Moisture-curable polyurethane hot melt adhesive composition with oleic chemical resistance

Abstract

A moisture-curable polyurethane hot melt adhesive composition having good oleic acid resistance, particularly when exposed to 100% pure oleic acid under aging conditions of 65°C and 90% relative humidity, the adhesive composition comprising, consisting essentially of, or consisting of a moisture-curable polyurethane prepolymer, the prepolymer being the reaction product of at least one amorphous polyester polyol containing aromatic groups and at least one polyisocyanate, preferably at least one polyisocyanate containing aromatic groups, wherein the aromatic groups are present in the polyurethane prepolymer in an amount by weight of 23% or more, preferably 25% or more, more preferably 30% or more.

Description

[Technical field]

[0001] Technical Field The present invention relates to a moisture curable polyurethane hot melt adhesive composition having oleic acid chemical resistance. [Background technology]

[0002] 2. Background of the Invention Adhesive compositions are widely used in many applications, some of which may involve contact with oil or oil-containing compositions, the presence of which can result in reduced adhesive strength or adhesion failure.

[0003] Wearable devices and portable electronic devices are constructed with components bonded together with an adhesive composition. When the device is in contact with the body, the skin may have natural oils or may contain added oils, such as emollient lotions and oils, sunscreen lotions and oils, etc. If oils are transferred from the user to the electronic device and come into contact with the adhesive, they may cause a loss of adhesion or a decrease in cohesive or adhesive strength. Summary of the Invention [Problem to be solved by the invention]

[0004] It is desirable to provide an adhesive composition that maintains its bond strength when exposed to oil or oil-containing compositions, such as oil or oil-containing compositions present on an individual's skin. [Means for solving the problem]

[0005] Summary of the Invention The present invention provides a moisture-curable polyurethane hot melt adhesive composition that has good oleic acid resistance even when exposed to 100% pure oleic acid under aging conditions of 65° C. and 90% relative humidity, while the adhesive composition of the present invention has a long open time.

[0006] The moisture-curable polyurethane hot melt adhesive composition of the present invention comprises, consists essentially of, or consists of a moisture-curable polyurethane prepolymer which is the reaction product of at least one amorphous polyester polyol containing aromatic groups and at least one polyisocyanate, preferably at least one polyisocyanate containing aromatic groups, wherein the polyurethane prepolymer has an aromatic content of at least 23% by weight, preferably at least 25% by weight, more preferably at least 30% by weight.

[0007] In yet another aspect, the present invention provides an article comprising a first substrate, a cured adhesive, and a second substrate bonded to the first substrate via the cured adhesive, wherein the cured adhesive comprises a cured product derived from the moisture curable polyurethane hot melt adhesive composition of the present invention.

[0008] In yet another aspect, the present invention provides a method of laminating two substrates, the method comprising applying to at least one of the substrates a moisture curable polyurethane hot melt adhesive composition of the present invention and then laminating the substrates. [Brief description of the drawings]

[0009] Brief introduction of the drawing [Figure 1] FIG. 1 is a schematic diagram of a sample for lap shear strength testing. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0010] Detailed Description of the Invention Those skilled in the art will appreciate that this discussion is a description of exemplary embodiments only, and is not intended to limit the broader aspects of the present invention. Each aspect so described may be combined with other aspects, unless expressly indicated to the contrary. In particular, any feature indicated as being preferred or advantageous may be combined with any other feature or features indicated as being preferred or advantageous.

[0011] In the present invention, unless otherwise specified, the terms used are to be construed in accordance with the following definitions.

[0012] Unless otherwise specified, all wt.% or weight percent referred to herein are percent by weight.

[0013] As used herein, unless otherwise stated, the terms "a," "an," and "the" are intended to include singular and plural references.

[0014] As used herein, the terms "comprising" and "comprises" are synonymous with "including," "including" or "containing," and are inclusive or open-ended and do not exclude additional, unrecited members, elements or process steps.

[0015] As used herein, the term "consisting essentially of" means that the recited component makes up the majority of the composition, e.g., at least 70% by weight of the composition, at least 80% by weight of the composition, at least 85% by weight of the composition, or at least 90% by weight of the composition.

[0016] As used herein, the term "consisting of" is closed-ended and excludes additional, non-repeating members, elements or process steps.

[0017] The terms "at least one" or "one or more" used to define components herein refer to the type of component and not to the absolute numerical value of the molecule. For example, "one or more polyols" refers to one type of polyol or a mixture of multiple different polyols.

[0018] As used herein, the terms "about," "around," and the like, when used in connection with numerical values, refer to the numerical value ±10%, preferably ±5%. All numerical values ​​in this specification should be construed as being modified by the term "about."

[0019] As used herein, the term "amorphous" means having no melting transition as measured using a differential scanning calorimeter (DSC).

[0020] As used herein, the term "crystalline" means having a melting transition as measured using a differential scanning calorimeter (DSC).

[0021] Unless otherwise specified, the recitation of numerical endpoints is intended to include all numbers and fractions thereof subsumed within the respective ranges, in addition to the recited endpoints.

[0022] All documents cited herein are incorporated by reference in their entirety.

[0023] Unless otherwise defined, all terms used herein, including technical and scientific terms, have the meaning commonly understood by one of ordinary skill in the art to which this invention belongs.

[0024] The molecular weight (M) in this context is determined by measuring the hydroxyl number according to DIN EN 4629 and the acid number according to DIN EN ISO 2114 and by end group analysis. In this case, the glass transition temperature (Tg) or melting point of a particular polymer is determined using DSC in accordance with DIN 53 765.

[0025] The softening points referred to in this specification are determined by the ring and ball method in accordance with DIN ISO 4625.

[0026] The moisture-curable polyurethane hot melt adhesive composition will now be described in detail.

