Amorphous alloy soft magnetic powder, dust core, magnetic element and electronic device

Abstract

To provide amorphous alloy soft magnetic powder which highly achieves low coercive force and high saturation magnetic flux density, a powder magnetic core and a magnetic element containing the amorphous alloy soft magnetic powder, and an electronic apparatus which enables downsizing and high output.SOLUTION: Amorphous alloy soft magnetic powder has a composition represented by (FexCo(1-x))(100-(a+b))(SiyB(1-y))aMb, wherein M is at least one selected from the group consisting of C, S, P, Sn, Mo, Cu and Nb; and x, y, and b are 0.73≤x≤0.85, 0.02≤y≤0.10, 13.0≤a≤19.0 and 0≤b≤2.0, where coercive force is 24[A / m] or more (0.3[Oe] or more) and 199[A / m] or less (2.5[Oe] or less), and saturation magnetic flux density is 1.60[T] or more and 2.20[T] or less.SELECTED DRAWING: Figure 2

Description

[Technical field]

[0001] The present invention relates to an amorphous alloy soft magnetic powder, a dust core, a magnetic element, and an electronic device. [Background technology]

[0002] In order to reduce the size and increase the output of various electronic devices equipped with magnetic elements, it is necessary to increase the saturation magnetic flux density while maintaining a low coercive force of the soft magnetic powder contained in the powder magnetic core.

[0003] Patent Document 1 describes the composition formula (Fe (1-(α+β) )X1 α X2 β ) (1-(a+b+c+d+e+f)) M a B b P c S d C e S f The present invention discloses a soft magnetic alloy powder having a main component consisting of Co and Ni, X1 being one or more selected from the group consisting of Co and Ni, X2 being one or more selected from the group consisting of Al, Mn, Ag, Zn, Sn, As, Sb, Cu, Cr, Bi, N, O and rare earth elements, and M being one or more selected from the group consisting of Nb, Hf, Zr, Ta, Mo, W, Ti and V. In this powder, 0≦a≦0.160, 0.020≦b≦0.200, 0≦c≦0.150, 0≦d≦0.060, 0≦e≦0.030, 0.0010≦f≦0.030, 0.005≦f / b≦1.50, α≧0, β≧0, 0≦α+β≦0.50. Patent Document 1 also discloses that by selecting Co as X1, the saturation magnetization after heat treatment is improved. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2020-070468 A Summary of the Invention [Problem to be solved by the invention]

[0005] However, the soft magnetic alloy powder described in Patent Document 1 still has room for improvement in terms of increasing saturation magnetization. In other words, there is a challenge to be overcome in a powder magnetic core to achieve both low coercivity and high saturation magnetic flux density. [Means for solving the problem]

[0006] The amorphous alloy soft magnetic powder according to the application example of the present invention has the following features: (Fe x Co (1-x) ) (100-(a+b)) (Si y B (1-y) ) a M b [wherein M is at least one selected from the group consisting of C, S, P, Sn, Mo, Cu and Nb; x, y, a, and b are 0.73≦x≦0.85, 0.02≦y≦0.10, 13.0≦a≦19.0, 0≦b≦2.0. The composition is represented by The crystallinity is 70% or less, The coercive force is 40 [A / m] or more ( 0.5 [Oe] or higher) 175 [A / m] or less ( 2.2 [Oe] or less), It is characterized by having a saturation magnetic flux density of 1.60 [T] or more and 2.20 [T] or less.

[0007] The powder magnetic core according to the application example of the present invention is The present invention is characterized by including an amorphous alloy soft magnetic powder according to an application example of the present invention.

[0008] The magnetic element according to the application example of the present invention includes: The present invention is characterized by including a powder magnetic core according to an application example of the present invention.

[0009] The electronic device according to the application example of the present invention includes: The present invention is characterized by including a magnetic element according to an application example of the present invention. [Brief description of the drawings]

[0010] [Figure 1] FIG. 1 is a vertical cross-sectional view showing an example of an apparatus for producing amorphous alloy soft magnetic powder by a rotating water jet atomization method. [Diagram 2] FIG. 2 is a plan view illustrating a schematic diagram of a toroidal type coil component. [Diagram 3] FIG. 2 is a see-through perspective view that typically illustrates a closed magnetic circuit type coil component. [Figure 4] FIG. 1 is a perspective view showing a mobile personal computer, which is an electronic device including a magnetic element according to an embodiment. [Diagram 5] FIG. 1 is a plan view showing a smartphone, which is an electronic device including a magnetic element according to an embodiment. [Figure 6] FIG. 1 is a perspective view showing a digital still camera, which is an electronic device including a magnetic element according to an embodiment. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0011] DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The amorphous alloy soft magnetic powder, the dust core, the magnetic element, and the electronic device of the present invention will be described in detail below with reference to preferred embodiments shown in the accompanying drawings.

[0012] 1. Amorphous alloy soft magnetic powder The amorphous alloy soft magnetic powder according to the embodiment is an amorphous alloy powder exhibiting soft magnetic properties. Such amorphous alloy soft magnetic powder can be used in any application that utilizes soft magnetic properties, and can be used to obtain a powder magnetic core by, for example, bonding particles together and molding them.

[0013] The amorphous alloy soft magnetic powder according to the embodiment is made of (Fe x Co (1-x) ) (100-(a+b)) (Siy B (1-y) ) a M b Here, M is at least one selected from the group consisting of C, S, P, Sn, Mo, Cu and Nb. x, y, a and b are numerical values ​​representing atomic % in the above composition formula, and are 0.73≦x≦0.85, 0.02≦y≦0.10, 13.0≦a≦19.0, and 0≦b≦2.0. In addition, this amorphous alloy soft magnetic powder has a coercive force of 24 [A / m] or more (0.3 [Oe] or more) and 199 [A / m] or less (2.5 [Oe] or less), and a saturation magnetic flux density of 1.60 [T] or more and 2.20 [T] or less.

[0014] Such amorphous alloy soft magnetic powder has both low coercivity and high saturation magnetic flux density, and therefore the use of such amorphous alloy soft magnetic powder makes it possible to reduce the size and increase the output of magnetic elements.

