Plasma processing equipment

Abstract

We provide technology that can reduce the environmental impact and costs by reducing the use of highly functional sealing materials. [Solution] A plasma processing apparatus includes a processing vessel having a plasma processing space therein where plasma is generated, and a substrate support part that supports a substrate inside the processing vessel. The processing vessel and / or the substrate support part are configured by assembling multiple members, and have multiple boundaries connecting the multiple members. The multiple boundaries include a radical blocking part that blocks radicals generated in the plasma processing space, and a seal part that is located farther away from the plasma processing space than the radical blocking part and blocks the passage of gas.

Description

[Technical Field]

[0001] The present disclosure relates to a plasma processing apparatus. [Background technology]

[0002] Patent Document 1 discloses a plasma processing apparatus (plasma etching apparatus) including a processing vessel (processing chamber) for performing plasma processing and a substrate support (susceptor) provided inside the processing vessel on which a semiconductor wafer is placed. This type of plasma processing apparatus includes various components inside the substrate support, such as a lifter for raising and lowering the substrate, wiring for an electrostatic chuck that attracts the substrate, and wiring for a lower electrode that induces radicals.

[0003] In order to protect the various components of the substrate support from radicals in the plasma processing space, the processing vessel and the substrate support are provided with high-performance sealing members at the boundaries between multiple components, which are highly durable against plasma and high temperatures. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] Japanese Patent Application Laid-Open No. 2010-3958 Summary of the Invention [Problem to be solved by the invention]

[0005] The present disclosure provides a technology that can reduce the environmental impact and costs by reducing the number of highly functional sealing members. [Means for solving the problem]

[0006] According to one aspect of the present disclosure, there is provided a plasma processing apparatus including a processing vessel having a plasma processing space therein for generating plasma, and a substrate support part for supporting a substrate inside the processing vessel, wherein the processing vessel and / or the substrate support part are constructed by assembling a plurality of members, and have a plurality of boundaries connecting the plurality of members, and the plurality of boundaries include a radical blocking part for blocking radicals generated in the plasma processing space, and a sealing part located at a position farther away from the plasma processing space than the radical blocking part and for blocking the passage of gas. [Effects of the Invention]

[0007] According to one aspect, the number of highly functional sealing members can be reduced, thereby reducing environmental impact and costs. [Brief explanation of the drawings]

[0008] [Figure 1] 1 is a diagram illustrating an overall configuration of a plasma processing system including a plasma processing apparatus according to an embodiment; [Figure 2] 2 is a cross-sectional view showing an enlarged view of the lower side of the plasma processing chamber and the substrate support; FIG. [Figure 3] Fig. 3(A) is an enlarged cross-sectional view of a sealing portion at point IIIA in Fig. 2. Fig. 3(B) is an enlarged cross-sectional view of a radical blocking portion at point IIIB in Fig. 2. Fig. 3(C) is an enlarged cross-sectional view of a radical blocking portion according to a modified example. DETAILED DESCRIPTION OF THE INVENTION

[0009] Hereinafter, embodiments of the present disclosure will be described with reference to the drawings. In the drawings, the same components are denoted by the same reference numerals, and redundant explanations may be omitted.

[0010] 1 is a diagram schematically illustrating the overall configuration of a plasma processing system including a plasma processing apparatus 1 according to an embodiment. First, an example of the configuration of the plasma processing system according to the embodiment will be described with reference to FIG.

[0011] The plasma processing system includes a capacitively coupled plasma processing apparatus 1, which is a substrate processing apparatus, and a controller 2. The capacitively coupled plasma processing apparatus 1 includes a plasma processing chamber (processing vessel) 10, a gas supply unit 20, a power supply 30, and an exhaust system 40. The plasma processing apparatus 1 also includes a substrate support 11 and a gas inlet. The gas inlet is configured to introduce at least one process gas into the plasma processing chamber 10. The gas inlet includes a showerhead 13. The substrate support 11 is disposed within the plasma processing chamber 10. The showerhead 13 is disposed above the substrate support 11. In one embodiment, the showerhead 13 forms at least a portion of the ceiling of the plasma processing chamber 10. The plasma processing chamber 10 has a plasma processing space 10s defined by the showerhead 13, a sidewall 102 of the plasma processing chamber 10, and the substrate support 11. The plasma processing chamber 10 has at least one gas inlet for supplying at least one processing gas to the plasma processing space 10s and at least one gas outlet for exhausting gas from the plasma processing space 10s. The plasma processing chamber 10 is grounded. The showerhead 13 and the substrate support 11 are electrically insulated from the plasma processing chamber 10 housing.