[0027] The moisture-curable polyurethane hot melt adhesive composition according to the present invention comprises, consists essentially of or consists of a moisture-curable polyurethane prepolymer which is the reaction product of at least one amorphous polyester polyol containing aromatic groups and at least one polyisocyanate, preferably at least one polyisocyanate containing aromatic groups, wherein the aromatic groups are contained in the polyurethane prepolymer in a content by weight of at least 23%, preferably at least 25%, more preferably at least 30%.

[0028] The hot melt adhesive composition of the present invention can form good adhesive strength and can exhibit a lap shear strength of more than 2.5 MPa, preferably more than 3 MPa, more preferably more than 5 MPa when tested according to ASTM D1002 with an ABS / ABS substrate and 100% pure oleic acid, whereas the hot melt adhesive composition of the present invention can exhibit an adhesion retention of more than 40%, preferably more than 50%, more preferably more than 80% after testing according to ASTM D1002 with an ABS / ABS substrate and 100% pure oleic acid.

[0029] The moisture-curable polyurethane prepolymer of the present invention may be derived only from two main reactants (or two main raw materials), namely, an aromatic group-containing amorphous polyester polyol and a polyisocyanate. The aromatic group-containing amorphous polyester polyol, which is the main reactant, must have an aromatic group, such as a substituted or unsubstituted benzene group, particularly in the backbone. The polyisocyanate, which is the main reactant, does not necessarily have to have an aromatic group, but preferably the polyisocyanate used in the present invention contains an aromatic group, such as a group derived from benzene.

[0030] In addition to the above two main reactants, the co-reactant for forming the polyurethane prepolymer of the present invention can optionally contain a very small amount of crystalline polyester polyol. It can also be expressed interchangeably that the crystalline polyester polyol can be optionally contained in the polyurethane prepolymer at a very small content. For example, the crystalline polyester polyol can be optionally contained in the polyurethane prepolymer at a content of less than 10% by weight, preferably less than 5% by weight, more preferably less than 3% by weight, based on the weight of the polyurethane prepolymer. Preferably, the polyurethane prepolymer of the present invention does not contain crystalline polyester polyol. The very small content of crystalline polyester polyol or the absence of crystalline polyester polyol is also an important aspect of the present invention.

[0031] In addition, as a co-reactant for forming the polyurethane prepolymer of the present invention, amorphous polyester polyols having no aromatic groups may be optionally included, preferably at a very small content. It can also be expressed interchangeably as amorphous polyester polyols having no aromatic groups may be optionally included, preferably at a very small content, in the polyurethane prepolymer. For example, amorphous polyester polyols having no aromatic groups may be optionally included at a content of less than 30% by weight, preferably less than 15% by weight, more preferably less than 10% by weight, for example less than 5% by weight, based on the weight of the polyurethane prepolymer. Preferably, polyester polyols having no aromatic groups are not included in the polyurethane prepolymer. When amorphous polyester polyols having no aromatic groups are present, useful ones can include those that have been used in the preparation of polyurethanes in the past.

[0032] Furthermore, polyether polyols can be optionally included, preferably in very small amounts, as a co-reactant for forming the polyurethane prepolymer of the present invention. Polyether polyols can be interchangeably expressed as being optionally included in the polyurethane prepolymer, preferably in a very small content. For example, polyether polyols can be optionally included in a content of less than 30% by weight, preferably less than 15% by weight, more preferably less than 10% by weight, more preferably less than 5% by weight, based on the weight of the polyurethane prepolymer. Preferably, the polyurethane prepolymer does not include polyether polyols. When polyether polyols are present, suitable polyether polyols include those with aromatic groups and those without aromatic groups, preferably those with molecular weights of about 100 g / mol to about 8000 g / mol, about 200 g / mol to about 4000 g / mol, or about 200 g / mol to about 1000 g / mol. For example, useful polyether polyols are derived from oxide monomers (e.g., ethylene oxide, propylene oxide, 1,2-butylene oxide, 1,4-butylene oxide, tetrahydrofuran, and combinations thereof) and polyol initiators (e.g., ethylene glycol, propylene glycol, butanediol, hexanediol, glycerol, trimethylolethane, trimethylolpropane, pentaerythritol, and combinations thereof), and optionally contain aromatic groups.

[0033] The expression "the aromatic group is contained in the polyurethane prepolymer at a content of 23% by weight or more" can be interpreted as meaning that the aromatic group constitutes 23% by weight or more of the reactants for forming the polyurethane prepolymer. The content of the aromatic group is calculated from the chemical formula of the reactants and their amounts. For example, when the aromatic group is a group derived from benzene, the content of the aromatic group is calculated based on the benzene ring.

[0034] When the polyurethane prepolymer is derived from only two main reactants, that is, aromatic group-containing amorphous polyester polyol and polyisocyanate, the content of aromatic group in the polyurethane prepolymer is calculated based on the aromatic group-containing amorphous polyester polyol and polyisocyanate. Under such conditions, the content of aromatic group in the amorphous polyester polyol and the content of aromatic group in the polyisocyanate are not particularly limited, as long as the total of the amorphous polyester polyol and the polyisocyanate is 23% by weight or more, preferably 24% by weight or less, more preferably 25% by weight or less, more preferably 26% by weight or less, more preferably 27% by weight or less, more preferably 28% by weight or less, more preferably 29% by weight or less, more preferably 30% by weight or less, calculated based on the weight of the amorphous polyester polyol and the polyisocyanate.

