Fibrous amino acid-based substrates, particularly nonionic high molecular weight fatty acid compounds for hair treatment.

Abstract

Based primarily on sustainable raw materials, it can be synthesized in a simple, cost-effective, and flexible manner, is easy to formulate and use, and provides hair care formulations useful for conditioning hair and improving combability, smoothness, and a pleasant finish for both dry and wet hair. [Solution] The present invention provides a hair care formulation comprising at least one nonionic compound comprising at least one terminal estolide moiety, a nonionic compound comprising at least one terminal estolide moiety, the use of a nonionic compound comprising at least one terminal estolide moiety in a cosmetic formulation for skin and / or hair care, the use of a nonionic compound comprising at least one terminal estolide moiety for fiber treatment, and a composition comprising at least one such compound for hair treatment.

Description

[Technical Field]

[0001] This invention relates to nonionic polymer fatty acid compounds, the use of nonionic polymer fatty acid compounds, aqueous compositions containing the same, cosmetic compositions containing the same, particularly hair care compositions, and the use of the same for hair treatment. [Background technology]

[0002] Hair can generally be straight, wavy, curly, twisted, or kinky. Human hair consists of three main morphological elements: the cuticle (the outermost thin shell of several concentric layers), the cortex (the body of the hair), and, in the case of larger diameter hair, the medulla (a thin central nucleus). The cuticle and cortex give rise to the mechanical properties of the hair, namely its tendency to be wavy, curly, or twisted. Straight hair may resemble a rod with a circular cross-section, wavy hair may appear compressed into an oval cross-section, curly hair may appear even more compressed into an elongated oval cross-section, and the cross-section of twisted hair may be even flatter.

[0003] The main component of hair is the cross-linked alpha-helix protein keratin. Keratin is an intermediate filament protein specifically found in epithelial cells, such as human skin and hair, wool, feathers, and nails. Alpha-helix type I and type II keratin intermediate filament proteins (KIFs), with molecular weights of approximately 45-60 kDa, are embedded in an amorphous matrix of keratin-related proteins (KAPs), with molecular weights of 20-30 kDa (MA Rogers, L. Langbein, S. Praetzel-Wunder, H. Winter, J. Schweizer, J. Int Rev Cytol. 2006; 251:209-6); both intramolecular and intermolecular disulfide bonds provided by cystine contribute to the cytoskeletal protein network that maintains the cytoskeleton. In addition to disulfide crosslinks, ionic bonds or salt bridges pairing various amino acids found in hair proteins contribute to the outward shape of the hair.

[0004] It is known in the art that hair can be treated with functionalized silicones and hydrocarbons that provide one or more cosmetic benefits, such as conditioning, shine, UV protection, and color retention. Typically, these silicone and hydrocarbon-based derivatives physically deposit on the fiber surface (cuticle) and thus contribute to the appearance of the hair, namely its smoothness, silky feel, friction resistance, alignment, and combability. Advanced silicone derivatives are generally considered high-performance materials with respect to attributes such as a smooth, silky hair feel, reduced friction, easy combability, and protection of hair color.

[0005] Classified silicones are described in the prior art disclosures, namely US4891166, EP282720, US2008027202, US6730766, US6240929, WO02 / 10257, WO02 / 10259, WO2004 / 069137, WO2013 / 148629, WO2013 / 148635, and WO2013 / 148935.

[0006] Typical hydrocarbon-based monoquaternary ammonium compounds are saturated or unsaturated fatty acid-based monofatty acid esters and difatty acid ester quats, as well as fatty amide quats having 10 to 24 carbon atoms in the alkyl chain. Details of these materials containing quaternary ammonium groups are disclosed, for example, in US2009 / 0000638, WO2012 / 027369, US2013 / 259820 and US5880086, US6465419, US6462014, US6323167, US6037315, US5854201, US5750490, US5463094 and US2003 / 013627. Certain monoquats containing polymerized fatty acids as hydrophobic tails are proposed for personal care applications in WO2004 / 093834.

[0007] Nonionic ester derivatives containing polymerized fatty acids have been proposed as lubricants (US2011 / 0282084).

[0008] C3 to C20 alcohol esters of high molecular weight fatty acids have been proposed as conditioning agents (WO2016 / 174256). WO2013 / 009471 describes C1 to C40 alcohol esters of high molecular weight fatty acids for the same application.

[0009] Esters of Guerbet alcohols containing ricinoleic acid improve skin radiance (US5786389). Polyesters of Guerbet alcohols containing dimer acids and dimer alcohols are proposed for the same application (US7259226). Polyesters of polyalkylene oxides with dimer acids and monofunctional acids are skin conditioners (US6800275).

[0010] Esterified monomers and polymeric castor oil derivatives are also known and have been proposed as lubricants (US 2049072; A. Erdem-Senatalar et. al., J. Am. Oil Chem.Soc.1994, 71(9), 1035-1037; AT Erciyes et. al., J. Am. Oil Chem.Soc.1991, 68(9), 639-641; KDPathak, J. Scientific & Industrial Res. 1955, 14B, 637-639). EP665286 describes the estolide moiety containing triglycerides as a lubricant and thickener.

[0011] Partial transesterification of high molecular weight fatty acids with plant-based oils yields products useful as emollients and moisturizers (FR2858616).

[0012] Esterilization of castor oil with succinic acid or dimer acid and monofunctional C6 to C34 acids yields polyesters that give a glossy finish to the skin (US6787129, US6670441).

[0013] There is a need for a fibrous amino acid-based substrate, particularly an efficient compound for hair treatment, that can be synthesized in a simple, cost-effective, and flexible manner, is easy to formulate and use, provides long-term stable formulations even in the presence of other functional ingredients, and helps condition hair, improve combability in both dry and wet hair, and give hair smoothness and a pleasant finish. In particular, it is necessary to achieve improved combability in both wet and dry conditions, similar to silicone-based conditioning agents.

[0014] The inventors have found that nonionic polymer fatty acid-based estolide compounds and aqueous compositions containing the same are suitable for meeting the above needs. Accordingly, the present invention provides nonionic polymer fatty acid-based estolide compounds, aqueous compositions containing the same, cosmetic compositions containing the same, particularly hair care compositions, and their use for hair treatment, wherein nonionic polymer fatty acid-based estolide compounds can be synthesized in a simple, cost-effective, and flexible manner, mainly based on sustainable raw materials, are easy to formulate and use, and are useful for hair conditioning and improved combability, smoothness, and pleasant alignment of dry and wet hair. [Overview of the project]

[0015] The present invention relates to nonionic polymer fatty acid-based estolide compounds, aqueous compositions containing the same, cosmetic compositions containing the same, particularly hair care compositions, and their use in hair treatment.

[0016] According to the present invention, the present invention provides a hair care formulation comprising at least one compound of formula (I), R 1 (-XC(O)-F) p (I) Here R in equation (I) 1 It is selected from p-valent, optionally substituted hydrocarbon radicals, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] It may contain one or more groups selected from quaternary ammonium groups, and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups. p≧2, more preferably 2-8¹¹, X may be the same or different, and it can be -O- or -NR. 10 - Selected from, here R 10is selected from the group consisting of optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals having hydrogen, or up to 100 carbon atoms, and optionally containing one or more groups selected from -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups

Chemical formula

Chemical formula

[0017] According to the present invention, estolids are natural and synthetic compounds derived particularly from oils and fats, and more specifically from fatty acid compounds typically obtained by the hydrolysis of oils and fats.

[0018] The estrid structure is identified by a secondary ester bond of one fatty acid fragment of one fatty acid molecule to an alkyl backbone. The terms “fatty acid” and “fatty acid molecule” may seem to imply that the individual residues must be derived from fatty components, but this is not the case. In this specification, the term “fatty acid” refers to carboxylic acids having a chain organyl group, particularly unbranched aliphatic monocarboxylic acids. Fatty acids differ from one another by the number of carbon atoms (chain length) and, if referring to unsaturated fatty acids, the number and position of double bonds. Fatty acids can be classified into short-chain fatty acids with up to 7 carbon atoms, medium-chain fatty acids with 8 to 12 carbon atoms, long-chain fatty acids with 13 to 21 carbon atoms, and very long-chain fatty acids with more than 22 carbon atoms.

[0019] According to the present invention, the residue R of formula (I) 1 The following groups can be optionally selected: -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. [ka] The p-valent, optionally substituted hydrocarbon radicals may comprise one or more groups selected from quaternary ammonium groups and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups.

[0020] According to the present invention, residue R 1 is the p-value, where p is 2 to 811, preferably 2 to 100, more preferably 2 to 50, and even more preferably 2 to 30, which is the residue R 1 This indicates that it has a p residue of the structure (-XC(O)-F), where F is as defined above. Therefore, the term "p-value" refers to the residue R which can be a carboxyl group or a hydroxyl group. 1 This does not refer to or limit the number of additional optional substituents other than (-XC(O)-F).

[0021] According to the present invention, the expression “optionally substituted hydrocarbon radical” may optionally contain and be substituted with one or more specific groups, and refers to an organyl radical linked to one or more further groups via at least one of its carbon atoms, where the hydrocarbyl structure of the radical may be interrupted by the defined specific groups that will be included, and one or more hydrogen atoms of the hydrocarbyl group may be substituted with the indicated substituents.

[0022] R 1 In this case, for example, one or more hydrogen atoms may be substituted with a hydroxyl group or a carboxyl group.

[0023] Furthermore, optionally substituted hydrocarbon radicals R 1 Specifically, these are -O-, -NH-, -C(O)-, -C(S)- and tertiary amino groups. [ka] Since it may contain one or more groups selected from R1 The hydrocarbyl structure of the group can be interrupted by these groups or combinations thereof. Therefore, the residue can include ester groups, carboxyl groups, amide groups, ether groups, amino groups, carbonyl groups, thione groups, thiocarboxylate groups, thioester groups, carbamate groups, urethane groups, epoxide groups, and all other groups identified for this radical and combinations thereof. The same principle applies to optionally substituted hydrocarbon radicals R. 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 7* , and R 10 Applies to .

[0024] R is the p-value for the residue (-XC(O)-F) 1 The hydrocarbyl structure is preferably selected from the group consisting of linear, branched or cyclic alkylene groups, linear, branched or cyclic alkenylene groups, linear, branched or cyclic alkylene groups, linear, branched or cyclic aralkylene groups, and linear, branched or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, in particular, such groups having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms.

[0025] Preferably, the hydrocarbon structure is a linear or branched alkylene group, or a linear or branched alkylene group interrupted by an ether group, an ester group, or both an ether and an ester group, particularly a branched structure derived from a product obtained by esterification of a mono- or polyhydroxycarboxylic acid having up to 150 carbon atoms or a linear alkylene group having up to 22 carbon atoms.

[0026] Comfort, p-value R 1The radical is selected from alkylene groups, which can be selected from linear, branched, and cyclic alkylene groups, particularly from the group consisting of linear C1-C22 alkyl groups such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, and branched C1-C22 alkylene groups such as isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups.

[0027] Which C atom of the hydrocarbyl radical is R 1 There are no restrictions regarding whether it has a (-XC(O)-F) group attached to it.

[0028] R 1 Regarding the presence of any functional groups and any substituents included in R 1 It is preferably derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, or R 1 It is preferable that the linear alkylene group is derived from a linear alkylene group, particularly an alkylene group that does not have further substituents in addition to the (-XC(O)-F) group, and R 1 It is even more preferable that the fatty acids are derived from glycidol, glycerol, glycerol diglycidyl ether, condensation products of diglycidyl ethers and polyglycerol compounds, and C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid, or 12-hydroxystearic acid.

[0029] Typically, the base (-XC(O)-F) is R 1 -OH or -NHR in the parent compound derived from 10 Radical R via the -XC(O)- unit, particularly the -OC(O)- unit, at the position substituted by the group. 1 It is obvious to those skilled in the art that they can be combined.

[0030] For example, R derived from glycerol 1The group is a 1,2,3-propylene radical, where "1,2,3" indicates the position where the radical is substituted with a (-XC(O)-F)- group.

[0031] According to the present invention, the term “optionally substituted hydrocarbon residues” does not impose further restrictions on radicals, and is therefore limited by the groups that may be optionally included or present as substituents, the number of carbon atoms in the identified residues, and the way in which they are bonded to other structural parts of the compound according to the present invention, as defined by formula (I), formula (II), formula (II*), formula (III), formula (IV), formula (V) or formula (V) or any further formula used to define embodiments according to the present invention.

[0032] According to the present invention, the group X may be the same or different, and may be -O- or -NR. 10 - Selected from, here R 10 It has hydrogen, or up to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [ka] Selected from the group consisting of optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from, or in formula (I), R 10 R 1 It can form bonds to form a ring structure.

[0033] R 10 Preferred examples include C1-C10 alkyl groups, particularly methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentane, and n-hexane, cyclopentyl, and cyclohexane, C2-C10 alkenyl groups, particularly vinyl and allyl groups, and C6-C12 aromatic groups, particularly phenyl, tolyl, and benzyl groups, each of which may be substituted with a hydroxyl or halide group.

[0034] According to the present invention, residue F may be the same or different, and may have up to 1005 carbon atoms, and may optionally be -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and optionally substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, provided that at least one compound of the hair care formulation comprises at least one part of formula (II) or formula (II*). -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (II) -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (II*)

[0035] Preferably, base F consists only of the base of formula (II), or base F consists only of the base of formula (II*).

[0036] According to the present invention, R 6 R is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 36 carbon atoms, and therefore R 6 R can be a divalent, optionally substituted linear, cyclic, or branched, saturated, unsaturated, or aromatic hydrocarbon radical, i.e., R 6This can represent a hydrocarbyl group selected from the group consisting of linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkalilene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene groups, benzylene groups, or torylene groups, each optionally containing one or more functional groups as described above, and having 1 to 100 carbon atoms.

[0037] Comfortable, R 6 The radicals are selected from linear alkylene groups and linear alkenylene groups, in particular linear C6-C24 alkylenes, such as hexylene, heptylene, octylene, nonylene, decene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecylen, octadecylene, nonadecylen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or linear C6-C24 alkenylenes. The group is selected from, for example, hexenylene, heptenylene, octenylene, nonenylene, decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where the group is most preferably bonded to an adjacent C(O) group by a terminal C atom.

[0038] In the hydrocarbyl radical, at which C atom is the adjacent C(O) group and X group R 6 There are no restrictions on whether it should be combined with other elements.

[0039] However, R 6 It is preferably derived from a hydroxycarboxylic acid having one or more hydroxyl groups, more preferably from a monohydroxycarboxylic acid, and most preferably from a C7-C25 fatty acid having one hydroxyl group as a substituent. Therefore, R 6R preferably represents the alkylene or alkenylene chain of such a carboxylic acid. For example, R 6 If it is derived from ricinoleic acid, [ka] At that time R 6 This represents the 1,11-heptadeca-8-enyl radical, [ka] Here, "1,11" indicates the positions where the radical is bonded to adjacent groups X and C(O).

[0040] R 6 A preferred example is a structure derived from the corresponding hydroxylcarboxylic acid obtained by subtracting a carboxylate group and one OH group, where the hydroxylcarboxylic acid is preferably selected from ricinoleic acid, reskerolic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or dihydroxycarboxylic acid, and in particular selected from 2,2'-di-hydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or polyhydroxycarboxylic acid, especially gluconic acid. Most preferably, R 6 The compounds are derived from reskerolic acid or ricinoleic acid by the methods described above. In both cases, naturally occurring enantiomers of the compound, namely (9Z,12R)-12-hydroxyoctadeca-9-enoic acid obtained by saponification or fractional distillation of castor oil, which is hydrolyzed castor seed oil, and (11Z,14R)-14-hydroxyicos-11-enoic acid isolated from Paysonia and Physaria species, are particularly preferred. However, racemates, S enantiomers, and E constituent isomers, racemates, enantiomers, and any possible mixtures thereof of the compound are also preferred according to the present invention.

[0041] R of at least one part present in group F of the compound of general formula (I) 6 The number m of the repeating unit (-X-C(O)-R 6 ) is from 0 to 20, preferably from 0 to 15, 0 to 12, 0 to 10, 0 to 8, or 1 to 20, 2 to 20, 3 to 20, 4 to 20, 5 to 20, specifically 0, 1, 2, 3, 4, 5, 6, 7, 8, 9, or 10.

[0042] R 7 has 1 to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, a tertiary amino group,

Chemical formula

Chemical formula

[0043] According to the present invention, the radical R 7are the same or different and can be selected from optionally substituted, straight-chain, cyclic or branched, saturated or unsaturated hydrocarbon radicals having from 1 to 36 carbon atoms, and thus can be straight-chain, branched or cyclic alkyl groups, straight-chain, branched or cyclic alkenyl groups, straight-chain, branched or cyclic alkynyl groups, straight-chain, branched or cyclic alkaryl groups, straight-chain, branched or cyclic aralkyl groups and straight-chain, branched or cyclic aryl groups, for example, those selected from the group consisting of phenyl, benzyl or tolyl, especially such groups having from 6 to 24 carbon atoms, each optionally containing one or more functional groups as shown above.

[0044] More preferably, R 7 radicals are selected from straight-chain alkyl groups and straight-chain alkenyl groups, especially straight-chain C6-C24 alkyl groups, such as hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, docosyl, tricosyl, and tetracosyl, or straight-chain C6-C24 alkenyl groups, such as hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicosenyl, henicosenyl, docosenyl, tricosenyl, and tetracosenyl, where the groups are most preferably bonded to the adjacent C(O) group or X group by the terminal C atom.

[0045] There is no restriction regarding to which C atom of the hydrocarbyl radical the adjacent C(O) group is bonded to R 7 No restriction exists regarding to which C atom of the hydrocarbyl radical the adjacent C(O) group is bonded to R.

[0046] However, R 7It is preferably derived from a carboxylic acid or hydroxycarboxylic acid having one or more hydroxyl groups, more preferably from a carboxylic acid or monohydroxycarboxylic acid, and most preferably from a C7-C25 fatty acid that does not have a hydroxyl group as a substituent. Therefore, R 7 Preferably, R represents the alkyl or alkenyl chain of such a carboxylic acid. For example, R 7 If it is derived from ricinoleic acid, [ka] Here R 7 This represents the 11-hydroxyheptadeca-8-enyl radical, [ka] or R 7 If it originates from oleic acid, [ka] Here R 7 This represents the heptadeca-8-enyl radical. [ka]

[0047] R 7A preferred example is a structure derived from the corresponding carboxylic acid or hydroxylcarboxylic acid from which the carboxylate group has been removed, where the carboxylic acid is acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, margaric acid, stearic acid, linoleic acid, α-linolenic acid, γ-linolenic acid, nonadecylic acid, arachidic acid, meadic acid, arachidonic acid, heneicosanoic acid, docosanic acid, tricosyl It can be selected from lic acid and lignoceric acid, hydroxyl carboxylic acids, such as reskerol acid, ricinoleic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or dihydroxycarboxylic acids, in particular 2,2'-di-hydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or polyhydroxycarboxylic acids, in particular gluconic acid.

[0048] Radical R 7 The following are optional: -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] It may contain one or more groups selected from quaternary ammonium groups. [ka] And it can be substituted with an OH group or a halide group, but radical R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, for forming an internal carboxylate group, i.e., an internal ester group or an internal amide group.

[0049] According to the present invention, in at least one compound of a hair care formulation, at least one portion of formula (II) is R 7 It has at least two, preferably at least six, carbon atoms, and at least one R in the same part of formula (II) 6 It is essential that it has at least 6, preferably at least 8, carbon atoms.

[0050] According to the present invention, the group R of formula (II*) 7* It has 1 to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] A branched or dendrimeric hydrocarbon radical that is optionally substituted and comprises one or more groups selected from and may be substituted with a carboxyl group, a hydroxyl group, or a halide group, and is independently selected from, where Radical R 7* It is terminated by two or more of the following general structures: -XC(O)-T Here, X is as defined above, and T is a monovalent linear, cyclic, or branched saturated or unsaturated hydrocarbon radical having up to 36 carbon atoms and optionally substituted with a carboxyl group, a hydroxyl group, or a halide group. However, in at least one part of equation (II*), R 7* It is terminated by one or more groups T having at least two, preferably at least six, carbon atoms, and in the same part of formula (II*), at least one R 6 It has at least 6, preferably at least 8, carbon atoms.

[0051] R7* Since it is defined as a monovalent group, the general structure -XC(O)-T To provide the structural characteristic of being terminated by at least two groups of residue R, 7* This requires the presence of at least one branching structure.

[0052] R 7* If it is a branched hydrocarbon radical, then as a branched structure, this group includes at least one part of the following general formula: -B(-O-) b Here, B is a linear or branched hydrocarbon group having 3-20 or 3-10 carbon atoms, b is 2 or more, preferably 2-6, more preferably 2-4, and here The (-O-) group bonded to group B on one side is bonded to a C atom on the other side. This C atom could be a CH2 group or a carbonyl group.

[0053] R 7* If it is a dendrimeric hydrocarbon radical, then its group is at least one part of the following general formula -B(-O-) b Here B and b are as defined above, and the group (-O-) bonded to group B on one side is bonded to the C atom on the other side, and At least one further part that functions as a branching structure in the general formula below -C(O)-B(-O-) b Here, B and b are as defined above, and the group (-O-) bonded to group B on one side is bonded to a C atom on the other side, where the C atom may be a CH2 group or a carbonyl group. Thus, the term dendrimeric hydrocarbon structure refers to a branched structure that includes at least two consecutive branched structures.

[0054] Each group T is R 7*It constitutes one of at least two terminal groups of the group and is typically derived from a fatty acid. Therefore, group T is preferably a linear saturated or monounsaturated hydrocarbon radical having 2 to 24 carbon atoms.

[0055] The group T is preferably via a carbonyl group or an estolide chain. General formula -B(-O-) b or -C(O)-B(-O-) b It is connected to the (-O-) group of the branched structure.

[0056] Due to the existence of the above branching structure, R 7* It employs a branched or dendritic structure.

[0057] The following structure is a branched hydrocarbon radical R as defined above. 7* This is an example, [ka] Among them, the general formula B(-O-) b The branched structure originates from 2,2'-dihydroxymethylpropionic acid, and group T is an n-heptadecanyl group bonded to the branched structure. It originates from stearic acid and is bonded to group B by a -C(O)-O- unit. Thus, this structure is terminated by two groups of the general structure -X-(CO)-T and contains the branched structure of formula -B(-O-)2.

[0058] Branching base R 7* Examples of groups from which it may originate are shown below, [ka] Here, R is as follows: [ka]

[0059] Corresponding base R 7*In this case, the branched structure is the same as the structure described above, but the two terminal groups T, which are n-heptadeca-9-enyl groups derived from oleic acid, are attached to the branched structure via an estolide chain structure derived from ricinoleic acid.

[0060] The present invention's group R is a dendrimer hydrocarbon. 7* Another example is shown below. Within that, branched structure -B(-O-) b Immediately following that are two more branched structures -(C(O)-B(-O-) b This continues, and the terminal groups of the general structure -XC(O)-T increase further. [ka]

[0061] In this structure, the branched structure originates from 2,2'-dihydroxymethylpropionic acid, and the terminal group is based on stearic acid.

[0062] Branched or dendrimer-like group R 7* Therefore, it is also within the scope of the present invention as defined above, that the terminal group -XC(O)-T is not directly bonded to group B of the branched structure, but is bonded to the (-O-) group of the branched structure by an optionally substituted or heteroatomic alkylene or alkenylene, preferably an n-alkylene having 2 to 10 carbon atoms, a poly(alkylene oxide) group, such as a poly(ethylene oxide) or poly(propylene oxide) group, or in particular by an oligo or polyester group, i.e., an estolide chain.

[0063] In the following example, the stearic acid-based group XC(O)-T is linked to a branched structure by an estolide chain. [ka] Here [ka]

[0064] Dendrimer-like group R 7* So, the structure is -(C(O)-B(-O-) b One or more branching elements of structure -B(-O-) b or -(C(O)-B(-O-) b Not directly bonded but optionally substituted or containing heteroatomic hydrocarbon groups such as alkylene or alkenylene, preferably via poly(alkylene oxide) groups such as n-alkylene, poly(ethylene oxide) or poly(propylene oxide) groups having 2 to 10 carbon atoms, or particularly via oligo or polyester groups, i.e., via estrid chains, is also within the scope of the present invention as defined above.

[0065] In the following example, the branched structure is linked by estrido chains. [ka] Here [ka]

[0066] In another preferred embodiment of the present invention, R 7* These are derived from carboxylic acids having an additional ester moiety, preferably monocarboxylic acids having one ester moiety. Preferred examples are derived from the reaction of C2 to C24 alcohols, particularly lauryl alcohol, oleyl alcohol, and stearyl alcohol, with carboxylic acid anhydrides, particularly succinic anhydride, maleic anhydride, and itacone anhydride, in the presence of an optional esterification catalyst, to produce the corresponding ester moieties having carboxylic acids, as illustrated below. [ka]

[0067] Alternatively, these groups R are derived from carboxylic acids having additional ester groups. 7*As illustrated in Example 28, this can result from a series of reactions between the OH-terminal intermediate and, in particular, a carboxylic acid anhydride, followed by esterification with a suitable alcohol.

[0068] According to the present invention, the residue R of formula (IV) 1 This is defined in the same way as formula (I), except that it is a q-valent residue where q is from 2 to 55, preferably 2 to 40, more preferably 2 to 4, and this is the same as the residue R in formula (IV). 1 This indicates that has a q residue of the structure (-C(O)-XG), where G is defined below. Thus, the term "q-valence" refers to the residue R of formula (IV), which can be a carboxyl group or a hydroxyl group. 1 The number of any further substituents other than (-C(O)-XG) is not indicated or limited.

[0069] The R of formula (IV) is q-valent with respect to the residue (-C(O)-XG). 1 The hydrocarbyl structure is preferably selected from the group consisting of linear, branched or cyclic alkylene groups, linear, branched or cyclic alkenylene groups, linear, branched or cyclic alkynylene groups, linear, branched or cyclic alkaline groups, linear, branched or cyclic aralkylene groups, and linear, branched or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, particularly those having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms.

[0070] Preferably, the hydrocarbon structure is a linear or branched alkylene group, or a linear or branched alkylene group interrupted by an ether group, an ester group, or both an ether and an ester group, and more particularly, a branched structure derived from a product obtained by esterifying a polyol with a mono or polyhydroxycarboxylic acid having up to 150 carbon atoms, or a linear alkylene group having up to 22 carbon atoms. Also preferred are C2-C6 linear alkenylene groups, particularly 1,2-ethenylene radicals derived from maleic acid or fumaric acid.

[0071] More preferably, the q-valence R of formula (IV) 1 The radical is selected from alkylene groups, which can be selected from the group consisting of linear, branched, and cyclic alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups. Particularly preferred are 1,1-methylene, 1,2-ethylene, 1,3-propylene, 1,2,3-propylene, and 1,4-butylene radicals.

[0072] Which of the C atoms in the hydrocarbyl radical is the R in formula (IV)? 1 There are no restrictions regarding whether it has a (-C(O)-XG) group attached to it.

[0073] R in equation (IV) 1 Regarding the presence of any functional groups and any optional substituents in formula (IV), R 1 It is preferably derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, more preferably from compounds derived from the condensation products of glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds and C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid or 12-hydroxystearic acid, or R 1 This is the case when the group is a linear alkylene group, particularly an alkylene group that has no further substituents in addition to the (-C(O)-XG) group.

[0074] The group (-C(O)-XG) is usually mediated through the -C(O)-X- unit, and especially the -C(O)-O- unit, R 1 It will be obvious to those skilled in the art that it is bonded to radical R1 at the position substituted with the -C(O)OH group in the parent compound from which it originates.

[0075] For example, R derived from succinic acid 1 The group is a 1,2-ethylene radical, where "1,2" indicates the position where the radical is substituted with a (-C(O)-XG)- group.

[0076] According to the present invention, X, R 10 , R 6 , and m are defined for equations (IV) and (V) in the same way as for equations (I) and (II).

[0077] As defined above, R 11 It has 1 to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated, or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with carboxyl, hydroxyl, or halide groups.

[0078] Therefore, R 11 This can represent a hydrocarbyl group selected from the group consisting of linear, branched or cyclic alkyl groups, linear, branched or cyclic alkenyl groups, linear, branched or cyclic alkynyl groups, linear, branched or cyclic alkaryl groups, linear, branched or cyclic aralkyl groups, and linear, branched or cyclic aryl groups, such as phenyl, benzyl, or tolyl, each optionally containing one or more functional groups as described above, and having 6 to 24 carbon atoms.

[0079] Comfortable, R 11The radicals are selected from linear alkyl and linear alkenyl groups, particularly linear C6-C24 alkyl groups, such as hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or linear C6-C24 alkenyl groups, such as hexenyl, heptenyl, octenyl, and nonenyl. Selected from decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the residue may have one or more hydroxyl or carboxyl substituents, and where the group is most preferably bonded to an adjacent C(O) or X group by a terminal C atom.

[0080] Which of the C atoms in the hydrocarbyl radical is adjacent to the group X, R 11 There are no restrictions on whether it should be combined with other elements.

[0081] However, R 11 Preferably, it is derived from a monoalcohol, diol, or polyol having two or more OH groups, or a monohydroxycarboxylic acid or carboxylic acid having two or more hydroxyl groups, more preferably from a monoalcohol or monohydroxycarboxylic acid, and most preferably from a C6-C24 fatty acid having one hydroxyl group as a substituent. Therefore, R 11 Preferably, R represents the alkyl or alkenyl chain of such a carboxylic acid. For example, R 11 If it is derived from ricinoleic acid, [ka] At that time, R 11 This represents the 12-(octadeca-9-enoic acid) radical, [ka] or R 11 If it is derived from dodecanol, [ka] At that time, R 7 This represents a 1-dodecyl radical. [ka]

[0082] R 11 A preferred example is a structure formally derived from the corresponding hydroxylcarboxylic acid from which the hydroxyl group has been removed, where the hydroxylcarboxylic acid can be selected from monohydroxycarboxylic acids, e.g., reskerolic acid, ricinoleic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or from dihydroxycarboxylic acids, in particular from 2,2'-dihydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or from polyhydroxycarboxylic acids, in particular from gluconic acid.

[0083] Similarly, R 11 A preferred example is a structure formally derived from the corresponding mono and diols by formally subtracting one hydroxyl group, where the alcohol can be selected from the group consisting of methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, and 1,6-hexanediol.

[0084] R 11Further preferred examples include compounds formally derived as described above from glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols formally containing 4 to 6 glycerol units, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, and polyalkylene oxides, such as ethylene oxide, propylene oxide, and / or butylene oxide-based polyethers.

[0085] Radical R 11 These are -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Quaternary ammonium group [ka] It may optionally contain one or more groups selected from and may be substituted with an OH group or a carboxyl group, but radical R 7 It may not contain a combination of -C(O)- and -O- groups, or a combination of -C(O)- and -NH- or tertiary amino groups, that form an internal carboxylate group, internal ester group, or internal amide group.

[0086] According to the present invention, in at least one compound of formula (IV) of the hair care formulation, formula (V)R 11 At least one portion of has at least two, preferably at least six, carbon atoms, and in the same portion of formula (V), at least one R 6 It is essential that it has at least 6, preferably at least 8, carbon atoms.

[0087] According to the present invention, it is also essential that the compound of formula (I) is not composed solely of glycerol and ricinoleic acid moieties; that is, it is not a polyglycerol polyricinolate (PGPR).

[0088] According to the present invention, the terms "polyglycerin polyricinoleic acid" or "PGPR" include structures of oligomeric glycerols esterified or partially esterified with polyricinoleic acid and / or ricinoleic acid.

[0089] Among these, oligomeric glycerol can be obtained by either a base-catalyzed oligomerization reaction of glycerol, or a reaction between glycerol and 2,3-epoxy-1-propanol (glycidol).

[0090] The polyricinoleic acid structure is obtained by the condensation of two or more ricinoleic acid molecules via intermolecular esterification.

[0091] Therefore, polyglycerol polyricinolate is represented by the following structure: [ka] Here, n is typically an integer between 1 and 4, but it can also be greater than that, and R is independently selected from H and / or ricinoleic acid and / or polyricinoleic acid residues. Both the ricinoleic acid residue and the polyricinoleic acid residue are bonded to the polyglycerol structure via a carboxylic acid group.

[0092] Therefore, the ricinoleic acid residue has the following structure, [ka] The polyricinoleic acid residue is represented by the following structure: [ka] Here, m is typically 2 or 3, but it can also be more than that.

[0093] In a preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) or (IV), wherein in the compound of formula (I) or (IV), R 1 As defined above, it has a maximum of 10,000 carbon atoms, preferably a maximum of 1,000, more preferably a maximum of 300, even more preferably a maximum of 100, and most preferably a maximum of 50 carbon atoms.

[0094] According to this embodiment, R in formula (I) 1 Preferably, the linear or branched alkylene group is selected from linear or branched alkylene groups interrupted by an ether group, an ester group, or both an ether group and an ester group, particularly branched structures derived from products obtained by esterification of polyols with mono- or polyhydroxycarboxylic acids, or linear alkylene groups.

[0095] More preferably, R of formula (I) according to this embodiment 1 The radical is selected from alkylene groups selected from the group consisting of linear and branched alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups.

[0096] R in equation (I) according to this embodiment 1 Regarding the presence of functional groups and optional substituents that are optionally included in the radical, R 1It is preferably derived from glycidyl compounds, glycerol, and glycerol derivatives, particularly glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether, and polyglycerol compounds, or R 1 When is a linear alkylene group, an alkylene group that does not have further substituents in addition to the (-XC(O)-F) group is particularly preferred, R 1 It is even more preferable if it is derived from a condensation product of glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds with C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid or 12-hydroxystearic acid.

[0097] Preferably, the R of formula (IV) according to this embodiment 1 The linear or branched alkylene group is selected from linear or branched alkylene groups, or linear or branched alkylene groups interrupted by ether groups, ester groups, or both ether and ester groups, particularly branched structures derived from products obtained by esterification of polyols with mono or polyhydroxycarboxylic acids, or linear alkylene groups. Also preferred are C2-C6 linear alkenylene groups, particularly 1,2-ethenylene radicals derived from maleic acid or fumaric acid.

[0098] More preferably, R in formula (IV) 1 The radicals are selected from alkylene groups, and can be selected from the group consisting of linear or branched alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups. Particularly preferred are 1,1-methylene, 1,2-ethylene, 1,3-propylene, 1,2,3-propylene, and 1,4-butylene radicals.

[0099] R in equation (IV)1 Regarding the presence of optional functional groups and optional substituents, the R of formula (IV) 1 It is preferably derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, and more preferably from compounds derived from the condensation products of glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds and C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid or 12-hydroxystearic acid, or R 1 This is the case when the group is a linear alkylene group, particularly an alkylene group that does not have any further substituents in addition to the (-C(O)-XG) group.

[0100] Another preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or (IV), wherein any R of the compound is present. 7 or R 11 The number of carbon atoms in the molecule is 3 to 300, preferably 3 to 100, more preferably 3 to 50, even more preferably 3 to 36, even more preferably 3 to 24, and most preferably 11 to 24.

[0101] According to this embodiment, R 7 Preferably, these are independently selected from optionally substituted linear, branched or cyclic alkyl groups, linear, branched or cyclic alkenyl groups, linear, branched or cyclic alkynyl groups, linear, branched or cyclic alkaryl groups, linear, branched or cyclic aralkyl groups, and linear, branched or cyclic aryl groups, such as phenyl, benzyl, or tolyl, each of which optionally comprises one or more functional groups as described above, and having 6 to 24 carbon atoms.

[0102] Comfortable, R 7The radical is selected from linear alkyl and linear alkenyl groups, particularly linear C6-C24 alkyl groups, e.g., hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or linear C6-C24 alkenyl groups, e.g., Selected from hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where these groups are most preferably bonded to an adjacent C(O) or X group by a terminal C atom.

[0103] According to this embodiment, R 11 Preferably, these are independently selected from optionally substituted linear, branched or cyclic alkyl groups, linear, branched or cyclic alkenyl groups, linear, branched or cyclic alkynyl groups, linear, branched or cyclic alkaryl groups, linear, branched or cyclic aralkyl groups, and linear, branched or cyclic aryl groups, such as phenyl, benzyl, or tolyl, each of which optionally comprises one or more functional groups as described above, and having 6 to 24 carbon atoms.

