Mixing device, heat exchange equipment, and related mixing method for promoting homogeneous distribution of biphasic mixtures

Abstract

The present invention relates to a heat exchanger (1) having plates (2), a source of a first phase (61) of a first fluid (F1) fluidly connected to at least one first collector (30) of the heat exchanger (1), a source of a second phase (62) of the first fluid (F1) fluidly connected to at least one second collector (52) of the heat exchanger (1), and a mixing device (3) for distributing a mixture of the first phase (61) and the second phase (62) of the first fluid (F1) generally in the longitudinal direction (z) of at least one passage (10) of the heat exchanger (1), the mixing device (3) comprising at least one transverse channel (31) configured for flow of the first phase (61) of the first fluid (F1) from at least one first inlet (311). The present invention relates to a heat exchange assembly comprising a mixer (3), a series of longitudinal channels (32) extending in a longitudinal direction (z) and each configured for the flow of a second phase (62) of a first fluid (F1) from a second inlet (321) to a second outlet (322), the series of longitudinal channels (32) being continuous with one another in a transverse direction (y) perpendicular to the longitudinal direction (z), and at least one opening (34) fluidly connecting the transverse channel (31) to at least one longitudinal channel (32), such that the mixer (3) is configured to distribute the mixture of the first phase (61) and the second phase (62) through the second outlet (322) of at least one longitudinal channel (32). According to the present invention, at least one longitudinal channel (32) is divided in the longitudinal direction (z) into at least one upstream portion (323) and one downstream portion (324), each having a length (L3, L4) measured in the longitudinal direction (z) and a width (D3, Dy) measured in the transverse direction (y), the downstream portion (324) being located between the upstream portion (323) and the second outlet (322), and the downstream portion (324) having, at any point along its length (L4), a width (Dy) greater than the width (D3) of the upstream portion (323).

Description

[Technical field]

[0001] The present invention relates to a mixing device for distributing a mixture of two liquid / gas phases more homogeneously in at least one passage of a heat exchanger, and to a heat exchange installation comprising such a mixing device.

[0002] In particular, the present invention is applicable to heat exchangers which vaporize at least one stream of a gas-liquid mixture, in particular a gas-liquid mixture having multiple constituent components, e.g. a stream of a mixture comprising hydrocarbons, by exchanging heat with at least one other fluid, e.g. natural gas which is cooled or even at least partially liquefied, or liquefied natural gas which is sub-cooled. [Background technology]

[0003] Several methods are known for liquefying a natural gas stream to obtain liquefied natural gas (LNG), among other methods using one or more fluid refrigeration cycles with a two-phase refrigerant, i.e. in a liquid / gas mixed state. Usually, a cooling stream, generally a mixture with several component elements, such as a mixture containing hydrocarbons, is compressed in a compressor and then introduced into an exchanger or a series of exchangers where it is fully liquefied and subcooled to the lowest temperature of the method reached by the fluid to be cooled, generally a liquefied natural gas stream. At the coldest outlet of the exchanger, the cooling stream is expanded by forming a first phase and a second phase. These two phases are separated by a phase separator and then reintroduced into the exchanger and remixed before being reintroduced into the exchanger. The cooling stream introduced into the exchanger in a two-phase state is vaporized therein against the hydrocarbon stream to be liquefied and against the natural gas. Document WO-A-2017 / 081374 describes one of these known methods.

[0004] The use of brazed plate and fin aluminium exchangers makes it possible to provide very compact devices offering a large exchange surface, thereby improving the energy performance of the process and taking place in a limited volume.

[0005] These exchangers comprise a stack of plates extending in two dimensions, length and width, thus forming a stack of sets of passages positioned on top of each other, some intended to circulate a heat transfer fluid, e.g. a hydrocarbon stream to be liquefied, and the rest intended to circulate a refrigerant, e.g. a biphasic cooling stream to be vaporized.

[0006] Heat exchange structures, such as heat exchange corrugations, are generally placed in the passages of the exchanger. These structures comprise fins that extend between the plates of the exchanger and can increase the heat exchange surface area of ​​the exchanger. They also act as spacers and contribute to the mechanical strength of the passages.

[0007] In exchangers implementing cooling flows of a biphasic nature, some problems arise, especially when their vaporization occurs in an upward vertical flow.

[0008] Indeed, to ensure that an exchanger operates correctly, i.e. in particular for exchangers implementing gas-liquid mixtures, and in particular to maximize the use of its exchange surface, the ratio of liquid and gas phases must be the same in all passes and uniform within the same pass.

[0009] The dimensioning of the exchanger is calculated assuming a uniform distribution of the phases and therefore a single temperature at the end of vaporization of the liquid phase per pass, equal to the dew point of the mixture.

[0010] In particular for mixtures having multiple constituent components, the temperature at the end of vaporization will depend on the ratio of liquid and vapor phases in the passageway, since the two phases will not have the same composition.

[0011] If the distribution of the two phases is not uniform, the temperature profile of the first fluid will thereby vary from pass to pass and / or within the same pass. This uneven distribution can cause one or more fluids in exchange with the two-phase mixture to have an exchanger outlet temperature that is higher than the expected temperature, which in turn results in poor performance of the heat exchanger.

[0012] One solution to distribute the liquid and gas phases of the mixture as evenly as possible involves introducing them separately into the exchanger and then mixing them together only when they are inside the exchanger.

[0013] Document FR-A-2563620 or WO-A-2018 / 172644 describes such an exchanger in which grooved bars are inserted into a series of passages to guide the two-phase mixture. This mixing device comprises a series of separate channels or grooves for the flow of the liquid phase of the refrigerant and another series of separate channels for the flow of the gas phase of the refrigerant. One series of channels is fluidly connected to the other series of channels via openings so that the gas-liquid mixture, i.e. the two-phase flow, is distributed from the mixing device towards the heat exchange area. Each refrigerant passage of the exchanger is provided with such a device.

[0014] One problem that arises with mixing devices of this type relates to the uneven distribution of the gas-liquid mixture across the width of the exchanger passages.

[0015] In fact, the two-phase mixture is distributed at the outlet of the channels where it leaves the passage. The channels are arranged at a certain distance from each other so that the gas-liquid mixture is introduced separately into the exchange zone over the width of the passage. Since the fluids flow in the general direction of flow in the exchanger, a distribution can occur in a direction perpendicular to the general direction of flow, especially with exchange corrugations such as perforated corrugations or sawtooth corrugations, which are commonly used in this type of exchanger. Thus, the "sawtooth" type corrugations tend to bend part of the fluid away from its flow direction, while the perforated corrugations fluidly connect the channels formed by the corrugations.

[0016] However, homogenization of the fluid distribution across the width of the exchanger is only achieved after the mixture has traveled a certain distance after leaving the mixer. Over this distance, the fluid supplies the exchange zone with an uneven mass flow rate, depending on the considered position in the width of the exchanger, and some channels of the exchange corrugation may have limited or even no supply. The performance of the exchanger is deteriorated. Furthermore, such distribution by lateral deflection of the fluid is not possible with straight non-perforated corrugations.

[0017] Exchangers that function under the influence of low temperature deviations between the heat transfer and refrigerant fluids are even more susceptible to this severe distribution phenomenon. Moreover, in the case of refrigerant mixtures having several component elements, the phenomenon of uneven distribution is intensified.

