Multilayer cosmetic

Abstract

To provide a multilayer cosmetic that, even during use at low temperatures, achieves superior layer separability upon standing after shaking and maintains high transparency under low-temperature conditions.SOLUTION: A multilayer cosmetic contains the following components (A) to (D): (A) a lipophilic resin, (B) a volatile oil agent, (C) a polar oil that is liquid at 25°C and has a molecular weight of 370 or less, and (D) water.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a multi-layered cosmetic composition. [Background technology]

[0002] There are consumer needs to prevent makeup from coming off due to sweat or rubbing against clothes after makeup application.

[0003] For example, Patent Document 1 discloses a skin cosmetic that is particularly in the form of a lotion or cream and is used over a foundation with makeup to moisturize the skin, and that has excellent long-term stability, does not cause the foundation to smudge even when applied over a face with makeup, and provides an excellent feeling of moisture over time.

[0004] Furthermore, Patent Document 2 proposes a water-based or oil-in-water mist cosmetic that contains a specific water-soluble thickener and is filled in a pump-type spray container with a diameter of 0.25 to 0.55 mm.

[0005] For example, Patent Document 3 proposes, as claim 1, a multi-layered makeup protection cosmetic composition that contains an oil-soluble film-forming agent, 40 to 95% by mass of water, and a volatile oil, and that is to be sprayed onto makeup. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] Japanese Patent Application Laid-Open No. 2002-138030 [Patent Document 2] Japanese Patent Application Laid-Open No. 2014-237615 [Patent Document 3] WO2020 / 175398 Brochure Summary of the Invention [Problem to be solved by the invention]

[0007] A primary object of the present invention is to provide a multi-layered cosmetic that exhibits excellent layer separation when left to stand after shaking, particularly when used at low temperatures, and that has high transparency even at low temperatures. [Means for solving the problem]

[0008] As a result of extensive research, the present inventors have discovered that, although it is common practice to use a non-polar oil in the oil layer to reduce compatibility with the water layer in order to accelerate layer separation between the oil and water layers, by combining a specific polar oil with a lipophilic resin, a volatile oil, and water, it is surprisingly possible to provide a multi-layered cosmetic that exhibits excellent layer separation properties and transparency at low temperatures, as well as an excellent film-forming rate when used, and have thus completed the present invention, which can solve the above-mentioned problems.

[0009] That is, the present invention is as described below. [1] The following components (A) to (D); (A) Lipophilic resin (B) Volatile oil (C) A polar oil that is liquid at 25°C and has a molecular weight of 370 or less (D)Water The present invention provides a multi-layered cosmetic composition containing the above. [2] The multi-layered cosmetic composition according to [1], wherein the component (C) is one or more selected from fatty acids and higher alcohols. [3] The multi-layered cosmetic composition according to [1] or [2], wherein the component (C) has a branched structure. [4] The multi-layered cosmetic according to [1] or [2], wherein the component (A) is a silicone resin. [5] The multi-layered cosmetic composition according to [1] or [2], wherein the mass ratio (C) / (A) of the component (C) to the component (A) is 0.01 to 10. [6] The multi-layered cosmetic composition according to [1] or [2] is used by spraying. [7] The multi-layered cosmetic composition according to [1] or [2] is used for makeup protection. [8] The following components (A), (B) and (D) (A) Lipophilic resin (B) Volatile oil (D)Water A multi-layered cosmetic composition comprising: Furthermore, the present invention provides a multi-layered cosmetic containing a component that makes the oil layer transmittance 50% or more when the multi-layered cosmetic is left to stand after shaking. [Effects of the Invention]

[0010] According to the present invention, it is possible to provide a multi-layered cosmetic that is excellent in layer separation at low temperatures, transparency at low temperatures, and film formation speed. DETAILED DESCRIPTION OF THE INVENTION

[0011] Preferred embodiments of the present invention will be described in detail. However, the present invention is not limited to the following preferred embodiments and can be freely modified within the scope of the present invention. In this specification, "%" represents mass % unless otherwise specified. In addition, in this specification, when a numerical range is expressed using "to", the range includes both ends of the numerical range.

[0012] <Component (A) Lipophilic resin> The lipophilic resin used in the present invention (hereinafter also referred to as "component (A) lipophilic resin" or "component (A)") is a resin that is soluble in an oily agent or that swells and disperses uniformly in an oily agent, and is not particularly limited as long as it is one that can be commonly used in cosmetics or topical skin preparations, regardless of its origin, such as a natural resin, semi-synthetic resin, or synthetic resin.

[0013] The component (A) lipophilic resin is not particularly limited, and examples thereof include silicone-based resins such as polymethylsilsesquioxane, polypropylsilsesquioxane, trimethylsiloxysilicate, trifluoroalkyldimethyltrimethylsiloxysilicate, (trimethylsiloxysilicate / dimethiconol) crosspolymer, (dimethicone / vinyltrimethylsiloxysilicate) crosspolymer, (dimethicone / vinyldimethicone) crosspolymer, (vinyldimethyl / trimethylsiloxysilicate / dimethicone) crosspolymer, and (vinyldimethyl / stearyldimethiconetrimethylsiloxysilicate) crosspolymer; (meth)acrylic acid-based resins such as (styrene / acrylates) copolymer and (cyclohexyl methacrylate / ethylhexyl methacrylate) copolymer; Examples of suitable components include (meth)acrylic-silicone graft polymers such as (acrylates / dimethicone) copolymer and (acrylates / polytrimethylsiloxy methacrylate) copolymer; dextrin fatty acid esters such as dextrin isostearate; α-olefin / vinylpyrrolidone copolymers such as (VP / eicosene) copolymer; silicone-modified polysaccharide compounds such as tri(trimethylsiloxy)silylpropylcarbamate pullulan; pullulan fatty acid esters such as myristoylated pullulan and palmitoylated pullulan; rosin acid resins such as rosin-modified phenolic resins and rosin esters; candelilla resins; vinyl acetate resins; saturated or unsaturated hydrocarbon resins such as butene resins such as polybutene resins, polyisoprene resins, and hydrogenated resins thereof; and polyurethane resins. Combining these components (A) with the components described below also facilitates favorable phase separation. One or more of these components (A) can be selected, and combining multiple components is preferred. It should be noted that "(meth)acrylic acid" means "acrylic acid" and / or "methacrylic acid", and "(meth)acrylic" means acrylic and / or methacrylic.

[0014] Furthermore, among the component (A) lipophilic resins, film-forming resins are preferred from the viewpoint of film formation speed. Film formation refers to the process of uniformly applying a resin solution prepared by dissolving a lipophilic resin in a volatile oil to a glass plate to a certain thickness (e.g., 400 μm), and then forming a film after the volatile oil has evaporated.

[0015] From the viewpoint of low-temperature transparency and film-forming speed, the component (A) lipophilic resin is preferably one or more selected from the group consisting of silicone-based resins, (meth)acrylic acid-based resins, (meth)acrylic-silicone graft polymers, and dextrin fatty acid esters. One or more selected from the group consisting of silicone-based resins, (meth)acrylic acid-based resins, and (meth)acrylic-silicone graft polymers is more preferred, with silicone-based resins being particularly preferred. In this embodiment, one lipophilic resin selected from the examples may be used alone, but a combination of two or more is more preferred, as this provides better low-temperature phase separation and transparency. Furthermore, to further improve low-temperature phase separation and transparency, two or more selected from the group consisting of silicone-based resins such as trimethylsiloxysilicate may be used in combination. For example, a combination of (dimethicone / vinyltrimethylsiloxysilicate) crosspolymer and trimethylsiloxysilicate may be used.

