Damaged hair improving agent and hair cosmetic

Abstract

To provide a combination and / or structure of hair-improving compositions capable of reducing roughness and dryness on the hair surface and improving the manageability of the hair, thereby solving the problem in which: various silicones enhance the lubricity of hair; however, their adsorption and residue may affect treatments and effects such as coloring and perming; furthermore, the suppression of dryness in damaged hair is only temporary, and the resulting manageability of the hair is not fully satisfactory.SOLUTION: The problem can be solved by applying to the hair a composition relating to a combination and / or structure containing one or more substances selected from a group consisting of dimer acid derivatives that exhibit a highly viscous liquid or paste form at 25°C.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] The present invention relates to a combination and / or structure of a damaged hair improving agent and a hair cosmetic. The hair improving agent of the present invention includes a combination and / or structure of a damaged hair improving agent and a hair cosmetic. [Background technology]

[0002] In recent years, hair damage caused by chemical treatments such as hair dyes and perms, or physical treatments such as friction and heat, has become a major problem. Therefore, how to improve this damaged hair is a major issue, and various companies are conducting research into improving and repairing the quality of damaged hair. Here, improving hair damage means improving so-called hair that is difficult to run your fingers through and dry hair, giving the hair a smooth and slippery feel, making it easy to run your fingers through, and eliminating the dry feeling.

[0003] A conventional method for improving such damaged hair is to apply a high molecular weight dimethylpolysiloxane and a low viscosity silicone to the hair to impart smoothness and a moisturized feel to the hair (Patent Document 1). On the other hand, as hair coloring has become commonplace, there are concerns that using hair care products containing a high concentration of silicone oil may reduce the effectiveness of hair dyes or permanent agents, and so silicone-free formulations are in demand. As a result, non-silicone shampoo formulations (Patent Documents 2 and 3) and silicone-free hair care conditioning agents have been developed (Patent Document 4).

[0004] Furthermore, the market for natural cosmetics is growing, and many hair cosmetics using vegetable oils and plant-derived ingredients are now being used. One known method for improving the feel of hair involves combining one or more vegetable oils selected from olive oil, meadowfoam oil, and camellia japonica oil with pentaerythrityl tetra-2-ethylhexanoate, which improves manageability at the ends of hair, provides an oily feel to the touch, and imparts softness (Patent Document 5). Vegetable oils have a higher affinity for skin and hair than mineral oils, but are prone to oxidation and therefore have poor storage stability. Oxidized vegetable oils are known to cause pigmentation on the skin. Furthermore, vegetable oils pose various challenges, such as price fluctuations, due to fluctuations in harvest yields caused by weather, resulting in unstable supply.

[0005] To address these issues with conventional vegetable oils, a hair wax formulation has been disclosed that uses a dimer dilinoleic acid derivative in combination with a (diglycerin / dilinoleic acid / hydroxystearic acid) copolymer and a (polyglyceryl-2 isostearate / dimer dilinoleic acid) copolymer, in combination with dimethicone (Patent Document 6). [Prior art documents] [Patent documents]

[0006] [Patent Document 1] Japanese Patent Application Laid-Open No. 2005-015462 [Patent Document 2] Japanese Patent Application Publication No. 2017-052726 [Patent Document 3] Japanese Patent Publication No. 2020-083848 [Patent Document 4] Special Publication No. 2018-515577 [Patent Document 5] Japanese Patent Application Laid-Open No. 2012-092039 [Patent Document 6] Japanese Patent Application Laid-Open No. 2007-284371 Summary of the Invention [Problem to be solved by the invention]

[0007] While various silicones increase the lubricity of hair, there are concerns that residual adsorption may affect the effectiveness of treatments such as coloring and perming, and the reduction in dryness of damaged hair is only temporary, and the manageability of hair is not fully satisfactory.

[0008] That is, the present invention has been made in view of the above circumstances, and has an object to provide a hair improving agent that reduces the roughness and dryness of the hair surface and improves the manageability of hair. [Means for solving the problem]

[0009] The present inventors have conducted various investigations to solve the above-mentioned problems, and as a result, have found that the above-mentioned problems can be solved by applying to hair a composition having a structure containing one or more substances selected from the group consisting of dimer acid derivatives that are in a highly viscous liquid or paste state at 25°C, and have thus completed the present invention.

[0010] Surprisingly, it has been found that compositions according to a specific combination and / or structure comprising at least one dimer acid derivative and at least one oil in at least one organic solvent make it possible to achieve the above-stated objectives.

[0011] One subject of the present invention is therefore a combination and / or structure of hair improvement agents, a) one or more substances selected from dimer acid derivatives and mixtures thereof that are in the form of a highly viscous liquid or paste at 25°C; and b) one or more solvents; The hair improvement agent has a combination and / or structure containing 0 or less than 10% by mass of silicone.

[0012] Examples of the dimer acid derivatives include hydrogenated castor oil isostearate, hydrogenated castor oil dimer dilinoleate, (polyglyceryl-2 isostearate / dimer dilinoleate) copolymer, (phytosteryl / isostearyl / cetyl / stearyl / behenyl) dimer dilinoleate, dimer dilinoleyl bis(phytosteryl / behenyl / isostearyl) dimer dilinoleate, (phytosteryl / behenyl) dimer dilinoleate, di(isostearyl / phytosteryl) dimer dilinoleate, dimer dilinoleyl hydrogenated rosin condensate, dimer dilinoleyl isostearate, dimer dilinoleyl diisostearate, di(C20-40)alkyl dimer dilinoleate, dimer dilinoleyl dimer dilinoleate, (PPG-26 / dimer dilinoleate) copolymer, (hemp seed oil dimer dilinoleyl esters / dimer dilinoleate), Acid) copolymer, (polyglyceryl-2 isononanoate / dimer dilinoleate) copolymer, (ethylenediamine / stearyl dimer dilinoleate) copolymer, (ethylenediamine / stearyl dimer tall oil fatty acid) copolymer, (diethylene glycol / dimer dilinoleate) copolymer, (diethylene glycol / hydrogenated dimer dilinoleate) copolymer, (dimer dilinoleate / stearic acid / hydroxystearic acid) polyglyceryl-10, (mango seed butter dimer dilinoleyl esters / dimer dilinoleate) copolymer, (hydrogenated dimer dilinoleyl / dimethyl carbonate) copolymer, dimer dilinoleate (IPDI / PEG-15 cocamine) copolymer, dimer dilinoleate (IPDI / PEG-15 soyamine) copolymer, octyldodecyl dimer dilinoleate / PPG-3 myristyl ether, and the like. Among the above dimer acid derivatives, more preferred examples from the viewpoint of improving the body and resilience of hair include (polyglyceryl-2 isostearate / dimer dilinoleate) copolymer, hydrogenated castor oil isostearate, (diglycerin / dilinoleic acid / hydroxystearic acid) copolymer, dipentaerythrityl hexa(hydroxystearate / stearic acid / rosin acid), and hydrogenated castor oil dimer dilinoleate.

[0013] In the present invention, the above-mentioned object can be achieved by using a volatile oil, an ester oil, a hydrocarbon oil, or an animal or vegetable oil as the oil to be combined with the dimer acid derivative. From the viewpoint of adapting to individual differences in hair, the degree of damage, and a wide range of uses, it is preferable to use a combination of two or more of these oils. Specific examples of oils that can be used in the present invention include the following volatile oils, ester oils, hydrocarbon oils, higher fatty acids, and animal or vegetable oils.

[0014] Specific preferred examples of the volatile oil include hydrocarbon oils such as isododecane and isohexadecane, and cyclic silicone oils such as decamethylcyclopentasiloxane. Among the above volatile oils, more preferred examples include isododecane and isohexadecane from the viewpoint of the feel on the hair when applied to the hair and after evaporation, and from the viewpoint of application to silicone-free formulations.

