Composite fiber, method for manufacturing the same, and fiber structure containing the same

Abstract

The present invention provides a composite fiber that can be processed into a fibrous structure having good flexibility and bulkiness, a method for manufacturing the same, and a fibrous structure containing the same. [Solution] This invention relates to a composite fiber comprising a first component containing poly-L-lactic acid with an optical purity of 95% or more, and a second component containing an aliphatic polyester composed of glycol and dicarboxylic acid, wherein, in a DSC curve obtained by differential scanning calorimetry (DSC), the crystallization temperature of the second component during the cooling process is 78°C or higher, and the heat of fusion per unit mass of the second component during the second heating process is 73.5 mJ / mg or less. The composite fiber can be manufactured by melt-spinning the first component at a lower temperature than the second component, and then stretching it at a temperature of 55°C to 90°C and a stretch ratio of 1.4 times or more. This makes it possible to provide a composite fiber that can be processed into a fiber structure having good flexibility and bulkiness, a method for manufacturing the same, and a fiber structure containing the same.

Description

[Technical Field]

[0001] The present invention relates to a composite fiber comprising a first component containing polylactic acid and a second component containing aliphatic polyester, a method for producing the same, and a fiber structure containing the same. [Background technology]

[0002] Composite fibers containing low-melting-point and high-melting-point resin components are widely used as materials for fibrous structures such as nonwoven fabrics. In recent years, in order to be environmentally conscious, biomass-derived resins or biodegradable resins have been used in composite fibers. For example, Patent Documents 1 to 4 propose composite fibers using polylactic acid as the core component and polybutylene succinate as the sheath component. [Prior art documents] [Patent Documents]

[0003] [Patent Document 1] Japanese Patent Publication No. 2006-112012 [Patent Document 2] Japanese Patent Publication No. 2007-119928 [Patent Document 3] Japanese Patent Publication No. 2007-126780 [Patent Document 4] Japanese Patent Publication No. 2014-37656 [Overview of the project] [Problems that the invention aims to solve]

[0004] However, the nonwoven fabrics using composite fibers containing polylactic acid and polybutylene succinate described in Patent Documents 1 to 4 lack flexibility and bulkiness, and further improvements in texture are needed.

[0005] To solve the aforementioned conventional problems, the present invention provides a composite fiber that can be processed into a fiber structure having good flexibility and bulkiness, a method for producing the same, and a fiber structure containing the same. [Means for solving the problem]

[0006] The present invention relates to a composite fiber comprising a first component containing poly-L-lactic acid with an optical purity of 95% or more, and a second component containing an aliphatic polyester composed of glycol and dicarboxylic acid, wherein the second component occupies 50% or more of the fiber surface, and the composite fiber is such that, in a DSC curve obtained by differential scanning calorimetry (DSC), the crystallization temperature of the second component during the cooling process is 78.0°C or higher, and the heat of fusion per unit mass of the second component during the second heating process is 73.5 mJ / mg or less.

[0007] The present invention also relates to a method for producing a composite fiber, comprising the steps of: preparing a first component containing 70% by mass or more of poly-L-lactic acid with an optical purity of 95% or more, and a second component containing 70% by mass or more of an aliphatic polyester consisting of glycol and dicarboxylic acid; melt-spinning the first component and the second component to produce a spun filament; and stretching the spun filament to obtain a composite fiber in which the second component occupies 50% or more of the fiber surface, wherein in the step of producing the spun filament, the first component is melt-spun at a lower temperature than the second component, and in the stretching step, the stretching temperature is 55°C or higher and 90°C or lower, and the stretching ratio is 1.4 times or higher.

[0008] The present invention also relates to a fiber structure containing 5% by mass or more of the composite fiber. [Effects of the Invention]

[0009] The present invention can provide a composite fiber that can be processed into a fibrous structure having good flexibility and bulkiness. The present invention can also provide a fibrous structure having good flexibility and bulkiness. According to the manufacturing method of the present invention, composite fibers having good flexibility and bulkiness can be obtained. [Brief explanation of the drawing]

[0010] [Figure 1]The DSC curve obtained by differential scanning calorimetry (DSC) of the composite fiber of Example 8. [Figure 2] Among the DSC curves obtained by differential scanning calorimetry (DSC) of the composite fiber of Example 8, it is a partial view of the DSC curve in the first heating process. [Figure 3] In the DSC curve obtained by differential scanning calorimetry (DSC), it is a schematic explanatory diagram of a method for calculating the peak height / full width at half maximum ratio of the first component in the first heating process.

Mode for Carrying Out the Invention

[0011] In order to solve the above conventional problems, the present inventor repeated studies. As a result, in a composite fiber containing a first component containing poly-L-lactic acid and a second component containing an aliphatic polyester composed of glycol and dicarboxylic acid, the non-woven fabric obtained by thermally processing the conventional composite fiber has high stiffness and softness, but is inferior in flexibility and bulkiness. However, in the DSC curve obtained by differential scanning calorimetry (DSC) of the composite fiber, the crystallization temperature of the second component in the cooling process is 78 °C or higher, and the heat of fusion per unit mass of the second component in the second heating process is 73.5 mJ / mg or less. By controlling the melting and solidification states of the second component within the above range, it has been found that the processability during thermal processing of the non-woven fabric is also improved, and a non-woven fabric excellent in flexibility and bulkiness can be obtained.

[0012] Specifically, if the crystallization temperature per unit mass of the second component during the cooling process is 78.0°C or higher, the solidification temperature of the resin after melt extrusion is high during melt spinning, resulting in faster cooling and enabling high-speed take-up, thus allowing for finer fiber denier production. Furthermore, even during the cooling of the second component present on the fiber surface after melting during processing into nonwoven fabric, the high solidification temperature makes it suitable for high-speed production, and the amount of heat transferred to the first component is reduced, making it easier to obtain bulkiness. Moreover, if the heat of fusion per unit mass of the second component during the second heating process is 73.5 mJ / mg or less, the second component has appropriate crystallinity, so it melts easily during processing into nonwoven fabric, has adhesive strength, and does not transfer excessive heat to the first component, resulting in a nonwoven fabric with good texture (bulkiness and adhesion).

[0013] Unlike Patent Documents 1-4, we have discovered that by melt-spinning the first component at a lower temperature than the second component and then stretching it at a predetermined stretching temperature and stretching ratio, we can obtain a composite fiber that satisfies the above requirements. Normally, in composite spinning, the spinning temperature of the component with a high melting point is set higher than that of the component with a low melting point, or the spinning temperatures of the components with high and low melting points are set to the same. However, in this invention, surprisingly, we have found that by setting the spinning temperature of the first component with a high melting point lower than that of the second component with a low melting point, the spinnability of the composite fiber is improved, and the flexibility and bulkiness of the nonwoven fabric using the obtained composite fiber are improved.

