Coating bar and method for producing separation membrane using same

Abstract

The present invention relates to a coating bar and a method for producing a separation membrane using the same. The coating bar according to the present invention can form a coating layer having regions with different thicknesses by only one coating. In addition, the method for manufacturing a separator according to the present invention includes a step of forming a porous coating layer using a predetermined coating bar, thereby manufacturing a separator including a porous coating layer having regions of different thicknesses. In particular, the present invention can manufacture a separator having a thickness greater at both ends than at the center, thereby preventing a phenomenon in which insufficient adhesive strength occurs at both ends of the TD when the separator and the electrode are bonded, and can provide uniform adhesive strength over the entire interface between the separator and the electrode.

Description

[Technical field]

[0001] The present invention relates to a coating bar and a method for producing a separation membrane using the same.

[0002] This application claims priority to Korean Patent Application No. 10-2021-0133531, filed on October 7, 2021, the entire contents of which are incorporated herein by reference in their entirety in the specification and drawings. [Background technology]

[0003] Lithium secondary batteries, which can be repeatedly charged and discharged, are attracting attention as an alternative to fossil energy. Lithium secondary batteries have been mainly used in traditional handheld devices such as mobile phones, video cameras, and power tools. However, their application fields are gradually increasing in recent years, including electrically driven automobiles (EV, HEV, PHEV), large-capacity energy storage systems (ESS), and uninterruptible power supplies (UPS).

[0004] A secondary battery includes an electrode assembly including a positive electrode, a negative electrode, and a separator interposed between them, and an electrolyte that electrochemically reacts with the active material coated on the positive electrode and the negative electrode. A typical secondary battery is a lithium-ion secondary battery in which lithium ions act as working ions to induce an electrochemical reaction at the positive electrode and the negative electrode during charging and discharging. In existing lithium-ion secondary batteries, lamination is applied during the assembly process to realize adhesion between the electrodes and separator within the electrode assembly. Lamination is a process of bonding the separator and the electrodes. Lamination increases the adhesion between the separator and the electrodes by applying pressure and heating to the separator and electrodes that are stacked vertically.

[0005] Typically, positive or negative electrodes are manufactured by coating an active material slurry on a current collector and then drying it. However, when the active material slurry is coated on the current collector, a sliding phenomenon occurs in which the active material slurry flows toward both ends of the TD (transverse direction). As a result, an active material layer with a thinner thickness is formed toward both ends of the TD.

[0006] FIG. 1 shows a typical laminated structure of an electrode and a separator. As shown in FIG. 1, the separator 1 includes a porous coating layer 12 having a certain thickness on at least one surface of a porous polymer substrate 11, and the electrode 2 includes an active material layer 22 on at least one surface of a current collector 21. The active material layer 22 has a thickness that gradually decreases toward both ends of the TD. As a result, there is a problem that the adhesive strength at both ends of the TD is particularly low even when the separator and the electrode are laminated due to the insufficient thickness at both ends of the TD. In severe cases, there is a problem that the separator and the electrode are not adhered to each other and float up.

[0007] Meanwhile, methods for forming a coating layer by applying another material onto a substrate include, for example, gravure coating, reverse roll coating, and wire bar coating. Among these, wire bar coating is widely used due to its advantages of being relatively easy to operate and manage compared to other coating methods and being able to apply a thin and uniform coating over a wide area. Specifically, the wire bar coating method may involve supplying a coating solution to a coating bar around which a wire is wound, bringing the substrate into contact with the coating bar, and transferring the coating solution onto the substrate while rotating the coating bar, or applying the coating solution to one side of the substrate and then rotating the coating bar around which a wire is wound.

[0008] However, since a coating layer formed using a coating bar is formed to a uniform thickness, there is a problem in that the wire bar coating method cannot be used to form a coating layer having regions of different thicknesses in a single coating. Summary of the Invention [Problem to be solved by the invention]

[0009] The present invention has been made in consideration of the above problems, and an object of the present invention is to provide a coating bar capable of forming a coating layer having regions with different thicknesses by only one coating.

[0010] Another object of the present invention is to provide a predetermined coating bar.

[0011] Other objects and advantages of the present invention can be realized by the means or methods recited in the claims, and combinations thereof. [Means for solving the problem]

[0012] The present inventors have found that the above-mentioned problems can be solved by the following coating bar and a method for producing a separation membrane using the same.