[0015] The composition of the amorphous alloy soft magnetic powder according to the embodiment will be described in detail below. Fe (iron) has a significant effect on the basic magnetic properties and mechanical properties of the amorphous alloy soft magnetic powder according to the embodiment.

[0016] The content of Fe is not particularly limited, but is set so that Fe is the main component in the amorphous alloy soft magnetic powder, that is, the ratio of the number of atoms is the highest. In the amorphous alloy soft magnetic powder according to this embodiment, it is preferable that 61.0≦x(100-(a+b))≦71.0, more preferably 63.0≦x(100-(a+b))≦69.0, and even more preferably 65.0≦x(100-(a+b))≦68.0. If the content of Fe is below the lower limit, the magnetic flux density of the amorphous alloy soft magnetic powder may decrease depending on the composition. On the other hand, if the content of Fe is above the upper limit, it may be difficult to stably form an amorphous structure depending on the composition.

[0017] x represents the ratio of the number of Fe atoms to the total number of atoms when the sum of the number of Fe atoms and the number of Co atoms is 1. In the amorphous alloy soft magnetic powder according to this embodiment, 0.73≦x≦0.85 is satisfied. Also, 0.75≦x≦0.83 is preferably satisfied, and 0.77≦x≦0.81 is more preferably satisfied.

[0018] Co (cobalt) can increase the saturation magnetic flux density of the amorphous alloy soft magnetic powder.

[0019] When the total number of Fe atoms and Co atoms is 1, the ratio of the number of Co atoms to the total number of atoms is 0.15≦1-x≦0.27. Also, it is preferably 0.17≦1-x≦0.25, and more preferably 0.19≦1-x≦0.23. By setting 1-x within the above range, it is possible to increase the saturation magnetic flux density of the amorphous alloy soft magnetic powder while suppressing an increase in coercive force.

[0020] If 1-x is below the lower limit, the Co content relative to the Fe content becomes too low, making it impossible to sufficiently increase the saturation magnetic flux density, whereas if 1-x is above the upper limit, the Co content relative to the Fe content becomes too high, making it difficult to stably form an amorphous structure and increasing the coercive force.

[0021] The Co content is preferably 12.0 atomic % or more and 22.0 atomic % or less, and more preferably 15.0 atomic % or more and 19.0 atomic % or less.

[0022] When producing amorphous alloy soft magnetic powder from raw materials, silicon (Si) promotes amorphization and increases the magnetic permeability of the amorphous alloy soft magnetic powder, thereby achieving low coercive force and high magnetic permeability.

[0023] B (boron) promotes amorphization when manufacturing amorphous alloy soft magnetic powder from raw materials. In particular, by using Si and B together, amorphization can be promoted synergistically based on the difference in atomic radius between the two. This allows sufficient achievement of low coercive force and high magnetic permeability.

[0024] y represents the ratio of the number of Si atoms to the total number of atoms when the total number of Si atoms and the number of B atoms is 1. In the amorphous alloy soft magnetic powder according to this embodiment, 0.02≦y≦0.10 is set. Also, preferably 0.04≦y≦0.08, more preferably 0.05≦y≦0.07 is set. By setting y within the above range, the balance between the number of Si atoms and the number of B atoms can be optimized. As a result, even if Fe and Co are at relatively high concentrations, sufficient amorphousization can be achieved. Therefore, by setting y within the above range, the saturation magnetic flux density can be particularly increased without compromising the low coercive force.

[0025] When y is below the lower limit or above the upper limit, the balance between the number of Si atoms and the number of B atoms is lost, and therefore amorphization cannot be promoted in a composition ratio with relatively high concentrations of Fe and Co.

[0026] a determines the balance between Si and B, and Fe and Co. In the amorphous alloy soft magnetic powder according to this embodiment, a is 13.0≦a≦19.0. Also, it is preferably 14.0≦a≦18.0, and more preferably 15.0≦a≦17.0. By setting a within the above range, the balance between Si and B, which mainly promote amorphization, and Fe and Co, which mainly increase the saturation magnetic flux density, is optimized.

[0027] If a is below the lower limit, the ratios of Si and B decrease and the ratios of Fe and Co increase, making it difficult to form an amorphous structure. On the other hand, if a is above the upper limit, the ratios of Si and B increase and the ratios of Fe and Co decrease, making it difficult to sufficiently increase the saturation magnetic flux density.

[0028] The Si content is preferably 0.40 atomic % or more and 1.80 atomic % or less, and more preferably 0.80 atomic % or more and 1.50 atomic % or less.

[0029] The content of B is preferably 11.0 atomic % or more and 18.0 atomic % or less, and more preferably 14.0 atomic % or more and 16.0 atomic % or less.

[0030] M is at least one selected from the group consisting of C, S, P, Sn, Mo, Cu, and Nb. By containing a certain amount of M, the saturation magnetic flux density can be further increased. In addition, by containing two or more of the above elements, the saturation magnetic flux density can be further increased compared to the case where no M is contained or where only one type of M is contained.

[0031] b represents the content of M. When multiple elements are included as M, b is the total content of the multiple elements. In the amorphous alloy soft magnetic powder according to this embodiment, 0≦b≦2.0 is satisfied. Also, 0.5≦b≦1.5 is preferably satisfied, and 0.7≦b≦1.2 is more preferably satisfied. By setting b within the above range, the saturation magnetic flux density can be increased without inhibiting the amorphization.

[0032] If b is below the lower limit, the above effect may not be sufficiently obtained, whereas if b is above the upper limit, the amorphization is inhibited.

[0033] The amorphous alloy soft magnetic powder according to the embodiment is made of (Fe x Co (1-x) ) (100-(a+b)) (Si y B (1-y) ) a Mb In addition to the composition represented by the formula (1), impurities may be contained. Examples of impurities include any elements other than those mentioned above, and the total content of impurities is preferably 0.2 mass % or less, and more preferably 0.1 mass % or less.

