Highly spreadable ULV formulations for disinfectants

Abstract

The present invention relates to pesticide compositions; their use for foliar application; their use in small spray volumes; their use by unmanned aerial systems (UAS), by unmanned guided vehicles (UGV) and by tractor-mounted boom sprayers equipped not only with conventional nozzles but also with pulse-width modulated spray nozzles or spinning disk droplet applicators; and their application to control agricultural pests, weeds or diseases, in particular on waxy leaves.

Description

[Technical field]

[0001] The present invention relates to pesticide compositions; their use for foliar application; their use in small spray volumes; their use by unmanned aerial systems (UAS), by unmanned guided vehicles (UGV) and by tractor mounted boom sprayers equipped not only with conventional nozzles but also with pulse width modulated spray nozzles or spinning disk droplet applicators; and their application for controlling agricultural pests, weeds or diseases, in particular for controlling agricultural pests, weeds or diseases on waxy leaves. [Background technology]

[0002] Modern agriculture faces many challenges in producing enough food in a safe and sustainable way. It is therefore required to utilize crop protection products to enhance safety, quality and yield while minimizing the impact on the environment and on the farmland. Many crop protection products, whether chemical or biological, are usually applied in relatively large volumes, e.g. in selected cases more than 50 L / ha, and often more than 150-400 L / ha. This results in a lot of energy having to be consumed to transport the large volumes of spray solution, which are then applied to the crop by spray application. This can be carried out by large tractors, which, due to their weight and the weight of the spray solution, generate CO2 from the mechanical work involved, and also cause harmful compaction of the soil (which affects plant root growth, health and yield), and energy is then expended to ameliorate these effects.

[0003] A solution is needed that significantly reduces the volume of spray solution and reduces the weight of the equipment required to apply the product.

[0004] In agriculture, low-volume application technologies such as unmanned aerial systems (UAS), unmanned guided vehicles (UGV) and tractor-mounted boom sprayers with pulse-width modulated spray nozzles or spinning disk droplet applicators offer farmers the solution of applying products at low volumes (typically reduced to 10-20 L / ha or less). These solutions have advantages including, for example, requiring significantly less water (which is important in areas with limited water supplies), less energy required to transport and apply the spray solution, faster due to both faster filling of spray tanks and application, reduced CO2 production due to both the reduced volume of spray solution transported and the use of smaller, lighter vehicles (which reduce soil compaction damage and allow the use of cheaper application systems).

[0005] However, Wang et al. [Field evaluation of an unmanned aerial vehicle (UAV) sprayer: effect of spray volume on deposition and the control of pests and disease in wheat. Pest Management Science 2019 doi / epdf / 10.1002 / ps.5321] showed that as spray volumes were decreased from 450 and 225 L / ha to 28.1, 16.8, and 9.0 L / ha, the area covered (% area), number of spray deposits per area, and diameter of spray deposits all decreased as measured by water test strips (see Table 3 in Wang et al., 2019). At the same time, the biological control efficacy for both aphid and powdery mildew control in wheat was reduced at low application rates, with the greatest reduction at 9.0 L / ha, followed by 16.8 L / ha (see Figures 6, 7, and 8 in Wang et al., 2019).

[0006] Therefore, even when the number of spray deposits per area is reduced (the number of spray droplets per unit area is proportionally reduced for the same spray droplet spectral size as the spray volume is reduced), it is necessary to design a formulation system that overcomes the reduction in coverage area and diameter of spray deposits at low spray volumes, particularly below 25 L / ha, more particularly below 17 L / ha, and even more particularly below 10 L / ha.

[0007] A solution is provided by formulations containing organosilicone surfactants at surprisingly low total amounts applied per hectare, below the levels typically used and below the levels at which they are expected to function. Such formulations provide increased coverage and the increased diameter of the spray deposit is comparable to the coverage achieved with higher conventional spray rates. Furthermore, formulations embodying the present invention are particularly effective on difficult-to-wet leaf surfaces where more conventional spray rates provide insufficient retention and coverage.

[0008] A particular advantage of the present invention is the low cost of the formulations and their ease of manufacture due to the low total amount of organosilicone surfactant compared to the levels required for typical high spray volumes. Further advantages include improved stability and simplified manufacture of the formulations, lower cost of goods, and less impact on the environment.

[0009] There has been a long-standing recognition that the use of organosilicone surfactants as tank-mix adjuvants can be advantageous for lower application volumes. Gaskin et al. [Adjuvant prescriptions to lower water volumes and improve disease control in vineyards, ISAA 2004 proceedings; R. Gaskin et al., New adjuvant technology for pesticide use on wine grapes, New Zealand Plant Protection 55:154-158 (2002); and R. Gaskin et al., Use of a superspreader adjuvant to reduce spray application volumes on avocados, New Zealand Avocado Growers' Association Annual Research Report 2004.4:8-12] report that organosilicone surfactants can be advantageous for reducing spray volumes. However, they refer to relatively high application volumes of 100-2500 L / ha and high adjuvant volumes of 100-800 g / ha. They do not indicate or suggest that organosilicone surfactants can provide benefits at very low application rates (typically less than 10-20 L / ha or even less), nor that they can provide benefits at small amounts of surfactant (typically less than 50 g / h).

[0010] R. Gaskin et al. [Effect of surfactant concentration and spray volume on retention of organosilicone sprays on wheat, Proc. 50th NZ Plant Protection Conf. 1997:139-142] concluded that organosilicone surfactants are expected to enhance retention of pesticide sprays on poorly wetted arable species over a wide range of spray application rates. However, the data only covered 37-280 L / ha and only covered retained pesticide sprays, not plant coverage or size of spray deposits. Furthermore, there was no mention of low spray volume application according to the present invention using application volumes reduced to 10-20 L / ha (and in certain embodiments even lower, e.g., 1-5 L / ha).

[0011] All of these are for tank mix adjuvants and not for ready to use formulations.

[0012] The formulations of the present invention (which are most preferably ready-to-use formulations as opposed to tank mixes) offer the advantage of smaller application volumes due to the use of higher concentrations of organosilicon in the formulations of the present invention shown herein, thus providing a smaller, yet effective amount on the surface of the plant, and thus a smaller amount in the environment after application due to the smaller application volume.

[0013] The formulations known in the prior art that contain organosilicone surfactants (and also tank mix formulations) are mainly designed for very large spray volumes, and generally contain low concentrations of organosilicone surfactants in their spray broths.Nevertheless, due to the large spray volumes used in the prior art, the total amount of organosilicone surfactants used is greater than that of the present invention, and therefore the total amount in the environment is also greater than that of the present invention.

[0014] The concentration of the organosilicone surfactant is an important element of the present invention because proper spreading requires a certain minimum concentration of organosilicone surfactant, usually 0.05% w / w or w / v (these are preferred when the density of the organosilicone surfactant is about 1.0 g / cm 3 This occurs when (and therefore is equivalent to) is achieved.

[0015] For clarity, as will be understood by those skilled in the art, "spreading" means the rapid spreading of a droplet over a surface (i.e., in the context of the present invention, the surface of a plant part such as a leaf). [Prior art documents] [Non-patent literature]

[0016] [Non-Patent Document 1] Field evaluation of an unmanned aerial vehicle(UAV) sprayer:effect of spray volume on deposition and the control of pests and disease in wheat.Pest Management Science 2019 doi / epdf / 10.1002 / ps.5321 [Non-Patent Document 2] Adjuvant prescriptions to lower water volumes and improve disease control in vineyards,ISAA 2004 proceedings [Non-Patent Document 3] New adjuvant technology for pesticide use on wine grapes, New Zealand Plant Protection 55:154-158(2002) [Non-Patent Document 4] Use of a superspreader adjuvant to reduce spray application volumes on avocados,New Zealand Avocado Growers' Association Annual Research Report 2004.4:8-12 [Non-Patent Document 5] Effect of surfactant concentration and spray volume on retention of organosilicone sprays on wheat,Proc.50th NZPlant Protection Conf.1997:139-142 Summary of the Invention [Problem to be solved by the invention]

[0017] Thus, for a spray volume of 500 L / ha as used in the prior art, about 250 g / ha of organosilicone surfactant would be required to achieve adequate spreading. Thus, faced with the task of reducing the spray volume, a person skilled in the art would apply the same concentration of organosilicone surfactant in the formulation. For example, for a spray volume of 10 L / ha, about 5 g / ha (about 0.05% in the spray broth) of surfactant would be required. However, such a small spray volume containing such a low concentration of organosilicone surfactant cannot achieve sufficient spreading (see examples). [Means for solving the problem]

[0018] In the present invention, the inventors have surprisingly found that by increasing the concentration of the organosilicone surfactant as the spray rate is reduced, the loss of coverage (due to insufficient spreading) caused by the reduction in the spray rate can be compensated for.Surprisingly, it has been found that for every 50% reduction in the spray rate, the surfactant concentration needs to be approximately doubled.

[0019] Thus, although the absolute concentration of organosilicone surfactant is increased compared to formulations known in the art, the relative total amount per hectare can be reduced (which is advantageous both economically and ecologically), while the coverage of the formulations of the invention and the efficacy of the formulations of the invention are improved, maintained, or at least maintained at acceptable levels, taking into account the other advantages of application with low spray volumes (e.g. lower cost of formulation due to lower cost of goods, smaller vehicles with less labor costs, less soil compaction, etc.).