[0013] The first embodiment is A coating bar for coating an organic / inorganic slurry onto one side of a substrate, comprising: The coating bar is a cylindrical bar having a wire wound on its surface. The cylindrical bar has a diameter at both ends smaller than the diameter at the center, The coating bar has a wire diameter that is larger than the wire diameter that is wound around the center portion.

[0014] The second embodiment is the same as the first embodiment, The coating bar is characterized in that the outer diameter of the coating bar is constant.

[0015] The third embodiment is the first or second embodiment, The present invention relates to a coating bar, wherein the length of one of the two ends is 0.1 to 10% of the total length of the coating bar.

[0016] A fourth embodiment is any one of the first to third embodiments, The present invention relates to a coating bar, characterized in that the diameter of the wire wound around the both ends is 10% to 100% larger than the diameter of the wire wound around the center.

[0017] The fifth embodiment is Providing a porous polymeric substrate; and coating at least one surface of the porous polymer substrate with an organic / inorganic slurry including a binder polymer and inorganic particles using the coating bar according to any one of the first to fourth embodiments to form a porous coating layer.

[0018] The sixth embodiment is the fifth embodiment, The present invention relates to a method for producing a separator, wherein the thickness of both ends of the porous coating layer in a transverse direction (TD) is greater than the thickness of the central portion of the TD.

[0019] The seventh embodiment is the fifth or sixth embodiment, The present invention relates to a method for producing a separation membrane, wherein the thickness of the porous coating layer at both TD ends is 10 to 150% thicker than the thickness of the TD center portion.

[0020] The eighth embodiment is any one of the fifth to seventh embodiments, The present invention relates to a method for producing a separation membrane, wherein the length of one of both ends of the porous coating layer is 0.1 to 10% of the entire length of the separation membrane in the width direction. Effect of the Invention

[0021] The coating bar according to the present invention can form a coating layer having regions with different thicknesses by only one coating.

[0022] In addition, the method for manufacturing a separator according to the present invention includes a step of forming a porous coating layer using a predetermined coating bar, thereby manufacturing a separator including a porous coating layer having regions of different thicknesses. Specifically, the present invention can manufacture a separator having a thicker thickness at both ends than at the center, thereby preventing a phenomenon in which insufficient adhesive strength occurs at both ends of the TD when the separator and the electrode are bonded, and can provide uniform adhesive strength at the entire interface between the separator and the electrode.

[0023] The following drawings attached to this specification are for illustrating preferred embodiments of the present invention, and serve to further understand the technical idea of ​​the present invention together with the detailed description of the invention, so the present invention should not be interpreted as being limited to only the matters described in the drawings. In addition, the shape, size, scale, ratio, etc. of the elements in the drawings attached to this specification may be exaggerated in order to emphasize a clearer description. [Brief description of the drawings]

[0024] [Figure 1] FIG. 1 is a cross-sectional view showing a schematic structure in which a conventional separator and electrodes are stacked. [Diagram 2] FIG. 2 is a schematic diagram of the structure of a coating bar according to the present invention; [Diagram 3] FIG. 2 is a schematic diagram showing the structure of a cylindrical bar included in a coating bar according to the present invention. [Figure 4] 1 is a cross-sectional view illustrating an example of a stacked structure of a separator and an electrode manufactured according to the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0025] Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the attached drawings. Prior to this, the terms and words used in the specification and claims should not be interpreted as being limited to their ordinary or dictionary meanings, but should be interpreted as having meanings and concepts according to the technical ideas of the present invention, in accordance with the principle that the inventor himself can appropriately define the concepts of terms in order to best describe the invention.

[0026] Throughout the specification, when a part is described as "comprising" or "having" certain elements, this does not mean excluding other elements, but means that it may further include or further comprise other elements, unless otherwise specified.

[0027] The terms "about," "substantially," and the like, used throughout this specification, when given the meaning inherent in the manufacturing and material tolerances, are used to mean a numerical value or a approximation thereof, and are used to prevent unconscionable infringers from unfairly using disclosures in which precise or absolute numerical values ​​are recited to aid in the understanding of this application.

