Grain-oriented electrical steel sheet and its manufacturing method

Abstract

An object of the present invention is to provide a grain-oriented electrical steel sheet in which, after grooves are formed, Fe-O oxides formed on the surface are removed to appropriately form islands, thereby improving magnetic properties and adhesion to an insulating coating layer, and a method for manufacturing the same. [Solution] The method for producing a grain-oriented electrical steel sheet of the present invention includes the steps of producing a cold-rolled sheet, irradiating the cold-rolled sheet with a laser to form grooves, removing Fe—O oxides formed on the surface of the cold-rolled sheet, subjecting the cold-rolled sheet to primary recrystallization annealing, and applying an annealing separator to the primarily recrystallized cold-rolled sheet and subjecting it to secondary recrystallization annealing, and is characterized in that the adhesion coefficient calculated by the following equation 1 is 0.016 to 1.13. [Number 1] Adhesion coefficient (S ad )=(0.8×R) / H hill-up In Equation 1, R represents the average roughness (μm) of the cold-rolled sheet surface after the oxide removal step, and H hill-up indicates the average height (μm) of hill-ups present on the surface of the cold-rolled sheet after the oxide removal step.

Description

[Technical field]

[0001] The present invention relates to a grain-oriented electrical steel sheet and a manufacturing method thereof, and more particularly to a grain-oriented electrical steel sheet in which, after grooves are formed, Fe-O oxide formed on the surface is removed to appropriately form islands, thereby improving magnetic properties and adhesion to an insulating coating layer, and a manufacturing method thereof. [Background technology]

[0002] Grain-oriented electrical steel sheets are used as core materials in electromagnetic products such as transformers. In order to reduce the power loss of electrical equipment and improve energy conversion efficiency, steel sheets that have excellent core loss and a high space factor during lamination and winding are required. Grain-oriented electrical steel sheets are made by hot rolling, cold rolling, and annealing processes, and the grains are recrystallized in the rolling direction. <001> This refers to a functional steel sheet that has a texture (also known as "Goss Texture") oriented in the direction. A method for reducing the iron loss of grain-oriented electrical steel sheets is known to be a method for refining the magnetic domains. That is, the magnetic domains are scratched or energetically impacted to reduce the size of the large magnetic domains that grain-oriented electrical steel sheets have. In this case, the amount of energy consumed when the magnetic domains are magnetized and change direction can be reduced compared to when the magnetic domains were large. There are two methods for refining the magnetic domains: permanent magnetic domain refinement, in which the magnetic properties are improved and the effect is maintained even after heat treatment, and temporary magnetic domain refinement, in which the effect is not maintained.

[0003] Permanent magnetic domain refinement methods that show iron loss improvement effects even after stress relief heat treatment above the heat treatment temperature at which recovery occurs can be divided into etching, rolling, and laser methods. The etching method forms grooves on the steel sheet surface through selective electrochemical reactions in a solution, making it difficult to control the groove shape and ensuring uniform iron loss characteristics in the width direction of the final product. In addition, it has the disadvantage of inducing environmental pollution due to the acid solution used as a solvent. The permanent magnetic domain refinement method using rolls is a magnetic domain refinement technology that shows an iron loss improvement effect by forming grooves with a certain width and depth on the plate surface by processing a protrusion shape on the roll and pressing the roll or plate, and then annealing to cause partial recrystallization under the groove. The roll method has the disadvantages of being stable against machining, being difficult to ensure stable iron loss depending on the thickness, being unreliable, and the complex process, and the iron loss and magnetic flux density characteristics deteriorating immediately after groove formation (before stress relief annealing). The laser method of miniaturizing permanent magnetic domains involves irradiating a high-power laser onto the surface of a magnetic steel sheet moving at high speed, forming grooves in the matrix by melting the laser irradiation. However, even with this method of miniaturizing permanent magnetic domains, it is difficult to miniaturize magnetic domains to the minimum size.