[0034] The composition of the amorphous alloy soft magnetic powder according to the embodiment has been described in detail above, but the above composition and impurities are identified by the following analytical method.

[0035] Examples of analytical methods include iron and steel-atomic absorption spectrometry specified in JIS G 1257:2000, iron and steel-inductively coupled plasma atomic emission spectrometry specified in JIS G 1258:2007, iron and steel-spark discharge atomic emission spectrometry specified in JIS G 1253:2002, iron and steel-fluorescent X-ray analysis specified in JIS G 1256:1997, and gravimetry, titration, and absorptiometry specified in JIS G 1211 to G 1237.

[0036] Specific examples include a solid-state optical emission spectrometer manufactured by SPECTRO, in particular a spark discharge optical emission spectrometer, model: SPECTROLAB, type: LAVMB08A, and an ICP device, CIROS120 type manufactured by Rigaku Corporation.

[0037] In particular, when identifying C (carbon) and S (sulfur), the oxygen flow combustion (high-frequency induction heating furnace combustion)-infrared absorption method specified in JIS G 1211:2011 is also used. Specifically, the LECO carbon / sulfur analyzer, CS-200, can be used.

[0038] Furthermore, when specifying N (nitrogen) and O (oxygen), the method for determining nitrogen in iron and steel specified in JIS G 1228:1997 and the general method for determining oxygen in metallic materials specified in JIS Z 2613:2006 are also used. Specifically, the LECO oxygen / nitrogen analyzer, TC-300 / EF-300, can be mentioned.

[0039] The degree of amorphization in the amorphous alloy soft magnetic powder can be determined based on the crystallinity. The crystallinity in the amorphous alloy soft magnetic powder is calculated based on the following formula from the spectrum obtained by X-ray diffraction for the amorphous alloy soft magnetic powder.

[0040] Crystallinity = {crystal intensity / (crystal intensity + amorphous intensity)} x 100 As the X-ray diffraction device, for example, RINT2500V / PC manufactured by Rigaku Corporation is used.

[0041] The degree of crystallinity measured by such a method is preferably 70% or less, more preferably 60% or less. This makes the improvement in soft magnetic properties due to amorphization more noticeable. As a result, an amorphous alloy soft magnetic powder with sufficiently low coercive force is obtained. In other words, it is preferable that the amorphous alloy soft magnetic powder is entirely amorphous, but it may contain crystalline structures at a volume ratio of, for example, 70% or less.

[0042] The average particle size D50 of the amorphous alloy soft magnetic powder is not particularly limited, but is preferably 5.0 μm or more and 60.0 μm or less, more preferably 10.0 μm or more and 50.0 μm or less, and even more preferably 20.0 μm or more and 40.0 μm or less. By using an amorphous alloy soft magnetic powder with such an average particle size, a high green compaction density can be obtained. As a result, the filling density of the green compact can be increased, and the green compact can have a high saturation magnetic flux density and high magnetic permeability.

[0043] The average particle size D50 of the amorphous alloy soft magnetic powder is determined as the particle size at which the cumulative 50% from the small diameter side is reached in the mass-based particle size distribution obtained by laser diffraction method.

[0044] If the average particle size of the amorphous alloy soft magnetic powder is below the lower limit, the particle size becomes too small, which may result in insufficient reduction in the crystallinity, whereas if the average particle size of the amorphous alloy soft magnetic powder is above the upper limit, the particle size becomes too large, which may result in reduced filling properties during powder compaction.

[0045] Furthermore, for the amorphous alloy soft magnetic powder, in the mass-based particle size distribution obtained by laser diffraction, when the particle size at 10% cumulative from the small diameter side is D10 and the particle size at 90% cumulative from the small diameter side is D90, (D90-D10) / D50 is preferably about 1.5 to 3.5, more preferably about 2.0 to 3.0. (D90-D10) / D50 is an index showing the degree of spread of the particle size distribution, and when this index is within the above range, the packing property of the amorphous alloy soft magnetic powder becomes particularly good. As a result, an amorphous alloy soft magnetic powder capable of manufacturing a dust core with a particularly high saturation magnetic flux density can be obtained.

[0046] The coercive force of the amorphous alloy soft magnetic powder according to the embodiment is 24 [A / m] or more (0.3 [Oe] or more) and 199 [A / m] or less (2.5 [Oe] or less), preferably 40 [A / m] or more (0.5 [Oe] or more) and 175 [A / m] or less (2.2 [Oe] or less), and more preferably 56 [A / m] or more (0.7 [Oe] or more) and 159 [A / m] or less (2.0 [Oe] or less).

[0047] By using such amorphous alloy soft magnetic powder having a relatively small coercive force, it is possible to manufacture a dust core capable of sufficiently suppressing hysteresis loss even at high frequencies.

[0048] If the coercive force is below the lower limit, it becomes difficult to stably produce such a low-coercive amorphous alloy soft magnetic powder, and if the coercive force is too high, the saturation magnetic flux density is affected and decreases, whereas if the coercive force is above the upper limit, the hysteresis loss increases at high frequencies, resulting in increased iron loss in the powder magnetic core.

[0049] The coercive force of the amorphous alloy soft magnetic powder can be measured, for example, by a vibrating sample magnetometer such as TM-VSM1230-MHHL manufactured by Tamagawa Seisakusho Co., Ltd.

[0050] The saturation magnetic flux density of the amorphous alloy soft magnetic powder according to the embodiment is 1.60 T or more and 2.20 T or less, preferably 1.60 T or more and 2.10 T or less, and more preferably 1.65 T or more and 2.00 T or less.

[0051] By using such amorphous alloy soft magnetic powder having a relatively high saturation magnetic flux density, a dust core having a high saturation magnetic flux density can be obtained, which allows the magnetic element to be made smaller and have higher output.

[0052] If the saturation magnetic flux density is below the lower limit, it becomes difficult to miniaturize the magnetic element and increase its output. On the other hand, if the saturation magnetic flux density exceeds the upper limit, it becomes difficult to stably manufacture the amorphous alloy soft magnetic powder having such a saturation magnetic flux density. Moreover, if the saturation magnetic flux density is pursued too much, it affects the coercive force, leading to an increase in the coercive force.