[0028] Throughout this specification, the phrase "A and / or B" means "A or B, or all of these."

[0029] The present invention relates to a coating bar and a method for producing a separation membrane using the same.

[0030] <Coating bar> According to one aspect of the invention, the coating bar of the invention comprises: A coating bar for coating an organic / inorganic slurry onto one side of a substrate, comprising: The coating bar is a cylindrical bar having a wire wound on its surface. The cylindrical bar has a diameter at both ends smaller than the diameter at the center, The wire diameter of the wire wound around the both ends is larger than the wire diameter of the wire wound around the center portion.

[0031] The coating bar of the present invention is a coating bar for coating one surface of a substrate with an organic / inorganic slurry, and the coating bar has a form in which a wire is wound around the surface of a cylindrical bar.

[0032] The substrate may be a film, sheet, nonwoven fabric, etc., without limitation, as long as it is a material that can be used as a support. For example, the substrate may be a porous polymer substrate that can be used as a substrate for a separator in a secondary battery. The porous polymer substrate is an ion-conductive barrier that allows ions to pass while blocking electrical contact between a negative electrode and a positive electrode, and is a substrate having a plurality of pores formed therein. The porous polymer substrate may be formed of a polyolefin polymer such as polyethylene, polypropylene, or polybutylene.

[0033] The organic / inorganic slurry is a slurry that can be coated on at least one surface of the substrate, and can contain an organic compound and / or an inorganic substance, but the components contained in the slurry are not limited.

[0034] A typical coating bar is formed by winding a wire having a certain wire diameter around a cylindrical bar having a certain diameter. When coating is performed using such a coating bar, a coating solution is contained in the space between adjacent wires, and a coating layer having a certain thickness can be formed on one side of a substrate.

[0035] However, while coating using a conventional coating bar has the advantage of being able to form a uniform coating layer over a wide area, it has the problem that only a coating layer having a constant thickness can be formed and it is not possible to form a coating layer having regions with different thicknesses.

[0036] Therefore, the inventors of the present invention aim to provide a coating bar capable of forming a coating layer having regions with different thicknesses even in a single coating run by modifying the design of the coating bar.

[0037] According to one embodiment of the present invention, the cylindrical bar provided in the coating bar of the present invention has a diameter at both ends that is smaller than the diameter at the center, and the wire diameter of the wire wound at the both ends is larger than the wire diameter of the wire wound at the center.

[0038] If at least two types of wires with different diameters are wound around a cylindrical bar having a certain diameter, the portion around which the wire with the larger diameter (i.e., thicker wire) is wound will have a thicker outer diameter than the portion around which the wire with the smaller diameter (i.e., thinner wire) is wound. In this case, the wire in the portion with the thicker outer diameter applies a larger pressure to the substrate, which may cause deformation of the substrate.

[0039] Therefore, in the present invention, the diameter of the cylindrical bar around which a wire with a larger wire diameter is wound is set to be smaller than the diameter of the cylindrical bar around which a wire with a smaller wire diameter is wound, thereby making it possible to make the pressure received by the coating bar on the substrate uniform.

[0040] In addition, by making the wire diameter thickness of the wire wound around both ends and the center of the cylindrical bar of the present invention different, the thickness of the organic / inorganic slurry coated on the substrate can be adjusted. Specifically, according to the present invention, the amount of organic / inorganic slurry accommodated in the space between the adjacent wires wound around both ends of the cylindrical bar is greater than the amount of organic / inorganic slurry accommodated in the space between the adjacent wires wound around the center of the cylindrical bar. This allows a larger amount of organic / inorganic slurry to be coated on both ends of the substrate than on the center, so that the coating layer can be formed thicker on both ends of the substrate than on the center.

[0041] In particular, the present invention is characterized by changing the design of both ends of the coating bar. In the present invention, the coating bar includes a central portion and end portions, and the regions excluding the central portion may be referred to as both ends. Specifically, the length of one of the both ends may be about 0.1 to 10% or about 0.2 to 5% of the total length of the coating bar.

[0042] According to a specific embodiment of the present invention, the outer diameter of the coating bar may be approximately constant.