[0004] In the case of temporary magnetic domain miniaturization, we are researching a method of applying laser light to a coated material without applying the coating again, so we do not attempt to irradiate the laser with a strength greater than a certain level, because if the strength exceeds a certain level, the coating will be damaged and the tension effect will not be fully exerted. In the case of miniaturizing permanent magnetic domains, the grooves are carved to expand the free charge area that can receive magnetostatic energy, so the groove depth must be as deep as possible. Of course, a deep groove depth can also cause side effects such as a decrease in magnetic flux density. Therefore, the groove depth must be controlled to an appropriate level in order to reduce the deterioration of magnetic flux density. Meanwhile, grain-oriented electrical steel sheets manufactured using magnetic domain refinement technology are manufactured into products such as transformer cores through forming and heat treatment processes. In addition, since the products are used in relatively high-temperature environments, it is necessary to ensure not only the core loss characteristics but also the adhesion with the insulating coating layer. Summary of the Invention [Problem to be solved by the invention]

[0005] An object of the present invention is to provide a grain-oriented electrical steel sheet and a manufacturing method thereof. More specifically, it is an object of the present invention to provide a grain-oriented electrical steel sheet and a manufacturing method thereof in which, after grooves are formed, Fe-O oxides formed on the surface are removed to appropriately form islands, thereby improving magnetic properties and adhesion to an insulating coating layer. [Means for solving the problem]

[0006] The grain-oriented electrical steel sheet of the present invention is characterized by comprising grooves located on the surface of the electrical steel sheet, a metal oxide layer located on the grooves, and metal oxide islands located below the grooves and discontinuously dispersed.

[0007] The average particle size of the islands located under the groove is 0.5 to 5 μm. The island density is 0.5 / μm 2 The present invention is characterized in that:

[0008] When bending an electromagnetic steel sheet into a rod-shaped cylinder, the minimum diameter at which the insulating coating layer does not peel off or crack is less than 25 mm, In electrical steel sheets, R / H hill-up is characterized in that it is 0.02 to 1.0.

[0009] The method for producing a grain-oriented electrical steel sheet of the present invention includes the steps of producing a cold-rolled sheet, forming grooves in the cold-rolled sheet, removing Fe-O oxides formed on the surface of the cold-rolled sheet, subjecting the cold-rolled sheet to primary recrystallization annealing, and applying an annealing separator to the primarily recrystallized cold-rolled sheet and subjecting it to secondary recrystallization annealing, and is characterized in that the adhesion coefficient, calculated by the following equation 1, is 0.016 to 1.13. [Number 1] Adhesion coefficient (S ad )=(0.8×R) / H hill-up In the formula 1, R is the average roughness (μm) of the cold-rolled sheet surface after removing oxides, and H hill-up indicates the average height (μm) of hill-ups present on the surface of the cold-rolled sheet after the oxide removal step.

[0010] After removing the oxides, the average roughness (R) of the cold-rolled sheet surface is 3.0 μm or less. The average height of hill-ups on the surface of the cold-rolled sheet (H hill-up ) is 5.0 μm or less.

[0011] In the step of forming the groove, the cold rolled sheet is irradiated with a laser or plasma to form a groove; This is characterized by the fact that a resolidified layer can be formed at the bottom of the groove.

[0012] The roughness before the oxide removal step is characterized in that the average roughness (R) of the cold rolled sheet surface is 1.2 μm or more. Effect of the Invention

[0013] According to the present invention, the adhesion coefficient is appropriately controlled and islands are appropriately formed under the grooves, thereby making it possible to improve adhesion and corrosion resistance. [Brief description of the drawings]

[0014] [Figure 1] FIG. 2 is a schematic diagram of the rolled surface (ND surface) of the grain-oriented electrical steel sheet of the present invention. [Diagram 2] FIG. 2 is a schematic diagram of a groove of the present invention. [Diagram 3] FIG. 2 is a schematic diagram of a cross section of a groove of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0015] Terms such as first, second and third are used to describe various parts, components, regions, layers and / or sections, but are not limited thereto. These terms are used only to distinguish one part, component, region, layer or section from another part, component, region, layer or section. Thus, a first part, component, region, layer or section described below can be referred to as a second part, component, region, layer or section without departing from the scope of the present invention. The terminology used herein is for the purpose of referring to particular embodiments only and is not intended to limit the invention. As used herein, the singular form includes the plural form unless the phrase clearly indicates otherwise. As used in the specification, the meaning of "comprising" embodies the specified features, regions, integers, steps, operations, elements and / or components and does not exclude the presence or addition of other features, regions, integers, steps, operations, elements and / or components. When an element is referred to as being "on" or "on" another element, it may be immediately on or above the other element, or there may be other elements between them. In contrast, when an element is referred to as being "directly on" another element, there are no other elements between them. Unless otherwise defined, all terms, including technical and scientific terms, used herein have the same meaning as commonly understood by a person of ordinary skill in the art to which the present invention belongs. Terms defined in commonly used dictionaries are additionally interpreted to have a meaning consistent with the relevant technical literature and the currently disclosed content, and are not interpreted in an ideal or very formal sense unless otherwise defined.