[0104] Comfortable, R 11The radicals are selected from linear alkyl groups and linear alkenyl groups, in particular linear C6-C24 alkyl groups, e.g., hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or linear C6-C24 alkenyl groups, e.g., hexenyl, heptenyl, octenyl, nonenyl Selected from decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the residue may have one or more hydroxyl or carboxyl substituents, and where these groups are most preferably bonded to an adjacent C(O) or X group by a terminal C atom.

[0105] In yet another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) or (IV), wherein the compound of formula (I) or (IV) has a molecular weight in the range of 1500 to 2000000 g / mol, preferably 1500 to 100000 g / mol, more preferably 1500 to 30000 g / mol, even more preferably 1500 to 10000 g / mol, even more preferably 1500 to 5000 g / mol, and most preferably 1500 to 3000 g / mol.

[0106] In a more preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) or (IV), wherein the compound of formula (I) comprises 2 to 100 parts of formula (II), more preferably 2 to 50 parts of formula (II), even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, most preferably 2 to 4 parts of formula (II); or wherein the compound of formula (IV) comprises 2 to 100 parts of formula (V), more preferably 2 to 50 parts of formula (V), even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, most preferably 2 to 4 parts of formula (V); or wherein the compound of formula (I) comprises 2 to 100 parts of formula (II*), more preferably 2 to 50 parts of formula (II*), even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, most preferably 2 to 4 parts of formula (II*).

[0107] In the present invention, the presence of the (II), (V), or (II*) portion of formula, i.e., the estolide portion of the compound, is important for obtaining and adjusting the desirable properties of preferred fatty acid-based compounds, and therefore, hair care formulations containing these compounds.

[0108] In a preferred embodiment of the present invention, a hair care formulation comprising at least one compound of formula (I), where at least one compound of general formula (I) is represented by general formula (III), {[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 -C(O)-X-} r -R 2 (-XC(O)-F) s (III) Here, X is as defined above.

[0109] R in equation (III) 2It has up to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] and may comprise one or more groups selected from quaternary ammonium groups, and may optionally be substituted with one or more carboxyl or hydroxyl groups, selected from optionally substituted hydrocarbon radicals with (r+s) valence, and R 10 R 2 If the join is to base-NR, optional base-NR 10 - forms a bond with the nitrogen atom in - R 3 It has up to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from optionally substituted hydrocarbon radicals with divalent to hexavalent nucleotides, which may contain one or more groups selected from formula (III), where multiple R 3 If they exist, they may be the same or different. R 4 The following groups can be optionally selected: -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, which are optionally substituted with divalent to tetravalent groups and include one or more groups selected from the following: Here, equation (III) contains multiple R 4 If they exist, they may be the same or different. And here r+s=2-55, r=0-54, s≧1, And in equation (III), F is as defined above, except that at least one of the radicals F includes at least one part of equation (II) or equation (II*), -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (II) -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (II*) Here X, R 6 , R 7 , and R 7* This is defined as above, M = 0-20, preferably 1-20. And however, in at least one part of equation (II), R 7 It has at least two, preferably at least six, carbon atoms, and in the same portion of formula (II), at least one R 6 It has at least 6, preferably at least 8, carbon atoms, or in at least one part of formula (II*), R 7* It is terminated by one or more groups T having at least two, preferably at least six, carbon atoms, and in the same part of formula (II*), at least one R 6 The condition is that it has at least 6, preferably at least 8, carbon atoms.

[0110] According to the present invention, R of formula (III) 2 It has up to 1000 carbon atoms and can optionally have -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from optionally substituted hydrocarbon radicals of (r+s) valence, which may include one or more groups selected from quaternary ammonium groups and may optionally be substituted with one or more carboxyl or hydroxyl groups, and R 10 R 2 If the join is to base-NR, optional base-NR 10 - is defined as forming a bond to the nitrogen atom in -

[0111] R 2 is the (r+s) valency, where (r+s) is from 2 to 55, preferably from 2 to 40, more preferably from 2 to 30. And r is R 2 A structure combined with, -{[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 -C(O)-X-} This indicates the number of bases, and r = 0-54, preferably 0-10, most preferably selected from 0, 1, 2, 3, 4, 5, 6, 7, or 8, while s is R 2 This indicates the number of groups of the bonded structure -(-XC(O)-F), and S≧1, preferably 1-50, more preferably 1-30, even more preferably 1-20, most preferably selected from 1, 2, 3, 4, 5, 6, 7, or 8. It is particularly preferable that r=0 and s=1-39, especially when r=0 and s=1, 2, 3, 4, 5, 6, 7, 8, 9, or 10.

[0112] The term "(r+s)-valent" refers to a residue R, which can be a carboxyl group or a hydroxyl group. 2 The number of optional additional substituents other than (-XC(O)-F) is not indicated or limited.

[0113] s valence for residue (-XC(O)-F) and residue -{[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4R is the r-valence for -C(O)-X-}. 2 The hydrocarbyl structure is preferably selected from the group consisting of linear, branched or cyclic alkylene groups, linear, branched or cyclic alkenylene groups, linear, branched or cyclic alkylylene groups, linear, branched or cyclic alkalilene groups, linear, branched or cyclic aralkylene groups, and linear, branched or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, particularly those having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms.

[0114] Preferably, the hydrocarbon structure is a linear or branched alkylene group, or a linear or branched alkylene group interrupted by an ether group, an ester group, or both an ether group and an ester group, particularly a branched structure derived from a product obtained by esterification of a polyol with a mono or polyhydroxycarboxylic acid having up to 150 carbon atoms, or a linear alkylene group having up to 22 carbon atoms.

[0115] More preferably, R with (r+s) valence 2 The radical is selected from alkylene groups, which can be selected from the group consisting of linear, branched, and cyclic alkylene groups, in particular from linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene, or n-octylene groups, branched C1-C22 alkylene groups, such as isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups.

[0116] Which C atom of the hydrocarbyl radical is R 2 The (-XC(O)-F) group and {[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 There are no restrictions regarding whether it contains -C(O)-X-}-.

[0117] However, R 2 Each carbon atom has more than 1 (-XC(O)-F) group or {[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 It is preferable that the group does not have a -C(O)-X-}- group.

[0118] R (optional) 2 Regarding the presence of functional groups and optional substituents contained in R 2 This includes glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, or R 2 In particular, when it is a linear alkylene group, -(-XC(O)-F) group and {[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 Preferably, it is derived from an alkylene group that does not have further substituents in addition to the -C(O)-X-}- group, and more preferably, R 2 These are derived from glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether, polyglycerol compounds, and condensation products of C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid, or 12-hydroxystearic acid.

[0119] Typically, the base-(-XC(O)-F) and base-{[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 -C(O)-X-}- is a radical R 2 via the -XC(O)- unit, especially the -OC(O)- unit, R 2 -OH or -NHR of the parent compound derived from 10 It is obvious to those skilled in the art that the bonds are formed at the positions where the base is substituted.

[0120] For example, R derived from glycerol2 The group is a 1,2,3-propylene radical, where "1,2,3" means that the radical is a (-XC(O)-F)- group or (-XC(O)-F) group, and {[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 This indicates the position where the -C(O)-X-}- group is substituted.

[0121] According to the present invention, R 3 It has up to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from optionally substituted hydrocarbon radicals with divalent to hexavalent nucleotides, which may contain one or more groups selected from, where multiple R 3 If they exist in equation (III), they may be the same or different. 3 If it is defined as having a valency of 2 to 6, then this represents the number of groups in the formula (FC(O)-X-)- plus 1, because one valency is R 3 to R 4 The bonding portion -(XC(O))- is used to bond to the X group, and the remaining valence is used to bond to the group of the structure (FC(O)-X-). Thus R 3 one or more parts (FC(O)-X-)- are bonded to R 3 to R 4 The group X, in particular O, that is bonded to the (XC(O))-part is R 3 OH or NHR of compounds derived from 10 It is derived from the basis, and therefore R 3 It is obvious to those skilled in the art that the radicals constituting these compounds are the hydrocarbyl skeletons of these compounds. For example, the 1,2,3-propylene radical R 3 It is derived from glycerol from which the OH group has been removed. Such R3 を In the preparation of compounds containing such R3 To obtain the group, a step of esterification of glycerol is required.

[0122] Divalent to hexavalent R 3 The hydrocarbyl structure of the radical is preferably selected from the group consisting of linear, branched or cyclic alkylene groups, linear, branched or cyclic alkenylene groups, linear, branched or cyclic alkylynylene groups, linear, branched or cyclic alkalilene groups, linear, branched or cyclic aralkylene groups, and linear, branched or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, particularly those having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms.

[0123] Preferably, the hydrocarbon structure is a linear or branched alkylene group, or a linear or branched alkylene group interrupted by an ether group, an ester group, or both an ether group and an ester group, in particular a branched structure derived from a product obtained by esterifying a polyol with a mono or polyhydroxycarboxylic acid having up to 150 carbon atoms, or a linear alkylene group having up to 22 carbon atoms.

[0124] Comfortable, R 3 The radical is selected from alkylene groups, which can be selected from the group consisting of linear, branched, and cyclic alkylene groups, and in particular can be selected from linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene, or n-octylene groups, and branched C1-C22 alkylene groups, such as isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups.

[0125] Hydrocarbyl radical R 3 Which C atom in the throat has a (-XC(O)-F)- group, and which C atom is R 3 to R 4There are no restrictions on whether the bond is to the -(XC(O)-) group via the bond.

[0126] However, R 3 Each carbon atom has one more (-XC(O)-F) group or {[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 It is preferable that the group does not have a -C(O)-X-}- group.

[0127] R 3 Regarding the presence of optional functional groups, 4 However, it includes an ether group, an ester group, or both, or R 3 However, when derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, or R 4 is a linear alkylene group, in particular, R 3 to R 4 When the alkylene group has no further substituents in addition to the -(-XC(O)-F) group and -(XC(O)-) group bonded to it, preferably, And R 3 However, it is even more preferable when it is a 1,2-ethylene radical, a 1,3-propylene radical, a 1,4-butylene radical, a 1,5-pentylene radical, a 1,12-octadecylen radical, a 1,14-octadecylen radical, a 1,2,3-propylene radical, a 1,2,4-butylene radical, a 1,2,5-pentylene radical, a 1,3,5-pentylene radical, a 1,2,3,4-butylene radical, a 1,2,3,4-pentylene radical, a 1,2,4,5-pentylene radical, a 1,2,3,4,5-pentylene group, or a 1,2,3,4,5,6-hexylene radical.

[0128] According to the present invention, R 4 It has up to 300 carbon atoms and can optionally have -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from linear, cyclic, or branched, saturated, unsaturated, or aromatic hydrocarbon radicals, which are optionally substituted with divalent to tetravalent groups and include one or more groups selected from formula (III), where multiple R 4 When they exist, they may be identical or different.

[0129] R 4 R is via the -(C(O)-X)- part 2 and R 3 To join, here R 4 The 2 to 4 terminal C atoms of the radical are bonded to the carbonyl group of the -(C(O)-X)- bond, R 4 Structurally, it is derived from dicarboxylic acid to tetracarboxylic acid. 4 If R is derived from a hydrocarbon carboxylic acid that does not contain further functional groups or substituents, 4 Radicals are hydrocarbyl radicals, such as ethylene or propylene radicals. However, in many cases, R 4 The derived structure is obtained by the condensation of dicarboxylic acids to tetracarboxylic acids and monohydroxycarboxylic acids, or from dicarboxylic acids to tetracarboxylic acids, particularly dicarboxylic acids, with diols, triols, or polyols containing more than three hydroxyl groups. In these cases, R 4 Radicals contain an internal ester group. For example, R 4 If it originates from a cross-condensation product of 1 equivalent of succinic acid and 1 equivalent of ricinoleic acid, the ester group obtained by the condensation of one carboxylic acid group of succinic acid and a hydroxyl group of ricinoleic acid is R 4 While present as a radical, the other carboxylate groups of succinic acid and the carboxylate group of ricinoleic acid are R in the structure of formula (III). 4 Provides a carbonyl group adjacent to a radical.

[0130] Structure of equation (III) and F, R 2 , R 3and R 4 Considering the definition, in a given structure, if you start from F and move to the center of the structure, F stops and R 3 or R 2 It starts, and if it exists, R 3 The process has finished and R 4 It is clear that it will start. 4 It stopped, R 2 Regarding the problem where it begins, R 2 and R 4 Regarding the definition, there may be several acceptable options for a particular structure. To clarify, according to the present invention, the structure of the compound by formula (III) is as R as possible. 2 It is included as belonging to R 4 This is defined as minimizing the number of carbon atoms as much as possible.

[0131] In a more preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) or formula (IV) represented by the general formula (III) defined above, Here, R in the compound of formula (IV) 1 or R in the compound of formula (III) 2 It has 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups [ka] Selected from optionally substituted hydrocarbon radicals, which may comprise one or more groups selected from and may optionally be substituted with a carboxyl group or a hydroxyl group.

[0132] According to the present invention, R of formula (IV) 1 or R of the compound of formula (III) 2Preferably, the group consists of optionally substituted linear or branched alkylene groups, or linear or branched alkylene groups interrupted by both ether groups, ester groups, or both ether and ester groups, in particular branched structures derived from products obtained by esterifying a polyol with a mono or polyhydroxycarboxylic acid having up to 150 carbon atoms, or group alkylene groups having up to 22 carbon atoms.

[0133] More preferably, R in formula (IV) 1 Radical or R of formula (III) 2 The radical is selected from alkylene groups, which can be selected from the group consisting of linear and branched alkylene groups, particularly linear alkylene groups such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups.

[0134] R in equation (IV) 1 or R in equation (III) 2 Regarding the presence of optional functional groups and optional substituents, R 1 and R 2 The radical is derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, or R of formula (IV). 1 or R in equation (III) 2 If R is a linear alkylene group, particularly an alkylene group that does not have further substituents in addition to the (-XC(O)-F) group, then R is even more preferable. 1 It is preferable that the fatty acids are derived from condensation products of glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds with C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid or 12-hydroxystearic acid.

[0135] Typically, the base (-XC(O)-F) is R 1 -OH or -NHR in the parent compound derived from 10 At the position substituted by the group, the radical R is transmitted via the -XC(O)- unit, particularly the -OC(O)- unit. 1 It is obvious to those skilled in the art that they are coupled together.

[0136] For example, R derived from glycerol 1 The group is a 1,2,3-propylene radical, where "1,2,3" indicates the position where the radical is substituted with a (-XC(O)-F)- group.

[0137] In a more preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) represented by the general formula (III) defined above, or at least one compound of formula (IV), where R 3 This is selected from divalent to tetravalent residues, specifically from divalent, trivalent, or tetravalent residues.

[0138] Another preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) represented by the general formula (III) defined above, where R 3 It has up to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from optionally substituted hydrocarbon radicals, which may contain one or more groups selected from the following.

[0139] Preferred base R according to this embodiment 3R is a linear C1-C22 alkylene group, for example, methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene group, a branched C1-C22 alkylene group, for example, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene group, 3 However, it is more preferable when the radical is a 1,2-ethylene radical, a 1,3-propylene radical, a 1,4-butylene radical, a 1,5-pentylene radical, a 1,12-octadecylen radical, a 1,14-octadecylen radical, a 1,2,3-propylene radical, a 1,2,4-butylene radical, a 1,2,5-pentylene radical, a 1,3,5-pentylene radical, a 1,2,3,4-butylene radical, a 1,2,3,4-pentylene radical, a 1,2,4,5-pentylene radical, a 1,2,3,4,5-pentylene group, or a 1,2,3,4,5,6-hexylene radical.

[0140] In yet another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) or formula (IV) that can be represented by the general formula (III) defined above, where F and G have up to 200 carbon atoms, preferably 10 to 200 carbon atoms, more preferably 10 to 150, and even more preferably 10 to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and optionally substituted with one or more carboxyl groups, hydroxyl groups, or halide groups.

[0141] The halide group is independently selected from fluoro, chloro, bromo, or iodo groups, where the chloro group is preferred.

[0142] According to the present invention, preferably, base F consists only of the portion of formula (II), where R 6 and R 7 is a hydrocarbyl group that does not contain any further functional groups optionally substituted with a hydroxyl group, and also preferably, group G consists only of the part of formula (V), where R 6 and R 11 is a hydrocarbyl group that does not contain any further functional groups optionally substituted with a hydroxyl group, or preferably group F consists only of the portion of formula (II*) defined above, and more preferably R 7 It consists only of the part of formula (II*) in which the hydrocarbyl group does not contain any functional groups other than the -C(O)- and -O- groups.

[0143] Furthermore, according to a more preferred embodiment of the present invention, a hair care formulation comprising at least one compound of formula (III) is provided, where R 4 It has 2 to 300 carbon atoms, preferably 5 to 200 carbon atoms, more preferably 8 to 150 carbon atoms, and even more preferably 10 to 120 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals that are substituted with one or more divalent to tetravalent, preferably divalent, trivalent, or tetravalent, and containing one or more groups selected from the above.

[0144] In another preferred embodiment of the present invention, a hair care formulation comprising at least one compound of formula (III) is provided, where r = 0-50 or 1-50, preferably 0-20, more preferably 0-10, even more preferably 1-10, specifically 1-5, more specifically 0, 1, 2, 3, 4, 5, and even more specifically 2.

[0145] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I), which may be specifically represented by general formula (III), wherein at least one of the radicals F comprises at least one portion selected from the following portions: -R 6 (-OC(O)-R 6 ) m -OC(O)-R 7 , -R 6 (-NR 10 -C(O)-R 6 ) m -OC(O)-R 7 , -R 6 (-NR 10 -C(O)-R 6 ) m -NR 10 -C(O)-R 7 , Preferably, -R 6 (-OC(O)-R 6 ) m -OC(O)-R 7 , Here R 10 , R 6 , R 7 , and m are as defined above, Or, in the basket of formula (I) or (III), At least one of the radicals F includes at least one portion selected from the following portions: -R 6 (-OC(O)-R 6 ) m -OC(O)-R 7* , -R 6 (-NR 10 -C(O)-R 6 ) m -OC(O)-R 7* , -R 6 (-NR 10 -C(O)-R 6 ) m -NR 10 -C(O)-R 7* , Preferably, -R 6 (-OC(O)-R 6 ) m -OC(O)-R 7* , Here R 10 , R 6 , R 7* , and m are as defined above.

[0146] According to the present invention, R in the above structure 6 Preferably, the hydroxyl-substituted hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecylene, octadecylene, nonadesilene, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, nonenilen. , independently selected from decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where these groups are most preferably bonded to adjacent C(O) or X groups by a terminal C atom, R 7 These are independently selected from hydroxyl-substituted hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where these groups are most preferably bonded to adjacent C(O) groups by a terminal C atom, and R 7*This is as defined in any embodiment of the present invention, m is 0-10, preferably 1, 2, 3, 4, or 5.

[0147] In a preferred embodiment of the present invention, a hair care formulation comprising at least one compound of formula (IV) is provided, where at least one radical G is at least one portion. -R 6 (-C(O)-OR 6 ) m -C(O)-OR 11 , -R 6 (-C(O)-NR 10 -R 6 ) m -C(O)-OR 11 , -R 6 (-C(O)-NR 10 -R 6 ) m -C(O)-NR 10 -R 11 , Preferably -R 6 (-C(O)-OR 6 ) m -C(O)-OR 11 , This includes R 10 , R 6 , R 11 , and m are as defined above.

[0148] Preferably, in the above structure according to this embodiment, R 6This includes hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, noneniylene, decenylene A group independently selected from lene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where these groups are most preferably bonded to an adjacent C(O) or X group by a terminal C atom. R 11 The group is independently selected from any optional hydroxyl-substituted hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the residue may have one or more hydroxyl or carboxyl substituents, and where the group is most preferably bonded to an adjacent C(O) group by a terminal C atom, and m is 0-10, preferably 1, 2, 3, 4, or 5.

[0149] A preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or formula (IV), which can be specifically represented by formula (III), where m = 0 to 10, preferably 1 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6, more specifically 0 or 1.

[0150] In another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) or formula (IV), which may be specifically represented by formula (III), where R 10 This is hydrogen, n-, iso-, or tert.-C1-C 22 -Alkyl, C2-C 22 -Alkoxyalkyl, C5-C 30 -Cycloalkyl, C6-C 30 -Aryl, C6-C 30 -Aryl (C1-C6)alkyl, C6-C 30 -Alkylaryl, C2-C 22 -Alkenyl, C2-C 22 -Selected from the group consisting of alkenyloxyalkyl groups, which can optionally be substituted with hydroxyl and halogen, respectively, and may optionally contain one or more ether groups (-O-), preferably R 10 This is hydrogen or n-, iso-, and tert.-C1-C 22 - Selected from alkyl groups.

[0151] Among these, the most preferred C1-C22-alkyl groups in this embodiment are methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentane, and n-hexane groups, cyclopentyl groups, and cyclohexane groups.

[0152] In yet another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) or formula (IV), which may be specifically represented by formula (III), where R6 This is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated radicals having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms.

[0153] Most preferably, according to this embodiment, R 6 The radicals are selected from reskerol acid, ricinoleic acid, 12-hydroxystearic acid, or 14-hydroxystearic acid, particularly radicals derived from ricinoleic acid.

[0154] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I), which can be specifically represented by formula (III), where R 7 This is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals, having up to 24 carbon atoms, preferably 1-24, more preferably 2-20, and even more preferably 8-18 carbon atoms, and optionally substituted with one or more groups selected from -C(O)O-, carboxyl groups, hydroxyl groups, or halide groups.

[0155] According to this embodiment, the halide group is independently selected from fluoro, chloro, bromo, or iodo groups, where the chloro group is preferred.

[0156] Most preferably, according to this embodiment, R 7 The radicals originate from oleic acid or stearic acid, particularly oleic acid.

[0157] Another preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (IV), where R 11This is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms.

[0158] Most preferably, according to this embodiment, R 11 The radicals are derived from monohydroxycarboxylic acids, reskerolic acid, ricinoleic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or from dihydroxycarboxylic acids, particularly 2,2'-dihydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or from mono- and diols, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, particularly ricinoleic acid.

[0159] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I), which can be specifically represented by formula (III), where R 6 and R 7 R in each single part of the general formula (II) which is composed of 6 +R 7 The total number of carbon atoms (Σ carbon atoms R 6 ,R 7 ) is 10 to 300, preferably 15 to 200, more preferably 20 to 150, even more preferably 30 to 100, or Here, in the compound of formula (I) or (III), R 6 and R 7* R of each single part of the general formula (II*) consisting of 6 +R 7* The total number of carbon atoms (Σ carbon atoms R 6,R 7* The value is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100.

[0160] Another preferred embodiment of the present invention provides a hair care formulation comprising at least one compound represented by formula (IV), where R 6 and R 11 R of each single part of the general formula (V) consisting of 6 +R 11 The total number of carbon atoms (Σ carbon atoms R 6 , R 11 The value is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100.

[0161] In yet another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) or formula (IV), which may be specifically represented by formula (III), where R of formula (III) 2 or R of the compound of formula (IV) 1 The hydrocarbon radicals are selected from divalent to hexavalent, preferably divalent to tetravalent, more preferably divalent to trivalent, in particular divalent, trivalent, tetravalent, pentavalent, and even more preferably divalent, trivalent, and tetravalent or hexavalent, optionally substituted with linear, cyclic or branched, saturated, unsaturated or aromatic, preferably saturated radicals, preferably derived from polyols, preferably derived from dihydroxycarboxylic acids having up to 25 carbon atoms selected from the group consisting of 2,2'-dihydroxymethylpropanoic acid and 9,10-dihydroxystearic acid, or preferably derived from polyhydroxycarboxylic acids having up to 25 carbon atoms selected from the group consisting of gluconic acid, glyceric acid, xylonic acid, and ascorbic acid.

[0162] As already explained in a general manner, the term “derived” in the present invention refers to radical R2 or R 1 This explains that the structures are formally obtained by removing a hydroxyl group, an amino group, and a carboxyl group, respectively, in formulas (I), (III), or (IV), R 1 or R 2 It forms an adjacent group, for example, -C(O)-X-, where X is O or NR as described above. 10 Therefore, according to this definition, for example, R 1 In a compound of formula (IV) in which is a divalent 1,2-ethylene radical, the group R 1 It will be obvious to those skilled in the art that it can be defined as being derived from succinic acid.

[0163] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or formula (IV), which can be specifically represented by formula (III), where R 10 This is hydrogen, n-, iso-, or tert.-C1-C 22 - Selected from the group consisting of alkyl, more preferably hydrogen.

[0164] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or formula (IV), which can be specifically represented by formula (III), where R 6 Preferably, it is derived from a monohydroxycarboxylic acid having up to 25 carbon atoms, independently selected from the group consisting of glycolic acid, lactic acid, 2-hydroxybutyric acid, 3-hydroxybutyric acid, 4-hydroxybutyric acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, ricinoleic acid, and reskerolic acid.

[0165] Among them, R 6 If it is derived from a carboxylic acid having more than one hydroxyl group, then only one of the hydroxyl groups is the R group. 6 to R 7 , R 11 Or another R 6Connecting to the base, or base R 6 to R 7* It is used to construct the structural element X of the ester group of the general formula (II) or (V) portion that is linked to the base.

[0166] A preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I), which can be specifically represented by formula (III), where R 7 Preferably, it is derived from a carboxylic acid having up to 25 carbon atoms without hydroxyl substituents, independently selected from the group consisting of acetic acid, propanoic acid, butanoic acid, pentanoic acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, nonadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, 2,2-dimethylheptanoic acid, 2,2-dimethyloctanoic acid, neodecanoic acid, undecyl-10-enoic acid, oleic acid, linoleic acid, linolenic acid, and erucic acid.

[0167] Most preferably, according to this embodiment, in particular R 7 In part of formula (II), one or more R derived from ricinoleic acid or reskerolic acid. 6 When combined with a base, R 7 These are derived from oleic acid, linoleic acid, or linolenic acid.

[0168] Another preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) represented by formula (IV), wherein the compound of formula (IV) R 11Preferably, the alcohol is a linear or branched alcohol having up to 26 carbon atoms, independently selected from the group consisting of methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, and triglycerol, and 4 to 6 glycerol units. Formally derived from linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, such as ethylene oxide, propylene oxide, and / or butylene oxide-based polyethers, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, and 1,6-hexanediol.

[0169] Most preferably, according to this embodiment, R 11 In part of formula (V), one or more R derived from ricinoleic acid or reskerolic acid. 6 When combined with a base, R 11 It is derived from glycerol or oligoglycerol, castor oil, or poly-(C2-C4)-alkylene oxide.

[0170] In yet another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I), which can be specifically represented by formula (III), where R of the general formula (II) is provided. 6 and R 7 At least one, preferably both, of these is derived from an unsaturated carboxylic acid.

[0171] More preferably, according to this embodiment, R 6 It is derived from ricinoleic acid, most preferably R 6It is derived from ricinoleic acid, and R 7 It is derived from oleic acid.

[0172] Another preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or formula (IV), specifically represented by formula (III), wherein R in the compound of formula (IV) is provided. 1 or R in the compound of formula (III) 2 The group is selected from the following: - Residues derived from polyols, preferably 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols, such as oligoglycerols formally containing 4 to 6 glycerol units, trimethylolpropane, pentaerythritol, and sorbitol. - Residues derived from polyalkylene oxides such as ethylene oxide, propylene oxide, and / or butylene oxide-based polyethers, in particular from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, or polypropylene glycol, e.g., dipropylene glycol (especially derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, derived from mixed ethylene oxide and butylene oxide-based copolyethers, derived from mixed propylene oxide and butylene oxide-based copolyethers, and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers, and residues derived from oligomers or polymer polyols, e.g., hydroxy-functional polyacrylates, hydroxy-functional polyesters, hydroxy-functional polyurethanes, - Residues derived from dihydroxycarboxylic acids, preferably from the group consisting of 2,2'-dihydroxymethylpropanoic acid and 9,10-dihydroxystearic acid, - Preferably 3,5-dihydroxy-3-methylpentanoic acid, and residues derived from polyhydroxycarboxylic acids having up to 25 carbon atoms, selected from the group consisting of sugar acids, such as gluconic acid, glyceric acid, xylonic acid, and ascorbic acid. - Residues derived from epoxy compounds, preferably ether epoxy compounds, having a total of more than 1, preferably more than 2, carbon atoms, preferably selected from ethylene oxide, propylene oxide, butylene oxide, and glycidyl ether, for example, prepared from the reaction of epichlorohydrin with alcohol, for example methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol Panediols, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols, in particular formally comprising 4 to 6 glycerol units, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, such as ethylene oxide, propylene oxide, and / or butylene Oxide-based polyethers, particularly those derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or polypropylene glycol, e.g., dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from mixed ethylene oxide and butylene oxide-based copolyethers; derived from mixed propylene oxide and butylene oxide-based copolyethers; and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers; or preferably glycidyl esters, particularly those derived from acids, especially neodecanoic acid; oligomers or polymer polyols, e.g., hydroxy-functional polyacrylates, hydroxy-functional polyesters, hydroxy-functional polyurethanes; - Ester compounds obtained from the reaction of polyols or epoxides with hydroxycarboxylic acids, ester compounds obtained from the reaction of alcohols, In particular, alcohols are selected from 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols, such as trimethylolpropane, castor oil (ricinoleic acid triglyceride), skellerella oil, pentaerythritol, sorbitol, and polyalkylene oxides, such as ethylene oxide, propylene oxide, and / or butylene oxide-based polyethers. In particular, derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or derived from polypropylene glycol, e.g., dipropylene glycol (especially derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from mixed ethylene oxide and butylene oxide-based copolyethers; derived from mixed propylene oxide and butylene oxide-based copolyethers; and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers. Alternatively, epoxy compounds, particularly selected from ethylene oxide, propylene oxide, butylene oxide, and glycidyl ether, and alcohols, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or butylene Oxide-based polyethers, particularly those derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or polypropylene glycol, e.g., dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from mixed ethylene oxide and butylene oxide-based copolyethers; derived from mixed propylene oxide and butylene oxide-based copolyethers; and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers; or preferably glycidyl esters. Hydroxyl-functionalized carboxylic acids, particularly those derived from lactic acid, 4-hydroxybutanoic acid, ricinoleic acid, reskerolic acid, 2,2-bis(hydroxymethyl)propionic acid, malic acid, tartaric acid, and gluconic acid, especially preferred are residues of glycerol derived from esters of ricinoleic acid, i.e., castor oil, and reskerolic acid, i.e., reskerella oil. - Residues derived from ester compounds obtained from the reaction of an alcohol or epoxide with a hydroxyl-free carboxylic acid, For example, divalent to hexavalent, preferably divalent to tetravalent, more preferably divalent to trivalent, and even more preferably divalent, trivalent and tetravalent, optionally amino or amide-substituted linear, cyclic or branched, saturated, unsaturated or aromatic radicals, derived from the reaction of alcohols, i.e., 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), skellerella oil, pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or butylene oxide-based polyalkylenes. Polypropylene glycol, particularly derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or derived from polypropylene glycol, e.g., dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from mixed ethylene oxide and butylene oxide-based copolyethers; derived from mixed propylene oxide and butylene oxide-based copolyethers; or derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers. Epoxy compounds, particularly ethylene oxide, propylene oxide, butylene oxide, glycidyl ethers, and alcohols, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or Butylene oxide-based polyethers, particularly those derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or polypropylene glycol, e.g., dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from mixed ethylene oxide and butylene oxide-based copolyethers; derived from mixed propylene oxide and butylene oxide-based copolyethers; or derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers. Preferably a glycidyl ester, Residues derived from acids, especially neodecanoic acid; carboxylic acids, especially acetic acid, propionic acid, butyric acid, dodecanoic acid, stearic acid, oleic acid, oxalic acid, malonic acid, succinic acid, maleic acid, itaconic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, and dimer fatty acids, preferably residues derived from the reaction of anhydrides or acid chlorides with alcohols. - The above monocarboxylic acids or polycarboxylic acids, such as succinic acid, maleic acid, itaconic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, dimer fatty acids, preferably their anhydrides or acid chlorides, and residues derived from polyacrylic acid.

[0173] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or formula (IV) represented by formula (III), where R of formula (IV) 1 or R in equation (III) 2 and R 3 At least one of them is a divalent hydrocarbon radical derived from the above polyalkylene oxy group of the following general formula, -[CH2CH2O] q1 -[CH2CH(CH3)O] r1 -[CH2CH(C2H5)O] s1 -{[CH2CH2] q2 -[CH2CH(CH3)] r2 -[CH2CH(C2H5)] s2}- Here q1 = 0 to 49, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, r1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, s1 = 0 to 24, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, q2 = 0 or 1, r2 = 0 or 1, s2 = 0 or 1, and Σ(q²+r²+s²)=1, However, the total number of carbon atoms in such polyalkylene oxide groups is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15.

[0174] Therefore, according to this embodiment, preferably q2=0, one or two of q1, r1, and s1 are 0, and more preferably, q2=0, r1 and s1 are 0, or q2=0, and q1 and s1 are 0.

[0175] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or formula (IV) represented by formula (III), where R of formula (IV) 1 or R in equation (III) 2 and R 3 At least one of them is a divalent hydrocarbon radical derived from the above oligoglycerol, of the following general formula: -[CH2CH(R 8 )CH2O] t1 -[CH2CH(R 8 )CH2)] t2 - Here t1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, specifically 1 and 2. t2=1, R 8 =OH or -OC(O)-R 6 -N + (R 10 )3, here R 10 and R 6 This is as defined above, However, R 8 The condition is that the total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15.

[0176] Another preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or formula (IV) represented by formula (III), where R of formula (IV) 1 or R in equation (III) 2 and R 3At least one of them is a divalent hydrocarbon radical containing at least one ester group of the following general formula, -[CH2CH2O] q1 -R 9 -[CH2CH2O] q1 -[CH2CH2] q2 - Here q1 may be the same or different, as defined above, and q2=1 Furthermore -[CH2CH(R 8 )CH2O] t1 -R 9 -[CH2CH(R 8 )CH2O] t1 -[CH2CH(R 8 )CH2)] t2 - Here t1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, specifically 1 and 2. t2=1, R 8 =OH or -OC(O)-R 6 -N + (R 10 )3, here R 10 and R 6 This is defined as above, However, R 8 The conditions are that the total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15, and R 9 These are derived from succinic acid, adipic acid, sebacic acid, etc., and are -C(O)C(O)O-, -C(O)(CH2) 1-8 C(O)O-, or, that is, derived from phthalic acid and terephthalic acid, -C(O)(C6H4)C(O)O-, -C(O)CH=CHC(O)O-, -C(O)C(=CH2)-CH2C(O)O-, -C(O)CH(OH)CH(OH)C(O)O-, However, R 9The condition is that the total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15.

[0177] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or formula (IV) represented by formula (III), where R of formula (IV) 1 or R in equation (III) 2 is a hydrocarbon residue that does not contain a heteroatom or contains one or more -O- groups, preferably 1 to 5 -O- groups, where the -O- group is preferably an ether group, but can also form an ester group together with a carbonyl group, and where the group R 2 It can be optionally substituted with one or more hydroxyl groups, but preferably it is not substituted with hydroxyl groups.

[0178] According to this embodiment, when the compound contains an ether or ester group, it is more preferable, and most preferably, that the compound contains 1 to 5 -O- groups and no more heteroatoms except for an optional carbonyl O atom.

[0179] In another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I), which can be specifically represented by formula (III), wherein one or more groups F of at least one portion of the following formula, -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (II) X and m are as defined above, and R 6 These are independently derived from lactic acid, ricinoleic acid, reskerolic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, 14-hydroxytetradecanoic acid, and R 7These are derived from octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, neodecanoic acid, or oleic acid.

[0180] According to this embodiment, R 6 Preferably, these are independently derived from 10-hydroxystearic acid and ricinoleic acid, R 6 These are independently derived from 10-hydroxystearic acid and ricinoleic acid, and R 7 It is more preferable if the oleic acid is derived from it.

[0181] In yet another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) or formula (IV), which may be specifically represented by formula (III), where R 10 Preferably, hydrogen, or R which forms a cyclic structure as shown in the schematic formula below. 1 or R 2 Selected from the group consisting of connections to . [ka]

[0182] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I), which can be represented by general formula (III), wherein group F comprises at least one portion of formula (II), -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (II) Here R 6 , R 7 X and m are as defined above, and each part of equation (II) is at least two different bases R 6 This includes the above base R 6 They are arranged either randomly or in blocks, or here Base F includes at least one part of equation (II*), -R6 (-XC(O)-R 6 ) m -XC(O)-R 7* (II*) Here R 6 , R 7* X and m are as defined above, and each part of equation (II*) is at least two different bases R 6 This includes the above R 6 They are arranged either randomly or in a block-like pattern.