[0012] The substrate support 11 includes a main body 111 and a ring assembly 112. The main body 111 has a central region (substrate support surface) 111a for supporting a substrate (wafer) W and an annular region (ring support surface) 111b for supporting the ring assembly 112. The annular region 111b of the main body 111 surrounds the central region 111a of the main body 111 in a plan view. The substrate W is disposed on the central region 111a of the main body 111, and the ring assembly 112 is disposed on the annular region 111b of the main body 111 so as to surround the substrate W on the central region 111a of the main body 111. In one embodiment, the main body 111 includes an electrostatic chuck 113 and a base 114. The base 114 includes a conductive member. The conductive member of the base functions as a lower electrode. The electrostatic chuck 113 is disposed on the base 114. The electrostatic chuck 113 has an upper surface that forms a substrate support surface 111a. The ring assembly 112 includes one or more annular members, at least one of which is an edge ring.

[0013] The showerhead 13 is configured to introduce at least one processing gas from the gas supply unit 20 into the plasma processing space 10s. The showerhead 13 has at least one gas supply port 13a, at least one gas diffusion chamber 13b, and multiple gas inlets 13c. The processing gas supplied to the gas supply port 13a passes through the gas diffusion chamber 13b and is introduced into the plasma processing space 10s from the multiple gas inlets 13c. The showerhead 13 also includes a conductive member. The conductive member of the showerhead 13 functions as an upper electrode. In addition to the showerhead 13, the gas introduction unit may also include one or more side gas injectors (SGIs) attached to one or more openings formed in the sidewall 102.

[0014] The gas supply unit 20 may include at least one gas source 21 and at least one flow controller 22. In one embodiment, the gas supply unit 20 is configured to supply at least one process gas from a corresponding gas source 21 to the showerhead 13 via a corresponding flow controller 22. Each flow controller 22 may include, for example, a mass flow controller or a pressure-controlled flow controller. Additionally, the gas supply unit 20 may include one or more flow modulation devices to modulate or pulse the flow rate of the at least one process gas.

[0015] The power supply 30 includes an RF power supply 31 coupled to the plasma processing chamber 10 via at least one impedance matching circuit. The RF power supply 31 is configured to supply at least one RF signal (RF power), such as a source RF signal and a bias RF signal, to the conductive members of the substrate support 11 and / or the conductive members of the showerhead 13. This causes plasma to be formed from at least one process gas supplied to the plasma processing space 10s. Thus, the RF power supply 31 can function as at least a part of a plasma generating unit configured to generate plasma from one or more process gases in the plasma processing chamber 10. Furthermore, supplying a bias RF signal to the conductive members of the substrate support 11 generates a bias potential on the substrate W, thereby attracting ion components in the formed plasma to the substrate W.

[0016] In one embodiment, the RF power supply 31 includes a first RF generating unit 31a and a second RF generating unit 31b. The first RF generating unit 31a is coupled to the conductive members of the substrate support 11 and / or the conductive members of the showerhead 13 via at least one impedance matching circuit. In one embodiment, the source RF signal has a frequency in the range of 13 MHz to 150 MHz. In one embodiment, the first RF generating unit 31a may be configured to generate multiple source RF signals having different frequencies. The generated one or more source RF signals are supplied to the conductive members of the substrate support 11 and / or the conductive members of the showerhead 13. The second RF generating unit 31b is coupled to the conductive members of the substrate support 11 via at least one impedance matching circuit and is configured to generate a bias RF signal (bias RF power). In one embodiment, the bias RF signal has a lower frequency than the source RF signal. In one embodiment, the bias RF signal has a frequency in the range of 400 kHz to 13.56 MHz. In one embodiment, the second RF generator 31b may be configured to generate multiple bias RF signals having different frequencies. The generated bias RF signals are supplied to the conductive members of the substrate support 11. In various embodiments, at least one of the source RF signal and the bias RF signal may be pulsed.

[0017] The power supply 30 may also include a DC power supply 32 coupled to the plasma processing chamber 10. The DC power supply 32 includes a first DC generator 32a and a second DC generator 32b. In one embodiment, the first DC generator 32a is connected to a conductive member of the substrate support 11 and configured to generate a first DC signal. The generated first bias DC signal is applied to the conductive member of the substrate support 11. In one embodiment, the first DC signal may be applied to another electrode, such as an electrode in an electrostatic chuck. In one embodiment, the second DC generator 32b is connected to a conductive member of the showerhead 13 and configured to generate a second DC signal. The generated second DC signal is applied to the conductive member of the showerhead 13. In various embodiments, at least one of the first and second DC signals may be pulsed. The first and second DC generating units 32a and 32b may be provided in addition to the RF power supply 31, or the first DC generating unit 32a may be provided instead of the second RF generating unit 31b.

[0018] The exhaust system 40 may be connected to, for example, a gas exhaust port 10e provided at the bottom of the plasma processing chamber 10. The exhaust system 40 may include a pressure regulating valve and a vacuum pump. The pressure regulating valve regulates the pressure in the plasma processing space 10s. The vacuum pump may include a turbomolecular pump, a dry pump, or a combination thereof.