[0016] DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will now be described in detail with reference to exemplary embodiments thereof, so that those skilled in the art will be able to easily practice the present invention. However, the present invention may be embodied in many different forms and is not limited to the embodiments set forth herein. FIG. 1 shows a schematic diagram of a grain-oriented electrical steel sheet 10 with magnetic domain refinement according to one embodiment of the present invention. As shown in FIG. 1, a grain-oriented electrical steel sheet 10 of the present invention has linear grooves 20 formed on one or both sides of the electrical steel sheet in a direction intersecting the rolling direction (RD direction). Each step will be explained in detail below. First, a cold-rolled sheet is manufactured. The present invention is characterized by a method for refining magnetic domains after the cold-rolled sheet is manufactured, and the cold-rolled sheet to be refined can be any cold-rolled sheet used in the field of grain-oriented electrical steel sheets without any restrictions. In particular, the effect of the present invention is achieved regardless of the alloy composition of the grain-oriented electrical steel sheet. Therefore, a detailed description of the alloy composition of the grain-oriented electrical steel sheet is omitted. As an example, the cold-rolled sheet contains, by weight, C: 0.07% or less, Si: 1.0 to 6.5%, Mn: 0.005 to 3.0%, Nb + V + Ti: 0.050% or less, Cr + Sn: 1.0% or less, Al: 3.0% or less, P + S: 0.08% or less, and rare earth and other impurities total 0.3% or less, with the balance being Fe. Regarding the method for producing the cold rolled sheet, any method for producing a cold rolled sheet used in the field of grain-oriented electrical steel sheets may be used without any restrictions, and a detailed description thereof will be omitted.

[0017] Next, grooves are formed in the cold rolled sheet. In the step of forming the grooves, 2 to 10 grooves are formed intermittently in the rolling direction. Fig. 1 shows an example in which 4 grooves are formed intermittently in the rolling direction. However, the present invention is not limited to this, and the grooves can be formed continuously. 1 and 2, the longitudinal direction of the groove 20 (RD direction in FIG. 1, X direction in FIG. 2) and the rolling direction (RD direction) form an angle of 75 to 88°. When the groove 20 is formed at the above angle, it contributes to improving the iron loss of the grain-oriented electrical steel sheet. The width (W) of the groove is 10 to 200 μm. If the width of the groove 20 is too narrow or too large, a suitable magnetic domain refining effect may not be obtained. In addition, the groove depth (H) is 30 μm or less. If the groove depth (H) is too deep, the strong laser irradiation may significantly change the structural characteristics of the steel sheet 10 or may form a large amount of hill-up and spatter, deteriorating the magnetic properties. Therefore, the depth of the groove 20 can be controlled within the above-mentioned range. More specifically, the groove depth is 3 to 30 μm.

[0018] In the step of forming the grooves, the cold rolled sheet is irradiated with a laser or plasma to form the grooves. When using a laser, grooves can be formed on the surface of the cold-rolled sheet by irradiating the surface with a TEMoo (M2≦1.25) laser beam with an average output of 500W to 10KW. There are no limitations on the laser oscillation mode. That is, continuous oscillation or pulsed mode can be used. In this manner, the laser is irradiated so that the surface beam absorption rate is equal to or greater than the heat of fusion of the steel sheet, thereby forming the grooves 20 shown in FIG. 1 and FIG. 2. In FIG. 2, the X direction indicates the length direction of the groove 20. When using a laser or plasma in this way, a resolidified layer can be formed under the groove due to the heat emitted from the laser or plasma. The resolidified layer is classified based on its grain size, which is different from the overall structure of the electrical steel sheet during manufacturing. The thickness of the resolidified layer can be 5.0 μm or less. If the resolidified layer is too thick, the metal oxide layer described below will form too thick, which can reduce the adhesion and corrosion resistance of the metal oxide layer and the matrix structure. After the groove formation step, the surface of the steel sheet is partially oxidized by the heat generated by the laser or plasma, the oxygen and moisture in the air, and the oxygen and moisture in the injected gas, resulting in the presence of Fe-O oxides.