[0020] Another part of the present invention that allows the use of surprisingly low total amount of organosilicone surfactant is the surface texture of the target crop leaf.Bico et al. [Wetting of textured surfaces, Colloids and Surfaces A, 206 (2002) 41-46] established that compared with smooth surface, rough surface can enhance wetting for formulation spray dilution with contact angle less than 90 ° and reduce wetting for contact angle more than 90 °.

[0021] This also applies to leaf surfaces (especially rough leaf surfaces) when sprayed in the manner of the present invention, which results in a low total amount of organosilicone surfactant (per hectare) due to the low spray volume of the formulation of the present invention with a high concentration of organosilicone surfactant. It was possible to demonstrate a significantly higher coverage of the leaf surface with the spray (even to a higher level than would normally be expected).

[0022] Rough leaf surfaces include leaves containing micron-scale wax crystals on the surface, such as, for example, wheat, barley, rice, rapeseed, soybean (young plants) and cabbage leaves, as well as leaves with surface texture, such as, for example, lotus plant leaves. Surface texture can be ascertained by observation with a scanning electron microscope (SEM) and by the wettability of the leaf, determined by measuring the contact angle made by a drop of water on the leaf surface.

[0023] In summary, the object of the present invention is to provide a formulation that can be applied in small amounts (i.e. less than 20 L / ha) while providing good leaf coverage, uptake and biological efficacy against fungicidal pathogens, while at the same time reducing the amount of additional additives applied per hectare, as well as to provide a method of using the formulation in small amounts (i.e. less than 20 L / ha) and the use of the formulation for applying in small amounts as defined above.

[0024] Application to rough leaves is preferred, but it has surprisingly been found that even on non-rough leaves the formulations according to the invention show better spreading and coverage and other properties compared to classical spray application formulations for 200 L / ha.

[0025] In one aspect, the present invention is directed to the use of a composition according to the present invention for foliar application.

[0026] Unless otherwise indicated, "%" in this application means percent by weight (% w / w).

[0027] It is understood that when combining various ingredients, the percentages of all ingredients in a formulation will always add up to 100.

[0028] Additionally, unless otherwise indicated, a reference to "to volume" with respect to water indicates that water is added to bring the total volume of the formulation to 1000 mL (1 L).

[0029] In the context of the present invention, aqueous-based pesticide compositions contain at least 5% water and include suspension concentrates, aqueous suspensions, suspoemulsions or capsule suspensions, preferably suspension concentrates and aqueous suspensions.

[0030] It is further understood that the given preferred ranges of application volume or application rate, and the given preferred ranges of each component described herein, can be freely combined, and while all combinations are disclosed herein, in more preferred embodiments, the components are preferably present within the same preferred ranges, and even more preferred components are present within the most preferred ranges. [Brief description of the drawings]

[0031] [Figure 1] FIG. 1 shows scanning electron micrographs of leaf texture, where the top photograph shows a grape leaf surface (non-textured) and the bottom photograph shows a soybean leaf surface (textured). DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0032] In one aspect, the invention relates to a formulation comprising: (a) one or more active ingredients selected from the group of pesticide-applied fungicides; (b) one or more organosilicone surfactants (preferably, polyalkylene oxide-modified heptamethyltrisiloxane); (c) one or more other formulation aids; (d) water to a specified volume; Here, (b) is present at 5 to 250 g / L.

[0033] Unless otherwise indicated in the present invention, water is usually used in the formulation up to the volume specified. Preferably, the concentration of water in the formulation according to the present invention is at least 50 g / L, more preferably at least 100 g / L, such as at least 200 g / L, at least 400 g / L, at least 500 g / L, at least 600 g / L, at least 700 g / L and at least 800 g / L.

[0034] The formulation is preferably a spray application used on crops.

[0035] In a preferred embodiment, the formulation of the invention comprises: (a) one or more active ingredients selected from the group of pesticide-applied fungicides; (b) an organosilicone surfactant (preferably a polyalkylene oxide-modified heptamethyltrisiloxane); (c1) at least one suitable non-ionic surfactant and / or a suitable ionic surfactant; (c2) optionally, a rheology modifier; (c3) optionally, a suitable antifoaming substance; (c4) optionally, a suitable antifreeze; (c5) optionally, other suitable formulation aids; (d) Water to a specified volume.

[0036] In a preferred embodiment, component (a) is present in an amount of from 5 to 500 g / L, preferably from 10 to 300 g / L, and most preferably from 20 to 200 g / L.

[0037] In a preferred embodiment, component (b) is present at 4-250 g / L, preferably 8-120 g / L, and most preferably 10-80 g / L.

[0038] In a preferred embodiment, the one or more components (c1) are present at 4 to 250 g / L, preferably at 8 to 120 g / L, and most preferably at 10 to 80 g / L.

[0039] In a preferred embodiment, the one or more components (c2) are present at 0-60 g / L, preferably at 1-20 g / L, and most preferably at 2-10 g / L.

[0040] In a preferred embodiment, the one or more components (c3) are present at 0-30 g / L, preferably at 0.5-20 g / L, and most preferably at 1-12 g / L.

[0041] In a preferred embodiment, the one or more components (c4) are present at 0-200 g / L, preferably at 5-150 g / L, and most preferably at 10-120 g / L.

[0042] In a preferred embodiment, the one or more components (c5) are present at 0-200 g / L, preferably 0.1-120 g / L, most preferably 0.5-80 g / L.

[0043] In one embodiment, the formulation comprises components (a)-(d) in the following amounts: (a) 5 to 500 g / L, preferably 10 to 300 g / L, and most preferably 20 to 200 g / L; (b) 4 to 250 g / L, preferably 8 to 120 g / L, and most preferably 10 to 80 g / L; (c1) 4 to 250 g / L, preferably 8 to 120 g / L, and most preferably 10 to 80 g / L; (c2) 0 to 60 g / L, preferably 1 to 20 g / L, and most preferably 2 to 10 g / L; (c3) 0 to 30 g / L, preferably 0.5 to 20 g / L, and most preferably 1 to 12 g / L; (c4) 0 to 200 g / L, preferably 5 to 150 g / L, and most preferably 10 to 120 g / L; (c5) 0 to 200 g / L, preferably 0.1 to 120 g / L, and most preferably 0.5 to 80 g / L; (d) Water to a specified volume.

[0044] In another embodiment, the formulation comprises components (a)-(d) in the following amounts: (b) 5~250g / L (c) 5~250g / L (c1) 5~120g / L (c2) 1~20g / L (c3) 0.1 to 14 g / L (c4) 5~120g / L (c5) 0.1 to 100 g / L (d) Water to a specified volume.

[0045] As indicated above, component (d) is always added to a given volume (ie, to 1 L).

[0046] In a further preferred embodiment of the invention, the formulation consists only of components (a)-(d) as described above in the amounts and ranges specified.

[0047] The present invention is further applicable to a method of applying the above formulation, wherein the formulation is applied in a spray volume of 1 to 20 L / ha, preferably 2 to 15 L / ha, more preferably 5 to 15 L / ha.

[0048] More preferably, the present invention also applies to a method of application of said formulation, wherein the formulation is applied in a spray volume of 1-20 L / ha, preferably 2-15 L / ha, more preferably 5-15 L / ha, and (b) is present in an amount of 4-250 g / L, preferably 8-120 g / L, and most preferably 10-80 g / L, wherein in a further preferred embodiment (a) is present in an amount of 5-500 g / L, preferably 10-300 g / L, and most preferably 20-200 g / L.

[0049] In an alternative embodiment, (a) is present at 50-100 g / L.

[0050] In another embodiment, (a) is present at 5-30 g / L.

[0051] In another aspect, the present invention relates to a method of application of the above formulation, Here, the formulation is applied in a spray volume of 1 to 20 L / ha, preferably 2 to 15 L / ha, more preferably 5 to 15 L / ha; Here, the application rate of (a) to the crop is preferably 2 to 150 g / ha, more preferably 5 to 120 g / ha, and further preferably 20 to 100 g / ha.

[0052] In one embodiment, the application rate of (a) to the crop by the method set forth above is between 2 and 10 g / ha.

[0053] In another embodiment, the application rate of (a) to the crop by the method set forth above is between 40 and 110 g / ha.

[0054] In one embodiment of said application, the active ingredient (ai)(a) is preferably applied at 2 to 150 g / ha, preferably at 5 to 120 g / ha and more preferably at 20 to 100 g / ha, while correspondingly the organosilicone surfactant is preferably applied at 10 g / ha to 100 g / ha, more preferably at 20 g / ha to 80 g / ha and most preferably at 40 g / ha to 60 g / ha.

[0055] In particular, the formulations of the present invention are useful for application to plants or crops having a rough leaf surface, preferably to wheat, barley, rice, rapeseed, soybean (young plants) and cabbage, at spray volumes of 1-20 L / ha, preferably 2-15 L / ha, more preferably 5-15 L / ha.

[0056] Furthermore, the present invention relates to a method for treating crops with a rough leaf surface, preferably wheat, barley, rice, rapeseed, soybean (young plants) and cabbage, with a spray volume of 1-20 L / ha, preferably 2-15 L / ha, more preferably 5-15 L / ha.

[0057] In a preferred embodiment, said application is to crops having a rough leaf surface, preferably to wheat, barley, rice, rapeseed, soybean (young plants) and cabbage.

[0058] The corresponding dosages of organosilicone surfactant agent (b) in the formulation according to the invention relative to the dosage applied are as follows:

[0059] A liquid formulation at 2L / ha delivers: 50 g / ha of organosilicone surfactant contains 25 g / L of surfactant (b); 30 g / ha of organosilicone surfactant containing 15 g / L of surfactant (b); 12 g / ha of organosilicone surfactant containing 6 g / L of surfactant (b); The organosilicone surfactant at 10 g / ha contains 5 g / L of surfactant (b).