[0015] Specific preferred examples of the ester oil include monoesters such as isononyl isononanoate and isotridecyl isononanoate, which are isononanoic acid esters, cetyl ethylhexanoate and hexyldecyl ethylhexanoate, which are 2-ethylhexanoic acid esters, isopropyl myristate, isocetyl myristate, and octyldodecyl myristate, which are myristate esters, ethyl isostearate, isopropyl isostearate, hexyldecyl isostearate, isostearyl isostearate, cholesteryl isostearate, and phytosteryl isostearate, which are lactic acid esters, isostearyl lactate and octyldodecyl lactate, and hydrochloric acid esters such as hydroxypropyl ... Examples of hydroxystearic acid esters include ethylhexyl hydroxystearate, octyl hydroxystearate, phytosteryl hydroxystearate, and cholesteryl hydroxystearate; oleic acid esters include oleyl oleate, phytosteryl oleate, and octyldodecyl oleate; neopentanoic acid esters include isodecyl neopentanoate and isostearyl neopentanoate; palmitic acid esters include isopropyl palmitate and ethylhexyl palmitate; and others include octyldodecyl neodecanoate, octyldodecyl ricinoleate, oleyl erucate, octyldodecyl erucate, and isopropyl lauroyl sarcosine.

[0016] Examples of diester oils include diisobutyl adipate, diisopropyl adipate, diethylhexyl succinate, neopentyl glycol diisononanoate, neopentyl glycol diethylhexanoate, neopentyl glycol dicaprate, diisostearyl malate, diisopropyl dilinoleate, ethylene glycol dioctanoate, octyldodecyl stearoyloxystearate, diisopropyl sebacate, di(cholesteryl / octyldodecyl) lauroyl glutamate, and di(phytosteryl / octyldodecyl) lauroyl glutamate. Examples of triester oils include triethylhexanoin, trimethylolpropane triethylhexanoate, tri(caprylic / capric acid)glyceryl, triisostearin, and trimethylolpropane triisostearate. Examples of tetraester oils include pentaerythrityl tetraethylhexanoate and pentaerythrityl tetraisostearate.

[0017] Examples of polyester oils include polyglycerin fatty acid esters such as polyglyceryl-2 isostearate, polyglyceryl-2 diisostearate, polyglyceryl-2 triisostearate, and polyglyceryl-2 tetraisostearate. Examples of high viscosity ester oils include dipentaerythrityl hexa(hydroxystearate / stearic acid / rosinate), di(cholesteryl / behenyl / octyldodecyl) lauroyl glutamate, di(octyldodecyl / phytosteryl / behenyl) lauroyl glutamate, myristoyl methylalanine (phytosteryl / decyltetradecyl), and diglycerin / dilinoleic acid / hydroxystearic acid copolymer.

[0018] Specific preferred examples of hydrocarbon oils include ozokerite, squalane, squalene, ceresin, paraffin, isoparaffin, paraffin wax, liquid paraffin, pristane, polyisobutylene, polyisobutene, hydrogenated polyisobutene, microcrystalline wax, polyethylene wax, and petrolatum. Among the above hydrocarbon oils, more preferred examples from the viewpoint of the feel when applied to hair include squalane and liquid paraffin.

[0019] Specific preferred examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), isostearic acid, and 12-hydroxystearic acid. Among the above higher fatty acids, from the viewpoint of the feeling when applied to hair, a more preferred example is isostearic acid.

[0020] Specific preferred examples of animal and vegetable oils include avocado oil, perilla oil, olive oil, cacao butter, kaya oil, apricot kernel oil, hydrogenated oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sugarcane wax, camellia oil, safflower oil, shea butter, Chinese ginger oil, cinnamon oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, rapeseed oil, germ oil, palm oil, palm kernel oil, castor oil, hydrogenated castor oil, sunflower oil, grape oil, jojoba oil, macadamia nut oil, beeswax, cottonseed oil, cotton wax, Japan wax, montan wax, coconut oil, hydrogenated coconut oil, peanut oil, lanolin, liquid lanolin, reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, and lanolin fatty acid isopropyl. Among the above-mentioned animal and vegetable oils and fats, or hydrogenated animal and vegetable oils and fats, more preferred specific examples from the viewpoint of the feel when applied to hair (ease of spreadability) and imparting softness to hair include camellia oil, rice bran oil, jojoba oil, shea butter, etc.

[0021] In addition to the above-listed ingredients, the composition may optionally contain moisturizers, surfactants, UV absorbers, sunscreens, fragrances, thickeners, preservatives, coloring agents such as extender pigments and coloring pigments, pH adjusters, etc., as well as whitening agents, antioxidants, anti-inflammatory agents, vitamins, hormones, enzymes, blood circulation promoters, amino acids, tanning agents, hair restoration agents (hair loss prevention agents, hair growth promoters, etc.), animal and plant extracts, anti-wrinkle agents, preservatives, hair softeners, hair moisturizers, makeup preparations, hair conditioners, skin conditioners, hair whitening agents, chelating agents, cell turnover promoters, coloring agents, skin softeners or moisturizers, deodorants or antiperspirants, etc. Ingredients normally used in topical preparations may also be appropriately contained within the range that does not impair the effects of the present invention.

[0022] Examples of surfactants include sodium lauroyl methyl alanine, sodium cocoyl methyl taurine, sodium lauroyl sarcosine, cocamidopropyl betaine, lauramidopropyl betaine, myristyl betaine, cocamide DEA, cocamide MEA, cocamide methyl MEA, TEA lauroyl methyl alanine, TEA cocoyl glutamate, sodium cocoyl glutamate, disodium cocoyl glutamate, sodium lauroyl aspartate, sodium dilauroyl glutamate lysine, Olefin (C14-16) Sodium Sulfonate, Hydroxyalkyl (C12-14) Hydroxyethyl Sarcosine, Lauramidopropyl Hydroxysultaine, Sodium Laureth-4 Carboxylate, PPG-2 Cocamide Cocoamphoacetate, Stearamidopropyl Dimethylamine, Distearyldimonium Chloride, Behentrimonium Chloride, Guar Hydroxypropyltrimonium Chloride, Polyquaternium-10, Polyquaternium-50.

[0023] The hair cosmetic composition of the present invention may contain other oily components. The other oily components may be, for example, hydrocarbons, oils and fats, waxes, hydrogenated oils, ester oils, fatty acids, higher alcohols, fluorinated oils, lanolin derivatives, etc., regardless of their origin (e.g., animal oil, vegetable oil, synthetic oil) and their properties (e.g., solid oil, semi-solid oil, liquid oil, volatile oil, etc.). Silicone oils may also be appropriately contained within a range that does not impair the effects of the present invention. Specific examples include hydrocarbons such as light liquid isoparaffin, liquid paraffin, squalane, petrolatum, polyisobutylene, and polybutene; oils and fats such as olive oil, castor oil, jojoba oil, mink oil, and macadamia nut oil; petroleum waxes such as paraffin wax and microcrystalline wax; mineral waxes such as ozokerite and ceresin; natural waxes such as carnauba wax and candelilla wax; esters such as cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, rosin acid pentaerythritol ester, neopentyl glycol dioctanoate, and cholesterol fatty acid esters; stearic acid, lauric acid, myristic acid, behenic acid, isostearyl alcohol, and the like. Fatty acids such as allylic acid, oleic acid, and 12-hydroxystearic acid; higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, and behenyl alcohol; silicones such as low-polymerization dimethylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclosiloxane, high-polymerization dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified polysiloxane, polyoxyalkylene-alkylmethylpolysiloxane-methylpolysiloxane copolymer, alkoxy-modified polysiloxane, and fluorine-modified polysiloxane; fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether; and lanolin derivatives such as lanolin, lanolin acetate, lanolin fatty acid isopropyl, and lanolin alcohol.