[0016] Of the component (A) lipophilic resins, one or more selected from the group consisting of polymethylsilsesquioxane, trimethylsiloxysilicate, (acrylates / dimethicone) copolymer, trifluoroalkyldimethyltrimethylsiloxysilicate, (dimethicone / vinyltrimethylsiloxysilicate) crosspolymer, (trimethylsiloxysilicate / dimethiconol) crosspolymer, (dimethicone / vinyldimethicone) crosspolymer, (styrene / acrylates) copolymer, (cyclohexyl methacrylate / ethylhexyl methacrylate) copolymer, and dextrin isostearate are preferred, and polymethylsilsesquioxane, trimethylsiloxysilicate, (acrylates / dimethicone) copolymer, trifluoroalkyldimethyltrimethylsiloxysilicate, (trimethylsiloxysilicate / dimethiconol) crosspolymer, (dimethicone / vinyldimethicone) crosspolymer, (styrene / acrylates) copolymer, (cyclohexyl methacrylate / ethylhexyl methacrylate) copolymer, and dextrin isostearate are preferred. More preferred are one or more selected from the group consisting of trimethylsiloxysilicate, (dimethicone / vinyltrimethylsiloxysilicate) crosspolymer, (trimethylsiloxysilicate / dimethiconol) crosspolymer, (styrene / acrylates) copolymer, (cyclohexyl methacrylate / ethylhexyl methacrylate) copolymer, and dextrin isostearate, and even more preferred are one or more selected from the group consisting of polymethylsilsesquioxane, trimethylsiloxysilicate, (acrylates / dimethicone) copolymer, trifluoroalkyldimethyltrimethylsiloxysilicate, (dimethicone / vinyltrimethylsiloxysilicate) crosspolymer, and (trimethylsiloxysilicate / dimethiconol) crosspolymer. This results in better layer separation at low temperatures, transparency at low temperatures, and film formation speed. It is more preferable that the component (A) lipophilic resin contains at least trimethylsiloxysilicate, and in this case, trimethylsiloxysilicate may be combined with other lipophilic resins or different silicone resins. Among these, a combination of trimethylsiloxysilicate and polymethylsilsesquioxane, or a combination of trimethylsiloxysilicate and (dimethicone / vinyltrimethylsiloxysilicate) crosspolymer is more preferable, and a combination of trimethylsiloxysilicate, polymethylsilsesquioxane, and (dimethicone / vinyltrimethylsiloxysilicate) crosspolymer is even more preferable. This improves the layer separation properties at low temperatures, transparency at low temperatures, and film formation speed.

[0017] In this embodiment, a commercially available product can be used as the component (A). For example, KF7312J (50% solids, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), KF-9021 (50% solids, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), BY11-018 (30% solids, solvent: cyclopentasiloxane, manufactured by Toray Dow Corning Co., Ltd.), KP541 (60% solids, solvent: isopropanol, manufactured by Shin-Etsu Chemical Co., Ltd.), SR-1000 (manufactured by Momentive Performance Materials Japan), KP545 (30% solids, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), KP575 (30% solids, solvent: cyclopentasiloxane, manufactured by Shin-Etsu Chemical Co., Ltd.), BELSIL TMS 803 (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.), BELSIL RG Examples of suitable resins include 90 (20% solids, solvent: isododecane, manufactured by Wacker Asahi Kasei Silicones), BELSIL RG 100 (20% solids, solvent: decamethylcyclopentasiloxane, manufactured by Wacker Asahi Kasei Silicones), DOWSIL FC-5004DM (1.5 cSt) Silicone Resin Gum (40% solids, solvent: dimethicone, manufactured by Dow Corning Toray), SILFORM FLEXIBLE RESIN (manufactured by Momentive Performance Materials Japan), XS66-B8226 (50% solids, solvent: cyclopentasiloxane, manufactured by Momentive Performance Materials Japan), Oppanol B-100 (manufactured by BASF), and Unifilma HVY (manufactured by Chiba Flour Mills). One or more selected from these may be used.

[0018] The content of the lipophilic resin (preferably a film-forming lipophilic resin) as component (A) relative to the total mass of the multi-layered cosmetic is not particularly limited. However, from the viewpoint of film-forming speed, the preferred lower limit is preferably 0.01% or more, more preferably 0.05% or more, and even more preferably 1% or more. The preferred upper limit is preferably 10% or less, more preferably 8% or less, and even more preferably 5% or less, from the viewpoint of layer separation at low temperatures and transparency at low temperatures. Furthermore, the preferred range of the content of the lipophilic resin as component (A) relative to the total mass of the multi-layered cosmetic is preferably 0.01 to 10%, more preferably 0.05 to 8%, and even more preferably 1 to 5%. By adjusting the content within this range, better layer separation at low temperatures, transparency at low temperatures, and film-forming speed can be achieved. The content of the lipophilic resin described in the examples is the amount of solids. The following commercially available products were blended into each composition, and the solids content at that time is indicated.

[0019] The content of the silicone resin is not particularly limited, but from the viewpoint of transparency at low temperatures and film formation speed, the lower limit of the content of the component (A) lipophilic resin is preferably 50% or more, more preferably 80% or more, and even more preferably 90% or more.

[0020] <Component (B) Volatile oil> The volatile oil used in the present invention (hereinafter also referred to as "component (B) volatile oil" or "component (B)") is not particularly limited as long as it is liquid at 20°C and normal pressure and has volatility, and its viscosity and origin are not important. The volatile oil agent of component (B) is not particularly limited, but may be, for example, any of silicone-based oils, hydrocarbon-based oils, etc., and one or more of these may be used.

[0021] More specifically, examples of the silicone oils include, but are not limited to, low-molecular-weight dimethylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, methyltrimethicone, decamethyltetrasiloxane, and ethyltrisiloxane; and hydrocarbon oils such as light liquid isoparaffin, isododecane, and isohexadecane. One or more of these oils can be used.

[0022] Commercially available volatile oils for component (B) include light liquid isoparaffin such as Isopar H (manufactured by Esso Chemical Co., Ltd.), isododecane (manufactured by Bayer), isohexadecane (manufactured by Uniqema), IP Solvent 1620MU, IP Solvent 2028MU, and IP Solvent 2835 (all manufactured by Idemitsu Kosan Co., Ltd.), decamethylcyclopentasiloxane such as TSF405 (manufactured by Toshiba Silicone Co., Ltd.), SH245, and DC345 (manufactured by Dow Corning Toray Co., Ltd.), and KF-995 (manufactured by Shin-Etsu Chemical Co., Ltd.), methyl trimethicone such as Silicone TMF-1.5 (manufactured by Shin-Etsu Chemical Co., Ltd.), low molecular weight dimethylpolysiloxane such as KF-96L-2CS (manufactured by Shin-Etsu Chemical Co., Ltd.), decamethyltetrasiloxane such as KF-96L-1.5CS (manufactured by Shin-Etsu Chemical Co., Ltd.), and ethyltrisiloxane such as SILSOFT. ETS (manufactured by Momentive Performance Materials), etc. One or more of these may be used.

