR 6 R 7 , C(=NOR 9 ) R 5 , C(=NOR 9 ) (NR 6 R 7 ), N=S(O) p R 28 R 15 , a cyano group, a halogen atom, or a hydrogen atom; Z 1 represents an oxygen atom or a sulfur atom, p represents 0 or 1; R 5 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group B, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom, R 6 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R 7 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group B, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom, R 9 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group B, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom, R 12 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R 15 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group B, or a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group B, R 2 represents a phenyl group which may be substituted with one or more substituents selected from group A, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group A, C(O)NR 6 R 7 , C(=NOR 9 ) R 5 , C(=NOR 9 ) (NR 6 R 7 ), C(O)R 5 , N.R. 16 C(O)R 17 , N.R. 16 C(O)OR 17 , N.R. 16 C(O)NR 17 R 18 , S(O) 2 N.R. 16 R 17 , OR 18 , S(O) m R 15 , a mercapto group, a group represented by formula E1, a group represented by formula E2, or a group represented by formula E3 (# 2 represents a bonding site to a group represented by formula A1, a group represented by formula A2, a group represented by formula A3, a group represented by formula A4, a group represented by formula A5, or a group represented by formula A6), 【Chemistry 3】 m represents 0, 1, or 2; R 16 , R 17 , and R 18 are the same or different and represent a phenyl group which may be substituted by one or more substituents selected from group B, a 5- or 6-membered heterocyclic group which may be substituted by one or more substituents selected from group B, a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more substituents selected from group E, or a hydrogen atom; R 2 is NR 16 C(O)R 17 If R 16 and R 17 is R 16 A nitrogen atom to which R is bonded, 17 may form, together with the carbon atom to which it is bonded, a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group (the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms); R 2 is NR 16 C(O)OR 17 If R 16 and R 17 is R 16 a nitrogen atom to which the nitrogen atom is bonded, a carbon atom to which the nitrogen atom is bonded, and R 17 may form, together with the oxygen atom to which it is bonded, a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group (the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms); R 2 is NR 16 C(O)NR 17 R 18 If R 16 and R 17 is R 16 a nitrogen atom to which the nitrogen atom is bonded, a carbon atom to which the nitrogen atom is bonded, and R 17 may form, together with the nitrogen atom to which it is bonded, a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group (the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms); Q 5 is CR E11 R 27 , N.R. E12 , an oxygen atom, or a sulfur atom; Q 4 is CR E13 or a nitrogen atom, Q 6 is CR E14 or a nitrogen atom, Q 7 is CR E15 or a nitrogen atom, Q 8 is CR E16 or a nitrogen atom, Q 9 is CR E17 or a nitrogen atom (provided that in the group represented by formula E2, Q 6 and Q. 7 is also a nitrogen atom, Q 6 , Q 8 , and Q 9 are simultaneously nitrogen atoms, and Q 7 , Q 8 , and Q 9 is also a nitrogen atom), Q 10 is CR E18 or a nitrogen atom, R E11 and R E31 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group C, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, C(O)NR 7 R 8 , N.R. 9 C(O)R 5 a C3-C6 cycloalkyl group optionally substituted by one or more substituents selected from group E, a cyano group, a halogen atom, or a hydrogen atom, R 8 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E, or a hydrogen atom; R E12 and R E32 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group C, a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from group E, or a hydrogen atom; R 27 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, a phenyl group which may be substituted with one or more substituents selected from group B, or a hydrogen atom; R E13 , R E14 , R E15 , R E16 , R E17 , and R E18 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group C, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, C(O)NR 7 R 8 , N.R. 9 C(O)R 5 a C3-C6 cycloalkyl group optionally substituted by one or more substituents selected from group E, a cyano group, a halogen atom, or a hydrogen atom, X is NR 10 C(Z)R 11 , N.R. 10 C(O)OR 11 , N.R. 10 C(Z)NR 11 R 12 , N.R. 10 C (=NOR 9 ) R 11 , N.R. 10 C (=NOR 9 ) (NR 11 R 12 ), N=C(OR 9 ) R 11 , N=C(SR 15 ) R 11 , N=C(NR 6 R 7 ) R 11 , N.R. 10 X 1 Or N=S(O) p R 11 R 28 represents Z represents an oxygen atom or a sulfur atom; X 1 represents a 9- or 10-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group A, R 10 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group F, a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from group E, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, OR 14 , C(O)R 13 , C(O)OR 13 , C(=NR 7 ) R 13 , C(O)NR 6 R 7 、 or a hydrogen atom, R 11 represents a phenyl group which may be substituted with one or more substituents selected from group A, or a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group A, R 13 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group {the phenyl group is optionally substituted with one or more substituents selected from the group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a cyano group, and