Fragrance Mixtures (V)

Abstract

Proposed is a fragrance mixture comprising or consisting of (a) a first fragrance having at least one citrus, floral and lactone odor note, and (b) 4-ethyl-oct-2 / 3-enoic acid.

Description

[Technical field]

[0001] FIELD OF THEINVENTION The present invention relates to the perfumery field and to fragrance mixtures containing 4-ethyl-oct-2 / 3-enoic acid having improved odor notes. [Background technology]

[0002] 2. Background of the Invention In the perfume industry, there is a high demand for ingredients, especially notes, that can expand the spectrum of a perfume's composition. There is a particularly high demand for ingredients that, in small quantities, have a big effect on other fragrances, transforming them for the better.

[0003] Related Prior Art Japanese Patent Application Laid-Open No. 56-65842 (HASEGAWA) discloses 3-substituted cis- or trans-4-octenoic acids or esters thereof as perfume raw materials.

[0004] JP 2004-262871 (KURARAY) relates to 7-octenoic acid or its derivatives which are useful as pharmaceutical intermediates and perfume raw materials.

[0005] In JP 56-120678 and JP 2007-297286 (SHIONO), 7-methyl-4-hydroxy-5-octenoic acid and 3,7-dimethyl-5E-octenoic acid, 3,7-dimethyl-5Z-octenoic acid and lactones of lower alkyl or alkynyl esters are proposed as raw materials for perfumes.

[0006] US Patent 5,141,921 (TAKASAGO) discloses a fragrance composition containing 3-methyl-2-hexenoic acid and / or 7-octenoic acid. [Prior art documents] [Patent documents]

[0007] [Patent Document 1] Japanese Patent Application Publication No. 56-65842 [Patent Document 2] JP 2004-262871 A [Patent Document 3] Japanese Patent Application Publication No. 56-120678 [Patent Document 4] JP 2007-297286 A [Patent Document 5] U.S. Patent No. 5,141,921 Summary of the Invention

[0008] Object of the invention The object of the present invention is therefore to provide new fragrance mixtures based on perfumes which inventively have citrus, floral and lactone odor notes, in particular showing improvements with regard to stronger, fuller and greener odor notes, whilst for example technical and terpenic odor notes are reduced. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0009] Brief description of the invention The first object of the present invention is to (a) at least one first fragrance having citrus, floral and lactone odor notes; and (b) 4-Ethyl-oct-2 / 3-enoic acid The present invention relates to a fragrance mixture comprising or consisting of:

[0010] Surprisingly, it has been observed that 4-ethyl-oct-2 / 3-enoic acid, even in very small amounts, can enhance, improve and / or adjust the inherent odor of a first fragrance with citrus, floral and lactone notes. In particular, the citrus, floral and lactone odor notes are enhanced and made more intense, while other desirable odor notes such as power, volume and greenness are accentuated and undesirable odor notes such as technical and terpenes are attenuated. Thus, the addition of very small amounts of some ingredients significantly expands the perfumer's olfactory palette.

[0011] 4-Ethyl-oct-2 / 3-enoic acid [ka] 4-Ethyl-oct-2 / 3-enoic acid of formula (I) is a known organic compound and can be prepared according to conventional methods known in organic chemistry. The term "4-ethyl-oct-2 / 3-enoic acid" includes 4-ethyl-oct-2-enoic acid, 4-ethyl-oct-3-enoic acid, and mixtures thereof.

[0012] First Fragrance The first fragrance group is characterized by a predominance of citrus, floral and lactone scents.Typical examples include citral, methyl pampelmousse, limonene, dihydromyrcenol, linolol, methyl dihydrojasmonate, phenylethyl alcohol, benzyl acetate, 2,4-dimethyltetrahydroindenodioxin, florosa, methyl anthranilic acid, tetradecanal, octadecanal, delta decalactone, and mixtures thereof.

[0013] The mixture according to the present invention may comprise said first fragrance and said 4-ethyl-oct-2 / 3-enoic acid, present in an amount ranging from about 98:2% by weight to about 99.9:0.5 percent by weight, preferably in an amount ranging from about 0.6 to 1.0 percent by weight, calculated on said mixture.

[0014] solvent In a preferred embodiment, the mixture according to the present invention may include at least one solvent. Suitable solvents are selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol and triethyl citrate. Typically, the at least one solvent is present in the mixture in an amount ranging from about 10 to about 90 percent by weight, preferably from about 25 to about 50 percent by weight.

[0015] fragrance composition Another object of the invention relates to a fragrance composition comprising a mixture as defined above and at least one second fragrance different from said first fragrance and from 4-ethyl-oct-2 / 3-enoic acid. Said second fragrance may be chosen from the group consisting of: [(3,7-dimethyl-6-octenyl)-xy]-cetaldehyde, 1-(p-menthen-6(2)-yl)-1-propanone, 1,2,3,4,5,6,7,8-Octahydro-8,8-dimethyl-2-naphthaldehyde, 10-Undecene-1-ar, 10-Undecen-1-ol, 1-Decanal, 1-dodecanal, 1-Methyl-3-(4-methylpentyl)-3-cyclohexenecarboxaldehyde, 1-Methyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde, 1-nonanal, 1-Octanal, 1-octen-3-ol, 1-p-menthene-q-carboxaldehyde, 1-Undecanal, 2-(2-(4-methyl-3-cyclohexen-1-yl)propyl)cyclopentanone, 2,4,4,7-tetramethyl-oct-6-en-3-one, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 2,4-Dimethyl-3-cyclohexene-1-carboxaldehyde 4-Methoxybenzaldehyde, 2,4-Dimethyl-3-cyclohexene-1-carboxaldehyde, 2,6,10-trimethyl-5,9-undecadienal, 2,6,10-trimethyl-9-undecenal, 3-dodecen-1-al, 2,6-Dimethyl-5-heptenal; 2,6-dimethylhept-5-en-1-al, 2,6-dimethylheptan-2-ol, 2,6-nonadienal, 2-acetyl-3,3-dimethyl-norbornane, 2-Methyldecanal, 2-Methyloctanal, 2-Methylundecanal, 2-Methyl-3-(4-tertbutyl)propanal, 2-Methyl-3-(isopropyl-phenyl)propanal, 2-Methyl-3-(para-methoxy-phenylpropanal), 2-methyl-3-phenyl-2-propen-1-al, 2-Methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal, 2-Methylbutanol, 2-Methylpentanol, 2-phenoxyethanol, 2-phenylpropan-1-al, 2-phenylpropanol, 2-tert-butylcyclohexanol, 3-(3,4-methylenedioxy-phenyl)-2-methylpropan-1-al, 3-(3-isopropylphenyl)-butan-1-al, 3-(4-ethylphenyl)-2,2-dimethylpropan-1-al, 3-(4-ethylphenyl)-2,2-dimethylpropanal, 3-(4-isopropylphenyl)-2-methylpropan-1-al, 3-(4-methoxyphenyl)-2-methylpropanal, 3-(4-tert-butylphenyl)-2-methyl-propanal, 3-(4-tert-butylphenyl)propanal, 3,4-Dimethoxybenzaldehyde, 3,4-methylenedioxybenzaldehyde, 3,5,5-trimethylcyclohexanol, 3,5,5-trimethylhexanal, 3,5,6-trimethyl-3-cyclohexenecarboxaldehyde, 3,7-Dimethyl-2-methylene-6-octenal, 3,7-dimethyl-6-octen-1-al, 3,7-dimethyloctan-1-al, 3-ethoxy-4-hydroxybenzaldehyde, 3-Hexanol, 3-Methoxy-4-hydroxy-benzaldehyde, 3-methyl-5-phenyl-1-pentanal, 3-methyl-5-phenylpentanol, 3-octanol, 3-Phenyl-2-hexylprop-2-enal, 3-Phenyl-2-pentylprop-2-en-1-al, 3-phenyl-2-propenal, 3-phenylprop-2-en-1-al, 3-phenylpropanol, 3-Propyl-bicyclo[2.2.1]-hept-5-ene-2-carbaldehyde, 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanone, 4-(3)(4-methyl-3-pentenyl)-3-cyclohexene-carboxaldehyde, 4-(4-hydroxy-3-methoxyphenyl)-2-butanone, 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde, · 4-(tricyclo[5.2.1.0(2,6)]-decylidene-8)-butanal; 4-Damaskol, 4-heptenol, 4-Hydroxy-3-methoxybenzaldehyde, 4-isopropyl benzyaldehyde, 4-Isopropylcyclohexanol, 4-Methoxybenzaldehyde, 4-Methylphenylacetaldehyde, 4-tert-butylcyclohexanol, 5,9-dimethyl-4,8-decadienal, 5-Methoxyhexahydro-4,7-methanoindan-1-carboxaldehyde, 5-Methoxyhexahydro-4,7-methanoindan-2-carboxaldehyde, 6,10-dimethyl-3-oxa-5,9-undecadien-1-al, 6,6-Dimethyl-2-norpinen-2-propionaldehyde, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, 6,8-Dimethyl-2-nonanol, 6-nonen-1-ol, 6-isopropyl-deca-hydro-2-naphthone, 6-Methoxyhexahydro-4,7-methanoindan-1-carboxaldehyde, 6-Methoxyhexahydro-4,7-methanoindan-2-carboxaldehyde, 7-Hydroxy-3,7-dimethyloctanal, 7-Methoxy-3,7-dimethyloctan-1-al, 9-Decen-1-ol, 9-Decenar, Acetophenone, Adoxal Allyl cyclohexyl propionate, Alfaronen, Ambroxan, Amylsalicylat, Anethole, Anisaldehyde, Benzaldehyde, Benzophenone, Benzyl acetate, Benzyl acetone, Benzyl alcohol, Benzyl salicylate, Benzyl ethyl ether, · Bourjonal, -Bukkoxim, -Butyl salicylate, ·camphor, Canthoxal, Carvone, Cassion, Celery ketone, Chlorhydral, Cinnam alcohol, cis- / trans-3,7-dimethyl-2,6-octadien-1-al, Cis-Jasmon, citral or mixtures thereof, Citronellal, Citronellol, Citronellyloxyacetaldehyde, Cumal, Cyclamen aldehyde, Cyclohexyl salicylate, -Simar, Damarose, Damascenone, Decanol, Decyl aldehyde, Delphon, Dihydrojasmone, Dihydromyrcenol, Dihydrodimethaldehyde, Dihydro-β-ionone, Dimethylbenzylcarbinol, Dimethylbenzylcarbinyl acetate, Dimethylheptanol, Dimethyloctanol, Dimethyloctenone, -Dalcinil, Ethyl salicylate, Ethyl vanillin, Ethyl methylphenylglycinate, Eugenol, Fenchon, Floramon, Floralozone, Floramat, -Florhydral, Gerson, Geraniol, Hedion, Helional, Heliotropin, Heptanol, Hexahydro-4,7-methanoindan-1-carboxaldehyde, Hexahydro-8,8-dimethyl-2-naphthaldehyde, Hexalon, Hexyl salicylate, Hydroxycitronellal, Isoborneol, Isodamascone, Isoeugenol, Isojasmone, Isopulegol, Jasma cykratat, Corebon, Lauric aldehyde, Ligustral, Lilial citral, Liliar, Limonene, Linalool, Linalyl acetate, Livescon, Lillard, m-Cymene-7-carboxaldehyde, Melonal, Merasat, ·menthol, Menthon, Methylacetophenone, Methyl cedrenyl ketone, Methyl cedrylon, Methyl cedrylone, Methylcyclocitron, Methyl dihydrojasmonate, Methylheptenone, Methyl lavender ketone, Methyl dihydrojasmonate, Methylnonylacetaldehyde, Methyl-β-naphthyl ketone, Musk Indanone, Muscon, Myrtenol, n-Dodecanal, Neobutenone, Nellore, n-Hexanol, Nonanol, n-Undecanal, Octahydro-4,7-methano-1H-indenecarboxaldehyde; Octanal, Octanol, o-Methoxyzimtaldehyde, Orivone, p-ethyl-α,α-dimethylhydrozimtaldehyde Phenol, Phenoxyacetaldehyde; Phenoxyisobutyrate, Phenylacetaldehyde, Phenyl salicylate, Phenylethyl acetate, Phenylethyl alcohol, p-Hydroxyphenylbutanone, Pinene, -Plicatone, p-menthan-7-ol, p-Methoxyacetophenone, p-Methylphenoxyacetaldehyde, p-tert.-bucinal, p-tert-butylcyclohexanone, p-tert-cyclohexyl acetate, p-Tolyl acetaldehyde, Styrallyl propionate, Tetrahydrogeraniol, Tetrahydrolinalool, Tetramelane, Thymol, Tonalide / Musk Plus, trans-2-cis-6-nonadienol, trans-2-nonen-1-ol, trans-2-octenol, trans-4-decenal, Triplar, Undecanal, Undecanol, Undecylenaldehyde, Vanillin, Belton, Beldon, α-Methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde, α-damascone, α-Methylbenzyl alcohol, α-Methyl-4-(1-methylethyl)benzeneacetaldehyde, α-Methylphenylacetaldehyde, α-n-Amylzimtaldehyde, α-n-hexyl-cinnamaldehyde, α-Terpineol, β-damascone, β-ionone, β-terpineol, gamma-methyl ionone, · δ-damascone. The fragrance composition may contain the 4-ethyl-oct-2 / 3-enoic acid alone or a mixture of 4-ethyl-oct-2 / 3-enoic acid and the first fragrance in an amount ranging from about 0.01 to about 2 percent by weight, preferably from about 0.1 to 1 percent by weight, calculated on the composition.

[0016] Cosmetics and personal care preparations Another object of the present invention relates to a cosmetic or personal care preparation comprising said fragrance mixture or said perfume composition as described above. Said preparation may contain said fragrance mixture or perfume composition in an amount ranging from about 0.01 to about 2 percent by weight, preferably from about 0.1 to 1 percent by weight, calculated on the basis of the preparation. Said composition may represent, for example, a cosmetic cream, lotion, spray, milk, ointment, gel or mousse.

[0017] The formulations according to the invention may be used in the form of antidandruff agents, anti-irritation agents, anti-irritation agents, antioxidants, astringents, antiperspirants, preservatives, antistatic agents, binders, buffers, carrier materials, chelating agents, cell stimulants, cleansing agents, care agents, deodorants, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibers, film-forming agents, fixing agents, foam-forming agents, foam stabilizers, foam-preventing substances, foam boosters, gels, gel-forming agents, hair care agents, hair setting agents, hair straightening agents, moisturizing agents, moisturizing substances, moisture-retaining substances, bleaching agents, reinforcing agents, stain removers, optical brightening agents, impregnating agents, stain repellents, friction reducers, lubricants, moisture creams, ointments, opacifying agents, plasticizers, coating agents, polishing agents, brightening agents, polymers, powders, proteins, re-oiling agents, polishing ... They may contain additional auxiliaries and additives such as abrasives, silicones, skin soothing agents, skin cleansing agents, skin care agents, skin healing agents, skin lightening agents, skin protecting agents, skin softening agents, hair growth promoting agents, cooling agents, skin cooling agents, warming agents, skin warming agents, stabilizers, UV absorbers, UV filters, cleaning agents, fabric conditioning agents, suspending agents, skin tanning agents, thickeners, vitamins, oils, waxes, fats, phospholipids, saturated fatty acids, mono- or poly-unsaturated fatty acids, alpha-hydroxy acids, polyhydroxy fatty acids, liquefying agents, dyes, colour protection agents, pigments, anticorrosive agents, fragrances, perfumed substances, odoriferous substances, polyols, surfactants, electrolytes, organic solvents or silicone derivatives.

[0018] Surfactants Preferred auxiliaries and additives are anionic and / or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants can also be present in the composition. Suitable examples are described together with the paragraph dealing with emulsifiers.

[0019] Representative examples of anionic and zwitterionic surfactants include: almondamidopropylamine oxide, almondamidopropyl betaine, aminopropyl lauryl glutamine, ammonium C12-15 alkyl sulfate, ammonium C12-16 alkyl sulfate, ammonium capryleth sulfate, ammonium coco monoglyceride sulfate, ammonium cocosulfate, ammonium cocoyl isethionate, ammonium cocoyl sarcosinate, ammonium C12-15 pareth sulfate, ammonium C9-10 perfluoroalkyl sulfonate, ammonium dinonyl sulfosuccinate, ammonium dodecylbenzene sulfonate. nate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 sulfate, ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myreth sulfate, ammonium myristyl sulfate, ammonium nonoxynol-4 sulfate, ammonium nonoxynol-30 sulfate, ammonium oleate, ammonium palm kernelate Kernel Sulfate, Ammonium Stearate, Ammonium Thalate, AMPD-Isostearyl Hydrolyzed Collagen, AMPD-Rosin Hydrolyzed Collagen, AMP-Isostearyl Hydrolyzed Collagen, AMP-Isostearyl Hydrolyzed Keratin, AMP-Isostearyl Hydrolyzed Soy Protein, AMP-Isostearyl Hydrolyzed Wheat Protein, Apricot Amidopropyl Betaine, Arachidic Acid, Arginine Hexyldecyl Phosphate, Avocado Amidopropyl Betaine, Avocado Oil Glycereth-8 Ester, Babassu Acid, Babassu Amidopropyl Amine Oxide, Babassu Amidopropyl Betaine, Beeswax Acid (BeeswaxAcid), Behenamidopropyl Betaine, Behenamine Oxide, Beheneth-25, Beheneth-30, Behenic Acid, Behenyl Betaine, Bis-Butyl Dimethicone Polyglyceryl-3, Butoxynol-5 Carboxylic Acid, Butoxynol-19 Carboxylic Acid, Butyldimonium Hydroxypropyl Butylglucoside Chloride, Butyldimonium Hydroxypropyl Laurylglucoside Chloride, Butyl Glucoside, Butyl Glucoside Caprate, Butyl Glu Coside Hydroxypropyltrimonium Chloride, Butyl Octanoic Acid, C18-36 Acid, C20-40 Acid, C30-50 Acid, C16-22 Acid Amide MEA, Calcium Dodecyl Benzene Sulfonate, Calcium Lauroyl Taurate, C9-16 Alkane / Cycloalkane, C10-14 Alkyl Benzene Sulfonic Acid, C12-14 Alkyl Diaminoethyl Glycine HCL, C9-15 Alkyl Phosphate, Candida Bombicola (Candida Bombicola / Glucose / Methyl Rapeseedate Ferment, Canolamidopropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glucoside, Capryl / Capramidopropyl Betaine, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Capryloyl Collagen Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids, Caprylyl / Capryl Glucoside, Caprylyl / Capryl Wheat Bran / Straw Glycosides, Caprylyl Glucoside,

[0020] Caprylyl Glyceryl Ether, Caprylyl Pyrrolidone, Carnitine, Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Ceteareth-4 Phosphate, Ceteareth-5 Phosphate, Ceteareth-10 Phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Cetyl Betaine, Chrysanthemum Sinense Flower Extract Extract), C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidoethyl Betaine, Cocamidopropyl Amine Oxide, Cocamidopropyl Betaine Amide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid, Coceth-7 Carboxylic Acid, Coceth-4 Glucoside, Cocoamphodipropionic Acid, Cocobetaine Amido Amphopropionate, Coco Betaine, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Coco Glucoside, Coco Glucoside Hydroxypropyltrimonium Chloride, Coco Hydroxysultaine, Coco Morpholine Oxide, Coconut Acid, Coconut Oil Glycereth-8 Esters, Coco / Oleamidopropyl Betaine, Coco Sultaine, Coco / Sunflower Amidopropyl Betaine, Cocoyl Choline Methosulfate,

[0021] Cocoyl glutamic acid, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn acid, cottonseed acid, cottonseed oil glyceryl-8 ester, C10-16 pareth-1, C10-16 pareth-2, C11-13 pareth-6, C11-13 pareth-9, C11-13 pareth-10, C11-15 pareth-30, C11-15 pareth-40, C12-13 pareth-1, C12-13 pareth-23, C12-14 pareth-5, C12-14 pareth-9, C1 3-15 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 carboxylic acid, C9-11 Pareth-8 carboxylic acid, C11-15 Pareth-7 carboxylic acid, C12-13 Pareth-5 carboxylic acid, C12-1 3 Pareth-7 carboxylic acid, C12-13 Pareth-8 carboxylic acid, C12-13 Pareth-12 carboxylic acid, C12-15 Pareth-7 carboxylic acid, C12-15 Pareth-8 carboxylic acid, C12-15 Pareth-12 carboxylic acid, C14-15 Pareth-8 carboxylic acid, C6-10 Pareth-4 phosphate, C12-13 Pareth-2 phosphate, C12-13 Pareth-10 phosphate, C12-15 Pareth-6 phosphate, C12-15 Pareth-8 phosphate, C12-15 Pareth-10 phosphate, C12-16 Pareth-6 phosphate, C4-18 Perfluoroalkylethylthiohydroxypropyltrimonium chloride, Cupuassuamidopropyl betaineBetaine), DEA-C12-13 Alkyl Sulfate, DEA-C12-15 Alkyl Sulfate, DEA-Ceteareth-2 Phosphate, DEA-Cetyl Sulfate, DEA-Cocoamphodipropionate, DEA-C12-13 Pareth-3 Sulfate, DEA-Cyclocarboxypropyloleate, DEA-Dodecylbenzenesulfonate, DEA-Isostearate, DEA-Laureth Sulfate, DEA-Lauryl Sulfate, DEA-Linoleate, DEA-Methyl Myristate Sulfonate, DEA-Myreth Sulfate, DEA-Myristate, DEA-Myristyl Sulfate, DEA-Oleth-5 Phosphate, DEA-Oleth-20 Phosphate, DEA PG-oleate, deceth-7 carboxylic acid, deceth-7 glucoside, deceth-9 phosphate, decylamine oxide, decylbetaine, decylglucoside, decyltetradeceth-30, decyltetradecylamine oxide,

[0022] Diammonium Lauramide-MEA Sulfosuccinate, Diammonium Lauryl Sulfosuccinate, Diammonium Oleamide PEG-2 Sulfosuccinate, Dibutoxymethane, Di-C12-15 Pareth-2 Phosphate (Di-CI 2-15 Pareth-2 Phosphate), Di-C12-15 Pareth-4 Phosphate, Di-C12-15 Pareth-6 Phosphate, Di-C12-15 Pareth-8 Phosphate, Di-C12-15 Pareth-10 Phosphate, Didodecyl Butane Tetracarboxylate, Diethylamine Laureth Sulfate, Diethylhexyl Sodium Sulfosuccinate, Dihydroxyethyl C8-10 Alkoxypropylamine Oxide, Dihydroxyethyl C9-11 Alkoxypropylamine Oxide, Dihydroxyethyl C12-15 Alkoxypropylamine Oxide, Dihydroxyethyl Cocamine Oxide, Dihydroxyethyl Lauramine Oxide, Dihydroxyethyl Stearamine Oxide, Dihydroxyethyl Tallowamine Oxide, Dimethicone PEG-7 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG- 12 / 4 Phosphate, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone Propyl PG-Betaine, Dimyristyl Phosphate, Dioleoylamidoethyl Hydroxyethylmonium Methosulfate, DIPA-Hydrogenated Cocoate, DIPA-Lanolate, DIPA-Myristate, Dipotassium Capryloyl Glutamate, Dipotassium Lauryl Sulfosuccinate, Dipotassium Undecylenoyl Glutamate, Babassuamide MEA-Sulfosuccinate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Capryloyl Glutamate, Disodium Cetearyl Sulfosuccinate, Disodium Cetyl Phenyl Ether Disulfonate, Disodium Cetyl Sulfosuccinate, Disodium Cocamide MEA-Sulfosuccinate, Disodium Cocamide MIPA PEG-4 disodium sulfosuccinate,

[0023] Cocamide MIPA Sulfosuccinate Disodium, Cocamide PEG-3 Sulfosuccinate Disodium, Coceth-3 Sulfosuccinate Disodium, Cocoamphocarboxyethylhydroxypropylsulfonate Disodium, Cocoamphodiacetate Disodium, Cocoamphodipropionate Disodium, Coco-glucoside Sulfosuccinate Disodium, Coco-sulfosuccinate Disodium, Cocoyl Butylgluceth-10 Sulfosuccinate Disodium, Cocoyl Glutamate Disodium, C12-14 Pareth-1 Sulfosuccinate Disodium, C12-14 Pareth-2 Sulfosuccinate Disodium, C12-15 Pareth Sulfosuccinate Disodium, C12-14 Sec-Pareth-3 Sulfosuccinate Disodium, C12-14 Sec-Pareth-5 Sulfosuccinate Disodium, C12-14 Disodium Sec-Palace-7 Sulfosuccinate, Disodium C12-14 Sec-Palace-9 Sulfosuccinate, Disodium C12-14 Sec-Palace-12 Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosuccinate, Disodium Decyl Phenyl Ether Disulfonate, Disodium Dihydroxyethyl Sulfosuccinyl Undecylenate, Disodium Ethylene Dicocamide PEG-15 Disulfate, Disodium Hydrogenated Cottonseed Glyceride Sulfosuccinate, Disodium Hydrogenated Tallow Glutamate, Disodium Hydroxydecyl Sorbitol Citrate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamide MEA Sulfosuccinate, Disodium Isodecyl Sulfosuccinate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamide MEA Sulfosuccinate, Disodium Stearamide MIPA-Sulfosuccinate, Disodium Isostearoamphodiacetate, Disodium Isostearoamphodipropionate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramide MEA-Sulfosuccinate, Disodium Lauramide MIPA Glycol Sulfosuccinate, Disodium Lauramide PEG-2 Sulfosuccinate, Disodium Lauramide PEG-5 Sulfosuccinate, Disodium Laureth-5 Carboxyamphodiacetate, Disodium Laureth-7 CitrateCitrate), sodium laureth disulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium lauriminobishydroxypropylsulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate,

[0024] Disodium Lauryl Tocopheryl Phosphate, Disodium Lauroamphodiacetate, Disodium Lauroamphodipropionate, Disodium N-Lauroyl Aspartate, Disodium Lauroyl Glutamate, Disodium Lauryl Phenyl Ether Disulfonate, Disodium Lauryl Sulfosuccinate, Disodium Myristamide MEA-Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamide MEA-Sulfosuccinate, Disodium Oleamide MIPA-Sulfosuccinate, Disodium Oleamide PEG-2 Sulfosuccinate, Disodium Oleamide Amphodipropionate, Disodium Oleth-3 Sulfosuccinate, Disodium Oleyl Phosphate, Disodium Oleyl Sulfosuccinate , Palmitamide PEG-2 Disodium Sulfosuccinate, Palmitoleamide PEG-2 Disodium Sulfosuccinate, PEG-4 Cocamide MIPA Disodium Sulfosuccinate, PEG-12 Dimethicone Disodium Sulfosuccinate, PEG-8 Palm Glyceride Disodium Sulfosuccinate, PPG-2-Isodeceth-7 Carboxyamphodiacetate Disodium, Ricinoleamide MEA Disodium Sulfosuccinate, Sitosterol-14 Disodium Sulfosuccinate, Soyamphodiacetate Disodium, Stearamide MEA Disodium Sulfosuccinate, Steariminodipropionate Disodium, Stearoamphodiacetate Disodium, Stearoyl Glutamate Disodium, Stearyl Sulfosuccinamate Disodium (Disodium Stearyl Sulfosuccinamate, Disodium Stearyl Sulfosuccinate, Disodium 2-Sulfolaurate, Disodium 2-Sulfopalmitate, Disodium Talamide MEA Sulfosuccinate, Disodium Tallowamide MEA Sulfosuccinate, Disodium Tallow Amphodiacetate, Disodium Tallow Iminodipropionate, Disodium Tallow Sulfosuccinate, Disodium Tridecyl Sulfosuccinate, Disodium Undecylenamide MEA Sulfosuccinate, Disodium Undecylenamide PEG-2 Sulfosuccinate, Disodium Undecylenoyl Glutamate, Disodium Wheat Germamido MEA SulfosuccinateMEA-Sulfosuccinate), Wheat Germ PEG-2 Disodium Sulfosuccinate,

[0025] Wheat Germ Amphodiacetate Disodium, Di-TEA-Cocamide Diacetate, Di-TEA-Oleamide PEG-2 Sulfosuccinate, Di-TEA-Palmitoyl Aspartate, Ditridecyl Sodium Sulfosuccinate, Dodecyl Benzene Sulfonic Acid, Erucamidopropyl Hydroxysultaine, Ethylhexeth-3 Carboxylic Acid, Ethyl PEG-15 Cocamine Sulfate, Glyceryl Capryl Ether, Hexyldecanoic Acid, Hydrogenated Coconut Acid, Hydrogenated Laneth-25, Hydrogenated Menhaden Acid, Hydrogenated Palm Acid, Hydrogenated Palm Kernel Amine Oxide, Hydrogenated Tallow Acid, Hydrogenated Tallow Amine Oxide, Hydrogenated Tallow Betaine, Hydrogenated Talloweth-25, Hydrogenated Tallowoyl Glutamic Acid Acid), Hydrolyzed Candida Bombicola Extract, Hydroxyceteth-60, Hydroxyethylacetemonium PG-Dimethicone, Hydroxyethyl Butylamine Laureth Sulfate, Hydroxyethyl Carboxymethyl Cocamidopropylamine, Hydroxyethyl Hydroxypropyl C12-15 Alkoxypropylamine Oxide, Hydroxylauryl / Hydroxymyristyl Betaine, Hydroxystearic Acid, Hydroxysuccinimidyl C10-40 Isoalkyl AcidateAcidate), Hydroxysuccinimidyl C21-22 Isoalkyl Acidate, Hydroxysultaine, IPDI / PEG-15 Soyamine Oxide Copolymer, IPDI / PEG-15 Soyethonium Ethosulfate Copolymer, IPDI / PEG-15 Soy Glycinate Copolymer, Isoceteth-30, Isolaureth-4 Phosphate, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropanolamine Lanolate, Isopropylamine Dodecyl Betaine Benzene sulfonate, isostearamidopropyl amine oxide, isostearamidopropyl betaine, isostearamidopropyl morpholine oxide, isosteareth-8, isosteareth-16, isosteareth-22, isosteareth-25, isosteareth-50, isostearic acid, isostearoyl hydrolyzed collagen, jojoba oil PEG-150 ester, jojoba wax PEG-80 ester, jojoba wax PEG-120 ester, laneth-20, laneth-25, laneth-40,

[0026] Laneth-50, Laneth-60, Laneth-75, Lanolinic Acid, Lauramidopropylamine Oxide, Lauramidopropyl Betaine, Lauramidopropyl Hydroxysultaine, Lauramine Oxide, Lauraminopropionic Acid, Laurdimonium Hydroxypropyl Decyl Glucoside Chloride, Laurdimonium Hydroxypropyl Lauryl Glucoside Chloride, Laureth-16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-3 8, Laureth-40, Laureth-3 Carboxylic Acid, Laureth-4 Carboxylic Acid, Laureth-5 Carboxylic Acid, Laureth-6 Carboxylic Acid, Laureth-8 Carboxylic Acid, Laureth-10 Carboxylic Acid, Laureth-11 Carboxylic Acid, Laureth-12 Carboxylic Acid, Laureth-13 Carboxylic Acid, Laureth-14 Carboxylic Acid, Laureth-17 Carboxylic Acid, Laureth-6 Citric Acid, Laureth-7 Citric Acid, Laureth-1 Phosphate, Laureth-2 Phosphate, Laureth-3 Phosphate, Laureth-4 Phosphate, Laureth- Laureth-7 Phosphate, Laureth-8 Phosphate, Laureth-7 Tartaric Acid, Lauryl Acid, Lauriminobispropanediol, Lauriminodipropionic Acid, Lauroamphodipropionic Acid, Lauroyl Beta-Alanine, Lauroyl Collagen Amino Acids, Lauroyl Ethyltrimonium Methosulfate, Lauroyl Hydrolyzed Collagen, Lauroyl Hydrolyzed Elastin, Lauroyl Methylglucamide, Lauroyl Sarcosine, Lauroyl Silk Amino Acids, Lauryl Betaine, Lauryl Dimethicone / Polyglycerin-3 Crosspolymer, Lauryldimonium Hydroxypropyl Cocoglucoside Chloride, Lauryl Glucoside, Lauryl Glucoside Hydroxypropyltrimonium Chloride, Lauryl Glycol Hydroxypropyl Ether, Lauryl Hydroxysultaine, Lauryl Malamide, Lauryl Methylglucamide, Lauryl / Myristyl Glycol Hydroxypropyl Ether, Lauryl / Myristyl Wheat Bran / Straw Glycoside Wheat Bran / Straw Glycosides), Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Pyrrolidone, Lauryl Sultaine, Linoleic Acid, Linolenic Acid, Flaxseed Acid, Lysine Cocoate,