[0018] None of the existing solutions is satisfactory. Thus, the arrangement of free spaces at the mixer outlet creates problems with the mechanical strength of the exchanger and can lead to retention of the first phase in this zone. Increasing the number of successive channels in the width of the exchanger leads to a decrease in the flow rate of the first phase through each opening of each channel, which is detrimental to a proper distribution of the biphasic mixture at the mixer outlet. Finally, a "hardway" type corrugated arrangement at the mixer outlet or an arrangement of mixers with more complex geometries increases the pressure losses which deteriorate the performance of the process. Summary of the Invention [Problem to be solved by the invention]

[0019] The object of the present invention is to address all or part of the above problems, in particular by proposing a mixing device that provides a more homogeneous distribution of the biphasic mixture in the width of the heat exchanger passages, while limiting the pressure losses that the biphasic mixture may undergo at the outlet of the mixing device. [Means for solving the problem]

[0020] The solution according to the invention therefore comprises a mixing device for distributing a mixture of a first phase and a second phase of a first fluid generally in the longitudinal direction of at least one passage of a heat exchanger, said mixing device comprising: - at least one lateral channel configured for a first phase of a first fluid to flow from at least one first inlet; - a series of longitudinal channels extending in a longitudinal direction and each configured for a second phase of the first fluid to flow from a second inlet to a second outlet, said longitudinal channels being contiguous with one another in a lateral direction perpendicular to the longitudinal direction; at least one opening fluidly connecting the lateral channel to the at least one longitudinal channel, such that a mixing device is configured to distribute a mixture of the first phase and the second phase through a second outlet of the at least one longitudinal channel; wherein the at least one longitudinal channel of the mixing device is divided longitudinally into an upstream portion and a downstream portion each having a length measured longitudinally and a width measured transversely, the downstream portion being disposed between the upstream portion and the second outlet, the downstream portion having a width at any point along its length that is greater than the width of the upstream portion.

[0021] As applicable, the invention may comprise one or more of the following features. the downstream portion has an increasing width, preferably a continuously increasing width, over its length towards the second outlet; - the downstream portion has a minimum width and a maximum width and has a ratio D M / D m is 1.1 or more, preferably 1.8 or more and / or 4 or less. all or part of the downstream section has, as a longitudinal section in a plane parallel to the longitudinal and transverse directions, an external profile in the form of an isosceles trapezoid. all or part of the downstream portion has, as a longitudinal section in a plane parallel to the longitudinal and transverse directions, a curvilinear external profile. - the downstream part emerges at the downstream side of the mixing device, the external profile forming an angle of 5 to 85°, measured between the tangent of said external profile at its intersection with the downstream side and the axis of symmetry of the longitudinal channel. the upstream part of the longitudinal channel is connected to the downstream part at one end, said at least one opening emerging in said longitudinal channel in the upstream part at a distance from the end, preferably said distance being at least 4% of the length of the upstream part, preferably being between 7 and 90% of the length of the upstream part. the at least one opening is arranged such that mixing of the first and second phase occurs upstream of the downstream portion when the first phase flows from the first inlet of the transverse channel and the second phase flows from the second inlet of the longitudinal channel. The opening or openings of the mixing device all occur in the upstream part of the longitudinal channel. each longitudinal channel of the series of longitudinal channels comprises at least one opening which appears in its upstream part, the position of the at least one opening in the longitudinal direction differing between the longitudinal channels; the length of the upstream portion and the length of the downstream portion are such that the ratio L3 / L4 is between 1 and 15, preferably between 3 and 12; all or part of the upstream portion has, as a longitudinal section in a plane parallel to the longitudinal and transverse directions, a straight external profile having a constant width, preferably equal to the minimum width of the downstream portion. the downstream portion has an increasing depth towards the second outlet, measured in a direction called the stack direction, perpendicular to the longitudinal direction and perpendicular to the transverse direction. the longitudinal channel is provided with at least one obstacle arranged to further divide the downstream portion into a plurality of intermediate channels emerging at the second outlet, said intermediate channels being preferably arranged symmetrically relative to an axis of symmetry of the longitudinal channel. at the second outlet, the total surface of the at least one obstacle measured in a transverse cross-section perpendicular to the longitudinal direction is between 20 and 80%, preferably between 30 and 70%, of the total fluid passage cross-sectional area of ​​the downstream portion measured in said transverse cross-section. - the width, measured laterally, of the at least one obstacle increases towards the second outlet, and the at least one obstacle preferably has, along a longitudinal cross section, a curvilinear external profile. the longitudinal channels further comprise at least one balancing channel fluidly connecting the intermediate channels;

[0022] Furthermore, the present invention relates to a heat exchanger comprising a plurality of plates arranged parallel to one another and in a longitudinal direction, said plates being stacked in a spaced apart manner so as to together define at least one first set of passages configured for a first fluid to flow generally in a longitudinal direction and at least one second set of passages configured for a flow of a second fluid in a heat exchange relationship with the first fluid, at least one passage of the first set comprising a mixing device according to the present invention.

[0023] Furthermore, the present invention relates to a method for producing a - a heat exchanger comprising a plurality of plates arranged parallel to one another and in a longitudinal direction, said plates being stacked in a spaced manner such that together they define at least one first set of passages configured for a first fluid to flow generally in a longitudinal direction, and at least one second set of passages configured for a flow of a second fluid in heat exchange relationship with the first fluid; - a source of a first phase of a first fluid fluidly connected to at least one first manifold of the heat exchanger; - a source of a second phase of the first fluid fluidly connected to at least one second manifold of the heat exchanger; a mixing device according to the invention, said mixing device being arranged in at least one passage of a first series of passages and configured to distribute a first fluid formed by a mixture of a first phase and a second phase to said passages of the first series of passages, a first inlet of a transverse channel being in fluid communication with said first manifold and a second inlet being in fluid communication with a second manifold, the first phase being a liquid phase and the second phase being a gas phase; The present invention relates to a heat exchanger equipped with:

[0024] Preferably, the first phase is a liquid phase and the second phase is a gas phase.

[0025] According to another aspect, the present invention relates to a method for mixing a first phase and a second phase of a first fluid in a mixing device according to the invention, said method comprising the steps of: i) introducing a first phase of a first fluid through at least one first inlet of a lateral channel; ii) introducing a second phase of the first fluid through a second inlet of each longitudinal channel, the second phase flowing longitudinally in each longitudinal channel to a second outlet of said longitudinal channel; iii) flowing at least a portion of the first phase from the transverse channel towards the longitudinal channel through the opening so as to mix the first phase with the second phase in the longitudinal channel; iv) distributing the mixture of the first and second phases through a second outlet of each longitudinal channel; Includes.

[0026] Preferably, the first phase is mixed with the second phase upstream of the downstream section.

[0027] Furthermore, the present invention also relates to a method for liquefying a hydrocarbon stream, such as natural gas, as a second fluid, by heat exchange with at least one biphasic cooling stream as a first fluid, said method implementing the mixing method according to the invention, a) introducing a hydrocarbon stream into a second set of passages of a heat exchanger; b) introducing a cooling flow into a third set of passages of the heat exchanger; c) discharging the cooling stream from the heat exchanger and expanding the cooling stream to at least one pressure level to generate at least one biphasic cooling stream; d) separating at least a portion of the biphasic cooling stream obtained in step c) into a second phase and a first phase; e) disposing a mixing device in at least one passage of the first set of passages of the heat exchanger; f) introducing at least a portion of the second phase and at least a portion of the first phase into a mixer so as to obtain a first fluid formed by a mixture of the first phase and the second phase at the outlet of the mixer; g) vaporizing at least a portion of the first fluid obtained in step f) in the passage by heat exchange with at least a hydrocarbon stream so as to obtain, at the outlet of the exchanger, a cooled and / or at least partially liquefied hydrocarbon stream; Includes.

[0028] The term "natural gas" refers to any composition containing hydrocarbons, including at least methane. It also includes "raw" compositions (before any treatment or cleaning), as well as any compositions that have been partially, substantially, or completely processed to reduce and / or remove one or more compounds, including, but not limited to, sulfur, carbon dioxide, water, mercury, and certain heavy aromatic hydrocarbons.