[0183] Preferably, according to this embodiment, the above R 6 The bases are arranged in a block-like manner. According to the present invention, the block-like arrangement refers to the structure of formula (II), where each is one of two or more R of the same type. 6 Two or more subunits consisting of radicals are bonded together by covalent bonds or act as bonding groups of the above subunits R 6 A different single R 6 They are connected by a base.

[0184] In yet another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I), which can be represented by general formula (III), wherein group F comprises at least one portion of formula (VI), -R 6 (-XC(O)-R 61 ) m1 (-XC(O)-R 62 ) m2 -XC(O)-R 7 (VI) Here, R in equation (VI) 6 R 61 and R 62 Selected from, X and R 7 As defined above, and R 61 and R 62 This is two different bases R defined in previous embodiments. 6 This represents, And here m1 = 0 to 20, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, or 6. m2 = 0 to 20, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, or 6. m = m1 + m2 = 0 to 20, preferably 0 to 10, more preferably 0 to 6, and even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, or 6.

[0185] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) which can be represented by general formula (III), wherein in the compound of formula (I) or (III), Base F includes at least one part of formula (VI), -R 6 (-XC(O)-R 61 ) m1 (-XC(O)-R 62 ) m2 -XC(O)-R 7 (VI) Here, X, m1, and m2 are as defined above, and R 6 , R 61 , R 62 , and R 7 This is defined in the following table, [Table 1]

[0186] According to this embodiment, R in a general way 6 , R 61 , R 62 and R 7 According to the specific compounds shown in the rows of the table above, which indicate preferred combinations, R 6 , R 61 , R 62 and R 7When selected, it is particularly preferred, and whenever there are alternatives to ricinoleic acid and reskerolic acid, ricinoleic acid is selected, which is even more preferred.

[0187] Another preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) which can be represented by general formula (III), wherein in the compound of formula (I) or (III), group F comprises at least one portion of formula (VI), -R 6 (-XC(O)-R 61 ) m1 (-XC(O)-R 62 ) m2 -XC(O)-R 7 (VI) Here, X, m1, m2, R 6 , R 61 , R 62 , and R 7 These are as defined above, and R per base F 6 , R 61 , R 62 , and R 7 The total number of carbon atoms (Σ carbon atoms R 6 , R 61 , R 62 , and R 7 ) is about 19 to 300, preferably 25 to 300, more preferably 30 to 300, specifically 30 to 200, and more specifically 30 to 150.

[0188] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or general formula (IV) which can be represented by formula (III), wherein in the compound of formula (I), (III), or (IV), R 6These are independently derived from mono- or poly-(di-,tri-,tetra-)hydroxycarboxylic acids selected from the group consisting of lactic acid, ricinoleic acid, reskerolic acid, 10-hydroxystearic acid, and 12-hydroxystearic acid, 14-hydroxytetradecanoic acid, 2,2'-di-hydroxymethylpropanoic acid, and 9,10-dihydroxystearic acid, and gluconic acid, preferably at least one or all R 6 It is derived from ricinoleic acid.

[0189] A preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) which can be represented by general formula (III), wherein in the compounds of formulas (I) and (III), R 7 These are independently derived from octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, neodecanoic acid, and oleic acid, preferably all R 7 It is derived from oleic acid.

[0190] According to this embodiment, the above R 7 However, in one or more parts of formula (II), R derived from ricinoleic acid, reskerolic acid, 10-hydroxystearic acid, and 12-hydroxystearic acid 6 Preferably, it is combined with a part, and more preferably, 50% or more of the part of formula (II) is R as described above. 6 and R 7 It includes a group, and most preferably, in all parts of formula (II), each R 6 It is derived from ricinoleic acid or 10-hydroxystearic acid, and each R 7 It is derived from oleic acid.

[0191] In a more preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I), (III), or (IV) as defined above, where the low melting point fatty acid ≥ C5 and the high melting point fatty acid ≥ C5 are particularly R of general formula (II). 6 and R7 Containing ester elements, and R of general formula (V) 6 and R 11 Within the contained ester elements, -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (II), and -R 6 (-C(O)-XR 6 ) m -C(O)-XR 11 (V) Particularly, -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Placed, Here, X, R 6 , R 7 , R 11 , and R 10 This is as defined above, or Here, in the compounds of formula (I), (III), or (IV), the low-melting point and high-melting point fatty acids ≥ C5 are R of general formula (II*). 6 and R 7* Within the contained ester elements, -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (II*) Particularly, -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* and -NR 10 -C(O)-R 6 -(OC(O)-R 6 )m -OC(O)-R 7* , It is specifically placed in Here, X, R 6 , R 7* and R 10 This is as defined above.

[0192] It is generally within the scope of the present invention that low-melting-point and high-melting-point fatty acids ≥C5 are specifically and independently arranged for each ester group of a portion selected from the portions of general formulas (II), (II*), and (V) present in compounds of general formulas (I), (III), and (IV). The term "≥C5" indicates that each high-melting-point fatty acid and low-melting-point fatty acid has five or more carbon atoms. The carbonyl group of the fatty acid is R 6 and R 7 Since they are formally excluded from the group, R derived from high-melting-point and low-melting-point fatty acids ≥ C5 6 and R 7 The group has four or more carbon atoms.

[0193] For example, according to this embodiment of the present invention, it is preferable that some parts of the general formula (II) of the compounds of formulas (I) and (III) present in the hair care formulation indicate specific positions of the low-melting-point and high-melting-point fatty acid scaffolds (backbone) described below, while other parts of general formula (II) do not. This may be particularly the case for parts located at different residues F as defined above.

[0194] Within the framework of this invention, low-melting-point fatty acids ≥ C5 are defined as those with a melting point ≤ 40°C. Preferred examples include, in particular, oleic acid, reskerolic acid, ricinoleic acid, octanoic acid, decanoic acid, pivalic acid, and neodecanoic acid.

[0195] Within the framework of this invention, high melting point fatty acids ≥ C5 are defined as those with a melting point > 40°C. Preferred examples include, in particular, dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, arachidic acid, behenic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, and 14-hydroxytetradecanoic acid.

[0196] The corresponding melting points can be obtained from the literature (G. Knothe et al., J. Am. Oil Chem. Soc., 2009, 86, 844-856).

[0197] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of formula (I) or (III) as defined above, wherein one or more portions of formula (II) each of at least one, preferably more than one, more preferably one, two or three low-melting-point fatty acids ≥ C5 are grouped R 6 The things that form R 7 One or more radicals R adjacent to it 6 The compound containing, on the other hand, at least one, preferably more than one, more preferably one, two or three high-melting-point fatty acids ≥ C5, is R of formula (II). 6 and R 7 One or more radicals R at the opposite end of the contained ester element 6 Forms or in one or more parts of formula (II), at least one, preferably more than one, more preferably one, two or three, each R 6 High melting point fatty acids ≥ C5 that form R 7 One or more radicals R adjacent to it 6 It forms a low melting point fatty acid ≥ C5 of formula (II), on the other hand, at least one, preferably more than one, more preferably one, two or three low melting point fatty acids ≥ C5. 6 and R 7 One or more radicals R at the opposite end of the contained ester element 6 It forms. At least 50% of all parts of formula (II) are derived from high-melting-point and low-melting-point fatty acids as described above.6 When such a configuration of radicals is observed, it is preferable that more than 80% of all parts of formula (II) are derived from high-melting-point and low-melting-point fatty acids as described above. 6 When such a radical configuration is observed, and most preferably all parts of general formula (II) are residues R as described above, 6 and R 7 Such an arrangement is more preferable.

[0198] Similarly, in a preferred embodiment, a hair care formulation is provided comprising at least one compound of formula (IV) defined above, wherein in one or more parts of formula (V), each of at least one, preferably more than one, more preferably one, two or three low-melting-point fatty acids ≥ C5 is a group R 6 The things that form R 11 One or more radicals R adjacent to it 6 Included in, on the other hand, at least one, preferably more than one, more preferably one, two or three high melting point fatty acids ≥ C5 are R of formula (V) 6 and R 11 One or more radicals R at the opposite end of the contained ester element 6 Forms, or in one or more parts of formula (V), at least one, preferably more than one, more preferably one, two or three, each R 6 The high melting point fatty acids ≥ C5 that form R 11 One or more radicals R adjacent to it 6 It forms a low melting point fatty acid ≥ C5 of formula (V), on the other hand, at least one, preferably more than one, more preferably one, two or three low melting point fatty acids ≥ C5 of formula (V) 6 and R 11 At the opposite end of the contained ester element, one or more radicals R 6 It forms.

[0199] At least 50% of all parts of formula (V) are derived from high-melting-point and low-melting-point fatty acids as described above. 6When such a configuration of radicals is observed, it is preferable that more than 80% of all parts of formula (V) are derived from high-melting-point and low-melting-point fatty acids as described above. 6 When such a radical configuration is observed, more preferably, and most preferably, all parts of general formula (V) are residues R as described above. 6 and R 11 This shows such an arrangement.

[0200] In another equally preferred embodiment, a hair care formulation is provided comprising at least one compound of formula (I) or (III) as defined above, wherein one or more portions of formula (II*) comprise at least one, preferably more than one, more preferably one, two or three low-melting-point fatty acids, each having five or more carbon atoms and a melting point of 40°C or less, and each of these is a group R 6 The things that form R 7* One or more adjacent R 6 A fatty acid that is included in and has five or more carbon atoms, preferably at least one, preferably more than one, more preferably one, two, or three, and has a high melting point above 40°C, is R of formula (II*). 6 and R 7* One or more radicals R at the opposite end of the contained ester element 6 Forms, or in one or more parts of formula (II*), each of at least one, preferably more than one, more preferably one, two or three high melting point fatty acids ≥ C5 is R 6 The things that form R 7* One or more radicals R adjacent to it 6 A low-melting-point fatty acid having five or more carbon atoms, at least one, preferably more than one, more preferably one, two, or three, and a melting point of less than 40°C, is R of formula (II*). 6 and R 7* One or more radicals R at the opposite end of the contained ester element 6 It forms and at least 50% of all parts of formula (II*) are derived from high-melting-point and low-melting-point fatty acids as described above. 6When such a radical configuration is observed, preferably more than 80% of all parts of formula (II*) are derived from high-melting-point and low-melting-point fatty acids as described above. 6 When such a configuration of radicals is observed, it is more preferable, and all parts of general formula (II) are of the above-mentioned residue R 6 and R 7* Such an arrangement is most preferable.

[0201] As already mentioned above, the specific configurations of high-melting-point and low-melting-point fatty acids are those of the compound of formula (I) or (III) in formula (II) 6 and R 7 For each ester portion contained, or for each R of formula (II*) of the compound of formula (I) or (III) 6 and R 7* Each ester moiety and in a completely similar manner, the individual R of formula (V) of the compound of general formula (IV) 6 and R 11 Each ester component can be changed independently.

[0202] The preferred embodiments outlined above are -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (II) and -R 6 (-C(O)-XR 6 ) m -C(O)-XR 11 (V) In Part in particular -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Here, X, R 6, R 7 , R 10 , and R 11 This is as defined above. In, These ester elements exhibit a tendency for localized changes in crystallization, viscosity increase, and phase formation throughout their entire length. 6 and R 7 Containing ester elements, or R 6 and R 11 It enables the incorporation of contained ester elements, or, -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (II*) In, Part in particular -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* , Here, X, R 6 , R 7* , R 10 , and R 11 This is as defined above. In, Each of these ester elements has a tendency to change locally over the entire length of the structure, with respect to crystallization, viscosity increase, and phase formation. 6 and R 7* This enables the incorporation of contained ester elements.

[0203] The above combination of carboxylic acids and synthetic concepts provides for obtaining ester condensates with specified properties such as molecular weight, molecular weight distribution, carboxylic acid arrangement, and viscosity.

[0204] Radical R1 , R 2 or R 3 teeth, In particular, the formation of the following general structure base, -R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Preferably, - Monohydroxycarboxylic acids, especially lactic acid, 4-hydroxybutanoic acid, -Dihydroxycarboxylic acids, especially 2,2-bis(hydroxymethyl)propanoic acid, -Dendrimeric oligomers of polyhydroxycarboxylic acids, especially gluconic acid, or dihydroxycarboxylic acid oligomers, especially dendrimeric oligomers of 2,2-bis(hydroxymethyl)propanoic acid, Corresponding acid chloride precursor, Cl-C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Here, X, R 6 , and R 7 and R 10 This is as defined above. Through esterification with, The part of general formula (II) that exists in base F is R 6 and R 7 It can be linked to the contained ester element, And in a similar way, radical R 1 , R 2 , or R 3 teeth, In particular, the formation of the following general structure base, -R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* , Preferably, - Monohydroxycarboxylic acids, especially lactic acid, 4-hydroxybutanoic acid, -Dihydroxycarboxylic acids, especially 2,2-bis(hydroxymethyl)propanoic acid, -Dendrimeric oligomers of polyhydroxycarboxylic acids, especially gluconic acid, or dihydroxycarboxylic acid oligomers, especially dendrimeric oligomers of 2,2-bis(hydroxymethyl)propanoic acid, Corresponding acid chloride precursor, Cl-C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* , Here, X, R 6 , and R 7* and R 10 This is as defined above. Through esterification with, R exists in the part of the general formula (II*) that exists in base F. 6 and R 7* It can bond to the contained ester elements.

[0205] A more preferred embodiment of the present invention provides a hair care formulation comprising at least one compound of general formula (I) represented by formula (III), where R 4 is selected from divalent to tetravalent, e.g., divalent, trivalent, tetravalent, preferably divalent, optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals, which have up to 200 carbon atoms, more preferably up to 150 carbon atoms, even more preferably up to 100 carbon atoms, specifically up to 80 carbon atoms, and preferably at least 2, more preferably at least 10, more preferably at least 14 carbon atoms, and optionally comprising one or more groups selected from -O-, -NH-, and -C(O)-, and where formula (III) has multiple R4 If they exist, they may be identical or different.

[0206] According to this embodiment, R 4 It is preferable that the dicarboxylic acid and one or two hydroxycarboxylic acids are derived by cross-condensation, or by cross-condensation of a di, tri, or tetraol with an excess dicarboxylic acid, more preferably by cross-condensation of one equivalent of a dicarboxylic acid with a monohydroxycarboxylic acid.

[0207] In another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of general formula (I) represented by general formula (III), where R 4 It contains at least one ester group (-OC(O)- or -C(O)-O-, respectively).

[0208] According to this embodiment, R 4 Preferably, it is derived from at least one dicarboxylic acid and at least one C8-C22 hydroxycarboxylic acid or C2-C20 ditetraol, more preferably from at least one dicarboxylic acid and at least one C14-C22 monohydroxycarboxylic acid.

[0209] In yet another preferred embodiment of the present invention, a hair care formulation is provided comprising at least one compound of formula (I) represented by general formula (III), where R 4 This includes dicarboxylic acids, tricarboxylic acids, or tetracarboxylic acids, in particular dicarboxylic acids such as succinic acid, oxalic acid, malonic acid, malic acid, tartaric acid, maleic acid, itaconic acid, succinic acid, sebacic acid, dimer acid, amino-functional dicarboxylic acids such as D-glutamic acid, and dicarboxylic acids of the following formulas. [ka] and derived from hydroxycarboxylic acids, particularly ricinoleic acid or reskerolic acid, and dicarboxylic acids, such as succinic acid, oxalic acid, malonic acid, tartaric acid, maleic acid, itaconic acid, succinic acid, sebacic acid, dimer acid, amino-functional dicarboxylic acids, such as D-glutamic acid, and condensation products of dicarboxylic acids of the following formula: [ka] or R 4 It is derived from amide condensation products of amino acids with maleic acid or succinic acid, for example, N-maleoyl-β-alanine ((E)-4-(2-carboxyethylamino)-4-oxo-buto-2-enoic acid), N-succinyl-β-alanine (4-[(2-hydroxy-1-methyl-2-oxo-ethyl)amino]-4-oxo-butanoic acid), N-maleoyl-asparagine (4-amino-2-[[(E)-4-hydroxy-4-oxo-buta-2-enoyl]amino]-4-oxo-butanoic acid); or R 4 These are derived from ester condensation products of dihydric alcohols, namely ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butanediol, 1,4-butanediol, and dicarboxylic acid anhydrides, namely maleic anhydride, succinic anhydride, phthalic anhydride; or R 4 It is derived from tricarboxylic acids or tetracarboxylic acids, such as citric acid, isocitric acid, trimellitic acid, pyromellitic acid, cyclobutanetetracarboxylic acid; or R 4 It is derived from the bisamide condensation product of an amino acid and maleic acid or succinic acid, namely bis-(N-maleoil)-lysine; or R 4 It is derived from ester condensation products of trihydric alcohols, such as glycerol and trimethylolpropane, and dicarboxylic acid anhydrides, such as maleic anhydride, succinic anhydride, and phthalic anhydride; or R 4It is derived from ester condensation products of tetrahydric alcohols, such as diglycerol and pentaerythritol, and dicarboxylic acid anhydrides, such as maleic anhydride, succinic anhydride, and phthalic anhydride, and Most preferably, R 4 It is derived from ricinoleic acid or succinic acid.

[0210] In a preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (I), (III), or (IV), at least one of the portions of formula (II), (II*), or (V) comprises two or more different R 6 A basis exists.

[0211] At least two different bases R in part of formula (II), (II*), or (V) 6 The presence of different groups R means that at least two different types of hydroxy-substituted or amino-substituted carboxylic acid derivatives can be used to prepare these chain structures. 6 They can differ from one another in terms of the number of C atoms, the number and position of double bonds, and, if any, the position of substituents and the position of bonds to adjacent groups. They can also differ in terms of whether they are linear or branched. In at least one group F, R 6 It is preferable that the hydrocarbon groups derived from ricinoleic acid and 12-hydroxystearic acid are represented independently.

[0212] Another preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (I), (III), or (IV), wherein at least one of the portions of formula (II), (II*), or (V) contains the group R of formula (II). 6 and R 7 , the base R of equation (II*) 6 and R 7* , or the base R of formula (V) 6 and R 11 They are not based on the same carboxylic acid structure.

[0213] R 6 and R 7 , R6 and R 7* , or R 6 and R 11 These groups differ from one another in terms of the number of carbon atoms, the number or position of double bonds in the carbon chain, whether they exist or not, or the position of oxygen or nitrogen atoms bonded to the carbon chain of the group. The carboxylic acid structures from which the above groups originate may also differ by two or more of the above characteristics.

[0214] In yet another preferred embodiment of the hair care formulation according to the present invention, comprising at least one compound of formula (I) or (III), the compound of general formula (I) is: p is 2-6, R 1 These are selected from divalent to hexavalent linear, branched or cyclic alkylene groups, linear, branched or cyclic alkenylene groups, linear, branched or cyclic alkynylene groups, linear, branched or cyclic alkalilene groups, linear, branched or cyclic aralkylene groups, and linear, branched or cyclic arylene groups, such as phenylene, benzylene or torylene groups, and in particular selected from such groups having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms. And at least one base F includes one or more parts of general formula (II*), -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (II*) Here R 6 , R 7* , and m are as defined above, Or, in the case of a compound of general formula (III), r+s=2-6, R 2These are selected from divalent to hexavalent linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkalilene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, and in particular, selected from such groups having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms. And at least one base F includes one or more parts of general formula (II*), Here R 6 , R 7* , and m are defined as above.

[0215] According to this embodiment, in formula (I), p is 2, 3, or 4, most preferably p is 2, or in formula (III), r+s=2, 3, or 4, most preferably r+s is 2.

[0216] In compounds of general formula (I), R 1 R is preferably selected from a linear, branched, or cyclic alkylene group having 1 to 150 carbon atoms, more preferably a linear alkylene group having 1 to 12 carbon atoms, or in formula (III), R 2 It is preferable that the alkylene group be selected from a linear, branched, or cyclic alkylene group having 1 to 150 carbon atoms, more preferably a linear alkylene group having 1 to 12 carbon atoms.

[0217] In a more preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (I) or (III), the at least one compound of general formula (I) is: X=O, p is 2, R 1This is selected from divalent linear, branched, and cyclic alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups, preferably selected from ethylene, n-propylene, n-butylene, n-pentylene and n-hexylene. And at least one base F includes one or more parts of general formula (II*), -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (II*) Here R 6 , R 7* , and m are as defined above, Or, in the compound of general formula (III), X=O, r+s=2, R 2 is selected from divalent linear, branched and cyclic alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene and 2-ethylhexylene groups, preferably selected from ethylene, n-propylene, n-butylene, n-pentylene and n-hexylene, and at least one group F comprises one or more parts of general formula (II*), where R 6 , R 7* , and m are as defined above.

[0218] In yet another preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (I), (III), or (IV), the compound of formula (I) or (III) is one or more R groups terminated by three or more -OC(O)-T groups, preferably four or more -OC(O)-T groups, most preferably four to twelve -OC(O)-T groups. 7* Includes.

[0219] Among these, R includes one branching structure defined above. 7* The branched structure is preferably terminated by 3 to 10 -OC(O)-T groups, while the dendrimer-like structure containing at least two branched structures as defined above is preferably terminated by 4 to 20 -OC(O)-T groups.

[0220] A more preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (I), (III), or (IV), wherein the compound of formula (I) or (III) comprises one or more groups R 7* Each of these includes at least two branching structures of the following general formula: -C(O)-B(-O-) b Here, B is a linear or branched hydrocarbon group having 2 to 20 carbon atoms, and b is 2 or more, where b groups (-O-) bonded to group B on one side are bonded to a carbon atom on the other side that may be a carbon atom of a CH2 group or a carbonyl group.

[0221] The following general formula as defined above -B(-O-) b The presence of the branched structure allows for branched structures that can be terminated by two or more groups R 7* It is essential in the following general formula as defined above. -C(O)-B(-O-) b The presence of two or more further branched structures indicates a dendritic structure, i.e., R 7*From the bond that connects to the rest of the molecule, R 7* This results in the formation of a structure with several branching points that can be arranged sequentially or parallel when moving to the terminal groups. However, deviating from the IUPAC definition of dendrimer molecules [see A. Fradet et al., Pure and Applied Chemistry, 91(3), 523-561: Nomenclature and terminology for dendrimers with regular dendrons and for hyperbranched polymers (IUPAC Recommendations 2017)], dendrons do not necessarily have to contain only dendritic and terminal constructing repeating units, R 7* The free valence of R 7* Each path from the valence to any terminal group that binds to the rest of the molecule does not need to contain the same number of constituent repeating units.

[0222] The general formula defined above is -B(-O-) b All (-O-) groups in the branched structure are defined by the general formula -C(O)-B(-O-) b It is even more preferable that it be replaced with a branched structure.

[0223] 1 or more groups R 7* This is a branched structure of three or more -C(O)-B(-O-) b It is also preferable to include three to five of the branched structures, if more so.

[0224] According to this embodiment, it is preferable that b of both branch structures be independently selected from the range of 2 to 6, more preferably from the range of 2 to 4.

[0225] In a preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (I), (III), or (IV), the compound of formula (I) or (III) comprises at least one group R 7* The general formula defined above is -B(-O-) bor -C(O)-B(-O-) b One or more branched structures are independently derived from glyceric acid, 2,2-dihydroxymethylpropionic acid, gluconic acid, maltobionic acid, and lactobionic acid.

[0226] base R 7* All branched structures present are preferably independently derived from 2,2-dihydroxymethylpropionic acid, and more preferably from at least one group R 7* All branched structures originate from 2,2-dihydroxymethylpropionic acid.

[0227] All groups R of the compound of formula (I) or (III) 7* It is even more preferable that all branched structures present are derived from the same polyhydroxycarboxylic acid.

[0228] In another preferred embodiment of the hair care formulation according to the present invention, the compound of formula (I) or (III) contains one or more groups R 7* These are the following general formulas, respectively -R 6 (-XC(O)-R 6 ) t -XC(O)-T Terminated by two or more units, Here R 6 And T is as defined above, X=O, t is independently 0 to 12, preferably independently 0 to 6, and most preferably independently 0, 1, 2, or 3.

[0229] According to this embodiment, two or more terminal groups defined above are located at the ends of the estolide chain. One or more groups R 7* These are general formulas -R 6 (-XC(O)-R 6 ) t 2 to 48 units of -XC(O)-T, more preferably formula -R 6 (-XC(O)-R 6 ) t-X-C(O)-T from 2 to 27 groups, most preferably the formula -R 6 (-X-C(O)-R 6 ) t -X-C(O)-T is preferably terminated by 4 to 16 groups.

[0230] In a further preferred embodiment of the hair care composition according to the invention, one or more groups R of the compound of formula (I) or (III) 7* are terminated by two or more groups, preferably 4 to 12 groups of the following structure, -R 6 (-X-C(O)-R 6 ) t -X-C(O)-T where R 6 is independently derived from a C8-C24 monocarboxy-monohydroxycarboxylic acid, particularly ricinoleic acid, 12-hydroxystearic acid, lesquerolic acid, 11-hydroxy-undecanoic acid, X is O, and T is independently derived from a C2-C24, preferably C8-C24 fatty acid, particularly lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, arachidic acid, and t is 0-6, preferably 0, 1, or 2, or 3.

[0231] According to this embodiment, it is preferred that R 6 is derived from ricinoleic acid and T is derived from stearic acid or oleic acid.

[0232] More preferably, all groups R 7* of R 6 are derived from ricinoleic acid, even more preferably all groups R 7* in which R 6 is derived from ricinoleic acid, T is derived from stearic acid or oleic acid, and t is 0, 1, 2 or 3.

[0233] In another preferred embodiment of the hair care composition according to the invention, One or more groups R of a compound of formula (I) or (III) 7* It is independently selected from one of the following branched or dendrimer fatty acid structures, -R 12 -OC(O)-R 6 -(OC(O)-R 61 ) m1 -(OC(O)-R 62 ) m2 -OC(O)-T, or -R 12 -NR 10 -C(O)-R 6 -(OC(O)-R 61 ) m1 -(OC(O)-R 62 ) m2 -OC(O)-T, here R 12 It has 2 to 50 carbon atoms, specifically 2 to 20 carbon atoms, more specifically 2 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from divalent, optionally substituted hydrocarbon radicals, where radical R may comprise one or more groups selected from and may be substituted with -OH or halide groups, where radical R 10 It cannot include a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group that forms an internal carboxylate group or an internal amide group, and preferably represents a C1-C24n-alkylene group and a CC2-C24n-alkenylene group, in particular -CH2-, -CH2CH2-, -CH2CH2CH2-, R 6 This is as defined above, m1 is from 0 to 12, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. m2 is 0 to 12, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. And m1 + m2 is t, where t is from 0 to 12, preferably from 0 to 10, more preferably from 0 to 6, even more preferably from 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6, and T is defined as above, R 61 and R 62 This is the base R defined above. 6 Selected from.

[0234] Preferably, R 6 , R 61 , R 62 , and T are selected as follows: [Table 2] Here R 6 +R 7 The total number of carbon atoms (Σ carbon atoms R 6 , R 7 ) is 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150. However, R derived from dihydroxylated carboxylic acid or polyhydroxylated carboxylic acid 6 , R 61 and R 62 The condition is that at least one, preferably one to two, more preferably two, and even more preferably all of the OH groups are esterified.

[0235] According to this embodiment, one or more groups R of a compound of formula (I) or (III) 7*These are independently derived from branched or dendrimeric fatty acid structures, which are obtained by esterification with 2,2'-di-hydroxymethylpropanoic acid and di-hydroxymethylpropanoic acid itself, C2 to C24, preferably C8 to C24 fatty acids, more preferably lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, arachidic acid, and optionally monohydroxy fatty acids, particularly ricinoleic acid, for example, the following structural formula: [ka] Here R is as follows: [ka] Or the following structure [ka] Here, R is as shown above, as exemplified by [example].

[0236] Preferably, all groups R of the compound of formula (I) or (III) 7* This is selected independently from the group of structures cited above.

[0237] More preferably, all groups R of the compound of formula (I) or (III) 7* It is represented by a single formula selected from the basis of the above structure.

[0238] In preferred embodiments of the hair care formulation according to the present invention, at least one compound of general formula (I) or (III) is represented by one of the following specific structures: i) (fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(fatty acid) or ii) (branched fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(branched fatty acid) or iii) (Dendrimeric fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(dendrimeric fatty acid), Here - C2-C10 hydrocarbons are C2-C10 hydrocarbon groups, particularly those derived from ethylene glycol, 1,3-propylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,2-propylene glycol, and 1,3-butanediol. - Mono- or oligo-C8-C24 hydroxy fatty acids are groups derived from C8-C24 hydroxy-substituted carboxylic acid monomers or oligomers of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification, particularly mono- or oligo-ricinoleic acid with a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4. - The fatty acids are saturated or unsaturated hydrocarbyl residues derived from C2-C24 carboxylic acids having such residues, preferably derived from such C8-C24 fatty acids, particularly lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, and arachidic acid. - Branched fatty acids are residues obtained by esterifying polyhydroxy monocarboxylic acids, particularly 2,2'-dihydroxymethylpropanoic acid, with C2 to C24, preferably C8 to C24 fatty acids, particularly lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, arachidic acid, and optionally monohydroxy fatty acids, particularly ricinoleic acid. - Dendrimer fatty acids are residues obtained by esterification, namely, the esterification of the branched fatty acid residues described above with at least one further polyhydroxy monocarboxylic acid, particularly 2,2'-dihydroxymethylpropanoic acid, with C2 to C24, preferably C8 to C24 fatty acids, particularly lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, arachidic acid, and optionally monohydroxy fatty acids, particularly ricinoleic acid.

[0239] Branched fatty acid groups are exemplified by the following structure: [ka] Here R is as follows: [ka] The dendrimer fatty acid group is exemplified by the following structure: [ka] Here, R is a branched fatty acid group as shown above.

[0240] In a more preferred embodiment of the hair care formulation according to the present invention, the compound of formula (I), (III), or (IV) comprises at least one part of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- Here R 6 This is defined as above, l is an integer independently selected from 0 to 20, more preferably from 1 to 12, and even more preferably from 2 to 10, and L may have 1 to 30 carbon atoms and optionally -O-, -S-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [ka] and may contain one or more groups selected from quaternary ammonium groups, and is a divalent hydrocarbon radical, Preferably, L is a divalent alkylene or alkenylene radical having 1 to 30 carbon atoms. More preferably, L is selected from methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, nonylene, etenylene, propenylene, butenylene, pentenylene, hexenylene, heptenylene, octenylene, nonenylene. Most preferably, L is selected from methylene, ethylene, ethenylene, or butenylene.

[0241] According to the embodiment, preferably, R 6 These are independently derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, more preferably ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, 11-hydroxy-undecanoic acid, and even more preferably all R 6 These are independently derived from ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, 11-hydroxy-undecanoic acid, and most preferably all R 6 This is the same group derived from one carboxylic acid selected from the group consisting of ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid.

[0242] Structure of part (V) -R 6 (-C(O)-XR 6 ) m -C(O)-XR 11 (V) and the structure of the following formula -([-OC(O)-R 6(-O-C(O)-R 6 ) l -O-C(O)-L-C(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- may be present in duplicate, and it is explicitly described that that is, according to the present invention, the structure of the following general formula is -([-O-C(O)-R 6 (-O-C(O)-R 6 ) l -O-C(O)-L-C(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-R 11 meets the requirements of the radical G of formula (IF).

[0243] In another preferred embodiment of the hair care formulation according to the present invention, the compound of formula (I), (III) or (IV) comprises at least one moiety of the following general formula -([-O-C(O)-R 6 (-O-C(O)-R 6 ) l -O-C(O)-L-C(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- where L and l are as defined above, and R 6 is independently derived from a C8-C24 monocarboxy-monohydroxycarboxylic acid, particularly from ricinoleic acid, 12-hydroxystearic acid, lesquerolic acid, 11-hydroxy-undecanoic acid, and most preferably, R 6 is derived from ricinoleic acid.

[0244] Preferably, L is selected from C1 to C10, preferably methylene, ethylene, butylene, octylene, decene, l is independently in the range from 0 to 4, and R 6 is derived from ricinoleic acid.

[0245] In yet another preferred embodiment of the hair care formulation according to the present invention, the compound of formula (I), (III), or (IV) comprises at least one portion of the following general formula: ([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- Here, L is selected from methylene, ethylene, and ethenylene. R 6 It is derived from ricinoleic acid, and l is independently selected from 0, 1, 2, and 3, and the sum of l is in the range of 0 to 4.

[0246] Preferably, L is an ethylene group, and R 6 l is derived from ricinoleic acid, and l is independently selected from 0 or 1.

[0247] In preferred embodiments of the hair care formulation according to the present invention, the compound of formula (I), (III), or (IV) comprises at least one portion of the following structure: (Fatty alcohol)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(C1-C12 hydrocarbon)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(fatty alcohol), Here - C2-C12 hydrocarbons are C2-C12 hydrocarbon groups, particularly derived from succinic acid, maleic acid, itaconic acid, adipic acid, sebacic acid, and dodecanediic acid. - Mono- or oligo-C8-C24 hydroxy fatty acids are groups derived from C8-C24 hydroxy-substituted carboxylic acid monomers or oligomers of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification, and are particularly groups derived from mono- or oligo-licinoleic acid with a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4. - Fatty alcohols are groups derived from C2 to C24, preferably C8 to C24 fatty alcohols, particularly n-octanol, n-decanol, n-dodecanol, n-tetradecanol, n-hexasedanol, oleyl alcohol, stearyl alcohol, behenyl alcohol, and arachidyl alcohol.

[0248] This type of compound is exemplified by the following structure: [ka] Here R 1 The following is: [ka] Here the dashed line represents the above R 1 R to the O atom of the structure 1 This shows the combination.

[0249] In another preferred embodiment of the hair care formulation according to the present invention, the compound of formula (I), (III), or (IV) comprises at least one portion of the following structure: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-R 11 Here L, l, R 6 , and R 11 This is as defined above.

[0250] Preferably, L, l, and R 6 This is as defined above, and R 11 The group is selected from C1-C23 hydrocarbyl groups, preferably C1-C18 hydrocarbyl groups, more preferably C7-C19 hydrocarbyl groups, and even more preferably C11-C17 hydrocarbyl groups, most preferably derived from lauric acid, myristic acid, palmitic acid, oleic acid, and stearic acid.

[0251] More preferably, the compound of formula (IV) has the following structure: R 11 -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-R 11 Here, L, l, and R 6 This is as defined above, and R 11 These are independently selected from C1-C23 hydrocarbyl groups, preferably C1-C18 hydrocarbyl groups, more preferably C7-C19 hydrocarbyl groups, and even more preferably C11-C17 hydrocarbyl groups, and most preferably derived from lauric acid, myristic acid, palmitic acid, oleic acid, and stearic acid.

[0252] More preferably, L is selected from methylene, ethylene or ethenylene, butylene, hexylene, octylene, decene, or derived from itaconic acid. l is independently selected from the range 0 to 4. R 6 It was selected from ricinoleic acid, and R 11 It is selected from oleic acid or stearic acid.

[0253] The present invention also relates to compounds of general formula (Ia), R 1 (-XC(O)-F) p (Ia) Here R in equation (Ia) 1 The following are optional: -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Selected from p-valent, optionally substituted hydrocarbon radicals, which may contain one or more groups selected from quaternary ammonium groups and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups. p≧2, more preferably from 2 to 811, X may be the same or different, and it can be -O- or -NR. 10 - Selected from, here R 10 It has hydrogen, or up to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [ka] Selected from groups consisting of optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, including one or more groups selected from, or in formula (Ia), R 10 is R 1 They may form bonds and create a cyclic structure. F may be the same or different, and can be optionally -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and optionally substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, However, the condition is that at least one of the radicals F contains at least one part of formula (IIa) or formula (IIa*), -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (IIa) -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (IIa*) Here X is as defined above, m = 1 to 20, preferably 2 to 20. R 6 These are independently selected from divalent, optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals having up to 36 carbon atoms. R 7 It independently has 1 to 1000 carbon atoms, and optionally has -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] Selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals, where radical R comprises one or more groups selected from and may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R 7 It cannot contain internal carboxyl groups or amides, i.e., R 7It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, in at least one part of equation (IIa), R 7 The condition is that it has at least two, preferably at least six, carbon atoms, and In the same part of equation (IIa), at least one R 6 It has at least 6, preferably at least 8, carbon atoms. R 7* It has 1 to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] A branched or dendrimeric hydrocarbon radical, independently selected from optionally substituted, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R 7* It is terminated by two or more units of the general structure, -XC(O)-T Here, X is as defined above, and T is a monovalent linear, cyclic, or branched saturated or unsaturated hydrocarbon radical having up to 36 carbon atoms and optionally substituted with carboxyl, hydroxyl, or halide groups. However, in at least one part of equation (II*), R 7* It is terminated by one or more groups T having at least two, preferably at least six, carbon atoms, and in the same portion of formula (IIa*), at least one R 6 The condition is that it has at least 6, preferably at least 8, carbon atoms. or It contains at least one compound of general formula (IVa), R 1 (-C(O)-XG) q (IVa) Here, X is as defined above, R in equation (IVa) 1 It preferably has up to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Selected from optionally substituted hydrocarbon radicals of q valence, which may contain one or more groups selected from quaternary ammonium groups and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups. q = 2 to 55, preferably 2 to 40, more preferably 2 to 4, and G may be the same or different, and may have up to 1005 carbon atoms, and may optionally be -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, wherein at least one of the radicals G comprises at least one part of formula (Va), -R 6 (-C(O)-XR 6 ) m -C(O)-XR 11 (Va) Here, X is as defined above, m = 1 to 20, preferably 2 to 20. R of equation (Va) 6 As defined above for equation (Ia), R 11It has 1 to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R 11 It cannot contain an internal carboxyl group or amide, that is, R 11 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, in at least one part of equation (Va), R 11 It has at least two, preferably at least six, carbon atoms, and in the same part of formula (Va), at least one R 6 The condition is that it has at least 6, preferably at least 8, carbon atoms. However, the compound of formula (Ia) does not consist solely of glycerol and ricinoleic acid moieties, i.e., polyglycerol polyricinolate (PGPR).