[0035] When the polyurethane prepolymer is obtained from two main reactants and other co-reactants such as the polyester polyol and / or polyether polyol that do not have aromatic groups, the content of aromatic groups in the polyurethane prepolymer is calculated based on the two main reactants and the co-reactant. Under such conditions, the content of aromatic groups in the amorphous polyester polyol and the content of aromatic groups in the polyisocyanate are not particularly limited, as long as the total content of aromatic groups in the polyurethane prepolymer is 23% by weight or more, preferably 24% by weight or less, more preferably 25% by weight or less, more preferably 26% by weight or less, more preferably 27% by weight or less, more preferably 28% by weight or less, more preferably 29% by weight or less, more preferably 30% by weight or less, calculated based on the weight of the main reactant and the co-reactant.

[0036] Herein, when the term "amorphous polyester polyol" is used without indicating whether it contains an aromatic group, it should be interpreted as an amorphous polyester polyol that contains an aromatic group.

[0037] The aromatic group-containing amorphous polyester polyol of the present invention may have a molecular weight of about 500 g / mol to about 10,000 g / mol, about 600 g / mol to about 6000 g / mol, or about 700 g / mol to about 5000 g / mol. In the present invention, when two or more aromatic group-containing amorphous polyester polyols are used as a mixture to participate in the reaction, each amorphous polyester polyol may have a molecular weight within the above range.

[0038] The aromatic group-containing amorphous polyester polyol used in the present invention may be liquid or solid. When a solid one is used, the softening point is preferably 130° C. or less, preferably 120° C. or less, preferably 105° C. or less, for example, 60° C., 80° C., or 100° C., from the viewpoint of obtaining good adhesive strength and easy application.

[0039] Aromatic group-containing amorphous polyester polyols useful in the present invention include those having at least two OH groups in one molecule, such as those having three OH groups or four OH groups and having an aromatic group(s) in the molecule.

[0040] The expression "at least one amorphous polyester polyol has a Tg of -20°C or more as a whole" used in this specification should be interpreted as follows. When polyurethane prepolymer is obtained from only two main reactants, namely aromatic group-containing amorphous polyester polyol and polyisocyanate, if only one type of amorphous polyester polyol is used to participate in the reaction in the present invention, the Tg of the amorphous polyester polyol itself is the Tg of the at least one type of amorphous polyester polyol as a whole. If two or more types of amorphous polyester polyol are used to participate in the reaction in the present invention, the Tg of the at least one type of amorphous polyester polyol refers to the Tg calculated according to the following modified Gordon-Taylor formula (I), that is, these amorphous polyester polyols have a calculated Tg of -20°C or more as a whole, which means that amorphous polyester polyols having a Tg of less than -20°C can be used as long as the calculated Tg of the whole is -20°C or more. In the present invention, the calculated Tg of the two or more amorphous polyester polyols can be calculated according to the following modified Gordon-Taylor equation (I).

[0041] Tg=W1×Tg1+W2×Tg2+...Wn×Tgn (I)

[0042] During the ceremony: - W1 is the weight percent of the first polyester polyol based on the total polyester polyols. Tg1 is the Tg of the first polyester polyol. - W2 is the weight percent of the second polyester polyol based on the total polyester polyol. Tg2 is the Tg of the second polyester polyol. Wn is the weight percent of the nth polyester polyol based on the total polyester polyols. Tgn is the Tg of the nth polyester polyol.

[0043] The upper limit of the Tg of the amorphous polyester polyol as a whole used in the present invention is not particularly limited. For example, the upper limit of the Tg of the amorphous polyester polyol as a whole may be 50° C., 60° C., or higher.

[0044] The expression "the polyol as a whole has a Tg of -20°C or more, preferably -17°C or more, more preferably -16°C or more" should be interpreted as follows: When the polyurethane prepolymer is obtained from two main reactants and other co-reactants such as polyester polyols and / or polyether polyols without aromatic groups, the Tg of the polyol means the Tg calculated according to the following modified Gordon-Taylor formula (II). That is, these polyols as a whole have a calculated Tg of -20°C or more, which means that polyols having a Tg of less than -20°C can be used as long as the calculated Tg of the whole is -20°C or less. In the present invention, the calculated Tg of two or more polyols can be calculated according to the following modified Gordon-Taylor formula (II).

[0045] Tg=W1×Tg1+W2×Tg2+...Wn×Tgn (II)

[0046] During the ceremony: - W1 is the weight percent of the first polyol based on the total polyol. Tg1 is the Tg of the first polyol. - W2 is the weight percent of the second polyol based on the total polyol. Tg2 is the Tg of the second polyol. Wn is the weight percent of the nth polyol based on the total polyols. - Tgn is the Tg of the nth polyol.

[0047] The upper limit of the Tg of the entire polyol used in the present invention is not particularly limited. For example, the upper limit of the Tg of the entire polyol may be 50° C., 60° C., or higher.

[0048] Preferably, the hot melt adhesive composition of the present invention exhibits a viscosity at 110°C of 30000 mPas or less, preferably a viscosity at 110°C of 10000 mPas or less, preferably a viscosity at 110°C of 7000 mPas or less, more preferably a viscosity at 110°C of 6000 mPas or less, measured with a Brookfield Thermosel viscometer using spindle 27 at 20 rpm.

[0049] As used herein, amorphous polyester polyols include or are the reaction products of one or more polyacids and one or more polyols, where at least one of the polyacids and / or at least one of the polyols contains aromatic groups, such as groups derived from benzene.

[0050] The one or more polyacids may be selected from terephthalic acid (TPA), isophthalic acid (IPA), phthalic acid (PA), methylhexahydrophthalic acid, methyltetrahydrophthalic acid, hexahydrophthalic acid, tetrahydrophthalic acid, maleic acid, succinic acid, glutaric acid, adipic acid (AA), pimelic acid, suberic acid, azelaic acid, sebacic acid, chlorendic acid, 1,2,4-butanetricarboxylic acid, decanedicarboxylic acid, octadecanedicarboxylic acid, dimer acid, dimerized fatty acid, trimer fatty acid, fumaric acid, 1,3-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, anhydrides of the above acids, and combinations thereof. Preferably, the one or more polyacids may be selected from terephthalic acid, isophthalic acid, phthalic acid, and adipic acid, and anhydrides thereof.