[0027] Macadamia Seed Oil Glycereth-8 Esters, Magnesium Coceth Sulfate, Magnesium Coco Sulfate, Magnesium Isododecylbenzene Sulfonate, Magnesium Laureth-11 Carboxylate, Magnesium Laureth Sulfate, Magnesium Laureth-5 Sulfate, Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfonate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myreth Sulfate, Magnesium Oleth Sulfate, Magnesium / TEA-Cocosulfate, Manicouagan Clay, MEA-Cocoate, MEA-Laureth-6 Carboxylate, MEA-Laureth Sulfate, MEA-Lauryl Sulfate, MEA PPG-6 Laureth-7 Carboxylate, MEA-PPG-8 Steareth-7 Carboxylate, MEA-Undecylenate, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, Methoxy PEG-450 Amido Glutaroyl Succinimide, Methoxy PEG-450 Amido Hydroxysuccinimidyl Succinamate, Methoxy PEG-450 Maleimide, Methylmorpholine Oxide, Milk Amidopropylamine Oxide, Milk Amidopropyl Betaine, Mincamidopropylamine Oxide, Mincamidopropyl Betaine, MIPA C12-15 Pareth Sulfate, MIPA Dodecyl Benzene Sulfonate, MIPA Laureth Sulfate, MIPA Lauryl Sulfate, Mixed Isopropanolamine Lanolate lsopropanolaminesLanolate), mixed isopropanolamine lauryl sulfate, mixed isopropanolamine myristate, morpholine oleate, morpholine stearate, myreth-3 carboxylic acid, myreth-5 carboxylic acid, myristalkonium chloride, myristamidopropylamine oxide, myristamidopropyl betaine, myristamidopropyl dimethylamine phosphate, myristamidopropyl hydroxysultaine, myristamidopropyl PG-dimonium chloride phosphate, myristamido oxide, myristaminopropionic acid, myristic acid, myristoyl ethyltrimonium methosulfate, myristoyl glutamic acid,

[0028] Myristoyl Hydrolyzed Collagen, Myristoyl Sarcosine, Myristyl Betaine, Myristyl / Cetylamine Oxide, Myristyldimonium Hydroxypropyl Cocoglucoside Chloride, Myristyl Glucoside, Myristyl Phosphate, Nonoxynol-20, Nonoxynol-23, Nonoxynol-25, Nonoxynol-30, Nonoxynol-35, Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 Carboxylic Acid, Nonoxynol-8 Carboxylic Acid, Nonoxynol-10 Carboxylic Acid, Nonoxynol-3 Phosphate, Nonoki Cinol-4 phosphate, Nonoxynol-6 phosphate, Nonoxynol-9 phosphate, Nonoxynol-10 phosphate, Nonylnonoxynol-30, Nonylnonoxynol-49, Nonylnonoxynol-100, Nonylnonoxynol-150, Nonylnonoxynol-7 phosphate, Nonylnonoxynol-8 phosphate, Nonylnonoxynol-9 phosphate, Nonylnonoxynol-10 phosphate, Nonylnonoxynol-11 phosphate, Nonylnonoxynol-15 phosphate, Nonylnonoxynol-24 phosphate, Oatamidopropyl betaine Betaine), Octoxynol-16, Octoxynol-25, Octoxynol-30, Octoxynol-33, Octoxynol-40, Octoxynol-70, Octoxynol-20 Carboxylic Acid, Octyldodeceth-20, Octyldodeceth-25, Octyldodeceth-30, Oleamidopropylamine Oxide, Oleamidopropyl Betaine, Oleamidopropyl Hydroxysultaine, Oleamine Oxide, Oleic Acid, Oleoyl Additive Hydrolyzed Collagen, Oleoyl Sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleth-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Olivamidopropylamine Oxide, Olivamidopropyl Betaine, Oliv Acid, Olivoyl Hydrolyzed Wheat Protein, Ophiopogon Extract StearateStearate), Ozonized Oleth-10, Ozonized PEG-10 Oleate, Ozonized PEG-14 Oleate, Ozonized Polysorbate 80, Palm Acid, Palmamidopropyl Betaine,

[0029] Palmitic Acid, Palmitoyl Collagen Amino Acid, Palmitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Milk Protein, Palmitoyl Hydrolyzed Wheat Protein, Palmitoyl Keratin Amino Acid, Palmitoyl Oligopeptide, Palmitoyl Silk Amino Acid, Palm Kernel Acid, Palmitoyl Amino ... In, Peach Kernel Oil Glycereth-8 Esters, Peanut Acid, PEG-10 Castor Oil, PEG-40 Castor Oil, PEG-44 Castor Oil, PEG-50 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibenzylglycerin, PEG-100 Castor Oil, PEG-100 Cocamide ... Henate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl SoyateSoyate), PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tallowate, PEG-80 Glyceryl Tallowate, PEG-82 Glyceryl Tallowate, PEG-130 Glyceryl Tallowate, PEG-200 Glyceryl Tallowate, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil, PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin,

[0030] PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glycerides (PEG-70 Mango)Glycerides), PEG-20 Mannitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanate, PEG-30 Oleamine, PEG-20 Oleate, PEG-23 Oleate, PEG-32 Oleate, PEG-36 Oleate, PEG-75 Oleate, PEG-150 Oleate, PEG-20 Palmitate, PEG-150 Polyglyceryl-2 Tristearate, PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG -10 / 30 copolymer, PEG / PPG-10 / 65 copolymer, PEG / PPG-12 / 35 copolymer, PEG / PPG-16 / 17 copolymer, PEG / PPG-20 / 9 copolymer, PEG / PPG-20 / 20 copolymer, PEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, PEG / PPG-28 / 30 copolymer mer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer, PEG / PPG-300 / 55 copolymer,

[0031] PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG / PPG-4 / 2 Propylheptyl Ether, PEG / PPG-6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol (PEG-5 Rapeseed Sterol)Sterol), PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Glycerides, PEG-75 Shea Glycerides, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearamide Carboxylic Acid, PEG -9 Stearamide Carboxylic Acid, PEG-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG-120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallate, PEG-50 Tallowamide, PEG-2 Tallowamide DEA, PEG-20 Tallowate, PEG-66 Trihydroxystearin, PEG-200 Trihydroxystearin, PEG-60 Camellia Glycerides (PEG-60 Tsubakiate Glycerides), Pelargonic Acid, Pentadoxynol-200, Phenes-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288,

[0032] Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octacaprylate Sononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomaderis Melahou Flower / Leaf Extract Kumerahou Flower / Leaf Extract, Poria Cocos Extract, Potassium Abithoyl Hydrolyzed Collagen, Potassium Babassuate, Potassium Behenate, Potassium C9-15 Alkyl Phosphate, Potassium C11-15 Alkyl Phosphate, Potassium C12-13 Alkyl Phosphate, Potassium C12-14 Alkyl Phosphate, Potassium Caprate, Potassium Capryloyl Glutamate, Potassium Capryloyl Hydrolyzed Rice Protein, Potassium Castorate, Potassium CocoateCocoate), potassium cocoyl glutamate, potassium cocoyl glycinate, potassium cocoyl hydrolyzed caseinate, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin, potassium cocoyl hydrolyzed oat protein, potassium cocoyl hydrolyzed potato protein, potassium cocoyl hydrolyzed rice bran protein, potassium cocoyl hydrolyzed rice protein, potassium cocoyl hydrolyzed silk, potassium cocoyl hydrolyzed soy protein, potassium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed yeast protein,

[0033] Potassium Cocoyl PCA, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Cornate, Potassium Cyclocarboxypropyloleate, Potassium Dihydroxyethyl Cocamine Oxide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecylbenzene Sulfonate, Potassium Hempseedate, Potassium Hydrogenated Coconut Acid Cocoate), potassium hydrogenated palmate, potassium hydrogenated tallowate, potassium hydroxystearate, potassium isostearate, potassium lanolate, potassium laurate, potassium laureth-3 carboxylate, potassium laureth-4 carboxylate, potassium laureth-5 carboxylate, potassium laureth-6 carboxylate, potassium laureth-10 carboxylate, potassium laureth phosphate, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, potassium lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed pea protein, potassium lauroyl hydrolyzed soy protein, potassium lauroyl PCA, potassium lauroyl pea amino acid, lauroyl Potassium Sarcosinate, Potassium Lauroyl Silk Amino Acids, Potassium Lauroyl Wheat Amino Acids, Potassium Lauryl Phosphate, Potassium Lauryl Sulfate, Potassium Linoleate, Potassium Metaphosphate, Potassium Methyl Cocoyl Taurate, Potassium Myristate, Potassium Myristoyl Glutamate, Potassium Myristoyl Hydrolyzed Collagen, Potassium Octoxynol-12 Phosphate, Potassium Oleate, Potassium Oleoyl Hydrolyzed Collagen, Potassium Olivoyl Hydrolyzed Oat Protein, Potassium Olivoyl Hydrolyzed Wheat Protein, Potassium Olivoyl / Lauroyl Wheat Amino Acids, Potassium Olivoyl PCA, Potassium PalmitatePalmate), Potassium Palmitate, Potassium Palmitoyl Hydrolyzed Corn Protein, Potassium Palmitoyl Hydrolyzed Oat Protein, Potassium Palmitoyl Hydrolyzed Rice Protein, Potassium Palmitoyl Hydrolyzed Sweet Almond Protein,

[0034] Potassium Palmitoyl Hydrolyzed Wheat Protein, Potassium Palm Kernelate, Potassium Peanutate, Potassium Rapeseed Oil Fatty Acid, Potassium Ricinoleate, Potassium Safflowerate, Potassium Soyate, Potassium Stearate, Potassium Stearoyl Hydrolyzed Collagen, Potassium Tartarate Tallate), potassium tallowate, potassium taurine laurate, potassium trideceth-3 carboxylate, potassium trideceth-4 carboxylate, potassium trideceth-7 carboxylate, potassium trideceth-15 carboxylate, potassium trideceth-19 carboxylate, potassium trideceth-6 phosphate, potassium trideceth-7 phosphate, potassium camellia acid, potassium undecylenate, potassium undecylenoyl hydrolyzed collagen, potassium undecylenoyl hydrolyzed rice protein, PPG-30-buteth-30, PPG-36-buteth-36, PPG-38-buteth-37, PPG-30-capryleth-4 phosphate, PPG-10 cetyl ether phosphate, PPG-2 C9-11 Pareth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylic Acid, PPG-30 Ethylhexeth-4 Phosphate, PPG-20 Glycereth-30, PPG-2 Hydroxyethyl Coco / Isostearamide, PPG-2-Isodeceth-8, PPG-2-Isodeceth-10, PPG-2-Isodeceth-18, PPG-2-Isodeceth-25, PPG-4-Isodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Oil Fatty Acid, Rice Bran Acid, Rice Oil Glycereth-8 Ester, Ricinoleamidopropyl Betaine, Ricinoleic Acid, Ricinoleth-40, Safflower Acid, Sapindus oafensis Oahuensis Fruit Extract, Soapwort (Saponaria Officinalis) Root Powder, Saponin, Soap-K, Soap-Na / K, Soap BaseSoji), Soap Base-K, Sesame Oil Glycereth-8 Ester, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butter Amidopropyl Betaine, Shea Butter Glycereth-8 Ester, Sodium Arachidate, Sodium Argan Amphodiacetate, Sodium Astrocaryum Murumuruate, Sodium Avocado Acid, Sodium Babassu Amphoacetate, Sodium Babassu Acid, Sodium Babassu Sulfate, Sodium Behenate,

[0035] Sodium Bisglycolic Acid Sulfosuccinate, Sodium Bishydroxyethylglycinate Cocoglucoside Crosspolymer, Sodium Bishydroxyethylglycinate Lauryl Glucoside Crosspolymer, Sodium Boramide Propyl PG-Dimonium Chloride Phosphate, Sodium Butoxynol-12 Sulfate, Sodium Butyl Glucoside Hydroxypropyl Phosphate, Sodium C13-17 Alkanesulfonate, Sodium C14-18 Alkanesulfonate, Sodium C12-15 Alkoxypropyliminodipropionate, Sodium C10-16 Alkyl Sulfate, Sodium C11-15 Alkyl Sulfate, Sodium C12-13 Alkyl Sulfate, Sodium C12-15 Alkyl Sulfate, Sodium C12-18 Alkyl Sulfate, Sodium C16-20 Alkyl Sulfate, Sodium C9-22 Alkyl Sec Sulfonate, Sodium C14-17 Alkyl Sec Sulfonate, Sodium Caprate, Sodium Caproamphoacetate, Capric Acid Sodium loamphohydroxypropylsulfonate, Sodium caproamphopropionate, Sodium caproyl methyl taurate, Sodium caprylate, Sodium capryleth-2 carboxylate, Sodium capryleth-9 carboxylate, Sodium capryloamphoacetate, Sodium capryloamphohydroxypropylsulfonate, Sodium capryloamphopropionate, Sodium capryloyl glutamate, Sodium capryloyl hydrolyzed wheat protein, Sodium caprylyl PG-sulfonate, Sodium caprylyl sulfonate, Sodium castor oil, Sodium ceteareth-13 carboxylate, Sodium cetearyl sulfate, Sodium ceteth-13 carboxylate, Sodium cetyl sulfate, Sodium cocamidopropyl PG-dimonium chloride phosphate, Sodium cocaminopropionate, Sodium coceth sulfate, Sodium coceth-30 sulfate, Sodium cocoa butter amphoacetate, Sodium cocoa butterate Cocoa Butterate, Sodium Cocoamphoacetate, Sodium Cocoamphohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cocoate, Sodium Coco / Babassu / Andiroba SulfateSulfate), Sodium Coco / Babasu Sulfate, Sodium Coco Glucoside Hydroxypropyl Phosphate,

[0036] Sodium Coco Glucoside Hydroxypropyl Sulfonate, Sodium Coco Glucoside Tartrate, Sodium Coco Glyceryl Ether Sulfonate, Sodium Coco / Hydrogenated Tallow Sulfate, Sodium Cocoiminodiacetate, Sodium Coco Monoglyceride Sulfate, Sodium Coco Monoglyceride Sulfonate, Sodium Coco PG-Dimonium Chloride Phosphate, Sodium Coco Sulfate, Sodium Coco Sulfoacetate, Sodium Cocoyl Alaninate, Sodium Cocoyl Amino Acids, Sodium Cocoyl Collagen Amino Acids, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutamate Glutaminate, Sodium Cocoyl Glycinate, Sodium Cocoyl / Hydrogenated Tallow Glutamate, Sodium Cocoyl Hydrolyzed Collagen, Sodium Cocoyl Hydrolyzed Keratin, Sodium Cocoyl Hydrolyzed Rice Protein, Sodium Cocoyl Hydrolyzed Silk, Sodium Cocoyl Hydrolyzed Soy Protein, Sodium Cocoyl Hydrolyzed Sweet Almond Protein, Sodium Cocoyl Hydrolyzed Wheat Protein, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Isethionate, Sodium Cocoyl Methylaminopropionate, Sodium Cocoyl Oat Amino Acids, Sodium Cocoyl / Palmoyl / Sunfloweroyl Glutamate Glutamate), Sodium Cocoyl Proline, Sodium Cocoyl Sarcosinate, Sodium Cocoyl Taurate, Sodium Cocoyl Threonate, Sodium Cocoyl Wheat Amino Acids, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium Corn Amphopropionate, Sodium Cottonseed Amphoacetate (SodiumCottonseedamphoacetate), C13-15 Pareth-8 Sodium Butyl Phosphate, C9-11 Pareth-6 Sodium Carboxylate, C11-15 Pareth-7 Sodium Carboxylate, C12-13 Pareth-5 Sodium Carboxylate, C12-13 Pareth-8 Sodium Carboxylate, C12-13 Pareth-12 Sodium Carboxylate, C12-15 Pareth-6 Sodium Carboxylate, C12-15 Pareth-7 Sodium Carboxylate, C12-15 Pareth-8 Sodium Carboxylate, C14-15 Pareth-8 Sodium Carboxylate, C12-14Sec-Pareth-8 Sodium Carboxylate,

[0037] C14-15 Pareth-PG Sodium Sulfonate, C12-13 Pareth-2 Sodium Phosphate, C13-15 Pareth-8 Sodium Phosphate, C9-15 Pareth-3 Sodium Sulfate, C10-15 Pareth Sodium Sulfate, C10-16 Pareth-2 Sodium Sulfate, C12-13 Pareth Sodium Sulfate, C12-15 Pareth Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfate, C13-15 Pareth-3 Sodium Sulfate, C12-14 Sec-Pareth-3 Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfonate, C12-15 Pareth-7 Sodium Sulfonate, C12-15 Pareth-15 Sodium Sulfonate, Sodium Deceth-2 Carboxylate, Sodium Deceth Sulfate, Sodium Decyl Benzene Sulfonate, Sodium Decyl Glucoside Hydroxypropyl Phosphate, Sodium Decyl Glucoside Hydroxypropyl Sulfonate, Sodium Dilaureth-7 Citrate, Sodium Dilaureth-10 Phosphate, Sodium Dilinoleate, Sodium Dilaureth-8 Phosphate, Sodium Dodecyl Benzene Sulfonate, Sodium Ethyl 2-Sulfolaurate, Sodium Glyceryl Oleate Phosphate (Sodium Glyceryl Oleate Phosphate, Grape Seed Amidopropyl PG-Dimonium Chloride Phosphate, Grape Seed Sodium Amphoacetate, Grape Seed Sodium Amphoacetate, Sodium Grapeseedate, Hemp Seed Sodium Amphoacetate, Sodium Hexace-4 Carboxylate, Sodium Hydrogenated Cocoate, Sodium Hydrogenated Cocoyl Methyl Isethionate, Sodium Hydrogenated Palm Oil Fatty Acid, Sodium Hydrogenated Tallowate, Sodium Hydrogenated Tallowyl Glutamate, Sodium Hydroxylauryldimonium Ethyl Phosphate, Sodium Hydroxypropyl Palm Kernel Acid Sulfonate, Sodium Hydroxypropyl Phosphate Decyl Glucoside Crosspolymer, Sodium Hydroxypropyl Phosphate Lauryl Glucoside Crosspolymer, Sodium Hydroxypropyl Sulfonate Coco Glucoside Crosspolymer, Sodium Hydroxypropyl Sulfonate Decyl Glucoside Crosspolymer, Sodium Hydroxypropyl Sulfonate Lauryl Glucoside Crosspolymer,

[0038] Sodium Hydroxystearate, Sodium Isostearate, Sodium Isosteareth-6 Carboxylate, Sodium Isosteareth-11 Carboxylate, Sodium Isostearoamphoacetate, Sodium Isostearoamphopropionate, Sodium N-Isostearoylmethyltaurate, Sodium Lanosulfate, Sodium Lanolinate, Sodium Lardate, Sodium Lauramide Diacetate, Sodium Lauraminopropionate, Sodium Laurate, Sodium Laureth-3 Carboxylate, Sodium Laureth-4 Carboxylate, Sodium Laureth-5 Carboxylate, Sodium Laureth-6 Carboxylate, Sodium Laureth-8 Carboxylate, Sodium Laureth-11 Carboxylate, Sodium Laureth-12 Carboxylate, Sodium Laureth-13 Carboxylate, Sodium Laureth-14 Carboxylate, Sodium Laureth-16 Carboxylate, Sodium Laureth-17 Carboxylate, Sodium Laureth Sulfate, Sodium Laureth-5 Sulfate, Sodium Laureth-7 Sulfate, Sodium Laureth-8 Sulfate, Sodium Laureth-12 Sulfate, Sodium Laureth-40 Sulfate Sodium Laureth-7 Tartrate, Sodium Laurylaminodipropionate, Sodium Lauroamphoacetate, Sodium Lauroamphohydroxypropylsulfonate, Sodium LauroamphoPG-Acetate Phosphate, Sodium Lauroamphopropionate, Sodium Lauroyl Aspartate, Sodium Lauroyl Collagen Amino Acids, Sodium Lauroyl Glycine Propionate, Sodium Lauroyl Hydrolyzed Collagen, Sodium Lauroyl Hydrolyzed Silk, Sodium Lauroyl Hydroxypropylsulfonate, Sodium Lauroyl Iseethionate, Sodium Lauroyl Methylaminopropionate, Sodium Lauroyl Methylisethionate, Sodium Lauroyl Millet Amino AcidsAcids), Sodium Lauroyl / Myristoyl Aspartate, Sodium Lauroyl Oat Amino Acid, Sodium Lauroyl Sarcosinate, Sodium Lauroyl Silk Amino Acid, Sodium Lauroyl Taurate, Sodium Lauroyl Wheat Amino Acid, Sodium Lauryl Diethylenediaminoglycinate, Sodium Lauryl Glucose Carboxylate, Sodium Lauryl Glucoside Hydroxypropyl Phosphate,

[0039] Sodium Lauryl Glucoside Hydroxypropyl Sulfonate, Sodium Lauryl Glycol Carboxylate, Sodium Lauryl Hydroxyacetamide Sulfate, Sodium Lauryl Phosphate, Sodium Lauryl Sulfate, Sodium Lauryl Sulfoacetate, Sodium Linoleate, Sodium Macadamiaseedate, Sodium Mango Amphoacetate, Sodium Mango SeedateMangoseedate), Sodium / MEA Laureth-2 Sulfosuccinate, Sodium Methoxy PPG-2 Acetate, Sodium Methyl Cocoyl Taurate, Sodium Methyl Lauroyl Taurate, Sodium Methyl Myristoyl Taurate, Sodium Methyl Oleyl Taurate, Sodium Methyl Palmitoyl Taurate, Sodium Methyl Stearoyl Taurate, Sodium Methyl 2-Sulfolaurate, Sodium Methyl 2-Sulfopalmitate, Sodium Methyl Taurate Isopalmitamide, Sodium Methyl Taurate Cocoyl Methyl Taurate, Sodium Myreth Sulfate, Sodium Myristate, Sodium Myristamphoacetate, Sodium Myristoyl Glutamate, Sodium Myristoyl Hydrolyzed Collagen, Sodium Myristoyl Isethionate, Sodium Myristoyl Sarcosinate, Sodium Myristyl Sulfate, Sodium Nonoxynol-6 Phosphate, Sodium Nonoxynol-9 Phosphate, Sodium Nonoxynol-1 Sulfate Sodium nonoxynol-3 sulfate, sodium nonoxynol-4 sulfate, sodium nonoxynol-6 sulfate, sodium nonoxynol-8 sulfate, sodium nonoxynol-10 sulfate, sodium nonoxynol-25 sulfate, sodium octoxynol-2 ethanesulfonate, sodium octoxynol-2 sulfate, sodium octoxynol-6 sulfate, sodium octoxynol-9 sulfate, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropylsulfonate, sodium oleoamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl isethionate, sodium oleth sulfate, sodium oleyl methyl isethionate, sodium oleyl sulfate, sodium oliveamphoacetate, sodium olive fatty acid, sodium olivoyl glutamate, sodium palmamphoacetate, sodium palm fatty acid, sodium palm glyceride sulfonate,

[0040] Sodium Palmitate, Sodium Palmitoyl Hydrolyzed Collagen, Sodium Palmitoyl Hydrolyzed Wheat Protein, Sodium Palmitoyl Sarcosinate, Sodium Palm Kernelate, Sodium Palm Carnelyl Isethionate, Sodium Palmoyl Glutamate, Sodium Passiflora Edulis Seedate, Sodium Peanut Amphoacetate, Sodium Peanut Fatty Acid Peanutate), PEG-6 Sodium Cocamide Carboxylate, PEG-8 Sodium Cocamide Carboxylate, PEG-4 Sodium Cocamide Sulfate, PEG-3 Sodium Lauramide Carboxylate, PEG-4 Sodium Lauramide Carboxylate, PEG-8 Sodium Palm Glyceride Carboxylate, Sodium Pentaerythrityl Hydroxypropylminodiacetate Dendrimer, Sodium Propoxy PPG-2 Acetate, Sodium Rapeseed Oil Fatty Acid, Sodium Rice Bran Amphoacetate, Sodium Ricinoleate, Sodium Ricinoleoamphoacetate, Sodium Rosehip Amphoacetate, Sodium Rosinate, Sodium Safflower Fatty Acid, Sodium Saffloweroyl Hydrolyzed Soy Protein, Sodium Sesame Seed Oil Fatty Acid, Sodium SesamphoacetateSesamphoacetate, Shea Butter Sodium Amphoacetate, Sodium Soybean Oil Fatty Acid, Sodium Soy Hydrolyzed Collagen, Sodium Stearate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Stearoyl Caseinate, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl Hydrolyzed Silk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Lactalbumin, Sodium Stearoyl Methylisethionate, Sodium Stearoyl Oat Protein, Sodium Stearoyl Pea Protein, Sodium Stearoyl Soy Protein, Sodium Stearyl Dimethylglycine, Sodium Stearyl Sulfate, Sunflower Seed Sodium Amphoacetate, Sodium Surfactin, Sweet Almond Sodium Amphoacetate, Sodium Sweet Almond Fatty Acid (Sodium Sweet Almondate, Sodium Tallamphopropionate, Sodium Tallate,

[0041] Sodium Tallow Amphoacetate, Sodium Tallowate, Sodium Tallow Sulfate, Sodium Tamanuseedate, Sodium Taurate, Sodium Methyl Cocoyl Taurate, Sodium Taurate Laurate, Sodium / TEA-Lauroyl Collagen Amino Acids, Sodium / TEA-Lauroyl Hydrolyzed Collagen, Sodium / TEA-Lauroyl Hydrolyzed Keratin, Sodium / TEA-Lauroyl Keratin Amino Acids, Sodium / TEA-Undecylenoyl Collagen Amino Acids, Sodium / TEA-Undecylenoyl Hydrolyzed Collagen, Sodium / TEA-Undecylenoyl Hydrolyzed Corn Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Soy Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Wheat Protein, Sodium Theobroma Grandiflorum Seed Acid Seedate), Sodium Trideceth-3 Carboxylate, Sodium Trideceth-4 Carboxylate, Sodium Trideceth-6 Carboxylate, Sodium Trideceth-7 Carboxylate, Sodium Trideceth-8 Carboxylate, Sodium Trideceth-12 Carboxylate, Sodium Trideceth-15 Carboxylate, Sodium Trideceth-19 Carboxylate, Sodium Trideceth Sulfate, Sodium Tridecylbenzenesulfonate, Sodium Tridecyl Sulfate, Sodium Trimethylolpropane Hydroxypropyliminodiacetate Dendrimer, Sodium Undeceth-5 Carboxylate, Sodium Undecylenate, Sodium Undecylenoamphoacetate, Sodium Undecylenoamphopropionate, Sodium Undecylenoyl Glutamate, Sodium Wheat Germ AmphoacetateGermamphoacetate), Sorbeth-160 Tristearate, Soy Acid, Soyamidopropylamine Oxide, Soyamidopropyl Betaine, Soybean Oil Glycereth-8 Ester, Stearamidopropylamine Oxide, Stearamidpropyl Betaine, Stearamine Oxide, Steareth-15, Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyltrimonium Chloride, Stearoyl Glutamic Acid,

[0042] Stearoyl Sarcosine, Stearyl Betaine, Stearyldimonium Hydroxypropyl Butyl Glucoside Chloride, Stearyldimonium Hydroxypropyl Decyl Glucoside Chloride, Stearyldimonium Hydroxypropyl Lauryl Glucoside Chloride, Sulfated Castor Oil, Sulfated Coconut Oil, Sulfated Glyceryl Oleate, Sulfated Olive Oil, Sulfated Peanut Oil, Sunflower Amide MEA, Sunflower Seed Acid, Sunflower Seed Amide Propyl Hydroxyethyl Dimonium Chloride, Sunflower Seed Oil Glycereth-8 Ester, Tall Oil Acid, Tallow Acid, Tallowamidopropylamine oxide, tallowamidopropyl betaine, tallowamidopropyl hydroxysultaine, tallowamine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallowyl ethyl glucoside, TEA-abietyl hydrolyzed collagen, TEA-C12-14 alkyl phosphate, TEA-C10-15 alkyl sulfate, TEA-C11-15 alkyl sulfate, TEA-C12-13 alkyl sulfate, TEA-C12-14 alkyl sulfate, TEA-C12-15 alkyl sulfate, T EA-C14-17 Alkyl Sec Sulfonate, TEA-Canolate, TEA-Cocamide Diacetate, TEA-Cocoate, TEA-Coco-Sulfate, TEA-Cocoyl Alaninate, TEA-Cocoyl Glutamate, TEA-Cocoyl Glutaminate, TEA-Cocoyl Glycinate, TEA-Cocoyl Hydrolyzed Collagen, TEA-Cocoyl Hydrolyzed Soy Protein, TEA-Cocoyl Sarcosinate, TEA-Dimethicone PEG-7 Phosphate, TEA-Dodecyl Benzene Sulfonate, TEA-Hydrogenated Cocoyl ate, TEA-hydrogenated thallusyl glutamate, TEA-isostearate, TEA-isostearoyl hydrolyzed collagen, TEA-lauraminopropionate, TEA-laurate, TEA-laurate / myristate, TEA-laureth sulfate, TEA-lauroyl collagen amino acid, TEA-lauroyl glutamate, TEA-lauroyl hydrolyzed collagen, TEA-lauroyl keratin amino acid, TEA-lauroyl methylaminopropionate, TEA-lauroyl / myristoyl aspartate, TEA-lauroyl sarcosinate,TEA-lauryl phosphate, TEA-lauryl sulfate, TEA-myristaminopropionate, TEA-myristate, TEA-myristoyl hydrolyzed collagen,

[0043] TEA-Oleate, TEA-Oleoyl Hydrolyzed Collagen, TEA-Oleoyl Sarcosinate, TEA-Oleyl Sulfate, TEA-Palmitate, TEA-Palm Kernel Sarcosinate, TEA-PEG-3 Cocamide Sulfate, TEA-Rosinate, TEA-Stearate, TEA-Tallate, TEA-Tridecylbenzenesulfonate, TEA-Undecylenate, TEA-Undecylenoyl Hydrolyzed Collagen, Tetramethyldecynediol, Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinate Sulfosuccinamate, TIPA-Laureth Sulfate, TIPA-Lauryl Sulfate, TIPA-Myristate, TIPA-Stearate, Tocopherol Phosphate, Trehalose Undecylenoate, TM-C12-15 Pareth-2 Phosphate, TM-C12-15 Pareth-6 Phosphate, TM-C12-15 Pareth-8 Phosphate, TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Trideceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate, Tridecyl Benzene Sulfonic Acid, Trilaureth-9 Citric Acid, Trimethylolpropane Hydroxypropyl Bis-Hydroxyethylamine Dendrimer, Trisodium Lauroampho PG Acetate Chloride Phosphate PG-Acetate Chloride Phosphate, Undecanoic Acid, Undeceth-5 Carboxylic Acid, Undecylenamidopropylamine Oxide, Undecylenamidopropyl Betaine, Undecylenic Acid, Undecylenoyl Collagen Amino Acid, Undecylenoyl Glycine, Undecylenoyl Hydrolyzed Collagen, Undecylenoyl Wheat Amino Acid, Undecyl Glucoside, Wheat Germ Acid, Wheat Germ Aminopropylamine Oxide, Wheat Germ Aminopropyl Betaine, Yucca Schidigera Leaf / Root / Stem Extract, Yucca Schidigera Stem Extract, Zinc Coceth Sulfate and Zinc Coco Sulfate.

[0044] Preferred are one or more compounds selected from the group consisting of sodium laureth sulfate, cocamidopropyl betaine, sodium cocoamphoacetate, cocoglucoside and ammonium lauryl sulfosuccinate.

[0045] The content of the surfactant in the preparation may be 0.1 to 10% by weight, preferably 0.5 to 5% by weight, based on the preparation.