[0254] According to the present invention, the residue R of formula (Ia) 1 The following are optional: -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] The p-valent, optionally substituted hydrocarbon radicals are selected from those comprising one or more groups selected from quaternary ammonium groups and optionally substituted with one or more groups selected from carboxyl groups or hydroxyl groups.

[0255] According to the present invention, residue R 1 is the p-value, where p is 2 to 811, preferably 2 to 100, more preferably 2 to 50, and even more preferably p is 2 to 30, which is R 1 This indicates that it has a p residue of the structure (-XC(O)-F) which is F as defined above. Therefore, the term "p-valence" refers to the residue R 1 This does not indicate or limit the number of additional optional substituents other than (-XC(O)-F), which may be carboxyl or hydroxyl groups.

[0256] R is the p-value for the residue (-XC(O)-F) 1 The hydrocarbyl structure is preferably selected from the group consisting of linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkalilene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, particularly those having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms.

[0257] Preferably, the hydrocarbon structure is a linear or branched alkylene group, or a linear or branched alkylene group interrupted by an ether group, an ester group, or both an ether group and an ester group, and in particular a branched structure derived from a product obtained by esterification of a polyol having up to 150 carbon atoms with a mono or polyhydroxycarboxylic acid, or a linear alkylene group having up to 22 carbon atoms.

[0258] Comfort, p-value R 1The radical can be selected from the group consisting of linear, branched, and cyclic alkylene groups, and is selected from alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups.

[0259] Which C atom of the hydrocarbyl radical is R 1 There are no restrictions regarding whether it has a (-XC(O)-F) group attached to it.

[0260] R 1 Regarding the presence of optional functional groups and optional substituents, R 1 It is preferably derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, or R 1 In the case of a linear alkylene group, it is an alkylene group that does not have any further substituents in addition to the (-XC(O)-F) group, and more preferably R 1 This is when the compound is derived from glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds and C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid or 12-hydroxystearic acid.

[0261] Typically, the base (-XC(O)-F) is R 1 -OH or -NHR of the parent compound derived from 10 Radical R via the -XC(O)- unit, particularly the -OC(O)- unit, at the position substituted by the group. 1 It is obvious to those skilled in the art that they can be combined.

[0262] For example, R derived from glycerol 1The group is a 1,2,3-propylene radical, where "1,2,3" indicates the position where the radical is substituted with a (-XC(O)-F)- group.

[0263] According to the present invention, the group X may be the same or different, and may be -O- or -NR. 10 - Selected from, here R 10 It has hydrogen, or up to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [ka] Selected from groups consisting of optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, including one or more groups selected from, or in formula (Ia), R 10 R 1 It can form bonds to form a ring structure.

[0264] R 10 Preferred examples include C1-C10 alkyl groups, particularly methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentane and n-hexane groups, cyclopentyl and cyclohexane groups, C2-C10 alkenyl groups, particularly vinyl and allyl groups, and C6-C12 aromatic groups, particularly phenyl, tolyl and benzyl groups, each of which may be substituted with a hydroxyl or halide group.

[0265] According to the present invention, residue F may be the same or different, and may have up to 1005 carbon atoms, and may optionally be -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and optionally substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, provided that the compound comprises at least one part of formula (IIa) or formula (IIa*). -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (IIa) -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (IIa*)

[0266] Preferably, group F consists only of the group of formula (IIa), or group F consists only of the group of formula (IIa*).

[0267] According to the present invention, R 6 R is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 36 carbon atoms, and therefore R 6 R can be a divalent, optionally substituted linear, cyclic, or branched, saturated, unsaturated, or aromatic hydrocarbon radical, i.e., R 6 This can represent a hydrocarbyl group selected from the group consisting of linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkalilene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, in particular from such groups having 1 to 100 carbon atoms, each optionally containing one or more functional groups as described above.

[0268] Comfortable, R 6The radicals are selected from linear alkylene groups and linear alkenylene groups, in particular linear C6-C24 alkylenes, e.g., hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecylen, octadecylene, nonadecylen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or linear C6-C24 alkenylene groups, e.g. For example, these are selected from hexenylene, heptenylene, octenylene, nonenylene, decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where these groups are most preferably bonded to adjacent C(O) groups by terminal C atoms.

[0269] Which of the C atoms in the hydrocarbyl radical is adjacent to the C(O) group and the X group R 6 There are no restrictions on whether it should be combined with other elements.

[0270] However, R 6 It is preferably derived from a hydroxycarboxylic acid having one or more hydroxyl groups, more preferably from a monohydroxycarboxylic acid, and most preferably from a C7 to C25 fatty acid having one hydroxyl group as a substituent. Therefore, R 6 Preferably, represents an alkylene or alkenylene chain of such a carboxylic acid.

[0271] R 6A preferred example is a structure derived from the corresponding hydroxylcarboxylic acid obtained by subtracting a carboxylic acid group and one OH group, where the hydroxylcarboxylic acid is preferably selected from ricinoleic acid, reskerolic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or dihydroxycarboxylic acid, particularly 2,2'-di-hydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or polyhydroxycarboxylic acid, particularly gluconic acid. Most preferably, R 6 The compounds are derived from reskerolic acid or ricinoleic acid by the methods described above. In both cases, the naturally occurring enantiomers of the compound, namely (9Z,12R)-12-hydroxyoctadeca-9-enoic acid obtained by saponification or fractional distillation of hydrolyzed castor oil, which is the seed oil of the castor plant, and (11Z,14R)-14-hydroxyicos-11-enoic acid isolated from the species Paysonia and Physaria, are particularly preferred. However, racemates, S enantiomers, and E constituent isomers, racemates, enantiomers, and any possible mixtures thereof of the compound are also preferred according to the present invention.

[0272] R of at least one part present in the F group of the compound of general formula (Ia) 6 Containing repeating units (-XC(O)-R 6 The number of m is 1 to 20, preferably 1 to 15, 1 to 12, 1 to 10, 1 to 8, or 2 to 20, 3 to 20, 4 to 20, 5 to 20, specifically 1, 2, 3, 4, 5, 6, 7, 8, 9, or 10.

[0273] R 7 It has 1 to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, a third amino group, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R 7 It cannot contain an internal carboxyl group or amide, that is, R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group.

[0274] According to the present invention, radical R 7 These may be the same or different and can represent a hydrocarbyl group selected from the group consisting of linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms and optionally substituted, and therefore can represent a hydrocarbyl group selected from the group consisting of linear, branched, or cyclic alkyl groups, linear, branched, or cyclic alkenyl groups, linear, branched, or cyclic alkynyl groups, linear, branched, or cyclic alkaryl groups, linear, branched, or cyclic aralkyl groups, and linear, branched, or cyclic aryl groups, such as phenyl, benzyl, or tolyl, each optionally comprising one or more functional groups as described above, and having 6 to 24 carbon atoms.

[0275] Comfortable, R 7The radical is selected from linear alkyl and linear alkenyl groups, in particular linear C6-C24 alkyl groups, e.g., hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or linear C6-C24 alkenyl groups, e.g., Selected from hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where these groups are most preferably bonded to an adjacent C(O) or X group by a terminal C atom.

[0276] Which of the C atoms in the hydrocarbyl radical has an adjacent C(O) group? 7 There are no restrictions on whether it should be combined with other elements.

[0277] However, R 7 It is preferably derived from a carboxylic acid or a hydroxycarboxylic acid having one or more hydroxyl groups, more preferably from a carboxylic acid or monohydroxycarboxylic acid, and most preferably from a C7-C25 fatty acid that does not have a hydroxyl group as a substituent. Therefore R 7 Preferably, represents an alkyl or alkenyl chain of such a carboxylic acid.

[0278] R 7A preferred example is a structure derived from the corresponding carboxylic acid or hydroxylcarboxylic acid from which the carboxylate group has been removed, where the carboxylic acid is acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, pelargonic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, margaric acid, stearic acid, linolenic acid, α-linolenic acid, γ-linolenic acid, nonadecyl acid, arachidic acid, meadic acid, arachidonic acid, heneicosanoic acid, docosanic acid, tricosyl Acids and lignoceric acid can be selected, hydroxycarboxylic acids such as reskerol acid, ricinoleic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid can be selected, or dihydroxycarboxylic acids in particular, 2,2'-di-hydroxymethylpropanoic acid, 9,10-dihydroxystearic acid can be selected, or polyhydroxycarboxylic acids in particular, gluconic acid can be selected.

[0279] Radical R 7 These are -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Quaternary ammonium group [ka] It may optionally contain one or more groups selected from and may be substituted with an OH group or a halide group, but radical R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, that forms an internal carboxylate group, an internal ester group, or an internal amide group.

[0280] According to the present invention, in at least one portion of formula (IIa) of the compound, R 7It has at least two, preferably at least six, carbon atoms, and in the same part of formula (IIa), at least one R 6 It is essential that it has at least 6, preferably at least 8, carbon atoms.

[0281] According to the present invention, the group R of formula (IIa*) 7* It independently has 1 to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] A branched or dendrimeric hydrocarbon radical, independently selected from optionally substituted, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R 7* It is terminated by two or more units of the following general formula, -XC(O)-T Here, X is as defined above, and T is a monovalent linear, cyclic, or branched saturated or unsaturated hydrocarbon radical having up to 36 carbon atoms and optionally substituted with carboxyl, hydroxyl, or halide groups. However, in at least one part of equation (IIa*), R 7* It is terminated by one or more groups T having at least two, preferably at least six, carbon atoms, and in the same portion of formula (IIa*), at least one R 6 The condition is that it has at least 6, preferably at least 8, carbon atoms.

[0282] R 7*Since it is defined as a monovalent group, it results in the structural characteristic of being terminated by at least two groups of the general structure below, -XC(O)-T residue R 7* There must be at least one branching structure.

[0283] R 7* If it is a branched hydrocarbon radical, then as a branched structure, the group includes at least one part of the general formula. -B(-O-) b Here, B is a linear or branched hydrocarbon group having 3 to 20 or 3 to 10 carbon atoms, and b is 2 or more, preferably 2 to 6, more preferably 2 to 4, and here The (-O-) group bonded to group B on one side is bonded to the C atom on the other side.

[0284] In this group, the C atom can be either a CH2 group or a carbonyl group.

[0285] R 7* If the group is a dendrimeric hydrocarbon radical, the group is at least one part of the following general formula: -B(-O-) b Here B and b are as defined above, and the group (-O-) bonded to group B on one side is bonded to the C atom on the other side, and At least one further part that functions as a branching structure in the general formula below -C(O)-B(-O-) b Here, B and b are as defined above, and the group (-O-) bonded to group B on one side is bonded to a C atom on the other side, where the C atom may be a CH2 group or a carbonyl group. Thus, the term dendrimeric hydrocarbon structure refers to a branched structure that includes at least two consecutive branched structures.

[0286] Each group T is R7* It constitutes one of at least two terminal groups of the group and is usually derived from a fatty acid. Therefore, group T is preferably a linear saturated or monounsaturated hydrocarbon radical having 2 to 24 carbon atoms.

[0287] Group T is preferably connected via a carbonyl group or an estolide chain, to the general formula -B(-O-) b or -C(O)-B(-O-) b It is connected to the (-O-) group of the branched structure.

[0288] Due to the existence of the above branching structure, R 7* It employs a branched or dendritic structure.

[0289] The following structure is a branched hydrocarbon radical R as defined above. 7* This is an example. [ka]

[0290] Among them, the general formula B(-O-) b The branched structure originates from 2,2'-dihydroxymethylpropionic acid, and group T is an n-heptadecanyl group bonded to the branched structure. It originates from stearic acid and is bonded to group B by a -C(O)-O-unit.

[0291] Therefore, this structure is terminated by two groups of the general structure -X-(CO)-T and includes the branched structure of formula -B(-O-)2.

[0292] Branching base R 7* Examples of groups from which it may originate are shown below, [ka] Here, R is as follows: [ka]

[0293] Corresponding base R 7* In this case, the branched structure is the same as the previous structure, but the two terminal groups T, which are n-heptadeca-9-enyl groups derived from oleic acid, are attached to the branched structure via an estolide chain structure derived from ricinoleic acid.

[0294] The present invention's group R is a dendrimer hydrocarbon. 7* Another example is shown below. Within that, branched structure -B(-O-) b It has two further branched structures -(C(O)-B(-O-) b This continues directly, resulting in a further increase in the terminal group of the general structure -XC(O)-T. [ka]

[0295] In this structure, the branched structure originates from 2,2'-dihydroxymethylpropionic acid, and the terminal group is based on stearic acid.

[0296] Branched or dendrimer-like group R 7* Therefore, it is also within the scope of the present invention as defined above, that the terminal group -XC(O)-T is not directly bonded to group B of the branched structure, but is bonded to the (-O-) group of the branched structure by a hydrocarbon group, for example, optionally substituted or heteroatom-containing alkylene or alkenylene, preferably n-alkylene having 2 to 10 carbon atoms, a poly(alkylene oxide) group, for example, a poly(ethylene oxide) or poly(propylene oxide) group, or in particular by an oligo or polyester group, i.e., by an estrid chain.

[0297] In the following example, the stearic acid-based group -XC(O)-T is attached to the branched structure by an estolide chain. [ka] Here, [ka]

[0298] Using the same method, dendrimer-like group R 7* So, the structure is -(C(O)-B(-O-) b One or more branching elements of structure -B(-O-) b or -(C(O)-B(-O-) b It is also within the scope of the present invention as defined above, that the branching elements are not directly connected, but are connected by hydrocarbon groups, for example optionally substituted or heteroatom-containing alkylenes or alkenylenes, preferably n-alkylenes having 2 to 10 carbon atoms, poly(alkylene oxide) groups, for example, poly(ethylene oxide) or poly(propylene oxide) groups, or in particular by oligo- or polyester groups, i.e., by estrid chains.

[0299] In the following example, the branched structure is linked by estrido chains. [ka] Here [ka]

[0300] According to the present invention, the residue R of formula (IVa) 1 is a residue of q-valence, where q is 2 to 55, preferably 2 to 40, more preferably 2 to 4, and this is the residue R of formula (IVa). 1 It is defined in the same way as in formula (Ia), except that it indicates that it has q residues of the structure (-CO-XG) having G as defined below. Therefore, the term "q-valence" is the same as the residue R in formula (IVa). 1 This does not refer to or limit the number of any further optional substituents other than (-CO-XG), which may be carboxyl or hydroxyl groups.

[0301] The R of formula (IVa) is q-valent with respect to residue (-CO-XG). 1 The hydrocarbyl structure is preferably selected from the group consisting of linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkalilene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, particularly those having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms.

[0302] Preferably, the hydrocarbon structure is a linear or branched alkylene group, or a linear or branched alkylene group interrupted by an ether group, an ester group, or both an ether group and an ester group, particularly a branched structure derived from a product obtained by esterifying a polyol with a mono- or polyhydroxycarboxylic acid having up to 150 carbon atoms, or a linear alkylene group having up to 22 carbon atoms. Also preferred are C2-C6 linear alkenylene groups, particularly 1,2-ethenylene radicals derived from maleic acid or fumaric acid.

[0303] More preferably, the q-valence R of formula (IVa) 1 The radical is selected from alkylene groups, which can be selected from the group consisting of linear, branched, or cyclic alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups. Particularly preferred are 1,1-methylene, 1,2-ethylene, 1,3-propylene, 1,2,3-propylene, and 1,4-butylene radicals.

[0304] Which of the C atoms in the hydrocarbyl radical is the R in formula (IVa)? 1There are no restrictions regarding whether it has a (-CO-XG) group attached to it.

[0305] R in equation (IVa) 1 Regarding the presence of optional functional groups and optional substituents, the R of formula (IVa) 1 It is preferably derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, and more preferably from compounds derived from the condensation products of glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds and C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid or 12-hydroxystearic acid, or R 1 This refers to a linear alkylene group, particularly an alkylene group without further substituents in addition to the (-C(O)-XG) group.

[0306] The base (-C(O)-XG) is usually R 1 At the position substituted by the -C(O)OH group of the parent compound from which it originates, radical R is formed via the -C(O)-X- unit, particularly the -C(O)-X- unit. 1 It is obvious to those skilled in the art that they can be combined.

[0307] For example, R derived from succinic acid 1 The group is a 1,2-ethylene radical, where "1,2" indicates the position where the radical is substituted with a (-C(O)-XG)- group.

[0308] According to the present invention, X, R 10 , R 6 , and m are defined for equations (IVa) and (Va) in the same way as for equations (Ia) and (IIa).

[0309] As defined above, R 11 It has 1 to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated, or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with carboxyl, hydroxyl, or halide groups.

[0310] Therefore, R 11 This can represent a hydrocarbyl group selected from the group consisting of linear, branched, or cyclic alkyl groups, linear, branched, or cyclic alkenyl groups, linear, branched, or cyclic alkynyl groups, linear, branched, or cyclic alkaryl groups, linear, branched, or cyclic aralkyl groups, and linear, branched, or cyclic aryl groups, such as phenyl, benzyl, or tolyl, in particular, such groups having 6 to 24 carbon atoms, each optionally containing one or more functional groups as described above.

[0311] Comfortable, R 11The radicals are selected from linear alkyl and linear alkenyl groups, particularly linear C6-C24 alkyl groups, e.g., hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or linear C6-C24 alkenyl groups, e.g., hexenyl, heptenyl, octenyl, nonenyl, Selected from decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the residue may have one or more hydroxyl or carboxyl substituents, and where these groups are most preferably bonded to an adjacent C(O) or X group by a terminal C atom.

[0312] Which of the C atoms in the hydrocarbyl radical is adjacent to the group X? 11 There are no restrictions on whether it should be combined with other elements.

[0313] However, R 11 Preferably, it is derived from a monoalcohol, diol, or polyol having two or more OH groups, or from a monohydroxycarboxylic acid or a carboxylic acid having one or more hydroxyl groups, more preferably from a monoalcohol or monohydroxycarboxylic acid, and most preferably from a C6-C24 fatty acid having one hydroxyl group as a substituent. Therefore, R 11 Preferably, represents an alkyl or alkenyl chain of such a carboxylic acid.

[0314] R 11A preferred example is a structure formally derived from the corresponding hydroxylcarboxylic acid from which the hydroxyl group has been removed, where the hydroxylcarboxylic acid can be selected from monohydroxycarboxylic acids, such as reskerolic acid, ricinoleic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, or dihydroxycarboxylic acids, in particular from 2,2'-dihydroxymethylpropanoic acid, 9,10-dihydroxystearic acid, or polyhydroxycarboxylic acids, in particular from gluconic acid.

[0315] Similarly, R 11 A preferred example is a structure formally derived from the corresponding mono and diols by formally subtracting one hydroxyl group, where the alcohol can be selected from the group consisting of methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, and 1,6-hexanediol.

[0316] R 11 Further preferred examples are compounds formally derived from glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols formally containing 4 to 6 glycerol units, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, such as ethylene oxide, propylene oxide, and / or butylene oxide-based polyethers, as defined above.

[0317] Radical R 11 These are -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Quaternary ammonium group [ka] It may optionally contain one or more groups selected from and may be substituted with an OH group or a carboxyl group, but radical R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group, that forms an internal carboxylate group, an internal ester group, or an internal amide group.

[0318] According to the present invention, in the compound of formula (IVa), at least one part of formula (Va) contains R 11 It has at least two, preferably at least six, carbon atoms, and in the same part of formula (Va), at least one R 6 It is essential that it has at least 6, preferably at least 8, carbon atoms.

[0319] According to the present invention, the compound of formula (Ia) is not composed solely of glycerol and ricinoleic acid moieties; in other words, it is essential that it is not a polyglycerol polyricinolate (PGPR). In this context, polyglycerol polyricinolate (PGPR) is defined above in accordance with the present invention.

[0320] In general, the compounds according to the present invention and the embodiments thereof are the same as the compounds of the hair care compositions and embodiments described above, except that m cannot be 0 and is at least 1.

[0321] In a preferred embodiment of the present invention, a compound according to general formula (Ia) or (IVa) is provided, where R 1As defined above, it has a maximum of 1000 carbon atoms, preferably a maximum of 1000, more preferably a maximum of 300, even more preferably a maximum of 100, and most preferably a maximum of 50 carbon atoms.

[0322] Preferably, the R of formula (Ia) according to this embodiment 1 This refers to linear or branched alkylene groups, or linear or branched alkylene groups interrupted by ether groups, ester groups, or both ether and ester groups, particularly branched structures or linear alkylene groups derived from products obtained by esterification of polyols with mono or polyhydroxycarboxylic acids.

[0323] More preferably, R of formula (Ia) according to this embodiment 1 The radical is selected from alkylene groups selected from the group consisting of linear and branched alkylene groups, and is particularly selected from linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups.

[0324] R in equation (Ia) according to this embodiment 1 Regarding the presence of any functional group and any optional substituent in the radical, R 1 It is preferably derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, or R 1 It is preferable that the group is a linear alkylene group, particularly an alkylene group that does not have any further substituents in addition to the (-XC(O)-F) group, and R 1It is even more preferable that the compound is derived from a condensation product of glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds with C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid or 12-hydroxystearic acid.

[0325] Preferably, the R of formula (IVa) according to this embodiment 1 The linear or branched alkylene group is selected from linear or branched alkylene groups, or linear or branched alkylene groups interrupted by ether groups, ester groups, or both ether and ester groups, particularly branched structures derived from products obtained by esterification of polyols with mono or polyhydroxycarboxylic acids, or linear alkylene groups. Also preferred are C2-C6 linear alkenylene groups, particularly 1,2-ethenylene radicals derived from maleic acid or fumaric acid.

[0326] More preferably, R in formula (IVa) 1 The radical is selected from alkylene groups, which can be selected from the group consisting of linear or branched alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups. Particularly preferred are 1,1-methylene, 1,2-ethylene, 1,3-propylene, 1,2,3-propylene, and 1,4-butylene radicals.

[0327] R in equation (IVa) 1 Regarding the presence of optional functional groups and optional substituents, the R of formula (IVa) 1It is preferably derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, and more preferably from compounds derived from the condensation products of glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds and C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid or 12-hydroxystearic acid, or R 1 This is the case when the group is a linear alkylene group, particularly an alkylene group that does not have any further substituents in addition to the (-C(O)-XG) group.

[0328] In another preferred embodiment of the present invention, a compound according to general formula (Ia) or (IVa) is provided, where any R of the compound is given. 7 or R 11 The number of carbon atoms in the molecule is 3 to 300, preferably 3 to 100, more preferably 3 to 50, even more preferably 3 to 36, even more preferably 3 to 24, and most preferably 11 to 24.

[0329] According to this embodiment, R 7 Preferably, these are independently selected from optionally substituted linear, branched, or cyclic alkyl groups, linear, branched, or cyclic alkenyl groups, linear, branched, or cyclic alkynyl groups, linear, branched, or cyclic alkaryl groups, linear, branched, or cyclic aralkyl groups, and linear, branched, or cyclic aryl groups, such as phenyl, benzyl, or tolyl, each having 6 to 24 carbon atoms, each optionally comprising one or more of the above functional groups.

[0330] Comfortable, R 7The radical is selected from linear alkyl and linear alkenyl groups, particularly linear C6-C24 alkyl groups, e.g., hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or linear C6-C24 alkenyl groups, e.g., Selected from hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where these groups are most preferably bonded to an adjacent C(O) or X group by a terminal C atom.

[0331] According to this embodiment, R 11 Preferably, these are independently selected from optionally substituted linear, branched, or cyclic alkyl groups, linear, branched, or cyclic alkenyl groups, linear, branched, or cyclic alkynyl groups, linear, branched, or cyclic alkaryl groups, linear, branched, or cyclic aralkyl groups, and linear, branched, or cyclic aryl groups, such as phenyl, benzyl, or tolyl, each having 6 to 24 carbon atoms, each optionally comprising one or more of the above functional groups.

[0332] Comfortable, R 11The radicals are selected from linear alkyl and linear alkenyl groups, particularly linear C6-C24 alkyl groups, e.g., hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or linear C6-C24 alkenyl groups, e.g., hexenyl, heptenyl, octenyl, nonenyl, Selected from decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the residue may have one or more hydroxyl or carboxyl substituents, and where these groups are most preferably bonded to an adjacent C(O) or X group by a terminal C atom.

[0333] In yet another preferred embodiment of the present invention, at least one compound according to formula (Ia) or (IVa) is provided, where the compound of formula (Ia) or (IVa) has a molecular weight in the range of 1500 to 2,000,000 g / mol, preferably 1500 to 100,000 g / mol, more preferably 1500 to 30,000 g / mol, even more preferably 1500 to 10,000 g / mol, even more preferably 1500 to 5,000 g / mol, and most preferably 1500 to 3,000 g / mol.

[0334] In more preferred embodiments of the present invention, compounds according to general formula (Ia) or (IVa) are provided, where the compound of formula (Ia) comprises a portion of formula (IIa) from 2 to 100, more preferably a portion of formula (IIa) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, and most preferably 2 to 4; or, where the compound of formula (Ia) comprises a portion of formula (IIa*) from 2 to 100, more preferably a portion of formula (IIa*) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, and most preferably 2 to 4; or, where the compound of formula (IVa) comprises a portion of formula (Va) from 2 to 100, more preferably a portion of formula (Va) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, and most preferably 2 to 4.

[0335] In the present invention, the presence of the (IIa) or (Va) portion of formula, i.e., the estolide portion of the compound, is important for obtaining and adjusting the desired properties of fatty acid-based compounds, and therefore hair care formulations containing these compounds.

[0336] In a preferred embodiment of the present invention, a compound according to general formula (Ia) is provided, which is represented by general formula (IIIa). {[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 -C(O)-X-} r -R 2 (-XC(O)-F) s (IIIa) Here X may be the same or different, and it can be -O- or -NR. 10 - Selected from, here R 10 It has hydrogen, or up to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [ka] Selected from groups consisting of optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, including one or more groups selected from, or in formula (IIIa), R 10 R 2 It can form bonds to form a ring structure, R in equation (IIIa) 2 It is selected from (r+s) valent, optionally substituted hydrocarbon radicals having up to 1000 carbon atoms, optionally containing -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups and quaternary ammonium groups, and optionally substituted with one or more carboxyl groups or hydroxyl groups, and R 10 R 2 If the join is to base-NR, optional base-NR 10 - forms a bond to the nitrogen atom, R 3 It has up to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from optionally substituted hydrocarbon radicals ranging from divalent to hexavalent, which may contain one or more groups selected from the following: Here are multiple R 3 If they exist in equation (IIIa), they may be the same or different. R 4 It has up to 300 carbon atoms and can optionally have -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, which are optionally substituted with divalent to tetravalent groups and include one or more groups selected from the following: Here, equation (IIIa) contains multiple R 4 If they exist, they may be the same or different. And here r+s=2, so 55. r=0 to 54, s≧1, In formula (IIIa), F may be the same or different, and may have up to 1005 carbon atoms, and may optionally be -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and optionally substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, However, this is conditional on at least one radical F containing at least one part of equation (IIa) or (IIa*), -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (IIa) -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (IIa*) Here X is as defined above, Here, m=1 to 20, preferably m=2 to 20, R 6 These are independently selected from divalent, optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 36 carbon atoms. R 7 It has 1 to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R 7 It cannot contain an internal carboxyl group or amide, i.e., R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. And however in at least one part of equation (IIa), R 7 The condition is that it has at least two, preferably at least six, carbon atoms. And in the same part of equation (IIa), at least one R 6 It has at least 6, preferably at least 8, carbon atoms, R 7* It has 1 to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] Quaternary ammonium group [ka] A branched or dendrimeric hydrocarbon radical, independently selected from optionally substituted, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R 7* It is terminated by two or more of the following general structures: -XC(O)-T Here, X is as defined above, and T is a monovalent linear, cyclic, or branched saturated or unsaturated hydrocarbon radical having up to 36 carbon atoms, optionally substituted with a carboxyl group, a hydroxyl group, or a halide group. However, in at least one part of equation (IIa*), R 7* It is terminated by one or more groups T having at least two, preferably at least six, carbon atoms, and in the same portion of formula (IIa*), at least one R 6 The condition is that it has at least 6, preferably at least 8, carbon atoms.

[0337] According to the present invention, the R of the compound of formula (IIIa) 2 , R 3 , R 4 X, R 6 , R 7 , R 7* r and s are as defined above for the compound of formula (III) of the hair care formulation, and m is also defined in the same way as in formula (III), except that it cannot be 0 and is at least 1.

[0338] In a more preferred embodiment of the present invention, compounds of formula (Ia), (IIIa), or (IVa) are provided, where R 10 This is hydrogen, n-, iso-, or tert.-C1-C 22 -Alkyl, C2-C 22 -Alkoxyalkyl, C5-C 30 -Cycloalkyl, C6-C 30 -Aryl, C6-C 30 -Aryl (C1-C6)alkyl, C6-C 30 -alkylaryl, C2-C 22 -Alkenyl, C2-C 22 -Selected from the group consisting of alkenyloxyalkyl groups, which can optionally be substituted with hydroxyl and halogen groups, respectively, and can optionally contain one or more ether groups (-O-), preferably R 10 These are hydrogen or n-, iso-, and tert.-C1-C22 - Selected from alkyl groups.

[0339] According to this embodiment, the most preferred C1-C22-alkyl groups are methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentane, and n-hexane groups, cyclopentyl groups, and cyclohexane groups.

[0340] Another preferred embodiment of the present invention provides a compound of formula (IIIa) or (IVa), where R of the compound of formula (IVa) 1 or R of the compound of formula (IIIa) 2 It has a maximum of 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups [ka] The optionally substituted hydrocarbon radicals may comprise one or more groups selected from and may optionally be substituted with carboxyl groups, hydroxyl groups, and quaternary ammonium groups.

[0341] According to this embodiment, R in formula (IVa) 1 or R of the compound of formula (IIIa) 2 Preferably, the group consists of a linear or branched alkylene group that is optionally substituted, or a linear or branched alkylene group interrupted by an ether group, an ester group, or both an ether group and an ester group, in particular a branched structure derived from a product obtained by esterifying a polyol with a mono or polyhydroxycarboxylic acid having up to 150 carbon atoms, or a linear alkylene group having up to 22 carbon atoms.

[0342] More preferably, R in formula (IVa) 1Radical or R of formula (IIIa) 2 The radical is selected from alkylene groups that can be selected from the group consisting of linear and branched alkylene groups, and in particular from linear alkylene groups such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched alkylene groups such as isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups.

[0343] R in equation (IVa) 1 or R in equation (IIIa) 2 Regarding the presence of optional functional groups and optional substituents, R 1 and R 2 The radical is preferably derived from glycidyl compounds, glycerol and glycerol derivatives, particularly glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether and polyglycerol compounds, or R of formula (IVa). 1 or R in equation (IIIa) 2 However, it is preferable that the alkylene group is a linear alkylene group, particularly a (-XC(O)-F) group, and more preferably R 1 This is when the compound is derived from glycidol, glycerol, glycerol diglycidyl ether, diglycidyl ether, and polyglycerol compounds, and a condensation product of C8-C24 monohydroxy fatty acids, particularly ricinoleic acid, reskerolic acid, or 12-hydroxystearic acid.

[0344] Typically, the base (-XC(O)-F) is R 1 -OH or -NHR of the parent compound derived from 10 Radical R via the -XC(O)- unit, particularly the -OC(O)- unit, at the position substituted by the group. 1 It is obvious to those skilled in the art that they are coupled together.

[0345] For example, R derived from glycerol 1The group is a 1,2,3-propylene radical, where "1,2,3" indicates the position where the radical is substituted with a (-XC(O)-F)- group.

[0346] A more preferred embodiment of the present invention is provided, which is a compound of formula (IIIa) or (IVa), where R in the compound of formula (IVa) 1 or R in the compound of formula (IIIa) 2 The hydrocarbon radicals are selected from divalent to hexavalent, preferably divalent to tetravalent, more preferably divalent to trivalent, and particularly from hydrocarbon radicals optionally substituted with divalent, trivalent, tetravalent, pentavalent, or hexavalent.

[0347] In a preferred embodiment of the present invention, a compound of formula (IIIa) is provided, where R 3 It is selected from residues with two to six valent

[0348] In a more preferred embodiment of the present invention, a compound of formula (IIIa) is provided, where R 3 It has up to 300 carbon atoms, preferably 1 to 200 carbon atoms, more preferably 1 to 150 carbon atoms, even more preferably 1 to 50 carbon atoms, specifically 1 to 20 carbon atoms, and more specifically 1 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from the above.

[0349] Preferred base R according to this embodiment 3R is a linear C1-C22 alkylene group, for example, methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene group, a branched C1-C22 alkylene group, for example, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene group, 3 However, it is more preferable if the radical is a 1,2-ethylene radical, a 1,3-propylene radical, a 1,4-butylene radical, a 1,5-pentylene radical, a 1,12-octadecylen radical, a 1,14-octadecylen radical, a 1,2,3-propylene radical, a 1,2,4-butylene radical, a 1,2,5-pentylene radical, a 1,3,5-pentylene radical, a 1,2,3,4-butylene radical, a 1,2,3,4-pentylene radical, a 1,2,4,5-pentylene radical, a 1,2,3,4,5-pentylene group, or a 1,2,3,4,5,6-hexylene radical.

[0350] In another preferred embodiment of the present invention, a compound of formula (IIIa) is provided, where R 4 It has 2 to 300 carbon atoms, preferably 5 to 200 carbon atoms, more preferably 8 to 150 carbon atoms, and even more preferably 10 to 120 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, which are substituted with divalent to tetravalent, preferably divalent, trivalent, or tetravalent, optionally, and containing one or more groups selected from the above.

[0351] In yet another preferred embodiment of the present invention, a compound of formula (IIIa) is provided, where r = 0 to 50, preferably 0 to 20, more preferably 0 to 10, even more preferably 1 to 10, specifically 1 to 5, more specifically 0, 1, 2, 3, 4, 5, and even more specifically r = 2.

[0352] In a more preferred embodiment of the present invention, a compound of formula (Ia) or specifically formula (IIIa) is provided, where at least one of the radicals F is at least one portion -R 6 (-OC(O)-R 6 ) m -OC(O)-R 7 , -R 6 (-NR 10 -C(O)-R 6 ) m -OC(O)-R 7 , -R 6 (-NR 10 -C(O)-R 6 ) m -NR 10 -C(O)-R 7 , Preferably -R 6 (-OC(O)-R 6 ) m -OC(O)-R 7 This includes R 10 , R 6 , R 7 , and m are as defined above, Or, in the compound of formula (Ia) or (IIIa), At least one of the radicals F is a part -R 6 (-OC(O)-R 6 ) m -OC(O)-R 7* , -R 6 (-NR 10 -C(O)-R 6 ) m -OC(O)-R 7* , -R 6 (-NR 10 -C(O)-R 6 ) m -NR 10 -C(O)-R 7* , Preferably, -R 6(-OC(O)-R 6 ) m -OC(O)-R 7* , It includes at least one part selected from, where R 10 , R 6 , R 7* , and m are as defined above.