[0019] The controller 2 processes computer-executable instructions that cause the plasma processing apparatus 1 to perform various processes described in this disclosure. The controller 2 may be configured to control each element of the plasma processing apparatus 1 to perform various processes described herein. In one embodiment, part or all of the controller 2 may be included in the plasma processing apparatus 1. The controller 2 may include, for example, a computer 2a. The computer 2a may include, for example, a processing unit (CPU: Central Processing Unit) 2a1, a storage unit 2a2, and a communication interface 2a3. The processing unit 2a1 may be configured to perform various control operations based on programs stored in the storage unit 2a2. The storage unit 2a2 may include a random access memory (RAM), a read-only memory (ROM), a hard disk drive (HDD), a solid state drive (SSD), or a combination thereof. The communication interface 2a3 may communicate with the plasma processing apparatus 1 via a communication line such as a local area network (LAN).

[0020] 2 is an enlarged cross-sectional view showing the lower side of plasma processing chamber 10 and substrate support part 11. Next, plasma processing chamber 10 and substrate support part 11 will be described in more detail with reference to FIG.

[0021] The plasma processing chamber 10 has a bottom wall 101, a side wall 102 provided on the outer periphery of the bottom wall 101, and a cylindrical wall (wall portion) 103 that supports the bottom wall 101 in the center of the bottom wall 101. The plasma processing chamber 10 is constructed by assembling a plurality of members that constitute the wall. The bottom wall 101 and the side wall 102 are separated from each other in FIG. 2 because a passage 10f communicating with the gas exhaust port 10e is shown, but they are continuous with each other (molded integrally) in areas where the gas exhaust port 10e is not present.

[0022] The cylindrical wall 103 extends vertically and has a flange 103f on its upper vertical side. The flange 103f of the cylindrical wall 103 is connected to the bottom wall 101 by fastening bolts (not shown). A seal portion 60 is provided at a boundary 70A between the upper surface of the flange 103f and the lower surface of the bottom wall 101, and is capable of airtightly sealing this boundary 70A. The configuration of the seal portion 60 will be described in detail later.

[0023] On the other hand, as described above, the substrate support 11 (main body 111) has the electrostatic chuck 113 and the base 114. The base 114 is mounted on the bottom wall 101 of the plasma processing chamber 10 and, together with the bottom wall 101 and the cylindrical wall 103, forms an internal space 11s therein that accommodates various components of the substrate support 11. A seal 60 provided at a boundary 70A between the bottom wall 101 and the cylindrical wall 103 airtightly seals the internal space 11s of the substrate support 11 from the outside of the plasma processing chamber 10.

[0024] The base 114 includes a cylindrical side portion 114a provided on the bottom wall 101, a ceiling portion 114b covering the upper end of the cylindrical side portion 114a, a housing portion 114c for housing various wirings of the substrate support portion 11, and a disk portion 114d provided between the housing portion 114c and the electrostatic chuck 113. In other words, the base 114 is formed by assembling multiple members. The base 114 also includes a baffle plate holder 115 on the outer circumferential surface of the cylindrical side portion 114a for holding the baffle plate 105 of the plasma processing chamber 10.

[0025] The baffle plate 105 is formed in a circular ring shape around the side of the substrate support 11 in the circumferential direction and has a plurality of through-holes extending through its thickness in the circumferential and radial directions. The baffle plate 105 is connected to ground potential via the plasma processing chamber 10. The baffle plate 105 configured in this manner allows gas supplied to the plasma processing space 10s by the gas supply unit 20 to pass through the passage 10f, while forming a sheath electric field to block the passage of radicals in the plasma processing space 10s. As an example, the baffle plate holder 115 is composed of a clamping member 115a, which is circular in plan view and clamps the inner end of the baffle plate 105 between itself and the bottom wall 101 of the plasma processing chamber 10. The bottom wall 101 and the clamping member 115a may be configured to fasten the baffle plate 105 with screws.

[0026] The base 114 also has a protective member 116 installed on the top of the baffle plate holding portion 115. The protective member 116 has the function of protecting the radially outer sides of the ceiling portion 114b, the accommodation portion 114c, and the disk portion 114d. The protective member 116, like the clamping member 115a, has an annular shape in a plan view and is made of an insulating material such as quartz. The upper surface of the protective member 116 is flush with a step provided on the outer periphery of the electrostatic chuck 113 and forms, together with the electrostatic chuck 113, a ring support surface 111b that supports the ring assembly 112.

[0027] The cylindrical side portion 114a of the base 114 is mounted on the bottom wall 101 of the plasma processing chamber 10 and protrudes vertically upward by a short distance from the upper surface of the bottom wall 101. The protruding height of the cylindrical side portion 114a is set to be higher than that of the clamping member 115a. Therefore, the upper end of the cylindrical side portion 114a is located radially inside the protective member 116 supported by the clamping member 115a.

[0028] The bottom wall 101 of the plasma processing chamber 10 and the cylindrical side portion 114a of the substrate support portion 11 (base 114) are fixed together by fastening bolts or the like (not shown). A radical blocking portion 50, which has a structure different from that of the seal portion 60, is provided at a boundary 70D between the upper surface of the bottom wall 101 and the lower surface of the cylindrical side portion 114a. The configuration of this radical blocking portion 50 will be described in detail later.