[0014] Furthermore, by ensuring that the crystallization temperature of the second component during the cooling process is 78°C or higher, and the heat of fusion per unit mass of the second component is 73.5 mJ / mg or less, as measured by differential scanning calorimetry (DSC) of the composite fiber, the resulting DSC curve is less prone to adhesion (sticking) during spinning and / or drawing, reducing the likelihood of yarn breakage and making it easier to obtain highly productive fibers. When crimp is applied to the fibers, the crimp shape is easier to maintain, and the crimp development is also easier to achieve. Moreover, it is possible to draw the fibers at a ratio close to the maximum draw ratio (Vmax), allowing for the production of finer composite fibers. The composite fibers obtained in this way exhibit excellent fiber web formation properties when processed into nonwoven fabrics, resulting in a uniform nonwoven fabric.

[0015] In this invention, differential scanning calorimetry (DSC) is performed under the following conditions, based on JIS K 7121:1987. A sample of 3.0 mg of fiber is weighed and then placed in the sample holder. Next, the fiber placed in the sample holder is heated from room temperature (23±2°C) to 250°C at a rate of 5°C / min (first heating process), and a DSC measurement is performed during the first melting. After reaching 250°C, it is held for 10 minutes, and then the temperature is lowered from 250°C to 40°C at a rate of 1°C / min (cooling process), allowing the molten sample to solidify. At this time, the DSC is measured during the cooling process. After the first heating and cooling processes are completed, the sample is not removed from the DSC measuring instrument, held at 40°C for 10 minutes, and then heated again from 40°C to 250°C at a rate of 5°C / min (second heating process), and a DSC measurement is performed during the second melting.

[0016] In the DSC curve obtained by differential scanning calorimetry (DSC) of the composite fiber of the present invention, from the viewpoint of preventing fusion between fibers, the crystallization temperature of the second component during the cooling process is preferably 78.0°C to 115.0°C, more preferably 79.0°C to 105.0°C, even more preferably 80.0°C to 100.0°C, even more preferably 81.0°C to 95.0°C, and particularly preferably 82.0°C to 93.0°C. In the present invention, the crystallization temperature of the second component during the cooling process of the DSC curve refers to the temperature at the exothermic peak of the second component in the DSC curve obtained during the cooling process.

[0017] In the DSC curve obtained by differential scanning calorimetry (DSC) of the composite fiber of the present invention, from the viewpoint of improving the bulkiness and adhesion of the nonwoven fabric, the heat of fusion per unit mass of the second component in the second heating process is preferably 25.0 mJ / mg or more and 73.5 mJ / mg or less, more preferably 27.0 mJ / mg or more and 72.5 mJ / mg or less, even more preferably 28.5 mJ / mg or more and 71.5 mJ / mg or less, even more preferably 30.0 mJ / mg or more and 70.5 mJ / mg or less, and particularly preferably 32.0 mJ / mg or more and 69.5 mJ / mg or less. In the present invention, the heat of fusion per unit mass of the second component in the second heating process of the DSC curve is calculated by determining the heat of fusion from the endothermic peak of the second component in the DSC curve obtained in the second heating process, and converting the determined heat of fusion to the heat of fusion per 1 mg of the second component.

[0018] In the DSC curve obtained by differential scanning calorimetry (DSC) of the composite fibers of the present invention, from the viewpoint of further improving the flexibility, bulkiness, and texture of the nonwoven fabric, the amount of heat of fusion per unit mass of the second component in the first heating process is preferably 68.0 mJ / mg or less, more preferably 25.0 mJ / mg or more and 68.0 mJ / mg or less, even more preferably 27.0 mJ / mg or more and 67.0 mJ / mg or less, particularly preferably 30.0 mJ / mg or more and 66.0 mJ / mg or less, even more preferably 32.0 mJ / mg or more and 64.0 mJ / mg or less, even more preferably 35.0 mJ / mg or more and 62.0 mJ / mg or less, even more preferably 37.0 mJ / mg or more and 59.0 mJ / mg or less, and particularly preferably 40.0 mJ / mg or more and 55.0 mJ / mg or less. If the heat of fusion per unit mass of the second component during the first heating process is 68.0 mJ / mg or less, the second component present on the fiber surface melts quickly during processing into a nonwoven fabric, and the fibers adhere in a short time, enabling high-speed production. Furthermore, the thermal impact on the first component is minimized, thus maintaining the bulkiness of the card web and ultimately yielding a bulky nonwoven fabric. In this invention, the heat of fusion per unit mass of the second component during the first heating process of the DSC curve is calculated by determining the heat of fusion from the endothermic peak of the second component in the DSC curve obtained during the first heating process, and then converting the determined heat of fusion to the heat of fusion per 1 mg of the second component.

[0019] In the DSC curve obtained by differential scanning calorimetry (DSC) of the composite fibers of the present invention, from the viewpoint of more effectively preventing fusion between fibers and further improving the flexibility and bulkiness of the nonwoven fabric, it is preferable that the crystallization heat per unit mass of the second component during the cooling process is 59.5 mJ / mg or less, more preferably 15.0 mJ / mg or more and 59.5 mJ / mg or less, even more preferably 20.0 mJ / mg or more and 56.0 mJ / mg or less, even more preferably 25.0 mJ / mg or more and 53.0 mJ / mg or less, even more preferably 30.0 mJ / mg or more and 50.0 mJ / mg or less, and particularly preferably 35.0 mJ / mg or more and 48.5 mJ / mg or less. When the crystallization heat per unit mass of the second component during the cooling process is 59.5 mJ / mg or less, the second component present on the fiber surface during processing into a nonwoven fabric solidifies quickly during cooling after melting, so the nonwoven fabric does not collapse. In this invention, the amount of heat of crystallization per unit mass of the second component during the cooling process of the DSC curve is calculated by determining the amount of heat of crystallization from the exothermic peak of the second component in the DSC curve obtained during the cooling process, and then converting the determined amount of heat of crystallization to the amount of heat of crystallization per 1 mg of the second component.

[0020] In the DSC curve obtained by differential scanning calorimetry (DSC) of the composite fiber of the present invention, from the viewpoint of further improving the flexibility and bulkiness of the nonwoven fabric, the ratio of the peak height (endothermic peak) of the first component to the width at half maximum in the first heating process is preferably 11.0 or less, more preferably 10.5 or less, even more preferably 10.0 or less, even more preferably 9.5 or less, even more preferably 9.0 or less, and particularly preferably 8.5 or less. Furthermore, the ratio of the peak height (endothermic peak) of the first component to the width at half maximum in the first heating process is preferably 2.0 or more, more preferably 2.5 or more, even more preferably 3.0 or more, even more preferably 3.5 or more, even more preferably 4.0 or more, and particularly preferably 4.5 or more. If the ratio of the peak height to the full width at half maximum (FWHM) of the first component during the first heating process is within the range described above, the endothermic peak (melting peak) of the first component (polylactic acid) constituting the core component of the composite fiber will have a relatively broad shape. This eliminates the drawbacks of polylactic acid, which is generally said to be hard and brittle, and makes it easier to obtain a nonwoven fabric with good flexibility and bulkiness. In this invention, the peak FWHM in the DSC curve is measured based on the FWHM method of the Japanese Pharmacopoeia.