[0046] oil body Suitable oil bodies which are components of O / W emulsions are, for example, Guerbet alcohols, which are based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms; linear C6-C 22 Fatty acids and straight or branched C6-C 22 Esters with fatty alcohols or branched C6-C 13 Carboxylic acids and linear or branched C6-C 22Esters with fatty alcohols, for example myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate allyl, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate. Also suitable are linear C6-C 22 Esters of fatty acids with branched alcohols, especially 2-ethylhexanol, C 18 -C 38 Alkyl hydroxy carboxylic acids and linear or branched C6-C 22 Esters with fatty alcohols, in particular dioctyl malate, esters of linear and / or branched fatty acids with polyhydric alcohols (e.g. propylene glycol, dimer diol, trimer triol) and / or Guerbet alcohols, C6-C 10 Triglycerides based on fatty acids, C6-C 18 Liquid mono / di / triglyceride mixture based on fatty acids, C6-C 22 Esters of fatty alcohols and / or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, C2-C 12Esters of dicarboxylic acids with linear or branched alcohols having 1-22 carbon atoms or polyols having 2-10 carbon atoms and 2-6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C6-C 22 Fatty alcohol carbonates, such as dicaprylyl carbonate (Cetiol® CC), Guerbet carbonates based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, benzoic acid and linear and / or branched C6-C 22 esters with alcohols (e.g. Finsolv® TN), linear or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as dicaprylyl ether (Cetiol® OE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicone, silicone methicone grades, etc.) and / or aliphatic or naphthenic hydrocarbons, such as squalane, squalene or dialkylcyclohexanes.

[0047] emulsifier Other non-ionic or cationic surfactants may also be added to the preparation as emulsifiers, including, for example: 2-30 moles of ethylene oxide and / or 0-5 moles of propylene oxide, 8-22 Fatty alcohols, C 12-22 Products of addition to fatty acids and to alkylphenols containing 8 to 15 carbon atoms in the alkyl group C, the addition products of 1-30 mol of ethylene oxide to glycerol 12 / 18 Fatty acid monoesters and diesters Glycerol mono- and diesters, sorbitan mono- and diesters of saturated and unsaturated fatty acids containing 6 to 22 carbon atoms, and their ethylene oxide addition products Addition products of 15 to 60 moles of ethylene oxide onto castor oil and / or hydrogenated castor oil Polyol esters, in particular polyglycerol esters, such as polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimerate isostearate. Mixtures of several compounds from these classes are also suitable. Addition products of 2 to 15 moles of ethylene oxide onto castor oil and / or hydrogenated castor oil Linear, branched, unsaturated or saturated C 6 / 22 Partial esters based on fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol dipentaerythritol, sugar alcohols (e.g. sorbitol), alkyl glucosides (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g. cellulose) Mono-, di- and trialkyl phosphates, and mono-, di- and / or tri-PEG-alkyl phosphates, and their salts Wool wax alcohol Polysiloxane / polyalkylpolyether copolymers and corresponding derivatives Pentaerythritol, mixed esters of fatty acids, citric acid and fatty alcohols and / or C 6-22 Mixed esters of fatty acids, methylglucose and a polyol, preferably glycerol or polyglycerol polyalkylene glycols, and Glycerol carbonate.

[0048] The addition products of ethylene oxide and / or propylene oxide onto fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or onto castor oil are known products available commercially. They are homolog mixtures in which the average degree of alkoxylation corresponds to the ratio of the amounts of ethylene oxide and / or propylene oxide to the substrate with which the addition reaction is carried out. The addition products of ethylene oxide onto glycerol, C12 / 18 Fatty acid mono- and diesters are known as lipid layer enhancers for cosmetic preparations. Preferred emulsifiers are described in detail below.

[0049] Partial glycerides Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, linolenic acid monoglyceride, linolenic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid monoglyceride, malic acid diglyceride, and technical mixtures thereof which may contain small amounts of triglycerides from the manufacturing process. Also suitable are addition products of 1 to 30, preferably 5 to 10, moles of ethylene oxide to the aforementioned partial glycerides.

[0050] Sorbitan Esters Suitable sorbitan esters include sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquierucate, sorbitan diricinoleate, sorbitan triricinoleate, sorbitan Monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and technical mixtures thereof. Also suitable are addition products of 1 to 30, preferably 5 to 10, moles of ethylene oxide to the aforementioned sorbitan esters.

[0051] Polyglycerol Ester Representative examples of suitable polyglycerol esters are Polyglyceryl-2 Dipolyhydroxystearate (Dehymuls® PGPH), Polyglycerin-3-Diisostearate (Lameform® TGI), Polyglyceryl-4 Isostearate (Isolan® GI 34), Polyglyceryl-3 Oleate, Diisostearoyl Polyglyceryl-3 Diisostearate (Isolan® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care® 450), Polyglyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether (Chimexane® NL), Polyglyceryl-3 Distearate (Cremophor® GS 32) and polyglyceryl polyricinoleate (Admul® WOL 1403), polyglyceryl dimerate isostearate and mixtures thereof. Examples of other suitable polyol esters are the mono-, di- and triesters of trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid, etc., optionally reacted with 1 to 30 moles of ethylene oxide.

[0052] Tetraalkylammonium salts Cationic active surfactants contain a hydrophobic polymeric group which dissociates in aqueous solution, thereby providing the necessary cationic surface activity. An important representative group of cationic surfactants has the general formula: 1 R 2 R 3 R 4 N + )X - where R 1 represents C1-C8 alkyl or alkenyl, R 2 , R 3 and R 4are each independently an alkyl or alkenyl group having 1 to 22 carbon atoms. X is a counterion, preferably selected from the group of halides, alkyl sulfates and alkyl carbonates. Cationic surfactants in which the nitrogen group is substituted with two long acyl groups and two short alkyl or alkenyl groups are particularly preferred.

[0053] Esterquats A further class of cationic surfactants particularly useful as co-surfactant of the present invention is represented by so-called esterquats. Esterquats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by related methods of preparation organic chemistry. In this connection, reference is made to International Patent Application WO91 / 01295, which describes partial esterification of triethanolamine with fatty acid in the presence of hypophosphorous acid, passing air through the reaction mixture, and total quaternization with dimethyl sulfate or ethylene oxide. Furthermore, German Patent No. 4308794 describes a process for the preparation of solid esterquats, which involves quaternization of triethanolamine ester in the presence of a suitable dispersant, preferably fatty alcohol.

[0054] Typical examples of ester quats suitable for use according to the invention are products whose acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, where RCO is an acyl group containing 6 to 10 carbon atoms, and whose amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and their technical mixtures, such as the so-called head-fractionated fatty acids. Ester quats whose acyl component is derived from a monocarboxylic acid containing 8 to 10 carbon atoms are preferably used. Other ester quats are those whose acyl component is derived from a dicarboxylic acid such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. Overall, mixtures of monocarboxylic acids whose acyl component is derived from 6 to 22 carbon atoms and ester quats whose acyl component is derived from adipic acid are preferably used. The molar ratio of mono- and dicarboxylic acids in the final esterquat may be in the range of 1:99 to 99:1, preferably in the range of 50:50 to 90:10, more particularly in the range of 70:30 to 80:20. Besides the quaternized fatty acid triethanolamine ester salts, other suitable esterquats are quaternized ester salts of diethanolalkylamines or 1,2-dihydroxypropyldialkylamines with mono / dicarboxylic acid mixtures. The esterquats may be obtained either from fatty acids or from the corresponding triglycerides in admixture with the corresponding dicarboxylic acids. Such a process is proposed in EP 0750606 as representative of the relevant prior art. To produce the quaternized esters, mixtures of mono- and dicarboxylic acids with triethanolamine may be used in molar ratios of 1.1:1 to 3:1 (based on the available carboxyl functional groups). Considering the performance of the esterquats, ratios of 1.2:1 to 2.2:1, preferably 1.5:1 to 1.9:1, have proven to be particularly advantageous. The preferred esterquats are technical mixtures of mono-, di- and triesters having an average degree of esterification of 1.5 to 1.9.

[0055] SUPERFATTING AGENTS AND CONSISTENCY FACTORS Superfatting agents may be selected from materials such as lanolin and lecithin, polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, the latter also functioning as foam stabilizers.

[0056] The consistency factors mainly used are fatty alcohols or hydroxyfatty alcohols containing 12 to 22, preferably 16 to 18, carbon atoms, as well as partial glycerides, fatty acids or hydroxyfatty acids. A combination of these substances with alkyl oligoglucosides and / or fatty acid N-methylglucamides of the same chain length and / or polyglycerol poly-12-hydroxystearates is preferably used.

[0057] Thickeners and Rheology Additives Suitable thickeners are polymeric thickeners, such as Aerosil® types (hydrophilic silicas), polysaccharides, more particularly xanthan gum, guar, agar agar, alginates and tyrosine, carboxymethylcellulose and hydroxyethylcellulose, also relatively high molecular weight polyethylene glycol monoesters and diesters of fatty acids, polyacrylates (e.g. Carbopols® [Goodrich] or Synthalens® [Sigma]), polyacrylamides, polyvinyl alcohols and polyvinylpyrrolidones, surfactants, such as ethoxylated fatty acid glycerides, esters of fatty acids with polyols, such as pentaerythritol or trimethylolpropane, narrow-range fatty alcohol ethoxylates, and electrolytes, such as sodium chloride and ammonium chloride.

[0058] polymer Suitable cationic polymers are, for example, cationic cellulose derivatives, for example quaternized hydroxyethylcellulose available from Amerchol under the name Polymer JR 400®, cationic starch, copolymers of diallyl ammonium salts and acrylamide, quaternized vinylpyrrolidone / vinylimidazole polymers, for example Luviquat® (BASF), condensates of polyglycols with amines, quaternized collagen polypeptides, for example lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat® L, Grunau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, for example amodimethicone, copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetriamine (Cartaretine®, Sandoz), copolymers of acrylic acid and dimethyldiallylammonium chloride (Merquat®). 550, Chemviron), polyaminopolyamides and crosslinked water-soluble polymers thereof, cationic chitin derivatives such as quaternized chitosan (optionally in microcrystalline distribution), condensation products of dihaloalkyls, such as dibromobutane, with bis-dialkylamines, such as bis-dimethylamino-1,3-propane, cationic guar gums, such as Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese, quaternized ammonium salt polymers, such as Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol, and the various polyquaternium types (for example 6, 7, 32 or 37) available commercially under the trade names Rheocare® CC and Ultragel® 300.

[0059] Suitable anionic, zwitterionic, amphoteric and nonionic polymers are, for example, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and their esters, uncrosslinked and polyol-crosslinked polyacrylic acids, acrylamidopropyltrimethylammonium chloride / acrylate copolymers, octylacrylamide / methyl methacrylate / tert.-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers, Polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, vinylpyrrolidone / dimethylaminoethyl methacrylate / vinyl caprolactam terpolymer and optionally derivatized cellulose ethers and silicones.

[0060] PEARLIZING WAXES Suitable pearlescent waxes are, for example, alkylene glycol esters, in particular ethylene glycol distearate; fatty acid alkanolamides, in particular coco fatty acid diethanolamide; partial glycerides, in particular stearic acid monoglyceride; esters of polybasic, optionally hydroxy-substituted carboxylic acids with fatty alcohols containing 6 to 22 carbon atoms, in particular the long-chain esters of tartaric acid; fatty compounds, for example fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, in particular laurone and distearyl ether, each of which contains at least 24 carbon atoms; fatty acids, for example stearic acid, hydroxystearic acid or behenic acid, ring-opening products of olefin epoxides containing 12 to 22 carbon atoms with fatty alcohols containing 12 to 22 carbon atoms and / or polyols containing 2 to 15 carbon atoms and 2 to 10 hydroxyl groups, and mixtures thereof.

[0061] silicone Suitable silicones may be selected from the group consisting of: acefylline methylsilanol mannuronate, acetyl methionyl methylsilanol elastinate acrylates / behenyl, acrylates / dimethicone methacrylate copolymer, acrylates / behenyl methacrylate / dimethicone methacrylate copolymer, acrylates / bis-hydroxypropyl dimethicone crosspolymer, acrylates / dimethicone copolymer, acrylates / dimethicone methacrylate / ethylhexyl acrylate ... Nol acrylate copolymer, acrylates / ethylhexyl acrylate / dimethicone methacrylate copolymer, acrylates / octylacrylamide / diphenylamodimethicone copolymer, acrylates / polytrimethylsiloxymethacrylate copolymer, acrylates / propyl trimethicone methacrylate copolymer, acrylates / stearyl acrylate / dimethicone methacrylate copolymer, acrylates / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate copolymer, acrylates Ingredients: acrylate / trifluoropropyl methacrylate / polytrimethylsiloxymethacrylate copolymer, aminobispropyl dimethicone, aminoethyl aminopropyl dimethicone, aminopropyl dimethicone, aminopropyl phenyl trimethicone, aminopropyl triethoxysilane, ammonium dimethicone PEG-7 sulfate, amodimethicone, amodimethicone hydroxystearate, amodimethicone / silsesquioxane copolymer, ascorbyl carboxydecyl trisiloxane, ascorbyl methylsilanol pectinate, behenoxyethanol Dimethicone, Behentrimonium Dimethicone PEG-8 Phthalate, Behenyl Dimethicone, Bis-Amino PEG / PPG-41 / 3 Aminoethyl PG-Propyl Dimethicone, Bis-Aminopropyl / Ethoxy Aminopropyl Dimethicone, Bis(Butyl Benzoate) Diamino Triazine Aminopropyl Trisiloxane, Bis-Butyl Dimethicone Polyglyceryl-3, Bis-Butyloxy Amodimethicone / PEG-60 Copolymer, Bis(C13-15 Alkoxy) Hydroxybutamide Amidodimethicone, Bis(C13-15 Alkoxy) PG-Amodimethicone,Bis(C1-8 alkyl lauroyl lysine decyl carboxamide) dimethicone, bis-cetyl cetyl dimethicone,

[0062] Bis-Cetyl / PEG-8 Cetyl PEG-8 Dimethicone, Bis-Diphenylethyl Disiloxane, Bis-Ethyl Ethyl Methicone, Bis-Gluconamidoethyl Aminopropyl Dimethicone, Bis-Hydroxy Dimethicone, Bis-Hydroxyethoxypropyl Dimethicone Bis-Hydroxylauryl, Dimethicone / IPDI Copolymer, Bis-Hydroxy / Methoxy Amodimethicone, Bis-Hydroxypropyl Dimethicone Behenate, Bis-Hydroxypropyl Dimethicone / SMDI Copolymer, Bis-Isobutyl PEG-14 / Amodimethicone Copolymer Polymer, Bis-Isobutyl PEG-15 / Amodimethicone Copolymer, Bis-Isobutyl PEG / PPG-20 / 35 / Amodimethicone Copolymer, Bis-Isobutyl PEG / PPG-10 / 7 / Dimethicone Copolymer, Bis-Isobutyl PEG-24 / PPG-7 / Dimethicone Copolymer, Bis-PEG-1 Dimethicone, Bis-PEG-4 Dimethicone, Bis-PEG-8 Dimethicone, Bis-PEG-12 Dimethicone, Bis-PEG-20 Dimethicone, Bis-PEG-12 Dimethicone Beeswax, Bis-PEG-12 Dimethicone Cande RELATE, Bis-PEG-15 Dimethicone / IPDI Copolymer, Bis-PEG-15 Methyl Ether Dimethicone, Bis-PEG-18 Methyl Ether Dimethyl Silane, Bis-PEG / PPG-14 / 14 Dimethicone, Bis-PEG / PPG-15 / 5 Dimethicone, Bis-PEG / PPG-18 / 6 Dimethicone, Bis-PEG / PPG-20 / 20 Dimethicone, Bis-PEG / PPG-16 / 16 PEG / PPG-16 / 16 Dimethicone, Bis-PEG / PPG-20 / 5 PEG / PPG-20 / 5 Dimethicone, Bisphenylhexamethicone , Bis-phenylpropyl dimethicone, Bis-polyethylene dimethicone, Bis-(polyglyceryl-3 oxyphenylpropyl) dimethicone, Bis-(polyglyceryl-7 oxyphenylpropyl) dimethicone, Bis-PPG-15 dimethicone / IPDI copolymer, Bis(PPG-7 undeceneth-21) dimethicone, Bis-stearyl dimethicone, Bis-trimethoxysilylethyl tetramethyldisiloxyethyl dimethicone, Bis-vinyl dimethicone, Bis-vinyl dimethicone / dimethicone copolymer, Borage Seed OilOil) PEG-7 Dimethicone Ester, Butyl Acrylate / C6-14 Perfluoroalkylethyl Acrylate / Mercaptopropyl Dimethicone Copolymer, Butyl Acrylate / Hydroxypropyl Dimethicone Acrylate Copolymer,

[0063] Butyl Dimethicone Acrylate / Cyclohexyl Methacrylate / Ethylhexyl Acrylate Copolymer, Butyl Dimethicone Methacrylate / Methyl Methacrylate Crosspolymer, t-Butyldimethylsilyl Grape Seed Extract, Butyl Polydimethylsiloxyethylene / Propylene / Vinyl Norbornene Copolymer, C6-8 Alkyl C3-6 Alkyl Glucoside Dimethicone, C20-24 Alkyl Dimethicone, C24-28 Alkyl Dimethicone, C26-28 Alkyl Dimethicone, C30-45 Alkyl Dimethicone, C30-60 Alkyl Dimethicone , C32 Alkyl Dimethicone, C30-45 Alkyl Dimethicone / Polycyclohexene Oxide Crosspolymer, C26-28 Alkyl Dimethylsilyl Polypropyl Silsesquioxane, C30-45 Alkyl Dimethylsilyl Polypropyl Silsesquioxane, C20-24 Alkyl Methicone, C24-28 Alkyl Methicone, C26-28 Alkyl Methicone, C30-45 Alkyl Methicone, C20-28 Alkyl Perfluorodecyl Ethoxy Dimethicone, C26-54 Alkyl Tetradecyl Dimethicone, Capryl Dimethicone, Caprylyl Dimethicone Ethoxyglucoside, Caprylyl Methicone, Caprylyl Trimethicone, Carboxydecyl Trisiloxane, Castor Oil Bis-Hydroxypropyl Dimethicone Esters Cerotyle Dimethicone, Cetearyl Dimethicone Crosspolymer, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer, Cetearyl Methicone, Cetrimonium Carboxydecyl PEG-8 Dimethicone, Cetrimonium Dimethicone PEG-7 Phthalate, Cetyl Behenyl Dimethicone, Cetyl Dimethicone, Cetyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Cetyl Hexacosyl Dimethicone Con, Cetyl Oxydimethicone, Cetyl PEG-8 Dimethicone, Cetyl PEG / PPG-15 / 15 Butyl Ether Dimethicone, Cetyl PEG / PPG-7 / 3 Dimethicone, Cetyl PEG / PPG-10 / 1 Dimethicone, Cetyl Triethylmonium Dimethicone PEG-8 Phthalate, Cetyl Triethylmonium Dimethicone PEG-8 Succinate, Copper Acetyl Tyrosinate Methylsilanol, Copper PCA Methylsilanol, C4-14 Perfluoroalkylethoxydimethicone, Cycloethoxymethicone, Cycloheptasiloxane, Cyclohexasiloxane,Cyclomethicone,

[0064] Cyclopentasiloxane, cyclophenylmethicone, cyclotetrasiloxane, m-cyclovinylmethicone, cystine bis-PG-propyl silanetriol, DEA PG-Propyl PEG / PPG-18 / 21 Dimethicone, Diisostearoyl Trimethylolpropane Siloxysilicate, Dilauroyl Trimethylolpropane Siloxysilicate, Dilinoleamidopropyl Dimethylamine Dimethicone PEG-7 Phosphate, Dimethicone, Dimethicone Crosspolymer, Dimethicone Crosspolymer-3, Dimethicone / Divinyl Dimethicone / Silsesquioxane Crosspolymer, Dimethicone Ethoxyglucoside, Dimethicone Hydroxypropyltrimonium Chloride, Dimethicone / Mercaptopropyl Methicone Copolymer, Dimethicone PEG-15 Acetate, Dimethicone PEG-8 Adipate, Dimethicone PEG-7 Avocadoate, Dimethicone PEG-8 Avocadoate, Dimethicone PEG-8 Beeswax, Dimethicone PEG-8 Benzoate, Dimethicone PEG-8 Borate PEG-8 Borageate), Dimethicone PEG-7 Cocoate, Dimethicone / PEG-10 Crosspolymer, Dimethicone / PEG-10 / 15 Crosspolymer, Dimethicone / PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG-8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG-8 Lanolate, Dimethicone PEG-8 Laurate, Meadowfoam Oil PEG-8 Dimethicone, Dimethicone PEG-7 Octyldodecyl Citrate, Dimethicone PEG-7 Olivate, Dimethicone PEG-8 Oleate Rebate, Dimethicone PEG-7 Phosphate, Dimethicone PEG-8 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG-7 Phthalate, Dimethicone PEG-8 Phthalate, Dimethicone PEG-8 Polyacrylate, Dimethicone PEG / PPG-20 / 23 Benzoate, Dimethicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethicone PEG-7 Succinate, Dimethicone PEG-8 Succinate, Dimethicone PEG-7 Sulfate, Dimethicone PEG-7 Undecylenate,

[0065] Dimethicone PG-Diethylmonium Chloride, Dimethicone / Phenyl Vinyl Dimethicone Crosspolymer, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone / PPG-20 Crosspolymer, Dimethicone Propyl Ethylenediamine Behenate, Dimethicone Propyl PG-Betaine, Dimethicone / Silsesquioxane Copolymer, Dimethicone Silylate, Dimethicone / Inyl Dimethicone Crosspolymer, Dimethicone / Vinyl Trimethylsiloxysilicate Crosspolymer, Dimethiconol, Dimethiconol Arginine, Dimethiconol Beeswax, Dimethiconol Behenate, Dimethiconol Borate, Dimethiconol Candelillate, Dimethiconol Carnaubate, Dimethiconol Cysteine, Dimethiconol Dhupabuterate Butterate, Dimethiconol Fluoroalcohol Dilinoleic Acid, Dimethiconol Hydroxystearate, Dimethiconol Lilipe Butterate, Dimethiconol / IPDI Copolymer, Dimethiconol Isostearate, Dimethiconol Kokum Butterate, Dimethiconol Lactate, Dimethiconol Meadowfoam Oil Fatty Acid Salt, Dimethiconol Methionine, Dimethiconol / Methylsilanol / Silicate Crosspolymer, Dimethiconol Mohwa Butterate, Dimethiconol Panthenol, Dimethiconol SalbuterateButterate), Dimethiconol / Silica Crosspolymer, Dimethiconol / Silsesquioxane Copolymer, Dimethiconol Stearate, Dimethiconol / Stearyl, Methicone / Phenyl Trimethicone Copolymer, Dimethoxysilyl Ethylenediaminopropyl Dimethicone, Dimethylaminopropylamide PCA Dimethicone, Dimethyloxobenzodioxasilane, Dimethylsilanol Hyaluronate, Dioleyl Tocopheryl Methylsilanol, Diphenyl Amodimethicone, Diphenyl Dimethicone, Diphenyl Dimethicone Crosspolymer Diphenyl Dimethicone / Inyl Diphenyl Dimethicone / Silsesquioxane Crosspolymer, Diphenyl Ethyl Benzyloxydyl Siloxane, Diphenyl Isopropyl Dimethicone, Diphenyl Siloxyphenyl / Propyl Trimethicone,

[0066] Diphenylsiloxy Phenyl Trimethicone Disiloxane, Amodimethicone Disuccinamide Disodium, PEG-12 Dimethicone Sulfosuccinate Disodium, PEG-8 Lauryl Dimethicone Sulfosuccinate Disodium, Divinyl Dimethicone / Dimethicone Copolymer, Divinyl Dimethicone / Dimethicone Crosspolymer, Drometrizole Trisiloxane, Ethylhexyl Acrylate / VP / Dimethicone Methacrylate Copolymer, Ethyl Methicone, Ethyl Trisiloxane, Fluor C2-8 Alkyl Dimethicone, Gluconamidopropylaminopropyl dimethicone, 4-(2-beta-glucopyranosyloxy)propoxy-2-hydroxybenzophenone, glyceryl undecyl dimethicone, glycidoxy dimethicone, hexadecyl methicone, hexyl dimethicone, hexylmethicone, hexyltrimethoxysilane, hydrogen dimethicone, hydrogen dimethicone / octylsilsesquioxane copolymer, hydrolyzed collagen PG-propyl dimethiconol, hydrolyzed collagen PG-propyl methylsilanediol, hydrolyzed collagen PG-propyl silanetriol, hydrolyzed keratin PG-propyl methyl silanediol, hydrolyzed sesame protein PG-propyl methyl silanediol, hydrolyzed silk PG-propyl methyl silanediol, hydrolyzed silk PG-propyl methyl silanediol crosspolymer, hydrolyzed soy protein / dimethicone PEG-7 acetate, hydrolyzed soy protein PG-propyl methyl silanediol, hydrolyzed vegetable protein PG-propyl silanetriol, hydrolyzed wheat protein / cystine bis-PG-pro Pyrsilanetriol Copolymer, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Acetate, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Phosphate Copolymer, Hydrolyzed Wheat Protein PG-Propyl Methylsilanediol, Hydrolyzed Wheat Protein PG-Propyl Silanetriol, Hydroxyethyl Acetomonium PG-Dimethicone, Hydroxypropyl Dimethicone, Hydroxypropyl Dimethicone Behenate, Hydroxypropyl Dimethicone Isostearate, Hydroxypropyl Dimethicone Stearate,

[0067] Isobutyl Methacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isobutyl Methacrylate / Trifluoroethyl Methacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isopentyl Trimethoxycinnamate Trisiloxane, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropyl Titanium Triisostearate / Triethoxysilylethyl, Polydimethylsiloxyethyl Dimethicone Crosspolymer, Isostearyl Carboxydecyl PEG-8 Dimethicone Ingredients include: Lactoyl Methylsilanol Elastinate, Lauryl Dimethicone, Lauryl Dimethicone PEG-15 Crosspolymer, Lauryl Dimethicone PEG-10 Phosphate, Lauryl Dimethicone / Polyglycerin-3 Crosspolymer, Lauryl Methicone, Lauryl PEG-8 Dimethicone, Lauryl PEG-10 Methyl Ether Dimethicone, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Lauryl PEG / PPG-18 / 18 Methicone, Lauryl Phenyl Isopropyl Methicone, Lauryl Phenyl Propyl Methicone, Lauryl Polydimethylsiloxyethyl Dimethicone, Ingredients: Tylsiloxyethyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Trimethicone, Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone, Methacryloylpropyl Trimethoxysilane, Methicone, Methoxyamodimethicone / Silsesquioxane Copolymer, Methoxycinnamoylpropyl Polysilsesquioxane, Methoxycinnamoylpropyl Silsesquioxane Silicate, Methoxy PEG-13 Ethyl Polysilsesquioxane, Meth Ingredients: methoxy PEG / PPG-7 / 3 aminopropyl dimethicone, methoxy PEG / PPG-25 / 4 dimethicone, methoxy PEG-10 propyl trimethoxysilane, methyl eugenyl PEG-8 dimethicone, methyl polysiloxane emulsion, methyl silanol acetyl methionate, methyl silanol acetyl tyrosine, methyl silanol ascorbate, methyl silanol carboxymethyl theophylline, methyl silanol carboxymethyl theophylline alginate, methyl silanol elastinate, methyl silanol glycyrrhizinate,Methylsilanol Hydroxyproline,

[0068] Methylsilanol Hydroxyproline Aspartate, Methylsilanol Mannuronate, Methylsilanol PCA, Methylsilanol PEG-7 Glyceryl Cocoate, Methylsilanol / Silicate Crosspolymer, Methylsilanol Spirulinate, Methylsilanol Tri-PEG-8 Glyceryl Cocoate, Methyltrimethicone, Methyltrimethoxysilane, Myristylamidopropyldimethylamine Dimethicone PEG-7 Phosphate, Myristylmethicone Dimethicone, Myristyl Trisiloxane, Nylon-611 / Dimethicone Copolymer, PCA Dimethicone, PEG-7 Amodimethicone, PEG-8 Amodimethicone, PEG-8 Cetyl Dimethicone, PEG-3 Dimethicone, PEG-6 Dimethicone, PEG-7 Dimethicone, PEG-8 Dimethicone, PEG-9 Dimethicone, PEG-10 Dimethicone, PEG-12 Dimethicone, PEG-14 Dimethicone, PEG-17 Dimethicone, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoleate, PEG-8 Dimethicone / Dimer Dilinoleate Copolymer, PEG-10 Dimethicone / Vinyl Dimethicone Crosspolymer, PEG-8 Distearumonium Chloride PG-Dimethicone, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, PEG-8 Methicone, PEG-6 Methicone Acetate, PEG-6 Methyl Ether Dimethicone, PEG-7 Methyl Ether Dimethicone, PEG-8 Methyl Ether Dimethicone, PEG-9 Methyl Ether Dimethicone, PEG-10 Methyl Ether Dimethicone, PEG-11 Methyl Ether Dimethicone, PEG-32 Methyl Ether Dimethicone, PEG-8 Methyl Ether Triethoxysilane, PEG-10 Nonafluorohexyl Dimethicone Copolymer, PEG-4 PEG-12 Dimethicone, PEG-8 PG-Coco Glucoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG / PPG-20 / 22 Butyl Ether Dimethicone, PEG / PPG-22 / 22 Butyl Ether Dimethicone,

[0069] PEG / PPG-23 / 23 Butyl Ether Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-27 / 9 Butyl Ether Dimethicone, PEG / PPG-3 / 10 Dimethicone, PEG / PPG-4 / 12 Dimethicone, PEG / PPG-6 / 4 Dimethicone, PEG / PPG-6 / 11 Dimethicone, PEG / PPG-8 / 14 Dimethicone, PEG / PPG-8 / 26 Dimethicone, PEG / PPG-10 / 2 Dimethicone, PEG / PPG-12 / 16 Dimethicone, PEG / PPG-12 / 18 Dimethicone, PEG / PPG-14 / 4 Dimethicone, PEG / PPG-15 / 5 Dimethicone, PEG / PPG-15 / 15 Dimethicone, PEG / PPG-16 / 2 Dimethicone, PEG / PPG-16 / 8 Dimethicone, PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 6 Dimethicone, PEG / PPG-18 / 12 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG / PPG-20 / 6 Dimethicone, PEG / PPG- 20 / 15 Dimethicone, PEG / PPG-20 / 20 Dimethicone, PEG / PPG-20 / 23 Dimethicone, PEG / PPG-20 / 29 Dimethicone, PEG / PPG-22 / 23 Dimethicone, PEG / PPG-22 / 24 Dimethicone, PEG / PPG-23 / 6 Dimethicone, PEG / PPG-25 / 25 Dimethicone, PEG / PPG-27 / 27 Dimethicone, PEG / PPG-30 / 10 Dimethicone, PEG / PPG-25 / 25 Dimethicone / Acrylates Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG / PPG-24 / 24 Methyl Ether Glycidoxy Dimethicone, PEG / PPG-10 / 3 Oleyl Ether Dimethicone, PEG / PPG-5 / 3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorocaprylyl Riethoxysilylethyl MethiconeMethicone), Perfluorononyl Dimethicone, Perfluorononyl Dimethicone / Methicone / Amodimethicone Crosspolymer, Perfluorononylethyl Carboxydecyl Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Hexacosyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl / Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl Dimethicone, Perfluorononylethyl Carboxydecyl PEG-8 Dimethicone, Perfluorononylethyl Carboxydecyl PEG-10 Dimethicone,

[0070] Perfluorononylethyl Dimethicone / Methicone Copolymer, Perfluorononylethyl PEG-8 Dimethicone, Perfluorononylethyl Stearyl Dimethicone, Perfluorooctylethyl / Diphenyl Dimethicone Copolymer, Perfluorooctylethyl Triethoxysilane, Perfluorooctylethyl Trimethoxysilane, Perfluorooctylethyl Trisiloxane, Perfluorooctyltriethoxysilane, PG-Amodimethicone, Phenethyl Dimethicone, Phenethyl Disiloxane, Phenyl Dimethicone, Phenylisopropyl Dimethicone, Phenylmethicone, Phenylmethiconol, Phenylpropyl Dimethylsiloxysilocate, Phenylpropyl Ethyl Methicone, Phenylpropyl Trimethicone, Phenylpropyl Trimethicone / Diphenylmethicone, Phenyl Trimethicone, Platinum Divinyldisiloxane, Polyacrylate-6, Polydiethylsiloxane, Polydimethylsiloxyethyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Polydimethylsiloxyethyl Dimethicone Chicone / Methicone Copolymer, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-3 Disiloxane Dimethicone, Polyglyceryl-3 / Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Poly(glycol adipate) / Bis-hydroxyethoxypropyl Dimethicone Copolymer, Polymethylsil Sesquioxane, Polymethylsilsesquioxane / Trimethylsiloxysilicate, Polyphenylsilsesquioxane, Polypropylsilsesquioxane, Polysilicone-1, Polysilicone-2, Polysilicone-3, Polysilicone-4, Polysilicone-5, Polysilicone-6, Polysilicone-7, Polysilicone-8, Polysilicone-9, Polysilicone-10, Polysilicone-11, Polysilicone-12, Polysilicone-13, Polysilicone-14, Polysilicone-15,