[0060] 1 L / ha of the liquid formulation delivers: 50 g / ha of organosilicone surfactant contains 50 g / L of surfactant (b); 30 g / ha of organosilicone surfactant contains 30 g / L of surfactant (b); 12 g / ha of organosilicone surfactant contains 12 g / L of surfactant (b); 10 g / ha of the organosilicone surfactant contains 10 g / L of surfactant (b).

[0061] A liquid formulation at 0.5 L / ha delivers: 50 g / ha of organosilicone surfactant contains 100 g / L of surfactant (b); 30 g / ha of organosilicone surfactant contains 60 g / L of surfactant (b); 12 g / ha of organosilicone surfactant contains 24 g / L of surfactant (b); 10 g / ha of the organosilicone surfactant contains 20 g / L of surfactant (b).

[0062] A liquid formulation at 0.2 L / ha delivers: 50 g / ha of organosilicone surfactant contains 250 g / L of surfactant (b); 30 g / ha of organosilicone surfactant containing 150 g / L of surfactant (b); 12 g / ha of organosilicone surfactant containing 60 g / L of surfactant (b); 10 g / ha of the organosilicone surfactant contains 50 g / L of surfactant (b).

[0063] A solid formulation at 2 kg / ha delivers: 50 g / ha of organosilicone surfactant contains 25 g / kg of surfactant (b); 30 g / ha of organosilicone surfactant contains 15 g / kg of surfactant (b); 12 g / ha of organosilicone surfactant containing 6 g / kg of surfactant (b); 10 g / ha of the organosilicone surfactant contains 5 g / kg of surfactant (b).

[0064] A solid formulation at 1 kg / ha delivers: 50 g / ha of the organosilicone surfactant contains 50 g / kg of surfactant (b); 30 g / ha of the organosilicone surfactant contains 30 g / kg of surfactant (b); 12 g / ha of the organosilicone surfactant contains 12 g / kg of surfactant (b); 10 g / ha of the organosilicone surfactant contains 10 g / kg of surfactant (b).

[0065] A solid formulation at 0.5 kg / ha delivers: 50 g / ha of organosilicone surfactant contains 100 g / kg of surfactant (b); 30 g / ha of organosilicone surfactant contains 60 g / kg of surfactant (b); 12 g / ha of organosilicone surfactant contains 24 g / kg of surfactant (b); 10 g / ha of the organosilicone surfactant contains 20 g / kg of surfactant (b).

[0066] The concentrations of organosilicone surfactant (b) in formulations applied at other rates per hectare can be calculated in the same way.

[0067] In the context of the present invention, suitable formulation types are by definition suspension concentrates, aqueous suspensions, suspoemulsions or capsule suspensions, EW formulations, water dispersible granules, oil dispersions, emulsifiable concentrates, preferably suspension concentrates, aqueous suspensions, suspoemulsions and oil dispersions, where in the case of non-aqueous or solid formulations a sprayable formulation is obtained by adding water.

[0068] Thus, in one embodiment, the formulation is obtained from a suspension formulation (SC) by dilution.

[0069] The SC diluent according to the present invention comprises: (a) 0.2 to 200 g / L of active ingredient, preferably 1 to 100 g / L; (b) 0.5 to 10 g / L of an organosilicone surfactant, preferably 1 to 5 g / L; (c) C1 0.05 to 24, preferably 0.5 to 12 g / L; C2 0-4g / L, preferably 0.1-2g / L; C3 0-4g / L, preferably 0.01-2g / L; C4 0-20g / L, preferably 0.5-24g / L; C5 0.001 to 20 g / L, preferably 0.01 to 5 g / L.

[0070] Thus, in one embodiment, the formulation is obtained from a suspoemulsion formulation (SE) by dilution.

[0071] The SE dilution according to the present invention comprises: (a) 0.2 to 200 g / L of active ingredient, preferably 1 to 100 g / L; (b) 0.5 to 10 g / L of an organosilicone surfactant, preferably 1 to 5 g / L; (c) C1 0.05 to 24, preferably 0.5 to 12 g / L; C2 0-4g / L, preferably 0.1-2g / L; C3 0-4g / L, preferably 0.01-2g / L; C4 0-20g / L, preferably 0.5-24g / L; C5 0.001 to 20 g / L, preferably 0.01 to 5 g / L.

[0072] Active ingredient (a): The active compounds identified herein by common names are known and are described, for example, in the Pesticides Handbook ("The Pesticide Manual" 16th Ed., British Crop Protection Council 2012) or can be found on the Internet (e.g., http: / / www.alanwood.net / pesticides). The classification is based on the "IRAC Mode of Action Classification Scheme" current at the time of filing of the patent application.

[0073] Examples of fungicides (a) according to the invention are:

[0074] (1) Inhibitors of ergosterol biosynthesis, for example: (1.001) cyproconazole, (1.002) difenoconazole, (1.003) epoxiconazole, (1.004) fenhexamid, (1.005) fenpropidin, (1.006) fenpropimorph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1.009) flutriafol, (1.010) imazalil, (1.011) imazalil sulfate, (1.012) ipconazole, (1.013) metconazole, (1.014). Myclobutanil, (1.015) Paclobutrazol, (1.016) Prochloraz, (1.017) Propiconazole, (1.018) Prothioconazole, (1.019) Pyrisoxazole, (1.020) Spiroxamine, (1.021) Tebuconazole, (1.022) Tetraconazole, (1.023) Triadimenol, (1.024) Tridemorph, (1.025) Triticonazole, (1.026) (1R,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H -1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.027) (1S,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.028) (2R)-2-(1-chlorocyclopropyl)-4-[(1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol (1.029) (2R)-2-(1-chlorocyclopropyl)- 4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.030) (2R)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.031) (2S)-2-(1-chlorocyclopropyl)-4-[(1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.032) (2S)-2-(1-chlorocyclopropyl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.033) (2S)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.034) (R)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl) (1.035) (S)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.036) [3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.037) 1-({(2R,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl )-1H-1,2,4-triazole, (1.038) 1-({(2S,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole, (1.039) 1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.040) 1-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate (1.041) 1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.042) 2-[(2R,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.043) 2-[(2R,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.044) 2-[(2R,4S,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.045) 2-[(2R,4S,5S)-1-(2,4-dichlorophenyl )-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.046) 2-[(2S,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.047) 2-[(2S,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2 ,4-dihydro-3H-1,2,4-triazole-3-thione, (1.048) 2-[(2S,4S,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.049) 2-[(2S,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1. 050) 2-[1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.051) 2-[2-chloro-4-(2,4-dichlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.052) 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.053) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.054) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)pentan-2-ol, (1.055) Mefentrifluconazole, (1.056) 2-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2, 4-Triazole-3-thione, (1.057) 2-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.058) 2-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.059) 5-(4-chlorobenzyl)-2-(chloromethyl)-2- Methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.060) 5-(arylsulfanyl)-1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.061) 5-(arylsulfanyl)-1-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.062) 5-(arylsulfanyl)- 1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.063) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide, (1.064) N'-(2,5-dimethyl-4-{[3-(2,2,2-trifluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide, (1.065) N'-(2,5-dimethyl-4-{[3-(2,2,3,3-tetrafluoropropoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide, (1.066) N'-(2,5-dimethyl-4-{[3-(pentafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide, (1.067) N'-(2,5-dimethyl-4-{3-[(1,1,2,2-tetrafluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methyl Imidoformamide, (1.068) N'-(2,5-dimethyl-4-{3-[(2,2,2-trifluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.069) N'-(2,5-dimethyl-4-{3-[(2,2,3,3-tetrafluoropropyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.070) N'-(2,5-dimethyl-4-{3-[(pentafluoroethyl)sulfanyl]phenoxy}phenyl)-N -ethyl-N-methylimidoformamide, (1.071) N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylimidoformamide, (1.072) N'-(4-{[3-(difluoromethoxy)phenyl]sulfanyl}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamide, (1.073) N'-(4-{3-[(difluoromethyl)sulfanyl]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamide, (1.074) N'-[5 -Bromo-6-(2,3-dihydro-1H-inden-2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylimidoformamide, (1.075) N'-{4-[(4,5-dichloro-1,3-thiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylimidoformamide, (1.076) N'-{5-bromo-6-[(1R)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.077) N'-{5-bromo-6-[(1S)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.078) N'-{5-bromo-6-[(cis-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.079) N'-{5-bromo-6-[(trans-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.080) N'-{5-bromo-6-[1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide. , (1.081) ipfentrifluconazole, (1.082) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.083) 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol, (1.084) 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol, (1.085) 3-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluoro-phenyl)-2-hydroxy-propyl]imidazole 4-[[6-[rac-(2R)-2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-thioxo-4H-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, (1.087) N-isopropyl-N'-[5-methoxy-2-methyl-4-(2,2,2-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile (1.087) N'-{5-bromo-2-methyl-6-[(1-propoxypropan-2-yl)oxy]pyridin-3-yl}-N-ethyl-N-methylimido-formamide, (1.088) N'-{5-bromo-2-methyl-6-[(1-propoxypropan-2-yl)oxy]pyridin-3-yl}-N-ethyl-N-methylimido-formamide, (1.089) hexaconazole, (1.090) penconazole, (1.091) fenbuconazole.