[0024] Examples of essential oils and extracts that are added for purposes such as hair protection and fragrance include bergamot fruit oil, marigold flower oil, lime oil, lemon peel oil, tea leaf water, bitter orange flower oil, bitter orange leaf / twig oil, marjoram flower oil, pelargonium graveolens oil, jojoba seed oil, argania spinosa kernel oil, broccoli seed oil, avocado oil, macadamia seed oil, olive fruit oil, olive leaf extract, white willow bark extract, Job's tears seed extract, and grape seed extract. Other examples of plant extracts among animal and plant extracts include tea extract, Rosa rugosa extract, Scutellaria root extract, Houttuynia cordata extract, Phellodendron bark extract, Melilot extract, Nettle leaf extract, Licorice extract, Peony extract, Soapwort extract, Luffa extract, Cinchona extract, Saxifraga extract, Sophora flavescens extract, Water hyacinth extract, Fennel extract, Primrose extract, Rose extract, Rehmannia root extract, Lemon extract, Lithospermum root extract, Aloe extract, Calamus root extract, Eucalyptus extract, Horsetail extract, Sage extract, Thyme extract, Seaweed extract, Cucumber extract, Clove extract, Raspberry extract, Melissa extract, Carrot extract, Horse chestnut extract, Peach extract, Peach leaf extract, Mulberry extract, Cornflower extract, Hamamelis extract, Licorice extract, Ginkgo extract, Ichigo extract, Swertia japonica extract, Capsicum tincture extract, Cantharis extract, etc. Furthermore, animal extracts include placenta extract, collagen, etc., which can be appropriately incorporated into the present invention.

[0025] Examples of amino acids and amino acid derivatives that may be added for hair repair purposes include glycine, alanine, valine, isoleucine, proline, acetylhydroxyproline, arginine, dihydroxypropylarginine HCl, aspartic acid, acetylglutamine, glutamic acid, PCA, PCA-Na, acetylglutamic acid, histidine, lysine HCl, phenylalanine, serine, threonine, citrulline, and cystine. In addition to the above ingredients, amino acids include amphoteric amino acids such as stearyl acetyl glutamate, capryloyl silk amino acids, capryloyl collagen amino acids, capryloyl keratin amino acids, capryloyl pea amino acids, cocodimonium hydroxypropyl silk amino acids, corn gluten amino acids, cysteine, glutamic acid, glycine, hair keratin amino acids, hair amino acids such as aspartic acid, threonine, serine, glutamic acid, proline, glycine, alanine, half-cystine, valine, methionine, isoleucine, leucine, tyrosine, phenylalanine, cysteic acid, lysine, histidine, arginine, cysteine, tryptophan, citrulline, lysine, silk amino acids, wheat amino acids, and mixtures thereof.

[0026] Other examples of active ingredients include, from the perspective of hair protection, keratin (wool), hydrolyzed keratin (wool), quaternium-33 (wool), hydrolyzed collagen, isostearoyl hydrolyzed collagen, AMPD isostearoyl hydrolyzed collagen, hydrolyzed silk, sodium lauroyl hydrolyzed silk, hydrolyzed eggshell membrane, hydrolyzed conchiolin protein, hydrolyzed vegetable protein, hydrolyzed rice protein, hydrolyzed soy protein, hydrolyzed hyaluronic acid, sodium hyaluronate, platinum, silver oxide, fullerene, hydroxyapatite, tocopherol, menthol, panthenol, ascorbyl glucoside, retinol palmitate, isomerized sugar, hydrolyzed hydrogenated starch, Swertia japonica extract, acetylcholine derivatives, cepharanthine, blood circulation promoters such as carpronium chloride, capsicum tincture, and cantharis extract. , topical irritants such as nonylic acid vanillamide, antiseborrheic agents such as pyridoxine or its derivatives, antibacterial agents such as benzalkonium chloride, isopropylmethylphenol, zinc pyrithione, photosensitizer No. 101, photosensitizer No. 102, orthopirox, and hinokitiol, metabolic activators such as photosensitizer No. 301, placenta extract, and biotin, vitamin B2, vitamin B12, vitamin A, C, D, E, or K, vitamin A palmitate, thiamine, vitamin B6, vitamin B6 derivatives such as vitamin B6 hydrochloride, vitamin B2, vitamin B12, nicotinic acid, and nicotinamide, vitamin B complexes such as pantothenic acid, pantothenyl ethyl ether, pyridoxine, inositol, and carnitine, panthenol, mixtures thereof, and vitamins such as pantothenic acid or its derivatives. Examples of antioxidants include thiotaurine, glutathione, catechin, albumin, ferritin, metallothionein, the above-mentioned L-ascorbic acid or its derivatives, and the like. Examples of the enzyme include trypsin, lysozyme chloride, chymotrypsin, chymotrypsin-like enzymes, trypsin, aspartic acid proteinase, semi-alkaline proteinase, serrapeptase, lipase, and hyaluronidase.

[0027] The pH adjuster may include, for example, potassium hydroxide, citric acid, sodium citrate, lactic acid, sodium lactate, and malic acid.

[0028] The salts may include, for example, sodium chloride, sodium bicarbonate, sodium metaphosphate, and seawater.

[0029] The alcohols preferably used in the present invention are not particularly limited, but include the following: The branched alcohols have 10 to 40 carbon atoms, and examples thereof include hexyldecanol, isostearyl alcohol, octyldodecanol, decyltetradecanol, dodecylhexadecanol, tetradecyloctadecanol, and hexadecyl eicosanol. Examples of dihydric alcohols include butylene glycol, pentylene glycol, propylene glycol, dipropylene glycol, hexylene glycol, octylene glycol, and polypropylene glycol having an average molecular weight of 200 to 2000.

[0030] In the present invention, from the viewpoints of skin irritation and emulsifying ability when used as an emulsion, the higher alcohol that can be used in combination is preferably one having 7 or more carbon atoms, more preferably one having 10 or more carbon atoms, and even more preferably one having 15 or more carbon atoms. Specific examples include lauryl alcohol, myristyl alcohol, stearyl alcohol, eicosanol, behenyl alcohol, oleyl alcohol, cetostearyl alcohol, cholesterol, phytosterol, POE cholesterol ether, monostearyl glycerin ether (batyl alcohol), monooleyl glyceryl ether (selachyl alcohol), cetanol, etc.

[0031] Examples of bacteriostatic agents and disinfectants that can be preferably used in combination with the above alcohols include phenoxyethanol, sodium benzoate, potassium sorbate, and methylparaben.

[0032] Examples of ultraviolet absorbers include benzophenone, bornelone, butyl perva, cinnamidopropyl trimethyl ammonium chloride, disodium distyrylbiphenyl disulfonate, perva, potassium methoxycinnamate, and mixtures thereof. Sunscreens include butyl methoxydibenzoylmethane, octyl methoxycinnamate, octocrylene, octyl salicylate, phenylbenzimidazole sulfonate, ethyl hydroxypropyl aminobenzoate, menthyl anthranilate, aminobenzoic acid, cinoxate, diethanolamine methoxycinnamate, glyceryl aminobenzoate, titanium dioxide, zinc dioxide, oxybenzone, padimate-O, red petrolatum, and mixtures thereof.

[0033] The thickener preferably used in the present invention is not particularly limited, but examples thereof include alginic acid, polyaspartic acid, deoxyribonucleic acid and its salts, guar gum, agar, gelatin, sodium polyacrylate, cellulose ester, calcium alginate, carboxyvinyl polymer, ethylene / acrylic acid copolymer, vinylpyrrolidone polymer, vinyl alcohol / vinylpyrrolidone copolymer, nitrogen-substituted acrylamide polymer, polyacrylamide, cationized guar gum, dimethylacrylammonium polymer, acrylic acid methacrylic acid acrylic copolymer, POE / POP copolymer, polyvinyl alcohol, pullulan, tamarind seed polysaccharide, xanthan gum, caramel, etc. Examples of natural or artificial thickeners include geenan, high methoxyl pectin, low methoxyl pectin, gum arabic, crystalline cellulose, arabinogalactan, karaya gum, tragacanth gum, albumin, casein, curdlan, gellan gum, dextrin fatty acid ester, cellulose, polyethyleneimine, highly polymerized polyethylene glycol, cationic silicone polymer, synthetic latex, silicon gelling agents such as alkyl dimethicone with 18 or more carbon atoms and silicone polyamide copolymer, glyceryl (behenate eicosadioate), polyglyceryl-10 (behenate eicosadioate), and (vinylcaprolactam / VP / dimethylaminoethyl methacrylate) copolymer.