[0019] In the present invention, Fe-O oxide formed on the surface of the cold rolled steel sheet is removed. The method for removing the Fe-O oxide is not particularly limited, and a dry or wet polishing method can be used. After polishing, the Fe-O oxide may flow into the grooves, and a rinsing process may be performed to remove the Fe-O oxide. Fe-O oxides refer to iron oxides such as Fe2O3, Fe3O4, etc. The Fe-O oxides can be removed in whole or in part. Before removing the Fe-O oxide, the average roughness (R) of the cold-rolled sheet surface is 1.2μm or more. If the subsequent process is carried out without removing the Fe-O oxide, the metal oxide layer in the grooves may be formed unstably, which may reduce adhesion and corrosion resistance. After removing the Fe-O oxides, the average roughness (R) of the cold-rolled sheet surface is 3.0 μm or less. By removing the Fe-O oxides in the above-mentioned range, the metal oxide layer is stably formed, and the adhesion and corrosion resistance can be improved. Preferably, the average roughness (R) of the cold-rolled sheet surface is 0.05 to 0.30 μm. In the process of removing the Fe-O oxides, some of the hill-ups that were generated during the groove formation process can also be removed. If the hill-ups are formed too high, the oxide layer can be formed unstable, which can lead to poor adhesion and corrosion resistance. Specifically, after the oxide removal step, the average height (H hill-up ) is less than 5.0 μm.

[0020] Next, the cold-rolled sheet is subjected to primary recrystallization annealing. The primary recrystallization annealing step is widely known in the field of grain-oriented electrical steel sheets, so a detailed description will be omitted. The primary recrystallization annealing process may include decarburization or decarburization and nitridation, and annealing may be performed in a wet atmosphere for decarburization or decarburization and nitridation. The soaking temperature in the primary recrystallization annealing step is 800~950℃. Next, an annealing separator is applied and the secondary recrystallization annealing is performed. Annealing separators are widely known, so a detailed description is omitted. As an example, an annealing separator containing MgO as a main component can be used. In one embodiment of the present invention, the adhesion coefficient calculated by the following equation 1 is 0.016 to 1.13. [Number 1] Adhesion coefficient (S ad )=(0.8×R) / H hill-up In the formula 1, R is the average roughness (μm) of the cold-rolled sheet surface after removing oxides, and H hill-up indicates the average height (μm) of hill-ups present on the surface of the cold-rolled sheet after the oxide removal step. By ensuring that the adhesion coefficient falls within the above-mentioned range, excellent adhesion and corrosion resistance can be ensured.

[0021] The purpose of the secondary recrystallization annealing is to obtain {110} <001> This involves forming texture, forming a metal oxide (glassy) film through the reaction of MgO with the oxide layer formed during the first recrystallization annealing, which gives insulation, and removing impurities that impair magnetic properties. As for the method of second recrystallization annealing, in the temperature rise section before the second recrystallization occurs, a mixture of nitrogen and hydrogen gas is maintained to protect the nitride, which acts as a grain growth inhibitor, allowing the second recrystallization to develop well, and after the second recrystallization is complete, the soaking stage is maintained in a 100% hydrogen atmosphere for a long time to remove impurities. The secondary recrystallization annealing step can be performed at a soaking temperature of 900 to 1210°C. During the secondary recrystallization annealing process, the MgO component in the annealing separator reacts with the oxide layer formed on the surface of the steel sheet to form a metal oxide layer (forsterite layer) on the surface of the steel sheet and the grooves. Figure 3 shows a schematic representation of the metal oxide layer 30. In one embodiment of the present invention, the grooves are formed before the secondary recrystallization annealing, so that the metal oxide layer 30 can be formed not only on the steel sheet but also on the surface of the grooves. In one embodiment of the present invention, after the grooves are formed, MgO in the annealing separator penetrates or passes through the inside of the steel sheet to remove Fe-O oxides on the surface of the steel sheet, forming islands 40 below the metal oxide layer 30. The islands 40 include a metal oxide. More specifically, they include forsterite.