[0053] The saturation magnetic flux density of the amorphous alloy soft magnetic powder can be measured, for example, by forming the powder core into a toroidal shape and using a BH analyzer such as a DC BH analyzer, BH-5501, manufactured by Denshijiki Kogyo Co., Ltd. The number of turns of the excitation coil is, for example, 169 turns for the primary coil and 169 turns for the secondary coil. It can also be calculated from the maximum magnetization using the method described below.

[0054] The amorphous alloy soft magnetic powder according to the embodiment has a magnetic permeability of 20.0 or more at a measurement frequency of 100 kHz, and more preferably 21.0 or more. Such amorphous alloy soft magnetic powder contributes to the realization of a powder magnetic core and a magnetic element that are unlikely to become saturated in magnetic flux density even when a strong magnetic field is applied, that is, have a high saturation magnetic flux density. The upper limit of the magnetic permeability is not particularly limited, but is set to 50.0 or less in consideration of stable production.

[0055] The magnetic permeability of the amorphous alloy soft magnetic powder is, for example, the relative magnetic permeability obtained from the self-inductance of the closed magnetic circuit magnetic core coil when the powder core is in a toroidal shape, that is, the effective magnetic permeability. The magnetic permeability is measured using an impedance analyzer such as Agilent Technologies 4194A, and the measurement frequency is 1MHz. The number of turns of the excitation coil is 7, and the wire diameter of the winding is 0.5mm.

[0056] In the amorphous alloy soft magnetic powder, it is preferable that the apparent density and tap density are within a predetermined range. Specifically, the apparent density [g / cm 3 ] is 100, the tap density [g / cm 3 ] is preferably 103 or more and 120 or less, more preferably 105 or more and 115 or less, and even more preferably 107 or more and 113 or less. Such amorphous alloy soft magnetic powder is relatively difficult to fill when not tapped (vibrated), and is easy to fill when tapped. From this, it can be said that when the tap density is within the above range, the powder has a particle distribution with relatively few irregularly shaped particles and high packing ability. Such amorphous alloy soft magnetic powder can produce a high-density dust core, and therefore can particularly increase the saturation magnetic flux density of the dust core and the magnetic element.

[0057] The apparent density of the amorphous alloy soft magnetic powder is 4.55 [g / cm 3 ] or more than 4.80[g / cm 3] or less, and 4.58 [g / cm 3 ] or more than 4.70[g / cm 3 ] or less is more preferable.

[0058] The tap density of the amorphous alloy soft magnetic powder is 4.95 [g / cm 3 ] or more than 5.30[g / cm 3 ] or less, and 5.00 [g / cm 3 ] or more than 5.20[g / cm 3 ] or less is more preferable.

[0059] By ensuring that the apparent density and tap density of the amorphous alloy soft magnetic powder are within the above ranges, the saturation magnetic flux density of the powder magnetic core and magnetic element can be particularly increased.

[0060] If the relative value of the tap density is below the lower limit, the packing property of the amorphous alloy soft magnetic powder may be reduced when the amorphous alloy soft magnetic powder is compressed to obtain a powder core. On the other hand, if the relative value of the tap density is above the upper limit, the shrinkage rate may be increased when the amorphous alloy soft magnetic powder is compressed to obtain a powder core. As a result, the powder core may be easily deformed, and the dimensional accuracy may be reduced.

[0061] The apparent density of the amorphous alloy soft magnetic powder is measured in accordance with the metal powder-apparent density measurement method specified in JIS Z 2504:2012, and the unit is g / cm. 3 It is.

[0062] The tap density of the amorphous alloy soft magnetic powder is measured in accordance with the metal powder tap density measurement method specified in JIS Z 2512:2012, and the unit is g / cm. 3 It is.

[0063] 2. Manufacturing method of amorphous alloy soft magnetic powder Next, a method for producing the amorphous alloy soft magnetic powder will be described.

[0064] The amorphous alloy soft magnetic powder may be produced by any method, for example, by various powdering methods such as atomization methods such as water atomization, gas atomization, and rotary water flow atomization, reduction methods, carbonyl methods, and pulverization methods.

[0065] The atomization method includes water atomization, gas atomization, and rotary water flow atomization, etc., depending on the type of cooling medium and the device configuration. Among these, the amorphous alloy soft magnetic powder is preferably manufactured by the atomization method, more preferably by the water atomization method or the rotary water flow atomization method, and even more preferably by the rotary water flow atomization method. The atomization method is a method of manufacturing powder by colliding a molten raw material with a fluid such as a liquid or gas injected at high speed, pulverizing it and cooling it. By using such an atomization method, it is possible to efficiently manufacture an amorphous alloy soft magnetic powder with excellent filling properties while achieving good amorphization.

[0066] In this specification, the "water atomization method" refers to a method of producing metal powder by using a liquid such as water or oil as a coolant, spraying it in an inverted cone shape that converges to one point, and then allowing molten metal to flow down toward this convergence point and collide with it.

[0067] On the other hand, the rotary water jet atomization method allows the molten metal to be cooled at an extremely high speed, making it particularly easy to achieve amorphous formation.

[0068] When producing amorphous alloy soft magnetic powder, the cooling rate of the molten metal is 10 6 [K / sec] or more, preferably 10 7 [K / sec] or more. This allows for the production of amorphous alloy soft magnetic powder that is sufficiently amorphous. In other words, even if the composition has a relatively high content of Fe or Co, it is possible to achieve amorphousization. In particular, by using the rotating water flow atomization method, 7Cooling rates of more than [K / sec] can be easily achieved.

[0069] The method for producing the amorphous alloy soft magnetic powder by the rotary water jet atomization method will be further described below.