[0021] In this invention, the ratio of the peak height (endothermic peak) to the full width at half maximum (FWHM) of the first component in the DSC curve during the first heating process can be calculated as follows. Figure 3 is a schematic diagram illustrating the method for calculating the peak height / FWHM ratio of the first component in the first heating process in a DSC curve obtained by differential scanning calorimetry (DSC). (1) Draw a perpendicular line L1 from the peak top St of the endothermic peak to the baseline Lb, and define the length of the perpendicular line as the peak height (h). In the case of a double peak, use the highest peak. (2) The distance between point S1 and point S2 where the endothermic peak curve intersects a line drawn perpendicular to the perpendicular L1 from position Sh, which is half the peak height of the perpendicular L1 (h / 2), is defined as the full width at half maximum (Wh). (3) Calculate the peak ratio using formula 1 below. [Formula 1] Peak ratio = h / Wh

[0022] In the DSC curve obtained by differential scanning calorimetry (DSC) of the composite fiber of the present invention, from the viewpoint of further improving the flexibility and bulkiness of the nonwoven fabric, it is preferable that the heat of fusion per unit mass of the first component in the first heating process is 30.0 mJ / mg or more, more preferably 30.0 mJ / mg or more and 100.0 mJ / mg or less, even more preferably 35.0 mJ / mg or more and 90.0 mJ / mg or less, even more preferably 40.0 mJ / mg or more and 80.0 mJ / mg or less, even more preferably 42.0 mJ / mg or more and 75.0 mJ / mg or less, and particularly preferably 45.0 mJ / mg or more and 70.0 mJ / mg or less. In this invention, the heat of fusion per unit mass of the first component in the first heating process of the DSC curve is calculated by determining the heat of fusion from the endothermic peak of the first component in the DSC curve obtained in the first heating process, and then converting the determined heat of fusion to the heat of fusion per 1 mg of the first component.

[0023] In the DSC curve obtained by differential scanning calorimetry (DSC) of the composite fibers of the present invention, from the viewpoint of preventing fusion between fibers and improving the processability of the nonwoven fabric, the crystallization time of the second component during the cooling process is preferably 208 minutes or more and 228 minutes or less, more preferably 210 minutes or more and 227 minutes or less, even more preferably 212 minutes or more and 226 minutes or less, even more preferably 214 minutes or more and 225 minutes or less, and particularly preferably 216 minutes or more and 224 minutes or less. In the present invention, the crystallization time of the second component during the cooling process of the DSC curve refers to the time at the exothermic peak of the second component in the DSC curve obtained during the cooling process.

[0024] The first component contains poly-L-lactic acid. The poly-L-lactic acid preferably has a melting point of 160°C or higher, more preferably 165°C or higher, even more preferably 168°C or higher, and particularly preferably 173°C or higher. When the melting point of poly-L-lactic acid is 160°C or higher, the difference in melting point with the sheath component is not small, and the difference with the processing temperature when heat-processing fibrous structures such as nonwoven fabrics is large, so that it does not deteriorate during heat processing. The upper limit of the melting point of poly-L-lactic acid is preferably 230°C or lower.

[0025] The first component may contain a nucleating agent. Any known nucleating agent may be used, but preferably, inorganic fillers such as calcium carbonate, talc, silica, and aluminum compounds, fatty acid metal salts such as calcium stearate, phosphate ester metal salts, amide compounds, minerals such as mica and urastonite, and barium sulfate. The nucleating agent may be added in an amount of 0.01 parts by mass to 10 parts by mass per 100 parts by mass of poly-L-lactic acid, preferably 0.05 parts by mass to 5 parts by mass.

[0026] The optical purity of poly-L-lactic acid is 95% or higher, preferably 98.0% or higher, more preferably 98.5% or higher, even more preferably 99.0% or higher, and particularly preferably 99.5% or higher. When the optical purity is 95% or higher, it does not degrade during heat processing and its bulk recovery properties are improved.

[0027] The poly-L-lactic acid used in this invention tends to have high heat resistance and high flexural elasticity, making it easier to obtain nonwoven fabrics with low thermal shrinkage, high bulk, and excellent bulk recovery.

[0028] In addition to poly-L-lactic acid, other resins may be mixed into the first component, as long as they do not hinder the effects of the present invention. Examples of other resins include aromatic polyesters such as polyethylene terephthalate, polybutylene terephthalate, and polytrimethylene terephthalate, aromatic aliphatic polyesters, aliphatic polyesters, and polyolefins. The proportion of poly-L-lactic acid in the first component is preferably 70% by mass or more, more preferably 80% by mass or more, even more preferably 90% by mass or more, and most preferably 95% by mass or more.

[0029] The second component comprises an aliphatic polyester consisting of a glycol and a dicarboxylic acid. The aliphatic polyester is preferably a polyalkylene carboxylate, specifically polybutylene succinate, polybutylene adipate, polybutylene sebacate, polyethylene oxalate, polyethylene succinate, polyethylene adipate, polyethylene azelate, polyhexamethylene sebacate, polyneopentyl oxalate, and copolymers thereof. Among these, polybutylene succinate, which is a condensate of succinic acid and 1,4-butanediol, and / or its copolymers are preferred because they have a relatively high melting point of about 110°C, excellent fiber productivity, nonwoven fabric processability and nonwoven fabric properties, and can be used as a biomass raw material.

[0030] The melting point of the aliphatic polyester is preferably 100°C to 130°C, and more preferably 110°C to 125°C. If the melting point is 100°C or higher, the molten resin discharged from the nozzle during melt spinning solidifies quickly, suppressing the formation of fused yarns. If the melting point is 130°C or lower, the difference in melting point with the first component is large, preventing deformation during heat processing.