[0071] Polysilicone-16, Polysilicone-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysilicone-21, Polysilicone-18 Cetyl Phosphate, Polysilicone-1 Crosspolymer, Polysilicone-18 Stearate, Polyurethane-10, Dimethicone PEG-7 Potassium Panthenyl Phosphate, Dimethicone PEG-7 Potassium Phosphate, PPG-12 Butyl Ether Dimethicone, PPG-2 Dimethicone, PPG-12 Dimethicone, PPG-27 Dimethicone, PPG-4 Oleth-10 Dimethicone, Propoxylated Lamethylpiperidinyl Dimethicone, Propyl Trimethicone, Quaternium-80, Retinoxytrimethylsilane, Silanediol Salicylate, Silanetriol, Silanetriol Alginate, Silanetriol Glutamate, Silanetriol Lysinate, Silanetriol Melaninate, Silanetriol Trehalose Ether, Silica, Silica Dimethicone Silylate, Silica Dimethyl Silylate, Silica Silylate, Silicon Carbide, Silicone Quaternium-1, Silicone Quaternium-2, Silicone Quaternium-2 Panthenol Succinate, Silicone Quaternium-3, Silicone Quaternium-4, Silicone Quaternium-5, Silicone Quaternium-6, Silicone Quaternium-7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, Silicone Quaternium-16, Silicone Quaternium-16 / Glycidoxy Dimethicone Crosspolymer, Silicone Quaternium-17, Silicone Quaternium-18, Silicone Quaternium-19, Silicone Quaternium-20, Silicone Quaternium-21, Silicone Quaternium-22, Silicone Quaternium-24, Silicone Quaternium-25, Siloxanetriol Alginate, Siloxanetriol Phytate, Simethicone, Sodium Carboxydecyl PEG-8 Dimethicone, Sodium Dimethicone PEG-7 Acetyl Methyl Taurate, Sodium Dimethylsilanol Hyaluronate, Sodium Methylsilanol Lactate, Sodium Methylsilanol Mannuronate, Sodium Methylsilanol PCA,PG-Propyl Dimethicone Sodium Thiosulfate Copolymer, PG-Propyl Dimethicone Sodium Thiosulfate,

[0072] Propoxyhydroxypropyl thiosulfate sodium silicate, sorbityl silanediol, soy triethoxysilylpropyl dimonium chloride, stearalkonium dimethicone PEG-8 phthalate, stearamidopropyl dimethicone, steardimonium hydroxypropyl panthenyl PEG-7 dimethicone phosphate chloride, steardimonium hydroxypropyl PEG-7 dimethicone phosphate chloride, stearoxy dimethicone, stearoxymethicone / dimethicone copolymer, stearoxytrimethylsilane, stearyl aminopropyl methicone, stearyl dimethicone, stearyl / lauryl methacrylate crosspolymer, stearyl methicone, stearyl triethoxysilane (Stearyl Triethoxysilanek), Stearyl Trimethicone, Styrene / Acrylates / Dimethicone Acrylate Crosspolymer, Styrene / Acrylates / Dimethicone Copolymer, TEA-Dimethicone PEG-7 Phosphate, Tetrabutoxypropyltrisiloxane, Tetramethylhexaphenyltetrasiloxane, Tetramethyltetraphenyltrisiloxane, Tocopheryloxypropyltrisiloxane, Trideceth-9 PG-Amodimethicone, Triethoxycaprylylsilane, Triethoxysilylethyl Dimethicone / Methicone Copolymer, Triethoxysilylethyl Polydimethylsiloxyethyl Dimethicone, Triethoxysilylethyl Polydimethylsiloxyethyl Hexyl Dimethicone, Triethoxysilylpropyl Carbamoylethoxypropyl Butyl Dimethicone, Trifluoromethyl C1-4 Alkyl Dimethicone, Trifluoropropyl Cyclopentasiloxane, Trifluoropropyl Cyclotetrasiloxane, Trifluoropropyl Dimethicone, Trifluoropropyl Dimethicone / PEG-10 Crosspolymer, Trifluoropropyl Dimethicone / Trifluoropropyl Divinyl Dimethicone Crosspolymer, Trifluoropropyl Dimethicone / Vinyl Trifluoropropyl, Dimethicone / Silsesquioxane Crosspolymer, Trifluoropropyl Dimethiconol, Trifluoropropyl Dimethyl / Trimethylsiloxysilicate,

[0073] Trifluoropropylmethicone, trimethoxycaprylylsilane, trimethoxysilyl dimethicone, trimethylpentaphenyltrisiloxane, trimethylsiloxyamodimethicone, trimethylsiloxyphenyl dimethicone, trimethylsiloxysilicate, trimethylsiloxysilicate / dimethicone crosspolymer, trimethylsiloxysilicate / dimethiconol crosspolymer, trimethylsiloxysilylcarbamoyl pullulan, trimethylsilyl hydrolyzed conchiolin protein PG-propyl methylsilanediol crosspolymer, trimethylsilyl hydrolyzed silk PG-propyl methylsilanediol crosspolymer, trimethylsilyl hydrolyzed wheat protein ... Methylsilyl Pullulan, Trimethylsilyl Trimethylsiloxy Glycolate, Trimethylsilyl Trimethylsiloxy Lactate, Trimethylsilyl Trimethylsiloxy Salicylate, Triphenyl Trimethicone, Trisiloxane, Tris-tributoxysiloxymethylsilane, Undecyl Clylene Dimethicone, Vinyl Dimethicone, Vinyl Dimethicone / Lauryl Dimethicone Crosspolymer, Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer, Vinyl Dimethyl / Trimethylsiloxysilicate Stearyl Dimethicone Crosspolymer, VP / Dimethiconyl Acrylate / Polycarbamyl / Polyglycol Esters, Zinc Carboxydecyl Trisiloxane and Dimethicone PEG-8 Zinc Succinate, and mixtures thereof.

[0074] More preferably, the silicones that may be included in the mixture according to the invention are dimethicone, cyclomethicone, phenyltrimethicone, cyclohexasiloxane and cyclopentasiloxane.A detailed overview of suitable volatile silicones can be found in Todd et al., in Cosm. Toil. 91, 27 (1976).

[0075] Waxes and Stabilizers Besides the natural oils used, waxes may also be present in the preparation, more particularly natural waxes such as candelilla wax, carnauba wax, Japan wax, esparto grass wax, cork wax, guaruma wax, rice oil wax, sugar cane wax, auricurie wax, montan wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), uropygial fat, ceresin, ozokerite (earth wax), petrolatum, paraffin wax and microwaxes; chemically modified waxes (hard waxes), such as montan ester wax, sasol wax, hydrogenated jojoba wax, and synthetic waxes, such as polyalkylene waxes and polyethylene glycol waxes.

[0076] Metal salts of fatty acids, such as magnesium, aluminium and / or zinc stearates or ricinoleates, may be used as stabilizers.

[0077] PRIMARY SUN PROTECTION FACTORS A primary sun protection factor in the context of the present invention is, for example, an organic substance (light filter) which is liquid or crystalline at room temperature and capable of absorbing ultraviolet radiation and releasing the absorbed energy in the form of longer wavelength radiation, for example heat.

[0078] The preparations according to the invention advantageously comprise at least one UV-A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic pigment. The preparations according to the invention preferably comprise at least one UV-B filter or a broadband filter, more particularly preferably at least one UV-A filter and at least one UV-B filter.

[0079] The following UV filters that can be used within the context of the present invention are preferred, but are of course not limited to them. The UV filters preferably used are selected from the group consisting of one, two, three, four, five or more of the following species: TIFF2025515108000002.tif239163

[0080] In a preferred embodiment, the sunscreen filter forming component (ii) represents a blend of UVA and UVB filters selected from the group consisting of homosalate, octocrylene, bisethylhexyloxyphenol methoxyphenyl triazine, butyl methoxydibenzoylmethane, ethylhexyl salicylate, and mixtures thereof. Particularly preferred is the blend of all these filters marketed under the trademark NeoHeli-opan® Flat (SYMRISE) and also according to WO2020088778A1.

[0081] Suitable pigments include oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminum (Al2O3), cerium (e.g. Ce2O3) and / or mixtures thereof.

[0082] In a further preferred embodiment, the preparations according to the invention comprise sunscreens, i.e. in particular UV filters and / or inorganic pigments (UV filter pigments), in a total amount such that the preparations according to the invention have a photoprotection factor of ≧5 and ≦50. Such preparations according to the invention are particularly suitable for protecting the skin and hair.

[0083] SECONDARY SUN PROTECTION FACTORS In addition to the group of primary sun protection factors mentioned above, secondary sun protection factors of the antioxidant type may also be used, which interrupt the photochemical reaction chain that is initiated when UV radiation penetrates the skin. Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (e.g. α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrolipoic acid), aurothioglucose, Propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, α-linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, Nucleotides, nucleosides and salts) and very small compatible amounts of sulfoximine compounds (e.g. buthionine sulfoximine, homocysteine ​​sulfoximine, buthionine sulfone, penta-, hexa- and hepta-thionine sulfoximine), (metal) chelating agents (e.g. α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, bile acids, bile extracts, bilirubin, biliverdin, EDT A, EGTA and its derivatives, unsaturated fatty acids and their derivatives (e.g., linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and its derivatives, vitamin C and its derivatives (e.g., ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate), tocopherol and its derivatives (e.g., vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate) and coniferyl benzoate of benzoin resin,Rutinic acid and its derivatives, glycosyl rutin, ferulic acid, furfurylidene glucitol, carnosine, butylated hydroxytoluene, butylated hydroxyanisole, nordihydroguaiac resin acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (for example dispersion in ethanol), zinc and its derivatives (for example ZnO, ZnSO4), selenium and its derivatives (for example selenium methionine), stilbene and its derivatives (for example stilbene oxide, trans-stilbene oxide), and derivatives of these active substances suitable for the purposes of the present invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids).

[0084] Advantageous inorganic second light-protective pigments are the finely dispersed metal oxides and metal salts also mentioned in WO 2005 / 123101. The total amount of inorganic pigments, in particular hydrophobic inorganic micropigments, in the final cosmetic preparation according to the invention is advantageously 0.1 to 30% by weight, preferably 0.5 to 10.0% by weight, in each case based on the total weight of the formulation.

[0085] Also preferred are particulate UV filters or inorganic pigments, which can optionally be hydrophobized, for example oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminium (Al2O3), cerium (e.g. Ce2O3) and / or mixtures thereof.

[0086] Biogenic and Antioxidant Agents Biogenic agents include, for example, tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy)ribonucleic acid and its fragmentation products, β-glucan, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts such as cherry extract and bambara nut extract, and vitamin complexes.

[0087] Antioxidants disrupt the photochemical reaction chain that is triggered when UV radiation penetrates the skin. Typical examples of these substances are amino acids (e.g., glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g., urocanic acid) and their derivatives, peptides, e.g., D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g., anserine), carotenoids, carotenes (e.g., -carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g., dihydroglucosamine), aurothioglucosamine, glycerol ... thiol, propylthiouracil and other thiols (e.g., thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleosides, etc.) tides, nucleosides and salts), as well as sulfoximine compounds at very low tolerated amounts (e.g. pmol-μmol / kg) (e.g. buthionine sulfoximine, homocysteine ​​sulfoximine, buthionine sulfone, penta-, hexa-, heptathionine sulfoximine), as well as (metal) chelating agents (e.g. hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, bile acids, bile extracts, bilirubin, bilibe Ludine, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g., linoleic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (e.g., ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate), tocopherol and derivatives (e.g., vitamin E acetate), vitamin A and derivatives (vitamin A palmitate), and conifer aryl benzoates of benzoic resin.benzoate), rutinic acid and its derivatives, glycosyl rutin, ferulic acid, furfurylidene glucitol, carnosine, butylated hydroxytoluene, butylated hydroxyanisole, nordihydroguaiac resin acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (e.g., ZnO, ZnSO4), selenium and its derivatives (e.g., selenium methionine), stilbene and their derivatives (e.g., styrene oxide, trans-stilbene oxide), and derivatives of these active ingredients suitable for the present invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides, and lipids).

[0088] Active substances that regulate hair pigmentation Preferred active ingredients for lightening hair are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinols and 4-(1-phenylethyl)1,3-dihydroxybenzene (phenylethylresorcinol), cyclohexyl carbamates (preferably one or more of the cyclohexyl carbamates disclosed in WO 2010 / 122178 and WO 2010 / 097480), sulfur-containing molecules, preferably glutathione or are cysteine, α-hydroxy acids (preferably citric acid, lactic acid, malic acid), their salts and esters, N-acetyl tyrosine and derivatives, undecenoyl phenylalanine, gluconic acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, thujaplicin and derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably senkyunolide, vinylgyacol, ethylgyacol, dionic acids, preferably octodecenedioic acid and / or azelaic acid, inhibitors of nitric oxide synthesis, preferably L-nitroarginine and derivatives thereof, 2,7-dinitroindazole or thiocitrulline, metal chelators (preferably α-hydroxy fatty acids, phytic acid, humic acid, bile acids, bile extracts, EDTA, EGTA and their derivatives), retinoids, soy milk and extracts, serine protease inhibitors or lipoic acid or other synthetic or natural active substances for lightening the skin and hair, the latter preferably used in the form of extracts from plants, preferably bearberry extract, rice extract, papaya extract, turmeric extract, mulberry extract, benkoan extract, nutsedge extract, licorice root extract or components concentrated or isolated therefrom, preferably glabridin or licochalcone A, Artocarpus extract, extracts of Rumex and Ramulus species, extracts of pine seeds (pine nuts), extracts of seeds of the genus Vitis or stilbene derivatives isolated or concentrated therefrom, Saxifrage extract, Scutellaria extract, grape extract and / or microalgae extract, in particular Tetraselmis suecica extract.

[0089] In this respect, advantageous skin and hair tanning active ingredients are substrates or substrate analogues of tyrosinase, such as L-tyrosine, N-acetyltyrosine, L-DOPA or L-dihydroxyphenylalanine, xanthine alkaloids, such as caffeine, theobromine and theophylline and derivatives thereof, proopiomelanocortin peptides, such as ACTH, α-MSH, peptide analogues thereof and other substances that bind to the melanocortin receptor, peptides, such as Val-Gly-Val-Ala-Pro-Gly, Lys-lle-Gly-Arg-Lys or Leu-lle-Gly-Lys, purines, pyrimidines, folic acid, copper salts, such as copper gluconate, copper chloride or copper pyrrolidonate, 1,3,4-oxadiazole-2-thiols, such as 5-pyrazin-2-yl-1,3,4-oxadiazole-2-thiol, curcumin, zinc diglycinate (Zn(Gly)2), e.g. manganese(II) bicarbonate complexes ("catalase mimics") as described in State Patent 0584178, tetrasubstituted cyclohexene derivatives as described, for example, in WO 2005 / 032501, isoprenoids as described, for example, in WO 2005 / 102252 and WO 2006 / 010661, melanin derivatives such as Melasyn-100 and MelanZe, diacylglycerols, aliphatic or cyclic diols, psoralens, prostaglandins and their analogues, activators of adenylate cyclase, and compounds which activate the transfer of melanosomes to keratinocytes, such as, for example, serine proteases or agonists of the PAR-2 ​​receptor, extracts of plants and plant parts of Chrysanthemum species, Sanguisorba species, walnut extracts, urucum extracts, rhubarb extracts, microalgae extracts, in particular Isochrysis galbana extracts, trehalose, erythrulose and dihydroxyacetone. Flavonoids which cause skin and hair pigmentation or browning (e.g., quercetin, rhamnetin, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosmin and diosmetin, morin, quercitrin, naringenin, hesperidin, phloridzin and phloretin) may also be used.

[0090] The amount of the aforementioned examples of additional active ingredients (one or more compounds) for regulating skin and hair pigmentation in the products according to the invention is preferably 0.00001 to 30% by weight, preferably 0.0001 to 20% by weight, particularly preferably 0.001 to 5% by weight, based on the total weight of the formulation.

[0091] Hair growth activators or inhibitors The preparations and products according to the invention may also contain one or more hair growth activators, i.e. agents that stimulate hair growth. The hair growth activators are preferably pyrimidine derivatives such as 2,4-diaminopyrimidine-3-oxide (aminexil), 2,4-diamino-6-piperidinopyrimidine-3-oxide (minoxidil) and derivatives thereof, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and derivatives thereof, xanthine alkaloids such as caffeine, theobromine, theophylline and derivatives thereof, quercetin and derivatives thereof, Dihydroquercetin (taxifolin) and its derivatives, potassium channel openers, antiandrogens, synthetic or natural 5-reductase inhibitors, nicotinic acid esters such as tocopheryl nicotinate, benzyl nicotinate, C1-C6 alkyl nicotinates, e.g. tripeptide Lys-Pro-Val, diphencyprene, hormones, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives. conductors, proteins such as cyproterone acetate, spironolactone and other diuretics, calcineurin inhibitors such as FK506 (tacrolimus, fujimycin) and its derivatives, cyclosporin A and its derivatives, zinc and zinc salts, polyphenols, procyanidins, proanthocyanidins, phytosterols such as beta-sitosterol, biotin, eugenol, (±)-beta-citronellol, panthenol, glycogen from e.g. mussels, microorganisms, algae, plants and other compounds from e.g. dandelion (Leontodon or Taraxacum), Orthosiphon, Vitex, Coffea, Paullinia, Theobroma, Asiasarum, Cucurbita or Styphnolobium, Serenoa Serenoa repens (Saw Palmetto), Sophora flavescens, Pygeum africanum, Panicum miliaceummiliaceum, Cimicifuga racemosa, Glycine max, Eugenia caryophyllata, Cotinus coggygria, Hibiscus rosa-sinensis, Camellia sinensis, Ilex paraguariensis, Isochrysis galbana, licorice, extracts from plant parts such as grapes, apples, barley or hops, or hydrolysates of rice or wheat.

[0092] Alternatively, preparations and products according to the invention may contain one or more hair growth inhibitors (as described above), ie agents which inhibit or prevent hair growth. The hair growth inhibitor is preferably selected from the group consisting of activins, activin derivatives or activin agonists, ornithine decarboxylase inhibitors such as α-difluoromethylornithine, or pentacyclic triterpenes such as, for example, ursolic acid, betulin, betulinic acid, oleanolic acid and derivatives thereof, 5α-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, γ-glutamyltranspeptidase inhibitors, transglutaminase inhibitors, serine protease inhibitors from soybean, microorganisms, algae, various microalgae or plants, and also compounds derived from, for example, the families Fabaceae, Solanaceae, Poaceae, Asclepiadaceae or Cucurbitaceae, the genus Chondrus, Gloiopeltis, Ceramium, Durvillea, Glycine max, Sanguisorba officinalis, Calendula ... officinalis, Hamamelis virginiana, Arnica montana, Salix alba, Hypericum perforatum or Gymnema sylvestre.

[0093] Physiological Cooling and Heating Agents The physiological cooling agent is preferably selected from the group formed by the species shown in the table below, including their optical isomers and racemates. TIFF2025515108000003.tif253141 TIFF2025515108000004.tif105143

[0094] The physiological hyperthermic agent may be selected from the group consisting of capsaicin, dihydrocapsaicin, nordihydrocapsaicin, homocapsaicin, homodihydrocapsaicin nonivamide, and chili pepper extract.

[0095] Anti-inflammatory agents Suitable anti-inflammatory agents may be selected from the group formed by: (i) steroidal anti-inflammatory substances of the corticosteroid type, in particular hydrocortisone, hydrocortisone derivatives, such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone (ii) non-steroidal anti-inflammatory substances, in particular oxicams such as piroxicam or tenoxicam, salicylates such as aspirin, disalcid, solprin or fendosal, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or clindanac, fenamates such as mefenamic, meclofenamic, flufenamic or niflumic, propionic acid derivatives such as ibuprofen, naproxen or benoxaprofen, pyrazoles such as phenylbutazone, oxyphenylbutazone, febrazone or azapropazone. (iii) natural or naturally occurring anti-inflammatory substances or substances which reduce redness and / or itching, in particular extracts or fractions from chamomile, aloe vera, Commiphora species, Rubia species, willow, willow herb, oat, calendula, arnica, St. John's wort, honeysuckle, rosemary, Passiflora incarnata, witch hazel, ginger, echinacea, or single active compounds thereof; (iv) histamine receptor antagonists, serine protease inhibitors (e.g. soybean extracts), TRPV1 antagonists (e.g. 4-t-butylcyclohexanol), NK1 antagonists (e.g. aprepitant, hydroxyphenylpropamidobenzoic acid), cannabinoid receptor agonists (e.g. palmitoylethanolamine) and TRPV3 antagonists.

[0096] Antibacterial agents Suitable antibacterial agents are in principle all substances which are effective against gram-positive bacteria, such as, for example, 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxydiphenyl ether (triclosan), 4-chloro-3,5-dimethylphenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy)-1,2- propanediol, 3-iodo-2-propynyl butylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial fragrances, thymol, thyme oil, eugenol, clove oil, menthol, mint oil, farnesol, phenoxyethanol, glycerol monocaprate, glycerol monocaprylate, glycerol monolaurate (GML), diglycerol monocaprate (DMC), salicylic acid N-alkylamides, such as n-octyl salicylamide or n-decyl salicylamide.

[0097] Enzyme inhibitors Suitable enzyme inhibitors are, for example, esterase inhibitors. These are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate, and especially triethyl citrate (Hydagen CAT). These substances inhibit enzyme activity and thereby reduce the formation of odor. Other substances suitable as esterase inhibitors are sterol sulfates or phosphates, such as lanosterol, cholesterol, campesterol, stigmasterol and sitosterol sulfate or phosphate, dicarboxylic acids and their esters, such as glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid and diethyl malonate, hydroxycarboxylic acids and their esters, such as citric acid, malic acid, tartaric acid or diethyl tartrate, and zinc glycinate.

[0098] Odor absorbing and antiperspirant active ingredients Suitable odor absorbers are substances that are able to absorb and largely retain odor-forming compounds. These substances reduce the partial pressure of the individual components, thus reducing their diffusion rate. In this process, it is important that the aroma is not damaged. Odor absorbers are ineffective against bacteria. They contain, for example, as main components, complex zinc salts of ricinoleic acid, or certain fragrances that are almost odorless, known to those skilled in the art as "fixatives", such as extracts of labdanum or styrax, or certain abietic acid derivatives. Odor masking agents are fragrances or perfume oils which, in addition to functioning as odor masking agents, also impart the respective fragrance notes to the deodorant. Perfume oils that may be mentioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts from flowers, stems and leaves, fruits, peels, roots, trees, herbs and grasses, needles and branches, as well as resins and balsams. Also suitable are those of animal origin, such as civet and castoreum. Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Fragrance compounds of the ester type are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexyl propionate, styrallyl propionate and benzyl salicylate. The ethers include, for example, benzyl ethyl ether, the aldehydes include, for example, the linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal, the ketones include, for example, the ionones and methyl cedryl ketone, the alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol, and the hydrocarbons include mainly the terpenes and balsams.However, it is preferred to use mixtures of different fragrances which together produce a pleasant fragrance note.Essential oils of relatively low volatility are primarily used as aroma ingredients and are also suitable as perfume oils, such as sage oil, chamomile oil, clove oil, melissa oil, mint oil, cinnamon leaf oil, linden flower oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil and lavandin oil. Bergamot Oil, Dihydromyrcenol, Lilial, Lyral, Citronellol, Phenylethyl Alcohol, Alpha-Hexylcinnamaldehyde, Geraniol, Benzyl Acetone, Cyclamen Aldehyde, Linalool, Boisambrene Forte, Ambroxan, Indole, Hedione, Sandelice, Lemon Oil, Mandarin Oil, Orange Oil, Allyl Amyl Glycolate, Cyclovertal, Lavandin Oil, Clary Sage Oil, Beta-Damascone, Geranium Oil Bourbon, Cyclohexyl Salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, Evernyl, Iraldein Gamma gamma), phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, irotyl and floramat, either alone or in mixtures, are preferred.

[0099] Suitable astringent antiperspirant active ingredients are primary salts of aluminum, zirconium or zinc.Such suitable antiperspirant active ingredients are, for example, aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesquichlorohydrate and their complexes, for example with 1,2-propylene glycol, aluminum hydroxyallantoinate, aluminum chloride tartrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate and their complexes, for example with amino acids such as glycine.

[0100] Film-forming and anti-dandruff agents Standard film-forming agents are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, polymers based on acrylic acid, quaternary cellulose derivatives, collagen, hyaluronic acid and its salts, and similar compounds.

[0101] Suitable antidandruff agents include Piroctone Olamine (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), Baypival® (climbazole), Ketoconazol® (4-acetyl-1-{4-[2-(2,4-dichlorophenyl)r-2-(1H-imidazol-1-ylmethyl)-1,3-dioxiran-c-4-ylmethoxyphenyl}-piperazine), ketoconazole, Elbio These include, but are not limited to, sodium sulphide, selenium disulphide, colloidal sulphur, sulphur polyethylene glycol sorbitan monooleate, sulphur ricinol polyethoxylate, sulphur tar distillate, salicylic acid (or in combination with hexachlorophene), undecylenic acid, monoethanolamide sulphosuccinate sodium salt, Lamepon® UD (protein / undecylenic acid condensate), zinc pyrithione, aluminium pyrithione and magnesium pyrithione / dipyrithione magnesium sulphate.

[0102] Carriers and Hydrotropes Preferred cosmetic carrier materials are solid or liquid (including highly viscous substances) at 25°C and 1013 mbar, such as glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water and mixtures of two or more of the above liquid carrier materials with water. Optionally, these preparations according to the invention may be produced with preservatives or solubilizers. Other preferred liquid carrier substances that may be a component of the preparations according to the invention are selected from the group consisting of oils, such as vegetable oils, neutral oils and mineral oils.

[0103] Preferred solid carrier materials which may be a constituent of the preparation according to the invention are hydrocolloids, such as starch, degraded starches, chemically or physically modified starches, dextrins, (powdered) maltodextrins (preferably with a dextrose equivalent value of 5 to 25, preferably 10 to 20), lactose, silicon dioxide, glucose, modified cellulose, gum arabic, gum ghatti, traganth, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, carob bean flour, alginates, agar, pectin and inulin, and mixtures of two or more of these solids, in particular maltodextrins (preferably with a dextrose equivalent value of 15 to 20), lactose, silicon dioxide and / or glucose.

[0104] Furthermore, hydrotropes, such as ethanol, isopropyl alcohol or polyols, may be used to improve the flow behavior. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols may contain other functional groups, more particularly amino groups, or may be modified with nitrogen. Typical examples are Glycerol Alkylene glycols, such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycol, with an average molecular weight of 100 to 1000 daltons Industrial oligoglycerol mixtures with a degree of self-condensation of 1.5-10, e.g. industrial diglycerol mixtures with a diglycerol content of 40-50% by weight Methylol compounds, such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol Lower alkyl glucosides, especially those containing 1 to 8 carbon atoms in the alkyl group, e.g. methyl and butyl glucosides Sugar alcohols containing 5 to 12 carbon atoms, such as sorbitol or mannitol Sugars containing 5 to 12 carbon atoms, such as glucose or sucrose Amino sugars, e.g. glucamine Dialcoholamines, such as diethanolamine or 2-aminopropane-1,3-diol It is.

[0105] Preservatives and / or product protectants Suitable preservatives are listed in the Annex to the Cosmetics Directive ("Cosmetics Directive"). 6, Parts A and B.

[0106] Suitable species may be selected from the group consisting of preservatives selected from the group consisting of: Benzoic acid and parahydroxybenzoic acid, their esters and salts, benzyl benzoate, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienoic acid (sorbic acid) and its salts, levulinic acid and its salts, anisic acid and its salts, perillic acid and its salts, cinnamic acid and its salts, formaldehyde and paraformaldehyde, 4-hydroxybenzaldehyde, ortho-, meta- and para-anisaldehyde, cinnamaldehyde, cinnamyl alcohol, 2-hydroxybenzoic acid, ... aryloxybiphenyl ether and its salts, 2-zinc-sulfidopyridine-N-oxide, inorganic sulfites and bisulfites, sodium iodate, chlorobutanol, 4-ethylmercury-(II) 5-amino-1,3-bis(2-hydroxybenzoic acid), its salts and esters, dehydrated acetic acid, formic acid, 1,6-bis(4-amidino-2-bromophenoxy)-n-hexane and its salts, sodium salt of ethylmercury(II)-thiosalicylic acid, phenylmercury and its salts, 10-undecylenyl Acid and its salts, 5-amino-1,3-bis(2-ethylhexyl)-5-methyl-hexahydropyrimidine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3-propanediol, 2,4-dichlorobenzyl alcohol, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)-urea, 4-chloro-m-cresol, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether, 4-chloro-3,5-dimethylphenol, 1, 1'-Methylene-bis(3-(1-hydroxymethyl-2,4-dioxyimidazolidin-5-yl)urea), poly-(hexamethylenediguanide) hydrochloride, (benzyloxymethoxy)-methanol hexamethylenetetramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azonia-adamantane chloride, 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethyl-2-butanone, 1,3-bis-(hydroxymethyl)-5.5-Dimethyl-2,4-imidazolidinedione, 1,2-Dibromo-2,4-dicyanobutane, 2,2'-Methylene-bis(6-bromo-4-chlorophenol), Bromochlorophene, 5-Chloro-2-methyl-3(2H)-isothiazolinone, 2-Methyl-3(2H)-isothiazolinone mixed with magnesium chloride and magnesium nitrate, 2-Octyl-2H-isothiazol-3-one, 1,2-Benzisothiazol-3(2H)-one, 2-Benzyl-4-chlorophenol, 3-(4-Chlorophenoxy)-1,2-propanediol (chlorphenesin), 2-Chloroacetamide, Chlorhexidine, Chlorhexidine acetate, Chlorhexidine gluconate, Chlorhexidine hydrochloride, N-Alkyl(C. 12 -C 22 )trimethylammonium bromide and chloride, 4,4-dimethyl-1,3-oxazolidine, N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)-N'-hydroxymethylurea, 1,6-bis(4-amidino-phenoxy)-n-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, 3-(4-chlorophenoxy)-1,2-propanediol, hyamine, alkyl-(C8-C 18 )-Dimethylbenzyl-ammonium chloride, alkyl-(C8-C 18 )-Dimethyl-benzyl-ammonium bromide, alkyl-(C8-C 18)-Dimethyl-benzyl-ammonium saccharinate, benzyl hemiformal, 3-iodo-2-propynyl butylcarbamate, sodium hydroxymethyl-aminoacetate or sodium hydroxymethyl aminoacetate, imidazolidinyl urea, diazolidinyl urea, sodium hydroxymethyl glycinate, DMDM ​​hydantoin, tropolone, (ethylenedioxy)dimethanol, 2-bromo-2-(bromomethyl)pentanedinitrile, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, α,α',α”-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethylene ethanol, pyridine-2-thiol-1-oxide, sodium salt, tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo[4,5-d]imidazole-2,5(1H,3H)-dione, 1,3-bis(hydroxymethyl)-1-(1,3,4-tris(hydroxy-methyl)-2,5-dioxoimidazolidin-4-yl)urea (diazolidinyl urea), 1,3-bis(hydroxy-methyl)-5,5-dimethylimidazolidine-2,4-dione, 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, cetylpyridinium chloride, caprylhydroxamic acid, sorbohydroxamic acid and mixtures thereof;1,3-Propanediol, Methylpropanediol, 1,2-Pentanediol, 1,2-Hexanediol, 1,2-Octanediol, 1,2-Decanediol, 1,5-Pentanediol, 1,6-Hexanediol, 1,8-Octanediol, 1,2-Decanediol, Ethylhexylglycerin, Hexoxy-propane-1,2-diol, Heptoxy-propane-1,2-diol, Octoxy-propane-1,2-diol, 3-Phenoxy-propane-1,2-diol, 3-Benzyloxy-propane-1,2-diol, 3-Phenylethyloxy-propane-1,2-diol, 3-Phenylpropyloxy-propane-1,2-diol, 3-Methylbenzyloxy-propane-1,2-diol, Sorbitan Caprylate, Triclosan, Climb sol, octopirox (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)-pyridone, 2-aminoethanol), chitosan, farnesol, 2-butyloctanoic acid, 2-benzylheptan-1-ol, glycerol monolaurate, bis(2-pyridylthio)zinc 1,1'-dioxide, N,N'-(decane-1,10)-diyldipyridin-1-yl-4-ylidene)-dioctan-1-amine dihydrochloride (octenidine dihydrochloride), thymol, eugenol, benzyl alcohol, 2-phenylethyl alcohol, 3-phenylpropanol, 2-phenoxyethanol, 1-phenoxy-propan-2-ol, 3-phenoxypropanol, benzyloxymethanol, 4-hydroxyacetophenone and mixtures thereof;

[0107] perfume oil Suitable perfume oils are mixtures of natural and synthetic fragrances. Natural fragrances include extracts of flowers (lily, lavender, rose, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway, juniper), peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calmus), wood (pinewood, sandalwood, guaiacwood, cedarwood, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), needles and branches (spruce, fir, pine, pumila), resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax). Animal raw materials, such as civet and beaver, can also be used.