[0023] Among the volatile oils of component (B), volatile silicone oils are preferred from the viewpoint of transparency at low temperatures and film-forming speed. More specifically, decamethylcyclopentasiloxane, methyltrimethicone, volatile dimethylpolysiloxane (preferably, a volatile silicone oil having a kinematic viscosity of 2 mm at 25°C) are preferred. 2 It is preferable to use one or more selected from the group consisting of dimethylpolysiloxanes having a kinematic viscosity (mm 2 Kinematic viscosity (mm / s) can be measured using a Brookfield viscometer under the following measurement conditions. 2 / s) is viscosity (mPa s) / density (g / cm 3 ) can be calculated.

[0024] The content of the volatile oil (component (B)) in the total mass of the multi-layered cosmetic is not particularly limited, but a suitable lower limit is preferably 1% or more, more preferably 3% or more, and even more preferably 5% or more, and a suitable upper limit is preferably 40% or less, more preferably 30% or less, and even more preferably 20% or less, thereby enabling the production of a cosmetic that is excellent in layer separation at low temperatures, transparency at low temperatures, and film formation speed. The preferred range of the volatile oil (B) is 1 to 40% of the total mass of the multi-layered cosmetic, more preferably 3 to 30%, and even more preferably 5 to 20%. By adjusting the range to this range, a multi-layered cosmetic can be obtained that has good transparency at low temperatures, a good film-forming speed, and a good feel when used.

[0025] <Component (C) Polar oil that is liquid at 25°C and has a molecular weight of 370 or less> The polar oil used in the present invention, which is liquid at 25°C and has a molecular weight of 370 or less (hereinafter also referred to as "component (C) polar oil which is liquid at 25°C and has a molecular weight of 370 or less" or "component (C)"), is not particularly limited as long as it is a polar oil (excluding component (B)) which is liquid at 25°C and has a molecular weight of 370 or less, and its viscosity and origin are not important. Component (C), a polar oil that is liquid at 25°C and has a molecular weight of 370 or less, is not particularly limited, but may be, for example, any of fatty acids, higher alcohols, ester oils, etc., and one or more of these may be used.

[0026] More specifically, for example, fatty acids such as isostearic acid (molecular weight: 284.48) and oleic acid (molecular weight: 282.46); higher alcohols such as octyldodecanol (molecular weight: 298.55) and oleyl alcohol (molecular weight: 268.48); bisethoxydiglycol cyclohexanedicarboxylate (molecular weight: 334.4), isotridecyl isononanoate (molecular weight: 340.6), octocrylene (molecular weight: 361.5), methoxy Examples of suitable oils include, but are not limited to, ester oils such as ethylhexyl cinnamate (molecular weight: 290.4), isostearyl alcohol (molecular weight: 270.49), isopropyl myristate (molecular weight: 270.5), and benzyl benzoate (molecular weight: 212.3); and monoterpenes such as linalool (molecular weight: 154.3), geraniol (molecular weight: 154.3), citronellol (molecular weight: 156.3), and citral (molecular weight: 152.2). One or more of these may be used.

[0027] Commercially available products of component (C) include, for example, Isostearic Acid EX (manufactured by Kokyu Alcohol Kogyo Co., Ltd.) for isostearic acid, NAA-400 Oleic Acid (manufactured by NOF Corporation) for oleic acid, EUTANOL G-JP (manufactured by BASF) for octyldodecanol, Oleyl Alcohol VP (manufactured by Kokyu Alcohol Kogyo Co., Ltd.) for oleyl alcohol, NEOSOLUE-AQULIO (manufactured by Nippon Fine Chemical Co., Ltd.) for bisethoxydiglycol cyclohexanedicarboxylate, and UVINUL MC 80 (manufactured by BASF) for ethylhexyl methoxycinnamate. One or more of these may be used.

[0028] Of the components (C), from the viewpoint of phase separation at low temperatures and transparency at low temperatures, one or more selected from fatty acids and higher alcohols are preferred, and those having a branched structure in the alkyl chain are more preferred.

[0029] The content of component (C), a polar oil that is liquid at 25°C and has a molecular weight of 370 or less, relative to the total mass of the multi-layered cosmetic is not particularly limited, but a suitable lower limit is preferably 0.01% or more, more preferably 0.05% or more, and even more preferably 0.1% or more, and a suitable upper limit is preferably 10% or less, more preferably 8% or less, and even more preferably 5% or less. This allows for the production of a cosmetic that exhibits excellent layer separation properties at low temperatures, transparency at low temperatures, and film formation speed. The preferred range of component (C) is 0.01 to 10%, more preferably 0.05 to 8%, and even more preferably 0.1 to 5% of the total mass of the multi-layered cosmetic. By adjusting the content within this range, a multi-layered cosmetic can be obtained that exhibits good layer separation at low temperatures, transparency at low temperatures, and film formation speed, and that provides a good feel when used.

[0030] In the present technology, the mass ratio (C) / (A) of the component (C) to the component (A) in the total mass of the multi-layered cosmetic is not particularly limited, but a suitable lower limit is preferably 0.01 or more, more preferably 0.05 or more, and even more preferably 0.1 or more, and a suitable upper limit is preferably 10 or less, more preferably 5 or less, and even more preferably 1 or less. This makes it possible to obtain a cosmetic that has excellent layer separation properties and transparency at low temperatures. Furthermore, the preferred range of the mass ratio (C) / (A) of the component (C) to the component (A) is, relative to the total mass of the multi-layered cosmetic, preferably 0.01 to 10, and more preferably 0.05 to 5. By setting it within this range, a multi-layered cosmetic can be obtained that exhibits good layer separation properties at low temperatures, good transparency at low temperatures, and a pleasant feel when used.

[0031] <Component (D) Water> The water used in the present invention (hereinafter also referred to as "component (D) water" or "component (D)") is not particularly limited as long as it is water that can normally be used in cosmetics or topical skin preparations. In addition to purified water, ion-exchanged water, seawater, deep-sea water, and steam-distilled water from plants can also be used, and one or more types selected from these can be used.

[0032] The content of component (D) water relative to the total mass of the multi-layered cosmetic is not particularly limited, but a suitable lower limit of the content is preferably 40% or more, more preferably 50% or more, and even more preferably 60% or more, and a suitable upper limit of the content is preferably 95% or less, more preferably 90% or less, and even more preferably 85% or less, relative to the total mass of the multi-layered cosmetic. This allows for the production of a multi-layered cosmetic with good layer separation properties and film formation speed at low temperatures.

[0033] Furthermore, the preferred range of the amount of water (component (D)) is 40 to 95% of the total mass of the multi-layered cosmetic, more preferably 50 to 90%, and even more preferably 60 to 85%. By adjusting the amount to this range, a multi-layered cosmetic can be obtained that exhibits better layer separation properties and film formation speed at low temperatures.