[0353] Preferably, in the above structure, R 6 These are optionally hydroxylated hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, nonenilen Independently selected from decenylene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where the group is most preferably bonded to an adjacent C(O) group or X group by a terminal C atom. R 7 These are independently selected from hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, which are optionally hydroxyl-substituted. Here, the group is most preferably bonded to an adjacent C(O) group by a terminal C atom, and R 7*This is as defined in any embodiment of the present invention, m is 1 to 10, preferably 1, 2, 3, 4, or 5.

[0354] In another preferred embodiment of the present invention, a compound of formula (IVa) is provided, where at least one of the radicals G is at least one portion -R 6 (-C(O)-OR 6 ) m -C(O)-OR 11 , -R 6 (-C(O)-NR 10 -R 6 ) m -C(O)-OR 11 , -R 6 (-C(O)-NR 10 -R 6 ) m -C(O)-NR 10 -R 11 , Preferably, -R 6 (-C(O)-OR 6 ) m -C(O)-OR 11 , Includes, Here R 10 , R 6 , R 11 , and m are as defined above for equation (IVa).

[0355] Preferably, in the above structure according to this embodiment R 6These are optionally hydroxyl-substituted hexylene, heptylene, octylene, nonylene, decylene, undecylene, dodecylene, tridecylene, tetradecylene, pentadecylene, hexadecylene, heptadecilen, octadecylene, nonadecilen, eicosilene, henicosilene, doicosilene, tricosilene, and tetraicosilene, or hexenylene, heptenylene, octenylene, noneniylene, decenylene Selected independently from lene, undecenylene, dodecenylene, tridecenylene, tetradecenylene, pentadecenylene, hexadecenylene, heptadecenylene, octadecenylene, nonadecenylene, eicocenylene, henicocenylene, doicocenylene, tricocenylene, and tetraicocenylene, where the group is most preferably bonded to an adjacent C(O) or X group by a terminal C atom. R 11 The group is independently selected from hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylene, nonadecyl, eicosyl, henicosyl, doicosyl, tricosyl, and tetraicosyl, or hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicocenyl, henicocenyl, doicocenyl, tricocenyl, and tetraicocenyl, where the residue may have one or more hydroxyl or carboxyl substituents, and where the group is most preferably bonded to an adjacent C(O) group by a terminal C atom, and m is 1 to 10, preferably 1, 2, 3, 4, or 5.

[0356] R of parts (II) and (IIa) 6 and R 7 Containing ester elements, or R of parts (V) and (Va) 6 and R 11 Containing ester elements, -R 6 (-XC(O)-R6 ) m -XC(O)-R 7 (II) or (IIa), and -R 6 (-C(O)-XR 6 ) m -C(O)-XR 11 (V) or (Va), In particular, the following section, -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , And parts (II*) and (IIa*) of R 6 and R 7* Containing ester elements, -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (II) or (IIa), In particular, the following section, -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* , and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* , These can be synthesized from the corresponding carboxylic acids by esterification using methods known in the prior art. In preferred embodiments, these esterifications can be carried out thermally under reduced pressure at 180 to 250°C, preferably 150 to 350°C (US2011 / 0282084, GB 841554, DE 694943). Furthermore, esterification can be carried out using a catalyst (EP 3009494, WO 2012069386, DD 150064, CH 151317, TA Isbell, Grasas y Aceites, 2011, 62(1), 8-20).

[0357] In another preferred embodiment, the enzyme is used to condense the carboxylic acid (JP 05304966, JP 05211878, JP01016591, A. Bodalo et al., Biochem. Eng. J., 2008, 39(3), 450-456, A. Bodalo et al., Biochem. Eng. J. 2005, 26(2-3), 155-158, Y.Yasuko et al., J.Am. Oil Chem. Soc., 1997, 74(3), 261-267). Generally, the above method provides a multimodal condensate.

[0358] Generally, monomodal condensates can be synthesized by condensation sequences based on the stepwise esterification of hydroxylated carboxylic acids and their derivatives with carboxylic acid anhydrides (K. Meier, Farbe und Lack, 1951, 57, 437-439, FHH Valentin, J. South African Chem. Inst. 1949, 2, 59-61), or preferably carboxylic acid chlorides (KD Pathak et al., J. Scientific & Industrial Research, 1955, 14B, 637-639).

[0359] The repeated cycles based on esterification and acid chloride synthesis generally yield monomodal ester condensates. Further details are outlined in the examples section.

[0360] The following is a schematic diagram of the synthesis sequence of ester condensates based on the stepwise esterification of the OH groups of carboxylic acid chlorides, hydroxylated carboxylic acids, and their derivatives. [ka]

[0361] The arrows here indicate that the product obtained by the esterification of the acyl chloride of fatty acid R1-C(O)Cl by reaction with hydroxylcarboxylic acid HO-R2-C(O)OH, followed by the formation of the acyl chloride by reaction with SOCl2, can be resubmitted to such a reaction sequence. Therefore, in the next reaction sequence, R1 of the starting material R1-C(O)Cl is "R1-C(O)O-R2" from the previous reaction sequence. Thus, the estolide structure can be obtained iteratively, and the number of fatty acid residues in the final estolide moiety is determined by the number of iterative steps.

[0362] Carboxylic acids that do not contain an OH group terminate the chain of the ester condensate, and according to the scheme above, the reaction sequence must be initiated by the formation of an acyl chloride of such a "terminal" carboxylic acid. Monohydroxycarboxylic acids extend the chain of the ester condensate. Dihydroxycarboxylic acids and polyhydroxycarboxylic acids can provide branched and dendrimeric (self-repeating) elements within the ester condensate. The synthesis of a dendrimeric structure of 2,2'-dihydroxymethylpropanoic acid is described in US2016 / 0102179.

[0363] In a more preferred embodiment of the present invention, compounds of formula (Ia), (IIIa), or (IVa) defined above are provided, where the low-melting point and high-melting point fatty acids ≥ C5 are R of general formula (IIa). 6 and R 7Within the contained ester element, and of the general formula (Va) R 6 and R 11 Within the contained ester elements, -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (IIa), and -R 6 (-C(O)-XR 6 ) m -C(O)-XR 11 (Va), Part in particular -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Here, X, R 6 , R 7 , R 10 , and R 11 This is as defined above, Or R in general formula (IIa*) 6 and R 7 *Within the contained ester elements, -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (IIa*) Part in particular -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* , Here, X, R 6 , R 7* This is as defined above. It will be placed there.

[0364] It is generally within the scope of the present invention that low-melting-point and high-melting-point fatty acids ≥ C5 are independently arranged for individual ester groups of parts selected from the parts of general formula (IIa) and (Va) present in compounds of general formula (Ia), (IIIa), and (IVa), or for individual ester groups of parts selected from the part of general formula (IIa*) present in compounds of general formula (Ia), (IIIa), and (IVa).

[0365] For example, this embodiment of the present invention applies when, while other parts of general formula (IIa) are not shown, certain parts of general formula (IIa) indicate specific positions of low-melting-point and high-melting-point fatty acid scaffolds, as described below. This may be particularly the case of parts located at different residues F as defined above.

[0366] Within the framework of this invention, low melting point fatty acids ≥ 5 are defined by a melting point of 40°C or less. Preferred examples include, in particular, oleic acid, ricinoleic acid, octanoic acid, decanoic acid, pivalic acid, and neodecanoic acid.

[0367] Within the framework of the present invention, high melting point fatty acids ≥ 5 are defined by a melting point greater than 40°C. Preferred examples include, in particular, dodecanoic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, arachidic acid, behenic acid, 10-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, and 14-hydroxytetradecanoic acid.

[0368] The corresponding melting points can be obtained from the literature (G. Knothe et al., J. Am. Oil Chem.Soc., 2009, 86, 844-856).

[0369] In a more preferred embodiment of the present invention, compounds of formula (Ia) or (IIIa) as defined above are provided, wherein at least one, and in each of the one or more of formula (IIa), at least one, more preferably one, one, two or three groups are R 6 Low melting point fatty acids ≥ 5 that form R7 One or more radicals adjacent to R 6 It is included in, on the other hand, R of equation (IIa) 6 and R 7 At the opposite end of the contained ester element, at least one, preferably more than one, more preferably one, two, or three high melting point fatty acids ≥ C5 are present in one or more R 6 To form, or in such a way, in one or more parts of formula (IIa), at least one, preferably more than one, more preferably one, two or three R 6 High melting point fatty acids ≥ C5 that form R 7 One or more radicals adjacent to R 6 It forms R of equation (IIa), while on the other hand 6 and R 7 At the opposite end of the contained ester element, at least one, preferably more than one, more preferably one, two, or three low-melting point fatty acids ≥ C5 are present, one or more radicals R 6 It forms.

[0370] According to this embodiment, at least 50% of all parts of formula (IIa) are derived from high-melting-point and low-melting-point fatty acids as described above. 6 When such a configuration of radicals is observed, it is preferable that more than 80% of all parts of formula (IIa) are derived from high-melting-point and low-melting-point fatty acids as described above. 6 -If such a configuration of radicals is observed, more preferably, and most preferably, all parts of general formula (IIa) are the residue R as described above. 6 and R 7 This shows the arrangement.

[0371] Similarly preferred embodiments provide compounds of formula (IVa) defined above, where one or more parts of formula (Va) each have at least one, preferably more than one, more preferably one, two or three groups R 6 Low melting point fatty acids ≥ 5 that form R 11 One or more radicals adjacent to R 6It is included in, on the other hand, the R of equation (Va) 6 and R 11 At the opposite end of the contained ester element, at least one, preferably more than one, more preferably one, two, or three high-melting-point fatty acids ≥ C5 are present, one or more radicals R 6 To form, or in such a way, one or more parts of formula (Va) each have at least one, preferably more than one, more preferably one, two or three R 6 High melting point fatty acids ≥ C5 that form R 11 One or more radicals adjacent to R 6 It forms R of equation (Va), while on the other hand 6 and R 11 At the opposite end of the contained ester element, at least one, preferably more than one, more preferably one, two, or three low-melting point fatty acids ≥ C5 are present, one or more radicals R 6 It forms.

[0372] At least 50% of all parts of formula (Va) are derived from high-melting-point and low-melting-point fatty acids as described above. 6 When such a configuration of radicals is observed, it is preferable that more than 80% of all parts of formula (Va) are derived from high-melting-point and low-melting-point fatty acids as described above. 6 When such a radical configuration is observed, more preferably, and most preferably, all parts of the general formula (Va) are the residue R as described above. 6 and R 11 This shows such an arrangement.

[0373] In another equally preferred embodiment, compounds of formula (Ia) or (IIIa) as defined above are provided, where R is one or more parts of formula (IIa*). 7* One or more radicals adjacent to R 6 It contains at least one, preferably more than one, more preferably one, two, or three, each having 5 or more carbon atoms and a melting point of 40°C or less, and each of these is R 6It is preferable that the mixture contains low-melting-point fatty acids that form a compound, while high-melting-point fatty acids having five or more carbon atoms, preferably at least one, preferably more than one, more preferably one, two, or three, and having a melting point above 40°C, are defined as R of formula (IIa*). 6 and R 7* One or more radicals R at the opposite end of the contained ester element 6 Forms or in one or more parts of formula (IIa*), at least one, preferably more than one, more preferably one, two or three, each R 6 High melting point fatty acids ≥ C5 that form R 7* One or more radicals adjacent to R 6 A low-melting-point fatty acid having five or more carbon atoms, at least one, more than one, more preferably one, two, or three, and having a melting point of less than 40°C, is R of formula (IIa*). 6 and R 7* One or more radicals R at the opposite end of the contained ester element 6 It forms and at least 50% of all parts of formula (IIa*) are derived from high-melting-point and low-melting-point fatty acids as described above. 6 -When such a radical configuration is observed, preferably more than 80% of all parts of formula (IIa*) are derived from high-melting-point and low-melting-point fatty acids as described above. 6 - When such a radical configuration is observed, it is more preferable, and all parts of general formula (IIa) are residues R as described above. 6 and R 7* Such an arrangement is most preferable.

[0374] As already mentioned above, the specific arrangement of high-melting-point and low-melting-point fatty acids is the individual R of formula (IIa) of compounds of general formula (Ia) or (IIIa). 6 and R 7 For each ester moiety, and in a completely similar manner, the individual R of formula (Va) of the compound of general formula (IVa) 6 and R 11 Each ester component can be changed independently.

[0375] The preferred embodiments outlined above are -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (IIa), and -R 6 (-C(O)-XR 6 ) m -C(O)-XR 11 (Va), Part in particular -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Here, X, R 6 , R 7 , R 10 , and R 11 This is as defined above. In this case, crystallization, viscosity increase, and a tendency for local variation in phase formation along the entire length of these ester elements are observed, R 6 and R 7 Containing ester elements and R 6 and R 11 It enables the incorporation of contained ester elements, or -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (IIa*) Particularly, -OC(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7* , and -NR 10 -C(O)-R 6-(OC(O)-R 6 ) m -OC(O)-R 7* , Here, X, R 6 , R 7* , R 10 , and R 11 This is as defined above. Crystallization, viscosity increase, and a tendency for localized changes in phase formation along the entire length of these ester elements are observed in R. 6 and R 7* This enables the incorporation of contained ester elements.

[0376] The above combination of carboxylic acids and synthetic concepts provides for obtaining ester condensates with specified properties such as molecular weight, molecular weight distribution, carboxylic acid arrangement, and viscosity.

[0377] Radical R 1 , R 2 or R 3 This is particularly due to the formation of the following general structure base, -R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , and -NR 10 -C(O)-R 6 -(OC(O)-R 6 ) m -OC(O)-R 7 , Preferably, - Monohydroxycarboxylic acids, especially lactic acid, 4-hydroxybutanoic acid, -Dihydroxycarboxylic acids, especially 2,2-bis(hydroxymethyl)propanoic acid, -Dendrimeric oligomers of polyhydroxycarboxylic acids, especially gluconic acid, or dihydroxycarboxylic acid oligomers, especially dendrimeric oligomers of 2,2-bis(hydroxymethyl)propanoic acid, Corresponding acid chloride precursor, Cl-C(O)-R 6 -(OC(O)-R 6 )m -OC(O)-R 7 , Here, X, R 6 , R 7 , and R 10 This is as defined above. Due to esterification with, The part of general formula (IIa) that exists in base F is R 6 and R 7 It can be bonded to the contained ester elements.

[0378] in general, R of the following structure 6 and R x Containing ester elements, {[-R 6 -OC(O)-] m} n R x ,or - [R 6 -OC(O)] m -R x -, This is, for example, the residue R of general formula (III) or (IIIa). 4 It exists in, or can constitute, Here R 6 This is as defined above, m is 1-10, n is from 2 to 4, and R x These are single bonds or C1 to C34 hydrocarbon radicals derived from substituted linear, cyclic or branched saturated or unsaturated polycarboxylic acids having 2 to 36 carbon atoms, preferably 2 to 24 carbon atoms, more preferably 2 to 18 carbon atoms, and even more preferably 4 to 18 carbon atoms. - Preferably derived from dicarboxylic acids, particularly oxalic acid, malonic acid, malic acid, tartaric acid, maleic acid, itaconic acid, succinic acid, sebacic acid, dimer acid, [ka] Derived from amide condensation products of amino acids with maleic acid or succinic acid, particularly N-maleoil-β-alanine, N-succinyl-β-alanine, N-maleoil-asparagine, dicarboxylic acid anhydrides, particularly maleic anhydride, succinic anhydride, and dihydric alcohols with phthalic anhydride, particularly ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butanediol, and 1,4-butanediol. - Preferably derived from tricarboxylic acids, particularly citric acid, isocitric acid, mellitic acid, bis-amide condensation products of amino acids with maleic acid or succinic acid, particularly bis-(N-maleoil)-lysine, trihydric alcohols, particularly glycerol, trimethylolpropane and dicarboxylic acid anhydrides, particularly ester condensation products of maleic anhydride, succinic anhydride, and phthalic anhydride. - Preferably derived from tetracarboxylic acids, particularly pyromellitic acid, cyclobutanetetracarboxylic acid, tetrahydric alcohols, particularly diglycerol, pentaerythritol and dicarboxylic anhydrides, particularly maleic anhydride, succinic anhydride, and phthalic anhydride, R 6 and R 7 It can be synthesized using the main structure outlined for the contained ester elements. 7 The carboxylic acid that results in R x It is substituted with a carboxylic acid that brings about the following:

[0379] Preferably, ultimately a radical {[-R 6 -OC(O)-] m} n R x R is an intermediate that generates an intermediate. x Acid chloride precursors and R x It can be synthesized by reaction with a hydroxylated precursor having [a specific compound].

[0380] Furthermore, preferably, the final radical-[R 6 -OC(O)] m -R x - The intermediate that generates is R x Acid anhydride precursor having and R 6It can be synthesized by reaction with a hydroxylated precursor having [a specific compound].

[0381] In a more preferred embodiment of the present invention, compounds of general formula (Ia), (IIIa), or (IVa) are provided, where m = 1 to 10, more preferably 1 to 6, even more preferably 2 to 6, specifically 1, 2, 3, 4, 5, 6, more specifically 1 or 2.

[0382] In a more preferred embodiment of the present invention, compounds of general formula (Ia) or formula (IIIa) or (IVa) are provided, where R 6 This is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms.

[0383] According to one embodiment, preferably, R 6 The radical is selected from reskerol acid, ricinoleic acid, 12-hydroxystearic acid, or 14-hydroxystearic acid, particularly from ricinoleic acid.

[0384] In another, more preferred embodiment of the present invention, a compound of general formula (Ia) or specifically formula (IIIa) is provided, where R 7 This is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms.

[0385] The halide group is independently selected from fluoro, chloro, bromo, or iodo groups, where the chloro group is preferred.

[0386] According to this embodiment, preferably, R 7 The radicals originate from oleic acid or stearic acid, particularly oleic acid.

[0387] In a more preferred embodiment of the present invention, a compound of general formula (Ia) or specifically formula (IIIa) is provided, where R 6 and R 7 R in each single part of the general formula (IIa) which is composed of 6 +R 7 The total number of carbon atoms (Σ carbon atoms R 6 , R 7 ) is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100. Here, in the compound of formula (Ia) or (IIIa), R 6 and R 7* Each single part of the general formula (IIa*) is R 6 +R 7* The total number of carbon atoms (Σ carbon atoms R 6 , R 7* The value is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100.

[0388] In another preferred embodiment of the present invention, a compound of formula (IVa) is provided, where R 6 and R 7 R in each single part of the general formula (a) which is composed of 6 +R 11 The total number of carbon atoms (Σ carbon atoms R 6 , R 11 The value is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100.

[0389] In a more preferred embodiment of the present invention, compounds of general formula (Ia) or specifically formula (IIIa) or (IVa) are provided, where R 6It is derived from a monohydroxycarboxylic acid having up to 25 carbon atoms, and is preferably independently selected from the group consisting of glycolic acid, lactic acid, 2-hydroxybutyric acid, 3-hydroxybutyric acid, 4-hydroxybutyric acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, ricinoleic acid, and reskerolic acid.

[0390] Another preferred embodiment of the present invention provides a compound of general formula (Ia) or specifically formula (IIIa), where R 7 The carboxylic acid is derived from a carboxylic acid having up to 25 carbon atoms without hydroxyl substituents, and is preferably independently selected from the group consisting of acetic acid, propanoic acid, butanoic acid, pentanoic acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, nonadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, 2,2-dimethylheptanoic acid, 2,2-dimethyloctanoic acid, neodecanoic acid, undecyl-10-enoic acid, oleic acid, linoleic acid, linolenic acid, and erucic acid.

[0391] More preferably, according to this embodiment, R 7 It is derived from oleic acid, linoleic acid, or linolenic acid, especially R 7 However, as part of formula (IIa), one or more R derived from ricinoleic acid or reskerolic acid 6 This is the case when it is combined with a base.

[0392] In yet another preferred embodiment of the present invention, a compound of general formula (Ia) is provided, which can be specifically represented by formula (IIIa), where R is the part of general formula (IIa). 6 and R 7 At least one, preferably both, of these is derived from an unsaturated carboxylic acid.

[0393] In a more preferred embodiment of the present invention, a compound of formula (IIIa) is provided, where R 4 is selected from divalent to tetravalent, e.g., divalent, trivalent, tetravalent, preferably trivalent, optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals, which have up to 200 carbon atoms, more preferably up to 150 carbon atoms, even more preferably up to 100 carbon atoms, specifically up to 80 carbon atoms, and preferably at least 2, more preferably at least 10, more preferably at least 14 carbon atoms, and optionally include one or more groups selected from -O-, -NH-, and -C(O)-, and where formula (IIIa) has multiple R 4 If they exist, they may be identical or different.

[0394] Another preferred embodiment of the present invention provides a compound of formula (IIIa), where R is a compound of general formula (IIIa). 4 It contains at least one ester group (each -OC(O)- or -C(O)-O-).

[0395] In yet another preferred embodiment of the present invention, a compound of formula (IIIa) is provided, wherein in the compound of formula (IIIa), R 4 This includes dicarboxylic acids, tricarboxylic acids or tetracarboxylic acids, particularly dicarboxylic acids, such as succinic acid, oxalic acid, malonic acid, malic acid, tartaric acid, maleic acid, itaconic acid, succinic acid, sebacic acid, dimer acid, amino-functional dicarboxylic acids, such as D-glutamic acid, and dicarboxylic acids of the following formulas: [ka] and hydroxycarboxylic acids, particularly ricinoleic acid or reskerolic acid, and dicarboxylic acids, such as succinic acid, oxalic acid, malonic acid, malic acid, tartaric acid, maleic acid, itaconic acid, succinic acid, sebacic acid, dimer acid, amino-functional dicarboxylic acids, such as D-glutamic acid, and derived from condensation products of dicarboxylic acids of the following formula: [ka] or R 4 It is derived from amide condensation products of amino acids with maleic acid or succinic acid, for example, N-maleoyl-β-alanine ((E)-4-(2-carboxyethylamino)-4-oxo-buto-2-enoic acid), N-succinyl-β-alanine (4-[(2-hydroxy-1-methyl-2-oxo-ethyl)amino]-4-oxo-butanoic acid), N-maleoyl-asparagine (4-amino-2-[[(E)-4-hydroxy-4-oxo-buta-2-enoyl]amino]-4-oxo-butanoic acid), or R 4 These are derived from ester condensation products of dihydric alcohols, namely ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butanediol, 1,4-butanediol, and dicarboxylic acid anhydrides, namely maleic anhydride, succinic anhydride, phthalic anhydride; or R 4 These are derived from tricarboxylic acids or tetracarboxylic acids, such as citric acid, isocitric acid, trimellitic acid, pyromellitic acid, cyclobutanetetracarboxylic acid, or R 4 It is derived from the bisamide condensation product of an amino acid and maleic acid or succinic acid, namely bis-(N-maleoil)-lysine, or R 4 It is derived from the ester condensation products of trihydric alcohols, such as glycerol and trimethylolpropane, with dicarboxylic acid anhydrides, such as maleic anhydride, succinic anhydride, and phthalic anhydride, or R 4 It is derived from the ester condensation products of tetrahydric alcohols, such as diglycerol and pentaerythritol, with dicarboxylic acid anhydrides, such as maleic anhydride, succinic anhydride, and phthalic anhydride, and Most preferably R 4 It originates from the condensation product of ricinoleic acid or reskerolic acid and succinic acid.

[0396] A preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (Ia), (IIIa), or (IVa), wherein at least one portion of formula (IIa), (IIa*), or (Va) contains two or more different R 6 A basis exists.

[0397] At least two different bases R in the part of formula (IIa), (IIa*), or (Va) 6 The presence of different groups R occurs when at least two different types of hydroxy-substituted or amino-substituted carboxylic acid derivatives are used in the preparation of these chain structures. 6 They may differ from one another in the number of C atoms, and if any, in the number and position of double bonds, and / or the position of substituents and the position of bonds to adjacent groups. They may also differ in whether they are linear or branched. At least one group F, R 6 It is preferable that the hydrocarbon groups derived from ricinoleic acid and 12-hydroxystearic acid are represented independently.

[0398] Another preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (Ia), (IIIa), or (IVa), wherein at least one of the portions of formula (IIa), (IIa*), or (Va) contains the group R of formula (IIa). 6 and R 7 , the base R of equation (IIa*) 6 and R 7* , or the base R of formula (Va) 6 and R 11 These are not based on the same carboxylic acid structure.

[0399] R 6 and R 7 , R 6 and R 7* , or R 6 and R 11Preferably, the groups differ from each other in the carbon chain of the group with respect to the number of carbon atoms, the number or position of double bonds in the carbon chain, or the position of oxygen or nitrogen atoms bonded to the carbon chain of the group. The carboxylic acid structure from which the group is derived may also differ by two or more of the above characteristics.

[0400] In yet another preferred embodiment of the hair care formulation according to the present invention, comprising at least one compound of formula (Ia) or (IIIa), the compound of general formula (Ia) is: p is 2-6, R 1 These are selected from divalent to hexavalent linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkali-lene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene, benzylene, or trilene groups, in particular from such groups having 1 to 1000 carbon atoms, more specifically from 1 to 150 carbon atoms. And at least one base F includes one or more parts of general formula (IIa*), -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (IIa*) Here, R 6 , R 7* , and m are as defined above, Alternatively, in the compound of general formula (IIIa), r+s=2-6, R 2These are selected from divalent to hexavalent linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkalilene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, in particular from such groups having 1 to 1000 carbon atoms, more specifically from 1 to 150 carbon atoms. And at least one base F includes one or more parts of general formula (IIa*), Here R 6 , R 7* , and m are as defined above.

[0401] According to this embodiment, in formula (Ia), p is preferably 2, 3, or 4, most preferably p is 2, or in formula (IIIa), r+s=2, 3, or 4, most preferably r+s is 2.

[0402] Compounds of general formula (Ia), R 1 R is preferably selected from linear, branched, or cyclic alkylene groups having 1 to 150 carbon atoms, more preferably from linear alkylene groups having 1 to 12 carbon atoms, or in formula (IIIa), R 2 It is preferable that the alkylene group be selected from a linear, branched, or cyclic alkylene group having 1 to 150 carbon atoms, more preferably a linear alkylene group having 1 to 12 carbon atoms.

[0403] In a more preferred embodiment of the hair care formulation according to the present invention, comprising at least one compound of formula (Ia) or (IIIa), the at least one compound of general formula (Ia) is: X=O, p is 2, R 1The group is selected from divalent linear, branched, and cyclic alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups, preferably selected from ethylene, n-propylene, n-butylene, n-pentylene and n-hexylene. And at least one base F includes one or more parts of general formula (IIa*), -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7* (IIa*) Here R 6 , R 7* , and m are as defined above, Alternatively, in the case of a compound of general formula (IIIa), X=O, r+s=2, R 2 The group is selected from divalent linear, branched, and cyclic alkylene groups, particularly linear C1-C22 alkyl groups, e.g., methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene, or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups, preferably selected from ethylene, n-propylene, n-butylene, n-pentylene, and n-hexylene, and at least one group F comprises one or more parts of general formula (IIa*), where R 6 , R 7* , and m are as defined above.

[0404] In yet another preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (Ia), (IIIa), or (IVa), the compound of formula (Ia) or (IIIa) comprises one or more groups R 7* It includes, each terminated with three or more -OC(O)-T groups, preferably four or more -OC(O)-T groups, most preferably 4 to 12 -OC(O)-T groups.

[0405] Among these, R includes one branching structure defined above. 7* The branched structure is terminated by 3 to 10 -OC(O)-T groups, while the dendrimer-like structure containing at least two of the branched structures defined above is preferably terminated by 4 to 20 -OC(O)-T groups.

[0406] A more preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (Ia), (IIIa), or (IVa), wherein the compound of formula (Ia) or (IIIa) comprises one or more groups R 7* Each of these includes at least two branching structures of the following general formula: -C(O)-B(-O-) b Here, B is a linear or branched hydrocarbon group having 2 to 20 carbon atoms, and b is 2 or more, where b groups (-O-) bonded to group B on one side are bonded to a carbon atom on the other side that may be a carbon atom of a CH2 group or a carbonyl group.

[0407] On the other hand, as defined above, the existence of a branching structure in the following general formula means that -B(-O-) b To enable branched structures that can be terminated by two or more groups -OC(O)-T, the group R 7* It is essential in and, as defined above, the existence of two or more further branching structures in the general formula below is -C(O)-B(-O-) b Dendrimer-like structure, i.e., R7* From the bond that connects to the rest of the molecule, R 7* This results in the formation of a structure with several branching points that can be arranged sequentially or parallel when moving to the terminal groups. However, deviating from the IUPAC definition of dendrimer molecules [see A. Fradet et al., Pure and Applied Chemistry, 91(3), 523-561: Nomenclature and terminology for dendrimers with regular dendrons and for hyperbranched polymers (IUPAC Recommendations 2017)], a dendron does not have to contain only dendritic and terminal constituent repeating units, and R 7* The free valence of R 7* Each path from the valence to any terminal group that binds to the rest of the molecule does not need to contain the same number of constituent repeating units.

[0408] The general formula is -B(-O-) as defined above. b All (-O-) groups in the branched structure are of the general formula -C(O)-B(-O-) as defined above. b It is even more preferable that it be replaced with a branched structure.

[0409] 1 or more groups R 7* This is a branched structure of three or more -C(O)-B(-O-) b It is also preferable to include, more preferably, the branched structures 3 to 5.

[0410] In this embodiment, it is preferable that b of both branch structures be independently selected from the range of 2 to 6, more preferably from the range of 2 to 4.

[0411] In a preferred embodiment of the hair care formulation according to the present invention comprising at least one compound of formula (Ia), (IIIa), or (IVa), the compound of formula (Ia) or (IIIa) comprises at least one group R 7* The general formula -B(-O-) defined aboveb or -C(O)-B(-O-) b One or more branched structures are independently derived from glyceric acid, 2,2-dihydroxymethylpropionic acid, gluconic acid, maltobionic acid, and lactobionic acid.

[0412] base R 7* Preferably, all branched structures present are independently derived from 2,2-dihydroxymethylpropionic acid, and more preferably, at least one group R 7* All branched structures originate from 2,2-dihydroxymethylpropionic acid.

[0413] All groups R of the compound of formula (Ia) or (IIIa) 7* It is even more preferable that all branched structures present are derived from the same polyhydroxycarboxylic acid.

[0414] In another preferred embodiment of the hair care formulation according to the present invention, the compound of formula (Ia) or (IIIa) contains one or more groups R 7* Each is terminated by two or more units of the following general formula, -R 6 (-XC(O)-R 6 ) t -XC(O)-T, Here R 6 , and T are as defined above, and X=O, t is independently 0-12, preferably independently 0-6, and most preferably independently 0, 1, 2, or 3.

[0415] In this embodiment, two or more terminal groups defined above are located at the ends of the estolide chain. One or more groups R 7* Preferably, each is a general formula -R 6 (-XC(O)-R 6 ) t Terminated by 2 to 48 units of -XC(O)-T, more preferably with formula -R 6 (-XC(O)-R 6) t Terminated by 2 to 27 units of -XC(O)-T, most preferably with formula -R 6 (-XC(O)-R 6 ) t It is terminated by 4 to 16 -XC(O)-T units.

[0416] A more preferred embodiment of the hair care formulation according to the present invention is one or more groups R of the compound of formula (Ia) or (IIIa). 7* It is terminated by two or more groups, preferably 4 to 12 groups, of the following structure: -R 6 (-XC(O)-R 6 ) t -XC(O)-T, Here R 6 These are independently derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. X is O, and T is independently derived from C2 to C24, preferably C8 to C24 fatty acids, particularly lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, and arachidic acid. And t is 0-6, preferably 0, 1, 2, or 3.

[0417] According to this embodiment, R 6 It is preferable that T is derived from ricinoleic acid and T is derived from stearic acid or oleic acid.

[0418] more preferably, all base R 7* R 6 It is derived from ricinoleic acid, and more preferably all groups R 7* In R 6 is derived from ricinoleic acid, T is derived from stearic acid or oleic acid, and t is 0, 1, 2, or 3.

[0419] In another preferred embodiment of the hair care formulation according to the present invention, one or more groups R of the compound of formula (Ia) or (IIIa) 7* It is independently selected from one of the following branched or dendrimer fatty acid structures, -R 12 -OC(O)-R 6 -(OC(O)-R 61 ) m1 -(OC(O)-R 62 ) m2 -OC(O)-T, or -R 12 -NR 10 -C(O)-R 6 -(OC(O)-R 61 ) m1 -(OC(O)-R 62 ) m2 -OC(O)-T, here R 12 It has 2 to 50 carbon atoms, specifically 2 to 20 carbon atoms, more specifically 2 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from divalent, optionally substituted hydrocarbon radicals, where radical R may comprise one or more groups selected from and may be substituted with -OH or halide groups, where radical R 10 It cannot include a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group that forms an internal carboxylate group or an internal amide group, and preferably represents a C1-C24n-alkylene group and a CC2-C24n-alkenylene group, particularly -CH2-, -CH2CH2-, -CH2CH2CH2-, R 6 This is defined as above, m1 is 0 to 12, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. m2 is 0 to 12, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. And m1 + m2 is t, where t is from 0 to 12, preferably from 0 to 10, more preferably from 0 to 6, even more preferably from 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6, and T is defined as above, R 61 and R 62 This is the base R defined above. 6 Selected from.

[0420] Preferably, R 6 , R 61 , R 62 , and T are selected as follows: [Table 3] Here R 6 +R 7 The total number of carbon atoms (Σ carbon atoms R 6 , R 7 ) is 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150. However, R derived from dihydroxylated carboxylic acid or polyhydroxylated carboxylic acid 6 , R 61 and R 62 The condition is that at least one, preferably one to two, more preferably two, and even more preferably all of the OH groups are esterified.

[0421] According to this embodiment, also preferably, one or more groups R of the compound of formula (Ia) or (IIIa) 7*These are independently derived from 2,2'-di-hydroxymethylpropanoic acid and di-hydroxymethylpropanoic acid itself, C2 to C24, preferably C8 to C24 fatty acids, more preferably lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, arachidic acid, and optionally monohydroxy fatty acids, particularly ricinoleic acid, resulting in branched or dendrimer fatty acid structures, as shown below. [ka] Here R is as follows: [ka] Or the following structure, [ka] Here, R is as shown above. This is illustrated by [example].

[0422] Preferably, all groups R of the compound of formula (Ia) or (IIIa) 7* This is selected independently from the group of structures cited above.

[0423] More preferably, all groups R of the compound of formula (Ia) or (IIIa) 7* This is represented by a single formula selected from the group of structures cited above.

[0424] In preferred embodiments of the hair care formulation according to the present invention, at least one compound of general formula (Ia) or (IIIa) is represented by one of the following specific structures: i) (fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(fatty acid), or ii) (branched fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(branched fatty acid) or iii) (Dendrimeric fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(dendrimeric fatty acid), Here -C2-C10 hydrocarbons are C2-C10 hydrocarbon groups, and are particularly derived from ethylene glycol, 1,3-propylene glycol, 1,4-butanediol, 1,6-hexanediol, 1,2-propylene glycol, and 1,3-butanediol. - Mono- or oligo-C8-C24 hydroxy fatty acids are groups derived from C8-C24 hydroxy-substituted carboxylic acid monomers or oligomers of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification, and in particular, derived from mono-oligolicinoleic acid or oligolicinoleic acid with a degree of oligomerization of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4. - Fatty acids are saturated or unsaturated hydrocarbyl residues derived from C2-C24 carboxylic acids having such residues, preferably from such C8 to C24 fatty acids, particularly from lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, and arachidic acid. - Branched fatty acids are residues obtained by esterifying polyhydroxy monocarboxylic acids, particularly 2,2'-dihydroxymethylpropanoic acid, with C2 to C24, preferably C8 to C24 fatty acids, in particular lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, arachidic acid, and optionally monohydroxy fatty acids, particularly ricinoleic acid. -Dendrimer fatty acids are residues obtained by esterification, that is, the esterification of the branched fatty acid residues described above with at least one further polyhydroxy monocarboxylic acid, particularly 2,2'-dihydroxymethylpropanoic acid, with C2 to C24, preferably C8 to C24 fatty acids, in particular lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, arachidic acid, and an optional monohydroxy fatty acid, particularly ricinoleic acid.

[0425] Branched fatty acid groups are exemplified by the following structures: [ka] Here R is as follows: [ka] Dendrimer fatty acid groups are exemplified by the following structures: [ka] Here, R is as described above for branched fatty acid groups.

