Naturally derived fragrance complex, fragrance composition, and aqueous fragrance composition

Abstract

The present invention relates to a fragrance complex comprising 5-70% fragrance, 10-30% caprylyl glycol and 0-85% monopropylene glycol, the percentages being expressed by weight relative to the total weight of said three components. The present invention relates to a fragrance composition comprising 25-34% of said fragrance complex and 66-75% of a mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, the percentages being expressed by weight relative to the total weight of said two components. The present invention relates to an aqueous fragrance composition comprising 20-30% of said fragrance composition; and 70-80% water, the percentages being expressed by weight relative to the total weight of said two components. The present invention is used in the fields of fine fragrance, cosmetics, optionally rinsable hygiene products, cleaning products and ambient fragrance or room deodorant or deodorizing sprays.

Description

[Technical field]

[0001] The present invention relates to the field of perfumes and perfume compositions. The invention finds particularly advantageous applications in the fields of fine perfumes, cosmetics, rinsed or no-rinsed hygiene products, ambient fragrances or room deodorants, cleaning agents or air fresheners. [Background technology]

[0002] One recurring problem in the perfumery field concerns the solubility of perfumes in water.

[0003] It has been found that in order to ensure both sufficient solubility and olfactory performance for the user, it is necessary to add certain additives, which have the drawback, among other things, of leaving a sticky or greasy feeling and in most cases of being irritating to the skin, and also of modifying the properties of the solutions in which they are contained, such as the viscosity and the rate of foam formed.

[0004] Many compositions currently on the market contain ethanol, which is, however, a harmful VOC (volatile organic compound) with regard to certain regulatory and environmental constraints. In parallel, research has made it possible to demonstrate that the presence of water and the reduction or absence of ethanol makes it possible to improve the long-term persistence of fragrances over time, to avoid irritation and dryness of the skin and hair, to eliminate the risks associated with exposure to sunlight, and to avoid problems related to storage, transport (customs), flammability.

[0005] In order to improve the above-mentioned shortcomings, compositions based on cosolvents, such as isosorbide, solketal, and their ethers, have been proposed.Also proposed are compositions that contain ethoxylated oleyl alcohol (marketed under the name Ameroscol®) or sulfates, such as sodium lauryl sulfate and sodium laureth sulfate, as surfactants.However, such compounds irritate and dry skin and hair, and therefore should be avoided in the field of perfumery and cosmetics.

[0006] One solution identified by the applicant of this application is described in WO 2019 / 154892 A1. This solution consists of a composition comprising a solvent selected to ensure a high proportion of fragrance, without the drawbacks mentioned above. However, consumer demand is increasingly directed towards compositions of natural origin. The fragrance composition provided must, however, make it possible to solubilize essential oils, which are ingredients that are very difficult to solubilize in water. Furthermore, the weak capacity of stabilizers and solvents of natural origin greatly limits the possible proportion of fragrance.

[0007] Moreover, this also raises the question of the transparency of the composition to facilitate its use in various fields, without constituting any particular limitation. [Prior art documents] [Patent documents]

[0008] [Patent Document 1] International Publication No. 2019 / 154892A1 Summary of the Invention [Problem to be solved by the invention]

[0009] In perfumery, obtaining fragrance mixtures which are versatile in terms of application, transparent, have improved sensory properties and are preferentially stable and of natural origin is the subject of ongoing research.

[0010] There is therefore a need to provide a fragrance composition which overcomes all or some of these shortcomings. [Means for solving the problem]

[0011] To this end, according to one aspect, the present invention comprises a composition comprising the following components: - 25-34% of a fragrance complex as described below; - a mixture of 66-75% of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, and these percentages relate to the perfume composition, expressed by weight, relative to the total weight of the two components mentioned above.

[0012] The fragrance complex above contains the following ingredients: - 5-70% fragrance, - 10-30% caprylyl glycol as a solvent, and - 0-85% monopropylene glycol as a solvent; These percentages are expressed by weight based on the total weight of the three components.

[0013] This fragrance complex has the advantage that it can solvate fragrance in a high proportion in so-called solvents of natural origin, which are not usually used in such proportions for this purpose.In particular, caprylyl glycol is usually known as the optimizer of preservatives used to protect against microorganisms.For this purpose, it is used in small amounts, and the use of this complex in the above proportions does not result from the obvious step that a minimum amount is required to obtain optimal effect for this type of product.

[0014] Advantageously, the perfume complex is free of water.

[0015] The perfume complex according to the invention has the advantage of being water-free, which makes it easy to transport and package, as well as being stable and non-irritating to the skin.

[0016] The fragrance composition has the advantage of using a solubilizer, also known by the name Easytens S2, which is of natural origin and has a solubilizing synergy with fragrance solvents, in particular monopropylene glycol.

[0017] Advantageously, the perfume composition is free of water, meaning that the perfume composition does not contain additional water in addition to the components of the composition. As with perfume complexes, this makes them stable and non-irritating to the skin, while at the same time facilitating their transportation and packaging.

[0018] To this end, according to another aspect, the present invention provides a composition comprising the following components: - 20 to 30% of the above fragrance composition, - 70-80% water, and these percentages are expressed by weight relative to the total weight of the two components mentioned above.

[0019] Advantageously, the aqueous perfume composition is in the form of a microemulsion.

[0020] According to another aspect, the present invention relates to a method for producing a fragrance composition as described above, the method comprising the steps of: - preparing the fragrance complex as defined above; - heating a mixture of caprylic / capric polyglyceryl-6 and sodium caproyl / lauroyl lactylate, preferentially at a maximum temperature of 65°C; - adding the heated mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate to the fragrance complex; and - homogenizing the obtained flavor composition; Includes.

[0021] According to another aspect, the present invention relates to a method for producing the aqueous fragrance composition described above, the method comprising the steps of: - adding water to the flavor composition described above; and - homogenizing the obtained aqueous fragrance composition; Includes.

[0022] The present invention also relates to a cosmetic base, a cleansing base, or an ambient fragrance comprising the aqueous fragrance composition or fragrance composition or fragrance complex described above.

[0023] The present invention also relates to the use of an aqueous perfume composition, or a cosmetic base, or a cleaning base, or an ambient fragrance as described above, for masking malodours.

[0024] Preferentially, the perfume complexes, the perfume compositions and the aqueous perfume compositions are of natural origin and even more preferentially are COSMOS certified.

[0025] Finally, the formulations created are compatible with whatever perfume or olfactory system is chosen. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0026] Before discussing embodiments of the present invention in detail, optional features are described below which can optionally be used as alternatives or in combination with each other.

[0027] According to one example, the aqueous perfume composition or perfume composition or perfume complex is transparent.

[0028] According to one example, the aqueous perfume composition is in the form of a microemulsion.

[0029] According to one example, the aqueous perfume composition or perfume composition or perfume complex does not contain any ethoxylated solvents.

