Electrode manufacturing method

Abstract

To provide a manufacturing method of an electrode capable of reducing metal foreign matter in the electrode.SOLUTION: The manufacturing method of an electrode includes the steps of (a)-(d): (a) preparing active material powder including foreign particles and active material particles; (b) preparing a first electrode material including active material powder; (c) reducing foreign particles included in the first electrode material by performing a series of dry classification processing on the first electrode material; and (d) forming an active material layer that includes the first electrode material after classification. The first electrode material is in powder form. Foreign particles include the metal foreign matter and are coarse particles.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present disclosure relates to a method for manufacturing an electrode. [Background technology]

[0002] Japanese Patent Laid-Open Publication No. 2014-102967 (Patent Document 1) discloses a filter for filtering a slurry for forming an active material layer. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2014-102967 A Summary of the Invention [Problem to be solved by the invention]

[0004] Conventionally, battery electrodes are manufactured by coating a slurry (particle dispersion). That is, an active material powder, a binder, and a solvent are mixed to prepare a slurry. An active material layer is formed by coating the slurry on the surface of a substrate.

[0005] The solvent can dissolve the binder. The solvent is also a dispersion medium for solid particles. The solvent can include, for example, an organic solvent. For example, from the viewpoint of production cost, environmental load, etc., it is required to reduce the amount of solvent used in electrode production. Therefore, a process that does not go through a slurry has also been proposed. For example, a powdery or granular composition is prepared by mixing an active material powder and a binder. An active material layer can be formed by coating the powdery or granular composition on the surface of a substrate.

[0006] The active material powder includes active material particles. The active material particles cause an electrode reaction. Ideally, the active material powder is made of active material particles. However, the active material powder may also include a small amount of metallic foreign matter. The metallic foreign matter is an unintended impurity. The metallic foreign matter is considered to be generated, for example, by wear of the manufacturing equipment for the active material powder. The metallic foreign matter is in particulate form. The metallic foreign matter mixed into the electrode may adversely affect the battery performance. In particular, when the metallic foreign matter is a coarse particle, the effect is likely to be observed. For example, the self-discharge amount of the battery may increase.

[0007] The metallic foreign matter may include a magnetic material (e.g., iron, etc.). Conventionally, after the synthesis of an active material powder, the active material powder is subjected to a magnetic separation process (hereinafter referred to as "magnetic separation process") to reduce the metallic foreign matter. However, the separation efficiency of the magnetic separation process is not sufficient. For example, active material particles such as lithium cobalt oxide may be magnetic. When the active material particles are magnetic, the separation efficiency of the metallic foreign matter may decrease. This is because the active material particles also adhere to the magnet. Furthermore, the metallic foreign matter may be a non-magnetic material (e.g., copper, etc.).

[0008] It is also possible to reduce the amount of metallic foreign matter by dispersing the active material powder in a solvent to prepare a slurry and then filtering the slurry through a filter, but this would increase the amount of solvent used.

[0009] An object of the present disclosure is to reduce metallic foreign matter in electrodes. [Means for solving the problem]

[0010] The technical configuration and effects of the present disclosure will be described below. However, the mechanism of action in this specification includes assumptions. The mechanism of action does not limit the technical scope of the present disclosure.

[0011] 1. A method for producing an electrode includes the following steps (a) to (d): (a) An active material powder containing foreign particles and active material particles is prepared. (b) A first electrode material containing an active material powder is prepared. (c) The first electrode material is subjected to a dry classification process to reduce foreign particles contained in the first electrode material. (d) forming an active material layer containing the classified first electrode material; The first electrode material is in a powder form. The foreign particles include metallic foreign matter and are large particles.

[0012] Metallic foreign matter that may adversely affect battery performance is coarse particles. Coarse particles are outside the particle size distribution of the active material powder. The coarse particles can be separated from the active material powder by classification. Therefore, by subjecting the active material powder to classification, metallic foreign matter that may adversely affect battery performance can be reduced. In principle, classification is not affected by magnetism. Separation is possible regardless of whether the active material particles and foreign particles are magnetic or not. Furthermore, since the classification is a dry type, the amount of solvent used can be reduced.

[0013] It should be noted that the metallic foreign matter may have an oxidized surface, for example. That is, the foreign matter particles may further include metal oxides in addition to the metallic foreign matter.

[0014] The first electrode material may be made of an active material powder. That is, the active material powder may be classified alone. The first electrode material may further include at least one selected from the group consisting of a conductive material, a solid electrolyte, and a binder, in addition to the active material powder. That is, a mixed powder containing the active material powder may be classified.