[0031] The second component preferably contains a nucleating agent from the viewpoint of improving spinnability. Examples of nucleating agents include inorganic nucleating agents and organic nucleating agents. Examples of inorganic nucleating agents include inorganic fillers such as calcium carbonate, talc, silica, and aluminum compounds, minerals such as mica and urastonite, and barium sulfate. Examples of organic nucleating agents include fatty acid metal salts, phosphate ester metal salts, and amide compounds. Organic nucleating agents are preferred, and fatty acid metal salts are particularly preferred. Fatty acid metal salts further have the effect of improving heat resistance after fiber formation because they yield uniform and fine crystals. Examples of fatty acid metal salts include sodium laurate, potassium laurate, potassium hydrogen laurate, magnesium laurate, calcium laurate, zinc laurate, sodium myristate, potassium hydrogen myristate, magnesium myristate, calcium myristate, zinc myristate, silver myristate, aluminum myristate, potassium palmitate, magnesium palmitate, calcium palmitate, zinc palmitate, copper palmitate, lead palmitate, sodium oleate, potassium oleate, magnesium oleate, calcium oleate, zinc oleate, lead oleate, copper oleate, nickel oleate, sodium stearate, calcium stearate, magnesium stearate, zinc stearate, barium stearate, aluminum stearate, and t Lium, lead stearate, nickel stearate, zinc montanate, calcium morutanate, magnesium morutanate, sodium 12-hydroxystearate, lithium 12-hydroxystearate, lead 12-hydroxystearate, nickel 12-hydroxystearate, zinc 12-hydroxystearate, calcium 12-hydroxystearate, magnesium 12-hydroxystearate, barium 12-hydroxystearate, potassium isostearate, magnesium isostearate, calcium isostearate, aluminum isostearate, zinc isostearate, nickel isostearate, sodium behenate, potassium behenate, magnesium behenate, calcium behenate, zinc behenate, nickel behenate, sodium montanate, potassium montanate,Magnesium montana, calcium montana, aluminum montana, zinc montana, nickel montana, sodium octoate, lithium octoate, magnesium octoate, calcium octoate, barium octoate, aluminum octoate, nickel octoate, sodium sebacate, lithium sebacate, magnesium sebacate, calcium sebacate, barium sebacate, aluminum sebacate, thallium sebacate, lead sebacate, nickel sebacate, undecile Examples include sodium undecylenate, lithium undecylenate, magnesium undecylenate, calcium undecylenate, barium undecylenate, aluminum undecylenate, lead undecylenate, nickel undecylenate, bevelium undecylenate, sodium ricinoleate, lithium ricinoleate, magnesium ricinoleate, calcium ricinoleate, barium ricinoleate, aluminum ricinoleate, thallium ricinoleate, lead ricinoleate, nickel ricinoleate, and bevelium ricinoleate. Among the above, it is preferable to use a metal salt with a valency of 2 or higher. Using a metal salt with a valency of 2 or higher facilitates the formation of a physical crosslink structure, which restricts the mobility of the polymer chain segments and allows them to act as crystal nuclei, enabling rapid crystallization. Furthermore, from the viewpoint of spinnability, a fatty acid metal salt exhibiting a melting point higher than the resin melting point of the second component is preferred, and a metal salt with high bonding strength to fatty acids is preferred. Examples include calcium, magnesium, and zinc, but calcium is particularly preferred. In addition, as the fatty acid, a saturated fatty acid with a high melting point is preferred. The number of carbon atoms in the fatty acid is preferably between 12 and 28, and more preferably between 14 and 20. Within this range, the molecular chain is not too long, and the melting point is lower than the spinning temperature of the second component, allowing the nucleating agent to disperse uniformly within the resin. Particularly preferred is one or more selected from the group consisting of calcium stearate, magnesium stearate, and zinc stearate.

[0032] From the viewpoint of increasing crystallinity and improving spinnability, the second component preferably contains 0.01 parts by mass to 20 parts by mass of the nucleating agent per 100 parts by mass of the aliphatic polyester, more preferably 0.03 parts by mass to 10 parts by mass, and even more preferably 0.06 parts by mass to 5 parts by mass. If the nucleating agent is an inorganic nucleating agent, from the viewpoint of promoting the crystallization of the resin, it is preferable to contain 0.1 parts by mass to 20 parts by mass of the inorganic nucleating agent per 100 parts by mass of the aliphatic polyester, more preferably 0.5 parts by mass to 10 parts by mass, and even more preferably 1.0 part by mass to 5.0 parts by mass. If the nucleating agent is an organic nucleating agent, from the viewpoint of promoting the crystallization of the resin, it is preferable to contain 0.01 parts by mass to 5.0 parts by mass of the organic nucleating agent per 100 parts by mass of the aliphatic polyester, more preferably 0.03 parts by mass to 4.0 parts by mass, and even more preferably 0.06 parts by mass to 3.0 parts by mass.

[0033] In addition to the aliphatic polyester, other resins may be mixed into the second component, as long as they do not hinder the effects of the present invention. Examples of other resins include polylactic acid, polyhydroxybutyrate, polyhydroxybutyrate variate, polycaprolactam, and aromatic polyesters, polyamides, polyolefins, etc. The proportion of the aliphatic polyester in the second component is preferably 70% by mass or more, more preferably 80% by mass or more, even more preferably 90% by mass or more, and most preferably 95% by mass or more.

[0034] The shape of the fiber cross-section is not particularly limited, as long as the second component occupies 50% or more of the fiber surface. For example, the shape of the fiber cross-section of the first component may be anything other than circular, such as a semicircle, ellipse, Y-shape, X-shape, grid, polygon, or star shape. The shape of the fiber cross-section of the composite fiber may be anything other than circular, such as an ellipse, Y-shape, X-shape, grid, polygon, or star shape, or it may be hollow.

[0035] From the viewpoint of strength and bulkiness of the nonwoven fabric, the composite fiber is preferably a core-sheath composite fiber in which the first component is a core component and the second component is a sheath component, and more preferably a concentric core-sheath composite fiber in which the center position of the first component coincides with the center position of the fiber. The composite fiber may also be an eccentric core-sheath composite fiber in which the center position of the first component does not coincide with the center position of the composite fiber.

[0036] The composite fibers preferably have a composite ratio (first component / second component) of 80 / 20 to 30 / 70 by mass, more preferably 75 / 25 to 35 / 65, even more preferably 70 / 30 to 40 / 60, even more preferably 65 / 35 to 50 / 50, and particularly preferably 60 / 40 to 55 / 45. Having a composite ratio within the above range makes the nonwoven fabric more flexible and improves its strength and bulk recovery.

[0037] The composite fiber preferably has a crimp ratio of 2% to 20%, and more preferably 4% to 15%. A crimp ratio of 2% or more makes it easier to obtain a bulky nonwoven fabric because the fibers do not become straight. A crimp ratio of 20% or less results in good defibration properties, making it easier to obtain card webs and airlaid webs with good form.

[0038] In the aforementioned composite fiber, the crimp shape is not particularly limited and any crimp shape such as mechanical crimp, wave-shaped crimp, or spiral crimp may be used.

[0039] The single fiber strength of the composite fiber is not particularly limited, but is preferably 1.0 cN / dtex or more and 5.0 cN / dtex or less, and more preferably 1.0 cN / dtex or more and 4.0 cN / dtex or less. If it is 1.0 cN / dtex or more, the occurrence of fiber breakage in the carding process is suppressed. If it is 4.0 cN / dtex or less, the bulk recovery and flexibility of the fiber structure such as nonwoven fabric are good.

[0040] The fineness of the single fibers of the composite fibers is not particularly limited, but from the viewpoint of bulk recovery of fibrous structures such as nonwoven fabrics, it is preferably 0.3 dtex or more and 30 dtex or less, more preferably 1 dtex or more and 20 dtex or less, even more preferably 1.5 dtex or more and 10 dtex or less, even more preferably 1.6 dtex or more and 8 dtex or less, even more preferably 1.7 dtex or more and 6 dtex or less, and particularly preferably 1.8 dtex or more and 3 dtex or less.

[0041] The composite fiber of the present invention can be produced by melt-spinning the first component at a lower temperature than the second component and stretching it under predetermined conditions.

[0042] First, a first component containing 70% by mass or more of poly-L-lactic acid with an optical purity of 95% or higher, and a second component containing 70% by mass or more of an aliphatic polyester consisting of glycol and dicarboxylic acid are prepared. The first component preferably contains 80% by mass or more of the poly-L-lactic acid, more preferably 90% by mass or more, and particularly preferably 95% by mass or more. The second component preferably contains 80% by mass or more of the aliphatic polyester, more preferably 90% by mass or more, and particularly preferably 95% by mass or more. The poly-L-lactic acid and aliphatic polyester can be those described above.