[0075] (2) Inhibitors of the respiratory chain at complex I or complex II, such as (2.001) benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.004) carboxin, (2.005) fluopyram, (2.006) flutolanil, (2.007) fluxapyroxad, (2.008) furametpyr, (2.009) isofetamide, (2.010) isopyrazam (anti-epimer enantiomer 1R,4S,9S), (2.011) isopyrazam (anti-epimer enantiomer 1S,4R,9R), (2.012) isopyrazam (anti-epimer racemate 1RS,4SR,9SR), (2.013) Isopyrazam (mixture of syn-epimeric racemate (1RS,4SR,9RS) and anti-epimeric racemate (1RS,4SR,9SR)), (2.014) Isopyrazam (syn-epimeric enantiomers 1R,4S,9R), (2.015) Isopyrazam (syn-epimeric enantiomers 1S,4R,9S), (2.016) Isopyrazam (syn-epimeric racemate 1RS,4SR,9RS), (2.017) Penflufen, (2.018) Penthiopyrad, (2.019) Pydiflumetofen, (2.020) Pyraziflumide, (2.021) Sedaxane, (2.022) 1,3-dimethyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.023) 1,3-dimethyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide boxamide, (2.024) 1,3-dimethyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.025) 1-methyl-3-(trifluoromethyl)-N-[2'-(trifluoromethyl)biphenyl-2-yl]-1H-pyrazole-4-carboxamide, (2.026) 2-fluoro-6-(trifluoromethyl)-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)benzamide, (2.027) 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.028) Inpyrfluxam, (2.029) 3-(difluoromethyl)-1-methyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.030) Fluindapyr, (2.031) 3-(difluoromethyl)-N-[(3R)-7-fluindapyr Fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.032) 3-(difluoromethyl)-N-[(3S)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.033) 5,8-difluoro-N-[2-(2-fluoro-4-{[4-(trifluoromethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazoline -4-amine, (2.034) N-(2-cyclopentyl-5-fluorobenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.035) N-(2-tert-butyl-5-methylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.036) N-(2-tert-butylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro (2.037) N-(5-chloro-2-ethylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) isoflucipram, (2.039) N-[(1R,4S)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.040)040) N-[(1S,4R)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.041) N-[1-(2,4-dichlorophenyl)-1-methoxypropan-2-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.042) N-[2-chloro-6-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5- Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.043) N-[3-chloro-2-fluoro-6-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.044) N-[5-chloro-2-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.045) N-cyclopropyl-3-(difluoro Methyl)-5-fluoro-1-methyl-N-[5-methyl-2-(trifluoromethyl)benzyl]-1H-pyrazole-4-carboxamide, (2.046) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-fluoro-6-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.047) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropyl-5-methylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.048 ) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carbothioamide, (2.049) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.050) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(5-fluoro-2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.051) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-4,5-dimethylbenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.053) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-methylbenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.054) N-cyclopropyl-N-(2-cyclopropyl-5-fluorobenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole -4-carboxamide, (2.055) N-cyclopropyl-N-(2-cyclopropyl-5-methylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.056) N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.057) pyrapropoine, (2.058) N-[rac-(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)-nicotinamide, (2.059) N-[(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)nicotinamide.

[0076] (3) Inhibitors of the respiratory chain at complex III, such as (3.001) amethoctrazine, (3.002) amisulbrom, (3.003) azoxystrobin, (3.004) coumethoxystrobin, (3.005) coumoxystrobin, (3.006) cyazofamid, (3.007) dimoxystrobin, (3.008) enoxastrobin, (3.009) famoxadone, (3.010) fenamidone, (3.011) flufenoxystrobin, (3.01 2) Fluoxastrobin, (3.013) Kresoxim-methyl, (3.014) Metominostrobin, (3.015) Orysastrobin, (3.016) Picoxystrobin, (3.017) Pyraclostrobin, (3.018) Pyrametstrobin, (3.019) Pyraoxystrobin, (3.020) Trifloxystrobin, (3.021) (2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-fluoro-2-phenylvinyl]oxy}phenyl)ethylidene]amino}oxy)methyl]phenyl}-2-(methoxy imino)-N-methylacetamide, (3.022) (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.023) (2R)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3.024) (2S)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3.025) fenpicoxamide, (3.0 26) Mandestrobin, (3.027) N-(3-ethyl-3,5,5-trimethylcyclohexyl)-3-formamido-2-hydroxybenzamide, (3.028) (2E,3Z)-5-{[1-(4-chloro-2-fluorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.029) Methyl {5-[3-(2,4-dimethylphenyl)-1H-pyrazol-1-yl]-2-methylbenzyl}carbamate, (3.030) Methyltetraprole, (3.031) Florylpicoxamide.

[0077] (4) Mitosis and cell division inhibitors, for example, (4.001) carbendazim, (4.002) diethofencarb, (4.003) ethaboxam, (4.004) fluopicolide, (4.005) pencycuron, (4.006) thiabendazole, (4.007) thiophanate-methyl, (4.008) zoxamide, (4.009) pyridaclomethyl, (4.010) 3-chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl)-6-methylpyridazine, (4.011) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.012) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.013) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.014) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.015) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.016) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.017) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.018) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.019) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.020) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.021) 3-chloro-5-(6-chloropyridine-3-yl)pyridazin, (4.012) 4-(2-bromo-4-fluorophenyl)-N-(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.013) 4-(2-bromo-4-fluorophenyl)-N-(2-bromo-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.014) 4-(2-bromo-4-fluorophenyl)-N-(2-bromophenyl)-1,3-dimethyl-1H-pyrazol-5-amine , (4.015) 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.016) 4-(2-bromo-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.017) 4-(2-bromo-4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.018) 4-(2-chloro-4-fluorophenyl)-N-(2,6-di fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.019) 4-(2-chloro-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.020) 4-(2-chloro-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.021) 4-(2-chloro-4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.022) 4-(4-chlorophenyl)-5-(2,6-difluorophenyl)-3,6-dimethylpyridazine, (4.023) N-(2-bromo-6-fluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.024) N-(2-bromophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.025) N-(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.026) fluopimomide.

[0078] (5) Compounds capable of exerting activity at multiple sites, for example, (5.001) Bordeaux mixture, (5.002) captafol, (5.003) captan, (5.004) chlorothalonil, (5.005) copper hydroxide, (5.006) copper naphthenate, (5.007) copper oxide, (5.008) copper chloride dibasic, (5.009) copper(2+) sulfate, (5.010) dithianone, (5.011) dodine, (5.012) folpet, (5.013) mancozeb, (5. 014) Maneb, (5.015) Metiram, (5.016) Metiram zinc, (5.017) Oxine copper, (5.018) Propineb, (5.019) Sulphur and sulphur agents such as calcium polysulphide, (5.020) Thiuram, (5.021) Zineb, (5.022) Ziram, (5.023) 6-Ethyl-5,7-dioxo-6,7-dihydro-5H-pyrrolo[3',4':5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-carbonitrile.

[0079] (6) Compounds capable of inducing host defenses, such as (6.001) acibenzolar-S-methyl, (6.002) isotianil, (6.003) probenazole, (6.004) thiadinil.

[0080] (7) Inhibitors of amino acid and / or protein biosynthesis, for example (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.006) 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinoline.

[0081] (8) Inhibitors of ATP production, for example, (8.001) Silthiofam.

[0082] (9) Inhibitors of cell wall synthesis, such as (9.001) benthiavalicarb, (9.002) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, (9.005) mandipropamide, (9.006) pyrimorph, (9.007) valifenalate, (9.008) (2E)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one, (9.009) (2Z)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one.

[0083] (10) Inhibitors of lipid and membrane synthesis, for example, (10.001) propamocarb, (10.002) propamocarb hydrochloride, (10.003) tolclofos-methyl.

[0084] (11) Inhibitors of melanin biosynthesis, for example, (11.001) tricyclazole, (11.002) tolprocarb.

[0085] (12) Inhibitors of nucleic acid synthesis, such as (12.001) benalaxyl, (12.002) benalaxyl-M (chiralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam).

[0086] (13) Signal transduction inhibitors, such as (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazide, (13.005) quinoxyfen, (13.006) vinclozolin.

[0087] (14) Compounds which can act as uncouplers, for example, (14.001) fluazinam, (14.002) meptyldinocap.