[0030] According to one example, the method for producing an aqueous fragrance composition comprises the subsequent step of adding a preservative, for example in an amount of 0.8% to 1.2% by weight, preferably in an amount of 1% or less by weight, of the total weight of the composition. Preferentially, the method comprises mixing until homogenization. This preservative is an additive. As usual, additives, especially preservatives, are counted in the amount of water. Preferably, the amount of water stated includes water and any additives, especially additives of preservative type.

[0031] According to one example, the method for producing the aqueous perfume composition includes the steps of maceration, cooling, preferentially at 4° C., and then filtration.

[0032] According to another aspect, the present invention relates to the use of the aqueous perfume composition or perfume composition or perfume complex as described above for fine perfumery.

[0033] According to another aspect, the present invention relates to the use of the aqueous fragrance composition or fragrance composition or fragrance complex described above for cosmetic purposes.

[0034] According to another aspect, the present invention relates to the use of an aqueous fragrance composition or a fragrance composition or a fragrance complex as described above for hygiene products that are intended to be rinsed, such as shower gels, shampoos, etc., or hygiene products that are not intended to be rinsed, such as deodorants, etc.

[0035] According to another aspect, the present invention relates to the use of an aqueous perfume composition or perfume composition or perfume complex as described above for an ambient fragrance or room deodorant or air freshener or cleaning product.

[0036] By "compatible with all types of olfactory systems" it is meant that the composition can contain any type of fragrance for any olfactory system.

[0037] By "high proportion of perfume" it is meant that the aqueous perfume composition may contain up to 10% by weight of the perfume complex.

[0038] By "stable" is meant a composition that does not decompose over time and whose compounds do not react with each other. By "stable" is meant that the composition maintains its uniformity, color, olfactory intensity, olfactory quality, and viscosity.

[0039] More specifically, the compositions according to the invention are stable under accelerated aging after 24 hours under UV (Suntest) and after 2 months at 25°C and 45°C compared to samples kept away from light at 5°C.

[0040] "Ethanol-free" or "isopropanol-free" means a composition that contains 0% ethyl alcohol or 0% isopropyl alcohol by weight.

[0041] "Free of ethoxylated compounds" means a composition containing 0% by weight of ethoxylated compounds, i.e., compounds containing -(-CH2-CH2-O-) units.

[0042] By "transparent" is meant that the composition is transparent at a temperature between 4 and 50° C., whatever the flavoring used. By transparent composition is meant a composition whose turbidity is less than or equal to 12 NTU (Nephelometric Turbidity Units), preferably less than or equal to 7 NTU, preferentially measured by a turbidity meter of the Hanna Instruments brand HI88713 ISO Turbidity Meter type.

[0043] A "good smell" means a smell that is detected by the human sense of smell and is perceived as pleasant.

[0044] "Having a viscosity close to that of water" means that the dynamic viscosity (viscosity) of the composition at 20°C is 1 to 50 mPa·s, preferentially 1 to 40 mPa·s, preferentially 1 to 30 mPa·s, preferentially 1 to 10 mPa.s. According to the present invention, the dynamic viscosity is measured at 20°C, 500 s using a Viscotester IQ viscometer, geometry CC27 DG / TI-01160025. -1 is measured for 30 seconds.

[0045] By "perfume" is meant a composition comprising a mixture of perfumery substances, said perfumery substances being in an isolated state, in solution or suspension, in a common diluent, solvent or co-ingredient, such a composition being intended to provide a pleasant olfactory sensation.

[0046] "Fragrance substance" means one or more fragrance raw materials of natural or synthetic origin.

[0047] By "aqueous fragrance composition" is meant a composition comprising more than 50% water and a fragrance or fragrance complex or fragrance composition.

[0048] "COSMOS certified" means that the complex, fragrance composition, and / or aqueous fragrance composition meets the standards for obtaining the COSMOS label, which will come into effect in 2022.

[0049] Percentage means mass percentage, ie mass relative to the mass of the composite or composition.

[0050] By cosmetic base is meant adult, child, baby or animal lotions, body mists, hair sprays, sunscreens, towelette solutions and the like.

[0051] By detergent base is meant laundry perfume, cleaning perfume, floor perfume, and the like.

[0052] Ambient fragrance means a fragrance composition for a home, car, enclosed public, work, private or environmental space, structure, and the like.

[0053] According to a first aspect, the present invention relates to a perfume complex comprising a perfume, a first solvent, and a second solvent.

[0054] The perfume complex advantageously comprises perfume in an amount of 5-70% by weight, preferentially 5-55%, preferentially 5-50% by weight of the total weight of the perfume complex, the total weight of the perfume complex meaning the sum of the perfume, the first solvent and the second solvent.

[0055] The perfume complex advantageously comprises the first solvent in an amount ranging from 0 to 85% by weight, preferentially from 35 to 85% by weight of the total weight of the perfume complex.

[0056] Preferentially, the first solvent is monopropylene glycol, which has the CAS number 57-55-6.

[0057] Monopropylene glycol is a COSMOS certified hydrophilic vegetable-based solvent used in fragrances. Its chemical formula is: [ka]

[0058] Its logP of -0.92 gives it hydrophilic properties that are particularly advantageous for the formulation of aqueous microemulsions, yet these same hydrophilic properties make it ineffective as a fragrance solvent.

[0059] The perfume complex advantageously comprises the second solvent in an amount ranging from 10 to 30% by weight, optionally from 10 to 20% and even from 10 to 15% of the total weight of the perfume complex.

[0060] Preferentially, the second solvent is caprylyl glycol. Caprylyl glycol is known by the CAS number 1117-86-8. Caprylyl glycol is also known by the names A-Leen8 or 1,2-octanediol. Its chemical formula is: [ka]

[0061] Surprisingly, the Applicant has identified the solvent properties of this raw material known for its preservative properties, which improve its properties: Caprylyl glycol allows the preparation of homogeneous and transparent fragrance compositions.

[0062] Advantageously, the perfume complex is free of water.

[0063] According to one embodiment, the perfume complex is preferentially intended to be used in perfume compositions without added water or in aqueous perfume compositions, i.e. compositions mixed with water.

[0064] Advantageously, the perfume complex comprises from 5 to 70% by weight of perfume, from 0 to 85% by weight of monopropylene glycol and from 10 to 30% by weight of caprylyl glycol, based on the total weight of the perfume complex.

[0065] According to a second aspect, the present invention relates to a perfume complex comprising the above-mentioned perfume complex and a solubilizer.

[0066] Preferentially, the perfume complex comprises a perfume complex in an amount of 25-34% by weight of the total weight of the perfume composition, the total weight of the perfume composition meaning the sum of the perfume complex and the solubilizer.

[0067] Preferentially, the fragrance composition comprises the solubilizer in an amount of at least 66% by weight, preferentially between 66 and 75% by weight, relative to the total weight of the fragrance composition. According to a preferred embodiment, the solubilizer is a mixture of polyglyceryl-6 (caprylic / capric) and sodium (caproyl / lauroyl) lactylate, also known under the name Easytens S2, sold by the company Lavollee and manufactured by the company Hydrior.