[0022] 3 shows a schematic representation of an island 40. As shown in FIG 3, an island 40 may be formed below the metal oxide layer 30 and separated from the metal oxide layer 30. The island 40 is made of a similar alloy composition to the metal oxide layer 30 and is therefore distinguished from the electrical steel sheet matrix structure. The islands 40 are appropriately formed discontinuously, which can contribute to improving the adhesion between the metal oxide layer 30 and the steel sheet. Specifically, the density of the islands containing metal oxide in the lower part of the groove is 0.5 pieces / μm 2 Here, the criteria refer to the density of islands in a depth area within 5 μm below the groove 20 from a cross section (TD surface) including the rolling direction (RD direction) and thickness direction (ND direction) of the steel sheet. The islands 40 located under the grooves 20 have an average grain size of 0.5 to 5 μm. At this time, the reference is a cross section (TD plane) including the rolling direction (RD direction) and thickness direction (ND direction) of the steel sheet. The grain size means the diameter of a virtual circle having the same area as the area of ​​the islands 40 measured on the TD plane. The average grain size of the islands 40 is the average grain size of the islands 40 located under the grooves 20, and the islands 40 located under the surface where the grooves 20 are not formed are excluded from the calculation of the average grain size. By controlling the average grain size of the islands 40, it is possible to improve the adhesion with the insulating coating layer as well as the magnetic property. More specifically, the islands 40 located under the grooves 20 have an average grain size of 0.75 to 3 μm.

[0023] After the step of performing the second recrystallization annealing, the method may further include the step of forming an insulating coating layer on the metal oxide layer. The method for forming the insulating coating layer is not particularly limited, and as an example, the insulating coating layer can be formed by applying an insulating coating liquid containing phosphate. As the insulating coating liquid, it is preferable to use a coating liquid containing colloidal silica and a metal phosphate. In this case, the metal phosphate may be Al phosphate, Mg phosphate, or a combination thereof, and the content of Al, Mg, or a combination thereof based on the weight of the insulating coating liquid is 15 wt% or more. The grain-oriented electrical steel sheet according to one embodiment of the present invention includes grooves 20 located on the surface of the electrical steel sheet 10, a metal oxide layer 30 located on the grooves 20, and islands 40 located below the grooves.

[0024] The average particle size of the islands 40 located under the grooves is 0.5 to 5 μm. If the metal oxide layer is too thin, the average particle size of the islands will also be too small, which will reduce adhesion, and if the metal oxide layer is too thick, the average particle size of the islands will also be too large, which will tend to reduce adhesion of the metal oxide layer. In the present invention, by controlling the average particle size of the islands 40, it is possible to improve the adhesion of the metal oxide layer to the insulating coating and the matrix structure as well as improve the magnetic properties. Preferably, the islands 40 located under the grooves 20 have an average particle size of 0.75 to 3 μm. If the density of the islands 40 under the grooves 20 is 0.5 pieces / μm 2 In this case, the standard means the density of islands in a depth area within 5 μm below the groove 20 from a cross section (TD surface) including the rolling direction (RD direction) and thickness direction (ND direction) of the steel sheet. It is preferable that the density of islands 40 below the groove 20 is 0.1 pieces / μm 2 The following is the result. The present invention will be described in more detail with reference to the following examples, which are merely for illustrative purposes and are not intended to limit the scope of the present invention. EXAMPLES

[0025] A cold-rolled sheet with a thickness of 0.23 mm was prepared. A 2.0 kW Gaussian mode continuous wave laser was irradiated onto this cold-rolled sheet at a scanning speed of 10 m / s to form grooves at an angle of 85° to the RD direction. The entire surface of the steel sheet was then polished with an abrasive cloth to remove Fe-O oxides. This was followed by primary recrystallization annealing, application of an MgO annealing separator, and secondary recrystallization. An insulating coating layer was then formed. Adhesion was measured by bending the product plate into rod-shaped cylinders of various diameters and measuring the minimum diameter at which the insulating coating layer did not peel off or crack. The better the adhesion, the smaller the rod diameter becomes. Preferably, the minimum cylinder diameter at which the insulating coating layer does not peel off or crack should be less than 25mm. If it is more than 25mm, adhesion decreases, and the reduced adhesion also reduces corrosion resistance. (Minimum cylinder diameter 20mm, 24mm) The corrosion resistance was measured by the natural corrosion current density through a positive polarization experiment in a 3.5 wt% NaCl aqueous solution at 30°C. The corrosion resistance was 1.6×10 -9 A / cm 2 The following is preferred:

[0026] The adhesion coefficient of the electrical steel sheet according to the present invention is preferably 0.016 to 1.13. If the adhesion coefficient is less than 0.016, the corrosion resistance may be significantly deteriorated, and if the adhesion coefficient exceeds 1.13, the corrosion resistance may be deteriorated. The formula for calculating the adhesion coefficient is as follows. The viscosity of the annealing separator is preferably 10 to 84. If the viscosity is less than 10, the annealing separator may run off, and if it exceeds 84, the thickness becomes too thick, resulting in a large consumption of the annealing separator. Therefore, when considering the viscosity of a normal annealing separator, the R / H of the electrical steel sheet of the present invention is hill-up is preferably 0.02 to 1.0. [Number 1] Adhesion coefficient (S ad )=(0.8×R) / H hill-up In the formula 1, R is the average roughness (μm) of the cold-rolled sheet surface after removing oxides, and H hill-up indicates the average height (μm) of hill-ups present on the surface of the cold-rolled sheet after the oxide removal step.