[0043] Next, the first and second components are melt-spun to produce a spun filament in which the second component occupies 50% or more of the fiber surface (hereinafter also referred to as the "spinning process"). Specifically, a composite nozzle that provides a predetermined fiber cross-section is attached to a melt-spinning machine, and the first and second components are extruded and melt-spun so that the second component occupies 50% or more of the fiber surface to obtain a spun filament (i.e., an undrawn filament). In the spinning process, the first component is melt-spun at a lower temperature than the second component. This facilitates the cooling of the first component, allowing for faster crystallization, and thus making it easier to control the crystallization of the first component. As a result, a spun filament with less crystal orientation and finer denier can be obtained. The spun filament has good drawability, and not only does it become a fiber with consistent crystallinity and orientation during drawing, but it can also be made even finer after drawing. Furthermore, a composite fiber with high crystallinity of the second component can be obtained. It is preferable to melt-spin the first component at a temperature 1°C to 30°C lower than that of the second component, more preferably at a temperature 3°C to 20°C lower, even more preferably at a temperature 5°C to 18°C ​​lower, and particularly preferably at a temperature 7°C to 16°C lower. Specifically, the first component may be melt-spun at a temperature of 200°C to 240°C and the second component at a temperature of 220°C to 250°C; the first component may be melt-spun at a temperature of 205°C to 235°C and the second component at a temperature of 225°C to 245°C; the first component may be melt-spun at a temperature of 210°C to 230°C and the second component at a temperature of 225°C to 240°C; or the first component may be melt-spun at a temperature of 215°C to 225°C and the second component at a temperature of 225°C to 235°C.

[0044] Next, the spun filament is stretched to obtain a stretched filament (composite fiber).

[0045] The stretching process may be a single-stage stretching process, or a multi-stage stretching process with two or more stages. In single-stage stretching or the first stage of multi-stage stretching, the stretching temperature is set to 55°C or higher and 90°C or lower. If the stretching temperature is 90°C or lower, fusion will not occur during the stretching process. If the stretching temperature is 55°C or higher, a high degree of stretching is possible. Preferably, the stretching temperature is 60°C or higher and 85°C or lower, and more preferably 70°C or higher and 80°C or lower. In the second and subsequent stages of multi-stage stretching, preferably, the stretching temperature is 60°C or higher and 100°C or lower, more preferably 70°C or higher and 95°C or lower, and particularly preferably 75°C or higher and 90°C or lower. In the case of multi-stage stretching, it is preferable that the stretching temperature for the second and subsequent stages is the same as or higher than that of the first stage. The temperature difference between the first stage and the subsequent stages is preferably 0°C to 30°C, more preferably 0°C to 25°C, even more preferably 1°C to 20°C, and particularly preferably 2°C to 17°C.

[0046] The stretching ratio is 1.4 times or more. This increases the crystallinity of the first and second components, and consequently improves the flexibility and bulkiness of the nonwoven fabric. The stretching ratio is preferably 1.4 times or more and 3.8 times or less, more preferably 1.5 times or more and 3.5 times or less, even more preferably 1.6 times or more and 3.2 times or less, even more preferably 1.7 times or more and 2.9 times or less, and particularly preferably 1.8 times or more and 2.6 times or less. When the stretching ratio is 1.4 times or more, the spun filament can be uniformly stretched without yarn breakage occurring during the stretching process. The stretching treatment may be a single-stage stretching or a multi-stage stretching of two or more stages. Furthermore, the second and subsequent stages of multi-stage stretching may be a tension heat set, in which heat treatment is performed in a tensioned state, or a relaxation heat set, in which heat treatment is performed in a relaxed state. In the case of a tension heat set, it may be 1.0 times or more and 1.2 times or more and 1.0 times or more and 1.1 times or less. In the case of relaxation heat setting, the stretch ratio may be 0.9 times or more and less than 1.0 times, and may be 0.95 times or more and less than 1.0 times. For the second and subsequent stages of multi-stage stretching, tension heat setting is preferable. Performing tension heat setting allows the crystallinity of the first and second components to be adjusted and stabilized, thereby improving processability during subsequent secondary molding (e.g., nonwoven molding). Furthermore, the adjustment of crystallinity improves the texture of the nonwoven fabric and also improves its bulkiness. In the case of multi-stage stretching, the stretch ratio is the product of the stretch ratio of each stage.

[0047] In the stretching process, the stretching ratio is preferably 60% to 99% of the maximum stretching ratio (Vmax), more preferably 65% ​​to 99%, and even more preferably 70% to 99%. When the stretching ratio is 60% to 99% of the maximum stretching ratio, it is possible to stretch the yarn to a high degree while suppressing yarn breakage during the stretching process.

[0048] The drawing method may be either a wet drawing method or a dry drawing method. As a heat transfer medium, air, steam, water, oils such as glycerin, etc., can be used as appropriate. In the case of a wet drawing method, drawing can be performed while heating in a liquid, for example, in hot water or warm water. In the case of a dry drawing method, drawing can be performed while heating in a high-temperature gas or with a high-temperature metal roll, etc. Drawing is preferably performed in warm water. This is because, in the case of a core-sheath type composite fiber, drawing in warm water makes it easier to create strain in the core and sheath components, and makes it easier to curve the crimp peaks.

[0049] In this invention, "maximum stretch ratio (Vmax)" refers to the value measured as follows: Melt spinning is performed using a core-sheath type composite nozzle, and the resulting spun filament (undrawn fiber bundle) is wet-drawn in hot water at a predetermined temperature. At this time, the feed speed (V1) of the roll that feeds out the undrawn fiber bundle is set to 10 m / min, and the winding speed (V2) of the metal roll that takes up the fiber is gradually increased from 10 m / min. The winding speed of the metal roll that takes up the fiber is set to the maximum stretch speed when the undrawn fiber bundle breaks, and the ratio of the maximum stretch speed to the feed speed of the roll that feeds out the undrawn fiber bundle (V2 / V1) is calculated, and the obtained speed ratio is set to the maximum stretch ratio (Vmax).

[0050] In the case of a single-stage stretching process, or when the same stretching method and temperature are used for multiple stretching processes, the maximum stretching ratio can be measured using the same method and temperature as the stretching process performed. When stretching a spun filament using a multi-stage stretching process, where the stretching temperature differs for each stretching process, the maximum stretching ratio should be measured using the same stretching method and temperature as the stretching process performed at the higher temperature.

[0051] When spinning a filament using a multi-stage drawing process, where the drawing temperature is the same for all drawing processes but the drawing methods differ, the maximum drawing ratio should be measured for both methods, and the larger of the two maximum drawing ratios should be taken as the maximum drawing ratio under those manufacturing conditions.

[0052] The resulting drawn filaments are then coated with a predetermined amount of fiber treatment agent as needed, and further mechanical crimping is applied using a crimper (crimping device) as needed. When nonwoven fabrics are manufactured using a wet papermaking method, the fiber treatment agent can easily disperse the fibers in water or other liquids. Furthermore, applying an external force from the fiber surface to the fibers coated with the fiber treatment agent (for example, the force applied when crimping is applied by a crimper) allows the fiber treatment agent to permeate the fibers, further improving its dispersibility in water or other liquids.