[0088] (15) Further fungicides selected from the group consisting of: (15.001) abscisic acid, (15.002) benthiazole, (15.003) bethoxazin, (15.004) capsimycin, (15.005) carvone, (15.006) quinomethionate, (15.007) kufuraneb, (15.008) cyflufenamid, (15.009) cymoxanil, (15.010) cyprosulfamide, (15.011) fluthianil, (15.012) fosetyl-aluminium, (15.013) fosetyl (15.014) fosetyl sodium, (15.015) methyl isothiocyanate, (15.016) metrafenone, (15.017) mildiomycin, (15.018) natamycin, (15.019) nickel dimethyldithiocarbamate, (15.020) nitrothal-isopropyl, (15.021) oxamocarb, (15.022) oxathiapiproline, (15.023) oxyfenthiin, (15.024) pentachlorophenol and salts, (15.025) phosphonic acids and their salts, (15.026) propamocarb-fosetylate, (15.027) pyriophenone (chlazafenone), (15.028) tebufloquine, (15.029) tecloftalam, (15.030) tolnifanide, (15.031) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidine, lysine-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.032) 1-(4-{4-[(5S)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.033) 2-(6-benzylpyridin-2-yl)quinazoline, (15.034) dipimethitrone, (15.035) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15.036) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-chloro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15.037) 2-[3,5-bis(difluoro methyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-fluoro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15.038) 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline, (15.039) 2-{(5R)-3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl Methanesulfonate, (15.040) 2-{(5S)-3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15.041) ipflufenoquine, (15.042) 2-{2-fluoro-6-[(8-fluoro-2-methylquinolin-3-yl)oxy]phenyl}propan-2-ol, (15.043) fluoxapiproline, (15.044) 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}phenyl methanesulfonate, (15.045) 2-Phenylphenol and salts, (15.046) 3-(4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15.047) quinofumelin, (15.048) 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2(1H)-one), (15.049) 4-oxo-4-[(2-phenylethyl)amino]butanoic acid, (15.050) 5-amino-1,3,4-thiadiazole-2-thiol, (15.051) 5-chloro-N'-phenyl-N'-(prop-2-yn-1-yl)thiophene 2-Sulfonohydrazide, (15.052) 5-Fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.053) 5-Fluoro-2-[(4-methylbenzyl)oxy]pyrimidin-4-amine, (15.054) 9-Fluoro-2,2-dimethyl-5-(quinolin-3-yl)-2,3-dihydro-1,4-benzoxazepine, (15.055) Buta-3 -yn-1-yl{6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.056) ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate, (15.057) phenazine-1-carboxylic acid, (15.058) propyl 3,4,5-trihydroxybenzoate, (15 .059) Quinolin-8-ol, (15.060) Quinolin-8-ol sulfate (2:1), (15.061) tert-butyl {6-[({[(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.062) 5-fluoro-4-imino-3-methyl-1-[(4-methylphenyl)sulfonyl n-3,4-dihydropyrimidin-2(1H)-one, (15.063) aminopyrifen, (15.064) (N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylimido-formamide), (15.065) (N'-(2-chloro-5-methyl-4-phenoxyphenyl)-N-ethyl-N-methylimidoformamide), (15.066) (2-{2-[(7,8-difluoro-2-methylquinolin-3-yl)oxy]-6-fluorophenyl}propan-2-ol), (15.067) (5-bromo-1-(5,6-dimethylpyridin-3-yl)-3,3-dimethyl-3,4-dihydroisoquinoline), (15.068) (3-(4,4-difluoro-5,5-dimethyl-4,5-dihydrothieno[2,3-c]pyridin-7-yl)quinoline), (15.069) (1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-di methyl-3,4-dihydroisoquinoline), (15.070) 8-fluoro-3-(5-fluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinolone, (15.071) 8-fluoro-3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinolone, (15.072) 3-(4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)-8-fluoroquinoline, (15.073) (N-methyl-N-phenyl-4-[5-(trifluoromethyl)-1,2 ,4-oxadiazol-3-yl]benzamide), (15.074) methyl {4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}carbamate, (15.075) (N-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}cyclopropanecarboxamide), (15.076) N-methyl-4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.077) N-[(E)-methoxyimino-methyl]-4-[5-( trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.078) N-[(Z)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.079) N-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]cyclopropanecarboxamide, (15.080) N-(2-fluorophenyl)-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.081) 2,2-difluoro-N-methyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]acetamide, (15.082) N-allyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl)phenyl]methyl]acetamide, (15.083) N-[(E)-N-methoxy-C-methyl-carbonimidoyl]-4-(5-(trifluoro-methyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.084) N-[(Z)-N-meth (15.085) N-allyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, (15.086) 4,4-dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidin-2-one, (15.087) N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidin-2-one, ,2,4-Oxadiazol-3-yl]benzenecarbothioamide, (15.088) 5-Methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidin-2-one, (15.089) N-((2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-3,3,3-trifluoro-propanamide, (15.090) 1-Methoxy-1-methyl-3-[[4-[5-(trifluoro-methyl}-1,2,4- oxadiazol-3-yl]phenyl]methyl]urea, (15.091) 1,1-diethyl-3-[[4-[5-(trifluoromethyl}-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.092) N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, (15.093) N-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]cyclopropanecarboxamide, (15.094) 1-Methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.095) N-Methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl)cyclopropanecarboxamide, (15.096) N,2-Dimethoxy-N-[[4-[5-(trifluoromethyl}-1,2,4-oxadiazol-3-yl. ]phenyl]methyl]propanamide, (15.097) N-ethyl-2-methyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl)phenyl]methyl]propanamide, (15.098) 1-methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.099) 1,3-dimethoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea azole-3-yl]phenyl]methyl]urea, (15.100) 3-ethyl-1-methoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.101) 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]-methyl]piperidin-2-one, (15.102) 4,4-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidine-2-one, (15.103) 4,4-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.104) 4-methyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidine-2-one, (15.105) 4-methyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidine-2-one, (15.106) 4-methyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidine-2-one, (15.107) 4-methyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidine-2-one, (15.109) 4-methyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidine-2 -yl]phenyl]-methyl]isoxazolidin-3-one, (15.103) 5,5-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, (15.104) 3,3-dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidin-2-one, (15.105) 1-[[3-fluoro-4-(5-(trifluoro) methyl)-1,2,4-oxadiazol-3-yl]-phenyl]methyl]azepan-2-one, (15.106) 4,4-dimethyl-2-[[4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]-phenyl]methyl]isoxazolidin-3-one, (15.107) 5,5-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, (15.108) ethyl 1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}-1H-pyrazole-4-carboxylate, (15.109) N,N-Dimethyl-1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}-1H-1,2,4-triazol-3-amine, (15.110) N-{2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}butanamide, (15.111) N-(1-methylcyclopropyl)-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.112) N-(2,4-difluorophenyl)-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.113) 1-(5,6-dimethylpyridine- 3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.114) 1-(6-(difluoromethyl)-5-methyl-pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydro-isoquinoline, (15.115) 1-(5-(fluoromethyl)-6-methyl-pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.116) 1-(6-(difluoromethyl)-5-methoxy-pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.117) 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl Dimethyl carbamate, (15.118) N-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}propanamide, (15.119) 3-[2-(1-{[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate, (15.120) 9-fluoro-3-[2-(1-{[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate, (15.121) 3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate, (15.122) 3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-9-fluoro-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate, (15.123) 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.124) 8-fluoro-N-(4,4,4-trifluoro-2-methyl-1-phenylbutan-2-yl)quinoline-3-carboxamide, (15.125) 8-fluoro-N-[(2S) -4,4,4-trifluoro-2-methyl-1-phenylbutan-2-yl]quinoline-3-carboxamide, (15.126) N-(2,4-dimethyl-1-phenylpentan-2-yl)-8-fluoroquinoline-3-carboxamide, and (15.127) N-[(2S)-2,4-dimethyl-1-phenylpentan-2-yl]-8-fluoroquinoline-3-carboxamide.

[0089] The at least one active ingredient is preferably selected from the group comprising fungicides selected from the group comprising classes (1) inhibitors of the respiratory chain in complexes (especially azoles), (2) inhibitors of the respiratory chain in complexes I or II, (3) inhibitors of the respiratory chain in complexes, (4) inhibitors of mitosis and cell division, (6) compounds capable of inducing host defense, (10) inhibitors of lipid and membrane synthesis and (15) described above.

[0090] More preferably, the at least one active ingredient (a) is selected from the group comprising trifloxystrobin, prothioconazole, tebuconazole, fluopyram, bixafen, isoflucipram, impirfluxam, fluoxapiproline, fluopicolide, isotianil, spiroxamine and propamocarb.

[0091] All fungicides named in the above described classes (1) to (15) can be present in the form of free compounds and / or, if their functional groups allow, in the form of their agriculturally active salts.

[0092] Additionally, mesomeric forms and stereoisomers or enantiomers, where appropriate, are to be included, as these variations are well known to those skilled in the art, as are polymorphs.

[0093] Unless otherwise indicated, in the context of the present invention, solid pesticidally active compounds (a) are to be understood as meaning all substances customary for the treatment of plants, the melting point of which is above 20°C.

[0094] In a preferred embodiment, there is only one active ingredient as a fungicide.

[0095] In another embodiment, the formulation comprises as (a) a mixture of two fungicides.

[0096] In yet another embodiment, the formulation comprises as (a) a mixture of three fungicides.

[0097] In an alternative embodiment, the formulation comprises as (a) a fungicide and as a mixing partner a further active ingredient selected from the group of insecticides, herbicides and safeners.

[0098] Organosilicone Surfactants (b) Suitable organosilicone surfactants are organosilicone ethoxylates, in particular organically modified polysiloxane / trisiloxane alkoxylates having the following CAS numbers: CAS No. 27306-78-1, 67674-67-3, 134180-76-0, such as Silwet® L77, Silwet® 408, Silwet® 806, BreakThru® S240, BreakThru® S278, etc.

[0099] Preferred are polyalkylene oxide modified heptamethyltrisiloxanes, preferably those containing the siloxane group poly(oxy-1,2-ethanediyl),.alpha.-methyl-.omega.-[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]disiloxanyl]propoxy] (CAS No. 27306-78-1), poly(oxy-1,2-ethanediyl),.alpha.-[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]disiloxanyl]propyl]-.omega.-hydroxy (Cas No. 67674-67-3), and polymers containing oxirane, methyl-, mono 3-1,3,3,3-tetramethyl-1-(trimethylsilyl)oxydisiloxanylpropyl ether (Cas No. The polyalkylene oxide-modified heptamethyltrisiloxane is selected from the group including (but not limited to) 1,2-dimethylphenylsiloxane (DMSO) (No. 134180-76-0).