[0027] [Table 1]

[0028] As shown in Table 1, the grain-oriented electrical steel sheet manufactured by appropriately controlling the adhesion coefficient after groove formation has excellent adhesion and corrosion resistance. On the other hand, the comparative example in which the adhesion coefficient is not appropriately controlled has relatively poor adhesion and corrosion resistance. It was also confirmed that the average particle size of the islands 40 located under the grooves in Examples 1 to 10 was in the range of 0.5 to 5.0 μm. 2 I confirmed that it was the following. On the other hand, in the comparative example, it was confirmed that the average particle size of the islands 40 was less than 0.5 μm, and the density of the islands 40 was 0.5 pieces / μm. 2 It was confirmed that a large number of them were formed due to excess. The present invention is not limited to the embodiments, and can be manufactured in various different forms, and those skilled in the art to which the present invention pertains should understand that the present invention can be embodied in other specific forms without changing the technical concept or essential features of the present invention. Therefore, it should be understood that the embodiments described above are illustrative in all respects and are not limiting. [Explanation of symbols]

[0029] 10: Grain-oriented electrical steel sheet 20: Groove 30: Metal oxide layer 40: Island

Claims

1. Grooves located on the surface of the electrical steel sheet, a metal oxide layer located on the groove; and The metal oxide-based islands are located below the groove and are discontinuously dispersed and distributed therein; The metal oxide islands located under the grooves have an average particle size of 0.75 to 3 μm. The density of the metal oxide islands located under the groove is greater than 0 to 0.1 / μm ２ A directional electrical steel sheet comprising:

2. 2. The grain-oriented electrical steel sheet according to claim 1, wherein when the electrical steel sheet is bent into a rod-shaped cylinder, the minimum diameter at which the insulating coating layer does not peel off or crack is less than 25 mm.

3. A method for producing the grain-oriented electrical steel sheet according to claim 1 or 2, producing a cold rolled sheet; forming a groove in the cold rolled sheet; removing Fe—O oxides formed on the surface of the cold-rolled sheet; subjecting the cold-rolled sheet to a first recrystallization annealing; and The method includes applying an annealing separator to the first recrystallized cold-rolled sheet and subjecting it to a second recrystallization annealing step, A method for producing a grain-oriented electrical steel sheet, characterized in that the adhesion coefficient calculated by the following equation 1 is 0.016 to 1.

13. [Equation 1] Adhesion coefficient (Sad) = (0.8 x Ra) / H ｈｉｌｌ－ｕｐ In Equation 1, Ra represents the arithmetic mean roughness (Ra, μm) of the cold-rolled sheet surface after removing the Fe—O oxides; H ｈｉｌｌ－ｕｐ indicates the average height (μm) of hill-ups present on the surface of the cold-rolled steel sheet after the step of removing the Fe—O oxides.

4. The method for producing a grain-oriented electrical steel sheet according to claim 3, wherein after the step of removing the Fe-O oxides, the cold-rolled sheet has a surface roughness (Ra) of 3.0 μm or less.

5. After removing the Fe—O oxide, the average height of hill-ups (H ｈｉｌｌ－ｕｐ 5. The method for producing a grain-oriented electrical steel sheet according to claim 3, wherein the grain size is 5.0 μm or less.

6. The method for producing a grain-oriented electrical steel sheet according to any one of claims 3 to 5, wherein in the step of forming the grooves, the grooves are formed by irradiating the cold-rolled sheet with a laser or plasma.

7. The method for manufacturing a grain-oriented electrical steel sheet according to claim 3 , wherein a resolidified layer is formed under the groove during the forming of the groove.

8. The method for producing a grain-oriented electrical steel sheet according to any one of claims 3 to 7, wherein the arithmetic mean roughness (Ra) of the surface of the cold-rolled sheet before the step of removing the Fe-O oxides is 1.2 μm or more.

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