[0034] In addition to the oily base and the above-mentioned components, the present invention may contain other components typically used in topical preparations, such as moisturizers, surfactants, UV absorbers, UV scattering agents, fragrances, thickeners, preservatives, extender pigments, coloring agents such as coloring pigments, pH adjusters, etc., as needed, within the scope that does not impair the effects of the present invention.

[0035] The present invention also relates to a method for producing an oily hair cosmetic or hair cosmetic product that provides excellent care for damaged hair and a pleasant feel when used. The method is not particularly limited and any known, conventional method can be used as appropriate, and includes a step of mixing a dimer acid derivative with one or more oils selected from the group consisting of volatile oils, ester oils, hydrocarbon oils, and animal and vegetable oils.

[0036] For example, a gel-type oily hair cosmetic can be produced by stirring the dimer acid derivative and oil of the present invention shown in Figure 1 together with alcohols, water-soluble polymers, etc. to uniformly disperse the mixture, followed by cooling to form a gel. Cream-type or emulsion-type oily hair cosmetic products can be produced by emulsifying the dimer acid derivative and oil of the present invention with alcohols, polyhydric alcohols, water-soluble polymers, and ingredients commonly used in cosmetics, such as emulsifiers and solubilizers, while heating, followed by cooling to form a cream or emulsion. Mousse-type or foam-type oily hair cosmetic products can be produced by dissolving and dispersing the dimer acid derivative and oil of the present invention with a surfactant and a thickener (water-soluble polymer), filling the resulting mixture into an aerosol can with liquefied petroleum gas (propellant), and spraying the mixture into a mousse or foam form at the time of use. [Effects of the Invention]

[0037] The hair improvement agent of the present invention can make hair feel manageable even with a relatively small amount added, and has a repair effect on the hair surface.Other expected effects include repairing hair damage, adding softness, allowing the formulation to be applied evenly, and adding shine and luster.

[0038] The hair improvement agents according to the present invention can be clear or opaque in the form of an emulsion. Even clear embodiments of the present invention are stable over time, and therefore clear hair improvement agents according to the present invention can be attractive to consumers.

[0039] The hair improvement agent of the present invention, whether in the form of a liquid, ointment, aerosol, or other formulation, or in the form of a powder, tablet, cream, or other form, has the advantageous effects of relieving dandruff and itching, suppressing dandruff and itching, replenishing and maintaining hair moisture and oil, preventing hair breakage, breakage, and split ends, styling and maintaining the hairstyle, and preventing static electricity in the hair, making it highly versatile.It is also excellent for hair and skin treatments for hair growth, hair removal, pilarization, and permanent waves.

[0040] The hair improvement agent of the present invention can be added to the group consisting of hair mists, hair oils, hair liquids, hair gels, hair sticks, hair oil balms, hair sprays, hair mousses, hair milks, hair treatments, hair conditioners, hair masks, and hair packs.

[0041] The hair improving agent of the present invention can be added to hair cosmetics such as hair restorers, hair growth agents, hair removers, hair dyes, permanent wave agents, shampoos, and rinses. [Brief explanation of the drawings]

[0042] [Figure 1] This is a photo of the actual product of (polyglyceryl-2 isostearate / dimer dilinoleate) copolymer. DETAILED DESCRIPTION OF THE INVENTION

[0043] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples and various modifications are possible within the scope of the technical concept of the present invention. Furthermore, unless otherwise specified, "%" in the following description means "% by mass."

[0044] <Silicone-free shampoo formula> Component name Content (mass%) 1 Water, Sodium Laureth Sulfate 40 2 Water, Cocamidopropyl Betaine 10 3 Cocamidomethyl MEA 3 4 Sodium chloride 0.7 5 Sodium citrate 0.5 6 Pentylene glycol 0.5 7 EDTA-2Na 0.2 8 Citric acid 0.1 9 (Polyglyceryl-2 Isostearate 0.05 / dimer dilinoleic acid) copolymer 10 Wed 44.95 By incorporating polyglyceryl-2 isostearate / dimer dilinoleate copolymer, the product reduces the rough feeling of hair when shampooing, making it easier to run your fingers through. It also leaves hair feeling smooth after washing and reduces hair damage by preventing tangles.

[0045] <Non-silicone treatment formula> [Oil phase] Component name Content (mass%) 1 Isoamyl laurate 3 2 Cetearyl Alcohol 2.6 3 Hydrogenated rapeseed oil alcohol 2.4 4 (Polyglyceryl-2 Isostearate 2 / dimer dilinoleic acid copolymer 5 N-oleylhydroxyhexanamide 2 6 Behenamidopropyl dimethylamine 2 [Aqueous phase] Component name Content (mass%) 7 Glycerin 5 8 Pentylene Glycol 3 9 BG 3 10 Lactic acid 0.7 11 BG, water, plum fruit extract 0.5 12 Hydroxyethylcellulose 0.3 13 Wednesday 74 The combination of Polyglyceryl-2 Isostearate / Dimer Dilinoleate Copolymer reduces friction between hair strands when rinsing, preventing tangles and leaving hair feeling moisturized. Furthermore, the inclusion of Polyglyceryl-2 Isostearate / Dimer Dilinoleate Copolymer has the effect of repairing damaged hair, reducing frizz and giving hair a more manageable feel.

[0046] <Non-silicone treatment formula> [Oil phase] Component name Content (mass%) 1 Hydrogenated rapeseed oil alcohol 3.9 2 Isoamyl laurate 2 3 Hydrogenated Castor Oil Dimer Dilinoleate 1 4 Myristyl alcohol 0.9 [Aqueous phase] Component name Content (mass%) 5 Glycerin 5 6 Pentylene Glycol 3 7 BG 2.5 8 Stearyltrimonium Chloride 2 9 Butylene Glycol, Water, Plum Fruit Extract 0.5g 10 Hydroxyethylcellulose 0.3 11 Wed 78.9 The inclusion of hydrogenated castor oil dimer dilinoleate, like dimethicone, creates an oily film on the hair surface, repairing damaged hair and providing a smooth, silky feel. It also has an anti-static effect, preventing hair from frizzing and allowing for manageable styling.

[0047] <Hair oil formula> Component name Content (mass%) 1 Isoamyl laurate 40 2 Squalane 20 3 Jojoba seed oil 20 4 Diisopropyl Dilinoleate 10 5 Isostearyl Isostearate 5 6 Ethylhexyl methoxycinnamate 5 The oil film coats the entire hair, reducing the roughness of the hair surface. By combining diisopropyl dilinoleate, a film-like oil, with light-feeling oils such as isoamyl laurate and vegetable oil jojoba seed oil, the product provides a light feel without any unpleasant stickiness.

[0048] <Hair oil balm formula> Component name Content (mass%) 1 Hexyldecyl Isostearate 35 2 Ethylhexyl Hydroxystearate 25 3 Hydrogenated Castor Oil Dimer Dilinoleate 15 4 Caprylic / Capric Triglyceride 15 5 Polyethylene 5 6 Ethylhexyl methoxycinnamate 5 When combined with hydrogenated castor oil dimer dilinoleate, it reduces the roughness of hair, leaving it feeling moisturized and smooth, and giving the hair a more manageable feel overall.

[0049] <Hair wax formula> [Oil phase] Component name Content (mass%) 1 (Diglycerin / Dilinoleic Acid / 5 Hydroxystearic acid copolymer 2. Hydrogenated Castor Oil Dimer Dilinoleate 5 3 Octyldodecyl myristate 3 4 Hydrogenated rapeseed oil alcohol 3 5 Candelilla wax 3 6 PEG-20 Stearate 2 7 Steares-11 1 8 Steareth-3 0.5 9 Methylparaben 0.2 [Aqueous phase] Component name Content (mass%) 10 BG 3 11 Wed 73.8 12 Water, Sodium hydroxide 0.5 The high viscosity and adhesion of diglycerin / dilinoleic acid / hydroxystearic acid copolymer allows for a reduction in the amount of wax used, and its high water-holding capacity allows for a high water content, giving hair a fresh feel.Furthermore, the inclusion of hydrogenated castor oil dimer dilinoleate gives hair a natural shine and styling effect.