[0029] The ceiling 114b of the base 114 is formed in a radially wide annular shape, and its outer periphery is installed at the upper end of the cylindrical side 114a. A placement hole (not shown) for placing the accommodation portion 114c is formed through the center of the ceiling 114b. The internal space 11s of the substrate support 11 is defined by the bottom wall 101, cylindrical wall 103, cylindrical side 114a, and ceiling 114b of the plasma processing chamber 10.

[0030] The cylindrical side portion 114a and the ceiling portion 114b of the base 114 are fixed together by fastening bolts or the like (not shown). A radical blocking portion 50 is provided at a boundary 70E between the upper surface of the cylindrical side portion 114a and the lower surface of the ceiling portion 114b.

[0031] The storage section 114c of the base 114 includes a support column 114c1 extending vertically through the center of the substrate support section 11, and a horizontally deployed section 114c2 extending radially outward from the vertically upper side of the support column 114c1. In FIG. 2, the support column 114c1 and the horizontally deployed section 114c2 are indicated by the same hatching and are shown as being integrated with each other, but the storage section 114c may be composed of multiple components. The horizontally deployed section 114c2 is disposed between the ceiling section 114b and the disk section 114d and is supported by the ceiling section 114b. The vertically upper side of the support column 114c1 and part or all of the horizontally deployed section 114c2 of the storage section 114c are made of a conductive material.

[0032] Although not shown, the interior of the support pillar 114c1 has a cavity or multiple passages. The support pillar 114c1 accommodates one or more wires 35 connected to the RF power supply 31, one or more wires 36 connected to the DC power supply 32, one or more wires 37 connected to the electrostatic chuck 113, and the like. The wires 35 and 36 extend radially outward from the upper portion of the support pillar 114c1 and are electrically connected to the conductive members of the horizontally expanding portion 114c2. This allows appropriate signals, such as a source RF signal, a bias RF signal, a first bias DC signal, and a second bias DC signal, to be applied to the horizontally expanding portion 114c2. The housing portion 114c may be formed of an insulating material, and the wires 35 and 36 housed in the housing portion 114c may be connected to the disk portion 114d, which may be formed of a conductive material.

[0033] The ceiling 114b and the storage section 114c (horizontally deployed section 114c2) of the base 114 are fixed together with fastening bolts (not shown) or the like. A radical blocking section 50 is provided at a boundary 70F between the upper surface of the ceiling 114b and the lower surface of the storage section 114c.

[0034] Meanwhile, a partition member 106 is provided between the cylindrical wall 103 of the plasma processing chamber 10 and the support column 114c1 of the base 114, separating the space below the cylindrical wall 103 from the internal space 11s. The partition member 106 is formed in a circular ring shape in a plan view and is made of a material capable of blocking the movement of gas. A seal portion 60 is provided at a boundary 70B between the outer peripheral surface of the partition member 106 and the inner peripheral surface of the cylindrical wall 103. Similarly, a seal portion 60 is provided at a boundary 70C between the inner peripheral surface of the partition member 106 and the outer peripheral surface of the support column 114c1. This allows the plasma processing apparatus 1 to airtightly close the lower side of the internal space 11s of the substrate support member 11. Note that the plasma processing apparatus 1 may be configured so that the substrate support member 11 is rotatable relative to the plasma processing chamber 10. For example, a configuration in which the support column 114c1 is rotated about its axis to rotate a vertically upper member. In this case, the plasma processing apparatus 1 may employ, instead of the partition member 106, a magnetic fluid seal that seals the internal space 11s while allowing the support 114c1 to rotate.

[0035] The disk portion 114d of the base 114 is provided on the upper surface of the accommodation portion 114c (horizontally deployed portion 114c2) and supports the electrostatic chuck 113. The upper surface of the disk portion 114d and the lower surface of the electrostatic chuck 113 are firmly fixed together using an adhesive or the like with high thermal conductivity. The disk portion 114d has a temperature adjustment unit 117 therein that adjusts at least one of the substrate W and the ring assembly 112 to a target temperature. The temperature adjustment unit 117 includes a heater that generates heat based on power supply, a flow path through which a heat transfer fluid such as brine or gas flows, or a combination of these (FIG. 2 illustrates a flow path). Alternatively, the substrate support unit 11 may include a heat transfer gas supply unit that supplies a heat transfer gas between the back surface of the substrate W and the substrate support surface 111a.

[0036] The storage section 114c (horizontally expanded section 114c2) and the disk section 114d of the base 114 are fixed together by fastening bolts or the like (not shown). A radical blocking section 50 is provided at the boundary 70G between the upper surface of the storage section 114c and the lower surface of the disk section 114d. As described above, the base 114 is provided with a plurality of (four in this embodiment) radical blocking sections 50 at the same planar position (positions that roughly overlap in the vertical direction) in the height direction of the outer periphery. This allows the plasma processing apparatus 1 to use radical blocking sections 50 of the same structure, making it possible to use common components.