[0070] In the rotating water flow atomization method, a cooling liquid is jetted along the inner peripheral surface of a cooling cylinder and rotated along the inner peripheral surface of the cooling cylinder to form a cooling liquid layer on the inner peripheral surface. Meanwhile, the raw material of the amorphous alloy soft magnetic powder is melted, and the resulting molten metal is allowed to fall naturally while a jet of liquid or gas is sprayed onto it. When the molten metal is scattered in this way, it is captured in the cooling liquid layer. As a result, the scattered and finely powdered molten metal is rapidly cooled and solidified, and the amorphous alloy soft magnetic powder is obtained.

[0071] FIG. 1 is a vertical cross-sectional view showing an example of an apparatus for producing amorphous alloy soft magnetic powder by the rotating water jet atomization method.

[0072] The powder manufacturing apparatus 30 shown in Fig. 1 includes a cooling cylinder 1, a crucible 15, a pump 7, and a jet nozzle 24. The cooling cylinder 1 is a cylinder for forming a cooling liquid layer 9 on its inner circumferential surface. The crucible 15 is a supply container for supplying molten metal 25 to flow down into a space 23 inside the cooling liquid layer 9. The pump 7 supplies the cooling liquid to the cooling cylinder 1. The jet nozzle 24 ejects a gas jet 26 that breaks the molten metal 25 in the form of a thin stream that flows down into droplets. The molten metal 25 is prepared according to the composition of the amorphous alloy soft magnetic powder.

[0073] The cooling cylinder 1 has a cylindrical shape and is installed so that the axis of the cylinder is aligned vertically or inclined at an angle of 30° or less with respect to the vertical.

[0074] The upper end opening of the cooling cylinder 1 is closed by a lid 2. The lid 2 is formed with an opening 3 for supplying the flowing molten metal 25 to the space 23 of the cooling cylinder 1.

[0075] A cooling liquid ejection pipe 4 is provided at the upper part of the cooling cylinder 1 to eject a cooling liquid onto the inner peripheral surface of the cooling cylinder 1. A plurality of ejection ports 5 of the cooling liquid ejection pipe 4 are provided at equal intervals along the circumferential direction of the cooling cylinder 1.

[0076] The cooling liquid ejection pipe 4 is connected to the tank 8 through a pipe connected to the pump 7, and the cooling liquid in the tank 8 sucked up by the pump 7 is ejected and supplied into the cooling cylinder 1 through the cooling liquid ejection pipe 4. As a result, the cooling liquid gradually flows down while rotating along the inner circumferential surface of the cooling cylinder 1, and a cooling liquid layer 9 is formed along the inner circumferential surface. In addition, a cooler may be interposed in the tank 8 or in the middle of the circulation flow path as necessary. As the cooling liquid, in addition to water, oil such as silicone oil is used, and various additives may be added. In addition, by removing the dissolved oxygen in the cooling liquid in advance, oxidation of the powder to be produced can be suppressed.

[0077] A cylindrical draining net 17 is connected to the lower part of the cooling cylinder 1, and a funnel-shaped powder recovery container 18 is provided below this draining net 17. A cooling liquid recovery cover 13 is provided around the draining net 17 so as to cover it, and a drain port 14 formed at the bottom of this cooling liquid recovery cover 13 is connected to the tank 8 via a pipe.

[0078] The jet nozzle 24 is provided in the space 23. The jet nozzle 24 is attached to the tip of a gas supply pipe 27 inserted through the opening 3 of the lid 2, and is disposed so that its nozzle is directed toward the molten metal 25 in the form of a thin stream.

[0079] To produce amorphous alloy soft magnetic powder in such powder production apparatus 30, first, pump 7 is operated to form a cooling liquid layer 9 on the inner peripheral surface of cooling cylinder 1. Next, molten metal 25 in crucible 15 is caused to flow down into space 23. When gas jet 26 is blown onto the flowing molten metal 25, molten metal 25 is scattered, and the finely powdered molten metal 25 is caught in cooling liquid layer 9. As a result, the finely powdered molten metal 25 is cooled and solidified, and amorphous alloy soft magnetic powder is obtained.

[0080] In the rotary water flow atomization method, a very high cooling rate can be stably maintained by continuously supplying a cooling liquid, which promotes the amorphization of the produced amorphous alloy soft magnetic powder.

[0081] In addition, the molten metal 25 atomized to a certain size by the gas jet 26 falls with inertia until it is caught in the cooling liquid layer 9, and the droplets are made spherical at that time. As a result, it is possible to produce an amorphous alloy soft magnetic powder with a good particle size distribution and excellent packing ability.

[0082] For example, the amount of molten metal 25 flowing down from crucible 15 varies depending on the size of the device, etc., but is preferably more than 1.0 [kg / min] and not more than 20.0 [kg / min], and more preferably 2.0 [kg / min] or more and 10.0 [kg / min] or less. This makes it possible to optimize the amount of molten metal 25 flowing down in a certain period of time, and therefore makes it possible to efficiently manufacture amorphous alloy soft magnetic powder that is sufficiently amorphized.

[0083] The pressure of the gas jet 26 varies slightly depending on the configuration of the jet nozzle 24, but is preferably 2.0 MPa or more and 20.0 MPa or less, and more preferably 3.0 MPa or more and 10.0 MPa or less. This optimizes the particle size when the molten metal 25 is scattered, and allows the production of amorphous alloy soft magnetic powder that is sufficiently amorphized. That is, if the pressure of the gas jet 26 is below the lower limit, it becomes difficult to scatter the molten metal 25 finely, and the particle size tends to become large. This may result in a decrease in the cooling rate inside the droplets, which may cause insufficient amorphization. On the other hand, if the pressure of the gas jet 26 exceeds the upper limit, the particle size of the droplets after scattering may become too small. This may result in the droplets being gradually cooled by the gas jet 26, which may prevent rapid cooling by the cooling liquid layer 9, which may cause insufficient amorphization.

[0084] The flow rate of the gas jet 26 is not particularly limited, but is preferably 1.0 [Nm 3 / min] or more than 20.0[Nm 3 / min or less is preferable.