[0029] The invention will now be better understood from the following description, given purely as a non-limiting example and made with reference to the accompanying drawings, in which: [Brief description of the drawings]

[0030] [Figure 1] 1 illustrates diagrammatically a heat exchange installation according to one embodiment of the invention; [Diagram 2] FIG. 1 is a three-dimensional schematic diagram of a mixing device according to one embodiment of the present invention. [Diagram 3]FIG. 2 is a schematic cross-sectional view of a first mixing device according to one embodiment of the invention, taken in a plane perpendicular to the plates of the exchanger. [Figure 4] FIG. 2 is a schematic longitudinal section of a mixing device according to one embodiment of the invention, taken in a plane parallel to the longitudinal direction z and the transverse direction y. [Diagram 5] FIG. 2 is a schematic longitudinal section, in a plane parallel to the longitudinal direction z and the transverse direction y, of a mixing device according to another embodiment of the invention. [Figure 6] FIG. 2 is a schematic longitudinal section, in a plane parallel to the longitudinal direction z and the transverse direction y, of a mixing device according to another embodiment of the invention. [Figure 7] FIG. 2 is a schematic longitudinal section, in a plane parallel to the longitudinal direction z and the transverse direction y, of a mixing device according to another embodiment of the invention. [Figure 8] FIG. 2 is a schematic longitudinal section, in a plane parallel to the longitudinal direction z and the transverse direction y, of a mixing device according to another embodiment of the invention. [Figure 9] FIG. 2 is a schematic longitudinal section, in a plane parallel to the longitudinal direction z and the transverse direction y, of a mixing device according to another embodiment of the invention. [Figure 10] 1 illustrates a mixer and exchanger configuration according to the present invention used to perform fluid flow simulations. [Figure 11] 1 shows the results of a fluid flow simulation through a mixer constructed according to the prior art and through a mixer according to one embodiment of the present invention. [Figure 12] 1 illustrates generally a method for liquefying a hydrocarbon stream according to one embodiment of the present invention; [Figure 13] 2 illustrates generally a method for liquefying a hydrocarbon stream according to another embodiment of the present invention; DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0031] 1 is a cross-sectional view of a heat exchanger 1 equipped with a mixing device 3 according to the invention. The exchanger 1 is preferably of the type having brazed plates and fins. It comprises a stack of plates 2 (not shown) extending in two dimensions parallel to a plane defined by a longitudinal direction z and a transverse direction y. The plates 2 are arranged parallel and one above the other with a space between them, thus forming a stack of passages for the flow of fluids in indirect heat exchange relationship through said plates.

[0032] Preferably, each passage has a parallelepiped and flat shape, the gap between two successive plates being small compared to the length, measured in the longitudinal direction z, and the width, measured in the transverse direction y, of each passage.

[0033] The exchanger 1 may comprise more than 20, or even more than 100, plates which together define a first set 10 of passages (a single passage is shown in FIG. 1) for conducting at least one first fluid F1 and a second set 20 of passages (not shown in FIG. 1) for conducting at least one second fluid F2, the flow of said fluids generally occurring in the direction z. The passages 10 may be arranged, in whole or in part, alternating and / or adjacent to all or in part of the passages 20. The exchanger 1 may comprise a third or even more sets of passages for the flow of one or more additional fluids. These sets of passages are stacked on top of each other to form a stack of passages.

[0034] Sealing of the passages 10, 20 along the edges of the plate 2 is generally provided by lateral and longitudinal sealing strips 4 attached to the plate 2. The lateral sealing strips 4 do not completely seal the passages 10, 20 but advantageously leave fluid inlet and outlet openings located at diagonally opposed corners of the passages.

[0035] The openings of the first set of passages 10 are arranged to coincide one above the other in the stacking direction x of the passages, which is perpendicular to the directions y and z, while the openings of the second set of passages 20 are arranged in the other corner of the exchanger, as indicated in FIG. 1 by the arrow F2, with the inlet and outlet for the second fluid F2 located at the top left and bottom right, respectively. The openings arranged one above the other are joined in semi-tubular manifolds 40, 45, 52, 55, respectively, through which the fluids are distributed to and discharged from the passages 10, 20.

[0036] It should be noted that configurations for the introduction and discharge of fluids other than that shown in Figure 1 can be used, and thus the passage openings can be located at other positions in the width of the exchanger, in particular in the center of the width of the exchanger, and / or at other positions in the length of the exchanger.

[0037] In the illustration of FIG. 1, semi-tubular manifolds 52 and 45 are used to introduce fluids into the exchanger 1 and semi-tubular manifolds 40 , 55 are used to discharge these fluids from the exchanger 1 .

[0038] In this alternative embodiment, the manifold supplying one of the fluids and the manifold discharging the other fluid are located at the same end of the exchanger, so that the fluids F1, F2 flow countercurrently through the exchanger 1.

[0039] According to another alternative embodiment, the first and second fluids can also circulate in parallel, so that the means for supplying one of the fluids and the means for discharging the other fluid are located at opposite ends of the exchanger 1.

[0040] Preferably, the direction z is oriented vertically when the exchanger 1 is in operation. The first fluid F1 generally flows vertically and upwards. Other flow directions and paths of the fluids F1, F2 are obviously conceivable without departing from the scope of the invention.

[0041] It should be noted that within the scope of the present invention, one or more second fluids F2 having different properties may flow within the second set of passages 20.

[0042] Preferably, the first fluid F1 is a refrigerant and the second fluid F2 is a heat transfer fluid.

[0043] The exchanger advantageously comprises distribution corrugations 51, 54 in the form of corrugated sheets extending from the inlet and outlet openings and arranged between two successive plates 2. The distribution corrugations 51, 54 ensure uniform distribution and recovery of the fluid over the entire width of the passages 10, 20.

[0044] Furthermore, the passages 10, 20 advantageously comprise heat exchange structures arranged between the plates 2. The purpose of these structures is to increase the heat exchange surface of the exchanger and to increase the exchange coefficient between the fluids by making the flow more turbulent. In fact, the heat exchange structures are in contact with the fluid circulating in the passages and transfer the heat flow by conduction to the adjacent plate 2, which can be attached by brazing to the adjacent plate 2, thereby increasing the mechanical strength of the exchanger.

[0045] The heat exchange structures also act as spacers between the plates 2 to avoid any deformation of the plates during the installation of pressurized fluids, especially when assembling the exchanger by brazing. They also provide guidance for the flow of fluids in the passages of the exchanger.

[0046] Preferably, these structures comprise heat exchange corrugations 11 which advantageously extend parallel to the plate 2 over the width and length of the passages 10, 20 in the extension of the distribution corrugations over the length of the passage. The exchanger passages 10, 20 thus have a major part of their length covered by a heat exchange structure, forming the heat exchange section itself, said major part being delimited by a distribution section covered by distribution corrugations 51, 54.

[0047] FIG. 1 shows a first set of passages 10 configured for the flow of a first fluid F1 in the form of a two-phase mixture, also called a biphasic mixture. The first set comprises a plurality of such passages 10 stacked one above the other. The first fluid F1 is separated in a separator device 6 into a first phase 61 and a second phase 62, which are introduced separately into the exchanger 1 by separate first and second manifolds 30 and 52. The separator 6 then forms a source of the first and second phases. The term "source" of a fluid means any means adapted to supply a fluid to the channels of the mixing device.

[0048] Preferably, the first phase 61 is a liquid and the second phase 62 is a gas. When the longitudinal channel is configured for a vertical and upward flow of the first phase and of the biphasic mixture at the second outlet, gravity has less effect on the flow of the gas phase compared to the flow of the liquid phase. The transport of the liquid phase at the opening 34 is facilitated by the greater velocity of the gas phase. Furthermore, the presence of the gas phase facilitates the flow of the liquid phase when said liquid phase is introduced into the longitudinal channel through the opening 34.

[0049] The phases 61, 62 are then mixed together by a mixer 3 arranged in at least one passage 10. Advantageously, some passages 10 of the first set, or even all passages 10, are equipped with a mixer 3. The semi-tubular manifolds 52 and 55 are fluidly connected to the inlets and outlets of the passages 10. The first manifold 30 is fluidly connected to at least one first inlet 311 of the mixer 3. The second manifold 52 is fluidly connected to at least one second inlet 321 of the mixer 3. The first and second manifolds may be any manifold means adapted to collect fluids from a fluid source and may introduce said fluids into one or more passages of the heat exchanger.

[0050] It should be noted that Fig. 1 shows the mixer 3 positioned at a certain distance from the distribution zone 51 of the exchanger 1. According to alternative embodiments, the mixer 3 can be positioned immediately after the distribution zone or juxtaposed with said zone, i.e. by being of integral construction with said zone. According to this latter possibility, the mixer forms an integral part, which can be manufactured by conventional machining or by additive manufacturing, i.e. by 3D printing, for example by laser sintering.