a halogen atom}, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom, R 14 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a phenylmethyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 28 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group C, or a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group E. Group A: a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, a cyano group, and a halogen atom}, a C3-C6 cycloalkyl group {the C3-C6 cycloalkyl group may be substituted with one or more substituents selected from the group consisting of a C1-C6 alkoxy group, a cyano group, and a halogen atom}, a phenyl group which may be substituted with one or more substituents selected from Group B, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from Group B, OR 3a , S.F. 5 , N.R. 3d OR 3b , N.R. 3b C(O)R 3c , N.R. 3d N.R. 3b C(O)R 3c , N.R. 3b C(O)OR 3e , N.R. 3d N.R. 3b C(O)OR 3e , N.R. 3b C(O)NR 3f R 3g , N.R. 3d N.R. 3b C(O)NR 3f R 3g , N=S(O) p R 3h R 3i , C(O)R 3c , C(O)OR 3j , C(O)NR 3f R 3g , S(O) 2 N.R. 3f R 3g , N.R. 3b C (=NOR 3j ) R 3d , N.R. 3b S (O) 2 R 3k , S(O) m R 3k The group consisting of a cyano group, a nitro group, and a halogen atom. R 3a represents a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a halogen atom and a cyano group, a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group B, C(O)R 3c , C(O)OR 3j , C(O)NR 3f R 3g , S(O) 2 R 3k or a hydrogen atom, R 3b represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 3c represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group B, or a hydrogen atom, R 3d represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 3e represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a (C1-C3 alkyl)phenyl group {the phenyl moiety in the (C1-C3 alkyl)phenyl group may be substituted with one or more substituents selected from group B}, R 3f represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 3g represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 3h represents a C1-C6 alkyl group optionally substituted by one or more halogen atoms, a phenyl group optionally substituted by one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from group B, or a C3-C6 cycloalkyl group optionally substituted by one or more halogen atoms, R 3i represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, R 3j represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group B, or a hydrogen atom; R 3k represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group B, or a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms. Group B: a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C3-C6 cycloalkyl groups optionally substituted with one or more halogen atoms, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, cyano groups, hydroxy groups, and halogen atoms. Group C: a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from group E, a phenyl group optionally substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group B, OR 3a , N.R. 3d OR 3b , N.R. 3b C(O)R 3c , N.R. 3d N.R. 3b C(O)R 3c , N.R. 3b C(O)OR 3e , N.R. 3d N.R. 3b C(O)OR 3e , N.R. 3b C(O)NR 3f R 3g , N.R. 3d N.R. 3b C(O)NR 3f R 3g , N=S(O) p R 3h R 3i , C(O)R 3c , C(O)OR 3j , C(O)NR 3f R 3g , S(O) m R 3k The group consisting of a cyano group, a nitro group, and a halogen atom. Group E: a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, OR 3a , S(O) m R 3k The group consisting of an oxo group, a cyano group, and a halogen atom. Group F: a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from group E, a phenyl group optionally substituted with one or more substituents selected from group B, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group B, OR 3a , S(O) m R 3k , C(O)R 3c , C(O)OR 3j , C(O)NR 3f R 3g , N.R. 3b R 3c , N.R. 3b C(O)R 3c , N.R. 3b C(O)NR 3f R 3g , N=S(O) p R 3h R 3i the group consisting of a 3- to 6-membered non-aromatic heterocyclic group, a cyano group, and a halogen atom. or an N-oxide thereof, or a salt thereof to harmful arthropods, a habitat of harmful arthropods, a plant, or a cultivation carrier of a plant.

2. 2. The method for controlling arthropod pests according to claim 1, wherein the cultivation carrier for the plant is soil.

3. A composition comprising the compound represented by formula (I) according to claim 1 or an N-oxide thereof, or a salt thereof, and one or more components selected from the group consisting of group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i) and group (j): Group (a): A group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients; Group (b): bactericidal active ingredient; Group (c): plant growth regulating ingredients; Group (d): phytotoxicity-safening components; Group (e): synergists; Group (f): repellent components; Group (g): molluscicidal components; Group (h): insect pheromones; Group (i): herbicidal active ingredients; Group (j): biological control materials.

4. A method for controlling arthropod pests, which comprises the step of applying an effective amount of the composition according to claim 3 to arthropod pests, their habitats, plants, or cultivation carriers for plants.

5. The method for controlling arthropod pests according to claim 4, wherein the support for cultivating plants is soil.

6. A seed or vegetative reproductive organ carrying an effective amount of a compound of formula (I) or an N-oxide thereof or a salt thereof as defined in claim 1, or a composition as defined in claim 3.

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