[0051] The one or more polyols may be ethylene glycol (EG), propanediol (including 1,2- or 1,3-propanediol), butanediol (including 1,2- or 2,3- or 1,3- or 1,4-butanediol), butenediol (including 1,3- or 2,3- or 1,4-butenediol), butynediol (including 1,4-butynediol), pentanediol (including 1,2- or 1,3- or 1,4- or 1,5-pentanediol), pentenediol, pentynediol, hexanediol (HD) (including 1,2-, 1,3-, 1,4-, 1,5-, 1,6-, 2,3-, 2,4-, 2,5-, 2,6-, 3,4-hexanediol), octanediol (including 1,2- or 1,3- or 1,4- or 1,5- or 1,6- or 1,8 ... including 1,7- or 1,8-hexanediol), nonanediol, decanediol, neopentyl glycol (NPG), diethylene glycol (DEG), triethylene glycol, tetraethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, cyclohexanedimethanol, cyclohexanediol, dimer diol, bisphenol A, bisphenol F, hydrogenated bisphenol A, hydrogenated bisphenol F, glycerol, tetramethylene glycol, polytetramethylene glycol, 3-methyl-1,5-pentanediol, 2-methyl-1,8-octanediol, trimethylolpropane, pentaerythritol, sorbitol, glucose, and combinations thereof. Preferably, the one or more polyols may be selected from hexanediol (including 1,2- or 1,3- or 1,4- or 1,5- or 1,6- or 2,3- or 2,4- or 2,5- or 2,6- or 3,4-hexanediol), ethylene glycol, neopentyl glycol, diethylene glycol.

[0052] The polyisocyanates useful in the present invention include those conventionally used in the preparation of polyurethanes, for example, those having at least two isocyanate groups (-NCO groups) in one molecule, preferably those having at least one aromatic group such as a benzene-derived group in one molecule, etc. In the present invention, one or more polyisocyanates can be used in the preparation of the polyurethane prepolymer.

[0053] Polyisocyanates useful in the present invention include aliphatic polyisocyanates such as hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI), hydrogenated diphenylmethane diisocyanate, 1,6-diisocyanato-2,4,4-trimethylhexane, 1,4-cyclohexane diisocyanate (CHDI), 1,4-cyclohexane bis(methylene isocyanate) (BDI), 1,3-bis(isocyanatomethyl)cyclohexane (H6XDI), dicyclohexylmethane diisocyanate (H12MDI); aromatic polyisocyanates such as diphenylmethane diisocyanate compounds (MDI) including their isomers (e.g., diphenylmethane 4,4'-diisocyanate, diphenylmethane-2,2'-diisocyanate, diphenylmethane-2,4'-diisocyanate, having the formula:

[0054] JPEG0007635256000001.jpg2980

[0055] wherein n is an integer of 0 to 5, and mixtures thereof), carbodiimide-modified MDI, naphthalene diisocyanates including their isomers (e.g., 1,5-naphthalene diisocyanate (NDI)), isomers of triphenylmethane triisocyanate (e.g., triphenylmethane-4,4',4''-triisocyanate), toluene diisocyanate compounds (TDI) including their isomers, 1,3-xylylene diisocyanate (XDI), tetramethylxylylene diisocyanate (TMXDI) (e.g., p-1,1,4,4-tetramethylxylylene diisocyanate (p-TMXI) and m-1,1,3,3-tetramethylxylylene diisocyanate (m-TMXDI)), and mixtures thereof. and oligomeric methylene isocyanates having the formula:

[0056] Preferably, the molar ratio of hydroxy groups to isocyanate groups in the composition used to prepare the polyurethane prepolymer is about 0.2: 1 to about 0.9: 1. Under the condition that the above molar ratio is satisfied, the weight ratio of polyol to polyisocyanate is not particularly limited.

[0057] The polyurethane prepolymers of the present invention can be prepared by any suitable method, including reacting a polyol with a polyisocyanate at an elevated temperature, from greater than 60°C to about 160°C. The polyol may be first introduced into a reaction vessel, heated to the reaction temperature, and dried under vacuum to remove ambient moisture absorbed by the polyol. The polyisocyanate is then added to the reactor. The reaction between the polyol and the polyisocyanate is carried out at an OH:NCO ratio of from about 0.2:1 to about 0.9:1, or even from about 0.3:1 to about 0.7:1. Catalysts conventionally used in polyurethane preparation may be used herein, if desired.

[0058] In addition to the polyurethane prepolymer, the moisture-curable polyurethane hot melt adhesive composition may contain a catalyst to promote moisture curing. Catalysts useful herein include ether and morpholine functional groups, examples of which include 2,2'-dimorpholinoethyl ether, di(2,6-dimethylmorpholinoethyl)ether, and 4,4'-(oxydi-2,1-ethanediyl)bismorpholine. For example, various metal catalysts are suitable, including catalysts based on tin (e.g., dibutyltin dilaurate and dibutyltin acetate), bismuth, zinc, and potassium. The moisture-curable hot melt adhesive composition optionally contains from about 0.01% to about 2% by weight, or alternatively from about 0.05% to about 1% by weight, of a catalyst to promote moisture curing.

[0059] The moisture curable adhesive composition optionally includes various additives including, for example, thermoplastic polymers, tackifiers, plasticizers, waxes, stabilizers, antioxidants, fillers (talc, clay, silica and treated versions thereof, carbon black, mica, microparticles including, for example, microspheres (e.g., glass microspheres, polymeric microspheres, combinations thereof, and the like), ultraviolet light (UV) scavengers and absorbers, pigments (e.g., reactive or non-reactive oxides), fluorescent agents, odor inhibitors, adhesion promoters (i.e., silane-based adhesion promoters), surfactants, defoamers, and combinations thereof.