[0053] The drawn filaments, after being treated with a fiber treatment agent (or while wet but without the treatment agent), are dried at a temperature between 80°C and 110°C for several seconds to about 30 minutes to dry the fibers. The drying process may be omitted in some cases. After that, the drawn filaments are cut so that the fiber length is preferably between 1 mm and 100 mm, more preferably between 2 mm and 70 mm.

[0054] In the case of core-sheath type composite fibers, the core component poly-L-lactic acid and the sheath component aliphatic polyester have high compatibility, making core-sheath delamination less likely and allowing for the production of high-strength heat-bonded nonwoven fabrics. Furthermore, the aliphatic polyester sheath component also exhibits excellent adhesion to polylactic acid, polyesters other than poly-L-lactic acid, and cellulose, resulting in nonwoven fabrics with stronger bonding points.

[0055] The composite fibers of the present invention can be used, for example, in fiber structures such as yarn, nonwoven fabrics, and woven or knitted fabrics. The fiber structure may contain 5% by mass or 10% by mass or more of the composite fibers. In particular, when used as a nonwoven fabric, it is preferable that it contains 5% by mass or more of the composite fibers of the present invention, and that the second component of the composite fibers melts so that the constituent fibers are heat-bonded to each other. The nonwoven fabric may contain 20% by mass or more, 30% by mass or more, 40% by mass or more, 50% by mass or more, 60% by mass or more, 70% by mass or more, 80% by mass or more, 90% by mass or more, 95% by mass or more, or 100% by mass of the composite fibers. When other fibers are included, for example, natural fibers, regenerated fibers, and synthetic fibers can be used as other fibers. Examples of the above-mentioned natural fibers include cotton, silk, wool, hemp, pulp, and kapok. Examples of the above-mentioned regenerated fibers include rayon, cupro, and polynosic. Examples of the above-mentioned synthetic fibers include acrylic fibers, polyester fibers, polyamide fibers, polyolefin fibers, and polyurethane fibers. As for other fibers, one or more types of fibers can be appropriately selected from the above-mentioned fibers depending on the application.

[0056] Examples of fiber web configurations constituting the nonwoven fabric of the present invention include parallel webs, semi-random webs, random webs, crosslay webs, crisscross webs, airlaid webs, and wet-machine webs. The fiber webs exert their effects when the second component is bonded by heat treatment. The fiber webs may also be subjected to needle punching or water entanglement treatment as needed. The heat treatment method is not particularly limited, but any method that fully exhibits the functionality of the composite fibers of the present invention is acceptable, and it is preferable to use a heat treatment machine that does not apply excessive pressure, such as air pressure, such as a hot air penetration heat treatment machine, a hot air upward and downward blowing heat treatment machine, or an infrared heat treatment machine.

[0057] The aforementioned nonwoven fabric has an excellent initial bulkiness of 2.96 N / cm². 3 The specific volume under load is 20 cm³. 3It is preferably 30 cm or more per g, and more preferably 100 cm or more and 100 cm or less per g. From the viewpoint of excellent bulk recovery property, the specific volume at the time of loading is preferably 10 cm or more per g, and more preferably 15 cm or more and 40 cm or less per g. 3 It is preferably 100 cm or more and 100 cm or less per g. From the viewpoint of excellent bulk recovery property, the specific volume at the time of loading is preferably 10 cm or more per g, and more preferably 15 cm or more and 40 cm or less per g. 3 It is more preferably 100 cm or less per g. The non-woven fabric preferably has a specific volume at the time of loading of 10 cm or more per g, more preferably 15 cm or more and 40 cm or less per g, from the viewpoint of excellent bulk recovery property. 3 The specific volume at the time of loading is preferably 10 cm or more per g, and more preferably 15 cm or more and 40 cm or less per g. 3 It is preferably 15 cm or more per g, and more preferably 15 cm or more and 40 cm or less per g. 3 It is preferably 15 cm or more and 40 cm or less per g. 3 It is more preferably 40 cm or less per g.

[0058] From the viewpoints of excellent bulkiness and flexibility, when the basis weight of the non-woven fabric is about 20 g / m² (specifically, 20 ± 3 g / m²), the stiffness in the machine direction (MD direction) is preferably 100 mN·mm or less, and more preferably 15 mN·mm or more and 50 mN·mm or less. When the basis weight of the non-woven fabric is about 40 g / m² (specifically, 40 ± 3 g / m²), the stiffness in the MD direction is preferably 250 mN·mm or less, and more preferably 30 mN·mm or more and 200 mN·mm or less. Here, the machine direction refers to the direction in which the fibers are oriented. From the viewpoints of excellent bulkiness and flexibility, when the basis weight of the non-woven fabric is about 20 g / m² (specifically, 20 ± 3 g / m²), the stiffness in the cross direction (CD direction) is preferably 30 mN·mm or less, and more preferably 5 mN·mm or more and 20 mN·mm or less. When the basis weight of the non-woven fabric is about 40 g / m² (specifically, 40 ± 3 g / m²), the stiffness in the CD direction is preferably 50 mN·mm or less, and more preferably 15 mN·mm or more and 45 mN·mm or less. 2 (Specifically, 20 ± 3 g / m² 2 )), the stiffness in the machine direction (MD direction) is preferably 100 mN·mm or less, and more preferably 15 mN·mm or more and 50 mN·mm or less. When the basis weight of the non-woven fabric is about 40 g / m² (specifically, 40 ± 3 g / m² 2 (Specifically, 40 ± 3 g / m² 2 )), the stiffness in the MD direction is preferably 250 mN·mm or less, and more preferably 30 mN·mm or more and 200 mN·mm or less. Here, the machine direction refers to the direction in which the fibers are oriented. From the viewpoints of excellent bulkiness and flexibility, when the basis weight of the non-woven fabric is about 20 g / m² (specifically, 20 ± 3 g / m² 2 (Specifically, 20 ± 3 g / m² 2 )), the stiffness in the cross direction (CD direction) is preferably 30 mN·mm or less, and more preferably 5 mN·mm or more and 20 mN·mm or less. When the basis weight of the non-woven fabric is about 40 g / m² (specifically, 40 ± 3 g / m² 2 (Specifically, 40 ± 3 g / m² 2 )), the stiffness in the CD direction is preferably 50 mN·mm or less, and more preferably 15 mN·mm or more and 45 mN·mm or less.

[0059] From the viewpoint of excellent water resistance and heat resistance, the reduction rate of the tensile strength of the nonwoven fabric measured in the following water resistance and heat resistance tests is preferably 50% or less, more preferably 40% or less, and even more preferably 30% or less. It may also be 0% or more. When the reduction rate is within this range, appropriate strength can be obtained even when used in environments that are constantly heated and environments that are impregnated with liquids, while still possessing biodegradable functionality.