[0034] <Other ingredients> It is preferable that the multi-layered cosmetic of the present invention contains substantially no emulsifier, from the viewpoints of layer separation property and transparency at low temperatures. Furthermore, from the viewpoint of layer separation property at low temperatures, a small amount of emulsifier is preferable. Here, "substantially containing no emulsifier" means that the content of emulsifier is less than 0.25%, preferably less than 0.1%, more preferably less than 0.05%, and most preferably no emulsifier is contained, based on the total mass of the multi-layered cosmetic. In other words, it is preferable that the multi-layered cosmetic of the present technology does not contain more than 0.25%, preferably more than 0.1%, more preferably more than 0.05%, of emulsifier, from the viewpoints of being emulsifier-free or emulsifier-reduced.

[0035] The multi-layered cosmetic of the present invention preferably further contains a metal salt. The metal salt in the present invention is a compound composed of a cation and anion, which are metal ions. The acid that ionizes the anion source in water can be exemplified by an inorganic acid or an organic acid. The metal salt is preferably an ionic compound. The acid is not particularly limited as long as it is one that can be commonly used in cosmetics or topical skin preparations, and may be an inorganic acid and / or an organic acid. The metal is also not particularly limited as long as it is one that can be commonly used in cosmetics or topical skin preparations, and is preferably one or more selected from alkali metals such as lithium, potassium, and sodium; alkaline earth metals such as barium, magnesium, and calcium; and the like. Of the metal salts, alkali metal salts or alkaline earth metal salts are preferred, and alkali metal salts are more preferred. Among these, inorganic acid metal salts are preferred.

[0036] Among the inorganic acid metal salts, from the viewpoint of phase separation properties and transparency at low temperatures, one or more selected from metal chlorides, metal sulfites (e.g., sodium pyrosulfite), metal phosphates (e.g., sodium metaphosphate), etc. are preferred, and alkali metal chlorides (e.g., sodium chloride, potassium chloride, lithium chloride, etc.) are more preferred, with sodium chloride being more preferred.

[0037] Among the organic acid metal salts, from the viewpoint of phase separation properties and transparency at low temperatures, one or more selected from metal citrates, metal salts of vitamin C (ascorbic acid and its derivatives (e.g., ascorbic acid phosphate), etc.), metal salts of benzoic acid, etc. are preferred, and alkali metal citrates and alkali metal ascorbic phosphates are more preferred, with sodium citrate and magnesium ascorbate phosphate being more preferred.

[0038] The content of the metal salt is not particularly limited, but is preferably 0.1% to 5%, and more preferably 0.1% to 3%, of the total mass of the multi-layered cosmetic, which allows for better layer separation and transparency at low temperatures.

[0039] Furthermore, in a multi-layered cosmetic containing the above-mentioned components (A), (B), and (D), by including a component that causes the oil layer to have a transmittance of 50% or more when the multi-layered cosmetic is left to stand after shaking, it is possible to obtain a multi-layered cosmetic that has excellent layer separation properties at low temperatures, transparency at low temperatures, and film formation speed.

[0040] The components that give an oil layer transmittance of 50% or more when the multi-layered cosmetic is left to stand after shaking are those that give a transmittance of 50% or more when the multi-layered cosmetic is left to stand for 24 hours at 5°C, shaken 10 times, and then left to stand for 30 minutes, and the upper layer (oil layer) is placed in a 1 cm square glass cell and the transmittance at a wavelength of 660 nm is measured using a UV-2600 ultraviolet-visible spectrophotometer (manufactured by Shimadzu Corporation). There are no particular limitations on the components that can be used as long as they are typically used in cosmetics or topical skin preparations. Examples of such components include component (C), a polar oil that is liquid at 25°C and has a molecular weight of 370 or less, as well as terpenes such as monoterpenes, sesquiterpenes, diterpenes, and triterpenes, and ester oils. More specifically, examples include, but are not limited to, monoterpenes such as limonene and pinene, sesquiterpenes such as potassium olefin and zingiberene, triterpenes such as squalene, and ester oils such as diisostearyl malate, polyglyceryl-2 triisostearate, and ethylhexyl hydroxystearate. One or more of these may be used.

[0041] <Optional ingredients> In addition to the above (A) to (D) and other components, the multi-layered cosmetic of the present invention may contain, as necessary, components used in conventional cosmetic compositions, provided that the effects of the present invention are not impaired. Examples of such components include water-soluble polymers, aqueous components, oily components, powders, moisturizers, thickeners, preservatives, UV absorbers, pH adjusters, fragrances, and medicinal ingredients. One or more components selected from these may be used.

[0042] The water-soluble polymer is not particularly limited, but examples thereof include guar gum, sclerotium gum, gellan gum, pectin, agar, sodium chondroitin sulfate, hyaluronic acid, gum arabic, sodium alginate, carrageenan, xanthan gum, locust bean gum, methylcellulose, hydroxyethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone, (sodium acrylate / sodium acryloyldimethyltaurate) copolymer, (PEG-240 / decyltetradeceth-20 / HDI) copolymer, and the like, and one or more selected from these may be used.

[0043] The aqueous component is not particularly limited, but examples thereof include glycerols such as glycerin, diglycerin, and polyglycerin; sugar alcohols such as sorbitol, maltitol, and glucose; and lower alcohols such as ethanol and 1,3-butylene glycol. One or more selected from these may be used. The aqueous component may also function as a solvent. Among these, lower alcohols (preferably those having 1 to 3 carbon atoms) are preferred. In the multi-layered cosmetic composition of the present technology, the inclusion of ethanol in particular can achieve a good film formation rate. In this case, the content of the lower alcohol, including ethanol, relative to the total mass of the multi-layered cosmetic is not particularly limited, but a suitable lower limit is preferably 1% or more, more preferably 3% or more, and even more preferably 5% or more, and a suitable upper limit is preferably 15% or less, and more preferably 10% or less.

[0044] Examples of oily components include solid oils, semi-solid oils, liquid oils, etc., of animal, vegetable, synthetic, and other origins that are commonly used in cosmetics, and include, for example, waxes, hydrocarbons, fats and oils, hardened oils, ester oils, fatty acids, and non-volatile silicone oils. (Excluding the above components (A) to (C).) More specific examples include hydrocarbons such as liquid paraffin, squalane, polyisobutylene, and polybutene; ester oils such as octyldodecyl myristate, glyceryl trioctanoate, diglyceryl diisostearate, diglyceryl triisostearate, diisostearyl malate, propylene glycol dicaprate, cetyl 2-ethylhexanoate, 2-ethylhexyl hydroxystearate, pentaerythrityl tetraisostearate, octyldodecyl stearoyloxystearate, di(phytosteryl / octyldodecyl) lauroyl glutamate, and 2-ethylhexyl paramethoxycinnamate; non-volatile silicone oils such as dimethylpolysiloxane and methylphenylpolysiloxane; essential oils; and fragrances. One or more selected from these may be used. In the present technology, it is preferable to contain nonvolatile silicone oils (preferably nonvolatile dimethylpolysiloxane and / or nonvolatile methylphenylpolysiloxane, etc.) from the viewpoint of better layer separation at low temperatures. When a silicone resin is used, nonvolatile dimethylpolysiloxane is preferable from the viewpoint of compatibility and better layer separation at low temperatures. The kinematic viscosity of the nonvolatile silicone oil at 25°C is preferably 6 mm from the viewpoint of better mist fineness. 2 / s or more, preferably 6 to 20 mm 2 / s, more preferably 6 to 10 mm 2 / s, and is also preferred from the viewpoint of preventing nozzle clogging after use. The preferred content of non-volatile silicone oils is not particularly limited, but is preferably 1 to 20%, more preferably 3 to 15%, and even more preferably 3 to 10% of the total mass of the multi-layered cosmetic.