[0060] Useful thermoplastic polymers include, for example, ethylene vinyl acetate, ethylene vinyl acetate-vinyl alcohol copolymers, ethylene vinyl butyrate, ethylene acrylic acid, ethylene methacrylic acid, ethylene acrylamide copolymers, ethylene methacrylamide, acrylate copolymers (e.g., methyl acrylate, ethyl acrylate, methyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, methoxyethyl methacrylate, methoxyethyl acrylate, ethylene ethyl acrylate, ethylene n-butyl acrylate, ethylene hydroxyethyl acrylate, etc.), ethylene n-butyl acrylate carbon monoxide terpolymers, polyolefins (e.g., polypropylene, polyethylene), thermoplastic polyurethanes, butylene / poly(alkylene ether) phthalates, thermoplastic polyesters, and combinations thereof. The moisture curable adhesive composition optionally includes from about 0 to about 4 weight percent, alternatively from about 0.1 to about 4 weight percent, of a thermoplastic polymer.

[0061] Useful tackifiers include, for example, aromatic, aliphatic, and cycloaliphatic hydrocarbon resins, mixed aromatic and aliphatic modified resins, aromatic modified hydrocarbon resins, and hydrogenated versions thereof; terpenes, modified terpenes, and hydrogenated versions thereof; rosin esters (e.g., glycerol rosin ester, pentaerythritol rosin ester, and hydrogenated versions thereof); and combinations thereof. Useful aromatic resins include, for example, aromatic modified hydrocarbon resins, α-methylstyrene resins, styrene, polystyrene, cumolone, indene, and vinyl toluene, as well as styrenated terpene resins, polyphenols, polyterpenes, and combinations thereof. Useful aliphatic and cycloaliphatic petroleum hydrocarbon resins include, for example, branched and unbranched C5-C9 resins and hydrogenated derivatives thereof. Useful polyterpene resins include copolymers and terpolymers of natural terpenes (e.g., styrene-terpene, α-methylstyrene-terpene, vinyl toluene-terpene).

[0062] Useful waxes include, for example, hydroxy-modified waxes, carbon monoxide-modified waxes, hydroxystearamide waxes, fatty amide waxes, hydrocarbon waxes such as high density low molecular weight polyethylene waxes, paraffin waxes and microcrystalline waxes, and combinations thereof. The moisture-curable adhesive composition optionally includes from about 0% to about 3%, alternatively from about 0% to about 1%, by weight of a wax.

[0063] One useful class of stabilizers includes carbodiimide stabilizers.

[0064] Examples of useful antioxidants include hindered phenolic antioxidants, phosphite antioxidants, thioether antioxidants, etc. Commercially available examples include RGANOX 565, 1010 and 1076 available from Ciba-Geigy (Hawthorne, NY). The moisture curable polyurethane hot melt adhesive composition optionally includes up to about 2% by weight of an antioxidant.

[0065] The fillers can be in a variety of forms including, for example, particles (spherical particles, beads, elongated particles), fibers, and combinations thereof.

[0066] Examples of useful pigments include inorganic pigments, organic pigments, reactive pigments, non-reactive pigments, and combinations thereof.

[0067] The moisture curable adhesive composition may also optionally include an organofunctional silane adhesion promoter. Preferred organofunctional silane adhesion promoters include silyl groups such as alkoxysilyl, aryloxysilyl, and combinations thereof. Examples of useful alkoxysilyl groups include methoxysilyl, ethoxysilyl, propoxysilyl, butoxysilyl, and acyloxysilyl reactive groups such as silyl esters of various acids such as, for example, acetic acid, 2-ethylhexanoic acid, palmitic acid, stearic acid, and oleic acid.

[0068] Suitable silane-based adhesion promoters include, for example: Epoxyglycidoxypropyltrimethoxysilane, octyltriethoxysilane, methyltrimethoxysilane, β-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, methacryloxypropyltrimethoxysilane, alkyloxyinosilane, vinyltrimethoxysilane, vinyltriethoxysilane, vinylmethyldimethoxysilane, aminopropyltrimethoxysilane, aminopropyltriethoxysilane, N-phenylaminopropyltrimethoxysilane, bis(trimethoxysilylpropyl)amine, N-β-(aminoethyl)-aminopropyltrimethoxysilane, N-β-(aminoethyl)-aminopropyltrimethoxysilane, N-β-(aminoethyl)-aminopropylmethyldimethoxysilane, ureidopropyltrimethoxysilane, tris[3-(trimethoxysilyl)propyl]isocyanurate, 4-amino-3,3-dimethylbutyldimethoxymethylsilane, and their ethoxy and methoxy / ethoxy versions, mercaptopropyltrimethoxysilane and mixtures thereof.

[0069] The total amount of the additives is 10% by weight or less, preferably 5% by weight or less, based on the adhesive composition of the present invention.

[0070] In another aspect of the invention, there is provided a method of bonding two substrates comprising applying the moisture-curable polyurethane hot melt adhesive composition of the invention to at least one of the substrates.

[0071] The moisture-curable adhesive composition can be applied to a substrate using any suitable application method, including, for example, automated fine line dispensing, jet dispensing, slot die coating, roll coating, gravure coating, transfer coating, pattern coating, screen printing, spray coating, filament coating, by extrusion, air knife, trailing blade, brush, dipping, doctor blade, offset gravure coating, gravure coating, and combinations thereof. The moisture-curable adhesive composition can be applied as a continuous or discontinuous coating, in single or multiple layers, and combinations thereof. The moisture-curable adhesive composition can be applied at any suitable temperature, including, for example, from about 60°C to about 175°C, or from about 90°C to about 130°C.