[0043] The outer diameter of the coating bar means the outer diameter of the coating bar measured at the position where the wire is wound. That is, the outer diameter of the coating bar is twice the sum of the radius of the cylindrical bar and the wire diameter of the wire. In addition, "constant outer diameter" means that the outer diameters of both ends and the center of the coating bar are uniform, or that both ends and the center of the coating bar have substantially the same outer diameter, or that the outer diameters may be substantially the same within the error range during measurement. Specifically, the diameter of the cylindrical bar and the wire diameter of the both ends and the center of the coating bar of the present invention may be different from each other, but the outer diameter of the coating bar may be constant. That is, the diameter of the cylindrical bar may be thicker at the center and thinner at both ends. Thus, the wire diameter of the wire wound around both ends of the cylindrical bar may be thicker than the wire diameter of the wire wound around the center of the cylindrical bar.

[0044] Fig. 2 shows a schematic structure of a coating bar according to one embodiment of the present invention. Fig. 3 shows a schematic cylindrical bar of the coating bar according to one embodiment of the present invention. Fig. 2 shows the shape of a coating bar 30 in which a wire 32 is wound around a cylindrical bar 31 according to Fig. 3. The wire with a larger wire diameter is wound around both ends B1 and B2, and the wire with a smaller wire diameter is wound around the center A, so that the outer diameter is constant.

[0045] Meanwhile, according to a specific embodiment of the present invention, the wire diameter of the wire wound around both ends may be about 10% to 100%, or 20% to 80% larger than the wire diameter of the wire wound around the center. By setting the difference in wire diameter between the wire wound around the center and both ends of the cylindrical bar within the above range, the thickness of the organic / inorganic slurry coated on both ends and the center of the substrate can be adjusted within an appropriate range.

[0046] According to a specific embodiment of the present invention, the diameter of both ends of the cylindrical bar of the present invention is smaller than that of the center, and the diameter of both ends of the cylindrical bar may be determined depending on the thickness of the wire diameter of the wire wound around both ends. In particular, the diameters of both ends and the center of the cylindrical bar may be determined depending on the thickness of the wire diameter so that the outer diameter of the coating bar is constant. For example, the diameter of both ends of the cylindrical bar may be smaller than the diameter of the center by about 0.5 to 10% or 1 to 5%. When the difference in diameter between both ends and the center of the cylindrical bar is within the above range, the pressure applied to the substrate by the coating bar when coating one side of the substrate with an organic / inorganic slurry can be minimized, thereby suppressing deformation of the substrate.

[0047] <Membrane manufacturing method> According to one aspect of the present invention, a method for producing a separation membrane of the present invention includes the steps of: Providing a porous polymeric substrate; and coating at least one surface of the porous polymer substrate with an organic / inorganic slurry including a binder polymer and inorganic particles using a coating bar according to an embodiment of the present invention to form a porous coating layer.

[0048] In particular, in the present invention, when forming a porous coating layer, the thickness of both ends of the porous coating layer may be controlled by coating at least one surface of the porous polymer substrate with an organic inorganic slurry using a coating bar according to an embodiment of the present invention as described above. Specifically, after supplying the organic inorganic slurry to a coating bar according to an embodiment of the present invention, the coating bar contacts one surface of the porous polymer substrate and rotates, so that the organic inorganic slurry is transferred to the porous polymer substrate, thereby forming a porous coating layer on one surface of the porous polymer substrate. Alternatively, after applying the organic inorganic slurry to at least one surface of the porous polymer substrate, the coating bar according to an embodiment of the present invention rotates on the organic inorganic slurry while the polymer substrate moves along the coating direction, so that a porous coating layer may be formed on one surface of the porous polymer substrate.

[0049] In a separator manufactured by a conventional manufacturing method, there is a problem that the adhesive strength at both ends is insufficient, resulting in poor adhesion to the electrodes. In the present invention, however, the thickness of only both ends of the porous coating layer is selectively made thicker, thereby improving the problem of insufficient adhesive strength at both ends and providing a method for manufacturing a separator that can ensure sufficient adhesive strength when laminating the separator and electrodes.

[0050] If the content of the binder polymer is increased or a separate adhesive layer is formed to ensure the adhesive strength between the separator and the electrode, the resistance of the battery cell may increase or the thickness of the separator may increase, resulting in a loss in capacity of the battery cell. However, in the separator of the present invention, the porous coating layer is formed thicker only at both ends of the TD than at the center of the TD, so that no loss in capacity of the secondary battery occurs.