[0045] The powder is not particularly limited as long as it is one that is normally used in cosmetics, and examples thereof include inorganic powders such as titanium oxide, zinc oxide, cerium oxide, aluminum oxide, silicic anhydride, calcium carbonate, chromium oxide, chromium hydroxide, konjo, ultramarine, iron oxide, carbon black, mica, synthetic phlogopite, sericite, talc, kaolin, barium sulfate, and boron nitride; nylon, polymethyl methacrylate, polyethylene, polypropylene, polystyrene, silicone resin powder, cellulose and its derivatives, urethane, silk powder, crystalline cellulose, N-acyl lysine; Red No. 201, Red No. 202, and Red No. 22; Examples of suitable pigment powders include organic tar-based pigments such as No. 8, Orange No. 203, Blue No. 404, Yellow No. 401, Red No. 3, Red No. 104, Red No. 106, Orange No. 205, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, Purple No. 401, and Purple No. 201, as well as their lake pigments; composite powders such as titanium dioxide-coated mica, titanium dioxide-coated mica, zinc oxide-coated mica, titanium dioxide-coated glass powder, and carmine-coated mica; laminated film powders such as polyethylene terephthalate-aluminum-epoxy laminated powder and polyethylene terephthalate-polymethyl methacrylate laminated powder; and aluminum powder, gold powder, silver powder, and other metal powders. These powders may be surface-treated with one or more of fluorine-based compounds, silicone-based compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, amino acids, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, surfactants, and the like. One or more of these powders may be used. By including this powder, it is possible to make the multi-layered cosmetic composition into three or more layers, as long as the effect of the present technology is not impaired. The content of the powder in the total mass of the multi-layered cosmetic is not particularly limited, but a suitable lower limit is preferably 0.5% or more, more preferably 1% or more, and a suitable upper limit is preferably 10% or less, more preferably 5% or less, and even more preferably 3% or less.

[0046] Examples of antioxidants include α-tocopherol and ascorbic acid; examples of cosmetic ingredients include vitamins, anti-inflammatory agents, and herbal medicines; and examples of preservatives include parahydroxybenzoic acid esters, phenoxyethanol, alkanediols, and chlorphenesin, but are not limited to these, and one or more of these may be used.

[0047] Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, malic acid, or salts thereof (excluding metal salts), potassium carbonate, sodium bicarbonate, ammonium bicarbonate, etc.; examples of cooling agents include L-menthol, camphor, etc., but are not limited to these, and one or more of these can be appropriately selected and used.

[0048] The method for producing the multi-layered cosmetic of the present technology is not particularly limited, and can be produced by a commonly known method. For example, the multi-layered cosmetic of the present technology can be obtained by filling components (A) to (D) and other components into a container (e.g., a container with a dispenser, a container with a spray nozzle, a spray container, a finger spray container, a pressure-accumulating spray container, a mist spray container, etc.). The components used in the present technology may be mixed and then filled. Alternatively, the components used in the present technology may be filled into multiple containers, such as a container for the aqueous layer, a container for the oil layer, and a container for the powder, to form a multi-component product (kit), such as a two-component or three-component product. In the case of a multi-component product, the user can mix the aqueous layer component, oil layer component, powder component, etc. in the desired ratio before spraying. Furthermore, it is preferable to use a transparent or translucent container as the container for filling the multi-layered cosmetic of the present technology. In the present technology, "transparent or translucent" means that the interface of the multi-layered cosmetic inside can be seen. However, the entire container does not need to be transparent or translucent, and a container that allows the contents to be partially visible is also included in the "transparent or translucent" container of this technology.

[0049] The multi-layered cosmetic composition of the present technology is not particularly limited in its application, but is preferably used to protect makeup by spraying it onto the face after applying base makeup such as foundation, or makeup such as eye shadow or blush. It can be used in a container with a spray nozzle or in aerosol form. A spray container with a spray nozzle diameter of approximately 0.1 to 0.6 mm (preferably 0.2 to 0.5 mm) may be used, and a diameter of 0.3 mm can be used for spray evaluation. Since it is used by spraying, it is preferably a liquid cosmetic composition.

[0050] As shown in the Examples below, the multi-layered cosmetic composition of the present technology is a multi-layered composition with at least two layers, including an upper oil layer and a lower water layer, and can also be made into a multi-layered composition with three or more layers by including powder or the like or by using oil layers with different specific gravities. The multi-layered cosmetic composition of the present technology can be well dispersed by mixing immediately before use by spraying, and can maintain this dispersed state for a certain period of time, but will return to a multi-layered structure if left for a certain period of time.

[0051] Furthermore, the viscosity (mPa·s) of the multi-layered cosmetic preparation of the present technology is preferably 1500 mPa·s or less at 25°C when measured as an average value over one minute using a Brookfield viscometer with a No. 2 rotor at 6 rpm, and more preferably 1000 mPa·s or less, as this results in excellent mist fineness.

[0052] The present invention can also employ the following configurations. [1] The following components (A) to (D); (A) Lipophilic resin (B) Volatile oil (C) A polar oil that is liquid at 25°C and has a molecular weight of 370 or less (D)Water The multi-layered cosmetic composition contains the following: [2] The multi-layered cosmetic according to [1], wherein the component (C) is one or more selected from fatty acids and higher alcohols. [3] The multi-layered cosmetic according to [1] or [2], wherein the component (C) has a branched structure. [4] The multi-layered cosmetic according to any one of [1] to [3], wherein the component (A) is a silicone-based resin. [5] The multi-layered cosmetic according to any one of [1] to [4], wherein the mass ratio (C) / (A) of the component (C) to the component (A) is 0.01 to 10. [6] The multi-layered cosmetic composition according to any one of [1] to [5], which is used by spraying. [7] The multi-layered cosmetic composition according to any one of [1] to [6], which is for makeup protection. [8] The following components (A), (B) and (D) (A) Lipophilic resin (B) Volatile oil (D)Water A multi-layered cosmetic composition comprising: Furthermore, the multi-layered cosmetic contains a component that makes the oil layer transmittance 50% or more when the multi-layered cosmetic is left to stand after shaking. [Example]

[0053] The present invention will be described in detail below with reference to examples, but the present invention is not limited to these examples. Examples 1 to 30 and Comparative Examples 1 to 4: Multi-layered makeup protection cosmetics Multi-layered makeup protection cosmetics were prepared according to the formulations shown in Tables 1 to 3 below, and evaluated for (i) layer separation at low temperatures, (ii) transparency at low temperatures, and (iii) film formation rate using the following evaluation methods. The results are also shown in Tables 1 to 3.