[0108] Woody fragrance Suitable woody fragrances are selected from the following group: TIFF2025515108000005.tif157164

[0109] Amber scented fragrance Suitable fragrances with an amber scent are selected from the group consisting of: TIFF2025515108000006.tif55164

[0110] Fruity fragrance Suitable fragrances with a fruity smell are selected from the group consisting of: TIFF2025515108000007.tif192165 TIFF2025515108000008.tif183162

[0111] Musk scented fragrance Suitable fragrances with a musk scent are selected from the group consisting of: TIFF2025515108000009.tif86164 The fragrances summarized above also represent preferred embodiments of said second fragrances which form the basis of the claimed perfume composition.

[0112] dye Suitable dyes are, for example, the substances suitable and approved for cosmetic purposes described in the publication "Kosmetische Farbemittel" of the Farbstoff-kommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pages 81-106. Examples include cochineal red A (CI 16255), patent blue V (CI 42051), indigotine (CI 73015), chlorophyllin (CI 75810), quinoline yellow (CI 47005), titanium dioxide (CI 77891), indanthrene blue RS (CI 69800) and madder lake (CI 58000). Luminol may be present as a luminescent dye. Advantageous color pigments are, for example, titanium dioxide, mica, iron oxides (e.g. Fe2O3, Fe3O4, FeO(OH)) and / or tin oxide. Advantageous dyes are, for example, carmine, Berlin blue, chromium oxide green, ultramarine blue and / or manganese violet.

[0113] preparation Preferred compositions according to the invention are selected from the group of products for the treatment, protection, care and cleansing of the skin and / or hair or as make-up products, preferably as leave-on products (meaning that one or more compounds remain on the skin and / or hair for a longer period of time compared to rinse-off products).

[0114] The preparations according to the invention are preferably emulsions, such as W / O (water in oil), O / W (oil in water), W / O / W (water in oil in water), O / W / O (oil in water in oil) emulsions, PIT emulsions, Pickering emulsions, emulsions with a low oil content, microemulsions or nanoemulsions, solutions, such as oils (fatty oils or fatty acid esters, in particular C6-C 32 Fatty acid C2-C 30esters) or solutions in silicone oils, depending on the production method and ingredients, dispersions, suspensions, creams, lotions or milks, gels (including hydrogels, hydrodispersed gels, oleogels), sprays (e.g. pump sprays or sprays with propellants) or foams or impregnating liquids for cosmetic wipes, detergents, e.g. soaps, detergents, liquid detergents, shower and bath additives, bath products (capsules, oils, tablets, salts, bath salts, soaps, etc.), effervescent preparations, skin care products, e.g. emulsions (as mentioned above), ointments, pastes, gels (as mentioned above), oils, balsams, serums, powders (e.g. face powders, body powders), eau de parfum, eau de toilette, aftershaves, masks, pens Sills, sticks, roll-ons, pumps, aerosols (foaming, non-foaming, post-foaming), deodorants and / or antiperspirants, mouthwashes and mouth rinses, foot care products (including keratolytics, deodorants), insect repellents, sunscreens, after-sun preparations, shaving products, after-shave balms, pre- and after-shave lotions, depilatories, hair care products such as shampoos (including 2-in-1 shampoos, anti-dandruff shampoos, baby shampoos, shampoos for dry scalp, concentrated shampoos), conditioners, hair tonics, hair waters, hair rinses, styling creams, pomades, perm and setting lotions, hair sprays, styling aids (e.g. gels or waxes), hair smootheners (hair smoothing agents (detanning agents, relaxers), hair dyes, such as temporary direct hair dyes, semi-permanent hair dyes, permanent hair dyes, hair conditioners, hair mousses, eye care products, make-up, make-up removers or baby products.

[0115] The auxiliary substances and additives can be present in an amount of 5 to 99% by weight, preferably 10 to 80% by weight, based on the total weight of the preparation. The amount of cosmetic or dermatological auxiliary substances and additives and fragrances to be used in each case can be easily determined by the skilled person by simple trial and error, depending on the nature of the particular product.

[0116] The preparation may also contain water in an amount up to 99 weight percent, preferably from about 5 to about 80 weight percent, and more preferably from about 10 to about 50 or from about 60 to about 80 weight percent, based on the total weight of the preparation.

[0117] Detergent Preparations Another object of the present invention relates to a detergent formulation comprising said fragrance mixture or said perfume composition as described above. The formulation may contain said fragrance mixture or perfume composition in an amount ranging from about 0.01 to about 2% by weight, preferably from about 0.1 to 1% by weight, calculated on the basis of the formulation. Suitable examples of detergents include heavy duty powder detergents, heavy duty liquid detergents, light duty powder detergents, light duty liquid detergents, detergent tablets, fabric softeners, manual dishwashing detergents, multi-purpose cleaners, etc.

[0118] The detergent compositions of the present invention may contain any of the ingredients normally included in such compositions, such as anionic, nonionic, cationic, amphoteric or zwitterionic (co)surfactants, organic solvents, builders, enzymes, and additional adjuvants such as soil release agents, thickeners, colorants, fragrances, etc.

[0119] Representative examples of anionic and zwitterionic surfactants include: almondamidopropylamine oxide, almondamidopropyl betaine, aminopropyl lauryl glutamine, ammonium C12-15 alkyl sulfate, ammonium C12-16 alkyl sulfate, ammonium capryleth sulfate, ammonium coco monoglyceride sulfate, ammonium cocosulfate, ammonium cocoyl isethionate, ammonium cocoyl sarcosinate, ammonium C12-15 pareth sulfate, ammonium C9-10 perfluoroalkyl sulfonate, ammonium dinonyl sulfosuccinate, ammonium dodecylbenzene sulfonate. nate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 sulfate, ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myreth sulfate, ammonium myristyl sulfate, ammonium nonoxynol-4 sulfate, ammonium nonoxynol-30 sulfate, ammonium oleate, ammonium palm kernelate Kernel Sulfate, Ammonium Stearate, Ammonium Thalate, AMPD-Isostearyl Hydrolyzed Collagen, AMPD-Rosin Hydrolyzed Collagen, AMP-Isostearyl Hydrolyzed Collagen, AMP-Isostearyl Hydrolyzed Keratin, AMP-Isostearyl Hydrolyzed Soy Protein, AMP-Isostearyl Hydrolyzed Wheat Protein, Apricot Amidopropyl Betaine, Arachidic Acid, Arginine Hexyldecyl Phosphate, Avocado Amidopropyl Betaine, Avocado Oil Glycereth-8 Ester, Babassu Acid, Babassu Amidopropyl Amine Oxide, Babassu Amidopropyl Betaine, Beeswax Acid (BeeswaxAcid), Behenamidopropyl Betaine, Behenamine Oxide, Beheneth-25, Beheneth-30, Behenic Acid, Behenyl Betaine, Bis-Butyl Dimethicone Polyglyceryl-3, Butoxynol-5 Carboxylic Acid, Butoxynol-19 Carboxylic Acid, Butyldimonium Hydroxypropyl Butylglucoside Chloride, Butyldimonium Hydroxypropyl Laurylglucoside Chloride, Butyl Glucoside, Butyl Glucoside Caprate, Butyl Glu Coside Hydroxypropyltrimonium Chloride, Butyl Octanoic Acid, C18-36 Acid, C20-40 Acid, C30-50 Acid, C16-22 Acid Amide MEA, Calcium Dodecyl Benzene Sulfonate, Calcium Lauroyl Taurate, C9-16 Alkane / Cycloalkane, C10-14 Alkyl Benzene Sulfonic Acid, C12-14 Alkyl Diaminoethyl Glycine HCL, C9-15 Alkyl Phosphate, Candida Bombicola (Candida Bombicola / Glucose / Methyl Rapeseedate Ferment, Canolamidopropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glucoside, Capryl / Capramidopropyl Betaine, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Capryloyl Collagen Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids, Caprylyl / Capryl Glucoside, Caprylyl / Capryl Wheat Bran / Straw Glycosides, Caprylyl Glucoside,

[0120] Caprylyl Glyceryl Ether, Caprylyl Pyrrolidone, Carnitine, Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Ceteareth-4 Phosphate, Ceteareth-5 Phosphate, Ceteareth-10 Phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Cetyl Betaine, Chrysanthemum Sinense Flower Extract Extract), C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidoethyl Betaine, Cocamidopropyl Amine Oxide, Cocamidopropyl Betaine Amide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid, Coceth-7 Carboxylic Acid, Coceth-4 Glucoside, Cocoamphodipropionic Acid, Cocobetaine Amido Amphopropionate, Coco Betaine, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Coco Glucoside, Coco Glucoside Hydroxypropyltrimonium Chloride, Coco Hydroxysultaine, Coco Morpholine Oxide, Coconut Acid, Coconut Oil Glycereth-8 Esters, Coco / Oleamidopropyl Betaine, Coco Sultaine, Coco / Sunflower Amidopropyl Betaine, Cocoyl Choline Methosulfate,

[0121] Cocoyl glutamic acid, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn acid, cottonseed acid, cottonseed oil glyceryl-8 ester, C10-16 pareth-1, C10-16 pareth-2, C11-13 pareth-6, C11-13 pareth-9, C11-13 pareth-10, C11-15 pareth-30, C11-15 pareth-40, C12-13 pareth-1, C12-13 pareth-23, C12-14 pareth-5, C12-14 pareth-9, C1 3-15 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 carboxylic acid, C9-11 Pareth-8 carboxylic acid, C11-15 Pareth-7 carboxylic acid, C12-13 Pareth-5 carboxylic acid, C12-1 3 Pareth-7 carboxylic acid, C12-13 Pareth-8 carboxylic acid, C12-13 Pareth-12 carboxylic acid, C12-15 Pareth-7 carboxylic acid, C12-15 Pareth-8 carboxylic acid, C12-15 Pareth-12 carboxylic acid, C14-15 Pareth-8 carboxylic acid, C6-10 Pareth-4 phosphate, C12-13 Pareth-2 phosphate, C12-13 Pareth-10 phosphate, C12-15 Pareth-6 phosphate, C12-15 Pareth-8 phosphate, C12-15 Pareth-10 phosphate, C12-16 Pareth-6 phosphate, C4-18 Perfluoroalkylethylthiohydroxypropyltrimonium chloride, Cupuassuamidopropyl betaineBetaine), DEA-C12-13 Alkyl Sulfate, DEA-C12-15 Alkyl Sulfate, DEA-Ceteareth-2 Phosphate, DEA-Cetyl Sulfate, DEA-Cocoamphodipropionate, DEA-C12-13 Pareth-3 Sulfate, DEA-Cyclocarboxypropyloleate, DEA-Dodecylbenzenesulfonate, DEA-Isostearate, DEA-Laureth Sulfate, DEA-Lauryl Sulfate, DEA-Linoleate, DEA-Methyl Myristate Sulfonate, DEA-Myreth Sulfate, DEA-Myristate, DEA-Myristyl Sulfate, DEA-Oleth-5 Phosphate, DEA-Oleth-20 Phosphate, DEA PG-oleate, deceth-7 carboxylic acid, deceth-7 glucoside, deceth-9 phosphate, decylamine oxide, decylbetaine, decylglucoside, decyltetradeceth-30, decyltetradecylamine oxide,

[0122] Diammonium Lauramide-MEA Sulfosuccinate, Diammonium Lauryl Sulfosuccinate, Diammonium Oleamide PEG-2 Sulfosuccinate, Dibutoxymethane, Di-C12-15 Pareth-2 Phosphate (Di-CI 2-15 Pareth-2 Phosphate), Di-C12-15 Pareth-4 Phosphate, Di-C12-15 Pareth-6 Phosphate, Di-C12-15 Pareth-8 Phosphate, Di-C12-15 Pareth-10 Phosphate, Didodecyl Butane Tetracarboxylate, Diethylamine Laureth Sulfate, Diethylhexyl Sodium Sulfosuccinate, Dihydroxyethyl C8-10 Alkoxypropylamine Oxide, Dihydroxyethyl C9-11 Alkoxypropylamine Oxide, Dihydroxyethyl C12-15 Alkoxypropylamine Oxide, Dihydroxyethyl Cocamine Oxide, Dihydroxyethyl Lauramine Oxide, Dihydroxyethyl Stearamine Oxide, Dihydroxyethyl Tallowamine Oxide, Dimethicone PEG-7 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG- 12 / 4 Phosphate, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone Propyl PG-Betaine, Dimyristyl Phosphate, Dioleoylamidoethyl Hydroxyethylmonium Methosulfate, DIPA-Hydrogenated Cocoate, DIPA-Lanolate, DIPA-Myristate, Dipotassium Capryloyl Glutamate, Dipotassium Lauryl Sulfosuccinate, Dipotassium Undecylenoyl Glutamate, Babassuamide MEA-Sulfosuccinate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Capryloyl Glutamate, Disodium Cetearyl Sulfosuccinate, Disodium Cetyl Phenyl Ether Disulfonate, Disodium Cetyl Sulfosuccinate, Disodium Cocamide MEA-Sulfosuccinate, Disodium Cocamide MIPA PEG-4 disodium sulfosuccinate,

[0123] Cocamide MIPA Sulfosuccinate Disodium, Cocamide PEG-3 Sulfosuccinate Disodium, Coceth-3 Sulfosuccinate Disodium, Cocoamphocarboxyethylhydroxypropylsulfonate Disodium, Cocoamphodiacetate Disodium, Cocoamphodipropionate Disodium, Coco-glucoside Sulfosuccinate Disodium, Coco-sulfosuccinate Disodium, Cocoyl Butylgluceth-10 Sulfosuccinate Disodium, Cocoyl Glutamate Disodium, C12-14 Pareth-1 Sulfosuccinate Disodium, C12-14 Pareth-2 Sulfosuccinate Disodium, C12-15 Pareth Sulfosuccinate Disodium, C12-14 Sec-Pareth-3 Sulfosuccinate Disodium, C12-14 Sec-Pareth-5 Sulfosuccinate Disodium, C12-14 Disodium Sec-Palace-7 Sulfosuccinate, Disodium C12-14 Sec-Palace-9 Sulfosuccinate, Disodium C12-14 Sec-Palace-12 Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosuccinate, Disodium Decyl Phenyl Ether Disulfonate, Disodium Dihydroxyethyl Sulfosuccinyl Undecylenate, Disodium Ethylene Dicocamide PEG-15 Disulfate, Disodium Hydrogenated Cottonseed Glyceride Sulfosuccinate, Disodium Hydrogenated Tallow Glutamate, Disodium Hydroxydecyl Sorbitol Citrate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamide MEA Sulfosuccinate, Disodium Isodecyl Sulfosuccinate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamide MEA Sulfosuccinate, Disodium Stearamide MIPA-Sulfosuccinate, Disodium Isostearoamphodiacetate, Disodium Isostearoamphodipropionate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramide MEA-Sulfosuccinate, Disodium Lauramide MIPA Glycol Sulfosuccinate, Disodium Lauramide PEG-2 Sulfosuccinate, Disodium Lauramide PEG-5 Sulfosuccinate, Disodium Laureth-5 Carboxyamphodiacetate, Disodium Laureth-7 CitrateCitrate), sodium laureth disulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium lauriminobishydroxypropylsulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate,

[0124] Disodium Lauryl Tocopheryl Phosphate, Disodium Lauroamphodiacetate, Disodium Lauroamphodipropionate, Disodium N-Lauroyl Aspartate, Disodium Lauroyl Glutamate, Disodium Lauryl Phenyl Ether Disulfonate, Disodium Lauryl Sulfosuccinate, Disodium Myristamide MEA-Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamide MEA-Sulfosuccinate, Disodium Oleamide MIPA-Sulfosuccinate, Disodium Oleamide PEG-2 Sulfosuccinate, Disodium Oleamide Amphodipropionate, Disodium Oleth-3 Sulfosuccinate, Disodium Oleyl Phosphate, Disodium Oleyl Sulfosuccinate , Palmitamide PEG-2 Disodium Sulfosuccinate, Palmitoleamide PEG-2 Disodium Sulfosuccinate, PEG-4 Cocamide MIPA Disodium Sulfosuccinate, PEG-12 Dimethicone Disodium Sulfosuccinate, PEG-8 Palm Glyceride Disodium Sulfosuccinate, PPG-2-Isodeceth-7 Carboxyamphodiacetate Disodium, Ricinoleamide MEA Disodium Sulfosuccinate, Sitosterol-14 Disodium Sulfosuccinate, Soyamphodiacetate Disodium, Stearamide MEA Disodium Sulfosuccinate, Steariminodipropionate Disodium, Stearoamphodiacetate Disodium, Stearoyl Glutamate Disodium, Stearyl Sulfosuccinamate Disodium (Disodium Stearyl Sulfosuccinamate, Disodium Stearyl Sulfosuccinate, Disodium 2-Sulfolaurate, Disodium 2-Sulfopalmitate, Disodium Talamide MEA Sulfosuccinate, Disodium Tallowamide MEA Sulfosuccinate, Disodium Tallow Amphodiacetate, Disodium Tallow Iminodipropionate, Disodium Tallow Sulfosuccinate, Disodium Tridecyl Sulfosuccinate, Disodium Undecylenamide MEA Sulfosuccinate, Disodium Undecylenamide PEG-2 Sulfosuccinate, Disodium Undecylenoyl Glutamate, Disodium Wheat Germamido MEA SulfosuccinateMEA-Sulfosuccinate), Wheat Germ PEG-2 Disodium Sulfosuccinate,

[0125] Wheat Germ Amphodiacetate Disodium, Di-TEA-Cocamide Diacetate, Di-TEA-Oleamide PEG-2 Sulfosuccinate, Di-TEA-Palmitoyl Aspartate, Ditridecyl Sodium Sulfosuccinate, Dodecyl Benzene Sulfonic Acid, Erucamidopropyl Hydroxysultaine, Ethylhexeth-3 Carboxylic Acid, Ethyl PEG-15 Cocamine Sulfate, Glyceryl Capryl Ether, Hexyldecanoic Acid, Hydrogenated Coconut Acid, Hydrogenated Laneth-25, Hydrogenated Menhaden Acid, Hydrogenated Palm Acid, Hydrogenated Palm Kernel Amine Oxide, Hydrogenated Tallow Acid, Hydrogenated Tallow Amine Oxide, Hydrogenated Tallow Betaine, Hydrogenated Talloweth-25, Hydrogenated Tallowoyl Glutamic Acid Acid), Hydrolyzed Candida Bombicola Extract, Hydroxyceteth-60, Hydroxyethylacetemonium PG-Dimethicone, Hydroxyethyl Butylamine Laureth Sulfate, Hydroxyethyl Carboxymethyl Cocamidopropylamine, Hydroxyethyl Hydroxypropyl C12-15 Alkoxypropylamine Oxide, Hydroxylauryl / Hydroxymyristyl Betaine, Hydroxystearic Acid, Hydroxysuccinimidyl C10-40 Isoalkyl AcidateAcidate), Hydroxysuccinimidyl C21-22 Isoalkyl Acidate, Hydroxysultaine, IPDI / PEG-15 Soyamine Oxide Copolymer, IPDI / PEG-15 Soyethonium Ethosulfate Copolymer, IPDI / PEG-15 Soy Glycinate Copolymer, Isoceteth-30, Isolaureth-4 Phosphate, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropanolamine Lanolate, Isopropylamine Dodecyl Betaine Benzene sulfonate, isostearamidopropyl amine oxide, isostearamidopropyl betaine, isostearamidopropyl morpholine oxide, isosteareth-8, isosteareth-16, isosteareth-22, isosteareth-25, isosteareth-50, isostearic acid, isostearoyl hydrolyzed collagen, jojoba oil PEG-150 ester, jojoba wax PEG-80 ester, jojoba wax PEG-120 ester, laneth-20, laneth-25, laneth-40,

[0126] Laneth-50, Laneth-60, Laneth-75, Lanolinic Acid, Lauramidopropylamine Oxide, Lauramidopropyl Betaine, Lauramidopropyl Hydroxysultaine, Lauramine Oxide, Lauraminopropionic Acid, Laurdimonium Hydroxypropyl Decyl Glucoside Chloride, Laurdimonium Hydroxypropyl Lauryl Glucoside Chloride, Laureth-16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-3 8, Laureth-40, Laureth-3 Carboxylic Acid, Laureth-4 Carboxylic Acid, Laureth-5 Carboxylic Acid, Laureth-6 Carboxylic Acid, Laureth-8 Carboxylic Acid, Laureth-10 Carboxylic Acid, Laureth-11 Carboxylic Acid, Laureth-12 Carboxylic Acid, Laureth-13 Carboxylic Acid, Laureth-14 Carboxylic Acid, Laureth-17 Carboxylic Acid, Laureth-6 Citric Acid, Laureth-7 Citric Acid, Laureth-1 Phosphate, Laureth-2 Phosphate, Laureth-3 Phosphate, Laureth-4 Phosphate, Laureth- Laureth-7 Phosphate, Laureth-8 Phosphate, Laureth-7 Tartaric Acid, Lauryl Acid, Lauriminobispropanediol, Lauriminodipropionic Acid, Lauroamphodipropionic Acid, Lauroyl Beta-Alanine, Lauroyl Collagen Amino Acids, Lauroyl Ethyltrimonium Methosulfate, Lauroyl Hydrolyzed Collagen, Lauroyl Hydrolyzed Elastin, Lauroyl Methylglucamide, Lauroyl Sarcosine, Lauroyl Silk Amino Acids, Lauryl Betaine, Lauryl Dimethicone / Polyglycerin-3 Crosspolymer, Lauryldimonium Hydroxypropyl Cocoglucoside Chloride, Lauryl Glucoside, Lauryl Glucoside Hydroxypropyltrimonium Chloride, Lauryl Glycol Hydroxypropyl Ether, Lauryl Hydroxysultaine, Lauryl Malamide, Lauryl Methylglucamide, Lauryl / Myristyl Glycol Hydroxypropyl Ether, Lauryl / Myristyl Wheat Bran / Straw Glycoside Wheat Bran / Straw Glycosides), Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Pyrrolidone, Lauryl Sultaine, Linoleic Acid, Linolenic Acid, Flaxseed Acid, Lysine Cocoate,

[0127] Macadamia Seed Oil Glycereth-8 Esters, Magnesium Coceth Sulfate, Magnesium Coco Sulfate, Magnesium Isododecylbenzene Sulfonate, Magnesium Laureth-11 Carboxylate, Magnesium Laureth Sulfate, Magnesium Laureth-5 Sulfate, Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfonate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myreth Sulfate, Magnesium Oleth Sulfate, Magnesium / TEA-Cocosulfate, Manicouagan Clay, MEA-Cocoate, MEA-Laureth-6 Carboxylate, MEA-Laureth Sulfate, MEA-Lauryl Sulfate, MEA PPG-6 Laureth-7 Carboxylate, MEA-PPG-8 Steareth-7 Carboxylate, MEA-Undecylenate, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, Methoxy PEG-450 Amido Glutaroyl Succinimide, Methoxy PEG-450 Amido Hydroxysuccinimidyl Succinamate, Methoxy PEG-450 Maleimide, Methylmorpholine Oxide, Milk Amidopropylamine Oxide, Milk Amidopropyl Betaine, Mincamidopropylamine Oxide, Mincamidopropyl Betaine, MIPA C12-15 Pareth Sulfate, MIPA Dodecyl Benzene Sulfonate, MIPA Laureth Sulfate, MIPA Lauryl Sulfate, Mixed Isopropanolamine Lanolate lsopropanolaminesLanolate), mixed isopropanolamine lauryl sulfate, mixed isopropanolamine myristate, morpholine oleate, morpholine stearate, myreth-3 carboxylic acid, myreth-5 carboxylic acid, myristalkonium chloride, myristamidopropylamine oxide, myristamidopropyl betaine, myristamidopropyl dimethylamine phosphate, myristamidopropyl hydroxysultaine, myristamidopropyl PG-dimonium chloride phosphate, myristamido oxide, myristaminopropionic acid, myristic acid, myristoyl ethyltrimonium methosulfate, myristoyl glutamic acid,

[0128] Myristoyl Hydrolyzed Collagen, Myristoyl Sarcosine, Myristyl Betaine, Myristyl / Cetylamine Oxide, Myristyldimonium Hydroxypropyl Cocoglucoside Chloride, Myristyl Glucoside, Myristyl Phosphate, Nonoxynol-20, Nonoxynol-23, Nonoxynol-25, Nonoxynol-30, Nonoxynol-35, Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 Carboxylic Acid, Nonoxynol-8 Carboxylic Acid, Nonoxynol-10 Carboxylic Acid, Nonoxynol-3 Phosphate, Nonoki Cinol-4 phosphate, Nonoxynol-6 phosphate, Nonoxynol-9 phosphate, Nonoxynol-10 phosphate, Nonylnonoxynol-30, Nonylnonoxynol-49, Nonylnonoxynol-100, Nonylnonoxynol-150, Nonylnonoxynol-7 phosphate, Nonylnonoxynol-8 phosphate, Nonylnonoxynol-9 phosphate, Nonylnonoxynol-10 phosphate, Nonylnonoxynol-11 phosphate, Nonylnonoxynol-15 phosphate, Nonylnonoxynol-24 phosphate, Oatamidopropyl betaine Betaine), Octoxynol-16, Octoxynol-25, Octoxynol-30, Octoxynol-33, Octoxynol-40, Octoxynol-70, Octoxynol-20 Carboxylic Acid, Octyldodeceth-20, Octyldodeceth-25, Octyldodeceth-30, Oleamidopropylamine Oxide, Oleamidopropyl Betaine, Oleamidopropyl Hydroxysultaine, Oleamine Oxide, Oleic Acid, Oleoyl Additive Hydrolyzed Collagen, Oleoyl Sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleth-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Olivamidopropylamine Oxide, Olivamidopropyl Betaine, Oliv Acid, Olivoyl Hydrolyzed Wheat Protein, Ophiopogon Extract StearateStearate), Ozonized Oleth-10, Ozonized PEG-10 Oleate, Ozonized PEG-14 Oleate, Ozonized Polysorbate 80, Palm Acid, Palmamidopropyl Betaine,

[0129] Palmitic Acid, Palmitoyl Collagen Amino Acid, Palmitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Milk Protein, Palmitoyl Hydrolyzed Wheat Protein, Palmitoyl Keratin Amino Acid, Palmitoyl Oligopeptide, Palmitoyl Silk Amino Acid, Palm Kernel Acid, Palmitoyl Amino ... In, Peach Kernel Oil Glycereth-8 Esters, Peanut Acid, PEG-10 Castor Oil, PEG-40 Castor Oil, PEG-44 Castor Oil, PEG-50 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibenzylglycerin, PEG-100 Castor Oil, PEG-100 Cocamide ... Henate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl SoyateSoyate), PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tallowate, PEG-80 Glyceryl Tallowate, PEG-82 Glyceryl Tallowate, PEG-130 Glyceryl Tallowate, PEG-200 Glyceryl Tallowate, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil, PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin,

[0130] PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glycerides (PEG-70 Mango)Glycerides), PEG-20 Mannitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanate, PEG-30 Oleamine, PEG-20 Oleate, PEG-23 Oleate, PEG-32 Oleate, PEG-36 Oleate, PEG-75 Oleate, PEG-150 Oleate, PEG-20 Palmitate, PEG-150 Polyglyceryl-2 Tristearate, PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG -10 / 30 copolymer, PEG / PPG-10 / 65 copolymer, PEG / PPG-12 / 35 copolymer, PEG / PPG-16 / 17 copolymer, PEG / PPG-20 / 9 copolymer, PEG / PPG-20 / 20 copolymer, PEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, PEG / PPG-28 / 30 copolymer mer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer, PEG / PPG-300 / 55 copolymer,

[0131] PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG / PPG-4 / 2 Propylheptyl Ether, PEG / PPG-6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol (PEG-5 Rapeseed Sterol)Sterol), PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Glycerides, PEG-75 Shea Glycerides, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearamide Carboxylic Acid, PEG -9 Stearamide Carboxylic Acid, PEG-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG-120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallate, PEG-50 Tallowamide, PEG-2 Tallowamide DEA, PEG-20 Tallowate, PEG-66 Trihydroxystearin, PEG-200 Trihydroxystearin, PEG-60 Camellia Glycerides (PEG-60 Tsubakiate Glycerides), Pelargonic Acid, Pentadoxynol-200, Phenes-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288,

[0132] Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octacaprylate Sononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomaderis Melahou Flower / Leaf Extract Kumerahou Flower / Leaf Extract, Poria Cocos Extract, Potassium Abithoyl Hydrolyzed Collagen, Potassium Babassuate, Potassium Behenate, Potassium C9-15 Alkyl Phosphate, Potassium C11-15 Alkyl Phosphate, Potassium C12-13 Alkyl Phosphate, Potassium C12-14 Alkyl Phosphate, Potassium Caprate, Potassium Capryloyl Glutamate, Potassium Capryloyl Hydrolyzed Rice Protein, Potassium Castorate, Potassium CocoateCocoate), potassium cocoyl glutamate, potassium cocoyl glycinate, potassium cocoyl hydrolyzed caseinate, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin, potassium cocoyl hydrolyzed oat protein, potassium cocoyl hydrolyzed potato protein, potassium cocoyl hydrolyzed rice bran protein, potassium cocoyl hydrolyzed rice protein, potassium cocoyl hydrolyzed silk, potassium cocoyl hydrolyzed soy protein, potassium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed yeast protein,

[0133] Potassium Cocoyl PCA, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Cornate, Potassium Cyclocarboxypropyloleate, Potassium Dihydroxyethyl Cocamine Oxide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecylbenzene Sulfonate, Potassium Hempseedate, Potassium Hydrogenated Coconut Acid Cocoate), potassium hydrogenated palmate, potassium hydrogenated tallowate, potassium hydroxystearate, potassium isostearate, potassium lanolate, potassium laurate, potassium laureth-3 carboxylate, potassium laureth-4 carboxylate, potassium laureth-5 carboxylate, potassium laureth-6 carboxylate, potassium laureth-10 carboxylate, potassium laureth phosphate, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, potassium lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed pea protein, potassium lauroyl hydrolyzed soy protein, potassium lauroyl PCA, potassium lauroyl pea amino acid, lauroyl Potassium Sarcosinate, Potassium Lauroyl Silk Amino Acids, Potassium Lauroyl Wheat Amino Acids, Potassium Lauryl Phosphate, Potassium Lauryl Sulfate, Potassium Linoleate, Potassium Metaphosphate, Potassium Methyl Cocoyl Taurate, Potassium Myristate, Potassium Myristoyl Glutamate, Potassium Myristoyl Hydrolyzed Collagen, Potassium Octoxynol-12 Phosphate, Potassium Oleate, Potassium Oleoyl Hydrolyzed Collagen, Potassium Olivoyl Hydrolyzed Oat Protein, Potassium Olivoyl Hydrolyzed Wheat Protein, Potassium Olivoyl / Lauroyl Wheat Amino Acids, Potassium Olivoyl PCA, Potassium PalmitatePalmate), Potassium Palmitate, Potassium Palmitoyl Hydrolyzed Corn Protein, Potassium Palmitoyl Hydrolyzed Oat Protein, Potassium Palmitoyl Hydrolyzed Rice Protein, Potassium Palmitoyl Hydrolyzed Sweet Almond Protein,