[0015] . 2. The above (d) may include, for example, the following (d2) and (d3). (d2) The second electrode material is mixed with the classified first electrode material to prepare a powder or granular composition. (d3) The powder or granular composition is applied to the surface of a substrate. The second electrode material may include, for example, at least one selected from the group consisting of a conductive material, a solid electrolyte, a binder, and a solvent.

[0016] For example, materials used in the manufacture of the electrodes may be classified into a first electrode material and a second electrode material. The second electrode material may, for example, include a group of materials suitable for a magnetic separation process. The materials suitable for a magnetic separation process may, for example, consist of a substantially non-magnetic material. The materials suitable for a magnetic separation process may be subjected to a magnetic separation process.

[0017] The powdery composition has a powdery or granular appearance. The powdery composition can be applied to the surface of a substrate to form an active material layer. The powdery composition can contain a small amount of solvent. However, the powdery composition is different from a slurry (particle dispersion). In the powdery composition, the solvent is dispersed in the form of droplets in the solid material (powder, granules). On the other hand, in a slurry, the solid material is dispersed in the solvent (dispersion medium).

[0018] 3. The powder or granular composition may have a solid content of, for example, 70 to 100% by mass.

[0019] The "solid content" refers to the mass fraction of components other than the solvent contained in the mixture relative to the mass of the entire mixture. For example, when a binder is dissolved in a solvent, the binder (solute) is considered to be a component other than the solvent. For example, a powdered or granular composition having a solid content of 100% does not substantially contain a solvent. A powdered or granular composition having a solid content of 100% may be a dry powder or dry granules. For example, a powdered or granular composition having a solid content of 70% or more and less than 100% may be a wet powder or wet granules. Note that a slurry may have a solid content of, for example, 60% or less by mass. Granules may also be called "granules".

[0020] 4. The above (d) may further include the following (d1) before the above (d2): (d1) At least a part of the second electrode material is subjected to a magnetic separation process to reduce the magnetic metal particles contained in the second electrode material.

[0021] For example, the magnetic separation process may be applied to the entire second electrode material (mixed powder). For example, the magnetic separation process may be applied to a part of the second electrode material (for example, only the conductive material). By applying the magnetic separation process to the second electrode material, the metallic foreign matter in the electrode can be further reduced.

[0022] 5. The active material particles may be magnetic.

[0023] When the active material particles are magnetic, the separation efficiency in the magnetic separation process decreases. When the active material particles are magnetic, the dry classification process is considered to be particularly effective.

[0024] 6. The coarse particles have a short diameter and a long diameter. The short diameter may be, for example, two or more times the D99 of the active material powder. D99 indicates the particle size at which the cumulative frequency of the smaller particle sizes in the volume-based particle size distribution reaches 99% of the total.

[0025] The amount of coarse particles is very small. The coarse particles are not considered to appear in the particle size distribution up to D99. D99 may also be referred to as "Dmax." [Brief description of the drawings]

[0026] [Figure 1] FIG. 1 is a schematic flow chart showing a method for producing an electrode in this embodiment. [Diagram 2] FIG. 2 is a conceptual diagram showing the first coating method. [Diagram 3] FIG. 3 is a conceptual diagram showing the second coating method. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0027] <Definitions of terms, etc.> Hereinafter, an embodiment of the present disclosure (which may be abbreviated as "the present embodiment") and an example of the present disclosure (which may be abbreviated as "the present embodiment") will be described. However, the present embodiment and the example do not limit the technical scope of the present disclosure.

[0028] In this specification, the words "comprise," "include," "have," and variations thereof (e.g., "consisting of") are open-ended. The open-ended form may or may not include additional elements in addition to the required elements. The word "consisting of" is closed-ended. However, even in a closed form, additional elements that are normally associated impurities or unrelated to the disclosed technology are not excluded. The word "consisting essentially of..." is semi-closed. In a semi-closed form, the addition of elements that do not substantially affect the basic and novel characteristics of the disclosed technology is permitted.

[0029] In the methods described herein, the order of execution of multiple steps, operations, and the like is not limited to the order described unless otherwise specified. For example, multiple steps may proceed simultaneously. For example, multiple steps may be performed one after the other.

[0030] In this specification, the expressions "may" and "can" are used in the permissive sense of "have the potential to" rather than in the obligatory sense of "must".

[0031] In this specification, elements expressed in the singular include the plural unless otherwise specified. For example, a "particle" can mean not only "one particle" but also "a group of particles."