[0051] FIG. 2 is a three-dimensional view of a mixing device 3 which advantageously consists of a bar or rod housed in a passage 10 .

[0052] Preferably, the mixing device 3 extends over substantially the entire height, or even the entire height, of the passage 10 at its cross section, so as to be in contact with each plate 2 forming the passage 10 .

[0053] The mixing device 3 is advantageously attached to the plate 2 by brazing.

[0054] The mixing device 3 is advantageously of general parallelepiped shape.

[0055] Preferably, the mixing device 3 is a one-piece part, i.e. formed in a block or as a monolithic structure. The mixing device 3 can be manufactured by conventional machining or by additive manufacturing. The mixing device 3 can have a first dimension parallel to the longitudinal direction z of 20-200 mm and a second dimension parallel to the transverse direction y of 100-1,400 mm.

[0056] The mixer 3 comprises at least one lateral channel 31 arranged for the first phase 61 of the first fluid F1 to flow from at least one first inlet 311. Preferably, the lateral channel 31 extends parallel to the lateral direction y.

[0057] The mixing device 3 further comprises a series of longitudinal channels 32 extending parallel to the longitudinal direction z and arranged for the second phase 62 of the first fluid F1 to flow from a second inlet 321 to a second outlet 322, said longitudinal channels 32 being arranged at successive positions y i , y i+1 , placed at ···.

[0058] Preferably, the lateral channels 31 extend across the entire second dimension and / or the longitudinal channels 32 extend across the entire first dimension.

[0059] Preferably, the mixing device 3 comprises at least one first inlet 311 in fluid communication with the first manifold 30 and a second inlet 321 in fluid communication with the second manifold 52, separate from the first inlet 311, i.e. separate from the first inlet 311. The first manifold 30 is fluidly connected to a source 61 of a first phase, and the second manifold 52 is fluidly connected to a separate source 62 of a second phase. The at least one first inlet 311 and the at least one second inlet 321 are in fluid communication via at least one opening 34. In practice, the mixing device is configured for separate introduction of the first and second phases, the first inlet 311 being adapted to provide a lateral channel 31 for the first phase 61 and the at least one second inlet 321 being adapted to provide a longitudinal channel 32 for the second phase 62.

[0060] The first and second inlets are advantageously formed by exiting lateral and longitudinal channels at the lateral and longitudinal periphery of the device 3 .

[0061] FIG. 2 shows the introduction of the first phase 61 through an end of the device 3 that is equipped with a number of first inlets 311. According to an advantageous embodiment, the mixing device 3 is equipped with at least one other first inlet for the first phase 61, located at the opposite end of the device 3. Advantageously, these other inlets are obtained by extending the transverse channel 31 until it exits at the opposite side edge of the exchanger 1. In this case, another first manifold 30 is placed on the opposite side of the exchanger 1. The introduction of the first phase 61 on either side of the mixing device makes it possible to reduce the effects of pressure losses when the first phase flows in the transverse channel, which promotes a more homogeneous distribution of the biphasic mixture over the width of the exchanger.

[0062] Preferably, the mixer 3 comprises a mixing volume located in the longitudinal channel 32 downstream of the opening 34 in the direction of flow of the first phase 61 of the opening 34 .

[0063] The transverse channels 31 are fluidly connected to at least one longitudinal channel 32, such that when a first phase 61 flows in the transverse channel 31 and a second phase 62 flows in the longitudinal channel 32, the mixer 3 distributes a mixture of the first phase 61 and the second phase 62, preferably a two-phase liquid / gas mixture F1, also called a biphasic mixture, via a second outlet 322 of the channel 32. Preferably, the longitudinal channels and / or the transverse channels are substantially straight.

[0064] The channels 31, 32 are advantageously in the form of longitudinal recesses provided in the mixer 3. They preferably appear on the upper face 3a and on the lower face 3b of the mixer 3.

[0065] Preferably, the channels 31, 32 have a square or rectangular cross section, although optionally other shapes (circular, radiused, etc.) are conceivable.

[0066] The opening 34 is advantageously a hole 34 made in the material of the device 3 and preferably extends between the first channel 31 and the second channel 32 in a plane formed by the directions x and y, the opening 34 being inclined with respect to the direction x or preferably aligned with the perpendicular direction x. Preferably, the opening 34 has cylindrical symmetry and, more preferably, is cylindrical.

[0067] Preferably, the at least one lateral channel 31 has a bottom wall 3c and the at least one longitudinal channel 32 has a top wall 3d extending opposite the bottom wall 3c, and an opening 34 is drilled in the bottom wall of the first channel 31 and appears in the top wall of the longitudinal channel 32.

[0068] FIG. 3 is a view of the mixing device 3 of FIG. 2 in a cross section perpendicular to the lateral direction y and passing through the opening 34.

[0069] According to the prior art, a mixing device 3 is arranged in the first set of passages 10, said mixing device having a longitudinal channel whose width, measured in the transverse direction y, remains constant in the longitudinal direction z, in particular having a longitudinal channel of parallelepiped shape, such as the shape of the transverse channel 31 shown in FIG. 2.

[0070] At the outlet of each longitudinal channel 32, a flow of a two-phase mixture of the first fluid F1 preferably occurs in the longitudinal direction z, gradually widening the flow across the width of the passage 10. Homogenization of the flow in each passage is only obtained over a certain distance covered by the mixture. This lack of homogenization of the mixture F1 occurs throughout the stack of passages 10 of the first set.

[0071] To address these problems, the invention proposes to arrange a mixer 3 in the first set of passages 10, at least one longitudinal channel 32 of the mixer being divided in the longitudinal direction z into an upstream portion 323 and a downstream portion 324, each of which has a length L3, L4 measured in the longitudinal direction z and a width D3, D4 measured parallel to the transverse direction y. yand the downstream portion 324 is disposed between the upstream portion 323 and the second outlet 322. According to the invention, the downstream portion 324 has, at any point of its length L4, a width D that is (strictly) greater than the width D3 of the upstream portion 323. y has.

[0072] It should be noted that the term "width" is understood to mean the distance measured between the edges defining the longitudinal channel 32 in a given longitudinal cross-section parallel to the longitudinal direction z and parallel to the transverse direction y, i.e., the width of the external profile of the channel in said cross-section, for example as shown in Figures 4 to 9.

[0073] The arrangement of the downstream portion with a lateral expansion promotes the lateral expansion of the biphasic mixture leaving the longitudinal channel 32. The inventors of the present invention have shown that the fluid jet forms a wider base cone at the outlet of the longitudinal channel, which allows the fluid leaving the longitudinal channel 32 to draw more exchange channels of the exchange corrugation located downstream of the mixer 3 during operation. Thus, a faster homogenization can be obtained by the fluid jet exiting the adjacent longitudinal channel.

[0074] Thus, the variations in the mixing velocity across the width of the passage 10 are reduced or even eliminated after a shorter propagation distance of the mixture downstream of the mixer 3. The heat exchange between the biphasic mixture and the second fluid F2, and thus the operation of the exchanger, is improved.

[0075] Furthermore, widening the downstream portion in the lateral direction y offers the possibility, in the case of a relatively high mass flow rate of the biphasic mixture in the longitudinal channel 32, of slowing down the flow of the mixture in the downstream portion when water is drawn into the exchange corrugations located downstream of the mixer 3, thus reducing the pressure loss caused by the biphasic mixture at the outlet of the longitudinal channel 32.

[0076] Preferably, some, and preferably all, of the series of longitudinal channels 32 are constructed in accordance with the present invention and may include all or some of the features described below.

[0077] Preferably, the downstream portion 324 emerges at the downstream side 326 of the mixer 3 and the second outlet 322 is provided at the downstream side 326. At least a portion of the first phase 61 flowing into the transverse channel 31 is fed to the opening 34 to flow into the longitudinal channel where mixing occurs. The second phase 62 flows successively into the upstream portion 323 and the downstream portion 324. The mixture is distributed via the second outlet 322.

[0078] Preferably, the downstream portion 324 extends toward the second outlet 322 over a length L4 of a width D y increases, preferably throughout the entire length L4.