[0060] [Tensile strength reduction rate (water and heat resistance tests)] Nonwoven fabric (basis weight: approximately 40g / m²) produced by heat-treating a fiber web created using a parallel carding machine at 128°C for 10 seconds using a hot air penetration heat treatment machine. 2 Specifically, 40±3g / m 2 The material is impregnated in deionized water at 45°C for 7 weeks. The tensile strength before impregnation and after 7 weeks is measured by tensile testing using a constant-speed tension tensile testing machine in accordance with JIS L 1913:2010 6.3, under the conditions of a specimen width of 5 cm, grip spacing of 10 cm, and tensile speed of 30 ± 2 cm / min, and the load value at break is measured. The rate of decrease in tensile strength is calculated using the following formula 2. [Formula 2] Tensile strength reduction rate (%) = ((Load value before impregnation - Load value after 7 weeks) / Load value before impregnation) × 100

[0061] The nonwoven fabric of the present invention can be used as at least a part of a cushioning material. Examples of such cushioning materials include interior materials for household chairs and vehicle seats, sanitary materials such as diapers and sanitary napkins, cosmetic materials such as filters and cosmetic puffs, and molded products such as bra pads. [Examples]

[0062] The present invention will be described in more detail below using examples and comparative examples. However, the present invention is not limited to the following examples.

[0063] [Evaluation Method] (1) Differential scanning calorimetry: Based on JIS K 7121:1987, differential scanning calorimetry was performed using a differential scanning calorimetry meter (manufactured by Hitachi High-Tech Science Co., Ltd.) under the following conditions. A sample of 3.0 mg of fiber was weighed and placed in a sample holder. Next, the fiber placed in the sample holder was heated from room temperature (23±2°C) to 250°C at a rate of 5°C / min (first heating process), and DSC measurement was performed during the first melting. After reaching 250°C, it was held for 10 minutes, and then cooled from 250°C to 40°C at a rate of 1°C / min (cooling process), allowing the molten sample to solidify. At this time, DSC was measured during the cooling process. After the first heating and cooling processes were completed, the sample was not removed from the DSC measuring instrument, held at 40°C for 10 minutes, and then heated again from 40°C to 250°C at a rate of 5°C / min (second heating process), and DSC measurement was performed during the second melting. (2) Fiber properties: Single fiber fineness, single fiber strength, elongation, and Young's modulus were measured in accordance with JIS L 1015:2021. (3) Crimping ratio: Measured in accordance with JIS L 1015:2021. (4) Basis weight: The basis weight of the nonwoven fabric was measured in accordance with JIS L 1913:2010 6.2. (5) Specific volume: 2.96 N / cm using a thickness measuring instrument (product name "THICKNESS GAUGE", model "CR-60A", manufactured by Daiei Kagaku Seiki Seisakusho Co., Ltd.) 3 , or 19.6 N / cm 3 The thickness of the nonwoven fabric was measured while a load was applied, and the weight and thickness of the nonwoven fabric were used to calculate the result. (6) Stiffness / softness: Measured according to the 41.5° cantilever method of JIS L 1913:2010. (7) Tensile strength reduction rate (water and heat resistance test): Nonwoven fabric (basis weight: approximately 40 g / m²) prepared by heat-treating a fiber web made using a parallel carding machine at 128°C for 10 seconds using a hot air penetration heat treatment machine. 2 Specifically, 40±3g / m 2The material was impregnated in deionized water at 45°C for 7 weeks. The tensile strength before impregnation and after 7 weeks was measured by tensile testing using a constant-speed tension tensile testing machine in accordance with JIS L 1913:2010 6.3, under the conditions of a specimen width of 5 cm, gripping distance of 10 cm, and tensile speed of 30 ± 2 cm / min, and the load value at break was measured. The rate of decrease in tensile strength was calculated using the following formula 2. [Formula 2] Tensile strength reduction rate (%) = ((Load value before impregnation - Load value after 7 weeks) / Load value before impregnation) × 100

[0064] (Examples 1-18, Comparative Examples 1-2) The specific conditions are shown in Tables 1-4. (1) Resin (i) Poly-L-lactic acid (hereinafter also referred to as PLA) A: L-130, optical purity 99% or higher, melting point 175°C, manufactured by Total-Corbion. B: Ingeo3251D, optical purity 98.5%, melting point 155-170°C, manufactured by NatureWorks. (ii) Aliphatic polyester C: Polybutylene succinate (hereinafter also referred to as PBS), FZ71 PM, melting point 115°C, manufactured by PTT MCC Biochem. (iii) Nucleating agent (added to the sheath component; in the table, the amount of nucleating agent is the amount added to the sheath component) D: Talc (manufactured by Nippon Talc Co., Ltd., product name "Micro Ace PS") E: Calcium stearate (manufactured by NOF Corporation, product name "Calcium Stearate S") (2) Core component, sheath component resin Core components: Tables 1~4 Sheath component: C (3) Pickup speed: 926 m / min (410 m / min for Comparative Example 1 only) (4) Cross-section: Concentric circles (5) Stretching method: Wet (warm water), two-stage stretching (6) Oil concentration: 5% by mass (7) Drying temperature: 85℃ (8) Cut length: 51 mm (Examples 1-14, 16-18, Comparative Examples 1-2), 5 mm (Example 15) (9) The nonwoven fabric was prepared by heating a fiber web made using a parallel carding machine using a hot air penetration heat treatment machine. In Examples 1-10, Comparative Example 1, and Examples 13-18, the heat treatment was performed at 128°C for 10 seconds, while in Examples 11, 12, and Comparative Example 2, the heat treatment was performed at 115°C for 100 seconds.

[0065] In the examples and comparative examples, the composite fibers and nonwoven fabrics were evaluated using the evaluation method described above, and the results are shown in Tables 1 to 5 below. In Tables 1 to 5 below, "-" (minus) in the column for PBS crystallization heat quantity indicates crystallization.

[0066] [Table 1]

[0067] [Table 2]

[0068] [Table 3]

[0069] [Table 4]

[0070] [Table 5]

[0071] Figures 1 and 2 show the DSC curves of the composite fiber of Example 8. The composite fiber of Example 8 contains calcium stearate.

[0072] As can be seen from Tables 1 to 4 above, in the composite fibers of the examples, the crystallization temperature of the second component during the cooling process was 78°C or higher in the DSC curve, and the heat of fusion per unit mass of the second component during the second heating process was 73.5 mJ / mg or less. Furthermore, the basis weight obtained using this composite fiber is approximately 40 g / m². 2 The nonwoven fabrics in Examples 1-5 and 11-18 had an MD stiffness of 250 mN·mm or less and exhibited excellent flexibility and bulkiness. Furthermore, their basis weight was approximately 20 g / m². 2 The nonwoven fabrics in Examples 6-10 had an MD stiffness of 100 mN·mm or less and exhibited excellent flexibility and bulkiness. Furthermore, the nonwoven fabric in the example had a density of 2.96 N / cm². 3 The specific volume under load is 20 cm³. 3 It is greater than / g, has a high initial bulk, and is 19.6 N / cm 3 The specific volume under a load of g is 10 cm³ 3 The volume was above / g and it also maintained its bulk well.

[0073] In Comparative Example 1, the composite fiber showed that the heat of fusion per unit mass of the second component during the second heating process exceeded 73.5 mJ / mg in the DSC curve, resulting in poor carding properties of the composite fiber and making it impossible to obtain a nonwoven fabric. In Comparative Example 2, the crystallization temperature of the second component (PBS) during the cooling process was less than 78.0°C in the DSC curve of the composite fiber. Due to the low crystallization temperature, spinning draft occurred, resulting in undrawn yarn with high orientation. Consequently, the drawability was reduced and sufficient crystals were not obtained in the fiber, resulting in a tendency for the nonwoven fabric to have a harder texture compared to Examples 11 and 12, which had similar heat treatment conditions during nonwoven fabric production.