[0426] In a more preferred embodiment of the hair care formulation according to the present invention, the compound of formula (Ia), (IIIa), or (IVa) comprises at least one portion of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- Here R 6 This is as defined above, l is an integer independently selected from 0 to 20, more preferably from 1 to 12, and even more preferably from 2 to 10. L may have 1 to 30 carbon atoms and optionally -O-, -S-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [ka] A divalent hydrocarbon radical which may include one or more groups selected from quaternary ammonium groups, Preferably, L is a divalent alkylene or alkenylene radical having 1 to 30 carbon atoms. More preferably, L is selected from methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, nonylene, etenylene, propenylene, butenylene, pentenylene, hexenylene, heptenylene, octenylene, nonenylene. Most preferably, L is selected from methylene, ethylene, ethenylene, or butenylene.

[0427] According to one embodiment, preferably, R 6 These are independently derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, more preferably from ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, 11-hydroxy-undecanoic acid, and even more preferably from all R 6 These are independently derived from ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, 11-hydroxy-undecanoic acid, and most preferably all R 6 This is the same group derived from one carboxylic acid selected from the group consisting of ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid.

[0428] Structure of part of equation (Va) -R 6 (-C(O)-XR 6 ) m -C(O)-XR 11 (Va) and the structure of the general formula below -([-OC(O)-R6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- It is explicitly stated that duplicates may exist. In other words, according to the present invention, the following general formula is: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-R 11 The requirements for the radical G in equation (Iva) are satisfied.

[0429] In another preferred embodiment of the hair care formulation according to the present invention, Compounds of formula (Ia), (IIIa), or (IVa) include at least one part of the following general formula: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-, Here, L and l are as defined above, And R 6 These are independently derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid, most preferably R 6 It is derived from ricinoleic acid.

[0430] Preferably, L is selected from C1 to C10, preferably methylene, ethylene, butylene, octylene, and decene, l is independently in the range of 0 to 4, and R 6 It is derived from ricinoleic acid.

[0431] In yet another preferred embodiment of the hair care formulation according to the present invention, the compound of formula (Ia), (IIIa), or (IVa) comprises at least one portion of the following general formula: ([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])- Here, L is selected from methylene, ethylene, and ethenylene. R 6 It is derived from ricinoleic acid, and l is independently selected from 0, 1, 2, and 3, and the sum of l is in the range of 0 to 4.

[0432] Preferably, L is an ethylene group, and R 6 l is derived from ricinoleic acid, and l is independently selected from 0 or 1.

[0433] In a preferred embodiment of the hair care formulation according to the present invention, the compound of formula (Ia), (IIIa), or (IVa) comprises at least one portion of the following structure: (Fatty alcohol)-OC(O)-(mono or oligo C8-C24 hydroxy fatty acid)-OC(O)-(C1-C12 hydrocarbon)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(fatty alcohol), Here -C2-C12 hydrocarbons are C2-C12 hydrocarbon groups, particularly derived from succinic acid, maleic acid, itaconic acid, adipic acid, sebacic acid, and dodecanediic acid. - Mono- or oligo-C8-C24 hydroxy fatty acids are groups derived from C8-C24 hydroxy-substituted carboxylic acid monomers or oligomers of up to 20 C8-C24 hydroxy-substituted carboxylic acid monomers formed by esterification, and in particular, derived from monoricinoleic acid or oligoricinoleic acid with a degree of oligonucleotide formation of 2 to 20, preferably 2 to 10, more preferably 2 to 6, and even more preferably 2 to 4. - Fatty alcohols are groups derived from C2 to C24, preferably C8 to C24 fatty alcohols, particularly n-octanol, n-decanol, n-dodecanol, n-tetradecanol, n-hexasedanol, oleyl alcohol, stearyl alcohol, behenyl alcohol, and arachidyl alcohol.

[0434] This type of compound is exemplified by the following structure: [ka] Here R 1 The following is: [ka] The dashed line connection is R 1 R to the O atom in the above structure 1 This shows the combination.

[0435] In another preferred embodiment of the hair care formulation according to the present invention, the compound of formula (Ia), (IIIa), or (IVa) comprises at least one portion of the following structure: -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-R 11 Here L, l, R 6 , and R 11 This is as defined above.

[0436] Preferably, L, l, and R 6 This is as defined above, and R 11 The group is selected from C1-C23 hydrocarbyl groups, preferably C1-C18 hydrocarbyl groups, more preferably C7-C19 hydrocarbyl groups, and even more preferably C11-C17 hydrocarbyl groups, most preferably derived from lauric acid, myristic acid, palmitic acid, oleic acid, and stearic acid.

[0437] More preferably, the compound of formula (IVa) has the following structure: R 11 -([-OC(O)-R 6 (-OC(O)-R 6 ) l -OC(O)-LC(O)-O-(R 6 -C(O)-O) l -R 6 -C(O)O])-R 11 Here, L, l, and R 6 This is as defined above, and R 11 These are independently selected from C1-C23 hydrocarbyl groups, preferably C1-C18 hydrocarbyl groups, more preferably C7-C19 hydrocarbyl groups, and even more preferably C11-C17 hydrocarbyl groups, and most preferably derived from lauric acid, myristic acid, palmitic acid, oleic acid, and stearic acid.

[0438] More preferably, L is selected from methylene, ethylene or ethenylene, butylene, hexylene, octylene, decene, or derived from itaconic acid. l is independently selected from the range 0 to 4. R 6 It was selected from ricinoleic acid, and R 11 It is selected from oleic acid or stearic acid.

[0439] use The present invention further relates to the use of the above-mentioned high-molecular-weight fatty acid compounds of formula (Ia), particularly formulas (IIIa) and (IVa), in cosmetic formulations for skincare and haircare, such as conditioners and shampoos, as described in the above embodiments of the present invention.

[0440] The present invention further relates to the use of the above-mentioned polymer fatty acid compounds of formulas (I), (III), (IV), (Ia), (IIIa), and (IVa), as described in the above embodiments of the present invention, for treatments of fibers, preferably amino acid-based fibers, more preferably human hair, particularly for retaining hair color, enhancing hair shine, enhancing hair color, protecting hair color, for hair conditioning, for making hair smooth or soft, for improving hair manageability, particularly for improving hair combability, anti-friction and anti-static properties.

[0441] compound The present invention further relates to a composition comprising at least one high-molecular-weight fatty acid compound of formulas (I), (III), (IV), (Ia), (IIIa), and (IVa), as defined in the embodiments above, together with at least one additional component commonly used in such compositions.

[0442] Preferred compositions comprising at least one compound of formulas (I), (III), and (IV) or (Ia), (IIIa), and (Iva) as defined in the above embodiments for hair treatment according to the present invention are selected from the group consisting of hair shampoo compositions, hair care compositions, hair conditioning compositions, hair coloring or dyeing compositions, hair combability improving compositions, frizz prevention compositions, hair rinse-off and leave-on compositions.

[0443] The formulations and compositions according to the present invention are generally preferably aqueous formulations and compositions, that is, they contain water, and more preferably they contain more than 20% by weight of water.

[0444] In particular, the present invention relates to a cosmetic composition comprising at least one high-molecular-weight fatty acid compound as defined in the above embodiments, together with at least one additional component commonly used in such compositions.

[0445] Specifically, the present invention relates to a hair care formulation composition comprising at least one high-molecular-weight fatty acid compound as defined in the above embodiments, together with at least one additional component commonly used in such compositions.

[0446] Summary of a specific preferred embodiment of the present invention The following summarizes certain preferred embodiments of the present invention.

[0447] 1. A hair care formulation comprising at least one compound of formula (I), R 1 (-XC(O)-F) p (I) Here R in equation (I) 1 It is selected from p-valent, optionally substituted hydrocarbon radicals, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, [ka] and may comprise one or more groups selected from quaternary ammonium groups, and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups. p≧2, more preferably 2-811. X may be the same or different, and it can be -O- or -NR. 10 - Selected from, here R 10 It has hydrogen, or up to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [ka] Selected from the group consisting of optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from the following: Alternatively, in equation (I), R 10 R 1 It can form bonds to form a ring structure, F may be the same or different, and may have up to 1005 carbon atoms, and may optionally contain -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and optionally substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, However, this is conditional on at least one radical F containing at least one part of equation (II), -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (II) Here X is as defined above, m = 0 to 20, preferably 1 to 20. R 6 These are independently selected from divalent, optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 36 carbon atoms. R 7 It has 1 to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R 7 It cannot contain an internal carboxyl group or amide, i.e., R 7 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, in at least one part of equation (II), R 7 It has at least two, preferably at least six, carbon atoms, and in the same part of formula (II), at least one R 6 The condition is that it has at least 6, preferably at least 8, carbon atoms. or A compound comprising at least one compound of general formula (IV), R 1 (-C(O)-XG) q (IV) Here X is as defined above, R in equation (IV) 1 It preferably has up to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Selected from q-valent, optionally substituted hydrocarbon radicals, which may comprise one or more groups selected from quaternary ammonium groups and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups. q = 2 to 55, preferably 2 to 40, more preferably 2 to 4, and G may be the same or different, and may have up to 1005 carbon atoms, and may optionally contain -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, However, this is conditional on at least one radical G containing at least one part of equation (V), -R 6 (-C(O)-XR 6 ) m -C(O)-XR 11 (V) Here X is as defined above, m = 0 to 20, preferably 1 to 20. R in equation (V) 6 As defined above for equation (I), R 11 It has 1 to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] Quaternary ammonium group [ka] A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R 11 It cannot contain an internal carboxyl group or amide, i.e., R 11 It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, in at least one part of equation (V), R 11 It has at least two, preferably at least six, carbon atoms, and in the same part of formula (V), at least one R 6 The condition is that it has at least 6, preferably at least 8, carbon atoms. Hair care ingredients.

[0448] 2. In a compound of formula (I) or (IV), R 1 A hair care formulation according to Embodiment 1, having a maximum of 1000 carbon atoms, preferably a maximum of 1000, more preferably a maximum of 300, even more preferably a maximum of 100, and most preferably a maximum of 50 carbon atoms, as defined above.

[0449] 3. In a compound of formula (I) or (IV), any R of the compound 7 or R 11 A hair care formulation according to Embodiment 1 or 2, wherein the number of carbon atoms in the compound is 3 to 300, preferably 3 to 100, more preferably 3 to 50, even more preferably 3 to 36, even more preferably 3 to 24, and most preferably 11 to 24.

[0450] 4. A hair care formulation according to any one of Embodiments 1 to 3, wherein the compound of formula (I) or (IV) has a molecular weight in the range of 1,500 to 200,000 g / mol, preferably 1,500 to 100,000 g / mol, more preferably 1,500 to 30,000 g / mol, even more preferably 1,500 to 10,000 g / mol, even more preferably 1,500 to 5,000 g / mol, and most preferably 1,500 to 3,000 g / mol.

[0451] 5. A hair care formulation according to any one of Embodiments 1 to 4, wherein the compound of formula (I) comprises a portion of formula (II) from 2 to 100, more preferably a portion of formula (II) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, still more preferably 2 to 6, and most preferably 2 to 4, or the compound of formula (IV) comprises a portion of formula (V) from 2 to 100, more preferably a portion of formula (V) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, still more preferably 2 to 6, and most preferably a portion of formula (V) from 2 to 4.

[0452] 6. At least one compound of general formula (I) is represented by general formula (III), {[(FC(O)-X-) 1-5 R 3 (-XC(O)-)] 1-3 R 4 -C(O)-X-} r -R 2 (-XC(O)-F) s (III) Here, X is as defined above, R in equation (III) 2 It has up to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, [ka] and may comprise one or more groups selected from quaternary ammonium groups, and optionally substituted with one or more carboxyl or hydroxyl groups, selected from (r+s) valent, optionally substituted hydrocarbon radicals, and R 10 R 2 If the join is to base-NR, optionally, 10 - forms a bond to the nitrogen atom, R 3 It has up to 1000 carbon atoms, and -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from divalent to hexavalent, optionally substituted hydrocarbon radicals, which may optionally contain one or more groups selected from, where multiple R 3 If they exist in equation (III), they may be the same or different. R 4 It has up to 300 carbon atoms and can optionally have -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Selected from linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, which are optionally substituted with divalent to tetravalent groups and include one or more groups selected from the following: Here are multiple R 4 If they exist in equation (III), they may be the same or different. And here r+s=2, so 55. r=0 to 54, s≧1, and In equation (III), F is as defined above, provided that at least one of the radicals F contains at least one part of equation (II). -R 6 (-XC(O)-R 6 ) m -XC(O)-R 7 (II) Here X, R 6 , and R 7 This is as defined above, m = 0 to 20, preferably 1 to 20. And however, in at least one part of equation (II), R 7 It has at least two, preferably at least six, carbon atoms, and in the same part of formula (II), at least one R 6A hair care formulation according to any one of Embodiments 1 to 5, wherein the compound has at least 6, preferably at least 8, carbon atoms.

[0453] 7. R in the compound of formula (IV) 1 or R in the compound of formula (III) 2 It has 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups [ka] A hair care formulation according to any one of Embodiments 1 to 6, which is selected from optionally substituted hydrocarbon radicals, which may comprise one or more groups selected from and may optionally be substituted with a carboxyl group or a hydroxyl group.

[0454] 8. In the compound of formula (III), R 3 The hair care formulations according to Embodiments 6 and 7 are selected from divalent to tetravalent residues, specifically from divalent, trivalent, or tetravalent residues.

[0455] 9. In the compound of formula (III), R 3 It has up to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Hair care formulations according to embodiments 6 to 8, selected from optionally substituted hydrocarbon radicals, which may include one or more groups selected from the above.

[0456] 10. In compounds of formula (I), (III), or (IV), F and G have up to 200 carbon atoms, preferably 10 to 200 carbon atoms, more preferably 10 to 150, and even more preferably 10 to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] A hair care formulation according to any of the above embodiments, comprising one or more groups selected from and which may be substituted with one or more carboxyl groups, hydroxyl groups, or halide groups, optionally substituted from linear, cyclic, or branched, saturated, unsaturated, or aromatic hydrocarbon radicals.

[0457] 11. In the compound of formula (III), R 4 It has 2 to 300 carbon atoms, preferably 5 to 200 carbon atoms, more preferably 8 to 150 carbon atoms, and even more preferably 10 to 120 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [ka] Hair care formulations according to Embodiments 6 to 10, selected from linear, cyclic, or branched, saturated, unsaturated, or aromatic hydrocarbon radicals that are optionally substituted with divalent to tetravalent, preferably divalent, trivalent, or tetravalent groups, comprising one or more groups selected from the above.

[0458] 12. In the compound of formula (III), Hair care formulations according to embodiments 6 to 11, where r = 0 to 50 or 1 to 50, preferably 0 to 20, more preferably 0 to 10, even more preferably 1 to 10, specifically 1 to 5, more specifically 0, 1, 2, 3, 4, 5, and even more specifically 2.

[0459] 13. In a compound of formula (I) or (III), At least one of the radicals F is a part -R 6 (-OC(O)-R 6 ) m -OC(O)-R 7 , -R 6 (-NR 10 -C(O)-R 6 ) m -OC(O)-R 7 , -R 6 (-NR 10 -C(O)-R 6 ) m -NR 10 -C(O)-R 7 , Preferably -R 6 (-OC(O)-R 6 ) m -OC(O)-R 7 , here, R 10 , R 6 , R 7 , and m are as defined above, A hair care formulation according to any of the above embodiments, comprising at least one part selected from.

[0460] 14. In the compound of formula (IV), At least one of the radical G is at least one part -R 6 (-C(O)-OR 6 ) m -C(O)-OR 11 , -R 6 (-C(O)-NR 10 -R 6 ) m -C(O)-OR 11 , -R 6 (-C(O)-NR 10 -R 6 ) m -C(O)-NR 10 -R11 , Preferably -R 6 (-C(O)-OR 6 ) m -C(O)-OR 11 , here R 10 , R 6 , R 11 , and m are as defined above, A hair care formulation according to any one of embodiments 1-5, 7, and 10, including the following:

[0461] 15. In formula (II) or (V) of a compound according to formula (I), (III), or (IV), A hair care formulation according to any of the above embodiments, wherein m = 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6, more specifically 0 or 1.

[0462] 16. In compounds of formula (I), (III), or (IV), R 10 This is hydrogen, n-, iso-, or tert.-C1-C 22 -Alkyl, C2-C 22 -Alkoxyalkyl, C5-C 30 -Cycloalkyl, C6-C 30 -Aryl, C6-C 30 -Aryl (C1-C6)alkyl, C6-C 30 -alkylaryl, C2-C 22 -Alkenyl, C2-C 22 - Selected from the group consisting of alkenyloxyalkyls which may be optionally substituted with hydroxyl and halogen, respectively, and which may optionally contain one or more ether groups (-O-), preferably R 10 These are hydrogen or n-, iso-, and tert.-C1-C 22 - Hair care formulations according to any of the above embodiments, selected from alkyl groups.

[0463] 17. In compounds of formula (I), (III), or (IV), R6 A hair care formulation according to any of the above embodiments, which is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated radicals, having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms.

[0464] 18. In a compound of formula (I) or (III), R 7 A hair care formulation according to any of the above embodiments 1 to 13 and 15 to 17, which is independently selected from optionally substituted linear, cyclic or branched, saturated or unsaturated hydrocarbon radicals, having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms, and which may be optionally substituted with one or more groups selected from carboxyl groups, hydroxyl groups, or halide groups.

[0465] 19. In the compound of formula (IV), R 11 A hair care formulation according to any of embodiments 1 to 5, 7, 10 and 14 to 17, which is independently selected from optionally substituted linear, cyclic or branched saturated or unsaturated hydrocarbon radicals having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms.

[0466] 20. In a compound of formula (I) or (III), R 6 and R 7 R in each single part of the general formula (II) which is composed of 6 +R 7 (Σ carbon atom R 6 , R 7 A hair care formulation according to any of the above embodiments 1 to 13 and 15 to 18, wherein the total number of carbon atoms is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100.

[0467] 21. In the compound of formula (IV), R 6 and R 11 R of each single part of the general formula (V) composed of 6 +R 11 The total number of carbon atoms (Σ carbon atoms R 6 , R 11 A hair care formulation according to any of embodiments 1 to 5, 7, 10, 14 to 17 and 19, wherein the amount is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100.

[0468] 22. R of the compound of formula (IV) 1 or R of the compound of formula (III) 2 teeth, Hair care formulations according to any of the above embodiments, preferably derived from polyols, preferably from dihydroxycarboxylic acids having up to 25 carbon atoms, selected from the group consisting of 2,2'-dihydroxymethylpropanoic acid and 9,10-dihydroxystearic acid, or preferably from polyhydroxycarboxylic acids having up to 25 carbon atoms, selected from the group consisting of 3,5-dihydroxy-3-methylpentanoic acid and sugar acids such as gluconic acid, glyceric acid, xylonic acid, and ascorbic acid, which are divalent to hexavalent, preferably divalent to tetravalent, more preferably divalent to trivalent, particularly divalent, trivalent, tetravalent, pentavalent, and more preferably divalent, trivalent and tetravalent or hexavalent, optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic, preferably saturated radicals, preferably optionally substituted with hydroxyl, amino or amide.

[0469] 23. In compounds of formula (I), (III), or (IV), R 10 The hair care formulation according to any of the above embodiments, which is selected from the group consisting of hydrogen, n-, iso-, or tert.-C1-C22-alkyl, more preferably hydrogen.

[0470] 24. In compounds of formula (I), (III), or (IV), R 6 Preferably, the hair care formulation according to any of the above embodiments is derived from a monohydroxycarboxylic acid having up to 25 carbon atoms, independently selected from the group consisting of glycolic acid, lactic acid, 2-hydroxybutyric acid, 3-hydroxy-butyric acid, 4-hydroxybutyric acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, ricinoleic acid, and reskerolic acid.

[0471] 25. In compounds of formula (I) or (III), R 7 Preferably, a hair care formulation according to any one of Embodiments 1 to 13, 15 to 18, 20 and 22 to 24, derived from a carboxylic acid having up to 25 carbon atoms without hydroxyl substituents, independently selected from the group consisting of acetic acid, propanoic acid, butanoic acid, pentadecanoic acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, nonadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, 2,2-dimethylheptanoic acid, 2,2-dimethyloctanoic acid, neodecanoic acid, undecyl-10-enoic acid, oleic acid, linoleic acid, linolenic acid, and erucic acid.

[0472] 26. In the compound of formula (IV), R 11Preferably, methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols formally containing 4 to 6 glycerol units, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride) Hair care formulations according to any of Embodiments 1 to 5, 7, 10, 14 to 17, 19, 21 to 24, derived from linear or branched carboxylic acids or linear or branched alcohols having up to 26 carbon atoms, selected from the group consisting of cerides, pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide and / or butylene oxide-based polyethers, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, and 1,6-hexanediol.

[0473] 27. In compounds of formula (I) or (III), the R of the general formula (II) 6 and R 7 A hair care formulation according to any one of embodiments 1 to 13, 15 to 18, 20 and 22 to 25, wherein at least one, preferably both, of the hair care formulations are derived from an unsaturated carboxylic acid.

[0474] 28. R of the compound of formula (IV) 1 or R of the compound of formula (III) 2 teeth, -Residues derived from polyols, preferably 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols, for example, oligoglycerols formally containing 4 to 6 glycerol units, trimethylolpropane, pentaerythritol, and sorbitol. -Polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or butylene oxide-based polyethers, in particular derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, or polypropylene glycol, e.g., dipropylene glycol (e.g., derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, derived from mixed ethylene oxide and butylene oxide-based copolyethers, derived from mixed propylene oxide and butylene oxide-based copolyethers, and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers, residues derived from oligomers or polymer polyols, e.g., hydroxy-functional polyacrylates, hydroxy-functional polyesters, hydroxy-functional polyurethanes, - A residue derived from a dihydroxycarboxylic acid, preferably a residue derived from the group consisting of 2,2'-dihydroxymethylpropanoic acid and 9,10-dihydroxystearic acid, - Preferably, a residue derived from a polyhydroxycarboxylic acid having up to 25 carbon atoms, selected from the group consisting of 3,5-dihydroxy-3-methylpentanoic acid and sugar acids, such as gluconic acid, glyceric acid, xylonic acid, and ascorbic acid. - Residues derived from epoxy compounds, preferably ether epoxy compounds having a total of at least one, preferably two or more carbon atoms, preferably selected from ethylene oxide, propylene oxide, butylene oxide, and glycidyl ether, for example, prepared from the reaction of epichlorohydrin with alcohol, for example methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-Propanediol, 1,3-Butanediol, 1,4-Butanediol, 1,2-Hexanediol, 1,6-Hexanediol, Glycerol, Diglycerol, Triglycerol, and Linear or Branched Oligoglycerols, in particular, formally comprising 4 to 6 glycerol units, Trimethylolpropane, Castor Oil (Ricinoleic Acid Triglyceride), Reskerella Oil (Reskerolic Acid Triglyceride), Pentaerythritol, Sorbitol, Polyalkylene Oxides, e.g., Ethylene Oxide, Propylene Oxide, and / or The residues are derived from butylene oxide-based polyethers, particularly polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, or polypropylene glycol, e.g., dipropylene glycol (especially derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, mixed ethylene oxide and butylene oxide-based copolyethers, mixed propylene oxide and butylene oxide-based copolyethers, and mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers, or preferably glycidyl ethers, and residues derived from acids, particularly neodecanoic acid, oligomers or polymer polyols, e.g., hydroxy-functional polyacrylates, hydroxy-functional polyesters, hydroxy-functional polyurethanes. - Ester compounds obtained from the reaction of polyols or epoxides with hydroxycarboxylic acids, ester compounds obtained from the reaction of alcohols, In particular, alcohols are selected from 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), skellerella oil, pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or butylene oxide-based polyethers, and especially polyethylene glycol, e.g., diethylene glycol, triethylene glycol Derived from cellulose, tetraethylene glycol, and pentaethylene glycol, or polypropylene glycol, for example, dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, derived from mixed ethylene oxide and butylene oxide-based copolyethers, derived from mixed propylene oxide and butylene oxide-based copolyethers, and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers, or epoxy compounds, particularly selected from ethylene oxide, propylene oxide, butylene oxide, and glycidyl ether, and alcohols, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or butylene oxide Hoxide-based polyethers, particularly those derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, or polypropylene glycol, e.g., dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, derived from mixed ethylene oxide and butylene oxide-based copolyethers, derived from mixed propylene oxide and butylene oxide-based copolyethers, and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers, or preferably glycidyl esters. Hydroxyl-functionalized carboxylic acids, particularly those derived from lactic acid, 4-hydroxybutanoic acid, ricinoleic acid, reskerolic acid, 2,2-bis(hydroxymethyl)propionic acid, malic acid, tartaric acid, and gluconic acid, and especially preferably residues of glycerol esterified with ricinoleic acid, i.e., castor oil, and reskerolic acid, i.e., reskerella oil. - Residues derived from ester compounds obtained from the reaction of an alcohol or epoxide with a hydroxyl-free carboxylic acid, For example, divalent to hexavalent, preferably divalent to tetravalent, more preferably divalent to trivalent, and even more preferably divalent, trivalent and tetravalent, optionally amino or amide-substituted linear, cyclic or branched, saturated, unsaturated or aromatic radicals, derived from the reaction of alcohols, i.e., 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), skellerella oil, pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or butylene oxide-based polyethyl In particular, derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or derived from polypropylene glycol, e.g., dipropylene glycol (especially derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from mixed ethylene oxide and butylene oxide-based copolyethers; derived from mixed propylene oxide and butylene oxide-based copolyethers; or derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers. Epoxy compounds, particularly ethylene oxide, propylene oxide, butylene oxide, glycidyl ethers, which are alcoholic, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or Butylene oxide-based polyethers, particularly those derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or polypropylene glycol, e.g., dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from mixed ethylene oxide and butylene oxide-based copolyethers; derived from mixed propylene oxide and butylene oxide-based copolyethers; or derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers. Preferably a glycidyl ester, Residues derived from acids, especially neodecanoic acid; carboxylic acids, especially acetic acid, propionic acid, butyric acid, dodecanoic acid, stearic acid, oleic acid, oxalic acid, malonic acid, succinic acid, maleic acid, itaconic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, and dimer fatty acids, preferably residues derived from the reaction of anhydrides or acid chlorides with alcohols. - Monocarboxylic acids o...

Claims

1. A hair care formulation comprising at least one compound of formula (I), R １ (-X-C(O)-F) ｐ (I) Here R in equation (I) １ It is selected from p-valent, optionally substituted hydrocarbon radicals, optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, 【Chemistry 1】 and may comprise one or more groups selected from quaternary ammonium groups, and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups. p ≥ 2, more preferably 2 - 8¹¹, X may be the same or different, and -O- or -NR １０ - is selected, and here R １０ It has hydrogen, or up to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. 【Chemistry 2】 Selected from the group consisting of linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals that are optionally substituted with one or more groups selected from the group, Alternatively, in equation (I), R １０ is R １ It can form bonds to form a ring structure, F may be the same or different, and may have a maximum of 1005 carbon atoms, and may optionally be -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Transformation 3】 Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and optionally substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, However, this is conditional on at least one radical F containing at least one part of formula (II) or formula (II*),  ６ (. ６ ) ｍ ︁!() ７ (=)  ６ (. ６ ) ｍ ︁!() ７＊ (=)) Here X is as defined above, m = 0 to 20, preferably 1 to 20. R ６ These are independently selected from divalent, optionally substituted, linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 36 carbon atoms. R ７ It has 1 to 1000 carbon atoms, and optionally has -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Chemistry 4】 Quaternary ammonium group 【Transformation 5】 A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R ７ It cannot contain an internal carboxyl group or amide; that is, R7 cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, in at least one part of equation (II), R ７ It has at least two, preferably at least six, carbon atoms, and in the same portion of formula (II), at least one R ６ The condition is that it has at least six, preferably at least eight, carbon atoms. R ７＊ It has 1 to 1000 carbon atoms, and optionally has -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Transformation 6】 Quaternary ammonium group 【Transformation 7】 A radical R is independently selected from optionally substituted branched or dendrimer hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R ７＊ It is terminated by two or more of the following general structures: -X-C(O)-T Here, X is as defined above, and T is a monovalent, linear, cyclic, or branched, saturated or unsaturated hydrocarbon radical having up to 36 carbon atoms and optionally substituted with a carboxyl group, a hydroxyl group, or a halide group. However, in at least one part of equation (II*), R ７＊ It is terminated by one or more groups T having at least two, preferably at least six, carbon atoms, and in the same portion of formula (II*), at least one R ６ The condition is that it has at least 6, preferably at least 8, carbon atoms. or, A compound comprising at least one compound of general formula (IV), R １ (-C(O)-E-G) ｑ (IV) Here X is as defined above, R in equation (IV) １ Preferably having up to 1000 carbon atoms, optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, 【Transformation 8】 Selected from q-valent, optionally substituted hydrocarbon radicals, which may comprise one or more groups selected from quaternary ammonium groups and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups. q = 2 to 55, preferably 2 to 40, more preferably 2 to 4, and G may be the same or different, and may have a maximum of 1005 carbon atoms, and may optionally contain -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 9】 Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, However, this is conditional on at least one radical G containing at least one part of formula (V), -R ６ (-C(O)-X-R ６ ) ｍ -C(O)-X-R １１ (V) Here X is as defined above, m = 0 to 20, preferably 1 to 20. R in equation (V) ６ As defined above for equation (I), R １１ It has 1 to 1000 carbon atoms, and optionally has -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Chemistry 10】 Quaternary ammonium group 【Chemistry 11】 A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R １１ It cannot contain internal carboxyl groups or amides; that is, R11 cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, in at least one part of equation (V), R １１ It has at least two, preferably at least six, carbon atoms, and in the same portion of formula (V), at least one R ６ The condition is that it has at least six, preferably at least eight, carbon atoms. However, the compound of formula (I) does not consist solely of glycerol and ricinoleic acid moieties, i.e., polyglycerol polyricinolate (PGPR). Hair care ingredients.

2. In a compound of formula (I) or (IV), R １ The hair care compound according to claim 1, wherein the carbon atom has a maximum of 10,000 carbon atoms, preferably a maximum of 1,000, more preferably a maximum of 300, even more preferably a maximum of 100, and most preferably a maximum of 50 carbon atoms, as defined above.

3. In a compound of formula (I) or (IV), any R of the compound ７ or R １１ The hair care formulation according to claim 1 or 2, wherein the number of carbon atoms in the formulation is 3 to 300, preferably 3 to 100, more preferably 3 to 50, even more preferably 3 to 36, even more preferably 3 to 24, and most preferably 11 to 24.

4. The hair care formulation according to any one of claims 1 to 3, wherein the compound of formula (I) or (IV) has a molecular weight in the range of 1,500 to 200,000 g / mol, preferably 1,500 to 100,000 g / mol, more preferably 1,500 to 30,000 g / mol, even more preferably 1,500 to 1,000 g / mol, even more preferably 1,500 to 5,000 g / mol, and most preferably 1,500 to 3,000 g / mol.

5. The hair care formulation according to any one of claims 1 to 4, wherein the compound of formula (I) comprises a portion of formula (II) from 2 to 100, more preferably a portion of formula (II) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, and most preferably 2 to 4 of formula (II); or wherein the compound of formula (IV) comprises a portion of formula (V) from 2 to 100, more preferably a portion of formula (V) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, and most preferably 2 to 4 of formula (V); or wherein the compound of formula (I) comprises a portion of formula (II*) from 2 to 100, more preferably a portion of formula (II*) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, and most preferably 2 to 4 of formula (II*).

6. At least one compound of general formula (I) is represented by general formula (III), {[(F-C(O)-X-) １－５ R ３ (-X-C(O)-)] １－３ R ４ -C(O)-X-} ｒ -R ２ (-X-C(O)-F) ｓ (III) Here, X is as defined above, R in equation (III) ２ It has up to 1000 carbon atoms, and optionally includes -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 12】 and may comprise one or more groups selected from quaternary ammonium groups, and may optionally be substituted with one or more carboxyl or hydroxyl groups, selected from (r+s) valent, optionally substituted hydrocarbon radicals, and R １０ R ２ If the combination is to, then optionally base-NR １０ - Forms a bond to the nitrogen atom, R ３ It has up to 1000 carbon atoms and can optionally have -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 13】 Selected from optionally substituted, divalent to hexavalent hydrocarbon radicals, which may contain one or more groups selected from: Here, multiple R ３ If they exist in equation (III), they may be the same or different. R ４ It has up to 300 carbon atoms and can optionally have -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 14】 Selected from linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, which are optionally substituted with divalent to tetravalent groups and include one or more groups selected from the following: Here, multiple R ４ If they exist in equation (III), they may be the same or different. And here r + s = 2, so 55. r = 0 to 54, s ≥ 1, and In formula (III), F is as defined above, provided that at least one of the radicals F includes at least one part of formula (II) or formula (II*),  ６ (. ６ ) ｍ ︁!() ７ (=)  ６ (. ６ ) ｍ ︁!() ７＊ (=)) Here X, R ６ , R ７ , and R ７＊ This is as defined in the previous section, m = 0 to 20, preferably 1 to 20. And however, in at least one part of equation (II), R ７ It has at least two, preferably at least six, carbon atoms, and in the same portion of formula (II), at least one R ６ It has at least six, preferably at least eight, carbon atoms, or in at least one part of formula (II*), R ７＊ It is terminated by one or more groups T having at least two, preferably at least six, carbon atoms, and in the same portion of formula (II*), at least one R ６ The hair care formulation according to any one of claims 1 to 5, wherein the compound has at least six, preferably at least eight, carbon atoms.

7. R in the compound of formula (IV) １ or R in the compound of formula (III) ２ It has 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups 【Chemistry 15】 A hair care formulation according to any one of claims 1 to 6, which may comprise one or more groups selected from and optionally substituted with a carboxyl group or a hydroxyl group.

8. In the compound of formula (III), R ３ The hair care formulation according to claims 6 and 7, wherein the residue is selected from divalent to tetravalent residues, specifically from divalent residues, trivalent residues, or tetravalent residues.

9. In the compound of formula (III), R ３ It has a maximum of 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 16】 A hair care formulation according to claims 6 to 8, selected from optionally substituted hydrocarbon radicals, which may include one or more groups selected from the above.

10. In compounds of formula (I), (III), or (IV), F and G have up to 200 carbon atoms, preferably 10 to 200 carbon atoms, more preferably 10 to 150, and even more preferably 10 to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 17】 A hair care formulation according to any of the preceding claims, comprising one or more groups selected from and optionally substituted with one or more carboxyl groups, hydroxyl groups or halide groups, selected from optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals.

11. In the compound of formula (III), R ４ It has 2 to 300 carbon atoms, preferably 5 to 200 carbon atoms, more preferably 8 to 150 carbon atoms, and even more preferably 10 to 120 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. [Chemistry 18] A hair care formulation according to claims 6 to 10, selected from linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals that are optionally substituted with divalent to tetravalent, preferably divalent, trivalent, or tetravalent groups, comprising one or more groups selected from the above.

12. In the compound of formula (III), The hair care formulation according to claims 6 to 11, wherein r = 0 to 50 or 1 to 50, preferably 0 to 20, more preferably 0 to 10, even more preferably 1 to 10, specifically 1 to 5, more specifically 0, 1, 2, 3, 4, 5, and even more specifically 2.

13. In a compound of formula (I) or (III), At least one of the radicals F is a part -R ６ (-O-C(O)-R ６ ) ｍ -O-C(O)-R ７ 、 -R ６ (-NR １０ -C(O)-R ６ ) ｍ -O-C(O)-R ７ 、 -R ６ (-NR １０ -C(O)-R ６ ) ｍ -NR １０ -C(O)-R ７ 、 Preferably, -R ６ (-O-C(O)-R ６ ) ｍ -O-C(O)-R ７ , where R １０ , R<, where R ６ , R ７ and m are as defined above. It includes at least one part selected from, Alternatively, in the compound of formula (I) or (III), At least one of the radicals F is a part -R ６ (-O-C(O)-R ６ ) ｍ -O-C(O)-R ７＊ 、 -R ６ (-NR １０ -C(O)-R ６ ) ｍ -O-C(O)-R ７＊ 、 -R ６ (-NR １０ -C(O)-R ６ ) ｍ -NR １０ -C(O)-R ７＊ 、 Preferably -R ６ (-OC(O)-R ６ ) ｍ -O-C(O)-R ７＊ Here, R １０ , R ６ , R ７＊ , and m are as defined above, A hair care formulation according to any of the preceding claims, comprising at least one portion selected from the above.