[0079] It should be noted that the widening of the downstream portion in the longitudinal direction z can be introduced ad-hoc, in one or more increments, or in a stepwise manner, i.e., a continuous increase along all or part of the downstream portion 324.

[0080] Preferably, the width D of the downstream portion 324 y increases continuously, i.e. gradually, over the entire length L4 towards the second outlet 322. Thus, disturbances in the mixture flow that may cause abrupt changes in the channel width are limited.

[0081] Preferably, the downstream portion 324 has a minimum width D m and maximum width D M With a ratio D M / D m is greater than or equal to 1.1, preferably greater than or equal to 1.8 and / or less than or equal to 4. Such a dimensional ratio allows the width of the longitudinal channel 32 to be increased sufficiently at the ends 322 while maintaining the simplicity of machining the longitudinal channel 32 without excessively increasing the length of the longitudinal channel 32 in the direction z.

[0082] In particular, width D M The thickness can be set to 6 to 25 mm, preferably 8 to 20 mm.

[0083] It should also be noted that the mixing device according to the invention can be intended to be arranged in a passage 10 in which, downstream of the mixing device, at least one exchange corrugation is provided, each with an exchange channel having a width of 0.6 to 2 mm, preferably at least 0.7 mm and / or at most 1.5 mm.

[0084] Preferably, the minimum width D m is measured at the end 324a of the downstream portion 324 and has a maximum width D M is measured at the second outlet 322.

[0085] Advantageously, the longitudinal channel 32 is defined by side walls 325 which, in a longitudinal section parallel to the longitudinal direction z and the transverse direction y, form an external profile of said channel 32 having an axis of symmetry AA' parallel to the longitudinal direction z.

[0086] It should be noted that the side walls 325 of the channel are preferably erected in a direction perpendicular to the longitudinal direction z and the transverse direction y. The walls 325 advantageously have a height, measured in the direction x, that is constant over the entire length of the channel 32.

[0087] Alternatively, one can consider a change in the height of the wall 325, in particular an increase in said height towards the second outlet 322, i.e. towards the downstream portion 324, the depth of which optionally increases towards the second outlet 322 until it reaches the height of the passage 10 at the second outlet 322. This provides an additional degree of freedom to increase the fluid passage cross section in the downstream portion 324, thus slowing down the fluid so that it can be homogenized in the height of the passage 10 as well.

[0088] Advantageously, at least part of the downstream portion 324 has a curved external profile, preferably a convex external profile. Figure 4 shows diagrammatically an embodiment of a longitudinal channel 32 with such a downstream portion 324. The presence of a curved external profile of the downstream portion provides a better guidance for the flow of fluid in the downstream portion from the mixing device to its outlet, in particular preventing any separation phenomena, fluid recirculation or turbulences that may occur as a result of sharp angles on the walls and which would result in undesirable further pressure losses of the fluid.

[0089] It is also possible that all or part of the downstream portion 324 has an external profile in the form of an isosceles trapezoid in longitudinal section in a plane parallel to the longitudinal direction z and the transverse direction y, the side walls of this portion being straight walls. Figure 5 shows diagrammatically an example where the entire downstream portion 324 has such an external profile.

[0090] In particular, by considering the downstream side 326 of the mixer 3, where the downstream portion 324 emerges, the external profile can form an angle θ between 5 and 85°, measured between the tangent T of said external profile at the intersection with the downstream side 326 and the axis of symmetry AA'. These values ​​allow to sufficiently increase the width of the channel 32 at the second outlet 322 to promote a better distribution of the two-phase fluid F1 in the width of the exchanger in the direction y, without, moreover, creating an excessively rapid widening that could cause pressure losses in the fluid F1, and without excessively increasing the length L4, and therefore the length of the mixer 3.

[0091] FIG. 9 shows an embodiment in which the expansion of the downstream part in the longitudinal direction z is caused only in situ at the end 324a, at one time.

[0092] Preferably, the upstream portion 323 is connected to the downstream portion 324 by its end 324a.

[0093] Advantageously, the upstream portion 323 has a length L3, measured in the longitudinal direction z, and a ratio L3 / L4 between 1 and 15, preferably between 3 and 12.

[0094] As an example, the length L4 may be 5 to 40 mm, and the length L3 may be 30 to 70 mm.

[0095] Advantageously, the at least one opening 34 is located at its upstream portion 323, preferably at a distance L from the end 324a of the downstream portion 324. z At the position of z is equal to 4% of the length L3 of the upstream portion 323, more preferably 7 to 90%, and even more preferably 10 to 50%. In particular, the opening 34 is at a distance L from the end 324a of the downstream portion 324 of 3 to 70 mm. z Advantageously, the opening or openings 34 of the longitudinal channel 32 all occur in its upstream part 323. The mixing device advantageously has no openings 34 occurring in its upstream part 324.

[0096] Thus, the first phase 61 and the second phase 62 are well mixed upstream of the downstream portion 324, on the one hand, the two-phase fluid has time to be adequately homogenized before entering the downstream portion 324, and on the other hand, any recirculation zone for the fluid of the downstream portion 324 does not cause disturbances that could cause a bad distribution of the flow of the first phase 61 through the opening 34 of the transverse channel 31 into the longitudinal channel 32. The higher velocity of the second phase 62 in the portion 323 of the channel 32 compared to the velocity of the fluid F1 in the portion 324 can also facilitate the passage of the phase 61 through the opening 34 from the channel 31 into the channel 32, due to the high inertia of the phase 62 and the resulting driven phase 61.

[0097] It should be noted that preferably the position of the at least one opening 34 in the longitudinal direction z varies among the longitudinal channels, and for this reason in particular some openings 34 may be closer to the end 324a than others.

[0098] Furthermore, within the scope of the present invention, the longitudinal channels can advantageously have identical dimensional characteristics, i.e. the same external profile, the same depth, the same ratio L3 / L4, the same distance L z However, it should be noted that in some configurations it is possible to vary at least one characteristic of at least one channel relative to another, particularly the ratio of the lengths of the downstream and upstream portions.

[0099] Preferably, as particularly shown in FIG. 4, all or a portion of the upstream portion 323 is preferably smaller than the minimum width D m According to one possibility, it is possible to consider that the upstream portion 323 has a variable width D3 over all or part of its length, D y is greater than the maximum value that can be reached by D3.

[0100] 6 and 7 show diagrammatically an embodiment in which the longitudinal channel 32 comprises at least one obstruction 327 arranged to further divide the downstream portion 324 into a number of intermediate channels 328 emerging at the second outlet 322.

[0101] This prevents the mixture from flowing completely in the longitudinal direction z and spreads the flow in the lateral direction y. The creation of an intermediate channel is particularly advantageous when the mass flow rate in the longitudinal channel 32 is relatively high, since in this case the mixture has significant inertia in the longitudinal direction z, i.e., the mixture tends to continue to flow in direction z even as the longitudinal channel widens.

[0102] The installation of one or more obstacles can redirect the flow of the biphasic mixture by providing a y-component in its velocity, thus increasing the angular opening of the fluid jet at the outlet of the longitudinal channel, thereby providing more exchange channels located downstream of the mixer.

[0103] Obstacles can also be used to keep the fluid passage cross section in the downstream part constant or quasi-constant, or, optionally, to reduce said cross section despite its widening. It should be noted that "fluid passage cross section" is understood to be the surface through which the fluid flows, measured perpendicular to the longitudinal direction z. This ensures a lateral spread of the mixture, without further increasing the fluid passage cross section.

[0104] Thus, the pressure loss is rebalanced along the longitudinal channels.

[0105] Preferably, at the second outlet 322, the total surface of said obstacles 327, measured in a cross-section perpendicular to the longitudinal direction z, is between 20 and 80%, preferably between 30 and 70%, of the total fluid passage cross-section of the downstream portion 324 measured in said cross-section.

[0106] If several obstacles are present, the total surface is understood to be the sum of the surfaces of each obstacle.

[0107] In particular, the surface of the obstacle measured at a distance of 1 mm in the longitudinal direction z in the direction of fluid flow after the point of emergence into the channel 32, i.e. located 1 mm after the point of emergence of the obstacle where the fluid impacts the obstacle, referred to as the impact position, can represent 1% to 80% of the fluid passage cross-section of the channel 32, determined at a cross-section located at the impact position.