[0085] The pressure at which the cooling liquid is supplied to the cooling cylinder 1 is ejected is preferably about 5 MPa to 200 MPa, more preferably about 10 MPa to 100 MPa. This optimizes the flow rate of the cooling liquid layer 9, and the finely powdered molten metal 25 is less likely to become irregular in shape. As a result, an amorphous alloy soft magnetic powder with better packing properties is obtained. In addition, the cooling rate of the molten metal 25 by the cooling liquid can be sufficiently increased. In this manner, amorphous alloy soft magnetic powder is obtained.

[0086] The particle size of the amorphous alloy soft magnetic powder can be reduced by, for example, reducing the amount of molten metal 25 flowing down from the crucible 15, increasing the pressure of the gas jet 26, or increasing the flow rate of the gas jet 26. The particle size can be increased by performing the opposite operations.

[0087] The particle size distribution of the amorphous alloy soft magnetic powder can be narrowed by, for example, setting the flow rate of the molten metal 25 and the pressure and flow rate of the gas jet 26 within the above ranges. This setting can increase the ratio of the tap density to the apparent density of the amorphous alloy soft magnetic powder.

[0088] The amorphous alloy soft magnetic powder after production may be heat-treated as necessary. The heat treatment conditions include, for example, a heating temperature of 200°C or more and 500°C or less, and a holding time at this temperature of 5 minutes or more and 2 hours or less. The heat treatment atmosphere may be, for example, an inert gas atmosphere such as nitrogen or argon, a reducing gas atmosphere such as hydrogen or ammonia decomposition gas, or a reduced pressure atmosphere thereof.

[0089] The amorphous alloy soft magnetic powder may be subjected to classification treatment as necessary. Examples of the classification treatment method include dry classification such as sieving classification, inertial classification, centrifugal classification, and air classification, and wet classification such as sedimentation classification.

[0090] If necessary, an insulating film may be formed on the surface of each particle of the obtained soft magnetic powder. Examples of materials constituting this insulating film include inorganic materials such as phosphates, such as magnesium phosphate, calcium phosphate, zinc phosphate, manganese phosphate, and cadmium phosphate, and silicates, such as sodium silicate.

[0091] 3. Powder cores and magnetic components Next, the powder magnetic core and the magnetic element according to the embodiment will be described.

[0092] The magnetic element according to the embodiment can be applied to various magnetic elements having a magnetic core, such as a choke coil, an inductor, a noise filter, a reactor, a transformer, a motor, an actuator, an electromagnetic valve, a generator, etc. Furthermore, the powder magnetic core according to the embodiment can be applied to the magnetic cores included in these magnetic elements.

[0093] Two types of coil components will be described below as representative examples of the magnetic element. 3.1.Toroidal type First, a toroidal type coil component, which is a magnetic element according to the embodiment, will be described.

[0094] 2 is a plan view showing a schematic diagram of a toroidal-type coil component. The coil component 10 shown in FIG. 2 has a ring-shaped powder core 11 and a conductive wire 12 wound around the powder core 11.

[0095] The powder magnetic core 11 is obtained by mixing the above-mentioned amorphous alloy soft magnetic powder with a binder, supplying the mixture to a molding die, and pressing and molding it. That is, the powder magnetic core 11 is a compact containing the amorphous alloy soft magnetic powder according to the embodiment. Such a powder magnetic core 11 has a high saturation magnetic flux density and a low coercive force. Therefore, when a coil component 10 having the powder magnetic core 11 is mounted on an electronic device or the like, the power consumption of the electronic device or the like can be reduced, and the electronic device can be made smaller and have a higher output.

[0096] Moreover, the coil component 10 includes such a powder magnetic core 11. Such a coil component 10 contributes to miniaturization and high output of electronic devices.

[0097] Examples of constituent materials of the binder used in producing the powder magnetic core 11 include organic materials such as silicone-based resins, epoxy-based resins, phenol-based resins, polyamide-based resins, polyimide-based resins, and polyphenylene sulfide-based resins, and inorganic materials such as phosphates such as magnesium phosphate, calcium phosphate, zinc phosphate, manganese phosphate, and cadmium phosphate, and silicates such as sodium silicate.

[0098] The conductive wire 12 may be made of a highly conductive material, such as a metal material containing Cu, Al, Ag, Au, Ni, etc. An insulating film may be provided on the surface of the conductive wire 12 as necessary.

[0099] The shape of the powder magnetic core 11 is not limited to the ring shape shown in FIG. 2, and may be, for example, a ring shape with a part missing, or a shape with a linear shape in the longitudinal direction.

[0100] Furthermore, the dust core 11 may contain soft magnetic powder other than the amorphous alloy soft magnetic powder according to the embodiment described above, or non-magnetic powder, as necessary.

[0101] 3.2.Closed magnetic circuit type Next, a closed magnetic circuit type coil component, which is a magnetic element according to the embodiment, will be described. FIG. 3 is a see-through perspective view that typically shows a closed magnetic circuit type coil component.

[0102] The closed magnetic circuit type coil component will be described below, but in the following description, the differences from the toroidal type coil component will be mainly described, and a description of similar points will be omitted.

[0103] 3 includes a chip-shaped powder core 21 and a conductor wire 22 embedded in the powder core 21 and formed into a coil shape. That is, the powder core 21 is a compact containing the amorphous alloy soft magnetic powder according to the embodiment. Such a powder core 21 has a high saturation magnetic flux density and a low coercive force.

[0104] Moreover, the coil component 20 includes such a powder magnetic core 21. Such a coil component 20 contributes to miniaturization and high output of electronic devices.

[0105] The dust core 21 may contain soft magnetic powder other than the amorphous alloy soft magnetic powder according to the embodiment described above or non-magnetic powder, as necessary.

[0106] 4.Electronic equipment Next, an electronic device including the magnetic element according to the embodiment will be described with reference to FIGS.

[0107] Fig. 4 is a perspective view showing a mobile personal computer, which is an electronic device including a magnetic element according to the embodiment. The personal computer 1100 shown in Fig. 4 includes a main body 1104 including a keyboard 1102, and a display unit 1106 including a display unit 100. The display unit 1106 is rotatably supported by the main body 1104 via a hinge structure. Such a personal computer 1100 includes a magnetic element 1000, such as a choke coil or inductor for a switching power supply, or a motor.