[0072] Optionally, the surface of the substrate to which the moisture-curable adhesive composition is applied is treated to enhance adhesion using any suitable method to enhance adhesion to the substrate surface including, for example, corona treatment, chemical treatment (e.g., chemical etching), flame treatment, abrasion, and combinations thereof.

[0073] In another aspect of the present invention, there is provided an article having adhered thereto the curable polyurethane hot melt adhesive composition of the present invention.

[0074] The articles can include substrates having a variety of properties including rigidity (e.g., a rigid substrate (i.e., the substrate cannot be bent by an individual using both hands or would break if an individual attempted to bend it using both hands), flexibility (e.g., a flexible substrate (i.e., the substrate can be bent with only the strength of two hands), porosity, electrical conductivity, lack of electrical conductivity, and combinations thereof.

[0075] The substrate of the article can be in a variety of forms including, for example, fibers, threads, yarns, woven fabrics, nonwoven fabrics, films (e.g., polymeric films, metallized polymeric films, continuous films, discontinuous films, and combinations thereof), foils (e.g., metal foils), sheets (e.g., metal sheets, polymeric sheets, continuous sheets, discontinuous sheets, and combinations thereof), and combinations thereof.

[0076] Useful substrate compositions include, for example, polymers (e.g., polycarbonate, ABS resin (acrylonitrile-butadiene-styrene resin), polyolefins (e.g., polypropylene, polyethylene, low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, oriented polypropylene, copolymers of polyolefins with other comonomers, etc.), polyether terephthalate, ethylene-vinyl acetate, ethylene-methacrylic acid ionomer, ethylene-vinyl alcohol, polyesters such as polyethylene terephthalate, polycarbonate, polyamides such as nylon-6 and nylon-6,6, polyvinyl chloride ... Examples of suitable composites include glass, ceramic, cellulose-based, polystyrene, epoxy, polymer composites (e.g., composites of polymer and metal, cellulose, glass, polymer, and combinations thereof), metals (aluminum, copper, zinc, lead, gold, silver, platinum, magnesium, and metal alloys such as steel (e.g., stainless steel), tin, brass, and alloys of magnesium and aluminum), carbon fiber composites, other fiber-based composites, graphene, fillers, glass (e.g., alkali aluminosilicate reinforced glass, borosilicate glass, etc.), quartz, boron nitride, gallium nitride, sapphire, silicon, carbide, ceramics, and combinations thereof.

[0077] The substrate may be a single material, a single layer, or it may include multiple layers of the same or different materials. The layers may be continuous or discontinuous.

[0078] A variety of articles may comprise the adhesive composition, including, for example, clothing (e.g., jackets, coats, shirts, sweaters, pants, socks, belts, watches (e.g., watch bands), footwear (e.g., shoes and boots, e.g., ski boots), handwear (e.g., gloves), headwear (e.g., hats, headbands, earmuffs), neckwear (e.g., scarves), and combinations thereof. In some embodiments, the article is part of a garment that is intended to be worn by an individual and includes a first substrate, a moisture cured polyurethane hot melt adhesive composition in contact with the first substrate, and optionally a second substrate bonded to the first substrate via the adhesive composition.

[0079] The adhesive compositions are useful in a variety of electronic devices including, for example, wearable electronic devices (e.g., watches, eyeglasses), handheld electronic devices (e.g., phones (e.g., cell phones, cell phone-type smart phones), cameras, tablets, e-readers, monitors (e.g., monitors used by hospitals, medical personnel, athletes, individuals), watches, calculators, mice, touchpads, joysticks), computers (e.g., desktop PCs, laptop PCs), computer monitors, televisions, media players, home appliances (e.g., refrigerators, washers, dryers, ovens, microwaves), light bulbs (e.g., incandescent, light emitting diode, fluorescent), visible transparent or transparent components, glass housing structures, protective transparent covers for displays or other optical components. EXAMPLES

[0080] Working Example The present invention will now be described by the following examples. The following examples are intended to assist those skilled in the art in better understanding and practicing the present invention. The scope of the present invention is not limited by the examples, but is defined in the appended claims. All parts and percentages are by weight unless otherwise specified.

[0081] Preparation of Polyurethane Hot Melt Adhesive Compositions According to the ingredients and amounts (g) in Table 1, the polyol was introduced into a reaction vessel together with 0.1 g of Evernox 10 as an antioxidant and 0.05 g of p-toluenesulfonyl isocyanate (PTSI) as a moisture scavenger, and heated to a reaction temperature of 140°C, followed by drying under vacuum to remove ambient moisture absorbed by the raw materials. The temperature was then lowered to 120°C, and the polyisocyanate was added to the vessel. After reacting for 60 minutes under stirring, the catalyst 2,2'-dimorpholinoethyl ether was added thereto, and stirring was continued for another 10 minutes, after which the stirring was stopped and the vacuum was released; and the resulting composition was stored in a sealed tube.

[0082] Viscosity measurement: Viscosity was measured using a Brookfield Thermosel viscometer at 20 rpm and 110°C using spindle 27.

[0083] Test sample preparation Each test sample consisted of two cleaned ABS plastic sheets (25.4 mm wide, 101.6 mm long, 3 mm thick), two 0.127 mm diameter stainless steel wires, and polyurethane adhesive. First, the ABS sheets were wiped with isopropanol and washed. Next, polyurethane adhesive melted at 110°C was applied to one end of one ABS sheet so that the amount of adhesive formed an adhesive area of ​​2 ± 0.2 mm wide and 25.4 mm long, and two stainless steel wires were attached to each side. The other ABS sheet was overlapped on top of the first ABS sheet with an overlap area of ​​12.7 mm × 25.4 mm, with the applied adhesive centered in the overlap area. The overlap was pressed with a force of 2 kg under conditions of 23°C and 50% relative humidity until the adhesive cured.