[0054] [Table 1]

[0055] [Table 2]

[0056] [Table 3]

[0057] The compounds used in Tables 1 to 3 are shown below. <Lipophilic resin> The lipophilic resin contents listed in Tables 1 to 3 are the amount of solids. Each composition contained the following commercially available products, and the solid content at that time is the amount. Commercially available products that were dissolved or swollen in an oil solution and uniformly dispersed were considered lipophilic resins. When a volatile oil solution or other commercially available resin solution (temperature: 10 to 20°C) was added to a solid content of 10% to 100 mL and stirred, the resulting solution was considered a lipophilic resin. For example, a compound that can be dissolved using any of the oil solutions (e.g., dimethylpolysiloxane) used as a solvent for the commercially available component (A) can be considered a lipophilic resin. The following compounds were considered lipophilic resins. The film-forming ability of resin solutions dissolved in the same oil solution or commercially available resin solutions was evaluated as described above in <Component (A) Lipophilic Resin>. Film formation was observed for all of the following compounds, confirming that they are lipophilic resins with film-forming ability. The following compounds can be used as lipophilic resins in Examples 1 to 30, and the content of the lipophilic resin in Examples 1 to 30 is the amount of solid content.

[0058] <Lipophilic resin> 1) Trimethylsiloxysilicate: KF-9021, manufactured by Shin-Etsu Chemical Co., Ltd. (solid content 50%, solvent: cyclopentasiloxane) 2) Polymethylsilsesquioxane: SILFORM FLEXIBLE RESIN, manufactured by Momentive Performance Materials Japan (solids 100%) 3) Polymethylsilsesquioxane / trimethylsiloxysilicate: Granresin MQI-T50, manufactured by Grant Industries (50% solids, solvent: isododecane) 4) (Dimethicone-vinyltrimethylsiloxysilicate) crosspolymer: BELSIL RG100, manufactured by Wacker Asahi Kasei Silicone Co., Ltd. (solid content 20%, solvent: cyclopentasiloxane) 5) (Acrylates / Dimethicone) Copolymer: KP545, manufactured by Shin-Etsu Chemical Co., Ltd. (solid content 30%, solvent: cyclopentasiloxane) 6) Trifluoroalkyldimethyltrimethylsiloxysilicate: XS66-B8226, manufactured by Momentive Performance Materials Japan (solid content 50%, solvent: cyclopentasiloxane) 7) (Trimethylsiloxysilicate / Dimethiconol) Crosspolymer: DOWSIL FC-5004DM (1.5 cSt) Silicone Resin Gum, manufactured by Dow Corning Toray Co., Ltd. (solids content 40%, solvent: dimethylpolysiloxane) 8) (Dimethicone / vinyl dimethicone) crosspolymer: KSG-16, manufactured by Shin-Etsu Chemical Co., Ltd. (solid content 25%, solvent: dimethylpolysiloxane) 9) (Styrene / acrylates) copolymer: Nissetsu U-3710A (Nippon Carbide Industries Co., Ltd.) 10) (Cyclohexyl methacrylate / ethylhexyl methacrylate) copolymer: Plussize L-250, manufactured by GOO Chemical Industry Co., Ltd. (solid content 40%, solvent: light liquid isoparaffin) 11) Dextrin isostearate: Unifilma HVY, manufactured by Chiba Flour Mills (solid content 100%)

[0059] <Water-soluble polymer> 12) PVP (Polyvinylpyrrolidone) LUVISLOL K90 POWDER, manufactured by Nikko Chemicals Co., Ltd.

[0060] <Volatile oil> 13) Cyclomethicone: KF-995, manufactured by Shin-Etsu Chemical Co., Ltd. 14) Methyl trimethicone: TMF-1.5, manufactured by Shin-Etsu Chemical Co., Ltd. 15) Dimethylpolysiloxane (1.5CS), KF-96L-1.5CS, manufactured by Shin-Etsu Chemical Co., Ltd. 16) Isododecane: Marukasol R, manufactured by Maruzen Petrochemical Co., Ltd.

[0061] <Non-volatile oil> 18) Dimethylpolysiloxane (25℃, 6mm2 / s): Silicon KF-96 (6CS), manufactured by Shin-Etsu Chemical Co., Ltd.

[0062] <Polar oil with a molecular weight of 370 or less that is liquid at 25°C> 19) Octyldodecanol: EUTANOL G-JP, manufactured by BASF 20) Isostearic acid: Isostearic acid EX, manufactured by Kokyu Alcohol Kogyo Co., Ltd. 21) Oleyl alcohol: Oleyl alcohol VP, manufactured by Kokyu Alcohol Kogyo Co., Ltd. 22) Oleic acid: NAA-400 oleic acid, manufactured by NOF Corporation 23) Bisethoxydiglycol Cyclohexanedicarboxylate: NEOSOLUE-AQULIO, manufactured by Nippon Fine Chemicals Co., Ltd. 24) Decyltetradecanol: Lisonol 24SP, manufactured by Kokyu Alcohol Kogyo Co., Ltd. 25) Octocrylene: EUSOLEX OCR, manufactured by Merck Performance Materials

[0063] (Manufacturing method) (A) Oil layer: (1) to (11), (13) to (28) are uniformly heated (75 to 80°C) and mixed. (B) Aqueous layer: (12), (29) to (35) are mixed uniformly. (C) The water layer (B) and the oil layer (A) were filled in this order into a transparent container with a push-type spray nozzle (spray nozzle diameter φ0.3 mm: non-aerosol container) to obtain a multi-layered cosmetic composition. Alternatively, the components (1) to (11) and (13) to (26) may be filled in any order into a transparent container equipped with a spray nozzle and vigorously shaken to obtain a multi-layered cosmetic composition.

[0064] (Evaluation method) The following evaluation items were evaluated by the following methods. (Evaluation items) 1. Layer separation at low temperatures After standing at 5°C for 24 hours, the mixture was shaken 10 times and then left to stand for 30 minutes, after which it was judged according to the following criteria. <Judgment criteria> (Judgment): (Evaluation) A: The interface is clearly separated. B: The interface is slightly blurred, but it is clear that the particles are separated. C: The interface is quite blurred, but it is clear that the particles are separated. D: The interface is blurred and separation is not clear. E: No separation (Evaluation items) B. Transparency at low temperatures After standing at 5°C for 24 hours, the solution was shaken 10 times, and after standing for 30 minutes, the upper layer (oil layer) was placed in a 1 cm square glass cell, and the transmittance at a wavelength of 660 nm was measured using a UV-2600 ultraviolet-visible spectrophotometer (Shimadzu Corporation) to evaluate the transparency of the solution. Note that when the "layer separation at low temperatures" was judged to be E, the upper layer could not be removed and therefore could not be measured. <Judgment criteria> (Judgment): (Evaluation) A:Transmittance 60% or more B: Transmittance 50% or more, less than 60% C: Transmittance 40% or more, less than 50% D: Transmittance less than 40% (Evaluation items) C. Film formation speed Ten cosmetic expert evaluators shook the spray nozzle-equipped container filled with each multi-layered cosmetic ten times, then sprayed the multi-layered cosmetic ten times onto a glass plate (5 cm x 5 cm), and observed the film formation of the multi-layered cosmetic applied to the glass plate. <Evaluation criteria>: [Evaluation result]: [Score] A cosmetic film is formed within 3 minutes of application: 4 points A cosmetic film forms within 3 to 5 minutes after application: 3 points A cosmetic film is formed within 5 to 7 minutes after application: 2 points A cosmetic film is formed within 7 to 9 minutes after application: 1 point No cosmetic film formed even after more than 9 minutes of application: 0 points <Judgment criteria>: Film formation speed (Judgment): (Average score) A: 3.5 points or more B: 2.5 points or more and less than 3.5 points C: 1.5 points or more and less than 2.5 points D: Less than 1.5 points