[0037] The electrostatic chuck 113 provided on the upper surface of the disk portion 114d of the base 114 is electrically connected to wiring 37 passing through the inside of the base 114 (accommodation portion 114c, disk portion 114d). The electrostatic chuck 113 generates an electrostatic force based on power supplied from the wiring 37, and adsorbs the substrate W placed on the substrate support surface 111a. Note that, although FIG. 2 shows the electrostatic chuck 113 that electrostatically adsorbs the substrate W, the present invention is not limited to this, and the substrate support portion 111 may hold the substrate W by vacuum adsorption or mechanical locking.

[0038] As described above, a step lower than the substrate support surface 111a is formed on the outer periphery of the electrostatic chuck 113. The electrostatic chuck 113 electrostatically attracts the ring assembly 112 by supplying power to this step as well. The electrostatic chuck 113 also transfers the temperature adjusted by the temperature adjustment unit 117 of the disk portion 114d to the substrate W, and also attracts radicals generated in the plasma processing space 10s toward the electrostatic chuck 113 (substrate W) based on an appropriate signal from the power supply 30.

[0039] Furthermore, the substrate support part 11 includes a plurality of pipes 117a, a plurality of lifters 118, etc. of the temperature adjustment part 117, which are accommodated in an internal space 11s provided inside the base 114 (one pipe 117a and one lifter 118 are shown as representatives in FIG. 2). Alternatively, the substrate support part 11 may include wiring 37 installed in the accommodation part 114c in the internal space 11s, and may also include a fluorescent thermometer (not shown) or the like in the internal space 11s.

[0040] Each pipe 117a of the temperature adjustment unit 117 is connected to each pipe 117b provided outside the plasma processing chamber 10 via the bottom wall 101. Each pipe 117b is connected to a chiller (not shown) or the like that adjusts the temperature of the heat transfer fluid. Each pipe 117a extends vertically through the internal space 11s and is connected to a flow path in the disk portion 114d. Thus, the temperature adjustment unit 117 circulates the heat transfer fluid through each pipe 117a, 117b and the flow path in the disk portion 114d.

[0041] Each lifter 118 has pins 118p extending vertically and a drive unit 118a that raises and lowers the pins 118p. Each lifter 118 raises and lowers the pins 118p from the substrate support surface 111a to receive and deliver the substrate W to and from a transport device (not shown).

[0042] The plasma processing chamber 10 may also include a pressure reduction unit 119 that reduces the pressure in the internal space 11s of the substrate support 11. The pressure reduction unit 119 includes, for example, a pressure reduction pipe 119L connected to the bottom wall 101, and the pressure reduction pipe 119L is connected to a pressure adjustment valve and a vacuum pump (not shown) that are provided separately from the exhaust system 40. By providing the pressure reduction unit 119 in addition to the exhaust system 40 that reduces the pressure in the plasma processing space 10s, the plasma processing chamber 10 can smoothly reduce the pressure in the internal space 11s of the substrate support 11. The pressure reduction unit 119 may also be connected to the vacuum pump of the exhaust system 40.

[0043] Next, the configurations of the seal unit 60 and the radical blocking unit 50 provided in the plasma processing apparatus 1 will be described with reference to FIG. 3. FIG. 3(A) is an enlarged cross-sectional view of the seal unit 60 at point IIIA in FIG. 2. FIG. 3(B) is an enlarged cross-sectional view of the radical blocking unit 50 at point IIIB in FIG. 2. FIG. 3(C) is an enlarged cross-sectional view of a radical blocking unit 50A according to a modified example. Below, the seal unit 60 provided at the boundary 70A between the bottom wall 101 and the cylindrical wall 103 in FIG. 3(A) will be described as a representative example, but it goes without saying that seal units 60 at other locations have a similar configuration. Furthermore, the radical blocking unit 50 provided at the boundary 70D between the bottom wall 101 and the cylindrical side portion 114a in FIG. 3(B) will be described as a representative example, but it goes without saying that radical blocking units 50 at other locations also have a similar configuration.

[0044] The seal portion 60 includes a groove portion 61 and a seal member 62 housed inside the groove portion 61. Although the seal portion 60 is formed on the flange 103f of the cylindrical wall 103 in Fig. 3(A), the seal portion 60 may be provided on the bottom wall 101. In short, the seal portion 60 may be provided on one (or both) of the two members forming the boundaries 70A to 70C.

[0045] The groove 61 of the seal portion 60 is formed at a position facing the bottom wall 101, and extends around the upper surface of the cylindrical wall 103 (flange 103f) in a circular shape in plan view. The depth of the groove 61 is set smaller than the diameter of the seal member 62.

[0046] The seal member 62 is formed as an O-ring that is accommodated in the annular groove 61. When the seal member 62 is accommodated in the groove 61, the portion of the seal member 62 that protrudes from the groove 61 comes into contact with the bottom wall 101, causing the seal member 62 to elastically deform. This allows the seal member 62 to airtightly seal the outside of the plasma processing chamber 10 from the internal space 11s. Note that although FIG. 3(A) illustrates the seal member 62 as being solid in cross section, the seal member 62 may also be hollow in cross section.