[0032] In this specification, unless otherwise specified, a numerical range such as "70 to 100%" includes the upper limit and the lower limit. That is, "70 to 100%" indicates a numerical range of "70% or more and 100% or less". In addition, a numerical value arbitrarily selected from within the numerical range may be set as a new upper limit and a new lower limit. For example, a new numerical range may be set by arbitrarily combining a numerical value within the numerical range with a numerical value described in another part, table, figure, etc. in this specification.

[0033] In this specification, all numerical values ​​are modified by the term "about". The term "about" may mean, for example, ±5%, ±3%, ±1%, etc. All numerical values ​​are approximations that may vary depending on the application of the disclosed technology. All numerical values ​​are expressed with significant figures. All measurements may be rounded to the nearest significant figure. All numerical values ​​may include errors associated with, for example, the detection limits of the measuring device.

[0034] In this specification, when a compound is expressed by a stoichiometric composition formula such as "LiCoO2", the stoichiometric composition formula is merely a representative example. The composition ratio may be non-stoichiometric. For example, when lithium cobalt oxide is expressed as "LiCoO2", unless otherwise specified, the lithium cobalt oxide is not limited to the composition ratio of "Li / Co / O=1 / 1 / 2" and may contain Li, Co and O in any composition ratio. Furthermore, doping, substitution, etc. with trace elements may be allowed.

[0035] In this specification, a particle has a minor axis and a major axis. The "major axis" refers to the distance between the two most distant points on the contour of a particle image. The "minor axis" refers to the diameter perpendicular to the line segment that forms the major axis at the midpoint of the line segment. The minor axis may be equal to the major axis.

[0036] In this specification, the volumetric particle size distribution can be measured by a laser diffraction particle size distribution analyzer. "D50" indicates the particle size at which the cumulative frequency from the smallest particle size reaches 50% of the total in the volumetric particle size distribution. "D99" indicates the particle size at which the cumulative frequency from the smallest particle size reaches 99% of the total in the volumetric particle size distribution.

[0037] Geometric terms in this specification (e.g., "parallel," "orthogonal," etc.) should not be interpreted in a strict sense. For example, "parallel" may deviate slightly from the strict meaning of "parallel." Geometric terms in this specification may include, for example, tolerances, errors, etc. in design, work, manufacturing, etc. The dimensional relationships in each figure may not match the actual dimensional relationships. In order to facilitate understanding of the disclosed technology, the dimensional relationships (length, width, thickness, etc.) in each figure may be changed. Furthermore, some configurations may be omitted.

[0038] <Electrode manufacturing method> Fig. 1 is a schematic flow chart showing the method for producing an electrode in this embodiment. Hereinafter, the method for producing an electrode in this embodiment may be abbreviated as "this production method". This production method includes "(a) preparation of active material powder", "(b) preparation of first electrode material", "(c) classification", and "(d) formation of active material layer".

[0039] In this manufacturing method, for example, an electrode for a lithium ion battery can be manufactured. However, lithium ion batteries are merely an example. This manufacturing method can be applied to any battery system. In this manufacturing method, at least one of a positive electrode and a negative electrode can be manufactured.

[0040] (a) Preparation of active material powder The manufacturing method includes preparing an active material powder. The active material powder may be prepared by any method. For example, a ready-made active material powder may be obtained from the market. For example, the active material powder may be prepared by manufacturing the active material powder. For example, the active material powder may be manufactured through processes such as raw material mixing, co-precipitation, firing, pulverization, granulation, magnetic separation, and packaging.

[0041] The active material powder includes foreign particles and active material particles. The active material powder may have a D50 of, for example, 1 to 30 μm. The active material powder may have a D50 of, for example, 5 to 20 μm. The active material powder may have a D99 of, for example, less than 50 μm. The active material powder may have a D99 of, for example, 30 to 40 μm. The foreign particles are coarse and in small quantities. Therefore, it is considered that the foreign particles are not included in the particle size distribution up to D99. Therefore, it is considered that D50 and D99 do not change substantially before and after classification.

[0042] <Foreign particles> The active material powder may unavoidably contain foreign particles. The foreign particles are coarse particles. The foreign particles may have a minor axis of, for example, 50 μm or more. The foreign particles may have a minor axis of, for example, 1 mm or less. The minor axis of the foreign particles may be, for example, two or more times the D99 of the active material powder. The minor axis of the foreign particles may be, for example, 2 to 10 times, 2 to 5 times, or 2 to 3 times the D99 of the active material powder.