[0050] Other hair care cosmetics that apply this invention are shown below. These formulations also have the same effects as those described above, that is, they do not use silicone but use biologically derived substances instead, while still achieving the same effects on hair as silicone (repairing hair damage, providing smoothness to the hair surface, making hair soft, firm and resilient, providing a uniform coating when applied, and visually aesthetic effects (gloss, shine, color reproducibility, and sustained hair dye effects)).

[0051] <Hair treatment ingredient example 1> Water, cetearyl alcohol, glycerin, 3-methyl-1,3-butanediol, triisostearin, triethylhexanoin, alanine, sugarcane extract, L-hydroxyproline, sodium dl-pyrrolidonecarboxylate solution, propanediol, keratin, hydrolyzed conchiolin protein, hydrolyzed collagen, hydrolyzed keratin (wool, feather), hydrolyzed hyaluronic acid, steardimonium hydroxypropyl hydrolyzed keratin, gamma-docosalactone, cetearamidoethyldiethonium hydrolyzed rice protein, isostearyl alcohol, jojoba seed oil, tri(caprylic / capric acid)glyceryl, dimer dilinoleyl dimer dilinoleate, Polyglyceryl-2 Isostearate / Dimer Dilinoleate Copolymer, Sclerocarya Birrea Seed Oil, Prunus Prunus Seed Extract, Isononyl Isononanoate, Isostearoyl Hydrolyzed Keratin, Phytosterols, Anemone Acetate (Adansonia Digitata) Seed Oil, HEC, Polysorbate 60, Steartrimonium Chloride, Quaternium-18, Behentrimonium Chloride, Citric Acid, Sodium Citrate, Phenoxyethanol, Sodium Benzoate, Fragrance, Purple 401, Red 504, 4-Hydroxypropylamino-3-Nitrophenol, HC Yellow 2, HC Blue 2, HC Red 3, HC Blue 15, Basic Brown 16, Basic Brown 17, Basic Yellow 57, Basic Red 76, Basic Blue 99

[0052] <Hair treatment ingredient example 2> Water, glycerin, triethylhexanoin, cetyl alcohol, stearamidopropyl dimethylamine, cetearyl alcohol, polyglyceryl-2 isostearate / dimer dilinoleate copolymer, hydrogenated castor oil isostearate, stearyl alcohol, glyceryl stearate (SE), isodecyl neopentanoate, citric acid, sorbitol, orange oil, phenoxyethanol, cetearamidoethyldiethonium succinoyl hydrolyzed pea protein, polyquaternium-47, behentrimonium chloride, alcohol, cationized guar gum-2, Diglycerin, Trimethylglycine, Rosemary Leaf Oil, Sodium Citrate, English Lavender Oil, Butylene Glycol, Squalane, Sunflower Seed Oil, Ferulic Acid, Camellia Oil, Jasmine Flower Extract, Hydrolyzed Viola Trifoliata Extract, Calendula Officinalis Extract, Leuconostoc / Radish Root Ferment Filtrate (Filtrated and Fermented), Chamomile Flower Extract, Polyglyceryl-10 Oleate, Sage Leaf Extract, Rosemary Leaf Extract, Rice Bran Extract, Lemongrass Leaf / Stem Extract, Gynostemma Pentaphyllum Extract, Rice Bran Oil, Glucocerebroside, Fumaric Acid, Sodium Benzoate, Sodium Hydroxide

[0053] <Hair treatment ingredient example 3> Water, tea leaf water, ethylhexyl palmitate, behenyl alcohol, glycerin, stearoxypropyltrimonium chloride, polyglyceryl-2 isostearate / dimer dilinoleate copolymer, stearyl alcohol, cetyl alcohol, mandarin orange peel oil, pelargonium graveolens oil, orange oil, lemon peel oil, palmarosa oil, chamomile flower oil, hydrolyzed soy protein, hydrolyzed rice protein, theobroma grandiflorum seed butter, sodium dilauramidoglutamide lysine, avocado oil, macadamia nut fatty acid ethyl ester, opuntia ficus-indica stem extract, caesalpinia spinosa gum, Watermelon Seed Oil, Diisostearyl / Phytosteryl Dimer Dilinoleate, Hibiscus sabdariffa Extract, Butylene Glycol, Butyrospermum Parkii (Shea) Butter Extract, Glyceryl Stearate, Euterpe Oleracea Fruit Extract, Sodium Benzoate, Vanilla Planifolia (Vanilla Flour) Fruit Extract, Citric Acid, Adansonia Digitata Fruit Extract, HEC, Cymbopogon Root Oil, Lavandula Hybrida (Lavandula) Flower Oil, Phytic Acid, Grapefruit Peel Oil, Stearamidopropyl Dimethylamine, Limbopogon Cubeba Fruit Oil, Potassium Sorbate, Bendera Officinalis (Willow) Flower Oil, Melissa Officinalis (Melissa) Leaf Oil, Silver Oxide, Thymus Vulgaris (Thymus Vulgaris) Flower / Leaf Oil, Tea Tree Oil, Tocopherol, Eucalyptus Oil, Cucumber (Cucumber) Fruit Extract, Malic Acid, Coriander (Coriander) Fruit Oil, Arginine, Peppermint Oil

[0054] <Hair treatment ingredient example 4> Water, ethylhexyl palmitate, cetearyl alcohol, cetyl alcohol, polyglyceryl-2 isostearate / dimer dilinoleate copolymer, steartrimonium chloride, cocoa butter, quinoa seed oil, sweet almond oil, kale leaf extract, oatmeal extract, hydrolyzed pea protein, menthol, butylene glycol, glyceryl stearate, dicocodimonium chloride, cetrimonium chloride, isopropyl alcohol, lactic acid, sodium gluconate, phenoxyethanol, fragrance

[0055] <Hair treatment ingredient example 5> Water, tea leaf water, ethylhexyl palmitate, behenyl alcohol, glycerin, stearoxypropyltrimonium chloride, polyglyceryl-2 isostearate / dimer dilinoleate copolymer, stearyl alcohol, cetyl alcohol, diisostearyl / phytosteryl dimer dilinoleate, butylene glycol, palmarosa oil, mandarin orange peel oil, glyceryl stearate, lavandula hybrida oil, sodium benzoate, HEC, pelargonium graveolens oil, coriander fruit oil, orange oil, lemongrass oil, lemon peel oil, peppermint oil, citric acid, eucalyptus oil, lily of the valley fruit oil, tea tree oil, arginine Bendera officinalis flower oil, Thymus vulgaris flower / leaf oil, Grapefruit peel oil, Chamomile flower oil, Shea butter, Watermelon seed oil, Theobroma grandiflorum seed butter, Avocado oil, Macadamia nut fatty acid ethyl ester, Melissa officinalis leaf oil, Tocopherol, Sodium dilauramidoglutamide lysine, Hydrolyzed rice protein, Phytic acid, Stearamidopropyl dimethylamine, Hydrolyzed soy protein, Silver oxide, Opuntia ficus-indica stem extract, Euterpe oleracea fruit extract, Vanilla planifolia fruit extract, Hibiscus sabdariffa extract, Adansonia baobab fruit extract, Caesalpinia spinosa gum, Potassium sorbate, Cucumis sativus (cucumber) fruit extract, Malic acid, Benzyl alcohol, Dehydroacetic acid, Glyoxal This hair treatment penetrates dry, stressed hair, moisturizing it and locking in moisture, transforming it into smooth, manageable hair.