[0134] Potassium Palmitoyl Hydrolyzed Wheat Protein, Potassium Palm Kernelate, Potassium Peanutate, Potassium Rapeseed Oil Fatty Acid, Potassium Ricinoleate, Potassium Safflowerate, Potassium Soyate, Potassium Stearate, Potassium Stearoyl Hydrolyzed Collagen, Potassium Tartarate Tallate), potassium tallowate, potassium taurine laurate, potassium trideceth-3 carboxylate, potassium trideceth-4 carboxylate, potassium trideceth-7 carboxylate, potassium trideceth-15 carboxylate, potassium trideceth-19 carboxylate, potassium trideceth-6 phosphate, potassium trideceth-7 phosphate, potassium camellia acid, potassium undecylenate, potassium undecylenoyl hydrolyzed collagen, potassium undecylenoyl hydrolyzed rice protein, PPG-30-buteth-30, PPG-36-buteth-36, PPG-38-buteth-37, PPG-30-capryleth-4 phosphate, PPG-10 cetyl ether phosphate, PPG-2 C9-11 Pareth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylic Acid, PPG-30 Ethylhexeth-4 Phosphate, PPG-20 Glycereth-30, PPG-2 Hydroxyethyl Coco / Isostearamide, PPG-2-Isodeceth-8, PPG-2-Isodeceth-10, PPG-2-Isodeceth-18, PPG-2-Isodeceth-25, PPG-4-Isodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Oil Fatty Acid, Rice Bran Acid, Rice Oil Glycereth-8 Ester, Ricinoleamidopropyl Betaine, Ricinoleic Acid, Ricinoleth-40, Safflower Acid, Sapindus oafensis Oahuensis Fruit Extract, Soapwort (Saponaria Officinalis) Root Powder, Saponin, Soap-K, Soap-Na / K, Soap BaseSoji), Soap Base-K, Sesame Oil Glycereth-8 Ester, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butter Amidopropyl Betaine, Shea Butter Glycereth-8 Ester, Sodium Arachidate, Sodium Argan Amphodiacetate, Sodium Astrocaryum Murumuruate, Sodium Avocado Acid, Sodium Babassu Amphoacetate, Sodium Babassu Acid, Sodium Babassu Sulfate, Sodium Behenate,

[0135] Sodium Bisglycolic Acid Sulfosuccinate, Sodium Bishydroxyethylglycinate Cocoglucoside Crosspolymer, Sodium Bishydroxyethylglycinate Lauryl Glucoside Crosspolymer, Sodium Boramide Propyl PG-Dimonium Chloride Phosphate, Sodium Butoxynol-12 Sulfate, Sodium Butyl Glucoside Hydroxypropyl Phosphate, Sodium C13-17 Alkanesulfonate, Sodium C14-18 Alkanesulfonate, Sodium C12-15 Alkoxypropyliminodipropionate, Sodium C10-16 Alkyl Sulfate, Sodium C11-15 Alkyl Sulfate, Sodium C12-13 Alkyl Sulfate, Sodium C12-15 Alkyl Sulfate, Sodium C12-18 Alkyl Sulfate, Sodium C16-20 Alkyl Sulfate, Sodium C9-22 Alkyl Sec Sulfonate, Sodium C14-17 Alkyl Sec Sulfonate, Sodium Caprate, Sodium Caproamphoacetate, Capric Acid Sodium loamphohydroxypropylsulfonate, Sodium caproamphopropionate, Sodium caproyl methyl taurate, Sodium caprylate, Sodium capryleth-2 carboxylate, Sodium capryleth-9 carboxylate, Sodium capryloamphoacetate, Sodium capryloamphohydroxypropylsulfonate, Sodium capryloamphopropionate, Sodium capryloyl glutamate, Sodium capryloyl hydrolyzed wheat protein, Sodium caprylyl PG-sulfonate, Sodium caprylyl sulfonate, Sodium castor oil, Sodium ceteareth-13 carboxylate, Sodium cetearyl sulfate, Sodium ceteth-13 carboxylate, Sodium cetyl sulfate, Sodium cocamidopropyl PG-dimonium chloride phosphate, Sodium cocaminopropionate, Sodium coceth sulfate, Sodium coceth-30 sulfate, Sodium cocoa butter amphoacetate, Sodium cocoa butterate Cocoa Butterate, Sodium Cocoamphoacetate, Sodium Cocoamphohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cocoate, Sodium Coco / Babassu / Andiroba SulfateSulfate), Sodium Coco / Babasu Sulfate, Sodium Coco Glucoside Hydroxypropyl Phosphate,

[0136] Sodium Coco Glucoside Hydroxypropyl Sulfonate, Sodium Coco Glucoside Tartrate, Sodium Coco Glyceryl Ether Sulfonate, Sodium Coco / Hydrogenated Tallow Sulfate, Sodium Cocoiminodiacetate, Sodium Coco Monoglyceride Sulfate, Sodium Coco Monoglyceride Sulfonate, Sodium Coco PG-Dimonium Chloride Phosphate, Sodium Coco Sulfate, Sodium Coco Sulfoacetate, Sodium Cocoyl Alaninate, Sodium Cocoyl Amino Acids, Sodium Cocoyl Collagen Amino Acids, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutamate Glutaminate, Sodium Cocoyl Glycinate, Sodium Cocoyl / Hydrogenated Tallow Glutamate, Sodium Cocoyl Hydrolyzed Collagen, Sodium Cocoyl Hydrolyzed Keratin, Sodium Cocoyl Hydrolyzed Rice Protein, Sodium Cocoyl Hydrolyzed Silk, Sodium Cocoyl Hydrolyzed Soy Protein, Sodium Cocoyl Hydrolyzed Sweet Almond Protein, Sodium Cocoyl Hydrolyzed Wheat Protein, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Isethionate, Sodium Cocoyl Methylaminopropionate, Sodium Cocoyl Oat Amino Acids, Sodium Cocoyl / Palmoyl / Sunfloweroyl Glutamate Glutamate), Sodium Cocoyl Proline, Sodium Cocoyl Sarcosinate, Sodium Cocoyl Taurate, Sodium Cocoyl Threonate, Sodium Cocoyl Wheat Amino Acids, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium Corn Amphopropionate, Sodium Cottonseed Amphoacetate (SodiumCottonseedamphoacetate), C13-15 Pareth-8 Sodium Butyl Phosphate, C9-11 Pareth-6 Sodium Carboxylate, C11-15 Pareth-7 Sodium Carboxylate, C12-13 Pareth-5 Sodium Carboxylate, C12-13 Pareth-8 Sodium Carboxylate, C12-13 Pareth-12 Sodium Carboxylate, C12-15 Pareth-6 Sodium Carboxylate, C12-15 Pareth-7 Sodium Carboxylate, C12-15 Pareth-8 Sodium Carboxylate, C14-15 Pareth-8 Sodium Carboxylate, C12-14Sec-Pareth-8 Sodium Carboxylate,

[0137] C14-15 Pareth-PG Sodium Sulfonate, C12-13 Pareth-2 Sodium Phosphate, C13-15 Pareth-8 Sodium Phosphate, C9-15 Pareth-3 Sodium Sulfate, C10-15 Pareth Sodium Sulfate, C10-16 Pareth-2 Sodium Sulfate, C12-13 Pareth Sodium Sulfate, C12-15 Pareth Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfate, C13-15 Pareth-3 Sodium Sulfate, C12-14 Sec-Pareth-3 Sodium Sulfate, C12-15 Pareth-3 Sodium Sulfonate, C12-15 Pareth-7 Sodium Sulfonate, C12-15 Pareth-15 Sodium Sulfonate, Sodium Deceth-2 Carboxylate, Sodium Deceth Sulfate, Sodium Decyl Benzene Sulfonate, Sodium Decyl Glucoside Hydroxypropyl Phosphate, Sodium Decyl Glucoside Hydroxypropyl Sulfonate, Sodium Dilaureth-7 Citrate, Sodium Dilaureth-10 Phosphate, Sodium Dilinoleate, Sodium Dilaureth-8 Phosphate, Sodium Dodecyl Benzene Sulfonate, Sodium Ethyl 2-Sulfolaurate, Sodium Glyceryl Oleate Phosphate (Sodium Glyceryl Oleate Phosphate, Grape Seed Amidopropyl PG-Dimonium Chloride Phosphate, Grape Seed Sodium Amphoacetate, Grape Seed Sodium Amphoacetate, Sodium Grapeseedate, Hemp Seed Sodium Amphoacetate, Sodium Hexace-4 Carboxylate, Sodium Hydrogenated Cocoate, Sodium Hydrogenated Cocoyl Methyl Isethionate, Sodium Hydrogenated Palm Oil Fatty Acid, Sodium Hydrogenated Tallowate, Sodium Hydrogenated Tallowyl Glutamate, Sodium Hydroxylauryldimonium Ethyl Phosphate, Sodium Hydroxypropyl Palm Kernel Acid Sulfonate, Sodium Hydroxypropyl Phosphate Decyl Glucoside Crosspolymer, Sodium Hydroxypropyl Phosphate Lauryl Glucoside Crosspolymer, Sodium Hydroxypropyl Sulfonate Coco Glucoside Crosspolymer, Sodium Hydroxypropyl Sulfonate Decyl Glucoside Crosspolymer, Sodium Hydroxypropyl Sulfonate Lauryl Glucoside Crosspolymer,

[0138] Sodium Hydroxystearate, Sodium Isostearate, Sodium Isosteareth-6 Carboxylate, Sodium Isosteareth-11 Carboxylate, Sodium Isostearoamphoacetate, Sodium Isostearoamphopropionate, Sodium N-Isostearoylmethyltaurate, Sodium Lanosulfate, Sodium Lanolinate, Sodium Lardate, Sodium Lauramide Diacetate, Sodium Lauraminopropionate, Sodium Laurate, Sodium Laureth-3 Carboxylate, Sodium Laureth-4 Carboxylate, Sodium Laureth-5 Carboxylate, Sodium Laureth-6 Carboxylate, Sodium Laureth-8 Carboxylate, Sodium Laureth-11 Carboxylate, Sodium Laureth-12 Carboxylate, Sodium Laureth-13 Carboxylate, Sodium Laureth-14 Carboxylate, Sodium Laureth-16 Carboxylate, Sodium Laureth-17 Carboxylate, Sodium Laureth Sulfate, Sodium Laureth-5 Sulfate, Sodium Laureth-7 Sulfate, Sodium Laureth-8 Sulfate, Sodium Laureth-12 Sulfate, Sodium Laureth-40 Sulfate Sodium Laureth-7 Tartrate, Sodium Laurylaminodipropionate, Sodium Lauroamphoacetate, Sodium Lauroamphohydroxypropylsulfonate, Sodium LauroamphoPG-Acetate Phosphate, Sodium Lauroamphopropionate, Sodium Lauroyl Aspartate, Sodium Lauroyl Collagen Amino Acids, Sodium Lauroyl Glycine Propionate, Sodium Lauroyl Hydrolyzed Collagen, Sodium Lauroyl Hydrolyzed Silk, Sodium Lauroyl Hydroxypropylsulfonate, Sodium Lauroyl Iseethionate, Sodium Lauroyl Methylaminopropionate, Sodium Lauroyl Methylisethionate, Sodium Lauroyl Millet Amino AcidsAcids), Sodium Lauroyl / Myristoyl Aspartate, Sodium Lauroyl Oat Amino Acid, Sodium Lauroyl Sarcosinate, Sodium Lauroyl Silk Amino Acid, Sodium Lauroyl Taurate, Sodium Lauroyl Wheat Amino Acid, Sodium Lauryl Diethylenediaminoglycinate, Sodium Lauryl Glucose Carboxylate, Sodium Lauryl Glucoside Hydroxypropyl Phosphate,

[0139] Sodium Lauryl Glucoside Hydroxypropyl Sulfonate, Sodium Lauryl Glycol Carboxylate, Sodium Lauryl Hydroxyacetamide Sulfate, Sodium Lauryl Phosphate, Sodium Lauryl Sulfate, Sodium Lauryl Sulfoacetate, Sodium Linoleate, Sodium Macadamiaseedate, Sodium Mango Amphoacetate, Sodium Mango SeedateMangoseedate), Sodium / MEA Laureth-2 Sulfosuccinate, Sodium Methoxy PPG-2 Acetate, Sodium Methyl Cocoyl Taurate, Sodium Methyl Lauroyl Taurate, Sodium Methyl Myristoyl Taurate, Sodium Methyl Oleyl Taurate, Sodium Methyl Palmitoyl Taurate, Sodium Methyl Stearoyl Taurate, Sodium Methyl 2-Sulfolaurate, Sodium Methyl 2-Sulfopalmitate, Sodium Methyl Taurate Isopalmitamide, Sodium Methyl Taurate Cocoyl Methyl Taurate, Sodium Myreth Sulfate, Sodium Myristate, Sodium Myristamphoacetate, Sodium Myristoyl Glutamate, Sodium Myristoyl Hydrolyzed Collagen, Sodium Myristoyl Isethionate, Sodium Myristoyl Sarcosinate, Sodium Myristyl Sulfate, Sodium Nonoxynol-6 Phosphate, Sodium Nonoxynol-9 Phosphate, Sodium Nonoxynol-1 Sulfate Sodium nonoxynol-3 sulfate, sodium nonoxynol-4 sulfate, sodium nonoxynol-6 sulfate, sodium nonoxynol-8 sulfate, sodium nonoxynol-10 sulfate, sodium nonoxynol-25 sulfate, sodium octoxynol-2 ethanesulfonate, sodium octoxynol-2 sulfate, sodium octoxynol-6 sulfate, sodium octoxynol-9 sulfate, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropylsulfonate, sodium oleoamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl isethionate, sodium oleth sulfate, sodium oleyl methyl isethionate, sodium oleyl sulfate, sodium oliveamphoacetate, sodium olive fatty acid, sodium olivoyl glutamate, sodium palmamphoacetate, sodium palm fatty acid, sodium palm glyceride sulfonate,

[0140] Sodium Palmitate, Sodium Palmitoyl Hydrolyzed Collagen, Sodium Palmitoyl Hydrolyzed Wheat Protein, Sodium Palmitoyl Sarcosinate, Sodium Palm Kernelate, Sodium Palm Carnelyl Isethionate, Sodium Palmoyl Glutamate, Sodium Passiflora Edulis Seedate, Sodium Peanut Amphoacetate, Sodium Peanut Fatty Acid Peanutate), PEG-6 Sodium Cocamide Carboxylate, PEG-8 Sodium Cocamide Carboxylate, PEG-4 Sodium Cocamide Sulfate, PEG-3 Sodium Lauramide Carboxylate, PEG-4 Sodium Lauramide Carboxylate, PEG-8 Sodium Palm Glyceride Carboxylate, Sodium Pentaerythrityl Hydroxypropylminodiacetate Dendrimer, Sodium Propoxy PPG-2 Acetate, Sodium Rapeseed Oil Fatty Acid, Sodium Rice Bran Amphoacetate, Sodium Ricinoleate, Sodium Ricinoleoamphoacetate, Sodium Rosehip Amphoacetate, Sodium Rosinate, Sodium Safflower Fatty Acid, Sodium Saffloweroyl Hydrolyzed Soy Protein, Sodium Sesame Seed Oil Fatty Acid, Sodium SesamphoacetateSesamphoacetate, Shea Butter Sodium Amphoacetate, Sodium Soybean Oil Fatty Acid, Sodium Soy Hydrolyzed Collagen, Sodium Stearate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Stearoyl Caseinate, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl Hydrolyzed Silk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Lactalbumin, Sodium Stearoyl Methylisethionate, Sodium Stearoyl Oat Protein, Sodium Stearoyl Pea Protein, Sodium Stearoyl Soy Protein, Sodium Stearyl Dimethylglycine, Sodium Stearyl Sulfate, Sunflower Seed Sodium Amphoacetate, Sodium Surfactin, Sweet Almond Sodium Amphoacetate, Sodium Sweet Almond Fatty Acid (Sodium Sweet Almondate, Sodium Tallamphopropionate, Sodium Tallate,

[0141] Sodium Tallow Amphoacetate, Sodium Tallowate, Sodium Tallow Sulfate, Sodium Tamanuseedate, Sodium Taurate, Sodium Methyl Cocoyl Taurate, Sodium Taurate Laurate, Sodium / TEA-Lauroyl Collagen Amino Acids, Sodium / TEA-Lauroyl Hydrolyzed Collagen, Sodium / TEA-Lauroyl Hydrolyzed Keratin, Sodium / TEA-Lauroyl Keratin Amino Acids, Sodium / TEA-Undecylenoyl Collagen Amino Acids, Sodium / TEA-Undecylenoyl Hydrolyzed Collagen, Sodium / TEA-Undecylenoyl Hydrolyzed Corn Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Soy Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Wheat Protein, Sodium Theobroma Grandiflorum Seed Acid Seedate), Sodium Trideceth-3 Carboxylate, Sodium Trideceth-4 Carboxylate, Sodium Trideceth-6 Carboxylate, Sodium Trideceth-7 Carboxylate, Sodium Trideceth-8 Carboxylate, Sodium Trideceth-12 Carboxylate, Sodium Trideceth-15 Carboxylate, Sodium Trideceth-19 Carboxylate, Sodium Trideceth Sulfate, Sodium Tridecylbenzenesulfonate, Sodium Tridecyl Sulfate, Sodium Trimethylolpropane Hydroxypropyliminodiacetate Dendrimer, Sodium Undeceth-5 Carboxylate, Sodium Undecylenate, Sodium Undecylenoamphoacetate, Sodium Undecylenoamphopropionate, Sodium Undecylenoyl Glutamate, Sodium Wheat Germ AmphoacetateGermamphoacetate), Sorbeth-160 Tristearate, Soy Acid, Soyamidopropylamine Oxide, Soyamidopropyl Betaine, Soybean Oil Glycereth-8 Ester, Stearamidopropylamine Oxide, Stearamidpropyl Betaine, Stearamine Oxide, Steareth-15, Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyltrimonium Chloride, Stearoyl Glutamic Acid,

[0142] Stearoyl Sarcosine, Stearyl Betaine, Stearyldimonium Hydroxypropyl Butyl Glucoside Chloride, Stearyldimonium Hydroxypropyl Decyl Glucoside Chloride, Stearyldimonium Hydroxypropyl Lauryl Glucoside Chloride, Sulfated Castor Oil, Sulfated Coconut Oil, Sulfated Glyceryl Oleate, Sulfated Olive Oil, Sulfated Peanut Oil, Sunflower Amide MEA, Sunflower Seed Acid, Sunflower Seed Amide Propyl Hydroxyethyl Dimonium Chloride, Sunflower Seed Oil Glycereth-8 Ester, Tall Oil Acid, Tallow Acid, Tallowamidopropylamine oxide, tallowamidopropyl betaine, tallowamidopropyl hydroxysultaine, tallowamine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallowyl ethyl glucoside, TEA-abietyl hydrolyzed collagen, TEA-C12-14 alkyl phosphate, TEA-C10-15 alkyl sulfate, TEA-C11-15 alkyl sulfate, TEA-C12-13 alkyl sulfate, TEA-C12-14 alkyl sulfate, TEA-C12-15 alkyl sulfate, T EA-C14-17 Alkyl Sec Sulfonate, TEA-Canolate, TEA-Cocamide Diacetate, TEA-Cocoate, TEA-Coco-Sulfate, TEA-Cocoyl Alaninate, TEA-Cocoyl Glutamate, TEA-Cocoyl Glutaminate, TEA-Cocoyl Glycinate, TEA-Cocoyl Hydrolyzed Collagen, TEA-Cocoyl Hydrolyzed Soy Protein, TEA-Cocoyl Sarcosinate, TEA-Dimethicone PEG-7 Phosphate, TEA-Dodecyl Benzene Sulfonate, TEA-Hydrogenated Cocoyl ate, TEA-hydrogenated thallusyl glutamate, TEA-isostearate, TEA-isostearoyl hydrolyzed collagen, TEA-lauraminopropionate, TEA-laurate, TEA-laurate / myristate, TEA-laureth sulfate, TEA-lauroyl collagen amino acid, TEA-lauroyl glutamate, TEA-lauroyl hydrolyzed collagen, TEA-lauroyl keratin amino acid, TEA-lauroyl methylaminopropionate, TEA-lauroyl / myristoyl aspartate, TEA-lauroyl sarcosinate,TEA-lauryl phosphate, TEA-lauryl sulfate, TEA-myristaminopropionate, TEA-myristate, TEA-myristoyl hydrolyzed collagen,

[0143] TEA-Oleate, TEA-Oleoyl Hydrolyzed Collagen, TEA-Oleoyl Sarcosinate, TEA-Oleyl Sulfate, TEA-Palmitate, TEA-Palm Kernel Sarcosinate, TEA-PEG-3 Cocamide Sulfate, TEA-Rosinate, TEA-Stearate, TEA-Tallate, TEA-Tridecylbenzenesulfonate, TEA-Undecylenate, TEA-Undecylenoyl Hydrolyzed Collagen, Tetramethyldecynediol, Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinate Sulfosuccinamate, TIPA-Laureth Sulfate, TIPA-Lauryl Sulfate, TIPA-Myristate, TIPA-Stearate, Tocopherol Phosphate, Trehalose Undecylenoate, TM-C12-15 Pareth-2 Phosphate, TM-C12-15 Pareth-6 Phosphate, TM-C12-15 Pareth-8 Phosphate, TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Trideceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate, Tridecyl Benzene Sulfonic Acid, Trilaureth-9 Citric Acid, Trimethylolpropane Hydroxypropyl Bis-Hydroxyethylamine Dendrimer, Trisodium Lauroampho PG Acetate Chloride Phosphate PG-Acetate Chloride Phosphate, Undecanoic Acid, Undeceth-5 Carboxylic Acid, Undecylenamidopropylamine Oxide, Undecylenamidopropyl Betaine, Undecylenic Acid, Undecylenoyl Collagen Amino Acid, Undecylenoyl Glycine, Undecylenoyl Hydrolyzed Collagen, Undecylenoyl Wheat Amino Acid, Undecyl Glucoside, Wheat Germ Acid, Wheat Germ Aminopropylamine Oxide, Wheat Germ Aminopropyl Betaine, Yucca Schidigera Leaf / Root / Stem Extract, Yucca Schidigera Stem Extract, Zinc Coceth Sulfate and Zinc Coco Sulfate.

[0144] Nonionic Surfactants Alcohol Alkoxylate The nonionic surfactants added are preferably alkoxylated and / or propoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per mole of alcohol. C8-C 16 -alcohol alkoxylates, advantageously ethoxylated and / or propoxylated C 10 -C 15 - alcohol alkoxylates, in particular C having a degree of ethoxylation of 2 to 10, preferably 3 to 8, and / or a degree of propoxylation of 1 to 6, preferably 1.5 to 5 12 -C 14 Alcohol alkoxylates are particularly preferred. The quoted degrees of ethoxylation and propoxylation constitute statistical averages and can be whole or partial numbers for a particular product. Preferred alcohol ethoxylates and propoxylates have a narrow homolog distribution (narrow range ethoxylates / propoxylates, NRE / NRP). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples of these are (tallow) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO.

[0145] Alkyl Glycosides (APG®) Furthermore, as additional nonionic surfactants, alkyl glycosides satisfying the general formula RO(G)x can be added, for example as compounds, especially together with the anionic surfactants, where R denotes a primary linear or methyl-branched, especially 2-methyl-branched, aliphatic radical containing 8 to 22, preferably 12 to 18, carbon atoms, and G denotes a glycose unit containing 5 or 6 carbon atoms, preferably glucose. The degree of oligomerization x, which defines the distribution of monoglycosides and oligoglycosides, can be any number between 1 and 10, preferably between 1.1 and 1.4.

[0146] Fatty acid ester alkoxylate As the sole nonionic surfactant or in combination with other nonionic surfactants, Another class of preferred nonionic surfactants, particularly for use together with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters (preferably containing 1 to 4 carbon atoms in the alkyl chain), more particularly fatty acid methyl esters, for example as described in JP-A-58-217598 or preferably prepared by the process described in International Patent Application WO 90 / 13533, containing an average of 3 to 15 EOs, in particular C 2 O 4 O 5 to 12 EO 5 to 15 EO 6 to 12 EO 7 to 12 EO 8 to 12 EO 9 to 12 EO 10 to 12 EO 11 to 12 EO 12 to 12 EO 13 to 12 EO 14 to 14 EO 15 to 15 EO 16 to 16 EO 17 to 18 EO 18 to 19 EO 19 to 20 EO 21 to 22 EO 22 to 24 EO 23 to 25 EO 24 to 26 EO 25 to 27 EO 26 to 27 EO 27 to 28 EO 28 to 30 EO 29 to 31 EO 32 to 32 EO 33 to 33 EO 34 to 34 EO 35 to 35 EO 36 to 36 EO 37 to 37 EO 38 to 38 EO 39 to 39 EO 40 to 40 EO 41 to 42 EO 42 to 43 EO 44 to 45 EO 45 to 46 EO 46 to 47 EO 47 to 48 EO 48 to 49 EO 12 -C 18 Methyl esters of fatty acids are particularly preferred.

[0147] Amine Oxides Nonionic surfactants of the amine oxide type, such as N-cocoalkyl-N,N-dimethylamine oxide and N-tallowalkyl-N,N-dihydroxyethylamine oxide and fatty acid alkanolamides, are also suitable. The amount of these nonionic surfactants used is preferably equal to or less than the amount of the ethoxylated fatty alcohols used, in particular equal to or less than half that amount.

[0148] Gemini Surfactants The so-called gemini surfactants can be considered as further surfactants. In general, such compounds are understood to mean compounds with two hydrophilic and two hydrophobic groups per molecule. Generally, these groups are separated from each other by a "spacer". The spacer is usually a hydrocarbon chain intended to be long enough so that the hydrophilic groups are separated by a sufficient distance so that they can act independently of each other. These types of surfactants are generally characterized by an unusually low critical micelle concentration and an ability to strongly reduce the surface tension of water. However, in exceptional cases, not only dimeric but also trimeric surfactants are meant by the term gemini surfactants. Suitable gemini surfactants are, for example, sulfated hydroxy mixed ethers according to German patent application DE 4321022 A1 or dimeric alcohol bis- and trimer alcohol tris-sulfates and ether sulfates according to international patent application WO 96 / 23768 A1. Blocked end group dimeric and trimeric mixed ethers according to DE 19513391 A1 are particularly characterized by their bifunctionality and polyfunctionality. Gemini polyhydroxy fatty acid amides or polyhydroxy fatty acid amides, such as those described in the international patent applications WO 95 / 19953 A1, WO 95 / 19954 A1 and WO 95 / 19955 A1, can also be used.

[0149] Cationic Surfactants Tetraalkylammonium salts Cationically active surfactants contain a hydrophobic polymeric group which is necessary for cationic surface activity upon dissociation in aqueous solution. An important representative group of cationic surfactants has the general formula: 1 R 2 R 3 R 4 N + )X - where R 1 represents C1-C8 alkyl(alkenyl), R 2 , R 3 and R4 represent, independently of one another, an alk(en)yl radical having 1 to 22 carbon atoms. X is a counterion, preferably selected from the group of halides, alkyl sulfates and alkyl carbonates. Particularly preferred are cationic surfactants in which the nitrogen group is substituted with two long acyl groups and two short alk(en)yl groups.

[0150] Esterquat A further class of cationic surfactants particularly useful as co-surfactants in the present invention is represented by the so-called ester quats. Ester quats are generally understood to be quaternized fatty acid triethanolamine ester salts. They are known compounds that can be obtained by relevant methods of preparative organic chemistry. In this connection, reference is made to the international patent application WO 91 / 01295 A1, according to which triethanolamine is partially esterified with fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate or ethylene oxide. Furthermore, the German patent DE 4308794 C1 describes a process for the preparation of solid ester quats, in which the quaternization of triethanolamine esters is carried out in the presence of a suitable dispersant, preferably an aliphatic alcohol.

[0151] Typical examples of ester quats suitable for use according to the invention are products whose acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, where RCO is an acyl group containing 6 to 10 carbon atoms, and whose amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof, such as the so-called head fraction fatty acids. Ester quats whose acyl component is derived from a monocarboxylic acid containing 8 to 10 carbon atoms are preferably used. Other ester quats are those whose acyl component is derived from a dicarboxylic acid, such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. Overall, ester quats whose acyl component is derived from a mixture of monocarboxylic acids containing 6 to 22 carbon atoms and adipic acid are preferably used. The molar ratio of mono- and dicarboxylic acids in the final ester quat may range from 1:99 to 99:1, preferably from 50:50 to 90:10, more particularly from 70:30 to 80:20. Besides quaternized fatty acid triethanolamine ester salts, other suitable ester quats are quaternized ester salts of mono- / dicarboxylic acid mixtures with diethanolalkylamines or 1,2-dihydroxypropyldialkylamines. Ester quats may be obtained from both fatty acids and the corresponding triglycerides in mixture with the corresponding dicarboxylic acids. One such process, intended to be representative of the relevant prior art, is proposed in European patent EP 0750606B1. To produce the quaternized esters, a mixture of mono- and dicarboxylic acids with triethanolamine (based on available carboxyl functionality) may be used in a molar ratio of 1.1:1 to 3:1. With the performance properties of the ester quats in mind, ratios of 1.2:1 to 2.2:1, preferably 1.5:1 to 1.9:1, have proven particularly advantageous. The preferred ester quats are technical mixtures of mono-, di- and triesters having an average degree of esterification of 1.5 to 1.9.

[0152] Amphoteric surfactants Betaine Amphoteric or ampholytic surfactants have multiple functional groups that can be ionized in aqueous solution, thereby endowing the compound with anionic or cationic properties, depending on the conditions of the medium (see DIN 53900, July 1972). Near the isoelectric point (pH approx. 4), amphoteric surfactants form inner salts and become sparingly soluble or insoluble in water. Amphoteric surfactants are subdivided into ampholytes and betaines, the latter being present in solution as zwitterions. Ampholytes are ampholytes, i.e. compounds that have both acidic and basic hydrophilic groups and therefore behave as acids or bases, depending on the conditions. Betaines in particular are known surfactants, mainly prepared by carboxyalkylation, preferably carboxymethylation, of amine compounds. The starting material is preferably condensed with a halocarboxylic acid or its salt, more particularly sodium chloroacetate, to form one mole of salt per mole of betaine. The addition of unsaturated carboxylic acids, such as, for example, acrylic acid, is also possible. Examples of suitable betaines are of the formula R 1 R 2 R 3 N-(CH2) q COOX (in the formula, R 1 is an alkyl radical having 6 to 22 carbon atoms, R 2 is hydrogen or an alkyl group containing 1 to 4 carbon atoms, and R 3 are carboxyalkylation products of secondary and especially tertiary amines corresponding to the alkyl groups C, C is an alkyl group containing 1 to 4 carbon atoms, q is a number from 1 to 6 and X is an alkali and / or alkaline earth metal or ammonium. Typical examples are hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, C 12 / 14 -Cocoalkyl dimethylamine, myristyl dimethylamine, cetyl dimethylamine, stearyl dimethylamine, stearyl ethyl methylamine, oleyl dimethylamine, C 16 / 18- tallow alkyl dimethylamines and technical mixtures thereof, in particular the carboxymethylation products of dodecyl methylamine, dodecyl dimethylamine, dodecyl ethyl methylamine and technical mixtures thereof.

[0153] Alkylamide betaine Other suitable betaines have the formula R 1 CO(R 3 )(R 4 )-NH-(CH2) p -N-(CH2) q COOX is the carboxyalkylation product of the amidoamine corresponding to R 1 CO is an aliphatic acyl radical having 6-22 carbon atoms and 0 or 1-3 double bonds, R 2 is hydrogen or an alkyl radical having 1 to 4 carbon atoms, and R 3 is an alkyl radical having 1 to 4 carbon atoms, p is a number from 1 to 6, q is a number from 1 to 3 and X is an alkali and / or alkaline earth metal or ammonium. Typical examples are the reaction products of fatty acids having 6 to 22 carbon atoms, such as caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, eleostearic acid, arachidonic acid, gadoleic acid, behenic acid, erucic acid and technical mixtures thereof, with N,N-dimethylaminoethylamine, N,N-dimethylaminopropylamine, N,N-diethylaminopropylamine, N,N-diethylaminoethylamine and N,N-diethylamino-propylamine, which are condensed with sodium chloroacetate. Commercially available products include Dehyton® K and Dehyton® PK (Cognis Deutschland GmbH & Co., KG) and Tego® Betaine (Goldschmidt).