[0068] This solubilizer is a mixture of COSMOS surfactants. The solubilizing properties of the molecules contained in this mixture have been studied in order to obtain synergistic effects. This solubilizer makes it possible to obtain very satisfactory results in cutting with perfumes. Moreover, surprisingly, this solubilizer acts synergistically with the solvent selected for the perfume complex, making it possible to obtain clear, homogeneous aqueous solutions. This raw material is suitable as a solubilizer for COSMOS microemulsions. Advantageously, the perfume composition is configured not to foam excessively or to have an excessively high viscosity, parameters that make it difficult to use the perfume composition during the manufacture and / or during the manufacture of aqueous perfume compositions.

[0069] Preferentially, the perfume composition does not comprise additional water. The perfume composition does not comprise water as an ingredient in addition to the other ingredients of the perfume composition.

[0070] Preferentially, the perfume composition comprises from 25 to 34% by weight of the perfume complex relative to the total weight of the perfume composition and at least 66% and preferentially from 66 to 75% by weight of a mixture of polyglyceryl-6 (caprylic / capric) (and) sodium (caproyl / lauroyl) lactylate relative to the total weight of the perfume composition.

[0071] Thus, the fragrance composition 1.25-23.8% flavoring, 0 to 28.9% monopropylene glycol; 2.5 to 10.2% Caprylyl Glycol, A mixture of 66-75% polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate; Includes.

[0072] According to a third aspect, the present invention relates to an aqueous fragrance composition comprising the fragrance composition described above and water.

[0073] Advantageously, the aqueous fragrance composition comprises 20-30% of the above-mentioned fragrance composition. Preferentially, the aqueous fragrance composition comprises the remaining amount of water, preferentially 70-80% of water. The percentages (%) are by weight relative to the total weight of the aqueous fragrance composition. Preferentially, the amount of water includes any additives such as preservatives.

[0074] Advantageously, the aqueous fragrance composition comprises: 5-10% of the above fragrance complex; 13.2 to 22.5%, preferentially at least 13.2%, of a solubilizer, namely the mixture of polyglyceryl-6 (caprylic / capric acid) (and) sodium (caproyl / lauroyl) lactylate as defined above, The supplemental amount to make it 100%, usually about 70-80%, is water. Includes.

[0075] The percentages (%) are by weight based on the total weight of the aqueous fragrance composition.

[0076] Therefore, the aqueous fragrance composition is 0.25 to 7.14% fragrance, 0 to 8.67% monopropylene glycol; 0.5 to 3.06% Caprylyl Glycol, 13.2 to 22.5%, preferentially at least 13.2%, of a mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, 70-80% water, Includes.

[0077] According to one embodiment, the aqueous fragrance composition comprises a preservative. Preferentially, the preservative is present in an amount between 0.8 and 1.2%, preferentially in an amount of less than or equal to 1%. Advantageously, the amount of preservative is defined in the total amount of water.

[0078] Advantageously, the aqueous perfume composition and / or the perfume composition is clear.

[0079] Advantageously, the aqueous perfume composition is a microemulsion.

[0080] An aqueous perfume composition is said to be aqueous because the composition comprises a majority amount of water. Advantageously, the aqueous perfume composition is an oil-in-water microemulsion.

[0081] Advantageously, the aqueous perfume composition and / or the perfume composition is free of ethoxylated solvents.

[0082] Advantageously, the aqueous fragrance composition and / or the fragrance composition is paraben-free.

[0083] Advantageously, the aqueous perfume composition and / or the perfume composition is sulfate-free.

[0084] Advantageously, the aqueous perfume composition has a viscosity similar to that of water, and therefore is light in texture.

[0085] Advantageously, the aqueous fragrance composition is sprayable.

[0086] Advantageously, the aqueous fragrance composition and / or the fragrance composition has emollient properties as it does not dry out the skin.

[0087] Advantageously, the aqueous fragrance composition produces very little foam.

[0088] Advantageously, the aqueous perfume composition and / or the perfume composition is of natural origin.

[0089] Advantageously, the aqueous fragrance composition and / or the fragrance composition is COSMOS certifiable.

[0090] In another aspect, the present invention relates to a method for preparing an aqueous fragrance composition.

[0091] The method includes preparing a perfume complex. The preparation of the perfume complex includes mixing a perfume with a first solvent and a second solvent.

[0092] The method then includes a method for preparing a fragrance composition. This step includes heating a mixture of polyglyceryl-6 (caprylic / capric) acid and sodium (caproyl / lauroyl) lactylate. Heating is carried out by means known to those skilled in the art, for example convection heating by storing in a hot chamber, or conduction heating (bain marie, sand bath, hot plate, double jacket, etc.). Heating is carried out until a usable viscosity is obtained. Advantageously, heating is carried out at a maximum temperature of 65°C.

[0093] The process for preparing the perfume composition includes, after the heating step, mixing the mixture of heated polyglyceryl-6 (caprylic / capric) (and) sodium (caproyl / lauroyl) lactylate with the perfume complex, advantageously without volute, until a homogeneous and transparent perfume composition is obtained.

[0094] The method then comprises the step of preparing an aqueous perfume composition from the previously obtained perfume composition. The perfume composition is mixed with water. The mixing is advantageously carried out without a volute until a homogeneous and transparent aqueous perfume composition is obtained.

[0095] According to one embodiment, the method includes the step of adding a preservative to the aqueous fragrance composition.

[0096] According to one example, the method for producing the aqueous perfume composition comprises, optionally, a maceration step, preferentially for 2 to 4 weeks, followed by a cooling step, preferentially at 4° C., and a filtration step, which is carried out after adding water and preservatives.

[0097] The aqueous fragrance composition can be packaged in many types of packages suitable for receiving aqueous liquid compositions, including, but not limited to, tubes, bottles, sprays, vaporizers, roll-ons, pots, brushes with reservoirs, pencils with reservoirs, etc.

[0098] A fragrance according to the invention may comprise ingredients of preferentially natural origin, and optionally synthetic ingredients. The choice of this fragrance depends firstly on the fragrance effect desired and secondly on the application in which it is to be incorporated.

[0099] Such materials can include esters, ethers, alcohols, aldehydes, ketones, lactones, acetals, nitriles, phenols, acids, terpenes, heterocyclic nitrogen or sulfur compounds, saturated or unsaturated, and naturally occurring complex products, whether of natural or synthetic origin.