[0043] The number of foreign particles contained in the active material powder can be measured by the following procedure. A particle dispersion liquid is prepared by dispersing a predetermined amount of active material powder in a dispersion medium. For example, N-methyl-2-pyrrolidone (NMP) is suitable as the dispersion medium. A filter is prepared. The filter has a mesh size of 38 μm. The particle dispersion liquid is filtered through the filter. The residue on the filter is analyzed by SEM-EDX (Scanning Electron Microscope - Energy Dispersive X-ray spectroscopy). Particles having a short diameter of 50 μm or more are counted by image analysis of the analysis field. At the same time, the composition of the particles is qualified. This allows the number of foreign particles having a short diameter of 50 μm or more to be measured. The number of foreign particles is displayed as the number per 10 g of active material powder.

[0044] The active material powder may contain, for example, 1 to 100 foreign particles per 10 g, and the remaining active material particles. The active material powder may contain, for example, 5 to 50 foreign particles per 10 g, and the remaining active material particles. The active material powder may contain, for example, 10 to 30 foreign particles per 10 g, and the remaining active material particles. The active material powder may contain, for example, 10 to 20 foreign particles per 10 g, and the remaining active material particles. 6 ~10 7 The active material particles may include

[0045] The active material powder may contain, for example, 0.1 to 100 ppm (parts per million) of foreign particles by mass fraction, with the remainder being active material particles. The mass fraction of the foreign particles can be measured by ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectroscopy) or the like.

[0046] The foreign particles include metallic foreign matter. The metallic foreign matter is considered not to contribute to the electrode reaction. For example, in a lithium ion battery, the electrode reaction shows an absorption reaction and a release reaction of lithium ions. The foreign particles may be substantially made of metallic foreign matter. The foreign particles may include at least one selected from the group consisting of stainless steel (SUS), iron (Fe), nickel (Ni), chromium (Cr), silicon (Si), manganese (Mn), molybdenum (Mo) and copper (Cu). A part or all of the metallic foreign matter may form, for example, an oxide, a carbide, a nitride, or the like. For example, an oxide layer may be formed on the surface of the metallic foreign matter. In addition to the metal, the foreign particles may further include at least one selected from the group consisting of oxygen, carbon, nitrogen, phosphorus, and sulfur.

[0047] The active material powder may contain, for example, 0.1 to 10 ppm of Fe in terms of mass fraction, and 10 to 100 ppb (parts per billion) of Cu in terms of mass fraction.

[0048] <Active material particles> The active material particles include an active material. The active material can cause an electrode reaction. The active material particles may consist essentially of an active material. The active material particles may include any component. The active material particles may include a positive electrode active material. The active material particles may include a negative electrode active material. The active material particles may include, for example, LiCoO2, LiNiO2, LiMnO2, LiMn2O4, Li(NiCoMn)O2, Li(NiCoAl)O2, LiFePO4, Si, SiO, Sn, SnO, and Li4Ti5O 12 For example, "(NiCoMn)" in "Li(NiCoMn)O2" indicates that the sum of the composition ratios in the parentheses is 1. As long as the sum is 1, the amount of each component is arbitrary. Li(NiCoMn)O2 may contain, for example, Li(Ni 1 / 3 Co 1 / 3 Mn 1 / 3 )O2, Li(Ni 0.5 Co 0.2 Mn 0.3 )O2, Li(Ni 0.8 Co 0.1 Mn 0.1 ) O2, etc.

[0049] The active material particles may be magnetic. For example, active material particles containing a transition metal element such as Fe, Co, or Ni may be magnetic. For example, Li(NiCoMn)O2 and LiFePO4 may be magnetic.

[0050] (b) Preparation of First Electrode Material The manufacturing method includes preparing a first electrode material. The first electrode material is in powder form. The first electrode material includes an active material powder. For example, the first electrode material may be made of an active material powder. For example, the first electrode material may further include other powder materials in addition to the active material powder. The other powder materials may include at least one selected from the group consisting of a conductive material, a solid electrolyte, and a binder.

[0051] For example, the first electrode material may be prepared by simply mixing the active material powder with other powder materials. For example, the first electrode material may be prepared so as to form composite particles. For example, the composite particles may be formed by fixing a conductive material, a solid electrolyte, a binder, etc. to the surface of the active material particles. The composite particles may be formed by, for example, a mechanochemical method.

[0052] Conductive material The conductive material may be in powder form. The conductive material may form an electronic conduction path in the electrode. The conductive material may include any component. The conductive material may include, for example, conductive carbon particles, conductive carbon fibers, etc. The conductive material may include, for example, at least one selected from the group consisting of carbon black, vapor-grown carbon fibers, carbon nanotubes, graphene flakes, and graphite. The carbon black may include, for example, at least one selected from the group consisting of acetylene black, furnace black, channel black, and thermal black.