[0051] According to a specific embodiment of the present invention, as shown in FIG. 4, the porous coating layer may have a shape in which the thickness of both ends of the porous coating layer in the TD is greater than the thickness of the central portion of the porous coating layer in the TD.

[0052] For example, the thickness of both ends of the TD of the porous coating layer may be about 10 to 150%, or about 30 to 80%, thicker than the thickness of the central portion of the TD. Alternatively, both ends of the TD of the porous coating layer may include a region in which the thickness gradually increases in a direction away from the central portion of the TD. By setting the thickness of both ends of the TD of the porous coating layer of the present invention to be thicker than the thickness of the central portion of the TD, the phenomenon of insufficient adhesive strength at both ends of the TD can be improved, and sufficient adhesive strength can be secured during lamination of the separator and the electrodes.

[0053] According to a specific embodiment of the present invention, the length of one of the ends of the porous coating layer may be about 0.1 to 10%, or about 0.2 to 5% of the entire length in the width direction of the substrate. By setting the end to have a length within this range, a phenomenon in which the adhesive strength with the electrode is reduced can be prevented, and uniform adhesive strength can be obtained over the entire interface where the electrode and the separator contact each other.

[0054] In the present invention, the porous polymer substrate means a substrate having a plurality of pores formed therein, as described above. The pores are structured to be interconnected, allowing gas or liquid to pass from one side of the substrate to the other side. As such a porous polymer substrate, a porous polymer film containing a thermoplastic resin may be used in order to provide a shutdown function. Here, the shutdown function refers to a function in which, when the temperature of the battery becomes high, the thermoplastic resin melts and closes the pores of the porous substrate, thereby blocking the movement of ions and preventing thermal runaway of the battery. In terms of the shutdown function, the thermoplastic resin preferably has a melting point of less than about 200°C.

[0055] The thickness of the porous polymer substrate is not particularly limited, but is preferably about 1 to 100 μm, more preferably about 5 to 50 μm or about 5 to 30 μm. The pores present in the porous polymer substrate are not particularly limited, but are preferably about 10 to 95%, or about 35 to 65%.

[0056] In the present invention, the porous coating layer may have a structure in which the inorganic particles are filled and in contact with each other and are bound to each other by the binder polymer, thereby forming interstitial volumes between the inorganic particles, and the interstitial volumes between the inorganic particles may become vacant spaces to form pores.

[0057] In the present invention, specifically, the weight ratio of the inorganic particles to the binder polymer in the porous coating layer may be 99:1 to 50:50.

[0058] In the present invention, the binder polymer is not particularly limited as long as it can provide a binding force between inorganic particles and a binding force between the porous coating layer and the electrode. For example, the binder polymer may be polyvinylidene fluoride-hexafluoropropylene (PVDF-co-HFP), polyvinylidene fluoride-trichloroethylene, polyvinylidene fluoride-chlorotrifluoroethylene, polyvinylidene fluoride-co ... ethylene), poly(methyl)methacrylate, polyethyl(meth)acrylate, poly n-propyl(meth)acrylate, polyisopropyl(meth)acrylate, poly n-butyl(meth)acrylate, poly t-butyl(meth)acrylate, poly sec-butyl(meth)acrylate, polypentyl(meth)acrylate, poly 2-ethylbutylpoly(meth)acrylate, poly 2-ethylhexyl(meth)acrylate, poly n-octyl(meth)acrylate, polyisooctyl(meth)acrylate, polyisononyl(meth)acrylate, polylauryl(meth)acrylate, polytetradecyl(meth)acrylate, poly N-vinylpyrrolidinone, polyacrylonitrile, polyvinylacetate, polyethylene-co-vinyl acetate, polyethylene oxide, cellulose acetate acetate), cellulose acetate butyrate, cellulose acetate propionateThe polymer may be one or a mixture of two or more selected from the group consisting of acrylonitrile-styrene-butadiene copolymer, cyanoethyl propionate, cyanoethyl pullulan, cyanoethyl polyvinyl alcohol, cyanoethyl cellulose, cyanoethyl sucrose, pullulan, carboxyl methyl cellulose, acrylonitrile-styrene-butadiene copolymer, and polyimide.