[0100] Examples of esters are benzyl acetate, p-tert-butylcyclohexyl acetate, 3,7-dimethyl-1,6-octadien-3-yl acetate (linalyl acetate), dimethyl-benzyl-carbinyl acetate, phenylethyl acetate, 1,1-dimethyl-2-phenylethyl acetate, linalyl benzoate, ethyl-methyl-phenylglycinate, allyl cyclohexyl propionate, styrallyl propionate, benzyl salicylate, methyl-3-oxo-2-pentyl cyclopentane acetate, prop-2-enyl-2,3 -Methylbutoxyacetate (allylamyl glycolate, 3-methylbutoxy-acetic acid, 2-propenyl ester), phenylmethyl acetate, isoamyl acetate (isopentyl acetate), cis-hex-3-yl acetate ((Z)-hex-3-enyl acetate), citronellyl acetate (3,7-dimethyl-6-octen-1-ol acetate), hexyl acetate, isobornyl acetate (bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethylexo-acetate), methanil acetate, (alpha,alpha,4-trimethylcyclohexyl methyl acetate), ethyl acetate, prenyl acetate (3-methyl-2-butenyl acetate), triethyl citrate, 4-tert-butylcyclohexyl acetate, (3R-(3alpha,3abeta,6alpha,7beta,8aalpha))-octahydro-3,6,8,8-tetramethyl-1H-3a-7-methanoazulen-5-yl acetate, 3,7-dimethylocta-1,6-dien-3-yl acetate, 1,4-dioxacyclohexadecane-5,16-dione, Benzyl 2-hydroxybenzoate, (Z)-3-hexenyl-2-hydroxybenzoate, 2-(1,1(dimethylethyl)cyclohexyl acetate, isopentyl acetate, methyl phenyl acetate, (Z)-hex-3-enyl acetate, 3,7-dimethylocta-1,6-dien-3-yl acetate, 3-methyl-2-butenyl acetate, alpha-methyl-benzenemethanol acetate, methyl 2-aminobenzoate, 2-propenyl-(cyclohexyloxy)acetate, methyl 2,4-dihydroxy-3,6-Dimethylbenzoate, methyl 3-oxo-2-pentylcyclopentane acetate, 3-alpha,4,5,6,7,7-alpha-hexahydro-4,7-methano-1H-inden-6-ylpropanoate, methyl 3-oxo-2-pentylcyclopentane acetate, 2-(1,1-dimethylethyl)cyclohexyl acetate, hexyl-2-hydroxybenzoate, (benzoic acid 2-hydroxy-2-hexyl ester), 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl Acetate, Ethyl 2-Methylbutyrate 3a,4,5,6,7,7a-Hexahydro-4,7-methano-1H-inden-5-yl, 2-Methylpropanoate, Alpha,Alpha-Dimethylphenethyl Acetate, 3,7-Dimethylocta-1,6-dien-3-yl Acetate, Exo(d'exo)-1,7,7-Trimethyl-bicyclo[2.2.1]heptan-2-ol Acetate, Ethyl Hexanoate, 3,7-Dimethylocta-1,6-dien-3-yl Acetate, Methyl 3-Oxo-2-pentylsilyl Clopentane acetate, methyl 2-(methylamino)benzoate, 10-undecenoic acid, ethyl ester, ethyl 2-methylpentanoate, cis-3,7-dimethyl-2,6-octadienyl ethanoate, benzyl 2-hydroxybenzoate, (Z)-hex-3-enyl acetate, benzoic acid 2-hydroxy-2-hexyl ester, prop-2-enyl-2-cyclohexyloxy acetate (2-propenyl-(cyclohexyloxy)acetate), acetic acid (3-methylbutoxy), 2-propenyl ethanoate ester, 2-phenylethanol, hexyl acetate, (1R,2S,5R)-5-methyl-2-(1-methylethyl)-cyclohexanol ethanoate, terpenyl acetate (4-methyl-1-propan-2-yl-1-cyclohex-2-enyl acetate), alpha-3,3-trimethylcyclohexyl-methyl formate, 3-methylbutyl butanoate (isoamyl butyrate), alpha,alpha-dimethylphenethyl butanoate, 3-dihydrodicyclopentadiene-2,3-yl acetate, prop-2-enyl, 3-cyclohexyl propanoate (allyl cyclohexane propionate), allyl heptanoate (2-propenyl heptanoate), 2-phenoxy-ethyl 2-methyl propanoate (phenoxyethyl isobutyrate), ethyl 2-methyl-pentanoate, ethyl 2-methyl-butyrate (2-methyl-butanoic acid ethyl ester), 1,4-dioxacycloheptadecane-5,17-dione (ethylene brassylate), (2S)-2-propanol Pyr-1,1-dimethylpropoxypropionate, ((2S)-2-(1,1-dimethylpropoxy)-propanoic acid propyl ester), 2-tert-butylcyclohexyl acetate (2-(1,1-dimethylethyl)cyclohexyl acetate), cis-3-hexenyl salicylate, [(1S)-3-(4-methylpent-3-enyl)-1-cyclohex-3-enyl]methyl acetate, 3-pentyltetrahydro[2H]pyranyl acetate, linalyl propionate, cetyl a Acetate, cedryl acetate, anisyl acetate, nopyr acetate, neryl acetate, 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate, 3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-inden-6-yl propanoate, 2-propenyl 3-cyclohexanepropanoate, 1,2,3-triethyl 2-hydroxypropane-1,2,3-tricarboxylate, (2E)-3,7-dimethylocta-2,6-diene -1-yl acetate, 3,5,5-trimethylhexyl acetate, 3,7-dimethylocta-1,6-dien-3-yl acetate, cis-3,7-dimethyl-2,6-octadienyl ethanoate, tetradecanoic acid 1-methylethyl ester, 2-hydroxy-benzoic acid 3-methylbutyl ester, 2-hydroxy-benzoic acid phenylmethyl ester, 2-hydroxy-benzoic acid 2-hexyl ester, 2-hydroxy-benzoic acid methyl ester, acetoacetique acid ethyl ester, 3,7-dimethylocta-1,6-dien-3-yl acetate, 1,2-benzenedicarboxylic acid 1,2-Diethyl ester, (Z)-hex-3-enyl 2-methylpropanoate, (4-methyl-1-propan-2-yl-1-cyclohex-2-enyl)acetate, 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate, ethyl 2,3-epoxy-3-phenylbutyrate, methyl 2-aminobenzoate, methyl 2-(methylamino)benzoate, methyl benzoate, methyl 2,4-dihydroxy-3,6- Examples include, but are not limited to, dimethyl benzoate, (3R-(3alpha,3beta,6beta,7beta,8alpha))-octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methanoazulene acetate, hexyl salicylate, 4-tert-butylcyclohexyl) acetate, methyl palmitate, 1,6-octadien-3-ol, 3,7-dimethyl-acetate, and triethyl citrate. Preferred examples of esters include linalyl propionate, cetyl acetate, cedryl acetate, anisyl acetate, nopyr acetate, neryl acetate, hexyl acetate (3R-(3alpha,3beta,6beta,7beta,8alpha))-octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methanoazulene, hexyl salicylate, 4-tert-butylcyclohexyl) acetate, methyl palmitate, 1,6-octadien-3-ol, 3,7-dimethyl-acetate, linalyl acetate, and triethyl citrate.