[0047] 2, each seal 60 provided in the plasma processing apparatus 1 is spaced apart from the plasma processing space 10s. That is, each seal 60 is located radially inward of the outer periphery (such as the cylindrical side portion 114a) of the substrate support 11, and is provided on the opposite side of the internal space 11s from the ceiling portion 114b of the base 114. In other words, the seal 60 airtightly closes the vertically lower side of the internal space 11s at a position where radicals generated in the plasma processing space 10s cannot reach and where heat from the plasma processing space 10s is difficult to transfer.

[0048] For this reason, a general-purpose O-ring with low plasma durability and reduced heat resistance can be used as the seal member 62 housed in each seal portion 60. Specifically, the seal member 62 can be made of an organic compound that does not contain fluorine or silicone. Examples of materials for this type of seal member 62 include nitrile rubber, acrylic rubber, ethylene propylene rubber, and chloroprene rubber. Alternatively, the seal member 62 may be made of natural rubber or natural synthetic rubber.

[0049] 3(B), the radical blocking section 50 also includes a groove 51 and a sealing member 52 housed inside the groove 51. Although the radical blocking section 50 is formed in the bottom wall 101 in FIG. 3(B), the radical blocking section 50 may be provided in the cylindrical side section 114a. In short, the radical blocking section 50 may also be provided in one (or both) of the two members forming the boundaries 70D to 70G.

[0050] The groove 51 of the radical blocking part 50 is formed at a position facing the cylindrical side part 114a, and in a plan view, surrounds the upper surface of the bottom wall 101 in an annular shape. The depth of the groove 51 is set smaller than the diameter of the seal member 52.

[0051] The seal member 52 is formed as an O-ring that is housed in the annular groove 51. When housed in the groove 51, the portion of the seal member 52 that protrudes from the groove 51 comes into contact with the cylindrical side portion 114a, causing the seal member 52 to elastically deform. This allows the seal member 52 to airtightly seal the outside (passage 10f) of the substrate support 11 from the internal space 11s. Note that although FIG. 3(B) illustrates the seal member 52 as being solid in cross section, the seal member 52 may also be hollow in cross section.

[0052] 2, each radical blocking unit 50 provided in the plasma processing apparatus 1 is located closer to the plasma processing space 10s than the seal unit 60. That is, each radical blocking unit 50 is located on the outer periphery of the substrate support unit 11, where radicals generated in the plasma processing space 10s may reach and where heat from the plasma processing space 10s is easily transmitted.

[0053] For this reason, a high-performance O-ring with high plasma resistance and heat resistance is used as the seal member 52 housed in each radical blocking unit 50. Specifically, the seal member 52 can be made of an organic compound containing one or both of fluorine and silicone. Examples of materials for this type of seal member 52 include fluororubber (FKM, FPM), tetrafluoroethylene-propylene fluororubber (FPEM), and perfluoroelastomer (FFKM). The seal member 52 may have a surface coated with a coating 53 that is plasma-resistant and heat-resistant.

[0054] However, since the substrate support 11 is installed inside the plasma processing chamber 10, which is in a vacuum atmosphere, the internal space 11s can be evacuated (reduced in pressure) even if the internal space 11s is in communication with the plasma processing space 10s. Therefore, the radical blocking unit 50 does not need to have the function of completely closing the internal space 11s. For example, instead of the sealing member 52, the radical blocking unit 50 may be filled with a material (such as a plasma-resistant or heat-resistant curing agent or porous material) that fills the gap between two members (including the groove 51).

[0055] 3(C), the radical blocking unit 50A according to the modified example has irregularities 55 on the bottom wall 101 and irregularities 56 on the cylindrical side portion 114a, whereby these irregularities 55, 56 fit together to form a labyrinth structure. In this way, even when the radical blocking unit 50A has a labyrinth structure, it can block radicals in the plasma processing space 10s from moving toward the internal space 11s. Note that the radical blocking unit 50A may be configured such that gaps between the irregularities 55, 56 are filled with a material (such as a plasma-resistant or heat-resistant curing agent or porous material) that fills the gaps.

[0056] The plasma processing apparatus 1 according to the embodiment is basically configured as described above. In this plasma processing apparatus 1, a substrate W is placed on the substrate support surface 111a of the substrate support member 11 and adsorbed thereto. Thereafter, the plasma processing apparatus 1 generates plasma in the plasma processing space 10s by supplying RF power from the power supply 30 to the substrate support member 11 and the shower head 13 while supplying a processing gas from the gas supply unit 20. This allows the plasma processing apparatus 1 to perform appropriate plasma processing (etching, film formation, etc.) on the substrate W.