[0154] Other suitable starting materials for the betaines used for the purposes of the present invention are imidazolines. These are also known and include, for example, 1-2 moles of C6-C 22 They may be obtained by cyclocondensation of fatty acids with polyfunctional amines, such as aminoethylethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are the condensation products of the above-mentioned fatty acids with AEEA, preferably imidazolines based on lauric acid, which are subsequently betained with sodium chloroacetate. Commercially available products include Dehyton® G (Cognis Deutschland GmbH & Co., KG).

[0155] The amount of (co)surfactant contained in the composition according to the invention is advantageously from 0.1% to 90% by weight, in particular from 10% to 80% by weight and particularly preferably from 20% to 70% by weight.

[0156] Organic solvents The liquid light or heavy duty detergent may contain an organic solvent, preferably one that is miscible with water. The polydiols, ethers, alcohols, ketones, amides and / or esters may be Preferably 0 to 90% by weight, more preferably 0.1 to 70% by weight, particularly preferably 0.1 to 60% by weight Low molecular weight polar substances, such as methanol, ethanol, etc., are used as organic solvents for this purpose. Alcohol, propylene carbonate, acetone, acetonylacetone, diacetone alcohol ethanol, ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, Glycerin, diethylene glycol, dipropylene glycol monomethyl ether and di Methylformamide or mixtures thereof are preferred.

[0157] enzyme Cellulase Enzymes The cellulase enzymes optionally used in the detergent compositions, when present, are preferably incorporated at levels sufficient to provide up to about 5 mg by weight, more preferably from about 0.01 mg to about 3 mg of active enzyme per gram of composition. Unless otherwise indicated, the compositions herein preferably contain from about 0.001% to about 5%, preferably from 0.01% to 1%, by weight of a commercially available enzyme preparation.

[0158] Suitable cellulases for the present invention include either bacterial or fungal cellulases. Preferably, they have an optimum pH of 5 to 9.5. Suitable cellulases include fungal cellulases produced from Humicola insolens and Humicola strain DSM 1800 or cellulase 212 producing bacteria belonging to the genus Aeromonas, cellulases extracted from the hepatopancreas of the marine mollusc Dolabella Auricula Solander, also described in GB 2,075,028 A. Further, cellulases particularly suitable for use herein are disclosed in WO 1992013057 A1. Most preferably, the cellulases used in the detergent compositions of the present invention are commercially available under the trade names CAREZYMEO and CELLUZYMEO from NOVO Industries A / S.

[0159] Other enzymes Additional enzymes can be included in the detergent compositions herein for a wide range of fabric washing purposes, for example, for the removal of protein-based, carbohydrate-based, or triglyceride-based stains, and for preventing refugie dye transfer, and for fabric restoration. Additional enzymes incorporated include proteases, amylases, lipases, and peroxidases, and mixtures thereof. Other types of enzymes can also be included. They can be of any suitable origin, such as vegetable, animal, bacterial, fungal, and yeast origin. However, their selection is governed by several factors, such as pH-activity and / or stability optimization, thermal stability, stability versus active surfactant, builder, and potential for causing malodor during use. In this respect, bacterial or fungal enzymes, such as bacterial amylases and proteases, are preferred.

[0160] Enzymes are typically incorporated at levels sufficient to provide up to about 5 mg, more typically about 0.01 mg to about 3 mg, of active enzyme by weight per gram of composition. Stated differently, the compositions herein typically contain from about 0.001% to about 5%, preferably 0.01% to 1%, by weight of a commercially available enzyme preparation. Protease enzymes are typically present in such commercial preparations at levels sufficient to provide from 0.005 to 0.1 Anson Units (AU) of activity per gram of composition.

[0161] A suitable example of a protease is subtilisin obtained from certain strains of B. subtilis and B. licheniformis. Another suitable protease is obtained from a Bacillus strain with maximum activity over the entire pH range of 8-12 developed and sold under the registered trade name ESPERASE® by Novo Industries A / S. The preparation of this enzyme and similar enzymes is described in Novo's UK Patent Specification No. 1,243,784. Commercially available proteolytic enzymes suitable for removing protein-based stains include those sold under the trade names ALCALASE® and SAVINASE® by Novo Industries A / S and MAXATASE® by International Bio-Synthetics, Inc. Other proteases include protease A; protease B, and the proteases manufactured by Genencor International, Inc. according to US Pat. Nos. 5,204,015 and 5,244,791.

[0162] Amylases include α-amylases such as RAPIDASE®, International Bio-Synthetics, Inc. and TERMAMYL®, Novo Industries.

[0163] Suitable lipase enzymes for detergent use include those produced by microorganisms of the Pseudomonas group, such as Pseudomonas stutzeri ATCC 19154. This lipase is commercially available under the trade name Lipase P "Amano" from Amano Pharmaceutical Co. Ltd. Other commercially available lipases include Amano-CES, lipases from Chromobacter viscosum, such as Chromobacter viscosum var. lipolyticum NRRLB3673 (available from Toyo Jozo Co.), and also Chromobacter viscosum lipases from USBiochemical Corp. and Disoynth Co., and lipases from Pseudomonas gladioli. The LIPOLASE® enzyme from Humicola lanuginosa (commercially available from Novo Industries A / S) is a preferred lipase for use herein.

[0164] Peroxidase enzymes are used in combination with oxygen sources such as percarbonates, perborates, persulfates, hydrogen peroxide, etc. They are used for "solution bleaching", i.e., to prevent the transfer of dyes or pigments removed from a substrate during a washing operation to other substrates in the washing solution. Peroxidase enzymes are known in the art and include, for example, horseradish peroxidase, ligninase, and haloperoxidases such as chloroperoxidase and bromoperoxidase. Peroxidase-containing detergent compositions are disclosed, for example, in WO1989099813A1.

[0165] Enzyme Stabilizers The enzymes used herein are stabilized by the presence of a water-soluble source of calcium and / or magnesium ions in the final detergent composition that provides such ions to the enzyme. (Calcium ions are generally somewhat more effective than magnesium ions and are preferred herein when only one type of cation is used). Further stability can be provided by the presence of various other art-disclosed stabilizers, particularly borate species (see U.S. Pat. No. 4,537,706, incorporated herein in its entirety). Typical detergents, especially liquids, contain from about 1 to about 30, preferably from about 2 to about 20, more preferably from about 5 to about 15, and most preferably from about 8 to about 12 millimoles of calcium ions per liter of final composition. In solid detergent compositions, the formulation can include a water-soluble calcium ion source in an amount sufficient to provide such an amount in the wash liquor. Alternatively, natural water hardness is sufficient.

[0166] It should be understood that the above levels of calcium and / or magnesium ions are sufficient to provide enzyme stability. More calcium and / or magnesium ions can be added to the composition to provide an additional measure of grease removal performance. Thus, as a general proposition, the compositions herein typically contain about 0.05% to about 2% by weight of a water-soluble source of calcium or magnesium ions or both. The amount can, of course, vary depending on the amount and type of enzyme used in the composition.

[0167] The compositions herein may also optionally, but preferably, include various additional stabilizers, particularly borate-type stabilizers. Typically, such stabilizers are used in the compositions at levels of about 0.25% to about 10%, preferably about 0.5% to about 5%, more preferably about 0.75% to about 3% by weight (calculated on a boric acid basis) of boric acid or other borate compounds capable of generating boric acid in the composition. Boric acid is preferred, although other compounds such as boron oxide, borax and other alkali metal borates (e.g., sodium ortho-, meta- and pyroborate and sodium pentaborate) are suitable. Substituted boric acids (e.g., phenylboronic acid, butaneboronic acid and p-bromophenylboronic acid) may also be used in place of boric acid.

[0168] builder Zeolite As builders, finely crystalline synthetic zeolites containing bound water can be used, for example, preferably zeolite A and / or P. Zeolite MAP.RTM (commercial product of Crosfield) is particularly preferred as zeolite P. However, zeolites X and mixtures of A, X, Y and / or P are also suitable. Cocrystallized sodium / potassium aluminum silicates from zeolite A and zeolite X, available as Vegobond® RX (commercial product of Condea Augusta SpA), are also of particular interest. Preferably, the zeolites can be used as spray-dried powders. If the zeolites are added as suspensions, this can be achieved by the addition of small amounts of nonionic surfactants as stabilizers, for example 1 to 3% by weight, based on the zeolite, of ethoxylated C12-C18 fatty alcohols with 2 to 5 ethylene oxide groups, C12-C18 fatty alcohols with 4 ... 12 -C 14It may contain fatty alcohols or ethoxylated isotridecanol. Suitable zeolites have an average particle size of less than 10 μm (test method: volume distribution Coulter counter) and preferably contain 18-22% by weight, in particular 20-22% by weight, of bound water. Apart from this, phosphates can also be used as builders.

[0169] Layered silicate A suitable alternative or partial alternative to phosphates and zeolites is crystalline layered sodium silicate. These types of crystalline layered silicates are described, for example, in European patent application EP 0164514 A1. A preferred crystalline layered silicate is obtained, for example, from the process described in International patent application WO 91 / 08171 A1.

[0170] Amorphous Silicate Preferred builders also include amorphous sodium silicates with a modulus (Na2O:SiO2 ratio) of 1:2 to 1:3.3, preferably 1:2 to 1:2.8, more preferably 1:2 to 1:2.6, which dissolve with delay and show multiple wash cycle properties. The delay in dissolution compared to conventional amorphous sodium silicates can be obtained in various ways, for example by surface treatment, compounding, pressing / compacting, or overdrying. In the context of the present invention, the term "amorphous" also means "X-ray amorphous". In other words, silicates do not produce the sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but give rise to one or more maxima of scattered X-rays with a width of several degrees in the diffraction angle. However, particularly good builder properties can be achieved even when silicate particles produce indistinct or sharp diffraction maxima in electron diffraction experiments. This should be interpreted as meaning that the product has microcrystalline regions with a size of 10 to several hundreds of nm, with values ​​of 50 nm or less, in particular 20 nm or less, being preferred. X-ray amorphous silicates of this type, which also have a delayed dissolution compared to conventional water glasses, are described, for example, in the German patent application DE 4400024 A1. Compacted / densified amorphous silicates, compound amorphous silicates and overdried X-ray amorphous silicates are particularly preferred.

[0171] Phosphate Also, commonly known phosphates can be added as builders, unless their use should be avoided on ecological grounds. Orthophosphate, pyrophosphate, and especially sodium salts of tripolyphosphate are particularly suitable. Their content is generally not more than 25% by weight, preferably not more than 20% by weight, each based on the finished composition. In some cases, tripolyphosphate has been shown to provide a synergistic improvement of secondary detergency in combination with other builders, even in small amounts, already up to 10% by weight, based on the finished composition. The preferred amount of phosphate is less than 10% by weight, especially 0% by weight.

[0172] Cobuilder Polycarboxylic acids Useful organic cobuilders are polycarboxylic acids, which can be used, for example, in the form of sodium salts of polycarboxylic acids, where polycarboxylic acids are understood to be carboxylic acids with more than one acid functional group.For example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acid, aminocarboxylic acid, nitrilotriacetic acid (NTA) and its derivatives and mixtures thereof.Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acid and mixtures thereof.

[0173] organic acid Acids themselves can also be used.In addition to their building effect, acids also typically have the properties of acidifying components, and therefore also serve to establish a relatively low and moderate pH in detergent or cleansing compositions.In this regard, citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and their mixtures can be mentioned in particular.Furthermore suitable acidifying agents are known pH adjusters, such as sodium hydrogen carbonate and sodium hydrogen sulfate.

[0174] polymer Particularly suitable polymeric cobuilders are polyacrylates, preferably having a molecular weight of 2,000 to 20,000 g / mol. Due to their excellent solubility, preferred representatives of this group are likewise short-chain polyacrylates, having a molecular weight of 2000 to 10,000 g / mol, more preferably 3,000 to 5,000 g / mol. Suitable polymers can also include substances which consist partially or completely of vinyl alcohol units or derivatives thereof.

[0175] Further suitable copolymeric polycarboxylates are, in particular, those of acrylic acid and methacrylic acid, and those of acrylic acid or methacrylic acid and maleic acid. Copolymers of acrylic acid and maleic acid, which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid, have proven particularly suitable. Their relative molecular weight, based on the free acid, is generally in the range of 2,000 to 70,000 g / mol, preferably 20,000 to 50,000 g / mol, in particular 30,000 to 40,000 g / mol. The (co)polymeric polycarboxylates can be added as an aqueous solution or, preferably, as a powder. To improve water solubility, the polymers can also contain allylsulfonic acid as a monomer, for example allyloxybenzenesulfonic acid and methallylsulfonic acid, as in EP 0 727 448 B1.

[0176] Particularly preferred are biodegradable polymers which contain more than two different monomer units, examples being those which contain acrylates and maleates, and also vinyl alcohol or vinyl alcohol derivatives as monomers, as for example in DE 43 00 772 A1, or those which contain acrylates and salts of 2-alkylarylsulfonic acid, and also sugar derivatives as monomers.Further preferred copolymers are those described in DE 43 03 320 A1 and DE 44 17 734 A1, preferably those which contain acrolein and acrylic acid / acrylates or acrolein and vinyl acetate as monomers.

[0177] Likewise, other preferred builders are polymeric aminodicarboxylic acids, their salts or precursors. Particular preference is given to polyaspartic acid or its salts and derivatives, which are disclosed in German patent application DE 19540086 A1 as having bleach stabilizing action in addition to cobuilder properties.

[0178] Further suitable builders are the polyacetals which can be obtained by treating dialdehydes with polyol carboxylic acids having 5 to 7 carbon atoms and at least three hydroxyl groups, as described in European patent application EP 0 280 223 A1. Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof, and from polycarboxylic acids such as gluconic acid and / or glucoheptonic acid.

[0179] carbohydrates Further suitable organic cobuilders are dextrins, oligomers or polymers of carbohydrates obtainable by partial hydrolysis of starch. Hydrolysis can be carried out using typical processes, for example acidic or enzymatically catalyzed processes. The hydrolysis products preferably have an average molecular weight in the range of 400 to 500,000 g / mol. Polysaccharides with a dextrose equivalent (DE) of 0.5 to 40, more particularly 2 to 30, are preferred, DE being an accepted measure of the reducing effect of the polysaccharide compared to dextrose with a DE of 100. Both maltodextrins with a DE of 3 to 20 and dry glucose syrups with a DE of 20 to 37 may be used, as well as so-called yellow dextrins and white dextrins with relatively high molecular weights of 2,000 to 30,000 g / mol. Preferred dextrins are described in the British patent application GB 9419091.

[0180] The oxidized derivatives of such dextrins refer to their reaction products with oxidizing compositions capable of oxidizing at least one alcohol function of the saccharide ring to a carboxylic acid function. Such oxidized dextrins and processes for their production are known, for example, from European patent application EP 0 232 202 A1. Products oxidized at C6 of the saccharide ring may be particularly advantageous.

[0181] Oxydisuccinates and other derivatives of disuccinates, preferably ethylenediamine disuccinate, are also further suitable cobuilders. Here, ethylenediamine-N,N'-disuccinate (EDDS), the synthesis of which is described, for example, in US Pat. No. 3,158,615, is preferably used in the form of its sodium or magnesium salt. In this context, glycerol disuccinate and glycerol trisuccinate are also particularly preferred, as described in US Pat. No. 4,524,009. Suitable addition amounts in zeolite-containing and / or silicate-containing formulations are in the range of 3 to 15% by weight.

[0182] Lactone Other useful organic cobuilders are, for example, acetylated hydroxycarboxylic acids, optionally present in lactone form, containing at least 4 carbon atoms, at least one hydroxyl group and at most two acid groups, and their salts. Such cobuilders are, for example, described in International Patent Application WO 1995020029 A1.

[0183] Bleaching Compounds, Bleaching Agents and Bleaching Activators The detergent compositions herein can optionally contain a bleaching agent and a bleaching composition comprising a bleaching agent and one or more bleach activators. When present, the bleaching agent is typically at a level of about 1% to about 30%, more typically about 5% to about 20%, of the detergent composition (especially for washing fabrics). When present, the amount of bleach activator is typically about 0.1% to about 60%, more typically about 0.5% to about 40%, of the bleaching composition including the bleaching agent + bleach activator.

[0184] The bleaching agent used herein can be any bleaching agent useful in detergent compositions for textile cleaning, hard surface cleaning, or other cleaning purposes that are currently known or will become known.These include oxygen bleaching agents and other bleaching agents.Perborate bleaching agents, such as sodium perborate (e.g., monohydrate or tetrahydrate), can be used herein.

[0185] Another category of bleaching agents that may be used without limitation includes percarboxylic acid bleaching agents and their salts. Suitable examples of this type of agent include magnesium monoperoxyphthalate hexahydrate, the magnesium salt of metachloroperbenzoic acid, 4-nonylamino-4-oxoperoxybutyric acid, and diperoxydodecanedioic acid.

[0186] Peroxygen bleaching agents can also be used.Suitable peroxygen bleaching compounds include sodium carbonate peroxide and equivalent "percarbonate" bleaching agents, sodium pyrophosphate peroxide, urea peroxide, and sodium peroxide.Persulfate bleaching agents (e.g., OXONEO®, marketed by DuPont) can also be used.

[0187] Preferred percarbonate bleaching agents include dry particles having an average particle size ranging from about 500 micrometers to about 1,000 micrometers, with not more than about 10% by weight of the particles being smaller than about 200 micrometers and not more than about 10% by weight of the particles being greater than about 1,250 micrometers. Optionally, the percarbonate can be coated with a silicate, borate, or water-soluble surfactant. Percarbonate is available from a variety of commercial sources.

[0188] Mixtures of bleaching agents may also be used.

[0189] Peroxygen bleaches, perborates, percarbonates, etc. are preferably combined with bleach activators to result in the in situ production in aqueous solution (i.e., during the cleaning process) of the peroxyacid corresponding to the bleach activator. Nonanoyloxybenzenesulfonate (NOBS) and tetraacetylethylenediamine (TAED) activators are typical, and mixtures thereof may also be used.

[0190] Preferred amide derived bleach activators include (6-octanamido-caproyl)oxybenzenesulfonate, (6-nonanamido-caproyl)oxybenzenesulfonate, (6-decanamido-caproyl)oxybenzenesulfonate, and mixtures thereof.

[0191] Another class of bleach activators is disclosed in U.S. Pat. No. 4,966,496, which is incorporated herein by reference. Examples of activators include the benzoxazine type activators disclosed in US Pat. No. 6,723.

[0192] Highly preferred lactam activators include benzoylcaprolactam, octanoylcaprolactam, 3,5,5-trimethylhexanoylcaprolactam, nonanoylcaprolactam, decanoylcaprolactam, undecenoylcaprolactam, benzoylvalerolactam, octanoylvalerolactam, decanoylvalerolactam, undecenoylvalerolactam, nonanoylvalerolactam, 3,5,5-trimethylhexanoylvalerolactam and mixtures thereof, optionally including acylcaprolactams, preferably benzoylcaprolactam, adsorbed onto a solid support, for example adsorbed onto sodium perborate.

[0193] Bleaching agents other than oxygen bleaches are known in the art and may be utilized herein. One type of non-oxygen bleaching agent of particular interest includes photoactivated bleaches such as sulfonated zinc and / or aluminum phthalocyanines. When used, the detergent composition typically contains from about 0.025% to about 1.25% by weight of such bleaching agents, particularly sulfonated zinc phthalocyanines.

[0194] If desired, the bleaching compounds may be catalyzed by manganese compounds. Such manganese-based catalysts are well known in the art and include Mn IV 2(uO)3(1,4,7-trimethyl-1,4,7-triazacyclononane)2(PF6)2, Mn III2(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)2, Mn IV 4(uO)6(1,4,7-triazacyclononane)4(ClO4)4, Mn III Mn IV 4(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)3, Mn IV (1,4,7-trimethyl-1,4,7-triazacyclononane)-(OCH3)3(PF6), and mixtures thereof.

[0195] As a practical matter, and without limitation, the compositions and processes herein can be tailored to provide active bleach catalyst species on the order of at least 1 part per million in the aqueous wash liquor, preferably providing from about 0.1 ppm to about 700 ppm, more preferably from about 1 ppm to about 500 ppm of catalyst species in the wash liquor.

[0196] Polymeric Soil Release Agents In the detergent composition and process of the present invention, any polymeric soil release agent known to those skilled in the art can be used.The polymeric soil release agent is characterized by having both a hydrophilic segment that hydrophilizes the surface of hydrophobic fibers such as polyester and nylon, and a hydrophobic segment that deposits on the hydrophobic fibers and remains attached after the completion of washing and rinsing cycles, thus serving as an anchor for the hydrophilic segment.This allows the soil that occurs after treatment with the soil release agent to be more easily cleaned in the subsequent washing procedure.

[0197] Polymeric soil release agents useful herein include, inter alia, one or more non-ionic hydrophilic components consisting essentially of (a) a polyoxyethylene segment having a degree of polymerization of at least 2, or (ii) an oxypropylene or polyoxypropylene segment having a degree of polymerization of 2 to 10, wherein the hydrophilic segment does not include an oxypropylene unit unless it is attached at each end to an adjacent moiety by an ether linkage, or (iii) a mixture of oxyethylene and oxyalkylene units containing from 1 to about 30 oxypropylene units, wherein the mixture contains a sufficient amount of oxyethylene units such that the hydrophilic component has a hydrophilicity great enough to increase the hydrophilicity of a conventional polyester synthetic fiber surface upon deposition of the soil release agent thereon, the hydrophilic segment preferably consisting essentially of a mixture containing at least about 25% oxyethylene units, more preferably about 20 to 30 oxypropylene units, at least about 50% oxyethylene units, particularly with respect to such components, or (b)(i) a C3 oxyalkylene terephthalate segment, wherein the hydrophobic component If the segment also contains oxyethylene terephthalate, the ratio of oxyethylene terephthalate:C3 oxyalkylene terephthalate units is about 2:1 or less; (ii) a C4-C6 alkylene or oxyC4-C6 alkylene segment, or mixtures thereof; (iii) a poly(vinyl ester) segment having a degree of polymerization of at least 2, preferably polyvinyl acetate; or (iv) a C1-C4 alkyl ether or C4 hydroxyalkyl ether substituent, or mixtures thereof, where the substituent is present in the form of a C1-C4 alkyl ether and / or C4 hydroxyalkyl ether cellulose derivative, or mixtures thereof, which cellulose derivatives are amphoteric and thereby have C1-C4 alkyl ether or C4 hydroxyalkyl ether units at a level sufficient to adhere to conventional polyester synthetic fiber surfaces and retain a sufficient level of hydroxyl and increase the hydrophilicity of the fiber surface once adsorbed onto such conventional synthetic fiber surfaces; or a soil release agent having a combination of (a) and (b).

[0198] Typically, the polyoxyethylene segments of (a)(i) have a degree of polymerization of about 200, although higher levels can be used, preferably from 3 to about 150, more preferably from 6 to about 100. Suitable oxy C4-C6 alkylene hydrophobic segments include, but are not limited to, the end caps of polymeric soil release agents.

[0199] Polymeric soil release agents useful in the present invention also include cellulose derivatives such as hydroxyether cellulose-based polymers, copolymer blocks of ethylene terephthalate or propylene terephthalate and polyethylene oxide or polypropylene oxide terephthalate. Such agents are commercially available and include hydroxyethers of cellulose, such as METHOCEL® (Dow). Cellulosic soil release agents for use herein also include those selected from the group consisting of C1-C4 alkyl and C4 hydroxyalkyl cellulose.

[0200] Soil release agents characterized by poly(vinyl ester) hydrophobic segments include poly(vinyl esters), such as graft copolymers of C1-C6 vinyl esters, preferably poly(vinyl acetate) grafted onto a polyalkylene oxide backbone, such as a polyethylene oxide backbone, see EP 0 219 048, which is incorporated herein in its entirety. Commercially available soil release agents of this type include SOKALAN® type materials, such as SOKALAN® HP-22 (available from BASF).

[0201] One type of preferred soil release agent is a copolymer having random blocks of ethylene terephthalate and polyethylene oxide (PEO) terephthalate. The molecular weight of this polymeric soil release agent preferably ranges from about 25,000 to about 55,000.

[0202] Another preferred polymeric soil release agent is a polyester having repeat units of ethylene terephthalate units, containing 10-15% by weight of ethylene terephthalate units with 90-80% by weight of polyoxyethylene terephthalate units derived from a polyoxyethylene glycol having an average molecular weight of 300 to 5000. Examples of this polymer include the commercially available materials ZELCON® 5126 (manufactured by DuPont) and MILEASE® T (manufactured by ICI).

[0203] Another preferred polymeric soil release agent is the sulfonation product of a substantially linear ester oligomer that comprises an oligomeric ester backbone of terephthaloyl and oxyalkyleneoxy repeat units and a terminal moiety covalently bonded to the backbone.These soil release agents are fully described in U.S. Pat. No. 4,968,451.Other suitable polymeric soil release agents include the terephthalate polyesters of U.S. Pat. No. 4,711,730, the anionic end-capped oligomeric esters of U.S. Pat. No. 4,721,580, the block polyester oligomeric compounds of U.S. Pat. No. 4,702,857, and the anionic, particularly sulfoaroyl end-capped terephthalate esters of U.S. Pat. No. 4,877,896, all of which are incorporated herein in their entirety.

[0204] Yet another preferred soil release agent is an oligomer having repeat units of terephthaloyl, sulfoisoterephthaloyl, oxyethyleneoxy and oxy-1,2-propylene units. The repeat units form the backbone of the oligomer and are preferably terminated with modified isethionate end caps. A particularly preferred soil release agent of this type contains about 1 sulfoisophthaloyl, 5 terephthaloyl, oxyethyleneoxy and oxy-1,2-propyleneoxy units in a ratio of about 1.7 to about 1.8, and two end cap units of sodium 2-(2-hydroxyethoxy)-ethanesulfonate. The soil release agent also contains about 0.5% to about 20% by weight of the oligomer of a crystallinity reducing stabilizer, which is preferably selected from the group consisting of xylene sulfonate, cumene sulfonate, toluene sulfonate, and mixtures thereof.

[0205] If used, the soil release agents generally comprise from about 0.01% to about 10.0%, typically from about 0.1% to about 5%, and preferably from about 0.2% to about 3.0%, by weight of the detergent compositions herein.

[0206] Polymer Dispersants Polymeric dispersants are advantageously utilized in the detergent compositions herein at levels of from about 0.1% to about 7% by weight, especially in the presence of zeolite and / or layered silicate builders. Suitable polymeric dispersants include polymeric polycarboxylates and polyethylene glycols, although others known in the art can also be used. Without intending to be limited by theory, it is believed that polymeric dispersants, when used in combination with other builders (including low molecular weight polycarboxylates), enhance overall detergent builder performance by inhibiting crystal growth, deflocculating particulate soil release, and preventing redeposition.

[0207] Polymeric polycarboxylate materials can be prepared by polymerizing or copolymerizing suitable unsaturated monomers, preferably in their acid form. Unsaturated monomeric acids that can be polymerized to form suitable polymeric polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid, and methylenemalonic acid. The presence of polymeric polycarboxylates herein or monomeric segments that do not contain carboxylate radicals, such as vinyl methyl ether, styrene, ethylene, etc., is preferred, provided that such segments do not exceed about 40% by weight.

[0208] Particularly suitable polymeric polycarboxylates can be derived from acrylic acid. Such acrylic acid-based polymers useful herein are water-soluble salts of polymerized acrylic acid. The average molecular weight of such polymers in the acid form preferably ranges from about 2,000 to 10,000, more preferably from about 4,000 to 7,000, and most preferably from about 4,000 to 5,000. Water-soluble salts of such acrylic acid polymers can include, for example, alkali metal, ammonium and substituted ammonium salts. Soluble polymers of this type are known materials. The use of this type of polyacrylate in detergent compositions is disclosed, for example, in U.S. Pat. No. 3,308,067.

[0209] Acrylic / maleic copolymers can also be used as a preferred component of the dispersion / anti-redeposition agent. Such materials include water-soluble salts of copolymers of acrylic acid and maleic acid. The average molecular weight of such copolymers in the acid form is preferably in the range of about 2,000 to 100,000, more preferably about 5,000 to 75,000, and most preferably about 7,000 to 65,000. The ratio of acrylate to maleate segments in such copolymers generally ranges from about 30:1 to about 1:1, more preferably about 10:1 to 2:1. Water-soluble salts of such acrylic acid / maleic acid copolymers can include, for example, alkali metal, ammonium and substituted ammonium salts. Soluble acrylate / maleate copolymers of this type are known materials described in EP 0 193 360 A1, which also describes such polymers containing hydroxypropyl acrylate. Still other useful dispersants include maleic acid / acrylic acid / vinyl alcohol terpolymers, such as a 45 / 45 / 10 terpolymer of acrylic acid / maleic acid / vinyl alcohol.

[0210] Another polymeric material that can be included is polyethylene glycol (PEG). PEG can act as a clay soil remover-antiredeposition agent as well as a dispersant. Typical molecular weight ranges for these purposes are from about 500 to about 100,000, preferably from about 1,000 to about 50,000, and more preferably from about 1,500 to about 10,000.

[0211] Polyaspartate and polyglutamate dispersing agents may also be used, particularly with zeolite builders. Dispersing agents such as polyaspartate preferably have a molecular weight (average) of about 10,000.

[0212] Foam suppressor / foam suppressor In particular, when used in automated cleaning processes, it may be advantageous to add a conventional foam suppressor to the composition. Suitable foam suppressors include, for example, C 18 -C24 These include soaps of natural or synthetic origin with a high content of fatty acids. Suitable non-surface-active foam inhibitors are, for example, organopolysiloxanes and their mixtures with finely divided silica, optionally silanized, and mixtures of paraffins, waxes, microcrystalline waxes and their mixtures with silanized silica or bis-stearylethylenediamine. Mixtures of various foam inhibitors, such as mixtures of silicones, paraffins or waxes, are also advantageously used. Preferably, the foam inhibitor, especially the silicone-containing and / or paraffin-containing foam inhibitor, is loaded into a particulate water-soluble or dispersible carrier material. In particular in this case, a mixture of paraffin and bis-stearylethylenediamide is preferred.

[0213] Compounds for reducing or inhibiting suds formation can be incorporated into the detergent compositions of the present invention. Suds inhibition can be particularly important in the so-called "high concentration cleaning process" and in front-loading European style washing machines.

[0214] A wide variety of materials can be used as foam suppressors, and foam suppressors are well known to those skilled in the art. See, for example, Kirk Othmer Encyclopedia of Chemical Technology, Third Edition, Volume 7, pages 430-447 (John Wiley & Sons, Inc., 1979). One category of foam suppressors of particular interest includes aliphatic monocarboxylic acids and their soluble salts. The aliphatic monocarboxylic acids and their salts used as foam suppressors typically have hydrocarbyl chains of 10 to about 24 carbon atoms, preferably 12 to 18 carbon atoms. Suitable salts include alkali metal salts, such as sodium, potassium and lithium salts, and ammonium and alkanolammonium salts.

[0215] The detergent compositions herein may also include non-surfactant suds suppressors. These include, for example, paraffins, fatty acid esters (e.g., fatty acid triglycerides), fatty acid esters of monohydric alcohols, fatty C18 -C 40 Other suds suppressors include high molecular weight hydrocarbons such as ketones (e.g., stearin) and the like. Other suds suppressors include N-alkylated aminotriazines such as tri- to hexaalkylmelamines or di- to tetraalkyldiaminechlorotriazines formed as the product of cyanuric chloride with 2 or 3 moles of a primary or secondary amine containing 1 to 24 carbon atoms, propylene oxide and monostearyl phosphates such as monostearyl alcohol phosphate ester and monostearyl dialkali metal (e.g., K, Na and Li) phosphates and phosphate esters. Hydrocarbons such as paraffins and haloparaffins can be utilized in liquid form. Liquid hydrocarbons are liquid at room temperature and atmospheric pressure and have a pour point in the range of about -40°C to about 50°C and a minimum boiling point of about 110°C (atmospheric pressure) or higher. It is also known to use waxy hydrocarbons, preferably having a melting point less than about 100°C. Hydrocarbon suds suppressors are known in the art and include aliphatic, alicyclic, aromatic, and heterocyclic saturated or unsaturated hydrocarbons having from about 12 to about 70 carbon atoms. The term "paraffin" as used in this discussion of suds suppressors is intended to include mixtures of true paraffins and cyclic hydrocarbons.