[0101] Examples of ethers include benzyl ether, ethyl ether, ambergris, diphenyl oxide, 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene, and ambercaran. carane), 1,1-dimethoxy-2,2,5-trimethyl-4-hexene, 3,4,4a,5,8,8a-hexahydro-3',7'-dimethylspiro(1,4-methanonaphthalene-2(1H),2'-oxirane), 2,4,6-trimethyl-4-phenyl-1,3-dioxane, benzene, 1,1'-oxybis, methyl 2-naphthyl ether, ethyl 2-naphthyl ether, 2,4-dimethyl-4-phenyltetrahydrofuran, (ethoxymethoxy)cyclododecane, (E)-1-methoxy-4-(1-propenyl)-benzene, 1-methoxy-4-(2-propenyl)-benzene, methyl cedryl ether, and 2-naphthyl ethyl ether. Preferred examples of ethers include 1,1-dimethoxy-2,2,5-trimethyl-4-hexene, methyl cedryl ether, and 2-naphthyl ethyl ether.

[0102] Examples of alcohols include menthol ([1R-(1alpha,2beta,5alpha)]-5-methyl-2-isopropylcyclohexanol), citronellol, geraniol, linalool (e.g., ethyl linalool and tetrahydrolinalool), phenylethyl alcohol, terpineol, 2,6-dimethylheptan-2-ol, 2-methyl-1-phenylpropan-2-ol (dimethylphenylcarbinol), 3-methyl-5-[2,2 ,3-Trimethylcyclopent-3-en-1-yl]pent-4-en-2-ol, 2-phenylethanol, 2-ethyl-4-(2,2,3-trimethyl-1-cyclopent-3-enyl)but-2-en-1-ol, (E)-4-methyldec-3-en-5-ol, cinnamic alcohol (3-phenyl-2-propen-1-ol), 3,7-dimethyl-6-octen-1-ol, p-menth-1-en-8-ol, cis-hex-3-en- 1-ol, 4-methyl-3-decen-5-ol, 2,6-dimethyloct-7-en-2-ol, 1,1'-oxydipropan-2-ol, 3,7-dimethyl-1,6-nonanedien-3-ol, 1,1'-oxydipropan-2-ol, 2,6-dimethyloct-7-en-2-ol, 3,7-dimethylocta-1,6-dien-3-ol, 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1- ol, phenylmethanol, 4-methyl-3-decen-5-ol, 2,6-dimethyloctan-2-ol, 3,7-dimethyl-6-octen-1-ol, 4-(1,1-dimethylethyl)-cyclohexanol, (2E)-3,7-dimethyl-2,6-octadien-1-ol, hexan-1-ol, exo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol, 2-(2,2,7,7-tetramethyltricyclo[6.2.1.0(1,6)]undec-5(4)-en-5-yl)propan-1-ol, 1-phenylethanol, 1,1'-oxydipropan-2-ol, 3,7-dimethyloctan-3-ol, cis-3,7-dimethyl-2,6-octadien-1-ol, 3,7-dimethyl-6-octen-1-ol, hex-2-en-1-ol, 3,7-dimethylocta-1,6-dien-3-ol, 2-methyl-4-phenylbutan-2-ol 2,6-Octadien-1-ol, 3,7-Dimethyl-, (2E)-, p-Menth-1-en-8-ol, 3-Phenylpropan-1-ol, Phenylmethanol, 2,6-Dimethyloct-7-en-2-ol, alpha, beta, 2,2,3-Pentamethylcyclopent-3-en-1-butanol, 3-(5,5,6-Trimethylbicyclo[2.2.1]hept-2-yl)cyclohexan-1-ol (IBCH), cis -3-Hexen-1-ol, methyl-trimethylbicyclo-hexylmethyl-cyclopropylmethanol benzyl alcohol, endo-1,7,7-trimethyl-bicyclo-[2.2.1]heptan-2-ol, 3,7-dimethyl-6-octen-1-ol, 3,7-dimethyl-1-octanol, (2E)-3,7-dimethyl-2,6-octadien-1-ol, cis-3,7-dimethyl-2,6-octadien-1-ol, ... ,7-dimethylocta-1,6-dien-3-ol, 2-(4-methyl-1-cyclohex-3-enyl)propan-2-ol, 4-methyl-1-(1-methylethyl)-3-cyclohexen-1-ol, (1R,2S,5R)-5-methyl-2-(1-methylethyl)-cyclohexanol, (2E)-3,7-dimethyl-2,6-octadien-1-ol, and 3-methylbutan-1-ol. Preferably, examples of alcohols include alpha, beta, 2,2,3-pentamethylcyclopent-3-ene-1-butanol, 3-(5,5,6-trimethylbicyclo[2.2.1]hept-2-yl)cyclohexan-1-ol (IBCH), cis-3-hexenol, methyl-trimethylbicyclo-hexylmethyl-cyclopropylmethanol, 3-methylbutan-1-ol, ethyl linalool, tetrahydrolinalool, and [1R-(1alpha,2beta,5alpha)]-5-methyl-2-isopropylcyclohexanol (menthol).

[0103] Examples of aldehydes include linear alkanals having 8 to 18 carbon atoms, 3,7-dimethyl-2,6-octadienal (citral), citronellal, cyclamen aldehyde, hydroxycitronellal, 3,7-dimethyl-2,6-octadienal, undecanal, alpha-methyl-4-(1-methylethyl)-benzenepropanal, 3-(4-isopropylphenyl)-2-methylpropanal, 2,4-dimethylcyclohex-3-ene-1-carbaldehyde, and 2,4-dimethylcyclohex-3-ene-1-carbaldehyde. , (2E)-2-dodecenal, octanal, lauryl aldehyde, nonanal, (E)-2-benzylidene octanal, 2,4-dimethylcyclohex-3-ene-1-carbaldehyde, 3-(4-ethylphenyl)-2,2-dimethylpropanal, 4-hydroxy-3-methoxybenzaldehyde, 3-(4-tert-butylphenyl)-2-methylpropanal, 3-(4-tert-butylphenyl)propanal, 2,6,10-trimethylundec-9-enal, 4(octahydro-4,7-methano[5H]ine 3-(3-propan-2-ylphenyl)butanal, 7-hydroxy-3,7-dimethyloctanal (hydroxycitronellal, 3,7-dimethyl-7-hydroxy-octan-1-al), 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde, octahydro-5-methoxy-4,7-methano-1H-indene-2-carboxaldehyde, alpha-methylcinnamaldehyde (2-methyl-3-phenyl-2-propenal), 4-methoxybenzaldehyde, Anisaldehyde, C10 aldehyde (decanal), undec-10-enal, C12 aldehyde (lauric acid or dodecanal), methyl-nonylacetaldehyde (2-methylundecanal), C16 aldehyde, C6 aldehyde (hexanal), cinnamic aldehyde (3-phenyl-2-propenal), 3-ethoxy-4-hydroxybenzaldehyde (ethyl vanillin), hexylcinnamic aldehyde (2-benzylideneheptanal), 3-phenylbutanal (3-phenylbutyraldehyde), 2,These include, but are not limited to, 4-dimethylcyclohex-3-ene-1-carbaldehyde, 5-heptanal, 2,6-dimethylhept-5-enal, 4-hydroxy-3-methoxybenzaldehyde (vanillin), alpha-methyl-1,3-benzodioxole-5-propionaldehyde, 4-isopropylbenzaldehyde, 3,7-dimethyl-6-octenal, 3,7-dimethyl-2,6-octadienal, 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde, trans-hex-2-enal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 2-(4-tert-butylbenzyl)propionaldehyde, and benzaldehyde. Preferred examples of aldehydes include 2,4-dimethylcyclohex-3-ene-1-carbaldehyde, 5-heptanal, 2,6-dimethyl-hept-5-enal, 4-hydroxy-3-methoxybenzaldehyde (vanillin), alpha-methyl-1,3-benzodioxole-5-propionaldehyde, citral, and benzaldehyde.