[0059] Also, the binder polymer may be a particle-type binder polymer resin. For example, it may be an acrylic copolymer, a styrene butadiene rubber, or a mixture of two or more of these. The acrylic copolymer may include a copolymer of ethylhexyl acrylate and methyl methacrylate, polymethylmethacrylate, polyethylhexyl acrylate, polybutylacrylate, polyacrylonitrile, a copolymer of butyl acrylate and methyl methacrylate, or a mixture of two or more of these.

[0060] In the present invention, the inorganic particles are not particularly limited as long as they are electrochemically stable. For example, the inorganic particles are not particularly limited as long as they do not undergo oxidation and / or reduction reactions within the operating voltage range of the applied electrochemical device (e.g., 0 to 5 V based on Li / Li+). Non-limiting examples include ZrO2, BaTiO3, Pb(Zr,Ti)O3 (PZT), Pb 1-x La x Zr 1-y Ti y O3(PLZT), PB(Mg3Nb 2 / 3)Examples of these include O3-PbTiO3 (PMN-PT), hafnia (HfO2), SrTiO3, SnO2, CeO2, MgO, NiO, CaO, ZnO, ZrO2, Y2O3, Al2O3, TiO2, AlOOH, Al(OH)3, SiC, or mixtures thereof. On the other hand, in addition to these, lithium phosphate (Li3PO4), lithium titanium phosphate (Li x Ti y (PO4)3, 0 < x < 2, 0 < y < 3), lithium aluminum titanium phosphate (Li x Al y Ti z (PO4)3, 0 < x < 2, 0 < y < 1, 0 < z < 3), (LiAlTiP) x O y -based glass (0 < x < 4, 0 < y < 13), lithium lanthanum titanate (Li x La y TiO3, 0 < x < 2, 0 < y < 3), lithium germanium thiophosphate (Li x Ge y P z S w , 0 < x < 4, 0 < y < 1, 0 < z < 1, 0 < w < 5), lithium nitride (Li x N y , 0 < x < 4, 0 < y < 2), SiS2-based glass (Li x Si y S z , 0 < x < 3, 0 < y < 2, 0 < z < 4), P2S5-based glass (Li x P y S z , 0 < x < 3, 0 < y < 3, 0 < z < 7) or may further contain two or more of these inorganic particles.

[0061] Hereinafter, the present invention will be described with specific examples. However, the examples according to the present invention can be deformed into various other forms, and the scope of the present invention should not be construed as being limited to the following examples. The examples of the present invention are provided to more fully explain the present invention to those with average knowledge in the industry.

[0062] Examples Each of the Examples and Comparative Examples was manufactured by the following method. The Examples and Comparative Examples will be described below with reference to the drawings and Tables 1 and 2.

[0063] Example 1 A slurry was prepared by adding a polyethylene porous substrate (thickness: 9 μm, porosity: 45%), polyvinylidene fluoride as a binder polymer, alumina (Al2O3) (particle size: 500 nm) as inorganic particles, and acetone as a solvent.

[0064] The slurry was applied to one side of the porous substrate using a slurry coating bar and dried to prepare a separator.

[0065] The coating bar used here has a structure as shown in Figure 2. The total length of the coating bar was 250 mm, with the central portion A being 200 mm and both ends B1 and B2 being 25 mm each. The outer diameter of the coating bar used was constant, with the diameter of the cylindrical bar at the central portion A being 12.7 mm, the wire diameter of the wire wound around the cylindrical bar at the central portion A being 0.4 mm, the diameter of the cylindrical bar at both ends B1 and B2 being 12.5 mm, and the wire diameter of the wire wound around the cylindrical bar at both ends B1 and B2 being 0.5 mm.

[0066] Example 2 and Comparative Examples 1 and 2 Separation membranes were produced in the same manner as in Example 1, and the diameters of the cylindrical bars at the center A and both ends B1 and B2 of the coating bar and the wire diameters of the wires wound around them were changed to coat the slurry, as shown in Table 1 below.