[0053] The conductive material may also contain foreign particles (metallic foreign matter). Details of the foreign particles are as described above. It is believed that the foreign particles may be mixed in during the manufacturing process of the conductive material.

[0054] The number of foreign particles contained in a conductive material can be measured by the following procedure. A sample solution is prepared by dispersing the conductive material in a sodium polytungstate (SPT) solution. The sample solution is processed using a centrifuge to recover a precipitate. The precipitate is analyzed by SEM-EDX. Particles having a short diameter of 50 μm or more in the analysis field are counted by image analysis. At the same time, the composition of the particles is characterized. This allows the number of foreign particles having a short diameter of 50 μm or more to be measured. The number of foreign particles is displayed as the number per 10 g of conductive material.

[0055] The conductive material may contain, for example, 1 to 100 foreign particles per 10 g, with the remainder being carbon particles (or carbon fibers). The conductive material may contain, for example, 5 to 50 foreign particles per 10 g, with the remainder being carbon particles. The conductive material may contain, for example, 10 to 30 foreign particles per 10 g, with the remainder being carbon particles.

[0056] The conductive material may contain, for example, foreign particles having a mass fraction of 0.1 to 100 ppm, with the remainder being carbon particles. The mass fraction of the foreign particles can be measured by ICP-AES or the like.

[0057] <Solid electrolyte> The solid electrolyte may be in powder form. For example, when the electrode is for an all-solid-state battery, the electrode may include a solid electrolyte. The solid electrolyte may form an ion-conducting path in the electrode. The solid electrolyte may include, for example, at least one selected from the group consisting of Li2S-P2S5, LiI-Li2S-P2S5, LiBr-Li2S-P2S5, and LiI-LiBr-Li2S-P2S5.

[0058] <Binding material> The binder may be in powder form. The binder binds the solid materials in the electrode together. The binder may include any component. The binder may include at least one selected from the group consisting of polyvinylidene fluoride (PVdF), polytetrafluoroethylene (PTFE), vinylidene fluoride-hexafluoropropylene copolymer (PVdF-HFP), styrene butadiene rubber (SBR), carboxymethyl cellulose (CMC), polyimide (PI), polyamideimide (PAI), and polyacrylic acid (PAA).

[0059] Foreign particles may also be mixed into the solid electrolyte and the binder. For example, the number of foreign particles contained in the binder may be measured using the same procedure as for the conductive material. From the qualitative analysis of the foreign particles, it may be determined whether the foreign particles contained in each material are magnetic or not. Based on the qualitative analysis of the foreign particles, the target material for the magnetic separation process (described later) may be determined.

[0060] 《(c) Classification》 The method includes reducing foreign particles contained in the first electrode material by subjecting the first electrode material to a dry classification process.

[0061] In the dry classification process, liquid is not substantially used, and classification is performed in air (or gas). For example, classification may be performed in a nitrogen gas atmosphere. In the wet classification process, classification is performed in liquid.

[0062] The manufacturing method may include drying the first electrode material before the classification treatment. By drying the first electrode material, it is expected that the separation efficiency will be improved. This is thought to be because particle aggregation is less likely to occur due to the reduction in moisture. For example, the first electrode material may be dried using an airflow dryer or the like. For example, the first electrode material may be dried so that the moisture content is 500 ppm or less by mass fraction. The moisture content of the first electrode material may be measured by the Karl Fischer method.

[0063] In the present manufacturing method, any dry classifier may be used. For example, an air classifier, a dry sieve classifier, or the like may be used. For example, a dry sieve classifier may be smaller than an air classifier. Also, a dry sieve classifier tends to consume less energy than an air classifier. By employing a dry sieve classifier, for example, a reduction in manufacturing costs is expected.

[0064] The first electrode material is classified by a dry classifier. A classification point is set so that the target coarse particles are separated. The classification point may be set to a size exceeding D99 of the active material powder, for example. The classification point may be set to a size at least twice the D99 of the active material powder, for example. One classification process may be performed. Two or more classification processes may be performed.

[0065] The dry classification process can reduce foreign particles (coarse particles). For example, the dry classification process may be performed so that the number of foreign particles is less than 6 in 10 g of the active material layer (described later). For example, the dry classification process may be performed so that the number of foreign particles is 1 or less in 10 g of the active material layer.

[0066] (d) Formation of active material layer The method includes forming an active material layer including the classified first electrode material. When the first electrode material includes a binder, the first electrode material may be coated on a surface of a substrate.