[0104] Examples of ketones include ionone, isomethylionone, methyl cedryl, (E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-2-en-1-one (alpha-damascone), 3-methyl-2-[(2Z)-pent-2-en-1-yl]cyclopent-2-en-1-one (cis-jasmone), 4-(4-methoxyphenyl)-butan-2-one, 4(3)-(4-methylpent-3-enyl)cyclohex-3-enecarbaldehyde, 1-(1,2,3,4,5,6,7,8-octahydro-2-phenyl-1,2-diphenyl-2,3-di ... ,3,8,8-tetramethyl-2-naphthalenyl)ethanone, 3-methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-3-buten-2-one, (E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, E)-4-(2,6,6-trimethylcyclohex-2-enyl)-but-3-en-2-one, 7-methyl-2H-benzo-1,5-dioxepin-3(4H)-one, 1-(2,6,6-trimethyl-1,3-cyclohexadienyl)-2-buten-1-one, methyl Hydroxypyrone, 2,2,5-trimethyl-5-pentylcyclopentan-1-one, 1-(5,5-dimethyl-1-cyclohexenyl)pent-4-en-1-one, 3-methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-3-buten-2-one, 2-[2-(4-methyl-3-cyclohexen-1-yl)propyl]-cyclopentanone, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone, (E)-4-(2,6,6-trimethyl-1-cyclopentan-1-one cyclohexen-1-yl)-3-buten-2-one, 4-phenylbutan-2-one, 2-cyclohexyl-1,6-heptadiene-3-one, 1-(5,5-dimethyl-1-cyclohexenyl)pent-4-en-1-one, 2-buten-1-one, 1-(2,6,6-trimethyl-3-cyclohexen-1-yl)-, 2H-1-benzopyran-2-one, 1-spiro(4.5)-7-decen-7-yl-4-penten-1-one and 1-spiro(4.5)-6-decen-7-yl-4-penten-1-one, (E)1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, (E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, dihydro-5-pentyl-2(3H)-furanone, 2,2,5-trimethyl-5-pentylcyclopentan-1-one, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone, methyl cedryl ketone, 7-methylbenzo[b][1,4]dihydro ... Oxepin-3-one, 1,7,7-trimethylbicyclo[2,2,1]heptan-2-one, 1-benzopyran-2-one (coumarin), 1-(2,6,6-trimethyl-1-cyclohex-3-enyl)but-2-en-1-one, butane-2,3-dione (diacetyl), 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8,-tetramethyl-2-naphthyl)ethan-1-one, irone, 1-(2-naphthalenyl)ethanone (2-acetonaphthone), menthone , Carvone, 3-Methyl-2-pentyl-2-cyclopentenone, 1-(2,6,6-trimethyl-3-cyclohexen-1-yl)-2-buten-1-one, 1-(2,6,6-trimethyl-2-cyclohexenyl)hepta-1,6-dien-3-one, 2-Ethyl-3-hydroxy-4H-pyran-4-one, (5R)-2-Methyl-5-prop-1-en-2-ylcyclohex-2-en-1-one, 1-(6-tert-butyl-1,1-dimethyl-2,3-dihydro-1H -inden-4-yl)ethanone, 1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one, 4-(2,6,6-trimethylcyclohex-2-enyl)-but-3-en-2-one, octan-2-one, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one, and 1,3,4,6,7,8a-hexahydro-1,1,5,5-tetramethyl-2H-2,Examples of ketones include, but are not limited to, 4a-methanonaphthalene-8(5H)-one. Preferred examples of ketones include irone, 1-(2-naphthalenyl)ethanone (2-acetonaphthone), menthone, carvone, 3-methyl-2-pentyl-2-cyclopentene, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one, and 1,3,4,6,7,8a-hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalene-8(5H)-one.

[0105] Examples of lactones include, but are not limited to, gamma decalactone (decane-4-olide, 4-decanolide), decan-5-olide (5-undecanolide), decan-4-olide (4-decanolide), undecane-4-olide gamma undecalactone (undecane-4-olide) (4-undecanolide), cis-jasmone lactone, gamma undecalactone, delta octalacone, delta decalactone, and hexahydro-3,6-dimethyl-2(3H)-benzofuranone.Preferably, examples of lactones include gamma undecalactone, delta octalacone, delta decalactone, and hexahydro-3,6-dimethyl-2(3H)-benzofuranone.

[0106] Examples of acetals include, but are not limited to, 2,4-dimethyltetrahydroindenodioxine, aldehyde phenylacetic acid diacetal, phenylacetaldehyde glyceryl acetal, citral diethyl acetal, citral dimethyl acetal, 2,6-octadienal, 1,1-dimethoxy-2-phenylethane, and 3,7-dimethyl isomerise acid.Preferably, examples of acetals include phenylacetaldehyde glyceryl acetal, citral diethyl acetal, citral dimethyl acetal, 2,6-octadienal, and 3,7-dimethyl isomerise acid.

[0107] Examples of nitriles include, but are not limited to, 3,7-dimethyloct-6-enenitrile (citronellylnitrile), tridec-2-enenitrile, 3-phenyl-2-propenenitrile, 3,7-dimethyl-6-enenitrile, dodecanenitrile, and 3,7-dimethylnona-2,6-dienenitrile.Preferably, examples of nitriles include tridec-2-enenitrile, 3-phenyl-2-propenenitrile, dodecanenitrile, and 3,7-dimethylnona-2,6-dienenitrile.

[0108] Examples of phenols include, but are not limited to, eugenol (2-methoxy-4-(2-propenyl)-phenol), isoeugenol, 5-methyl-2-(1-methylethyl)-phenol, 2-ethoxy-4-methylphenol, 2-isopropyl-5-methylphenol, 5-methyl-2-(1-methylethyl)-phenol, 2,6-di-tert-butyl-p-cresol, and 2-ethoxy-4-(methoxymethyl)-phenol.

[0109] Examples of acids include, but are not limited to, pentanoic acid, butyric acid, and 2-methylpent-2-enoic acid-1.