[0056] <Hair treatment ingredient example 6> Water, Ethylhexyl Palmitate, Cetearyl Alcohol, Cetyl Alcohol, Polyglyceryl-2 Isostearate / Dimer Dilinoleate Copolymer, Isoamyl Laurate, Hydroxypropyl Guar Hydroxypropyltrimonium Chloride, Hydrolyzed Pea Protein, Zein, Xylityl Glucoside, Anhydrous Xylitol, Maltitol, Xylitol, Velvetia Canaliculata Extract, Sclerocarya Birrea Seed Oil, Opuntia Ficus-Indica Seed Oil, Shea Butter, Jojoba Seed Oil, Argania Spinosa Kernel Oil, Steartrimonium Chloride, Cocoa Butter, Glyceryl Stearate, Dicocodimonium Chloride, Cetrimonium Chloride, Isopropyl Alcohol, Lactic Acid, DPG, Sodium Gluconate, Phenoxyethanol, Fragrance

[0057] <Hair treatment ingredient example 7 Water, Aloe Vera Juice, Stearamidopropyl Dimethylamine, Ethylhexyl Palmitate, Sunflower Seed Oil, Behenyl Alcohol, Hydrogenated Rapeseed Oil Alcohol, Aloe Vera Leaf Juice, Butylene Glycol, Tremella Fuciformis Polysaccharide, Sodium Dilauramidoglutamide Lysine, Hydrolyzed Sesame Protein PG Propylmethylsilanediol, Pomegranate Extract, Argania Spinosa Kernel Oil, Baobab Seed Oil, Prunus Prunus Seed Extract, Jojoba Seed Oil, Meadowfoam Oil, Rosa Canina Fruit Extract, Chamomile Flower Extract, Sage Leaf Extract, Thymus Vulgaris Flower / Leaf Extract, Lavender Flower Extract, Lemongrass Leaf / Stem Extract, Rosemary Leaf extract, Guar Hydroxypropyltrimonium Chloride, Isopropyl Myristate, Caprylic / Capric Triglyceride, Dimer Dilinoleyl Dimer Dilinoleate, Phytosteryl / Isostearyl / Cetyl / Stearyl / Behenyl Dimer Dilinoleate, Polyglyceryl-2 Isostearate / Dimer Dilinoleate Copolymer, Hydrogenated Castor Oil Isostearate, Carnauba Wax, Sodium Cocoamphoacetate, Steartrimonium Chloride, Glycerin, Lactic Acid, Citric Acid, Diethylhexyl Syringylidene Malonate, Etidronic Acid, Phenoxyethanol, Fragrance This hair treatment not only repairs hair but also leaves it feeling "smooth and silky after coming home from the salon." It also contains a rich blend of moisturizing ingredients, providing thorough care for damaged scalp and hair ends. Even after blow-drying, hair feels smooth and shiny thanks to its moisture, transforming it into hair that's easy to style.

[0058] <Hair treatment ingredient example 8> Water, Cetyl alcohol, Stearyl alcohol, Butylene Glycol, Stearamidopropyl dimethylamine, 1,2-Hexanediol, Hydrogenated Castor Oil Dimer Dilinoleate, Glycerin, Silk Powder, Pearl Extract, Olive Oil, Panthenol, Glyceryl Stearate, Propanediol, Yellow Earth, Rice Bran Extract, Shea Butter, Illicium Verum Fruit Extract, Propylene Glycol, Hamamelis Virginiana (Witch Hazel) Bark / Leaf / Twig Extract, Avocado Oil, Hydroxypropyltrimonium Hydrolyzed Silk, Calendula Officinalis Extract, Lychee Chestnut Fruit Extract, Glycerin Ingredients: DL-Serine, Glutamic Acid, BHT, Argania Spinosa Kernel Oil, L-Aspartic Acid, Leucine, Alanine, Lysine, Arginine, L-Tyrosine, Phenylalanine, L-Proline, Threonine, Valine, Isoleucine, L-Histidine, L-Cysteine, Methionine, Milk Protein Extract, Citric Acid, Polysorbate 60, Chlorphenesin, Caprylyl Glycol, Alcohol, Polyquaternium-7, PEG-14M, Quaternium-18, Ethylhexylglycerin, Silica, Phenoxyethanol, Fragrance

[0059] <Example of hair treatment ingredients 9> Water, Cetyl Alcohol, Cetearyl Alcohol, Dimethicone, PPG-3 Caprylyl Ether, Aminopropyl Dimethicone, Ethylhexyl Palmitate, Steartrimonium Chloride, Honey, Royal Jelly, Sodium PCA, Arginine, Aspartic Acid, PCA, Hydrolyzed Conchiolin Protein, Hydrolyzed Royal Jelly Protein, Glycine, Alanine, Serine, Valine, Inula Crismoides Flower / Leaf Extract, Isoleucine, Threonine, Proline, Histidine, Phenylalanine, Hydrolyzed Collagen, Hydrolyzed Soy Protein, Polyquaternium-50, Hydrolyzed Keratin (Wool), Hydrolyzed Silk, γ-Docosalactone, Quaternium-50 Ingredients: Um-33, Polyglyceryl-2 Isostearate / Dimer Dilinoleate Copolymer, Caprylic / Capric Triglyceride, Argania Spinosa Kernel Oil, Salvia Hispanica Seed Oil, Jojoba Seed Oil, Macadamia Integrifolia Seed Oil, Phytosteryl / Octyldodecyl Lauroyl Glutamate, Glycine Soja (Soybean) Sterols, Ceramide NG, Ceramide AP, Ceramide AG, Ceramide NP, Ceramide EOP, Helianthus Annuus (Sunflower) Seed Oil, Quinoa Seed Oil, Adansonia Digitata (Baobab) Seed Oil, Sodium Lactate, PEG-90M, Hydrogenated Lecithin, Isopropanol, Butylene Glycol, Sodium Citrate, Citric Acid, Tocopherol, Disodium EDTA, Phenoxyethanol, Sodium Benzoate, Fragrance

[0060] <Example 10 of hair treatment ingredients> Water, Cetearyl Alcohol, Dimethicone, γ-Docosalactone, Quaternium-18, Quaternium-33, Cholesterol, Ceramide EOP, Ceramide NG, Ceramide NP, Ceramide AG, Ceramide AP, PG, Hydrolyzed Keratin (Wool & Feathers), Argania Spinosa Kernel Oil, Mangifera Indica (Mango) Seed Oil, Theobroma Grandiflorum (Wool) Seed Butter, Prunus Prunus (Prunus Amygdalus Dulcis (Sweet Almond) Seed Oil, Sclerocarya Birrea (Sweet Almond) Seed Oil, Adansonia Digitata (Baobab) Seed Oil, Coconut Oil, Pouteria Sapota (Wool) Seed Oil, Keratin (Wool & Feathers), ), Platinum, Hydrolyzed Collagen, Sodium Hyaluronate, Collagen, Hydrolyzed Conchiolin Protein, Cetearamidoethyldiethonium Hydrolyzed Rice Protein, Pitaya Fruit Extract, Terminalia Ferdinandiana Fruit Extract, Microcitrus Australasica Fruit Extract, Hydrolyzed C12-13 Alkyl Glyceryl Hyaluronate, Hydrolyzed Hyaluronic Acid, Argania Spinosa Blast Extract, Apple Fruit Cell Culture Extract, Prunus Armeniaca Kernel Oil, Hydrogenated Prunus Armeniaca Kernel Oil, Hydrogenated Argania Spinosa Kernel Oil, Hyaluronic Acid Hydroxypropyltrimonium Chloride, Locust Bean Hydroxypropyltrimonium Chloride, Hydroxypropyltrimonium Starch Chloride, Fenugreek Hydroxypropyltrimonium Chloride, Castor Oil, Ethylhexyl Palmitate, Soybean Sterols, Propanediol, Bis(Behenyl / Isostearyl / Phytosteryl) Dimer Dilinoleyl Dimer Dilinoleate, Dipentaerythrityl Hexa(hydroxystearate / hexastearate / hexastearate / rosinate), Isostearic Acid Hydrogenated Castor Oil, Glucose, Butylene Glycol, Dimethiconol, Lactic Acid, Sodium Chloride, Sodium Bicarbonate, Cymen-5-ol, Hydroxyethylcellulose, Urea, Xanthan Gum, Cellulose Gum, Glyceryl Trihydrogenate Rosinate, Lecithin, Isomalt, Steartrimonium Chloride, Cetrimonium Chloride, Dicocodimonium Chloride, Behentrimonium Chloride, Isopropanol, Glycerin, Alcohol Denat., Lactic Acid, Tocopherol, Phenoxyethanol, Sodium Benzoate, Fragrance, Caramel