[0067] For example, a second electrode material may be added to the first electrode material after classification. The second electrode material may include at least one selected from the group consisting of a conductive material, a solid electrolyte, a binder, and a solvent. The details of the conductive material, the solid electrolyte, and the binder are as described above.

[0068] <solvent> The solvent is a liquid. The solvent can promote particle aggregation in a powder / granular composition (described later). The solvent in this embodiment is, so to speak, a "granulation promoter." The solvent may contain, for example, water, an organic solvent, etc. The solvent may contain a component capable of dissolving the binder. The solvent may contain, for example, at least one selected from the group consisting of water, butyl butyrate, and NMP.

[0069] (d1) Magnetic separation of second electrode material For example, "(d) Formation of an active material layer" may include "(d1) Magnetic separation of a second electrode material", "(d2) Preparation of a powder / granular composition", and "(d3) Coating".

[0070] The second electrode material may be, for example, substantially made of a non-magnetic material. For example, at least a part of the second electrode material may be subjected to a magnetic separation process. This can reduce magnetic metal particles (metallic foreign matter) contained in the second electrode material. For example, at least a part of the second electrode material may be passed through a magnet filter to perform the magnetic separation process. The magnetic separation process may be performed individually on each material. For example, the conductive material and the binder may each be subjected to the magnetic separation process individually. For example, the magnetic separation process may be performed on a mixture of the conductive material and the binder.

[0071] (d2) Preparation of powder / granular composition For example, the powder or granular composition may be prepared by mixing the second electrode material with the first electrode material after classification. The second electrode material may be after magnetic separation.

[0072] For example, the powdery composition may be prepared by any mixer, agitator, granulator, etc. The powdery composition may be in a powder form or a granular form. The powdery composition includes an active material powder and a binder. The powdery composition may further include a conductive material and a solid electrolyte. The powdery composition may include, for example, 1 to 10% of the binder, 0 to 10% of the conductive material, 0 to 50% of the solid electrolyte, and the remaining active material powder, by mass fraction. The powdery composition may include, for example, 1 to 10% of the binder, 1 to 10% of the conductive material, and the remaining active material powder, by mass fraction.

[0073] The powdery or granular composition may further contain a solvent. That is, the powdery or granular composition may contain at least one selected from the group consisting of dry powder, dry granules, wet powder, and wet granules. The powdery or granular composition may have a solid content of, for example, 70 to 100% by mass. The powdery or granular composition may have a solid content of, for example, 75 to 100% by mass. The powdery or granular composition may have a solid content of, for example, 80 to 100% by mass.

[0074] (d3) Painting The powder composition may be applied to the surface of the substrate, whereby an active material layer may be formed on the surface of the substrate, the active material layer including the first electrode material after classification.

[0075] In this manufacturing method, the powder or granular composition can be applied by any method. The first and second application methods described below are merely examples. For example, application may be performed continuously by a roll-to-roll method. This is expected to improve productivity.

[0076] <Base material> The substrate may be, for example, in the form of a sheet. The substrate may be, for example, an electrode current collector. The substrate may include, for example, a metal foil. The substrate may include, for example, at least one selected from the group consisting of an aluminum (Al) foil, an Al alloy foil, a Cu foil, a Cu alloy foil, a Ni foil, a Ni alloy foil, a titanium (Ti) foil, and a Ti alloy foil. The substrate may have a thickness of, for example, 5 to 50 μm, or 10 to 30 μm.

[0077] <First painting method> FIG. 2 is a conceptual diagram showing the first coating method. The first coating method is similar to the liquid film transfer method. In the first coating method, three rolls are used. The first roll 101, the second roll 102, and the third roll 103 may be arranged, for example, in a horizontal direction. The rotation axes of the rolls are parallel to each other. The arrows drawn on each roll indicate the rotation direction of each roll.

[0078] The first roll gap 111 is formed between the first roll 101 and the second roll 102. The second roll gap 112 is formed between the second roll 102 and the third roll 103.

[0079] Powdered granular composition 11 is supplied to first roll gap 111. Powdered granular composition 11 is leveled in first roll gap 111 to form active material layer 12. Second roll 102 transports active material layer 12 to second roll gap 112. Third roll 103 transports substrate 13. In second roll gap 112, active material layer 12 is transferred to substrate 13. That is, electrode 10 including active material layer 12 and substrate 13 is formed.

[0080] In the first coating method, the powder / granule composition may contain at least one of wet powder and wet granules, and may have a solid content of 70 to 90% by mass.