[0110] Examples of terpenes, such as cyclic terpene hydrocarbons (e.g., sesquiterpenes) or acyclic terpene hydrocarbons, include limonene, 1-methyl-4-isopropenyl-1-cyclohexene, 1-methyl-4-isopropyl-1,4-cyclohexadiene, 7-methyl-3-methyleneocta-1,6-diene, 1-methyl-4-(1-methylethyl)-1,3-cyclohexadiene, 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene, 6,6- Dimethyl-2-methylenebicyclo[3.1.1]heptane, 2,2-dimethyl-3-methylenebicyclo-[2.2.1]heptane, (3R-(3alpha,3abeta,6beta,7beta,8aalpha))-octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methanoazulene, 4,11,11-trimethyl-8-methylene-(1R,4E,9S)-bicyclo[7.2.0.]undec-4-ene, [1R,(1R * ,4E,9S * )]-4,11,11-trimethyl-8-methylene-bicyclo[7.2.0]undec-4-ene, 1-methyl-4-(1-methylethyl)benzene, and sesquiterpene essential oils. Preferably, examples of terpenes include sesquiterpene essential oils.

[0111] Examples of saturated or unsaturated heterocyclic nitrogen or sulfur compounds include, but are not limited to, indole, 1,3-benzopyrrole, tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, 2-methyl-pyrazine, 4-methyl-5-hydroxyethylthiazole (2-(4-methylthiazol-5-yl)ethanol), 6-tert-butylquinoline, 6-(isopropyl)quinoline, (3aR-(3aalpha,5abeta,9aalpha,9bbeta))-dodecahydro-3a,6,6,9a-tetramethylnaphtho(2,1-b)furan, 2-isopropyl-4-methyl-1,3-thiazole, cis-2-methyl-4-propyl-1,3-oxathiane, 6(8)-(1-methylpropyl)quinoline, and pyrazine. Preferably, heterocyclic nitrogen or sulfur compounds, saturated or unsaturated, include 6-tert-butylquinoline, 6-(isopropyl)quinoline, cis-2-methyl-4-propyl-1,3-oxathiane, 6(8)-(1-methylpropyl)quinoline, and pyrazine.

[0112] Examples of naturally derived complex products include, but are not limited to, essential oils extracted from various parts of plants (flowers, stems, leaves, fruits, bark, roots, woody parts, herbs, needles, sap, and gums), resinoids, and concretes or absolutes derived therefrom. Examples of preferably naturally derived complex products include Artemisia herba alba oil, Patchouli leaf oil, Mandarin orange peel oil, Barosma betulina leaf extract, Citrus limon (Lemon) peel extract, Eucalyptus leaf oil, Dipterocarpus turbinatus balsam oil, Patchouli leaf oil, Rosemary leaf oil, Juniperus officinalis oil, Mentha leaf oil, Spearmint oil, Citrus orange peel oil, Citrus orange peel extract, Italian cypress leaf oil, Patchouli (Pogostemon cablin) leaf oil, Texas cedar (Juniperus mexicana) oil, and Lavandula Hybrida oil.

[0113] The aqueous fragrance composition may optionally contain one or more additional ingredients selected from solvents, diluents, additives, excipients, etc. The ingredients and their appropriate amounts are well known to those skilled in the art.

[0114] According to a particular embodiment, the aqueous fragrance composition according to the invention further comprises at least one additive selected from antifoaming agents, antioxidants, chelating agents, UV filters, preservatives, thickeners, cosmetic actives, hydrating agents, moisturizing agents, softeners, pigments, dyes, refrigerants, pH adjusters, germicides, bacteriostats, insecticides, repellents, brighteners, activators, and mixtures thereof. Preferentially, the amount of water added is derived from the amount of these additives such that the sum of water and optional additives falls within the range of water amounts mentioned above.

[0115] The embodiments detailed above can be easily combined with each other in a non-limiting manner. EXAMPLES

[0116] Example 1: Spice No.1 To obtain Fragrance No. 1, the ingredients listed in Table 1 are mixed.

[0117] [Table 1]

[0118] Example 2: Aqueous fragrance composition No.1 To obtain Aqueous Fragrance Composition No. 1, the ingredients listed in Table 2 are mixed.

[0119] [Table 2]

[0120] The aqueous perfume composition according to the present invention is clear and homogeneous.

[0121] Aqueous fragrance composition 1 is formulated with a fragrance complex containing 51% fragrance No. 1, 10% caprylyl glycol, and 39% monopropylene glycol. The percentages are expressed by weight relative to the total weight of the three components. Then, 10% of the fragrance complex is mixed with 20% of a mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, preferentially heated. Finally, 69% of water is added to the mixture to obtain aqueous fragrance composition 1. The percentages are expressed by weight relative to the total weight of the aqueous fragrance composition.

[0122] The preservatives used are water-soluble, transparent preservatives that comply with the COSMOS Charter in force in 2022. The preservative selected is Epsan C.

[0123] Example 3: Spice No.2 To obtain Fragrance No. 2, the ingredients listed in Table 3 are mixed.

[0124] [Table 3]

[0125] Example 4: Aqueous fragrance composition No. 2~4 To obtain aqueous fragrance compositions Nos. 2 to 4, the components shown in Table 4 are mixed.

[0126] [Table 4]

[0127] The aqueous fragrance compositions 2, 3, 4 are formulated with a fragrance complex containing 81% or 70% fragrance No. 2, 0% or 10% or 30% caprylyl glycol, and 0% or 9% or 19% monopropylene glycol. The percentages (%) are expressed by weight, relative to the total weight of the three components. Then, 10% of the fragrance complex is mixed with 20% of a mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, preferentially heated. Finally, 69% of water is added to the mixture to obtain the aqueous fragrance compositions 2, 3, 4. The percentages (%) are expressed by weight, relative to the total weight of the aqueous fragrance composition. The preservatives used are water-soluble and transparent preservatives that comply with the COSMOS Charter in force in 2022. The preservative selected is Epsan C.

[0128] From these various aqueous fragrance compositions, it is evident that the solvent caprylyl glycol (A-Leen 8) is responsible for obtaining clear, homogeneous compositions.

[0129] Aqueous perfume composition 4 is prepared using the maximum amount of perfume in the perfume complex, ie 70% by weight of the total weight of the perfume complex, ie 7% by weight of the total weight of the final aqueous perfume composition 4.

[0130] This aqueous perfume composition is prepared using the maximum amount of A-Leen 8 in the perfume complex, i.e. 30% by weight of the total weight of the perfume complex, i.e. 3% by weight of the total weight of the final aqueous perfume composition 4.

[0131] This aqueous perfume composition is prepared with a minimal amount of monopropylene glycol in the perfume complex, i.e. 0% by weight of the total weight of the perfume complex, i.e. 0% by weight of the total weight of the final aqueous perfume composition 4.

[0132] The aqueous perfume composition 4 according to the present invention is transparent and homogeneous.

[0133] Example 5: Spice No.3 To obtain Fragrance No. 3, the ingredients listed in Table 5 are mixed.

[0134] [Table 5A]

[0135] [Table 5B]

[0136] (Example 6): Aqueous fragrance composition No.5 To obtain Aqueous Fragrance Composition No. 5, the ingredients listed in Table 6 are mixed.