[0061] <Hair treatment ingredient example 11> Water, behenyl alcohol, behenamidopropyl dimethylamine, glyceryl stearate, methylheptyl laurate, diethylhexyl sebacate, glycerin, soy milk fermented liquid, gamma-docosalactone, Swertia japonica extract, Laminaria japonica extract, Tremella fuciformis polysaccharide, C13-15 alkane, capryloyl glycerin / sebacic acid copolymer, diheptyl succinate, glyceryl glucoside, polyquaternium-10, dimer dilinoleyl dimer dilinoleate, caprylic / capric triglyceride, butylene glycol, citric acid, fragrance, pentylene glycol, phenoxyethanol

[0062] <Hair treatment ingredient example 12> Water, tea leaf water, behenyl alcohol, triethylhexanoin, stearoxypropyltrimonium chloride, glycerin, stearyl alcohol, cetyl alcohol, boswellia fruit oil, lemongrass oil, bergamot fruit oil, pelargonium graveolens oil, bitter orange flower oil, lemon peel oil, orange oil, lavender oil, dandelion seed oil, honey, polyquaternium-7, cetearamidoethyldiethonium succinoyl hydrolyzed pea protein, inula Lithumoides Flower / Leaf Extract, Citric Acid, Lithocarpus Cubeba Fruit Oil, Glyceryl Stearate, Astrocaryum Murumuru Seed Butter, Phytosteryl / Isostearyl / Cetyl / Stearyl / Behenyl Dimer Dilinoleate, Rosemary Leaf Oil, Butylene Glycol, Thymus Vulgaris Flower / Leaf Oil, Sodium Benzoate, Mentha Piperita Oil, Caprylic / Capric Triglyceride, Coptis Rhizome Root Extract, Hydroxyethylcellulose, Aloe Barbadensis Leaf Extract, Kale Leaf Extract, Caramel

[0063] <Hair treatment ingredient example 13> Water, Glycerin, Cetearyl Alcohol, Behentrimonium Chloride, Petrolatum, Avocado Oil, Stearoxypropyltrimonium Chloride, Isostearyl Isostearate, Betula Platycodon (White Birch) Sap, Hydrolyzed Vegetable Protein, Chili Atmentosa Bud Extract, Isomerized Saccharide, Grape Seed Extract, Terminalia Ferdinandiana Fruit Extract, Madonna Lily Root Extract, Bougainvillea Leaf Extract, Glycosyl Trehalose, Hydrogenated Starch Hydrolysates, Sorbitol, Trehalose, Lactobacillus / Bean Fermented milk filtrate, yuzu fruit extract, sodium dilauramidoglutamide lysine, glutamic acid, swertia japonica extract, rosemary leaf water, black currant fruit extract, chamomile flower extract, tremella fuciformis polysaccharide, malic acid, lactic acid, betaine, BG, phytosteryl / isostearyl / cetyl / stearyl / behenyl dimer dilinoleate, stearyl alcohol, cetanol, PEG-40 hydrogenated castor oil, isopropanol, EDTA-2Na, ethanol, tocopherol, sodium benzoate, fragrance

[0064] <Hair treatment ingredient example 14> Water, tea leaf water, ethylhexyl palmitate, cetyl alcohol, glycerin, behentrimonium chloride, stearyl alcohol, sodium dilauramidoglutamide lysine, cetearamidoethyldiethonium hydrolyzed rice protein, theobroma cacao (cocoa) seed butter, coconut oil, almond oil, pelargonium graveolens oil, jasmine oil, mandarin orange (citrus fruit) flower extract, hinoki cypress (Chamaecyparis obtusa) oil, kabosu (kabosu) peel oil, sudachi (citrus sudachi) peel oil, yuzu (citrus junos) peel oil, iyokan (citrus iyo) peel oil, hinoki cypress (cypress) wood oil, camphor tree (camphor) bark oil, lemon (citrus lemon) peel oil, pelargonium graveolens flower / leaf / stem extract, BG, thyme (thyme) flower / leaf extract, distearyldimonium chloride, European Elderflower Extract, Limonene, Glyceryl Stearate, Lavandula Hybrida Oil, Polyglyceryl-2 Isostearate / Dimer Dilinoleate Copolymer, Orange Oil, Hydroxyethylcellulose, Litsea Cubeba Fruit Oil, Isopropanol, Citric Acid, Fennel (Fennel) Fruit Oil, Arginine, Diisostearyl / Phytosteryl Dimer Dilinoleate, Cananga Odorata Flower Oil, Linalool, Behenyl Alcohol, Rosemary (Rosemary) Leaf Oil, Sodium Benzoate, Alcohol, Boswellia Officinalis (Boswellia) Oil, Phenoxyethanol, Geraniol, Rosa Centifolia Flower Oil, Fragrance, Rosa Damascena Flower Oil

[0065] <Examples of ingredients in non-silicone conditioners> Water, hydrogenated rapeseed oil alcohol, hydrogenated castor oil dimer dilinoleate, dimethylstearamine, octyldodecanol, behenyl alcohol, isoamyl laurate, sodium dilauramidoglutamide lysine, lavender oil, orange peel oil, jasmine oil, caramel, betaine, taurine, lysine HCl, glutamic acid, glycine, leucine, histidine HCl, serine, valine, sodium aspartate, threonine, alanine, isoleucine, allantoin, phenylalanine, arginine, proline, tyrosine, disodium inosinate, disodium guanylate, ethylhexylglycerin, butylene glycol, lactic acid, sodium benzoate

[0066] <Examples of silicone-free shampoo ingredients> Water, Disodium Laureth Sulfosuccinate, Cocamidopropyl Betaine, Cocamide MEA, Lauryl Glucoside, Hydrogenated Castor Oil Dimer Dilinoleate, Polyquaternium-10, Menthol, Salicylic Acid, PEG-40 Hydrogenated Castor Oil, PEG / PPG-120 / 10 Trimethylolpropane Trioleate, Laureth-2, Panthenol, Trimethylglycine, Sodium Disodium Edetate, Aster Extract, Polygonum Multiflorum Root Extract, Oriental Linalool Leaf Extract, Houttuynia Cordata Extract, Morus Alba Bark Extract, Betula Platycodon Sap, Butylene Glycol, Calamus Root Extract, Rehmannia Root Extract, Artemisia Princeps Extract, Panax Ginseng Root Extract, Hydrolyzed Silk, Chamomile Flower / Leaf Extract, Rosemary Extract, Bambusa Vulgaris Juice Extract, English Lavender Extract, Phenoxyethanol, Sodium Benzoate, Fragrance

[0067] <Examples of hair cleansing ingredients> Water, hydrogenated rapeseed oil alcohol, behenyl alcohol, 1,2-pentanediol, hydrogenated castor oil dimer dilinoleate, dimethylstearamine, octyldodecanol, isoamyl laurate, olive oil, burdock extract, parsley extract, cucumber fruit extract, ethylhexylglycerin, BG, sodium dilauramidoglutamide lysine, cetyl palmitate, lactic acid, menthol, fragrance, phenoxyethanol