14. In the compound of formula (IV), At least one of the radical Gs is a part -R ６ (-C(O)-O-R ６ ) ｍ -C(O)-O-R １１ 、 -R ６ (-C(O)-NR １０ -R ６ ) ｍ -C(O)-O-R １１ 、 -R ６ (-C(O)-NR １０ -R ６ ) ｍ -C(O)-NR １０ -R １１ 、 Preferably, -R ６ (-C(O)-OR ６ ) ｍ -C(O)-O-R １１ Here, R １０ , R ６ , R １１ , and m are as defined above, A hair care formulation according to any one of claims 1 to 5, 7, and 10, comprising at least one of the following.

15. In the compound (II), (V), or (II*) of the compound (I), (III), or (IV), A hair care formulation according to any of the above claims, wherein m = 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6, more specifically 0 or 1.

16. In compounds of formula (I), (III), or (IV), R １０ is hydrogen, n-, iso-, or tert.-C １ -C ２２ - Alkyl, C ２ -C ２２ - Alkoxyalkyl, C ５ -C ３０ - Cycloalkyl, C ６ -C ３０ - Aryl, C ６ -C ３０ -Aryl (C) １ -C ６ ) Alkyl, C ６ -C ３０ - Alkylaryl, C ２ -C ２２ - Alkenil, C ２ -C ２２ - Selected from the group consisting of alkenyloxyalkyl groups which may optionally be substituted with hydroxyl and halogen, respectively, and which may optionally contain one or more ether groups (-O-), preferably R １０ This is hydrogen or n-, iso-, and tert.-C １ -C ２２ - A hair care formulation according to any of the above claims, selected from alkyl groups.

17. In compounds of formula (I), (III), or (IV), R ６ The hair care formulation according to any of the above claims, which is independently selected from optionally substituted linear, cyclic or branched saturated or unsaturated radicals having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms.

18. In a compound of formula (I) or (III), R ７ The hair care formulation according to any one of claims 1 to 13 and 15 to 17, wherein the optionally substituted linear, cyclic or branched, saturated or unsaturated hydrocarbon radicals are independently selected from the optionally substituted linear, cyclic or branched, saturated or unsaturated hydrocarbon radicals, having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms, and may optionally be substituted with one or more groups selected from carboxyl groups, hydroxyl groups or halide groups.

19. In the compound of formula (IV), R １１ The hair care formulation according to any one of claims 1 to 5, 7, 10 and 14 to 17, wherein the hair care formulation is independently selected from optionally substituted linear, cyclic or branched saturated or unsaturated hydrocarbon radicals having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms.

20. In a compound of formula (I) or (III), R ６ and R ７ R in each single part of the general formula (II) which is composed of ６ +R ７ The total number of carbon atoms (Σ carbon atoms R) ６ , R ７ ) is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100. Alternatively, in the compound of formula (I) or (III), R ６ and R ７＊ R in each single part of the general formula (II*) composed of ６ +R ７＊ The total number of carbon atoms (Σ carbon atoms R) ６ , R ７＊ ) is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100. A hair care formulation according to any one of the above-mentioned claims 1 to 13 and 15 to 18.

21. In the compound of formula (IV), R ６ and R １１ R in each single part of the general formula (V) which is composed of ６ +R １１ The total number of carbon atoms (Σ carbon atoms R) ６ , R １１ The hair care formulation according to any one of claims 1 to 5, 7, 10, 14 to 17, and 19, wherein the amount of ) is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100.

22. R of the compound of formula (IV) １ or R of the compound of formula (III) ２ The hair care formulation according to any of the above claims is preferably derived from a polyol, preferably from a dihydroxycarboxylic acid having up to 25 carbon atoms, selected from the group consisting of 2,2'-dihydroxymethylpropanoic acid and 9,10-dihydroxystearic acid, or preferably from a polyhydroxycarboxylic acid having up to 25 carbon atoms, selected from the group consisting of 3,5-dihydroxy-3-methylpentanoic acid and sugar acids such as gluconic acid, glyceric acid, xylonic acid, and ascorbic acid, which is a hydrocarbon radical substituted with divalent to hexavalent, preferably divalent to tetravalent, more preferably divalent to trivalent, particularly divalent, trivalent, tetravalent, pentavalent, and more preferably divalent, trivalent and tetravalent or hexavalent, optionally substituted with hydroxyl, amino or amide, which is a linear, cyclic or branched, saturated, unsaturated or aromatic, preferably saturated radical.

23. In compounds of formula (I), (III), or (IV), R １０ The hair care formulation according to any of the above claims, wherein is selected from the group consisting of hydrogen, n-, iso-, or tert.-C1-C22-alkyl, more preferably hydrogen.

24. In compounds of formula (I), (III), or (IV), R ６ The hair care formulation according to any of the above claims, preferably derived from a monohydroxycarboxylic acid having up to 25 carbon atoms, independently selected from the group consisting of glycolic acid, lactic acid, 2-hydroxybutyric acid, 3-hydroxy-butyric acid, 4-hydroxybutyric acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, ricinoleic acid, and reskerolic acid.

25. In a compound of formula (I) or (III), R ７ The hair care formulation according to any one of claims 1 to 13, 15 to 18, 20 and 22 to 24, preferably derived from a carboxylic acid having up to 25 carbon atoms and no hydroxyl substituents, independently selected from the group consisting of acetic acid, propanoic acid, butanoic acid, pentanoic acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, nonadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, 2,2-dimethylheptanoic acid, 2,2-dimethyloctanoic acid, neodecanoic acid, undecyl-10-enoic acid, oleic acid, linoleic acid, linolenic acid, and erucic acid.

26. In the compound of formula (IV), R １１ Preferably, methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undec-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols formally containing 4 to 6 glycerol units, trimethylolpropane, castor oil (ricinoleic acid triglyceride), rescherella oil (reskerolic acid triglyceride) A hair care formulation according to any one of claims 1 to 5, 7, 10, 14 to 17, 19, 21 to 24, derived from a linear or branched carboxylic acid or a linear or branched alcohol having up to 26 carbon atoms, independently selected from the group consisting of cerides, pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide and / or butylene oxide-based polyethers, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, and 1,6-hexanediol.

27. In compounds of formula (I) or (III), the R of the general formula (II) ６ and R ７ A hair care formulation according to any one of claims 1 to 13, 15 to 18, 20 and 22 to 25, wherein at least one, preferably both, of are derived from an unsaturated carboxylic acid.

28. R in the compound of formula (IV) １ or R in the compound of formula (III) ２ teeth, - Residues derived from polyols, preferably 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols, for example oligoglycerols formally containing 4 to 6 glycerol units, trimethylolpropane, pentaerythritol, and sorbitol. - Residues derived from polyalkylene oxides, e.g., ethylene oxide, propylene oxide and / or butylene oxide-based polyethers, in particular from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol and pentaethylene glycol, or polypropylene glycol, e.g., dipropylene glycol (e.g., 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol and pentapropylene glycol, derived from mixed ethylene oxide and butylene oxide-based copolyethers, derived from mixed propylene oxide and butylene oxide-based copolyethers, and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers, oligomers or polymer polyols, e.g., hydroxy-functional polyacrylates, hydroxy-functional polyesters, hydroxy-functional polyurethanes, - Residues derived from dihydroxycarboxylic acids, preferably residues derived from the group consisting of 2,2'-dihydroxymethylpropanoic acid and 9,10-dihydroxystearic acid, - Preferably, 3,5-dihydroxy-3-methylpentanoic acid and residues derived from polyhydroxycarboxylic acids having up to 25 carbon atoms, selected from the group consisting of sugar acids, such as gluconic acid, glyceric acid, xylonic acid, and ascorbic acid. - Residues derived from epoxy compounds, preferably ether epoxy compounds, having a total of more than one, preferably more than two, carbon atoms, preferably selected from ethylene oxide, propylene oxide, butylene oxide, and glycidyl ether, for example, prepared from the reaction of epichlorohydrin with alcohol, for example methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undeca-10-enol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3- Propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols, in particular formally comprising 4 to 6 glycerol units, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or glycerols. A ethylene oxide-based polyether, particularly derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or derived from polypropylene glycol, e.g., dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from a mixed ethylene oxide and butylene oxide-based copolyether; derived from a mixed propylene oxide and butylene oxide-based copolyether; or preferably a glycidyl ester, and residues derived from an acid, particularly neodecanoic acid, oligomer or polymer polyol, e.g., hydroxy-functional polyacrylate, hydroxy-functional polyester, hydroxy-functional polyurethane. - Ester compounds obtained from the reaction of polyols or epoxides with hydroxycarboxylic acids, ester compounds obtained from the reaction of alcohols, In particular, alcohols are selected from 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and linear or branched oligoglycerols such as those formally containing 4 to 6 glycerol units, trimethylolpropane, castor oil (ricinoleic acid triglyceride), skellerella oil, pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or butylene oxide-based polyethers, and especially polyethylene glycol, e.g., diethylene glycol, triethylene glycol Derived from polypropylene glycol, tetraethylene glycol, and pentaethylene glycol, or polypropylene glycol, for example, dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, derived from mixed ethylene oxide and butylene oxide-based copolyethers, derived from mixed propylene oxide and butylene oxide-based copolyethers, and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers. or epoxy compounds, particularly selected from ethylene oxide, propylene oxide, butylene oxide, and glycidyl ether, and alcohols, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undec-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or butylene oxide Hoxide-based polyethers, particularly those derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or polypropylene glycol, e.g., dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from mixed ethylene oxide and butylene oxide-based copolyethers; derived from mixed propylene oxide and butylene oxide-based copolyethers; and derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers; or preferably glycidyl esters. Hydroxyl-functionalized carboxylic acids, particularly those derived from lactic acid, 4-hydroxybutanoic acid, ricinoleic acid, reskerolic acid, 2,2-bis(hydroxymethyl)propionic acid, malic acid, tartaric acid, and gluconic acid, especially preferred are residues of glycerol derived from esters of ricinoleic acid, i.e., castor oil, and reskerolic acid, i.e., reskerella oil. - Ester compounds obtained from the reaction of an alcohol or epoxide with a hydroxyl-free carboxylic acid, For example, divalent to hexavalent, preferably divalent to tetravalent, more preferably divalent to trivalent, and even more preferably divalent, trivalent, and tetravalent, optionally amino or amide-substituted linear, cyclic, or branched saturated, unsaturated, or aromatic radicals, derived from the reaction of alcohols, i.e., 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), resquerella oil, pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or butylene oxide-based polyethers. Polypropylene glycol, particularly derived from polyethylene glycol, such as diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol, or derived from polypropylene glycol, such as dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol, derived from mixed ethylene oxide and butylene oxide-based copolyethers, derived from mixed propylene oxide and butylene oxide-based copolyethers, or derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers. Epoxy compounds, particularly ethylene oxide, propylene oxide, butylene oxide, glycidyl ethers, which are alcoholic, particularly methanol, ethanol, 2-propanol, 1-butanol, t-butanol, undec-10-en-ol, oleyl alcohol, stearyl alcohol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, 1,2-hexanediol, 1,6-hexanediol, glycerol, diglycerol, triglycerol, and higher-order linear or branched oligoglycerols, trimethylolpropane, castor oil (ricinoleic acid triglyceride), reskerella oil (reskerolic acid triglyceride), pentaerythritol, sorbitol, polyalkylene oxides, e.g., ethylene oxide, propylene oxide, and / or Butylene oxide-based polyethers, particularly those derived from polyethylene glycol, e.g., diethylene glycol, triethylene glycol, tetraethylene glycol, and pentaethylene glycol; or polypropylene glycol, e.g., dipropylene glycol (particularly derived from 2,2'-oxydi-1-propanol, 1,1'-oxydi-2-propanol, and 2-(2-hydroxypropoxy)-1-propanol), tripropylene glycol, tetrapropylene glycol, pentapropylene glycol; derived from mixed ethylene oxide and butylene oxide-based copolyethers; derived from mixed propylene oxide and butylene oxide-based copolyethers; or derived from mixed ethylene oxide and propylene oxide and butylene oxide-based copolyethers. Preferably a glycidyl ester, Residues derived from acids, especially neodecanoic acid; carboxylic acids, especially acetic acid, propionic acid, butyric acid, dodecanoic acid, stearic acid, oleic acid, oxalic acid, malonic acid, succinic acid, maleic acid, itaconic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, and dimer fatty acids, preferably residues derived from the reaction of anhydrides or acid chlorides with alcohols. - Monocarboxylic acids or polycarboxylic acids as described above, for example succinic acid, maleic acid, itaconic acid, phthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, dimer fatty acids, preferably their anhydrides or acid chlorides, and residues derived from polyacrylic acid, A hair care formulation according to any of the above claims, selected from the group consisting of the above.

29. R in at least one compound of formula (III) ２ and R ３ At least one of the or R in a compound of formula (IV) １ This is a divalent hydrocarbon radical derived from a polyalkylene oxy group as described above in the general formula below, -[CH ２ CH ２ O] ｑ１ -[CH ２ CH(CH ３ )O] ｒ１ -[CH ２ CH(C) ２ H ５ )O] ｓ１ -{[CH ２ CH ２ ] ｑ２ -[CH ２ CH(CH ３ )] ｒ２ -[CH ２ CH(C) ２ H ５ )] ｓ２ }- Here q1 = 0 to 49, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, r1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5. s1 = 0 to 24, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, q2 = 0 or 1, r² = 0 or 1, s² = 0 or 1, and Σ(q2+r2+s2)=1, However, the total number of carbon atoms in such polyalkylene oxide groups is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15. A hair care formulation according to any of the above claims.

30. R in the compound of formula (III) ２ and R ３ At least one of the or R in a compound of formula (IV) １ This is a divalent hydrocarbon radical derived from oligoglycerol of the following general formula, -[CH ２ CH(R ８ )CH ２ O] ｔ１ -[CH ２ CH(R ８ )CH ２ )] ｔ２ - Here t1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, specifically 1 and 2. t2 = 1, R ８ =OH or -O-C(O)-R ６ -N ＋ (R １０ ) ３ Here, R １０ and R ６ This is as defined above, However, R ８ The total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15. A hair care formulation according to any of the above claims.

31. R in the compound of formula (III) ２ and R ３ At least one of the or R in a compound of formula (IV) １ This is a divalent hydrocarbon radical containing at least one ester group of the following general formula, -[CH ２ CH ２ O] ｑ１ -R ９ -[CH ２ CH ２ O] ｑ１ -[CH ２ CH ２ ] ｑ２ - Here q1 may be the same or different, and is as defined above, and q2 = 1, and -[CH ２ CH(R ８ )CH ２ O] ｔ１ -R ９ -[CH ２ CH(R ８ )CH ２ O] ｔ１ -[CH ２ CH(R ８ )CH ２ )] ｔ２ - Here t1 = 0 to 32, preferably 0 to 10, more preferably 1 to 10, even more preferably 1 to 5, specifically 1 and 2. t2 = 1, R ８ =OH or -O-C(O)-R ６ -N ＋ (R １０ ) ３ Here, R １０ and R ６ This is as defined above, However, R ８ The total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15. R ６ is -C(O)C(O)O-, -C(O)(CH ２ ) １－８ C(O)O-, for example derived from succinic acid, adipic acid, sebacic acid, or -C(O)(C ６ H ４ )C(O)O-, that is, derived from phthalic acid and terephthalic acid, -C(O)CH=CHC(O)O-, -C(O)C(=CH ２ ) - CH ２ Selected from C(O)O- and -C(O)CH(OH)CH(OH)C(O)O-, However, R ９ The total number of carbon atoms is 2 to 100, preferably 2 to 50, more preferably 2 to 30, even more preferably 2 to 20, specifically 2 to 15. A hair care formulation according to any of the above claims.

32. R in the compound of formula (III) ２ , or R in a compound of formula (IV) １ is a hydrocarbon residue that does not contain a heteroatom or contains one or more -O- groups, preferably 1 to 5 -O- groups, where the -O- group is preferably an ether group, but can also form an ester group with a carbonyl group, and where the group R ２ The hair care formulation according to any of the above claims, wherein the hydroxyl group may be optionally substituted with one or more hydroxyl groups, but is preferably not substituted with hydroxyl groups.

33. In a compound of formula (I) or (III), In one or more bases F of at least one part of the following formula,  ６ (. ６ ) ｍ ︁!() ７ (=) X and m are as defined above, R ６ These are independently derived from lactic acid, ricinoleic acid, reskerolic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, and 14-hydroxytetradecanoic acid, and R ７ It is derived from octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, neodecanoic acid, or oleic acid. A hair care formulation according to any one of claims 1 to 13, 15 to 18, 20, 22 to 25, and 27 to 32.

34. In compounds of formula (I), (III), or (IV), R １０ Preferably, hydrogen, or R which forms a cyclic structure as shown in the schematic formula below. １ or R ２ Selected from groups consisting of bonds to, 【Chemistry 19】 A hair care formulation according to any of the above claims.

35. In a compound of formula (I) or (III), Base F includes at least one part of formula (II),  ６ (. ６ ) ｍ ︁!() ７ (=) Here R ６ , R ７ X and m are as defined above, and each part of equation (II) is at least two different bases R ６ This includes, where the base R ６ They are arranged either randomly or in a block pattern, or here, Base F includes at least one part of formula (II*),  ６ (. ６ ) ｍ ︁!() ７＊ (=)) Here R ６ , R ７＊ X and m are as defined above, and each part of equation (II*) is at least two different bases R ６ This includes, where the base R ６ They are arranged either randomly or in blocks. A hair care formulation according to any one of claims 1 to 13, 15 to 18, 20, 22 to 25, and 27 to 34.

36. In a compound of formula (I) or (III), Base F includes at least one part of formula (VI), -R ６ (-E-C(O)-R ６１ ) ｍ１ (-E-C(O)-R ６２ ) ｍ２ -X-C(O)-R ７ (V) Here, R in equation (VI) ６ R ６１ and R ６２ Selected from, X and R ７ As defined above, and R ６１ and R ６２ These are the two different bases R defined above. ６ This represents, And here m1 = 0 to 20, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, or 6. m² = 0 to 20, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, or 6. m = m1 + m2, = 0 to 20, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, or 6. A hair care formulation according to any one of claims 1 to 13, 15 to 18, 20, 22 to 25, and 27 to 35.

37. In a compound of formula (I) or (III), Base F includes at least one part of formula (VI), -R ６ (-E-C(O)-R ６１ ) ｍ１ (-E-C(O)-R ６２ ) ｍ２ -X-C(O)-R ７ (V) Here, X, m1, and m2 are as defined above, and R ６ , R ６１ , R ６２ , and R ７ This is defined in the table below: Table 1 A hair care formulation according to any one of claims 1 to 13, 15 to 18, 20, 22 to 25, and 27 to 36.

38. In a compound of formula (I) or (III), Base F includes at least one part of formula (VI), -R ６ (-E-C(O)-R ６１ ) ｍ１ (-E-C(O)-R ６２ ) ｍ２ -X-C(O)-R ７ (V) Here, X, m1, m2, R ６ , R ６１ , R ６２ , and R ７ These are as defined above, R per base F ６ , R ６１ , R ６２ and R ７ The total number of carbon atoms (Σ carbon atoms R) ６ , R ６１ , R ６２ and R ７ ) is about 19 to 300, preferably 25 to 300, more preferably 30 to 300, specifically 30 to 200, and more specifically 30 to 150. A hair care formulation according to any one of claims 1 to 13, 15 to 18, 20, 22 to 25, and 27 to 37.

39. In compounds of formula (I), (III), or (IV), R ６ These are independently derived from mono- or poly-(e.g., di-, tri-, tetra-)hydroxycarboxylic acids selected from the group consisting of lactic acid, ricinoleic acid, reskerolic acid, 10-hydroxystearic acid, and 12-hydroxystearic acid, 14-hydroxytetradecanoic acid, 2,2'-di-hydroxymethylpropanoic acid, and 9,10-dihydroxystearic acid, and gluconic acid, preferably at least one or all R ６ The hair care formulation according to any of the above claims, wherein the hair care formulation is derived from ricinoleic acid or reskerolic acid.

40. In a compound of formula (I) or (III), R ７ These are independently derived from octadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, neodecanoic acid, and oleic acid, preferably at least one or all of R ７ It is derived from oleic acid. A hair care formulation according to any one of claims 1 to 13, 15 to 18, 20, 22 to 25, and 27 to 39.

41. In compounds of formula (I), (III), or (IV), the low-melting point and high-melting point fatty acids ≥ C5 are R of general formula (II). ６ and R ７ Containing ester elements, and R of general formula (V) ６ and R １１ Within the contained ester elements, -R ６ (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (II) and -R ６ (-C(O)-X-R ６ ) ｍ -C(O)-X-R １１ (V)、 Part in particular - O - C ( O) - R ６ -(O-C(O)-R ６ ) ｍ - O - C ( O) - R ７ および -NR １０ -C(O)-R ６ -(O-C(O)-R ６ ) ｍ -O-C(O)-R ７ 、 It is specifically located in Here, X, R ６ , and R ７ and R １０ This is as defined above, And here One or more portions of formula (II) have at least one, preferably more than one, more preferably one, two, or three, five or more carbon atoms and a melting point of 40°C or lower, each having a group R ６ The low-melting-point fatty acids that form are R ７ One or more radicals R adjacent to it ６ The high-melting-point fatty acids that are contained in and have five or more carbon atoms, preferably more than one, more preferably one, two or three, and a melting point above 40°C, are R of formula (II). ６ - and R ７ - One or more radicals R at the opposite end of the contained ester element ６ Forms, or in one or more parts of formula (II), at least one, preferably more than one, more preferably one, two or three, each R ６ The high melting point fatty acids ≥ C5 that form R ７ One or more radicals R adjacent to it ６ A low-melting-point fatty acid having five or more carbon atoms and a melting point of less than 40°C, which forms R of formula (II), is formed by R ６ - and R ７ - One or more radicals R at the opposite end of the contained ester element ６ The R forms, and at least 50% of all parts of formula (II) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a radical configuration is observed, preferably more than 80% of all parts of formula (II) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a configuration of radicals is observed, it is more preferable that all parts of general formula (II) are residues R as described above. ６ and R ７ When such an arrangement is shown, most preferably, Or here In one or more parts of formula (V), at least one, preferably more than one, more preferably one, two or three, each containing base R ６ Low melting point fatty acids ≥ C5 that form R １１ One or more radicals R adjacent to it ６ In addition, at least one, preferably more than one, more preferably one, two or three high melting point fatty acids ≥ C5 are R of formula (V). ６ and R １１ At the opposite end of the contained ester element, one or more radicals R ６ Forms or in one or more parts of formula (V), at least one, preferably more than one, more preferably one, two or three, each R ６ The high melting point fatty acids ≥ C5 that form R １１ One or more radicals R adjacent to it ６ It forms a compound, while at least one, preferably more than one, more preferably one, two or three low-melting-point fatty acids ≥ C5 of formula (V) ６ and R １１ One or more radicals R at the opposite end of the contained ester element ６ The R forms, and at least 50% of all parts of formula (V) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a radical configuration is observed, preferably more than 80% of all parts of formula (V) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a radical configuration is observed, more preferably, and most preferably, all parts of general formula (V) are residues R as described above. ６ and R １１ This shows such an arrangement, or Here, in compounds of formula (I), (III), or (IV), the low-melting point and high-melting point fatty acids ≥ C5 are R of general formula (II*). ６ and R ７＊ Within the contained ester elements,  ６ (. ６ ) ｍ ︁!() ７＊ (=)) Particularly, - O - C ( O) - R ６ -(O-C(O)-R ６ ) ｍ - O - C ( O) - R ７＊ および -NR １０ -C(O)-R ６ -(O-C(O)-R ６ ) ｍ -O-C(O)-R ７＊ 、 Here, X, R ６ , and R ７＊ and R １０ This is as defined above. It is specifically located in, And here One or more portions of formula (II*) have at least one, preferably more than one, more preferably one, two, or three, five or more carbon atoms and a melting point of 40°C or lower, each having a base R ６ The low-melting-point fatty acids that form are R ７＊ One or more radicals R adjacent to it ６ The fatty acids contained in, on the other hand, have five or more carbon atoms, preferably at least one, preferably more than one, more preferably one, two, or three, and a melting point above 40°C, and are R of formula (II*). ６ and R ７＊ One or more radicals R at the opposite end of the contained ester element ６ Forms or in one or more parts of formula (II*), at least one, preferably more than one, more preferably one, two or three, each R ６ The high melting point fatty acids ≥ C5 that form R ７＊ One or more radicals R adjacent to it ６ A low-melting-point fatty acid having five or more carbon atoms and a melting point of less than 40°C, which forms R of formula (II*), is formed by R ６ and R ７＊ One or more radicals R at the opposite end of the contained ester element ６ The R forms, and at least 50% of all parts of formula (II*) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a radical configuration is observed, preferably more than 80% of all parts of formula (II*) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ - When such a configuration of radicals is observed, it is more preferable, and all parts of general formula (II) are of the aforementioned residue R ６ and R ７＊ In the case of such arrangement, the most preferred is the hair care formulation according to any of the above claims.

42. In the compound of formula (III), R ４ Herein, R is selected from divalent to tetravalent, e.g., divalent, trivalent, tetravalent, preferably divalent, optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals, which have up to 200 carbon atoms, more preferably up to 150 carbon atoms, even more preferably up to 100 carbon atoms, specifically up to 80 carbon atoms, and preferably at least 2, more preferably at least 10, more preferably at least 14 carbon atoms, and optionally comprising one or more groups selected from -O-, -NH-, and -C(O)-, and wherein, a plurality of R ４ If they are present in formula (III), they may be the same or different, the hair care formulation according to any one of claims 6 to 13, 15 to 18, 20, 22 to 25, and 27 to 41.

43. In compounds of general formula (III), R ４ The hair care formulation according to any one of claims 6 to 13, 15 to 18, 20, 22 to 25, and 27 to 42, comprising at least one ester group (each -O-C(O)- or -C(O)-O-).

44. In the compound of formula (III), R ４ This includes dicarboxylic acids, tricarboxylic acids, or tetracarboxylic acids, particularly dicarboxylic acids, such as succinic acid, oxalic acid, malonic acid, malic acid, tartaric acid, maleic acid, itaconic acid, succinic acid, sebacic acid, dimer acid, amino-functional dicarboxylic acids, such as D-glutamic acid, and dicarboxylic acids of the following formulas: 【Chemistry 20】 and derived from hydroxycarboxylic acids, particularly ricinoleic acid or reskerolic acid, and dicarboxylic acids, such as succinic acid, oxalic acid, malonic acid, malic acid, tartaric acid, maleic acid, itaconic acid, succinic acid, sebacic acid, dimer acid, amino-functional dicarboxylic acids, such as D-glutamic acid, and condensation products of dicarboxylic acids of the following formulas, or 【Chemistry 21】 R ４ It is derived from amide condensation products of amino acids with maleic acid or succinic acid, for example, N-maleoyl-β-alanine ((E)-4-(2-carboxyethylamino)-4-oxo-buto-2-enoic acid), N-succinyl-β-alanine (4-[(2-hydroxy-1-methyl-2-oxo-ethyl)amino]-4-oxo-butanoic acid), N-maleoyl-asparagine (4-amino-2-[[(E)-4-hydroxy-4-oxo-buta-2-enoyl]amino]-4-oxo-butanoic acid); or R ４ These are derived from ester condensation products of dihydric alcohols, namely ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butanediol, 1,4-butanediol, and dicarboxylic acid anhydrides, namely maleic anhydride, succinic anhydride, phthalic anhydride; or R ４ It is derived from tricarboxylic acids or tetracarboxylic acids, such as citric acid, isocitric acid, trimellitic acid, pyromellitic acid, cyclobutanetetracarboxylic acid; or R ４ It is derived from the bisamide condensation product of an amino acid and maleic acid or succinic acid, namely bis-(N-maleoil)-lysine; or R ４ It is derived from the ester condensation product of trivalent alcohols, such as glycerol, dicarboxylic acid anhydrides, such as maleic anhydride, succinic anhydride, or phthalic anhydride, of trimethylolpropane; or R ４ It is derived from the ester condensation products of tetrahydric alcohols, such as diglycerol and pentaerythritol, with dicarboxylic acid anhydrides, such as maleic anhydride, succinic anhydride, and phthalic anhydride, and Most preferably R ４ It originates from the condensation product of ricinoleic acid or reskerolic acid and succinic acid. A hair care formulation according to any one of claims 6 to 13, 15 to 18, 20, 22 to 25, and 27 to 43.

45. In at least one compound of formula (II), (III), or (IV), at least one portion of formula (II), (II*), or (V), two or more different R ６ A hair care formulation according to any of the preceding claims, wherein a base is present.

46. In at least one of the parts of formula (II), (II*), or (V) of at least one compound of formula (I), (III), or (IV), the group R ６ and R ７ , R ６ and R ７＊ , or R ６ and R １１ The hair care formulation according to any of the above claims, which is not based on the same carboxylic acid structure.

47. In at least one compound of general formula (I), p is between 2 and 6, R １ These are selected from divalent to hexavalent linear, branched or cyclic alkylene groups, linear, branched or cyclic alkenylene groups, linear, branched or cyclic alkynylene groups, linear, branched or cyclic alkali-lene groups, linear, branched or cyclic aralkylene groups, and linear, branched or cyclic arylene groups, such as phenylene, benzylene or trilene groups, particularly those having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms. And at least one base F includes one or more parts of general formula (II*),  ６ (. ６ ) ｍ ︁!() ７＊ (=)) Here R ６ , R ７＊ , and m are as defined above, Or, in at least one compound of general formula (III), r + s = 2 - 6, R ２ These are selected from divalent to hexavalent linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkalilene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene, benzylene, or trilene groups, particularly those having 1 to 1000 carbon atoms, more specifically 1 to 150 carbon atoms. And at least one base F includes one or more parts of general formula (II*), Here R ６ , R ７＊ , and m are as defined above, A hair care composition according to any of the above claims.

48. In at least one compound of general formula (I), X = O, p is 2, R １ The group is selected from divalent linear, branched, and cyclic alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups, preferably selected from ethylene, n-propylene, n-butylene, n-pentene and n-hexylene. And at least one base F includes one or more parts of the following general formula (II*):  ６ (. ６ ) ｍ ︁!() ７＊ (=)) Here R ６ , R ７＊ , and m are as defined above, Or, in at least one compound of general formula (III), X = O, r + s = 2, R2 is selected from divalent linear, branched, and cyclic alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene and 2-ethylhexylene groups, preferably selected from ethylene, n-propylene, n-butylene, n-pentene and n-hexylene, and at least one group F comprises one or more parts of general formula (II*), Here R ６ , R ７＊ , and m are as defined above, A hair care composition according to any of the above claims.

49. In at least one compound of general formula (I) or (III), one or more groups R ７＊ The hair care composition according to any of the above claims, wherein each is terminated by three or more -O-C(O)-T groups, preferably by four or more -O-C(O)-T groups, most preferably by four to twelve -O-C(O)-T groups, where T is as defined above.

50. In at least one compound of general formula (I) or (III), one or more R ７＊ Each of these includes at least two branching structures in the following general formula: -C(O)-B(-O-) ｂ Here, B is a linear or branched hydrocarbon group having 2 to 20 carbon atoms, and b is 2 or more, and here the b groups (-O-) bonded to group B on one side are CH ２ The hair care composition according to any of the preceding claims, wherein a carbon atom, which may be a carbon atom of a group or a carbonyl group, is bonded on the other side to a carbon atom.

51. In at least one compound of general formula (I) or (III), one or more groups R ７＊ Now, the general formula defined above -B(-O-) ｂ or -C(O)-B(-O-) ｂ The hair care composition according to any one of the above claims, wherein one or more branched structures are independently derived from glyceric acid, 2,2-di-hydroxymethylpropionic acid, gluconic acid, maltobionic acid, and lactobionic acid.

52. In a compound of formula (I) or (III), one or more R ７＊ Each is terminated by two or more groups of the following structure: -R ６ (-X-C(O)-R ６ ) ｔ -X-C(O)-T Here R ６ And T is as defined above, X = O, t is independently 0 to 12, preferably independently 0 to 6, most preferably independently 0, 1, 2, or 3. A hair care formulation according to any of the above claims.

53. In a compound of formula (I) or (III), one or more groups R ７＊ It is terminated with two or more groups, preferably 4 to 12 groups, of the following structure: -R ６ (-X-C(O)-R ６ ) ｔ -X-C(O)-T、 Here R ６ These are independently derived from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. X is O, and T is independently derived from C2 to C24 fatty acids, preferably C8 to C24 fatty acids, particularly lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, and arachidic acid. And t is 0-6, preferably 0, 1, 2, or 3. A hair care formulation according to any of the above claims.

54. One or more groups R7* of the compound of formula (I) or (III) are independently selected from one of the following branched or dendrimer fatty acid structures: - R １２ - O - C ( O) - R ６ -(O-C(O)-R ６１ ) ｍ１ -(O-C(O)-R ６２ ) ｍ２ -O-C(O)-T または -R １２ -NR １０ -C(O)-R ６ -(O-C(O)-R ６１ ) ｍ１ -(O-C(O)-R ６２ ) ｍ２ -O-C(O)-T、 Here R １０ This is as defined above, R １２ It has 2 to 50 carbon atoms, specifically 2 to 20 carbon atoms, more specifically 2 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 22】 A divalent, optionally substituted hydrocarbon radical, where radical R may comprise one or more groups selected from and may be substituted with an -OH or halide group. １２ It cannot include a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group that forms an internal carboxylate group or internal amide group, and preferably a C1-C24n-alkylene group and a C2-C24n-alkenylene group, in particular -CH ２ -ien-CH ２ CH ２ -ien-CH ２ CH ２ CH ２ - represents, R ６ This is as defined above, m1 is 0 to 12, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. m2 is 0 to 12, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. And m1 + m2 is t, where t is from 0 to 12, preferably from 0 to 10, more preferably from 0 to 6, even more preferably from 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6, and T is as defined above, R ６１ and R ６２ This is the base R defined above. ６ Selected from, And here, preferably, Table 2 Here R ６ Total number of carbon atoms in +T (Σ carbon atoms R) ６ T) is 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150. However, R derived from dihydroxylated carboxylic acid or polyhydroxylated carboxylic acid. ６ , R ６１ and R ６２ The condition is that at least one, preferably one to two, more preferably two, and even more preferably all of the OH groups are esterified. A hair care formulation according to any of the above claims.

55. At least one compound of general formula (I) or (III) has the following schematic ester structure i) (fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-O-C(O)-(mono or oligo C8-C24 hydroxy fatty acid)-O-C(O)-(fatty acid), or ii) (branched fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-O-C(O)-(mono or oligo C8-C24 hydroxy fatty acid)-O-C(O)-(branched fatty acid) or iii) (Dendrimeric fatty acid) - C(O) - O - (Mono or oligo C8-C24 hydroxy fatty acid) - C(O) - O - (C2-C10 hydrocarbon) - O - C(O) - (Mono or oligo C8-C24 hydroxy fatty acid) - O - C(O) - (Dendrimeric fatty acid) It is represented by one of the following: A hair care formulation according to any of the above claims.

56. Compounds of formula (I), (III), or (IV) include at least one part of the following general formulas: -([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])- Here R ６ This is as defined above, l is an integer independently selected from 0 to 20, more preferably from 1 to 12, and even more preferably from 2 to 10. L may have 1 to 30 carbon atoms and optionally -O-, -S-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. 【Chemistry 23】 A divalent hydrocarbon radical which may contain one or more groups selected from quaternary ammonium groups, Preferably, L is a divalent alkylene or alkenylene radical having 1 to 30 carbon atoms. More preferably, L is selected from methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, nonylene, etenylene, propenylene, butenylene, pentenylene, hexenylene, heptenylene, octenylene, nonenylene, Most preferably, L is selected from methylene, ethylene, ethenylene, or butenylene. A hair care formulation according to any of the above claims.

57. Compounds of formula (I), (III), or (IV) include at least one part of the following general formulas: ([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])- L and l are as defined above, And R ６ These are independently selected from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. Most preferably, R ６ It is derived from ricinoleic acid. A hair care formulation according to any of the above claims.

58. Compounds of formula (I), (III), or (IV) include at least one part of the general formula, ([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])- Here, L is selected from methylene, ethylene, and ethenylene. R ６ It is derived from ricinoleic acid, and l is independently selected from 0, 1, 2, and 3, and the sum of l is in the range of 0 to 4. A hair care formulation according to any of the above claims.

59. Compounds of formula (I), (III), or (IV) have the following structure: (Fatty alcohol)-O-C(O)-(mono or oligo C8-C24 hydroxy fatty acid)-O-C(O)-(C1-C12 hydrocarbon)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(fatty alcohol) Including at least one part of, A hair care formulation according to any of the above claims.