[0137] [Table 6]

[0138] The aqueous fragrance composition 5 is formulated with a fragrance complex containing 5% fragrance No. 3, 15% caprylyl glycol, and 80% monopropylene glycol. The percentages are expressed by weight, relative to the total weight of the three components. Then, 10% of the fragrance complex is mixed with 20% of a mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, preferentially heated. Finally, 69% of water is added to the mixture to obtain the aqueous fragrance composition No. 5. The percentages are expressed by weight, relative to the total weight of the aqueous fragrance composition. The preservatives used are water-soluble and transparent preservatives that comply with the COSMOS Charter in force in 2022. The preservative chosen is Epsan C.

[0139] This aqueous perfume composition is prepared using a minimal amount of monopropylene glycol in the perfume complex, namely 5% by weight of the total weight of the perfume complex, i.e. 0.5% by weight of the total weight of the final aqueous perfume composition 5.

[0140] The aqueous fragrance compositions according to the present invention are clear and homogeneous.

[0141] Example 7: Spice No.4 To obtain Fragrance No. 4, the ingredients listed in Table 7 are mixed.

[0142] [Table 7A]

[0143] [Table 7B]

[0144] (Example 8): Aqueous fragrance composition No.6 To obtain Aqueous Fragrance Composition No. 6, the ingredients listed in Table 8 are mixed.

[0145] [Table 8]

[0146] The aqueous fragrance composition 6 is formulated with a fragrance complex containing 5% fragrance No. 4, 10% caprylyl glycol, and 85% monopropylene glycol. The percentages are expressed by weight relative to the total weight of the three components. Then, 10% of the fragrance complex is mixed with a mixture of 20% polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, preferentially heated. Finally, 69% of water is added to the mixture to obtain the aqueous fragrance composition 6. The percentages are expressed by weight relative to the total weight of the aqueous fragrance composition. The preservatives used are water-soluble and transparent preservatives that comply with the COSMOS Charter in force in 2022. The preservative selected is Epsan C.

[0147] This aqueous perfume composition is prepared using the maximum amount of A-Leen 8 in the perfume complex, i.e. 10% by weight of the total weight of the perfume complex, i.e. 1% by weight of the total weight of the final aqueous perfume composition No. 6.

[0148] This aqueous perfume composition is prepared using the maximum amount of monopropylene glycol in the perfume complex, i.e. 85% by weight of the total weight of the perfume complex, i.e. 8.5% by weight of the total weight of the final aqueous perfume composition No. 6.

[0149] The aqueous fragrance compositions according to the present invention are clear and homogeneous.

[0150] (Example 9): Aqueous fragrance composition No.7 To obtain Aqueous Fragrance Composition No. 7, the ingredients listed in Table 9 are mixed.

[0151] [Table 9]

[0152] Aqueous fragrance composition 7 is formulated from a fragrance complex containing 59.17% fragrance No. 1, 10% caprylyl glycol, and 30.83% monopropylene glycol. Then, 12% of the fragrance complex is mixed with 18% of a mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, preferentially heated. Finally, 69% of water is added to the mixture to obtain aqueous fragrance composition 7.

[0153] The preservatives used are water-soluble, transparent preservatives that comply with the COSMOS Charter in force in 2022. The preservative chosen is Epsan C.

[0154] This aqueous perfume composition is prepared using a lower amount of Easytens S2 solubilizer than the inventors would have preferred, namely 18% by weight of the total weight of the final aqueous perfume composition No. 7.

[0155] This aqueous fragrance composition is not clear.

[0156] (Example 10): Aqueous fragrance composition No.8 To obtain Aqueous Fragrance Composition No. 8, the ingredients listed in Table 10 are mixed.

[0157] [Table 10]

[0158] Aqueous fragrance composition 8 is formulated from a fragrance complex containing 59.17% fragrance No. 1, 16.67% caprylyl glycol, and 24.16% monopropylene glycol. Then, 12% of the fragrance complex is mixed with 18% of a mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, preferentially heated. Finally, 69% of water is added to the mixture to obtain aqueous fragrance composition 8.

[0159] The preservatives used are water-soluble, transparent preservatives that comply with the COSMOS Charter in force in 2022. The preservative chosen is Epsan C.

[0160] This aqueous perfume composition is prepared using a lower amount of Easytens S2 solubilizer than the inventors selected, namely 18% by weight of the total weight of the final aqueous perfume composition No. 8.

[0161] The aqueous fragrance composition is not clear.

[0162] The present invention is not limited to the above-described embodiments, but includes all embodiments and applications falling within the scope of this application.

Claims

1. Ingredients below: - 25-34% of a fragrance complex containing the following ingredients: 5-70% fragrance, 10-30% caprylyl glycol as solvent, 0-85% monopropylene glycol as solvent (the percentages (%) being expressed by weight relative to the total weight of said three ingredients) and not including water; and - 66-75% mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate, and their percentages (%) are expressed by weight relative to the total weight of the above two components.

2. - 20 to 30% of a fragrance composition according to claim 1, and - 70-80% water, and their percentages (%) are expressed by weight relative to the total weight of the two components.

3. 3. The aqueous fragrance composition of claim 2 in the form of a microemulsion.

4. 3. The aqueous fragrance composition of claim 2, which is transparent.

5. The fragrance composition of claim 1 which is transparent.

6. 3. The aqueous fragrance composition of claim 2, which is free of ethoxylated solvents.

7. 10. The fragrance composition of claim 1, which is free of ethoxylated solvents.

8. 3. The aqueous fragrance composition of claim 2, which is naturally derived.

9. The fragrance composition of claim 1 which is of natural origin.

10. A method for producing the fragrance composition according to any one of claims 1, 5 and 7, comprising the steps of: - preparing a perfume complex as defined in the corresponding claim 1, 5 or 7, - heating a mixture of polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate; - adding a mixture of heated polyglyceryl-6 caprylic / capric acid and sodium caproyl / lauroyl lactylate to said fragrance complex; and - homogenizing the obtained flavor composition; A method comprising:

11. A method for producing the aqueous fragrance composition according to any one of claims 2, 3, 4, 6 and 8, comprising the steps of: - adding water to the fragrance composition of claim 1; and - homogenizing the aqueous fragrance composition obtained; A method comprising:

12. 12. The process of claim 11, comprising the subsequent step of adding a preservative.

13. The method of claim 11, which may optionally include subsequent soaking, icing, and then filtering steps.

14. 10. Use of the aqueous fragrance composition according to any one of claims 2, 3, 4, 6 and 8 as all or part of a cosmetic base or a fine perfume product or a cleaning base or an ambient fragrance.

15. 10. Use of the fragrance composition according to any one of claims 1, 5, 7 and 9 as all or part of a cosmetic base or a fine perfume product or a cleaning base or an ambient fragrance.

16. A cosmetic base, a cleansing base, or an ambient fragrance comprising the aqueous fragrance composition of any one of claims 2, 3, 4, 6, and 8.

17. A cosmetic base, a cleansing base, or an ambient fragrance comprising the fragrance composition of any one of claims 1, 5, 7, and 9.

18. 17. Use of a cosmetic base, a cleansing base, or an ambient fragrance according to claim 16 to mask malodours.

19. 20. Use of a cosmetic base, a cleansing base, or an ambient fragrance according to claim 17 to mask malodours.

Images