[0100] Other formulation aids (c) (c1) Suitable nonionic surfactants or dispersants (c1) are all substances of this type that can be conventionally used in agrochemicals. Preferably, polyethylene oxide-polypropylene oxide block copolymers (preferably with a molecular weight of more than 6000 g / mol or a polyethylene oxide content of more than 45%, more preferably with a molecular weight of more than 6000 g / mol and a polyethylene oxide content of more than 45%), polyethylene glycol ethers of branched or linear alcohols, reaction products of fatty acids or fatty acid alcohols with ethylene oxide and / or propylene oxide, furthermore polyvinyl alcohols, polyoxyalkyleneamine derivatives, polyvinylpyrrolidone, copolymers of polyvinyl alcohol and polyvinylpyrrolidone, and copolymers of (meth)acrylic acid and (meth)acrylic acid esters, furthermore branched or linear alkyl ethoxylates and alkylaryl ethoxylates (here, polyethylene oxide-sorbitan fatty acid esters can be mentioned as an example). Of the above examples, selected classes may optionally be phosphorylated, sulfonated or sulfated and neutralized with bases.

[0101] Possible anionic surfactants (c1) are all substances of this type that can be conventionally used in agrochemicals. Preference is given to the alkali metal, alkaline earth metal and ammonium salts of alkylsulfonic or alkylphosphoric acids, as well as alkylarylsulfonic or alkylarylphosphoric acids. Further preferred groups of anionic surfactants or dispersants are the alkali metal, alkaline earth metal and ammonium salts of polystyrenesulfonic acid, the salts of polyvinylsulfonic acid, the salts of alkylnaphthalenesulfonic acids, the salts of naphthalene-sulfonic acid-formaldehyde condensation products, the salts of naphthalenesulfonic acid, phenolsulfonic acid and formaldehyde condensation products, and the salts of lignosulfonic acid.

[0102] (c2) Rheology modifiers are additives that provide a substantial increase in viscosity at low shear rates when added to a formulation at a concentration that reduces gravitational separation of dispersed active ingredients during storage. For purposes of this invention, low shear rates are defined as rates below 0.1 s -1 where a substantial increase is defined as greater than 2-fold, and a substantial increase is defined as greater than 2-fold. Viscosity can be measured with a rotational shear rheometer.

[0103] Suitable rheology modifiers (c4) are, by way of example, Polysaccharides including xanthan gum, guar gum and hydroxyethylcellulose, examples of which are Kelzan®, Rhodopol® G and 23, Satiaxane® CX911 and Natrosol® 250 range; Clays including montmorillonite, bentonite, sepiolite, attapulgite, laponite, hectorite, examples of which are Veegum® R, VanGel® B, Bentone® CT, HC, EW, Pangel® M100, M200, M300, S, M, W, Attagel® 50, Laponite® RD; Fumed and precipitated silicas, examples of which are Aerosil® 200, Siponat® 22.

[0104] Preferred are xanthan gum, montmorillonite clay, bentonite clay and fumed silica.

[0105] (c3) Suitable antifoaming substances (c3) are all substances customarily usable in agrochemicals for this purpose. Silicone oils and silicone oil preparations are preferred. Examples are Silcolapse® 426 and 432 from Bluestar Silicones, Silfoam® SRE and SC132 from Wacker, SAF-184® from Silchem, Foam-Clear ArraPro-S® from Basildon Chemical Company Ltd, SAG® 1572 and SAG® 30 from Momentive (dimethylsiloxanes and silicones, CAS No. 63148-62-9). Preferred is SAG® 1572.

[0106] (c4) Suitable antifreeze agents are all substances customarily usable in agricultural chemicals for this purpose. Suitable examples are propylene glycol, ethylene glycol, urea and glycerin.

[0107] (c5) Suitable further formulation auxiliaries (c5) are selected from biocides, antifreezes, colorants, pH regulators, buffers, stabilizers, antioxidants, inert filler substances, humectants, crystal growth inhibitors, micronutrients. Examples of these are:

[0108] Possible preservatives are all substances that are customarily usable in agrochemicals for this purpose.Suitable examples of preservatives are preparations that contain 5-chloro-2-methyl-4-isothiazolin-3-one [CAS-No. 26172-55-4], 2-methyl-4-isothiazolin-3-one [CAS-No. 2682-20-4] or 1,2-benzisothiazol-3(2H)-one [CAS-No. 2634-33-5].Examples that may be mentioned are Preventol® D7 (Lanxess), Kathon® CG / ICP (Dow), Acticide® SPX (Thor GmbH) and Proxel® GXL (Arch Chemicals).

[0109] Possible colorants are all substances which can be customarily used in agrochemicals for this purpose: titanium dioxide, carbon black, zinc oxide, blue pigments, Brilliant Blue FCF, red pigments and Permanent Red FGR may be mentioned by way of example.

[0110] Possible pH regulators and buffers are all substances customarily usable in pesticides for this purpose: citric acid, sulfuric acid, hydrochloric acid, sodium hydroxide, sodium hydrogen phosphate (Na2HPO4), sodium dihydrogen phosphate (NaH2PO4), potassium dihydrogen phosphate (KH2PO4), potassium dihydrogen phosphate (K2HPO4) may be mentioned as examples.

[0111] Suitable stabilizers and antioxidants are all substances which can be customarily used in agrochemicals for this purpose. Butylhydroxytoluene [3,5-di-tert-butyl-4-hydroxytoluene, CAS No. 128-37-0] is preferred.

[0112] These spray solutions are applied in the customary manner, ie for example by spraying, pouring or injection, in particular by spraying and most in particular by spraying by UAV.

[0113] The application rates of the formulations according to the invention can vary within relatively wide limits, depending on the particular pesticidal active substances and their amounts in the formulation.

[0114] By means of the formulations according to the invention it is possible to deliver agrochemically active substances to plants and / or their habitat in a particularly advantageous manner.

[0115] The present invention is further directed to the use of the pesticidal composition according to the invention for applying the pesticidal active compounds contained therein to plants and / or their habitat.

[0116] The formulations of the present invention can be used to treat all plants and plant parts. Here, plants refer to all plants and plant populations, such as desirable and undesirable wild plants or crop plants, including naturally occurring crop plants. Crop plants can be plants that can be obtained by conventional breeding and optimization methods, or by biotechnological and genetic engineering methods, or by a combination of these methods. Such crop plants also include transgenic plants, and also include plant varieties that can be protected by variety ownership and those that cannot. Plant parts refer to all parts and organs above and below ground of the plant, such as shoots, leaves, flowers and roots, an exemplary list of which includes leaves, needles, stems, trunks, flowers, fruiting bodies, fruits and seeds, and also roots, tubers and rhizomes. Plant parts also include harvested material, and also vegetative and generative propagation material.

[0117] In the context of the present invention, it may be emphasized that the present invention is applicable to cereal plants, such as wheat, oats, barley, spelt, triticale and rye, and also to maize, sorghum and millet, rice, sugarcane, soybean, sunflower, potato, cotton, rapeseed, canola, tobacco, sugar beet, fodder beet, asparagus, hops, and also to fruit plants, such as pome fruits, such as apple and pear, stone fruits, such as , peaches, nectarines, cherry trees, plums and apricots, citrus fruits such as oranges, grapefruits, limes, lemons, kumquats, tangerines and unshu mandarins, nuts such as pistachios, almonds, walnuts and pecans, tropical fruits such as mangoes, papayas, pineapples, dates and bananas, and grape vines), and vegetables (e.g. leafy vegetables such as endive, corn salad, Florence fennel, lettuce, cos lettuce, Swiss chard, spinach and salad chicory, cabbages such as cauliflower, broccoli, Chinese cabbage, kale (Brassica oleracea (L.) convar. acephala var. sabellica L.) (curly kale, feathered cabbage), kohlrabi, Brussels sprouts, red cabbage, white cabbage and Savoy cabbage, fruit vegetables such as eggplant, cucumber, capsicum, table pumpkin, tomato, zucchini and sweet corn, root vegetables such as root celery, wild turnip, carrot (including yellow varieties), radish (Raphanus sativus var. niger and var. radicula), beetroot, scorzonera and celery, legumes such as peas and beans, and allium vegetables such as leeks and onions, for which the formulations of the invention show particularly advantageous effects.

[0118] The treatment according to the invention of plants and parts of plants using the formulations of the invention is carried out directly, according to customary treatment methods, for example by dipping, spraying, vaporizing, atomizing, scattering or applying, or by acting on their surroundings, habitat or storage, and, in the case of reproductive organs, especially seeds, further by applying one or more layers of coating.

[0119] The pesticidal active substance comprised exhibits excellent biological activity compared to when applied in the form of the corresponding customary formulations.

[0120] Leaf surface In Tables 1a and 1b, the contact angles of water on the leaf surface are shown for the rough and non-rough cases. [Table 1] [Table 2]

[0121] Examples of non-rough crops and plants are tomato, pepper, potato, carrot, celery, sugar beet, beetroot, spinach, lettuce, legumes, pea, clover, apple, pear, peach, apricot, plum, mango, avocado, olive, citrus fruits, orange, lemon, lime, grape, fig, cucumber, melon, watermelon, strawberry, raspberry, blueberry, sunflower, pumpkin, soybean (>BBCH XX), maize (>BBCH15), cotton.

[0122] Examples of rough crops and plants are garlic, onion, leek, soybean (<BBCH-XX), rye, wheat, barley, rice, sugarcane, pineapple, banana, flax, lily, orchid, maize (<BBCH15), cabbage, Brussels sprouts, broccoli, cauliflower, timothy, rapeseed, tulip and peanut.