[0084] See Figure 1 for the completed test sample.

[0085] Lap Shear Strength Test Lap shear strength was tested according to ASTM test method D1002, entitled "Standard Test Method for Apparent Shear Strength of Single Lump Joint Adhesive Bonded Metal Specimens under Tension Loading (Metal to Metal)," except that the test samples were prepared according to the method described above. The pull rate was 10 mm / min. The maximum load was recorded and the lap shear strength was calculated by dividing the maximum load by the bond area.

[0086] Oleic acid tolerance test After preparing the test samples as described above and curing for 24 hours, 100% pure oleic acid was applied with a transfer pipette along the edge of the overlap bond so that it would be drawn to the center of the sample by capillary action. The oleic acid should completely fill the open space around the adhesive. The samples were then aged for 72 hours at 65°C and 90% relative humidity. The aged samples were removed and placed at room temperature, and after 2 hours, the lap shear strength was measured using the aged samples as described above.

[0087] Adhesive strength retention rate The retention rate was calculated by the following formula.

[0088] Retention rate = (lap shear strength after aging / lap shear strength before aging) x 100%.

[0089] For many applications, a retention rate of greater than 40%, preferably greater than 50%, and more preferably greater than 80% is acceptable.

[0090] raw materials: Amorphous polyester diols 1: Polyester diols prepared from TPA, IPA, AA, EG and NPG Amorphous polyester diols 2: Polyester diols prepared from PA, AA, EG and NPG Amorphous polyester diol 3: polyester diol prepared from TPA, AA, EG and NPG.

[0091] [Table 1]

[0092] While several preferred embodiments have been described, many modifications and variations can be made thereto in light of the above teachings, and it is therefore to be understood that the invention may be practiced otherwise than as specifically described without departing from the scope of the appended claims. Preferred aspects of the invention include the following. [1] A moisture-curable polyurethane adhesive composition comprising, consisting essentially of, or consisting of a moisture-curable polyurethane prepolymer, The polyurethane prepolymer is the reaction product of at least one amorphous polyester polyol containing aromatic groups and at least one polyisocyanate, preferably at least one polyisocyanate containing aromatic groups; The aromatic group is contained in the polyurethane prepolymer in an amount of 23% by weight or more, preferably 25% by weight or more, and more preferably 30% by weight or more. A moisture curable polyurethane adhesive composition. [2] The composition according to [1], wherein the at least one amorphous polyester polyol as a whole has a Tg of -20°C or higher, preferably -17°C or higher, more preferably -16°C or higher. [3] The composition according to [1] or [2], wherein the at least one amorphous polyester polyol comprises an amorphous polyester polyol having a softening point of 130°C or less, preferably 120°C or less, and preferably 105°C or less. [4] The composition according to any one of [1] to [3], wherein the at least one amorphous polyester polyol has a molecular weight of about 500 g / mol to about 10,000 g / mol, about 600 g / mol to about 6000 g / mol, or about 700 g / mol to about 5000 g / mol. [5] The composition according to any one of [1] to [4], wherein a polyether polyol is contained in a polyurethane prepolymer. [6] The composition according to [5], wherein the polyether polyol is contained in the polyurethane prepolymer in an amount of less than 30% by weight, preferably less than 15% by weight. [7] The composition according to any one of [1] to [6], wherein an amorphous polyester polyol having no aromatic group is contained in a polyurethane prepolymer. [8] The composition according to [7], wherein the amorphous polyester polyol having no aromatic group is contained in the polyurethane prepolymer in an amount of less than 30% by weight, preferably less than 15% by weight. [9] The composition according to [5] or [7], wherein the polyol as a whole has a Tg of -20°C or higher, preferably -17°C or higher, more preferably -16°C or higher.

[10] The composition according to any one of [1] to [9], which exhibits a lap shear strength of greater than 2.5 MPa, preferably greater than 3 MPa, and more preferably greater than 5 MPa, when tested according to ASTM D1002 using an ABS / ABS substrate and 100% pure oleic acid.

[11] The composition according to any one of [1] to [8], which has a viscosity of 30,000 mPas or less at 110°C, preferably 10,000 mPas or less at 110°C, and more preferably 6000 mPas or less at 110°C.

[12] The composition according to any one of [1] to

[11] , wherein the at least one amorphous polyester polyol comprises a reaction product of one or more polyacids and one or more polyols, and at least one of the polyacids and / or at least one of the polyols comprises an aromatic group; wherein the one or more polyacids are selected from terephthalic acid, isophthalic acid, phthalic acid, methylhexahydrophthalic acid, methyltetrahydrophthalic acid, hexahydrophthalic acid, tetrahydrophthalic acid, maleic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, chlorendic acid, 1,2,4-butanetricarboxylic acid, decanedicarboxylic acid, octadecanedicarboxylic acid, dimer acid, dimerized fatty acid, trimer fatty acid, fumaric acid, 1,3-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, anhydrides of the above acids, and combinations thereof; wherein the one or more polyols are selected from ethylene glycol, propanediol, butanediol, butenediol, butynediol, pentanediol, pentenediol, pentynediol, hexanediol, octanediol, nonanediol, decanediol, neopentyl glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, cyclohexanedimethanol, cyclohexanediol, dimer diol, bisphenol A, bisphenol F, hydrogenated bisphenol A, hydrogenated bisphenol F, glycerol, tetramethylene glycol, polytetramethylene glycol, 3-methyl-1,5-pentanediol, 2-methyl-1,8-octanediol, trimethylolpropane, pentaerythritol, sorbitol, glucose, and combinations thereof; composition.