[0108] Fig. 5 is a plan view showing a smartphone, which is an electronic device including the magnetic element according to the embodiment. The smartphone 1200 shown in Fig. 5 includes a plurality of operation buttons 1202, an earpiece 1204, and a mouthpiece 1206. A display unit 100 is disposed between the operation buttons 1202 and the earpiece 1204. Such a smartphone 1200 includes a built-in magnetic element 1000, such as an inductor, a noise filter, or a motor.

[0109] Fig. 6 is a perspective view showing a digital still camera, which is an electronic device equipped with a magnetic element according to the embodiment. Note that Fig. 6 also shows a simplified view of connections to external devices. The digital still camera 1300 photoelectrically converts an optical image of a subject using an imaging element such as a CCD (Charge Coupled Device) to generate an imaging signal.

[0110] 6 includes a display unit 100 provided on the back of a case 1302. The display unit 100 functions as a viewfinder that displays a subject as an electronic image. In addition, a light receiving unit 1304 including an optical lens, a CCD, etc. is provided on the front side of the case 1302, i.e., on the back side in the figure.

[0111] When the photographer checks the subject image displayed on the display unit 100 and presses the shutter button 1306, the image signal of the CCD at that time is transferred and stored in the memory 1308. In addition, in this digital still camera 1300, a video signal output terminal 1312 and an input / output terminal 1314 for data communication are provided on the side of the case 1302. As shown in the figure, the video signal output terminal 1312 is connected to a television monitor 1430, and the data communication input / output terminal 1314 is connected to a personal computer 1440, as necessary. Furthermore, the image signal stored in the memory 1308 is configured to be output to the television monitor 1430 or the personal computer 1440 by a predetermined operation. Such a digital still camera 1300 also has a built-in magnetic element 1000, such as an inductor or a noise filter.

[0112] Examples of electronic devices according to the embodiments include the personal computer of FIG. 4, the smartphone of FIG. 5, and the digital still camera of FIG. 6, as well as mobile phones, tablet terminals, watches, inkjet discharge devices such as inkjet printers, laptop personal computers, televisions, video cameras, video tape recorders, car navigation devices, pagers, electronic organizers, electronic dictionaries, calculators, electronic game devices, word processors, workstations, videophones, security television monitors, electronic binoculars, POS terminals, medical devices such as electronic thermometers, blood pressure monitors, blood glucose meters, electrocardiogram measuring devices, ultrasonic diagnostic devices, and electronic endoscopes, fish finders, various measuring devices, instruments for vehicles, aircraft, and ships, mobile object control devices such as automobile control devices, aircraft control devices, railway vehicle control devices, and ship control devices, and flight simulators.

[0113] As described above, such electronic devices include the magnetic element according to the embodiment, and can enjoy the effects of the magnetic element, such as low coercive force and high saturation magnetic flux density, to thereby achieve miniaturization and high output of the electronic devices.

[0114] The amorphous alloy soft magnetic powder, the dust core, the magnetic element, and the electronic device of the present invention have been described above based on the preferred embodiments, but the present invention is not limited thereto.

[0115] For example, in the above embodiment, the application of the amorphous alloy soft magnetic powder of the present invention has been described with reference to a dust core, but the application is not limited thereto and may be, for example, a magnetic device such as a magnetic fluid, a magnetic shielding sheet, a magnetic head, etc. Furthermore, the shapes of the dust core and the magnetic element are not limited to those shown in the drawings and may be any shape. EXAMPLES

[0116] Next, specific examples of the present invention will be described. 5. Manufacturing of powder magnetic cores (Sample No. 1) First, the raw material was melted in a high-frequency induction furnace and pulverized by a rotating water flow atomization method to obtain an amorphous alloy soft magnetic powder. At this time, the flow rate of the molten metal flowing down from the crucible was 10.0 [kg / min], the pressure of the gas jet was 10.0 MPa, and the flow rate of the gas jet was 10.0 [Nm 3 / min] and the cooling liquid pressure was 40 MPa.

[0117] Next, classification was performed using a classifier with a mesh of 150 μm opening. The alloy composition of the amorphous alloy soft magnetic powder after classification is shown in Table 1. The alloy composition was determined using a solid-state optical emission spectrometer manufactured by SPECTRO, model: SPECTROLAB, type: LAVMB08A.

[0118] Next, the particle size distribution of the obtained amorphous alloy soft magnetic powder was measured. This measurement was performed using a laser diffraction type particle size distribution measuring device, Microtrack HRA9320-X100 manufactured by Nikkiso Co., Ltd. In addition, the crystallinity of the obtained amorphous alloy soft magnetic powder was measured using an X-ray diffraction device. The measurement results are shown in Table 1.

[0119] Next, the obtained amorphous alloy soft magnetic powder was heated in a nitrogen atmosphere at 360° C. for 15 minutes.

[0120] Next, the obtained amorphous alloy soft magnetic powder was mixed with an epoxy resin as a binder and toluene as an organic solvent to obtain a mixture. The amount of epoxy resin added was 2 parts by mass per 100 parts by mass of the amorphous alloy soft magnetic powder.

[0121] Next, the mixture was stirred and then dried for a short time to obtain a lump-shaped dried body. The dried body was then sieved through a sieve with a mesh size of 400 μm, and the dried body was pulverized to obtain a granulated powder. The obtained granulated powder was dried at 50° C. for 1 hour.

[0122] Next, the obtained granulated powder was filled into a molding die, and a molded body was obtained based on the following molding conditions.

[0123] <Molding conditions> Molding method: Press molding Shape of molded body: Ring-shaped -Dimensions of molded body: Outer diameter 14mm, inner diameter 8mm, thickness 3mm ·Molding pressure: 3t / cm 2 (294MPa)

[0124] Next, the compact was heated in an air atmosphere at a temperature of 150° C. for 0.50 hour to harden the binder, thereby obtaining a powder magnetic core.