[0108] In certain embodiments, the longitudinal channels 32 further comprise at least one balancing channel 329 fluidly connecting the intermediate channels 328. This can rebalance the fluid pressure between the intermediate channels 328 in the event that there are variations in fluid flow and pressure between the intermediate channels. Figure 8 shows an example of such a configuration.

[0109] Advantageously, an even number of intermediate channels is provided in order to maintain distribution symmetry along the axis AA' for the mixture in the longitudinal channels.

[0110] The obstacle or obstacles can be manufactured together with the longitudinal channel by milling, by metal injection molding, by electro-discharge machining or by laser machining. Additive manufacturing methods can also be envisaged.

[0111] Preferably, the height of the obstacle 327 is equal to the height of the sidewalls of the longitudinal channel.

[0112] Preferably, said at least one obstacle 327 has a width dy, measured in the lateral direction y, that increases towards the second outlet 322 and preferably has a curved, convex and / or concave external profile, allowing the obstacle to be shaped to avoid further pressure losses of the fluid F1 in the downstream part 324 of the channel 32 by drawing the fluid away from the walls of the obstacle or due to a zone for recirculating the fluid.

[0113] Preferably, some of the passages 10 of the first set, advantageously all passages 10, are equipped with a mixing device according to the invention.

[0114] Preferably, at least one passageway 20 of the second set is disposed between at least one consecutive pair of passageways 10 of the first set.

[0115] Preferably, the longitudinal channel 32 of the mixing device 3 has a constant distance D measured parallel to the longitudinal direction y. A are separated from each other by

[0116] The horizontal position of each channel i , y i+1 , y i+2 It should be noted that , ··· can be determined by considering the position of the center of each channel in the lateral direction y. For example, by considering a channel in the form of a parallelepiped groove, such as the groove shown in Fig. 2, the position of the channel in the direction y corresponds to the position of the axis of symmetry of the channel, which is located at an equal distance from the side walls of the channel, as shown in Fig. 2.

[0117] Distance D A The distance can be set to 10 to 40 mm, and preferably to 20 mm or more and 30 mm or less.

[0118] To illustrate the homogenization effect obtained with the present invention, FIG. 11 shows the results of a simulation of the propagation of a two-phase mixture in the longitudinal channel of a conventional mixer (configuration A) and in the longitudinal channel of a mixer according to one embodiment of the present invention (configuration B).

[0119] In configuration A, the mixing device was in the form of a grooved bar with, as longitudinal channels, a series of parallelepiped grooves adjacent to one another at regular intervals of 30 mm, each groove being 7 mm wide, 70 mm long and 7 mm high.

[0120] In configuration B, partly shown diagrammatically in FIG. 10, the mixing device was in the form of a grooved bar with grooves adjacent to one another at regular intervals of 30 mm. Each groove was in the form of a longitudinal channel with an upstream portion 323 that was 7 mm wide, 63 mm long and 7 mm high. The downstream portion 324 had a frustoconical shape with a width of 7 mm at the end 324a and a width of 14 mm at the second outlet 322. The upstream portion 323 was 7 mm long and 7 mm high. An isosceles triangular obstacle was placed in the downstream portion 324 symmetrically with respect to the axis of symmetry AA′, had a height of 7 mm in the z direction and a base width of 7 mm at the second outlet 322. Width D M was twice as high as D3. The ratio L3 / L4 was 8, and the length Lz was 5 mm. The angle θ was 45°. It should be noted that configuration B corresponds to the particular case where, due to the presence of an obstacle, the fluid passage cross section of the downstream portion remains constant in the longitudinal direction z, but the width of said portion increases towards the second outlet 322.

[0121] The longitudinal channels of the mixing devices of configurations A and B are numbered according to the same numbers and are arranged at the same positions y in the transverse direction y. i , y i+1 , placed at ...

[0122] In configurations A and B, "sawtooth" type corrugations 11, i.e. partially offset corrugations, were placed at the mixer outlet in each passage. These corrugations were of the "1 / 8 inch sawtooth" type (1 inch=25.4 mm), i.e. a sawtooth length of 25.4 / 8=3.18 mm, and had a corrugation density of 23 fins per inch (1 inch=25.4 millimeters) as measured in the transverse direction y.

[0123] The simulation is a three-dimensional CFD (computational fluid dynamics) type calculation using the finite element method.

[0124] Figure 11 shows the evolution of the value of the minimum dimensionless velocity of the fluid in the longitudinal direction z (denoted Vz), measured on successive cross sections of the corrugation located after the outlet 322 in a plane parallel to the directions x and y, for several values ​​of the distance between the outlet 322 and said plane. These velocity values ​​represent the quality of the fluid distribution in the corrugation. Negative values ​​indicate the presence of a recirculation zone, where the fluid is stagnant in the center of the zone. Zero values ​​indicate the presence of stagnant fluid. As the stagnant fluid is not renewed, it does not take part in the heat exchange and reduces the overall efficiency of the exchanger.

[0125] The fluid distribution performance index is the minimum distance required in the longitudinal direction z over which all fluids have a positive velocity in the longitudinal direction z.

[0126] It can be seen that the minimum required distance is reduced from 45 mm to 31 mm, a reduction of 35% in the configuration B according to the invention with respect to the conventional configuration A. The present invention provides a significantly improved homogenization of the two-phase mixture distributed by the mixer and improves the efficiency of the exchanger.

[0127] 12 and 13 show examples of how one or more exchanges may be implemented in accordance with the present invention.

[0128] FIG. 12 shows diagrammatically a method for liquefying a hydrocarbon stream 102 as a second fluid F2, which may optionally be pre-treated, for example natural gas, which has undergone separation of at least one of its constituent elements water, carbon dioxide, sulfur compounds, methanol, mercury, before being introduced into the heat exchanger 1.

[0129] Preferably, the hydrocarbon stream comprises, as a mole fraction, at least 60% methane, preferably at least 80%.

[0130] The hydrocarbon stream 102 and the cooling stream 202 enter the exchanger 1 via the third inlet 25 and the fourth inlet 21, respectively, for circulation therein in dedicated passages of the exchanger in a direction parallel to the longitudinal direction z, which is generally vertical during operation. The hydrocarbon stream 102 circulates through a second set of passages 20 supplied by the third inlet 25. The cooling stream 202 circulates through a third set of passages arranged in the stack forming the exchanger 1. These streams exit via a third outlet 22 and a first outlet 23. The second and third sets of passages are arranged, in whole or in part, alternately and / or adjacent to all or in part of the first set of passages 10.

[0131] Advantageously, the fourth inlet 21 for the cooling stream 202 and the third inlet 25 for the hydrocarbon stream 102 are arranged such that the cooling stream 202 and, optionally, the hydrocarbon stream 102 flow cocurrently downwards towards the second end 1b of the exchanger, which is at a level lower than the level of the first end 1a of said exchanger. Preferably, the first end 1a corresponds to the hot end of the exchanger 1, i.e. the entry point of the exchanger where the fluid is introduced at the highest temperature of the exchanger, which entry point can be the fourth inlet 21 or the third inlet 25, depending on the method involved.

[0132] The hydrocarbon stream 102 may be introduced into the exchanger 1 at a temperature between -130 and 40°C.

[0133] According to one possibility, the hydrocarbon stream 102 is introduced into the exchanger 1 in a completely gaseous or partially liquefied state, at a temperature between -80 and -35°C.

[0134] According to another possibility, the hydrocarbon stream 102 is introduced into the exchanger 1 in a fully liquefied state, at a temperature of between -130 and -100°C.

[0135] The cooling stream 201 leaving the exchanger 1 is expanded by an expansion component T3, such as a turbine, a valve, or a combination of a turbine and a valve, to form a biphasic cooling stream 203 comprising a first phase and a second phase. The biphasic cooling stream 203 forms the first fluid F1 mentioned above. At least a portion of the biphasic cooling stream 203 resulting from the expansion is introduced into a separator component 27. The separator component may be any device adapted to separate a two-phase fluid into one predominantly gaseous fluid and another predominantly liquid fluid.