[0057] The plasma processing apparatus 1 has a radical blocking unit 50 and a sealing unit 60 in the plasma processing chamber 10 and the substrate support unit 11. For example, the substrate support unit 11 can reduce the pressure of the internal space 11s using the pressure reducing unit 119 to create a vacuum atmosphere. Even when plasma is generated in the plasma processing space 10s, the plasma processing apparatus 1 can maintain an appropriate environment within the substrate support unit 11 by preventing radicals from entering the internal space 11s using the radical blocking unit 50. This significantly reduces deterioration of various components within the substrate support unit 11. Furthermore, even though the plasma processing apparatus 1 has a configuration capable of preventing radicals from entering, it uses a general-purpose sealing member 62 in areas away from the plasma processing space 10s. This allows for fewer high-performance sealing members 52, thereby reducing environmental impact and costs.

[0058] In particular, by providing the radical blocking unit 50 on the outer periphery of the substrate support unit 11, it is possible to prevent radicals from entering around the outer periphery. On the other hand, by being located inside the radical blocking unit 50, the seal unit 60 can more reliably prevent exposure to radicals. Furthermore, deterioration of the multiple lifters 118 housed in the internal space 11s of the substrate support unit 11 due to radicals is also suppressed. Furthermore, by providing the pressure reducing unit 119, the plasma processing apparatus 1 can quickly create a vacuum atmosphere in the internal space 11s, thereby enabling efficient adjustment of the pressure in the plasma processing chamber 10 as a whole.

[0059] The installation positions of the radical blocking unit 50 and the sealing unit 60 are not limited to those in the above embodiment and may be designed arbitrarily. For example, in the above embodiment, the radical blocking unit 50 is provided at the boundary 70D between the bottom wall 101 and the substrate support unit 11 (cylindrical side portion 114a), thereby enhancing radical blocking performance. However, the boundary 70D between the bottom wall 101 and the cylindrical side portion 114a may be provided with the sealing unit 60 instead of the radical blocking unit 50. This is because this location is somewhat distant from the plasma processing space 10s and is less susceptible to the effects of plasma. Furthermore, the radical blocking unit 50 may be provided at the boundary between the clamping member 115a and the protective member 116, or at the boundary between the electrostatic chuck 113 and the base 114 (disk portion 114d).

[0060] The above-disclosed embodiments include, for example, the following aspects. [Appendix 1] a processing vessel having a plasma processing space therein for generating plasma; a substrate support unit that supports a substrate inside the processing chamber, the processing vessel and / or the substrate support unit are configured by assembling a plurality of members, and have a plurality of boundaries connecting the plurality of members together; The plurality of boundaries are: a radical blocking unit that blocks radicals generated in the plasma processing space; a seal part that is provided at a position farther away from the plasma processing space than the radical blocking part and that blocks the passage of gas. Plasma processing equipment. [Appendix 2] the substrate support part has the radical blocking part on its outer periphery, 2. The plasma processing apparatus according to claim 1. [Appendix 3] the substrate support portion has an internal space inside the outer periphery, and the internal space accommodates a plurality of lifters that raise and lower the substrate supported by the substrate support portion. 3. The plasma processing apparatus according to claim 2. [Appendix 4] a decompression unit that decompresses the internal space, separate from an exhaust system that decompresses the internal space by sucking gas therein; 4. The plasma processing apparatus according to claim 3. [Appendix 5] the sealing portion is located inside the radical blocking portion of the substrate support portion. 5. The plasma processing apparatus according to claim 2, wherein the plasma processing apparatus is a plasma processing apparatus. [Appendix 6] a plurality of the radical blocking portions of the substrate support portion are provided at the same planar positions in the height direction of the outer circumferential portion; 6. The plasma processing apparatus according to claim 2, wherein the plasma processing apparatus is a plasma processing apparatus. [Appendix 7] the processing vessel has a bottom wall to which the substrate support is fixed, The radical blocking portion is provided at the boundary between the bottom wall and the substrate support portion. 7. The plasma processing apparatus according to claim 1, [Appendix 8] the processing vessel has a wall portion connected to the bottom wall, The seal portion is provided at the boundary between the bottom wall and the wall portion. 8. The plasma processing apparatus according to claim 7. [Appendix 9] the substrate support section includes a support column inside the wall section that can accommodate wiring capable of supplying power, and a partition member that partitions a space between the support column and the wall section; The seal portion is provided at the boundary between the support column and the partition member, and at the boundary between the partition member and the wall portion. 9. The plasma processing apparatus according to claim 8. [Appendix 10] the radical blocking portion has a groove portion and a sealing member that is made of a material containing fluorine and is accommodated in the groove portion; 10. The plasma processing apparatus according to any one of claims 1 to 9. [Appendix 11] The radical blocking portion forms a labyrinth structure by the concave and convex portions formed on the plurality of members. 11. The plasma processing apparatus according to claim 1. [Appendix 12] The sealing portion has a groove and a sealing member that is made of a material that does not contain fluorine and is accommodated in the groove. 12. The plasma processing apparatus according to claim 1.

[0061] The plasma processing apparatus 1 according to the embodiment disclosed herein is illustrative in all respects and not restrictive. The embodiment can be modified and improved in various ways without departing from the spirit and scope of the appended claims. The matters described in the above-described embodiments can be configured in other ways as long as they are not inconsistent, and can be combined as long as they are not inconsistent.