[0125] (Sample No. 2-16) Powder cores were obtained in the same manner as in Sample No. 1, except that the amorphous alloy soft magnetic powders shown in Table 1 were used.

[0126] [Table 1]

[0127] (Sample No. 17-29) Powder cores were obtained in the same manner as in Sample No. 1, except that the amorphous alloy soft magnetic powders shown in Table 2 were used.

[0128] [Table 2]

[0129] (Sample No.30) Except for using water atomization instead of rotary water flow atomization, amorphous alloy soft magnetic powder was produced and a powder core was obtained in the same manner as in Sample No. 1. The cooling rate in the water atomization method is as shown in Table 2.

[0130] (Sample No.31) A dust core was obtained in the same manner as in Sample No. 30, except that the amorphous alloy soft magnetic powder shown in Table 2 was used.

[0131] In Tables 1 and 2, among the amorphous alloy soft magnetic powders of each sample number, those that correspond to the present invention are indicated as "Examples", and those that do not correspond to the present invention are indicated as "Comparative Examples".

[0132] 6. Evaluation of amorphous alloy soft magnetic powders and dust cores 6.1. Powder properties of amorphous alloy soft magnetic powder The amorphous alloy soft magnetic powders obtained in each Example and Comparative Example were measured for apparent density AD and tap density TD. The relative value of tap density TD, i.e., the ratio of tap density to apparent density, was calculated when apparent density AD was set to 100. The measurement results and calculation results are shown in Tables 3 and 4.

[0133] 6.2. Coercive force of amorphous alloy soft magnetic powder The coercive force of each of the amorphous alloy soft magnetic powders obtained in the respective Examples and Comparative Examples was measured using the following measuring device. The measurement results are shown in Tables 3 and 4.

[0134] Measurement equipment: Vibrating sample magnetometer, Tamagawa Manufacturing Co., Ltd. VSM system, TM-VSM1230-MHHL

[0135] 6.3. Saturation magnetic flux density of amorphous alloy soft magnetic powder The saturation magnetic flux density of each of the amorphous alloy soft magnetic powders obtained in the respective Examples and Comparative Examples was measured as follows.

[0136] First, the true specific gravity ρ of the amorphous alloy soft magnetic powder was measured using a fully automatic gas displacement densitometer, AccuPyc1330, manufactured by Micromeritics.

[0137] Next, the maximum magnetization Mm of the amorphous alloy soft magnetic powder was measured using the vibrating sample magnetometer used in 6.2. The saturation magnetic flux density Bs was then calculated using the following formula. The calculation results are shown in Tables 3 and 4. Bs = 4π / 10000 × ρ × Mm

[0138] 6.4.Permeability of Powder Cores The magnetic permeability of each of the powder magnetic cores obtained in the examples and comparative examples was measured under the following measurement conditions. The measurement results are shown in Tables 3 and 4.

[0139] <Measuring conditions for magnetic permeability> Measurement equipment: Impedance analyzer, Agilent Technologies 4194A Measurement frequency: 100kHz Number of turns of winding: 7 Winding wire diameter: 0.8mm

[0140] [Table 3]

[0141] [Table 4]

[0142] As is clear from Tables 3 and 4, the amorphous alloy soft magnetic powders obtained in each Example were found to have both low coercivity and high saturation magnetic flux density. In particular, it was found that by increasing the cooling rate, the crystallinity can be reduced, and low coercivity and high magnetic permeability can be obtained. In addition, it was found that the amorphous alloy soft magnetic powders obtained in each Example had a relatively narrow particle size distribution and a relatively large ratio of tap density to apparent density. [Explanation of symbols]

[0143] 1...cooling cylinder, 2...lid, 3...opening, 4...cooling liquid ejection pipe, 5...discharge port, 7...pump, 8...tank, 9...cooling liquid layer, 10...coil part, 11...powder core, 12...conductor, 13...cooling liquid recovery cover, 14...drain port, 15...crucible, 17...liquid draining mesh, 18...powder recovery container, 20...coil part, 21...powder core, 22...conductor, 23...space, 24...jet nozzle, 25...molten metal, 26...gas jet, 27...gas supply pipe, 30...powder manufacturing device, 100...display, 1000...magnetic A functional element, 1100, a personal computer, 1102, a keyboard, 1104, a main body, 1106, a display unit, 1200, a smartphone, 1202, an operation button, 1204, an earpiece, 1206, a mouthpiece, 1300, a digital still camera, 1302, a case, 1304, a light receiving unit, 1306, a shutter button, 1308, a memory, 1312, a video signal output terminal, 1314, an input / output terminal, 1430, a television monitor, 1440, a personal computer

Claims

1. (Fe ｘ Co （１－ｘ） ) （１００－（ａ＋ｂ）） (Si ｙ B （１－ｙ） ) ａ M ｂ [wherein M is at least one selected from the group consisting of C, S, P, Sn, Mo, Cu and Nb; x, y, a and b are 0.73≦x≦0.85, 0.02≦y≦0.10, 13.0≦a≦19.0, 0≦b≦2.0.] The composition is represented by The crystallinity is 70% or less, The coercive force is 40 [A / m] or more (0.5 [Oe] or more) and 175 [A / m] or less (2.2 [Oe] or less), Amorphous alloy soft magnetic powder having a saturation magnetic flux density of 1.60 T or more and 2.20 T or less.

2. 2. The amorphous alloy soft magnetic powder according to claim 1, which has a magnetic permeability of 20.0 or more at a measurement frequency of 100 kHz.

3. Apparent density [g / cm ３ ] is 100, the tap density [g / cm ３ 3. The amorphous alloy soft magnetic powder according to claim 1, wherein the value of Mn is 103 or more and 120 or less.

4. 4. The amorphous alloy soft magnetic powder according to claim 1, having an average particle size of 5.0 μm or more and 60.0 μm or less.

5. A dust core comprising the amorphous alloy soft magnetic powder according to any one of claims 1 to 4.

6. A magnetic element comprising the powder magnetic core according to claim 5.

7. An electronic device comprising the magnetic element according to claim 6.

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