[0136] The second phase 62 is introduced through a manifold 52 providing second inlets 321 of the mixers 3 located in the first set of passages 10. The first phase 61 is introduced through a first manifold 30 providing first inlets 311 of the mixers 3 located in each passage 10 (not shown in FIG. 9).

[0137] Preferably, the second phase is introduced through an inlet located at the cold end of the exchanger 1, i.e. in the region of the second end 1b, which corresponds to the entry point into the exchanger where the fluid is introduced at the lowest temperature of the exchanger fluid.

[0138] The two phases 61, 62 of the two-phase stream 203 are recombined in the exchanger 1 and distributed in a gas-liquid mixed state in the passages 10 of the exchanger 1, each of which is provided with a mixing device 3 according to the invention.

[0139] Preferably, the biphasic cooling stream 203 is introduced into the heat exchanger 1 at a first temperature T1 between -120 and -160°C and leaves the heat exchanger 1 at a second temperature T2 higher than the first temperature T1, preferably T2 between -35 and -130°C.

[0140] According to another possibility, the biphasic cooling stream 203 is introduced into the heat exchanger 1 at a first temperature T1 between -130 and -80°C and leaves the heat exchanger 1 at a second temperature T2 higher than the first temperature T1, preferably T2 between -10 and 50°C.

[0141] Said at least part of the biphasic cooling stream 203 flows upwards taking the passage 10 and is vaporized by countercurrently cooling the natural gas 102 and the cooling stream 202. Thus, a cooled and / or at least partially liquefied hydrocarbon stream 101 is obtained at the outlet of the exchanger 1.

[0142] The vaporized cooling stream leaves the exchanger 1 via a second outlet 42 connected to a manifold 55 for compression by the compressor and then cooling in an indirect heat exchanger by heat exchange with an external cooling fluid (at 26 in FIG. 12), e.g. water or air. The pressure of the cooling stream at the compressor outlet can be between 2 MPa and 9 MPa. The temperature of the cooling stream at the indirect heat exchanger outlet can be between 10°C and 45°C.

[0143] In the method described in FIG. 12, the cooling stream is not split into separate portions, but to optimize the approach in exchanger 1, the cooling stream could be separated into two or three portions, each of which is expanded at a different pressure level and then sent to various stages of the compressor.

[0144] Preferably, the cooling stream 202 contains hydrocarbons having at most 5, preferably at most 3, and more preferably at most 2 carbon atoms.

[0145] Preferably, the cooling stream 202 is formed by a mixture of hydrocarbons and nitrogen, such as, for example, a mixture of methane, ethane, and nitrogen, but may also contain propane, butane, isobutane, n-butane, pentane, isopentane, n-pentane, and / or ethylene.

[0146] The mole fractions (%) of the components of the cooling stream may be as follows: - Nitrogen: 0%~10%, - Methane: 20%~70%, - Ethane: 30% to 70%, - Ethylene: 20-70%, - Propane: 0%~20%, - n-butane: 0%~30%, - Isopentane: 0% to 20%.

[0147] Optionally, the cooling stream may include ethylene as a replacement for ethane, and C4, C5 type compounds as a replacement for all or part of the propane.

[0148] Preferably, the natural gas leaves exchanger 1 at least partially liquefied 101, preferably at a temperature at least 10° C. higher than the bubble temperature of liquefied natural gas produced at atmospheric pressure (the bubble temperature indicates the temperature at which the first vapor bubbles form in the liquefied natural gas at a given pressure) and at a pressure identical to the inlet pressure of the natural gas, to the nearest pressure drop. For example, the natural gas leaves exchanger 1 at a temperature between −100° C. and −162° C. and at a pressure between 2 MPa and 7 MPa. Under these temperature and pressure conditions, and depending on its composition, the natural gas generally does not remain liquid after expansion to atmospheric pressure.

[0149] Advantageously, the method for liquefying a hydrocarbon stream according to the invention may implement one or more additional refrigeration cycles carried out upstream of the main refrigeration cycle described above, so as to pre-cool the hydrocarbon stream.

[0150] 13 shows diagrammatically a method for liquefying a hydrocarbon stream such as natural gas, comprising an additional refrigeration cycle, in which the natural gas is cooled to a temperature close to its dew point using at least two different expansion levels in order to improve the efficiency of the cycle. This additional refrigeration cycle is then implemented by an additional cooling stream 300 in an additional heat exchanger 2, called pre-cooling exchanger, which is placed upstream of the heat exchanger 1 in the direction of flow of the hydrocarbon stream 110, forming the liquefaction exchanger.

[0151] In this embodiment, the feed stream 110 arrives, for example, at a pressure between 2.5 MPa and 7 MPa and at a temperature between 20° C. and 60° C. With the feed stream 110 comprising a mixture of hydrocarbons, such as natural gas, the cooled stream 202 and the additional cooled stream 300 enter the additional exchanger 2 for circulating therein in a downward parallel and cocurrent direction.

[0152] A cooled or even at least partially liquefied hydrocarbon stream 102 leaves the pre-cooling exchanger 2. Preferably, the hydrocarbon stream 102 leaves in a gaseous or partially liquefied state, for example at a temperature between −35° C. and −70° C. The cooled stream 202 can also leave the exchanger 2 fully condensed, for example at a temperature between −35° C. and −70° C. Stream 102 is then introduced into exchanger 1.

[0153] As can be seen in Fig. 13, stream 203 is vaporized in exchanger 1, compressed by compressor K2 and then leaves the exchanger for cooling in indirect heat exchanger C2 by heat exchange with an external cooling fluid, e.g. water or air. The cooling stream resulting from exchanger C2 is then returned to additional exchanger 2.

[0154] The additional cooling stream 300 may be formed by a mixture of hydrocarbons, such as a mixture of ethane and propane, but may also contain methane, ethylene, propylene, butane, and / or pentane. The mole fractions (%) of the components of the first refrigerant mixture may be as follows: - Ethane: 30% to 70%, - Propane: 30%~70%, - Butane: 0%~20%.

[0155] In the additional exchanger 2, also of the brazed plate and fin type, at least two partial flows resulting from the additional cooling stream 300 are led out of the exchanger at at least two separate exit points and then expanded at different pressure levels to produce partial biphasic expanded flows, each comprising a first phase and a second phase. At least a portion of these partial biphasic flows are introduced into the respective separator components 24, 25, 26.

[0156] In the embodiment of FIG. 13, three portions 301, 302, 303, also called partial flows or flows, of the additional cooling flow 300 in the first phase are withdrawn successively.

[0157] The gas and liquid phases separated by each separator element are introduced through separate inlets of the additional heat exchanger 2 and recombined in a mixer (not shown) to form at least two refrigerant fluids that are introduced in a gas-liquid mixed state into the dedicated cooling passages. Alternatively, only the first phase is injected into the exchanger 2 and the gas phase is directed towards the inlet of the compression stage of the compressor K1. These refrigerants are vaporized in the additional exchanger 2 by heat exchange with the feed stream 110 and the cooling stream 202 and the additional cooling stream 300.

[0158] Advantageously, at least two types of mixing devices 2, such as may be arranged in the exchanger 1 according to the invention, are arranged in the additional exchanger, which thus comprises at least two refrigerant passages each equipped with a mixing device, which devices comprise one or more of the features described above for the first and second mixing devices 3A, 3B.

[0159] The vaporized refrigerant in their respective refrigerant passages is sent to the various stages of the compressor K1, compressed and then condensed in a condenser by heat exchange with an external cooling fluid, for example water or air. The stream resulting from the condenser is returned to the additional exchanger 2. The pressure of the first cooling stream at the outlet of the compressor K1 can be between 2 MPa and 6 MPa. The temperature of the additional cooling stream at the outlet of the condenser C1 can be between 10 °C and 45 °C.

[0160] Preferably, the refrigerant flows in a longitudinal direction z upwards from one end 2b to another end 2a of the additional exchanger 2. End 2b corresponds to the cold end of the additional exchanger 2, where the refrigerant is introduced at the lowest temperature of the additional exchanger 2.