[0067] [Table 1]

[0068] [Table 2]

[0069] Specifically, the electrode adhesive strength (Lami strength, gf / 25mm) was evaluated using the following method: Active material [natural graphite and artificial graphite (weight ratio 5:5)], conductive material [Super P], and binder [Polyvinylidene fluoride (PVdF)] were mixed in a weight ratio of 92:2:6, dispersed in water, and then coated on copper foil with a width of 250mm to prepare a negative electrode.

[0070] As in Examples 1 and 2 and Comparative Examples 1 and 2, a separator having a width of 250 mm was manufactured and prepared.

[0071] The prepared separator and anode were stacked on top of each other, sandwiched between 100 μm PET films, and bonded using a roll lamination machine under the conditions of 60° C., 2.4 kgf / mm pressure, and 5 m / min speed.

[0072] The center A and both ends B1 and B2 of the bonded separator and negative electrode were cut to a size of 25 mm in width and 70 mm in length, and the separator and the end of the negative electrode were mounted on a UTM device (Instron). A force was then applied at 180° at a measurement speed of 300 mm / min to measure the force required to separate the separator bonded to the negative electrode from the negative electrode. [Explanation of symbols]

[0073] 1 Separation membrane 11 Porous polymer substrate 12 Porous coating layer 2 electrodes 21 Current collector 22 Active material layer 30 Coating bar 31 Cylindrical Bar 32 Wire A Central section B1, B2 ends

Claims

1. A coating bar for coating an organic / inorganic slurry onto one side of a substrate, comprising: The coating bar is a cylindrical bar having a wire wound on its surface. The cylindrical bar has a diameter at both ends smaller than a diameter at a center portion, A coating bar, characterized in that the wire diameter of the wire wound around the both ends is larger than the wire diameter of the wire wound around the center portion.

2. 2. The coating bar of claim 1, wherein the outer diameter of the coating bar is constant.

3. The cylindrical bar comprises a central portion and both end portions excluding the central portion, 2. The coating bar according to claim 1, wherein the length of one of the two ends is 0.1 to 10% of the total length of the coating bar.

4. 2. The coating bar according to claim 1, wherein the wire diameter of the wire wound around the both ends is 10% to 100% larger than the wire diameter of the wire wound around the center portion.

5. 2. The coating bar according to claim 1, wherein the substrate is a porous polymer substrate used as a substrate for a separator in a secondary battery.

6. 2. The coating bar according to claim 1, wherein the amount of organic / inorganic slurry contained in the spaces between the adjacent wires wound around both ends of the cylindrical bar is greater than the amount of organic / inorganic slurry contained in the spaces between the adjacent wires wound around the center of the cylindrical bar.

7. 3. The coating bar of claim 2, wherein the outer diameter of the coating bar is twice the sum of the radius of the cylindrical bar and the diameter of the wire.

8. 5. The coating bar according to claim 4, wherein the wire diameter of the wire wound around the both ends is 20 to 80% larger than the wire diameter of the wire wound around the center portion.

9. 2. The coating bar according to claim 1, wherein the diameters of both ends of the cylindrical bar are 0.5 to 10% smaller than the diameter of the central portion.

10. 2. The coating bar of claim 1, wherein the diameters of both ends of the cylindrical bar are 1-5% smaller than the diameter of the center portion.

11. Providing a porous polymeric substrate; and coating at least one surface of the porous polymer substrate with an organic / inorganic slurry including a binder polymer and inorganic particles using the coating bar according to claim 1 to form a porous coating layer.

12. The method for manufacturing a separation membrane according to claim 11, wherein the thickness of both ends of the porous coating layer in a transverse direction (TD) is greater than the thickness of a central portion of the porous coating layer in the TD.

13. The method for manufacturing a separation membrane according to claim 11, wherein the thickness of both ends of the porous coating layer in the TD is 10 to 150% thicker than the thickness of the central portion in the TD.

14. The porous coating layer comprises a TD center portion and both TD end portions, The method for producing a separation membrane according to claim 11, wherein the length of one of both TD ends of the porous coating layer is 0.1 to 10% of the entire length of the separation membrane in the width direction.

15. The method for producing a separation membrane according to claim 11, wherein the thickness of both ends of the porous coating layer in the TD is 30 to 80% thicker than the thickness of the central portion in the TD.

16. The method of claim 11, wherein a weight ratio of the inorganic particles to the binder polymer in the porous coating layer is 99:1 to 50:50.

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