60. Compounds of formula (I), (III), or (IV) have the following structure: -([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])-R １１ 、 Here L, l, R ６ , and R １１ This is as defined above. A hair care formulation according to any of the above claims.

61. Compound of formula (Ia), R １ (-X-C(O)-F) ｐ (Ia) Here R in equation (Ia) １ It is selected from p-valent, optionally substituted hydrocarbon radicals, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, 【Chemistry 24】 and may comprise one or more groups selected from quaternary ammonium groups, and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups. p ≥ 2, more preferably from 2 to 811. X may be the same or different, and -O- or -NR １０ - is selected, and here R １０ It has hydrogen or up to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. 【Chemistry 25】 Selected from the group consisting of optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from the following: Alternatively, in equation (I), R １０ is R １ It can form bonds to form a ring structure, F may be the same or different, and may have up to 1005 carbon atoms, and may optionally contain -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 26】 Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and optionally substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, However, the condition is that at least one of the radicals F contains at least one part of formula (IIa) or formula (IIa*), -R ６ (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７ (IIa) -R ６ (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７＊ (--a*) Here X is as defined above, m = 1 to 20, preferably 2 to 20. R ６ These are independently selected from divalent, optionally substituted, linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 36 carbon atoms. R ７ It has 1 to 1000 carbon atoms, and optionally has -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Chemistry 27】 Quaternary ammonium group 【Chemistry 28】 A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R ７ It cannot contain an internal carboxyl group or amide, i.e., R ７ It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, in at least one part of equation (IIa), R ７ It has at least two, preferably at least six, carbon atoms, and in the same portion of formula (IIa), at least one R ６ The condition is that it has at least six, preferably at least eight, carbon atoms. R ７＊ It has 1 to 1000 carbon atoms, and optionally has -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Chemistry 29】 Quaternary ammonium group 【Transformation 30】 A radical R is independently selected from optionally substituted branched or dendrimer hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R ７＊ It is terminated by two or more of the following general structures: -X-C(O)-T Here, X is as defined above, and T is a monovalent linear, cyclic, or branched saturated or unsaturated hydrocarbon radical having up to 36 carbon atoms and optionally substituted with a carboxyl group, a hydroxyl group, or a halide group. However, in at least one part of equation (II*), R ７＊ It is terminated by one or more groups T having at least two, preferably at least six, carbon atoms, and in the same portion of formula (IIa*), at least one R ６ The condition is that it has at least 6, preferably at least 8, carbon atoms. or It contains at least one compound of general formula (IVa), R １ (-C(O)-X-G) ｑ (IVa) Here, X is as defined above, R in equation (IVa) １ Preferably having up to 1000 carbon atoms, optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino group, 【Chemistry 31】 Selected from optionally substituted hydrocarbon radicals of q valence, which may comprise one or more groups selected from quaternary ammonium groups and may optionally be substituted with one or more groups selected from carboxyl groups or hydroxyl groups. q = 2 to 55, preferably 2 to 40, more preferably 2 to 4, and G may be the same or different, and may have up to 1005 carbon atoms, and may optionally contain -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 32】 Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, wherein at least one of the radicals G comprises at least one part of formula (Va), -R ６ (-C(O)-X-R ６ ) ｍ -C(O)-G-R １１ (Wa) Here, X is as defined above, m = 1 to 20, preferably 2 to 20. R in equation (Va) ６ As defined above for equation (Ia), R １１ It has 1 to 1000 carbon atoms, and optionally has -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Transformation 33】 Quaternary ammonium group 【Transformation 34】 A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R １１ It cannot contain an internal carboxyl group or amide, i.e., R １１ It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, in at least one part of equation (Va), R １１ It has at least two, preferably at least six, carbon atoms, and in the same portion of formula (Va), at least one R ６ The condition is that it has at least six, preferably at least eight, carbon atoms. A compound of formula (Ia), provided that it is not composed solely of glycerol and ricinoleic acid moieties, i.e., polyglycerol-polyricinoleic acid (PGPR).

62. R １ The compound of formula (Ia) or (IVa) according to claim 61, wherein, as defined above, it has a maximum of 10,000 carbon atoms, preferably a maximum of 1,000, more preferably a maximum of 300, even more preferably a maximum of 100, and most preferably a maximum of 50 carbon atoms.

63. Any R of the compound ７ or R １１ A compound of formula (Ia) or (IVa) according to claims 61 and 62, wherein the number of carbon atoms in the compound is 3 to 300, preferably 3 to 100, more preferably 3 to 50, even more preferably 3 to 36, even more preferably 3 to 24, and most preferably 11 to 24.

64. The compound of formula (Ia) or (IVa) according to any one of claims 61 to 63, having a molecular weight in the range of 1,500 to 200,000 g / mol, preferably 1,500 to 100,000 g / mol, more preferably 1,500 to 30,000 g / mol, even more preferably 1,500 to 10,000 g / mol, even more preferably 1,500 to 5,000 g / mol, and most preferably 1,500 to 3,000 g / mol.

65. The compound of formula (Ia) comprises a portion of formula (IIa) from 2 to 100, more preferably a portion of formula (IIa) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, most preferably 2 to 4 of formula (IIa), or the compound of formula (Ia) comprising a portion of formula (IIa*) from 2 to 100, more preferably a portion of formula (IIa*) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, most preferably 2 to 4 of formula (IIa*), or the compound of formula (IVa) comprising a portion of formula (Va) from 2 to 100, more preferably a portion of formula (Va) from 2 to 50, even more preferably 2 to 20, even more preferably 2 to 10, even more preferably 2 to 6, most preferably 2 to 4 of formula (Va), as described in any of claims 61 to 64.

66. It is expressed by the general formula (IIIa), {[(F-C(O)-X-) １－５ R ３ (-E-C(O)-)] １－３ R ４ -C(O)-E-} ｒ -R ２ (-X-C(O)-F) ｓ (IIa) Here X may be the same or different, and -O- or -NR １０ - is selected, and here R １０ It has hydrogen or up to 100 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. 【Chemistry 35】 Selected from the group consisting of optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from the following: Alternatively, in equation (IIIa), R １０ is R ２ It can form bonds to form a ring structure, R in equation (IIIa) ２ It has up to 1000 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, tertiary amino groups, 【Transformation 36】 and may comprise one or more groups selected from quaternary ammonium groups, and may be optionally substituted with one or more carboxyl or hydroxyl groups, selected from (r+s) valent, optionally substituted hydrocarbon radicals, and R １０ R ２ If the combination is to, then optionally base-NR １０ - Forms a bond to the nitrogen atom, R ３ It has up to 1000 carbon atoms and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 37】 Selected from optionally substituted, divalent to hexavalent hydrocarbon radicals, which may contain one or more groups selected from: Here, multiple R ３ If they exist in equation (IIIa), they may be the same or different. R ４ It has up to 300 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Transformation 38】 Selected from linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, which are optionally substituted with divalent to tetravalent groups and include one or more groups selected from the above. Here, multiple R ４ If they exist in equation (IIIa), they may be the same or different. And here r + s = 2, so 55. r = 0 to 54, s≧1, In formula (IIIa), F may be the same or different, and may have up to 1005 carbon atoms, and may optionally be -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Chemistry 39】 Selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from and optionally substituted with one or more selected from carboxyl groups, hydroxyl groups, or halide groups, However, this is conditional on at least one radical F containing at least one part of formula (IIa) or (IIa*), -R ６ (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７ (IIa) -R ６ (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７＊ (--a*) Here X is as defined above, Here, m = 1 to 20, preferably m = 2 to 20. R ６ These are independently selected from divalent, optionally substituted, linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 36 carbon atoms. R ７ It has 1 to 1000 carbon atoms, and optionally has -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Chemistry 40】 Quaternary ammonium group 【Chemistry 41】 A linear, cyclic, or branched saturated or unsaturated hydrocarbon radical, independently selected from optionally substituted linear, cyclic, or branched, saturated or unsaturated hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R ７ It cannot contain an internal carboxyl group or amide, i.e., R ７ It cannot contain a combination of a -C(O)- group and an -O- group, or a combination of a -C(O)- group and an -NH- or tertiary amino group. However, in at least one part of equation (IIa), R ７ It has at least two, preferably at least six, carbon atoms, and in the same portion of formula (IIa), at least one R ６ The condition is that it has at least six, preferably at least eight, carbon atoms. R ７＊ It has 1 to 1000 carbon atoms, and optionally has -O-, -NH-, -C(O)-, -C(S)-, and a tertiary amino group. 【Chemistry 42】 Quaternary ammonium group 【Chemistry 43】 A radical R is independently selected from optionally substituted branched or dendrimer hydrocarbon radicals, comprising one or more groups selected from and which may be substituted with a carboxyl group, a hydroxyl group, or a halide group, where radical R ７＊ It is terminated by two or more of the following general structures: -X-C(O)-T Here, X is as defined above, and T is a monovalent, linear, cyclic, or branched, saturated or unsaturated hydrocarbon radical having up to 36 carbon atoms and optionally substituted with a carboxyl group, hydroxyl group, or halide group. However, in at least one part of equation (IIa*), R ７＊ It is terminated by one or more groups T having at least two, preferably at least six, carbon atoms, and in the same portion of formula (IIa*), at least one R ６ The condition is that it has at least six, preferably at least eight, carbon atoms. A compound of formula (Ia) according to any one of claims 61 to 65.

67. R １０ is hydrogen, n-, iso-, or tert.-C １ -C ２２ - Alkyl, C ２ -C ２２ - Alkoxyalkyl, C ５ -C ３０ - Cycloalkyl, C ６ -C ３０ - Aryl, C ６ -C ３０ -Aryl (C) １ -C ６ ) Alkyl, C ６ -C ３０ - Alkylaryl, C ２ -C ２２ - Alkenil, C ２ -C ２２ - Selected from the group consisting of alkenyloxyalkyls which are optionally substituted with hydroxyl and halogen, and optionally contain one or more ether groups (-O-), preferably R １０ is hydrogen or n-, iso-, and tert.-C １ -C ２２ - A compound of formula (Ia), (IIIa), or (IVa) according to any one of claims 61 to 66, selected from alkyl groups.

68. R1 in the compound of formula (IVa) or R2 in the compound of formula (IIIa) has a maximum of 2 to 300 carbon atoms, more preferably 3 to 200 carbon atoms, even more preferably 3 to 150 carbon atoms, specifically 3 to 50 carbon atoms, and more specifically 3 to 20 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)- and a third amino group. 【Chemistry 44】 A compound of formula (IIIa) or (IVa) according to any one of claims 61 to 67, which may comprise one or more groups selected from and may optionally be substituted with a carboxyl group, a hydroxyl group, and a quaternary ammonium group, and which is optionally selected from optionally substituted hydrocarbon radicals.

69. R in the compound of formula (IVa) １ or R in the compound of formula (IIIa) ２ The compound of formula (IIIa) or (IVa) according to any one of claims 61 to 68, wherein is selected from optionally substituted hydrocarbon radicals that are divalent to hexavalent, preferably divalent to tetravalent, more preferably divalent to trivalent, and particularly divalent, trivalent, tetravalent, pentavalent, or hexavalent.

70. R ３ A compound of formula (IIIA) according to any one of claims 66 to 69, wherein the residue is selected from divalent to hexavalent residues.

71. R ３ It has a maximum of 300 carbon atoms, preferably 1 to 200 carbon atoms, more preferably 1 to 150 carbon atoms, even more preferably 1 to 50 carbon atoms, specifically 1 to 20 carbon atoms, and more specifically 1 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 45】 A compound of formula (IIIIa) according to any one of claims 66 to 70, selected from optionally substituted linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals, comprising one or more groups selected from the above.

72. R ４ It has 2 to 300 carbon atoms, preferably 5 to 200 carbon atoms, more preferably 8 to 150 carbon atoms, and even more preferably 10 to 120 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 46】 A compound of formula (IIIa) according to any one of the above claims 66 to 71, selected from linear, cyclic, or branched saturated, unsaturated, or aromatic hydrocarbon radicals that are optionally substituted with divalent to tetravalent, preferably divalent, trivalent, or tetravalent groups, comprising one or more groups selected from the above.

73. A compound of formula (IIIa) according to any one of claims 66 to 72, wherein r = 0 to 50, preferably 0 to 20, more preferably 0 to 10, even more preferably 1 to 10, specifically 1 to 5, more specifically 0, 1, 2, 3, 4, 5, and even more specifically r = 2.

74. At least one of the radicals F is at least one part -R ６ (-O-C(O)-R ６ ) ｍ -O-C(O)-R ７ 、 -R ６ (-NR １０ -C(O)-R ６ ) ｍ -O-C(O)-R ７ 、 -R ６ (-NR １０ -C(O)-R ６ ) ｍ -NR １０ -C(O)-R ７ ,or -R ６ (-O-C(O)-R ６ ) ｍ -O-C(O)-R ７＊ 、 -R ６ (-NR １０ -C(O)-R ６ ) ｍ -O-C(O)-R ７＊ 、 -R ６ (-NR １０ -C(O)-R ６ ) ｍ -NR １０ -C(O)-R ７＊ 、 Preferably -R ６ (-OC(O)-R ６ ) ｍ -O-C(O)-R ７ , or -R ６ (-OC(O)-R ６ ) ｍ -O-C(O)-R ７＊ Here, R １０ , R ６ , R ７ , R ７＊ , and m are as defined above, A compound of formula (Ia) or (IIIa) according to any one of claims 61 to 73, comprising:

75. At least one of the radical Gs is at least one part -R ６ (-C(O)-O-R ６ ) ｍ -C(O)-O-R １１ 、 -R ６ (-C(O)-NR １０ -R ６ ) ｍ -C(O)-O-R １１ 、 -R ６ (-C(O)-NR １０ -R ６ ) ｍ -C(O)-NR １０ -R １１ 、 Preferably -R ６ (-C(O)-OR ６ ) ｍ -C(O)-O-R １１ Here, R １０ , R ６ , R １１ , and m are as defined above, A compound of formula (IVa) according to any one of claims 61 to 65 and 67 to 69, comprising

76. Low-melting point and high-melting point fatty acids ≥ C5 are R of general formula (IIa). ６ and R ７ Within the contained ester element, and R of general formula (Va) ６ and R １１ Within the contained ester elements, -R ６ (-X-C(O)-R ６ ) ｍ -X-C(O)-R ７ (IIa) and -R ６ (-C(O)-X-R ６ ) ｍ -C(O)-G-R １１ (Va) Particularly, - O - C ( O) - R ６ -(O-C(O)-R ６ ) ｍ - O - C ( O) - R ７ および -NR １０ -C(O)-R ６ -(O-C(O)-R ６ ) ｍ -O-C(O)-R ７ 、 Here, X, R ６ , R ７ , R １１ , and R １０ This is as defined above. Or R in general formula (IIa*) ６ and R ７＊ Within the contained ester elements, -R ６ (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７＊ (--a*), Part in particular -O-C(O)-R ６ -(O-C(O)-R ６ ) ｍ -O-C(O)-R ７＊ 、 Here, X, R ６ , R ７＊ This is as defined above. It is specifically placed in And here In one or more portions of formula (IIa), at least one, preferably more than one, more preferably one, two or three, each containing base R ６ Low melting point fatty acids ≥ C5 that form R ７ One or more radicals R adjacent to it ６ It includes, on the other hand, at least one, preferably more than one, more preferably one, two or three high melting point fatty acids ≥ C5, which are R of formula (II). ６ and R ７ At the opposite end of the contained ester element, one or more radicals R ６ Forms or in one or more parts of formula (IIa), at least one, preferably more than one, more preferably one, two or three, each R ６ The high melting point fatty acids ≥ C5 that form R ７ One or more radicals R adjacent to it ６ It forms a low melting point fatty acid ≥ C5 of formula (IIa) ６ and R ７ At the opposite end of the contained ester element, one or more radicals R ６ The formula (IIa) is formed, and at least 50% of all parts of the formula are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a radical configuration is observed, preferably more than 80% of all parts of formula (IIa) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a configuration of radicals is observed, it is more preferable that all parts of general formula (IIa) are residues R as described above. ６ and R ７ When such an arrangement is shown, most preferably, Alternatively, in one or more parts of formula (IIa*), at least one, preferably more than one, more preferably one, two or three, each of which is a base R ６ Low melting point fatty acids ≥ C5 that form R ７＊ One or more radicals R adjacent to it ６ It contains, on the other hand, at least one, preferably more than one, more preferably one, two or three high melting point fatty acids ≥ C5, which are R of formula (IIa*). ６ and R ７＊ At the opposite end of the contained ester element, one or more radicals R ６ Forms or in one or more parts of formula (IIa*), at least one, preferably more than one, more preferably one, two or three, each R ６ The high melting point fatty acids ≥ C5 that form R ７＊ One or more radicals R adjacent to it ６ It forms a low melting point fatty acid ≥ C5 of formula (IIa*) ６ and R ７＊ At the opposite end of the contained ester element, one or more radicals R ６ The formula (IIa*) is formed, and at least 50% of all parts of the formula are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a radical configuration is observed, preferably more than 80% of all parts of formula (IIa*) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ - When such a configuration of radicals is observed, it is more preferable, and all parts of the general formula (IIa*) are residues R as described above. ６ and R ７＊ When such an arrangement is shown, most preferably, Or here In one or more parts of formula (Va), at least one, preferably more than one, more preferably one, two or three, each containing base R ６ Low melting point fatty acids ≥ C5 that form R １１ One or more radicals R adjacent to it ６ It contains, on the other hand, at least one, preferably more than one, more preferably one, two or three high melting point fatty acids ≥ C5, which are R of formula (Va). ６ and R １１ At the opposite end of the contained ester element, one or more radicals R ６ Forms or in one or more parts of formula (Va), at least one, preferably more than one, more preferably one, two or three, each R ６ The high melting point fatty acids ≥ C5 that form R １１ One or more radicals R adjacent to it ６ It forms a low melting point fatty acid ≥ C5 of formula (Va) ６ and R １１ At the opposite end of the contained ester element, one or more radicals R ６ The formula (Va) is formed, and at least 50% of all parts of formula (Va) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a radical configuration is observed, preferably more than 80% of all parts of formula (Va) are derived from high-melting-point and low-melting-point fatty acids as described above. ６ When such a radical configuration is observed, more preferably, and most preferably, all parts of the general formula (Va) are the residue R as described above. ６ and R １１ A compound of formula (Ia), (IIIa), or (IVa) according to any one of the above claims 61 to 75, exhibiting such configuration.

77. In part of equation (IIa), m = 1 to 10, more preferably 1 to 6, even more preferably 2 to 6, specifically 1, 2, 3, 4, 5, 6, more specifically 1 or 2. Or, in the part of equation (IIa*), m = 1 to 10, more preferably 1 to 6, even more preferably 2 to 6, specifically 1, 2, 3, 4, 5, 6, more specifically 1 or 2. A compound of formula (Ia), (IIIa), or (IVa) according to any one of claims 61 to 76.

78. R ６ A compound of formula (Ia), (IIIa), or (IVa) according to any one of claims 61 to 77, which is independently selected from optionally substituted linear, cyclic, or branched saturated or unsaturated hydrocarbon radicals having up to 24 carbon atoms, preferably 1 to 24, more preferably 2 to 20, and even more preferably 8 to 18 carbon atoms.

79. R ７ A compound of formula (Ia) or (IIIa) according to any one of claims 61 to 74 and 76 to 78, which is independently selected from optionally substituted linear, cyclic or branched saturated or unsaturated hydrocarbon radicals having 1 to 36 carbon atoms, preferably 1 to 24 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 8 to 18 carbon atoms.

80. R ６ and R ７ R of each single part of the general formula (IIa) composed of ６ +R ７ The total number of carbon atoms (Σ carbon atoms R) ６ , R ７ ) is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100. Or here, R ６ and R ７＊ R of each single part of the general formula (IIa*) composed of ６ +R ７＊ The total number of carbon atoms (Σ carbon atoms R) ６ , R ７＊ ) is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100. A compound of formula (Ia) or (IIIa) according to any one of claims 61 to 64 and 76 to 79.

81. R ６ and R ７ R in each single part of the general formula (a) which is composed of ６ +R １１ The total number of carbon atoms (Σ carbon atoms R) ６ , R １１ A compound of formula (IVa) according to any one of claims 61 to 65, 67 to 69, and 75 to 78, wherein the amount is 10 to 300, preferably 15 to 200, more preferably 20 to 150, and even more preferably 30 to 100.

82. R ６ The compound of formula (Ia), (IIIa), or (IVa) according to any one of claims 61 to 81 is derived from a monohydroxycarboxylic acid having up to 25 carbon atoms, preferably independently selected from the group consisting of glycolic acid, lactic acid, 2-hydroxybutyric acid, 3-hydroxybutyric acid, 4-hydroxybutyric acid, 14-hydroxytetradecanoic acid, 10-hydroxystearic acid, 12-hydroxystearic acid, ricinoleic acid, and reskerolic acid.

83. R ７ The compound of formula (Ia) or (IIIa) according to any one of claims 61 to 74, 76 to 80, and 82 is derived from a carboxylic acid having up to 25 carbon atoms without hydroxyl substituents, preferably independently selected from the group consisting of acetic acid, propanoic acid, butanoic acid, pentanoic acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, nonadecanoic acid, eicosanoic acid, docosanoic acid, 2-ethylhexanoic acid, 2,2-dimethylpropionic acid, 2,2-dimethylheptanoic acid, 2,2-dimethyloctanoic acid, neodecanoic acid, undecyl-10-enoic acid, oleic acid, linoleic acid, linolenic acid, and erucic acid.

84. R in the part of general formula (IIa) ６ and R ７ A compound of formula (Ia) or (IIIa) according to any of the above claims 61 to 74, 76 to 80, and 82 to 83, wherein at least one, preferably both, of the compounds are derived from an unsaturated carboxylic acid.

85. R ４ Herein, formula (III) has a maximum of 200 carbon atoms, more preferably a maximum of 150 carbon atoms, even more preferably a maximum of 100 carbon atoms, specifically a maximum of 80 carbon atoms, and preferably at least 2, more preferably at least 10, more preferably at least 14 carbon atoms, and optionally comprises one or more groups selected from -O-, -NH-, and -C(O)-, and is selected from divalent to tetravalent, e.g., divalent, trivalent, tetravalent, preferably divalent, optionally substituted linear, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radicals, and wherein formula (III) there are multiple R ４ A compound of formula (IIIa) according to any one of claims 66 to 74, 76 to 80, and 82 to 84, wherein if present, they may be the same or different.

86. A compound of formula (IIIa) according to any one of claims 66 to 74, 76 to 80, and 82 to 85, wherein R4 comprises at least one ester group (each -O-C(O)- or -C(O)-O-).

87. In the compound of formula (III), R ４ This includes dicarboxylic acids, tricarboxylic acids or tetracarboxylic acids, particularly dicarboxylic acids, such as succinic acid, oxalic acid, malonic acid, malic acid, tartaric acid, maleic acid, itaconic acid, succinic acid, sebacic acid, dimer acid, amino-functional dicarboxylic acids, such as D-glutamic acid, and dicarboxylic acids of the following formula: 【Chemistry 47】 and derived from hydroxycarboxylic acids, particularly ricinoleic acid or reskerolic acid, and dicarboxylic acids, such as succinic acid, oxalic acid, malonic acid, malic acid, tartaric acid, maleic acid, itaconic acid, succinic acid, sebacic acid, dimer acid, amino-functional dicarboxylic acids, such as D-glutamic acid, and condensation products of dicarboxylic acids of the following formulas; or 【Chemistry 48】 R ４ It is derived from amide condensation products of amino acids with maleic acid or succinic acid, for example, N-maleoyl-β-alanine ((E)-4-(2-carboxyethylamino)-4-oxo-buto-2-enoic acid), N-succinyl-β-alanine (4-[(2-hydroxy-1-methyl-2-oxo-ethyl)amino]-4-oxo-butanoic acid), N-maleoyl-asparagine (4-amino-2-[[(E)-4-hydroxy-4-oxo-buta-2-enoyl]amino]-4-oxo-butanoic acid); or R ４ These are derived from ester condensation products of dihydric alcohols, namely ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butanediol, 1,4-butanediol, and dicarboxylic acid anhydrides, namely maleic anhydride, succinic anhydride, phthalic anhydride; or R ４ It is derived from tricarboxylic acids or tetracarboxylic acids, such as citric acid, isocitric acid, trimellitic acid, pyromellitic acid, cyclobutanetetracarboxylic acid; or R ４ It is derived from the bisamide condensation product of an amino acid and maleic acid or succinic acid, namely bis-(N-maleoil)-lysine; or R ４ It is derived from ester condensation products of trihydric alcohols, such as glycerol and trimethylolpropane, and dicarboxylic acid anhydrides, such as maleic anhydride, succinic anhydride, and phthalic anhydride; or R ４ It is derived from ester condensation products of tetrahydric alcohols, such as diglycerol and pentaerythritol, and dicarboxylic acid anhydrides, such as maleic anhydride, succinic anhydride, phthalic anhydride, and phthalic anhydride; and Most preferably R ４ It originates from the condensation product of ricinoleic acid or reskerolic acid and succinic acid. A compound of formula (IIIa) according to any one of claims 66 to 74, 76 to 80, and 82 to 86.

88. In at least one of the parts of equation (IIa), (IIa*), or (Va), at least two different R ６ A compound of formula (Ia), (IIIa), or (IVa) according to any one of the above claims 61 to 87, wherein a group is present.

89. In at least one of the parts of formula (IIa), (IIa*), or (Va), base R ６ and R ７ , group R ６ and R ７＊ , or R ６ and R １１ The compounds of formula (Ia), (IIIa), or (IVa) according to any one of the above claims 61 to 88, which are not based on the same carboxylic acid structure.

90. p is 2-6, R １ These are selected from divalent to hexavalent linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkali-lene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, in particular from such groups having 1 to 1000 carbon atoms, more specifically from such groups having 1 to 150 carbon atoms. And at least one group F includes one or more parts of general formula (IIa*), -R ６ (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７＊ (--a*) Here R ６ , R ７＊ , and m are as defined above, Or, in the compound of general formula (IIIa), r + s = 2 - 6, R ２ These are selected from divalent to hexavalent linear, branched, or cyclic alkylene groups, linear, branched, or cyclic alkenylene groups, linear, branched, or cyclic alkynylene groups, linear, branched, or cyclic alkali-lene groups, linear, branched, or cyclic aralkylene groups, and linear, branched, or cyclic arylene groups, such as phenylene, benzylene, or torylene groups, in particular from such groups having 1 to 1000 carbon atoms, more specifically from such groups having 1 to 150 carbon atoms. And at least one group F includes one or more parts of the general formula (IIa*), where R ６ , R ７＊ , and m are as defined above. A compound of formula (Ia) as described in any of the above claims 61 to 89.

91. X = O, p is 2, R １ The alkylene group is selected from divalent linear, branched, and cyclic alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentylene, n-hexylene, n-heptylene, or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups, preferably selected from ethylene, n-propylene, n-butylene, n-pentylene, and n-hexylene. At least one base F comprises one or more parts of general formula (IIa*), -R ６ (-E-C(O)-R ６ ) ｍ -E-C(O)-R ７＊ (--a*) Here R ６ , R ７＊ , and m are as defined above, Or, in the compound of general formula (IIIa), X = O, r + s = 2, R ２ The group is selected from divalent linear, branched, and cyclic alkylene groups, particularly linear C1-C22 alkyl groups, such as methylene, ethylene, n-propylene, n-butylene, n-pentene, n-hexylene, n-heptylene or n-octylene groups, branched C1-C22 alkylene groups, isopropylene, isobutylene, tert-butylene, isobutylene, tert-pentylene, neopentylene, and 2-ethylhexylene groups, preferably selected from ethylene, n-propylene, n-butylene, n-pentylene and n-hexylene. At least one base F comprises one or more parts of general formula (IIa*), Here R ６ , R ７＊ , and m are as defined above, A compound of formula (Ia) as described in any of the above claims 61 to 90.

92. The compounds of formula (Ia) or (IIIa) are each terminated with three or more -O-C(O)-T groups, preferably four or more -O-C(O)-T groups, and preferably 4 to 12 -O-C(O)-T groups, and one or more R groups ７＊ A compound of formula (Ia) or (IIIa) according to any one of the above claims 61 to 91, comprising, where T is as defined above.

93. 1 or more groups R ７＊ Each of these includes at least two branching structures of the following general formula, -C(O)-B(-O-) ｂ Here, B is a linear or branched hydrocarbon group having 2 to 20 carbon atoms, and b is 2 or more, and here, the b groups (-O-) bonded to group B on one side are CH on the other side ２ A compound of formula (Ia) or (IIIa) according to any one of claims 61 to 92, wherein a carbon atom that may be a carbon atom of a group or a carbonyl group is bonded to the carbon atom.

94. 1 ELR ７＊ In the above, the general formula -B(-O-) ｂ or -C(O)-B(-O-) ｂ The compound of formula (Ia) or (IIIa) according to any one of the above claims 61 to 93, wherein one or more branched structures are independently derived from glyceric acid, 2,2-dihydroxymethylpropionic acid, gluconic acid, maltobionic acid, or lactobionic acid.

95. 1 ELR ７＊ It is terminated by two or more groups of the following structure: -R ６ (-X-C(O)-R ６ ) ｔ -X-C(O)-T Here R ６ , and T is as defined above, and X = 0, t independently from 0 to 12, preferably t independently from 0 to 6, most preferably t independently 0, 1, 2, or 3. A compound of formula (Ia) or (IIIa) as described in any of the above claims 61 to 94.

96. 1 or more groups R ７＊ It is terminated by two or more groups, preferably 4 to 12 groups, of the following structure: -R ６ (-X-C(O)-R ６ ) ｔ -X-C(O)-T Here R ６ These are independently selected from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. X is O, and T is independently derived from C2 to C24 fatty acids, preferably C8 to C24 fatty acids, particularly lauric acid, myristic acid, palmitic acid, oleic acid, stearic acid, behenic acid, and arachidic acid. And t is 0-6, preferably 0, 1, 2, or 3. A compound of formula (Ia) or (IIIa) as described in any of the above claims 61 to 95.

97. One or more groups R of a compound of formula (I) or (III) ７＊ It is independently selected from one of the following branched or dendrimer fatty acid structures. - R １２ - O - C ( O) - R ６ -(O-C(O)-R ６１ ) ｍ１ -(O-C(O)-R ６２ ) ｍ２ -O-C(O)-T または -R １２ -NR １０ -C(O)-R ６ -(O-C(O)-R ６１ ) ｍ１ -(O-C(O)-R ６２ ) ｍ２ -O-C(O)-T、 Here R １０ This is as defined above, R １２ It has 2 to 50 carbon atoms, specifically 2 to 20 carbon atoms, more specifically 2 to 10 carbon atoms, and optionally -O-, -NH-, -C(O)-, -C(S)-, and tertiary amino groups. 【Chemistry 49】 may comprise one or more groups selected from, and may be substituted with an —OH or halide group, and is selected from divalent optionally substituted hydrocarbon radicals, wherein radical R １２ cannot comprise a combination of a —C(O)— group and an —O— group, or a combination of a —C(O)— group and an —NH— or tertiary amino group, which form an internal carboxylate group or an internal amide group, and preferably is a C1-C24n-alkylene group and a C2-C24n-alkenylene group, particularly —CH ２ —, —CH ２ CH ２ —, —CH ２ CH ２ CH ２ —, indicating that R ６ This is as defined above, m1 is 0 to 12, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. m2 is 0 to 12, preferably 0 to 10, more preferably 0 to 6, even more preferably 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6. And m1 + m2 is t, where t is from 0 to 12, preferably from 0 to 10, more preferably from 0 to 6, even more preferably from 1 to 6, specifically 0, 1, 2, 3, 4, 5, 6, and T is as defined above. R ６１ and R ６２ This is the base R defined above. ６ Selected from, And here, preferably, Table 3 Here R ６ Total number of carbon atoms in +T (Σ carbon atoms R) ６ T) is 19 to 300, preferably 25 to 300, more preferably 35 to 300, even more preferably 50 to 300, specifically 35 to 200, more specifically 35 to 150, and even more specifically 50 to 150. However, R derived from di or polyhydroxylated carboxylic acids ６ , R ６１ and R ６２ The condition is that at least one, preferably one to two, more preferably two, and even more preferably all of the OH groups are esterified. A compound of formula (Ia) or (IIIa) as described in any of the above claims 61 to 96.

98. The compound is represented by one of the following schematic ester structures: i) (fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-O-C(O)-(mono or oligo C8-C24 hydroxy fatty acid)-O-C(O)-(fatty acid) or ii) (branched fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-O-C(O)-(mono or oligo C8-C24 hydroxy fatty acid)-O-C(O)-(branched fatty acid) or iii) (Dendrimer fatty acid)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(C2-C10 hydrocarbon)-O-C(O)-(mono or oligo C8-C24 hydroxy fatty acid)-O-C(O)-(dendrimer fatty acid), A compound of general formula (Ia) or (IIIa) as described in any of the above claims 61 to 97.

99. The compound comprises at least one part of the following general formula: -([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])- Here R ６ This is as defined above, l is an integer independently selected from 0 to 20, more preferably from 1 to 12, and even more preferably from 2 to 10, and L has 1 to 30 carbon atoms and can optionally be -O-, -S-, -NH-, -C(O)-, -C(S)-, or a tertiary amino group. [Transformation 50] A divalent hydrocarbon radical which may contain one or more groups selected from quaternary ammonium groups, Preferably, L is a divalent alkylene or alkenylene radical having 1 to 30 carbon atoms. More preferably, L is selected from methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, nonylene, etenylene, propenylene, butenylene, pentenylene, hexenylene, heptenylene, octenylene, nonenylene, Most preferably, L is selected from methylene, ethylene, ethenylene, or butenylene. A compound of general formula (Ia), (IIIa), or (IVa) as described in any of claims 61 to 98 above.

100. The compound comprises at least one part of the following general formula: -([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])- Here, L and l are as defined above, And R ６ These are independently selected from C8-C24 monocarboxy-monohydroxycarboxylic acids, particularly ricinoleic acid, 12-hydroxystearic acid, reskerolic acid, and 11-hydroxy-undecanoic acid. Most preferably, R ６ It is derived from ricinoleic acid. A compound of general formula (Ia), (IIIa), or (IVa) as described in any of the above claims 61 to 99.

101. The compound comprises at least one part of the following general formula: ([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])- Here, L is selected from methylene, ethylene, and ethenylene. R ６ It is derived from ricinoleic acid, and l is independently selected from 0, 1, 2, and 3, and the sum of l is in the range of 0 to 4. A compound of general formula (Ia), (IIIa), or (IVa) as described in any of claims 61 to 100 above.

102. The compound comprises at least one part of the following structure: (Fatty alcohol)-O-C(O)-(mono or oligo C8-C24 hydroxy fatty acid)-O-C(O)-(C1-C12 hydrocarbon)-C(O)-O-(mono or oligo C8-C24 hydroxy fatty acid)-C(O)-O-(fatty alcohol) A compound of general formula (Ia), (IIIa), or (IVa) as described in any of claims 61 to 101 above.

103. The compound comprises at least one part of the following structure: -([-O-C(O)-R ６ (-O-C(O)-R ６ ) ｌ -O-C(O)-L-C(O)-O-(R ６ -C(O)-O) ｌ -R ６ -C(O)O])-R １１ 、 Here L, l, R ６ and R １１ This is as defined above. A compound of general formula (Ia), (IIIa), or (IVa) as described in any of claims 61 to 102 above.

104. Use of a compound of formula (Ia), (IIIa), or (IVa) as defined in any of claims 61 to 103 in a cosmetic formulation for skin and / or hair care, such as a conditioner and shampoo.

105. Use of a compound of formula (Ia), (IIIa), or (IVa) as defined in any of claims 61 to 103 for use in the treatment of fibers, preferably amino acid-based fibers, more preferably human hair, particularly for hair treatments such as color-retaining hair treatments, hair shine enhancement, hair color enhancement, hair color protection, hair conditioning, hair smoothing or softening, and hair manageability, particularly for improving combability and improving frizz prevention and antistatic properties of hair.

106. A hair treatment composition comprising at least one compound of formulas (I), (III), and (IV) or (Ia), (IIIa), and (IVa) as defined in claims 1 to 103, selected from the group consisting of hair shampoo compositions, hair conditioning compositions, hair strengthening compositions, hair coloring or dyeing compositions, hair combability improving compositions, hair frizz prevention compositions, and hair rinse-off and leave-on compositions.

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