[0216] Another preferred category of non-surfactant suds suppressors includes silicone suds suppressors. This category includes polyorganosiloxane oils, such as polydimethylsiloxanes, dispersions or emulsions of polyorganosiloxane oils or resins, and combinations of polyorganosiloxanes with silica particles, where the polyorganosiloxanes are chemisorbed or condensed onto the silica. Silicone suds suppressors are well known in the art.

[0217] Other silicone suds suppressors are disclosed in U.S. Pat. No. 3,455,839, which is incorporated herein in its entirety, and which relates to a composition and process for defoaming aqueous solutions by incorporating small amounts of polydimethylsiloxane fluids therein.

[0218] Mixtures of silicones and silanated silicas are described, for example, in DE-OS 2 124 526, which is incorporated herein in its entirety. Silicone antifoams and foam suppressors in granular detergent compositions are disclosed in U.S. Pat. No. 4,652,392, which is incorporated herein in its entirety.

[0219] In the preferred silicone suds suppressors used herein, the continuous phase solvent is comprised of a specific polyethylene glycol or polyethylene-polypropylene glycol copolymer or mixtures thereof (preferably) or polypropylene glycol. The primary silicone suds suppressors are branched / crosslinked and preferably not linear.

[0220] The silicone suds suppressors herein preferably comprise polyethylene glycols and polyethylene glycol / polypropylene glycol copolymers having an average molecular weight of less than about 1,000, preferably from about 100 to 800. The polyethylene glycols and polyethylene / polypropylene copolymers herein have a solubility in water of greater than about 2% by weight, preferably greater than about 5% by weight, at room temperature.

[0221] Preferred solvents herein are polyethylene glycols having an average molecular weight of less than about 1,000, more preferably about 100-800, and most preferably 200-400, and copolymers of polyethylene glycol / polypropylene glycol, preferably PPG200 / PEG300. A weight ratio of polyethylene glycol:copolymer of about 1:1 to 1:10, most preferably 1:3 to 1:6, of polyethylene-polypropylene glycol is preferred.

[0222] Preferred silicone suds suppressors for use herein are free of polypropylene glycols, particularly those having a molecular weight of 4,000. They are also preferably free of block copolymers of ethylene oxide and propylene oxide, such as PLURONIC® L101.

[0223] Other suds suppressors useful herein include secondary alcohols (e.g., 2-alkyl alkanols) and mixtures of such alcohols with silicone oils. Secondary alcohols include those having C1-C 16 C6-C chain 16 Alkyl alcohols are included. A preferred alcohol is 2-butyl octanol, available from Condea under the trade name ISOFOL® 12. A mixture of secondary alcohols is available from Enichem under the trademark ISALCHEM® 123. Mixed suds suppressors typically contain a mixture of alcohol + silicone in a weight ratio of 1:5 to 5:1.

[0224] The compositions herein generally include 0% to about 5% of a suds suppressor. When used as a suds suppressor, aliphatic monocarboxylic acids and their salts are typically present in an amount up to about 5% by weight of the detergent composition. Preferably, about 0.5% to about 3% of an aliphatic monocarboxylate suds suppressor is utilized. Silicone suds suppressors are typically used in an amount up to about 2.0% by weight of the detergent composition, although higher amounts can be used. This upper limit is practical primarily due to concerns of minimizing cost and the effectiveness of small amounts to effectively control suds. Preferably, about 0.01% to about 1%, more preferably about 0.25% to about 0.5% of a silicone suds suppressor is utilized. As used herein, these weight percentage values ​​include any silica that may be utilized in combination with the polyorganosiloxane, and any adjunct materials that may be utilized. Monostearyl phosphate suds suppressors are generally utilized in an amount ranging from about 0.1% to about 2% by weight of the composition. Hydrocarbon suds suppressors are typically utilized in amounts ranging from about 0.01% to about 5.0%, although higher levels can be used. Alcohol suds suppressors are typically used at 0.2-3% by weight of the finished composition.

[0225] Sequestering and Chelating Agents The salts of polyphosphonic acids can be considered as sequestering agents or stabilizers, especially for peroxy compounds and enzymes which are sensitive to heavy metal ions, where, for example, the sodium salts of 1-hydroxyethane-1,1-diphosphonate, diethylenetriaminepentamethylenephosphonate or ethylenediaminetetramethylenephosphonate are used in amounts of 0.1 to 5% by weight.

[0226] The detergent compositions herein may also optionally contain one or more iron and / or manganese chelating agents. Such chelating agents may be selected from the group consisting of aminocarboxylates, aminophosphonates, polyfunctionally substituted aromatic chelating agents and mixtures thereof, all as defined below. Without wishing to be bound by theory, it is believed that the benefits of these materials are due in part to their exceptional ability to remove iron and manganese ions from the wash solution by forming soluble chelates. It is understood that some of the aforementioned detergent builders can function as chelating agents, and such detergent builders may be present in sufficient amounts to provide both functions.

[0227] Aminocarboxylates useful as optional chelating agents include ethylenediaminetetraacetate, N-hydroxyethylethylenediaminetriacetate, nitrilotriacetate, ethylenediaminetetrapropionate, triethylenetetraaminehexaacetate, diethylenetriaminepentaacetate and ethanol diglyceride, alkali metal, ammonium and substituted ammonium salts thereof and mixtures thereof.

[0228] Amino phosphonates are suitable for use as chelating agents in the compositions of the present invention, at least where low levels of total phosphorus are tolerated in the detergent composition, and include ethylenediaminetetrakis(methylenephosphonate) as DEQUEST. These amino phosphonates preferably do not contain alkyl or alkenyl groups having more than about 6 carbon atoms.

[0229] Polyfunctionally substituted aromatic chelating agents are also useful in the compositions herein. Preferred compounds of this type in the acid form are dihydroxydisulfobenzenes, such as 1,2-dihydroxy-3,5-disulfobenzene.

[0230] A preferred biodegradable chelating agent for use herein is ethylenediamine disuccinate ("EDDS"), particularly the [S,S] isomer.

[0231] When utilized, these chelating agents generally comprise from about 0.1% to about 10% by weight of the detergent compositions herein. More preferably, when utilized, the chelating agents comprise from about 0.1% to about 3.0% by weight of such compositions.

[0232] Clay stain remover / anti-redeposition agent The detergent compositions of the present invention may also optionally contain water-soluble ethoxylated amines having clay soil removal and anti-redeposition properties. Particulate detergent compositions containing these compounds typically contain from about 0.01% to about 10.0% by weight of the water-soluble ethoxylated amine; liquid detergent compositions typically contain from about 0.01% to about 5%.

[0233] The most preferred soil release and anti-redeposition agent is ethoxylated tetraethylenepentamine. Exemplary ethoxylated amines are further described in US Patent 4,597,898. Other groups of preferred clay soil removal-anti-redeposition agents are the cationic compounds disclosed in EP 0111965A1, the ethoxylated amine polymers disclosed in EP 0111984A1, the zwitterionic polymers disclosed in EP 0112592A1, and the amine oxides disclosed in US Patent 4,548,744. Another type of preferred anti-redeposition agent includes carboxymethyl cellulose (CMC) materials. These materials are well known in the art.

[0234] Graying prevention agent The antigraying agent has the function of keeping the dirt removed from the fibers suspended in the wash liquor, thereby preventing the dirt from being redeposited. Water-soluble colloids having mainly organic character, such as water-soluble salts of (co)polymeric carboxylic acids, glues, gelatins, salts of ether carboxylic acids or ether carboxylic acids of starch or cellulose, or salts of ether carboxylic acids or ether sulfonic acids of starch or cellulose, or salts of acidic sulfates of cellulose or starch, are suitable for this purpose. Water-soluble acid group-containing polyamides are also suitable for this purpose. Also soluble starch preparations, etc. can be used, as can starch decomposition products, such as aldehyde starch, as mentioned above. Polyvinylpyrrolidone can also be used. However, the use of cellulose ethers, such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof, as well as polyvinylpyrrolidone, is preferred, which can be added, for example, in amounts of 0.1 to 5% by weight, based on the composition.

[0235] Optical brighteners and UV absorbers Any optical brightener or other brightening or whitening agent known in the art can be incorporated into the detergent compositions herein at levels typically of about 0.05% to about 1.2% by weight. Commercially available optical brighteners that may be useful in the present invention can be divided into subgroups, including, but not necessarily limited to, stilbene derivatives, pyrazolines, coumarins, carboxylic acids, methylene cyanines, dibenzothiophene-5,5-dioxides, azoles, 5- and 6-membered heterocycles, and other miscellaneous agents.

[0236] Preferred brighteners include those in Verona's PHORWHITE series. Other brighteners disclosed in this reference include: Tinopal UNPA, Tinopal CBS and Tinopal 5 BM available from Ciba-Geigy; Artic White CC and Artic White CWD available from Hilton-Davis; 2-(4-stryl-phenyl)-2H-naphthol[1,2-d]triazole; 4,4'-bis-(1,2,3-triazol-2-yl)-stilbene; 4,4'-bis(stryl)bisphenyl; and aminocoumarin. Specific examples of these brighteners include 4-methyl-7-diethyl-aminocoumarin; 1,2-bis(-benzimidazol-2-yl)ethylene; 1,3-diphenyl-furazoline; 2,5-bis(benzoxazol-2-yl)thiophene; 2-styryl-naphtho-[1,2-d]oxazole; and 2-(stilben-4-yl)-2H-naphtho-[1,2-d]triazole. Anionic brighteners are preferred herein.

[0237] The composition may, for example, contain derivatives of diaminostilbene disulfonic acid or alkali metal salts thereof as optical brighteners. Suitable optical brighteners are, for example, 4,4'-bis-(2-anilino-4-morpholino-1,3,5-triazinyl-6-amino)stilbene-2,2'-di-sulfonic acid or compounds of similar structure containing diethanolamino, methylamino, anilino or 2-methoxyethylamino groups instead of morpholino groups. Substituted diphenylstyryl type optical brighteners may also be present, for example alkali metal salts of 4,4'-bis(2-sulfostyryl)diphenyl, 4,4'-bis(4-chloro-3-sulfostyryl)diphenyl or 4-(4-chlorostyryl)-4'-(2-sulfostyryl)diphenyl. Mixtures of the above-mentioned optical brighteners may also be used.

[0238] UV absorbers may also be added. These are compounds with a clear absorption capacity against ultraviolet light, which not only contribute as UV stabilizers, but also improve the photostability of colorants and pigments, both of the fibers of the textile product and of the skin of the wearer of the textile product, by protecting against UV rays penetrating the fabric. In general, efficient non-radiative deactivation compounds are derivatives of benzophenones, mainly substituted with hydroxyl and / or alkoxy groups in the 2- and / or 4-positions. Substituted benztriazoles, as well as acrylates (cinnamic acid derivatives) substituted with phenyl in the 3-position, acrylates optionally with a cyano group in the 2-position, salicylates, organic Ni complexes, and natural substances such as umbelliferone and endogenous urocanic acid are also suitable. In a preferred embodiment, the UV absorber absorbs UV-A and UV-B radiation as well as possible UV-C radiation, and re-emits light with blue wavelengths, thereby having an additional fluorescent whitening effect. Preferred UV absorbers include triazine derivatives, such as hydroxyaryl-1,3,5-triazines, sulfonated 1,3,5-triazines, o-hydroxyphenyl-benzotriazoles and 2-aryl-2H-benzotriazoles, as well as bis(anilinotriazinyl-amino)stilbenedisulfonic acid and its derivatives.As the UV absorber, UV absorbing pigments such as titanium dioxide can also be used.

[0239] [Dye transfer inhibitor] The detergent compositions of the present invention may also contain one or more materials that are effective in inhibiting the transfer of dyes from one fabric to another during the cleaning process. In general, such dye transfer inhibitors include polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese phthalocyanine, peroxidase, and mixtures thereof. When used, these agents typically comprise about 0.01% to about 10% by weight of the composition, preferably about 0.01% to about 5% by weight, and more preferably about 0.05% to about 2% by weight.

[0240] More specifically, preferred polyamine N-oxide polymers for use herein are described in US Pat. No. 6,491,728, which is incorporated herein by reference.

[0241] Any polymer backbone can be used so long as the amine oxide polymer formed is water soluble and has dye migration resistance properties. Examples of suitable polymer backbones are polyvinyls, polyalkylenes, polyesters, polyethers, polyamides, polyimides, polyacrylates and mixtures thereof. These polymers include random or block copolymers in which one monomer type is an amine N-oxide and the other monomer type is an N-oxide. Amine N-oxide polymers typically have a ratio of amine to amine N-oxide of 10:1 to 1:1,000,000. However, the number of amine oxide groups present in a polyamine oxide polymer can be varied by appropriate copolymerization or by an appropriate degree of N-oxidation. Polyamine oxides can be obtained with almost any degree of polymerization. Typically, the average molecular weight is in the range of 500 to 1,000,000, more preferably 1,000 to 500,000; most preferably 5,000 to 100,000. This preferred class of materials can be referred to as "PVNO".

[0242] The most preferred polyamine N-oxide useful in the detergent compositions herein is poly(4-vinylpyridine-N-oxide) having an average molecular weight of about 50,000 and an amine to amine N-oxide ratio of about 1:4.

[0243] Copolymers of N-vinylpyrrolidone and N-vinylimidazole polymers (classified as "PVPVI") are also preferred for use herein. Preferably, the PVPVI has an average molecular weight in the range of 5,000 to 1,000,000, more preferably 5,000 to 200,000, and most preferably 10,000 to 20,000. PVPVI copolymers typically have a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of 1:1 to 0.2:1, more preferably 0.8:1 to 0.3:1, and most preferably 0.6:1 to 0.4:1. These copolymers can be linear or branched.

[0244] The compositions of the present invention may also use polyvinylpyrrolidone ("PVP") having an average molecular weight of about 5,000 to about 400,000, preferably about 5,000 to about 200,000, more preferably about 5,000 to about 50,000. PVP is known to those skilled in the detergent arts. Compositions containing PVP may also contain polyethylene glycol ("PEG") having an average molecular weight of about 500 to about 100,000, preferably about 1,000 to about 10,000. Preferably, the ratio of PEG to PVP on a ppm basis delivered in the cleaning solution is about 2:1 to about 50:1, more preferably about 3:1 to about 10:1.

[0245] The detergent compositions herein can also optionally contain about 0.005% to 5% by weight of certain types of hydrophilic optical brighteners, which also provide dye transfer protection. If used, the compositions herein preferably contain about 0.01% to 1% by weight of such optical brighteners.

[0246] One preferred brightener is 4,4'-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-s-triazin-2-yl)amino]-2,2'-stilbenedisulfonic acid and disodium salt. This particular brightener species is commercially available under the trade name Tinopal-UNPA-GX® by Ciba-Geigy Corporation. Tinopal-UNPA-GX is a preferred hydrophilic fluorescent brightener useful in the detergent compositions herein.

[0247] Another preferred brightener is 4,4'-bis[(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-s-triazin-2-yl)amino]2,2'-stilbenedisulfonic acid disodium salt. This particular brightener species is marketed under the trade name Tinopal 5BM-GX® by Ciba-Geigy Corporation.

[0248] Another preferred optical brightener is 4,4'-bis[(4-anilino-6-morpholino-s-triazin-2-yl)amino]2,2'-stilbenedisulfonic acid, sodium salt. This particular brightener species is sold under the trade name Tinopal AMS-GX® by Ciba Geigy Corporation.

[0249] The particular fluorescent brightener species selected for use in the present invention provide the advantage of particularly effective dye transfer prevention performance when used in combination with the selected polymeric dye transfer inhibitors described above. The combination of such selected polymeric materials (e.g., PVNO and / or PVPVI) with such selected fluorescent brighteners (e.g., Tinopal UNPA-GX, Tinopal 5 BM-GX and / or Tinopal AMS-GX) provides significantly better dye transfer prevention in aqueous wash solutions than either of these two detergent composition components used alone. Without being bound by theory, it is believed that such brighteners act in this way because they have a high affinity for fabrics in the wash solution and therefore adhere relatively quickly to these fabrics. The degree to which a brightener adheres to fabrics in the wash solution can be defined by a parameter called the "exhaustion coefficient". The exhaustion coefficient is generally the ratio of a) the whitening material adhered to the fabric and b) the initial brightener concentration in the wash liquor. Brighteners with a relatively high exhaustion coefficient are best suited to prevent dye transfer in the context of the present invention.

[0250] It will, of course, be understood that other conventional optical brightener type compounds can optionally be used in the present compositions to provide conventional fabric "brightness" benefits rather than actual dye transfer inhibition effects, and such uses are conventional and well known in detergent formulations.

[0251] Thickener The composition may also contain common thickening and anti-adherent compositions, as well as viscosity modifiers, such as polyacrylates, polycarboxylic acids, polysaccharides and their derivatives, polyurethanes, polyvinylpyrrolidones, castor oil derivatives, polyamine derivatives, such as quaternized and / or ethoxylated hexamethylenediamines, and mixtures of any of these. The preferred compositions are soluble in water at a temperature of 20° C. and for 50 min. -1 10,000 mPa measured with a Brookfield viscometer at a shear rate of * It has a viscosity of less than s.

[0252] Inorganic salts Further suitable components of the composition are water-soluble inorganic salts such as bicarbonates, carbonates, amorphous silicates or mixtures thereof; alkali carbonates and amorphous silicates are used in particular, mainly sodium silicates with a molar ratio of Na2O:SiO2 of 1:1 to 1:4.5, preferably 1:2 to 1:3.5. Preferred compositions contain alkali salts, builders and / or cobuilders, preferably sodium carbonate, zeolite, crystalline layered sodium silicate and / or trisodium citrate, in an amount of 0.5 to 70% by weight, preferably 0.5 to 50% by weight, in particular 0.5 to 30% by weight of the anhydrous material.

[0253] Flavors and Colorants The composition can include typical detergent and cleansing composition ingredients, such as fragrances and / or colorants, preferably leaving no or negligible color on the washed fabric.The preferred amount of total colorant added is less than 1% by weight, preferably less than 0.1% by weight, based on the composition.The composition can also include a white pigment, such as TiO2.

[0254] Industrial Application Another object of the present invention is a method for enhancing, improving and / or adjusting the odor of a fragrance that naturally has citrus, floral and lactone odor notes, comprising the following steps: (a) providing at least one first fragrance having citrus, floral, and lactone odor notes in nature; (b) providing 4-ethyl-oct-2 / 3-enoic acid; (c) adding said 4-ethyl-oct-2 / 3-enoic acid to said at least one first fragrance in an amount sufficient to enhance, improve and / or adjust the inherent odor notes of said first fragrance. The present invention relates to a method comprising or consisting of:

[0255] Also claimed is the use of 4-ethyl-oct-2 / 3-enoic acid to enhance, improve and / or modify the odor of fragrances that naturally have a citrus, floral or lactone odor.

[0256] For the avoidance of doubt, it should be noted that all the preferred embodiments already mentioned above, in particular mixtures, combinations, amounts used, etc., are common to the claimed manufacturing process as well as the claimed uses and therefore need not be repeated. Furthermore, the indication of an effective amount preferably means that about 0.1% to about 2% by weight, and preferably about 0.5% to about 1% by weight, of p-tolylmethanol is added to said first fragrance.

[0257] A final object of the invention relates to the use of 4-ethyl-oct-2 / 3-enoic acid as a fragrance. EXAMPLES

[0258] Examples 1 to 16 Changes in aroma by adding 4-ethyl-oct-2 / 3-enoic acid 4-Ethyl-oct-2 / 3-enoic acid (4EOEA) was added in small amounts of 0.1 to 1 weight percent to a variety of first fragrances with citrus, floral, and lactone notes. The resulting odor changes were measured by a panel of five experienced perfumers. The results are shown in Table 1.

[0259] [Table 1-1] [Table 1-2]

[0260] Examples 1 to 3 Tables 2 to 4 below show typical fragrance compositions containing 4-ethyl-oct-2 / 3-enoic acid.

[0261] [Table 2]

[0262] The evaluation was carried out with 10% ethanol. The fatty aroma of 4-ethyl-oct-2 / 3-enoic acid gives it a tropical lychee juiciness. Combined with the sulfur element, it has more impact, more naturalness, and is well-balanced.

[0263] [Table 3]

[0264] The evaluation was carried out on a 1% pearl shampoo. 4-Ethyl-oct-2 / 3-enoic acid provided volume and diffusion to the plum accord, enhancing the effect of cooked plum, harmonizing the structure and softening the symbiosis of the green top notes and woody dry-out.

[0265] [Table 4]

[0266] The evaluation was carried out in 10% ethanol. The natural citrus notes were enhanced by the fatty and aldehydic aspects of 4-ethyl-oct-2 / 3-enoic acid. This harmony is very similar to the citrus albedo scent, which gives it more body when combined with the new scent.

Claims

1. (a) at least one first fragrance having citrus, floral and lactone scent notes; and (b) 4-ethyl-oct-2 / 3-enoic acid A fragrance mixture comprising or consisting of:

2. 2. The mixture of claim 1, wherein the first fragrance is selected from the group consisting of citral, methyl pampelmousse, limonene, dihydromyrcenol, linolol, methyl dihydrojasmonate, phenylethyl alcohol, benzyl acetate, 2,4-dimethyltetrahydroindenodioxine, florosa, methyl anthranilate, tetradecanal, octadecanal, deltadecalactone, and mixtures thereof.

3. 2. The mixture of claim 1, wherein the first fragrance and the 4-ethyl-oct-2 / 3-enoic acid are present in an amount ranging from about 98%:2% to about 99.9%:0.5% by weight, calculated on the mixture.

4. The mixture of claim 1 further comprising at least one solvent.

5. 5. The mixture of claim 4, wherein the solvent is selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol and triethyl citrate.

6. The mixture of claim 4, wherein the solvent is present in an amount ranging from about 10 to about 90 weight percent.

7. A fragrance composition comprising the mixture of claim 1 and at least one second fragrance different from said first fragrance and 4-ethyl-oct-2 / 3-enoic acid.

8. 8. The composition of claim 7, wherein the second fragrance is selected from the group consisting of: [(3,7-dimethyl-6-octenyl) -xy] -cetaldehyde, 1-(p-menthen-6(2)-yl)-1-propanone, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, 10-undecen-1-al, 10-undecen-1-ol, 1-decanal, 1-dodecanal, 1-methyl-3-(4-methylpentyl)-3-cyclohexene carboxaldehyde, 1-methyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde, 1-nonanal, 1-octanal, 1-octen-3-ol, 1-p-menthene-q-carboxaldehyde, 1-undecanal, 2-(2-(4-methyl-3-cyclohexen-1-yl)propyl)cyclopentanone, 2,4,4,7-tetramethyl-oct-6-en-3-one, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde 4-methoxybenzaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, 2,6,10-trimethyl-5,9-undecadienal, 2,6,10-trimethyl-9-undecenal, 3-dodecen-1-al, 2,6-dimethyl-5-heptenal; 2,6-dimethylhept-5-en-1-al, 2,6-dimethylheptan-2-ol, 2,6-nonadienal, 2-acetyl-3,3-dimethyl-norbornane, 2-methyldecanal, 2-methyloctanal, 2-methylundecanal, 2-methyl-3-(4-tertbutyl)propanal, 2-methyl-3-(isopropyl-phenyl)propanal, 2-methyl-3-(para-methoxy-phenylpropanal), 2-methyl-3-phenyl-2-propen-1-al, 2-methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal, 2-methylbutanol, 2-methylpentanol, 2-phenoxyethanol, 2-phenylpropan-1-al, 2-phenylpropanol, 2-tert-butylcyclohexanol, 3-(3,4-methylenedioxy-phenyl)-2-methylpropan-1-al, 3-(3-isopropylphenyl)-butan-1-al, 3-(4-ethylphenyl)-2,2-dimethylpropan-1-al, 3-(4-ethylphenyl)-2,2-dimethylpropanal, 3-(4-isopropylphenyl)-2-methylpropan-1-al, 3-(4-methoxyphenyl)-2-methylpropanal, 3-(4-tert-butylphenyl)-2-methyl-propanal, 3-(4-tert-butylphenyl)propanal, 3,4-dimethoxybenzaldehyde, 3,4-methylenedioxybenzaldehyde, 3,5,5-trimethylcyclohexanol, 3,5,5-trimethylhexanal, 3,5,6-trimethyl-3-cyclohexene carboxaldehyde, 3,7-dimethyl-2-methylene-6-octenal, 3,7-dimethyl-6-octen-1-al, 3,7-dimethyloctan-1-al, 3-ethoxy-4-hydroxybenzaldehyde, 3-hexanol, 3-Methoxy-4-hydroxy-benzaldehyde, 3-methyl-5-phenyl-1-pentanal, 3-methyl-5-phenylpentanol, 3-octanol, 3-phenyl-2-hexylprop-2-enal, 3-phenyl-2-pentylprop-2-en-1-al, 3-phenyl-2-propenal, 3-phenylprop-2-en-1-al, 3-phenylpropanol, 3-propyl-bicyclo[2.2.1]-hept-5-ene-2-carbaldehyde, 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanone, 4-(3)(4-methyl-3-pentenyl)-3-cyclohexene-carboxaldehyde, 4-(4-hydroxy-3-methoxyphenyl)-2-butanone, 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde, 4-(tricyclo[5.2.1.0(2,6)]-decylidene-8)-butanal; 4-Damaskol, 4-heptenol, 4-hydroxy-3-methoxybenzaldehyde, 4-isopropyl benzaldehyde, 4-isopropylcyclohexanol, 4-methoxybenzaldehyde, 4-methylphenylacetaldehyde, 4-tert-butylcyclohexanol, 5,9-dimethyl-4,8-decadienal, 5-methoxyhexahydro-4,7-methanoindan-1-carboxaldehyde, 5-methoxyhexahydro-4,7-methanoindan-2-carboxaldehyde, 6,10-dimethyl-3-oxa-5,9-undecadien-1-al, 6,6-dimethyl-2-norpinen-2-propionaldehyde, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, 6,8-dimethyl-2-nonanol, 6-nonen-1-ol, 6-isopropyl-deca-hydro-2-naphthone, 6-Methoxyhexahydro-4,7-methanoindan-1-carboxaldehyde, 6-Methoxyhexahydro-4,7-methanoindan-2-carboxaldehyde, 7-hydroxy-3,7-dimethyloctanal, 7-Methoxy-3,7-dimethyloctan-1-al, 9-decen-1-ol, 9-Decenal, acetophenone, Adoxal Allyl cyclohexyl propionate, ・Alfaronen, Ambroxan, ・Amylsalicylat, Anethole, Anisaldehyde, Benzaldehyde, Benzophenone, Benzyl acetate, Benzylacetone, Benzyl alcohol, Benzyl salicylate, benzyl ethyl ether, ・Bourjonal, ・Bukkoxim, butyl salicylate, ·camphor, Canthoxal, Carvone, ・Cashion, ・Celery ketone, Chlorhydral, ・Cinnam alcohol, cis- / trans-3,7-dimethyl-2,6-octadien-1-al, ・Cis-Jasmon, citral or a mixture thereof, ・Citronellal, ・Citronellol, ・Citronellyloxyacetaldehyde, ・Cumal, Cyclamen aldehyde, ・Cyclohexyl salicylate, ・Simar, ・Damarose, ・Damascenone, Decanol, ・Decyl aldehyde, ・Delphon, Dihydrojasmone, ・Dihydromyrcenol, Dihydrodimethaldehyde, dihydro-β-ionone, dimethylbenzylcarbinol, dimethylbenzylcarbinyl acetate, dimethylheptanol, dimethyloctanol, dimethyloctenone, ・Dalcinil, ethyl salicylate, ethyl vanillin, ethyl methylphenylglycinate, eugenol, ・Fenchon, ・Floramon, ・Florarozone, ・Floramat, ・Florhydral, Gerson, Geraniol, ・Hedion, - Helional, Heliotropin, Heptanol, hexahydro-4,7-methanoindan-1-carboxaldehyde, hexahydro-8,8-dimethyl-2-naphthaldehyde, ・Hexalon, hexyl salicylate, Hydroxycitronellal, - Isoborneol, ・Isodamascone, ・Isoeugenol, Isojasmone, - Isopulegol, Jasma cycla tat, ・Corebon, ・Lauric aldehyde, Ligustral, ・Lilial Citral, ・Liliar, Limonene, Linalool, Linalyl acetate, ・Libscon, ・Lillard, m-cymene-7-carboxaldehyde, ・Melonal, ・MeraSat, ·menthol, Menthone, ・Methylacetophenone, methyl cedrenyl ketone, ・Methyl cedrylon, ・Methyl cedrylone, methylcyclocitron, ・Methyl dihydrojasmonate, methylheptenone, ・Methyl lavender ketone, ・Methyl dihydrojasmonate, ・Methylnonylacetaldehyde, methyl-β-naphthyl ketone, ・Musk indanone, ・Muscon, Myrtenol, n-dodecanal, ・Neobutenone, Nerol, n-hexanol, Nonanol, n-Undecanal, Octahydro-4,7-methano-1H-indenecarboxaldehyde; octanal, Octanol, o-Methoxyzimtaldehyde, ・Olivon, p-ethyl-α,α-dimethylhydrozimtaldehyde Phenol, phenoxyacetaldehyde; phenoxyisobutyrate, phenylacetaldehyde, phenyl salicylate, phenylethyl acetate, phenylethyl alcohol, p-hydroxyphenylbutanone, Pinene, ・Plicaton, p-menthan-7-ol, p-Methoxyacetophenone, p-methylphenoxyacetaldehyde, p-tert.-bucinal, p-tert.-butylcyclohexanone, p-tert.-cyclohexyl acetate, p-tolyl acetaldehyde, styrallyl propionate, Tetrahydrogeraniol, Tetrahydrolinalool, Tetramelane, - Thymol, ・Tonalid / Musk Plus, trans-2-cis-6-nonadienol, trans-2-nonen-1-ol, trans-2-octenol, trans-4-decenal, Triplral, Undecanal, Undecanol, ・Undecylenraldehyde, vanillin, ・Belton, Beldon, α-Methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde, α-damascone, α-methylbenzyl alcohol, α-methyl-4-(1-methylethyl)benzeneacetaldehyde, α-methylphenylacetaldehyde, α-n-Amylzimtaldehyde, α-n-hexyl-cinnamaldehyde, α-terpineol, β-damascone, β-ionone, β-terpineol, gamma-methyl ionone, - δ-damascone.

9. 8. The composition of claim 7, wherein the 4-ethyl-oct-2 / 3-enoic acid or any of the mixtures of claim 1 is present in an amount ranging from about 0.01 to about 2 percent by weight calculated on the composition.

10. 8. A cosmetic or personal care preparation comprising a fragrance mixture according to claim 1 or a perfume composition according to claim 7.

11. 8. A detergent formulation comprising a fragrance mixture according to claim 1 or a perfume composition according to claim 7.

12. 12. A formulation according to claim 10 or claim 11, comprising the fragrance mixture according to claim 1 or the perfume composition according to claim 7 in an amount ranging from about 0.01 to about 2 weight percent.

13. A method for enhancing, improving and / or adjusting the odor of a perfume that inherently has citrus, floral and lactone odor notes, comprising the steps of: (a) providing at least one first fragrance having naturally citrus, floral, and lactone odor notes; (b) providing 4-ethyl-oct-2 / 3-enoic acid; (c) adding said 4-ethyl-oct-2 / 3-enoic acid to said at least one first fragrance in an amount sufficient to enhance, improve and / or adjust the original odor notes of said first fragrance. A method comprising or consisting of:

14. Use of 4-ethyl-oct-2 / 3-enoic acid to enhance, improve and / or adjust the odor of fragrances that inherently have citrus, floral and lactone odor notes.

15. Use of 4-ethyl-oct-2 / 3-enoic acid as a fragrance.

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