[0068] <Examples of ingredients in non-silicone treatment> Water, Aloe Barbadensis Leaf Juice, Behenyl Alcohol, Behenyl PG-Trimonium Chloride, Orange Oil, Eucalyptus Oil, Lavandula Hybrida Oil, Tea Tree Oil, Cedar (Atlas Cedar) Bark Oil, Citrus Lemon Peel Oil, Spearmint Oil, Pelargonium Graveolens Oil, Glycerin, Jojoba Seed Oil, Propanediol, Shea Butter, Hydrogenated Castor Oil Isostearate, Olive Fruit Oil, Hydroxyethylcellulose, Theobroma Cacao (Cocoa) Seed Butter, Glyceryl Stearate, Caprylic / Capric Triglyceride, Argania Spinosa Kernel Oil, Dimer Dilinoleyl Dimer Dilinoleate, Polyquaternium-10, Prunus Prunus (Mexico) Seed Oil, Potassium Hydroxide, Polyquaternium-7, Rice Bran Extract, Methylheptyl Laurate, Lavender Water, Benzyl Alcohol, Sodium Dehydroacetate, Cucumis Sativus (Cucumber) Fruit Extract, Alcohol, Hippophae Rhamnoides Fruit Oil

[0069] <Examples of hair oil ingredients> Sunflower Seed Oil, Squalane, Dodecane, Hexadecane, Ethyl Isostearate, Jojoba Seed Oil, Apricot Kernel Oil, Caprylic / Capric Triglyceride, Argania Spinosa Kernel Oil, Camellia Seed Oil, Olive Fruit Oil, Avocado Oil, Coconut Oil, Castor Oil, Almond Oil, Shea Butter, Camellia Sinensis Seed Oil, Kukui Nut Oil, Macadamia Integrifolia Seed Oil, Gardenia Taitensis Flower Extract, Gamma-Docosalactone, Ascorbyl Dipalmitate, Ascorbyl Palmitate, Ascorbic Acid, Tocopherol, Diisostearyl / Phytosteryl Dimer Dilinoleate, Glyceryl Diisostearate / Hydrogenated Rosinate, Phytosteryl / Isostearyl / Cetyl / Stearyl / Behenyl Dimer Dilinoleate, Lecithin BHT, Fragrance

[0070] <Examples of hair mask ingredients> Water, Tea Leaf Water, Stearyl Alcohol, Cetyl Alcohol, Ethylhexyl Palmitate, Stearoxypropyltrimonium Chloride, Glycerin, Hydrogenated Castor Oil Isostearate, Boswellia Fruit Oil, Lemongrass Oil, Bergamot Fruit Oil, Pelargonium Graveolens Oil, Bitter Orange Flower Oil, Citrus Limon (Lemon) Peel Oil, Hydrolyzed Soybean Protein, Crambe Abyssinica Seed Oil, Astrocaryum Murumuru Seed Butter, Sodium Dilauramidoglutamide Lysine, Theobroma Cacao (Cocoa) Butter, Mangifera Indica (Mango) Seed Butter, Jojoba Butter, African Mango Kernel Butter, Plukenetia Volubilis Seed Oil, Macadamia Ternifolia (Macadamia) Seed Ethyl Fatty Acid, Calophyllum Indicum (Caesarberry) Seed Oil, Caesalpini Aspinosa Gum, Prunus Amygdalus Dulcis (Sweet Almond) Oil, Diisostearyl / Phytosteryl Dimer Dilinoleate, Meadowfoam Oil, Glyceryl Stearate, Apple (Apple) Fruit Extract, Butylene Glycol, Rosa Canina Fruit Extract, Sodium Benzoate, Helianthus Annuus (Sunflower) Seed Oil, Citric Acid, Coptis Rhizome Root Extract, Hydroxyethylcellulose, Orange (Orange) Oil, PPG-3 Caprylyl Ether, Lavender Oil, Potassium Sorbate, Dimer Dilinoleyl Dimer Dilinoleate, Litsea Cubeba Fruit Oil, Tocopherol, Octyldodecanol, Rosemary Leaf Oil, Hydrogenated Cocoglycerides, Thymus Vulgaris (Thymus Vulgare) Flower / Leaf Oil, Arginine, Malic Acid, Mentha Piperita (Peppermint) Oil, Caramel This hair mask thoroughly repairs damaged hair, leaving it smooth and silky. It can also repair hair damaged by perms and coloring. By tightly sealing damaged hair, repair ingredients can be continuously delivered deep into the hair. By blending into damaged hair and adhering to it, it can transform hair into a silky, smooth hair that you can run your fingers through.

[0071] <Examples of ingredients in hair styling products> Water, glycerin, BG, cetanol, jojoba seed oil, betaine, cetearyl alcohol, glyceryl stearate, (sodium acrylate / sodium acryloyldimethyl taurate) copolymer, fullerene, hematin, sodium hyaluronate, sodium dilauramidoglutamide lysine, hydrolyzed collagen, hydrolyzed silk, hydrolyzed keratin, squalane, argania spinosa kernel oil, meadowfoam oil, macadamia nut oil, phytosteryl macadamiate, a Strocarium Murumuru Butter, Coco-Caprylate / Caprate, Zein, PPG-3 Caprylyl Ether, Diisostearyl / Phytosteryl Dimer Dilinoleate, Cetyl Palmitate, Isohexadecane, Xanthan Gum, Sorbitan Oleate, Polysorbate 60, Polysorbate 80, Citric Acid, Ethylhexylglycerin, Behenyl Alcohol, Pentylene Glycol, Phenoxyethanol, Ethanol, Tocopherol, DGP This hair styling product is an out-of-bath treatment that addresses complex hair concerns and restores balance. It moisturizes hair, reducing dryness, frizz, and volume, while adding volume and volume. It improves split ends and breakage, leaving hair shiny, bouncy, and resilient. It also repairs damage caused by color and perms, and prevents color fading. It also provides hair care benefits by protecting against heat from hair dryers and repairing and protecting against UV damage.

[0072] <Examples of ingredients in hair styling products> Water, Dimer Dilinoleyl Dimer Dilinoleate, Glyceryl Hydroxystearate, Ethyl Isostearate, Polyglyceryl-10 Stearate, Propanediol Diisostearate, Sodium Stearoyl Glutamate, Cetearyl Alcohol, Tribehenin, Polyglyceryl-2 Isostearate / Dimer Dilinoleate Copolymer, Polyglyceryl-10 Distearate, Diheptyl Succinate, Argania Spinosa Kernel Oil, Argania Spinosa Kernel Oil, Nia spinosa callus culture extract, hydrolyzed hyaluronic acid, palmarosa oil, rosemary leaf oil, canina rose fruit extract, chamomile flower extract, calendula officinalis flower extract, thyme extract, burdock root extract, peppermint extract, althea root extract, sea silt extract, isomalt, lecithin, capryloyl glycerin / sebacic acid copolymer, tocopherol, BG, benzyl alcohol, benzoic acid, sorbic acid, sodium benzoate, potassium sorbate This hair styling agent allows you to style your hair while preventing it from drying out, and can be used on a variety of hair types.

[0073] <Examples of silicone-free cream ingredients> Water, Butylene Glycol, Glycerin, Cetyl Alcohol, Jojoba Seed Oil, Macadamia Ternifolia Seed Oil, Betaine, Phytosteryl Macadamiate, Lavender Oil, Melia Azadirachta Leaf Extract, Hydrolyzed Eggshell Membrane, Meadowfoam-δ-Lactone, Shea Butter, Phytosteryl / Isostearyl / Cetyl / Stearyl / Behenyl Dimer Dilinoleate, Isohexadecane, Polysorbate 80, Polysorbate 60, Sodium Acrylate / Sodium Acryloyldimethyl Taurate Copolymer, Tocopherol, Ethylhexylglycerin, Phenoxyethanol, Fragrance, Caramel

Claims

1. A combination and / or structure of a hair improvement agent comprising one or more substances selected from dimer acid derivatives and mixtures thereof, and one or more oily agents, and further comprising no silicone derivatives or a silicone derivative content of 0 or 10% by mass or less.

2. The combination and / or structure of the hair improvement agent according to claim 1, wherein the dimer acid derivative is selected from one or more of (polyglyceryl-2 isostearate / dimer dilinoleate) copolymer, hydrogenated castor oil isostearate, (diglycerin / dilinoleic acid / hydroxystearic acid) copolymer, dipentaerythrityl hexa(hydroxystearate / stearic acid / rosin acid), and hydrogenated castor oil dimer dilinoleate.

Images