[0074] As can be seen from Table 5 above, the nonwoven fabrics prepared using 100% by mass of the fibers from Examples 2, 13, and 14 showed a decrease in tensile strength of 50% or less after water and heat resistance tests, indicating that they are water and heat resistant. In particular, when calcium stearate was added as a nucleating agent to the second component, excellent water and heat resistance was observed. Therefore, by adding a nucleating agent to the second component, biodegradability can be controlled, and furthermore, by using fatty acid metal salts, the crystallinity is standardized, contributing to water and heat resistance.

[0075] The present invention includes at least the following embodiments. [1] The first component contains poly-L-lactic acid with an optical purity of 95% or higher, A composite fiber comprising a second component containing an aliphatic polyester composed of glycol and dicarboxylic acid, The aforementioned second component accounts for more than 50% of the fiber surface. The composite fiber is a composite fiber in which, in the DSC curve obtained by differential scanning calorimetry (DSC), the crystallization temperature of the second component during the cooling process is 78°C or higher, and the heat of fusion per unit mass of the second component during the second heating process is 73.5 mJ / mg or less. [2] The composite fiber according to [1], wherein the composite fiber has a heat of fusion of the second component per unit mass in the first heating process, as shown in the DSC curve obtained by differential scanning calorimetry (DSC), which is 68.0 mJ / mg or less. [3] The composite fiber according to [1] or [2], wherein the composite fiber has a crystallization heat per unit mass of the second component during the cooling process of 59.5 mJ / mg or less in the DSC curve obtained by differential scanning calorimetry (DSC). [4] The composite fiber is the composite fiber according to any one of [1] to [3], wherein, in the DSC curve obtained by differential scanning calorimetry (DSC), the ratio of the peak height to the full width at half maximum of the first component during the first heating process is 11.0 or less. [5] The composite fiber is the composite fiber according to any one of [1] to [4], wherein the DSC curve obtained by differential scanning calorimetry (DSC) shows that the heat of fusion per unit mass of the first component in the first heating process is 30.0 mJ / mg or more. [6] The composite fiber according to any one of [1] to [5], wherein the aliphatic polyester is a copolymer of polybutylene succinate and / or polybutylene succinate. [7] A composite fiber according to any one of [1] to [6], wherein the second component comprises a nucleating agent. [8] The composite fiber according to [7], wherein the second component comprises 0.01 parts by mass or more and 20 parts by mass or less of the nucleating agent per 100 parts by mass of the aliphatic polyester. [9] The composite fiber according to [7], wherein the nucleating agent is a fatty acid metal salt.

[10] The composite fiber according to [9], wherein the fatty acid metal salt is contained in an amount of 0.01 parts by mass or more and 5.0 parts by mass or less per 100 parts by mass of the aliphatic polyester. A method for producing composite fibers according to any one of the items [1] to

[10] , A step of preparing a first component containing 70% by mass or more of poly-L-lactic acid with an optical purity of 95% or higher, and a second component containing 70% by mass or more of an aliphatic polyester consisting of glycol and dicarboxylic acid, A process of melt-spinning the first and second components to produce a spun filament, The process includes stretching the spun filament to obtain a composite fiber in which the second component accounts for 50% or more of the fiber surface, In the process of manufacturing the aforementioned spun filament, the first component is melt-spun at a lower temperature than the second component. A method for producing composite fibers, wherein in the stretching step, the stretching temperature is 55°C or higher and 90°C or lower, and the stretching ratio is 1.4 times or higher.

[12] A fiber structure containing 5% by mass or more of the composite fibers described in any one of items [1] to

[10] . [Industrial applicability]

[0076] The composite fiber of the present invention is suitable for nonwoven fabrics that are excellent in bulkiness and flexibility. Nonwoven fabrics using this composite fiber can be used, for example, in sanitary materials such as diapers and napkin components, filters, wipers, agricultural materials, food packaging materials, garbage bags, and automotive materials.

Claims

1. The first component contains poly-L-lactic acid with an optical purity of 95% or higher, A composite fiber comprising a second component containing an aliphatic polyester composed of glycol and dicarboxylic acid, The aforementioned second component accounts for more than 50% of the fiber surface. The composite fiber is a composite fiber in which, in the DSC curve obtained by differential scanning calorimetry (DSC), the crystallization temperature of the second component during the cooling process is 78°C or higher, and the heat of fusion per unit mass of the second component during the second heating process is 73.5 mJ / mg or less.

2. The composite fiber according to claim 1, wherein, in a DSC curve obtained by differential scanning calorimetry (DSC), the heat of fusion per unit mass of the second component during the first heating process is 68.0 mJ / mg or less.

3. The composite fiber according to claim 1 or 2, wherein the composite fiber has a crystallization heat per unit mass of the second component during the cooling process of 59.5 mJ / mg or less in a DSC curve obtained by differential scanning calorimetry (DSC).

4. The composite fiber according to any one of claims 1 to 3, wherein, in the DSC curve obtained by differential scanning calorimetry (DSC), the ratio of the peak height to the full width at half maximum of the first component during the first heating process is 11.0 or less.

5. The composite fiber according to any one of claims 1 to 4, wherein the composite fiber has a heat of fusion of 30.0 mJ / mg or more per unit mass of the first component in the first heating process, as shown in the DSC curve obtained by differential scanning calorimetry (DSC).

6. The composite fiber according to any one of claims 1 to 5, wherein the aliphatic polyester is a copolymer of polybutylene succinate and / or polybutylene succinate.

7. The composite fiber according to any one of claims 1 to 6, wherein the second component comprises a nucleating agent.

8. The composite fiber according to claim 7, wherein the second component contains 0.01 parts by mass or more and 20 parts by mass or less of the nucleating agent per 100 parts by mass of the aliphatic polyester.

9. The composite fiber according to claim 7, wherein the nucleating agent is a fatty acid metal salt.

10. The composite fiber according to claim 9, wherein the second component contains 0.01 parts by mass or more and 5.0 parts by mass or less of the fatty acid metal salt per 100 parts by mass of the aliphatic polyester.

11. A method for producing composite fibers according to any one of claims 1 to 10, A step of preparing a first component containing 70% by mass or more of poly-L-lactic acid with an optical purity of 95% or higher, and a second component containing 70% by mass or more of an aliphatic polyester consisting of glycol and dicarboxylic acid, A step of melt-spinning the first component and the second component to produce a spun filament, The process includes stretching the spun filament to obtain a composite fiber in which the second component accounts for 50% or more of the fiber surface, In the process of manufacturing the aforementioned spun filament, the first component is melt-spun at a lower temperature than the second component. A method for producing composite fibers, wherein in the stretching step, the stretching temperature is 55°C or higher and 90°C or lower, and the stretching ratio is 1.4 times or higher.

12. A fiber structure comprising 5% by mass or more of the composite fiber described in any one of claims 1 to 10.

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