[13] The composition according to any one of [1] to

[12] , further comprising a catalyst, and / or one or more additives selected from thermoplastic polymers, tackifiers, plasticizers, waxes, stabilizers, antioxidants, talc, clay, silica and treated versions thereof, carbon black, mica, glass particles, polymeric particles, ultraviolet light capture and absorption agents, pigments, fluorescent agents, deodorizers, adhesion promoters, surfactants, defoamers, and combinations thereof.

[14] The composition according to any one of [1] to

[13] , wherein the crystalline polyester polyol is contained in the polyurethane prepolymer in an amount of less than 10% by weight, preferably less than 5% by weight, and more preferably less than 3% by weight.

[15] A first substrate; Cured adhesive, and A second substrate adhered to a first substrate via a cured adhesive, the cured adhesive comprising a cured product derived from the hot melt adhesive composition according to any one of [1] to

[14] . Items including.

[16] The article according to

[15] , comprising a wearable electronic device, a portable electronic device, glasses, a phone, a tablet, a sound player, a remote control device, a mouse, a watch band, a pump for dispensing medication, a headband, or a combination thereof.

[17] A method for bonding two substrates, comprising applying the hot melt adhesive composition according to any one of [1] to

[14] to at least one of the substrates, and then bonding the substrates together.

Claims

1. 1. A moisture-curable polyurethane adhesive composition comprising a moisture-curable polyurethane prepolymer, The polyurethane prepolymer is the reaction product of at least one amorphous polyester polyol containing aromatic groups and at least one polyisocyanate; The aromatic group is contained in the polyurethane prepolymer in an amount of 30% by weight or more, the at least one amorphous polyester polyol generally has a Tg of −20° C. or greater; The crystalline polyester polyol is contained in the polyurethane prepolymer in an amount of 0% by weight or more and less than 10% by weight. A moisture curable polyurethane adhesive composition.

2. 2. The composition of claim 1, wherein the at least one amorphous polyester polyol as a whole has a Tg of -17°C or greater.

3. 3. The composition of claim 1 or 2, wherein the at least one amorphous polyester polyol comprises an amorphous polyester polyol having a softening point of 130° C. or less.

4. The composition according to any one of claims 1 to 3, wherein the at least one amorphous polyester polyol has a molecular weight of from 500 g / mol to 10,000 g / mol.

5. The composition according to any one of claims 1 to 4, comprising a polyether polyol in a polyurethane prepolymer.

6. The composition of claim 5, wherein the polyether polyol is present in the polyurethane prepolymer in an amount of less than 30% by weight.

7. The composition according to any one of claims 1 to 6, which contains an amorphous polyester polyol having no aromatic groups in the polyurethane prepolymer.

8. The composition of claim 7, wherein the amorphous polyester polyol having no aromatic groups is present in the polyurethane prepolymer in an amount of less than 30% by weight.

9. The composition according to claim 5 or 7, wherein the polyol as a whole has a Tg of -20°C or higher.

10. The composition of any one of claims 1 to 9, exhibiting a lap shear strength of greater than 2.5 Mpa when tested according to ASTM D1002 using an ABS / ABS substrate and 100% pure oleic acid.

11. The composition according to any one of claims 1 to 8, which exhibits a viscosity of 30,000 mPas or less at 110°C.

12. 12. The composition of claim 1, wherein the at least one amorphous polyester polyol comprises a reaction product of one or more polyacids and one or more polyols, wherein at least one of the polyacids and / or at least one of the polyols comprises an aromatic group, wherein the one or more polyacids are selected from terephthalic acid, isophthalic acid, phthalic acid, methylhexahydrophthalic acid, methyltetrahydrophthalic acid, hexahydrophthalic acid, tetrahydrophthalic acid, maleic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, chlorendic acid, 1,2,4-butanetricarboxylic acid, decanedicarboxylic acid, octadecanedicarboxylic acid, dimer acid, dimerized fatty acid, trimer fatty acid, fumaric acid, 1,3-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, anhydrides of the above acids, and combinations thereof; wherein the one or more polyols are selected from ethylene glycol, propanediol, butanediol, butenediol, butynediol, pentanediol, pentenediol, pentynediol, hexanediol, octanediol, nonanediol, decanediol, neopentyl glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, cyclohexanedimethanol, cyclohexanediol, dimer diol, bisphenol A, bisphenol F, hydrogenated bisphenol A, hydrogenated bisphenol F, glycerol, tetramethylene glycol, polytetramethylene glycol, 3-methyl-1,5-pentanediol, 2-methyl-1,8-octanediol, trimethylolpropane, pentaerythritol, sorbitol, glucose, and combinations thereof; composition.

13. 13. The composition of any one of claims 1 to 12, further comprising a catalyst and / or one or more additives selected from thermoplastic polymers, tackifiers, plasticizers, waxes, stabilizers, antioxidants, talc, clay, silica and treated versions of talc, clay, silica, carbon black, mica, glass particulates, polymeric particulates, UV light capture and absorbers, pigments, fluorescent agents, odor inhibitors, adhesion promoters, surfactants, defoamers, and combinations thereof.

14. The composition according to any one of claims 1 to 13, wherein the crystalline polyester polyol is contained in the polyurethane prepolymer in an amount of less than 5% by weight.

15. A first substrate; Cured adhesive, and A second substrate adhered to a first substrate via a cured adhesive, the cured adhesive comprising a cured product derived from the hot melt adhesive composition of any one of claims 1 to 14. Items including.

16. 16. The article of claim 15, comprising a wearable electronic device, a portable electronic device, glasses, a phone, a tablet, a sound player, a remote control, a mouse, a watch band, a pump for dispensing medication, a headband, or a combination thereof.

17. A method for laminating two substrates, comprising applying a hot melt adhesive composition according to any one of claims 1 to 14 to at least one of the substrates and then laminating the substrates.

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