[0123] Since soybeans and corn change leaf characteristics throughout their life cycle, the invention makes it possible to adapt the treatment in relation to leaf characteristics, i.e. the formulation according to the invention can be applied at a growth stage when the leaves are less likely to become wet. EXAMPLES

[0124] Highly spreadable ULV formulations for disinfectants The invention is illustrated by the following examples.

[0125] Working Example method Method 1: Preparation of SCs Methods for preparing suspension formulations are known to those skilled in the art and can be prepared by known methods well known to those skilled in the art. A 2% gel of xanthan (c) and biocide (c) in water was prepared with low shear agitation. The active ingredient (a), nonionic and anionic dispersants (c), antifoaming agent (c) and other formulation aids (c) were mixed with water to form a slurry, which was first mixed using a high shear rotor-stator mixer (Ultra-Turrax®) to reduce its particle size D (v, 0.9) to about 50 microns, and then passed through one or more bead mills (Eiger® 250 Mini Motormill) to achieve a particle size D (v, 0.9) typically between 1 and 15 microns. The polyalkylene oxide modified heptamethyltrisiloxane (b) and the xanthan gel prepared above were then added and mixed with low shear agitation until homogeneous. Finally, the pH was adjusted to 7.0 (+ / - 0.2) with acid or base (c).

[0126] Method 2: Preparation of WG Methods for preparing dispersible granule formulations are known to those skilled in the art and may be prepared by known methods well known to those skilled in the art.

[0127] To produce fluidized bed granules, first, a water-based formulation concentrate must be prepared. The active ingredient, safener (a), surfactant (b), dispersant (c), binder (d), antifoam (e), spreader (f) and bulking agent (g) are mixed in water under low shear stirring, and finally pre-milled in a high shear rotor-stator mixer (Ultra-Turrax®) to reduce their particle size D(v, 0.9) to about 50 microns, and then passed through one or more bead mills (KDL, Bachofen, Dynomill, Buhler, Drais, Lehmann) to achieve a particle size D(v, 0.9) typically between 1 and 15 microns.

[0128] This water-based pharmaceutical concentrate is then spray dried in a fluid bed granulation process to form water dispersible granules (WG).

[0129] The particle size is determined according to CIPAC (CIPAC = Collaborative International Pesticides Analytical Council; www.cipac.org) method MT187. The particle size distribution is determined by laser diffraction. A representative amount of the sample is dispersed in degassed water at ambient temperature (self-saturation of the sample), treated with ultrasound (usually for 60 seconds) and then measured with a Malvern Mastersizer series (Malvern Panalytical) instrument. The scattered light is measured at different angles using a multi-element detector and the relevant values ​​are recorded. Using the Fraunhofer model, the proportion of specific size classes is calculated from the scattering data, from which the volume-weighted particle size distribution is calculated. Usually, the d50 or d90 value = active ingredient particle size (50% or 90% of the total volume particles) is obtained. By mean particle size is meant the d50 value.

[0130] Method 3: Methods for preparing EC formulations are known to those skilled in the art and can be prepared by known methods well known to those skilled in the art.

[0131] The formulations shown in the table below were obtained by dissolving or mixing the active ingredient, safener (a), surfactant (b) and spreader (d) in organic solvent (c) in a standard apparatus, optionally facilitating dissolution or mixing by slightly increasing the temperature (not exceeding 60°C).

[0132] Method 4: Coverage area Greenhouse plants at the developmental stages shown in Tables 1a and 1b were used for these experiments. Immediately prior to the spraying experiments, a single leaf was cut, placed in a Petri dish, and taped at both ends at 0° (horizontal) or 60° (allowing 50% of the leaf area to be sprayed). The leaf was transported with care to avoid damaging the wax surface. These horizontally oriented leaves were either (a) placed in a spray chamber where the spray solution was applied via a hydraulic nozzle, or (b) a 4 μL droplet of the spray solution was pipetted onto the top without touching the leaf surface.

[0133] A small amount of UV dye was added to the spray solution to visualize the spray deposit under UV light. The concentration of the dye was chosen so as not to affect the surface properties of the spray solution and not to contribute to spreading itself. Tinopal OB as a colloidal suspension was used for all flowable and solid formulations such as WG, SC, OD and SE. For formulations with dissolved active ingredient such as EC, EW and SL, Tinopal CBS-X or Blankophor SOL was used. Tinopal CBS-X was dissolved in the water phase and Blankophor SOL was dissolved in the oil phase.

[0134] After the spray solution had evaporated, the leaves were placed in a Camag, Reprostar 3UV chamber where pictures of the spray deposits were taken under visible light and 366 nm UV light. A Canon EOS700D digital camera was attached to the UV chamber and used to capture the leaf images. The pictures taken under visible light were used to subtract the leaf shape from the background. ImageJ software was used to calculate (a) the coverage area of ​​the applied spray (%) for the sprayed leaves or (b) the spreading area of ​​the pipette-applied droplets (mm 2 ) was calculated.

[0135] Method 5: Fungicide greenhouse testing Seeds were placed in "peat soil T" in plastic pots, covered with soil and cultivated in a greenhouse under optimal growing conditions. Test plants were treated at the 1-2 leaf stage 2-3 weeks after sowing. Test fungicide formulations were prepared at different concentrations and sprayed on the plant surface using different spray volumes (200 L / ha for standard conventional spray volume and 10 L / ha for ultra-low volume (ULV) spray volume). The nozzle type used for all applications was TeeJet TP 8003E, used at 0.7-1.5 bar and at a height of 500-600 mm from plant level. Grains were placed at a 45° angle, as this best reflects field application conditions for cereals. ULV spray volumes were achieved at 30 Hz, 8%-100% aperture using a pulse width modulation (PWM) system connected to the nozzle and the track sprayer.

[0136] For protection treatments, test plants were inoculated with the respective disease one day after spray application and then kept in a greenhouse under optimal growing conditions for 1-2 weeks. The activity of the fungicide formulations was then visually evaluated.

[0137] In the treatment conditions, plants were first inoculated with the disease and then treated with the fungicide formulation 2 days later. Visual assessment of disease was performed 5 days after application of the formulation.

[0138] Methods of inoculation are well known to those skilled in the art.

[0139] The table below shows the diseases and crops used in the tests. [Table 3]

[0140] Leaf surface In Tables 1a and 1b the contact angles of water on textured and non-textured leaf surfaces are given. [Table 4] [Table 5]

[0141] Examples of non-grainy crops and plants include tomatoes, peppers, potatoes, carrots, celery, sugar beets, beetroot, spinach, lettuce, beans, peas, clover, apples, pears, peaches, apricots, plums, mangoes, avocados, olives, citrus fruits, oranges, lemons, limes, grapes, figs, cucumbers, melons, watermelons, strawberries, raspberries, blueberries, sunflowers, pumpkins, soybeans (≧ GS16 (BBCH16)), maize (≧ GS15 (BBCH15), cotton.

[0142] Examples of crops and plants that are rough include garlic, onions, leeks, soybeans (≦GS16(BBCH16)), oats, wheat, barley, rice, sugarcane, pineapple, bananas, linseed, lilies, orchids, maize (≦GS15(BBCH15)), cabbage, Brussels sprouts, broccoli, cauliflower, rye, rapeseed, tulips and peanuts.

[0143] material [Table 6] [Table 7]

[0144] Example 1 Isoflucipram 50SC [Table 8]

[0145] The preparation method used was similar to Method 1.

[0146] result greenhouse Efficacy Data [Table 9]

[0147] The above results show that formulation 2, illustrating the present invention, exhibits higher efficacy at a spray volume of 10 L / ha than at 200 L / ha. Additionally, formulation 2 exhibits higher efficacy than control formulation 1, which does not contain an organosilicone superspreader, at both spray volumes of 200 L / ha and 10 L / ha. [Table 10]

[0148] The above results show that formulation 2, illustrating the present invention, exhibits higher efficacy at a spray volume of 10 L / ha than at 200 L / ha. Additionally, formulation 2 exhibits higher efficacy than control formulation 1, which does not contain an organosilicone superspreader, at both spray volumes of 200 L / ha and 10 L / ha.

[0149] Example 3 Isoflucipram 50SC [Table 11]

[0150] The preparation method used was similar to Method 1.

[0151] Spreading - Leaf surface pipette spreading test The size of the leaf deposits was measured (2 μL) according to method 4(b). [Table 12]

[0152] The results above show that formulation 6 illustrating the present invention exhibits significantly greater deposit size at a spray volume of 10 L / ha than at 200 L / ha, and further shows that it exhibits significantly greater deposit size compared to control formulation 5.

[0153] Example 4: Fungicide TFS 100SC [Table 13]

[0154] The preparation method used was similar to Method 1.

[0155] result Foliar spray coverage test Leaf cover was measured according to method 4. [Table 14]

[0156] The results show that on non-textured leaves the coverage is generally greater at higher water application rates. [Table 15]

[0157] The results above show that formulation 8 illustrating the present invention provides greater coverage at a spray volume of 10 L / ha than at 200 L / ha and 500 L / ha, and also provides greater coverage compared to control formulation 7.

[0158] Example 6: PTZ 20SC [Table 16]

[0159] The preparation method used was similar to Method 1.