[0161] Of course, the invention is not limited to the specific examples described and illustrated in this application. Other alternative embodiments or embodiments within the ability of a person skilled in the art can also be envisaged without departing from the scope of the invention. For example, other configurations of transverse and longitudinal channels for injecting / extracting fluids from the exchanger, other flow paths and directions of fluids, other types of fluids, other forms of mixing devices, etc. are obviously conceivable depending on the constraints imposed by the method to be implemented.

Claims

1. A mixing device (3) for distributing a mixture of a first phase (61) and a second phase (62) of a first fluid (F1) generally in the longitudinal direction (z) of at least one passage (10) of a heat exchanger (1), comprising: at least one lateral channel (31) configured for said first phase (61) to flow from at least one first inlet (311); - a series of longitudinal channels (32) extending in said longitudinal direction (z), each configured for the second phase (62) to flow from a second inlet (321) to a second outlet (322), said longitudinal channels being adjacent to one another in a transverse direction (y) perpendicular to said longitudinal direction (z); at least one opening (34) fluidly connecting said transverse channel (31) to at least one longitudinal channel (32), such that said mixing device (3) is configured to distribute the mixture of said first phase (61) and said second phase (62) through said second outlet (322) of said longitudinal channel (32); In a mixing device (3), the at least one longitudinal channel (32) of the mixing device (3) is divided in the longitudinal direction (z) into an upstream portion (323) and a downstream portion (324) each having a length (L3, L4) measured in the longitudinal direction (z) and a width (D3, Dy) measured in the transverse direction (y), the downstream portion (324) being located between the upstream portion (323) and the second outlet (322), the downstream portion (324) having, at any point of its length (L4), a width (Dy) that is greater than the width (D3) of the upstream portion (323), said longitudinal channel (32) comprises at least one obstacle (327) arranged to further divide said downstream portion (324) into a plurality of intermediate channels (328) emerging at said second outlet (322), preferably said intermediate channels (328) being arranged symmetrically with respect to an axis of symmetry (AA′) of said longitudinal channel (32); The longitudinal channel (32) fluidly connects a first intermediate channel of the plurality of intermediate channels (328) with a second intermediate channel of the plurality of intermediate channels (328). Equipped with a balancing channel 329 Characterized in that Mixing device (3).

2. The downstream portion (324) has a width (Dy) that increases continuously over its entire length (L4) toward the second outlet (322). Characterized in that 2. The mixing device of claim 1.

3. all or part of said downstream portion (324) has, as a longitudinal section in a plane (P) parallel to said longitudinal direction (z) and said transverse direction (y), an external profile in the form of an isosceles trapezoid; Characterized in that 3. A mixing device according to claim 1 or 2.

4. The downstream portion (324) emerges at the downstream side (326) of the mixer (3) and the external profile forms an angle (θ) of 5 to 85° measured between a tangent (T) of the external profile at its intersection with the downstream side (326) and the axis of symmetry (AA′) of the longitudinal channel (32). Characterized in that 4. The mixing device of claim 3.

5. The upstream portion (323) of the longitudinal channel (32) is connected to the downstream portion at one end (324a), and the at least one opening (34) emerges in the longitudinal channel (32) in the upstream portion (323) at a distance (Lz) from the end (324a), preferably (Lz) being equal to or greater than 4% of the length (L3) of the upstream portion (323), and preferably between 7 and 90% of the length (L3) of the upstream portion (323). Characterized in that A mixing device according to any one of claims 1 to 4.

6. The at least one opening (34) is positioned such that mixing of the first phase (61) and the second phase (62) occurs upstream of the downstream portion (324) when the first phase (61) flows from the first inlet (321) of the transverse channel (31) and the second phase (62) flows from the second inlet (321) of the longitudinal channel (32). Characterized in that A mixing device according to any one of claims 1 to 5.

7. The one or more openings (34) of the mixing device (3) all emerge in the upstream portion (324) of the longitudinal channel (32). Characterized in that A mixing device according to any one of claims 1 to 6.

8. Each longitudinal channel of the series of longitudinal channels (32) comprises at least one opening (34) appearing in its upstream portion (323), the position of said at least one opening (34) in said longitudinal direction (z) differing among said longitudinal channels (32). Characterized in that A mixing device according to any one of claims 1 to 7.

9. The length (L3) of the upstream portion (323) and the length (L4) of the downstream portion (324) are such that the ratio L3 / L4 is between 1 and 15, preferably between 3 and 12. Characterized in that A mixing device according to any one of claims 1 to 8.

10. The downstream portion (324) has an increasing depth towards the second outlet (322), measured in a direction called the stacking direction (x), which is perpendicular to the longitudinal direction (z) and perpendicular to the transverse direction (y). Characterized in that A mixing device according to any one of claims 1 to 9.

11. a heat exchanger (1) comprising a plurality of plates (2) arranged parallel to one another and in a longitudinal direction (z), said plates (2) being stacked in a spaced manner so as to together define at least a first set of passages (10) arranged for a first fluid (F1) to flow generally in said longitudinal direction (z), and at least a second set of passages (20) arranged for a flow of a second fluid (F2) in heat exchange relationship with said first fluid (F1); a source of a first phase (61) of said first fluid (F1) fluidly connected to at least one first manifold (30) of said heat exchanger (1); a source of a second phase (62) of said first fluid (F1) fluidly connected to at least one second manifold (52) of said heat exchanger (1); A mixing device (3) according to any one of claims 1 to 10, wherein the mixing device (3) is arranged in at least one passage (10) of the first series of passages and is configured to distribute a first fluid (F1) formed by a mixture of the first phase (61) and the second phase (62) to the passages (10) of the first series of passages, the first inlet (311) of the transverse channel (31) being in fluid communication with the first manifold (30) and the second inlet (321) being in fluid communication with the second manifold (52), the first phase (61) being in a liquid phase and the second phase (62) being in a gas phase; Equipped with Heat exchange equipment.

12. A method for mixing a first phase (61) and a second phase (62) of a first fluid (F1) in a mixing device (3) according to any one of claims 1 to 10, comprising: i) introducing said first phase (61) of said first fluid (F1) through at least one first inlet (311) of said lateral channel (31); ii) introducing said second phase (62) of said first fluid (F1) through a second inlet (321) of each longitudinal channel (32), said second phase (62) flowing in said longitudinal direction (z) in each longitudinal channel (32) to a second outlet (322) of said longitudinal channel (32); iii) flowing at least a portion of said first phase (61) from said transverse channels (31) towards said longitudinal channels (32) through said openings (34) so ​​as to mix said first phase (61) with said second phase (62) in said longitudinal channels (32); iv) distributing the mixture of the first phase (61) and the second phase (62) through the second outlet (322) of each longitudinal channel (32); The method includes:

13. The first phase (61) is mixed with the second phase (62) upstream of the downstream portion (324). Characterized in that The method of claim 12.

14. A method for liquefying a hydrocarbon stream (102), such as natural gas, as a second fluid (F2), by heat exchange with at least one biphasic cooling stream (203) as a first fluid (F1), comprising: Implementing the mixing method according to claim 12 or 13, a) introducing said hydrocarbon stream (102) into a second set of passages (20) of a heat exchanger (1); b) introducing a cooling stream (202) into a third set of passages of said heat exchanger (1); c) discharging said cooling stream (201) from said heat exchanger (1) and expanding said cooling stream (201) to at least one pressure level to generate at least one biphasic cooling stream (203); d) separating at least a portion of the biphasic cooled stream (203) obtained in step c) into a second phase (62) and a first phase (61); e) disposing a mixing device (3) in at least one passage (10) of the first set of passages of said heat exchanger (1); f) introducing at least a portion of said second phase (62) and at least a portion of said first phase (61) into said mixer (3) so as to obtain a first fluid (F1) formed by a mixture of said first phase (61) and said second phase (62) at the outlet of said mixer (3); g) vaporizing at least a portion of said first fluid (F1) obtained in step f) in said passage (10) by heat exchange with at least said hydrocarbon stream (102) so as to obtain, at the outlet of said heat exchanger (1), a cooled and / or at least partially liquefied hydrocarbon stream (101); Including, method.

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