[0065] As is clear from the results in Tables 1 to 3, the multi-layered makeup protection cosmetics of Examples 1 to 30 of the present invention had superior layer separation at low temperatures, transparency at low temperatures, and film formation speed compared to Comparative Examples 1 to 4. On the other hand, in Comparative Example 1, which did not contain component (A), the layer separation property at low temperatures, the transparency at low temperatures, and the film formation rate were poor, and furthermore, a satisfactory product was not obtained. Furthermore, in Comparative Example 2, which did not contain component (B), the transparency at low temperatures and the film-forming rate were poor, and a satisfactory product was not obtained. Furthermore, in Comparative Example 3, in which component (C) was not used and solid fatty acid was used instead, the layer separation property and transparency at low temperatures were poor and a satisfactory product was not obtained. Furthermore, in Comparative Example 4, which did not contain component (C) and was replaced with a polar oil having a molecular weight of 370 or more, the layer separation property and transparency at low temperatures were poor, and a satisfactory product was not obtained.

[0066] Example 31: Multi-layered makeup protection lotion (Component) (%) 1. Dimethylpolysiloxane (*1) 10 2. (Dimethicone / Vinyltrimethylsiloxysilicate) Crosspolymer 1 3. Polymethylsilsesquioxane (*2) 1 4. Trimethylsiloxysilicate (*3) 1 5. Methyl trimethicone (*4) 5 6. Methylphenylpolysiloxane (*5) 1.5 7. Dimethylpolysiloxane (*6) 2 8. Octyldodecanol (*7) 0.5 9. Tocopherol 0.006 10.Fragrance 0.15 11. Glyceryl tri-2-ethylhexanoate 1 12. Ethanol 7 13. Tripropylene glycol (*8) 3 14. Sodium hyaluronate (*9) 0.1 15. Collagen (*10) 0.1 16. Sodium Chloride 1 17. Sodium monohydrogen phosphate 0.07 18. Sodium dihydrogen phosphate 0.07 19. Remaining purified water

[0067] Example 31: *1: KF-96L-2CS (25℃: 2mm 2 / s, manufactured by Shin-Etsu Chemical Co., Ltd.) *2: BELSIL PMS MK Powder (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.) *3: KF-7312T (Shin-Etsu Chemical Co., Ltd.) *4:TMF-1.5 (Shin-Etsu Chemical Co., Ltd.) *5: KF-56 (Shin-Etsu Chemical Co., Ltd.) *6: KF-96L-6CS (25℃: 6mm 2 / s, manufactured by Shin-Etsu Chemical Co., Ltd.) *7: Lisonol 20SP (Kyukyu Alcohol Kogyo Co., Ltd.) *8:TPG (ADEKA) *9: Hyaluronic acid FCH201 (Kikkoman Biochemifa Corporation) *10:PANCOGEN MARINE (manufactured by GATTEFOSSE)

[0068] (Manufacturing method) (A) Components (1) to (11) are heated to 75 to 80°C and mixed uniformly. (B) Components (12) to (19) are mixed uniformly. (C) Layer (B) and layer (A) were filled in this order into a finger spray container (φ0.3 mm: transparent non-aerosol container) to obtain a multi-layered makeup protection lotion.

[0069] The multi-layered makeup protection lotion of Example 31 was excellent in layer separation at low temperatures, transparency at low temperatures, and film formation rate.

[0070] Example 32: Multi-layered makeup protection lotion (Component) (%) 1. Methyl Trimethicone 10 2. Trimethylsiloxysilicate (*1) 3 3. (Dimethicone / Vinyltrimethylsiloxysilicate) Crosspolymer 1 4. Dimethylpolysiloxane (*2) 7 5. Dimethylpolysiloxane (*3) 1.5 6. Hydrogenated polydecene (*4) 2 7. Isostearic acid (*5) 0.1 8. Isostearyl alcohol (*6) 0.1 9.Menthol 0.02 10.Fragrance 0.15 11.Purple No. 201 0.01 12. Red No. 218 0.01 13. Ethanol 15 14. Glycerin 3 15. Niacinamide 0.05 16. Proline 0.01 17. Rosemary Leaf Extract 0.1 18. Sodium chloride 0.5 19. Sodium lactate 0.07 20. Lactic acid 0.07 21. Blue No. 1 0.02 22. Purple No. 401 0.007 23. Sodium pyrosulfite 0.05 24. Edetate disodium 0.02 25. Remaining purified water

[0071] Example 32: *1: KF-7312L (Shin-Etsu Chemical Co., Ltd.) *2: KF-96L-2CS (25℃: 2mm 2 / s, manufactured by Shin-Etsu Chemical Co., Ltd.) *3: KF-96L-20CS (25℃: 20mm 2 / s, manufactured by Shin-Etsu Chemical Co., Ltd.) *4: SILKFRO 364 (manufactured by LIPO CHEMICALS) *5: Isostearic acid EX (Kyushu Alcohol Kogyo Co., Ltd.) *6: Isostearyl alcohol EX (Kyushu Alcohol Kogyo Co., Ltd.)

[0072] (Manufacturing method) (A) Components (1) to (10) are heated to 75 to 80°C and mixed uniformly. (B) Components (11) to (25) are mixed uniformly. (C) Layer (B) and layer (A) were filled in this order into a container equipped with a spray nozzle (φ0.3 mm: transparent container for non-aerosol use) to obtain a multi-layered makeup protection lotion.

[0073] The multi-layered makeup protection lotion of Example 32 was excellent in layer separation at low temperatures, transparency at low temperatures, and film formation rate.

[0074] Example 33: Multi-layered makeup protection cosmetic (overcoat mist) (Component) (%) 1. Hydrogenated polyisobutene (*1) 10 2. Isododecane 5 3. Dextrin isostearate (*2) 1 4. Ethylhexyl salicylate (*3) 1 5. Octocrylene (*4) 0.5 6. Ethylhexyl methoxycinnamate 7 7. Diethylaminohydroxybenzoylhexyl benzoate 1.5 8.Fragrance 0.3 9. Soybean extract 0.005 10. 1,3-butylene glycol 3.5 11. Remaining purified water 12. Ethanol 15 13. Sodium Chloride 1

[0075] Example 33: *1: Pearleem EX (NOF Corporation) *2: Unifilma HVY (manufactured by Chiba Flour Mills) *3: EUSOLEX OS (Merck Performance Materials) *4: Parsol 340 (manufactured by DSM)

[0076] (Manufacturing method) (A) Oil layer: Components (1) to (8) are heated and mixed uniformly. (B) Aqueous layer: Components (9) to (13) are mixed uniformly. (C) Layer (B) and layer (A) were filled in this order into a finger spray container (φ0.3 mm: non-aerosol container) to obtain a multi-layered makeup protection cosmetic.