[0081] <Second painting method> 3 is a conceptual diagram showing the second coating method. In the second coating method, electrostatic coating is performed. The first roll 201, the second roll 202, and the third roll 203 have parallel rotation axes. The third roll 203 may be disposed vertically above the first roll 201. The power source 204 forms an electric field between the first roll 201 and the third roll 203. The first roll 201 is equipped with a magnet.

[0082] The powdered or granular composition 11 is supplied to a container 205. In the container 205, the powdered or granular composition 11 may be stirred. For example, a ferromagnetic material may be mixed with the powdered or granular composition 11 in the container 205. The powdered or granular composition 11 is attracted to the first roll 201 by a magnetic force F1 from the first roll 201. The first roll 201 transports the powdered or granular composition 11. The squeegee 206 scrapes off a portion of the powdered or granular composition 11, so that a certain range of the powdered or granular composition 11 is supplied to the roll gap between the first roll 201 and the third roll 203.

[0083] The second roll 202 transports the substrate 13. The substrate 13 is supplied to a roll gap between the first roll 201 and the third roll 203.

[0084] Between the first roll 201 and the third roll 203, an electric field is formed such that the electrostatic force F2 acting on the powdered or granular composition 11 is greater than the magnetic force F1 acting on the powdered or granular composition 11. The powdered or granular composition 11 is pulled away from the first roll 201 by the electrostatic force F2. The powdered or granular composition 11 then flies toward the third roll 203 by the electrostatic force F2. The substrate 13 is supported on the surface of the third roll 203. The powdered or granular composition 11 adheres to the surface of the substrate 13, thereby forming an active material layer 12. That is, an electrode 10 including the active material layer 12 and the substrate 13 is formed.

[0085] In the second coating method, the powder / granule composition may, for example, contain at least one of dry powder and dry granules. The powder / granule composition may, for example, have a solid content of 90 to 100% by mass. The powder / granule composition may, for example, have a solid content of 100% by mass.

[0086] In this way, an electrode (raw sheet) can be manufactured. When the powder / granular composition (active material layer) contains a solvent, the electrode may be dried. For example, the active material layer may be fixed to the substrate by applying at least one of pressure and heat to the active material layer.

[0087] Furthermore, the electrodes may be compressed to a predetermined thickness in accordance with the battery design, and the electrodes may be cut into a predetermined planar shape in accordance with the battery design.

[0088] The active material layer may be formed on only one side of the substrate. The active material layer may be formed on both sides of the substrate. The active material layer may have a thickness of, for example, 10 to 1000 μm. The active material layer 12 may have a thickness of, for example, 50 to 200 μm.

[0089] In the present manufacturing method, the amount of metallic foreign matter in the active material layer is reduced. In 10 g of the active material layer, the number of foreign matter particles may be less than 6. In 10 g of the active material layer, the number of foreign matter particles may be 1 or less.

[0090] The number of foreign particles contained in the active material layer is measured by the following procedure. The active material layer is peeled off from the substrate, and the active material layer is collected. The active material layer (powder-granular composition) is dispersed in a dispersion medium to prepare a particle dispersion. For example, NMP is a suitable dispersion medium. A filter is prepared. The filter has a mesh size of 38 μm. The particle dispersion is filtered through the filter. The residue on the filter is analyzed by SEM-EDX. Particles having a short diameter of 50 μm or more are counted by image analysis of the analysis field. At the same time, the composition of the particles is characterized. This allows the number of foreign particles having a short diameter of 50 μm or more to be measured. The number of foreign particles is displayed as the number per 10 g of active material layer. EXAMPLES

[0091] This embodiment will be described below.

[0092] <Material preparation> The electrode materials shown in Table 1 below were prepared. The number of foreign particles contained in each material was measured using the procedure described above. The measurement results are shown in Table 1 below. The number of foreign particles is shown per 10 g of each material.

[0093] [Table 1]

[0094] <Electrode manufacturing> Example 1 A powdered or granular composition was prepared by mixing an active material powder, a conductive material, a binder, and a solvent (NMP). The powdered or granular composition contained wet granules. The solid content was mixed in a ratio of active material powder / conductive material / binder=97.5 / 1 / 1.5 (mass ratio). An active material layer was formed by the first coating method (see FIG. 2). That is, an electrode was manufactured. The number of foreign particles contained in the active material layer was measured by the above-mentioned procedure. The measurement results are shown in Table 2 below.

[0095] Example 2 In Production Example 2, prior to the preparation of the powdery or granular composition, the active material powder and the conductive material were subjected to magnetic separation treatment. Except for this, an electrode was produced in the same manner as in Production Example 1.