[0160] greenhouse [Table 17]

[0161] The above results show that formulation 16, illustrating the present invention, exhibits greater efficacy at a spray volume of 10 L / ha than at 200 L / ha. Additionally, formulation 16 exhibits greater efficacy than control formulation 15, which does not contain an organosilicone superspreader, at both spray volumes of 200 L / ha and 10 L / ha. [Table 18]

[0162] The above results show that formulation 16, illustrating the present invention, exhibits greater efficacy at a spray volume of 10 L / ha than at 200 L / ha. Additionally, formulation 16 exhibits greater efficacy than control formulation 15, which does not contain an organosilicone superspreader, at both spray volumes of 200 L / ha and 10 L / ha. [Table 19]

[0163] The results above show that formulation 16, illustrating the present invention, shows greater efficacy at a spray volume of 10 L / ha than at 200 L / ha. [Table 20]

[0164] The above results show that formulation 16, illustrating the present invention, exhibits greater efficacy at a spray volume of 10 L / ha than at 200 L / ha. Additionally, formulation 16 exhibits greater efficacy than the control formulation that does not contain an organosilicone superspreader at both spray volumes of 200 L / ha and 10 L / ha. [Table 21]

[0165] A concentration of organosilicone super spreader at a spray volume of 10 L / ha provides better performance than 200 L / ha.

[0166] Example 7: TBZ 20SC [Table 22]

[0167] The preparation method used was similar to Method 1.

[0168] greenhouse [Table 23]

[0169] The above results show that formulation 18, illustrating the present invention, exhibits greater efficacy at a spray volume of 10 L / ha than at 200 L / ha. Additionally, formulation 18 exhibits greater efficacy than the control formulation that does not contain an organosilicone superspreader at both spray volumes of 200 L / ha and 10 L / ha. [Table 24]

[0170] The above results show that formulation 18, illustrating the present invention, exhibits greater efficacy at a spray volume of 10 L / ha than at 200 L / ha. Additionally, formulation 18 exhibits greater efficacy than control formulation 17, which does not contain an organosilicone superspreader, at both spray volumes of 200 L / ha and 10 L / ha.

[0171] Example 8: Bixafen 20SC [Table 25]

[0172] The preparation method used was similar to Method 1.

[0173] greenhouse [Table 26]

[0174] The above results show that formulation 20 illustrating the present invention exhibits greater efficacy than control formulation 19, which does not contain an organosilicone superspreader, at both 200 L / ha and 10 L / ha application volumes. [Table 27]

[0175] The above results show that formulation 20 illustrating the present invention exhibits greater efficacy than control formulation 19, which does not contain an organosilicone superspreader, at both 200 L / ha and 10 L / ha application volumes. [Table 28]

[0176] The above results show that formulation 20, illustrating the present invention, exhibits greater efficacy at a spray volume of 10 L / ha than at 200 L / ha. Additionally, formulation 20 exhibits greater efficacy than control formulation 19, which does not contain an organosilicone superspreader, at both spray volumes of 200 L / ha and 10 L / ha.

[0177] Example 9: Fluoxapiproline 5SC [Table 29]

[0178] The preparation method used was similar to Method 1.

[0179] greenhouse [Table 30]

[0180] The above results show that formulation 22, illustrating the present invention, exhibits greater efficacy than control formulation 21, which does not contain an organosilicone superspreader, at both 200 L / ha and 10 L / ha application volumes.

[0181] Example 10: Fluoxapiproline 50SC [Table 31]

[0182] The preparation method used was similar to Method 1.

[0183] Pipette spreading test on leaf surface Leaf deposit size was measured according to method 4(b) (2 μL deposit). [Table 32]

[0184] The results above show that formulation 24, illustrating the present invention, exhibits a larger deposit size at a spray volume of 10 L / ha than at 200 L / ha, and also exhibits a larger deposit size compared to the control formulation 23. The effect is observed on both textured and non-textured leaf surfaces.

[0185] Example 11 Impilfluxam 25SC [Table 33]

[0186] The preparation method used was similar to Method 1.

[0187] Pipette spreading test on leaf surface Leaf deposit size was measured according to method 4(b) (2 μL deposit). [Table 34]

[0188] The results above show that formulation 26 illustrating the present invention exhibits larger deposit size at a spray rate of 10 L / ha than at 200 L / ha and 800 L / ha, and further shows that formulation 26 exhibits larger deposit size compared to control formulation 25 at all spray rates.

[0189] Example 12: Fluopicolide 100SC [Table 35]

[0190] The preparation method used was similar to Method 1.

[0191] Pipette spreading test on leaf surface Leaf deposit size was measured according to method 4(b) (2 μL deposit). [Table 36]

[0192] The results above show that formulation 28 illustrating the present invention exhibits significantly greater deposit size at a spray volume of 10 L / ha than at 200 L / ha, and also exhibits significantly greater deposit size compared to control formulation 27. The effect is greater on rough leaf surfaces.

[0193] Example 13: Fluopyram 200SC [Table 37]

[0194] The preparation method used was similar to Method 1.

[0195] Pipette spreading test on leaf surface Leaf deposit size was measured according to method 4(b) (2 μL deposit). [Table 38]

[0196] The results above show that formulation 30 illustrating the present invention exhibits significantly greater deposit size at a spray volume of 10 L / ha than at 200 L / ha, and also exhibits significantly greater deposit size compared to control formulation 29. The effect is greater on rough leaf surfaces.

[0197] Example 15 PHC 625SL [Table 39]

[0198] The preparation method used was similar to Method 1.

[0199] Pipette spreading test on leaf surface Leaf encrustation size was measured according to method 4. [Table 40]

[0200] The results show that on non-textured leaves the coverage was similar for both water rates. [Table 41]

[0201] The results above show that formulation 36 illustrating the present invention exhibits greater coverage and greater deposit size at a spray volume of 10 L / ha than at 200 L / ha, and also exhibits greater coverage and greater deposit size compared to control formulation 35.

Claims

1. 1. A pesticide formulation comprising: (a) one or more active ingredients selected from the group of agriculturally applied fungicides; (b) one or more organosilicone surfactants; (c) one or more additional formulation aids; and (d) Water to volume; where (a) is present in an amount of 5 to 500 g / L; (b) is present at 5 to 250 g / L; (c) comprises at least one nonionic surfactant and / or ionic surfactant (c1); and may contain one rheology modifier (c2), one antifoaming agent (c3), one antifreeze agent (c4), and one other formulation auxiliary (c5); Where: (c1) is present at 4 to 250 g / L; (c2) is present at 0 to 60 g / L; (c3) is present at 0 to 30 g / L; (c4) is present at 0 to 200 g / L; and (c5) is present at 0 to 200 g / L; and The formulation is diluted and applied by spraying at a spray volume of 1 to 20 L / ha; The pesticide formulation.

2. 2. The pesticide formulation of claim 1, wherein (b) is a polyalkylene oxide-modified heptamethyltrisiloxane.

3. 3. The pesticide formulation of claim 1 or 2, wherein (a) is present in an amount of 10 to 300 g / L.

4. The pesticide formulation according to any one of claims 1 to 3, wherein the fungicide is selected from the group consisting of trifloxystrobin, prothioconazole, tebuconazole, fluopyram, bixafen, isoflucipram, impirfluxam, fluoxapiproline, fluopicolide, isotianil, spiroxamine and propamocarb.

5. 5. The pesticide formulation according to any one of claims 1 to 4, wherein (b) is present at 8 to 120 g / L.

6. 6. The pesticide formulation according to any one of claims 1 to 5, wherein (c) comprises at least one nonionic and / or ionic surfactant (c1), one rheology modifier (c2), one antifoaming substance (c3), one antifreeze agent (c4), and one further formulation auxiliary (c5).

7. (c1) is present at 8-120 g / L; (c2) is present at 1 to 20 g / L; (c3) is present at 0.5 to 20 g / L; (c4) is present at 5 to 150 g / L; and (c5) is present at 0.1 to 120 g / L; The pesticide formulation according to claim 6.

8. The pesticide formulation according to any one of claims 1 to 7, wherein the formulation is applied in a spray volume of 5 to 15 L / ha.

9. A method of applying the pesticide formulation according to any one of claims 1 to 7 to a crop, wherein the formulation is applied in a spray volume of 1 to 20 L / ha.

10. The method according to claim 9, wherein the application rate of (a) to the crop is from 2 to 150 g / ha.

11. The method of claim 9 or 10, wherein the organosilicone surfactant (b) is applied at from 10 g / ha to 100 g / ha.

12. 12. The method according to any one of claims 9 to 11, wherein the formulation is applied to a crop having a rough leaf surface, Here, the rough leaf surface is The method according to any one of claims 1 to 5, wherein the surface of the leaves of a crop is selected from the group consisting of garlic, onion, leek, soybean (BBCH 16 or less), oat, wheat, barley, rice, sugarcane, pineapple, banana, flaxseed, lily, orchid, corn (BBCH 15 or less), cabbage, Brussels sprouts, broccoli, cauliflower, rye, rapeseed, tulip and peanut.

13. 8. Use of the pesticide formulation according to any one of claims 1 to 7 in the application of pesticide compounds to control harmful fungi, wherein the formulation is applied by unmanned aerial vehicle (UAV), unmanned guided vehicle (UGV) or pulse width modulation (PWM).

14. A method for controlling harmful fungi, comprising contacting harmful fungi, their habitat, their hosts, including plants and seeds, as well as the soil, areas and environments in which they grow or may grow, as well as material, plants, seeds, soil, surfaces or spaces which are to be protected from attack or infestation by fungi harmful to plants, with an effective amount of a formulation according to any one of claims 1 to 7, The method, wherein the formulation is administered by unmanned aerial vehicle (UAV), unmanned guided vehicle (UGV) or pulse width modulation (PWM).

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