[0077] The multi-layered makeup protection cosmetic of Example 33 was excellent in layer separation at low temperatures, transparency at low temperatures, and film formation speed.

[0078] Example 34: Multi-layered makeup-keeping spray (Component) (%) 1. (Acrylates / Behenyl Acrylate / Dimethicone Methacrylate) Copolymer(*1) 0.3 2. Dimethylpolysiloxane (*2) 20 3. Cyclohexanedicarboxylic acid bisethoxydiglycol (*3) 3 4. (Dimethicone / vinyl dimethicone) crosspolymer (*4) 1 5. (Dimethicone / vinyltrimethylsiloxysilicate) crosspolymer 1.5 6.Fragrance 0.3 7. Calcium carbonate (*5) 2 8. Cellulose (*6) 1 9. Ethylhexylglycerin 0.05 10. 1,3-butylene glycol 3.5 11. Remaining purified water 12. Ethanol 15 13. Sodium Chloride 1 14. Centella asiatica leaf extract 0.02 15. Bentonite (*7) 0.8

[0079] Example 34: *1: KP-562P (melting point: 45-55°C, manufactured by Shin-Etsu Chemical Co., Ltd.) *2: KF-96L-2CS (25℃: 2mm 2 / s, manufactured by Shin-Etsu Chemical Co., Ltd.) *3: NEOSOLUE-AQULIO (manufactured by Nippon Fine Chemicals) *4: KSG-16, manufactured by Shin-Etsu Chemical Co., Ltd. (solid content 25%, solvent: dimethylpolysiloxane) *5: Karumaru SCS-M5 (manufactured by Sakai Chemical Industry Co., Ltd.) *6: SILNOS 350 (manufactured by ABC Nanotech) *7: Kunipia G-4 (manufactured by Kunimine Industries)

[0080] (A) Oil layer: Components (1) to (6) are heated and mixed uniformly. (B) Aqueous layer: Components (7) to (15) are mixed uniformly. (C) Layers (A) and (B) are mixed to obtain a stock solution. (D) Add 55 parts of propellant (dimethyl ether) to 45 parts of the undiluted solution of (C) and mix with an aerosol. The mixture was then filled into a container to obtain a multi-layered makeup-keeping spray.

[0081] The multi-layered makeup-keeping spray of Example 34 was excellent in layer separation at low temperatures, transparency at low temperatures, and film formation rate.

[0082] Example 35: Multi-layered makeup protection lotion (Component) (%) 1. Octyldodecanol (*1) 2 2. Dimethylpolysiloxane (*2) 10 3. Trimethylsiloxysilicate (*3) 1.5 4. (Dimethicone / vinyltrimethylsiloxysilicate) crosspolymer 2 5. Isododecane 5 6. Methylphenylpolysiloxane (*4) 2 7.Fragrance 0.1 8. Phenoxyethanol 0.3 9. Dipropylene Glycol 5 10. 1,3-Butylene Glycol 8 11. Glycerin 1 12. Disodium edetate 0.1 13. Pyridoxine hydrochloride 0.05 14.PEG―8(*5) 2 15. Sodium Chloride 1 16. Citric acid 0.01 17. Sodium citrate 0.04 18. Remaining purified water

[0083] Example 35: *1: EUTANOL G-JP (manufactured by BASF) *2: KF-96L-2CS (25℃: 2mm2 / s, manufactured by Shin-Etsu Chemical Co., Ltd.) *3: BELSIL TMS 803 (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.) *4:SH556 FLUID (manufactured by Toray Dow Corning) *5: PEG-400 (manufactured by Toho Chemical Industry Co., Ltd.)

[0084] (Manufacturing method) (A) Components (1) to (7) are heated to 75°C to 80°C and mixed uniformly. (B) Components (8) to (18) are mixed uniformly. (C) Layer (B) in a finger spray container (φ0.20 mm: non-aerosol container) Layer (A) and layer (B) were filled in this order to obtain a multi-layered makeup protection lotion.

[0085] The multi-layered makeup protection cosmetic of Example 35 was excellent in layer separation at low temperatures, transparency at low temperatures, and film formation speed.

[0086] Example 36: Multi-layered makeup protection lotion (Component) (%) 1. Isododecane 10 2. (Cyclohexyl methacrylate / Ethylhexyl methacrylate Copolymer 0.5 3. Dextrin isostearate (*1) 1 4. Undecane / Tridecane (*2) 5 5. Isostearic acid (*3) 0.5 6. Squalane 0.5 7. Hydrogenated polyisobutene (*4) 3.5 8.Fragrance 0.06 9. Xanthan gum (*5) 2 10. Ethanol 20 11. Phenoxyethanol 0.3 12.1,3-Butylene glycol 8 13. Glycerin 1 14. Ethylhexylglycerin 0.05 15. Sodium Chloride 1 16. Sodium monohydrogen phosphate 0.07 17. Sodium dihydrogen phosphate 0.07 18. PVP(*6) 0.3 19. Polyester-5(*7) 0.1 20. Remaining purified water

[0087] Example 36: *1: Unifilma HVY (manufactured by Chiba Flour Mills) *2: Cetiol Ultimate (manufactured by BASF Japan) *3: Isostearic acid EX (Kyushu Alcohol Kogyo Co., Ltd.) *4: Pearleem 6 (manufactured by NOF Corporation) *5: KELTROL CG (manufactured by CP Kelco) *6:PVP K-90 (ISP) *7: Lipo PE Base G-55 (Vantage Specialty Ingredients)

[0088] (A) Oil layer: Components (1) to (8) are heated and mixed uniformly. (B) Aqueous layer: Components (9) to (20) are mixed uniformly. (C) Layer (B) and layer (A) were filled in this order into a finger spray container (φ0.3 mm: non-aerosol container) to obtain a multi-layered makeup protection lotion.

[0089] The multi-layered makeup protection cosmetic of Example 36 was excellent in layer separation at low temperatures, transparency at low temperatures, and film formation speed.

Claims

1. The following components (A) to (D): (A) Lipophilic resin (B) Volatile oil (C) a polar oil that is liquid at 25°C and has a molecular weight of 370 or less (D) Water A multi-layered cosmetic comprising:

2. 2. The multi-layered cosmetic according to claim 1, wherein the component (C) is one or more selected from fatty acids and higher alcohols.

3. The multi-layered cosmetic according to claim 1 or 2, wherein the component (C) has a branched structure.

4. The multi-layered cosmetic according to claim 1 or 2, wherein the component (A) is a silicone-based resin.

5. 3. The multi-layered cosmetic according to claim 1, wherein the mass ratio (C) / (A) of the component (C) to the component (A) is 0.01 to 10.

6. The multi-layered cosmetic composition according to claim 1 or 2, which is used by spraying.

7. The multi-layered cosmetic composition according to claim 1 or 2, which is used for makeup protection.

8. The following components (A), (B) and (D) (A) Lipophilic resin (B) Volatile oil (D) Water A multi-layered cosmetic composition comprising: The multi-layered cosmetic further comprises a component that makes the oil layer transmittance 50% or more when the multi-layered cosmetic is left to stand after shaking.

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