[0096] Example 3 In Production Example 3, prior to the preparation of the powder / granular composition, the active material powder was subjected to a dry classification process. In this example, a dry sieve classifier was used. Furthermore, prior to the preparation of the powder / granular composition, the conductive material was subjected to a magnetic separation process. Except for these, an electrode was produced in the same manner as in Production Example 1.

[0097] [Table 2]

[0098] <Result> The active material powder and the conductive material contained foreign particles (Fe particles, Cu particles) in the raw material stage (Table 1 above).

[0099] From the results of Production Examples 1 and 2, it is seen that the magnetic separation treatment of the active material powder and the conductive material tends to reduce foreign particles in the active material layer (electrode) (Table 2 above). However, some foreign particles are not separated by the magnetic separation treatment and are mixed into the active material layer.

[0100] From the results of Production Example 3, it can be seen that the dry classification treatment of the active material powder tends to significantly reduce foreign particles in the active material layer (Table 2 above). It is believed that the dry classification treatment can separate foreign particles that cannot be separated by the magnetic separation treatment.

[0101] <Additional Notes> The present disclosure also relates to a method for manufacturing a battery. The method for producing a battery includes the following steps (a) to (f). (a) An active material powder containing foreign particles and active material particles is prepared. (b) A first electrode material containing an active material powder is prepared. (c) The first electrode material is subjected to a dry classification process to reduce foreign particles contained in the first electrode material. (d) forming an active material layer containing the classified first electrode material; (e) Producing an electrode including an active material layer. (f) fabricating a battery including the electrode; The first electrode material is in a powder form. The foreign particles include metallic foreign matter and are large particles.

[0102] The method for manufacturing the battery may include, for example, a method for manufacturing a lithium ion battery. In addition to the electrodes, the battery may further include, for example, a battery case (housing), a separator, an electrolyte, and the like.

[0103] The present disclosure also relates to a method for producing an active material powder. The method for producing the active material powder includes the following steps (a) and (c). (a) An active material powder containing foreign particles and active material particles is synthesized. (c) The active material powder is subjected to a dry classification process to reduce the amount of foreign particles contained in the active material powder. The foreign particles include metallic foreign matter and are large particles.

[0104] The method for producing the active material powder may further include, for example, subjecting the active material powder to a magnetic separation treatment. The method for producing the active material powder may further include, for example, packaging the classified active material powder in a packaging material. The packaging material may include, for example, a container, a bag, or the like.

[0105] The present embodiment and the present embodiment are illustrative in all respects. The present embodiment and the present embodiment are not restrictive. The technical scope of the present disclosure includes all modifications within the meaning and scope equivalent to the description of the claims. For example, it is also intended from the beginning that any configuration may be extracted from the present embodiment and the present embodiment, and that they may be arbitrarily combined. [Explanation of symbols]

[0106] 10 electrode, 11 powder / granular composition, 12 active material layer, 13 substrate, 101, 201 first roll, 102, 202 second roll, 103, 203 third roll, 111 first roll gap, 112 second roll gap, 204 power source, 205 container, 206 squeegee, F1 magnetic force, F2 electrostatic force.

Claims

1. (a) preparing an active material powder including foreign particles and active material particles; (b) preparing a first electrode material comprising the active material powder; (c) reducing the foreign particles contained in the first electrode material by performing a dry classification process on the first electrode material; and (d) forming an active material layer comprising the classified first electrode material; Including, The dry classification process is carried out by a dry sieve classifier, the first electrode material is in powder form; The foreign matter particles include metal foreign matter and are coarse particles, The coarse particles have a minor axis and a major axis, The short diameter is equal to or greater than twice the D99 of the active material powder, The D99 indicates a particle size at which the cumulative frequency of the smaller particle sizes reaches 99% of the total in a volume-based particle size distribution. A method for manufacturing an electrode.

2. The above (d) is (d2) mixing the first electrode material after classification with a second electrode material to prepare a powder or granular composition; and (d3) applying the powder or granular composition to a surface of a substrate; Including, The second electrode material includes at least one selected from the group consisting of a conductive material, a solid electrolyte, a binder, and a solvent. A method for producing the electrode according to claim 1 .

3. The powder or granular composition has a solid content of 70 to 100% by mass. A method for producing the electrode according to claim 2.

4. The above (d) is Before the step (d2), (d1) subjecting at least a portion of the second electrode material to a magnetic separation process to reduce magnetic metal particles contained in the second electrode material; Further comprising: A method for producing the electrode according to claim 2 or 3.

5. The active material particles are magnetic. A method for producing the electrode according to any one of claims 1 to 4.

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