[0062] The plasma processing apparatus 1 of the present disclosure can be applied to any type of apparatus, including atomic layer deposition (ALD) apparatus, capacitively coupled plasma (CCP), inductively coupled plasma (ICP), radial line slot antenna (RLSA), electron cyclotron resonance plasma (ECR), and helicon wave plasma (HWP).

[0063] This application claims priority from basic application No. 2023-134592, filed with the Japan Patent Office on August 22, 2023, the entire contents of which are incorporated herein by reference. [Explanation of symbols]

[0064] 1. Plasma processing equipment 10 Plasma Processing Chamber 10s Plasma treatment space 11 Substrate support 50 Radical blocking section 60 Seal part W substrate

Claims

1. a processing vessel having a plasma processing space therein for generating plasma; a substrate support unit that supports a substrate inside the processing chamber, the processing vessel and / or the substrate support unit are configured by assembling a plurality of members, and have a plurality of boundaries connecting the plurality of members together; The plurality of boundaries are: a radical blocking unit that blocks radicals generated in the plasma processing space; a seal part that is provided at a position farther away from the plasma processing space than the radical blocking part and that blocks the passage of gas, The substrate support includes: The radical blocking portion is provided on the outer periphery, an internal space is formed inside the outer periphery, and a plurality of lifters that raise and lower the substrate supported by the substrate support portion are housed in the internal space; a decompression unit that decompresses the internal space, separate from an exhaust system that decompresses the internal space by sucking gas therein; Plasma processing equipment.

2. a processing vessel having a plasma processing space therein for generating plasma; a substrate support unit that supports a substrate inside the processing chamber, the processing vessel and / or the substrate support unit are configured by assembling a plurality of members, and have a plurality of boundaries connecting the plurality of members together; The plurality of boundaries are: a radical blocking unit that blocks radicals generated in the plasma processing space; a seal part that is provided at a position farther away from the plasma processing space than the radical blocking part and that blocks the passage of gas, the processing vessel has a bottom wall to which the substrate support is fixed, The radical blocking portion is provided at the boundary between the bottom wall and the substrate support portion. Plasma processing equipment.

3. a processing vessel having a plasma processing space therein for generating plasma; a substrate support unit that supports a substrate inside the processing chamber, the processing vessel and / or the substrate support unit are configured by assembling a plurality of members, and have a plurality of boundaries connecting the plurality of members together; The plurality of boundaries are: a radical blocking unit that blocks radicals generated in the plasma processing space; a seal part that is provided at a position farther away from the plasma processing space than the radical blocking part and that blocks the passage of gas, the radical blocking portion forms a labyrinth structure by unevenness formed on the plurality of members; Plasma processing equipment.

4. the substrate support part has the radical blocking part on its outer periphery, 4. The plasma processing apparatus according to claim 2 or 3.

5. the substrate support portion has an internal space inside the outer periphery, and the internal space accommodates a plurality of lifters that raise and lower the substrate supported by the substrate support portion. The plasma processing apparatus according to claim 4 .

6. a decompression unit that decompresses the internal space, separate from an exhaust system that decompresses the internal space by sucking gas therein; The plasma processing apparatus according to claim 5 .

7. the sealing portion is located inside the radical blocking portion of the substrate support portion. The plasma processing apparatus according to claim 1 .

8. the sealing portion is located inside the radical blocking portion of the substrate support portion. The plasma processing apparatus according to claim 4 .

9. a plurality of the radical blocking portions of the substrate support portion are provided at the same planar positions in the height direction of the outer circumferential portion; The plasma processing apparatus according to claim 1 .

10. a plurality of the radical blocking portions of the substrate support portion are provided at the same planar positions in the height direction of the outer circumferential portion; The plasma processing apparatus according to claim 4 .

11. the processing vessel has a bottom wall to which the substrate support is fixed, The radical blocking portion is provided at the boundary between the bottom wall and the substrate support portion.

4. The plasma processing apparatus according to claim 1 or 3.

12. the processing vessel has a wall portion connected to the bottom wall, The seal portion is provided at the boundary between the bottom wall and the wall portion. The plasma processing apparatus according to claim 11 .

13. the substrate support section includes a support column inside the wall section that can accommodate wiring capable of supplying power, and a partition member that partitions a space between the support column and the wall section; The seal portion is provided at the boundary between the support column and the partition member, and at the boundary between the partition member and the wall portion. The plasma processing apparatus according to claim 12 .

14. the radical blocking portion has a groove portion and a sealing member that is made of a material containing fluorine and is accommodated in the groove portion; The plasma processing apparatus according to claim 1 .

15. the radical blocking portion forms a labyrinth structure by unevenness formed on the plurality of members; 3. The plasma processing apparatus according to claim 1 or 2.

16. The sealing portion has a groove and a sealing member that is made of a material that does not contain fluorine and is accommodated in the groove. The plasma processing apparatus according to claim 1 .

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